# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2015

data_mv_2_38Tb_A        
_publ_contact_author_name        'Dr Colette Boskovic'
_publ_contact_author_address     
;School of Chemistry
University of Melbourne
Parkville 3010, VIC 
Australia
;
_publ_contact_author_email       c.boskovic@unimelb.edu.au
loop_
_publ_author_name
_publ_author_address
'Vonci, Michele' ''
'Giansiracusa, Marcus J.' ''
'Gable, Robert W.' ''
'Van den Heuvel, Willem ' ''
'Latham, Kay' ''
'Moubaraki, Boujemaa' ''
'Murray, Keith S.' ''
'Yu, Dehong' ''
'Mole, Richard A.' ''
'Soncini, Alessandro' ''
'Boskovic, Colette' ''
_audit_creation_date             
;
'Fri Feb 13 10:28:49 2015'
;
_audit_creation_method           
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_publ_section_references         
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2008). Acta Cryst. A64, 112-122.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
;
_chemical_name_systematic        'Sodium terbium tungsten oxide hydrate'
_chemical_name_common            ?
_chemical_formula_moiety         'Na9 O68 Tb W10, 3(O)'
_chemical_formula_sum            'H70 Na9 O71 Tb W10'
_chemical_formula_weight         3410.89
_chemical_melting_point          ?
_exptl_crystal_description       'flat blades'
_exptl_crystal_colour            'clear light colourless'
_diffrn_ambient_temperature      130.01(10)
_diffrn_ambient_pressure         101
_chemical_oxdiff_formula         'Tb W10 O71 H70 Na9'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Na Na 0.1353 0.1239 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -9.1472 9.1891 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -5.4734 5.5774 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_symmetry_space_group_name_H-M_alt 'P -1'
_cell_length_a                   12.7251(4)
_cell_length_b                   13.0624(4)
_cell_length_c                   20.4974(7)
_cell_angle_alpha                82.857(3)
_cell_angle_beta                 74.521(3)
_cell_angle_gamma                88.927(3)
_cell_volume                     3257.65(19)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    11292
_cell_measurement_temperature    130.01(10)
_cell_measurement_theta_max      71.6930
_cell_measurement_theta_min      4.2960
_cell_oxdiff_angle_alpha         82.857(3)
_cell_oxdiff_angle_beta          74.521(3)
_cell_oxdiff_angle_gamma         88.927(3)
_cell_oxdiff_length_a            12.7251(4)
_cell_oxdiff_length_b            13.0624(4)
_cell_oxdiff_length_c            20.4974(7)
_cell_oxdiff_measurement_reflns_used 11292
_cell_oxdiff_volume              3257.65(19)
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    38.720
_exptl_absorpt_correction_T_max  0.410
_exptl_absorpt_correction_T_min  0.039
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    3.477
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             3084
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.1723
_exptl_crystal_size_mid          0.1367
_exptl_crystal_size_min          0.0300
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0454
_diffrn_reflns_av_unetI/netI     0.0425
_diffrn_reflns_Laue_measured_fraction_full 0.974
_diffrn_reflns_Laue_measured_fraction_max 0.953
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            22002
_diffrn_reflns_point_group_measured_fraction_full 0.974
_diffrn_reflns_point_group_measured_fraction_max 0.953
_diffrn_reflns_theta_full        68.000
_diffrn_reflns_theta_max         71.716
_diffrn_reflns_theta_min         3.410
_diffrn_ambient_environment      air
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.2273
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   30.00   83.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -30.0000  120.0000 53

#__ type_ start__ end____ width___ exp.time_
  2 omega   38.00   99.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -45.0000   60.0000 61

#__ type_ start__ end____ width___ exp.time_
  3 omega   60.00  116.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334 -111.0000  -30.0000 56

#__ type_ start__ end____ width___ exp.time_
  4 omega   51.00  114.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334 -111.0000 -150.0000 63

#__ type_ start__ end____ width___ exp.time_
  5 omega   48.00   79.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       36.1031 -125.0000 -180.0000 31

#__ type_ start__ end____ width___ exp.time_
  6 omega   14.00   80.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       36.1031  -99.0000 -120.0000 66

#__ type_ start__ end____ width___ exp.time_
  7 omega   37.00   89.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -30.0000    0.0000 52

#__ type_ start__ end____ width___ exp.time_
  8 omega   51.00  109.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -94.0000   90.0000 58

#__ type_ start__ end____ width___ exp.time_
  9 omega   39.00  103.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -94.0000    0.0000 64

#__ type_ start__ end____ width___ exp.time_
 10 omega   47.00  178.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334    0.0000    0.0000 131

#__ type_ start__ end____ width___ exp.time_
 11 omega  120.00  178.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334   45.0000   30.0000 58

#__ type_ start__ end____ width___ exp.time_
 12 omega  147.00  172.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  111.0000  -90.0000 25

#__ type_ start__ end____ width___ exp.time_
 13 omega  103.00  129.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  111.0000  -90.0000 26

#__ type_ start__ end____ width___ exp.time_
 14 omega   79.00  127.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334   45.0000   60.0000 48

#__ type_ start__ end____ width___ exp.time_
 15 omega   28.00   83.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -30.0000  -60.0000 55

#__ type_ start__ end____ width___ exp.time_
 16 omega   29.00   72.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -94.0000   60.0000 43

#__ type_ start__ end____ width___ exp.time_
 17 omega   24.00   83.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       36.1031 -125.0000   60.0000 59

#__ type_ start__ end____ width___ exp.time_
 18 omega   -6.00   69.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       36.1031  -57.0000    0.0000 75

#__ type_ start__ end____ width___ exp.time_
 19 omega   25.00   97.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -45.0000 -120.0000 72

#__ type_ start__ end____ width___ exp.time_
 20 omega   21.00   89.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.8334  -94.0000 -120.0000 68

#__ type_ start__ end____ width___ exp.time_
 21 omega   16.00  120.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       36.1031   37.0000 -180.0000 104

#__ type_ start__ end____ width___ exp.time_
 22 omega   -6.00   27.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      -36.1031   19.0000   30.0000 33

#__ type_ start__ end____ width___ exp.time_
 23 omega  -35.00  -10.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       36.1031  -57.0000    0.0000 25

#__ type_ start__ end____ width___ exp.time_
 24 omega  -46.00   66.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       36.1031  -37.0000 -120.0000 112

#__ type_ start__ end____ width___ exp.time_
 25 omega -109.00  -79.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      -36.1031  -99.0000   90.0000 30

#__ type_ start__ end____ width___ exp.time_
 26 omega -117.00  -76.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      -36.1031 -125.0000   60.0000 41

#__ type_ start__ end____ width___ exp.time_
 27 omega -119.00  -77.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      -36.1031 -125.0000  -60.0000 42
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0205356000
_diffrn_orient_matrix_UB_12      0.1058701000
_diffrn_orient_matrix_UB_13      0.0204756000
_diffrn_orient_matrix_UB_21      0.0911337000
_diffrn_orient_matrix_UB_22      0.0235002000
_diffrn_orient_matrix_UB_23      -0.0667577000
_diffrn_orient_matrix_UB_31      -0.0840078000
_diffrn_orient_matrix_UB_32      0.0486864000
_diffrn_orient_matrix_UB_33      -0.0360700000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_diffrn_special_details          ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                11308
_reflns_number_total             12145
_reflns_odcompleteness_completeness 97.42
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         2.555
_refine_diff_density_min         -3.026
_refine_diff_density_rms         0.457
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     820
_refine_ls_number_reflns         12145
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0501
_refine_ls_R_factor_gt           0.0476
_refine_ls_restrained_S_all      1.085
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0943P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1329
_refine_ls_wR_factor_ref         0.1365
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W9 W 1.12350(3) 0.22735(3) 0.61921(2) 0.01482(11) Uani 1 1 d . . . . .
W8 W 0.94983(3) 0.03453(3) 0.67999(2) 0.01486(11) Uani 1 1 d . . . . .
W2 W 0.73626(3) 0.44006(3) 0.90322(2) 0.01520(11) Uani 1 1 d . . . . .
W6 W 1.16746(3) 0.22219(3) 0.76998(2) 0.01499(11) Uani 1 1 d . . . . .
W5 W 0.82227(3) 0.56878(3) 0.75048(2) 0.01523(11) Uani 1 1 d . . . . .
W4 W 0.66250(3) 0.43074(3) 0.69305(2) 0.01513(11) Uani 1 1 d . . . . .
W3 W 0.57506(3) 0.30252(3) 0.84391(2) 0.01492(11) Uani 1 1 d . . . . .
W7 W 0.99337(3) 0.03062(3) 0.82952(2) 0.01511(11) Uani 1 1 d . . . . .
W1 W 0.55691(4) 0.55748(3) 0.82754(2) 0.01587(11) Uani 1 1 d . . . . .
W10 W 1.20276(3) 0.00854(3) 0.69374(2) 0.01554(11) Uani 1 1 d . . . . .
Tb1 Tb 0.87633(5) 0.28177(4) 0.76324(3) 0.01539(13) Uani 1 1 d . . . . .
Na6 Na 0.1859(3) 0.6022(3) 0.76740(19) 0.0239(8) Uani 1 1 d . . . . .
Na4 Na 0.2957(3) 0.2180(3) 0.9894(2) 0.0245(8) Uani 1 1 d . . . . .
Na2 Na 0.5595(3) -0.0486(3) 0.79315(19) 0.0224(8) Uani 1 1 d . . . . .
Na1 Na 0.6998(3) -0.0698(3) 0.62111(19) 0.0230(8) Uani 1 1 d . . . . .
Na8 Na 0.4690(3) 0.7061(3) 0.43695(19) 0.0239(8) Uani 1 1 d . . . . .
Na9 Na 0.0657(4) 0.6028(3) 0.50934(19) 0.0249(8) Uani 1 1 d . . . . .
Na3 Na 0.3201(3) -0.0464(3) 0.93801(19) 0.0248(8) Uani 1 1 d . . . . .
Na5 Na 0.1341(3) 0.5103(3) 0.94186(18) 0.0211(8) Uani 1 1 d . . . . .
Na7 Na 0.2473(3) 0.6358(3) 0.58777(19) 0.0248(8) Uani 1 1 d . . . . .
O2 O 0.6122(6) 0.5391(5) 0.9048(3) 0.0175(13) Uani 1 1 d . . . . .
O34 O 1.0908(6) -0.0445(5) 0.6635(3) 0.0195(13) Uani 1 1 d . . . . .
O25 O 1.1050(5) 0.1197(5) 0.8462(3) 0.0161(13) Uani 1 1 d . . . . .
O29 O 1.0293(5) 0.1262(5) 0.5996(3) 0.0165(13) Uani 1 1 d . . . . .
O35 O 1.2308(6) 0.1096(5) 0.6140(3) 0.0186(13) Uani 1 1 d . . . . .
O32 O 1.2676(5) 0.1067(5) 0.7349(3) 0.0176(13) Uani 1 1 d . . . . .
O3 O 0.4815(5) 0.4295(5) 0.8589(3) 0.0164(13) Uani 1 1 d . . . . .
O51 O 0.4284(6) 0.2979(5) 1.0243(3) 0.0183(13) Uani 1 1 d . . . . .
O9 O 0.6197(5) 0.3366(5) 0.9226(3) 0.0187(13) Uani 1 1 d . . . . .
O13 O 0.7637(6) 0.5479(5) 0.6735(3) 0.0175(13) Uani 1 1 d . . . . .
O7 O 0.8242(6) 0.5557(5) 0.8464(3) 0.0173(13) Uani 1 1 d . . . . .
O11 O 0.5587(5) 0.3306(5) 0.7520(3) 0.0156(13) Uani 1 1 d . . . . .
O46 O 0.3958(6) 0.0523(5) 0.8297(3) 0.0207(14) Uani 1 1 d . . . . .
O5 O 0.6828(6) 0.6410(5) 0.7819(3) 0.0178(13) Uani 1 1 d . . . . .
O33 O 1.1266(5) -0.0485(5) 0.7839(3) 0.0171(13) Uani 1 1 d . . . . .
O22 O 1.0102(6) 0.3035(5) 0.6551(3) 0.0176(13) Uani 1 1 d . . . . .
O27 O 0.9231(5) -0.0361(5) 0.7722(3) 0.0152(12) Uani 1 1 d . . . . .
O15 O 0.8360(6) 0.3467(5) 0.8688(3) 0.0184(13) Uani 1 1 d . . . . .
O63 O 0.1455(6) 0.7429(5) 0.4297(3) 0.0205(14) Uani 1 1 d . . . . .
O69 O 0.9828(6) 0.1129(5) 0.4731(3) 0.0233(15) Uani 1 1 d . . . . .
O49 O 0.1851(6) 0.0920(5) 0.9620(3) 0.0228(14) Uani 1 1 d . . . . .
O62 O -0.0463(6) 0.4789(5) 0.5824(3) 0.0192(13) Uani 1 1 d . . . . .
O12 O 0.6276(6) 0.4310(5) 0.6161(3) 0.0211(14) Uani 1 1 d . . . . .
O4 O 0.5535(5) 0.5330(5) 0.7361(3) 0.0152(12) Uani 1 1 d . . . . .
O24 O 1.2602(6) 0.2831(5) 0.8008(3) 0.0195(13) Uani 1 1 d . . . . .
O40 O 0.6481(6) 0.0676(5) 0.6901(3) 0.0228(14) Uani 1 1 d . . . . .
O19 O 1.0495(5) 0.3015(5) 0.7867(3) 0.0175(13) Uani 1 1 d . . . . .
O28 O 0.8792(6) -0.0410(5) 0.6415(3) 0.0206(14) Uani 1 1 d . . . . .
O6 O 0.6907(6) 0.4419(5) 0.7979(3) 0.0189(14) Uani 1 1 d . . . . .
O8 O 0.7592(6) 0.4522(5) 0.9819(3) 0.0199(14) Uani 1 1 d . . . . .
O16 O 0.6939(6) 0.2273(5) 0.8173(3) 0.0181(13) Uani 1 1 d . . . . .
O18 O 0.9137(5) 0.4631(5) 0.7346(3) 0.0178(13) Uani 1 1 d . . . . .
O21 O 0.8570(6) 0.1344(5) 0.7077(3) 0.0201(14) Uani 1 1 d . . . . .
O14 O 0.9046(6) 0.6767(5) 0.7158(3) 0.0203(14) Uani 1 1 d . . . . .
O30 O 1.1809(6) 0.2953(5) 0.5389(3) 0.0182(13) Uani 1 1 d . . . . .
O56 O 0.3435(6) 0.4823(5) 0.7399(3) 0.0247(15) Uani 1 1 d . . . . .
O26 O 0.9562(6) -0.0501(5) 0.9062(3) 0.0238(15) Uani 1 1 d . . . . .
O68 O 0.5195(6) 0.7985(5) 0.3238(3) 0.0201(14) Uani 1 1 d . . . . .
O55 O 0.2328(6) 0.6494(5) 0.8636(3) 0.0245(15) Uani 1 1 d . . . . .
O53 O 0.0189(6) 0.3804(5) 1.0213(3) 0.0236(14) Uani 1 1 d . . . . .
O54 O 0.0528(6) 0.4853(5) 0.8484(3) 0.0249(15) Uani 1 1 d . . . . .
O60 O 0.2281(6) 0.5177(5) 0.5109(3) 0.0246(15) Uani 1 1 d . . . . .
O52 O 0.2643(6) 0.3729(5) 0.9179(3) 0.0227(14) Uani 1 1 d . . . . .
O65 O 0.3020(6) 0.7800(6) 0.4911(4) 0.0270(15) Uani 1 1 d . . . . .
O41 O 0.7004(6) -0.1560(5) 0.7378(4) 0.0292(16) Uani 1 1 d . . . . .
O39 O 0.7349(7) -0.2450(6) 0.5942(4) 0.0294(16) Uani 1 1 d . . . . .
O45 O 0.1868(7) -0.1520(6) 0.9072(4) 0.0336(18) Uani 1 1 d . . . . .
O47 O 0.2738(6) -0.1483(5) 1.0393(3) 0.0278(16) Uani 1 1 d . . . . .
O44 O 0.6829(6) 0.0123(5) 0.8469(4) 0.0246(15) Uani 1 1 d . . . . .
O36 O 1.3090(6) -0.0770(5) 0.6713(3) 0.0208(14) Uani 1 1 d . . . . .
O48 O 0.3904(6) 0.0596(5) 1.0113(4) 0.0269(16) Uani 1 1 d . . . . .
O64 O 0.4413(7) 0.5992(6) 0.5423(4) 0.0286(16) Uani 1 1 d . . . . .
O43 O 0.4710(6) -0.1572(5) 0.8975(3) 0.0254(15) Uani 1 1 d . . . . .
O57 O 0.0559(7) 0.7413(6) 0.7834(4) 0.0313(17) Uani 1 1 d . . . . .
O50 O 0.1638(7) 0.2632(6) 1.0913(4) 0.0303(17) Uani 1 1 d . . . . .
O17 O 0.7716(6) 0.3417(5) 0.6857(3) 0.0173(13) Uani 1 1 d . . . . .
O71 O 0.9561(6) 0.2364(6) 0.9549(4) 0.0315(17) Uani 1 1 d . . . . .
O67 O 0.6134(6) 0.5956(5) 0.3884(3) 0.0241(15) Uani 1 1 d . . . . .
O58 O 0.2981(6) 0.7093(5) 0.6731(3) 0.0252(15) Uani 1 1 d . . . . .
O59 O 0.1384(6) 0.5089(5) 0.6801(3) 0.0228(14) Uani 1 1 d . . . . .
O61 O 0.0726(6) 0.7049(5) 0.5931(3) 0.0228(14) Uani 1 1 d . . . . .
O23 O 1.2082(6) 0.2791(5) 0.6731(3) 0.0181(13) Uani 1 1 d . . . . .
O20 O 0.8951(5) 0.1318(5) 0.8392(3) 0.0160(13) Uani 1 1 d . . . . .
O10 O 0.4716(6) 0.2131(5) 0.8820(3) 0.0207(14) Uani 1 1 d . . . . .
O37 O 0.5306(6) -0.0499(6) 0.5861(3) 0.0269(16) Uani 1 1 d . . . . .
O38 O 0.7788(6) 0.0037(5) 0.5022(3) 0.0246(15) Uani 1 1 d . . . . .
O31 O 1.0679(5) 0.1231(5) 0.7227(3) 0.0169(13) Uani 1 1 d . . . . .
O70 O 0.5211(7) 0.6838(6) 0.6417(4) 0.038(2) Uani 1 1 d . . . . .
O66 O 0.5551(6) 0.8540(6) 0.4632(4) 0.0291(16) Uani 1 1 d . . . . .
O42 O 0.4507(7) -0.1536(6) 0.7514(5) 0.037(2) Uani 1 1 d . . . . .
O1 O 0.4557(6) 0.6485(5) 0.8459(3) 0.0230(14) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W9 O29 1.948(6) . ?
W9 O35 2.031(7) . ?
W9 O22 1.780(7) . ?
W9 O30 1.747(6) . ?
W9 O23 1.920(7) . ?
W9 O31 2.318(6) . ?
W8 O34 2.023(7) . ?
W8 O29 1.960(6) . ?
W8 O27 1.942(6) . ?
W8 O28 1.736(7) . ?
W8 O21 1.785(7) . ?
W8 O31 2.321(6) . ?
W2 O2 2.018(6) . ?
W2 O9 1.953(7) . ?
W2 O7 1.955(6) . ?
W2 O15 1.809(7) . ?
W2 O6 2.377(6) . ?
W2 O8 1.740(6) . ?
W6 O25 1.929(6) . ?
W6 O32 2.030(6) . ?
W6 O24 1.727(7) . ?
W6 O19 1.788(6) . ?
W6 O23 1.966(6) . ?
W6 O31 2.290(6) . ?
W5 O13 1.965(6) . ?
W5 O7 1.958(6) . ?
W5 O5 1.983(7) . ?
W5 O6 2.309(7) . ?
W5 O18 1.792(6) . ?
W5 O14 1.732(7) . ?
W4 O13 1.951(7) . ?
W4 O11 1.933(6) . ?
W4 O12 1.748(6) . ?
W4 O4 2.014(6) . ?
W4 O6 2.293(6) . ?
W4 O17 1.781(6) . ?
W3 O3 2.030(6) . ?
W3 O9 1.949(6) . ?
W3 O11 1.939(6) . ?
W3 O6 2.303(6) . ?
W3 O16 1.786(7) . ?
W3 O10 1.729(7) . ?
W7 O25 1.977(6) . ?
W7 O33 2.036(6) . ?
W7 O27 1.946(6) . ?
W7 O26 1.736(6) . ?
W7 O20 1.795(6) . ?
W7 O31 2.330(6) . ?
W1 O2 1.885(6) . ?
W1 O3 1.896(6) . ?
W1 O5 1.908(7) . ?
W1 O4 1.952(6) . ?
W1 O6 2.264(6) . ?
W1 O1 1.735(7) . ?
W10 O34 1.874(7) . ?
W10 O35 1.927(6) . ?
W10 O32 1.928(7) . ?
W10 O33 1.907(6) . ?
W10 O36 1.740(7) . ?
W10 O31 2.262(6) . ?
Tb1 O22 2.397(6) . ?
Tb1 O15 2.349(6) . ?
Tb1 O19 2.403(7) . ?
Tb1 O16 2.369(7) . ?
Tb1 O18 2.394(6) . ?
Tb1 O21 2.403(6) . ?
Tb1 O17 2.386(6) . ?
Tb1 O20 2.396(6) . ?
Na6 Na5 3.517(5) . ?
Na6 Na7 3.526(5) . ?
Na6 O56 2.508(8) . ?
Na6 O55 2.360(8) . ?
Na6 O54 2.433(8) . ?
Na6 O57 2.428(9) . ?
Na6 O58 2.380(8) . ?
Na6 O59 2.489(8) . ?
Na4 Na3 3.717(6) . ?
Na4 O51 2.313(8) . ?
Na4 O49 2.397(8) . ?
Na4 O52 2.439(8) . ?
Na4 O48 2.429(8) . ?
Na4 O50 2.436(9) . ?
Na4 O10 2.694(8) . ?
Na2 Na1 3.544(5) . ?
Na2 Na3 3.645(6) . ?
Na2 O46 2.439(8) . ?
Na2 O40 2.456(8) . ?
Na2 O41 2.384(8) . ?
Na2 O44 2.345(8) . ?
Na2 O43 2.425(8) . ?
Na2 O42 2.351(9) . ?
Na1 O40 2.396(8) . ?
Na1 O28 2.471(8) . ?
Na1 O41 2.515(8) . ?
Na1 O39 2.426(8) . ?
Na1 O37 2.445(9) . ?
Na1 O38 2.453(8) . ?
Na8 Na7 3.618(6) . ?
Na8 O12 2.680(8) 2_666 ?
Na8 O68 2.406(7) . ?
Na8 O65 2.369(9) . ?
Na8 O64 2.366(8) . ?
Na8 O67 2.394(8) . ?
Na8 O66 2.425(9) . ?
Na9 Na9 3.305(8) 2_566 ?
Na9 Na7 3.210(6) . ?
Na9 O63 2.342(7) . ?
Na9 O62 2.289(7) . ?
Na9 O62 2.344(7) 2_566 ?
Na9 O60 2.335(9) . ?
Na9 O61 2.321(8) . ?
Na3 O46 2.389(7) . ?
Na3 O49 2.473(8) . ?
Na3 O45 2.461(9) . ?
Na3 O47 2.264(7) . ?
Na3 O48 2.500(8) . ?
Na3 O43 2.411(8) . ?
Na5 Na5 3.596(8) 2_567 ?
Na5 O8 2.425(7) 2_667 ?
Na5 O55 2.396(8) . ?
Na5 O53 2.410(8) . ?
Na5 O53 2.404(8) 2_567 ?
Na5 O54 2.463(8) . ?
Na5 O52 2.425(8) . ?
Na7 O60 2.397(8) . ?
Na7 O65 2.518(8) . ?
Na7 O64 2.455(9) . ?
Na7 O58 2.333(8) . ?
Na7 O59 2.481(8) . ?
Na7 O61 2.364(8) . ?
O62 Na9 2.344(7) 2_566 ?
O12 Na8 2.680(8) 2_666 ?
O8 Na5 2.424(7) 2_667 ?
O53 Na5 2.404(8) 2_567 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O29 W9 O35 83.9(3) . . ?
O29 W9 O31 77.8(2) . . ?
O35 W9 O31 74.1(2) . . ?
O22 W9 O29 92.0(3) . . ?
O22 W9 O35 158.0(3) . . ?
O22 W9 O23 91.4(3) . . ?
O22 W9 O31 84.0(2) . . ?
O30 W9 O29 102.7(3) . . ?
O30 W9 O35 98.2(3) . . ?
O30 W9 O22 103.7(3) . . ?
O30 W9 O23 101.7(3) . . ?
O30 W9 O31 172.2(3) . . ?
O23 W9 O29 153.8(3) . . ?
O23 W9 O35 83.4(3) . . ?
O23 W9 O31 76.8(2) . . ?
O34 W8 O31 73.5(2) . . ?
O29 W8 O34 83.7(3) . . ?
O29 W8 O31 77.5(2) . . ?
O27 W8 O34 84.0(3) . . ?
O27 W8 O29 155.4(3) . . ?
O27 W8 O31 78.6(2) . . ?
O28 W8 O34 98.1(3) . . ?
O28 W8 O29 99.5(3) . . ?
O28 W8 O27 103.3(3) . . ?
O28 W8 O21 104.2(3) . . ?
O28 W8 O31 171.2(3) . . ?
O21 W8 O34 157.7(3) . . ?
O21 W8 O29 91.3(3) . . ?
O21 W8 O27 92.0(3) . . ?
O21 W8 O31 84.2(3) . . ?
O2 W2 O6 72.8(2) . . ?
O9 W2 O2 82.9(3) . . ?
O9 W2 O7 152.4(3) . . ?
O9 W2 O6 75.8(2) . . ?
O7 W2 O2 83.4(3) . . ?
O7 W2 O6 77.4(2) . . ?
O15 W2 O2 156.5(3) . . ?
O15 W2 O9 90.6(3) . . ?
O15 W2 O7 92.5(3) . . ?
O15 W2 O6 83.7(3) . . ?
O8 W2 O2 100.1(3) . . ?
O8 W2 O9 105.2(3) . . ?
O8 W2 O7 100.7(3) . . ?
O8 W2 O15 103.4(3) . . ?
O8 W2 O6 172.8(3) . . ?
O25 W6 O32 84.4(3) . . ?
O25 W6 O23 154.5(3) . . ?
O25 W6 O31 78.7(2) . . ?
O32 W6 O31 74.4(3) . . ?
O24 W6 O25 101.2(3) . . ?
O24 W6 O32 96.0(3) . . ?
O24 W6 O19 104.2(3) . . ?
O24 W6 O23 102.0(3) . . ?
O24 W6 O31 170.4(3) . . ?
O19 W6 O25 93.2(3) . . ?
O19 W6 O32 159.7(3) . . ?
O19 W6 O23 91.3(3) . . ?
O19 W6 O31 85.3(3) . . ?
O23 W6 O32 82.8(3) . . ?
O23 W6 O31 76.6(2) . . ?
O13 W5 O5 83.3(3) . . ?
O13 W5 O6 77.2(2) . . ?
O7 W5 O13 155.6(3) . . ?
O7 W5 O5 84.7(3) . . ?
O7 W5 O6 79.0(3) . . ?
O5 W5 O6 73.6(2) . . ?
O18 W5 O13 91.7(3) . . ?
O18 W5 O7 91.7(3) . . ?
O18 W5 O5 158.3(3) . . ?
O18 W5 O6 84.8(3) . . ?
O14 W5 O13 100.5(3) . . ?
O14 W5 O7 102.1(3) . . ?
O14 W5 O5 97.9(3) . . ?
O14 W5 O6 171.3(3) . . ?
O14 W5 O18 103.8(3) . . ?
O13 W4 O4 83.4(3) . . ?
O13 W4 O6 77.9(2) . . ?
O11 W4 O13 154.5(3) . . ?
O11 W4 O4 83.3(3) . . ?
O11 W4 O6 77.6(2) . . ?
O12 W4 O13 102.6(3) . . ?
O12 W4 O11 101.0(3) . . ?
O12 W4 O4 99.2(3) . . ?
O12 W4 O6 173.3(3) . . ?
O12 W4 O17 103.2(3) . . ?
O4 W4 O6 74.2(2) . . ?
O17 W4 O13 91.5(3) . . ?
O17 W4 O11 92.5(3) . . ?
O17 W4 O4 157.5(3) . . ?
O17 W4 O6 83.4(3) . . ?
O3 W3 O6 74.1(2) . . ?
O9 W3 O3 83.5(3) . . ?
O9 W3 O6 77.7(2) . . ?
O11 W3 O3 83.1(3) . . ?
O11 W3 O9 154.0(3) . . ?
O11 W3 O6 77.3(2) . . ?
O16 W3 O3 158.9(3) . . ?
O16 W3 O9 91.9(3) . . ?
O16 W3 O11 92.6(3) . . ?
O16 W3 O6 84.8(3) . . ?
O10 W3 O3 96.3(3) . . ?
O10 W3 O9 101.5(3) . . ?
O10 W3 O11 102.1(3) . . ?
O10 W3 O6 170.4(3) . . ?
O10 W3 O16 104.8(3) . . ?
O25 W7 O33 82.7(3) . . ?
O25 W7 O31 76.8(2) . . ?
O33 W7 O31 73.6(2) . . ?
O27 W7 O25 154.2(3) . . ?
O27 W7 O33 83.9(3) . . ?
O27 W7 O31 78.3(2) . . ?
O26 W7 O25 101.1(3) . . ?
O26 W7 O33 97.4(3) . . ?
O26 W7 O27 102.4(3) . . ?
O26 W7 O20 104.8(3) . . ?
O26 W7 O31 170.9(3) . . ?
O20 W7 O25 91.8(3) . . ?
O20 W7 O33 157.8(2) . . ?
O20 W7 O27 92.3(3) . . ?
O20 W7 O31 84.2(2) . . ?
O2 W1 O3 88.5(3) . . ?
O2 W1 O5 87.8(3) . . ?
O2 W1 O4 153.8(3) . . ?
O2 W1 O6 77.9(2) . . ?
O3 W1 O5 153.4(3) . . ?
O3 W1 O4 86.7(3) . . ?
O3 W1 O6 77.5(3) . . ?
O5 W1 O4 85.1(3) . . ?
O5 W1 O6 76.0(3) . . ?
O4 W1 O6 76.0(2) . . ?
O1 W1 O2 104.6(3) . . ?
O1 W1 O3 103.9(3) . . ?
O1 W1 O5 102.5(3) . . ?
O1 W1 O4 101.5(3) . . ?
O1 W1 O6 177.1(3) . . ?
O34 W10 O35 87.6(3) . . ?
O34 W10 O32 154.5(3) . . ?
O34 W10 O33 87.8(3) . . ?
O34 W10 O31 77.6(3) . . ?
O35 W10 O32 86.4(3) . . ?
O35 W10 O31 77.3(2) . . ?
O32 W10 O31 76.9(2) . . ?
O33 W10 O35 154.8(3) . . ?
O33 W10 O32 87.3(3) . . ?
O33 W10 O31 77.5(2) . . ?
O36 W10 O34 103.8(3) . . ?
O36 W10 O35 102.0(3) . . ?
O36 W10 O32 101.6(3) . . ?
O36 W10 O33 103.1(3) . . ?
O36 W10 O31 178.4(3) . . ?
O22 Tb1 O19 73.4(2) . . ?
O22 Tb1 O21 73.7(2) . . ?
O15 Tb1 O22 139.5(2) . . ?
O15 Tb1 O19 74.7(2) . . ?
O15 Tb1 O16 75.5(2) . . ?
O15 Tb1 O18 75.5(2) . . ?
O15 Tb1 O21 144.2(2) . . ?
O15 Tb1 O17 117.9(2) . . ?
O15 Tb1 O20 78.0(2) . . ?
O19 Tb1 O21 115.9(2) . . ?
O16 Tb1 O22 143.0(2) . . ?
O16 Tb1 O19 141.6(2) . . ?
O16 Tb1 O18 118.0(2) . . ?
O16 Tb1 O21 77.5(2) . . ?
O16 Tb1 O17 73.6(2) . . ?
O16 Tb1 O20 76.3(2) . . ?
O18 Tb1 O22 73.4(2) . . ?
O18 Tb1 O19 76.8(2) . . ?
O18 Tb1 O21 138.9(2) . . ?
O18 Tb1 O20 144.8(2) . . ?
O17 Tb1 O22 77.0(2) . . ?
O17 Tb1 O19 143.1(2) . . ?
O17 Tb1 O18 73.9(2) . . ?
O17 Tb1 O21 75.3(2) . . ?
O17 Tb1 O20 140.2(2) . . ?
O20 Tb1 O22 115.8(2) . . ?
O20 Tb1 O19 74.2(2) . . ?
O20 Tb1 O21 73.1(2) . . ?
Na5 Na6 Na7 167.22(16) . . ?
O56 Na6 Na5 90.5(2) . . ?
O56 Na6 Na7 79.95(19) . . ?
O55 Na6 Na5 42.71(19) . . ?
O55 Na6 Na7 145.5(2) . . ?
O55 Na6 O56 93.2(3) . . ?
O55 Na6 O54 85.9(3) . . ?
O55 Na6 O57 85.6(3) . . ?
O55 Na6 O58 104.7(3) . . ?
O55 Na6 O59 166.0(3) . . ?
O54 Na6 Na5 44.44(19) . . ?
O54 Na6 Na7 128.5(2) . . ?
O54 Na6 O56 99.6(3) . . ?
O54 Na6 O59 84.4(3) . . ?
O57 Na6 Na5 95.2(2) . . ?
O57 Na6 Na7 95.4(2) . . ?
O57 Na6 O56 170.1(3) . . ?
O57 Na6 O54 90.1(3) . . ?
O57 Na6 O59 104.4(3) . . ?
O58 Na6 Na5 146.4(2) . . ?
O58 Na6 Na7 41.06(19) . . ?
O58 Na6 O56 82.3(3) . . ?
O58 Na6 O54 169.2(3) . . ?
O58 Na6 O57 88.5(3) . . ?
O58 Na6 O59 85.6(3) . . ?
O59 Na6 Na5 125.2(2) . . ?
O59 Na6 Na7 44.70(18) . . ?
O59 Na6 O56 78.5(3) . . ?
O51 Na4 Na3 123.9(2) . . ?
O51 Na4 O49 163.6(3) . . ?
O51 Na4 O52 93.1(3) . . ?
O51 Na4 O48 85.3(3) . . ?
O51 Na4 O50 87.9(3) . . ?
O51 Na4 O10 77.8(2) . . ?
O49 Na4 Na3 41.01(19) . . ?
O49 Na4 O52 102.0(3) . . ?
O49 Na4 O48 78.3(3) . . ?
O49 Na4 O50 97.3(3) . . ?
O49 Na4 O10 98.3(3) . . ?
O52 Na4 Na3 124.8(2) . . ?
O52 Na4 O10 80.3(2) . . ?
O48 Na4 Na3 41.77(19) . . ?
O48 Na4 O52 153.4(3) . . ?
O48 Na4 O50 112.5(3) . . ?
O48 Na4 O10 73.4(2) . . ?
O50 Na4 Na3 123.4(2) . . ?
O50 Na4 O52 94.0(3) . . ?
O50 Na4 O10 164.2(3) . . ?
O10 Na4 Na3 71.19(18) . . ?
Na1 Na2 Na3 155.24(15) . . ?
O46 Na2 Na1 125.0(2) . . ?
O46 Na2 Na3 40.47(17) . . ?
O46 Na2 O40 97.4(3) . . ?
O40 Na2 Na1 42.41(18) . . ?
O40 Na2 Na3 137.4(2) . . ?
O41 Na2 Na1 45.14(19) . . ?
O41 Na2 Na3 143.3(2) . . ?
O41 Na2 O46 166.8(3) . . ?
O41 Na2 O40 79.0(3) . . ?
O41 Na2 O43 102.8(3) . . ?
O44 Na2 Na1 108.4(2) . . ?
O44 Na2 Na3 96.0(2) . . ?
O44 Na2 O46 104.5(3) . . ?
O44 Na2 O40 88.5(3) . . ?
O44 Na2 O41 88.1(3) . . ?
O44 Na2 O43 90.2(3) . . ?
O44 Na2 O42 164.3(3) . . ?
O43 Na2 Na1 139.9(2) . . ?
O43 Na2 Na3 40.94(19) . . ?
O43 Na2 O46 81.1(3) . . ?
O43 Na2 O40 177.7(3) . . ?
O42 Na2 Na1 73.2(3) . . ?
O42 Na2 Na3 84.6(3) . . ?
O42 Na2 O46 86.1(3) . . ?
O42 Na2 O40 101.8(3) . . ?
O42 Na2 O41 82.2(3) . . ?
O42 Na2 O43 79.9(3) . . ?
O40 Na1 Na2 43.73(18) . . ?
O40 Na1 O28 82.4(3) . . ?
O40 Na1 O41 77.6(3) . . ?
O40 Na1 O39 158.2(3) . . ?
O40 Na1 O37 90.1(3) . . ?
O40 Na1 O38 109.2(3) . . ?
O28 Na1 Na2 92.42(19) . . ?
O28 Na1 O41 70.7(3) . . ?
O41 Na1 Na2 42.22(19) . . ?
O39 Na1 Na2 115.0(2) . . ?
O39 Na1 O28 95.7(3) . . ?
O39 Na1 O41 81.2(3) . . ?
O39 Na1 O37 96.3(3) . . ?
O39 Na1 O38 92.4(3) . . ?
O37 Na1 Na2 91.5(2) . . ?
O37 Na1 O28 164.4(3) . . ?
O37 Na1 O41 121.1(3) . . ?
O37 Na1 O38 81.9(3) . . ?
O38 Na1 Na2 152.4(2) . . ?
O38 Na1 O28 87.6(3) . . ?
O38 Na1 O41 156.5(3) . . ?
O12 Na8 Na7 83.46(19) 2_666 . ?
O68 Na8 Na7 145.4(2) . . ?
O68 Na8 O12 86.0(2) . 2_666 ?
O68 Na8 O66 82.4(3) . . ?
O65 Na8 Na7 43.85(19) . . ?
O65 Na8 O12 93.6(3) . 2_666 ?
O65 Na8 O68 104.4(3) . . ?
O65 Na8 O67 166.9(3) . . ?
O65 Na8 O66 85.7(3) . . ?
O64 Na8 Na7 42.3(2) . . ?
O64 Na8 O12 92.4(3) . 2_666 ?
O64 Na8 O68 171.5(3) . . ?
O64 Na8 O65 84.0(3) . . ?
O64 Na8 O67 88.8(3) . . ?
O64 Na8 O66 99.6(3) . . ?
O67 Na8 Na7 125.8(2) . . ?
O67 Na8 O12 75.6(3) . 2_666 ?
O67 Na8 O68 82.7(2) . . ?
O67 Na8 O66 106.4(3) . . ?
O66 Na8 Na7 104.1(2) . . ?
O66 Na8 O12 167.8(3) . 2_666 ?
Na7 Na9 Na9 133.3(2) . 2_566 ?
O63 Na9 Na9 130.4(3) . 2_566 ?
O63 Na9 Na7 87.6(2) . . ?
O63 Na9 O62 87.7(3) . 2_566 ?
O62 Na9 Na9 45.16(19) . 2_566 ?
O62 Na9 Na9 43.82(18) 2_566 2_566 ?
O62 Na9 Na7 139.0(2) 2_566 . ?
O62 Na9 Na7 102.5(2) . . ?
O62 Na9 O63 167.7(3) . . ?
O62 Na9 O62 89.0(3) . 2_566 ?
O62 Na9 O60 95.7(3) . . ?
O62 Na9 O61 95.0(3) . . ?
O60 Na9 Na9 95.4(3) . 2_566 ?
O60 Na9 Na7 48.1(2) . . ?
O60 Na9 O63 96.2(3) . . ?
O60 Na9 O62 92.1(3) . 2_566 ?
O61 Na9 Na9 139.6(3) . 2_566 ?
O61 Na9 Na7 47.3(2) . . ?
O61 Na9 O63 86.8(3) . . ?
O61 Na9 O62 171.4(3) . 2_566 ?
O61 Na9 O60 95.1(3) . . ?
Na2 Na3 Na4 107.84(14) . . ?
O46 Na3 Na4 80.0(2) . . ?
O46 Na3 Na2 41.50(19) . . ?
O46 Na3 O49 87.1(3) . . ?
O46 Na3 O45 99.3(3) . . ?
O46 Na3 O48 98.9(3) . . ?
O46 Na3 O43 82.4(3) . . ?
O49 Na3 Na4 39.49(19) . . ?
O49 Na3 Na2 128.0(2) . . ?
O49 Na3 O48 75.6(3) . . ?
O45 Na3 Na4 130.0(2) . . ?
O45 Na3 Na2 102.8(2) . . ?
O45 Na3 O49 90.6(3) . . ?
O45 Na3 O48 156.4(3) . . ?
O47 Na3 Na4 102.9(2) . . ?
O47 Na3 Na2 130.5(2) . . ?
O47 Na3 O46 171.5(3) . . ?
O47 Na3 O49 100.2(3) . . ?
O47 Na3 O45 84.9(3) . . ?
O47 Na3 O48 79.0(3) . . ?
O47 Na3 O43 90.0(3) . . ?
O48 Na3 Na4 40.33(19) . . ?
O48 Na3 Na2 100.7(2) . . ?
O43 Na3 Na4 134.4(2) . . ?
O43 Na3 Na2 41.22(18) . . ?
O43 Na3 O49 169.1(3) . . ?
O43 Na3 O45 94.2(3) . . ?
O43 Na3 O48 102.9(3) . . ?
Na6 Na5 Na5 123.74(18) . 2_567 ?
O8 Na5 Na6 126.5(2) 2_667 . ?
O8 Na5 Na5 100.2(2) 2_667 2_567 ?
O8 Na5 O54 170.0(3) 2_667 . ?
O8 Na5 O52 83.1(3) 2_667 . ?
O55 Na5 Na6 41.93(19) . . ?
O55 Na5 Na5 132.9(3) . 2_567 ?
O55 Na5 O8 86.6(3) . 2_667 ?
O55 Na5 O53 91.2(3) . 2_567 ?
O55 Na5 O53 174.4(3) . . ?
O55 Na5 O54 84.4(3) . . ?
O55 Na5 O52 100.0(3) . . ?
O53 Na5 Na6 95.6(2) 2_567 . ?
O53 Na5 Na6 137.0(2) . . ?
O53 Na5 Na5 41.73(19) 2_567 2_567 ?
O53 Na5 Na5 41.61(18) . 2_567 ?
O53 Na5 O8 95.8(3) . 2_667 ?
O53 Na5 O8 99.5(3) 2_567 2_667 ?
O53 Na5 O53 83.3(3) 2_567 . ?
O53 Na5 O54 85.2(3) 2_567 . ?
O53 Na5 O54 93.6(3) . . ?
O53 Na5 O52 85.4(3) . . ?
O53 Na5 O52 168.7(3) 2_567 . ?
O54 Na5 Na6 43.75(19) . . ?
O54 Na5 Na5 89.2(2) . 2_567 ?
O52 Na5 Na6 91.6(2) . . ?
O52 Na5 Na5 127.0(2) . 2_567 ?
O52 Na5 O54 94.1(3) . . ?
Na6 Na7 Na8 141.76(16) . . ?
Na9 Na7 Na6 121.67(15) . . ?
Na9 Na7 Na8 96.57(13) . . ?
O60 Na7 Na6 130.1(2) . . ?
O60 Na7 Na8 75.9(2) . . ?
O60 Na7 Na9 46.5(2) . . ?
O60 Na7 O65 91.3(3) . . ?
O60 Na7 O64 81.9(3) . . ?
O60 Na7 O59 86.3(3) . . ?
O65 Na7 Na6 138.3(2) . . ?
O65 Na7 Na8 40.67(19) . . ?
O65 Na7 Na9 80.5(2) . . ?
O64 Na7 Na6 108.3(2) . . ?
O64 Na7 Na8 40.44(18) . . ?
O64 Na7 Na9 123.4(2) . . ?
O64 Na7 O65 79.1(3) . . ?
O64 Na7 O59 117.2(3) . . ?
O58 Na7 Na6 42.1(2) . . ?
O58 Na7 Na8 103.9(2) . . ?
O58 Na7 Na9 148.9(3) . . ?
O58 Na7 O60 162.2(3) . . ?
O58 Na7 O65 100.0(3) . . ?
O58 Na7 O64 86.8(3) . . ?
O58 Na7 O59 86.8(3) . . ?
O58 Na7 O61 102.8(3) . . ?
O59 Na7 Na6 44.90(18) . . ?
O59 Na7 Na8 152.6(2) . . ?
O59 Na7 Na9 85.6(2) . . ?
O59 Na7 O65 162.9(3) . . ?
O61 Na7 Na6 90.3(2) . . ?
O61 Na7 Na8 119.3(2) . . ?
O61 Na7 Na9 46.2(2) . . ?
O61 Na7 O60 92.4(3) . . ?
O61 Na7 O65 81.6(3) . . ?
O61 Na7 O64 159.8(3) . . ?
O61 Na7 O59 81.5(3) . . ?
W1 O2 W2 117.4(3) . . ?
W10 O34 W8 116.4(3) . . ?
W6 O25 W7 113.4(3) . . ?
W9 O29 W8 114.0(3) . . ?
W10 O35 W9 115.0(3) . . ?
W10 O32 W6 114.6(3) . . ?
W1 O3 W3 115.2(3) . . ?
W3 O9 W2 115.8(3) . . ?
W4 O13 W5 113.4(3) . . ?
W2 O7 W5 113.9(3) . . ?
W4 O11 W3 114.1(3) . . ?
Na3 O46 Na2 98.0(3) . . ?
W1 O5 W5 117.2(3) . . ?
W10 O33 W7 115.6(3) . . ?
W9 O22 Tb1 131.8(3) . . ?
W8 O27 W7 113.5(3) . . ?
W2 O15 Tb1 130.4(3) . . ?
Na4 O49 Na3 99.5(3) . . ?
Na9 O62 Na9 91.0(3) . 2_566 ?
W4 O12 Na8 134.2(3) . 2_666 ?
W1 O4 W4 115.2(3) . . ?
Na1 O40 Na2 93.9(3) . . ?
W6 O19 Tb1 130.0(3) . . ?
W8 O28 Na1 144.0(4) . . ?
W5 O6 W2 88.8(2) . . ?
W4 O6 W2 173.5(3) . . ?
W4 O6 W5 90.7(2) . . ?
W4 O6 W3 89.9(2) . . ?
W3 O6 W2 89.8(2) . . ?
W3 O6 W5 173.6(3) . . ?
W1 O6 W2 91.9(2) . . ?
W1 O6 W5 93.2(2) . . ?
W1 O6 W4 94.6(2) . . ?
W1 O6 W3 93.1(2) . . ?
W2 O8 Na5 155.4(4) . 2_667 ?
W3 O16 Tb1 129.6(3) . . ?
W5 O18 Tb1 129.1(3) . . ?
W8 O21 Tb1 131.3(4) . . ?
Na6 O55 Na5 95.4(3) . . ?
Na5 O53 Na5 96.7(3) 2_567 . ?
Na6 O54 Na5 91.8(3) . . ?
Na9 O60 Na7 85.4(3) . . ?
Na5 O52 Na4 131.1(3) . . ?
Na8 O65 Na7 95.5(3) . . ?
Na2 O41 Na1 92.6(3) . . ?
Na4 O48 Na3 97.9(3) . . ?
Na8 O64 Na7 97.3(3) . . ?
Na3 O43 Na2 97.8(3) . . ?
W4 O17 Tb1 131.1(3) . . ?
Na7 O58 Na6 96.9(3) . . ?
Na7 O59 Na6 90.4(3) . . ?
Na9 O61 Na7 86.5(3) . . ?
W9 O23 W6 115.0(3) . . ?
W7 O20 Tb1 131.1(3) . . ?
W3 O10 Na4 131.5(3) . . ?
W9 O31 W8 89.9(2) . . ?
W9 O31 W7 173.1(3) . . ?
W8 O31 W7 88.7(2) . . ?
W6 O31 W9 90.6(2) . . ?
W6 O31 W8 173.3(3) . . ?
W6 O31 W7 90.0(2) . . ?
W10 O31 W9 93.6(2) . . ?
W10 O31 W8 92.6(2) . . ?
W10 O31 W6 94.1(2) . . ?
W10 O31 W7 93.2(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 W2 O15 Tb1 3.2(10) . . . . ?
O2 W2 O8 Na5 -121.7(9) . . . 2_667 ?
O2 W1 O3 W3 -76.5(3) . . . . ?
O34 W8 O28 Na1 173.3(6) . . . . ?
O34 W8 O21 Tb1 -1.0(10) . . . . ?
O25 W6 O19 Tb1 -77.3(4) . . . . ?
O25 W7 O20 Tb1 77.0(4) . . . . ?
O29 W9 O22 Tb1 76.6(4) . . . . ?
O29 W8 O28 Na1 -101.8(6) . . . . ?
O29 W8 O21 Tb1 -77.5(4) . . . . ?
O35 W9 O22 Tb1 -1.9(11) . . . . ?
O35 W10 O34 W8 -78.1(4) . . . . ?
O32 W6 O19 Tb1 5.1(10) . . . . ?
O32 W10 O34 W8 -1.8(8) . . . . ?
O3 W3 O16 Tb1 1.0(10) . . . . ?
O3 W3 O10 Na4 -34.8(5) . . . . ?
O3 W1 O2 W2 77.4(4) . . . . ?
O9 W2 O15 Tb1 76.7(4) . . . . ?
O9 W2 O8 Na5 153.0(9) . . . 2_667 ?
O9 W3 O16 Tb1 -75.7(4) . . . . ?
O9 W3 O10 Na4 49.8(5) . . . . ?
O13 W5 O18 Tb1 -78.6(4) . . . . ?
O13 W4 O12 Na8 165.0(4) . . . 2_666 ?
O13 W4 O17 Tb1 78.1(4) . . . . ?
O7 W2 O15 Tb1 -75.9(4) . . . . ?
O7 W2 O8 Na5 -36.5(9) . . . 2_667 ?
O7 W5 O18 Tb1 77.3(4) . . . . ?
O11 W4 O12 Na8 -24.8(5) . . . 2_666 ?
O11 W4 O17 Tb1 -76.7(4) . . . . ?
O11 W3 O16 Tb1 78.7(4) . . . . ?
O11 W3 O10 Na4 -119.1(4) . . . . ?
O5 W5 O18 Tb1 -2.6(10) . . . . ?
O5 W1 O2 W2 -76.3(4) . . . . ?
O5 W1 O3 W3 5.7(8) . . . . ?
O33 W7 O20 Tb1 2.1(10) . . . . ?
O33 W10 O34 W8 77.1(4) . . . . ?
O27 W8 O28 Na1 87.5(6) . . . . ?
O27 W8 O21 Tb1 78.1(4) . . . . ?
O27 W7 O20 Tb1 -77.5(4) . . . . ?
O15 W2 O8 Na5 58.6(9) . . . 2_667 ?
O12 W4 O17 Tb1 -178.7(4) . . . . ?
O4 W4 O12 Na8 -109.8(5) . . . 2_666 ?
O4 W4 O17 Tb1 1.8(10) . . . . ?
O4 W1 O2 W2 -2.0(8) . . . . ?
O4 W1 O3 W3 77.8(3) . . . . ?
O24 W6 O19 Tb1 -179.7(4) . . . . ?
O28 W8 O21 Tb1 -177.6(4) . . . . ?
O6 W2 O15 Tb1 1.1(4) . . . . ?
O6 W5 O18 Tb1 -1.5(4) . . . . ?
O6 W4 O17 Tb1 0.5(4) . . . . ?
O6 W3 O16 Tb1 1.8(4) . . . . ?
O6 W1 O2 W2 -0.1(3) . . . . ?
O6 W1 O3 W3 1.4(3) . . . . ?
O8 W2 O15 Tb1 -177.5(4) . . . . ?
O16 W3 O10 Na4 144.9(4) . . . . ?
O21 W8 O28 Na1 -8.0(7) . . . . ?
O14 W5 O18 Tb1 -179.8(4) . . . . ?
O30 W9 O22 Tb1 -179.7(4) . . . . ?
O26 W7 O20 Tb1 179.1(4) . . . . ?
O36 W10 O34 W8 -179.9(3) . . . . ?
O17 W4 O12 Na8 70.4(5) . . . 2_666 ?
O23 W9 O22 Tb1 -77.4(4) . . . . ?
O23 W6 O19 Tb1 77.6(4) . . . . ?
O10 W3 O16 Tb1 -178.1(4) . . . . ?
O31 W9 O22 Tb1 -0.8(4) . . . . ?
O31 W8 O21 Tb1 -0.2(4) . . . . ?
O31 W6 O19 Tb1 1.1(4) . . . . ?
O31 W7 O20 Tb1 0.5(4) . . . . ?
O31 W10 O34 W8 -0.6(3) . . . . ?
O1 W1 O2 W2 -178.6(4) . . . . ?
O1 W1 O3 W3 178.8(3) . . . . ?

_shelx_SHELXL_version_number     2014/7
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
0 -8 -12 0.0479 0.0556 -7.9434 -11.9616 -1.0847 0.6169 0.0400
-2 6 0 0.0635 -2.0049 5.9793 -0.0491 0.5908 -0.0389 0.4613
4 2 -1 0.0371 4.0250 2.0174 -0.9917 0.2759 0.4804 -0.2041
-6 1 -6 0.0388 -5.9945 0.9993 -5.9946 -0.1400 -0.1226 0.7685
0 0 1 0.0150 -0.0000 -0.0000 1.0000 0.0205 -0.0668 -0.0361
0 0 -1 0.0150 0.0000 0.0000 -1.0000 -0.0205 0.0668 0.0361

_olex2_submission_special_instructions 'No special instructions were received'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_h-m   'P -1'
_symmetry_int_tables_number      2
_chemical_absolute_configuration ?

#===END

data_mv_2_38Tb_B
_audit_creation_date              2015-04-02
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_publ_contact_author_address      ?
_publ_contact_author_email        ?
_publ_contact_author_name         ''
_publ_contact_author_phone        ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2008). Acta Cryst. A64, 112-122.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
;
_chemical_name_common             ?
_chemical_name_systematic         ?
_chemical_formula_moiety          'Na9 O71.5 Tb W10, 0.5(O)'
_chemical_formula_sum             'H72 Na9 O72 Tb W10'
_chemical_formula_weight          3428.90
_chemical_melting_point           ?
_chemical_oxdiff_formula          'W10 O72 Tb1 Na9 H72'
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'Na' 'Na' 0.1353 0.1239 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Tb' 'Tb' -9.1472 9.1891
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'W' 'W' -5.4734 5.5774 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system       'triclinic'
_space_group_IT_number            2
_space_group_name_H-M_alt         'P -1'
_space_group_name_Hall            '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_symmetry_space_group_name_H-M_alt 'P -1'
_cell_length_a                    12.8949(5)
_cell_length_b                    13.1098(5)
_cell_length_c                    20.9057(7)
_cell_angle_alpha                 76.956(3)
_cell_angle_beta                  83.954(3)
_cell_angle_gamma                 77.348(3)
_cell_volume                      3353.5(2)
_cell_formula_units_Z             2
_cell_measurement_reflns_used     9545
_cell_measurement_temperature     131.10(10)
_cell_measurement_theta_max       71.2540
_cell_measurement_theta_min       3.4960
_cell_oxdiff_angle_alpha          76.956(3)
_cell_oxdiff_angle_beta           83.954(3)
_cell_oxdiff_angle_gamma          77.348(3)
_cell_oxdiff_length_a             12.8949(5)
_cell_oxdiff_length_b             13.1098(5)
_cell_oxdiff_length_c             20.9057(7)
_cell_oxdiff_measurement_reflns_used 9545
_cell_oxdiff_volume               3353.5(2)
_shelx_estimated_absorpt_T_max    ?
_shelx_estimated_absorpt_T_min    ?
_exptl_absorpt_coefficient_mu     37.561
_exptl_absorpt_correction_T_max   0.511
_exptl_absorpt_correction_T_min   0.134
_exptl_absorpt_correction_type    gaussian
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details    ?
_exptl_crystal_colour             ?
_exptl_crystal_density_diffrn     3.396
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     ?
_exptl_crystal_description        block
_exptl_crystal_F_000              3104
_exptl_crystal_size_max           0.1477
_exptl_crystal_size_mid           0.0402
_exptl_crystal_size_min           0.0344
_exptl_transmission_factor_max    ?
_exptl_transmission_factor_min    ?
_diffrn_reflns_av_R_equivalents   0.0364
_diffrn_reflns_av_unetI/netI      0.0615
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.973
_diffrn_reflns_limit_h_max        15
_diffrn_reflns_limit_h_min        -15
_diffrn_reflns_limit_k_max        16
_diffrn_reflns_limit_k_min        -15
_diffrn_reflns_limit_l_max        25
_diffrn_reflns_limit_l_min        -25
_diffrn_reflns_number             22609
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.973
_diffrn_reflns_theta_full         67.684
_diffrn_reflns_theta_max          71.499
_diffrn_reflns_theta_min          3.519
_diffrn_ambient_environment       N~2~
_diffrn_ambient_temperature       131.10(10)
_diffrn_detector                  'CCD plate'
_diffrn_detector_area_resol_mean  10.2273
_diffrn_detector_type             Atlas
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   28.00   71.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       38.4657 -125.0000  -30.0000 43

#__ type_ start__ end____ width___ exp.time_
  2 omega   28.00   58.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       38.4657 -125.0000 -120.0000 30

#__ type_ start__ end____ width___ exp.time_
  3 omega   41.00  133.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  -61.0000  -30.0000 92

#__ type_ start__ end____ width___ exp.time_
  4 omega   66.00   91.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  -30.0000    0.0000 25

#__ type_ start__ end____ width___ exp.time_
  5 omega   74.00  173.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966   45.0000   60.0000 99

#__ type_ start__ end____ width___ exp.time_
  6 omega  135.00  176.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  111.0000  -30.0000 41

#__ type_ start__ end____ width___ exp.time_
  7 omega  123.00  149.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  178.0000 -150.0000 26

#__ type_ start__ end____ width___ exp.time_
  8 omega   94.00  138.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  178.0000 -120.0000 44

#__ type_ start__ end____ width___ exp.time_
  9 omega   74.00  178.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966   45.0000    0.0000 104

#__ type_ start__ end____ width___ exp.time_
 10 omega  115.00  177.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966   45.0000  -60.0000 62

#__ type_ start__ end____ width___ exp.time_
 11 omega   65.00   91.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  -30.0000  150.0000 26

#__ type_ start__ end____ width___ exp.time_
 12 omega   27.00   76.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  -30.0000   60.0000 49

#__ type_ start__ end____ width___ exp.time_
 13 omega   26.00  108.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  -94.0000  -30.0000 82

#__ type_ start__ end____ width___ exp.time_
 14 omega   58.00   85.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  -30.0000 -150.0000 27

#__ type_ start__ end____ width___ exp.time_
 15 omega   29.00   91.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966  -94.0000  -90.0000 62

#__ type_ start__ end____ width___ exp.time_
 16 omega   27.00  115.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      104.0966 -111.0000 -150.0000 88

#__ type_ start__ end____ width___ exp.time_
 17 omega   28.00   63.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       38.4657 -125.0000   60.0000 35

#__ type_ start__ end____ width___ exp.time_
 18 omega  -96.00  -27.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -38.4657  125.0000   60.0000 69

#__ type_ start__ end____ width___ exp.time_
 19 omega -130.00   53.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -38.4657    0.0000   30.0000 183
;
_diffrn_measurement_device        'four-circle diffractometer'
_diffrn_measurement_device_type   'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method        'ω scans'
_diffrn_orient_matrix_UB_11       -0.0041509000
_diffrn_orient_matrix_UB_12       0.1062301000
_diffrn_orient_matrix_UB_13       -0.0505259000
_diffrn_orient_matrix_UB_21       0.0974229000
_diffrn_orient_matrix_UB_22       0.0186708000
_diffrn_orient_matrix_UB_23       0.0291666000
_diffrn_orient_matrix_UB_31       0.0744045000
_diffrn_orient_matrix_UB_32       -0.0594378000
_diffrn_orient_matrix_UB_33       -0.0483541000
_diffrn_radiation_monochromator   mirror
_diffrn_radiation_probe           x-ray
_diffrn_radiation_type            CuK\a
_diffrn_radiation_wavelength      1.54184
_diffrn_source                    'sealed X-ray tube'
_diffrn_source_type               'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage          0.000
_reflns_Friedel_fraction_full     .
_reflns_Friedel_fraction_max      .
_reflns_number_gt                 10916
_reflns_number_total              12708
_reflns_odcompleteness_completeness 99.75
_reflns_odcompleteness_iscentric  1
_reflns_odcompleteness_theta      66.97
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression      'I > 2σ(I)'
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_molecular_graphics     'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material   'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement   'ShelXL (Sheldrick, 2008)'
_computing_structure_solution     'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max          4.488
_refine_diff_density_min          -2.607
_refine_diff_density_rms          0.338
_refine_ls_extinction_coef        .
_refine_ls_extinction_method      none
_refine_ls_goodness_of_fit_ref    1.052
_refine_ls_hydrogen_treatment     undef
_refine_ls_matrix_type            full
_refine_ls_number_parameters      848
_refine_ls_number_reflns          12708
_refine_ls_number_restraints      19
_refine_ls_R_factor_all           0.0439
_refine_ls_R_factor_gt            0.0353
_refine_ls_restrained_S_all       1.051
_refine_ls_shift/su_max           0.001
_refine_ls_shift/su_mean          0.000
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0430P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme       calc
_refine_ls_wR_factor_gt           0.0863
_refine_ls_wR_factor_ref          0.0912
_refine_special_details           ?
_olex2_refinement_description
;
1. Uiso/Uaniso restraints and constraints
Uanis(O26) \\sim Ueq, Uanis(O27) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(O18) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
2. Others
 1*[Sof(Na2)]+1*[Sof(Na1)]+1*[Sof(Na15)]+1*[Sof(Na14)]+1*[Sof(Na4)]+1*
 [Sof(Na3)]=1.5 with esd of 0.001
 Sof(Na5)=1-FVAR(1)
 Sof(Na6)=FVAR(1)
 Sof(O40)=1-FVAR(6)
 Sof(O41)=FVAR(6)
 Sof(O62)=1-FVAR(7)
 Sof(O63)=FVAR(7)
 Fixed Sof: O76(0.5) O67(0.5) O69(0.5) O72(0.5) O71(0.5) O68(0.5) O70(0.5)
 O74(0.5)
;
_atom_sites_solution_hydrogens    .
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 W5 W 0.00726(3) 0.36991(3) 0.13712(2) 0.00835(9) Uani 1 1 d . . . . .
 W4 W -0.10153(3) 0.25822(3) 0.27617(2) 0.00762(8) Uani 1 1 d . . . . .
 W9 W 0.25457(3) -0.10062(3) 0.18414(2) 0.00915(9) Uani 1 1 d . . . . .
 W1 W -0.10511(3) 0.51899(3) 0.24576(2) 0.00947(9) Uani 1 1 d . . . . .
 W8 W 0.26793(3) -0.12706(3) 0.34307(2) 0.00921(9) Uani 1 1 d . . . . .
 W3 W 0.05016(3) 0.34936(3) 0.35660(2) 0.00939(9) Uani 1 1 d . . . . .
 W2 W 0.15758(3) 0.46181(3) 0.21750(2) 0.00982(9) Uani 1 1 d . . . . .
 W7 W 0.46099(3) 0.00500(3) 0.31610(2) 0.01220(9) Uani 1 1 d . . . . .
 W6 W 0.44772(3) 0.03283(3) 0.15714(2) 0.00925(9) Uani 1 1 d . . . . .
 W10 W 0.48378(3) -0.21021(3) 0.25219(2) 0.01432(9) Uani 1 1 d . . . . .
 Tb1 Tb 0.19748(4) 0.15839(4) 0.24728(3) 0.00808(11) Uani 1 1 d . . . . .
 Na9 Na 0.1361(3) 0.1605(3) 0.94190(18) 0.0151(7) Uani 1 1 d . . . . .
 Na10 Na 0.1379(3) 0.0462(3) 0.80789(18) 0.0144(7) Uani 1 1 d . . . . .
 Na12 Na 0.1174(3) 0.0257(3) 0.52464(18) 0.0146(7) Uani 1 1 d . . . . .
 Na8 Na 0.3078(3) 0.2852(3) 0.96703(19) 0.0178(8) Uani 1 1 d . . . . .
 Na11 Na 0.1021(3) 0.1922(3) 0.64100(19) 0.0184(8) Uani 1 1 d . . . . .
 Na7 Na 0.4411(3) 0.5558(3) 0.8619(2) 0.0196(8) Uani 1 1 d . . . . .
 Na13 Na 0.0000 0.5000 0.5000 0.0238(13) Uani 1 2 d S T P . .
 O5 O -0.1006(5) 0.4999(5) 0.1573(3) 0.0134(13) Uani 1 1 d . . . . .
 O9 O 0.1439(5) 0.4431(5) 0.3127(3) 0.0127(13) Uani 1 1 d . . . . .
 O25 O 0.5220(5) 0.0522(6) 0.2278(3) 0.0150(13) Uani 1 1 d . . . . .
 O2 O 0.0224(5) 0.5740(5) 0.2232(3) 0.0132(13) Uani 1 1 d . . . . .
 O29 O 0.2043(5) -0.1642(5) 0.2731(3) 0.0124(13) Uani 1 1 d . . . . .
 O4 O -0.1855(5) 0.4080(5) 0.2691(3) 0.0116(12) Uani 1 1 d . . . . .
 O34 O 0.3890(5) -0.2462(5) 0.3284(3) 0.0177(14) Uani 1 1 d . . . . .
 O23 O 0.3538(5) -0.0342(5) 0.1199(3) 0.0117(12) Uani 1 1 d . . . . .
 O11 O -0.0685(5) 0.2754(5) 0.3609(3) 0.0103(12) Uani 1 1 d . . . . .
 O7 O 0.1090(5) 0.4622(5) 0.1331(3) 0.0134(13) Uani 1 1 d . . . . .
 O18 O 0.1099(5) 0.2528(5) 0.1485(3) 0.0084(11) Uani 1 1 d . U . . .
 O13 O -0.1022(5) 0.2928(5) 0.1800(3) 0.0111(12) Uani 1 1 d . . . . .
 O32 O 0.5336(5) -0.1175(6) 0.1769(4) 0.0180(14) Uani 1 1 d . . . . .
 O16 O 0.1442(5) 0.2322(5) 0.3448(3) 0.0107(12) Uani 1 1 d . . . . .
 O17 O 0.0125(5) 0.1545(5) 0.2717(3) 0.0086(11) Uani 1 1 d . . . . .
 O3 O -0.0654(5) 0.4805(5) 0.3343(3) 0.0139(13) Uani 1 1 d . . . . .
 O22 O 0.1733(5) 0.0268(5) 0.1914(3) 0.0113(12) Uani 1 1 d . . . . .
 O20 O 0.3555(5) 0.1203(5) 0.3065(3) 0.0121(12) Uani 1 1 d . . . . .
 O19 O 0.3426(5) 0.1443(5) 0.1658(3) 0.0101(12) Uani 1 1 d . . . . .
 O54 O 0.1118(6) 0.3372(5) 0.9518(3) 0.0160(14) Uani 1 1 d . . . . .
 O48 O 0.0253(5) 0.1987(5) 0.8463(3) 0.0160(13) Uani 1 1 d . . . . .
 O39 O 0.0133(5) 0.1883(5) 0.5468(3) 0.0143(13) Uani 1 1 d . . . . .
 O21 O 0.1862(5) 0.0042(5) 0.3305(3) 0.0096(12) Uani 1 1 d . . . . .
 O35 O 0.3782(6) -0.2232(5) 0.1995(3) 0.0170(14) Uani 1 1 d . . . . .
 O6 O 0.0210(5) 0.3684(5) 0.2466(3) 0.0100(12) Uani 1 1 d . . . . .
 O31 O 0.3648(5) -0.0563(5) 0.2502(3) 0.0103(12) Uani 1 1 d . . . . .
 O27 O 0.3763(5) -0.0788(5) 0.3805(3) 0.0154(13) Uani 1 1 d . U . . .
 O10 O 0.0556(6) 0.3530(5) 0.4386(3) 0.0140(13) Uani 1 1 d . . . . .
 O24 O 0.5252(6) 0.0816(5) 0.0885(3) 0.0172(14) Uani 1 1 d . . . . .
 O52 O -0.0053(6) 0.1026(6) 1.0084(4) 0.0198(14) Uani 1 1 d . . . . .
 O55 O 0.2258(6) 0.1455(5) 1.0399(3) 0.0177(14) Uani 1 1 d . . . . .
 O42 O -0.0246(5) -0.0537(5) 0.5759(3) 0.0140(13) Uani 1 1 d . . . . .
 O33 O 0.5466(5) -0.1396(6) 0.3058(3) 0.0195(15) Uani 1 1 d . . . . .
 O45 O -0.0623(6) 0.3033(6) 0.6818(4) 0.0216(15) Uani 1 1 d . . . . .
 O65 O 0.6517(7) 0.4449(6) 0.6887(4) 0.0266(17) Uani 1 1 d . . . . .
 O30 O 0.1820(6) -0.1481(5) 0.1362(3) 0.0176(14) Uani 1 1 d . . . . .
 O51 O 0.2321(6) -0.0041(6) 0.9157(4) 0.0247(16) Uani 1 1 d . . . . .
 O46 O 0.0229(5) 0.0580(5) 0.7146(3) 0.0169(14) Uani 1 1 d . . . . .
 O14 O -0.0218(6) 0.3911(5) 0.0559(3) 0.0141(13) Uani 1 1 d . . . . .
 O53 O 0.2821(5) 0.2247(5) 0.8731(3) 0.0177(14) Uani 1 1 d . . . . .
 O8 O 0.2461(6) 0.5472(5) 0.1972(3) 0.0162(14) Uani 1 1 d . . . . .
 O1 O -0.1997(5) 0.6355(5) 0.2443(3) 0.0136(13) Uani 1 1 d . . . . .
 O61 O 0.2988(6) 0.7101(7) 0.8782(5) 0.0300(18) Uani 1 1 d . . . . .
 O59 O 0.5797(6) 0.3927(6) 0.8835(4) 0.0300(18) Uani 1 1 d . . . . .
 O58 O 0.2966(6) 0.4726(6) 0.9161(4) 0.0279(17) Uani 1 1 d . . . . .
 O26 O 0.5494(5) 0.0345(6) 0.3646(3) 0.0199(15) Uani 1 1 d . U . . .
 O15 O 0.2410(5) 0.3319(5) 0.2228(3) 0.0126(13) Uani 1 1 d . . . . .
 O78 O 0.2163(7) 0.8084(8) 0.0123(4) 0.035(2) Uani 1 1 d . . . . .
 O47 O 0.2253(5) 0.1675(5) 0.7250(3) 0.0155(13) Uani 1 1 d . . . . .
 O28 O 0.2066(6) -0.1968(5) 0.4129(3) 0.0167(14) Uani 1 1 d . . . . .
 O12 O -0.2051(5) 0.1894(5) 0.2992(3) 0.0139(13) Uani 1 1 d . . . . .
 O60 O 0.3934(6) 0.5341(6) 0.7617(4) 0.0265(17) Uani 1 1 d . . . . .
 O56 O 0.4928(7) 0.1952(7) 0.9568(4) 0.0311(19) Uani 1 1 d . . . . .
 O38 O 0.1159(7) 0.3767(6) 0.5825(4) 0.0257(17) Uani 1 1 d . . . . .
 O50 O 0.2782(6) -0.0934(6) 0.7865(4) 0.0186(14) Uani 1 1 d . . . . .
 O36 O 0.5745(6) -0.3282(6) 0.2541(4) 0.0265(17) Uani 1 1 d . . . . .
 O44 O 0.2511(7) 0.0951(8) 0.4518(4) 0.0325(19) Uani 1 1 d . . . . .
 O57 O 0.3286(9) 0.3294(6) 1.0683(4) 0.039(2) Uani 1 1 d . . . . .
 O37 O 0.1445(7) 0.5685(7) 0.4385(6) 0.044(2) Uani 1 1 d . . . . .
 O64 O 0.5394(7) 0.6802(7) 0.7956(5) 0.0341(19) Uani 1 1 d . . . . .
 O41 O 0.2198(8) 0.0240(8) 0.6178(5) 0.020(3) Uiso 0.69(2) 1 d . . . A 2
 O75 O 0.2745(9) 0.4327(7) 0.4057(5) 0.052(3) Uani 1 1 d . . . . .
 O77 O 0.3488(9) 0.6700(7) 0.0011(5) 0.047(3) Uani 1 1 d . . . . .
 O66 O 0.6413(11) 0.6939(9) 0.6460(6) 0.059(3) Uani 1 1 d . . . . .
 O43 O 0.2178(12) -0.1586(11) 0.5426(6) 0.085(5) Uani 1 1 d . . . . .
 O63 O 0.5042(11) 0.5810(11) 0.9591(7) 0.038(4) Uiso 0.68(3) 1 d . . . B 1
 O73 O 0.6097(10) 0.3005(11) 0.4546(7) 0.064(3) Uani 1 1 d . . . . .
 Na6 Na 0.5221(5) 0.5961(5) 0.6933(3) 0.022(2) Uani 0.646(17) 1 d . . . B 1
 O49 O 0.0275(5) -0.0824(5) 0.8573(3) 0.0142(13) Uiso 1 1 d . . . . .
 Na5 Na 0.4814(11) 0.6014(10) 0.6469(7) 0.029(4) Uani 0.354(17) 1 d . . . B 2
 O76 O 0.2780(16) 0.2786(16) 0.4995(10) 0.040(4) Uiso 0.5 1 d . . . . .
 O67 O 0.3312(16) 0.5414(16) 0.6125(10) 0.043(4) Uiso 0.5 1 d . . . . .
 O69 O 0.3369(17) 0.4102(17) 0.6163(11) 0.048(5) Uiso 0.5 1 d . . . B .
 Na2 Na 0.5585(18) 0.3541(17) 0.5554(10) 0.021(7) Uiso 0.199(19) 1 d . . . B 3
 Na1 Na 0.5951(17) 0.2486(17) 0.3546(11) 0.043(6) Uiso 0.272(16) 1 d . . . B 4
 O72 O 0.482(2) 0.246(2) 0.5406(14) 0.068(7) Uiso 0.5 1 d . . . . .
 Na15 Na 0.1900(14) 0.5833(12) 0.0176(8) 0.029(5) Uiso 0.31(2) 1 d . . . C 6
 Na14 Na 0.250(2) 0.543(2) 0.0294(12) 0.062(8) Uiso 0.32(2) 1 d . . . C 5
 O71 O 0.7742(17) 0.3774(17) 0.4457(10) 0.045(5) Uiso 0.5 1 d . . . . .
 O68 O 0.5715(18) 0.5566(18) 0.5503(11) 0.050(5) Uiso 0.5 1 d . . . . .
 O40 O 0.2519(19) 0.1035(19) 0.5818(12) 0.021(7) Uiso 0.31(2) 1 d . . . A 1
 O62 O 0.4392(19) 0.6371(18) 0.9736(11) 0.021(7) Uiso 0.32(3) 1 d . . . B 2
 Na4 Na 0.669(2) 0.4118(19) 0.5255(12) 0.025(8) Uiso 0.187(19) 1 d . . . B 1
 Na3 Na 0.605(3) 0.392(3) 0.5391(16) 0.048(10) Uiso 0.21(2) 1 d . . . B 2
 O70 O 0.353(2) 0.333(2) 0.6046(12) 0.058(6) Uiso 0.5 1 d . . . . .
 O74 O 0.428(2) 0.246(2) 0.4840(12) 0.060(6) Uiso 0.5 1 d . . . B .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 W5 O5 2.045(6) . ?
 W5 O7 1.954(7) . ?
 W5 O18 1.782(6) . ?
 W5 O13 1.941(7) . ?
 W5 O6 2.310(6) . ?
 W5 O14 1.724(6) . ?
 W4 O4 2.005(6) . ?
 W4 O11 1.937(6) . ?
 W4 O13 1.959(6) . ?
 W4 O17 1.781(6) . ?
 W4 O6 2.315(6) . ?
 W4 O12 1.739(7) . ?
 W9 O29 1.964(7) . ?
 W9 O23 1.949(6) . ?
 W9 O22 1.796(6) . ?
 W9 O35 1.995(7) . ?
 W9 O31 2.325(6) . ?
 W9 O30 1.733(7) . ?
 W1 O5 1.914(6) . ?
 W1 O2 1.910(7) . ?
 W1 O4 1.914(7) . ?
 W1 O3 1.900(7) . ?
 W1 O6 2.264(6) . ?
 W1 O1 1.729(6) . ?
 W8 O29 1.949(6) . ?
 W8 O34 2.005(6) . ?
 W8 O21 1.789(6) . ?
 W8 O31 2.318(6) . ?
 W8 O27 1.952(7) . ?
 W8 O28 1.751(7) . ?
 W8 Na2 3.69(2) 2_656 ?
 W3 O9 1.929(7) . ?
 W3 O11 1.967(6) . ?
 W3 O16 1.784(6) . ?
 W3 O3 2.014(6) . ?
 W3 O6 2.318(6) . ?
 W3 O10 1.735(6) . ?
 W2 O9 1.944(6) . ?
 W2 O2 2.032(6) . ?
 W2 O7 1.932(6) . ?
 W2 O6 2.314(6) . ?
 W2 O8 1.725(7) . ?
 W2 O15 1.790(6) . ?
 W7 O25 1.950(6) . ?
 W7 O20 1.788(6) . ?
 W7 O31 2.319(6) . ?
 W7 O27 1.940(7) . ?
 W7 O33 2.019(7) . ?
 W7 O26 1.758(7) . ?
 W6 O25 1.933(7) . ?
 W6 O23 1.955(6) . ?
 W6 O32 2.013(7) . ?
 W6 O19 1.791(6) . ?
 W6 O31 2.319(6) . ?
 W6 O24 1.740(7) . ?
 W10 O34 1.938(7) . ?
 W10 O32 1.907(7) . ?
 W10 O35 1.897(7) . ?
 W10 O31 2.247(6) . ?
 W10 O33 1.939(8) . ?
 W10 O36 1.718(7) . ?
 Tb1 O18 2.407(6) . ?
 Tb1 O16 2.423(6) . ?
 Tb1 O17 2.396(6) . ?
 Tb1 O22 2.380(6) . ?
 Tb1 O20 2.395(6) . ?
 Tb1 O19 2.400(6) . ?
 Tb1 O21 2.371(6) . ?
 Tb1 O15 2.393(6) . ?
 Na9 Na10 3.459(5) . ?
 Na9 Na8 3.174(6) . ?
 Na9 O54 2.322(7) . ?
 Na9 O48 2.474(8) . ?
 Na9 O52 2.330(8) . ?
 Na9 O55 2.406(8) . ?
 Na9 O51 2.390(8) . ?
 Na9 O53 2.429(8) . ?
 Na10 Na11 3.604(5) . ?
 Na10 O48 2.441(7) . ?
 Na10 O51 2.558(9) . ?
 Na10 O46 2.529(8) . ?
 Na10 O47 2.436(8) . ?
 Na10 O50 2.361(7) . ?
 Na10 O49 2.426(8) . ?
 Na12 Na12 3.542(8) 2_556 ?
 Na12 Na11 3.581(5) . ?
 Na12 O39 2.371(7) . ?
 Na12 O42 2.345(8) . ?
 Na12 O42 2.443(7) 2_556 ?
 Na12 O44 2.372(9) . ?
 Na12 O41 2.459(11) . ?
 Na12 O43 2.445(12) . ?
 Na12 O40 2.69(2) . ?
 Na8 O54 2.505(8) . ?
 Na8 O55 2.458(8) . ?
 Na8 O53 2.356(8) . ?
 Na8 O58 2.426(8) . ?
 Na8 O56 2.429(9) . ?
 Na8 O57 2.374(9) . ?
 Na8 Na15 4.197(16) 1_556 ?
 Na8 Na14 3.79(2) 1_556 ?
 Na11 O39 2.396(7) . ?
 Na11 O45 2.484(8) . ?
 Na11 O46 2.396(8) . ?
 Na11 O47 2.412(8) . ?
 Na11 O38 2.488(9) . ?
 Na11 O41 2.503(10) . ?
 Na11 O40 2.40(2) . ?
 Na7 O61 2.475(9) . ?
 Na7 O59 2.456(9) . ?
 Na7 O58 2.415(9) . ?
 Na7 O60 2.338(8) . ?
 Na7 O64 2.388(9) . ?
 Na7 O63 2.380(14) . ?
 Na7 Na6 3.524(8) . ?
 Na7 Na14 4.06(2) 1_556 ?
 Na7 O62 2.77(2) . ?
 Na13 O10 2.489(6) . ?
 Na13 O10 2.489(6) 2_566 ?
 Na13 O38 2.459(8) . ?
 Na13 O38 2.459(8) 2_566 ?
 Na13 O37 2.374(10) 2_566 ?
 Na13 O37 2.374(10) . ?
 O34 Na2 2.60(2) 2_656 ?
 O34 Na3 2.99(3) 2_656 ?
 O7 Na15 2.813(17) . ?
 O7 Na14 2.85(3) . ?
 O42 Na12 2.443(7) 2_556 ?
 O65 Na6 2.310(10) . ?
 O65 Na5 2.723(16) . ?
 O14 Na15 2.707(18) 2_565 ?
 O58 Na15 2.898(17) 1_556 ?
 O58 Na14 2.69(2) 1_556 ?
 O26 Na1 2.95(2) . ?
 O78 Na15 3.020(18) . ?
 O28 Na4 3.00(2) 2_656 ?
 O12 Na1 2.74(2) 1_455 ?
 O60 Na6 2.241(11) . ?
 O60 Na5 2.595(16) . ?
 O57 Na14 2.72(3) 1_556 ?
 O37 Na4 2.68(3) 2_666 ?
 O64 Na6 2.667(12) . ?
 O75 Na4 2.99(3) 2_666 ?
 O77 Na15 2.51(2) . ?
 O77 Na14 2.26(3) . ?
 O77 O62 1.28(3) 1_554 ?
 O66 Na6 2.227(14) . ?
 O66 Na5 2.608(18) . ?
 O66 Na1 2.98(3) 2_666 ?
 O73 Na5 2.48(2) 2_666 ?
 O73 Na2 2.36(2) . ?
 O73 Na1 2.38(2) . ?
 O73 Na4 2.57(3) . ?
 O73 Na3 2.34(3) . ?
 Na5 O73 2.48(2) 2_666 ?
 Na5 O67 2.47(3) . ?
 Na5 O68 2.35(2) . ?
 Na5 Na3 3.91(3) . ?
 Na5 Na3 4.13(3) 2_666 ?
 O67 O69 1.69(3) . ?
 O67 Na4 2.81(3) 2_666 ?
 O69 Na2 3.01(3) . ?
 O69 O70 1.07(3) . ?
 Na2 W8 3.69(2) 2_656 ?
 Na2 O34 2.60(2) 2_656 ?
 Na2 Na2 4.06(4) 2_666 ?
 Na2 O72 1.99(4) . ?
 Na2 O68 2.67(3) . ?
 Na2 O68 2.80(3) 2_666 ?
 Na2 O70 2.79(3) . ?
 Na1 O12 2.74(2) 1_655 ?
 Na1 O66 2.98(3) 2_666 ?
 O72 Na3 2.73(5) . ?
 O72 O74 1.43(4) . ?
 Na15 Na8 4.197(16) 1_554 ?
 Na15 O14 2.707(18) 2_565 ?
 Na15 O58 2.898(17) 1_554 ?
 Na14 Na8 3.79(2) 1_554 ?
 Na14 Na7 4.06(2) 1_554 ?
 Na14 O58 2.69(2) 1_554 ?
 Na14 O57 2.72(3) 1_554 ?
 O71 Na4 2.11(3) . ?
 O71 Na3 2.77(4) . ?
 O68 Na2 2.80(3) 2_666 ?
 O68 Na4 2.17(3) . ?
 O68 Na3 2.97(4) 2_666 ?
 O68 Na3 2.17(4) . ?
 O62 O77 1.28(3) 1_556 ?
 Na4 O28 3.00(2) 2_656 ?
 Na4 O37 2.68(3) 2_666 ?
 Na4 O75 2.99(3) 2_666 ?
 Na4 O67 2.81(3) 2_666 ?
 Na3 O34 2.99(3) 2_656 ?
 Na3 Na5 4.13(3) 2_666 ?
 Na3 O68 2.97(4) 2_666 ?
 Na3 Na3 3.69(6) 2_666 ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 O5 W5 O6 73.9(2) . . ?
 O7 W5 O5 83.1(3) . . ?
 O7 W5 O6 77.2(2) . . ?
 O18 W5 O5 160.1(3) . . ?
 O18 W5 O7 91.9(3) . . ?
 O18 W5 O13 93.3(3) . . ?
 O18 W5 O6 86.2(2) . . ?
 O13 W5 O5 83.4(3) . . ?
 O13 W5 O7 154.2(3) . . ?
 O13 W5 O6 77.9(2) . . ?
 O14 W5 O5 95.6(3) . . ?
 O14 W5 O7 102.6(3) . . ?
 O14 W5 O18 104.4(3) . . ?
 O14 W5 O13 100.6(3) . . ?
 O14 W5 O6 169.4(3) . . ?
 O4 W4 O6 74.0(2) . . ?
 O11 W4 O4 83.8(3) . . ?
 O11 W4 O13 154.8(3) . . ?
 O11 W4 O6 78.0(2) . . ?
 O13 W4 O4 84.0(2) . . ?
 O13 W4 O6 77.5(2) . . ?
 O17 W4 O4 157.6(3) . . ?
 O17 W4 O11 93.0(3) . . ?
 O17 W4 O13 90.0(3) . . ?
 O17 W4 O6 83.6(3) . . ?
 O12 W4 O4 99.0(3) . . ?
 O12 W4 O11 100.8(3) . . ?
 O12 W4 O13 102.8(3) . . ?
 O12 W4 O17 103.3(3) . . ?
 O12 W4 O6 173.0(3) . . ?
 O29 W9 O35 84.2(3) . . ?
 O29 W9 O31 77.5(2) . . ?
 O23 W9 O29 154.3(3) . . ?
 O23 W9 O35 83.7(3) . . ?
 O23 W9 O31 77.5(2) . . ?
 O22 W9 O29 90.3(3) . . ?
 O22 W9 O23 92.1(3) . . ?
 O22 W9 O35 157.0(3) . . ?
 O22 W9 O31 83.3(2) . . ?
 O35 W9 O31 73.7(2) . . ?
 O30 W9 O29 101.3(3) . . ?
 O30 W9 O23 103.0(3) . . ?
 O30 W9 O22 103.3(3) . . ?
 O30 W9 O35 99.7(3) . . ?
 O30 W9 O31 173.4(3) . . ?
 O5 W1 O4 86.5(3) . . ?
 O5 W1 O6 77.4(2) . . ?
 O2 W1 O5 88.3(3) . . ?
 O2 W1 O4 154.5(3) . . ?
 O2 W1 O6 77.7(2) . . ?
 O4 W1 O6 76.9(2) . . ?
 O3 W1 O5 154.6(3) . . ?
 O3 W1 O2 87.6(3) . . ?
 O3 W1 O4 86.6(3) . . ?
 O3 W1 O6 77.2(2) . . ?
 O1 W1 O5 102.4(3) . . ?
 O1 W1 O2 101.2(3) . . ?
 O1 W1 O4 104.2(3) . . ?
 O1 W1 O3 103.1(3) . . ?
 O1 W1 O6 178.9(3) . . ?
 O29 W8 O34 84.4(3) . . ?
 O29 W8 O31 77.9(2) . . ?
 O29 W8 O27 154.8(3) . . ?
 O29 W8 Na2 114.4(4) . 2_656 ?
 O34 W8 O31 74.4(3) . . ?
 O34 W8 Na2 42.6(4) . 2_656 ?
 O21 W8 O29 92.3(3) . . ?
 O21 W8 O34 158.6(3) . . ?
 O21 W8 O31 84.2(3) . . ?
 O21 W8 O27 91.1(3) . . ?
 O21 W8 Na2 151.6(4) . 2_656 ?
 O31 W8 Na2 109.7(4) . 2_656 ?
 O27 W8 O34 83.3(3) . . ?
 O27 W8 O31 77.6(2) . . ?
 O27 W8 Na2 69.0(4) . 2_656 ?
 O28 W8 O29 101.1(3) . . ?
 O28 W8 O34 97.9(3) . . ?
 O28 W8 O21 103.5(3) . . ?
 O28 W8 O31 172.3(3) . . ?
 O28 W8 O27 102.4(3) . . ?
 O28 W8 Na2 63.6(4) . 2_656 ?
 O9 W3 O11 153.9(3) . . ?
 O9 W3 O3 84.2(3) . . ?
 O9 W3 O6 77.3(2) . . ?
 O11 W3 O3 82.6(3) . . ?
 O11 W3 O6 77.4(2) . . ?
 O16 W3 O9 92.9(3) . . ?
 O16 W3 O11 90.9(3) . . ?
 O16 W3 O3 157.9(3) . . ?
 O16 W3 O6 84.2(3) . . ?
 O3 W3 O6 73.9(2) . . ?
 O10 W3 O9 102.4(3) . . ?
 O10 W3 O11 101.5(3) . . ?
 O10 W3 O16 105.0(3) . . ?
 O10 W3 O3 96.9(3) . . ?
 O10 W3 O6 170.8(3) . . ?
 O9 W2 O2 82.6(3) . . ?
 O9 W2 O6 77.2(2) . . ?
 O2 W2 O6 74.2(2) . . ?
 O7 W2 O9 153.7(3) . . ?
 O7 W2 O2 83.9(3) . . ?
 O7 W2 O6 77.5(2) . . ?
 O8 W2 O9 101.2(3) . . ?
 O8 W2 O2 97.7(3) . . ?
 O8 W2 O7 102.9(3) . . ?
 O8 W2 O6 171.9(3) . . ?
 O8 W2 O15 103.7(3) . . ?
 O15 W2 O9 91.5(3) . . ?
 O15 W2 O2 158.5(3) . . ?
 O15 W2 O7 92.9(3) . . ?
 O15 W2 O6 84.3(3) . . ?
 O25 W7 O31 76.8(3) . . ?
 O25 W7 O33 83.5(3) . . ?
 O20 W7 O25 91.6(3) . . ?
 O20 W7 O31 84.9(2) . . ?
 O20 W7 O27 92.3(3) . . ?
 O20 W7 O33 159.2(3) . . ?
 O27 W7 O25 153.8(3) . . ?
 O27 W7 O31 77.8(3) . . ?
 O27 W7 O33 83.7(3) . . ?
 O33 W7 O31 74.3(3) . . ?
 O26 W7 O25 101.3(3) . . ?
 O26 W7 O20 103.8(3) . . ?
 O26 W7 O31 171.2(3) . . ?
 O26 W7 O27 102.8(3) . . ?
 O26 W7 O33 97.0(3) . . ?
 O25 W6 O23 153.8(3) . . ?
 O25 W6 O32 84.1(3) . . ?
 O25 W6 O31 77.1(2) . . ?
 O23 W6 O32 82.7(3) . . ?
 O23 W6 O31 77.5(2) . . ?
 O32 W6 O31 73.8(3) . . ?
 O19 W6 O25 92.1(3) . . ?
 O19 W6 O23 91.9(3) . . ?
 O19 W6 O32 158.3(3) . . ?
 O19 W6 O31 84.6(3) . . ?
 O24 W6 O25 101.5(3) . . ?
 O24 W6 O23 102.6(3) . . ?
 O24 W6 O32 97.3(3) . . ?
 O24 W6 O19 104.3(3) . . ?
 O24 W6 O31 171.1(3) . . ?
 O34 W10 O31 77.3(3) . . ?
 O34 W10 O33 86.5(3) . . ?
 O32 W10 O34 154.8(3) . . ?
 O32 W10 O31 77.5(3) . . ?
 O32 W10 O33 87.7(3) . . ?
 O35 W10 O34 87.7(3) . . ?
 O35 W10 O32 87.2(3) . . ?
 O35 W10 O31 77.4(2) . . ?
 O35 W10 O33 154.9(3) . . ?
 O33 W10 O31 77.5(2) . . ?
 O36 W10 O34 102.4(3) . . ?
 O36 W10 O32 102.8(3) . . ?
 O36 W10 O35 102.6(4) . . ?
 O36 W10 O31 179.7(4) . . ?
 O36 W10 O33 102.5(4) . . ?
 O18 Tb1 O16 116.9(2) . . ?
 O17 Tb1 O18 74.2(2) . . ?
 O17 Tb1 O16 73.3(2) . . ?
 O17 Tb1 O19 145.2(2) . . ?
 O22 Tb1 O18 73.2(2) . . ?
 O22 Tb1 O16 144.2(2) . . ?
 O22 Tb1 O17 77.5(2) . . ?
 O22 Tb1 O20 117.1(2) . . ?
 O22 Tb1 O19 74.1(2) . . ?
 O22 Tb1 O15 139.4(2) . . ?
 O20 Tb1 O18 146.5(2) . . ?
 O20 Tb1 O16 74.7(2) . . ?
 O20 Tb1 O17 137.6(2) . . ?
 O20 Tb1 O19 74.6(2) . . ?
 O19 Tb1 O18 78.7(2) . . ?
 O19 Tb1 O16 139.9(2) . . ?
 O21 Tb1 O18 137.6(2) . . ?
 O21 Tb1 O16 77.4(2) . . ?
 O21 Tb1 O17 72.6(2) . . ?
 O21 Tb1 O22 74.5(2) . . ?
 O21 Tb1 O20 73.9(2) . . ?
 O21 Tb1 O19 117.3(2) . . ?
 O21 Tb1 O15 145.1(2) . . ?
 O15 Tb1 O18 74.2(2) . . ?
 O15 Tb1 O16 73.5(2) . . ?
 O15 Tb1 O17 115.7(2) . . ?
 O15 Tb1 O20 80.1(2) . . ?
 O15 Tb1 O19 76.3(2) . . ?
 Na8 Na9 Na10 126.01(15) . . ?
 O54 Na9 Na10 132.1(2) . . ?
 O54 Na9 Na8 51.4(2) . . ?
 O54 Na9 O48 95.5(3) . . ?
 O54 Na9 O52 102.4(3) . . ?
 O54 Na9 O55 77.3(3) . . ?
 O54 Na9 O51 155.9(3) . . ?
 O54 Na9 O53 76.3(3) . . ?
 O48 Na9 Na10 44.88(17) . . ?
 O48 Na9 Na8 128.5(2) . . ?
 O52 Na9 Na10 101.8(2) . . ?
 O52 Na9 Na8 131.8(2) . . ?
 O52 Na9 O48 88.4(3) . . ?
 O52 Na9 O55 88.6(3) . . ?
 O52 Na9 O51 100.6(3) . . ?
 O52 Na9 O53 178.7(3) . . ?
 O55 Na9 Na10 143.7(2) . . ?
 O55 Na9 Na8 49.98(19) . . ?
 O55 Na9 O48 171.5(3) . . ?
 O55 Na9 O53 91.1(3) . . ?
 O51 Na9 Na10 47.7(2) . . ?
 O51 Na9 Na8 106.8(2) . . ?
 O51 Na9 O48 92.0(3) . . ?
 O51 Na9 O55 96.4(3) . . ?
 O51 Na9 O53 80.7(3) . . ?
 O53 Na9 Na10 79.1(2) . . ?
 O53 Na9 Na8 47.47(19) . . ?
 O53 Na9 O48 91.6(3) . . ?
 Na9 Na10 Na11 125.03(13) . . ?
 O48 Na10 Na9 45.66(18) . . ?
 O48 Na10 Na11 89.0(2) . . ?
 O48 Na10 O51 88.8(2) . . ?
 O48 Na10 O46 94.5(2) . . ?
 O51 Na10 Na9 43.70(17) . . ?
 O51 Na10 Na11 152.4(2) . . ?
 O46 Na10 Na9 139.8(2) . . ?
 O46 Na10 Na11 41.56(18) . . ?
 O46 Na10 O51 165.9(3) . . ?
 O47 Na10 Na9 99.4(2) . . ?
 O47 Na10 Na11 41.73(18) . . ?
 O47 Na10 O48 90.0(2) . . ?
 O47 Na10 O51 110.8(3) . . ?
 O47 Na10 O46 83.0(3) . . ?
 O50 Na10 Na9 121.0(2) . . ?
 O50 Na10 Na11 98.3(2) . . ?
 O50 Na10 O48 165.7(3) . . ?
 O50 Na10 O51 78.9(3) . . ?
 O50 Na10 O46 99.2(3) . . ?
 O50 Na10 O47 87.4(3) . . ?
 O50 Na10 O49 90.4(3) . . ?
 O49 Na10 Na9 98.2(2) . . ?
 O49 Na10 Na11 119.8(2) . . ?
 O49 Na10 O48 96.6(3) . . ?
 O49 Na10 O51 87.7(3) . . ?
 O49 Na10 O46 78.3(2) . . ?
 O49 Na10 O47 160.6(3) . . ?
 Na12 Na12 Na11 120.45(16) 2_556 . ?
 O39 Na12 Na12 87.5(2) . 2_556 ?
 O39 Na12 Na11 41.56(18) . . ?
 O39 Na12 O42 89.8(2) . 2_556 ?
 O39 Na12 O44 99.0(3) . . ?
 O39 Na12 O41 85.8(3) . . ?
 O39 Na12 O43 160.4(4) . . ?
 O39 Na12 O40 76.4(5) . . ?
 O42 Na12 Na12 43.37(18) . 2_556 ?
 O42 Na12 Na12 41.24(18) 2_556 2_556 ?
 O42 Na12 Na11 94.6(2) . . ?
 O42 Na12 Na11 131.1(2) 2_556 . ?
 O42 Na12 O39 86.4(3) . . ?
 O42 Na12 O42 84.6(3) . 2_556 ?
 O42 Na12 O44 167.2(3) . . ?
 O42 Na12 O41 102.9(3) . . ?
 O42 Na12 O41 171.0(3) 2_556 . ?
 O42 Na12 O43 83.8(5) . . ?
 O42 Na12 O43 106.0(4) 2_556 . ?
 O42 Na12 O40 127.4(6) . . ?
 O42 Na12 O40 143.1(6) 2_556 . ?
 O44 Na12 Na12 124.9(3) . 2_556 ?
 O44 Na12 Na11 97.1(3) . . ?
 O44 Na12 O42 83.8(3) . 2_556 ?
 O44 Na12 O41 89.1(3) . . ?
 O44 Na12 O43 94.2(5) . . ?
 O44 Na12 O40 65.3(6) . . ?
 O41 Na12 Na12 146.1(3) . 2_556 ?
 O41 Na12 Na11 44.3(2) . . ?
 O43 Na12 Na12 96.8(5) . 2_556 ?
 O43 Na12 Na11 122.5(4) . . ?
 O43 Na12 O41 80.0(5) . . ?
 O43 Na12 O40 96.4(7) . . ?
 O40 Na12 Na12 162.6(5) . 2_556 ?
 O40 Na12 Na11 42.2(5) . . ?
 Na9 Na8 Na15 116.5(3) . 1_556 ?
 Na9 Na8 Na14 126.0(4) . 1_556 ?
 O54 Na8 Na9 46.46(18) . . ?
 O54 Na8 Na15 71.0(3) . 1_556 ?
 O54 Na8 Na14 81.3(4) . 1_556 ?
 O55 Na8 Na9 48.56(19) . . ?
 O55 Na8 O54 73.1(2) . . ?
 O55 Na8 Na15 111.0(3) . 1_556 ?
 O55 Na8 Na14 112.3(4) . 1_556 ?
 O53 Na8 Na9 49.5(2) . . ?
 O53 Na8 O54 74.3(3) . . ?
 O53 Na8 O55 91.6(3) . . ?
 O53 Na8 O58 98.0(3) . . ?
 O53 Na8 O56 86.9(3) . . ?
 O53 Na8 O57 174.0(3) . . ?
 O53 Na8 Na15 129.8(3) . 1_556 ?
 O53 Na8 Na14 138.9(5) . 1_556 ?
 O58 Na8 Na9 120.6(2) . . ?
 O58 Na8 O54 81.0(3) . . ?
 O58 Na8 O55 148.8(3) . . ?
 O58 Na8 O56 107.7(3) . . ?
 O58 Na8 Na15 42.1(3) . 1_556 ?
 O58 Na8 Na14 45.1(4) . 1_556 ?
 O56 Na8 Na9 116.1(3) . . ?
 O56 Na8 O54 160.3(3) . . ?
 O56 Na8 O55 102.4(3) . . ?
 O56 Na8 Na15 127.4(3) . 1_556 ?
 O56 Na8 Na14 117.5(5) . 1_556 ?
 O57 Na8 Na9 125.6(3) . . ?
 O57 Na8 O54 104.9(3) . . ?
 O57 Na8 O55 82.4(3) . . ?
 O57 Na8 O58 87.7(3) . . ?
 O57 Na8 O56 93.3(4) . . ?
 O57 Na8 Na15 54.2(3) . 1_556 ?
 O57 Na8 Na14 45.7(5) . 1_556 ?
 Na12 Na11 Na10 113.94(13) . . ?
 O39 Na11 Na10 139.2(2) . . ?
 O39 Na11 Na12 41.03(17) . . ?
 O39 Na11 O45 89.9(3) . . ?
 O39 Na11 O46 95.3(3) . . ?
 O39 Na11 O47 166.4(3) . . ?
 O39 Na11 O38 85.0(3) . . ?
 O39 Na11 O41 84.3(3) . . ?
 O39 Na11 O40 81.7(6) . . ?
 O45 Na11 Na10 88.1(2) . . ?
 O45 Na11 Na12 126.2(2) . . ?
 O45 Na11 O38 77.0(3) . . ?
 O45 Na11 O41 155.9(3) . . ?
 O46 Na11 Na10 44.43(19) . . ?
 O46 Na11 Na12 84.6(2) . . ?
 O46 Na11 O45 79.0(3) . . ?
 O46 Na11 O47 86.3(3) . . ?
 O46 Na11 O38 156.0(3) . . ?
 O46 Na11 O41 78.3(3) . . ?
 O46 Na11 O40 108.1(6) . . ?
 O47 Na11 Na10 42.23(18) . . ?
 O47 Na11 Na12 126.0(2) . . ?
 O47 Na11 O45 103.7(3) . . ?
 O47 Na11 O38 99.0(3) . . ?
 O47 Na11 O41 82.8(3) . . ?
 O38 Na11 Na10 133.8(2) . . ?
 O38 Na11 Na12 110.0(2) . . ?
 O38 Na11 O41 125.5(3) . . ?
 O41 Na11 Na10 81.2(3) . . ?
 O41 Na11 Na12 43.3(3) . . ?
 O40 Na11 Na10 102.4(6) . . ?
 O40 Na11 Na12 48.7(6) . . ?
 O40 Na11 O45 169.4(6) . . ?
 O40 Na11 O47 85.0(6) . . ?
 O40 Na11 O38 95.8(6) . . ?
 O61 Na7 Na6 107.6(3) . . ?
 O61 Na7 Na14 59.1(4) . 1_556 ?
 O61 Na7 O62 61.7(5) . . ?
 O59 Na7 O61 162.1(3) . . ?
 O59 Na7 Na6 90.0(3) . . ?
 O59 Na7 Na14 104.8(5) . 1_556 ?
 O59 Na7 O62 102.1(5) . . ?
 O58 Na7 O61 76.9(3) . . ?
 O58 Na7 O59 95.6(3) . . ?
 O58 Na7 Na6 127.3(3) . . ?
 O58 Na7 Na14 39.9(4) . 1_556 ?
 O58 Na7 O62 87.2(6) . . ?
 O60 Na7 O61 99.1(3) . . ?
 O60 Na7 O59 97.0(3) . . ?
 O60 Na7 O58 88.7(3) . . ?
 O60 Na7 O64 84.9(3) . . ?
 O60 Na7 O63 174.9(4) . . ?
 O60 Na7 Na6 38.7(3) . . ?
 O60 Na7 Na14 124.9(5) . 1_556 ?
 O60 Na7 O62 160.8(5) . . ?
 O64 Na7 O61 87.9(3) . . ?
 O64 Na7 O59 101.5(3) . . ?
 O64 Na7 O58 162.4(3) . . ?
 O64 Na7 Na6 49.1(3) . . ?
 O64 Na7 Na14 136.4(4) . 1_556 ?
 O64 Na7 O62 93.5(6) . . ?
 O63 Na7 O61 83.4(4) . . ?
 O63 Na7 O59 81.3(4) . . ?
 O63 Na7 O58 96.2(4) . . ?
 O63 Na7 O64 90.7(4) . . ?
 O63 Na7 Na6 136.3(4) . . ?
 O10 Na13 O10 180.0(2) . 2_566 ?
 O38 Na13 O10 83.1(2) . . ?
 O38 Na13 O10 96.9(2) . 2_566 ?
 O38 Na13 O10 83.1(2) 2_566 2_566 ?
 O38 Na13 O10 96.9(2) 2_566 . ?
 O38 Na13 O38 180.0 2_566 . ?
 O37 Na13 O10 84.5(3) . . ?
 O37 Na13 O10 84.5(3) 2_566 2_566 ?
 O37 Na13 O10 95.5(3) 2_566 . ?
 O37 Na13 O10 95.5(3) . 2_566 ?
 O37 Na13 O38 92.9(3) . . ?
 O37 Na13 O38 87.1(3) 2_566 . ?
 O37 Na13 O38 87.1(3) . 2_566 ?
 O37 Na13 O38 92.9(3) 2_566 2_566 ?
 O37 Na13 O37 180.0 . 2_566 ?
 W1 O5 W5 115.0(3) . . ?
 W3 O9 W2 114.9(3) . . ?
 W6 O25 W7 115.2(3) . . ?
 W1 O2 W2 115.0(3) . . ?
 W8 O29 W9 114.0(3) . . ?
 W1 O4 W4 116.0(3) . . ?
 W8 O34 Na2 105.9(5) . 2_656 ?
 W8 O34 Na3 101.3(6) . 2_656 ?
 W10 O34 W8 114.8(3) . . ?
 W10 O34 Na2 127.3(6) . 2_656 ?
 W10 O34 Na3 139.5(7) . 2_656 ?
 W9 O23 W6 114.3(3) . . ?
 W4 O11 W3 113.9(3) . . ?
 W5 O7 Na15 125.5(4) . . ?
 W5 O7 Na14 131.7(6) . . ?
 W2 O7 W5 114.3(3) . . ?
 W2 O7 Na15 120.2(4) . . ?
 W2 O7 Na14 110.6(6) . . ?
 W5 O18 Tb1 128.7(3) . . ?
 W5 O13 W4 113.9(3) . . ?
 W10 O32 W6 115.6(3) . . ?
 W3 O16 Tb1 130.7(3) . . ?
 W4 O17 Tb1 131.8(3) . . ?
 W1 O3 W3 116.0(3) . . ?
 W9 O22 Tb1 131.4(3) . . ?
 W7 O20 Tb1 129.6(3) . . ?
 W6 O19 Tb1 129.8(3) . . ?
 Na9 O54 Na8 82.1(2) . . ?
 Na10 O48 Na9 89.5(2) . . ?
 Na12 O39 Na11 97.4(3) . . ?
 W8 O21 Tb1 130.7(3) . . ?
 W10 O35 W9 116.2(3) . . ?
 W5 O6 W4 89.9(2) . . ?
 W5 O6 W3 173.4(3) . . ?
 W5 O6 W2 89.8(2) . . ?
 W4 O6 W3 89.9(2) . . ?
 W1 O6 W5 93.7(2) . . ?
 W1 O6 W4 93.1(2) . . ?
 W1 O6 W3 92.9(2) . . ?
 W1 O6 W2 93.1(2) . . ?
 W2 O6 W4 173.8(3) . . ?
 W2 O6 W3 89.7(2) . . ?
 W8 O31 W9 89.9(2) . . ?
 W8 O31 W7 89.5(2) . . ?
 W8 O31 W6 173.4(3) . . ?
 W7 O31 W9 173.7(3) . . ?
 W7 O31 W6 90.0(2) . . ?
 W6 O31 W9 89.8(2) . . ?
 W10 O31 W9 92.6(2) . . ?
 W10 O31 W8 93.4(2) . . ?
 W10 O31 W7 93.6(2) . . ?
 W10 O31 W6 93.2(2) . . ?
 W7 O27 W8 114.1(3) . . ?
 W3 O10 Na13 132.3(3) . . ?
 Na9 O55 Na8 81.5(2) . . ?
 Na12 O42 Na12 95.4(3) . 2_556 ?
 W10 O33 W7 114.6(3) . . ?
 Na9 O51 Na10 88.6(3) . . ?
 Na11 O46 Na10 94.0(3) . . ?
 W5 O14 Na15 140.0(5) . 2_565 ?
 Na8 O53 Na9 83.1(2) . . ?
 Na8 O58 Na15 103.7(4) . 1_556 ?
 Na8 O58 Na14 95.2(6) . 1_556 ?
 Na7 O58 Na8 126.7(4) . . ?
 Na7 O58 Na15 109.9(4) . 1_556 ?
 Na7 O58 Na14 105.0(6) . 1_556 ?
 W7 O26 Na1 124.8(5) . . ?
 W2 O15 Tb1 130.8(3) . . ?
 Na11 O47 Na10 96.0(3) . . ?
 W8 O28 Na4 115.9(6) . 2_656 ?
 W4 O12 Na1 131.2(5) . 1_455 ?
 Na7 O60 Na5 125.6(5) . . ?
 Na6 O60 Na7 100.6(4) . . ?
 Na13 O38 Na11 128.4(4) . . ?
 Na8 O57 Na14 95.7(6) . 1_556 ?
 Na13 O37 Na4 131.7(7) . 2_666 ?
 Na7 O64 Na6 88.2(3) . . ?
 Na12 O41 Na11 92.4(4) . . ?
 Na3 O73 Na5 118.1(10) . 2_666 ?
 O65 Na6 Na7 102.1(3) . . ?
 O65 Na6 O64 112.1(4) . . ?
 O60 Na6 Na7 40.7(2) . . ?
 O60 Na6 O65 103.8(4) . . ?
 O60 Na6 O64 80.6(3) . . ?
 O64 Na6 Na7 42.6(2) . . ?
 O66 Na6 Na7 124.4(4) . . ?
 O66 Na6 O65 88.3(4) . . ?
 O66 Na6 O60 162.1(5) . . ?
 O66 Na6 O64 82.6(4) . . ?
 O65 Na5 Na3 114.6(6) . 2_666 ?
 O65 Na5 Na3 60.4(5) . . ?
 O60 Na5 O65 84.6(5) . . ?
 O60 Na5 O66 116.1(6) . . ?
 O60 Na5 Na3 130.3(8) . 2_666 ?
 O60 Na5 Na3 118.2(7) . . ?
 O66 Na5 O65 72.7(5) . . ?
 O66 Na5 Na3 113.4(7) . 2_666 ?
 O66 Na5 Na3 100.8(7) . . ?
 O73 Na5 O65 141.5(6) 2_666 . ?
 O73 Na5 O60 127.4(6) 2_666 . ?
 O73 Na5 O66 104.2(6) 2_666 . ?
 O73 Na5 Na3 83.5(6) 2_666 . ?
 O73 Na5 Na3 29.9(5) 2_666 2_666 ?
 O67 Na5 O65 116.0(7) . . ?
 O67 Na5 O60 80.6(6) . . ?
 O67 Na5 O66 162.6(8) . . ?
 O67 Na5 O73 59.3(7) . 2_666 ?
 O67 Na5 Na3 73.4(8) . . ?
 O67 Na5 Na3 49.7(8) . 2_666 ?
 O68 Na5 O65 75.1(7) . . ?
 O68 Na5 O60 146.9(8) . . ?
 O68 Na5 O66 82.7(7) . . ?
 O68 Na5 O73 66.5(7) . 2_666 ?
 O68 Na5 O67 85.1(9) . . ?
 O68 Na5 Na3 44.7(8) . 2_666 ?
 O68 Na5 Na3 28.8(8) . . ?
 Na3 Na5 Na3 54.4(8) . 2_666 ?
 O69 O67 Na5 120.4(13) . . ?
 O69 O67 Na4 92.0(12) . 2_666 ?
 O67 O69 Na2 98.8(13) . . ?
 O70 O69 O67 163(3) . . ?
 O70 O69 Na2 68.0(19) . . ?
 W8 Na2 Na2 162.9(10) 2_656 2_666 ?
 O34 Na2 W8 31.5(3) 2_656 2_656 ?
 O34 Na2 O69 86.6(8) 2_656 . ?
 O34 Na2 Na2 146.0(9) 2_656 2_666 ?
 O34 Na2 O68 107.0(9) 2_656 . ?
 O34 Na2 O68 157.5(11) 2_656 2_666 ?
 O34 Na2 O70 83.7(9) 2_656 . ?
 O73 Na2 W8 96.3(7) . 2_656 ?
 O73 Na2 O34 127.1(9) . 2_656 ?
 O73 Na2 O69 128.0(10) . . ?
 O73 Na2 Na2 85.8(8) . 2_666 ?
 O73 Na2 O68 113.0(11) . . ?
 O73 Na2 O68 61.2(7) . 2_666 ?
 O73 Na2 O70 114.4(10) . . ?
 O69 Na2 W8 113.9(8) . 2_656 ?
 O69 Na2 Na2 77.0(8) . 2_666 ?
 O72 Na2 W8 86.0(11) . 2_656 ?
 O72 Na2 O34 93.1(12) . 2_656 ?
 O72 Na2 O73 66.6(10) . . ?
 O72 Na2 O69 74.2(11) . . ?
 O72 Na2 Na2 110.2(13) . 2_666 ?
 O72 Na2 O68 70.4(11) . 2_666 ?
 O72 Na2 O68 151.2(14) . . ?
 O72 Na2 O70 54.0(11) . . ?
 O68 Na2 W8 121.8(9) . 2_656 ?
 O68 Na2 W8 152.1(8) 2_666 2_656 ?
 O68 Na2 O69 74.5(8) 2_666 . ?
 O68 Na2 O69 86.4(8) . . ?
 O68 Na2 Na2 40.9(6) 2_666 2_666 ?
 O68 Na2 Na2 43.2(6) . 2_666 ?
 O68 Na2 O68 84.2(9) . 2_666 ?
 O68 Na2 O70 107.0(10) . . ?
 O70 Na2 W8 104.1(8) . 2_656 ?
 O70 Na2 O69 20.9(6) . . ?
 O70 Na2 Na2 90.4(9) . 2_666 ?
 O70 Na2 O68 74.3(9) . 2_666 ?
 O26 Na1 O66 80.6(6) . 2_666 ?
 O12 Na1 O26 91.7(6) 1_655 . ?
 O12 Na1 O66 153.9(9) 1_655 2_666 ?
 O73 Na1 O26 117.2(9) . . ?
 O73 Na1 O12 108.9(9) . 1_655 ?
 O73 Na1 O66 96.7(8) . 2_666 ?
 O74 O72 Na2 129(2) . . ?
 O74 O72 Na3 122(2) . . ?
 O7 Na15 Na8 84.3(4) . 1_554 ?
 O7 Na15 O58 118.2(6) . 1_554 ?
 O7 Na15 O78 120.8(5) . . ?
 O14 Na15 Na8 88.7(4) 2_565 1_554 ?
 O14 Na15 O7 97.2(5) 2_565 . ?
 O14 Na15 O58 81.3(5) 2_565 1_554 ?
 O14 Na15 O78 104.3(6) 2_565 . ?
 O58 Na15 Na8 34.2(2) 1_554 1_554 ?
 O58 Na15 O78 119.2(6) 1_554 . ?
 O78 Na15 Na8 149.1(5) . 1_554 ?
 O77 Na15 Na8 104.3(5) . 1_554 ?
 O77 Na15 O7 129.0(7) . . ?
 O77 Na15 O14 132.5(7) . 2_565 ?
 O77 Na15 O58 84.9(5) . 1_554 ?
 O77 Na15 O78 46.7(4) . . ?
 Na8 Na14 Na7 66.9(4) 1_554 1_554 ?
 O7 Na14 Na8 92.0(6) . 1_554 ?
 O7 Na14 Na7 158.5(8) . 1_554 ?
 O58 Na14 Na8 39.6(4) 1_554 1_554 ?
 O58 Na14 Na7 35.1(3) 1_554 1_554 ?
 O58 Na14 O7 124.4(9) 1_554 . ?
 O58 Na14 O57 75.7(7) 1_554 1_554 ?
 O57 Na14 Na8 38.6(3) 1_554 1_554 ?
 O57 Na14 Na7 91.1(7) 1_554 1_554 ?
 O57 Na14 O7 73.0(7) 1_554 . ?
 O77 Na14 Na8 124.5(9) . 1_554 ?
 O77 Na14 Na7 60.6(6) . 1_554 ?
 O77 Na14 O7 140.6(10) . . ?
 O77 Na14 O58 95.0(9) . 1_554 ?
 O77 Na14 O57 125.1(12) . 1_554 ?
 Na5 O68 Na3 101.5(11) . 2_666 ?
 Na2 O68 Na2 95.8(9) . 2_666 ?
 Na3 O68 Na5 119.8(14) . . ?
 Na3 O68 Na3 90.3(12) . 2_666 ?
 Na11 O40 Na12 89.1(8) . . ?
 O77 O62 Na7 117.5(15) 1_556 . ?
 O37 Na4 O28 69.8(6) 2_666 2_656 ?
 O37 Na4 O75 48.2(5) 2_666 2_666 ?
 O37 Na4 O67 109.2(10) 2_666 2_666 ?
 O75 Na4 O28 105.7(8) 2_666 2_656 ?
 O73 Na4 O28 81.8(7) . 2_656 ?
 O73 Na4 O37 135.4(10) . 2_666 ?
 O73 Na4 O75 172.3(10) . 2_666 ?
 O73 Na4 O67 53.9(7) . 2_666 ?
 O67 Na4 O28 116.0(9) 2_666 2_656 ?
 O67 Na4 O75 119.5(10) 2_666 2_666 ?
 O71 Na4 O28 79.5(9) . 2_656 ?
 O71 Na4 O37 77.1(10) . 2_666 ?
 O71 Na4 O75 114.6(12) . 2_666 ?
 O71 Na4 O73 64.2(9) . . ?
 O71 Na4 O67 42.4(8) . 2_666 ?
 O71 Na4 O68 134.6(15) . . ?
 O68 Na4 O28 141.8(12) . 2_656 ?
 O68 Na4 O37 98.1(11) . 2_666 ?
 O68 Na4 O75 50.3(8) . 2_666 ?
 O68 Na4 O73 124.5(13) . . ?
 O68 Na4 O67 102.2(11) . 2_666 ?
 O34 Na3 Na5 138.1(11) 2_656 2_666 ?
 O34 Na3 Na5 80.6(7) 2_656 . ?
 O34 Na3 Na3 131.5(17) 2_656 2_666 ?
 O73 Na3 O34 112.2(13) . 2_656 ?
 O73 Na3 Na5 155.2(13) . . ?
 O73 Na3 Na5 32.0(6) . 2_666 ?
 O73 Na3 O72 55.9(10) . . ?
 O73 Na3 O71 58.3(9) . . ?
 O73 Na3 O68 58.5(9) . 2_666 ?
 O73 Na3 Na3 90.7(13) . 2_666 ?
 Na5 Na3 Na5 125.6(8) . 2_666 ?
 O72 Na3 O34 71.7(11) . 2_656 ?
 O72 Na3 Na5 67.9(9) . 2_666 ?
 O72 Na3 Na5 113.4(12) . . ?
 O72 Na3 O71 112.1(12) . . ?
 O72 Na3 O68 59.5(10) . 2_666 ?
 O72 Na3 Na3 90.0(15) . 2_666 ?
 O71 Na3 O34 122.7(12) . 2_656 ?
 O71 Na3 Na5 65.8(8) . 2_666 ?
 O71 Na3 Na5 133.6(13) . . ?
 O71 Na3 O68 98.5(11) . 2_666 ?
 O71 Na3 Na3 105.9(15) . 2_666 ?
 O68 Na3 O34 125.3(15) 2_666 2_656 ?
 O68 Na3 O34 109.5(13) . 2_656 ?
 O68 Na3 O73 137.2(17) . . ?
 O68 Na3 Na5 31.4(8) . . ?
 O68 Na3 Na5 33.8(6) 2_666 2_666 ?
 O68 Na3 Na5 106.2(12) . 2_666 ?
 O68 Na3 Na5 96.7(9) 2_666 . ?
 O68 Na3 O72 133.9(17) . . ?
 O68 Na3 O71 105.3(17) . . ?
 O68 Na3 O68 89.7(12) . 2_666 ?
 O68 Na3 Na3 53.6(10) . 2_666 ?
 O68 Na3 Na3 36.1(8) 2_666 2_666 ?
 Na3 Na3 Na5 65.8(8) 2_666 . ?
 Na3 Na3 Na5 59.7(8) 2_666 2_666 ?
 O69 O70 Na2 91(2) . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 O5 W5 O18 Tb1 3.9(10) . . . . ?
 O5 W5 O14 Na15 -55.4(7) . . . 2_565 ?
 O9 W3 O16 Tb1 -75.2(4) . . . . ?
 O9 W3 O10 Na13 63.9(5) . . . . ?
 O9 W2 O15 Tb1 78.6(4) . . . . ?
 O25 W7 O20 Tb1 77.2(4) . . . . ?
 O25 W7 O26 Na1 57.9(6) . . . . ?
 O25 W6 O19 Tb1 -76.1(4) . . . . ?
 O2 W2 O15 Tb1 5.0(10) . . . . ?
 O29 W9 O22 Tb1 77.9(4) . . . . ?
 O29 W8 O21 Tb1 -76.3(4) . . . . ?
 O29 W8 O28 Na4 96.4(6) . . . 2_656 ?
 O4 W4 O17 Tb1 4.8(10) . . . . ?
 O4 W4 O12 Na1 -20.6(8) . . . 1_455 ?
 O34 W8 O21 Tb1 4.2(11) . . . . ?
 O34 W8 O28 Na4 10.5(6) . . . 2_656 ?
 O34 W10 O35 W9 77.8(4) . . . . ?
 O23 W9 O22 Tb1 -76.6(4) . . . . ?
 O23 W6 O19 Tb1 77.9(4) . . . . ?
 O11 W4 O17 Tb1 -76.2(4) . . . . ?
 O11 W4 O12 Na1 64.8(7) . . . 1_455 ?
 O11 W3 O16 Tb1 78.9(4) . . . . ?
 O11 W3 O10 Na13 -105.5(5) . . . . ?
 O7 W5 O18 Tb1 78.8(4) . . . . ?
 O7 W5 O14 Na15 -139.6(7) . . . 2_565 ?
 O7 W2 O15 Tb1 -75.5(4) . . . . ?
 O18 W5 O14 Na15 125.1(7) . . . 2_565 ?
 O13 W5 O18 Tb1 -75.9(4) . . . . ?
 O13 W5 O14 Na15 28.9(7) . . . 2_565 ?
 O13 W4 O17 Tb1 78.8(4) . . . . ?
 O13 W4 O12 Na1 -106.5(7) . . . 1_455 ?
 O32 W6 O19 Tb1 3.1(10) . . . . ?
 O32 W10 O35 W9 -77.5(4) . . . . ?
 O16 W3 O10 Na13 160.4(4) . . . . ?
 O17 W4 O12 Na1 160.5(7) . . . 1_455 ?
 O3 W3 O16 Tb1 6.5(10) . . . . ?
 O3 W3 O10 Na13 -21.6(5) . . . . ?
 O20 W7 O26 Na1 -36.6(7) . . . . ?
 O21 W8 O28 Na4 -168.5(6) . . . 2_656 ?
 O35 W9 O22 Tb1 2.1(10) . . . . ?
 O6 W5 O18 Tb1 1.8(4) . . . . ?
 O6 W5 O14 Na15 -52.1(19) . . . 2_565 ?
 O6 W4 O17 Tb1 1.4(4) . . . . ?
 O6 W3 O16 Tb1 1.7(4) . . . . ?
 O6 W2 O15 Tb1 1.7(4) . . . . ?
 O31 W9 O22 Tb1 0.6(4) . . . . ?
 O31 W8 O21 Tb1 1.4(4) . . . . ?
 O31 W7 O20 Tb1 0.6(4) . . . . ?
 O31 W6 O19 Tb1 0.7(4) . . . . ?
 O31 W10 O35 W9 0.3(3) . . . . ?
 O27 W8 O21 Tb1 78.7(4) . . . . ?
 O27 W8 O28 Na4 -74.3(6) . . . 2_656 ?
 O27 W7 O20 Tb1 -76.9(4) . . . . ?
 O27 W7 O26 Na1 -132.3(6) . . . . ?
 O10 W3 O16 Tb1 -178.9(4) . . . . ?
 O24 W6 O19 Tb1 -178.5(4) . . . . ?
 O33 W7 O20 Tb1 1.3(11) . . . . ?
 O33 W7 O26 Na1 142.6(6) . . . . ?
 O33 W10 O35 W9 1.1(9) . . . . ?
 O30 W9 O22 Tb1 179.6(4) . . . . ?
 O14 W5 O18 Tb1 -177.7(4) . . . . ?
 O8 W2 O15 Tb1 -179.5(4) . . . . ?
 O26 W7 O20 Tb1 179.3(4) . . . . ?
 O28 W8 O21 Tb1 -178.2(4) . . . . ?
 O12 W4 O17 Tb1 -178.0(4) . . . . ?
 O36 W10 O35 W9 180.0(4) . . . . ?
 Na5 O67 O69 O70 -85(9) . . . . ?
 O67 O69 O70 Na2 42(9) . . . . ?
 Na2 W8 O21 Tb1 122.9(9) 2_656 . . . ?
 Na4 O67 O69 O70 29(9) 2_666 . . . ?

_shelx_SHELXL_version_number      '2014/7'
loop_
  _exptl_crystal_face_index_h
  _exptl_crystal_face_index_k
  _exptl_crystal_face_index_l
  _exptl_crystal_face_perp_dist
  _exptl_oxdiff_crystal_face_indexfrac_h
  _exptl_oxdiff_crystal_face_indexfrac_k
  _exptl_oxdiff_crystal_face_indexfrac_l
  _exptl_oxdiff_crystal_face_x
  _exptl_oxdiff_crystal_face_y
  _exptl_oxdiff_crystal_face_z
 1 -1 8 0.0119 0.9842 -1.0080 7.9916 -0.5150 0.3102 -0.2533
 0 -3 -4 0.0174 -0.0037 -2.9984 -4.0078 -0.1160 -0.1732 0.3717
 -1 -6 3 0.0164 -1.0102 -6.0049 2.9837 -0.7845 -0.1235 0.1375
 2 6 -6 0.0227 2.0160 6.0061 -5.9785 0.9317 0.1342 0.0821
 0 0 0 0.0116 -0.0192 0.1246 -0.0645 0.0166 -0.0014 -0.0057
 0 0 0 0.0135 -0.0171 0.1090 0.2492 -0.0009 0.0076 -0.0198
 0 0 0 0.0367 0.3642 -0.1937 -0.1523 -0.0144 0.0274 0.0460
 0 0 0 0.0145 -0.0088 -0.0393 0.2887 -0.0187 0.0068 -0.0123
 0 0 0 0.0124 0.0286 0.0436 0.3495 -0.0131 0.0138 -0.0174
 0 0 0 0.0150 0.0230 0.1383 0.3314 -0.0021 0.0145 -0.0225
 0 0 0 0.0392 -0.0835 -0.1868 -0.1144 -0.0137 -0.0150 0.0104
 0 0 0 0.0414 0.2527 -0.0676 0.0378 -0.0101 0.0245 0.0210

_olex2_submission_special_instructions 'No special instructions were received'

#===END
data_mv2_06Y
_audit_creation_date             2015-04-16
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_publ_contact_author_name        'Dr Colette Boskovic'
_publ_contact_author_address     
;School of Chemistry
University of Melbourne
Parkville 3010, VIC 
Australia
;
_publ_contact_author_email       c.boskovic@unimelb.edu.au
loop_
_publ_author_name
_publ_author_address
'Vonci, Michele' ''
'Giansiracusa, Marcus J.' ''
'Gable, Robert W.' ''
'Van den Heuvel, Willem ' ''
'Latham, Kay' ''
'Moubaraki, Boujemaa' ''
'Murray, Keith S.' ''
'Yu, Dehong' ''
'Mole, Richard A.' ''
'Soncini, Alessandro' ''
'Boskovic, Colette' ''

_publ_contact_author_phone       ?
_publ_section_references         
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2008). Acta Cryst. A64, 112-122.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
;
_chemical_name_systematic        'Sodium terbium yttrium oxide hydrate'
_chemical_name_common            ?
_chemical_formula_moiety         'Na9 O68 W10 Y, 3(O)'
_chemical_formula_sum            'H70 Na9 O71 W10 Y'
_chemical_formula_weight         3340.88
_chemical_melting_point          ?
_exptl_crystal_description       'flat blades'
_exptl_crystal_colour            'clear light colourless'
_diffrn_ambient_temperature      130.01(10)
_diffrn_ambient_pressure         101
_chemical_oxdiff_formula         'Y W10 O71 Na9 H70'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Y Y -0.2670 2.0244 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.1353 0.1239 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -5.4734 5.5774 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_symmetry_space_group_name_H-M_alt 'P -1'
_cell_length_a                   12.7357(5)
_cell_length_b                   13.0732(4)
_cell_length_c                   20.4565(8)
_cell_angle_alpha                82.865(3)
_cell_angle_beta                 74.492(4)
_cell_angle_gamma                88.859(3)
_cell_volume                     3256.2(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    8826
_cell_measurement_temperature    130.01(10)
_cell_measurement_theta_max      73.9060
_cell_measurement_theta_min      3.3680
_cell_oxdiff_angle_alpha         82.865(3)
_cell_oxdiff_angle_beta          74.492(4)
_cell_oxdiff_angle_gamma         88.859(3)
_cell_oxdiff_length_a            12.7357(5)
_cell_oxdiff_length_b            13.0732(4)
_cell_oxdiff_length_c            20.4565(8)
_cell_oxdiff_measurement_reflns_used 8826
_cell_oxdiff_volume              3256.2(2)
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    34.502
_exptl_absorpt_correction_T_max  0.668
_exptl_absorpt_correction_T_min  0.147
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_density_diffrn    3.407
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             3032
_exptl_crystal_size_max          0.1585
_exptl_crystal_size_mid          0.0193
_exptl_crystal_size_min          0.0127
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0437
_diffrn_reflns_av_unetI/netI     0.0747
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.967
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            23776
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.967
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         74.082
_diffrn_reflns_theta_min         3.407
_diffrn_ambient_environment      N~2~
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.2273
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -25.00   27.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -      -41.0592   37.0000   30.0000 52

#__ type_ start__ end____ width___ exp.time_
  2 omega  -23.00   35.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -      -41.0592   37.0000 -120.0000 58

#__ type_ start__ end____ width___ exp.time_
  3 omega  -45.00   24.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -      -41.0592   37.0000 -180.0000 69

#__ type_ start__ end____ width___ exp.time_
  4 omega  -75.00  -23.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -      -41.0592  -37.0000   30.0000 52

#__ type_ start__ end____ width___ exp.time_
  5 omega   54.00   96.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -       41.0592 -125.0000 -180.0000 42

#__ type_ start__ end____ width___ exp.time_
  6 omega   93.00  121.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272 -125.0000  -90.0000 28

#__ type_ start__ end____ width___ exp.time_
  7 omega   59.00   98.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -45.0000 -120.0000 39

#__ type_ start__ end____ width___ exp.time_
  8 omega   33.00   91.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -30.0000  -60.0000 58

#__ type_ start__ end____ width___ exp.time_
  9 omega  111.00  177.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272   45.0000  -30.0000 66

#__ type_ start__ end____ width___ exp.time_
 10 omega  124.00  174.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  125.0000    0.0000 50

#__ type_ start__ end____ width___ exp.time_
 11 omega   50.00   77.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -61.0000   60.0000 27

#__ type_ start__ end____ width___ exp.time_
 12 omega   35.00  121.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272 -125.0000   90.0000 86

#__ type_ start__ end____ width___ exp.time_
 13 omega   53.00  111.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272 -125.0000  150.0000 58

#__ type_ start__ end____ width___ exp.time_
 14 omega   32.00  154.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -15.0000  150.0000 122

#__ type_ start__ end____ width___ exp.time_
 15 omega   33.00  107.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -61.0000  120.0000 74

#__ type_ start__ end____ width___ exp.time_
 16 omega   29.00   90.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -30.0000   60.0000 61

#__ type_ start__ end____ width___ exp.time_
 17 omega   30.00   89.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -30.0000    0.0000 59

#__ type_ start__ end____ width___ exp.time_
 18 omega   29.00  120.00   1.0000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      106.6272  -77.0000  -90.0000 91

#__ type_ start__ end____ width___ exp.time_
 19 omega  -92.00   -5.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -      -41.0592  125.0000 -120.0000 87
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.1027257000
_diffrn_orient_matrix_UB_12      0.0387122000
_diffrn_orient_matrix_UB_13      -0.0210303000
_diffrn_orient_matrix_UB_21      -0.0604949000
_diffrn_orient_matrix_UB_22      0.0038631000
_diffrn_orient_matrix_UB_23      0.0756869000
_diffrn_orient_matrix_UB_31      0.0393673000
_diffrn_orient_matrix_UB_32      0.1122194000
_diffrn_orient_matrix_UB_33      -0.0056360000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10812
_reflns_number_total             12808
_reflns_odcompleteness_completeness 99.97
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.438
_refine_diff_density_min         -2.386
_refine_diff_density_rms         0.324
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     820
_refine_ls_number_reflns         12808
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0446
_refine_ls_R_factor_gt           0.0354
_refine_ls_restrained_S_all      1.017
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0342P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0822
_refine_ls_wR_factor_ref         0.0879
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W9 W 1.12300(3) 0.22751(3) 0.61923(2) 0.01286(8) Uani 1 1 d . . . . .
W8 W 0.94982(3) 0.03490(3) 0.68008(2) 0.01292(8) Uani 1 1 d . . . . .
W2 W 0.73672(3) 0.43943(3) 0.90309(2) 0.01319(8) Uani 1 1 d . . . . .
W6 W 1.16678(3) 0.22268(3) 0.76987(2) 0.01299(8) Uani 1 1 d . . . . .
W5 W 0.82240(3) 0.56819(3) 0.75058(2) 0.01311(8) Uani 1 1 d . . . . .
W4 W 0.66280(3) 0.43017(3) 0.69317(2) 0.01304(8) Uani 1 1 d . . . . .
W3 W 0.57569(3) 0.30201(3) 0.84392(2) 0.01291(8) Uani 1 1 d . . . . .
W7 W 0.99307(3) 0.03126(3) 0.82950(2) 0.01319(8) Uani 1 1 d . . . . .
W1 W 0.55713(3) 0.55699(3) 0.82771(2) 0.01377(8) Uani 1 1 d . . . . .
W10 W 1.20251(3) 0.00886(3) 0.69375(2) 0.01350(8) Uani 1 1 d . . . . .
Y1 Y 0.87640(6) 0.28172(5) 0.76313(4) 0.01263(13) Uani 1 1 d . . . . .
Na6 Na 0.1865(3) 0.6023(3) 0.76719(19) 0.0205(7) Uani 1 1 d . . . . .
Na4 Na 0.2956(3) 0.2182(3) 0.9896(2) 0.0231(7) Uani 1 1 d . . . . .
Na2 Na 0.5587(3) -0.0481(3) 0.79317(19) 0.0195(7) Uani 1 1 d . . . . .
Na1 Na 0.6995(3) -0.0696(3) 0.6212(2) 0.0225(7) Uani 1 1 d . . . . .
Na8 Na 0.4693(3) 0.7063(3) 0.43658(19) 0.0216(7) Uani 1 1 d . . . . .
Na9 Na 0.0652(3) 0.6029(3) 0.50951(19) 0.0212(7) Uani 1 1 d . . . . .
Na3 Na 0.3193(3) -0.0463(3) 0.93815(19) 0.0228(7) Uani 1 1 d . . . . .
Na5 Na 0.1341(3) 0.5101(3) 0.94190(19) 0.0196(7) Uani 1 1 d . . . . .
Na7 Na 0.2473(3) 0.6354(3) 0.58791(19) 0.0218(7) Uani 1 1 d . . . . .
O2 O 0.6123(5) 0.5396(4) 0.9053(3) 0.0173(12) Uani 1 1 d . . . . .
O34 O 1.0906(5) -0.0441(5) 0.6627(3) 0.0174(12) Uani 1 1 d . . . . .
O25 O 1.1039(5) 0.1206(4) 0.8462(3) 0.0161(12) Uani 1 1 d . . . . .
O29 O 1.0294(5) 0.1269(4) 0.5993(3) 0.0168(12) Uani 1 1 d . . . . .
O35 O 1.2308(5) 0.1097(4) 0.6134(3) 0.0154(12) Uani 1 1 d . . . . .
O32 O 1.2673(5) 0.1067(5) 0.7349(3) 0.0175(12) Uani 1 1 d . . . . .
O3 O 0.4815(5) 0.4300(5) 0.8592(3) 0.0193(12) Uani 1 1 d . . . . .
O51 O 0.4290(5) 0.2973(5) 1.0244(4) 0.0213(13) Uani 1 1 d . . . . .
O9 O 0.6199(5) 0.3359(4) 0.9228(3) 0.0148(11) Uani 1 1 d . . . . .
O13 O 0.7657(5) 0.5477(5) 0.6727(3) 0.0159(11) Uani 1 1 d . . . . .
O7 O 0.8234(5) 0.5546(4) 0.8460(3) 0.0148(11) Uani 1 1 d . . . . .
O11 O 0.5597(5) 0.3295(4) 0.7521(3) 0.0145(11) Uani 1 1 d . . . . .
O46 O 0.3961(5) 0.0510(4) 0.8290(3) 0.0174(12) Uani 1 1 d . . . . .
O5 O 0.6820(5) 0.6422(4) 0.7820(3) 0.0172(12) Uani 1 1 d . . . . .
O33 O 1.1265(5) -0.0477(4) 0.7843(3) 0.0174(12) Uani 1 1 d . . . . .
O22 O 1.0095(5) 0.3028(4) 0.6558(3) 0.0151(11) Uani 1 1 d . . . . .
O27 O 0.9246(5) -0.0360(4) 0.7713(3) 0.0147(11) Uani 1 1 d . . . . .
O15 O 0.8355(5) 0.3478(4) 0.8677(3) 0.0153(11) Uani 1 1 d . . . . .
O63 O 0.1460(5) 0.7408(5) 0.4300(3) 0.0182(12) Uani 1 1 d . . . . .
O69 O 0.9817(5) 0.1122(5) 0.4738(4) 0.0217(13) Uani 1 1 d . . . . .
O49 O 0.1868(5) 0.0918(5) 0.9617(3) 0.0217(13) Uani 1 1 d . . . . .
O62 O -0.0456(5) 0.4791(5) 0.5812(3) 0.0196(12) Uani 1 1 d . . . . .
O12 O 0.6293(5) 0.4308(5) 0.6162(3) 0.0177(12) Uani 1 1 d . . . . .
O4 O 0.5522(5) 0.5328(5) 0.7368(3) 0.0170(12) Uani 1 1 d . . . . .
O24 O 1.2596(5) 0.2849(5) 0.8009(3) 0.0204(13) Uani 1 1 d . . . . .
O40 O 0.6474(5) 0.0677(5) 0.6899(4) 0.0198(12) Uani 1 1 d . . . . .
O19 O 1.0481(5) 0.3005(4) 0.7869(3) 0.0163(12) Uani 1 1 d . . . . .
O28 O 0.8785(5) -0.0403(5) 0.6414(3) 0.0166(12) Uani 1 1 d . . . . .
O6 O 0.6908(5) 0.4425(4) 0.7972(3) 0.0140(11) Uani 1 1 d . . . . .
O8 O 0.7593(5) 0.4502(5) 0.9814(3) 0.0172(12) Uani 1 1 d . . . . .
O16 O 0.6948(5) 0.2275(4) 0.8172(3) 0.0148(11) Uani 1 1 d . . . . .
O18 O 0.9130(5) 0.4614(4) 0.7349(3) 0.0159(12) Uani 1 1 d . . . . .
O21 O 0.8572(5) 0.1348(4) 0.7078(3) 0.0150(11) Uani 1 1 d . . . . .
O14 O 0.9056(5) 0.6758(5) 0.7162(3) 0.0204(13) Uani 1 1 d . . . . .
O30 O 1.1778(5) 0.2968(5) 0.5393(3) 0.0195(12) Uani 1 1 d . . . . .
O56 O 0.3419(5) 0.4814(5) 0.7404(4) 0.0227(13) Uani 1 1 d . . . . .
O26 O 0.9554(5) -0.0488(5) 0.9065(3) 0.0203(12) Uani 1 1 d . . . . .
O68 O 0.5195(5) 0.7979(5) 0.3241(3) 0.0193(12) Uani 1 1 d . . . . .
O55 O 0.2332(5) 0.6484(5) 0.8636(4) 0.0218(13) Uani 1 1 d . . . . .
O53 O 0.0210(6) 0.3815(5) 1.0214(4) 0.0236(14) Uani 1 1 d . . . . .
O54 O 0.0530(5) 0.4848(5) 0.8478(4) 0.0202(13) Uani 1 1 d . . . . .
O60 O 0.2272(6) 0.5170(5) 0.5111(3) 0.0220(13) Uani 1 1 d . . . . .
O52 O 0.2653(5) 0.3734(5) 0.9182(3) 0.0205(13) Uani 1 1 d . . . . .
O65 O 0.3017(6) 0.7792(5) 0.4912(4) 0.0240(14) Uani 1 1 d . . . . .
O41 O 0.6998(6) -0.1554(5) 0.7384(4) 0.0237(13) Uani 1 1 d . . . . .
O39 O 0.7344(6) -0.2458(5) 0.5940(4) 0.0256(14) Uani 1 1 d . . . . .
O45 O 0.1862(6) -0.1521(5) 0.9077(4) 0.0307(16) Uani 1 1 d . . . . .
O47 O 0.2728(6) -0.1481(5) 1.0393(3) 0.0242(14) Uani 1 1 d . . . . .
O44 O 0.6842(6) 0.0124(5) 0.8468(4) 0.0228(13) Uani 1 1 d . . . . .
O36 O 1.3090(5) -0.0771(5) 0.6713(3) 0.0198(13) Uani 1 1 d . . . . .
O48 O 0.3915(6) 0.0584(5) 1.0115(4) 0.0253(14) Uani 1 1 d . . . . .
O64 O 0.4415(6) 0.6002(5) 0.5416(4) 0.0261(14) Uani 1 1 d . . . . .
O43 O 0.4712(6) -0.1586(5) 0.8972(4) 0.0223(13) Uani 1 1 d . . . . .
O57 O 0.0548(6) 0.7413(5) 0.7841(4) 0.0249(14) Uani 1 1 d . . . . .
O50 O 0.1642(6) 0.2630(5) 1.0904(4) 0.0288(15) Uani 1 1 d . . . . .
O17 O 0.7730(5) 0.3403(5) 0.6861(3) 0.0177(12) Uani 1 1 d . . . . .
O71 O 0.9557(6) 0.2357(6) 0.9551(4) 0.0314(16) Uani 1 1 d . . . . .
O67 O 0.6135(5) 0.5965(5) 0.3889(4) 0.0223(13) Uani 1 1 d . . . . .
O58 O 0.2972(5) 0.7093(5) 0.6731(4) 0.0199(13) Uani 1 1 d . . . . .
O59 O 0.1368(5) 0.5098(5) 0.6803(4) 0.0214(13) Uani 1 1 d . . . . .
O61 O 0.0717(5) 0.7052(5) 0.5931(4) 0.0221(13) Uani 1 1 d . . . . .
O23 O 1.2086(5) 0.2814(4) 0.6736(3) 0.0158(12) Uani 1 1 d . . . . .
O20 O 0.8967(5) 0.1331(4) 0.8384(3) 0.0162(12) Uani 1 1 d . . . . .
O10 O 0.4721(5) 0.2128(4) 0.8827(3) 0.0185(12) Uani 1 1 d . . . . .
O37 O 0.5313(6) -0.0501(6) 0.5862(4) 0.0273(14) Uani 1 1 d . . . . .
O38 O 0.7783(6) 0.0038(5) 0.5030(4) 0.0262(14) Uani 1 1 d . . . . .
O31 O 1.0684(4) 0.1229(4) 0.7225(3) 0.0102(10) Uani 1 1 d . . . . .
O70 O 0.5193(6) 0.6825(6) 0.6416(5) 0.0356(18) Uani 1 1 d . . . . .
O66 O 0.5546(6) 0.8545(6) 0.4639(4) 0.0261(14) Uani 1 1 d . . . . .
O42 O 0.4501(7) -0.1542(6) 0.7525(5) 0.039(2) Uani 1 1 d . . . . .
O1 O 0.4555(5) 0.6477(5) 0.8461(4) 0.0197(13) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W9 O29 1.942(6) . ?
W9 O35 2.036(6) . ?
W9 O22 1.779(6) . ?
W9 O30 1.740(7) . ?
W9 O23 1.947(5) . ?
W9 O31 2.313(6) . ?
W8 O34 2.021(6) . ?
W8 O29 1.965(7) . ?
W8 O27 1.926(6) . ?
W8 O28 1.741(6) . ?
W8 O21 1.784(6) . ?
W8 O31 2.319(5) . ?
W2 O2 2.030(6) . ?
W2 O9 1.957(6) . ?
W2 O7 1.947(6) . ?
W2 O15 1.792(6) . ?
W2 O6 2.386(6) . ?
W2 O8 1.724(6) . ?
W6 O25 1.927(6) . ?
W6 O32 2.038(6) . ?
W6 O24 1.740(6) . ?
W6 O19 1.785(6) . ?
W6 O23 1.958(7) . ?
W6 O31 2.288(5) . ?
W5 O13 1.965(6) . ?
W5 O7 1.941(6) . ?
W5 O5 2.004(6) . ?
W5 O6 2.298(5) . ?
W5 O18 1.798(6) . ?
W5 O14 1.736(7) . ?
W4 O13 1.970(6) . ?
W4 O11 1.933(6) . ?
W4 O12 1.736(6) . ?
W4 O4 2.032(6) . ?
W4 O6 2.274(6) . ?
W4 O17 1.800(6) . ?
W3 O3 2.046(6) . ?
W3 O9 1.947(6) . ?
W3 O11 1.932(6) . ?
W3 O6 2.315(5) . ?
W3 O16 1.783(6) . ?
W3 O10 1.732(6) . ?
W7 O25 1.974(6) . ?
W7 O33 2.034(6) . ?
W7 O27 1.948(6) . ?
W7 O26 1.736(6) . ?
W7 O20 1.785(6) . ?
W7 O31 2.328(6) . ?
W1 O2 1.888(6) . ?
W1 O3 1.888(7) . ?
W1 O5 1.913(6) . ?
W1 O4 1.943(6) . ?
W1 O6 2.257(5) . ?
W1 O1 1.736(6) . ?
W10 O34 1.883(6) . ?
W10 O35 1.933(6) . ?
W10 O32 1.925(6) . ?
W10 O33 1.908(7) . ?
W10 O36 1.746(6) . ?
W10 O31 2.250(5) . ?
Y1 O22 2.377(6) . ?
Y1 O15 2.332(6) . ?
Y1 O19 2.386(6) . ?
Y1 O16 2.361(6) . ?
Y1 O18 2.373(6) . ?
Y1 O21 2.395(5) . ?
Y1 O17 2.361(6) . ?
Y1 O20 2.380(6) . ?
Na6 Na5 3.516(5) . ?
Na6 Na7 3.512(5) . ?
Na6 O56 2.496(8) . ?
Na6 O55 2.353(7) . ?
Na6 O54 2.439(7) . ?
Na6 O57 2.441(8) . ?
Na6 O58 2.368(8) . ?
Na6 O59 2.488(7) . ?
Na4 Na3 3.721(5) . ?
Na4 O51 2.316(7) . ?
Na4 O49 2.392(7) . ?
Na4 O52 2.436(8) . ?
Na4 O48 2.452(8) . ?
Na4 O50 2.411(8) . ?
Na4 O10 2.691(8) . ?
Na2 Na1 3.539(5) . ?
Na2 Na3 3.643(5) . ?
Na2 O46 2.413(7) . ?
Na2 O40 2.455(8) . ?
Na2 O41 2.380(7) . ?
Na2 O44 2.363(7) . ?
Na2 O43 2.428(8) . ?
Na2 O42 2.348(8) . ?
Na1 O40 2.392(7) . ?
Na1 O28 2.469(7) . ?
Na1 O41 2.519(8) . ?
Na1 O39 2.440(7) . ?
Na1 O37 2.432(8) . ?
Na1 O38 2.437(8) . ?
Na8 Na7 3.626(5) . ?
Na8 O12 2.693(7) 2_666 ?
Na8 O68 2.387(8) . ?
Na8 O65 2.371(8) . ?
Na8 O64 2.353(8) . ?
Na8 O67 2.381(7) . ?
Na8 O66 2.434(8) . ?
Na9 Na9 3.306(7) 2_566 ?
Na9 Na7 3.213(5) . ?
Na9 O63 2.325(7) . ?
Na9 O62 2.326(7) 2_566 ?
Na9 O62 2.271(7) . ?
Na9 O60 2.335(8) . ?
Na9 O61 2.317(7) . ?
Na3 O46 2.396(7) . ?
Na3 O49 2.450(8) . ?
Na3 O45 2.459(8) . ?
Na3 O47 2.257(8) . ?
Na3 O48 2.504(7) . ?
Na3 O43 2.434(8) . ?
Na5 Na5 3.595(7) 2_567 ?
Na5 O8 2.438(7) 2_667 ?
Na5 O55 2.391(8) . ?
Na5 O53 2.416(8) 2_567 ?
Na5 O53 2.390(8) . ?
Na5 O54 2.473(7) . ?
Na5 O52 2.425(7) . ?
Na7 O60 2.400(7) . ?
Na7 O65 2.514(8) . ?
Na7 O64 2.456(8) . ?
Na7 O58 2.327(7) . ?
Na7 O59 2.478(8) . ?
Na7 O61 2.379(8) . ?
O62 Na9 2.326(7) 2_566 ?
O12 Na8 2.693(7) 2_666 ?
O8 Na5 2.438(7) 2_667 ?
O53 Na5 2.416(8) 2_567 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O29 W9 O35 83.9(2) . . ?
O29 W9 O23 154.5(3) . . ?
O29 W9 O31 77.9(2) . . ?
O35 W9 O31 74.0(2) . . ?
O22 W9 O29 91.9(3) . . ?
O22 W9 O35 157.9(3) . . ?
O22 W9 O23 91.0(3) . . ?
O22 W9 O31 83.9(2) . . ?
O30 W9 O29 102.5(3) . . ?
O30 W9 O35 99.1(3) . . ?
O30 W9 O22 103.0(3) . . ?
O30 W9 O23 101.5(3) . . ?
O30 W9 O31 173.1(3) . . ?
O23 W9 O35 84.0(2) . . ?
O23 W9 O31 77.2(2) . . ?
O34 W8 O31 73.5(2) . . ?
O29 W8 O34 83.4(3) . . ?
O29 W8 O31 77.3(2) . . ?
O27 W8 O34 83.8(3) . . ?
O27 W8 O29 155.1(2) . . ?
O27 W8 O31 78.6(2) . . ?
O28 W8 O34 98.1(3) . . ?
O28 W8 O29 99.5(3) . . ?
O28 W8 O27 103.3(3) . . ?
O28 W8 O21 103.9(3) . . ?
O28 W8 O31 171.2(2) . . ?
O21 W8 O34 157.9(2) . . ?
O21 W8 O29 91.2(3) . . ?
O21 W8 O27 92.7(3) . . ?
O21 W8 O31 84.4(2) . . ?
O2 W2 O6 72.9(2) . . ?
O9 W2 O2 83.1(2) . . ?
O9 W2 O6 76.1(2) . . ?
O7 W2 O2 83.1(2) . . ?
O7 W2 O9 152.1(2) . . ?
O7 W2 O6 76.8(2) . . ?
O15 W2 O2 156.2(3) . . ?
O15 W2 O9 90.9(3) . . ?
O15 W2 O7 92.1(3) . . ?
O15 W2 O6 83.2(2) . . ?
O8 W2 O2 100.0(3) . . ?
O8 W2 O9 104.6(3) . . ?
O8 W2 O7 101.5(3) . . ?
O8 W2 O15 103.8(3) . . ?
O8 W2 O6 172.8(2) . . ?
O25 W6 O32 84.4(3) . . ?
O25 W6 O23 155.5(2) . . ?
O25 W6 O31 78.5(2) . . ?
O32 W6 O31 74.1(2) . . ?
O24 W6 O25 101.6(3) . . ?
O24 W6 O32 96.3(3) . . ?
O24 W6 O19 104.4(3) . . ?
O24 W6 O23 100.8(3) . . ?
O24 W6 O31 170.4(3) . . ?
O19 W6 O25 92.4(3) . . ?
O19 W6 O32 159.3(2) . . ?
O19 W6 O23 91.5(3) . . ?
O19 W6 O31 85.2(2) . . ?
O23 W6 O32 83.4(3) . . ?
O23 W6 O31 77.7(2) . . ?
O13 W5 O5 83.8(3) . . ?
O13 W5 O6 77.4(2) . . ?
O7 W5 O13 155.9(3) . . ?
O7 W5 O5 84.7(3) . . ?
O7 W5 O6 79.1(2) . . ?
O5 W5 O6 73.8(2) . . ?
O18 W5 O13 91.3(3) . . ?
O18 W5 O7 91.6(3) . . ?
O18 W5 O5 158.2(3) . . ?
O18 W5 O6 84.4(2) . . ?
O14 W5 O13 100.5(3) . . ?
O14 W5 O7 102.1(3) . . ?
O14 W5 O5 97.8(3) . . ?
O14 W5 O6 171.4(3) . . ?
O14 W5 O18 104.0(3) . . ?
O13 W4 O4 84.2(2) . . ?
O13 W4 O6 77.9(2) . . ?
O11 W4 O13 155.1(2) . . ?
O11 W4 O4 83.4(2) . . ?
O11 W4 O6 78.0(2) . . ?
O12 W4 O13 101.9(3) . . ?
O12 W4 O11 101.4(3) . . ?
O12 W4 O4 99.4(3) . . ?
O12 W4 O6 173.4(2) . . ?
O12 W4 O17 103.2(3) . . ?
O4 W4 O6 74.0(2) . . ?
O17 W4 O13 91.1(3) . . ?
O17 W4 O11 92.1(3) . . ?
O17 W4 O4 157.4(3) . . ?
O17 W4 O6 83.4(2) . . ?
O3 W3 O6 73.8(2) . . ?
O9 W3 O3 83.4(2) . . ?
O9 W3 O6 78.0(2) . . ?
O11 W3 O3 83.4(2) . . ?
O11 W3 O9 154.2(2) . . ?
O11 W3 O6 77.0(2) . . ?
O16 W3 O3 158.6(3) . . ?
O16 W3 O9 91.8(3) . . ?
O16 W3 O11 92.4(3) . . ?
O16 W3 O6 84.8(2) . . ?
O10 W3 O3 96.2(3) . . ?
O10 W3 O9 101.0(3) . . ?
O10 W3 O11 102.4(3) . . ?
O10 W3 O6 170.0(2) . . ?
O10 W3 O16 105.3(3) . . ?
O25 W7 O33 82.6(2) . . ?
O25 W7 O31 76.7(2) . . ?
O33 W7 O31 73.4(2) . . ?
O27 W7 O25 153.7(3) . . ?
O27 W7 O33 83.6(2) . . ?
O27 W7 O31 78.0(2) . . ?
O26 W7 O25 101.2(3) . . ?
O26 W7 O33 97.6(3) . . ?
O26 W7 O27 102.7(3) . . ?
O26 W7 O20 105.1(3) . . ?
O26 W7 O31 170.9(3) . . ?
O20 W7 O25 91.1(3) . . ?
O20 W7 O33 157.2(3) . . ?
O20 W7 O27 93.1(2) . . ?
O20 W7 O31 83.9(2) . . ?
O2 W1 O5 87.9(3) . . ?
O2 W1 O4 154.7(3) . . ?
O2 W1 O6 78.6(2) . . ?
O3 W1 O2 88.9(3) . . ?
O3 W1 O5 154.5(3) . . ?
O3 W1 O4 86.5(3) . . ?
O3 W1 O6 78.1(2) . . ?
O5 W1 O4 85.7(3) . . ?
O5 W1 O6 76.5(2) . . ?
O4 W1 O6 76.1(2) . . ?
O1 W1 O2 104.4(3) . . ?
O1 W1 O3 103.4(3) . . ?
O1 W1 O5 101.9(3) . . ?
O1 W1 O4 100.9(3) . . ?
O1 W1 O6 176.6(3) . . ?
O34 W10 O35 87.2(3) . . ?
O34 W10 O32 154.7(3) . . ?
O34 W10 O33 88.3(3) . . ?
O34 W10 O31 77.7(2) . . ?
O35 W10 O31 77.4(2) . . ?
O32 W10 O35 86.5(2) . . ?
O32 W10 O31 77.1(2) . . ?
O33 W10 O35 154.9(3) . . ?
O33 W10 O32 87.1(3) . . ?
O33 W10 O31 77.5(2) . . ?
O36 W10 O34 103.7(3) . . ?
O36 W10 O35 101.9(3) . . ?
O36 W10 O32 101.6(3) . . ?
O36 W10 O33 103.1(3) . . ?
O36 W10 O31 178.5(2) . . ?
O22 Y1 O19 73.5(2) . . ?
O22 Y1 O21 73.8(2) . . ?
O22 Y1 O20 115.3(2) . . ?
O15 Y1 O22 139.3(2) . . ?
O15 Y1 O19 74.9(2) . . ?
O15 Y1 O16 75.5(2) . . ?
O15 Y1 O18 74.9(2) . . ?
O15 Y1 O21 144.5(2) . . ?
O15 Y1 O17 117.6(2) . . ?
O15 Y1 O20 78.7(2) . . ?
O19 Y1 O21 115.7(2) . . ?
O16 Y1 O22 143.1(2) . . ?
O16 Y1 O19 141.3(2) . . ?
O16 Y1 O18 118.0(2) . . ?
O16 Y1 O21 77.4(2) . . ?
O16 Y1 O17 73.6(2) . . ?
O16 Y1 O20 76.7(2) . . ?
O18 Y1 O22 73.6(2) . . ?
O18 Y1 O19 77.1(2) . . ?
O18 Y1 O21 139.1(2) . . ?
O18 Y1 O20 144.5(2) . . ?
O17 Y1 O22 77.1(2) . . ?
O17 Y1 O19 143.4(2) . . ?
O17 Y1 O18 74.1(2) . . ?
O17 Y1 O21 75.1(2) . . ?
O17 Y1 O20 140.3(2) . . ?
O20 Y1 O19 73.4(2) . . ?
O20 Y1 O21 73.2(2) . . ?
Na7 Na6 Na5 167.06(14) . . ?
O56 Na6 Na5 90.2(2) . . ?
O56 Na6 Na7 80.2(2) . . ?
O55 Na6 Na5 42.60(18) . . ?
O55 Na6 Na7 145.8(2) . . ?
O55 Na6 O56 93.1(3) . . ?
O55 Na6 O54 86.1(3) . . ?
O55 Na6 O57 85.8(3) . . ?
O55 Na6 O58 105.0(3) . . ?
O55 Na6 O59 165.8(3) . . ?
O54 Na6 Na5 44.69(17) . . ?
O54 Na6 Na7 128.0(2) . . ?
O54 Na6 O56 98.9(3) . . ?
O54 Na6 O57 89.7(3) . . ?
O54 Na6 O59 83.5(2) . . ?
O57 Na6 Na5 94.8(2) . . ?
O57 Na6 Na7 95.8(2) . . ?
O57 Na6 O56 171.2(3) . . ?
O57 Na6 O59 103.8(3) . . ?
O58 Na6 Na5 146.7(2) . . ?
O58 Na6 Na7 41.13(16) . . ?
O58 Na6 O56 83.2(2) . . ?
O58 Na6 O54 168.6(3) . . ?
O58 Na6 O57 88.7(3) . . ?
O58 Na6 O59 85.9(2) . . ?
O59 Na6 Na5 124.9(2) . . ?
O59 Na6 Na7 44.88(18) . . ?
O59 Na6 O56 79.0(2) . . ?
O51 Na4 Na3 123.7(2) . . ?
O51 Na4 O49 162.9(3) . . ?
O51 Na4 O52 92.8(3) . . ?
O51 Na4 O48 85.0(3) . . ?
O51 Na4 O50 88.5(3) . . ?
O51 Na4 O10 77.2(2) . . ?
O49 Na4 Na3 40.34(18) . . ?
O49 Na4 O52 102.6(3) . . ?
O49 Na4 O48 78.0(2) . . ?
O49 Na4 O50 97.6(3) . . ?
O49 Na4 O10 98.1(2) . . ?
O52 Na4 Na3 125.0(2) . . ?
O52 Na4 O48 153.2(3) . . ?
O52 Na4 O10 80.5(2) . . ?
O48 Na4 Na3 41.87(17) . . ?
O48 Na4 O10 73.0(2) . . ?
O50 Na4 Na3 123.2(2) . . ?
O50 Na4 O52 93.9(3) . . ?
O50 Na4 O48 112.8(3) . . ?
O50 Na4 O10 164.2(3) . . ?
O10 Na4 Na3 71.33(16) . . ?
Na1 Na2 Na3 155.29(14) . . ?
O46 Na2 Na1 124.9(2) . . ?
O46 Na2 Na3 40.56(17) . . ?
O46 Na2 O40 97.4(2) . . ?
O46 Na2 O43 81.7(2) . . ?
O40 Na2 Na1 42.41(16) . . ?
O40 Na2 Na3 137.5(2) . . ?
O41 Na2 Na1 45.3(2) . . ?
O41 Na2 Na3 143.0(2) . . ?
O41 Na2 O46 166.8(3) . . ?
O41 Na2 O40 79.2(2) . . ?
O41 Na2 O43 101.9(3) . . ?
O44 Na2 Na1 107.8(2) . . ?
O44 Na2 Na3 96.5(2) . . ?
O44 Na2 O46 105.4(2) . . ?
O44 Na2 O40 88.2(2) . . ?
O44 Na2 O41 87.3(3) . . ?
O44 Na2 O43 90.6(3) . . ?
O43 Na2 Na1 139.2(2) . . ?
O43 Na2 Na3 41.52(17) . . ?
O43 Na2 O40 178.3(3) . . ?
O42 Na2 Na1 73.7(3) . . ?
O42 Na2 Na3 84.2(3) . . ?
O42 Na2 O46 85.9(3) . . ?
O42 Na2 O40 102.4(3) . . ?
O42 Na2 O41 82.4(3) . . ?
O42 Na2 O44 163.5(3) . . ?
O42 Na2 O43 79.0(3) . . ?
O40 Na1 Na2 43.80(18) . . ?
O40 Na1 O28 82.4(2) . . ?
O40 Na1 O41 77.7(2) . . ?
O40 Na1 O39 158.4(3) . . ?
O40 Na1 O37 90.0(3) . . ?
O40 Na1 O38 108.9(3) . . ?
O28 Na1 Na2 92.59(19) . . ?
O28 Na1 O41 70.9(2) . . ?
O41 Na1 Na2 42.21(17) . . ?
O39 Na1 Na2 115.1(2) . . ?
O39 Na1 O28 96.1(3) . . ?
O39 Na1 O41 81.4(2) . . ?
O37 Na1 Na2 91.4(2) . . ?
O37 Na1 O28 164.3(3) . . ?
O37 Na1 O41 121.1(3) . . ?
O37 Na1 O39 96.0(3) . . ?
O37 Na1 O38 82.1(3) . . ?
O38 Na1 Na2 152.2(2) . . ?
O38 Na1 O28 87.3(3) . . ?
O38 Na1 O41 156.5(3) . . ?
O38 Na1 O39 92.6(3) . . ?
O12 Na8 Na7 82.93(17) 2_666 . ?
O68 Na8 Na7 145.5(2) . . ?
O68 Na8 O12 86.2(2) . 2_666 ?
O68 Na8 O66 82.7(3) . . ?
O65 Na8 Na7 43.62(19) . . ?
O65 Na8 O12 92.9(2) . 2_666 ?
O65 Na8 O68 104.7(3) . . ?
O65 Na8 O67 166.6(3) . . ?
O65 Na8 O66 85.7(3) . . ?
O64 Na8 Na7 42.2(2) . . ?
O64 Na8 O12 92.3(2) . 2_666 ?
O64 Na8 O68 171.6(3) . . ?
O64 Na8 O65 83.6(3) . . ?
O64 Na8 O67 88.6(3) . . ?
O64 Na8 O66 99.3(3) . . ?
O67 Na8 Na7 125.5(2) . . ?
O67 Na8 O12 76.5(2) . 2_666 ?
O67 Na8 O68 83.0(3) . . ?
O67 Na8 O66 106.4(3) . . ?
O66 Na8 Na7 103.8(2) . . ?
O66 Na8 O12 168.1(3) . 2_666 ?
Na7 Na9 Na9 133.2(2) . 2_566 ?
O63 Na9 Na9 130.3(2) . 2_566 ?
O63 Na9 Na7 87.36(19) . . ?
O63 Na9 O62 87.9(2) . 2_566 ?
O63 Na9 O60 95.9(3) . . ?
O62 Na9 Na9 43.36(18) 2_566 2_566 ?
O62 Na9 Na9 44.68(17) . 2_566 ?
O62 Na9 Na7 138.9(2) 2_566 . ?
O62 Na9 Na7 102.9(2) . . ?
O62 Na9 O63 168.2(3) . . ?
O62 Na9 O62 88.0(3) . 2_566 ?
O62 Na9 O60 92.0(3) 2_566 . ?
O62 Na9 O60 95.3(3) . . ?
O62 Na9 O61 95.7(3) . . ?
O60 Na9 Na9 95.1(2) . 2_566 ?
O60 Na9 Na7 48.12(17) . . ?
O61 Na9 Na9 139.8(3) . 2_566 ?
O61 Na9 Na7 47.64(19) . . ?
O61 Na9 O63 86.9(2) . . ?
O61 Na9 O62 171.4(3) . 2_566 ?
O61 Na9 O60 95.4(3) . . ?
Na2 Na3 Na4 107.57(12) . . ?
O46 Na3 Na4 80.46(18) . . ?
O46 Na3 Na2 40.93(17) . . ?
O46 Na3 O49 87.3(2) . . ?
O46 Na3 O45 99.4(3) . . ?
O46 Na3 O48 99.2(3) . . ?
O46 Na3 O43 82.0(3) . . ?
O49 Na3 Na4 39.21(17) . . ?
O49 Na3 Na2 127.6(2) . . ?
O49 Na3 O45 91.1(3) . . ?
O49 Na3 O48 75.9(2) . . ?
O45 Na3 Na4 130.2(2) . . ?
O45 Na3 Na2 103.1(2) . . ?
O45 Na3 O48 156.7(3) . . ?
O47 Na3 Na4 103.1(2) . . ?
O47 Na3 Na2 130.6(2) . . ?
O47 Na3 O46 171.2(3) . . ?
O47 Na3 O49 100.5(3) . . ?
O47 Na3 O45 84.6(3) . . ?
O47 Na3 O48 79.1(3) . . ?
O47 Na3 O43 89.9(3) . . ?
O48 Na3 Na4 40.81(18) . . ?
O48 Na3 Na2 100.2(2) . . ?
O43 Na3 Na4 134.4(2) . . ?
O43 Na3 Na2 41.40(18) . . ?
O43 Na3 O49 168.8(3) . . ?
O43 Na3 O45 94.0(3) . . ?
O43 Na3 O48 102.4(3) . . ?
Na6 Na5 Na5 123.72(17) . 2_567 ?
O8 Na5 Na6 126.1(2) 2_667 . ?
O8 Na5 Na5 100.2(2) 2_667 2_567 ?
O8 Na5 O54 169.8(3) 2_667 . ?
O55 Na5 Na6 41.77(17) . . ?
O55 Na5 Na5 133.1(2) . 2_567 ?
O55 Na5 O8 86.1(2) . 2_667 ?
O55 Na5 O53 91.8(3) . 2_567 ?
O55 Na5 O54 84.5(2) . . ?
O55 Na5 O52 99.5(3) . . ?
O53 Na5 Na6 95.5(2) 2_567 . ?
O53 Na5 Na6 137.6(2) . . ?
O53 Na5 Na5 41.30(18) 2_567 2_567 ?
O53 Na5 Na5 41.84(18) . 2_567 ?
O53 Na5 O8 95.6(3) . 2_667 ?
O53 Na5 O8 99.6(2) 2_567 2_667 ?
O53 Na5 O55 174.9(3) . . ?
O53 Na5 O53 83.1(3) . 2_567 ?
O53 Na5 O54 94.0(2) . . ?
O53 Na5 O54 84.7(2) 2_567 . ?
O53 Na5 O52 85.5(3) . . ?
O53 Na5 O52 168.5(3) 2_567 . ?
O54 Na5 Na6 43.90(17) . . ?
O54 Na5 Na5 89.1(2) . 2_567 ?
O52 Na5 Na6 91.7(2) . . ?
O52 Na5 Na5 127.3(2) . 2_567 ?
O52 Na5 O8 83.3(2) . 2_667 ?
O52 Na5 O54 94.3(2) . . ?
Na6 Na7 Na8 141.60(14) . . ?
Na9 Na7 Na6 121.67(14) . . ?
Na9 Na7 Na8 96.73(13) . . ?
O60 Na7 Na6 129.9(2) . . ?
O60 Na7 Na8 76.4(2) . . ?
O60 Na7 Na9 46.43(19) . . ?
O60 Na7 O65 91.5(2) . . ?
O60 Na7 O64 82.3(3) . . ?
O60 Na7 O59 86.1(2) . . ?
O65 Na7 Na6 138.2(2) . . ?
O65 Na7 Na8 40.58(18) . . ?
O65 Na7 Na9 80.51(19) . . ?
O64 Na7 Na6 108.5(2) . . ?
O64 Na7 Na8 40.01(19) . . ?
O64 Na7 Na9 123.5(2) . . ?
O64 Na7 O65 78.6(3) . . ?
O64 Na7 O59 118.4(3) . . ?
O58 Na7 Na6 42.01(18) . . ?
O58 Na7 Na8 103.8(2) . . ?
O58 Na7 Na9 148.4(2) . . ?
O58 Na7 O60 162.7(3) . . ?
O58 Na7 O65 99.8(3) . . ?
O58 Na7 O64 87.0(3) . . ?
O58 Na7 O59 87.0(3) . . ?
O58 Na7 O61 102.5(3) . . ?
O59 Na7 Na6 45.10(17) . . ?
O59 Na7 Na8 153.3(2) . . ?
O59 Na7 Na9 85.12(19) . . ?
O59 Na7 O65 162.2(3) . . ?
O61 Na7 Na6 90.5(2) . . ?
O61 Na7 Na8 119.2(2) . . ?
O61 Na7 Na9 46.02(18) . . ?
O61 Na7 O60 92.1(3) . . ?
O61 Na7 O65 81.5(3) . . ?
O61 Na7 O64 159.2(3) . . ?
O61 Na7 O59 81.0(3) . . ?
W1 O2 W2 116.7(3) . . ?
W10 O34 W8 116.0(3) . . ?
W6 O25 W7 113.7(3) . . ?
W9 O29 W8 113.9(3) . . ?
W10 O35 W9 114.5(3) . . ?
W10 O32 W6 114.4(3) . . ?
W1 O3 W3 115.0(3) . . ?
W3 O9 W2 115.6(3) . . ?
W5 O13 W4 112.6(3) . . ?
W5 O7 W2 114.6(3) . . ?
W3 O11 W4 114.0(3) . . ?
Na3 O46 Na2 98.5(3) . . ?
W1 O5 W5 116.0(3) . . ?
W10 O33 W7 115.5(3) . . ?
W9 O22 Y1 132.4(3) . . ?
W8 O27 W7 113.6(3) . . ?
W2 O15 Y1 131.7(3) . . ?
Na4 O49 Na3 100.4(3) . . ?
Na9 O62 Na9 92.0(3) . 2_566 ?
W4 O12 Na8 133.8(3) . 2_666 ?
W1 O4 W4 114.7(3) . . ?
Na1 O40 Na2 93.8(2) . . ?
W6 O19 Y1 130.6(3) . . ?
W8 O28 Na1 144.5(3) . . ?
W5 O6 W2 88.60(19) . . ?
W5 O6 W3 173.0(3) . . ?
W4 O6 W2 172.9(3) . . ?
W4 O6 W5 91.4(2) . . ?
W4 O6 W3 89.9(2) . . ?
W3 O6 W2 89.3(2) . . ?
W1 O6 W2 91.8(2) . . ?
W1 O6 W5 93.7(2) . . ?
W1 O6 W4 95.2(2) . . ?
W1 O6 W3 93.1(2) . . ?
W2 O8 Na5 155.2(4) . 2_667 ?
W3 O16 Y1 129.9(3) . . ?
W5 O18 Y1 129.7(3) . . ?
W8 O21 Y1 131.4(3) . . ?
Na6 O55 Na5 95.6(2) . . ?
Na5 O53 Na5 96.9(3) . 2_567 ?
Na6 O54 Na5 91.4(2) . . ?
Na9 O60 Na7 85.5(2) . . ?
Na5 O52 Na4 131.1(3) . . ?
Na8 O65 Na7 95.8(3) . . ?
Na2 O41 Na1 92.5(3) . . ?
Na4 O48 Na3 97.3(3) . . ?
Na8 O64 Na7 97.8(3) . . ?
Na2 O43 Na3 97.1(3) . . ?
W4 O17 Y1 131.1(3) . . ?
Na7 O58 Na6 96.9(2) . . ?
Na7 O59 Na6 90.0(2) . . ?
Na9 O61 Na7 86.3(2) . . ?
W9 O23 W6 113.6(3) . . ?
W7 O20 Y1 132.1(3) . . ?
W3 O10 Na4 131.9(3) . . ?
W9 O31 W8 89.99(19) . . ?
W9 O31 W7 172.4(3) . . ?
W8 O31 W7 88.48(18) . . ?
W6 O31 W9 90.51(19) . . ?
W6 O31 W8 172.6(3) . . ?
W6 O31 W7 90.06(19) . . ?
W10 O31 W9 94.0(2) . . ?
W10 O31 W8 92.86(18) . . ?
W10 O31 W6 94.4(2) . . ?
W10 O31 W7 93.5(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 W2 O15 Y1 1.4(9) . . . . ?
O2 W2 O8 Na5 -119.0(8) . . . 2_667 ?
O2 W1 O3 W3 -76.9(3) . . . . ?
O34 W8 O28 Na1 173.2(6) . . . . ?
O34 W8 O21 Y1 -2.1(10) . . . . ?
O25 W6 O19 Y1 -77.9(4) . . . . ?
O25 W7 O20 Y1 77.7(4) . . . . ?
O29 W9 O22 Y1 76.7(4) . . . . ?
O29 W8 O28 Na1 -102.1(6) . . . . ?
O29 W8 O21 Y1 -77.4(4) . . . . ?
O35 W9 O22 Y1 -1.6(9) . . . . ?
O35 W10 O34 W8 -78.9(3) . . . . ?
O32 W6 O19 Y1 2.6(10) . . . . ?
O32 W10 O34 W8 -3.1(9) . . . . ?
O3 W3 O16 Y1 0.6(9) . . . . ?
O3 W3 O10 Na4 -33.9(4) . . . . ?
O3 W1 O2 W2 77.4(3) . . . . ?
O9 W2 O15 Y1 76.2(4) . . . . ?
O9 W2 O8 Na5 155.6(8) . . . 2_667 ?
O9 W3 O16 Y1 -75.8(4) . . . . ?
O9 W3 O10 Na4 50.5(4) . . . . ?
O13 W5 O18 Y1 -79.1(4) . . . . ?
O13 W4 O12 Na8 165.5(4) . . . 2_666 ?
O13 W4 O17 Y1 78.3(4) . . . . ?
O7 W2 O15 Y1 -76.1(4) . . . . ?
O7 W2 O8 Na5 -34.1(9) . . . 2_667 ?
O7 W5 O18 Y1 77.0(4) . . . . ?
O11 W4 O12 Na8 -23.4(5) . . . 2_666 ?
O11 W4 O17 Y1 -77.0(4) . . . . ?
O11 W3 O16 Y1 78.8(4) . . . . ?
O11 W3 O10 Na4 -118.5(4) . . . . ?
O5 W5 O18 Y1 -2.8(10) . . . . ?
O5 W1 O2 W2 -77.3(3) . . . . ?
O5 W1 O3 W3 5.8(8) . . . . ?
O33 W7 O20 Y1 4.5(9) . . . . ?
O33 W10 O34 W8 76.5(4) . . . . ?
O27 W8 O28 Na1 87.7(6) . . . . ?
O27 W8 O21 Y1 78.0(4) . . . . ?
O27 W7 O20 Y1 -76.3(4) . . . . ?
O15 W2 O8 Na5 61.0(9) . . . 2_667 ?
O12 W4 O17 Y1 -179.3(4) . . . . ?
O4 W4 O12 Na8 -108.5(4) . . . 2_666 ?
O4 W4 O17 Y1 0.8(10) . . . . ?
O4 W1 O2 W2 -2.0(8) . . . . ?
O4 W1 O3 W3 78.2(3) . . . . ?
O24 W6 O19 Y1 179.5(4) . . . . ?
O28 W8 O21 Y1 -177.5(4) . . . . ?
O6 W2 O15 Y1 0.3(4) . . . . ?
O6 W5 O18 Y1 -1.9(4) . . . . ?
O6 W4 O17 Y1 0.6(4) . . . . ?
O6 W3 O16 Y1 2.0(4) . . . . ?
O6 W3 O10 Na4 -33.1(18) . . . . ?
O6 W1 O2 W2 -0.7(3) . . . . ?
O6 W1 O3 W3 1.7(3) . . . . ?
O8 W2 O15 Y1 -178.5(4) . . . . ?
O16 W3 O10 Na4 145.5(4) . . . . ?
O21 W8 O28 Na1 -8.5(7) . . . . ?
O14 W5 O18 Y1 179.8(4) . . . . ?
O30 W9 O22 Y1 180.0(4) . . . . ?
O26 W7 O20 Y1 179.7(4) . . . . ?
O36 W10 O34 W8 179.6(3) . . . . ?
O17 W4 O12 Na8 71.5(5) . . . 2_666 ?
O23 W9 O22 Y1 -78.0(4) . . . . ?
O23 W6 O19 Y1 77.9(4) . . . . ?
O10 W3 O16 Y1 -177.7(4) . . . . ?
O31 W9 O22 Y1 -0.9(4) . . . . ?
O31 W8 O21 Y1 -0.3(4) . . . . ?
O31 W6 O19 Y1 0.4(4) . . . . ?
O31 W7 O20 Y1 1.3(3) . . . . ?
O31 W10 O34 W8 -1.1(3) . . . . ?
O1 W1 O2 W2 -179.0(3) . . . . ?
O1 W1 O3 W3 178.6(3) . . . . ?

_shelx_SHELXL_version_number     2014/7
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
5 0 2 0.0791 5.0000 -0.0000 2.0001 -0.5557 -0.1511 0.1856
0 0 -1 0.0064 -0.0000 0.0000 -1.0000 0.0210 -0.0757 0.0056
0 0 1 0.0064 0.0000 -0.0000 1.0000 -0.0210 0.0757 -0.0056
-1 -5 -1 0.0097 -1.0001 -4.9999 -1.0005 -0.0698 -0.0345 -0.5948
1 5 1 0.0097 1.0001 4.9999 1.0005 0.0698 0.0345 0.5948
-8 0 1 0.0669 -7.8021 -0.0486 0.8642 0.7814 0.5372 -0.3175

_olex2_submission_special_instructions 'No special instructions were received'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_h-m   'P -1'
_symmetry_int_tables_number      2
_chemical_absolute_configuration ?

