# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

data_global
_audit_creation_method                  'APEX2 v2014.9-0'

_publ_requested_journal                 ?

_publ_contact_author_name               'Ralf Haiges'
_publ_contact_author_address            
;
University of Southern California
Loker Hydrocarbon Research Institute and Department of Chemistry
Los Angeles, CA 90089
USA
;
_publ_contact_author_email              haiges@usc.edu
_publ_contact_author_fax                ?
_publ_contact_author_phone              '+1 (213) 740-3197'

_publ_section_title                     
;
;
_publ_section_abstract                  
;
;
_publ_section_references                
;
;
_publ_section_comment                   
;
;

data_AgFDNTzNH3
_chemical_name_systematic               ?
_chemical_name_common                   ?
_chemical_formula_moiety                'C24 H18 Ag12 F12 N78 O48'
_chemical_formula_sum                   'C24 H18 Ag12 F12 N78 O48'
_chemical_formula_iupac                 ?
_chemical_formula_weight                3689.60

_chemical_melting_point                 ?

_space_group_crystal_system             triclinic
_space_group_name_H-M_alt               'P -1'
_space_group_name_Hall                  '-P 1'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x, -y, -z'

_cell_length_a                          15.4270(10)
_cell_length_b                          15.4526(10)
_cell_length_c                          20.5225(13)
_cell_angle_alpha                       82.7270(10)
_cell_angle_beta                        88.1560(10)
_cell_angle_gamma                       82.6690(10)
_cell_volume                            4812.6(5)
_cell_formula_units_Z                   2
_cell_measurement_reflns_used           9868
_cell_measurement_theta_min             2.2662
_cell_measurement_theta_max             30.4904
_cell_measurement_temperature           100.(2)

_exptl_crystal_description              rod
_exptl_crystal_colour                   'clear colourless'
_exptl_crystal_size_max                 0.100
_exptl_crystal_size_mid                 0.030
_exptl_crystal_size_min                 0.020
_exptl_crystal_density_diffrn           2.546
_exptl_crystal_density_meas             ?
_exptl_crystal_density_method           'not measured'
_exptl_crystal_F_000                    3528

_exptl_absorpt_coefficient_mu           2.540
_exptl_absorpt_correction_type          multi-scan
_exptl_absorpt_process_details          'Bruker TWINABS V2014/4'
_exptl_absorpt_correction_T_min         0.79
_exptl_absorpt_correction_T_max         0.95

_exptl_special_details                  
;
 The crystal specimen consisted of two non-merohedral twin domains.
 The reflection data was integrated as two individual components
 and the data scaled with TWINABS.
; 

_diffrn_ambient_temperature             100.(2)

_diffrn_source                          'fine-focus tube'
_diffrn_source_type                     ?

_diffrn_radiation_type                  'MoK\a '
_diffrn_radiation_wavelength            0.71073
_diffrn_radiation_monochromator         'TRIUMPH curved-crystal'

_diffrn_measurement_device_type         'Bruker APEX II CCD'
_diffrn_measurement_method              'omega- and phi-scans'

_diffrn_detector_area_resol_mean        8.3333

_diffrn_reflns_number                   22050
_diffrn_reflns_av_R_equivalents         0.0939
_diffrn_reflns_av_unetI/netI            0.1087
_diffrn_reflns_theta_min                1.00
_diffrn_reflns_theta_max                27.48
_diffrn_reflns_theta_full               27.48
_diffrn_measured_fraction_theta_max     1.000
_diffrn_measured_fraction_theta_full    1.000
_diffrn_reflns_limit_h_min              -20
_diffrn_reflns_limit_h_max              20
_diffrn_reflns_limit_k_min              -20
_diffrn_reflns_limit_k_max              20
_diffrn_reflns_limit_l_min              -27
_diffrn_reflns_limit_l_max              27

_refine_special_details                 'Refined as a 2-component twin.'

_reflns_number_total                    22050
_reflns_number_gt                       13724
_reflns_threshold_expression            'I > 2σ(I)'

_refine_ls_structure_factor_coef        Fsqd
_refine_ls_matrix_type                  full
_refine_ls_R_factor_all                 0.1174
_refine_ls_R_factor_gt                  0.0584
_refine_ls_wR_factor_gt                 0.0977
_refine_ls_wR_factor_ref                0.1106
_refine_ls_goodness_of_fit_ref          0.992
_refine_ls_restrained_S_all             0.996
_refine_ls_number_reflns                22050
_refine_ls_number_parameters            1576
_refine_ls_number_restraints            66
_refine_ls_number_constraints           ?
_refine_ls_hydrogen_treatment           constr
_refine_ls_weighting_scheme             calc
_refine_ls_weighting_details            
    'w=1/[σ²(Fo²)+(0.0471P)²] where P=(Fo²+2Fc²)/3'

_atom_sites_solution_hydrogens          geom
_atom_sites_solution_primary            ?
_atom_sites_solution_secondary          ?

_refine_ls_shift/su_max                 0.001
_refine_ls_shift/su_mean                0.000
_refine_diff_density_max                1.387
_refine_diff_density_min                -2.437
_refine_ls_extinction_method            none
_refine_ls_extinction_coef              ?

loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    Ag Ag -0.8971 1.1015
     'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_computing_data_collection              
    'Bruker Instrument Service v2012.12.0.3'
_computing_cell_refinement              'APEX2 v2014.9-0 (Bruker AXS)'
_computing_data_reduction               'SAINT V8.34A (Bruker AXS, 2013)'
_computing_structure_solution           'SHELXTL XT 2014/4 (Bruker AXS)'
_computing_structure_refinement         'SHELXTL XL 2014/6 (Bruker AXS)'
_computing_molecular_graphics           ?
_computing_publication_material         'SHELXTL XL 2014/6 (Bruker AXS)'

loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags_adp
    _atom_site_refinement_flags_occupancy
    _atom_site_refinement_flags_posn
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C1 -0.2009(5) -0.0742(4) 0.5918(4) 0.0132(16) Uani d . . . 1 . .
    C C2 -0.2707(5) -0.1194(5) 0.6252(4) 0.0166(17) Uani d . . . 1 . .
    C C3 0.1993(4) -0.0203(4) 0.7584(3) 0.0118(15) Uani d . . . 1 . .
    C C4 0.2211(5) -0.0472(5) 0.8280(4) 0.0167(17) Uani d . . . 1 . .
    C C5 -0.0079(5) 0.2542(4) 0.5294(3) 0.0123(15) Uani d . . . 1 . .
    C C6 -0.1021(5) 0.2498(4) 0.5206(4) 0.0172(17) Uani d . . . 1 . .
    C C7 0.2575(5) 0.4702(5) 0.2924(4) 0.0138(16) Uani d . . . 1 . .
    C C8 0.2281(5) 0.4883(5) 0.2237(4) 0.0196(18) Uani d . . . 1 . .
    C C9 0.4916(5) 0.2132(5) 0.4966(3) 0.0126(15) Uani d . . . 1 . .
    C C10 0.5866(5) 0.2111(5) 0.4842(4) 0.0202(18) Uani d . . . 1 . .
    C C11 0.6864(5) 0.5377(5) 0.3734(4) 0.0165(17) Uani d . . . 1 . .
    C C12 0.7500(5) 0.5639(5) 0.3222(4) 0.0187(17) Uani d . . . 1 . .
    C C13 0.4628(5) 0.6789(5) 0.2402(3) 0.0131(15) Uani d . . . 1 . .
    C C14 0.4192(5) 0.6938(5) 0.3044(4) 0.0204(18) Uani d . . . 1 . .
    C C15 0.4683(5) 0.2674(5) 0.0881(4) 0.0149(16) Uani d . . . 1 . .
    C C16 0.4359(5) 0.1861(5) 0.1188(4) 0.0151(16) Uani d . . . 1 . .
    C C17 0.7530(5) 0.4980(4) 0.0266(3) 0.0127(15) Uani d . . . 1 . .
    C C18 0.7485(5) 0.4070(4) 0.0134(3) 0.0120(15) Uani d . . . 1 . .
    C C19 0.6914(5) 0.9931(5) -0.0148(4) 0.0170(17) Uani d . . . 1 . .
    C C20 0.6694(5) 1.0822(5) -0.0518(4) 0.0167(17) Uani d . . . 1 . .
    C C21 0.9797(4) 0.7732(5) -0.1954(4) 0.0151(16) Uani d . . . 1 . .
    C C22 1.0180(5) 0.7512(5) -0.2593(4) 0.0224(18) Uani d . . . 1 . .
    C C23 1.0161(5) 1.1999(4) -0.1288(4) 0.0144(16) Uani d . . . 1 . .
    C C24 1.0361(5) 1.2699(5) -0.1807(4) 0.0160(16) Uani d . . . 1 . .
    N N1 -0.1431(4) -0.0369(4) 0.6214(3) 0.0138(13) Uani d . . . 1 . .
    N N2 -0.0922(4) -0.0052(4) 0.5720(3) 0.0143(13) Uani d . . . 1 . .
    N N3 -0.1183(4) -0.0254(4) 0.5155(3) 0.0131(13) Uani d . . . 1 . .
    N N4 -0.1889(4) -0.0685(4) 0.5272(3) 0.0137(13) Uani d . . . 1 . .
    N N5 -0.2526(4) -0.2201(4) 0.6285(3) 0.0170(14) Uani d . . . 1 . .
    N N6 -0.2750(4) -0.1029(4) 0.6980(3) 0.0170(14) Uani d . . . 1 . .
    N N7 0.1223(4) -0.0237(4) 0.7320(3) 0.0138(13) Uani d . . . 1 . .
    N N8 0.1332(4) 0.0099(4) 0.6691(3) 0.0165(14) Uani d . . . 1 . .
    N N9 0.2134(4) 0.0315(4) 0.6596(3) 0.0148(14) Uani d . . . 1 . .
    N N10 0.2568(4) 0.0139(4) 0.7164(3) 0.0153(14) Uani d . . . 1 . .
    N N11 0.1464(4) -0.0931(4) 0.8639(3) 0.0188(14) Uani d . . . 1 . .
    N N12 0.3044(4) -0.1127(4) 0.8369(3) 0.0192(15) Uani d . . . 1 . .
    N N13 0.0446(4) 0.1909(4) 0.5617(3) 0.0147(13) Uani d . . . 1 . .
    N N14 0.1234(4) 0.2204(4) 0.5589(3) 0.0158(14) Uani d . . . 1 . .
    N N15 0.1143(4) 0.3004(4) 0.5259(3) 0.0136(13) Uani d . . . 1 . .
    N N16 0.0312(4) 0.3240(4) 0.5060(3) 0.0162(14) Uani d . . . 1 . .
    N N17 -0.1197(4) 0.1885(4) 0.4708(3) 0.0205(15) Uani d . . . 1 . .
    N N18 -0.1481(4) 0.3412(4) 0.4938(4) 0.0248(16) Uani d . . . 1 . .
    N N19 0.2023(4) 0.4629(4) 0.3435(3) 0.0146(13) Uani d . . . 1 . .
    N N20 0.2551(4) 0.4481(4) 0.3961(3) 0.0159(14) Uani d . . . 1 . .
    N N21 0.3382(4) 0.4467(4) 0.3759(3) 0.0131(13) Uani d . . . 1 . .
    N N22 0.3418(4) 0.4611(4) 0.3101(3) 0.0136(13) Uani d . . . 1 . .
    N N23 0.2208(4) 0.4055(4) 0.1909(3) 0.0210(15) Uani d . . . 1 . .
    N N24 0.2943(4) 0.5358(5) 0.1803(3) 0.0238(16) Uani d . . . 1 . .
    N N25 0.4384(4) 0.2875(4) 0.4850(3) 0.0129(13) Uani d . . . 1 . .
    N N26 0.3591(4) 0.2647(4) 0.5045(3) 0.0144(13) Uani d . . . 1 . .
    N N27 0.3681(4) 0.1804(4) 0.5262(3) 0.0113(13) Uani d U . . 1 . .
    N N28 0.4529(4) 0.1447(4) 0.5220(3) 0.0154(14) Uani d . . . 1 . .
    N N29 0.6082(5) 0.2363(5) 0.4108(4) 0.0289(17) Uani d . . . 1 . .
    N N30 0.6334(4) 0.1173(4) 0.5028(3) 0.0209(15) Uani d . . . 1 . .
    N N31 0.6165(4) 0.4997(4) 0.3608(3) 0.0187(14) Uani d . . . 1 . .
    N N32 0.5785(4) 0.4847(4) 0.4199(3) 0.0147(14) Uani d U . . 1 . .
    N N33 0.6239(4) 0.5137(4) 0.4650(3) 0.0154(14) Uani d . . . 1 . .
    N N34 0.6935(4) 0.5473(4) 0.4361(3) 0.0139(13) Uani d . . . 1 . .
    N N35 0.7816(5) 0.6509(5) 0.3304(3) 0.0251(16) Uani d U . . 1 . .
    N N36 0.7084(4) 0.5752(5) 0.2542(3) 0.0235(16) Uani d . . . 1 . .
    N N37 0.4726(4) 0.6000(4) 0.2191(3) 0.0138(13) Uani d . . . 1 . .
    N N38 0.5103(4) 0.6168(4) 0.1593(3) 0.0155(14) Uani d . . . 1 . .
    N N39 0.5194(4) 0.7007(4) 0.1481(3) 0.0148(13) Uani d . . . 1 . .
    N N40 0.4900(4) 0.7415(4) 0.1996(3) 0.0143(13) Uani d . . . 1 . .
    N N41 0.3202(5) 0.7210(6) 0.2985(5) 0.046(2) Uani d . . . 1 . .
    N N42 0.4564(6) 0.7705(6) 0.3314(4) 0.046(2) Uani d U . . 1 . .
    N N43 0.4975(4) 0.3268(4) 0.1209(3) 0.0170(14) Uani d . . . 1 . .
    N N44 0.5149(4) 0.3903(4) 0.0731(3) 0.0169(14) Uani d . . . 1 . .
    N N45 0.4973(4) 0.3685(4) 0.0149(3) 0.0149(14) Uani d U . . 1 . .
    N N46 0.4680(4) 0.2901(4) 0.0234(3) 0.0165(14) Uani d . . . 1 . .
    N N47 0.3347(4) 0.1912(4) 0.1144(3) 0.0149(14) Uani d . . . 1 . .
    N N48 0.4529(4) 0.1700(5) 0.1931(3) 0.0217(16) Uani d . . . 1 . .
    N N49 0.6858(4) 0.5482(4) 0.0507(3) 0.0137(13) Uani d . . . 1 . .
    N N50 0.7148(4) 0.6248(4) 0.0531(3) 0.0148(14) Uani d U . . 1 . .
    N N51 0.7979(4) 0.6201(4) 0.0317(3) 0.0156(14) Uani d . . . 1 . .
    N N52 0.8226(4) 0.5402(4) 0.0142(3) 0.0123(13) Uani d . . . 1 . .
    N N53 0.7255(4) 0.3458(4) 0.0740(3) 0.0145(13) Uani d . . . 1 . .
    N N54 0.8369(4) 0.3671(4) -0.0116(3) 0.0188(15) Uani d . . . 1 . .
    N N55 0.6312(4) 0.9492(4) 0.0166(3) 0.0133(13) Uani d . . . 1 . .
    N N56 0.6734(4) 0.8690(4) 0.0338(3) 0.0116(13) Uani d . . . 1 . .
    N N57 0.7571(4) 0.8661(4) 0.0140(3) 0.0143(13) Uani d . . . 1 . .
    N N58 0.7703(4) 0.9446(4) -0.0178(3) 0.0155(14) Uani d . . . 1 . .
    N N59 0.6776(5) 1.0758(4) -0.1270(3) 0.0223(16) Uani d . . . 1 . .
    N N60 0.7310(5) 1.1500(4) -0.0409(3) 0.0231(16) Uani d . . . 1 . .
    N N61 0.9651(4) 0.7172(4) -0.1429(3) 0.0187(14) Uani d . . . 1 . .
    N N62 0.9317(4) 0.7679(4) -0.0974(3) 0.0161(14) Uani d . . . 1 . .
    N N63 0.9278(4) 0.8517(4) -0.1231(3) 0.0162(14) Uani d . . . 1 . .
    N N64 0.9571(4) 0.8568(4) -0.1850(3) 0.0135(13) Uani d . . . 1 . .
    N N65 1.1159(5) 0.7113(7) -0.2519(4) 0.050(2) Uani d . . . 1 . .
    N N66 0.9810(4) 0.6783(4) -0.2889(3) 0.0253(16) Uani d . . . 1 . .
    N N67 0.9652(4) 1.1388(4) -0.1384(3) 0.0196(15) Uani d . . . 1 . .
    N N68 0.9639(4) 1.0915(4) -0.0784(3) 0.0180(14) Uani d . . . 1 . .
    N N69 1.0100(4) 1.1231(4) -0.0368(3) 0.0144(13) Uani d . . . 1 . .
    N N70 1.0441(4) 1.1936(4) -0.0680(3) 0.0129(13) Uani d . . . 1 . .
    N N71 1.1310(4) 1.2874(5) -0.1778(3) 0.0225(16) Uani d . . . 1 . .
    N N72 1.0228(5) 1.2426(5) -0.2494(3) 0.0252(16) Uani d U . . 1 . .
    N N73 0.5918(4) 0.3561(4) 0.2465(3) 0.0265(16) Uani d . . . 1 . .
    H H73A 0.5892 0.3397 0.2056 0.04 Uiso calc U . R 1 . .
    H H73B 0.5937 0.3077 0.2769 0.04 Uiso calc U . R 1 . .
    H H73C 0.6406 0.3827 0.2494 0.04 Uiso calc U . R 1 . .
    N N74 0.8739(4) 1.1062(4) -0.2775(3) 0.0321(18) Uani d . . . 1 . .
    H H74A 0.8445 1.1293 -0.2433 0.048 Uiso calc U . R 1 . .
    H H74B 0.835 1.0944 -0.3066 0.048 Uiso calc U . R 1 . .
    H H74C 0.9083 1.1454 -0.2979 0.048 Uiso calc U . R 1 . .
    N N75 0.4020(4) 0.1055(5) 0.8162(3) 0.0313(18) Uani d . . . 1 . .
    H H75A 0.4445 0.1409 0.8179 0.047 Uiso calc U . R 1 . .
    H H75B 0.4093 0.0603 0.8494 0.047 Uiso calc U . R 1 . .
    H H75C 0.3487 0.1372 0.8206 0.047 Uiso calc U . R 1 . .
    N N76 0.4762(4) -0.0013(4) 0.6408(3) 0.0240(16) Uani d . . . 1 . .
    H H76A 0.4573 -0.0537 0.6368 0.036 Uiso calc U . R 1 . .
    H H76B 0.5349 -0.0096 0.6473 0.036 Uiso calc U . R 1 . .
    H H76C 0.4642 0.0363 0.6034 0.036 Uiso calc U . R 1 . .
    N N77 0.0119(5) 0.5125(4) 0.3946(3) 0.0276(16) Uani d . . . 1 . .
    H H77A -0.0152 0.5659 0.3773 0.041 Uiso calc U . R 1 . .
    H H77B -0.0135 0.4692 0.3793 0.041 Uiso calc U . R 1 . .
    H H77C 0.0694 0.5078 0.3826 0.041 Uiso calc U . R 1 . .
    N N78 -0.0030(4) 0.4828(4) 0.1056(3) 0.0253(16) Uani d . . . 1 . .
    H H78A 0.0043 0.4244 0.1206 0.038 Uiso calc U . R 1 . .
    H H78B -0.0553 0.5079 0.1203 0.038 Uiso calc U . R 1 . .
    H H78C 0.0409 0.5088 0.1207 0.038 Uiso calc U . R 1 . .
    O O1 -0.3171(4) -0.2597(3) 0.6419(3) 0.0266(13) Uani d . . . 1 . .
    O O2 -0.1788(4) -0.2529(3) 0.6172(3) 0.0331(15) Uani d . . . 1 . .
    O O3 -0.3322(4) -0.0482(4) 0.7134(3) 0.0310(14) Uani d . . . 1 . .
    O O4 -0.2197(4) -0.1476(4) 0.7339(3) 0.0278(14) Uani d . . . 1 . .
    O O5 0.0941(3) -0.0472(4) 0.8935(3) 0.0312(15) Uani d . . . 1 . .
    O O6 0.1476(3) -0.1711(4) 0.8584(3) 0.0275(14) Uani d . . . 1 . .
    O O7 0.3469(3) -0.1093(3) 0.8852(3) 0.0224(13) Uani d . . . 1 . .
    O O8 0.3181(3) -0.1630(3) 0.7959(3) 0.0226(12) Uani d . . . 1 . .
    O O9 -0.1943(4) 0.1693(4) 0.4704(3) 0.0361(16) Uani d . . . 1 . .
    O O10 -0.0588(4) 0.1626(3) 0.4374(3) 0.0244(13) Uani d . . . 1 . .
    O O11 -0.1698(4) 0.3905(4) 0.5339(3) 0.0443(17) Uani d . . . 1 . .
    O O12 -0.1554(4) 0.3563(4) 0.4345(3) 0.0354(15) Uani d . . . 1 . .
    O O13 0.1857(3) 0.4166(4) 0.1387(3) 0.0269(13) Uani d . . . 1 . .
    O O14 0.2532(4) 0.3353(4) 0.2212(3) 0.0379(16) Uani d . . . 1 . .
    O O15 0.2850(4) 0.6143(4) 0.1779(3) 0.0328(15) Uani d . . . 1 . .
    O O16 0.3521(4) 0.4885(4) 0.1546(3) 0.0331(15) Uani d . . . 1 . .
    O O17 0.6655(4) 0.2819(4) 0.3982(3) 0.0422(17) Uani d . . . 1 . .
    O O18 0.5618(4) 0.2087(4) 0.3724(3) 0.0334(15) Uani d . . . 1 . .
    O O19 0.6607(4) 0.1030(4) 0.5586(3) 0.0329(15) Uani d . . . 1 . .
    O O20 0.6368(4) 0.0668(4) 0.4617(3) 0.0325(15) Uani d . . . 1 . .
    O O21 0.8594(4) 0.6569(4) 0.3219(3) 0.0398(16) Uani d . . . 1 . .
    O O22 0.7260(4) 0.7084(4) 0.3466(3) 0.0388(16) Uani d . . . 1 . .
    O O23 0.7193(4) 0.5123(4) 0.2250(3) 0.0391(16) Uani d . . . 1 . .
    O O24 0.6677(4) 0.6478(4) 0.2369(3) 0.0391(16) Uani d . . . 1 . .
    O O25 0.2768(6) 0.6990(7) 0.3460(4) 0.100(4) Uani d . . . 1 . .
    O O26 0.2967(5) 0.7652(5) 0.2466(4) 0.056(2) Uani d . . . 1 . .
    O O27 0.5236(6) 0.7472(6) 0.3585(4) 0.076(3) Uani d U . . 1 . .
    O O28 0.4137(6) 0.8421(5) 0.3209(4) 0.070(2) Uani d U . . 1 . .
    O O29 0.3056(3) 0.1230(3) 0.1320(2) 0.0226(13) Uani d . . . 1 . .
    O O30 0.2952(3) 0.2616(3) 0.0936(3) 0.0229(13) Uani d . . . 1 . .
    O O31 0.5071(4) 0.1081(5) 0.2117(3) 0.0451(18) Uani d . . . 1 . .
    O O32 0.4097(4) 0.2192(4) 0.2255(3) 0.0302(14) Uani d . . . 1 . .
    O O33 0.6987(4) 0.2777(3) 0.0637(3) 0.0259(13) Uani d . . . 1 . .
    O O34 0.7359(4) 0.3692(4) 0.1272(3) 0.0306(14) Uani d . . . 1 . .
    O O35 0.8478(4) 0.3745(4) -0.0706(3) 0.0280(14) Uani d . . . 1 . .
    O O36 0.8893(4) 0.3353(4) 0.0303(3) 0.0311(14) Uani d . . . 1 . .
    O O37 0.6095(4) 1.0738(4) -0.1553(3) 0.0374(16) Uani d . . . 1 . .
    O O38 0.7520(4) 1.0677(3) -0.1483(3) 0.0253(13) Uani d . . . 1 . .
    O O39 0.7136(4) 1.2201(3) -0.0754(3) 0.0400(17) Uani d . . . 1 . .
    O O40 0.7861(4) 1.1299(3) -0.0007(3) 0.0220(13) Uani d . . . 1 . .
    O O41 1.1696(5) 0.7552(6) -0.2768(4) 0.076(3) Uani d U . . 1 . .
    O O42 1.1261(5) 0.6399(6) -0.2197(4) 0.067(2) Uani d U . . 1 . .
    O O43 1.0073(4) 0.6678(4) -0.3436(3) 0.0425(17) Uani d . . . 1 . .
    O O44 0.9290(5) 0.6399(5) -0.2571(3) 0.058(2) Uani d . . . 1 . .
    O O45 1.1432(4) 1.3639(4) -0.1798(3) 0.0310(14) Uani d . . . 1 . .
    O O46 1.1867(4) 1.2248(4) -0.1753(3) 0.0369(16) Uani d . . . 1 . .
    O O47 0.9687(4) 1.2887(4) -0.2839(3) 0.0414(17) Uani d . . . 1 . .
    O O48 1.0686(4) 1.1758(4) -0.2621(3) 0.0378(16) Uani d . . . 1 . .
    F F1 -0.3488(3) -0.0959(3) 0.6003(2) 0.0196(10) Uani d . . . 1 . .
    F F2 0.2317(3) 0.0208(3) 0.8608(2) 0.0212(10) Uani d . . . 1 . .
    F F3 -0.1432(3) 0.2226(3) 0.5760(2) 0.0259(11) Uani d . . . 1 . .
    F F4 0.1501(3) 0.5356(3) 0.2180(2) 0.0257(11) Uani d . . . 1 . .
    F F5 0.6236(3) 0.2654(3) 0.5173(2) 0.0257(11) Uani d . . . 1 . .
    F F6 0.8229(3) 0.5050(3) 0.3203(2) 0.0327(12) Uani d . . . 1 . .
    F F7 0.4288(4) 0.6244(3) 0.3492(2) 0.0412(14) Uani d . . . 1 . .
    F F8 0.4683(3) 0.1147(3) 0.0924(2) 0.0247(11) Uani d . . . 1 . .
    F F9 0.6891(3) 0.4025(3) -0.0315(2) 0.0179(9) Uani d . . . 1 . .
    F F10 0.5886(3) 1.1170(3) -0.0394(2) 0.0294(11) Uani d . . . 1 . .
    F F11 1.0150(4) 0.8197(3) -0.3042(2) 0.0431(14) Uani d . . . 1 . .
    F F12 0.9869(3) 1.3462(3) -0.1781(2) 0.0285(11) Uani d . . . 1 . .
    Ag Ag1 0.03830(4) 0.03496(4) 0.58600(3) 0.01517(13) Uani d . . . 1 . .
    Ag Ag2 0.25363(3) 0.11380(4) 0.56713(3) 0.01490(13) Uani d . . . 1 . .
    Ag Ag3 0.41036(4) 0.05370(4) 0.72333(3) 0.02421(15) Uani d . . . 1 . .
    Ag Ag4 0.22602(4) 0.37803(4) 0.49944(3) 0.01564(13) Uani d . . . 1 . .
    Ag Ag5 0.45456(3) 0.43153(4) 0.44271(3) 0.01427(13) Uani d . . . 1 . .
    Ag Ag6 0.47699(4) 0.44687(4) 0.26441(3) 0.02209(14) Uani d . . . 1 . .
    Ag Ag7 0.53969(4) 0.52635(3) 0.08143(3) 0.01521(13) Uani d . . . 1 . .
    Ag Ag8 0.60913(4) 0.75007(3) 0.06546(3) 0.01413(13) Uani d . . . 1 . .
    Ag Ag9 0.86788(4) 0.73729(4) 0.00471(3) 0.01619(13) Uani d . . . 1 . .
    Ag Ag10 0.90825(4) 0.96458(3) -0.05522(3) 0.01610(13) Uani d . . . 1 . .
    Ag Ag11 0.95380(6) 0.98725(5) -0.24164(4) 0.0459(2) Uani d . . . 1 . .
    Ag Ag12 0 0.5 0.5 0.0247(2) Uani d . P S 1 . .
    Ag Ag13 0 0.5 0 0.0220(2) Uani d . P S 1 . .


_geom_special_details                   
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 N1 . 1.324(9) ?
    C1 N4 . 1.325(8) ?
    C1 C2 . 1.463(10) ?
    C2 F1 . 1.313(8) ?
    C2 N5 . 1.540(9) ?
    C2 N6 . 1.545(9) ?
    C3 N10 . 1.329(9) ?
    C3 N7 . 1.331(9) ?
    C3 C4 . 1.473(9) ?
    C4 F2 . 1.348(8) ?
    C4 N12 . 1.531(9) ?
    C4 N11 . 1.547(9) ?
    C5 N13 . 1.313(9) ?
    C5 N16 . 1.332(8) ?
    C5 C6 . 1.482(10) ?
    C6 F3 . 1.331(8) ?
    C6 N17 . 1.531(9) ?
    C6 N18 . 1.541(9) ?
    C7 N19 . 1.332(9) ?
    C7 N22 . 1.347(9) ?
    C7 C8 . 1.477(10) ?
    C8 F4 . 1.327(8) ?
    C8 N24 . 1.530(10) ?
    C8 N23 . 1.536(10) ?
    C9 N28 . 1.323(8) ?
    C9 N25 . 1.323(9) ?
    C9 C10 . 1.478(10) ?
    C10 F5 . 1.336(9) ?
    C10 N30 . 1.542(9) ?
    C10 N29 . 1.542(10) ?
    C11 N34 . 1.322(9) ?
    C11 N31 . 1.339(9) ?
    C11 C12 . 1.470(10) ?
    C12 F6 . 1.357(9) ?
    C12 N35 . 1.518(10) ?
    C12 N36 . 1.535(10) ?
    C13 N40 . 1.297(9) ?
    C13 N37 . 1.335(9) ?
    C13 C14 . 1.490(10) ?
    C14 F7 . 1.318(8) ?
    C14 N41 . 1.536(11) ?
    C14 N42 . 1.550(11) ?
    C15 N46 . 1.331(9) ?
    C15 N43 . 1.333(9) ?
    C15 C16 . 1.472(10) ?
    C16 F8 . 1.325(8) ?
    C16 N48 . 1.538(9) ?
    C16 N47 . 1.557(9) ?
    C17 N52 . 1.327(8) ?
    C17 N49 . 1.334(9) ?
    C17 C18 . 1.477(9) ?
    C18 F9 . 1.335(8) ?
    C18 N53 . 1.524(9) ?
    C18 N54 . 1.524(9) ?
    C19 N55 . 1.323(9) ?
    C19 N58 . 1.349(9) ?
    C19 C20 . 1.491(10) ?
    C20 F10 . 1.323(8) ?
    C20 N60 . 1.543(9) ?
    C20 N59 . 1.558(9) ?
    C21 N61 . 1.325(9) ?
    C21 N64 . 1.336(9) ?
    C21 C22 . 1.481(10) ?
    C22 F11 . 1.309(8) ?
    C22 N66 . 1.525(10) ?
    C22 N65 . 1.561(12) ?
    C23 N70 . 1.320(9) ?
    C23 N67 . 1.339(9) ?
    C23 C24 . 1.474(10) ?
    C24 F12 . 1.325(8) ?
    C24 N71 . 1.527(9) ?
    C24 N72 . 1.548(10) ?
    N1 N2 . 1.343(8) ?
    N2 N3 . 1.327(8) ?
    N2 Ag1 . 2.219(6) ?
    N3 N4 . 1.348(7) ?
    N3 Ag1 2_556 2.398(6) ?
    N4 Ag2 2_556 2.425(6) ?
    N5 O2 . 1.212(8) ?
    N5 O1 . 1.239(7) ?
    N6 O3 . 1.205(8) ?
    N6 O4 . 1.228(8) ?
    N7 N8 . 1.343(8) ?
    N7 Ag11 1_446 2.626(6) ?
    N8 N9 . 1.324(8) ?
    N8 Ag1 . 2.247(6) ?
    N9 N10 . 1.345(8) ?
    N9 Ag2 . 2.262(6) ?
    N10 Ag3 . 2.535(6) ?
    N11 O5 . 1.207(8) ?
    N11 O6 . 1.222(8) ?
    N12 O8 . 1.212(8) ?
    N12 O7 . 1.215(7) ?
    N13 N14 . 1.348(8) ?
    N13 Ag1 . 2.412(6) ?
    N14 N15 . 1.326(8) ?
    N14 Ag2 . 2.426(6) ?
    N15 N16 . 1.349(8) ?
    N15 Ag4 . 2.237(6) ?
    N17 O10 . 1.202(8) ?
    N17 O9 . 1.226(8) ?
    N18 O11 . 1.202(8) ?
    N18 O12 . 1.216(8) ?
    N19 N20 . 1.352(8) ?
    N20 N21 . 1.332(8) ?
    N20 Ag4 . 2.314(6) ?
    N21 N22 . 1.341(7) ?
    N21 Ag5 . 2.265(6) ?
    N22 Ag6 . 2.255(6) ?
    N23 O13 . 1.200(7) ?
    N23 O14 . 1.234(8) ?
    N24 O15 . 1.199(8) ?
    N24 O16 . 1.227(8) ?
    N25 N26 . 1.351(7) ?
    N25 Ag5 . 2.325(6) ?
    N26 N27 . 1.314(7) ?
    N26 Ag4 . 2.518(6) ?
    N27 N28 . 1.357(8) ?
    N27 Ag2 . 2.244(5) ?
    N29 O17 . 1.201(8) ?
    N29 O18 . 1.230(9) ?
    N30 O20 . 1.214(8) ?
    N30 O19 . 1.217(8) ?
    N31 N32 . 1.337(8) ?
    N32 N33 . 1.331(8) ?
    N32 Ag5 . 2.190(5) ?
    N33 N34 . 1.341(8) ?
    N33 Ag5 2_666 2.401(6) ?
    N34 Ag4 2_666 2.341(6) ?
    N35 O21 . 1.220(8) ?
    N35 O22 . 1.224(8) ?
    N36 O23 . 1.196(8) ?
    N36 O24 . 1.231(9) ?
    N37 N38 . 1.351(8) ?
    N37 Ag6 . 2.423(6) ?
    N38 N39 . 1.312(8) ?
    N38 Ag7 . 2.252(6) ?
    N39 N40 . 1.335(8) ?
    N39 Ag8 . 2.273(6) ?
    N41 O25 . 1.202(10) ?
    N41 O26 . 1.230(10) ?
    N42 O27 . 1.185(11) ?
    N42 O28 . 1.212(11) ?
    N43 N44 . 1.344(8) ?
    N44 N45 . 1.326(8) ?
    N44 Ag7 . 2.212(6) ?
    N45 N46 . 1.336(7) ?
    N45 Ag7 2_665 2.428(6) ?
    N46 Ag8 2_665 2.396(6) ?
    N47 O29 . 1.208(7) ?
    N47 O30 . 1.212(7) ?
    N48 O32 . 1.196(8) ?
    N48 O31 . 1.218(8) ?
    N49 N50 . 1.325(7) ?
    N49 Ag7 . 2.375(6) ?
    N50 N51 . 1.337(8) ?
    N50 Ag8 . 2.401(6) ?
    N51 N52 . 1.334(8) ?
    N51 Ag9 . 2.227(6) ?
    N53 O34 . 1.215(7) ?
    N53 O33 . 1.224(7) ?
    N54 O35 . 1.209(8) ?
    N54 O36 . 1.213(8) ?
    N55 N56 . 1.335(8) ?
    N56 N57 . 1.338(8) ?
    N56 Ag8 . 2.214(5) ?
    N57 N58 . 1.339(7) ?
    N57 Ag9 . 2.475(6) ?
    N58 Ag10 . 2.284(6) ?
    N59 O38 . 1.213(8) ?
    N59 O37 . 1.222(8) ?
    N60 O40 . 1.188(8) ?
    N60 O39 . 1.221(8) ?
    N61 N62 . 1.344(8) ?
    N62 N63 . 1.330(8) ?
    N62 Ag9 . 2.306(6) ?
    N63 N64 . 1.331(8) ?
    N63 Ag10 . 2.351(6) ?
    N64 Ag11 . 2.191(6) ?
    N65 O41 . 1.198(10) ?
    N65 O42 . 1.207(11) ?
    N66 O44 . 1.189(8) ?
    N66 O43 . 1.205(8) ?
    N67 N68 . 1.351(8) ?
    N68 N69 . 1.305(8) ?
    N68 Ag10 . 2.231(6) ?
    N69 N70 . 1.350(7) ?
    N69 Ag10 2_775 2.463(6) ?
    N70 Ag9 2_775 2.347(6) ?
    N71 O46 . 1.206(8) ?
    N71 O45 . 1.216(8) ?
    N72 O47 . 1.211(8) ?
    N72 O48 . 1.225(9) ?
    N73 Ag6 . 2.167(6) ?
    N73 H73A . 0.91 ?
    N73 H73B . 0.91 ?
    N73 H73C . 0.91 ?
    N74 Ag11 . 2.139(6) ?
    N74 H74A . 0.91 ?
    N74 H74B . 0.91 ?
    N74 H74C . 0.91 ?
    N75 Ag3 . 2.153(6) ?
    N75 H75A . 0.91 ?
    N75 H75B . 0.91 ?
    N75 H75C . 0.91 ?
    N76 Ag3 . 2.158(6) ?
    N76 H76A . 0.91 ?
    N76 H76B . 0.91 ?
    N76 H76C . 0.91 ?
    N77 Ag12 . 2.152(6) ?
    N77 H77A . 0.91 ?
    N77 H77B . 0.91 ?
    N77 H77C . 0.91 ?
    N78 Ag13 . 2.150(6) ?
    N78 H78A . 0.91 ?
    N78 H78B . 0.91 ?
    N78 H78C . 0.91 ?
    Ag1 N3 2_556 2.398(6) ?
    Ag2 N4 2_556 2.425(6) ?
    Ag4 N34 2_666 2.341(6) ?
    Ag5 N33 2_666 2.402(6) ?
    Ag7 N45 2_665 2.428(6) ?
    Ag8 N46 2_665 2.396(6) ?
    Ag9 N70 2_775 2.347(6) ?
    Ag10 N69 2_775 2.463(6) ?
    Ag11 N7 1_664 2.626(6) ?
    Ag12 N77 2_566 2.152(6) ?
    Ag13 N78 2_565 2.151(6) ?

loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    N1 C1 N4 . . 113.2(6) ?
    N1 C1 C2 . . 125.0(7) ?
    N4 C1 C2 . . 121.8(6) ?
    F1 C2 C1 . . 115.3(6) ?
    F1 C2 N5 . . 106.9(6) ?
    C1 C2 N5 . . 113.1(6) ?
    F1 C2 N6 . . 108.3(6) ?
    C1 C2 N6 . . 108.7(6) ?
    N5 C2 N6 . . 103.9(5) ?
    N10 C3 N7 . . 113.8(6) ?
    N10 C3 C4 . . 120.9(6) ?
    N7 C3 C4 . . 125.3(6) ?
    F2 C4 C3 . . 113.3(6) ?
    F2 C4 N12 . . 107.3(6) ?
    C3 C4 N12 . . 112.7(6) ?
    F2 C4 N11 . . 106.4(5) ?
    C3 C4 N11 . . 110.0(6) ?
    N12 C4 N11 . . 106.7(5) ?
    N13 C5 N16 . . 113.5(6) ?
    N13 C5 C6 . . 123.6(6) ?
    N16 C5 C6 . . 122.9(6) ?
    F3 C6 C5 . . 113.2(6) ?
    F3 C6 N17 . . 106.3(6) ?
    C5 C6 N17 . . 113.4(6) ?
    F3 C6 N18 . . 107.8(6) ?
    C5 C6 N18 . . 110.0(6) ?
    N17 C6 N18 . . 105.6(6) ?
    N19 C7 N22 . . 113.1(6) ?
    N19 C7 C8 . . 122.8(7) ?
    N22 C7 C8 . . 124.1(7) ?
    F4 C8 C7 . . 112.6(6) ?
    F4 C8 N24 . . 109.3(6) ?
    C7 C8 N24 . . 110.6(6) ?
    F4 C8 N23 . . 105.7(6) ?
    C7 C8 N23 . . 114.2(6) ?
    N24 C8 N23 . . 104.0(6) ?
    N28 C9 N25 . . 114.6(6) ?
    N28 C9 C10 . . 124.5(7) ?
    N25 C9 C10 . . 120.8(6) ?
    F5 C10 C9 . . 113.5(6) ?
    F5 C10 N30 . . 107.9(6) ?
    C9 C10 N30 . . 110.4(6) ?
    F5 C10 N29 . . 106.6(6) ?
    C9 C10 N29 . . 111.9(6) ?
    N30 C10 N29 . . 106.1(6) ?
    N34 C11 N31 . . 113.8(6) ?
    N34 C11 C12 . . 123.6(7) ?
    N31 C11 C12 . . 122.5(7) ?
    F6 C12 C11 . . 113.7(6) ?
    F6 C12 N35 . . 106.0(6) ?
    C11 C12 N35 . . 112.6(6) ?
    F6 C12 N36 . . 107.2(6) ?
    C11 C12 N36 . . 110.2(6) ?
    N35 C12 N36 . . 106.8(6) ?
    N40 C13 N37 . . 115.1(6) ?
    N40 C13 C14 . . 123.2(6) ?
    N37 C13 C14 . . 121.6(6) ?
    F7 C14 C13 . . 113.9(6) ?
    F7 C14 N41 . . 105.8(7) ?
    C13 C14 N41 . . 112.9(7) ?
    F7 C14 N42 . . 108.5(7) ?
    C13 C14 N42 . . 109.1(6) ?
    N41 C14 N42 . . 106.2(7) ?
    N46 C15 N43 . . 113.2(6) ?
    N46 C15 C16 . . 121.9(6) ?
    N43 C15 C16 . . 124.8(7) ?
    F8 C16 C15 . . 114.3(6) ?
    F8 C16 N48 . . 108.6(6) ?
    C15 C16 N48 . . 111.6(6) ?
    F8 C16 N47 . . 105.8(5) ?
    C15 C16 N47 . . 112.0(6) ?
    N48 C16 N47 . . 103.9(5) ?
    N52 C17 N49 . . 112.4(6) ?
    N52 C17 C18 . . 124.4(6) ?
    N49 C17 C18 . . 123.2(6) ?
    F9 C18 C17 . . 112.5(6) ?
    F9 C18 N53 . . 106.2(5) ?
    C17 C18 N53 . . 113.6(6) ?
    F9 C18 N54 . . 107.8(5) ?
    C17 C18 N54 . . 110.1(5) ?
    N53 C18 N54 . . 106.3(5) ?
    N55 C19 N58 . . 113.4(6) ?
    N55 C19 C20 . . 122.1(7) ?
    N58 C19 C20 . . 123.9(6) ?
    F10 C20 C19 . . 112.4(6) ?
    F10 C20 N60 . . 107.6(6) ?
    C19 C20 N60 . . 115.3(6) ?
    F10 C20 N59 . . 107.7(6) ?
    C19 C20 N59 . . 109.5(6) ?
    N60 C20 N59 . . 103.9(5) ?
    N61 C21 N64 . . 112.2(7) ?
    N61 C21 C22 . . 126.9(7) ?
    N64 C21 C22 . . 120.9(7) ?
    F11 C22 C21 . . 112.8(7) ?
    F11 C22 N66 . . 107.7(6) ?
    C21 C22 N66 . . 116.5(6) ?
    F11 C22 N65 . . 107.2(7) ?
    C21 C22 N65 . . 111.0(6) ?
    N66 C22 N65 . . 100.5(6) ?
    N70 C23 N67 . . 113.9(6) ?
    N70 C23 C24 . . 123.2(6) ?
    N67 C23 C24 . . 122.9(7) ?
    F12 C24 C23 . . 114.2(6) ?
    F12 C24 N71 . . 106.7(6) ?
    C23 C24 N71 . . 111.2(6) ?
    F12 C24 N72 . . 106.6(6) ?
    C23 C24 N72 . . 110.4(6) ?
    N71 C24 N72 . . 107.3(6) ?
    C1 N1 N2 . . 104.0(6) ?
    N3 N2 N1 . . 109.8(6) ?
    N3 N2 Ag1 . . 123.6(4) ?
    N1 N2 Ag1 . . 123.9(4) ?
    N2 N3 N4 . . 108.6(6) ?
    N2 N3 Ag1 . 2_556 129.2(4) ?
    N4 N3 Ag1 . 2_556 119.2(4) ?
    C1 N4 N3 . . 104.4(5) ?
    C1 N4 Ag2 . 2_556 138.9(4) ?
    N3 N4 Ag2 . 2_556 116.8(4) ?
    O2 N5 O1 . . 126.5(6) ?
    O2 N5 C2 . . 118.4(6) ?
    O1 N5 C2 . . 115.1(6) ?
    O3 N6 O4 . . 127.2(7) ?
    O3 N6 C2 . . 116.7(6) ?
    O4 N6 C2 . . 116.1(6) ?
    C3 N7 N8 . . 103.3(6) ?
    C3 N7 Ag11 . 1_446 142.9(5) ?
    N8 N7 Ag11 . 1_446 108.1(4) ?
    N9 N8 N7 . . 109.8(5) ?
    N9 N8 Ag1 . . 120.0(4) ?
    N7 N8 Ag1 . . 130.1(4) ?
    N8 N9 N10 . . 109.5(5) ?
    N8 N9 Ag2 . . 122.3(4) ?
    N10 N9 Ag2 . . 126.7(4) ?
    C3 N10 N9 . . 103.5(6) ?
    C3 N10 Ag3 . . 135.8(5) ?
    N9 N10 Ag3 . . 120.6(4) ?
    O5 N11 O6 . . 128.3(7) ?
    O5 N11 C4 . . 115.8(6) ?
    O6 N11 C4 . . 115.9(6) ?
    O8 N12 O7 . . 128.3(7) ?
    O8 N12 C4 . . 115.7(6) ?
    O7 N12 C4 . . 115.9(6) ?
    C5 N13 N14 . . 105.3(6) ?
    C5 N13 Ag1 . . 132.0(5) ?
    N14 N13 Ag1 . . 118.6(4) ?
    N15 N14 N13 . . 107.6(6) ?
    N15 N14 Ag2 . . 127.6(4) ?
    N13 N14 Ag2 . . 118.6(4) ?
    N14 N15 N16 . . 110.7(5) ?
    N14 N15 Ag4 . . 123.5(4) ?
    N16 N15 Ag4 . . 125.5(4) ?
    C5 N16 N15 . . 102.8(6) ?
    O10 N17 O9 . . 126.8(7) ?
    O10 N17 C6 . . 117.0(6) ?
    O9 N17 C6 . . 116.2(6) ?
    O11 N18 O12 . . 127.5(7) ?
    O11 N18 C6 . . 116.0(7) ?
    O12 N18 C6 . . 116.4(6) ?
    C7 N19 N20 . . 103.8(6) ?
    N21 N20 N19 . . 109.6(6) ?
    N21 N20 Ag4 . . 118.3(4) ?
    N19 N20 Ag4 . . 127.5(4) ?
    N20 N21 N22 . . 109.6(5) ?
    N20 N21 Ag5 . . 125.1(4) ?
    N22 N21 Ag5 . . 125.2(4) ?
    N21 N22 C7 . . 104.0(5) ?
    N21 N22 Ag6 . . 115.7(4) ?
    C7 N22 Ag6 . . 139.7(5) ?
    O13 N23 O14 . . 127.6(7) ?
    O13 N23 C8 . . 116.6(6) ?
    O14 N23 C8 . . 115.9(6) ?
    O15 N24 O16 . . 128.3(7) ?
    O15 N24 C8 . . 115.6(7) ?
    O16 N24 C8 . . 116.0(6) ?
    C9 N25 N26 . . 103.9(5) ?
    C9 N25 Ag5 . . 135.3(5) ?
    N26 N25 Ag5 . . 120.8(4) ?
    N27 N26 N25 . . 108.4(5) ?
    N27 N26 Ag4 . . 130.7(4) ?
    N25 N26 Ag4 . . 120.8(4) ?
    N26 N27 N28 . . 111.0(5) ?
    N26 N27 Ag2 . . 121.1(4) ?
    N28 N27 Ag2 . . 127.9(4) ?
    C9 N28 N27 . . 102.1(6) ?
    O17 N29 O18 . . 128.2(7) ?
    O17 N29 C10 . . 116.9(7) ?
    O18 N29 C10 . . 114.8(6) ?
    O20 N30 O19 . . 128.2(7) ?
    O20 N30 C10 . . 117.4(7) ?
    O19 N30 C10 . . 114.4(6) ?
    N32 N31 C11 . . 103.2(6) ?
    N33 N32 N31 . . 109.9(5) ?
    N33 N32 Ag5 . . 122.6(4) ?
    N31 N32 Ag5 . . 127.3(5) ?
    N32 N33 N34 . . 109.3(5) ?
    N32 N33 Ag5 . 2_666 118.1(4) ?
    N34 N33 Ag5 . 2_666 123.9(4) ?
    C11 N34 N33 . . 103.8(6) ?
    C11 N34 Ag4 . 2_666 138.5(5) ?
    N33 N34 Ag4 . 2_666 116.7(4) ?
    O21 N35 O22 . . 126.0(7) ?
    O21 N35 C12 . . 117.9(7) ?
    O22 N35 C12 . . 116.1(6) ?
    O23 N36 O24 . . 128.2(7) ?
    O23 N36 C12 . . 116.0(7) ?
    O24 N36 C12 . . 115.7(6) ?
    C13 N37 N38 . . 102.1(5) ?
    C13 N37 Ag6 . . 138.7(5) ?
    N38 N37 Ag6 . . 116.8(4) ?
    N39 N38 N37 . . 109.2(5) ?
    N39 N38 Ag7 . . 121.9(5) ?
    N37 N38 Ag7 . . 128.4(4) ?
    N38 N39 N40 . . 110.4(6) ?
    N38 N39 Ag8 . . 120.1(4) ?
    N40 N39 Ag8 . . 127.2(4) ?
    C13 N40 N39 . . 103.2(6) ?
    O25 N41 O26 . . 129.0(9) ?
    O25 N41 C14 . . 115.8(9) ?
    O26 N41 C14 . . 115.2(8) ?
    O27 N42 O28 . . 131.7(10) ?
    O27 N42 C14 . . 112.2(9) ?
    O28 N42 C14 . . 116.1(9) ?
    C15 N43 N44 . . 103.3(6) ?
    N45 N44 N43 . . 110.1(6) ?
    N45 N44 Ag7 . . 119.6(4) ?
    N43 N44 Ag7 . . 128.9(5) ?
    N44 N45 N46 . . 109.0(6) ?
    N44 N45 Ag7 . 2_665 124.3(4) ?
    N46 N45 Ag7 . 2_665 121.5(4) ?
    C15 N46 N45 . . 104.4(6) ?
    C15 N46 Ag8 . 2_665 134.5(5) ?
    N45 N46 Ag8 . 2_665 117.5(4) ?
    O29 N47 O30 . . 128.0(6) ?
    O29 N47 C16 . . 114.8(6) ?
    O30 N47 C16 . . 117.2(6) ?
    O32 N48 O31 . . 128.2(7) ?
    O32 N48 C16 . . 115.6(6) ?
    O31 N48 C16 . . 116.2(7) ?
    N50 N49 C17 . . 104.7(5) ?
    N50 N49 Ag7 . . 121.4(4) ?
    C17 N49 Ag7 . . 133.9(4) ?
    N49 N50 N51 . . 109.3(5) ?
    N49 N50 Ag8 . . 117.9(4) ?
    N51 N50 Ag8 . . 130.5(4) ?
    N52 N51 N50 . . 109.0(5) ?
    N52 N51 Ag9 . . 125.4(4) ?
    N50 N51 Ag9 . . 123.6(4) ?
    C17 N52 N51 . . 104.6(5) ?
    O34 N53 O33 . . 126.7(6) ?
    O34 N53 C18 . . 117.1(6) ?
    O33 N53 C18 . . 116.2(6) ?
    O35 N54 O36 . . 127.8(7) ?
    O35 N54 C18 . . 116.4(6) ?
    O36 N54 C18 . . 115.7(6) ?
    C19 N55 N56 . . 103.9(6) ?
    N55 N56 N57 . . 110.1(5) ?
    N55 N56 Ag8 . . 124.7(4) ?
    N57 N56 Ag8 . . 123.3(4) ?
    N56 N57 N58 . . 109.0(6) ?
    N56 N57 Ag9 . . 129.6(4) ?
    N58 N57 Ag9 . . 119.4(4) ?
    N57 N58 C19 . . 103.6(6) ?
    N57 N58 Ag10 . . 118.4(4) ?
    C19 N58 Ag10 . . 137.9(5) ?
    O38 N59 O37 . . 128.9(7) ?
    O38 N59 C20 . . 114.6(6) ?
    O37 N59 C20 . . 116.3(6) ?
    O40 N60 O39 . . 128.6(7) ?
    O40 N60 C20 . . 118.5(6) ?
    O39 N60 C20 . . 112.8(7) ?
    C21 N61 N62 . . 104.9(6) ?
    N63 N62 N61 . . 108.6(6) ?
    N63 N62 Ag9 . . 117.8(4) ?
    N61 N62 Ag9 . . 133.0(5) ?
    N62 N63 N64 . . 109.8(5) ?
    N62 N63 Ag10 . . 120.6(4) ?
    N64 N63 Ag10 . . 127.6(4) ?
    N63 N64 C21 . . 104.5(6) ?
    N63 N64 Ag11 . . 118.1(4) ?
    C21 N64 Ag11 . . 137.4(5) ?
    O41 N65 O42 . . 129.2(11) ?
    O41 N65 C22 . . 117.2(10) ?
    O42 N65 C22 . . 113.6(8) ?
    O44 N66 O43 . . 127.3(7) ?
    O44 N66 C22 . . 117.8(7) ?
    O43 N66 C22 . . 114.9(6) ?
    C23 N67 N68 . . 102.1(6) ?
    N69 N68 N67 . . 111.1(6) ?
    N69 N68 Ag10 . . 123.1(5) ?
    N67 N68 Ag10 . . 125.2(5) ?
    N68 N69 N70 . . 108.9(6) ?
    N68 N69 Ag10 . 2_775 125.1(4) ?
    N70 N69 Ag10 . 2_775 118.0(4) ?
    C23 N70 N69 . . 104.0(5) ?
    C23 N70 Ag9 . 2_775 139.9(5) ?
    N69 N70 Ag9 . 2_775 116.1(4) ?
    O46 N71 O45 . . 126.2(7) ?
    O46 N71 C24 . . 117.4(6) ?
    O45 N71 C24 . . 116.4(7) ?
    O47 N72 O48 . . 127.6(8) ?
    O47 N72 C24 . . 116.9(7) ?
    O48 N72 C24 . . 115.5(7) ?
    Ag6 N73 H73A . . 109.5 ?
    Ag6 N73 H73B . . 109.5 ?
    H73A N73 H73B . . 109.5 ?
    Ag6 N73 H73C . . 109.5 ?
    H73A N73 H73C . . 109.5 ?
    H73B N73 H73C . . 109.5 ?
    Ag11 N74 H74A . . 109.5 ?
    Ag11 N74 H74B . . 109.5 ?
    H74A N74 H74B . . 109.5 ?
    Ag11 N74 H74C . . 109.5 ?
    H74A N74 H74C . . 109.5 ?
    H74B N74 H74C . . 109.5 ?
    Ag3 N75 H75A . . 109.5 ?
    Ag3 N75 H75B . . 109.5 ?
    H75A N75 H75B . . 109.5 ?
    Ag3 N75 H75C . . 109.5 ?
    H75A N75 H75C . . 109.5 ?
    H75B N75 H75C . . 109.5 ?
    Ag3 N76 H76A . . 109.5 ?
    Ag3 N76 H76B . . 109.5 ?
    H76A N76 H76B . . 109.5 ?
    Ag3 N76 H76C . . 109.5 ?
    H76A N76 H76C . . 109.5 ?
    H76B N76 H76C . . 109.5 ?
    Ag12 N77 H77A . . 109.5 ?
    Ag12 N77 H77B . . 109.5 ?
    H77A N77 H77B . . 109.5 ?
    Ag12 N77 H77C . . 109.5 ?
    H77A N77 H77C . . 109.5 ?
    H77B N77 H77C . . 109.5 ?
    Ag13 N78 H78A . . 109.5 ?
    Ag13 N78 H78B . . 109.5 ?
    H78A N78 H78B . . 109.5 ?
    Ag13 N78 H78C . . 109.5 ?
    H78A N78 H78C . . 109.5 ?
    H78B N78 H78C . . 109.5 ?
    N2 Ag1 N8 . . 133.9(2) ?
    N2 Ag1 N3 . 2_556 107.10(19) ?
    N8 Ag1 N3 . 2_556 108.8(2) ?
    N2 Ag1 N13 . . 114.2(2) ?
    N8 Ag1 N13 . . 97.1(2) ?
    N3 Ag1 N13 2_556 . 84.79(19) ?
    N27 Ag2 N9 . . 139.5(2) ?
    N27 Ag2 N4 . 2_556 104.9(2) ?
    N9 Ag2 N4 . 2_556 109.4(2) ?
    N27 Ag2 N14 . . 108.9(2) ?
    N9 Ag2 N14 . . 97.0(2) ?
    N4 Ag2 N14 2_556 . 81.30(19) ?
    N75 Ag3 N76 . . 155.6(3) ?
    N75 Ag3 N10 . . 100.5(2) ?
    N76 Ag3 N10 . . 102.6(2) ?
    N15 Ag4 N20 . . 125.5(2) ?
    N15 Ag4 N34 . 2_666 130.8(2) ?
    N20 Ag4 N34 . 2_666 100.2(2) ?
    N15 Ag4 N26 . . 104.56(19) ?
    N20 Ag4 N26 . . 96.6(2) ?
    N34 Ag4 N26 2_666 . 85.09(19) ?
    N32 Ag5 N21 . . 126.4(2) ?
    N32 Ag5 N25 . . 126.1(2) ?
    N21 Ag5 N25 . . 94.3(2) ?
    N32 Ag5 N33 . 2_666 114.0(2) ?
    N21 Ag5 N33 . 2_666 96.4(2) ?
    N25 Ag5 N33 . 2_666 91.1(2) ?
    N73 Ag6 N22 . . 145.4(2) ?
    N73 Ag6 N37 . . 119.0(2) ?
    N22 Ag6 N37 . . 95.5(2) ?
    N44 Ag7 N38 . . 134.0(2) ?
    N44 Ag7 N49 . . 111.5(2) ?
    N38 Ag7 N49 . . 101.8(2) ?
    N44 Ag7 N45 . 2_665 114.93(19) ?
    N38 Ag7 N45 . 2_665 98.9(2) ?
    N49 Ag7 N45 . 2_665 84.0(2) ?
    N56 Ag8 N39 . . 138.3(2) ?
    N56 Ag8 N46 . 2_665 110.9(2) ?
    N39 Ag8 N46 . 2_665 97.3(2) ?
    N56 Ag8 N50 . . 107.3(2) ?
    N39 Ag8 N50 . . 104.0(2) ?
    N46 Ag8 N50 2_665 . 87.3(2) ?
    N51 Ag9 N62 . . 122.6(2) ?
    N51 Ag9 N70 . 2_775 130.4(2) ?
    N62 Ag9 N70 . 2_775 99.8(2) ?
    N51 Ag9 N57 . . 105.5(2) ?
    N62 Ag9 N57 . . 104.1(2) ?
    N70 Ag9 N57 2_775 . 85.50(19) ?
    N68 Ag10 N58 . . 127.5(2) ?
    N68 Ag10 N63 . . 123.5(2) ?
    N58 Ag10 N63 . . 97.8(2) ?
    N68 Ag10 N69 . 2_775 108.3(2) ?
    N58 Ag10 N69 . 2_775 98.2(2) ?
    N63 Ag10 N69 . 2_775 94.3(2) ?
    N74 Ag11 N64 . . 145.9(3) ?
    N74 Ag11 N7 . 1_664 117.9(2) ?
    N64 Ag11 N7 . 1_664 96.1(2) ?
    N77 Ag12 N77 2_566 . 180.0 ?
    N78 Ag13 N78 . 2_565 180.0 ?




