# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelxl
_database_code_depnum_ccdc_archive 'CCDC 945886'
_audit_update_record             
;
2015-03-27 deposited with the CCDC.
2015-04-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C31 H16 Dy F18 N2 O6'
_chemical_formula_weight         1016.96

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.636(2)
_cell_length_b                   13.080(3)
_cell_length_c                   13.390(3)
_cell_angle_alpha                100.04(3)
_cell_angle_beta                 100.45(3)
_cell_angle_gamma                90.01(3)
_cell_volume                     1972.4(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9482
_cell_measurement_theta_min      1.78
_cell_measurement_theta_max      27.85

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_exptl_crystal_density_meas      none
_exptl_crystal_density_diffrn    1.712
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             984
_exptl_absorpt_coefficient_mu    2.021
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6015
_exptl_absorpt_correction_T_max  0.6648
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            22905
_diffrn_reflns_av_R_equivalents  0.0319
_diffrn_reflns_av_unetI/netI     0.0384
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.78
_diffrn_reflns_theta_max         27.85
_reflns_number_total             9329
_reflns_number_gt                8639
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0623P)²+2.7127P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9329
_refine_ls_number_parameters     527
_refine_ls_number_restraints     96
_refine_ls_R_factor_all          0.0398
_refine_ls_R_factor_gt           0.0376
_refine_ls_wR_factor_ref         0.1041
_refine_ls_wR_factor_gt          0.1026
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_restrained_S_all      1.255
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2541(4) 1.0477(3) 0.2287(3) 0.0211(8) Uani 1 1 d . . .
H1 H 0.2277 1.0216 0.1590 0.025 Uiso 1 1 calc R . .
C2 C 0.2680(4) 1.1567(3) 0.2593(3) 0.0235(8) Uani 1 1 d . . .
C3 C 0.2379(5) 1.2235(4) 0.1780(4) 0.0361(11) Uani 1 1 d . . .
H3A H 0.1708 1.2632 0.1900 0.054 Uiso 1 1 calc R . .
H3B H 0.2207 1.1802 0.1111 0.054 Uiso 1 1 calc R . .
H3C H 0.3029 1.2698 0.1810 0.054 Uiso 1 1 calc R . .
C4 C 0.3203(5) 1.3118(3) 0.4014(4) 0.0318(10) Uani 1 1 d . . .
H4A H 0.2998 1.3483 0.3447 0.048 Uiso 1 1 calc R . .
H4B H 0.3999 1.3291 0.4343 0.048 Uiso 1 1 calc R . .
H4C H 0.2697 1.3315 0.4502 0.048 Uiso 1 1 calc R . .
C5 C 0.3067(4) 1.1968(3) 0.3622(3) 0.0223(8) Uani 1 1 d . . .
C6 C 0.3313(3) 1.1264(3) 0.4325(3) 0.0190(7) Uani 1 1 d . . .
C7 C 0.3144(3) 1.0191(3) 0.3942(3) 0.0157(7) Uani 1 1 d . . .
C8 C 0.3356(3) 0.9459(3) 0.4643(3) 0.0155(7) Uani 1 1 d . . .
C9 C 0.3721(3) 1.1595(3) 0.5408(3) 0.0234(8) Uani 1 1 d . . .
H9 H 0.3846 1.2302 0.5667 0.028 Uiso 1 1 calc R . .
C10 C 0.3930(3) 1.0913(3) 0.6064(3) 0.0231(8) Uani 1 1 d . . .
H10 H 0.4203 1.1159 0.6762 0.028 Uiso 1 1 calc R . .
C11 C 0.3740(3) 0.9818(3) 0.5705(3) 0.0180(7) Uani 1 1 d . . .
C12 C 0.3912(3) 0.9080(3) 0.6379(3) 0.0204(8) Uani 1 1 d . . .
C13 C 0.4278(4) 0.9432(4) 0.7521(3) 0.0288(9) Uani 1 1 d . . .
H13A H 0.3615 0.9693 0.7808 0.043 Uiso 1 1 calc R . .
H13B H 0.4873 0.9972 0.7652 0.043 Uiso 1 1 calc R . .
H13C H 0.4580 0.8857 0.7833 0.043 Uiso 1 1 calc R . .
C14 C 0.3799(5) 0.7187(4) 0.6591(4) 0.0317(10) Uani 1 1 d . . .
H14A H 0.4579 0.7204 0.6983 0.048 Uiso 1 1 calc R . .
H14B H 0.3636 0.6525 0.6144 0.048 Uiso 1 1 calc R . .
H14C H 0.3251 0.7292 0.7052 0.048 Uiso 1 1 calc R . .
C15 C 0.3694(3) 0.8042(3) 0.5948(3) 0.0211(8) Uani 1 1 d . . .
C16 C 0.3343(3) 0.7766(3) 0.4880(3) 0.0202(8) Uani 1 1 d . . .
H16 H 0.3228 0.7063 0.4602 0.024 Uiso 1 1 calc R . .
C17 C 0.5116(4) 0.7883(4) 0.0203(3) 0.0292(9) Uani 1 1 d . . .
C18 C 0.4663(4) 0.7548(3) 0.1109(3) 0.0226(8) Uani 1 1 d . . .
C19 C 0.5031(4) 0.6621(3) 0.1405(4) 0.0265(9) Uani 1 1 d . . .
C20 C 0.4682(4) 0.6330(3) 0.2257(4) 0.0250(8) Uani 1 1 d U . .
C21 C 0.5243(5) 0.5372(4) 0.2630(5) 0.0397(11) Uani 1 1 d U . .
C22 C 0.1930(5) 0.5127(5) -0.0400(5) 0.0480(15) Uani 1 1 d . . .
C23 C 0.1866(4) 0.6274(4) 0.0089(4) 0.0329(10) Uani 1 1 d . . .
C24 C 0.1601(5) 0.6997(5) -0.0553(4) 0.0394(12) Uani 1 1 d . . .
C25 C 0.1532(4) 0.8047(4) -0.0126(4) 0.0315(10) Uani 1 1 d . . .
C26 C 0.1269(6) 0.8816(5) -0.0880(4) 0.0488(14) Uani 1 1 d U . .
C27 C -0.1488(4) 0.8324(4) 0.2071(4) 0.0291(9) Uani 1 1 d . . .
C28 C -0.0353(3) 0.7829(3) 0.2484(3) 0.0210(8) Uani 1 1 d . . .
C29 C -0.0425(4) 0.6897(3) 0.2839(3) 0.0238(8) Uani 1 1 d . . .
C30 C 0.0592(4) 0.6371(3) 0.3105(3) 0.0220(8) Uani 1 1 d . . .
C31 C 0.0481(5) 0.5326(4) 0.3457(4) 0.0357(11) Uani 1 1 d . . .
Dy1 Dy 0.245374(14) 0.787847(12) 0.234595(12) 0.01571(7) Uani 1 1 d . . .
F1 F 0.4574(6) 0.4887(5) 0.3022(7) 0.129(2) Uani 1 1 d U . .
F2 F 0.6210(6) 0.5622(4) 0.3267(5) 0.120(2) Uani 1 1 d U . .
F3 F 0.5570(5) 0.4697(3) 0.1930(4) 0.0835(14) Uani 1 1 d U . .
F4 F 0.5836(4) 0.7210(3) -0.0199(3) 0.0642(12) Uani 1 1 d . . .
F5 F 0.4241(3) 0.7979(5) -0.0541(3) 0.0821(16) Uani 1 1 d . . .
F6 F 0.5714(4) 0.8767(3) 0.0487(3) 0.0521(9) Uani 1 1 d . . .
F7 F 0.2915(4) 0.4740(3) -0.0010(4) 0.0835(16) Uani 1 1 d . . .
F8 F 0.1056(5) 0.4572(3) -0.0303(5) 0.099(2) Uani 1 1 d . . .
F9 F 0.1973(5) 0.5005(4) -0.1416(3) 0.0815(15) Uani 1 1 d . . .
F10 F 0.1645(6) 0.8515(5) -0.1752(4) 0.1030(19) Uani 1 1 d U . .
F11 F 0.0196(5) 0.8979(6) -0.1101(6) 0.125(2) Uani 1 1 d U . .
F12 F 0.1857(6) 0.9687(4) -0.0519(4) 0.108(2) Uani 1 1 d U . .
F13 F 0.0623(4) 0.4547(2) 0.2715(3) 0.0604(11) Uani 1 1 d . . .
F14 F 0.1301(3) 0.5252(3) 0.4278(3) 0.0549(9) Uani 1 1 d . . .
F15 F -0.0551(3) 0.5172(3) 0.3714(3) 0.0537(9) Uani 1 1 d . . .
F16 F -0.2441(2) 0.7875(3) 0.2262(3) 0.0516(10) Uani 1 1 d . . .
F17 F -0.1498(3) 0.9327(2) 0.2478(3) 0.0422(7) Uani 1 1 d . . .
F18 F -0.1625(3) 0.8249(3) 0.1063(2) 0.0479(8) Uani 1 1 d . . .
N1 N 0.2761(3) 0.9801(3) 0.2924(3) 0.0175(6) Uani 1 1 d . . .
N2 N 0.3163(3) 0.8438(3) 0.4234(3) 0.0171(6) Uani 1 1 d . . .
O1 O 0.3981(3) 0.8180(2) 0.1498(2) 0.0220(6) Uani 1 1 d . . .
O2 O 0.3987(3) 0.6765(2) 0.2786(2) 0.0217(6) Uani 1 1 d . . .
O3 O 0.2062(3) 0.6428(2) 0.1054(2) 0.0275(7) Uani 1 1 d . . .
O4 O 0.1658(3) 0.8452(2) 0.0794(2) 0.0253(6) Uani 1 1 d . . .
O5 O 0.0545(2) 0.8321(2) 0.2423(2) 0.0218(6) Uani 1 1 d . . .
O6 O 0.1627(3) 0.6621(2) 0.3076(2) 0.0225(6) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.327(5) . ?
C1 C2 1.414(6) . ?
C1 H1 0.9300 . ?
C2 C5 1.378(6) . ?
C2 C3 1.505(6) . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C4 C5 1.502(6) . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5 C6 1.422(6) . ?
C6 C7 1.408(5) . ?
C6 C9 1.431(6) . ?
C7 N1 1.361(5) . ?
C7 C8 1.444(5) . ?
C8 N2 1.355(5) . ?
C8 C11 1.407(5) . ?
C9 C10 1.351(6) . ?
C9 H9 0.9300 . ?
C10 C11 1.433(6) . ?
C10 H10 0.9300 . ?
C11 C12 1.422(6) . ?
C12 C15 1.384(6) . ?
C12 C13 1.500(6) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 C15 1.518(6) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 C16 1.396(6) . ?
C16 N2 1.328(5) . ?
C16 H16 0.9300 . ?
C17 F6 1.310(6) . ?
C17 F5 1.313(6) . ?
C17 F4 1.327(6) . ?
C17 C18 1.535(6) . ?
C18 O1 1.259(5) . ?
C18 C19 1.385(6) . ?
C19 C20 1.389(6) . ?
C20 O2 1.245(5) . ?
C20 C21 1.532(6) . ?
C21 F1 1.244(8) . ?
C21 F3 1.282(7) . ?
C21 F2 1.286(8) . ?
C22 F8 1.288(8) . ?
C22 F7 1.311(8) . ?
C22 F9 1.352(8) . ?
C22 C23 1.536(7) . ?
C23 O3 1.250(6) . ?
C23 C24 1.384(8) . ?
C24 C25 1.400(8) . ?
C25 O4 1.236(6) . ?
C25 C26 1.540(7) . ?
C26 F11 1.256(8) . ?
C26 F12 1.299(8) . ?
C26 F10 1.317(8) . ?
C27 F18 1.317(5) . ?
C27 F17 1.331(6) . ?
C27 F16 1.340(6) . ?
C27 C28 1.526(6) . ?
C28 O5 1.250(5) . ?
C28 C29 1.391(6) . ?
C29 C30 1.391(6) . ?
C30 O6 1.257(5) . ?
C30 C31 1.535(6) . ?
C31 F13 1.327(6) . ?
C31 F15 1.332(6) . ?
C31 F14 1.336(7) . ?
Dy1 O5 2.311(3) . ?
Dy1 O3 2.317(3) . ?
Dy1 O6 2.342(3) . ?
Dy1 O1 2.344(3) . ?
Dy1 O2 2.360(3) . ?
Dy1 O4 2.363(3) . ?
Dy1 N2 2.491(3) . ?
Dy1 N1 2.504(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 124.5(4) . . ?
N1 C1 H1 117.8 . . ?
C2 C1 H1 117.8 . . ?
C5 C2 C1 118.6(4) . . ?
C5 C2 C3 123.1(4) . . ?
C1 C2 C3 118.3(4) . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C5 C4 H4A 109.5 . . ?
C5 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C5 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C2 C5 C6 118.3(4) . . ?
C2 C5 C4 121.9(4) . . ?
C6 C5 C4 119.8(4) . . ?
C7 C6 C5 118.7(4) . . ?
C7 C6 C9 118.3(4) . . ?
C5 C6 C9 122.9(4) . . ?
N1 C7 C6 122.6(4) . . ?
N1 C7 C8 117.5(3) . . ?
C6 C7 C8 119.9(3) . . ?
N2 C8 C11 122.6(4) . . ?
N2 C8 C7 117.3(3) . . ?
C11 C8 C7 120.1(3) . . ?
C10 C9 C6 121.9(4) . . ?
C10 C9 H9 119.0 . . ?
C6 C9 H9 119.0 . . ?
C9 C10 C11 121.2(4) . . ?
C9 C10 H10 119.4 . . ?
C11 C10 H10 119.4 . . ?
C8 C11 C12 118.7(4) . . ?
C8 C11 C10 118.6(4) . . ?
C12 C11 C10 122.7(4) . . ?
C15 C12 C11 117.8(4) . . ?
C15 C12 C13 121.8(4) . . ?
C11 C12 C13 120.4(4) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C15 C14 H14A 109.5 . . ?
C15 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C15 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C12 C15 C16 118.9(4) . . ?
C12 C15 C14 122.7(4) . . ?
C16 C15 C14 118.4(4) . . ?
N2 C16 C15 124.5(4) . . ?
N2 C16 H16 117.7 . . ?
C15 C16 H16 117.7 . . ?
F6 C17 F5 108.8(5) . . ?
F6 C17 F4 105.4(4) . . ?
F5 C17 F4 107.2(5) . . ?
F6 C17 C18 111.7(4) . . ?
F5 C17 C18 110.3(4) . . ?
F4 C17 C18 113.1(4) . . ?
O1 C18 C19 127.7(4) . . ?
O1 C18 C17 113.7(4) . . ?
C19 C18 C17 118.6(4) . . ?
C18 C19 C20 119.5(4) . . ?
O2 C20 C19 128.4(4) . . ?
O2 C20 C21 114.6(4) . . ?
C19 C20 C21 117.0(4) . . ?
F1 C21 F3 105.2(6) . . ?
F1 C21 F2 110.4(7) . . ?
F3 C21 F2 102.0(5) . . ?
F1 C21 C20 112.4(5) . . ?
F3 C21 C20 115.2(5) . . ?
F2 C21 C20 111.0(5) . . ?
F8 C22 F7 110.3(7) . . ?
F8 C22 F9 107.8(5) . . ?
F7 C22 F9 103.0(5) . . ?
F8 C22 C23 112.5(5) . . ?
F7 C22 C23 110.7(4) . . ?
F9 C22 C23 112.1(6) . . ?
O3 C23 C24 128.0(5) . . ?
O3 C23 C22 113.3(5) . . ?
C24 C23 C22 118.7(5) . . ?
C23 C24 C25 119.8(5) . . ?
O4 C25 C24 128.4(5) . . ?
O4 C25 C26 114.3(5) . . ?
C24 C25 C26 117.3(5) . . ?
F11 C26 F12 110.4(7) . . ?
F11 C26 F10 107.7(6) . . ?
F12 C26 F10 101.6(6) . . ?
F11 C26 C25 112.4(6) . . ?
F12 C26 C25 111.0(5) . . ?
F10 C26 C25 113.2(5) . . ?
F18 C27 F17 107.7(4) . . ?
F18 C27 F16 106.7(4) . . ?
F17 C27 F16 106.6(4) . . ?
F18 C27 C28 110.3(4) . . ?
F17 C27 C28 111.9(4) . . ?
F16 C27 C28 113.3(4) . . ?
O5 C28 C29 128.2(4) . . ?
O5 C28 C27 113.5(4) . . ?
C29 C28 C27 118.3(4) . . ?
C30 C29 C28 119.2(4) . . ?
O6 C30 C29 128.7(4) . . ?
O6 C30 C31 113.2(4) . . ?
C29 C30 C31 118.1(4) . . ?
F13 C31 F15 107.7(5) . . ?
F13 C31 F14 107.0(5) . . ?
F15 C31 F14 107.2(4) . . ?
F13 C31 C30 110.5(4) . . ?
F15 C31 C30 113.1(4) . . ?
F14 C31 C30 111.2(4) . . ?
O5 Dy1 O3 97.99(11) . . ?
O5 Dy1 O6 72.52(10) . . ?
O3 Dy1 O6 74.26(11) . . ?
O5 Dy1 O1 141.14(10) . . ?
O3 Dy1 O1 83.50(11) . . ?
O6 Dy1 O1 142.84(10) . . ?
O5 Dy1 O2 147.01(10) . . ?
O3 Dy1 O2 76.32(11) . . ?
O6 Dy1 O2 74.69(10) . . ?
O1 Dy1 O2 71.29(10) . . ?
O5 Dy1 O4 72.36(11) . . ?
O3 Dy1 O4 72.23(12) . . ?
O6 Dy1 O4 126.55(11) . . ?
O1 Dy1 O4 71.24(11) . . ?
O2 Dy1 O4 133.00(10) . . ?
O5 Dy1 N2 94.13(11) . . ?
O3 Dy1 N2 143.05(12) . . ?
O6 Dy1 N2 76.42(11) . . ?
O1 Dy1 N2 107.87(11) . . ?
O2 Dy1 N2 74.63(11) . . ?
O4 Dy1 N2 144.61(11) . . ?
O5 Dy1 N1 80.80(11) . . ?
O3 Dy1 N1 151.12(12) . . ?
O6 Dy1 N1 131.12(10) . . ?
O1 Dy1 N1 80.02(11) . . ?
O2 Dy1 N1 119.60(11) . . ?
O4 Dy1 N1 80.05(11) . . ?
N2 Dy1 N1 65.33(11) . . ?
C1 N1 C7 117.3(3) . . ?
C1 N1 Dy1 123.2(3) . . ?
C7 N1 Dy1 119.5(2) . . ?
C16 N2 C8 117.4(3) . . ?
C16 N2 Dy1 122.3(3) . . ?
C8 N2 Dy1 120.3(2) . . ?
C18 O1 Dy1 129.5(3) . . ?
C20 O2 Dy1 129.7(3) . . ?
C23 O3 Dy1 135.2(3) . . ?
C25 O4 Dy1 133.4(3) . . ?
C28 O5 Dy1 134.1(3) . . ?
C30 O6 Dy1 133.4(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C5 -0.1(6) . . . . ?
N1 C1 C2 C3 -179.2(4) . . . . ?
C1 C2 C5 C6 0.3(6) . . . . ?
C3 C2 C5 C6 179.3(4) . . . . ?
C1 C2 C5 C4 -178.1(4) . . . . ?
C3 C2 C5 C4 0.9(7) . . . . ?
C2 C5 C6 C7 -0.4(5) . . . . ?
C4 C5 C6 C7 178.0(4) . . . . ?
C2 C5 C6 C9 179.9(4) . . . . ?
C4 C5 C6 C9 -1.6(6) . . . . ?
C5 C6 C7 N1 0.4(5) . . . . ?
C9 C6 C7 N1 -179.9(3) . . . . ?
C5 C6 C7 C8 -178.3(3) . . . . ?
C9 C6 C7 C8 1.4(5) . . . . ?
N1 C7 C8 N2 0.3(5) . . . . ?
C6 C7 C8 N2 179.1(3) . . . . ?
N1 C7 C8 C11 -179.3(3) . . . . ?
C6 C7 C8 C11 -0.5(5) . . . . ?
C7 C6 C9 C10 -0.8(6) . . . . ?
C5 C6 C9 C10 178.8(4) . . . . ?
C6 C9 C10 C11 -0.7(6) . . . . ?
N2 C8 C11 C12 -1.2(5) . . . . ?
C7 C8 C11 C12 178.4(3) . . . . ?
N2 C8 C11 C10 179.5(3) . . . . ?
C7 C8 C11 C10 -1.0(5) . . . . ?
C9 C10 C11 C8 1.6(6) . . . . ?
C9 C10 C11 C12 -177.7(4) . . . . ?
C8 C11 C12 C15 0.2(5) . . . . ?
C10 C11 C12 C15 179.5(4) . . . . ?
C8 C11 C12 C13 -177.7(4) . . . . ?
C10 C11 C12 C13 1.6(6) . . . . ?
C11 C12 C15 C16 1.4(5) . . . . ?
C13 C12 C15 C16 179.3(4) . . . . ?
C11 C12 C15 C14 -177.6(4) . . . . ?
C13 C12 C15 C14 0.4(6) . . . . ?
C12 C15 C16 N2 -2.3(6) . . . . ?
C14 C15 C16 N2 176.7(4) . . . . ?
F6 C17 C18 O1 61.1(5) . . . . ?
F5 C17 C18 O1 -60.0(6) . . . . ?
F4 C17 C18 O1 179.9(4) . . . . ?
F6 C17 C18 C19 -118.8(5) . . . . ?
F5 C17 C18 C19 120.1(5) . . . . ?
F4 C17 C18 C19 0.0(6) . . . . ?
O1 C18 C19 C20 -3.4(7) . . . . ?
C17 C18 C19 C20 176.5(4) . . . . ?
C18 C19 C20 O2 5.7(8) . . . . ?
C18 C19 C20 C21 -172.2(4) . . . . ?
O2 C20 C21 F1 33.1(8) . . . . ?
C19 C20 C21 F1 -148.7(7) . . . . ?
O2 C20 C21 F3 153.6(5) . . . . ?
C19 C20 C21 F3 -28.2(7) . . . . ?
O2 C20 C21 F2 -91.1(6) . . . . ?
C19 C20 C21 F2 87.1(7) . . . . ?
F8 C22 C23 O3 72.0(7) . . . . ?
F7 C22 C23 O3 -51.9(7) . . . . ?
F9 C22 C23 O3 -166.4(5) . . . . ?
F8 C22 C23 C24 -107.6(7) . . . . ?
F7 C22 C23 C24 128.5(6) . . . . ?
F9 C22 C23 C24 14.0(7) . . . . ?
O3 C23 C24 C25 0.2(9) . . . . ?
C22 C23 C24 C25 179.7(5) . . . . ?
C23 C24 C25 O4 -1.6(9) . . . . ?
C23 C24 C25 C26 178.3(5) . . . . ?
O4 C25 C26 F11 -86.6(7) . . . . ?
C24 C25 C26 F11 93.6(8) . . . . ?
O4 C25 C26 F12 37.6(8) . . . . ?
C24 C25 C26 F12 -142.3(6) . . . . ?
O4 C25 C26 F10 151.1(6) . . . . ?
C24 C25 C26 F10 -28.8(8) . . . . ?
F18 C27 C28 O5 68.8(5) . . . . ?
F17 C27 C28 O5 -51.1(5) . . . . ?
F16 C27 C28 O5 -171.7(4) . . . . ?
F18 C27 C28 C29 -109.0(5) . . . . ?
F17 C27 C28 C29 131.1(4) . . . . ?
F16 C27 C28 C29 10.6(6) . . . . ?
O5 C28 C29 C30 -4.8(7) . . . . ?
C27 C28 C29 C30 172.5(4) . . . . ?
C28 C29 C30 O6 0.1(7) . . . . ?
C28 C29 C30 C31 -177.9(4) . . . . ?
O6 C30 C31 F13 -73.7(5) . . . . ?
C29 C30 C31 F13 104.6(5) . . . . ?
O6 C30 C31 F15 165.6(4) . . . . ?
C29 C30 C31 F15 -16.1(6) . . . . ?
O6 C30 C31 F14 45.0(6) . . . . ?
C29 C30 C31 F14 -136.7(4) . . . . ?
C2 C1 N1 C7 0.1(6) . . . . ?
C2 C1 N1 Dy1 178.5(3) . . . . ?
C6 C7 N1 C1 -0.3(5) . . . . ?
C8 C7 N1 C1 178.4(3) . . . . ?
C6 C7 N1 Dy1 -178.7(3) . . . . ?
C8 C7 N1 Dy1 0.0(4) . . . . ?
O5 Dy1 N1 C1 -79.6(3) . . . . ?
O3 Dy1 N1 C1 10.3(4) . . . . ?
O6 Dy1 N1 C1 -136.6(3) . . . . ?
O1 Dy1 N1 C1 66.4(3) . . . . ?
O2 Dy1 N1 C1 128.1(3) . . . . ?
O4 Dy1 N1 C1 -6.1(3) . . . . ?
N2 Dy1 N1 C1 -178.5(3) . . . . ?
O5 Dy1 N1 C7 98.7(3) . . . . ?
O3 Dy1 N1 C7 -171.4(2) . . . . ?
O6 Dy1 N1 C7 41.7(3) . . . . ?
O1 Dy1 N1 C7 -115.3(3) . . . . ?
O2 Dy1 N1 C7 -53.6(3) . . . . ?
O4 Dy1 N1 C7 172.2(3) . . . . ?
N2 Dy1 N1 C7 -0.2(2) . . . . ?
C15 C16 N2 C8 1.4(6) . . . . ?
C15 C16 N2 Dy1 -177.3(3) . . . . ?
C11 C8 N2 C16 0.4(5) . . . . ?
C7 C8 N2 C16 -179.2(3) . . . . ?
C11 C8 N2 Dy1 179.1(3) . . . . ?
C7 C8 N2 Dy1 -0.5(4) . . . . ?
O5 Dy1 N2 C16 101.0(3) . . . . ?
O3 Dy1 N2 C16 -8.1(4) . . . . ?
O6 Dy1 N2 C16 30.1(3) . . . . ?
O1 Dy1 N2 C16 -111.4(3) . . . . ?
O2 Dy1 N2 C16 -47.4(3) . . . . ?
O4 Dy1 N2 C16 166.0(3) . . . . ?
N1 Dy1 N2 C16 179.0(3) . . . . ?
O5 Dy1 N2 C8 -77.5(3) . . . . ?
O3 Dy1 N2 C8 173.3(2) . . . . ?
O6 Dy1 N2 C8 -148.4(3) . . . . ?
O1 Dy1 N2 C8 70.0(3) . . . . ?
O2 Dy1 N2 C8 134.0(3) . . . . ?
O4 Dy1 N2 C8 -12.6(4) . . . . ?
N1 Dy1 N2 C8 0.4(2) . . . . ?
C19 C18 O1 Dy1 -28.4(6) . . . . ?
C17 C18 O1 Dy1 151.7(3) . . . . ?
O5 Dy1 O1 C18 -135.9(3) . . . . ?
O3 Dy1 O1 C18 -41.2(3) . . . . ?
O6 Dy1 O1 C18 11.8(4) . . . . ?
O2 Dy1 O1 C18 36.5(3) . . . . ?
O4 Dy1 O1 C18 -114.6(4) . . . . ?
N2 Dy1 O1 C18 102.8(3) . . . . ?
N1 Dy1 O1 C18 162.6(4) . . . . ?
C19 C20 O2 Dy1 23.9(7) . . . . ?
C21 C20 O2 Dy1 -158.2(3) . . . . ?
O5 Dy1 O2 C20 136.8(3) . . . . ?
O3 Dy1 O2 C20 53.2(4) . . . . ?
O6 Dy1 O2 C20 130.4(4) . . . . ?
O1 Dy1 O2 C20 -34.4(4) . . . . ?
O4 Dy1 O2 C20 4.3(4) . . . . ?
N2 Dy1 O2 C20 -149.8(4) . . . . ?
N1 Dy1 O2 C20 -100.7(4) . . . . ?
C24 C23 O3 Dy1 -13.5(8) . . . . ?
C22 C23 O3 Dy1 167.0(3) . . . . ?
O5 Dy1 O3 C23 85.4(4) . . . . ?
O6 Dy1 O3 C23 154.6(4) . . . . ?
O1 Dy1 O3 C23 -55.4(4) . . . . ?
O2 Dy1 O3 C23 -127.7(4) . . . . ?
O4 Dy1 O3 C23 16.9(4) . . . . ?
N2 Dy1 O3 C23 -166.7(4) . . . . ?
N1 Dy1 O3 C23 0.0(6) . . . . ?
C24 C25 O4 Dy1 15.5(8) . . . . ?
C26 C25 O4 Dy1 -164.4(4) . . . . ?
O5 Dy1 O4 C25 -122.4(4) . . . . ?
O3 Dy1 O4 C25 -17.7(4) . . . . ?
O6 Dy1 O4 C25 -71.4(4) . . . . ?
O1 Dy1 O4 C25 71.4(4) . . . . ?
O2 Dy1 O4 C25 32.6(5) . . . . ?
N2 Dy1 O4 C25 166.0(4) . . . . ?
N1 Dy1 O4 C25 154.1(4) . . . . ?
C29 C28 O5 Dy1 21.6(7) . . . . ?
C27 C28 O5 Dy1 -155.9(3) . . . . ?
O3 Dy1 O5 C28 49.2(4) . . . . ?
O6 Dy1 O5 C28 -21.5(4) . . . . ?
O1 Dy1 O5 C28 138.7(3) . . . . ?
O2 Dy1 O5 C28 -28.0(5) . . . . ?
O4 Dy1 O5 C28 117.6(4) . . . . ?
N2 Dy1 O5 C28 -95.8(4) . . . . ?
N1 Dy1 O5 C28 -160.0(4) . . . . ?
C29 C30 O6 Dy1 -11.8(7) . . . . ?
C31 C30 O6 Dy1 166.3(3) . . . . ?
O5 Dy1 O6 C30 16.6(4) . . . . ?
O3 Dy1 O6 C30 -87.3(4) . . . . ?
O1 Dy1 O6 C30 -142.8(3) . . . . ?
O2 Dy1 O6 C30 -167.0(4) . . . . ?
O4 Dy1 O6 C30 -34.4(4) . . . . ?
N2 Dy1 O6 C30 115.5(4) . . . . ?
N1 Dy1 O6 C30 76.8(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        27.85
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         3.333
_refine_diff_density_min         -1.933
_refine_diff_density_rms         0.136

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.000 0.000 0.500 221.7 23.0
2 0.500 0.500 0.500 30.1 0.4
_platon_squeeze_details          
; ?
;

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p130915d
_database_code_depnum_ccdc_archive 'CCDC 965722'
_audit_update_record             
;
2015-03-27 deposited with the CCDC.
2015-04-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C31 H41 Dy N2 O8'
_chemical_formula_weight         732.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.6421(9)
_cell_length_b                   11.4005(8)
_cell_length_c                   14.6562(8)
_cell_angle_alpha                83.765(5)
_cell_angle_beta                 72.402(6)
_cell_angle_gamma                67.841(7)
_cell_volume                     1569.73(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    8529
_cell_measurement_theta_min      2.92
_cell_measurement_theta_max      25.01

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      none
_exptl_crystal_density_diffrn    1.549
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             742
_exptl_absorpt_coefficient_mu    2.431
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6687
_exptl_absorpt_correction_T_max  0.7591
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            10826
_diffrn_reflns_av_R_equivalents  0.0321
_diffrn_reflns_av_unetI/netI     0.0449
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.92
_diffrn_reflns_theta_max         25.01
_reflns_number_total             5538
_reflns_number_gt                5257
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0145P)²+0.6693P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5538
_refine_ls_number_parameters     389
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0258
_refine_ls_R_factor_gt           0.0239
_refine_ls_wR_factor_ref         0.0541
_refine_ls_wR_factor_gt          0.0528
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.013
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.0227(3) 0.3453(3) 0.6087(2) 0.0217(7) Uani 1 1 d . . .
H1 H -0.0503 0.3811 0.6633 0.026 Uiso 1 1 calc R . .
C2 C -0.0136(3) 0.3461(3) 0.5238(2) 0.0232(7) Uani 1 1 d . . .
C3 C -0.1681(3) 0.4076(3) 0.5263(2) 0.0317(8) Uani 1 1 d . . .
H3A H -0.1772 0.4643 0.4733 0.048 Uiso 1 1 calc R . .
H3B H -0.2210 0.4541 0.5851 0.048 Uiso 1 1 calc R . .
H3C H -0.2041 0.3434 0.5222 0.048 Uiso 1 1 calc R . .
C4 C 0.0926(3) 0.2898(3) 0.4426(2) 0.0220(7) Uani 1 1 d . . .
C5 C 0.0548(4) 0.2846(3) 0.3520(2) 0.0315(8) Uani 1 1 d . . .
H5A H -0.0228 0.2555 0.3668 0.047 Uiso 1 1 calc R . .
H5B H 0.1351 0.2274 0.3071 0.047 Uiso 1 1 calc R . .
H5C H 0.0282 0.3676 0.3246 0.047 Uiso 1 1 calc R . .
C6 C 0.2343(3) 0.2393(3) 0.4479(2) 0.0209(7) Uani 1 1 d . . .
C7 C 0.2597(3) 0.2452(2) 0.5364(2) 0.0167(6) Uani 1 1 d . . .
C8 C 0.4017(3) 0.1940(2) 0.54485(19) 0.0159(6) Uani 1 1 d . . .
C9 C 0.3555(3) 0.1810(3) 0.3686(2) 0.0239(7) Uani 1 1 d . . .
H9 H 0.3416 0.1736 0.3102 0.029 Uiso 1 1 calc R . .
C10 C 0.4888(3) 0.1368(3) 0.3762(2) 0.0230(7) Uani 1 1 d . . .
H10 H 0.5639 0.1015 0.3226 0.028 Uiso 1 1 calc R . .
C11 C 0.5180(3) 0.1427(2) 0.4646(2) 0.0186(6) Uani 1 1 d . . .
C12 C 0.6577(3) 0.0998(3) 0.4750(2) 0.0211(7) Uani 1 1 d . . .
C13 C 0.6714(3) 0.1081(3) 0.5644(2) 0.0200(6) Uani 1 1 d . . .
C14 C 0.5490(3) 0.1563(3) 0.6403(2) 0.0185(6) Uani 1 1 d . . .
H14 H 0.5606 0.1594 0.7003 0.022 Uiso 1 1 calc R . .
C15 C 0.8126(3) 0.0647(3) 0.5850(2) 0.0288(7) Uani 1 1 d . . .
H15A H 0.8670 -0.0208 0.5626 0.043 Uiso 1 1 calc R . .
H15B H 0.7981 0.0683 0.6527 0.043 Uiso 1 1 calc R . .
H15C H 0.8627 0.1189 0.5527 0.043 Uiso 1 1 calc R . .
C16 C 0.7855(3) 0.0463(3) 0.3906(2) 0.0295(8) Uani 1 1 d . . .
H16A H 0.8699 0.0304 0.4089 0.044 Uiso 1 1 calc R . .
H16B H 0.7812 0.1059 0.3391 0.044 Uiso 1 1 calc R . .
H16C H 0.7869 -0.0315 0.3703 0.044 Uiso 1 1 calc R . .
C17 C 0.3748(4) 0.6021(4) 0.6328(3) 0.0483(11) Uani 1 1 d . . .
H17A H 0.3918 0.5735 0.5694 0.073 Uiso 1 1 calc R . .
H17B H 0.4529 0.6232 0.6354 0.073 Uiso 1 1 calc R . .
H17C H 0.2895 0.6757 0.6484 0.073 Uiso 1 1 calc R . .
C18 C 0.3595(3) 0.4985(3) 0.7036(2) 0.0240(7) Uani 1 1 d . . .
C19 C 0.4526(3) 0.4555(3) 0.7606(2) 0.0261(7) Uani 1 1 d . . .
H19 H 0.5196 0.4925 0.7523 0.031 Uiso 1 1 calc R . .
C20 C 0.4507(3) 0.3610(3) 0.8286(2) 0.0218(7) Uani 1 1 d . . .
C21 C 0.5504(3) 0.3273(3) 0.8900(2) 0.0329(8) Uani 1 1 d . . .
H21A H 0.4978 0.3569 0.9542 0.049 Uiso 1 1 calc R . .
H21B H 0.6193 0.3664 0.8646 0.049 Uiso 1 1 calc R . .
H21C H 0.5975 0.2370 0.8902 0.049 Uiso 1 1 calc R . .
C22 C 0.3722(3) -0.1198(3) 0.9055(2) 0.0276(7) Uani 1 1 d . . .
H22A H 0.4580 -0.1582 0.8559 0.041 Uiso 1 1 calc R . .
H22B H 0.3285 -0.1810 0.9305 0.041 Uiso 1 1 calc R . .
H22C H 0.3935 -0.0905 0.9560 0.041 Uiso 1 1 calc R . .
C23 C 0.2718(3) -0.0087(3) 0.86492(19) 0.0189(6) Uani 1 1 d . . .
C24 C 0.1359(3) -0.0071(3) 0.8774(2) 0.0219(7) Uani 1 1 d . . .
H24 H 0.1094 -0.0693 0.9156 0.026 Uiso 1 1 calc R . .
C25 C 0.0370(3) 0.0823(3) 0.8359(2) 0.0200(7) Uani 1 1 d . . .
C26 C -0.0976(3) 0.0610(3) 0.8436(3) 0.0358(8) Uani 1 1 d . . .
H26A H -0.1689 0.1398 0.8345 0.054 Uiso 1 1 calc R . .
H26B H -0.1298 0.0281 0.9057 0.054 Uiso 1 1 calc R . .
H26C H -0.0796 0.0015 0.7953 0.054 Uiso 1 1 calc R . .
C27 C -0.0622(3) 0.3199(3) 1.1024(2) 0.0295(8) Uani 1 1 d . . .
H27A H -0.0032 0.2345 1.1117 0.044 Uiso 1 1 calc R . .
H27B H -0.1598 0.3296 1.1292 0.044 Uiso 1 1 calc R . .
H27C H -0.0417 0.3775 1.1336 0.044 Uiso 1 1 calc R . .
C28 C -0.0335(3) 0.3483(3) 0.9963(2) 0.0233(7) Uani 1 1 d . . .
C29 C -0.1454(3) 0.4283(3) 0.9616(2) 0.0268(7) Uani 1 1 d . . .
H29 H -0.2362 0.4509 1.0034 0.032 Uiso 1 1 calc R . .
C30 C -0.1313(3) 0.4763(3) 0.8696(2) 0.0224(7) Uani 1 1 d . . .
C31 C -0.2604(3) 0.5724(3) 0.8451(2) 0.0312(8) Uani 1 1 d . . .
H31A H -0.2656 0.6564 0.8544 0.047 Uiso 1 1 calc R . .
H31B H -0.3440 0.5602 0.8859 0.047 Uiso 1 1 calc R . .
H31C H -0.2535 0.5616 0.7795 0.047 Uiso 1 1 calc R . .
Dy1 Dy 0.202182(13) 0.286115(11) 0.779055(9) 0.01485(5) Uani 1 1 d . . .
N1 N 0.1536(2) 0.2972(2) 0.61632(16) 0.0167(5) Uani 1 1 d . . .
N2 N 0.4175(2) 0.1979(2) 0.63377(16) 0.0159(5) Uani 1 1 d . . .
O1 O 0.2625(2) 0.45899(18) 0.70701(14) 0.0210(5) Uani 1 1 d . . .
O2 O 0.3695(2) 0.29920(18) 0.84421(14) 0.0218(5) Uani 1 1 d . . .
O3 O 0.3196(2) 0.07506(17) 0.82109(13) 0.0182(4) Uani 1 1 d . . .
O4 O 0.0534(2) 0.17706(18) 0.78882(14) 0.0195(4) Uani 1 1 d . . .
O5 O -0.0153(2) 0.44887(18) 0.80326(14) 0.0215(5) Uani 1 1 d . . .
O6 O 0.0936(2) 0.29837(19) 0.94455(14) 0.0222(5) Uani 1 1 d . . .
O7 O 0.3156(2) 0.1621(2) 0.02575(15) 0.0337(6) Uani 1 1 d . . .
O8 O 0.6225(3) 1.0061(3) 0.82685(18) 0.0502(7) Uani 1 1 d . . .
H7B H 0.2441 0.2128 0.0053 0.075 Uiso 1 1 d R . .
H7A H 0.3810 0.1789 -0.0261 0.075 Uiso 1 1 d R . .
H8A H 0.6395 0.9497 0.8768 0.075 Uiso 1 1 d R . .
H8B H 0.5254 1.0259 0.8378 0.075 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.326(4) . ?
C1 C2 1.409(4) . ?
C1 H1 0.9300 . ?
C2 C4 1.382(4) . ?
C2 C3 1.515(4) . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C4 C6 1.420(4) . ?
C4 C5 1.512(4) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 C7 1.415(4) . ?
C6 C9 1.440(4) . ?
C7 N1 1.358(3) . ?
C7 C8 1.440(4) . ?
C8 N2 1.371(3) . ?
C8 C11 1.407(4) . ?
C9 C10 1.350(4) . ?
C9 H9 0.9300 . ?
C10 C11 1.434(4) . ?
C10 H10 0.9300 . ?
C11 C12 1.430(4) . ?
C12 C13 1.379(4) . ?
C12 C16 1.507(4) . ?
C13 C14 1.397(4) . ?
C13 C15 1.508(4) . ?
C14 N2 1.328(3) . ?
C14 H14 0.9300 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C18 1.509(4) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 O1 1.259(4) . ?
C18 C19 1.402(4) . ?
C19 C20 1.387(4) . ?
C19 H19 0.9300 . ?
C20 O2 1.265(4) . ?
C20 C21 1.509(4) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C23 1.516(4) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 O3 1.272(4) . ?
C23 C24 1.396(4) . ?
C24 C25 1.400(4) . ?
C24 H24 0.9300 . ?
C25 O4 1.258(4) . ?
C25 C26 1.510(4) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 C28 1.515(4) . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 O6 1.274(4) . ?
C28 C29 1.398(4) . ?
C29 C30 1.386(4) . ?
C29 H29 0.9300 . ?
C30 O5 1.271(4) . ?
C30 C31 1.514(4) . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
Dy1 O5 2.3094(19) . ?
Dy1 O2 2.3165(19) . ?
Dy1 O4 2.320(2) . ?
Dy1 O6 2.3441(19) . ?
Dy1 O1 2.346(2) . ?
Dy1 O3 2.3678(18) . ?
Dy1 N2 2.564(2) . ?
Dy1 N1 2.570(2) . ?
O7 H7B 0.8783 . ?
O7 H7A 0.9203 . ?
O8 H8A 0.9339 . ?
O8 H8B 0.9367 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 124.6(3) . . ?
N1 C1 H1 117.7 . . ?
C2 C1 H1 117.7 . . ?
C4 C2 C1 118.7(3) . . ?
C4 C2 C3 123.2(3) . . ?
C1 C2 C3 118.1(3) . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C2 C4 C6 118.1(3) . . ?
C2 C4 C5 119.4(3) . . ?
C6 C4 C5 122.5(3) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C7 C6 C4 118.8(3) . . ?
C7 C6 C9 117.1(3) . . ?
C4 C6 C9 124.1(3) . . ?
N1 C7 C6 122.4(3) . . ?
N1 C7 C8 117.2(2) . . ?
C6 C7 C8 120.4(3) . . ?
N2 C8 C11 122.2(3) . . ?
N2 C8 C7 117.1(2) . . ?
C11 C8 C7 120.8(2) . . ?
C10 C9 C6 122.2(3) . . ?
C10 C9 H9 118.9 . . ?
C6 C9 H9 118.9 . . ?
C9 C10 C11 122.0(3) . . ?
C9 C10 H10 119.0 . . ?
C11 C10 H10 119.0 . . ?
C8 C11 C12 118.9(3) . . ?
C8 C11 C10 117.5(3) . . ?
C12 C11 C10 123.6(3) . . ?
C13 C12 C11 117.9(3) . . ?
C13 C12 C16 121.3(3) . . ?
C11 C12 C16 120.7(3) . . ?
C12 C13 C14 118.7(3) . . ?
C12 C13 C15 123.1(3) . . ?
C14 C13 C15 118.2(3) . . ?
N2 C14 C13 125.4(3) . . ?
N2 C14 H14 117.3 . . ?
C13 C14 H14 117.3 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C12 C16 H16A 109.5 . . ?
C12 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C12 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 H17A 109.5 . . ?
C18 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C18 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O1 C18 C19 125.6(3) . . ?
O1 C18 C17 116.8(3) . . ?
C19 C18 C17 117.7(3) . . ?
C20 C19 C18 123.9(3) . . ?
C20 C19 H19 118.0 . . ?
C18 C19 H19 118.0 . . ?
O2 C20 C19 124.6(3) . . ?
O2 C20 C21 115.9(3) . . ?
C19 C20 C21 119.4(3) . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C23 C22 H22A 109.5 . . ?
C23 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C23 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
O3 C23 C24 125.3(3) . . ?
O3 C23 C22 116.9(3) . . ?
C24 C23 C22 117.8(3) . . ?
C23 C24 C25 124.0(3) . . ?
C23 C24 H24 118.0 . . ?
C25 C24 H24 118.0 . . ?
O4 C25 C24 125.2(3) . . ?
O4 C25 C26 116.7(3) . . ?
C24 C25 C26 118.0(3) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C28 C27 H27A 109.5 . . ?
C28 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C28 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
O6 C28 C29 124.2(3) . . ?
O6 C28 C27 116.8(3) . . ?
C29 C28 C27 118.9(3) . . ?
C30 C29 C28 125.0(3) . . ?
C30 C29 H29 117.5 . . ?
C28 C29 H29 117.5 . . ?
O5 C30 C29 124.7(3) . . ?
O5 C30 C31 116.3(3) . . ?
C29 C30 C31 119.0(3) . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
O5 Dy1 O2 119.94(7) . . ?
O5 Dy1 O4 78.19(7) . . ?
O2 Dy1 O4 143.13(7) . . ?
O5 Dy1 O6 73.52(7) . . ?
O2 Dy1 O6 75.77(7) . . ?
O4 Dy1 O6 80.22(7) . . ?
O5 Dy1 O1 77.25(7) . . ?
O2 Dy1 O1 72.95(7) . . ?
O4 Dy1 O1 143.76(6) . . ?
O6 Dy1 O1 117.15(7) . . ?
O5 Dy1 O3 144.10(7) . . ?
O2 Dy1 O3 75.61(7) . . ?
O4 Dy1 O3 73.18(7) . . ?
O6 Dy1 O3 80.61(7) . . ?
O1 Dy1 O3 137.80(7) . . ?
O5 Dy1 N2 134.85(7) . . ?
O2 Dy1 N2 82.96(7) . . ?
O4 Dy1 N2 107.28(7) . . ?
O6 Dy1 N2 151.20(7) . . ?
O1 Dy1 N2 73.46(7) . . ?
O3 Dy1 N2 75.41(7) . . ?
O5 Dy1 N1 77.83(7) . . ?
O2 Dy1 N1 140.36(7) . . ?
O4 Dy1 N1 71.10(7) . . ?
O6 Dy1 N1 142.86(7) . . ?
O1 Dy1 N1 77.96(7) . . ?
O3 Dy1 N1 111.77(7) . . ?
N2 Dy1 N1 63.08(7) . . ?
C1 N1 C7 117.4(2) . . ?
C1 N1 Dy1 121.12(19) . . ?
C7 N1 Dy1 121.24(17) . . ?
C14 N2 C8 116.8(2) . . ?
C14 N2 Dy1 122.03(18) . . ?
C8 N2 Dy1 121.14(17) . . ?
C18 O1 Dy1 134.70(18) . . ?
C20 O2 Dy1 136.97(19) . . ?
C23 O3 Dy1 131.22(18) . . ?
C25 O4 Dy1 133.25(18) . . ?
C30 O5 Dy1 134.07(19) . . ?
C28 O6 Dy1 133.81(19) . . ?
H7B O7 H7A 92.6 . . ?
H8A O8 H8B 100.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C4 2.1(4) . . . . ?
N1 C1 C2 C3 -178.6(3) . . . . ?
C1 C2 C4 C6 -3.0(4) . . . . ?
C3 C2 C4 C6 177.7(3) . . . . ?
C1 C2 C4 C5 177.3(3) . . . . ?
C3 C2 C4 C5 -2.0(4) . . . . ?
C2 C4 C6 C7 2.0(4) . . . . ?
C5 C4 C6 C7 -178.3(3) . . . . ?
C2 C4 C6 C9 -178.4(3) . . . . ?
C5 C4 C6 C9 1.3(4) . . . . ?
C4 C6 C7 N1 0.1(4) . . . . ?
C9 C6 C7 N1 -179.5(3) . . . . ?
C4 C6 C7 C8 179.4(3) . . . . ?
C9 C6 C7 C8 -0.2(4) . . . . ?
N1 C7 C8 N2 2.3(4) . . . . ?
C6 C7 C8 N2 -177.1(2) . . . . ?
N1 C7 C8 C11 -177.7(2) . . . . ?
C6 C7 C8 C11 3.0(4) . . . . ?
C7 C6 C9 C10 -2.0(4) . . . . ?
C4 C6 C9 C10 178.4(3) . . . . ?
C6 C9 C10 C11 1.3(5) . . . . ?
N2 C8 C11 C12 -3.6(4) . . . . ?
C7 C8 C11 C12 176.3(3) . . . . ?
N2 C8 C11 C10 176.5(3) . . . . ?
C7 C8 C11 C10 -3.6(4) . . . . ?
C9 C10 C11 C8 1.5(4) . . . . ?
C9 C10 C11 C12 -178.4(3) . . . . ?
C8 C11 C12 C13 1.5(4) . . . . ?
C10 C11 C12 C13 -178.6(3) . . . . ?
C8 C11 C12 C16 -178.9(3) . . . . ?
C10 C11 C12 C16 1.0(4) . . . . ?
C11 C12 C13 C14 0.8(4) . . . . ?
C16 C12 C13 C14 -178.8(3) . . . . ?
C11 C12 C13 C15 179.3(3) . . . . ?
C16 C12 C13 C15 -0.3(4) . . . . ?
C12 C13 C14 N2 -1.3(4) . . . . ?
C15 C13 C14 N2 -179.9(3) . . . . ?
O1 C18 C19 C20 0.8(5) . . . . ?
C17 C18 C19 C20 179.9(3) . . . . ?
C18 C19 C20 O2 3.2(5) . . . . ?
C18 C19 C20 C21 -176.5(3) . . . . ?
O3 C23 C24 C25 5.7(5) . . . . ?
C22 C23 C24 C25 -173.4(3) . . . . ?
C23 C24 C25 O4 -5.7(5) . . . . ?
C23 C24 C25 C26 171.1(3) . . . . ?
O6 C28 C29 C30 -8.2(5) . . . . ?
C27 C28 C29 C30 170.5(3) . . . . ?
C28 C29 C30 O5 3.7(5) . . . . ?
C28 C29 C30 C31 -173.9(3) . . . . ?
C2 C1 N1 C7 0.1(4) . . . . ?
C2 C1 N1 Dy1 -175.0(2) . . . . ?
C6 C7 N1 C1 -1.2(4) . . . . ?
C8 C7 N1 C1 179.5(3) . . . . ?
C6 C7 N1 Dy1 173.9(2) . . . . ?
C8 C7 N1 Dy1 -5.5(3) . . . . ?
O5 Dy1 N1 C1 -23.9(2) . . . . ?
O2 Dy1 N1 C1 -146.6(2) . . . . ?
O4 Dy1 N1 C1 57.6(2) . . . . ?
O6 Dy1 N1 C1 16.2(3) . . . . ?
O1 Dy1 N1 C1 -103.2(2) . . . . ?
O3 Dy1 N1 C1 119.8(2) . . . . ?
N2 Dy1 N1 C1 179.4(2) . . . . ?
O5 Dy1 N1 C7 161.3(2) . . . . ?
O2 Dy1 N1 C7 38.6(2) . . . . ?
O4 Dy1 N1 C7 -117.2(2) . . . . ?
O6 Dy1 N1 C7 -158.68(18) . . . . ?
O1 Dy1 N1 C7 81.9(2) . . . . ?
O3 Dy1 N1 C7 -55.0(2) . . . . ?
N2 Dy1 N1 C7 4.51(19) . . . . ?
C13 C14 N2 C8 -0.6(4) . . . . ?
C13 C14 N2 Dy1 -179.4(2) . . . . ?
C11 C8 N2 C14 3.1(4) . . . . ?
C7 C8 N2 C14 -176.8(2) . . . . ?
C11 C8 N2 Dy1 -178.13(19) . . . . ?
C7 C8 N2 Dy1 1.9(3) . . . . ?
O5 Dy1 N2 C14 142.48(19) . . . . ?
O2 Dy1 N2 C14 16.6(2) . . . . ?
O4 Dy1 N2 C14 -127.1(2) . . . . ?
O6 Dy1 N2 C14 -25.8(3) . . . . ?
O1 Dy1 N2 C14 90.8(2) . . . . ?
O3 Dy1 N2 C14 -60.3(2) . . . . ?
N1 Dy1 N2 C14 175.5(2) . . . . ?
O5 Dy1 N2 C8 -36.2(2) . . . . ?
O2 Dy1 N2 C8 -162.1(2) . . . . ?
O4 Dy1 N2 C8 54.2(2) . . . . ?
O6 Dy1 N2 C8 155.53(18) . . . . ?
O1 Dy1 N2 C8 -87.9(2) . . . . ?
O3 Dy1 N2 C8 121.0(2) . . . . ?
N1 Dy1 N2 C8 -3.22(18) . . . . ?
C19 C18 O1 Dy1 -12.0(5) . . . . ?
C17 C18 O1 Dy1 168.8(2) . . . . ?
O5 Dy1 O1 C18 139.8(3) . . . . ?
O2 Dy1 O1 C18 12.6(3) . . . . ?
O4 Dy1 O1 C18 -171.7(2) . . . . ?
O6 Dy1 O1 C18 76.1(3) . . . . ?
O3 Dy1 O1 C18 -30.9(3) . . . . ?
N2 Dy1 O1 C18 -74.9(3) . . . . ?
N1 Dy1 O1 C18 -140.1(3) . . . . ?
C19 C20 O2 Dy1 4.2(5) . . . . ?
C21 C20 O2 Dy1 -176.06(19) . . . . ?
O5 Dy1 O2 C20 -72.6(3) . . . . ?
O4 Dy1 O2 C20 175.4(2) . . . . ?
O6 Dy1 O2 C20 -133.7(3) . . . . ?
O1 Dy1 O2 C20 -8.9(3) . . . . ?
O3 Dy1 O2 C20 142.6(3) . . . . ?
N2 Dy1 O2 C20 65.9(3) . . . . ?
N1 Dy1 O2 C20 35.7(3) . . . . ?
C24 C23 O3 Dy1 18.4(4) . . . . ?
C22 C23 O3 Dy1 -162.45(18) . . . . ?
O5 Dy1 O3 C23 11.8(3) . . . . ?
O2 Dy1 O3 C23 133.5(2) . . . . ?
O4 Dy1 O3 C23 -26.7(2) . . . . ?
O6 Dy1 O3 C23 55.9(2) . . . . ?
O1 Dy1 O3 C23 176.3(2) . . . . ?
N2 Dy1 O3 C23 -140.2(2) . . . . ?
N1 Dy1 O3 C23 -87.6(2) . . . . ?
C24 C25 O4 Dy1 -19.5(4) . . . . ?
C26 C25 O4 Dy1 163.6(2) . . . . ?
O5 Dy1 O4 C25 -130.5(3) . . . . ?
O2 Dy1 O4 C25 -5.7(3) . . . . ?
O6 Dy1 O4 C25 -55.5(2) . . . . ?
O1 Dy1 O4 C25 -178.7(2) . . . . ?
O3 Dy1 O4 C25 27.6(2) . . . . ?
N2 Dy1 O4 C25 95.9(2) . . . . ?
N1 Dy1 O4 C25 148.5(3) . . . . ?
C29 C30 O5 Dy1 18.5(5) . . . . ?
C31 C30 O5 Dy1 -163.87(19) . . . . ?
O2 Dy1 O5 C30 -85.2(3) . . . . ?
O4 Dy1 O5 C30 60.2(3) . . . . ?
O6 Dy1 O5 C30 -23.0(2) . . . . ?
O1 Dy1 O5 C30 -146.7(3) . . . . ?
O3 Dy1 O5 C30 22.7(3) . . . . ?
N2 Dy1 O5 C30 162.9(2) . . . . ?
N1 Dy1 O5 C30 133.1(3) . . . . ?
C29 C28 O6 Dy1 -8.9(5) . . . . ?
C27 C28 O6 Dy1 172.33(19) . . . . ?
O5 Dy1 O6 C28 18.1(3) . . . . ?
O2 Dy1 O6 C28 145.8(3) . . . . ?
O4 Dy1 O6 C28 -62.4(3) . . . . ?
O1 Dy1 O6 C28 83.8(3) . . . . ?
O3 Dy1 O6 C28 -136.8(3) . . . . ?
N2 Dy1 O6 C28 -170.6(2) . . . . ?
N1 Dy1 O6 C28 -22.9(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.01
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.508
_refine_diff_density_min         -0.529
_refine_diff_density_rms         0.089
