# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mp
_database_code_depnum_ccdc_archive 'CCDC 1051838'
_audit_update_record             
;
2015-05-15 deposited with the CCDC.
2015-05-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        'TpyRu-Ag Polymer'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C36 H34 Ag N10 O Ru, 3(F6 P)'
_chemical_formula_sum            'C36 H34 Ag F18 N10 O P3 Ru'
_chemical_formula_weight         1266.58

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P2(1)/c  '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.726(3)
_cell_length_b                   14.091(3)
_cell_length_c                   20.346(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 93.632(4)
_cell_angle_gamma                90.00
_cell_volume                     4499.5(16)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    7687
_cell_measurement_theta_min      2.22
_cell_measurement_theta_max      27.77

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.870
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2504
_exptl_absorpt_coefficient_mu    0.998
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8648
_exptl_absorpt_correction_T_max  0.8813
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            39367
_diffrn_reflns_av_R_equivalents  0.0616
_diffrn_reflns_av_sigmaI/netI    0.0645
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         1.30
_diffrn_reflns_theta_max         28.32
_reflns_number_total             10834
_reflns_number_gt                8718
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0487P)²+4.3852P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10834
_refine_ls_number_parameters     635
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0621
_refine_ls_R_factor_gt           0.0478
_refine_ls_wR_factor_ref         0.1199
_refine_ls_wR_factor_gt          0.1123
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.285119(18) 0.364285(18) 0.329500(14) 0.02408(9) Uani 1 1 d . . .
Ru1 Ru 0.272001(15) -0.135719(17) 0.338264(12) 0.01229(8) Uani 1 1 d . . .
P1 P 0.23733(6) 0.34324(7) 0.10595(5) 0.0268(2) Uani 1 1 d . . .
P2 P 0.20742(7) 0.90475(7) 0.06046(5) 0.0264(2) Uani 1 1 d . . .
P3 P 0.49637(6) 0.89357(7) 0.74030(5) 0.0223(2) Uani 1 1 d . . .
F1 F 0.20768(17) 0.3850(2) 0.17407(14) 0.0523(8) Uani 1 1 d . . .
F2 F 0.32298(14) 0.30634(17) 0.14302(12) 0.0368(5) Uani 1 1 d . . .
F3 F 0.19131(16) 0.24654(17) 0.12187(12) 0.0458(7) Uani 1 1 d . . .
F4 F 0.15057(14) 0.38060(17) 0.06879(12) 0.0388(6) Uani 1 1 d . . .
F5 F 0.28226(17) 0.4416(2) 0.09235(19) 0.0757(11) Uani 1 1 d . . .
F6 F 0.26641(18) 0.3015(3) 0.03914(12) 0.0667(10) Uani 1 1 d . . .
F7 F 0.25172(15) 0.95697(16) 0.12410(10) 0.0346(5) Uani 1 1 d . . .
F8 F 0.20690(19) 0.80784(16) 0.10140(11) 0.0479(7) Uani 1 1 d . . .
F9 F 0.29994(16) 0.87748(17) 0.03631(11) 0.0384(6) Uani 1 1 d . . .
F10 F 0.21082(15) 1.00141(16) 0.02027(11) 0.0377(6) Uani 1 1 d . . .
F11 F 0.11624(15) 0.93216(18) 0.08501(11) 0.0396(6) Uani 1 1 d . . .
F12 F 0.16322(16) 0.85242(18) -0.00237(11) 0.0413(6) Uani 1 1 d . . .
F13 F 0.57563(12) 0.93215(15) 0.78606(10) 0.0274(5) Uani 1 1 d . . .
F14 F 0.45062(14) 0.85948(18) 0.80394(11) 0.0381(6) Uani 1 1 d . . .
F15 F 0.54241(15) 0.79287(16) 0.73670(13) 0.0433(6) Uani 1 1 d . . .
F16 F 0.54206(14) 0.92703(19) 0.67636(11) 0.0413(6) Uani 1 1 d . . .
F17 F 0.45098(14) 0.99434(16) 0.74390(12) 0.0369(5) Uani 1 1 d . . .
F18 F 0.41670(13) 0.85513(15) 0.69383(11) 0.0298(5) Uani 1 1 d . . .
O1 O -0.06951(16) -0.10850(19) 0.75703(12) 0.0300(6) Uani 1 1 d . . .
N1 N 0.37062(17) -0.13460(18) 0.41064(14) 0.0162(6) Uani 1 1 d . . .
N2 N 0.20699(17) -0.13283(17) 0.41692(13) 0.0133(5) Uani 1 1 d . . .
N3 N 0.14797(17) -0.13907(17) 0.29629(13) 0.0151(5) Uani 1 1 d . . .
N4 N 0.27390(16) -0.28295(19) 0.33452(13) 0.0153(5) Uani 1 1 d . . .
N5 N 0.27301(16) 0.01128(19) 0.33455(13) 0.0147(5) Uani 1 1 d . . .
N6 N 0.28232(17) 0.2093(2) 0.32556(13) 0.0188(6) Uani 1 1 d . . .
N7 N 0.28260(18) 0.5192(2) 0.32706(14) 0.0214(6) Uani 1 1 d . . .
N8 N 0.34481(17) -0.13690(17) 0.25742(13) 0.0154(5) Uani 1 1 d . . .
N9 N 0.3814(2) 0.3625(2) 0.44061(17) 0.0342(8) Uani 1 1 d . . .
N10 N 0.1441(2) 0.3647(3) 0.39266(18) 0.0391(9) Uani 1 1 d . . .
C1 C 0.4552(2) -0.1358(2) 0.40402(18) 0.0217(7) Uani 1 1 d . . .
H1 H 0.4753 -0.1382 0.3610 0.026 Uiso 1 1 calc R . .
C2 C 0.5138(2) -0.1338(3) 0.45741(19) 0.0259(8) Uani 1 1 d . . .
H2 H 0.5731 -0.1345 0.4509 0.031 Uiso 1 1 calc R . .
C3 C 0.4858(2) -0.1307(3) 0.52053(19) 0.0256(8) Uani 1 1 d . . .
H3 H 0.5255 -0.1295 0.5577 0.031 Uiso 1 1 calc R . .
C4 C 0.3985(2) -0.1293(2) 0.52856(17) 0.0207(7) Uani 1 1 d . . .
H4 H 0.3777 -0.1268 0.5714 0.025 Uiso 1 1 calc R . .
C5 C 0.3426(2) -0.1317(2) 0.47340(16) 0.0161(6) Uani 1 1 d . . .
C6 C 0.2487(2) -0.1285(2) 0.47674(16) 0.0147(6) Uani 1 1 d . . .
C7 C 0.2045(2) -0.1222(2) 0.53268(16) 0.0168(6) Uani 1 1 d . . .
H7 H 0.2344 -0.1215 0.5747 0.020 Uiso 1 1 calc R . .
C8 C 0.1150(2) -0.1169(2) 0.52799(16) 0.0153(6) Uani 1 1 d . . .
C9 C 0.0735(2) -0.1201(2) 0.46498(16) 0.0167(7) Uani 1 1 d . . .
H9 H 0.0131 -0.1160 0.4599 0.020 Uiso 1 1 calc R . .
C10 C 0.1205(2) -0.1291(2) 0.41045(16) 0.0162(6) Uani 1 1 d . . .
C11 C 0.0876(2) -0.1373(2) 0.34118(16) 0.0165(6) Uani 1 1 d . . .
C12 C 0.0019(2) -0.1451(2) 0.32254(17) 0.0193(7) Uani 1 1 d . . .
H12 H -0.0392 -0.1425 0.3548 0.023 Uiso 1 1 calc R . .
C13 C -0.0241(2) -0.1567(3) 0.25657(17) 0.0231(7) Uani 1 1 d . . .
H13 H -0.0828 -0.1627 0.2431 0.028 Uiso 1 1 calc R . .
C14 C 0.0373(2) -0.1593(2) 0.21088(16) 0.0203(7) Uani 1 1 d . . .
H14 H 0.0215 -0.1680 0.1654 0.024 Uiso 1 1 calc R . .
C15 C 0.1223(2) -0.1489(2) 0.23247(16) 0.0180(7) Uani 1 1 d . . .
H15 H 0.1641 -0.1487 0.2007 0.022 Uiso 1 1 calc R . .
C16 C 0.0666(2) -0.1110(2) 0.58818(16) 0.0173(7) Uani 1 1 d . . .
C17 C 0.1069(2) -0.0871(3) 0.64844(17) 0.0241(7) Uani 1 1 d . . .
H17 H 0.1659 -0.0721 0.6504 0.029 Uiso 1 1 calc R . .
C18 C 0.0644(2) -0.0844(3) 0.70571(17) 0.0236(7) Uani 1 1 d . . .
H18 H 0.0938 -0.0672 0.7462 0.028 Uiso 1 1 calc R . .
C19 C -0.0217(2) -0.1069(2) 0.70381(17) 0.0216(7) Uani 1 1 d . . .
C20 C -0.0631(2) -0.1288(3) 0.64370(18) 0.0261(8) Uani 1 1 d . . .
H20 H -0.1223 -0.1426 0.6416 0.031 Uiso 1 1 calc R . .
C21 C -0.0200(2) -0.1308(2) 0.58695(18) 0.0229(7) Uani 1 1 d . . .
H21 H -0.0499 -0.1460 0.5463 0.027 Uiso 1 1 calc R . .
C22 C -0.0272(3) -0.0955(3) 0.82065(17) 0.0313(9) Uani 1 1 d . . .
H22A H 0.0149 -0.1462 0.8289 0.047 Uiso 1 1 calc R . .
H22B H -0.0691 -0.0977 0.8543 0.047 Uiso 1 1 calc R . .
H22C H 0.0017 -0.0339 0.8223 0.047 Uiso 1 1 calc R . .
C23 C 0.2844(2) -0.3373(2) 0.38763(17) 0.0235(7) Uani 1 1 d . . .
H23 H 0.2899 -0.3078 0.4297 0.028 Uiso 1 1 calc R . .
C24 C 0.2668(2) -0.3295(2) 0.27621(16) 0.0187(7) Uani 1 1 d . . .
H24 H 0.2577 -0.2943 0.2366 0.022 Uiso 1 1 calc R . .
C25 C 0.2861(2) 0.0669(2) 0.38846(16) 0.0161(6) Uani 1 1 d . . .
H25 H 0.2925 0.0381 0.4307 0.019 Uiso 1 1 calc R . .
C26 C 0.2905(2) 0.1640(2) 0.38369(16) 0.0189(7) Uani 1 1 d . . .
H26 H 0.2995 0.2004 0.4228 0.023 Uiso 1 1 calc R . .
C27 C 0.2678(2) 0.1551(2) 0.27234(17) 0.0193(7) Uani 1 1 d . . .
H27 H 0.2609 0.1846 0.2303 0.023 Uiso 1 1 calc R . .
C28 C 0.2626(2) 0.0570(2) 0.27641(16) 0.0166(6) Uani 1 1 d . . .
H28 H 0.2514 0.0212 0.2373 0.020 Uiso 1 1 calc R . .
C29 C 0.2876(3) 0.5648(3) 0.38414(18) 0.0274(8) Uani 1 1 d . . .
H29 H 0.2935 0.5292 0.4238 0.033 Uiso 1 1 calc R . .
C30 C 0.2725(2) 0.5728(2) 0.27310(17) 0.0205(7) Uani 1 1 d . . .
H30 H 0.2691 0.5428 0.2312 0.025 Uiso 1 1 calc R . .
C31 C 0.3878(2) -0.1373(2) 0.21478(17) 0.0182(7) Uani 1 1 d . . .
C32 C 0.4423(2) -0.1369(2) 0.15944(18) 0.0239(7) Uani 1 1 d . . .
H32A H 0.4071 -0.1293 0.1183 0.036 Uiso 1 1 calc R . .
H32B H 0.4736 -0.1970 0.1584 0.036 Uiso 1 1 calc R . .
H32C H 0.4828 -0.0842 0.1644 0.036 Uiso 1 1 calc R . .
C33 C 0.3920(3) 0.3718(3) 0.4954(2) 0.0289(8) Uani 1 1 d . . .
C34 C 0.4049(3) 0.3845(3) 0.5670(2) 0.0399(10) Uani 1 1 d . . .
H34A H 0.4649 0.3991 0.5785 0.060 Uiso 1 1 calc R . .
H34B H 0.3891 0.3260 0.5893 0.060 Uiso 1 1 calc R . .
H34C H 0.3692 0.4368 0.5810 0.060 Uiso 1 1 calc R . .
C35 C 0.1089(2) 0.3615(3) 0.4395(2) 0.0299(8) Uani 1 1 d . . .
C36 C 0.0626(3) 0.3577(3) 0.4996(2) 0.0355(9) Uani 1 1 d . . .
H36A H 0.0641 0.4202 0.5207 0.053 Uiso 1 1 calc R . .
H36B H 0.0893 0.3107 0.5299 0.053 Uiso 1 1 calc R . .
H36C H 0.0033 0.3395 0.4885 0.053 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N7 2.184(3) . ?
Ag1 N6 2.186(3) . ?
Ag1 N10 2.632(4) . ?
Ag1 N9 2.640(3) . ?
Ru1 N2 1.953(3) . ?
Ru1 N8 2.063(3) . ?
Ru1 N1 2.070(3) . ?
Ru1 N5 2.073(3) . ?
Ru1 N4 2.076(3) . ?
Ru1 N3 2.080(3) . ?
P1 F6 1.575(3) . ?
P1 F3 1.586(2) . ?
P1 F5 1.588(3) . ?
P1 F2 1.589(2) . ?
P1 F1 1.602(3) . ?
P1 F4 1.606(2) . ?
P2 F10 1.591(2) . ?
P2 F11 1.595(2) . ?
P2 F12 1.596(2) . ?
P2 F8 1.600(2) . ?
P2 F7 1.609(2) . ?
P2 F9 1.611(3) . ?
P3 F17 1.593(2) . ?
P3 F14 1.595(2) . ?
P3 F16 1.597(2) . ?
P3 F15 1.597(2) . ?
P3 F13 1.603(2) . ?
P3 F18 1.615(2) . ?
O1 C19 1.357(4) . ?
O1 C22 1.429(5) . ?
N1 C1 1.345(4) . ?
N1 C5 1.378(4) . ?
N2 C6 1.347(4) . ?
N2 C10 1.360(4) . ?
N3 C15 1.342(4) . ?
N3 C11 1.359(4) . ?
N4 C23 1.326(4) . ?
N4 C24 1.354(4) . ?
N5 C28 1.348(4) . ?
N5 C25 1.353(4) . ?
N6 C27 1.333(4) . ?
N6 C26 1.343(4) . ?
N7 C29 1.325(4) . ?
N7 C30 1.334(4) . ?
N8 C31 1.133(4) . ?
N9 C33 1.125(5) . ?
N10 C35 1.134(5) . ?
C1 C2 1.380(5) . ?
C1 H1 0.9500 . ?
C2 C3 1.384(5) . ?
C2 H2 0.9500 . ?
C3 C4 1.394(5) . ?
C3 H3 0.9500 . ?
C4 C5 1.382(5) . ?
C4 H4 0.9500 . ?
C5 C6 1.483(4) . ?
C6 C7 1.374(4) . ?
C7 C8 1.406(4) . ?
C7 H7 0.9500 . ?
C8 C9 1.402(5) . ?
C8 C16 1.484(4) . ?
C9 C10 1.377(5) . ?
C9 H9 0.9500 . ?
C10 C11 1.475(5) . ?
C11 C12 1.381(5) . ?
C12 C13 1.388(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.382(5) . ?
C13 H13 0.9500 . ?
C14 C15 1.388(5) . ?
C14 H14 0.9500 . ?
C15 H15 0.9500 . ?
C16 C17 1.385(5) . ?
C16 C21 1.389(5) . ?
C17 C18 1.380(5) . ?
C17 H17 0.9500 . ?
C18 C19 1.389(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.383(5) . ?
C20 C21 1.375(5) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C29 1.383(5) 1_545 ?
C23 H23 0.9500 . ?
C24 C30 1.381(5) 1_545 ?
C24 H24 0.9500 . ?
C25 C26 1.374(5) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 C28 1.388(4) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 C23 1.383(5) 1_565 ?
C29 H29 0.9500 . ?
C30 C24 1.381(5) 1_565 ?
C30 H30 0.9500 . ?
C31 C32 1.457(5) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C34 1.468(6) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.463(6) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N7 Ag1 N6 176.07(11) . . ?
N7 Ag1 N10 89.66(11) . . ?
N6 Ag1 N10 90.27(11) . . ?
N7 Ag1 N9 92.14(10) . . ?
N6 Ag1 N9 91.79(10) . . ?
N10 Ag1 N9 92.14(12) . . ?
N2 Ru1 N8 177.74(11) . . ?
N2 Ru1 N1 79.89(11) . . ?
N8 Ru1 N1 97.96(11) . . ?
N2 Ru1 N5 90.84(10) . . ?
N8 Ru1 N5 88.46(10) . . ?
N1 Ru1 N5 90.64(10) . . ?
N2 Ru1 N4 93.46(10) . . ?
N8 Ru1 N4 87.29(10) . . ?
N1 Ru1 N4 91.25(10) . . ?
N5 Ru1 N4 175.54(10) . . ?
N2 Ru1 N3 79.10(11) . . ?
N8 Ru1 N3 103.06(11) . . ?
N1 Ru1 N3 158.95(11) . . ?
N5 Ru1 N3 90.97(10) . . ?
N4 Ru1 N3 88.71(10) . . ?
F6 P1 F3 90.96(17) . . ?
F6 P1 F5 91.1(2) . . ?
F3 P1 F5 177.97(19) . . ?
F6 P1 F2 90.22(14) . . ?
F3 P1 F2 90.34(13) . . ?
F5 P1 F2 89.72(14) . . ?
F6 P1 F1 179.62(19) . . ?
F3 P1 F1 88.69(15) . . ?
F5 P1 F1 89.29(19) . . ?
F2 P1 F1 89.64(14) . . ?
F6 P1 F4 90.04(14) . . ?
F3 P1 F4 89.58(14) . . ?
F5 P1 F4 90.35(14) . . ?
F2 P1 F4 179.73(15) . . ?
F1 P1 F4 90.10(14) . . ?
F10 P2 F11 90.79(13) . . ?
F10 P2 F12 90.63(13) . . ?
F11 P2 F12 90.47(13) . . ?
F10 P2 F8 178.34(16) . . ?
F11 P2 F8 90.53(14) . . ?
F12 P2 F8 90.36(14) . . ?
F10 P2 F7 89.72(13) . . ?
F11 P2 F7 89.39(13) . . ?
F12 P2 F7 179.62(15) . . ?
F8 P2 F7 89.29(13) . . ?
F10 P2 F9 89.25(13) . . ?
F11 P2 F9 179.44(15) . . ?
F12 P2 F9 90.09(13) . . ?
F8 P2 F9 89.41(14) . . ?
F7 P2 F9 90.06(13) . . ?
F17 P3 F14 90.27(13) . . ?
F17 P3 F16 90.02(14) . . ?
F14 P3 F16 179.61(14) . . ?
F17 P3 F15 179.66(14) . . ?
F14 P3 F15 89.92(14) . . ?
F16 P3 F15 89.79(14) . . ?
F17 P3 F13 90.30(12) . . ?
F14 P3 F13 90.28(12) . . ?
F16 P3 F13 89.97(12) . . ?
F15 P3 F13 89.42(12) . . ?
F17 P3 F18 89.58(12) . . ?
F14 P3 F18 90.06(12) . . ?
F16 P3 F18 89.69(12) . . ?
F15 P3 F18 90.70(13) . . ?
F13 P3 F18 179.64(14) . . ?
C19 O1 C22 118.1(3) . . ?
C1 N1 C5 118.0(3) . . ?
C1 N1 Ru1 129.0(2) . . ?
C5 N1 Ru1 113.0(2) . . ?
C6 N2 C10 120.8(3) . . ?
C6 N2 Ru1 119.4(2) . . ?
C10 N2 Ru1 119.6(2) . . ?
C15 N3 C11 118.2(3) . . ?
C15 N3 Ru1 128.0(2) . . ?
C11 N3 Ru1 113.6(2) . . ?
C23 N4 C24 115.7(3) . . ?
C23 N4 Ru1 123.2(2) . . ?
C24 N4 Ru1 121.1(2) . . ?
C28 N5 C25 116.0(3) . . ?
C28 N5 Ru1 120.6(2) . . ?
C25 N5 Ru1 123.4(2) . . ?
C27 N6 C26 116.5(3) . . ?
C27 N6 Ag1 127.2(2) . . ?
C26 N6 Ag1 116.2(2) . . ?
C29 N7 C30 116.4(3) . . ?
C29 N7 Ag1 117.7(2) . . ?
C30 N7 Ag1 125.9(2) . . ?
C31 N8 Ru1 177.1(3) . . ?
C33 N9 Ag1 152.7(3) . . ?
C35 N10 Ag1 151.9(3) . . ?
N1 C1 C2 122.4(3) . . ?
N1 C1 H1 118.8 . . ?
C2 C1 H1 118.8 . . ?
C1 C2 C3 119.7(3) . . ?
C1 C2 H2 120.1 . . ?
C3 C2 H2 120.1 . . ?
C2 C3 C4 118.8(3) . . ?
C2 C3 H3 120.6 . . ?
C4 C3 H3 120.6 . . ?
C5 C4 C3 119.0(3) . . ?
C5 C4 H4 120.5 . . ?
C3 C4 H4 120.5 . . ?
N1 C5 C4 122.0(3) . . ?
N1 C5 C6 114.9(3) . . ?
C4 C5 C6 123.1(3) . . ?
N2 C6 C7 120.6(3) . . ?
N2 C6 C5 112.7(3) . . ?
C7 C6 C5 126.7(3) . . ?
C6 C7 C8 120.3(3) . . ?
C6 C7 H7 119.9 . . ?
C8 C7 H7 119.9 . . ?
C9 C8 C7 117.8(3) . . ?
C9 C8 C16 121.5(3) . . ?
C7 C8 C16 120.7(3) . . ?
C10 C9 C8 119.8(3) . . ?
C10 C9 H9 120.1 . . ?
C8 C9 H9 120.1 . . ?
N2 C10 C9 120.7(3) . . ?
N2 C10 C11 112.2(3) . . ?
C9 C10 C11 127.1(3) . . ?
N3 C11 C12 121.7(3) . . ?
N3 C11 C10 115.2(3) . . ?
C12 C11 C10 123.1(3) . . ?
C11 C12 C13 119.8(3) . . ?
C11 C12 H12 120.1 . . ?
C13 C12 H12 120.1 . . ?
C14 C13 C12 118.6(3) . . ?
C14 C13 H13 120.7 . . ?
C12 C13 H13 120.7 . . ?
C13 C14 C15 118.9(3) . . ?
C13 C14 H14 120.5 . . ?
C15 C14 H14 120.5 . . ?
N3 C15 C14 122.8(3) . . ?
N3 C15 H15 118.6 . . ?
C14 C15 H15 118.6 . . ?
C17 C16 C21 117.2(3) . . ?
C17 C16 C8 121.0(3) . . ?
C21 C16 C8 121.8(3) . . ?
C18 C17 C16 122.3(3) . . ?
C18 C17 H17 118.8 . . ?
C16 C17 H17 118.8 . . ?
C17 C18 C19 119.6(3) . . ?
C17 C18 H18 120.2 . . ?
C19 C18 H18 120.2 . . ?
O1 C19 C20 116.7(3) . . ?
O1 C19 C18 124.7(3) . . ?
C20 C19 C18 118.6(3) . . ?
C21 C20 C19 121.2(3) . . ?
C21 C20 H20 119.4 . . ?
C19 C20 H20 119.4 . . ?
C20 C21 C16 121.0(3) . . ?
C20 C21 H21 119.5 . . ?
C16 C21 H21 119.5 . . ?
O1 C22 H22A 109.5 . . ?
O1 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
O1 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N4 C23 C29 122.5(3) . 1_545 ?
N4 C23 H23 118.8 . . ?
C29 C23 H23 118.8 1_545 . ?
N4 C24 C30 121.4(3) . 1_545 ?
N4 C24 H24 119.3 . . ?
C30 C24 H24 119.3 1_545 . ?
N5 C25 C26 121.7(3) . . ?
N5 C25 H25 119.1 . . ?
C26 C25 H25 119.1 . . ?
N6 C26 C25 122.2(3) . . ?
N6 C26 H26 118.9 . . ?
C25 C26 H26 118.9 . . ?
N6 C27 C28 122.0(3) . . ?
N6 C27 H27 119.0 . . ?
C28 C27 H27 119.0 . . ?
N5 C28 C27 121.6(3) . . ?
N5 C28 H28 119.2 . . ?
C27 C28 H28 119.2 . . ?
N7 C29 C23 121.9(3) . 1_565 ?
N7 C29 H29 119.0 . . ?
C23 C29 H29 119.0 1_565 . ?
N7 C30 C24 122.1(3) . 1_565 ?
N7 C30 H30 119.0 . . ?
C24 C30 H30 119.0 1_565 . ?
N8 C31 C32 179.2(4) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N9 C33 C34 179.4(5) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
N10 C35 C36 179.3(5) . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.967
_diffrn_reflns_theta_full        26.30
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         1.584
_refine_diff_density_min         -0.635
_refine_diff_density_rms         0.140
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: CH3CN/H2O'
