# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1049232'
_audit_update_record             
;
2015-02-12 deposited with the CCDC.
2015-05-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2012
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C35.50 H37 Au Cl4 P2 Ru'
_chemical_formula_weight         965.43


loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.8959(4)
_cell_length_b                   26.8401(6)
_cell_length_c                   13.1736(5)
_cell_angle_alpha                90
_cell_angle_beta                 113.398(4)
_cell_angle_gamma                90
_cell_volume                     3860.3(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.661
_exptl_crystal_F_000             1884
_exptl_transmission_factor_min   0.4564
_exptl_transmission_factor_max   0.7778
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.04
_exptl_absorpt_coefficient_mu    4.570
_shelx_estimated_absorpt_T_min   0.6332
_shelx_estimated_absorpt_T_max   0.7778
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_source                   'Enhance (Mo) X-ray Source'
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 16.4547
_diffrn_reflns_number            58881
_diffrn_reflns_av_unetI/netI     0.0801
_diffrn_reflns_av_R_equivalents  0.0890
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         1.847
_diffrn_reflns_theta_max         29.469
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.897
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.897
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.897
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             9623
_reflns_number_gt                5510
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_structure_solution    'Sir97 (Altomare, 1999)'
_computing_structure_refinement  'SHELXL-2012 (Sheldrick, 2012)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0909P)²+4.4285P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9623
_refine_ls_number_parameters     319
_refine_ls_number_restraints     8
_refine_ls_R_factor_all          0.1257
_refine_ls_R_factor_gt           0.0616
_refine_ls_wR_factor_ref         0.1931
_refine_ls_wR_factor_gt          0.1567
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.46517(7) 0.07462(2) 0.65897(6) 0.0558(2) Uani 1 1 d . . . . .
C1 C 0.35979(7) 0.10444(2) 0.49126(6) 0.075(3) Uani 1 1 d R . . . .
C2 C 0.33136(7) 0.13147(2) 0.56793(6) 0.072(3) Uani 1 1 d R . . . .
H2 H 0.3397 0.1660 0.5711 0.087 Uiso 1 1 calc R U . . .
C3 C 0.29052(7) 0.10696(2) 0.63986(6) 0.076(3) Uani 1 1 d R . . . .
H3 H 0.2715 0.1250 0.6912 0.091 Uiso 1 1 calc R U . . .
C4 C 0.27811(7) 0.05542(2) 0.63511(6) 0.078(3) Uani 1 1 d R . . . .
C5 C 0.30654(7) 0.02839(2) 0.55844(6) 0.077(4) Uani 1 1 d R . . . .
H5 H 0.2982 -0.0061 0.5553 0.092 Uiso 1 1 calc R U . . .
C6 C 0.34737(7) 0.05290(2) 0.48652(6) 0.077(3) Uani 1 1 d R . . . .
H6 H 0.3664 0.0348 0.4352 0.092 Uiso 1 1 calc R U . . .
C7 C 0.4141(13) 0.1288(5) 0.4154(11) 0.115(5) Uani 1 1 d . . . . .
H7A H 0.3530 0.1492 0.3616 0.172 Uiso 1 1 calc R U . . .
H7B H 0.4402 0.1033 0.3783 0.172 Uiso 1 1 calc R U . . .
H7C H 0.4830 0.1490 0.4588 0.172 Uiso 1 1 calc R U . . .
C8 C 0.2298(13) 0.0250(7) 0.7058(14) 0.123(6) Uani 1 1 d . . . . .
H8 H 0.2753 -0.0064 0.7232 0.147 Uiso 1 1 calc R U . . .
C9 C 0.249(2) 0.0496(8) 0.8123(18) 0.183(9) Uani 1 1 d . . . . .
H9A H 0.3289 0.0642 0.8433 0.275 Uiso 1 1 calc R U . . .
H9B H 0.2409 0.0254 0.8628 0.275 Uiso 1 1 calc R U . . .
H9C H 0.1881 0.0752 0.7997 0.275 Uiso 1 1 calc R U . . .
C10 C 0.0983(18) 0.0127(14) 0.648(2) 0.32(2) Uani 1 1 d . . . . .
H10A H 0.0772 -0.0132 0.6875 0.482 Uiso 1 1 calc R U . . .
H10B H 0.0826 0.0014 0.5743 0.482 Uiso 1 1 calc R U . . .
H10C H 0.0499 0.0418 0.6441 0.482 Uiso 1 1 calc R U . . .
Cl1 Cl 0.5441(3) 0.00971(9) 0.7940(3) 0.0773(8) Uani 1 1 d . . . . .
Cl2 Cl 0.6439(2) 0.06450(9) 0.6169(2) 0.0701(7) Uani 1 1 d . . . . .
P1 P 0.58462(17) 0.12735(7) 0.80450(16) 0.0474(5) Uani 1 1 d . . . . .
C11 C 0.52303(17) 0.13530(7) 0.90907(16) 0.055(2) Uani 1 1 d R . . . .
C12 C 0.43290(17) 0.17095(7) 0.89345(16) 0.067(3) Uani 1 1 d R . . . .
H12 H 0.4075 0.1914 0.8315 0.080 Uiso 1 1 calc R U . . .
C13 C 0.38080(17) 0.17596(7) 0.97050(16) 0.095(4) Uani 1 1 d R . . . .
H13 H 0.3205 0.1998 0.9601 0.114 Uiso 1 1 calc R U . . .
C14 C 0.41883(17) 0.14533(7) 1.06317(16) 0.117(5) Uani 1 1 d R . . . .
H14 H 0.3840 0.1487 1.1147 0.141 Uiso 1 1 calc R U . . .
C15 C 0.50896(17) 0.10968(7) 1.07878(16) 0.104(4) Uani 1 1 d R . . . .
H15 H 0.5344 0.0892 1.1408 0.125 Uiso 1 1 calc R U . . .
C16 C 0.56106(17) 0.10467(7) 1.00173(16) 0.085(3) Uani 1 1 d R . . . .
H16 H 0.6214 0.0808 1.0122 0.102 Uiso 1 1 calc R U . . .
C17 C 0.60875(17) 0.19011(7) 0.76049(16) 0.052(2) Uani 1 1 d R . . . .
C18 C 0.63474(17) 0.19240(7) 0.66662(16) 0.064(3) Uani 1 1 d R . . . .
H18 H 0.6342 0.1635 0.6276 0.077 Uiso 1 1 calc R U . . .
C19 C 0.66160(17) 0.23792(7) 0.63115(16) 0.072(3) Uani 1 1 d R . . . .
H19 H 0.6790 0.2395 0.5683 0.086 Uiso 1 1 calc R U . . .
C20 C 0.66246(17) 0.28115(7) 0.68953(16) 0.077(3) Uani 1 1 d R . . . .
H20 H 0.6804 0.3116 0.6658 0.093 Uiso 1 1 calc R U . . .
C21 C 0.63647(17) 0.27887(7) 0.78339(16) 0.073(3) Uani 1 1 d R . . . .
H21 H 0.6370 0.3078 0.8225 0.087 Uiso 1 1 calc R U . . .
C22 C 0.60961(17) 0.23334(7) 0.81887(16) 0.059(2) Uani 1 1 d R . . . .
H22 H 0.5922 0.2318 0.8817 0.070 Uiso 1 1 calc R U . . .
C23 C 0.7367(8) 0.1014(3) 0.8757(7) 0.053(2) Uani 1 1 d . . . . .
H23A H 0.7595 0.0854 0.8206 0.064 Uiso 1 1 calc R U . . .
H23B H 0.7310 0.0754 0.9246 0.064 Uiso 1 1 calc R U . . .
P2 P 0.86363(18) 0.14317(7) 0.95816(17) 0.0501(6) Uani 1 1 d . . . . .
C24 C 0.98675(18) 0.10230(7) 1.04458(17) 0.063(3) Uani 1 1 d R . . . .
C25 C 1.07474(18) 0.08366(7) 1.01001(17) 0.110(5) Uani 1 1 d R . . . .
H25 H 1.0730 0.0925 0.9411 0.133 Uiso 1 1 calc R U . . .
C26 C 1.16540(18) 0.05185(7) 1.07843(17) 0.127(6) Uani 1 1 d R . . . .
H26 H 1.2243 0.0394 1.0553 0.152 Uiso 1 1 calc R U . . .
C27 C 1.16807(18) 0.03870(7) 1.18142(17) 0.094(4) Uani 1 1 d R . . . .
H27 H 1.2287 0.0174 1.2272 0.113 Uiso 1 1 calc R U . . .
C28 C 1.08008(18) 0.05734(7) 1.21599(17) 0.121(6) Uani 1 1 d R . . . .
H28 H 1.0819 0.0485 1.2849 0.145 Uiso 1 1 calc R U . . .
C29 C 0.98942(18) 0.08915(7) 1.14757(17) 0.107(5) Uani 1 1 d R . . . .
H29 H 0.9305 0.1016 1.1707 0.128 Uiso 1 1 calc R U . . .
C30 C 0.91717(18) 0.17264(7) 0.86331(17) 0.059(2) Uani 1 1 d R . . . .
C31 C 0.94615(18) 0.22304(7) 0.87737(17) 0.077(3) Uani 1 1 d R . . . .
H31 H 0.9368 0.2407 0.9343 0.092 Uiso 1 1 calc R U . . .
C32 C 0.98914(18) 0.24708(7) 0.80639(17) 0.116(5) Uani 1 1 d R . . . .
H32 H 1.0085 0.2808 0.8158 0.139 Uiso 1 1 calc R U . . .
C33 C 1.00314(18) 0.22072(7) 0.72132(17) 0.136(7) Uani 1 1 d R . . . .
H33 H 1.0319 0.2368 0.6738 0.163 Uiso 1 1 calc R U . . .
C34 C 0.97416(18) 0.17032(7) 0.70725(17) 0.115(5) Uani 1 1 d R . . . .
H34 H 0.9835 0.1527 0.6503 0.137 Uiso 1 1 calc R U . . .
C35 C 0.93117(18) 0.14628(7) 0.77824(17) 0.090(4) Uani 1 1 d R . . . .
H35 H 0.9118 0.1126 0.7688 0.109 Uiso 1 1 calc R U . . .
Au1 Au 0.81137(3) 0.19720(2) 1.06025(3) 0.05388(15) Uani 1 1 d . . . . .
Cl3 Cl 0.7510(3) 0.25261(10) 1.1593(3) 0.0801(8) Uani 1 1 d . . . . .
C36 C 0.8312(17) 0.1566(11) 0.368(2) 0.146(12) Uani 0.5 1 d D U P . .
H36A H 0.7988 0.1522 0.2884 0.175 Uiso 0.5 1 calc R U P . .
H36B H 0.8307 0.1921 0.3820 0.175 Uiso 0.5 1 calc R U P . .
Cl4 Cl 0.7340(7) 0.1286(3) 0.4155(7) 0.112(2) Uani 0.5 1 d D . P . .
Cl5 Cl 0.9784(8) 0.1373(4) 0.4205(6) 0.130(3) Uani 0.5 1 d D . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C3 2.1720 . ?
Ru1 C4 2.1819 . ?
Ru1 C2 2.1872 . ?
Ru1 C5 2.2068 . ?
Ru1 C1 2.2121 . ?
Ru1 C6 2.2218 . ?
Ru1 P1 2.3525(19) . ?
Ru1 Cl1 2.399(3) . ?
Ru1 Cl2 2.417(3) . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C1 C7 1.535(16) . ?
C2 C3 1.3900 . ?
C3 C4 1.3900 . ?
C4 C5 1.3900 . ?
C4 C8 1.512(18) . ?
C5 C6 1.3900 . ?
C8 C9 1.49(2) . ?
C8 C10 1.48(2) . ?
P1 C11 1.8114 . ?
P1 C23 1.813(8) . ?
P1 C17 1.8406 . ?
C11 C12 1.3900 . ?
C11 C16 1.3900 . ?
C12 C13 1.3900 . ?
C13 C14 1.3900 . ?
C14 C15 1.3900 . ?
C15 C16 1.3900 . ?
C17 C18 1.3900 . ?
C17 C22 1.3901 . ?
C18 C19 1.3900 . ?
C19 C20 1.3900 . ?
C20 C21 1.3900 . ?
C21 C22 1.3900 . ?
C23 P2 1.848(9) . ?
P2 C30 1.7958 . ?
P2 C24 1.8220 . ?
P2 Au1 2.228(2) . ?
C24 C25 1.3899 . ?
C24 C29 1.3900 . ?
C25 C26 1.3900 . ?
C26 C27 1.3900 . ?
C27 C28 1.3900 . ?
C28 C29 1.3900 . ?
C30 C31 1.3900 . ?
C30 C35 1.3901 . ?
C31 C32 1.3900 . ?
C32 C33 1.3901 . ?
C33 C34 1.3900 . ?
C34 C35 1.3900 . ?
Au1 Cl3 2.275(3) . ?
C36 Cl5 1.688(17) . ?
C36 Cl4 1.694(16) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C3 Ru1 C4 37.2 . . ?
C3 Ru1 C2 37.2 . . ?
C4 Ru1 C2 66.9 . . ?
C3 Ru1 C5 66.7 . . ?
C4 Ru1 C5 36.9 . . ?
C2 Ru1 C5 78.5 . . ?
C3 Ru1 C1 66.6 . . ?
C4 Ru1 C1 78.5 . . ?
C2 Ru1 C1 36.8 . . ?
C5 Ru1 C1 66.0 . . ?
C3 Ru1 C6 78.5 . . ?
C4 Ru1 C6 66.3 . . ?
C2 Ru1 C6 66.2 . . ?
C5 Ru1 C6 36.6 . . ?
C1 Ru1 C6 36.5 . . ?
C3 Ru1 P1 95.42(5) . . ?
C4 Ru1 P1 120.72(5) . . ?
C2 Ru1 P1 95.72(5) . . ?
C5 Ru1 P1 157.40(5) . . ?
C1 Ru1 P1 121.04(5) . . ?
C6 Ru1 P1 157.34(5) . . ?
C3 Ru1 Cl1 116.79(8) . . ?
C4 Ru1 Cl1 90.66(7) . . ?
C2 Ru1 Cl1 153.96(8) . . ?
C5 Ru1 Cl1 91.50(7) . . ?
C1 Ru1 Cl1 154.57(7) . . ?
C6 Ru1 Cl1 118.03(7) . . ?
P1 Ru1 Cl1 84.30(8) . . ?
C3 Ru1 Cl2 155.06(7) . . ?
C4 Ru1 Cl2 151.70(6) . . ?
C2 Ru1 Cl2 117.89(7) . . ?
C5 Ru1 Cl2 114.83(6) . . ?
C1 Ru1 Cl2 90.74(7) . . ?
C6 Ru1 Cl2 89.49(6) . . ?
P1 Ru1 Cl2 87.29(8) . . ?
Cl1 Ru1 Cl2 88.15(10) . . ?
C2 C1 C6 120.0 . . ?
C2 C1 C7 122.5(5) . . ?
C6 C1 C7 117.3(5) . . ?
C2 C1 Ru1 70.6 . . ?
C6 C1 Ru1 72.1 . . ?
C7 C1 Ru1 125.9(5) . . ?
C1 C2 C3 120.0 . . ?
C1 C2 Ru1 72.6 . . ?
C3 C2 Ru1 70.8 . . ?
C4 C3 C2 120.0 . . ?
C4 C3 Ru1 71.8 . . ?
C2 C3 Ru1 72.0 . . ?
C3 C4 C5 120.0 . . ?
C3 C4 C8 124.7(7) . . ?
C5 C4 C8 115.3(7) . . ?
C3 C4 Ru1 71.0 . . ?
C5 C4 Ru1 72.5 . . ?
C8 C4 Ru1 130.8(6) . . ?
C4 C5 C6 120.0 . . ?
C4 C5 Ru1 70.6 . . ?
C6 C5 Ru1 72.3 . . ?
C5 C6 C1 120.0 . . ?
C5 C6 Ru1 71.1 . . ?
C1 C6 Ru1 71.4 . . ?
C9 C8 C10 108.6(18) . . ?
C9 C8 C4 113.0(14) . . ?
C10 C8 C4 112.7(17) . . ?
C11 P1 C23 105.9(3) . . ?
C11 P1 C17 107.0 . . ?
C23 P1 C17 105.4(3) . . ?
C11 P1 Ru1 113.25(5) . . ?
C23 P1 Ru1 110.3(3) . . ?
C17 P1 Ru1 114.40(5) . . ?
C12 C11 C16 120.0 . . ?
C12 C11 P1 119.3 . . ?
C16 C11 P1 120.6 . . ?
C11 C12 C13 120.0 . . ?
C12 C13 C14 120.0 . . ?
C15 C14 C13 120.0 . . ?
C14 C15 C16 120.0 . . ?
C15 C16 C11 120.0 . . ?
C18 C17 C22 120.0 . . ?
C18 C17 P1 116.0 . . ?
C22 C17 P1 123.9 . . ?
C19 C18 C17 120.0 . . ?
C18 C19 C20 120.0 . . ?
C19 C20 C21 120.0 . . ?
C22 C21 C20 120.0 . . ?
C21 C22 C17 120.0 . . ?
P1 C23 P2 119.1(5) . . ?
C30 P2 C24 106.3 . . ?
C30 P2 C23 106.9(3) . . ?
C24 P2 C23 105.6(3) . . ?
C30 P2 Au1 113.23(6) . . ?
C24 P2 Au1 111.25(5) . . ?
C23 P2 Au1 113.0(3) . . ?
C25 C24 C29 120.0 . . ?
C25 C24 P2 122.4 . . ?
C29 C24 P2 117.6 . . ?
C24 C25 C26 120.0 . . ?
C27 C26 C25 120.0 . . ?
C26 C27 C28 120.0 . . ?
C27 C28 C29 120.0 . . ?
C28 C29 C24 120.0 . . ?
C31 C30 C35 120.0 . . ?
C31 C30 P2 118.3 . . ?
C35 C30 P2 121.7 . . ?
C32 C31 C30 120.0 . . ?
C31 C32 C33 120.0 . . ?
C34 C33 C32 120.0 . . ?
C33 C34 C35 120.0 . . ?
C34 C35 C30 120.0 . . ?
P2 Au1 Cl3 177.88(10) . . ?
Cl5 C36 Cl4 117.5(12) . . ?

_refine_diff_density_max         1.821
_refine_diff_density_min         -0.668
_refine_diff_density_rms         0.172

_shelxl_version_number           2012-9


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: dichlorometane'
