# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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#######################################################################

data_p21c
_database_code_depnum_ccdc_archive 'CCDC 1420798'
_audit_update_record             
;
2015-12-02 deposited with the CCDC.
2015-12-04 downloaded from the CCDC.
;
_chemical_name_systematic        ?
_chemical_name_common            cageAg3PF6
_chemical_formula_moiety         'C86 H92 Ag3 N12, 6(C4 H8 O2), 3(F6 P)'
_chemical_formula_sum            'C110 H140 Ag3 F18 N12 O12 P3'
_chemical_formula_iupac          ?
_chemical_formula_weight         2580.85

_chemical_melting_point          ?

_space_group_crystal_system      monoclinic
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   34.813(3)
_cell_length_b                   20.6402(19)
_cell_length_c                   16.3040(15)
_cell_angle_alpha                90
_cell_angle_beta                 102.6780(10)
_cell_angle_gamma                90
_cell_volume                     11429.6(18)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?
_cell_measurement_temperature    150

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.200
_exptl_crystal_density_diffrn    1.500
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5312

_exptl_absorpt_coefficient_mu    0.644
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (Sheldrick 1996)'
_exptl_absorpt_correction_T_min  0.78
_exptl_absorpt_correction_T_max  0.88

_exptl_special_details           'SADABS (Sheldrick 1996)'

_diffrn_ambient_temperature      150

_diffrn_source                   'sealed tube'
_diffrn_source_type              ?

_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator  graphite

_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'Phi and Omega scans'

_diffrn_detector_area_resol_mean ?

_diffrn_reflns_number            55296
_diffrn_reflns_av_R_equivalents  0.0442
_diffrn_reflns_av_unetI/netI     0.0824
_diffrn_reflns_theta_min         1.616
_diffrn_reflns_theta_max         26.463
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.959
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_limit_h_min       -43
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       20

_refine_special_details          SQUEEZE

_reflns_number_total             22635
_reflns_number_gt                11439
_reflns_threshold_expression     'I > 2σ(I)'

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_R_factor_all          0.1336
_refine_ls_R_factor_gt           0.0707
_refine_ls_wR_factor_gt          0.1916
_refine_ls_wR_factor_ref         0.2158
_refine_ls_goodness_of_fit_ref   0.959
_refine_ls_restrained_S_all      0.958
_refine_ls_number_reflns         22635
_refine_ls_number_parameters     1340
_refine_ls_number_restraints     96
_refine_ls_hydrogen_treatment    constr
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1242P)²] where P=(Fo²+2Fc²)/3'

_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap

_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_diff_density_max         1.630
_refine_diff_density_min         -0.694
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_data_reduction        'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'XSHEL (Bruker AXS,2002)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'

loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_refinement_flags_posn
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O O5A 0.5458(7) 0.5386(10) 0.3058(11) 0.193(11) Uani d . P . 0.58(2) A 1
O O6A 0.5743(15) 0.6722(16) 0.2612(19) 0.315(18) Uani d . P . 0.58(2) A 1
O O5B 0.5898(15) 0.5630(15) 0.3122(19) 0.224(6) Uani d U P . 0.42(2) A 2
O O6B 0.5372(14) 0.6600(18) 0.242(2) 0.225(6) Uani d U P . 0.42(2) A 2
Ag Ag1 0.07060(2) 0.71132(2) 0.62841(3) 0.05578(16) Uani d . . . 1.0 . .
Ag Ag2 0.25666(2) 1.24180(2) 0.55331(4) 0.06186(18) Uani d . . . 1.0 . .
Ag Ag3 0.42317(2) 0.72407(2) 0.43063(3) 0.05684(16) Uani d . . . 1.0 . .
C C1 0.08645(18) 0.6226(3) 0.5829(4) 0.0558(17) Uani d . . . 1.0 . .
C C2 0.1180(2) 0.5499(3) 0.5224(5) 0.0642(19) Uani d . . . 1.0 . .
H H2 0.1352 0.5315 0.4909 0.077 Uiso calc U . R 1.0 . .
C C3 0.0961(2) 0.5178(4) 0.5646(5) 0.079(2) Uani d . . . 1.0 . .
H H3 0.0938 0.4721 0.5673 0.095 Uiso calc U . R 1.0 . .
C C4 0.0536(2) 0.5461(4) 0.6680(6) 0.089(3) Uani d . . . 1.0 . .
H H4A 0.0602 0.5021 0.6909 0.107 Uiso calc U . R 1.0 . .
H H4B 0.0592 0.5775 0.7149 0.107 Uiso calc U . R 1.0 . .
C C5 0.0137(4) 0.5492(6) 0.6270(7) 0.137(4) Uani d . . . 1.0 . .
H H5A 0.0067 0.5942 0.611 0.206 Uiso calc U . R 1.0 . .
H H5B -0.0026 0.5336 0.6648 0.206 Uiso calc U . R 1.0 . .
H H5C 0.0092 0.5221 0.5764 0.206 Uiso calc U . R 1.0 . .
C C6 0.12909(17) 0.6656(3) 0.4936(4) 0.0440(14) Uani d . . . 1.0 . .
C C7 0.10634(17) 0.7147(3) 0.4540(4) 0.0492(15) Uani d . . . 1.0 . .
H H7 0.0787 0.7146 0.4505 0.059 Uiso calc U . R 1.0 . .
C C8 0.12361(17) 0.7645(3) 0.4190(4) 0.0501(15) Uani d . . . 1.0 . .
H H8 0.1075 0.7991 0.3928 0.06 Uiso calc U . R 1.0 . .
C C9 0.16413(16) 0.7661(3) 0.4206(3) 0.0409(13) Uani d . . . 1.0 . .
C C10 0.18591(17) 0.7152(3) 0.4612(4) 0.0445(14) Uani d . . . 1.0 . .
H H10 0.2134 0.7139 0.4631 0.053 Uiso calc U . R 1.0 . .
C C11 0.16929(17) 0.6657(3) 0.4991(4) 0.0467(14) Uani d . . . 1.0 . .
H H11 0.1853 0.6323 0.5287 0.056 Uiso calc U . R 1.0 . .
C C12 0.1975(2) 1.2401(4) 0.5582(6) 0.081(3) Uani d . . . 1.0 . .
C C13 0.1364(2) 1.2055(4) 0.5613(7) 0.100(3) Uani d . . . 1.0 . .
H H13 0.1139 1.1784 0.5551 0.12 Uiso calc U . R 1.0 . .
C C14 0.1392(2) 1.2671(4) 0.5883(7) 0.107(4) Uani d . . . 1.0 . .
H H14 0.1194 1.2917 0.6059 0.128 Uiso calc U . R 1.0 . .
C C15 0.1911(3) 1.3545(4) 0.6051(8) 0.121(4) Uani d . . . 1.0 . .
H H15A 0.2198 1.3557 0.6079 0.145 Uiso calc U . R 1.0 . .
H H15B 0.1783 1.3831 0.5583 0.145 Uiso calc U . R 1.0 . .
C C16 0.1845(4) 1.3784(6) 0.6760(8) 0.159(6) Uani d . . . 1.0 . .
H H16A 0.1565 1.3743 0.6761 0.238 Uiso calc U . R 1.0 . .
H H16B 0.1921 1.4242 0.6807 0.238 Uiso calc U . R 1.0 . .
H H16C 0.2001 1.3544 0.7237 0.238 Uiso calc U . R 1.0 . .
C C17 0.17957(18) 1.1278(3) 0.5100(5) 0.0578(18) Uani d . . . 1.0 . .
C C18 0.19654(19) 1.1250(3) 0.4424(5) 0.0643(19) Uani d . . . 1.0 . .
H H18 0.2047 1.1637 0.4197 0.077 Uiso calc U . R 1.0 . .
C C19 0.20186(19) 1.0662(3) 0.4070(4) 0.0574(17) Uani d . . . 1.0 . .
H H19 0.2145 1.0651 0.361 0.069 Uiso calc U . R 1.0 . .
C C20 0.18947(16) 1.0090(3) 0.4358(4) 0.0482(15) Uani d . . . 1.0 . .
C C21 0.17380(18) 1.0113(3) 0.5084(4) 0.0551(16) Uani d . . . 1.0 . .
H H21 0.1666 0.9724 0.5324 0.066 Uiso calc U . R 1.0 . .
C C22 0.16881(18) 1.0713(3) 0.5453(4) 0.0576(17) Uani d . . . 1.0 . .
H H22 0.1581 1.0732 0.5941 0.069 Uiso calc U . R 1.0 . .
C C23 0.43254(18) 0.8099(3) 0.3722(5) 0.0594(18) Uani d . . . 1.0 . .
C C24 0.4255(2) 0.9042(4) 0.2998(6) 0.080(2) Uani d . . . 1.0 . .
H H24 0.4138 0.9417 0.2709 0.096 Uiso calc U . R 1.0 . .
C C25 0.4633(2) 0.8850(4) 0.3118(6) 0.093(3) Uani d . . . 1.0 . .
H H25 0.4839 0.9075 0.2942 0.112 Uiso calc U . R 1.0 . .
C C26 0.5045(3) 0.7908(5) 0.3790(8) 0.111(4) Uani d . . . 1.0 . .
H H26A 0.5227 0.8028 0.3427 0.133 Uiso calc U . R 1.0 . .
H H26B 0.4994 0.7436 0.3736 0.133 Uiso calc U . R 1.0 . .
C C27 0.5226(4) 0.8090(7) 0.4728(10) 0.163(6) Uani d . . . 1.0 . .
H H27A 0.5404 0.8461 0.4746 0.244 Uiso calc U . R 1.0 . .
H H27B 0.5374 0.772 0.5013 0.244 Uiso calc U . R 1.0 . .
H H27C 0.5015 0.8204 0.5011 0.244 Uiso calc U . R 1.0 . .
C C28 0.36604(17) 0.8589(3) 0.3389(4) 0.0494(16) Uani d . . . 1.0 . .
C C29 0.35186(17) 0.8411(3) 0.4102(4) 0.0490(15) Uani d . . . 1.0 . .
H H29 0.3697 0.8275 0.46 0.059 Uiso calc U . R 1.0 . .
C C30 0.31223(17) 0.8432(3) 0.4079(4) 0.0466(14) Uani d . . . 1.0 . .
H H30 0.303 0.8306 0.4563 0.056 Uiso calc U . R 1.0 . .
C C31 0.28523(17) 0.8635(3) 0.3366(3) 0.0431(14) Uani d . . . 1.0 . .
C C32 0.29970(18) 0.8801(3) 0.2660(4) 0.0528(16) Uani d . . . 1.0 . .
H H32 0.282 0.8936 0.2159 0.063 Uiso calc U . R 1.0 . .
C C33 0.3396(2) 0.8769(3) 0.2686(4) 0.0524(16) Uani d . . . 1.0 . .
H H33 0.3487 0.8877 0.2196 0.063 Uiso calc U . R 1.0 . .
C C34 0.18081(15) 0.8227(3) 0.3798(3) 0.0414(13) Uani d . . . 1.0 . .
C C35 0.17800(16) 0.8859(3) 0.4292(4) 0.0411(13) Uani d . . . 1.0 . .
H H35A 0.1502 0.8932 0.4321 0.049 Uiso calc U . R 1.0 . .
H H35B 0.1936 0.8809 0.4874 0.049 Uiso calc U . R 1.0 . .
C C36 0.19306(16) 0.9454(3) 0.3887(3) 0.0405(13) Uani d . . . 1.0 . .
C C37 0.23664(16) 0.9332(3) 0.3867(4) 0.0441(14) Uani d . . . 1.0 . .
H H37A 0.247 0.971 0.361 0.053 Uiso calc U . R 1.0 . .
H H37B 0.2523 0.9285 0.445 0.053 Uiso calc U . R 1.0 . .
C C38 0.24138(16) 0.8716(3) 0.3363(3) 0.0414(13) Uani d . . . 1.0 . .
C C39 0.22464(16) 0.8130(3) 0.3775(4) 0.0431(14) Uani d . . . 1.0 . .
H H39A 0.2274 0.7732 0.3455 0.052 Uiso calc U . R 1.0 . .
H H39B 0.2402 0.8072 0.4356 0.052 Uiso calc U . R 1.0 . .
C C40 0.15730(18) 0.8313(3) 0.2876(4) 0.0496(15) Uani d . . . 1.0 . .
H H40A 0.1601 0.792 0.2546 0.059 Uiso calc U . R 1.0 . .
H H40B 0.129 0.8373 0.2869 0.059 Uiso calc U . R 1.0 . .
C C41 0.16883(18) 0.9511(3) 0.2988(4) 0.0535(16) Uani d . . . 1.0 . .
H H41A 0.1782 0.9887 0.2709 0.064 Uiso calc U . R 1.0 . .
H H41B 0.1409 0.9585 0.2998 0.064 Uiso calc U . R 1.0 . .
C C42 0.21589(18) 0.8797(3) 0.2462(4) 0.0533(16) Uani d . . . 1.0 . .
H H42A 0.2252 0.9176 0.219 0.064 Uiso calc U . R 1.0 . .
H H42B 0.2187 0.8408 0.2124 0.064 Uiso calc U . R 1.0 . .
C C43 0.17242(18) 0.8891(3) 0.2485(4) 0.0512(16) Uani d . . . 1.0 . .
H H43 0.1567 0.8945 0.1897 0.061 Uiso calc U . R 1.0 . .
C C44 0.05588(19) 0.8006(3) 0.6734(4) 0.0550(16) Uani d . . . 1.0 . .
C C45 0.0598(2) 0.9033(3) 0.7252(5) 0.069(2) Uani d . . . 1.0 . .
H H45 0.07 0.944 0.7473 0.083 Uiso calc U . R 1.0 . .
C C46 0.0226(2) 0.8827(4) 0.7120(6) 0.082(2) Uani d . . . 1.0 . .
H H46 0.001 0.9074 0.7216 0.099 Uiso calc U . R 1.0 . .
C C47 -0.0148(2) 0.7803(4) 0.6635(5) 0.074(2) Uani d . . . 1.0 . .
H H47A -0.0219 0.7673 0.7167 0.089 Uiso calc U . R 1.0 . .
H H47B -0.0093 0.7405 0.6343 0.089 Uiso calc U . R 1.0 . .
C C48 -0.0486(3) 0.8151(6) 0.6098(7) 0.124(4) Uani d . . . 1.0 . .
H H48A -0.056 0.852 0.6409 0.187 Uiso calc U . R 1.0 . .
H H48B -0.071 0.7856 0.5943 0.187 Uiso calc U . R 1.0 . .
H H48C -0.041 0.8307 0.5588 0.187 Uiso calc U . R 1.0 . .
C C49 0.12204(18) 0.8554(3) 0.7041(4) 0.0500(15) Uani d . . . 1.0 . .
C C50 0.1457(2) 0.8876(3) 0.7701(4) 0.0620(18) Uani d . . . 1.0 . .
H H50 0.1345 0.908 0.8117 0.074 Uiso calc U . R 1.0 . .
C C51 0.1859(2) 0.8900(3) 0.7752(4) 0.0642(19) Uani d . . . 1.0 . .
H H51 0.2019 0.9131 0.8206 0.077 Uiso calc U . R 1.0 . .
C C52 0.20400(18) 0.8606(3) 0.7180(4) 0.0486(15) Uani d . . . 1.0 . .
C C53 0.17889(18) 0.8269(3) 0.6531(4) 0.0513(15) Uani d . . . 1.0 . .
H H53 0.1902 0.8045 0.6132 0.062 Uiso calc U . R 1.0 . .
C C54 0.13880(18) 0.8246(3) 0.6443(4) 0.0506(15) Uani d . . . 1.0 . .
H H54 0.1227 0.8024 0.5982 0.061 Uiso calc U . R 1.0 . .
C C55 0.31634(18) 1.2410(3) 0.5583(4) 0.0525(16) Uani d . . . 1.0 . .
C C56 0.3801(2) 1.2092(3) 0.5908(6) 0.086(3) Uani d . . . 1.0 . .
H H56 0.403 1.1834 0.6097 0.103 Uiso calc U . R 1.0 . .
C C57 0.3791(2) 1.2692(4) 0.5590(6) 0.085(3) Uani d . . . 1.0 . .
H H57 0.401 1.2938 0.5505 0.102 Uiso calc U . R 1.0 . .
C C58 0.3267(2) 1.3534(3) 0.5111(6) 0.082(2) Uani d . . . 1.0 . .
H H58A 0.2976 1.3553 0.5012 0.098 Uiso calc U . R 1.0 . .
H H58B 0.3376 1.3859 0.5547 0.098 Uiso calc U . R 1.0 . .
C C59 0.3388(3) 1.3690(5) 0.4344(7) 0.127(4) Uani d . . . 1.0 . .
H H59A 0.3676 1.3705 0.4452 0.19 Uiso calc U . R 1.0 . .
H H59B 0.328 1.4113 0.4138 0.19 Uiso calc U . R 1.0 . .
H H59C 0.3289 1.3358 0.392 0.19 Uiso calc U . R 1.0 . .
C C60 0.33109(16) 1.1311(3) 0.6207(4) 0.0482(15) Uani d . . . 1.0 . .
C C61 0.35057(17) 1.1102(3) 0.6997(4) 0.0557(17) Uani d . . . 1.0 . .
H H61 0.3699 1.1368 0.734 0.067 Uiso calc U . R 1.0 . .
C C62 0.34151(17) 1.0495(3) 0.7283(4) 0.0500(15) Uani d . . . 1.0 . .
H H62 0.3556 1.0343 0.7814 0.06 Uiso calc U . R 1.0 . .
C C63 0.31231(16) 1.0108(3) 0.6805(3) 0.0408(13) Uani d . . . 1.0 . .
C C64 0.29315(17) 1.0353(3) 0.6025(4) 0.0478(15) Uani d . . . 1.0 . .
H H64 0.2732 1.0097 0.5684 0.057 Uiso calc U . R 1.0 . .
C C65 0.30167(17) 1.0945(3) 0.5727(4) 0.0493(15) Uani d . . . 1.0 . .
H H65 0.2875 1.1098 0.5197 0.059 Uiso calc U . R 1.0 . .
C C66 0.41107(17) 0.6350(3) 0.4789(4) 0.0507(15) Uani d . . . 1.0 . .
C C67 0.3785(2) 0.5579(3) 0.5314(4) 0.0619(18) Uani d . . . 1.0 . .
H H67 0.3605 0.5371 0.5589 0.074 Uiso calc U . R 1.0 . .
C C68 0.4031(2) 0.5295(4) 0.4926(5) 0.070(2) Uani d . . . 1.0 . .
H H68 0.4063 0.4841 0.4876 0.084 Uiso calc U . R 1.0 . .
C C69 0.4540(2) 0.5661(4) 0.4110(5) 0.070(2) Uani d . . . 1.0 . .
H H69A 0.4741 0.6006 0.425 0.084 Uiso calc U . R 1.0 . .
H H69B 0.4671 0.5241 0.4277 0.084 Uiso calc U . R 1.0 . .
C C70 0.4386(2) 0.5658(5) 0.3216(5) 0.096(3) Uani d . . . 1.0 . .
H H70A 0.4174 0.5338 0.3075 0.144 Uiso calc U . R 1.0 . .
H H70B 0.4597 0.5547 0.2929 0.144 Uiso calc U . R 1.0 . .
H H70C 0.4283 0.6089 0.3034 0.144 Uiso calc U . R 1.0 . .
C C71 0.36494(18) 0.6729(3) 0.5600(3) 0.0475(15) Uani d . . . 1.0 . .
C C72 0.38689(18) 0.7242(3) 0.6042(4) 0.0496(15) Uani d . . . 1.0 . .
H H72 0.4146 0.7259 0.6095 0.06 Uiso calc U . R 1.0 . .
C C73 0.36797(19) 0.7723(3) 0.6402(4) 0.0561(17) Uani d . . . 1.0 . .
H H73 0.3832 0.8065 0.67 0.067 Uiso calc U . R 1.0 . .
C C74 0.32760(18) 0.7722(3) 0.6341(4) 0.0445(14) Uani d . . . 1.0 . .
C C75 0.30589(17) 0.7214(3) 0.5903(3) 0.0406(13) Uani d . . . 1.0 . .
H H75 0.2782 0.7199 0.5855 0.049 Uiso calc U . R 1.0 . .
C C76 0.32409(17) 0.6730(3) 0.5535(3) 0.0461(15) Uani d . . . 1.0 . .
H H76 0.3086 0.6392 0.5234 0.055 Uiso calc U . R 1.0 . .
C C77 0.24867(17) 0.8655(3) 0.7275(3) 0.0441(14) Uani d . . . 1.0 . .
C C78 0.25798(16) 0.9339(3) 0.6999(4) 0.0441(14) Uani d . . . 1.0 . .
H H78A 0.248 0.9666 0.7346 0.053 Uiso calc U . R 1.0 . .
H H78B 0.2445 0.9409 0.6405 0.053 Uiso calc U . R 1.0 . .
C C79 0.30337(16) 0.9429(3) 0.7099(3) 0.0423(13) Uani d . . . 1.0 . .
C C80 0.31817(17) 0.8920(3) 0.6566(3) 0.0409(13) Uani d . . . 1.0 . .
H H80A 0.3469 0.8974 0.6622 0.049 Uiso calc U . R 1.0 . .
H H80B 0.3052 0.8986 0.5967 0.049 Uiso calc U . R 1.0 . .
C C81 0.30976(16) 0.8226(3) 0.6830(3) 0.0426(14) Uani d . . . 1.0 . .
C C82 0.26506(16) 0.8157(3) 0.6736(3) 0.0438(14) Uani d . . . 1.0 . .
H H82A 0.259 0.7715 0.6905 0.053 Uiso calc U . R 1.0 . .
H H82B 0.2518 0.8217 0.6138 0.053 Uiso calc U . R 1.0 . .
C C83 0.26947(18) 0.8560(3) 0.8189(4) 0.0523(16) Uani d . . . 1.0 . .
H H83A 0.2637 0.8121 0.8376 0.063 Uiso calc U . R 1.0 . .
H H83B 0.2595 0.888 0.8544 0.063 Uiso calc U . R 1.0 . .
C C84 0.32293(17) 0.9316(3) 0.8022(4) 0.0485(15) Uani d . . . 1.0 . .
H H84A 0.3518 0.9373 0.8104 0.058 Uiso calc U . R 1.0 . .
H H84B 0.3131 0.964 0.8375 0.058 Uiso calc U . R 1.0 . .
C C85 0.32946(17) 0.8137(3) 0.7775(4) 0.0486(15) Uani d . . . 1.0 . .
H H85A 0.3236 0.7699 0.7962 0.058 Uiso calc U . R 1.0 . .
H H85B 0.3584 0.8179 0.7857 0.058 Uiso calc U . R 1.0 . .
C C86 0.31419(18) 0.8643(3) 0.8294(4) 0.0523(16) Uani d . . . 1.0 . .
H H86 0.3273 0.8583 0.89 0.063 Uiso calc U . R 1.0 . .
C C87 0.0585(4) 0.9658(6) 0.4136(10) 0.141(5) Uani d . . . 1.0 . .
H H87A 0.0365 0.9894 0.3769 0.169 Uiso calc U . R 1.0 . .
H H87B 0.0825 0.9928 0.4202 0.169 Uiso calc U . R 1.0 . .
C C88 0.0495(4) 0.9555(8) 0.4939(11) 0.183(6) Uani d . . . 1.0 . .
H H88A 0.0447 0.9977 0.5187 0.219 Uiso calc U . R 1.0 . .
H H88B 0.0723 0.9348 0.5319 0.219 Uiso calc U . R 1.0 . .
C C89 0.0214(4) 0.8565(5) 0.4471(9) 0.140(4) Uani d . . . 1.0 . .
H H89A -0.0016 0.8274 0.4405 0.168 Uiso calc U . R 1.0 . .
H H89B 0.0443 0.834 0.4824 0.168 Uiso calc U . R 1.0 . .
C C90 0.0291(3) 0.8695(6) 0.3686(7) 0.123(4) Uani d . . . 1.0 . .
H H90A 0.0067 0.8938 0.3342 0.148 Uiso calc U . R 1.0 . .
H H90B 0.0318 0.8282 0.3395 0.148 Uiso calc U . R 1.0 . .
C C91 0.3883(3) 0.9827(6) 0.5301(10) 0.146(5) Uani d . . . 1.0 . .
H H91A 0.3819 0.9711 0.4697 0.176 Uiso calc U . R 1.0 . .
H H91B 0.3633 0.9924 0.5472 0.176 Uiso calc U . R 1.0 . .
C C92 0.4126(5) 1.0377(8) 0.5424(14) 0.247(11) Uani d . . . 1.0 . .
H H92A 0.3996 1.0722 0.504 0.296 Uiso calc U . R 1.0 . .
H H92B 0.4146 1.0533 0.6006 0.296 Uiso calc U . R 1.0 . .
C C93 0.4659(5) 0.9738(10) 0.5733(16) 0.289(14) Uani d . . . 1.0 . .
H H93A 0.4883 0.9611 0.5485 0.347 Uiso calc U . R 1.0 . .
H H93B 0.4772 0.9875 0.6318 0.347 Uiso calc U . R 1.0 . .
C C94 0.4453(4) 0.9203(8) 0.5779(10) 0.176(6) Uani d . . . 1.0 . .
H H94A 0.4579 0.8967 0.6297 0.212 Uiso calc U . R 1.0 . .
H H94B 0.447 0.8923 0.5296 0.212 Uiso calc U . R 1.0 . .
C C95 0.5539(7) 0.5881(9) 0.3550(11) 0.219(5) Uani d U . . 1.0 . .
H H95A 0.5829 0.5906 0.3745 0.262 Uiso calc U P R 0.58(2) A 1
H H95B 0.5429 0.5801 0.4051 0.262 Uiso calc U P R 0.58(2) A 1
H H95C 0.532 0.5565 0.3434 0.262 Uiso calc U P R 0.42(2) A 2
H H95D 0.5634 0.5914 0.4167 0.262 Uiso calc U P R 0.42(2) A 2
C C96 0.5408(7) 0.6473(9) 0.3229(11) 0.220(5) Uani d U . . 1.0 . .
H H96A 0.5406 0.6786 0.3687 0.264 Uiso calc U P R 0.58(2) A 1
H H96B 0.5138 0.6438 0.2877 0.264 Uiso calc U P R 0.58(2) A 1
H H96C 0.5146 0.6543 0.3359 0.264 Uiso calc U P R 0.42(2) A 2
H H96D 0.5587 0.6803 0.3547 0.264 Uiso calc U P R 0.42(2) A 2
C C97 0.5583(7) 0.6154(10) 0.2007(12) 0.233(5) Uani d U . . 1.0 . .
H H97A 0.5292 0.6182 0.1839 0.279 Uiso calc U P R 0.58(2) A 1
H H97B 0.5689 0.6189 0.1493 0.279 Uiso calc U P R 0.58(2) A 1
H H97C 0.5419 0.6069 0.144 0.279 Uiso calc U P R 0.42(2) A 2
H H97D 0.5826 0.6372 0.1931 0.279 Uiso calc U P R 0.42(2) A 2
C C98 0.5684(7) 0.5593(10) 0.2369(12) 0.227(5) Uani d U . . 1.0 . .
H H98A 0.5969 0.5605 0.2628 0.273 Uiso calc U P R 0.58(2) A 1
H H98B 0.5643 0.5255 0.1928 0.273 Uiso calc U P R 0.58(2) A 1
H H98C 0.5442 0.5348 0.2387 0.273 Uiso calc U P R 0.42(2) A 2
H H98D 0.583 0.5344 0.2017 0.273 Uiso calc U P R 0.42(2) A 2
C C99 0.0908(8) 0.4371(10) 0.3524(12) 0.260(8) Uani d U . . 1.0 . .
H H99A 0.0756 0.4651 0.3829 0.312 Uiso calc U . R 1.0 . .
H H99B 0.1188 0.4506 0.3681 0.312 Uiso calc U . R 1.0 . .
C C100 0.0873(7) 0.3710(10) 0.3759(12) 0.244(7) Uani d U . . 1.0 . .
H H10A 0.098 0.3668 0.4372 0.293 Uiso calc U . R 1.0 . .
H H10B 0.0591 0.3596 0.3649 0.293 Uiso calc U . R 1.0 . .
C C101 0.0891(7) 0.3392(9) 0.2501(12) 0.228(7) Uani d U . . 1.0 . .
H H10C 0.0607 0.3292 0.2408 0.274 Uiso calc U . R 1.0 . .
H H10D 0.1006 0.3095 0.2141 0.274 Uiso calc U . R 1.0 . .
C C102 0.0936(6) 0.4080(8) 0.2213(10) 0.201(6) Uani d U . . 1.0 . .
H H10E 0.1217 0.419 0.2257 0.241 Uiso calc U . R 1.0 . .
H H10F 0.0791 0.4144 0.1625 0.241 Uiso calc U . R 1.0 . .
F F1 0.49163(15) 0.4114(3) 0.3835(4) 0.132(2) Uani d . . . 1.0 . .
F F2 0.45249(17) 0.3652(4) 0.2712(4) 0.161(3) Uani d . . . 1.0 . .
F F3 0.42621(14) 0.4078(2) 0.3692(4) 0.1095(17) Uani d . . . 1.0 . .
F F4 0.42756(18) 0.3028(3) 0.3517(5) 0.151(3) Uani d . . . 1.0 . .
F F5 0.4663(2) 0.3457(4) 0.4665(5) 0.182(3) Uani d . . . 1.0 . .
F F6 0.49250(18) 0.3069(3) 0.3645(6) 0.177(3) Uani d . . . 1.0 . .
F F7 0.29243(14) 0.5114(3) 0.5914(4) 0.1216(19) Uani d . . . 1.0 . .
F F8 0.2711(2) 0.5135(3) 0.4537(4) 0.142(2) Uani d . . . 1.0 . .
F F9 0.24855(12) 0.5854(2) 0.5311(4) 0.121(2) Uani d . . . 1.0 . .
F F10 0.20767(14) 0.5087(2) 0.4689(4) 0.1157(18) Uani d . . . 1.0 . .
F F11 0.22910(17) 0.5050(3) 0.6041(4) 0.127(2) Uani d . . . 1.0 . .
F F12 0.25162(14) 0.4331(2) 0.5250(4) 0.1125(18) Uani d . . . 1.0 . .
F F13 0.06292(19) 0.3666(3) 0.5597(5) 0.146(2) Uani d . . . 1.0 . .
F F14 0.0047(2) 0.3930(3) 0.5819(6) 0.175(3) Uani d . . . 1.0 . .
F F15 -0.00345(15) 0.2958(3) 0.6299(4) 0.1214(19) Uani d . . . 1.0 . .
F F16 0.05289(16) 0.2665(3) 0.6000(6) 0.167(3) Uani d . . . 1.0 . .
F F17 0.0491(2) 0.3559(5) 0.6823(4) 0.198(4) Uani d . . . 1.0 . .
F F18 0.0077(2) 0.3080(4) 0.5046(4) 0.157(3) Uani d . . . 1.0 . .
N N1 0.11166(14) 0.6140(2) 0.5317(3) 0.0475(12) Uani d . . . 1.0 . .
N N2 0.07714(17) 0.5622(3) 0.6038(4) 0.0699(17) Uani d . . . 1.0 . .
N N3 0.17210(15) 1.1889(3) 0.5445(4) 0.0678(17) Uani d . . . 1.0 . .
N N4 0.17695(17) 1.2876(3) 0.5853(5) 0.094(2) Uani d . . . 1.0 . .
N N5 0.40739(15) 0.8571(2) 0.3391(3) 0.0552(14) Uani d . . . 1.0 . .
N N6 0.46655(16) 0.8278(3) 0.3536(4) 0.0733(17) Uani d . . . 1.0 . .
N N7 0.08040(14) 0.8524(2) 0.6998(3) 0.0519(13) Uani d . . . 1.0 . .
N N8 0.02050(15) 0.8206(3) 0.6824(4) 0.0654(15) Uani d . . . 1.0 . .
N N9 0.34199(13) 1.1919(2) 0.5910(4) 0.0542(14) Uani d . . . 1.0 . .
N N10 0.34035(15) 1.2884(2) 0.5411(4) 0.0633(16) Uani d . . . 1.0 . .
N N11 0.38381(15) 0.6232(2) 0.5247(3) 0.0479(12) Uani d . . . 1.0 . .
N N12 0.42353(15) 0.5767(3) 0.4600(3) 0.0583(14) Uani d . . . 1.0 . .
O O1 0.0645(2) 0.9068(4) 0.3761(5) 0.117(2) Uani d . . . 1.0 . .
O O2 0.0140(3) 0.9132(5) 0.4869(6) 0.170(4) Uani d . . . 1.0 . .
O O3 0.4075(2) 0.9289(4) 0.5784(6) 0.149(3) Uani d . . . 1.0 . .
O O4 0.4491(3) 1.0290(5) 0.5300(7) 0.183(4) Uani d . . . 1.0 . .
O O7 0.0782(5) 0.4438(6) 0.2741(9) 0.238(5) Uani d U . . 1.0 . .
O O8 0.1066(5) 0.3261(6) 0.3342(8) 0.231(5) Uani d U . . 1.0 . .
P P1 0.45988(6) 0.35724(12) 0.36893(16) 0.0859(7) Uani d . . . 1.0 . .
P P2 0.25003(6) 0.50877(9) 0.52851(15) 0.0744(6) Uani d . . . 1.0 . .
P P3 0.02975(6) 0.33144(12) 0.59327(15) 0.0773(6) Uani d . . . 1.0 . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
O5A C95 . 1.29(2) ?
O5A C98 . 1.57(3) ?
O6A C97 . 1.55(3) ?
O6A C96 . 1.78(4) ?
O5B C98 . 1.29(4) ?
O5B C95 . 1.64(4) ?
O6B C96 . 1.32(3) ?
O6B C97 . 1.44(4) ?
Ag1 C44 . 2.089(6) ?
Ag1 C1 . 2.094(7) ?
Ag2 C55 . 2.061(6) ?
Ag2 C12 . 2.080(7) ?
Ag3 C23 . 2.072(7) ?
Ag3 C66 . 2.079(6) ?
C1 N1 . 1.350(7) ?
C1 N2 . 1.351(8) ?
C2 C3 . 1.314(9) ?
C2 N1 . 1.355(8) ?
C2 H2 . 0.95 ?
C3 N2 . 1.366(9) ?
C3 H3 . 0.95 ?
C4 C5 . 1.403(13) ?
C4 N2 . 1.502(9) ?
C4 H4A . 0.99 ?
C4 H4B . 0.99 ?
C5 H5A . 0.98 ?
C5 H5B . 0.98 ?
C5 H5C . 0.98 ?
C6 C7 . 1.359(8) ?
C6 C11 . 1.383(8) ?
C6 N1 . 1.433(7) ?
C7 C8 . 1.376(8) ?
C7 H7 . 0.95 ?
C8 C9 . 1.405(8) ?
C8 H8 . 0.95 ?
C9 C10 . 1.378(8) ?
C9 C34 . 1.521(8) ?
C10 C11 . 1.384(8) ?
C10 H10 . 0.95 ?
C11 H11 . 0.95 ?
C12 N4 . 1.343(8) ?
C12 N3 . 1.364(8) ?
C13 C14 . 1.342(10) ?
C13 N3 . 1.373(8) ?
C13 H13 . 0.95 ?
C14 N4 . 1.391(9) ?
C14 H14 . 0.95 ?
C15 C16 . 1.323(13) ?
C15 N4 . 1.479(9) ?
C15 H15A . 0.99 ?
C15 H15B . 0.99 ?
C16 H16A . 0.98 ?
C16 H16B . 0.98 ?
C16 H16C . 0.98 ?
C17 C18 . 1.362(9) ?
C17 C22 . 1.388(9) ?
C17 N3 . 1.427(8) ?
C18 C19 . 1.373(9) ?
C18 H18 . 0.95 ?
C19 C20 . 1.376(8) ?
C19 H19 . 0.95 ?
C20 C21 . 1.409(8) ?
C20 C36 . 1.540(8) ?
C21 C22 . 1.404(8) ?
C21 H21 . 0.95 ?
C22 H22 . 0.95 ?
C23 N6 . 1.337(7) ?
C23 N5 . 1.341(8) ?
C24 C25 . 1.346(10) ?
C24 N5 . 1.389(8) ?
C24 H24 . 0.95 ?
C25 N6 . 1.356(9) ?
C25 H25 . 0.95 ?
C26 N6 . 1.503(10) ?
C26 C27 . 1.567(17) ?
C26 H26A . 0.99 ?
C26 H26B . 0.99 ?
C27 H27A . 0.98 ?
C27 H27B . 0.98 ?
C27 H27C . 0.98 ?
C28 C33 . 1.356(9) ?
C28 C29 . 1.408(8) ?
C28 N5 . 1.439(7) ?
C29 C30 . 1.373(8) ?
C29 H29 . 0.95 ?
C30 C31 . 1.390(8) ?
C30 H30 . 0.95 ?
C31 C32 . 1.396(8) ?
C31 C38 . 1.535(8) ?
C32 C33 . 1.380(8) ?
C32 H32 . 0.95 ?
C33 H33 . 0.95 ?
C34 C39 . 1.547(7) ?
C34 C35 . 1.547(7) ?
C34 C40 . 1.556(8) ?
C35 C36 . 1.540(8) ?
C35 H35A . 0.99 ?
C35 H35B . 0.99 ?
C36 C41 . 1.527(8) ?
C36 C37 . 1.545(7) ?
C37 C38 . 1.543(8) ?
C37 H37A . 0.99 ?
C37 H37B . 0.99 ?
C38 C42 . 1.549(8) ?
C38 C39 . 1.557(8) ?
C39 H39A . 0.99 ?
C39 H39B . 0.99 ?
C40 C43 . 1.501(8) ?
C40 H40A . 0.99 ?
C40 H40B . 0.99 ?
C41 C43 . 1.539(9) ?
C41 H41A . 0.99 ?
C41 H41B . 0.99 ?
C42 C43 . 1.534(8) ?
C42 H42A . 0.99 ?
C42 H42B . 0.99 ?
C43 H43 . 1.0 ?
C44 N8 . 1.337(8) ?
C44 N7 . 1.376(8) ?
C45 C46 . 1.335(9) ?
C45 N7 . 1.386(8) ?
C45 H45 . 0.95 ?
C46 N8 . 1.366(9) ?
C46 H46 . 0.95 ?
C47 N8 . 1.460(8) ?
C47 C48 . 1.488(13) ?
C47 H47A . 0.99 ?
C47 H47B . 0.99 ?
C48 H48A . 0.98 ?
C48 H48B . 0.98 ?
C48 H48C . 0.98 ?
C49 C50 . 1.374(9) ?
C49 C54 . 1.394(8) ?
C49 N7 . 1.437(7) ?
C50 C51 . 1.387(9) ?
C50 H50 . 0.95 ?
C51 C52 . 1.376(8) ?
C51 H51 . 0.95 ?
C52 C53 . 1.400(8) ?
C52 C77 . 1.532(8) ?
C53 C54 . 1.372(8) ?
C53 H53 . 0.95 ?
C54 H54 . 0.95 ?
C55 N10 . 1.356(7) ?
C55 N9 . 1.378(8) ?
C56 C57 . 1.339(10) ?
C56 N9 . 1.376(8) ?
C56 H56 . 0.95 ?
C57 N10 . 1.376(8) ?
C57 H57 . 0.95 ?
C58 C59 . 1.440(12) ?
C58 N10 . 1.472(8) ?
C58 H58A . 0.99 ?
C58 H58B . 0.99 ?
C59 H59A . 0.98 ?
C59 H59B . 0.98 ?
C59 H59C . 0.98 ?
C60 C65 . 1.372(8) ?
C60 C61 . 1.387(9) ?
C60 N9 . 1.425(7) ?
C61 C62 . 1.397(8) ?
C61 H61 . 0.95 ?
C62 C63 . 1.389(8) ?
C62 H62 . 0.95 ?
C63 C64 . 1.394(8) ?
C63 C79 . 1.536(8) ?
C64 C65 . 1.371(8) ?
C64 H64 . 0.95 ?
C65 H65 . 0.95 ?
C66 N12 . 1.337(8) ?
C66 N11 . 1.352(7) ?
C67 C68 . 1.308(9) ?
C67 N11 . 1.368(8) ?
C67 H67 . 0.95 ?
C68 N12 . 1.380(8) ?
C68 H68 . 0.95 ?
C69 C70 . 1.439(10) ?
C69 N12 . 1.478(8) ?
C69 H69A . 0.99 ?
C69 H69B . 0.99 ?
C70 H70A . 0.98 ?
C70 H70B . 0.98 ?
C70 H70C . 0.98 ?
C71 C76 . 1.403(8) ?
C71 C72 . 1.408(8) ?
C71 N11 . 1.408(7) ?
C72 C73 . 1.391(8) ?
C72 H72 . 0.95 ?
C73 C74 . 1.387(9) ?
C73 H73 . 0.95 ?
C74 C75 . 1.394(8) ?
C74 C81 . 1.524(8) ?
C75 C76 . 1.388(8) ?
C75 H75 . 0.95 ?
C76 H76 . 0.95 ?
C77 C83 . 1.519(8) ?
C77 C78 . 1.539(8) ?
C77 C82 . 1.541(8) ?
C78 C79 . 1.564(8) ?
C78 H78A . 0.99 ?
C78 H78B . 0.99 ?
C79 C80 . 1.524(8) ?
C79 C84 . 1.528(8) ?
C80 C81 . 1.542(8) ?
C80 H80A . 0.99 ?
C80 H80B . 0.99 ?
C81 C82 . 1.536(8) ?
C81 C85 . 1.555(8) ?
C82 H82A . 0.99 ?
C82 H82B . 0.99 ?
C83 C86 . 1.538(8) ?
C83 H83A . 0.99 ?
C83 H83B . 0.99 ?
C84 C86 . 1.510(8) ?
C84 H84A . 0.99 ?
C84 H84B . 0.99 ?
C85 C86 . 1.512(8) ?
C85 H85A . 0.99 ?
C85 H85B . 0.99 ?
C86 H86 . 1.0 ?
C87 O1 . 1.399(13) ?
C87 C88 . 1.427(17) ?
C87 H87A . 0.99 ?
C87 H87B . 0.99 ?
C88 O2 . 1.497(15) ?
C88 H88A . 0.99 ?
C88 H88B . 0.99 ?
C89 O2 . 1.389(12) ?
C89 C90 . 1.391(14) ?
C89 H89A . 0.99 ?
C89 H89B . 0.99 ?
C90 O1 . 1.434(12) ?
C90 H90A . 0.99 ?
C90 H90B . 0.99 ?
C91 C92 . 1.403(18) ?
C91 O3 . 1.437(13) ?
C91 H91A . 0.99 ?
C91 H91B . 0.99 ?
C92 O4 . 1.344(13) ?
C92 H92A . 0.99 ?
C92 H92B . 0.99 ?
C93 C94 . 1.327(19) ?
C93 O4 . 1.399(17) ?
C93 H93A . 0.99 ?
C93 H93B . 0.99 ?
C94 O3 . 1.329(13) ?
C94 H94A . 0.99 ?
C94 H94B . 0.99 ?
C95 C96 . 1.367(19) ?
C95 H95A . 0.99 ?
C95 H95B . 0.99 ?
C95 H95C . 0.99 ?
C95 H95D . 0.99 ?
C96 H96A . 0.99 ?
C96 H96B . 0.99 ?
C96 H96C . 0.99 ?
C96 H96D . 0.99 ?
C97 C98 . 1.31(2) ?
C97 H97A . 0.99 ?
C97 H97B . 0.99 ?
C97 H97C . 0.99 ?
C97 H97D . 0.99 ?
C98 H98A . 0.99 ?
C98 H98B . 0.99 ?
C98 H98C . 0.99 ?
C98 H98D . 0.99 ?
C99 O7 . 1.26(2) ?
C99 C100 . 1.43(2) ?
C99 H99A . 0.99 ?
C99 H99B . 0.99 ?
C100 O8 . 1.40(2) ?
C100 H10A . 0.99 ?
C100 H10B . 0.99 ?
C101 O8 . 1.40(2) ?
C101 C102 . 1.52(2) ?
C101 H10C . 0.99 ?
C101 H10D . 0.99 ?
C102 O7 . 1.334(15) ?
C102 H10E . 0.99 ?
C102 H10F . 0.99 ?
F1 P1 . 1.553(6) ?
F2 P1 . 1.566(6) ?
F3 P1 . 1.571(5) ?
F4 P1 . 1.572(6) ?
F5 P1 . 1.575(8) ?
F6 P1 . 1.552(6) ?
F7 P2 . 1.603(6) ?
F8 P2 . 1.559(5) ?
F9 P2 . 1.584(5) ?
F10 P2 . 1.578(5) ?
F11 P2 . 1.565(5) ?
F12 P2 . 1.564(5) ?
F13 P3 . 1.560(5) ?
F14 P3 . 1.530(6) ?
F15 P3 . 1.593(5) ?
F16 P3 . 1.555(6) ?
F17 P3 . 1.544(6) ?
F18 P3 . 1.557(6) ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C95 O5A C98 . . 99.(2) ?
C97 O6A C96 . . 87.(2) ?
C98 O5B C95 . . 95.(3) ?
C96 O6B C97 . . 113.(3) ?
C44 Ag1 C1 . . 178.8(2) ?
C55 Ag2 C12 . . 175.4(3) ?
C23 Ag3 C66 . . 174.9(3) ?
N1 C1 N2 . . 104.9(6) ?
N1 C1 Ag1 . . 126.3(5) ?
N2 C1 Ag1 . . 128.5(5) ?
C3 C2 N1 . . 107.8(6) ?
C3 C2 H2 . . 126.1 ?
N1 C2 H2 . . 126.1 ?
C2 C3 N2 . . 107.6(6) ?
C2 C3 H3 . . 126.2 ?
N2 C3 H3 . . 126.2 ?
C5 C4 N2 . . 107.0(9) ?
C5 C4 H4A . . 110.3 ?
N2 C4 H4A . . 110.3 ?
C5 C4 H4B . . 110.3 ?
N2 C4 H4B . . 110.3 ?
H4A C4 H4B . . 108.6 ?
C4 C5 H5A . . 109.5 ?
C4 C5 H5B . . 109.5 ?
H5A C5 H5B . . 109.5 ?
C4 C5 H5C . . 109.5 ?
H5A C5 H5C . . 109.5 ?
H5B C5 H5C . . 109.5 ?
C7 C6 C11 . . 120.3(5) ?
C7 C6 N1 . . 120.1(5) ?
C11 C6 N1 . . 119.5(5) ?
C6 C7 C8 . . 119.4(6) ?
C6 C7 H7 . . 120.3 ?
C8 C7 H7 . . 120.3 ?
C7 C8 C9 . . 122.6(6) ?
C7 C8 H8 . . 118.7 ?
C9 C8 H8 . . 118.7 ?
C10 C9 C8 . . 115.8(5) ?
C10 C9 C34 . . 125.0(5) ?
C8 C9 C34 . . 119.2(5) ?
C9 C10 C11 . . 122.5(5) ?
C9 C10 H10 . . 118.8 ?
C11 C10 H10 . . 118.8 ?
C6 C11 C10 . . 119.3(5) ?
C6 C11 H11 . . 120.4 ?
C10 C11 H11 . . 120.4 ?
N4 C12 N3 . . 104.3(6) ?
N4 C12 Ag2 . . 127.1(5) ?
N3 C12 Ag2 . . 128.2(5) ?
C14 C13 N3 . . 107.4(6) ?
C14 C13 H13 . . 126.3 ?
N3 C13 H13 . . 126.3 ?
C13 C14 N4 . . 106.1(6) ?
C13 C14 H14 . . 126.9 ?
N4 C14 H14 . . 126.9 ?
C16 C15 N4 . . 115.2(10) ?
C16 C15 H15A . . 108.5 ?
N4 C15 H15A . . 108.5 ?
C16 C15 H15B . . 108.5 ?
N4 C15 H15B . . 108.5 ?
H15A C15 H15B . . 107.5 ?
C15 C16 H16A . . 109.5 ?
C15 C16 H16B . . 109.5 ?
H16A C16 H16B . . 109.5 ?
C15 C16 H16C . . 109.5 ?
H16A C16 H16C . . 109.5 ?
H16B C16 H16C . . 109.5 ?
C18 C17 C22 . . 120.3(6) ?
C18 C17 N3 . . 120.4(6) ?
C22 C17 N3 . . 119.4(6) ?
C17 C18 C19 . . 120.1(6) ?
C17 C18 H18 . . 120.0 ?
C19 C18 H18 . . 120.0 ?
C18 C19 C20 . . 122.3(6) ?
C18 C19 H19 . . 118.9 ?
C20 C19 H19 . . 118.9 ?
C19 C20 C21 . . 117.7(6) ?
C19 C20 C36 . . 119.8(5) ?
C21 C20 C36 . . 122.5(5) ?
C22 C21 C20 . . 119.8(6) ?
C22 C21 H21 . . 120.1 ?
C20 C21 H21 . . 120.1 ?
C17 C22 C21 . . 119.6(6) ?
C17 C22 H22 . . 120.2 ?
C21 C22 H22 . . 120.2 ?
N6 C23 N5 . . 104.0(6) ?
N6 C23 Ag3 . . 125.2(5) ?
N5 C23 Ag3 . . 130.6(4) ?
C25 C24 N5 . . 104.7(7) ?
C25 C24 H24 . . 127.6 ?
N5 C24 H24 . . 127.6 ?
C24 C25 N6 . . 107.5(7) ?
C24 C25 H25 . . 126.2 ?
N6 C25 H25 . . 126.2 ?
N6 C26 C27 . . 106.7(9) ?
N6 C26 H26A . . 110.4 ?
C27 C26 H26A . . 110.4 ?
N6 C26 H26B . . 110.4 ?
C27 C26 H26B . . 110.4 ?
H26A C26 H26B . . 108.6 ?
C26 C27 H27A . . 109.5 ?
C26 C27 H27B . . 109.5 ?
H27A C27 H27B . . 109.5 ?
C26 C27 H27C . . 109.5 ?
H27A C27 H27C . . 109.5 ?
H27B C27 H27C . . 109.5 ?
C33 C28 C29 . . 118.2(5) ?
C33 C28 N5 . . 120.2(6) ?
C29 C28 N5 . . 121.5(6) ?
C30 C29 C28 . . 120.1(6) ?
C30 C29 H29 . . 119.9 ?
C28 C29 H29 . . 119.9 ?
C29 C30 C31 . . 121.6(5) ?
C29 C30 H30 . . 119.2 ?
C31 C30 H30 . . 119.2 ?
C30 C31 C32 . . 117.6(5) ?
C30 C31 C38 . . 121.6(5) ?
C32 C31 C38 . . 120.6(5) ?
C33 C32 C31 . . 120.3(6) ?
C33 C32 H32 . . 119.8 ?
C31 C32 H32 . . 119.8 ?
C28 C33 C32 . . 122.1(6) ?
C28 C33 H33 . . 118.9 ?
C32 C33 H33 . . 118.9 ?
C9 C34 C39 . . 112.6(5) ?
C9 C34 C35 . . 110.2(4) ?
C39 C34 C35 . . 107.2(4) ?
C9 C34 C40 . . 109.9(4) ?
C39 C34 C40 . . 107.7(5) ?
C35 C34 C40 . . 109.1(5) ?
C36 C35 C34 . . 112.5(4) ?
C36 C35 H35A . . 109.1 ?
C34 C35 H35A . . 109.1 ?
C36 C35 H35B . . 109.1 ?
C34 C35 H35B . . 109.1 ?
H35A C35 H35B . . 107.8 ?
C41 C36 C20 . . 109.0(5) ?
C41 C36 C35 . . 107.8(5) ?
C20 C36 C35 . . 113.1(4) ?
C41 C36 C37 . . 109.3(5) ?
C20 C36 C37 . . 109.6(4) ?
C35 C36 C37 . . 107.9(4) ?
C38 C37 C36 . . 111.4(4) ?
C38 C37 H37A . . 109.3 ?
C36 C37 H37A . . 109.3 ?
C38 C37 H37B . . 109.3 ?
C36 C37 H37B . . 109.3 ?
H37A C37 H37B . . 108.0 ?
C31 C38 C37 . . 108.1(4) ?
C31 C38 C42 . . 112.1(4) ?
C37 C38 C42 . . 108.1(5) ?
C31 C38 C39 . . 112.4(5) ?
C37 C38 C39 . . 108.4(4) ?
C42 C38 C39 . . 107.6(5) ?
C34 C39 C38 . . 112.0(4) ?
C34 C39 H39A . . 109.2 ?
C38 C39 H39A . . 109.2 ?
C34 C39 H39B . . 109.2 ?
C38 C39 H39B . . 109.2 ?
H39A C39 H39B . . 107.9 ?
C43 C40 C34 . . 110.0(5) ?
C43 C40 H40A . . 109.7 ?
C34 C40 H40A . . 109.7 ?
C43 C40 H40B . . 109.7 ?
C34 C40 H40B . . 109.7 ?
H40A C40 H40B . . 108.2 ?
C36 C41 C43 . . 110.8(5) ?
C36 C41 H41A . . 109.5 ?
C43 C41 H41A . . 109.5 ?
C36 C41 H41B . . 109.5 ?
C43 C41 H41B . . 109.5 ?
H41A C41 H41B . . 108.1 ?
C43 C42 C38 . . 110.7(5) ?
C43 C42 H42A . . 109.5 ?
C38 C42 H42A . . 109.5 ?
C43 C42 H42B . . 109.5 ?
C38 C42 H42B . . 109.5 ?
H42A C42 H42B . . 108.1 ?
C40 C43 C42 . . 110.5(5) ?
C40 C43 C41 . . 110.9(5) ?
C42 C43 C41 . . 108.3(5) ?
C40 C43 H43 . . 109.0 ?
C42 C43 H43 . . 109.0 ?
C41 C43 H43 . . 109.0 ?
N8 C44 N7 . . 104.4(5) ?
N8 C44 Ag1 . . 127.9(5) ?
N7 C44 Ag1 . . 127.7(5) ?
C46 C45 N7 . . 104.9(6) ?
C46 C45 H45 . . 127.6 ?
N7 C45 H45 . . 127.6 ?
C45 C46 N8 . . 109.3(6) ?
C45 C46 H46 . . 125.3 ?
N8 C46 H46 . . 125.3 ?
N8 C47 C48 . . 111.6(7) ?
N8 C47 H47A . . 109.3 ?
C48 C47 H47A . . 109.3 ?
N8 C47 H47B . . 109.3 ?
C48 C47 H47B . . 109.3 ?
H47A C47 H47B . . 108.0 ?
C47 C48 H48A . . 109.5 ?
C47 C48 H48B . . 109.5 ?
H48A C48 H48B . . 109.5 ?
C47 C48 H48C . . 109.5 ?
H48A C48 H48C . . 109.5 ?
H48B C48 H48C . . 109.5 ?
C50 C49 C54 . . 119.9(6) ?
C50 C49 N7 . . 118.9(5) ?
C54 C49 N7 . . 121.2(5) ?
C49 C50 C51 . . 119.2(6) ?
C49 C50 H50 . . 120.4 ?
C51 C50 H50 . . 120.4 ?
C52 C51 C50 . . 123.3(6) ?
C52 C51 H51 . . 118.3 ?
C50 C51 H51 . . 118.3 ?
C51 C52 C53 . . 115.4(6) ?
C51 C52 C77 . . 120.4(5) ?
C53 C52 C77 . . 124.2(5) ?
C54 C53 C52 . . 123.3(6) ?
C54 C53 H53 . . 118.4 ?
C52 C53 H53 . . 118.4 ?
C53 C54 C49 . . 118.9(6) ?
C53 C54 H54 . . 120.6 ?
C49 C54 H54 . . 120.6 ?
N10 C55 N9 . . 103.5(5) ?
N10 C55 Ag2 . . 130.4(4) ?
N9 C55 Ag2 . . 125.7(4) ?
C57 C56 N9 . . 107.3(6) ?
C57 C56 H56 . . 126.3 ?
N9 C56 H56 . . 126.3 ?
C56 C57 N10 . . 106.8(6) ?
C56 C57 H57 . . 126.6 ?
N10 C57 H57 . . 126.6 ?
C59 C58 N10 . . 110.9(7) ?
C59 C58 H58A . . 109.5 ?
N10 C58 H58A . . 109.5 ?
C59 C58 H58B . . 109.5 ?
N10 C58 H58B . . 109.5 ?
H58A C58 H58B . . 108.0 ?
C58 C59 H59A . . 109.5 ?
C58 C59 H59B . . 109.5 ?
H59A C59 H59B . . 109.5 ?
C58 C59 H59C . . 109.5 ?
H59A C59 H59C . . 109.5 ?
H59B C59 H59C . . 109.5 ?
C65 C60 C61 . . 120.6(5) ?
C65 C60 N9 . . 120.8(6) ?
C61 C60 N9 . . 118.5(5) ?
C60 C61 C62 . . 119.3(6) ?
C60 C61 H61 . . 120.3 ?
C62 C61 H61 . . 120.3 ?
C63 C62 C61 . . 121.3(6) ?
C63 C62 H62 . . 119.4 ?
C61 C62 H62 . . 119.4 ?
C62 C63 C64 . . 116.6(5) ?
C62 C63 C79 . . 121.5(5) ?
C64 C63 C79 . . 121.8(5) ?
C65 C64 C63 . . 123.3(6) ?
C65 C64 H64 . . 118.3 ?
C63 C64 H64 . . 118.3 ?
C64 C65 C60 . . 118.8(6) ?
C64 C65 H65 . . 120.6 ?
C60 C65 H65 . . 120.6 ?
N12 C66 N11 . . 105.5(6) ?
N12 C66 Ag3 . . 127.3(5) ?
N11 C66 Ag3 . . 126.4(4) ?
C68 C67 N11 . . 106.7(6) ?
C68 C67 H67 . . 126.6 ?
N11 C67 H67 . . 126.6 ?
C67 C68 N12 . . 108.5(6) ?
C67 C68 H68 . . 125.7 ?
N12 C68 H68 . . 125.7 ?
C70 C69 N12 . . 113.4(6) ?
C70 C69 H69A . . 108.9 ?
N12 C69 H69A . . 108.9 ?
C70 C69 H69B . . 108.9 ?
N12 C69 H69B . . 108.9 ?
H69A C69 H69B . . 107.7 ?
C69 C70 H70A . . 109.5 ?
C69 C70 H70B . . 109.5 ?
H70A C70 H70B . . 109.5 ?
C69 C70 H70C . . 109.5 ?
H70A C70 H70C . . 109.5 ?
H70B C70 H70C . . 109.5 ?
C76 C71 C72 . . 117.7(6) ?
C76 C71 N11 . . 121.7(5) ?
C72 C71 N11 . . 120.5(5) ?
C73 C72 C71 . . 119.9(6) ?
C73 C72 H72 . . 120.0 ?
C71 C72 H72 . . 120.0 ?
C74 C73 C72 . . 122.3(6) ?
C74 C73 H73 . . 118.8 ?
C72 C73 H73 . . 118.8 ?
C73 C74 C75 . . 117.7(6) ?
C73 C74 C81 . . 118.9(5) ?
C75 C74 C81 . . 123.0(5) ?
C76 C75 C74 . . 121.0(5) ?
C76 C75 H75 . . 119.5 ?
C74 C75 H75 . . 119.5 ?
C75 C76 C71 . . 121.3(5) ?
C75 C76 H76 . . 119.3 ?
C71 C76 H76 . . 119.3 ?
C83 C77 C52 . . 110.3(5) ?
C83 C77 C78 . . 108.6(5) ?
C52 C77 C78 . . 107.8(5) ?
C83 C77 C82 . . 108.5(5) ?
C52 C77 C82 . . 113.1(5) ?
C78 C77 C82 . . 108.5(4) ?
C77 C78 C79 . . 110.5(5) ?
C77 C78 H78A . . 109.5 ?
C79 C78 H78A . . 109.5 ?
C77 C78 H78B . . 109.5 ?
C79 C78 H78B . . 109.5 ?
H78A C78 H78B . . 108.1 ?
C80 C79 C84 . . 108.9(5) ?
C80 C79 C63 . . 109.5(4) ?
C84 C79 C63 . . 111.7(4) ?
C80 C79 C78 . . 108.6(4) ?
C84 C79 C78 . . 107.8(4) ?
C63 C79 C78 . . 110.2(5) ?
C79 C80 C81 . . 111.9(4) ?
C79 C80 H80A . . 109.2 ?
C81 C80 H80A . . 109.2 ?
C79 C80 H80B . . 109.2 ?
C81 C80 H80B . . 109.2 ?
H80A C80 H80B . . 107.9 ?
C74 C81 C82 . . 113.9(5) ?
C74 C81 C80 . . 111.3(4) ?
C82 C81 C80 . . 108.0(5) ?
C74 C81 C85 . . 107.2(5) ?
C82 C81 C85 . . 107.7(4) ?
C80 C81 C85 . . 108.5(4) ?
C81 C82 C77 . . 112.1(5) ?
C81 C82 H82A . . 109.2 ?
C77 C82 H82A . . 109.2 ?
C81 C82 H82B . . 109.2 ?
C77 C82 H82B . . 109.2 ?
H82A C82 H82B . . 107.9 ?
C77 C83 C86 . . 110.4(5) ?
C77 C83 H83A . . 109.6 ?
C86 C83 H83A . . 109.6 ?
C77 C83 H83B . . 109.6 ?
C86 C83 H83B . . 109.6 ?
H83A C83 H83B . . 108.1 ?
C86 C84 C79 . . 110.8(5) ?
C86 C84 H84A . . 109.5 ?
C79 C84 H84A . . 109.5 ?
C86 C84 H84B . . 109.5 ?
C79 C84 H84B . . 109.5 ?
H84A C84 H84B . . 108.1 ?
C86 C85 C81 . . 109.9(5) ?
C86 C85 H85A . . 109.7 ?
C81 C85 H85A . . 109.7 ?
C86 C85 H85B . . 109.7 ?
C81 C85 H85B . . 109.7 ?
H85A C85 H85B . . 108.2 ?
C84 C86 C85 . . 110.7(5) ?
C84 C86 C83 . . 109.5(5) ?
C85 C86 C83 . . 109.4(5) ?
C84 C86 H86 . . 109.1 ?
C85 C86 H86 . . 109.1 ?
C83 C86 H86 . . 109.1 ?
O1 C87 C88 . . 110.7(10) ?
O1 C87 H87A . . 109.5 ?
C88 C87 H87A . . 109.5 ?
O1 C87 H87B . . 109.5 ?
C88 C87 H87B . . 109.5 ?
H87A C87 H87B . . 108.1 ?
C87 C88 O2 . . 111.1(12) ?
C87 C88 H88A . . 109.4 ?
O2 C88 H88A . . 109.4 ?
C87 C88 H88B . . 109.4 ?
O2 C88 H88B . . 109.4 ?
H88A C88 H88B . . 108.0 ?
O2 C89 C90 . . 111.1(10) ?
O2 C89 H89A . . 109.4 ?
C90 C89 H89A . . 109.4 ?
O2 C89 H89B . . 109.4 ?
C90 C89 H89B . . 109.4 ?
H89A C89 H89B . . 108.0 ?
C89 C90 O1 . . 111.1(11) ?
C89 C90 H90A . . 109.4 ?
O1 C90 H90A . . 109.4 ?
C89 C90 H90B . . 109.4 ?
O1 C90 H90B . . 109.4 ?
H90A C90 H90B . . 108.0 ?
C92 C91 O3 . . 110.7(13) ?
C92 C91 H91A . . 109.5 ?
O3 C91 H91A . . 109.5 ?
C92 C91 H91B . . 109.5 ?
O3 C91 H91B . . 109.5 ?
H91A C91 H91B . . 108.1 ?
O4 C92 C91 . . 115.5(14) ?
O4 C92 H92A . . 108.4 ?
C91 C92 H92A . . 108.4 ?
O4 C92 H92B . . 108.4 ?
C91 C92 H92B . . 108.4 ?
H92A C92 H92B . . 107.5 ?
C94 C93 O4 . . 122.3(16) ?
C94 C93 H93A . . 106.8 ?
O4 C93 H93A . . 106.8 ?
C94 C93 H93B . . 106.8 ?
O4 C93 H93B . . 106.8 ?
H93A C93 H93B . . 106.6 ?
C93 C94 O3 . . 116.0(15) ?
C93 C94 H94A . . 108.3 ?
O3 C94 H94A . . 108.3 ?
C93 C94 H94B . . 108.3 ?
O3 C94 H94B . . 108.3 ?
H94A C94 H94B . . 107.4 ?
O5A C95 C96 . . 117.(2) ?
C96 C95 O5B . . 109.9(19) ?
O5A C95 H95A . . 107.9 ?
C96 C95 H95A . . 107.9 ?
O5A C95 H95B . . 107.9 ?
C96 C95 H95B . . 107.9 ?
H95A C95 H95B . . 107.2 ?
C96 C95 H95C . . 109.7 ?
O5B C95 H95C . . 109.7 ?
C96 C95 H95D . . 109.7 ?
O5B C95 H95D . . 109.7 ?
H95C C95 H95D . . 108.2 ?
O6B C96 C95 . . 121.(2) ?
C95 C96 O6A . . 106.(2) ?
C95 C96 H96A . . 110.6 ?
O6A C96 H96A . . 110.6 ?
C95 C96 H96B . . 110.6 ?
O6A C96 H96B . . 110.6 ?
H96A C96 H96B . . 108.7 ?
O6B C96 H96C . . 107.1 ?
C95 C96 H96C . . 107.1 ?
O6B C96 H96D . . 107.1 ?
C95 C96 H96D . . 107.1 ?
H96C C96 H96D . . 106.8 ?
C98 C97 O6B . . 118.(2) ?
C98 C97 O6A . . 111.(2) ?
C98 C97 H97A . . 109.5 ?
O6A C97 H97A . . 109.5 ?
C98 C97 H97B . . 109.5 ?
O6A C97 H97B . . 109.4 ?
H97A C97 H97B . . 108.0 ?
C98 C97 H97C . . 107.9 ?
O6B C97 H97C . . 107.9 ?
C98 C97 H97D . . 107.9 ?
O6B C97 H97D . . 107.9 ?
H97C C97 H97D . . 107.2 ?
O5B C98 C97 . . 115.(3) ?
C97 C98 O5A . . 116.(2) ?
C97 C98 H98A . . 108.3 ?
O5A C98 H98A . . 108.3 ?
C97 C98 H98B . . 108.3 ?
O5A C98 H98B . . 108.3 ?
H98A C98 H98B . . 107.4 ?
O5B C98 H98C . . 108.6 ?
C97 C98 H98C . . 108.6 ?
O5B C98 H98D . . 108.6 ?
C97 C98 H98D . . 108.6 ?
H98C C98 H98D . . 107.6 ?
O7 C99 C100 . . 110.2(15) ?
O7 C99 H99A . . 109.6 ?
C100 C99 H99A . . 109.6 ?
O7 C99 H99B . . 109.6 ?
C100 C99 H99B . . 109.6 ?
H99A C99 H99B . . 108.1 ?
O8 C100 C99 . . 114.9(17) ?
O8 C100 H10A . . 108.5 ?
C99 C100 H10A . . 108.5 ?
O8 C100 H10B . . 108.5 ?
C99 C100 H10B . . 108.5 ?
H10A C100 H10B . . 107.5 ?
O8 C101 C102 . . 115.5(16) ?
O8 C101 H10C . . 108.4 ?
C102 C101 H10C . . 108.4 ?
O8 C101 H10D . . 108.4 ?
C102 C101 H10D . . 108.4 ?
H10C C101 H10D . . 107.5 ?
O7 C102 C101 . . 103.7(13) ?
O7 C102 H10E . . 111.0 ?
C101 C102 H10E . . 111.0 ?
O7 C102 H10F . . 111.0 ?
C101 C102 H10F . . 111.0 ?
H10E C102 H10F . . 109.0 ?
C1 N1 C2 . . 110.0(6) ?
C1 N1 C6 . . 124.4(5) ?
C2 N1 C6 . . 125.6(5) ?
C1 N2 C3 . . 109.6(6) ?
C1 N2 C4 . . 125.2(6) ?
C3 N2 C4 . . 124.8(6) ?
C12 N3 C13 . . 110.8(6) ?
C12 N3 C17 . . 125.6(5) ?
C13 N3 C17 . . 123.4(6) ?
C12 N4 C14 . . 111.4(6) ?
C12 N4 C15 . . 125.3(6) ?
C14 N4 C15 . . 123.3(6) ?
C23 N5 C24 . . 111.8(5) ?
C23 N5 C28 . . 125.7(5) ?
C24 N5 C28 . . 122.4(6) ?
C23 N6 C25 . . 111.9(6) ?
C23 N6 C26 . . 124.4(6) ?
C25 N6 C26 . . 123.6(6) ?
C44 N7 C45 . . 110.9(5) ?
C44 N7 C49 . . 126.8(5) ?
C45 N7 C49 . . 122.3(5) ?
C44 N8 C46 . . 110.4(6) ?
C44 N8 C47 . . 123.7(6) ?
C46 N8 C47 . . 125.9(6) ?
C56 N9 C55 . . 110.6(5) ?
C56 N9 C60 . . 123.9(5) ?
C55 N9 C60 . . 125.4(5) ?
C55 N10 C57 . . 111.7(5) ?
C55 N10 C58 . . 123.9(5) ?
C57 N10 C58 . . 124.3(6) ?
C66 N11 C67 . . 110.2(5) ?
C66 N11 C71 . . 122.8(5) ?
C67 N11 C71 . . 127.0(6) ?
C66 N12 C68 . . 109.0(6) ?
C66 N12 C69 . . 124.5(6) ?
C68 N12 C69 . . 126.5(6) ?
C87 O1 C90 . . 107.3(8) ?
C89 O2 C88 . . 106.9(10) ?
C94 O3 C91 . . 116.2(10) ?
C92 O4 C93 . . 109.7(12) ?
C99 O7 C102 . . 119.3(19) ?
C101 O8 C100 . . 101.3(17) ?
F6 P1 F1 . . 89.2(4) ?
F6 P1 F2 . . 89.0(4) ?
F1 P1 F2 . . 91.9(4) ?
F6 P1 F3 . . 177.5(4) ?
F1 P1 F3 . . 91.6(3) ?
F2 P1 F3 . . 88.7(3) ?
F6 P1 F4 . . 90.9(4) ?
F1 P1 F4 . . 178.6(5) ?
F2 P1 F4 . . 86.7(4) ?
F3 P1 F4 . . 88.3(3) ?
F6 P1 F5 . . 90.1(5) ?
F1 P1 F5 . . 90.9(4) ?
F2 P1 F5 . . 177.1(5) ?
F3 P1 F5 . . 92.2(4) ?
F4 P1 F5 . . 90.6(4) ?
F8 P2 F12 . . 90.5(3) ?
F8 P2 F11 . . 179.2(4) ?
F12 P2 F11 . . 90.3(3) ?
F8 P2 F10 . . 93.2(4) ?
F12 P2 F10 . . 90.7(3) ?
F11 P2 F10 . . 87.2(3) ?
F8 P2 F9 . . 88.9(3) ?
F12 P2 F9 . . 179.4(4) ?
F11 P2 F9 . . 90.3(3) ?
F10 P2 F9 . . 89.2(3) ?
F8 P2 F7 . . 88.5(4) ?
F12 P2 F7 . . 91.3(3) ?
F11 P2 F7 . . 91.2(4) ?
F10 P2 F7 . . 177.4(3) ?
F9 P2 F7 . . 88.8(3) ?
F14 P3 F17 . . 87.9(5) ?
F14 P3 F16 . . 175.9(5) ?
F17 P3 F16 . . 95.9(5) ?
F14 P3 F18 . . 89.7(4) ?
F17 P3 F18 . . 176.5(5) ?
F16 P3 F18 . . 86.5(5) ?
F14 P3 F13 . . 91.1(4) ?
F17 P3 F13 . . 88.4(4) ?
F16 P3 F13 . . 90.8(3) ?
F18 P3 F13 . . 94.1(4) ?
F14 P3 F15 . . 89.2(4) ?
F17 P3 F15 . . 90.1(3) ?
F16 P3 F15 . . 89.0(3) ?
F18 P3 F15 . . 87.4(4) ?
F13 P3 F15 . . 178.5(4) ?


# SQUEEZE RESULTS (Version =  11015)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.745 0.721 0.196 337 99 ' '
2 0.255 0.221 0.303 337 99 ' '
3 0.455 0.714 0.230 12 1 ' '
4 0.545 0.214 0.270 12 1 ' '
5 0.745 0.779 0.696 337 99 ' '
6 0.255 0.279 0.803 337 99 ' '
7 0.455 0.786 0.730 12 1 ' '
8 0.545 0.286 0.770 12 1 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          
;
The unit cell contains eight molecules of 1,4-dioxane which have 44 electrons 
and have been treated as a diffuse contribution to the overall scattering 
without specific atom positions by SQUEEZE/PLATON.
;


####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p21c
_database_code_depnum_ccdc_archive 'CCDC 1420799'
_audit_update_record             
;
2015-08-27 deposited with the CCDC.
2015-12-04 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C16 H16 Ag0.40 F2.40 N1.73 O0.53 P0.40'
_chemical_formula_weight         342.24

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   19.0224(7)
_cell_length_b                   15.7764(7)
_cell_length_c                   38.4287(15)
_cell_angle_alpha                90
_cell_angle_beta                 102.187(2)
_cell_angle_gamma                90
_cell_volume                     11272.7(8)
_cell_formula_units_Z            30
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9845
_cell_measurement_theta_min      2.9704
_cell_measurement_theta_max      65.0895

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.512
_exptl_crystal_F_000             5244
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.270
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    5.306
_shelx_estimated_absorpt_T_min   0.328
_shelx_estimated_absorpt_T_max   0.676
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.52
_exptl_absorpt_correction_T_max  0.68
_exptl_absorpt_process_details   'SADABS V2014/4 (Bruker AXS Inc.)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   'rotation anode'
_diffrn_measurement_device_type  'D8 Venture Ultra'
_diffrn_measurement_method       'φ and ω, two θ position'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_reflns_number            101361
_diffrn_reflns_av_unetI/netI     0.0426
_diffrn_reflns_av_R_equivalents  0.0593
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -45
_diffrn_reflns_limit_l_max       45
_diffrn_reflns_theta_min         3.659
_diffrn_reflns_theta_max         65.265
_diffrn_reflns_theta_full        65.265
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measured_fraction_theta_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_point_group_measured_fraction_full 0.989
_reflns_number_total             19114
_reflns_number_gt                15141
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker Instrument Service v4.2.3'
_computing_cell_refinement       'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_data_reduction        'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_structure_solution    'SHELXS-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    XP
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0738P)²+31.8329P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         19114
_refine_ls_number_parameters     1469
_refine_ls_number_restraints     40
_refine_ls_R_factor_all          0.0719
_refine_ls_R_factor_gt           0.0532
_refine_ls_wR_factor_ref         0.1438
_refine_ls_wR_factor_gt          0.1322
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_restrained_S_all      1.008
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1A P 0.43650(8) 1.04064(10) 0.75554(4) 0.0477(4) Uani 1 1 d . . . . .
F1A F 0.3889(2) 0.9723(2) 0.77140(11) 0.0716(11) Uani 1 1 d . . . . .
F2A F 0.4511(2) 0.9724(3) 0.72753(11) 0.0735(11) Uani 1 1 d . . . . .
F3A F 0.3646(2) 1.0679(3) 0.72814(12) 0.0777(12) Uani 1 1 d . . . . .
F4A F 0.4221(3) 1.1083(3) 0.78337(12) 0.0851(14) Uani 1 1 d . . . . .
F5A F 0.4792(2) 1.1099(3) 0.73887(10) 0.0693(11) Uani 1 1 d . . . . .
F6A F 0.5057(2) 1.0100(4) 0.78267(12) 0.0975(15) Uani 1 1 d . . . . .
P1B P 0.10606(8) 0.17033(10) 0.30642(4) 0.0418(3) Uani 1 1 d . . . . .
F1B F 0.08690(19) 0.1042(3) 0.27448(9) 0.0631(10) Uani 1 1 d . . . . .
F2B F 0.04785(17) 0.1256(2) 0.32490(9) 0.0545(9) Uani 1 1 d . . . . .
F3B F 0.16527(18) 0.1053(3) 0.32682(11) 0.0677(11) Uani 1 1 d . . . . .
F4B F 0.1655(2) 0.2122(3) 0.28801(9) 0.0702(11) Uani 1 1 d . . . . .
F5B F 0.1264(2) 0.2343(2) 0.33848(9) 0.0708(11) Uani 1 1 d . . . . .
F6B F 0.0470(2) 0.2324(3) 0.28584(11) 0.0783(12) Uani 1 1 d . . . . .
P1C P -0.38196(9) 0.27617(11) 0.53652(6) 0.0673(5) Uani 1 1 d . . . . .
F1C F -0.3953(2) 0.3487(2) 0.56293(11) 0.0693(10) Uani 1 1 d . . . . .
F2C F -0.4563(2) 0.2982(3) 0.51074(12) 0.0783(12) Uani 1 1 d . . . . .
F3C F -0.3067(2) 0.2543(3) 0.56207(15) 0.1014(18) Uani 1 1 d . . . . .
F4C F -0.3696(2) 0.2031(3) 0.51098(16) 0.115(2) Uani 1 1 d . . . . .
F5C F -0.3425(2) 0.3424(3) 0.51591(14) 0.0910(14) Uani 1 1 d . . . . .
F6C F -0.4217(3) 0.2116(3) 0.55784(15) 0.1015(18) Uani 1 1 d . . . . .
C1X C 0.2367(6) 1.1948(9) 0.6526(3) 0.134(4) Uani 1 1 d . . . . .
C2X C 0.1997(4) 1.2214(6) 0.6159(3) 0.079(3) Uani 1 1 d . . . . .
N3X N 0.1688(4) 1.2370(4) 0.5877(2) 0.078(2) Uani 1 1 d . . . . .
O1Y O 0.5693(2) 1.0664(3) 0.38644(12) 0.0650(12) Uani 1 1 d . . . . .
C2Y C 0.6381(4) 1.0524(5) 0.40972(19) 0.069(2) Uani 1 1 d . . . . .
H2YA H 0.6376 1.0757 0.4336 0.083 Uiso 1 1 calc R U . . .
H2YB H 0.6758 1.0827 0.4003 0.083 Uiso 1 1 calc R U . . .
C3Y C 0.6552(4) 0.9619(6) 0.41275(19) 0.076(2) Uani 1 1 d . . . . .
H3YA H 0.7027 0.9541 0.4289 0.091 Uiso 1 1 calc R U . . .
H3YB H 0.6189 0.9323 0.4233 0.091 Uiso 1 1 calc R U . . .
O4Y O 0.6566(3) 0.9260(3) 0.37947(13) 0.0770(15) Uani 1 1 d . . . . .
C5Y C 0.5868(4) 0.9380(5) 0.3561(2) 0.071(2) Uani 1 1 d . . . . .
H5YA H 0.5497 0.9080 0.3659 0.085 Uiso 1 1 calc R U . . .
H5YB H 0.5872 0.9137 0.3324 0.085 Uiso 1 1 calc R U . . .
C6Y C 0.5691(4) 1.0293(4) 0.35242(17) 0.0575(17) Uani 1 1 d . . . . .
H6YA H 0.6047 1.0587 0.3413 0.069 Uiso 1 1 calc R U . . .
H6YB H 0.5210 1.0366 0.3367 0.069 Uiso 1 1 calc R U . . .
O1Z O 0.7824(3) 1.0351(6) 0.80895(15) 0.130(3) Uani 1 1 d . . . . .
C2Z C 0.8111(6) 1.0316(8) 0.7786(2) 0.112(4) Uani 1 1 d . . . . .
H2ZA H 0.8568 0.9993 0.7838 0.134 Uiso 1 1 calc R U . . .
H2ZB H 0.8218 1.0897 0.7715 0.134 Uiso 1 1 calc R U . . .
C3Z C 0.7622(5) 0.9920(7) 0.7502(3) 0.121(4) Uani 1 1 d . . . . .
H3ZA H 0.7525 0.9333 0.7570 0.145 Uiso 1 1 calc R U . . .
H3ZB H 0.7835 0.9895 0.7289 0.145 Uiso 1 1 calc R U . . .
O4Z O 0.6933(4) 1.0409(6) 0.74190(17) 0.119(3) Uani 1 1 d . . . . .
C5Z C 0.6676(5) 1.0497(7) 0.7728(3) 0.098(3) Uani 1 1 d . . . . .
H5ZA H 0.6250 1.0872 0.7679 0.117 Uiso 1 1 calc R U . . .
H5ZB H 0.6515 0.9934 0.7795 0.117 Uiso 1 1 calc R U . . .
C6Z C 0.7157(6) 1.0815(10) 0.8010(3) 0.158(6) Uani 1 1 d . . . . .
H6ZA H 0.6938 1.0807 0.8223 0.190 Uiso 1 1 calc R U . . .
H6ZB H 0.7259 1.1413 0.7961 0.190 Uiso 1 1 calc R U . . .
Ag1 Ag -0.23794(2) 0.59466(2) 0.59320(2) 0.03036(10) Uani 1 1 d . . . . .
Ag2 Ag 0.42444(2) 0.77432(2) 0.72499(2) 0.03346(11) Uani 1 1 d . . . . .
Ag3 Ag 0.18610(2) 0.88519(2) 0.40051(2) 0.03714(11) Uani 1 1 d . . . . .
C1A C -0.1933(2) 0.5718(3) 0.64640(13) 0.0284(10) Uani 1 1 d . . . . .
N2A N -0.2286(2) 0.5717(3) 0.67318(10) 0.0291(9) Uani 1 1 d . . . . .
C3A C -0.1830(3) 0.5482(3) 0.70512(13) 0.0301(11) Uani 1 1 d . . . . .
C4A C -0.1960(3) 0.5353(3) 0.73907(13) 0.0342(11) Uani 1 1 d . . . . .
H4AA H -0.2414 0.5471 0.7446 0.041 Uiso 1 1 calc R U . . .
C5A C -0.1390(3) 0.5043(4) 0.76430(13) 0.0386(12) Uani 1 1 d . . . . .
H5AA H -0.1449 0.4960 0.7880 0.046 Uiso 1 1 calc R U . . .
C6A C -0.0728(3) 0.4848(4) 0.75581(13) 0.0393(13) Uani 1 1 d . . . . .
H6AA H -0.0359 0.4608 0.7737 0.047 Uiso 1 1 calc R U . . .
C7A C -0.0592(3) 0.4992(3) 0.72247(13) 0.0340(12) Uani 1 1 d . . . . .
H7AA H -0.0138 0.4874 0.7170 0.041 Uiso 1 1 calc R U . . .
C8A C -0.1165(2) 0.5324(3) 0.69717(12) 0.0282(10) Uani 1 1 d . . . . .
N9A N -0.12436(19) 0.5491(3) 0.66097(10) 0.0274(9) Uani 1 1 d . . . . .
C10A C -0.3055(3) 0.5904(4) 0.66868(15) 0.0404(13) Uani 1 1 d . . . . .
H10A H -0.3181 0.6384 0.6519 0.048 Uiso 1 1 calc R U . . .
H10B H -0.3156 0.6079 0.6919 0.048 Uiso 1 1 calc R U . . .
C11A C -0.3515(3) 0.5161(4) 0.65495(18) 0.0544(16) Uani 1 1 d . . . . .
H11A H -0.4022 0.5314 0.6524 0.082 Uiso 1 1 calc R U . . .
H11B H -0.3424 0.4992 0.6317 0.082 Uiso 1 1 calc R U . . .
H11C H -0.3400 0.4688 0.6717 0.082 Uiso 1 1 calc R U . . .
C12A C -0.0679(2) 0.5492(3) 0.64145(12) 0.0242(10) Uani 1 1 d . . . . .
C13A C -0.0034(3) 0.5895(3) 0.65530(12) 0.0319(11) Uani 1 1 d . . . . .
H13A H 0.0038 0.6162 0.6779 0.038 Uiso 1 1 calc R U . . .
C14A C 0.0511(3) 0.5908(3) 0.63610(12) 0.0306(11) Uani 1 1 d . . . . .
H14A H 0.0953 0.6179 0.6461 0.037 Uiso 1 1 calc R U . . .
C15A C 0.0424(2) 0.5535(3) 0.60259(12) 0.0249(10) Uani 1 1 d . . . . .
C16A C -0.0238(2) 0.5146(3) 0.58906(12) 0.0280(10) Uani 1 1 d . . . . .
H16A H -0.0321 0.4898 0.5660 0.034 Uiso 1 1 calc R U . . .
C17A C -0.0777(2) 0.5111(3) 0.60830(13) 0.0286(10) Uani 1 1 d . . . . .
H17A H -0.1215 0.4825 0.5987 0.034 Uiso 1 1 calc R U . . .
C1B C 0.4994(2) 0.7786(3) 0.69215(13) 0.0300(11) Uani 1 1 d . . . . .
N2B N 0.5660(2) 0.8101(3) 0.69996(11) 0.0325(9) Uani 1 1 d . . . . .
C3B C 0.5997(3) 0.8039(3) 0.67112(14) 0.0341(11) Uani 1 1 d . . . . .
C4B C 0.6672(3) 0.8277(4) 0.66639(15) 0.0433(13) Uani 1 1 d . . . . .
H4BA H 0.7019 0.8523 0.6851 0.052 Uiso 1 1 calc R U . . .
C5B C 0.6815(3) 0.8140(4) 0.63319(17) 0.0489(15) Uani 1 1 d . . . . .
H5BA H 0.7275 0.8287 0.6291 0.059 Uiso 1 1 calc R U . . .
C6B C 0.6309(3) 0.7792(4) 0.60546(16) 0.0439(14) Uani 1 1 d . . . . .
H6BA H 0.6426 0.7724 0.5828 0.053 Uiso 1 1 calc R U . . .
C7B C 0.5635(3) 0.7543(3) 0.61028(14) 0.0353(12) Uani 1 1 d . . . . .
H7BA H 0.5286 0.7305 0.5915 0.042 Uiso 1 1 calc R U . . .
C8B C 0.5499(2) 0.7660(3) 0.64383(13) 0.0292(11) Uani 1 1 d . . . . .
N9B N 0.48875(19) 0.7512(3) 0.65791(10) 0.0283(9) Uani 1 1 d . . . . .
C10B C 0.6004(3) 0.8476(4) 0.73446(15) 0.0436(13) Uani 1 1 d . . . . .
H10C H 0.5627 0.8641 0.7474 0.052 Uiso 1 1 calc R U . . .
H10D H 0.6266 0.8996 0.7303 0.052 Uiso 1 1 calc R U . . .
C11B C 0.6518(4) 0.7874(4) 0.75699(18) 0.0638(19) Uani 1 1 d . . . . .
H11D H 0.6734 0.8147 0.7796 0.096 Uiso 1 1 calc R U . . .
H11E H 0.6259 0.7363 0.7616 0.096 Uiso 1 1 calc R U . . .
H11F H 0.6897 0.7717 0.7444 0.096 Uiso 1 1 calc R U . . .
C12B C 0.4246(2) 0.7112(3) 0.63899(12) 0.0289(11) Uani 1 1 d . . . . .
C13B C 0.4294(3) 0.6311(4) 0.62446(19) 0.0584(17) Uani 1 1 d . . . . .
H13B H 0.4747 0.6036 0.6274 0.070 Uiso 1 1 calc R U . . .
C14B C 0.3684(3) 0.5916(4) 0.60580(17) 0.0536(16) Uani 1 1 d . . . . .
H14B H 0.3719 0.5374 0.5956 0.064 Uiso 1 1 calc R U . . .
C15B C 0.2997(2) 0.6319(3) 0.60170(12) 0.0291(11) Uani 1 1 d . . . . .
C16B C 0.2981(3) 0.7071(4) 0.61809(17) 0.0473(14) Uani 1 1 d . . . . .
H16B H 0.2529 0.7337 0.6169 0.057 Uiso 1 1 calc R U . . .
C17B C 0.3591(3) 0.7470(4) 0.63649(16) 0.0471(14) Uani 1 1 d . . . . .
H17B H 0.3552 0.8002 0.6475 0.057 Uiso 1 1 calc R U . . .
C1C C 0.0919(3) 0.8266(3) 0.37461(13) 0.0331(11) Uani 1 1 d . . . . .
N2C N 0.0544(2) 0.8424(3) 0.34120(11) 0.0363(10) Uani 1 1 d . . . . .
C3C C -0.0037(3) 0.7891(3) 0.33114(14) 0.0395(13) Uani 1 1 d . . . . .
C4C C -0.0557(3) 0.7798(4) 0.29983(15) 0.0511(15) Uani 1 1 d . . . . .
H4CA H -0.0572 0.8164 0.2801 0.061 Uiso 1 1 calc R U . . .
C5C C -0.1042(4) 0.7158(5) 0.29888(16) 0.0611(18) Uani 1 1 d . . . . .
H5CA H -0.1401 0.7080 0.2779 0.073 Uiso 1 1 calc R U . . .
C6C C -0.1032(4) 0.6611(4) 0.32755(16) 0.0580(17) Uani 1 1 d . . . . .
H6CA H -0.1378 0.6170 0.3256 0.070 Uiso 1 1 calc R U . . .
C7C C -0.0517(3) 0.6706(4) 0.35915(15) 0.0441(13) Uani 1 1 d . . . . .
H7CA H -0.0504 0.6341 0.3789 0.053 Uiso 1 1 calc R U . . .
C8C C -0.0030(3) 0.7354(3) 0.36019(12) 0.0334(11) Uani 1 1 d . . . . .
N9C N 0.0559(2) 0.7611(3) 0.38636(10) 0.0295(9) Uani 1 1 d . . . . .
C10C C 0.0725(4) 0.9109(4) 0.31831(17) 0.0512(16) Uani 1 1 d . . . . .
H10E H 0.1082 0.9493 0.3329 0.061 Uiso 1 1 calc R U . . .
H10F H 0.0287 0.9444 0.3087 0.061 Uiso 1 1 calc R U . . .
C11C C 0.1023(5) 0.8774(5) 0.2881(2) 0.084(3) Uani 1 1 d . . . . .
H11G H 0.1135 0.9248 0.2737 0.126 Uiso 1 1 calc R U . . .
H11H H 0.1463 0.8452 0.2975 0.126 Uiso 1 1 calc R U . . .
H11I H 0.0668 0.8403 0.2733 0.126 Uiso 1 1 calc R U . . .
C12C C 0.0755(3) 0.7243(3) 0.42117(12) 0.0287(10) Uani 1 1 d . . . . .
C13C C 0.1443(3) 0.6935(3) 0.43333(13) 0.0333(11) Uani 1 1 d . . . . .
H13C H 0.1792 0.6991 0.4190 0.040 Uiso 1 1 calc R U . . .
C14C C 0.1625(3) 0.6548(3) 0.46606(13) 0.0342(11) Uani 1 1 d . . . . .
H14C H 0.2101 0.6342 0.4740 0.041 Uiso 1 1 calc R U . . .
C15C C 0.1128(2) 0.6448(3) 0.48809(12) 0.0263(10) Uani 1 1 d . . . . .
C16C C 0.0444(2) 0.6773(3) 0.47535(12) 0.0256(10) Uani 1 1 d . . . . .
H16C H 0.0094 0.6718 0.4896 0.031 Uiso 1 1 calc R U . . .
C17C C 0.0249(3) 0.7177(3) 0.44229(13) 0.0296(11) Uani 1 1 d . . . . .
H17C H -0.0221 0.7402 0.4344 0.036 Uiso 1 1 calc R U . . .
C1D C 0.1013(2) 0.5518(3) 0.58126(12) 0.0253(10) Uani 1 1 d . . . . .
C2D C 0.0771(2) 0.5998(3) 0.54586(11) 0.0240(10) Uani 1 1 d . . . . .
H2DA H 0.0664 0.6594 0.5509 0.029 Uiso 1 1 calc R U . . .
H2DB H 0.0324 0.5738 0.5321 0.029 Uiso 1 1 calc R U . . .
C3D C 0.1714(2) 0.5925(3) 0.60213(12) 0.0273(10) Uani 1 1 d . . . . .
H3DA H 0.1878 0.5619 0.6249 0.033 Uiso 1 1 calc R U . . .
H3DB H 0.1618 0.6521 0.6077 0.033 Uiso 1 1 calc R U . . .
C4D C 0.1191(3) 0.4591(3) 0.57309(13) 0.0302(11) Uani 1 1 d . . . . .
H4DA H 0.1361 0.4280 0.5957 0.036 Uiso 1 1 calc R U . . .
H4DB H 0.0751 0.4307 0.5598 0.036 Uiso 1 1 calc R U . . .
C5D C 0.2314(2) 0.5900(3) 0.58046(13) 0.0299(11) Uani 1 1 d . . . . .
C6D C 0.1353(2) 0.5979(3) 0.52331(12) 0.0261(10) Uani 1 1 d . . . . .
C7D C 0.1771(3) 0.4572(3) 0.55100(13) 0.0323(11) Uani 1 1 d . . . . .
H7DA H 0.1873 0.3969 0.5458 0.039 Uiso 1 1 calc R U . . .
C8D C 0.1510(3) 0.5040(3) 0.51594(12) 0.0299(11) Uani 1 1 d . . . . .
H8DA H 0.1067 0.4768 0.5024 0.036 Uiso 1 1 calc R U . . .
H8DB H 0.1881 0.5011 0.5014 0.036 Uiso 1 1 calc R U . . .
C9D C 0.2045(2) 0.6379(3) 0.54548(12) 0.0261(10) Uani 1 1 d . . . . .
H9DA H 0.2424 0.6375 0.5314 0.031 Uiso 1 1 calc R U . . .
H9DB H 0.1949 0.6977 0.5508 0.031 Uiso 1 1 calc R U . . .
C10D C 0.2455(2) 0.4976(3) 0.57149(13) 0.0318(11) Uani 1 1 d . . . . .
H10G H 0.2828 0.4957 0.5571 0.038 Uiso 1 1 calc R U . . .
H10H H 0.2634 0.4656 0.5938 0.038 Uiso 1 1 calc R U . . .
C1E C -0.2840(2) 0.6218(3) 0.54036(13) 0.0286(10) Uani 1 1 d . . . . .
N2E N -0.3462(2) 0.5937(3) 0.51975(11) 0.0313(9) Uani 1 1 d . . . . .
C3E C -0.3605(3) 0.6344(3) 0.48695(12) 0.0315(11) Uani 1 1 d . . . . .
C4E C -0.4181(3) 0.6292(4) 0.45844(14) 0.0440(14) Uani 1 1 d . . . . .
H4EA H -0.4574 0.5923 0.4587 0.053 Uiso 1 1 calc R U . . .
C5E C -0.4159(3) 0.6797(5) 0.42962(15) 0.0565(17) Uani 1 1 d . . . . .
H5EA H -0.4545 0.6777 0.4094 0.068 Uiso 1 1 calc R U . . .
C6E C -0.3586(3) 0.7336(4) 0.42948(16) 0.0536(16) Uani 1 1 d . . . . .
H6EA H -0.3589 0.7670 0.4089 0.064 Uiso 1 1 calc R U . . .
C7E C -0.3013(3) 0.7409(4) 0.45788(13) 0.0378(12) Uani 1 1 d . . . . .
H7EA H -0.2626 0.7789 0.4577 0.045 Uiso 1 1 calc R U . . .
C8E C -0.3037(3) 0.6890(3) 0.48688(12) 0.0289(10) Uani 1 1 d . . . . .
N9E N -0.2576(2) 0.6797(2) 0.52042(10) 0.0255(8) Uani 1 1 d . . . . .
C10E C -0.3919(3) 0.5308(4) 0.53192(14) 0.0407(13) Uani 1 1 d . . . . .
H10I H -0.3613 0.4897 0.5478 0.049 Uiso 1 1 calc R U . . .
H10J H -0.4192 0.4992 0.5111 0.049 Uiso 1 1 calc R U . . .
C11E C -0.4440(3) 0.5714(4) 0.55166(15) 0.0480(14) Uani 1 1 d . . . . .
H11J H -0.4737 0.5274 0.5594 0.072 Uiso 1 1 calc R U . . .
H11K H -0.4172 0.6018 0.5725 0.072 Uiso 1 1 calc R U . . .
H11L H -0.4750 0.6112 0.5359 0.072 Uiso 1 1 calc R U . . .
C12E C -0.1931(2) 0.7275(3) 0.53336(12) 0.0272(10) Uani 1 1 d . . . . .
C13E C -0.1425(3) 0.7369(3) 0.51313(13) 0.0283(10) Uani 1 1 d . . . . .
H13D H -0.1489 0.7099 0.4906 0.034 Uiso 1 1 calc R U . . .
C14E C -0.0819(3) 0.7858(3) 0.52550(12) 0.0284(10) Uani 1 1 d . . . . .
H14D H -0.0474 0.7925 0.5110 0.034 Uiso 1 1 calc R U . . .
C15E C -0.0701(2) 0.8257(3) 0.55868(12) 0.0272(10) Uani 1 1 d . . . . .
C16E C -0.1215(2) 0.8124(3) 0.57966(12) 0.0306(11) Uani 1 1 d . . . . .
H16D H -0.1138 0.8362 0.6029 0.037 Uiso 1 1 calc R U . . .
C17E C -0.1829(3) 0.7652(3) 0.56703(13) 0.0298(11) Uani 1 1 d . . . . .
H17D H -0.2180 0.7585 0.5811 0.036 Uiso 1 1 calc R U . . .
C1F C 0.3544(3) 0.7779(3) 0.76045(14) 0.0383(12) Uani 1 1 d . . . . .
N2F N 0.3758(3) 0.7670(3) 0.79597(11) 0.0448(12) Uani 1 1 d . . . . .
C3F C 0.3204(3) 0.7862(4) 0.81312(15) 0.0469(15) Uani 1 1 d . . . . .
C4F C 0.3182(4) 0.7893(4) 0.84919(16) 0.0567(17) Uani 1 1 d . . . . .
H4FA H 0.3587 0.7751 0.8673 0.068 Uiso 1 1 calc R U . . .
C5F C 0.2540(4) 0.8140(4) 0.85686(17) 0.0589(18) Uani 1 1 d . . . . .
H5FA H 0.2505 0.8173 0.8811 0.071 Uiso 1 1 calc R U . . .
C6F C 0.1944(3) 0.8341(4) 0.83106(17) 0.0510(16) Uani 1 1 d . . . . .
H6FA H 0.1511 0.8499 0.8379 0.061 Uiso 1 1 calc R U . . .
C7F C 0.1965(3) 0.8318(3) 0.79487(16) 0.0432(14) Uani 1 1 d . . . . .
H7FA H 0.1558 0.8458 0.7768 0.052 Uiso 1 1 calc R U . . .
C8F C 0.2614(3) 0.8078(3) 0.78689(14) 0.0367(12) Uani 1 1 d . . . . .
N9F N 0.2847(2) 0.8019(3) 0.75445(11) 0.0336(10) Uani 1 1 d . . . . .
C10F C 0.4487(4) 0.7419(5) 0.81409(17) 0.070(2) Uani 1 1 d . . . . .
H10K H 0.4713 0.7088 0.7975 0.084 Uiso 1 1 calc R U . . .
H10L H 0.4459 0.7052 0.8346 0.084 Uiso 1 1 calc R U . . .
C11F C 0.4949(4) 0.8185(7) 0.8270(2) 0.087(3) Uani 1 1 d . . . . .
H11M H 0.5430 0.7998 0.8389 0.131 Uiso 1 1 calc R U . . .
H11N H 0.4984 0.8545 0.8066 0.131 Uiso 1 1 calc R U . . .
H11O H 0.4730 0.8509 0.8437 0.131 Uiso 1 1 calc R U . . .
C12F C 0.2419(3) 0.8239(3) 0.72034(13) 0.0308(11) Uani 1 1 d . . . . .
C13F C 0.2668(3) 0.8823(3) 0.69934(13) 0.0301(11) Uani 1 1 d . . . . .
H13E H 0.3131 0.9066 0.7070 0.036 Uiso 1 1 calc R U . . .
C14F C 0.2240(2) 0.9055(3) 0.66700(13) 0.0294(11) Uani 1 1 d . . . . .
H14E H 0.2419 0.9459 0.6527 0.035 Uiso 1 1 calc R U . . .
C15F C 0.1553(2) 0.8717(3) 0.65460(12) 0.0270(10) Uani 1 1 d . . . . .
C16F C 0.1320(3) 0.8120(3) 0.67655(13) 0.0334(11) Uani 1 1 d . . . . .
H16E H 0.0857 0.7873 0.6691 0.040 Uiso 1 1 calc R U . . .
C17F C 0.1745(3) 0.7879(3) 0.70896(14) 0.0374(12) Uani 1 1 d . . . . .
H17E H 0.1576 0.7468 0.7233 0.045 Uiso 1 1 calc R U . . .
C1G C 0.2793(3) 0.9506(3) 0.42494(14) 0.0371(12) Uani 1 1 d . . . . .
N2G N 0.3400(2) 0.9681(3) 0.41344(12) 0.0448(12) Uani 1 1 d . . . . .
C3G C 0.3868(3) 1.0174(4) 0.43809(14) 0.0397(13) Uani 1 1 d . . . . .
C4G C 0.4543(3) 1.0504(4) 0.43805(16) 0.0495(15) Uani 1 1 d . . . . .
H4GA H 0.4780 1.0400 0.4190 0.059 Uiso 1 1 calc R U . . .
C5G C 0.4853(3) 1.0991(4) 0.46700(18) 0.0582(17) Uani 1 1 d . . . . .
H5GA H 0.5315 1.1230 0.4680 0.070 Uiso 1 1 calc R U . . .
C6G C 0.4503(3) 1.1140(4) 0.49490(17) 0.0563(17) Uani 1 1 d . . . . .
H6GA H 0.4732 1.1479 0.5145 0.068 Uiso 1 1 calc R U . . .
C7G C 0.3835(3) 1.0806(4) 0.49469(15) 0.0449(14) Uani 1 1 d . . . . .
H7GA H 0.3598 1.0903 0.5137 0.054 Uiso 1 1 calc R U . . .
C8G C 0.3526(3) 1.0327(3) 0.46579(13) 0.0344(12) Uani 1 1 d . . . . .
N9G N 0.2870(2) 0.9893(3) 0.45699(11) 0.0321(9) Uani 1 1 d . . . . .
C10X C 0.3564(10) 0.9450(12) 0.3794(4) 0.041(4) Uani 0.557(18) 1 d D U P A 1
H10M H 0.3818 0.8898 0.3823 0.049 Uiso 0.557(18) 1 calc R U P A 1
H10R H 0.3903 0.9875 0.3735 0.049 Uiso 0.557(18) 1 calc R U P A 1
C11X C 0.2950(6) 0.9380(8) 0.3486(3) 0.045(4) Uani 0.557(18) 1 d D U P A 1
H11P H 0.3128 0.9222 0.3273 0.068 Uiso 0.557(18) 1 calc R U P A 1
H11Q H 0.2616 0.8946 0.3535 0.068 Uiso 0.557(18) 1 calc R U P A 1
H11R H 0.2702 0.9926 0.3446 0.068 Uiso 0.557(18) 1 calc R U P A 1
C10G C 0.363(2) 0.914(2) 0.3839(9) 0.085(10) Uani 0.443(18) 1 d D U P A 2
H10P H 0.4144 0.8969 0.3911 0.102 Uiso 0.443(18) 1 calc R U P A 2
H10Q H 0.3329 0.8634 0.3781 0.102 Uiso 0.443(18) 1 calc R U P A 2
C11G C 0.3529(13) 0.9728(12) 0.3544(6) 0.080(7) Uani 0.443(18) 1 d D U P A 2
H11S H 0.3662 0.9452 0.3339 0.120 Uiso 0.443(18) 1 calc R U P A 2
H11T H 0.3022 0.9898 0.3482 0.120 Uiso 0.443(18) 1 calc R U P A 2
H11U H 0.3830 1.0230 0.3611 0.120 Uiso 0.443(18) 1 calc R U P A 2
C12G C 0.2379(3) 0.9809(3) 0.48030(13) 0.0301(11) Uani 1 1 d . . . . .
C13G C 0.2124(3) 1.0524(3) 0.49397(13) 0.0304(11) Uani 1 1 d . . . . .
H13F H 0.2247 1.1070 0.4867 0.036 Uiso 1 1 calc R U . . .
C14G C 0.1686(2) 1.0445(3) 0.51847(12) 0.0280(10) Uani 1 1 d . . . . .
H14F H 0.1519 1.0942 0.5281 0.034 Uiso 1 1 calc R U . . .
C15G C 0.1486(2) 0.9662(3) 0.52922(12) 0.0270(10) Uani 1 1 d . . . . .
C16G C 0.1736(3) 0.8945(3) 0.51404(13) 0.0326(11) Uani 1 1 d . . . . .
H16F H 0.1593 0.8399 0.5203 0.039 Uiso 1 1 calc R U . . .
C17G C 0.2185(3) 0.9011(3) 0.49022(14) 0.0353(12) Uani 1 1 d . . . . .
H17F H 0.2359 0.8516 0.4807 0.042 Uiso 1 1 calc R U . . .
C1H C -0.0063(2) 0.8835(3) 0.57224(12) 0.0270(10) Uani 1 1 d . . . . .
C2H C -0.0342(3) 0.9711(3) 0.58143(13) 0.0310(11) Uani 1 1 d . . . . .
H2HA H -0.0650 0.9962 0.5599 0.037 Uiso 1 1 calc R U . . .
H2HB H -0.0636 0.9644 0.5997 0.037 Uiso 1 1 calc R U . . .
C3H C 0.0386(2) 0.8976(3) 0.54393(12) 0.0257(10) Uani 1 1 d . . . . .
H3HA H 0.0565 0.8423 0.5372 0.031 Uiso 1 1 calc R U . . .
H3HB H 0.0077 0.9225 0.5224 0.031 Uiso 1 1 calc R U . . .
C4H C 0.0430(2) 0.8466(3) 0.60597(12) 0.0273(10) Uani 1 1 d . . . . .
H4HA H 0.0145 0.8378 0.6245 0.033 Uiso 1 1 calc R U . . .
H4HB H 0.0613 0.7907 0.6002 0.033 Uiso 1 1 calc R U . . .
C5H C 0.1071(2) 0.9052(3) 0.62084(12) 0.0256(10) Uani 1 1 d . . . . .
C6H C 0.1027(2) 0.9566(3) 0.55727(12) 0.0259(10) Uani 1 1 d . . . . .
C7H C 0.0292(2) 1.0299(3) 0.59548(13) 0.0300(11) Uani 1 1 d . . . . .
H7HA H 0.0105 1.0861 0.6014 0.036 Uiso 1 1 calc R U . . .
C8H C 0.0766(3) 0.9923(3) 0.62896(12) 0.0286(10) Uani 1 1 d . . . . .
H8HA H 0.0480 0.9854 0.6475 0.034 Uiso 1 1 calc R U . . .
H8HB H 0.1168 1.0315 0.6382 0.034 Uiso 1 1 calc R U . . .
C9H C 0.0736(3) 1.0422(3) 0.56724(13) 0.0289(10) Uani 1 1 d . . . . .
H9HA H 0.1142 1.0809 0.5764 0.035 Uiso 1 1 calc R U . . .
H9HB H 0.0434 1.0684 0.5458 0.035 Uiso 1 1 calc R U . . .
C10H C 0.1500(2) 0.9183(3) 0.59124(12) 0.0267(10) Uani 1 1 d . . . . .
H10N H 0.1912 0.9566 0.6001 0.032 Uiso 1 1 calc R U . . .
H10O H 0.1694 0.8632 0.5854 0.032 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1A F6A 1.573(5) . ?
P1A F4A 1.575(4) . ?
P1A F5A 1.576(4) . ?
P1A F2A 1.588(4) . ?
P1A F3A 1.599(4) . ?
P1A F1A 1.609(4) . ?
P1B F6B 1.572(4) . ?
P1B F5B 1.576(4) . ?
P1B F1B 1.594(4) . ?
P1B F4B 1.599(4) . ?
P1B F2B 1.600(3) . ?
P1B F3B 1.601(4) . ?
P1C F4C 1.564(5) . ?
P1C F2C 1.584(4) . ?
P1C F1C 1.585(4) . ?
P1C F5C 1.592(5) . ?
P1C F3C 1.594(4) . ?
P1C F6C 1.595(5) . ?
C1X C2X 1.498(15) . ?
C2X N3X 1.143(11) . ?
O1Y C6Y 1.432(8) . ?
O1Y C2Y 1.439(8) . ?
C2Y C3Y 1.464(11) . ?
C3Y O4Y 1.405(9) . ?
O4Y C5Y 1.450(9) . ?
C5Y C6Y 1.480(10) . ?
O1Z C2Z 1.390(10) . ?
O1Z C6Z 1.441(12) . ?
C2Z C3Z 1.421(13) . ?
C3Z O4Z 1.496(12) . ?
O4Z C5Z 1.384(10) . ?
C5Z C6Z 1.359(13) . ?
Ag1 C1A 2.073(5) . ?
Ag1 C1E 2.079(5) . ?
Ag2 C1B 2.096(5) . ?
Ag2 C1F 2.098(5) . ?
Ag3 C1C 2.074(5) . ?
Ag3 C1G 2.094(5) . ?
C1A N2A 1.342(6) . ?
C1A N9A 1.362(6) . ?
N2A C3A 1.396(6) . ?
N2A C10A 1.466(6) . ?
C3A C8A 1.385(6) . ?
C3A C4A 1.393(7) . ?
C4A C5A 1.382(7) . ?
C5A C6A 1.400(7) . ?
C6A C7A 1.378(7) . ?
C7A C8A 1.400(7) . ?
C8A N9A 1.393(6) . ?
N9A C12A 1.434(5) . ?
C10A C11A 1.491(8) . ?
C12A C13A 1.385(6) . ?
C12A C17A 1.385(7) . ?
C13A C14A 1.393(6) . ?
C14A C15A 1.393(6) . ?
C15A C16A 1.399(6) . ?
C15A C1D 1.522(6) . ?
C16A C17A 1.386(6) . ?
C1B N2B 1.334(6) . ?
C1B N9B 1.359(6) . ?
N2B C3B 1.396(6) . ?
N2B C10B 1.473(6) . ?
C3B C4B 1.387(7) . ?
C3B C8B 1.391(7) . ?
C4B C5B 1.377(8) . ?
C5B C6B 1.389(8) . ?
C6B C7B 1.391(7) . ?
C7B C8B 1.380(7) . ?
C8B N9B 1.402(6) . ?
N9B C12B 1.428(6) . ?
C10B C11B 1.501(9) . ?
C12B C17B 1.353(7) . ?
C12B C13B 1.392(8) . ?
C13B C14B 1.378(9) . ?
C14B C15B 1.431(8) . ?
C15B C16B 1.346(7) . ?
C15B C5D 1.533(6) . ?
C16B C17B 1.378(8) . ?
C1C N2C 1.354(7) . ?
C1C N9C 1.368(6) . ?
N2C C3C 1.378(7) . ?
N2C C10C 1.478(7) . ?
C3C C4C 1.394(8) . ?
C3C C8C 1.399(7) . ?
C4C C5C 1.363(9) . ?
C5C C6C 1.396(9) . ?
C6C C7C 1.398(8) . ?
C7C C8C 1.374(7) . ?
C8C N9C 1.398(6) . ?
N9C C12C 1.434(6) . ?
C10C C11C 1.493(9) . ?
C12C C13C 1.382(7) . ?
C12C C17C 1.387(6) . ?
C13C C14C 1.375(7) . ?
C14C C15C 1.404(6) . ?
C15C C16C 1.388(6) . ?
C15C C6D 1.522(7) . ?
C16C C17C 1.400(7) . ?
C1D C2D 1.540(6) . ?
C1D C3D 1.543(6) . ?
C1D C4D 1.547(6) . ?
C2D C6D 1.542(6) . ?
C3D C5D 1.549(6) . ?
C4D C7D 1.529(6) . ?
C5D C10D 1.533(7) . ?
C5D C9D 1.533(7) . ?
C6D C9D 1.544(6) . ?
C6D C8D 1.549(7) . ?
C7D C10D 1.511(7) . ?
C7D C8D 1.525(7) . ?
C1E N2E 1.353(6) . ?
C1E N9E 1.355(6) . ?
N2E C3E 1.389(6) . ?
N2E C10E 1.460(6) . ?
C3E C4E 1.379(7) . ?
C3E C8E 1.382(7) . ?
C4E C5E 1.372(8) . ?
C5E C6E 1.383(9) . ?
C6E C7E 1.376(8) . ?
C7E C8E 1.392(7) . ?
C8E N9E 1.406(6) . ?
N9E C12E 1.437(6) . ?
C10E C11E 1.512(8) . ?
C12E C13E 1.367(6) . ?
C12E C17E 1.400(7) . ?
C13E C14E 1.386(7) . ?
C14E C15E 1.397(6) . ?
C15E C16E 1.408(6) . ?
C15E C1H 1.520(6) . ?
C16E C17E 1.384(7) . ?
C1F N2F 1.351(7) . ?
C1F N9F 1.351(7) . ?
N2F C3F 1.390(7) . ?
N2F C10F 1.469(8) . ?
C3F C8F 1.383(8) . ?
C3F C4F 1.396(8) . ?
C4F C5F 1.371(9) . ?
C5F C6F 1.376(9) . ?
C6F C7F 1.400(8) . ?
C7F C8F 1.386(7) . ?
C8F N9F 1.411(6) . ?
N9F C12F 1.432(6) . ?
C10F C11F 1.514(12) . ?
C12F C13F 1.372(7) . ?
C12F C17F 1.386(7) . ?
C13F C14F 1.384(7) . ?
C14F C15F 1.398(7) . ?
C15F C16F 1.398(7) . ?
C15F C5H 1.517(7) . ?
C16F C17F 1.388(7) . ?
C1G N2G 1.350(6) . ?
C1G N9G 1.355(6) . ?
N2G C3G 1.392(7) . ?
N2G C10X 1.455(15) . ?
N2G C10G 1.55(4) . ?
C3G C8G 1.381(7) . ?
C3G C4G 1.385(7) . ?
C4G C5G 1.378(9) . ?
C5G C6G 1.396(9) . ?
C6G C7G 1.373(8) . ?
C7G C8G 1.369(8) . ?
C8G N9G 1.402(6) . ?
N9G C12G 1.430(6) . ?
C10X C11X 1.48(2) . ?
C10G C11G 1.44(3) . ?
C12G C13G 1.375(7) . ?
C12G C17G 1.387(7) . ?
C13G C14G 1.388(6) . ?
C14G C15G 1.381(7) . ?
C15G C16G 1.400(6) . ?
C15G C6H 1.532(6) . ?
C16G C17G 1.381(6) . ?
C1H C3H 1.534(6) . ?
C1H C4H 1.544(7) . ?
C1H C2H 1.549(6) . ?
C2H C7H 1.527(7) . ?
C3H C6H 1.533(6) . ?
C4H C5H 1.541(6) . ?
C5H C10H 1.548(6) . ?
C5H C8H 1.548(6) . ?
C6H C9H 1.539(6) . ?
C6H C10H 1.544(7) . ?
C7H C9H 1.522(6) . ?
C7H C8H 1.526(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F6A P1A F4A 90.0(3) . . ?
F6A P1A F5A 92.9(3) . . ?
F4A P1A F5A 89.1(2) . . ?
F6A P1A F2A 89.9(3) . . ?
F4A P1A F2A 179.9(4) . . ?
F5A P1A F2A 90.9(2) . . ?
F6A P1A F3A 177.5(3) . . ?
F4A P1A F3A 91.0(3) . . ?
F5A P1A F3A 89.3(2) . . ?
F2A P1A F3A 89.1(2) . . ?
F6A P1A F1A 90.1(3) . . ?
F4A P1A F1A 90.2(2) . . ?
F5A P1A F1A 176.9(3) . . ?
F2A P1A F1A 89.7(2) . . ?
F3A P1A F1A 87.6(2) . . ?
F6B P1B F5B 91.5(2) . . ?
F6B P1B F1B 89.9(2) . . ?
F5B P1B F1B 178.7(3) . . ?
F6B P1B F4B 91.0(2) . . ?
F5B P1B F4B 90.1(2) . . ?
F1B P1B F4B 89.9(2) . . ?
F6B P1B F2B 90.6(2) . . ?
F5B P1B F2B 90.8(2) . . ?
F1B P1B F2B 89.17(19) . . ?
F4B P1B F2B 178.2(2) . . ?
F6B P1B F3B 178.7(3) . . ?
F5B P1B F3B 89.8(2) . . ?
F1B P1B F3B 88.9(2) . . ?
F4B P1B F3B 89.5(2) . . ?
F2B P1B F3B 88.9(2) . . ?
F4C P1C F2C 90.1(3) . . ?
F4C P1C F1C 178.7(3) . . ?
F2C P1C F1C 90.0(2) . . ?
F4C P1C F5C 91.3(3) . . ?
F2C P1C F5C 89.8(3) . . ?
F1C P1C F5C 90.0(2) . . ?
F4C P1C F3C 89.5(3) . . ?
F2C P1C F3C 179.3(3) . . ?
F1C P1C F3C 90.4(2) . . ?
F5C P1C F3C 89.5(3) . . ?
F4C P1C F6C 90.1(3) . . ?
F2C P1C F6C 90.2(2) . . ?
F1C P1C F6C 88.6(3) . . ?
F5C P1C F6C 178.6(3) . . ?
F3C P1C F6C 90.4(3) . . ?
N3X C2X C1X 175.6(11) . . ?
C6Y O1Y C2Y 109.3(5) . . ?
O1Y C2Y C3Y 110.9(6) . . ?
O4Y C3Y C2Y 111.6(6) . . ?
C3Y O4Y C5Y 108.7(6) . . ?
O4Y C5Y C6Y 110.3(6) . . ?
O1Y C6Y C5Y 110.8(6) . . ?
C2Z O1Z C6Z 109.2(9) . . ?
O1Z C2Z C3Z 110.6(8) . . ?
C2Z C3Z O4Z 109.9(8) . . ?
C5Z O4Z C3Z 108.6(7) . . ?
C6Z C5Z O4Z 115.0(10) . . ?
C5Z C6Z O1Z 113.3(10) . . ?
C1A Ag1 C1E 177.94(19) . . ?
C1B Ag2 C1F 175.3(2) . . ?
C1C Ag3 C1G 176.7(2) . . ?
N2A C1A N9A 106.2(4) . . ?
N2A C1A Ag1 126.1(3) . . ?
N9A C1A Ag1 127.6(3) . . ?
C1A N2A C3A 110.8(4) . . ?
C1A N2A C10A 123.9(4) . . ?
C3A N2A C10A 125.3(4) . . ?
C8A C3A C4A 122.1(5) . . ?
C8A C3A N2A 106.3(4) . . ?
C4A C3A N2A 131.5(4) . . ?
C5A C4A C3A 116.2(5) . . ?
C4A C5A C6A 121.7(5) . . ?
C7A C6A C5A 122.3(5) . . ?
C6A C7A C8A 115.8(4) . . ?
C3A C8A N9A 106.0(4) . . ?
C3A C8A C7A 121.8(4) . . ?
N9A C8A C7A 131.9(4) . . ?
C1A N9A C8A 110.6(4) . . ?
C1A N9A C12A 123.2(4) . . ?
C8A N9A C12A 126.1(4) . . ?
N2A C10A C11A 112.3(5) . . ?
C13A C12A C17A 119.3(4) . . ?
C13A C12A N9A 120.0(4) . . ?
C17A C12A N9A 120.6(4) . . ?
C12A C13A C14A 120.1(4) . . ?
C13A C14A C15A 121.8(4) . . ?
C14A C15A C16A 116.8(4) . . ?
C14A C15A C1D 123.2(4) . . ?
C16A C15A C1D 120.0(4) . . ?
C17A C16A C15A 121.9(4) . . ?
C12A C17A C16A 120.1(4) . . ?
N2B C1B N9B 106.1(4) . . ?
N2B C1B Ag2 127.6(4) . . ?
N9B C1B Ag2 126.2(3) . . ?
C1B N2B C3B 111.6(4) . . ?
C1B N2B C10B 124.9(4) . . ?
C3B N2B C10B 123.5(4) . . ?
C4B C3B C8B 121.3(5) . . ?
C4B C3B N2B 132.7(5) . . ?
C8B C3B N2B 105.9(4) . . ?
C5B C4B C3B 116.6(5) . . ?
C4B C5B C6B 122.2(5) . . ?
C5B C6B C7B 121.2(5) . . ?
C8B C7B C6B 116.6(5) . . ?
C7B C8B C3B 122.0(4) . . ?
C7B C8B N9B 132.3(4) . . ?
C3B C8B N9B 105.6(4) . . ?
C1B N9B C8B 110.7(4) . . ?
C1B N9B C12B 124.8(4) . . ?
C8B N9B C12B 124.5(4) . . ?
N2B C10B C11B 112.1(5) . . ?
C17B C12B C13B 119.2(5) . . ?
C17B C12B N9B 121.8(5) . . ?
C13B C12B N9B 119.0(4) . . ?
C14B C13B C12B 120.0(5) . . ?
C13B C14B C15B 120.4(6) . . ?
C16B C15B C14B 116.8(5) . . ?
C16B C15B C5D 122.0(4) . . ?
C14B C15B C5D 121.2(5) . . ?
C15B C16B C17B 122.9(5) . . ?
C12B C17B C16B 120.6(6) . . ?
N2C C1C N9C 104.6(4) . . ?
N2C C1C Ag3 127.0(3) . . ?
N9C C1C Ag3 128.4(4) . . ?
C1C N2C C3C 112.6(4) . . ?
C1C N2C C10C 123.8(5) . . ?
C3C N2C C10C 123.5(5) . . ?
N2C C3C C4C 133.4(5) . . ?
N2C C3C C8C 105.9(5) . . ?
C4C C3C C8C 120.7(5) . . ?
C5C C4C C3C 117.0(6) . . ?
C4C C5C C6C 122.7(6) . . ?
C5C C6C C7C 120.7(6) . . ?
C8C C7C C6C 116.7(5) . . ?
C7C C8C N9C 132.0(5) . . ?
C7C C8C C3C 122.3(5) . . ?
N9C C8C C3C 105.7(4) . . ?
C1C N9C C8C 111.3(4) . . ?
C1C N9C C12C 124.3(4) . . ?
C8C N9C C12C 124.4(4) . . ?
N2C C10C C11C 112.3(5) . . ?
C13C C12C C17C 120.0(4) . . ?
C13C C12C N9C 119.9(4) . . ?
C17C C12C N9C 120.0(4) . . ?
C14C C13C C12C 120.1(4) . . ?
C13C C14C C15C 122.0(5) . . ?
C16C C15C C14C 116.5(4) . . ?
C16C C15C C6D 123.9(4) . . ?
C14C C15C C6D 119.5(4) . . ?
C15C C16C C17C 122.4(4) . . ?
C12C C17C C16C 118.9(4) . . ?
C15A C1D C2D 110.5(4) . . ?
C15A C1D C3D 111.5(4) . . ?
C2D C1D C3D 108.6(4) . . ?
C15A C1D C4D 110.1(4) . . ?
C2D C1D C4D 108.8(4) . . ?
C3D C1D C4D 107.3(4) . . ?
C1D C2D C6D 111.8(4) . . ?
C1D C3D C5D 111.3(4) . . ?
C7D C4D C1D 110.3(4) . . ?
C15B C5D C10D 111.2(4) . . ?
C15B C5D C9D 110.0(4) . . ?
C10D C5D C9D 108.3(4) . . ?
C15B C5D C3D 109.9(4) . . ?
C10D C5D C3D 109.2(4) . . ?
C9D C5D C3D 108.1(4) . . ?
C15C C6D C2D 113.0(4) . . ?
C15C C6D C9D 109.8(4) . . ?
C2D C6D C9D 108.1(4) . . ?
C15C C6D C8D 109.3(4) . . ?
C2D C6D C8D 108.0(4) . . ?
C9D C6D C8D 108.5(4) . . ?
C10D C7D C8D 109.9(4) . . ?
C10D C7D C4D 110.1(4) . . ?
C8D C7D C4D 110.0(4) . . ?
C7D C8D C6D 110.0(4) . . ?
C5D C9D C6D 111.7(4) . . ?
C7D C10D C5D 110.3(4) . . ?
N2E C1E N9E 105.8(4) . . ?
N2E C1E Ag1 129.9(3) . . ?
N9E C1E Ag1 124.2(3) . . ?
C1E N2E C3E 111.1(4) . . ?
C1E N2E C10E 122.8(4) . . ?
C3E N2E C10E 126.1(4) . . ?
C4E C3E C8E 121.7(5) . . ?
C4E C3E N2E 131.6(5) . . ?
C8E C3E N2E 106.7(4) . . ?
C5E C4E C3E 116.9(5) . . ?
C4E C5E C6E 121.2(5) . . ?
C7E C6E C5E 122.8(6) . . ?
C6E C7E C8E 115.5(5) . . ?
C3E C8E C7E 121.8(5) . . ?
C3E C8E N9E 105.6(4) . . ?
C7E C8E N9E 132.5(5) . . ?
C1E N9E C8E 110.8(4) . . ?
C1E N9E C12E 123.3(4) . . ?
C8E N9E C12E 125.8(4) . . ?
N2E C10E C11E 111.7(5) . . ?
C13E C12E C17E 120.2(4) . . ?
C13E C12E N9E 120.8(4) . . ?
C17E C12E N9E 118.9(4) . . ?
C12E C13E C14E 120.0(4) . . ?
C13E C14E C15E 121.7(4) . . ?
C14E C15E C16E 117.3(4) . . ?
C14E C15E C1H 123.1(4) . . ?
C16E C15E C1H 119.6(4) . . ?
C17E C16E C15E 121.1(4) . . ?
C16E C17E C12E 119.6(4) . . ?
N2F C1F N9F 106.5(4) . . ?
N2F C1F Ag2 123.7(4) . . ?
N9F C1F Ag2 129.2(4) . . ?
C1F N2F C3F 110.8(5) . . ?
C1F N2F C10F 124.5(4) . . ?
C3F N2F C10F 124.7(5) . . ?
C8F C3F N2F 106.7(5) . . ?
C8F C3F C4F 121.7(5) . . ?
N2F C3F C4F 131.5(6) . . ?
C5F C4F C3F 116.0(6) . . ?
C4F C5F C6F 123.1(6) . . ?
C5F C6F C7F 121.2(5) . . ?
C8F C7F C6F 116.2(6) . . ?
C3F C8F C7F 121.9(5) . . ?
C3F C8F N9F 105.7(5) . . ?
C7F C8F N9F 132.4(5) . . ?
C1F N9F C8F 110.3(4) . . ?
C1F N9F C12F 124.9(4) . . ?
C8F N9F C12F 124.7(4) . . ?
N2F C10F C11F 111.3(6) . . ?
C13F C12F C17F 120.0(5) . . ?
C13F C12F N9F 120.1(4) . . ?
C17F C12F N9F 119.9(4) . . ?
C12F C13F C14F 119.7(5) . . ?
C13F C14F C15F 122.3(4) . . ?
C14F C15F C16F 116.4(4) . . ?
C14F C15F C5H 120.8(4) . . ?
C16F C15F C5H 122.6(4) . . ?
C17F C16F C15F 121.8(5) . . ?
C12F C17F C16F 119.8(5) . . ?
N2G C1G N9G 105.6(4) . . ?
N2G C1G Ag3 131.0(4) . . ?
N9G C1G Ag3 123.3(3) . . ?
C1G N2G C3G 111.1(4) . . ?
C1G N2G C10X 127.1(8) . . ?
C3G N2G C10X 121.7(8) . . ?
C1G N2G C10G 121.6(16) . . ?
C3G N2G C10G 124.1(17) . . ?
C8G C3G C4G 121.5(5) . . ?
C8G C3G N2G 106.6(4) . . ?
C4G C3G N2G 131.9(5) . . ?
C5G C4G C3G 116.5(5) . . ?
C4G C5G C6G 121.5(5) . . ?
C7G C6G C5G 121.4(6) . . ?
C8G C7G C6G 117.0(5) . . ?
C7G C8G C3G 122.1(5) . . ?
C7G C8G N9G 132.3(5) . . ?
C3G C8G N9G 105.6(4) . . ?
C1G N9G C8G 111.1(4) . . ?
C1G N9G C12G 124.6(4) . . ?
C8G N9G C12G 124.1(4) . . ?
N2G C10X C11X 117.1(12) . . ?
C11G C10G N2G 102(2) . . ?
C13G C12G C17G 120.2(4) . . ?
C13G C12G N9G 119.5(4) . . ?
C17G C12G N9G 120.2(4) . . ?
C12G C13G C14G 119.7(4) . . ?
C15G C14G C13G 121.7(4) . . ?
C14G C15G C16G 117.3(4) . . ?
C14G C15G C6H 122.2(4) . . ?
C16G C15G C6H 120.5(4) . . ?
C17G C16G C15G 121.8(4) . . ?
C16G C17G C12G 119.2(4) . . ?
C15E C1H C3H 111.6(4) . . ?
C15E C1H C4H 111.1(4) . . ?
C3H C1H C4H 108.7(4) . . ?
C15E C1H C2H 109.1(4) . . ?
C3H C1H C2H 107.5(4) . . ?
C4H C1H C2H 108.8(4) . . ?
C7H C2H C1H 109.8(4) . . ?
C6H C3H C1H 111.9(4) . . ?
C5H C4H C1H 112.2(4) . . ?
C15F C5H C4H 113.4(4) . . ?
C15F C5H C10H 110.9(4) . . ?
C4H C5H C10H 107.9(4) . . ?
C15F C5H C8H 108.8(4) . . ?
C4H C5H C8H 107.8(4) . . ?
C10H C5H C8H 107.9(4) . . ?
C15G C6H C3H 110.9(4) . . ?
C15G C6H C9H 112.2(4) . . ?
C3H C6H C9H 108.3(4) . . ?
C15G C6H C10H 108.4(4) . . ?
C3H C6H C10H 109.0(4) . . ?
C9H C6H C10H 108.0(4) . . ?
C9H C7H C8H 109.5(4) . . ?
C9H C7H C2H 110.0(4) . . ?
C8H C7H C2H 110.2(4) . . ?
C7H C8H C5H 110.7(4) . . ?
C7H C9H C6H 110.4(4) . . ?
C6H C10H C5H 111.7(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6Y O1Y C2Y C3Y -56.5(7) . . . . ?
O1Y C2Y C3Y O4Y 59.1(8) . . . . ?
C2Y C3Y O4Y C5Y -58.9(8) . . . . ?
C3Y O4Y C5Y C6Y 58.4(8) . . . . ?
C2Y O1Y C6Y C5Y 56.6(7) . . . . ?
O4Y C5Y C6Y O1Y -58.3(7) . . . . ?
C6Z O1Z C2Z C3Z -58.7(14) . . . . ?
O1Z C2Z C3Z O4Z 59.8(13) . . . . ?
C2Z C3Z O4Z C5Z -54.4(11) . . . . ?
C3Z O4Z C5Z C6Z 52.2(13) . . . . ?
O4Z C5Z C6Z O1Z -53.8(17) . . . . ?
C2Z O1Z C6Z C5Z 55.1(16) . . . . ?
N9A C1A N2A C3A -0.5(5) . . . . ?
Ag1 C1A N2A C3A 175.9(3) . . . . ?
N9A C1A N2A C10A -178.2(4) . . . . ?
Ag1 C1A N2A C10A -1.7(7) . . . . ?
C1A N2A C3A C8A -0.7(6) . . . . ?
C10A N2A C3A C8A 176.9(5) . . . . ?
C1A N2A C3A C4A -176.4(5) . . . . ?
C10A N2A C3A C4A 1.2(9) . . . . ?
C8A C3A C4A C5A -1.1(8) . . . . ?
N2A C3A C4A C5A 174.1(5) . . . . ?
C3A C4A C5A C6A -1.8(8) . . . . ?
C4A C5A C6A C7A 3.3(9) . . . . ?
C5A C6A C7A C8A -1.8(8) . . . . ?
C4A C3A C8A N9A 177.8(5) . . . . ?
N2A C3A C8A N9A 1.5(5) . . . . ?
C4A C3A C8A C7A 2.5(8) . . . . ?
N2A C3A C8A C7A -173.7(5) . . . . ?
C6A C7A C8A C3A -1.0(8) . . . . ?
C6A C7A C8A N9A -174.9(5) . . . . ?
N2A C1A N9A C8A 1.5(5) . . . . ?
Ag1 C1A N9A C8A -174.8(3) . . . . ?
N2A C1A N9A C12A -174.3(4) . . . . ?
Ag1 C1A N9A C12A 9.4(7) . . . . ?
C3A C8A N9A C1A -1.9(5) . . . . ?
C7A C8A N9A C1A 172.6(5) . . . . ?
C3A C8A N9A C12A 173.7(4) . . . . ?
C7A C8A N9A C12A -11.7(8) . . . . ?
C1A N2A C10A C11A 80.2(6) . . . . ?
C3A N2A C10A C11A -97.1(6) . . . . ?
C1A N9A C12A C13A 129.6(5) . . . . ?
C8A N9A C12A C13A -45.5(7) . . . . ?
C1A N9A C12A C17A -48.7(7) . . . . ?
C8A N9A C12A C17A 136.1(5) . . . . ?
C17A C12A C13A C14A -0.5(7) . . . . ?
N9A C12A C13A C14A -178.9(4) . . . . ?
C12A C13A C14A C15A 1.0(8) . . . . ?
C13A C14A C15A C16A 0.0(7) . . . . ?
C13A C14A C15A C1D -178.4(5) . . . . ?
C14A C15A C16A C17A -1.6(7) . . . . ?
C1D C15A C16A C17A 176.8(4) . . . . ?
C13A C12A C17A C16A -1.0(7) . . . . ?
N9A C12A C17A C16A 177.4(4) . . . . ?
C15A C16A C17A C12A 2.1(7) . . . . ?
N9B C1B N2B C3B 0.0(6) . . . . ?
Ag2 C1B N2B C3B -178.5(4) . . . . ?
N9B C1B N2B C10B 179.6(5) . . . . ?
Ag2 C1B N2B C10B 1.2(7) . . . . ?
C1B N2B C3B C4B 179.7(6) . . . . ?
C10B N2B C3B C4B 0.1(9) . . . . ?
C1B N2B C3B C8B 0.2(6) . . . . ?
C10B N2B C3B C8B -179.5(5) . . . . ?
C8B C3B C4B C5B 1.6(8) . . . . ?
N2B C3B C4B C5B -177.9(6) . . . . ?
C3B C4B C5B C6B 1.0(9) . . . . ?
C4B C5B C6B C7B -1.8(10) . . . . ?
C5B C6B C7B C8B 0.0(8) . . . . ?
C6B C7B C8B C3B 2.5(8) . . . . ?
C6B C7B C8B N9B 177.8(5) . . . . ?
C4B C3B C8B C7B -3.5(8) . . . . ?
N2B C3B C8B C7B 176.1(5) . . . . ?
C4B C3B C8B N9B -179.9(5) . . . . ?
N2B C3B C8B N9B -0.3(5) . . . . ?
N2B C1B N9B C8B -0.2(5) . . . . ?
Ag2 C1B N9B C8B 178.3(3) . . . . ?
N2B C1B N9B C12B 178.7(4) . . . . ?
Ag2 C1B N9B C12B -2.8(7) . . . . ?
C7B C8B N9B C1B -175.6(5) . . . . ?
C3B C8B N9B C1B 0.3(5) . . . . ?
C7B C8B N9B C12B 5.5(8) . . . . ?
C3B C8B N9B C12B -178.6(4) . . . . ?
C1B N2B C10B C11B 101.4(6) . . . . ?
C3B N2B C10B C11B -79.0(7) . . . . ?
C1B N9B C12B C17B 53.3(7) . . . . ?
C8B N9B C12B C17B -128.0(5) . . . . ?
C1B N9B C12B C13B -123.0(6) . . . . ?
C8B N9B C12B C13B 55.7(7) . . . . ?
C17B C12B C13B C14B 4.2(9) . . . . ?
N9B C12B C13B C14B -179.4(6) . . . . ?
C12B C13B C14B C15B -1.0(10) . . . . ?
C13B C14B C15B C16B -2.8(9) . . . . ?
C13B C14B C15B C5D 178.8(6) . . . . ?
C14B C15B C16B C17B 3.5(9) . . . . ?
C5D C15B C16B C17B -178.2(5) . . . . ?
C13B C12B C17B C16B -3.6(9) . . . . ?
N9B C12B C17B C16B -179.9(5) . . . . ?
C15B C16B C17B C12B -0.3(9) . . . . ?
N9C C1C N2C C3C -0.6(5) . . . . ?
Ag3 C1C N2C C3C 176.5(4) . . . . ?
N9C C1C N2C C10C 177.9(4) . . . . ?
Ag3 C1C N2C C10C -5.0(7) . . . . ?
C1C N2C C3C C4C -178.1(6) . . . . ?
C10C N2C C3C C4C 3.4(9) . . . . ?
C1C N2C C3C C8C -0.1(6) . . . . ?
C10C N2C C3C C8C -178.6(5) . . . . ?
N2C C3C C4C C5C 176.7(6) . . . . ?
C8C C3C C4C C5C -1.1(9) . . . . ?
C3C C4C C5C C6C 0.1(10) . . . . ?
C4C C5C C6C C7C 0.6(11) . . . . ?
C5C C6C C7C C8C -0.3(9) . . . . ?
C6C C7C C8C N9C -177.6(6) . . . . ?
C6C C7C C8C C3C -0.7(8) . . . . ?
N2C C3C C8C C7C -176.9(5) . . . . ?
C4C C3C C8C C7C 1.5(8) . . . . ?
N2C C3C C8C N9C 0.7(5) . . . . ?
C4C C3C C8C N9C 179.0(5) . . . . ?
N2C C1C N9C C8C 1.0(5) . . . . ?
Ag3 C1C N9C C8C -176.0(3) . . . . ?
N2C C1C N9C C12C -178.3(4) . . . . ?
Ag3 C1C N9C C12C 4.7(7) . . . . ?
C7C C8C N9C C1C 176.1(6) . . . . ?
C3C C8C N9C C1C -1.1(5) . . . . ?
C7C C8C N9C C12C -4.6(9) . . . . ?
C3C C8C N9C C12C 178.2(4) . . . . ?
C1C N2C C10C C11C 109.0(7) . . . . ?
C3C N2C C10C C11C -72.7(8) . . . . ?
C1C N9C C12C C13C -55.1(6) . . . . ?
C8C N9C C12C C13C 125.7(5) . . . . ?
C1C N9C C12C C17C 126.5(5) . . . . ?
C8C N9C C12C C17C -52.7(7) . . . . ?
C17C C12C C13C C14C 1.3(7) . . . . ?
N9C C12C C13C C14C -177.2(4) . . . . ?
C12C C13C C14C C15C 0.2(8) . . . . ?
C13C C14C C15C C16C -0.9(7) . . . . ?
C13C C14C C15C C6D 177.3(5) . . . . ?
C14C C15C C16C C17C 0.2(7) . . . . ?
C6D C15C C16C C17C -177.9(4) . . . . ?
C13C C12C C17C C16C -1.9(7) . . . . ?
N9C C12C C17C C16C 176.5(4) . . . . ?
C15C C16C C17C C12C 1.2(7) . . . . ?
C14A C15A C1D C2D -118.3(5) . . . . ?
C16A C15A C1D C2D 63.3(5) . . . . ?
C14A C15A C1D C3D 2.4(6) . . . . ?
C16A C15A C1D C3D -175.9(4) . . . . ?
C14A C15A C1D C4D 121.4(5) . . . . ?
C16A C15A C1D C4D -56.9(6) . . . . ?
C15A C1D C2D C6D -179.1(4) . . . . ?
C3D C1D C2D C6D 58.4(5) . . . . ?
C4D C1D C2D C6D -58.1(5) . . . . ?
C15A C1D C3D C5D 179.5(4) . . . . ?
C2D C1D C3D C5D -58.6(5) . . . . ?
C4D C1D C3D C5D 58.9(5) . . . . ?
C15A C1D C4D C7D 178.8(4) . . . . ?
C2D C1D C4D C7D 57.6(5) . . . . ?
C3D C1D C4D C7D -59.7(5) . . . . ?
C16B C15B C5D C10D -167.7(5) . . . . ?
C14B C15B C5D C10D 10.6(7) . . . . ?
C16B C15B C5D C9D 72.3(6) . . . . ?
C14B C15B C5D C9D -109.4(5) . . . . ?
C16B C15B C5D C3D -46.6(7) . . . . ?
C14B C15B C5D C3D 131.7(5) . . . . ?
C1D C3D C5D C15B 179.2(4) . . . . ?
C1D C3D C5D C10D -58.5(5) . . . . ?
C1D C3D C5D C9D 59.1(5) . . . . ?
C16C C15C C6D C2D -7.3(6) . . . . ?
C14C C15C C6D C2D 174.6(4) . . . . ?
C16C C15C C6D C9D -128.1(5) . . . . ?
C14C C15C C6D C9D 53.8(5) . . . . ?
C16C C15C C6D C8D 113.0(5) . . . . ?
C14C C15C C6D C8D -65.1(5) . . . . ?
C1D C2D C6D C15C 179.9(4) . . . . ?
C1D C2D C6D C9D -58.4(5) . . . . ?
C1D C2D C6D C8D 58.8(5) . . . . ?
C1D C4D C7D C10D 61.3(5) . . . . ?
C1D C4D C7D C8D -60.0(5) . . . . ?
C10D C7D C8D C6D -60.3(5) . . . . ?
C4D C7D C8D C6D 61.1(5) . . . . ?
C15C C6D C8D C7D 177.2(4) . . . . ?
C2D C6D C8D C7D -59.5(5) . . . . ?
C9D C6D C8D C7D 57.5(5) . . . . ?
C15B C5D C9D C6D -179.7(4) . . . . ?
C10D C5D C9D C6D 58.7(5) . . . . ?
C3D C5D C9D C6D -59.6(5) . . . . ?
C15C C6D C9D C5D -177.1(4) . . . . ?
C2D C6D C9D C5D 59.2(5) . . . . ?
C8D C6D C9D C5D -57.7(5) . . . . ?
C8D C7D C10D C5D 61.6(5) . . . . ?
C4D C7D C10D C5D -59.7(5) . . . . ?
C15B C5D C10D C7D 179.2(4) . . . . ?
C9D C5D C10D C7D -59.8(5) . . . . ?
C3D C5D C10D C7D 57.7(5) . . . . ?
N9E C1E N2E C3E -1.0(5) . . . . ?
Ag1 C1E N2E C3E 173.9(3) . . . . ?
N9E C1E N2E C10E -179.2(4) . . . . ?
Ag1 C1E N2E C10E -4.4(7) . . . . ?
C1E N2E C3E C4E -176.9(5) . . . . ?
C10E N2E C3E C4E 1.2(9) . . . . ?
C1E N2E C3E C8E 1.2(5) . . . . ?
C10E N2E C3E C8E 179.4(5) . . . . ?
C8E C3E C4E C5E 1.2(8) . . . . ?
N2E C3E C4E C5E 179.1(6) . . . . ?
C3E C4E C5E C6E -0.4(10) . . . . ?
C4E C5E C6E C7E -0.8(11) . . . . ?
C5E C6E C7E C8E 1.2(9) . . . . ?
C4E C3E C8E C7E -0.8(8) . . . . ?
N2E C3E C8E C7E -179.2(4) . . . . ?
C4E C3E C8E N9E 177.4(5) . . . . ?
N2E C3E C8E N9E -0.9(5) . . . . ?
C6E C7E C8E C3E -0.4(8) . . . . ?
C6E C7E C8E N9E -178.1(5) . . . . ?
N2E C1E N9E C8E 0.4(5) . . . . ?
Ag1 C1E N9E C8E -174.9(3) . . . . ?
N2E C1E N9E C12E 177.2(4) . . . . ?
Ag1 C1E N9E C12E 1.9(6) . . . . ?
C3E C8E N9E C1E 0.4(5) . . . . ?
C7E C8E N9E C1E 178.3(5) . . . . ?
C3E C8E N9E C12E -176.3(4) . . . . ?
C7E C8E N9E C12E 1.6(8) . . . . ?
C1E N2E C10E C11E 86.5(6) . . . . ?
C3E N2E C10E C11E -91.4(6) . . . . ?
C1E N9E C12E C13E 134.4(5) . . . . ?
C8E N9E C12E C13E -49.3(7) . . . . ?
C1E N9E C12E C17E -46.1(6) . . . . ?
C8E N9E C12E C17E 130.2(5) . . . . ?
C17E C12E C13E C14E -1.8(7) . . . . ?
N9E C12E C13E C14E 177.6(4) . . . . ?
C12E C13E C14E C15E 0.8(7) . . . . ?
C13E C14E C15E C16E 1.7(7) . . . . ?
C13E C14E C15E C1H -176.7(4) . . . . ?
C14E C15E C16E C17E -3.2(7) . . . . ?
C1H C15E C16E C17E 175.2(5) . . . . ?
C15E C16E C17E C12E 2.3(8) . . . . ?
C13E C12E C17E C16E 0.3(7) . . . . ?
N9E C12E C17E C16E -179.2(4) . . . . ?
N9F C1F N2F C3F -1.5(7) . . . . ?
Ag2 C1F N2F C3F 170.3(4) . . . . ?
N9F C1F N2F C10F -179.1(6) . . . . ?
Ag2 C1F N2F C10F -7.3(9) . . . . ?
C1F N2F C3F C8F 1.5(7) . . . . ?
C10F N2F C3F C8F 179.1(6) . . . . ?
C1F N2F C3F C4F -175.7(7) . . . . ?
C10F N2F C3F C4F 1.9(11) . . . . ?
C8F C3F C4F C5F 0.7(10) . . . . ?
N2F C3F C4F C5F 177.6(7) . . . . ?
C3F C4F C5F C6F 0.6(10) . . . . ?
C4F C5F C6F C7F -1.1(11) . . . . ?
C5F C6F C7F C8F 0.3(9) . . . . ?
N2F C3F C8F C7F -179.1(5) . . . . ?
C4F C3F C8F C7F -1.5(9) . . . . ?
N2F C3F C8F N9F -0.9(6) . . . . ?
C4F C3F C8F N9F 176.6(6) . . . . ?
C6F C7F C8F C3F 1.0(8) . . . . ?
C6F C7F C8F N9F -176.7(5) . . . . ?
N2F C1F N9F C8F 0.9(6) . . . . ?
Ag2 C1F N9F C8F -170.3(4) . . . . ?
N2F C1F N9F C12F 177.0(5) . . . . ?
Ag2 C1F N9F C12F 5.7(8) . . . . ?
C3F C8F N9F C1F 0.1(6) . . . . ?
C7F C8F N9F C1F 178.0(6) . . . . ?
C3F C8F N9F C12F -176.0(5) . . . . ?
C7F C8F N9F C12F 1.9(9) . . . . ?
C1F N2F C10F C11F 94.0(7) . . . . ?
C3F N2F C10F C11F -83.3(8) . . . . ?
C1F N9F C12F C13F -51.2(7) . . . . ?
C8F N9F C12F C13F 124.3(5) . . . . ?
C1F N9F C12F C17F 130.5(5) . . . . ?
C8F N9F C12F C17F -53.9(7) . . . . ?
C17F C12F C13F C14F 0.6(7) . . . . ?
N9F C12F C13F C14F -177.6(4) . . . . ?
C12F C13F C14F C15F 0.2(7) . . . . ?
C13F C14F C15F C16F -0.6(7) . . . . ?
C13F C14F C15F C5H 173.7(4) . . . . ?
C14F C15F C16F C17F 0.3(7) . . . . ?
C5H C15F C16F C17F -174.0(5) . . . . ?
C13F C12F C17F C16F -1.0(7) . . . . ?
N9F C12F C17F C16F 177.3(4) . . . . ?
C15F C16F C17F C12F 0.5(8) . . . . ?
N9G C1G N2G C3G 0.4(6) . . . . ?
Ag3 C1G N2G C3G 176.9(4) . . . . ?
N9G C1G N2G C10X -176.2(10) . . . . ?
Ag3 C1G N2G C10X 0.3(13) . . . . ?
N9G C1G N2G C10G 161.0(14) . . . . ?
Ag3 C1G N2G C10G -22.5(15) . . . . ?
C1G N2G C3G C8G -1.4(7) . . . . ?
C10X N2G C3G C8G 175.4(10) . . . . ?
C10G N2G C3G C8G -161.4(13) . . . . ?
C1G N2G C3G C4G 179.9(6) . . . . ?
C10X N2G C3G C4G -3.2(13) . . . . ?
C10G N2G C3G C4G 19.9(16) . . . . ?
C8G C3G C4G C5G 0.0(9) . . . . ?
N2G C3G C4G C5G 178.5(6) . . . . ?
C3G C4G C5G C6G 0.2(10) . . . . ?
C4G C5G C6G C7G 0.1(11) . . . . ?
C5G C6G C7G C8G -0.5(10) . . . . ?
C6G C7G C8G C3G 0.7(9) . . . . ?
C6G C7G C8G N9G 179.3(6) . . . . ?
C4G C3G C8G C7G -0.4(9) . . . . ?
N2G C3G C8G C7G -179.3(5) . . . . ?
C4G C3G C8G N9G -179.4(5) . . . . ?
N2G C3G C8G N9G 1.8(6) . . . . ?
N2G C1G N9G C8G 0.7(6) . . . . ?
Ag3 C1G N9G C8G -176.1(4) . . . . ?
N2G C1G N9G C12G -173.9(5) . . . . ?
Ag3 C1G N9G C12G 9.2(7) . . . . ?
C7G C8G N9G C1G 179.6(6) . . . . ?
C3G C8G N9G C1G -1.6(6) . . . . ?
C7G C8G N9G C12G -5.7(9) . . . . ?
C3G C8G N9G C12G 173.1(5) . . . . ?
C1G N2G C10X C11X 30(2) . . . . ?
C3G N2G C10X C11X -146.1(11) . . . . ?
C1G N2G C10G C11G 110(2) . . . . ?
C3G N2G C10G C11G -92(3) . . . . ?
C1G N9G C12G C13G -129.8(5) . . . . ?
C8G N9G C12G C13G 56.2(7) . . . . ?
C1G N9G C12G C17G 52.9(7) . . . . ?
C8G N9G C12G C17G -121.1(6) . . . . ?
C17G C12G C13G C14G 1.6(8) . . . . ?
N9G C12G C13G C14G -175.7(4) . . . . ?
C12G C13G C14G C15G -1.1(8) . . . . ?
C13G C14G C15G C16G -0.8(7) . . . . ?
C13G C14G C15G C6H 177.6(4) . . . . ?
C14G C15G C16G C17G 2.3(8) . . . . ?
C6H C15G C16G C17G -176.2(5) . . . . ?
C15G C16G C17G C12G -1.8(8) . . . . ?
C13G C12G C17G C16G -0.2(8) . . . . ?
N9G C12G C17G C16G 177.0(5) . . . . ?
C14E C15E C1H C3H 4.7(6) . . . . ?
C16E C15E C1H C3H -173.6(4) . . . . ?
C14E C15E C1H C4H -116.8(5) . . . . ?
C16E C15E C1H C4H 65.0(5) . . . . ?
C14E C15E C1H C2H 123.3(5) . . . . ?
C16E C15E C1H C2H -54.9(6) . . . . ?
C15E C1H C2H C7H 179.4(4) . . . . ?
C3H C1H C2H C7H -59.4(5) . . . . ?
C4H C1H C2H C7H 58.0(5) . . . . ?
C15E C1H C3H C6H 179.5(4) . . . . ?
C4H C1H C3H C6H -57.7(5) . . . . ?
C2H C1H C3H C6H 59.9(5) . . . . ?
C15E C1H C4H C5H -178.5(3) . . . . ?
C3H C1H C4H C5H 58.3(5) . . . . ?
C2H C1H C4H C5H -58.4(5) . . . . ?
C14F C15F C5H C4H 164.9(4) . . . . ?
C16F C15F C5H C4H -21.1(6) . . . . ?
C14F C15F C5H C10H 43.4(6) . . . . ?
C16F C15F C5H C10H -142.6(4) . . . . ?
C14F C15F C5H C8H -75.1(5) . . . . ?
C16F C15F C5H C8H 98.8(5) . . . . ?
C1H C4H C5H C15F 178.4(4) . . . . ?
C1H C4H C5H C10H -58.4(5) . . . . ?
C1H C4H C5H C8H 58.0(5) . . . . ?
C14G C15G C6H C3H 129.4(5) . . . . ?
C16G C15G C6H C3H -52.1(6) . . . . ?
C14G C15G C6H C9H 8.3(6) . . . . ?
C16G C15G C6H C9H -173.3(4) . . . . ?
C14G C15G C6H C10H -110.9(5) . . . . ?
C16G C15G C6H C10H 67.5(6) . . . . ?
C1H C3H C6H C15G 177.2(4) . . . . ?
C1H C3H C6H C9H -59.3(5) . . . . ?
C1H C3H C6H C10H 57.9(5) . . . . ?
C1H C2H C7H C9H 60.7(5) . . . . ?
C1H C2H C7H C8H -60.0(5) . . . . ?
C9H C7H C8H C5H -60.4(5) . . . . ?
C2H C7H C8H C5H 60.7(5) . . . . ?
C15F C5H C8H C7H 178.4(4) . . . . ?
C4H C5H C8H C7H -58.2(5) . . . . ?
C10H C5H C8H C7H 58.0(5) . . . . ?
C8H C7H C9H C6H 61.2(5) . . . . ?
C2H C7H C9H C6H -60.0(5) . . . . ?
C15G C6H C9H C7H -179.2(4) . . . . ?
C3H C6H C9H C7H 58.1(5) . . . . ?
C10H C6H C9H C7H -59.8(5) . . . . ?
C15G C6H C10H C5H -179.1(4) . . . . ?
C3H C6H C10H C5H -58.3(5) . . . . ?
C9H C6H C10H C5H 59.1(5) . . . . ?
C15F C5H C10H C6H -177.2(4) . . . . ?
C4H C5H C10H C6H 58.1(5) . . . . ?
C8H C5H C10H C6H -58.1(5) . . . . ?

_refine_diff_density_max         1.566
_refine_diff_density_min         -0.748
_refine_diff_density_rms         0.101


_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: '
