# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 932369'
_audit_update_record             
;
2015-04-01 deposited with the CCDC.
2015-06-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C73 H50 Cu7 N31 O'
_chemical_formula_weight         1822.22

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'

_cell_length_a                   18.775(3)
_cell_length_b                   15.626(3)
_cell_length_c                   12.872(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 99.973(2)
_cell_angle_gamma                90.00
_cell_volume                     3719.2(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       prism
_exptl_crystal_colour            ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.627
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1832
_exptl_absorpt_coefficient_mu    2.031
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            9690
_diffrn_reflns_av_R_equivalents  0.0498
_diffrn_reflns_av_sigmaI/netI    0.1073
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         1.71
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6106
_reflns_number_gt                3950
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0338P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.04(2)
_refine_ls_number_reflns         6106
_refine_ls_number_parameters     506
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.1017
_refine_ls_R_factor_gt           0.0562
_refine_ls_wR_factor_ref         0.1158
_refine_ls_wR_factor_gt          0.1013
_refine_ls_goodness_of_fit_ref   0.968
_refine_ls_restrained_S_all      0.968
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1023(6) 0.7650(6) 1.1966(7) 0.077(4) Uani 1 1 d . . .
H1 H 0.1030 0.8235 1.1836 0.093 Uiso 1 1 calc R . .
C2 C 0.0995(6) 0.7093(6) 1.1128(7) 0.077(3) Uani 1 1 d . . .
H2 H 0.1005 0.7309 1.0457 0.093 Uiso 1 1 calc R . .
C3 C 0.0952(4) 0.6216(5) 1.1270(6) 0.043(2) Uani 1 1 d . . .
C4 C 0.0949(5) 0.5964(6) 1.2299(7) 0.062(3) Uani 1 1 d . . .
H4 H 0.0907 0.5387 1.2455 0.075 Uiso 1 1 calc R . .
C5 C 0.1010(5) 0.6563(6) 1.3094(7) 0.063(3) Uani 1 1 d . . .
H5 H 0.1029 0.6368 1.3781 0.075 Uiso 1 1 calc R . .
C6 C 0.0920(4) 0.5650(5) 1.0367(6) 0.044(2) Uani 1 1 d . . .
C7 C 0.0932(4) 0.5246(6) 0.8814(6) 0.044(2) Uani 1 1 d . . .
C8 C 0.0949(5) 0.5274(6) 0.7685(6) 0.047(2) Uani 1 1 d . . .
C9 C 0.0871(5) 0.6032(7) 0.7173(7) 0.068(3) Uani 1 1 d . . .
H9 H 0.0791 0.6529 0.7534 0.082 Uiso 1 1 calc R . .
C10 C 0.0909(6) 0.6069(8) 0.6095(8) 0.090(4) Uani 1 1 d . . .
H10 H 0.0854 0.6601 0.5767 0.108 Uiso 1 1 calc R . .
C11 C 0.1079(6) 0.4681(9) 0.6019(8) 0.085(3) Uani 1 1 d . . .
H11 H 0.1138 0.4194 0.5628 0.102 Uiso 1 1 calc R . .
C12 C 0.1066(5) 0.4569(7) 0.7085(7) 0.064(3) Uani 1 1 d . . .
H12 H 0.1134 0.4029 0.7390 0.077 Uiso 1 1 calc R . .
C13 C -0.1974(5) 0.3500(6) 0.6475(7) 0.071(3) Uani 1 1 d . . .
H13 H -0.1842 0.3859 0.7053 0.085 Uiso 1 1 calc R . .
C14 C -0.2661(5) 0.3541(6) 0.5893(8) 0.074(3) Uani 1 1 d . . .
H14 H -0.2975 0.3938 0.6107 0.089 Uiso 1 1 calc R . .
C15 C -0.2441(6) 0.2530(7) 0.4804(9) 0.093(4) Uani 1 1 d . . .
H15 H -0.2585 0.2185 0.4217 0.111 Uiso 1 1 calc R . .
C16 C -0.1756(5) 0.2439(8) 0.5336(9) 0.096(4) Uani 1 1 d . . .
H16 H -0.1458 0.2030 0.5107 0.115 Uiso 1 1 calc R . .
C17 C -0.1487(5) 0.2933(5) 0.6204(6) 0.042(2) Uani 1 1 d . . .
C18 C -0.0758(5) 0.2781(5) 0.6759(7) 0.044(2) Uani 1 1 d . . .
C19 C 0.0251(5) 0.2234(6) 0.7174(7) 0.050(2) Uani 1 1 d . . .
C20 C 0.0872(4) 0.1656(6) 0.7140(7) 0.047(2) Uani 1 1 d . . .
C21 C 0.0838(5) 0.1067(6) 0.6343(8) 0.075(3) Uani 1 1 d . . .
H21 H 0.0432 0.1041 0.5815 0.090 Uiso 1 1 calc R . .
C22 C 0.1409(8) 0.0511(7) 0.6327(9) 0.092(4) Uani 1 1 d . . .
H22 H 0.1379 0.0149 0.5748 0.111 Uiso 1 1 calc R . .
C23 C 0.2015(6) 0.1009(9) 0.7791(10) 0.104(5) Uani 1 1 d . . .
H23 H 0.2426 0.1001 0.8312 0.125 Uiso 1 1 calc R . .
C24 C 0.1486(5) 0.1622(8) 0.7879(9) 0.089(4) Uani 1 1 d . . .
H24 H 0.1554 0.2006 0.8440 0.107 Uiso 1 1 calc R . .
C25 C 0.2580(6) 0.3699(6) 0.9932(10) 0.087(4) Uani 1 1 d . . .
H25 H 0.2170 0.3731 0.9411 0.104 Uiso 1 1 calc R . .
C26 C 0.3182(7) 0.4237(7) 0.9889(12) 0.105(5) Uani 1 1 d . . .
H26 H 0.3138 0.4642 0.9353 0.126 Uiso 1 1 calc R . .
C27 C 0.3801(6) 0.3671(8) 1.1311(10) 0.096(4) Uani 1 1 d . . .
H27 H 0.4226 0.3641 1.1803 0.116 Uiso 1 1 calc R . .
C28 C 0.3233(5) 0.3137(8) 1.1464(9) 0.085(3) Uani 1 1 d . . .
H28 H 0.3277 0.2783 1.2052 0.102 Uiso 1 1 calc R . .
C29 C 0.2608(4) 0.3141(6) 1.0735(7) 0.056(2) Uani 1 1 d . . .
C30 C 0.2016(5) 0.2545(6) 1.0865(7) 0.050(2) Uani 1 1 d . . .
C31 C 0.1466(4) 0.1539(5) 1.1451(6) 0.044(2) Uani 1 1 d . . .
C32 C 0.1347(4) 0.0824(5) 1.2125(6) 0.042(2) Uani 1 1 d . . .
C33 C 0.1949(5) 0.0448(6) 1.2746(7) 0.060(3) Uani 1 1 d . . .
H33 H 0.2411 0.0653 1.2729 0.072 Uiso 1 1 calc R . .
C34 C 0.1847(5) -0.0234(6) 1.3386(7) 0.065(3) Uani 1 1 d . . .
H34 H 0.2253 -0.0464 1.3810 0.078 Uiso 1 1 calc R . .
C35 C 0.0649(5) -0.0197(6) 1.2895(8) 0.063(3) Uani 1 1 d . . .
H35 H 0.0193 -0.0392 1.2971 0.076 Uiso 1 1 calc R . .
C36 C 0.0687(5) 0.0477(6) 1.2223(7) 0.064(3) Uani 1 1 d . . .
H36 H 0.0265 0.0701 1.1832 0.077 Uiso 1 1 calc R . .
Cu1 Cu 0.08101(5) 0.32728(7) 0.91829(7) 0.0492(3) Uani 1 1 d . . .
Cu2 Cu 0.10907(5) -0.17390(8) 1.41894(8) 0.0546(3) Uani 1 1 d . . .
Cu3 Cu -0.06956(5) 0.39920(7) 0.86003(8) 0.0473(3) Uani 1 1 d . . .
Cu4 Cu 0.0000 0.17104(10) 1.0000 0.0538(4) Uani 1 2 d S . .
N1 N 0.1040(4) 0.7387(5) 1.2944(6) 0.0534(19) Uani 1 1 d . . .
N2 N 0.0873(3) 0.4805(4) 1.0409(5) 0.0379(17) Uani 1 1 d . . .
N3 N 0.0878(3) 0.4520(4) 0.9377(5) 0.0426(17) Uani 1 1 d . . .
N4 N 0.0956(4) 0.5950(4) 0.9407(5) 0.0473(18) Uani 1 1 d . . .
N5 N 0.1017(5) 0.5406(8) 0.5519(7) 0.090(3) Uani 1 1 d . . .
N6 N -0.2914(3) 0.3072(5) 0.5063(5) 0.053(2) Uani 1 1 d . . .
N7 N -0.0334(4) 0.2203(4) 0.6423(6) 0.0526(19) Uani 1 1 d . . .
N8 N -0.0452(3) 0.3193(5) 0.7638(5) 0.0458(16) Uani 1 1 d . . .
N9 N 0.0227(4) 0.2817(4) 0.7923(5) 0.0431(17) Uani 1 1 d . . .
N10 N 0.1978(5) 0.0450(6) 0.7039(8) 0.094(3) Uani 1 1 d . . .
N11 N 0.3782(6) 0.4206(7) 1.0535(10) 0.101(4) Uani 1 1 d . . .
N12 N 0.2112(3) 0.1936(4) 1.1598(6) 0.0502(18) Uani 1 1 d . . .
N13 N 0.1341(4) 0.2574(4) 1.0303(5) 0.0438(18) Uani 1 1 d . . .
N14 N 0.0981(4) 0.1892(4) 1.0673(6) 0.0464(19) Uani 1 1 d . . .
N15 N 0.1213(4) -0.0584(4) 1.3438(6) 0.053(2) Uani 1 1 d . . .
C37 C 0.0268(4) -0.1733(6) 1.4819(6) 0.062(2) Uani 0.50 1 d P . .
N16 N 0.0268(4) -0.1733(6) 1.4819(6) 0.062(2) Uani 0.50 1 d P . .
O1 O 0.0000 0.0149(6) 1.0000 0.087(3) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.320(11) . ?
C1 C2 1.380(12) . ?
C1 H1 0.9300 . ?
C2 C3 1.386(12) . ?
C2 H2 0.9300 . ?
C3 C4 1.383(11) . ?
C3 C6 1.453(11) . ?
C4 C5 1.378(12) . ?
C4 H4 0.9300 . ?
C5 N1 1.304(11) . ?
C5 H5 0.9300 . ?
C6 N4 1.334(9) . ?
C6 N2 1.326(10) . ?
C7 N4 1.335(10) . ?
C7 N3 1.360(10) . ?
C7 C8 1.460(11) . ?
C8 C9 1.352(12) . ?
C8 C12 1.386(12) . ?
C9 C10 1.402(12) . ?
C9 H9 0.9300 . ?
C10 N5 1.310(14) . ?
C10 H10 0.9300 . ?
C11 N5 1.298(13) . ?
C11 C12 1.388(12) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C17 1.360(11) . ?
C13 C14 1.377(12) . ?
C13 H13 0.9300 . ?
C14 N6 1.315(10) . ?
C14 H14 0.9300 . ?
C15 N6 1.311(11) . ?
C15 C16 1.355(13) . ?
C15 H15 0.9300 . ?
C16 C17 1.381(12) . ?
C16 H16 0.9300 . ?
C17 C18 1.449(11) . ?
C18 N7 1.323(9) . ?
C18 N8 1.342(9) . ?
C19 N7 1.333(10) . ?
C19 N9 1.333(10) . ?
C19 C20 1.481(11) . ?
C20 C24 1.364(12) . ?
C20 C21 1.372(12) . ?
C21 C22 1.383(13) . ?
C21 H21 0.9300 . ?
C22 N10 1.284(13) . ?
C22 H22 0.9300 . ?
C23 N10 1.296(12) . ?
C23 C24 1.399(14) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C29 1.346(12) . ?
C25 C26 1.418(14) . ?
C25 H25 0.9300 . ?
C26 N11 1.278(14) . ?
C26 H26 0.9300 . ?
C27 N11 1.299(14) . ?
C27 C28 1.395(14) . ?
C27 H27 0.9300 . ?
C28 C29 1.368(12) . ?
C28 H28 0.9300 . ?
C29 C30 1.483(12) . ?
C30 N12 1.330(10) . ?
C30 N13 1.347(10) . ?
C31 N12 1.345(9) . ?
C31 N14 1.348(10) . ?
C31 C32 1.455(11) . ?
C32 C36 1.379(11) . ?
C32 C33 1.395(11) . ?
C33 C34 1.380(12) . ?
C33 H33 0.9300 . ?
C34 N15 1.322(10) . ?
C34 H34 0.9300 . ?
C35 N15 1.311(10) . ?
C35 C36 1.373(12) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
Cu1 N9 1.929(7) . ?
Cu1 N13 1.941(7) . ?
Cu1 N3 1.966(7) . ?
Cu1 Cu3 3.0138(15) . ?
Cu2 C37 1.865(6) . ?
Cu2 N6 2.029(7) 3_546 ?
Cu2 N15 2.079(7) . ?
Cu2 N1 2.095(8) 1_545 ?
Cu3 N2 1.870(7) 2_557 ?
Cu3 N8 1.871(7) . ?
Cu4 N14 1.916(7) . ?
Cu4 N14 1.916(7) 2_557 ?
Cu4 O1 2.440(10) . ?
N1 Cu2 2.095(8) 1_565 ?
N2 N3 1.402(8) . ?
N2 Cu3 1.870(7) 2_557 ?
N6 Cu2 2.029(7) 3_454 ?
N8 N9 1.393(8) . ?
N13 N14 1.390(9) . ?
C37 N16 1.179(12) 2_558 ?
C37 C37 1.179(12) 2_558 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 122.7(9) . . ?
N1 C1 H1 118.6 . . ?
C2 C1 H1 118.6 . . ?
C1 C2 C3 121.1(9) . . ?
C1 C2 H2 119.5 . . ?
C3 C2 H2 119.5 . . ?
C4 C3 C2 114.7(9) . . ?
C4 C3 C6 125.9(8) . . ?
C2 C3 C6 119.4(8) . . ?
C3 C4 C5 120.3(9) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
N1 C5 C4 124.2(9) . . ?
N1 C5 H5 117.9 . . ?
C4 C5 H5 117.9 . . ?
N4 C6 N2 113.7(7) . . ?
N4 C6 C3 121.7(8) . . ?
N2 C6 C3 124.6(7) . . ?
N4 C7 N3 112.4(7) . . ?
N4 C7 C8 122.7(8) . . ?
N3 C7 C8 124.9(8) . . ?
C9 C8 C12 116.1(8) . . ?
C9 C8 C7 119.6(8) . . ?
C12 C8 C7 124.4(8) . . ?
C8 C9 C10 119.9(10) . . ?
C8 C9 H9 120.0 . . ?
C10 C9 H9 120.0 . . ?
N5 C10 C9 124.5(11) . . ?
N5 C10 H10 117.7 . . ?
C9 C10 H10 117.7 . . ?
N5 C11 C12 125.8(11) . . ?
N5 C11 H11 117.1 . . ?
C12 C11 H11 117.1 . . ?
C11 C12 C8 118.9(10) . . ?
C11 C12 H12 120.6 . . ?
C8 C12 H12 120.6 . . ?
C17 C13 C14 120.0(9) . . ?
C17 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
N6 C14 C13 126.0(8) . . ?
N6 C14 H14 117.0 . . ?
C13 C14 H14 117.0 . . ?
N6 C15 C16 124.4(9) . . ?
N6 C15 H15 117.8 . . ?
C16 C15 H15 117.8 . . ?
C15 C16 C17 122.2(9) . . ?
C15 C16 H16 118.9 . . ?
C17 C16 H16 118.9 . . ?
C13 C17 C16 113.8(8) . . ?
C13 C17 C18 126.9(8) . . ?
C16 C17 C18 119.3(8) . . ?
N7 C18 N8 114.1(7) . . ?
N7 C18 C17 121.4(7) . . ?
N8 C18 C17 124.4(7) . . ?
N7 C19 N9 114.9(8) . . ?
N7 C19 C20 120.7(8) . . ?
N9 C19 C20 124.3(8) . . ?
C24 C20 C21 114.9(9) . . ?
C24 C20 C19 125.3(8) . . ?
C21 C20 C19 119.8(8) . . ?
C22 C21 C20 119.8(10) . . ?
C22 C21 H21 120.1 . . ?
C20 C21 H21 120.1 . . ?
N10 C22 C21 126.0(10) . . ?
N10 C22 H22 117.0 . . ?
C21 C22 H22 117.0 . . ?
N10 C23 C24 125.1(11) . . ?
N10 C23 H23 117.5 . . ?
C24 C23 H23 117.5 . . ?
C20 C24 C23 119.8(10) . . ?
C20 C24 H24 120.1 . . ?
C23 C24 H24 120.1 . . ?
C29 C25 C26 119.2(11) . . ?
C29 C25 H25 120.4 . . ?
C26 C25 H25 120.4 . . ?
N11 C26 C25 124.8(12) . . ?
N11 C26 H26 117.6 . . ?
C25 C26 H26 117.6 . . ?
N11 C27 C28 124.9(11) . . ?
N11 C27 H27 117.5 . . ?
C28 C27 H27 117.5 . . ?
C29 C28 C27 119.1(11) . . ?
C29 C28 H28 120.5 . . ?
C27 C28 H28 120.5 . . ?
C25 C29 C28 116.4(10) . . ?
C25 C29 C30 124.3(9) . . ?
C28 C29 C30 119.3(9) . . ?
N12 C30 N13 113.8(7) . . ?
N12 C30 C29 121.2(8) . . ?
N13 C30 C29 124.9(8) . . ?
N12 C31 N14 113.1(7) . . ?
N12 C31 C32 119.7(8) . . ?
N14 C31 C32 127.1(7) . . ?
C36 C32 C33 115.7(8) . . ?
C36 C32 C31 126.1(8) . . ?
C33 C32 C31 118.2(7) . . ?
C34 C33 C32 119.0(8) . . ?
C34 C33 H33 120.5 . . ?
C32 C33 H33 120.5 . . ?
N15 C34 C33 124.7(9) . . ?
N15 C34 H34 117.7 . . ?
C33 C34 H34 117.7 . . ?
N15 C35 C36 124.4(9) . . ?
N15 C35 H35 117.8 . . ?
C36 C35 H35 117.8 . . ?
C35 C36 C32 120.3(9) . . ?
C35 C36 H36 119.8 . . ?
C32 C36 H36 119.8 . . ?
N9 Cu1 N13 124.1(3) . . ?
N9 Cu1 N3 119.2(3) . . ?
N13 Cu1 N3 116.7(3) . . ?
N9 Cu1 Cu3 63.70(19) . . ?
N13 Cu1 Cu3 137.2(2) . . ?
N3 Cu1 Cu3 72.49(19) . . ?
C37 Cu2 N6 120.9(3) . 3_546 ?
C37 Cu2 N15 111.4(3) . . ?
N6 Cu2 N15 102.7(3) 3_546 . ?
C37 Cu2 N1 113.9(3) . 1_545 ?
N6 Cu2 N1 104.1(3) 3_546 1_545 ?
N15 Cu2 N1 101.8(3) . 1_545 ?
N2 Cu3 N8 176.1(3) 2_557 . ?
N2 Cu3 Cu1 110.7(2) 2_557 . ?
N8 Cu3 Cu1 65.75(19) . . ?
N14 Cu4 N14 163.0(4) . 2_557 ?
N14 Cu4 O1 98.5(2) . . ?
N14 Cu4 O1 98.5(2) 2_557 . ?
C5 N1 C1 117.0(8) . . ?
C5 N1 Cu2 121.9(6) . 1_565 ?
C1 N1 Cu2 121.1(6) . 1_565 ?
C6 N2 N3 105.4(6) . . ?
C6 N2 Cu3 136.5(6) . 2_557 ?
N3 N2 Cu3 117.5(5) . 2_557 ?
C7 N3 N2 104.7(7) . . ?
C7 N3 Cu1 140.2(6) . . ?
N2 N3 Cu1 115.1(5) . . ?
C6 N4 C7 103.8(7) . . ?
C11 N5 C10 114.8(10) . . ?
C15 N6 C14 113.7(8) . . ?
C15 N6 Cu2 123.5(7) . 3_454 ?
C14 N6 Cu2 122.5(6) . 3_454 ?
C18 N7 C19 101.9(7) . . ?
C18 N8 N9 104.9(7) . . ?
C18 N8 Cu3 139.6(6) . . ?
N9 N8 Cu3 115.1(5) . . ?
C19 N9 N8 104.0(7) . . ?
C19 N9 Cu1 140.8(6) . . ?
N8 N9 Cu1 115.2(5) . . ?
C22 N10 C23 114.4(10) . . ?
C26 N11 C27 115.4(11) . . ?
C30 N12 C31 102.8(7) . . ?
C30 N13 N14 104.9(7) . . ?
C30 N13 Cu1 137.1(6) . . ?
N14 N13 Cu1 117.9(5) . . ?
C31 N14 N13 105.2(6) . . ?
C31 N14 Cu4 138.4(6) . . ?
N13 N14 Cu4 116.4(5) . . ?
C35 N15 C34 115.7(8) . . ?
C35 N15 Cu2 120.3(6) . . ?
C34 N15 Cu2 123.8(6) . . ?
N16 C37 C37 0.0(9) 2_558 2_558 ?
N16 C37 Cu2 177.6(10) 2_558 . ?
C37 C37 Cu2 177.6(10) 2_558 . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.742
_refine_diff_density_min         -0.389
_refine_diff_density_rms         0.095
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: '
