# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1425093'
_audit_update_record             
;
2015-09-16 deposited with the CCDC.
2015-11-23 downloaded from the CCDC.
;
_audit_creation_date             2015-09-01
_audit_creation_method           
;
  Olex2 1.1
  (compiled 2011.11.01 svn.r2039, GUI svn.r3906)
;

_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C8 H7 Ag N2'
_chemical_formula_sum            'C8 H7 Ag N2'
_chemical_formula_weight         239.03
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.2337(11)
_cell_length_b                   9.5487(8)
_cell_length_c                   13.0666(13)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1526.4(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    2797
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4895
_cell_measurement_theta_min      2.2804
_exptl_absorpt_coefficient_mu    2.566
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.9274
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            'clear whitish colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whitish
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.080
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             928
_exptl_crystal_size_max          0.2000
_exptl_crystal_size_mid          0.2000
_exptl_crystal_size_min          0.1000
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0213
_diffrn_reflns_av_unetI/netI     0.0140
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            10798
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.468
_diffrn_reflns_theta_min         3.123
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1495
_reflns_number_total             1721
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material  
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  
;
SHELXL, G.M. Sheldrick, Acta Cryst.
2008). A64, 112-122
;
_computing_structure_solution    ?
_refine_diff_density_max         0.469
_refine_diff_density_min         -0.627
_refine_diff_density_rms         0.073
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.194
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     101
_refine_ls_number_reflns         1721
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0410
_refine_ls_R_factor_gt           0.0334
_refine_ls_restrained_S_all      1.194
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0142P)²+2.3191P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0569
_refine_ls_wR_factor_ref         0.0597
_refine_special_details          
;
 ?
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.15412(2) 0.25927(2) 0.00419(2) 0.03766(10) Uani 1 1 d . . . . .
N1 N -0.00282(19) 0.2039(3) -0.0402(2) 0.0316(6) Uani 1 1 d . . . . .
N3 N -0.1856(2) 0.1843(3) -0.0381(2) 0.0343(6) Uani 1 1 d . . . . .
C1 C -0.1456(2) 0.0858(3) -0.1054(2) 0.0326(7) Uani 1 1 d . . . . .
C2 C -0.0976(2) 0.2509(3) -0.0018(2) 0.0307(6) Uani 1 1 d . . . . .
C3 C -0.1036(3) 0.3657(4) 0.0743(3) 0.0488(10) Uani 1 1 d . . . . .
H3A H -0.1397 0.3327 0.1349 0.073 Uiso 1 1 calc R U . . .
H3B H -0.1438 0.4428 0.0460 0.073 Uiso 1 1 calc R U . . .
H3C H -0.0310 0.3959 0.0914 0.073 Uiso 1 1 calc R U . . .
C4 C -0.0313(2) 0.0977(3) -0.1067(2) 0.0299(6) Uani 1 1 d . . . . .
C5 C -0.1337(4) -0.1020(4) -0.2239(3) 0.0559(11) Uani 1 1 d . . . . .
H5 H -0.1666 -0.1709 -0.2636 0.067 Uiso 1 1 calc R U . . .
C6 C -0.0200(4) -0.0886(4) -0.2255(3) 0.0535(10) Uani 1 1 d . . . . .
H6 H 0.0211 -0.1477 -0.2670 0.064 Uiso 1 1 calc R U . . .
C8 C 0.0320(3) 0.0101(4) -0.1672(3) 0.0429(8) Uani 1 1 d . . . . .
H8 H 0.1077 0.0181 -0.1681 0.051 Uiso 1 1 calc R U . . .
C9 C -0.1984(3) -0.0150(4) -0.1647(3) 0.0461(9) Uani 1 1 d . . . . .
H9 H -0.2741 -0.0234 -0.1644 0.055 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.074(2) . ?
Ag1 N3 2.081(2) 3 ?
N1 C2 1.341(4) . ?
N1 C4 1.380(4) . ?
N3 Ag1 2.081(2) 3_455 ?
N3 C1 1.377(4) . ?
N3 C2 1.337(4) . ?
C1 C4 1.403(4) . ?
C1 C9 1.394(5) . ?
C2 C3 1.482(5) . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C4 C8 1.387(4) . ?
C5 H5 0.9300 . ?
C5 C6 1.397(6) . ?
C5 C9 1.385(6) . ?
C6 H6 0.9300 . ?
C6 C8 1.368(5) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N3 176.05(11) . 3 ?
C2 N1 Ag1 127.6(2) . . ?
C2 N1 C4 105.3(2) . . ?
C4 N1 Ag1 126.7(2) . . ?
C1 N3 Ag1 130.4(2) . 3_455 ?
C2 N3 Ag1 124.0(2) . 3_455 ?
C2 N3 C1 105.4(2) . . ?
N3 C1 C4 107.9(3) . . ?
N3 C1 C9 131.4(3) . . ?
C9 C1 C4 120.8(3) . . ?
N1 C2 C3 122.8(3) . . ?
N3 C2 N1 113.8(3) . . ?
N3 C2 C3 123.4(3) . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
N1 C4 C1 107.7(3) . . ?
N1 C4 C8 131.4(3) . . ?
C8 C4 C1 120.9(3) . . ?
C6 C5 H5 119.2 . . ?
C9 C5 H5 119.2 . . ?
C9 C5 C6 121.5(4) . . ?
C5 C6 H6 119.4 . . ?
C8 C6 C5 121.2(4) . . ?
C8 C6 H6 119.4 . . ?
C4 C8 H8 120.9 . . ?
C6 C8 C4 118.2(3) . . ?
C6 C8 H8 120.9 . . ?
C1 C9 H9 121.3 . . ?
C5 C9 C1 117.4(3) . . ?
C5 C9 H9 121.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N1 C2 N3 -172.8(2) . . . . ?
Ag1 N1 C2 C3 6.8(5) . . . . ?
Ag1 N1 C4 C1 172.9(2) . . . . ?
Ag1 N1 C4 C8 -6.4(5) . . . . ?
Ag1 N3 C1 C4 174.5(2) 3_455 . . . ?
Ag1 N3 C1 C9 -6.5(5) 3_455 . . . ?
Ag1 N3 C2 N1 -174.9(2) 3_455 . . . ?
Ag1 N3 C2 C3 5.5(5) 3_455 . . . ?
N1 C4 C8 C6 179.2(3) . . . . ?
N3 C1 C4 N1 -0.1(3) . . . . ?
N3 C1 C4 C8 179.3(3) . . . . ?
N3 C1 C9 C5 -178.6(3) . . . . ?
C1 N3 C2 N1 0.1(4) . . . . ?
C1 N3 C2 C3 -179.5(3) . . . . ?
C1 C4 C8 C6 -0.1(5) . . . . ?
C2 N1 C4 C1 0.2(3) . . . . ?
C2 N1 C4 C8 -179.2(3) . . . . ?
C2 N3 C1 C4 0.0(3) . . . . ?
C2 N3 C1 C9 178.9(3) . . . . ?
C4 N1 C2 N3 -0.2(4) . . . . ?
C4 N1 C2 C3 179.4(3) . . . . ?
C4 C1 C9 C5 0.2(5) . . . . ?
C5 C6 C8 C4 -0.5(6) . . . . ?
C6 C5 C9 C1 -0.8(6) . . . . ?
C9 C1 C4 N1 -179.2(3) . . . . ?
C9 C1 C4 C8 0.2(5) . . . . ?
C9 C5 C6 C8 1.0(6) . . . . ?

_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2013-2
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1425094'
_audit_update_record             
;
2015-09-16 deposited with the CCDC.
2015-11-23 downloaded from the CCDC.
;
_audit_creation_date             2015-09-01
_audit_creation_method           
;
  Olex2 1.1
  (compiled 2011.11.01 svn.r2039, GUI svn.r3906)
;

_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C36 H36 Ag4 N8'
_chemical_formula_sum            'C36 H36 Ag4 N8'
_chemical_formula_weight         1012.21
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y, -z+1/2'
3 'x+1/2, y+1/2, z'
4 '-x+1/2, y+1/2, -z+1/2'
5 '-x, -y, -z'
6 'x, -y, z-1/2'
7 '-x+1/2, -y+1/2, -z'
8 'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   20.633(4)
_cell_length_b                   20.797(4)
_cell_length_c                   16.615(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.842(4)
_cell_angle_gamma                90.00
_cell_volume                     7126(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9907
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      2.2913
_cell_measurement_theta_min      27.7238
_exptl_absorpt_coefficient_mu    2.204
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.9370
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            'clear whitish colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whitish
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.887
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3968
_exptl_crystal_size_max          0.2500
_exptl_crystal_size_mid          0.2000
_exptl_crystal_size_min          0.2000
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0183
_diffrn_reflns_av_unetI/netI     0.0181
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            27767
_diffrn_reflns_theta_full        27.59
_diffrn_reflns_theta_max         27.59
_diffrn_reflns_theta_min         2.78
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                6925
_reflns_number_total             8023
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material  
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max         0.770
_refine_diff_density_min         -0.582
_refine_diff_density_rms         0.065
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.664
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     442
_refine_ls_number_reflns         8023
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0270
_refine_ls_R_factor_gt           0.0231
_refine_ls_restrained_S_all      0.664
_refine_ls_shift/su_max          0.061
_refine_ls_shift/su_mean         0.007
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0781
_refine_ls_wR_factor_ref         0.0829
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.116880(8) 0.133590(7) 0.252469(11) 0.04060(6) Uani 1 1 d . . .
Ag2 Ag 0.0000 0.507042(12) 0.2500 0.04413(7) Uani 1 2 d S . .
Ag3 Ag 0.5000 0.253436(12) 0.2500 0.04406(7) Uani 1 2 d S . .
Ag4 Ag 0.246967(9) 0.380517(8) 0.151226(12) 0.04339(7) Uani 1 1 d . . .
Ag5 Ag 0.251577(8) 0.383774(8) 0.330980(11) 0.04200(6) Uani 1 1 d . . .
N1 N 0.17665(8) 0.31753(8) 0.32826(12) 0.0420(4) Uani 1 1 d . . .
N3 N 0.08780(8) 0.50185(9) 0.19611(12) 0.0428(4) Uani 1 1 d . . .
N5 N 0.17342(8) -0.05077(8) 0.17721(12) 0.0411(4) Uani 1 1 d . . .
N12 N 0.40783(8) 0.25868(9) 0.20031(12) 0.0434(4) Uani 1 1 d . . .
N14 N 0.12223(8) 0.04017(8) 0.21285(11) 0.0391(4) Uani 1 1 d . . .
N15 N 0.17909(8) 0.45349(8) 0.15622(12) 0.0420(4) Uani 1 1 d . . .
N16 N 0.12336(8) 0.22703(8) 0.29188(11) 0.0402(4) Uani 1 1 d . . .
N22 N 0.31553(9) 0.30770(9) 0.15825(12) 0.0449(4) Uani 1 1 d . . .
C1 C 0.11425(12) 0.61269(10) 0.14372(15) 0.0434(5) Uani 1 1 d . . .
H1 H 0.0761 0.6323 0.1592 0.052 Uiso 1 1 calc R . .
C5 C -0.01051(15) 0.40797(14) 0.47889(19) 0.0674(8) Uani 1 1 d . . .
H5A H 0.0203 0.4407 0.4943 0.101 Uiso 1 1 calc R . .
H5B H -0.0265 0.3878 0.5262 0.101 Uiso 1 1 calc R . .
H5C H -0.0460 0.4271 0.4486 0.101 Uiso 1 1 calc R . .
C9 C 0.14854(15) 0.71891(12) 0.08887(19) 0.0687(8) Uani 1 1 d . . .
H9A H 0.1835 0.7440 0.1118 0.103 Uiso 1 1 calc R . .
H9B H 0.1086 0.7315 0.1125 0.103 Uiso 1 1 calc R . .
H9C H 0.1455 0.7259 0.0318 0.103 Uiso 1 1 calc R . .
C10 C 0.10965(9) -0.05367(9) 0.14600(13) 0.0359(4) Uani 1 1 d . . .
C11 C 0.21880(12) 0.61767(11) 0.08115(14) 0.0432(5) Uani 1 1 d . . .
C13 C 0.07732(11) -0.10047(10) 0.10104(14) 0.0429(5) Uani 1 1 d . . .
H13 H 0.0985 -0.1381 0.0867 0.051 Uiso 1 1 calc R . .
C19 C -0.01906(10) -0.03267(12) 0.09984(14) 0.0429(5) Uani 1 1 d . . .
C20 C 0.36833(9) 0.21304(10) 0.16348(13) 0.0366(4) Uani 1 1 d . . .
C21 C 0.08489(12) 0.36756(9) 0.40460(16) 0.0438(5) Uani 1 1 d . . .
H21 H 0.1071 0.4048 0.4196 0.053 Uiso 1 1 calc R . .
C23 C 0.11479(10) 0.32124(9) 0.35899(12) 0.0359(4) Uani 1 1 d . . .
C25 C 0.22914(10) 0.55291(11) 0.09512(13) 0.0416(5) Uani 1 1 d . . .
H25 H 0.2671 0.5332 0.0791 0.050 Uiso 1 1 calc R . .
C27 C 0.01332(11) -0.09051(11) 0.07780(14) 0.0441(5) Uani 1 1 d . . .
C28 C 0.26932(11) 0.14364(11) 0.08658(14) 0.0434(5) Uani 1 1 d . . .
C29 C 0.18145(9) 0.51750(9) 0.13388(13) 0.0354(4) Uani 1 1 d . . .
C30 C 0.37690(11) 0.14736(11) 0.15014(14) 0.0416(5) Uani 1 1 d . . .
H30 H 0.4153 0.1272 0.1666 0.050 Uiso 1 1 calc R . .
C32 C 0.16115(12) 0.64796(11) 0.10563(14) 0.0452(5) Uani 1 1 d . . .
C34 C -0.01226(10) 0.30124(11) 0.40315(14) 0.0430(5) Uani 1 1 d . . .
C36 C 0.31092(9) 0.24334(10) 0.13779(13) 0.0372(4) Uani 1 1 d . . .
C37 C 0.07847(9) 0.00321(9) 0.16790(12) 0.0348(4) Uani 1 1 d . . .
C38 C 0.27002(14) 0.65541(14) 0.03875(16) 0.0618(7) Uani 1 1 d . . .
H38A H 0.2823 0.6922 0.0706 0.093 Uiso 1 1 calc R . .
H38B H 0.2531 0.6693 -0.0128 0.093 Uiso 1 1 calc R . .
H38C H 0.3073 0.6287 0.0315 0.093 Uiso 1 1 calc R . .
C41 C 0.02202(12) 0.35824(10) 0.42767(15) 0.0444(5) Uani 1 1 d . . .
C43 C 0.01392(10) 0.01354(10) 0.14535(13) 0.0396(5) Uani 1 1 d . . .
H43 H -0.0070 0.0510 0.1606 0.047 Uiso 1 1 calc R . .
C45 C 0.26134(10) 0.20874(12) 0.09867(13) 0.0440(5) Uani 1 1 d . . .
H45 H 0.2235 0.2293 0.0810 0.053 Uiso 1 1 calc R . .
C49 C 0.21534(13) 0.10533(14) 0.04552(17) 0.0583(7) Uani 1 1 d . . .
H49A H 0.1995 0.0738 0.0822 0.087 Uiso 1 1 calc R . .
H49B H 0.2316 0.0842 -0.0011 0.087 Uiso 1 1 calc R . .
H49C H 0.1806 0.1337 0.0293 0.087 Uiso 1 1 calc R . .
C50 C 0.37391(10) 0.31308(11) 0.19614(14) 0.0458(5) Uani 1 1 d . . .
H50 H 0.3893 0.3517 0.2176 0.055 Uiso 1 1 calc R . .
C51 C 0.32763(12) 0.11270(11) 0.11220(14) 0.0429(5) Uani 1 1 d . . .
C52 C 0.17775(10) 0.26133(10) 0.29008(14) 0.0426(5) Uani 1 1 d . . .
H52 H 0.2142 0.2470 0.2638 0.051 Uiso 1 1 calc R . .
C53 C -0.02215(15) -0.14076(13) 0.02705(19) 0.0624(7) Uani 1 1 d . . .
H53A H -0.0357 -0.1222 -0.0237 0.094 Uiso 1 1 calc R . .
H53B H -0.0595 -0.1554 0.0547 0.094 Uiso 1 1 calc R . .
H53C H 0.0063 -0.1764 0.0180 0.094 Uiso 1 1 calc R . .
C54 C 0.33795(14) 0.04160(11) 0.09786(18) 0.0619(7) Uani 1 1 d . . .
H54A H 0.3075 0.0173 0.1282 0.093 Uiso 1 1 calc R . .
H54B H 0.3813 0.0300 0.1148 0.093 Uiso 1 1 calc R . .
H54C H 0.3315 0.0323 0.0416 0.093 Uiso 1 1 calc R . .
C55 C 0.08143(10) 0.26472(9) 0.33594(12) 0.0355(4) Uani 1 1 d . . .
C56 C -0.08870(11) -0.02157(14) 0.07484(17) 0.0595(7) Uani 1 1 d . . .
H56A H -0.0928 -0.0203 0.0171 0.089 Uiso 1 1 calc R . .
H56B H -0.1030 0.0186 0.0966 0.089 Uiso 1 1 calc R . .
H56C H -0.1148 -0.0559 0.0948 0.089 Uiso 1 1 calc R . .
C57 C -0.08166(11) 0.29075(14) 0.42775(18) 0.0619(7) Uani 1 1 d . . .
H57A H -0.0834 0.2910 0.4854 0.093 Uiso 1 1 calc R . .
H57B H -0.0969 0.2501 0.4074 0.093 Uiso 1 1 calc R . .
H57C H -0.1086 0.3245 0.4060 0.093 Uiso 1 1 calc R . .
C58 C 0.12486(9) 0.54733(9) 0.15877(13) 0.0365(4) Uani 1 1 d . . .
C61 C 0.01777(10) 0.25508(10) 0.35820(14) 0.0406(5) Uani 1 1 d . . .
H61 H -0.0043 0.2178 0.3429 0.049 Uiso 1 1 calc R . .
C63 C 0.12270(10) 0.44791(10) 0.19349(15) 0.0449(5) Uani 1 1 d . . .
H63 H 0.1090 0.4094 0.2158 0.054 Uiso 1 1 calc R . .
C65 C 0.17685(10) 0.00544(10) 0.21553(14) 0.0412(5) Uani 1 1 d . . .
H65 H 0.2145 0.0195 0.2422 0.049 Uiso 1 1 calc R . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N14 2.0554(17) . ?
Ag1 N16 2.0537(17) . ?
Ag2 N3 2.0493(17) . ?
Ag2 N3 2.0493(17) 2 ?
Ag3 N12 2.0516(17) . ?
Ag3 N12 2.0516(17) 2_655 ?
Ag4 Ag5 2.9858(6) . ?
Ag4 N15 2.0686(17) . ?
Ag4 N22 2.0730(17) . ?
Ag5 N1 2.0702(16) . ?
Ag5 N5 2.0689(17) 4 ?
N1 C23 1.392(3) . ?
N1 C52 1.330(3) . ?
N3 C58 1.376(3) . ?
N3 C63 1.334(3) . ?
N5 Ag5 2.0689(17) 4_545 ?
N5 C10 1.400(3) . ?
N5 C65 1.332(3) . ?
N12 C20 1.381(3) . ?
N12 C50 1.331(3) . ?
N14 C37 1.386(3) . ?
N14 C65 1.338(3) . ?
N15 C29 1.383(3) . ?
N15 C63 1.341(3) . ?
N16 C52 1.331(3) . ?
N16 C55 1.393(3) . ?
N22 C36 1.383(3) . ?
N22 C50 1.346(3) . ?
C1 H1 0.9300 . ?
C1 C32 1.383(3) . ?
C1 C58 1.398(3) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C5 C41 1.510(3) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C9 C32 1.522(3) . ?
C10 C13 1.385(3) . ?
C10 C37 1.400(3) . ?
C11 C25 1.382(3) . ?
C11 C32 1.417(3) . ?
C11 C38 1.509(3) . ?
C13 H13 0.9300 . ?
C13 C27 1.380(3) . ?
C19 C27 1.429(3) . ?
C19 C43 1.388(3) . ?
C19 C56 1.501(3) . ?
C20 C30 1.396(3) . ?
C20 C36 1.396(3) . ?
C21 H21 0.9300 . ?
C21 C23 1.383(3) . ?
C21 C41 1.378(4) . ?
C23 C55 1.409(3) . ?
C25 H25 0.9300 . ?
C25 C29 1.402(3) . ?
C27 C53 1.516(3) . ?
C28 C45 1.379(3) . ?
C28 C49 1.514(3) . ?
C28 C51 1.418(3) . ?
C29 C58 1.397(3) . ?
C30 H30 0.9300 . ?
C30 C51 1.382(3) . ?
C34 C41 1.433(3) . ?
C34 C57 1.518(3) . ?
C34 C61 1.376(3) . ?
C36 C45 1.394(3) . ?
C37 C43 1.389(3) . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
C43 H43 0.9300 . ?
C45 H45 0.9300 . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50 H50 0.9300 . ?
C51 C54 1.514(3) . ?
C52 H52 0.9300 . ?
C53 H53A 0.9600 . ?
C53 H53B 0.9600 . ?
C53 H53C 0.9600 . ?
C54 H54A 0.9600 . ?
C54 H54B 0.9600 . ?
C54 H54C 0.9600 . ?
C55 C61 1.391(3) . ?
C56 H56A 0.9600 . ?
C56 H56B 0.9600 . ?
C56 H56C 0.9600 . ?
C57 H57A 0.9600 . ?
C57 H57B 0.9600 . ?
C57 H57C 0.9600 . ?
C61 H61 0.9300 . ?
C63 H63 0.9300 . ?
C65 H65 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N16 Ag1 N14 173.19(7) . . ?
N3 Ag2 N3 173.96(10) 2 . ?
N12 Ag3 N12 173.91(10) 2_655 . ?
N15 Ag4 Ag5 86.73(6) . . ?
N15 Ag4 N22 174.47(8) . . ?
N22 Ag4 Ag5 87.74(6) . . ?
N1 Ag5 Ag4 87.90(5) . . ?
N5 Ag5 Ag4 87.07(5) 4 . ?
N5 Ag5 N1 174.96(8) 4 . ?
C23 N1 Ag5 130.40(14) . . ?
C52 N1 Ag5 124.81(15) . . ?
C52 N1 C23 104.68(16) . . ?
C58 N3 Ag2 132.25(14) . . ?
C63 N3 Ag2 122.96(15) . . ?
C63 N3 C58 104.76(17) . . ?
C10 N5 Ag5 130.04(14) . 4_545 ?
C65 N5 Ag5 125.49(14) . 4_545 ?
C65 N5 C10 104.47(16) . . ?
C20 N12 Ag3 131.90(14) . . ?
C50 N12 Ag3 123.04(15) . . ?
C50 N12 C20 105.03(17) . . ?
C37 N14 Ag1 131.00(13) . . ?
C65 N14 Ag1 123.60(14) . . ?
C65 N14 C37 104.60(16) . . ?
C29 N15 Ag4 131.72(14) . . ?
C63 N15 Ag4 123.62(14) . . ?
C63 N15 C29 104.24(17) . . ?
C52 N16 Ag1 123.11(14) . . ?
C52 N16 C55 104.39(16) . . ?
C55 N16 Ag1 131.69(13) . . ?
C36 N22 Ag4 130.66(15) . . ?
C50 N22 Ag4 124.37(15) . . ?
C50 N22 C36 104.41(17) . . ?
C32 C1 H1 120.3 . . ?
C32 C1 C58 119.3(2) . . ?
C58 C1 H1 120.3 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C41 C5 H5A 109.5 . . ?
C41 C5 H5B 109.5 . . ?
C41 C5 H5C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C32 C9 H9A 109.5 . . ?
C32 C9 H9B 109.5 . . ?
C32 C9 H9C 109.5 . . ?
N5 C10 C37 107.55(17) . . ?
C13 C10 N5 131.35(18) . . ?
C13 C10 C37 121.10(19) . . ?
C25 C11 C32 120.8(2) . . ?
C25 C11 C38 118.6(2) . . ?
C32 C11 C38 120.6(2) . . ?
C10 C13 H13 120.5 . . ?
C27 C13 C10 119.0(2) . . ?
C27 C13 H13 120.5 . . ?
C27 C19 C56 120.6(2) . . ?
C43 C19 C27 119.83(19) . . ?
C43 C19 C56 119.5(2) . . ?
N12 C20 C30 131.83(19) . . ?
N12 C20 C36 107.93(18) . . ?
C36 C20 C30 120.2(2) . . ?
C23 C21 H21 120.2 . . ?
C41 C21 H21 120.2 . . ?
C41 C21 C23 119.66(19) . . ?
N1 C23 C55 107.45(17) . . ?
C21 C23 N1 132.06(19) . . ?
C21 C23 C55 120.48(19) . . ?
C11 C25 H25 120.6 . . ?
C11 C25 C29 118.8(2) . . ?
C29 C25 H25 120.6 . . ?
C13 C27 C19 120.4(2) . . ?
C13 C27 C53 119.5(2) . . ?
C19 C27 C53 120.1(2) . . ?
C45 C28 C49 119.5(2) . . ?
C45 C28 C51 120.4(2) . . ?
C51 C28 C49 120.1(2) . . ?
N15 C29 C25 131.30(19) . . ?
N15 C29 C58 108.12(17) . . ?
C58 C29 C25 120.56(18) . . ?
C20 C30 H30 120.4 . . ?
C51 C30 C20 119.2(2) . . ?
C51 C30 H30 120.4 . . ?
C1 C32 C9 118.7(2) . . ?
C1 C32 C11 120.1(2) . . ?
C11 C32 C9 121.2(2) . . ?
C41 C34 C57 120.2(2) . . ?
C61 C34 C41 120.3(2) . . ?
C61 C34 C57 119.4(2) . . ?
N22 C36 C20 108.10(19) . . ?
C45 C36 N22 131.10(19) . . ?
C45 C36 C20 120.8(2) . . ?
N14 C37 C10 108.17(17) . . ?
N14 C37 C43 131.47(18) . . ?
C43 C37 C10 120.35(19) . . ?
C11 C38 H38A 109.5 . . ?
C11 C38 H38B 109.5 . . ?
C11 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C21 C41 C5 120.0(2) . . ?
C21 C41 C34 119.9(2) . . ?
C34 C41 C5 120.2(2) . . ?
C19 C43 C37 119.28(19) . . ?
C19 C43 H43 120.4 . . ?
C37 C43 H43 120.4 . . ?
C28 C45 C36 119.0(2) . . ?
C28 C45 H45 120.5 . . ?
C36 C45 H45 120.5 . . ?
C28 C49 H49A 109.5 . . ?
C28 C49 H49B 109.5 . . ?
C28 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
N12 C50 N22 114.5(2) . . ?
N12 C50 H50 122.7 . . ?
N22 C50 H50 122.7 . . ?
C28 C51 C54 121.2(2) . . ?
C30 C51 C28 120.3(2) . . ?
C30 C51 C54 118.4(2) . . ?
N1 C52 H52 122.2 . . ?
N16 C52 N1 115.65(19) . . ?
N16 C52 H52 122.2 . . ?
C27 C53 H53A 109.5 . . ?
C27 C53 H53B 109.5 . . ?
C27 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C51 C54 H54A 109.5 . . ?
C51 C54 H54B 109.5 . . ?
C51 C54 H54C 109.5 . . ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
N16 C55 C23 107.82(17) . . ?
C61 C55 N16 131.81(18) . . ?
C61 C55 C23 120.37(19) . . ?
C19 C56 H56A 109.5 . . ?
C19 C56 H56B 109.5 . . ?
C19 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C34 C57 H57A 109.5 . . ?
C34 C57 H57B 109.5 . . ?
C34 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
N3 C58 C1 131.5(2) . . ?
N3 C58 C29 108.06(17) . . ?
C29 C58 C1 120.43(19) . . ?
C34 C61 C55 119.30(19) . . ?
C34 C61 H61 120.4 . . ?
C55 C61 H61 120.4 . . ?
N3 C63 N15 114.80(19) . . ?
N3 C63 H63 122.6 . . ?
N15 C63 H63 122.6 . . ?
N5 C65 N14 115.21(18) . . ?
N5 C65 H65 122.4 . . ?
N14 C65 H65 122.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N14 C37 C10 170.41(15) . . . . ?
Ag1 N14 C37 C43 -10.9(4) . . . . ?
Ag1 N14 C65 N5 -171.03(15) . . . . ?
Ag1 N16 C52 N1 -170.62(15) . . . . ?
Ag1 N16 C55 C23 169.36(15) . . . . ?
Ag1 N16 C55 C61 -10.4(4) . . . . ?
Ag2 N3 C58 C1 -1.4(4) . . . . ?
Ag2 N3 C58 C29 178.93(16) . . . . ?
Ag2 N3 C63 N15 -179.62(16) . . . . ?
Ag3 N12 C20 C30 2.6(4) . . . . ?
Ag3 N12 C20 C36 -177.74(16) . . . . ?
Ag3 N12 C50 N22 177.13(15) . . . . ?
Ag4 Ag5 N1 C23 -120.99(19) . . . . ?
Ag4 Ag5 N1 C52 54.59(18) . . . . ?
Ag4 N15 C29 C25 5.2(4) . . . . ?
Ag4 N15 C29 C58 -173.22(16) . . . . ?
Ag4 N15 C63 N3 174.57(16) . . . . ?
Ag4 N22 C36 C20 -172.63(16) . . . . ?
Ag4 N22 C36 C45 7.5(4) . . . . ?
Ag4 N22 C50 N12 173.63(16) . . . . ?
Ag5 Ag4 N15 C29 112.4(2) . . . . ?
Ag5 Ag4 N15 C63 -58.99(19) . . . . ?
Ag5 Ag4 N22 C36 112.8(2) . . . . ?
Ag5 Ag4 N22 C50 -57.21(19) . . . . ?
Ag5 N1 C23 C21 -4.4(4) . . . . ?
Ag5 N1 C23 C55 176.01(15) . . . . ?
Ag5 N1 C52 N16 -176.49(15) . . . . ?
Ag5 N5 C10 C13 0.3(4) 4_545 . . . ?
Ag5 N5 C10 C37 -179.48(15) 4_545 . . . ?
Ag5 N5 C65 N14 179.87(15) 4_545 . . . ?
N1 C23 C55 N16 0.3(2) . . . . ?
N1 C23 C55 C61 -179.8(2) . . . . ?
N3 Ag2 N3 C58 167.8(2) 2 . . . ?
N3 Ag2 N3 C63 -14.29(19) 2 . . . ?
N5 Ag5 N1 C23 -125.4(8) 4 . . . ?
N5 Ag5 N1 C52 50.2(9) 4 . . . ?
N5 C10 C13 C27 -179.9(2) . . . . ?
N5 C10 C37 N14 -0.8(2) . . . . ?
N5 C10 C37 C43 -179.60(19) . . . . ?
N12 Ag3 N12 C20 166.5(2) 2_655 . . . ?
N12 Ag3 N12 C50 -11.24(19) 2_655 . . . ?
N12 C20 C30 C51 178.8(2) . . . . ?
N12 C20 C36 N22 0.5(2) . . . . ?
N12 C20 C36 C45 -179.60(19) . . . . ?
N14 Ag1 N16 C52 12.5(7) . . . . ?
N14 Ag1 N16 C55 -155.6(5) . . . . ?
N14 C37 C43 C19 -179.5(2) . . . . ?
N15 Ag4 Ag5 N1 88.90(7) . . . . ?
N15 Ag4 Ag5 N5 -91.48(7) . . . 4 ?
N15 Ag4 N22 C36 114.2(7) . . . . ?
N15 Ag4 N22 C50 -55.8(8) . . . . ?
N15 C29 C58 N3 -0.1(2) . . . . ?
N15 C29 C58 C1 -179.9(2) . . . . ?
N16 Ag1 N14 C37 -153.1(5) . . . . ?
N16 Ag1 N14 C65 15.0(7) . . . . ?
N16 C55 C61 C34 179.6(2) . . . . ?
N22 Ag4 Ag5 N1 -91.23(8) . . . . ?
N22 Ag4 Ag5 N5 88.38(7) . . . 4 ?
N22 Ag4 N15 C29 111.0(7) . . . . ?
N22 Ag4 N15 C63 -60.4(8) . . . . ?
N22 C36 C45 C28 -179.3(2) . . . . ?
C10 N5 C65 N14 -0.2(3) . . . . ?
C10 C13 C27 C19 0.0(4) . . . . ?
C10 C13 C27 C53 178.7(2) . . . . ?
C10 C37 C43 C19 -1.0(3) . . . . ?
C11 C25 C29 N15 -179.0(2) . . . . ?
C11 C25 C29 C58 -0.8(3) . . . . ?
C13 C10 C37 N14 179.4(2) . . . . ?
C13 C10 C37 C43 0.6(3) . . . . ?
C20 N12 C50 N22 -1.1(3) . . . . ?
C20 C30 C51 C28 0.5(4) . . . . ?
C20 C30 C51 C54 179.7(2) . . . . ?
C20 C36 C45 C28 0.9(3) . . . . ?
C21 C23 C55 N16 -179.3(2) . . . . ?
C21 C23 C55 C61 0.6(3) . . . . ?
C23 N1 C52 N16 0.0(3) . . . . ?
C23 C21 C41 C5 178.8(2) . . . . ?
C23 C21 C41 C34 -1.1(4) . . . . ?
C23 C55 C61 C34 -0.2(3) . . . . ?
C25 C11 C32 C1 -0.3(4) . . . . ?
C25 C11 C32 C9 -178.6(2) . . . . ?
C25 C29 C58 N3 -178.76(19) . . . . ?
C25 C29 C58 C1 1.5(3) . . . . ?
C27 C19 C43 C37 0.9(3) . . . . ?
C29 N15 C63 N3 1.2(3) . . . . ?
C30 C20 C36 N22 -179.8(2) . . . . ?
C30 C20 C36 C45 0.1(3) . . . . ?
C32 C1 C58 N3 178.7(2) . . . . ?
C32 C1 C58 C29 -1.6(3) . . . . ?
C32 C11 C25 C29 0.1(4) . . . . ?
C36 N22 C50 N12 1.5(3) . . . . ?
C36 C20 C30 C51 -0.8(3) . . . . ?
C37 N14 C65 N5 -0.3(3) . . . . ?
C37 C10 C13 C27 -0.1(3) . . . . ?
C38 C11 C25 C29 -179.5(2) . . . . ?
C38 C11 C32 C1 179.3(2) . . . . ?
C38 C11 C32 C9 1.0(4) . . . . ?
C41 C21 C23 N1 -179.4(2) . . . . ?
C41 C21 C23 C55 0.1(4) . . . . ?
C41 C34 C61 C55 -0.8(3) . . . . ?
C43 C19 C27 C13 -0.5(4) . . . . ?
C43 C19 C27 C53 -179.1(2) . . . . ?
C45 C28 C51 C30 0.5(4) . . . . ?
C45 C28 C51 C54 -178.6(2) . . . . ?
C49 C28 C45 C36 178.9(2) . . . . ?
C49 C28 C51 C30 -179.6(2) . . . . ?
C49 C28 C51 C54 1.2(4) . . . . ?
C50 N12 C20 C30 -179.3(2) . . . . ?
C50 N12 C20 C36 0.3(2) . . . . ?
C50 N22 C36 C20 -1.2(2) . . . . ?
C50 N22 C36 C45 179.0(2) . . . . ?
C51 C28 C45 C36 -1.2(3) . . . . ?
C52 N1 C23 C21 179.3(2) . . . . ?
C52 N1 C23 C55 -0.2(2) . . . . ?
C52 N16 C55 C23 -0.3(2) . . . . ?
C52 N16 C55 C61 179.9(2) . . . . ?
C55 N16 C52 N1 0.2(3) . . . . ?
C56 C19 C27 C13 -179.9(2) . . . . ?
C56 C19 C27 C53 1.4(4) . . . . ?
C56 C19 C43 C37 -179.6(2) . . . . ?
C57 C34 C41 C5 0.6(4) . . . . ?
C57 C34 C41 C21 -179.6(2) . . . . ?
C57 C34 C61 C55 -179.8(2) . . . . ?
C58 N3 C63 N15 -1.2(3) . . . . ?
C58 C1 C32 C9 179.3(2) . . . . ?
C58 C1 C32 C11 1.0(4) . . . . ?
C61 C34 C41 C5 -178.4(2) . . . . ?
C61 C34 C41 C21 1.5(4) . . . . ?
C63 N3 C58 C1 -179.5(3) . . . . ?
C63 N3 C58 C29 0.8(2) . . . . ?
C63 N15 C29 C25 177.9(2) . . . . ?
C63 N15 C29 C58 -0.6(2) . . . . ?
C65 N5 C10 C13 -179.6(2) . . . . ?
C65 N5 C10 C37 0.6(2) . . . . ?
C65 N14 C37 C10 0.6(2) . . . . ?
C65 N14 C37 C43 179.3(2) . . . . ?

