# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1406510'
_audit_update_record             
;
2015-06-12 deposited with the CCDC.
2015-07-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'K3 La O9 Te2'
_chemical_formula_weight         655.41

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Hexagonal
_symmetry_space_group_name_H-M   P63/mmc

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'-y, -x, -z+1/2'
'-x+y, y, -z+1/2'
'x, x-y, -z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'y, x, z-1/2'
'x-y, -y, z-1/2'
'-x, -x+y, z-1/2'

_cell_length_a                   6.0589(9)
_cell_length_b                   6.0589(9)
_cell_length_c                   15.024(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_volume                     477.64(14)
_cell_formula_units_Z            2
_cell_measurement_temperature    153.1500
_cell_measurement_reflns_used    1918
_cell_measurement_theta_min      2.7115
_cell_measurement_theta_max      31.4147

_exptl_crystal_description       Chip
_exptl_crystal_colour            Colorless
_exptl_crystal_size_max          0.1700
_exptl_crystal_size_mid          0.1450
_exptl_crystal_size_min          0.0900
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    4.557
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             580
_exptl_absorpt_coefficient_mu    11.792
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6731
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      153.1500
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku AFC10 diffractometer'
_diffrn_measurement_method       dtprofit.ref
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            4437
_diffrn_reflns_av_R_equivalents  0.0377
_diffrn_reflns_av_sigmaI/netI    0.0178
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         2.71
_diffrn_reflns_theta_max         31.41
_reflns_number_total             344
_reflns_number_gt                340
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0100P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   none
_refine_ls_hydrogen_treatment    none
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0246(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         344
_refine_ls_number_parameters     22
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0233
_refine_ls_R_factor_gt           0.0227
_refine_ls_wR_factor_ref         0.0465
_refine_ls_wR_factor_gt          0.0463
_refine_ls_goodness_of_fit_ref   2.135
_refine_ls_restrained_S_all      2.135
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
K1 K 0.0000 0.0000 0.7500 0.0086(4) Uani 1 12 d S . .
K2 K 0.3333 0.6667 0.61656(11) 0.0122(3) Uani 1 6 d S . .
La1 La 0.0000 0.0000 0.5000 0.00297(16) Uani 1 12 d S . .
Te1 Te -0.3333 0.3333 0.65593(3) 0.00287(15) Uani 1 6 d S . .
O1 O -0.0592(7) 0.4704(4) 0.7500 0.0049(7) Uani 1 4 d S . .
O2 O -0.6412(5) 0.1794(2) 0.5945(2) 0.0088(6) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
K1 O2 3.000(3) 16_657 ?
K1 O2 3.000(3) 3_445 ?
K1 O2 3.000(3) 17_567 ?
K1 O2 3.000(3) 2_565 ?
K1 O2 3.000(3) 18_447 ?
K1 O2 3.000(3) 1_655 ?
K1 O1 3.0505(18) 2 ?
K1 O1 3.045(5) 3 ?
K1 O1 3.045(5) . ?
K1 O1 3.045(5) 2_665 ?
K1 O1 3.045(5) 1_545 ?
K1 O1 3.045(5) 3_455 ?
K2 O1 2.875(3) 3_565 ?
K2 O1 2.875(3) . ?
K2 O1 2.875(3) 2_665 ?
K2 O2 3.051(4) 3_455 ?
K2 O2 3.051(4) 1_665 ?
K2 O2 3.051(4) 2_565 ?
K2 O2 3.051(4) 2_675 ?
K2 O2 3.051(4) 1_655 ?
K2 O2 3.0505(18) 3 ?
K2 Te1 3.5478(6) 1_665 ?
K2 Te1 3.5478(6) . ?
K2 Te1 3.5478(6) 1_655 ?
La1 O2 2.358(3) 13_456 ?
La1 O2 2.358(3) 1_655 ?
La1 O2 2.358(3) 14_546 ?
La1 O2 2.358(3) 2_565 ?
La1 O2 2.358(3) 15_666 ?
La1 O2 2.358(3) 3_445 ?
La1 K1 3.7560(8) 13_556 ?
La1 K2 3.9119(9) 1_545 ?
La1 K2 3.9119(9) 13_566 ?
La1 K2 3.9119(9) 13_556 ?
Te1 O2 1.860(3) 2_565 ?
Te1 O2 1.860(3) . ?
Te1 O2 1.860(3) 3_455 ?
Te1 O1 2.016(3) . ?
Te1 O1 2.016(3) 3_455 ?
Te1 O1 2.016(3) 2_565 ?
Te1 Te1 2.8267(10) 16_557 ?
Te1 K2 3.5478(6) 1_445 ?
Te1 K2 3.5478(6) 1_455 ?
Te1 K1 3.7728(5) 1_565 ?
O1 Te1 2.016(3) 16_557 ?
O1 K2 2.875(3) 16_557 ?
O1 K1 3.045(5) 1_565 ?
O2 La1 2.358(3) 1_455 ?
O2 K1 3.000(3) 1_455 ?
O2 K2 3.0505(18) 1_445 ?
O2 K2 3.0505(18) 1_455 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 K1 O2 143.43(4) 16_657 3_445 ?
O2 K1 O2 65.84(8) 16_657 17_567 ?
O2 K1 O2 143.43(4) 3_445 17_567 ?
O2 K1 O2 143.43(4) 16_657 2_565 ?
O2 K1 O2 65.84(8) 3_445 2_565 ?
O2 K1 O2 102.27(10) 17_567 2_565 ?
O2 K1 O2 65.84(9) 16_657 18_447 ?
O2 K1 O2 102.27(11) 3_445 18_447 ?
O2 K1 O2 65.84(8) 17_567 18_447 ?
O2 K1 O2 143.43(4) 2_565 18_447 ?
O2 K1 O2 102.27(11) 16_657 1_655 ?
O2 K1 O2 65.84(8) 3_445 1_655 ?
O2 K1 O2 143.43(4) 17_567 1_655 ?
O2 K1 O2 65.84(8) 2_565 1_655 ?
O2 K1 O2 143.43(4) 18_447 1_655 ?
O2 K1 O1 120.57(5) 16_657 2 ?
O2 K1 O1 55.07(5) 3_445 2 ?
O2 K1 O1 93.67(5) 17_567 2 ?
O2 K1 O1 93.67(5) 2_565 2 ?
O2 K1 O1 55.07(5) 18_447 2 ?
O2 K1 O1 120.57(5) 1_655 2 ?
O2 K1 O1 55.07(5) 16_657 3 ?
O2 K1 O1 93.67(4) 3_445 3 ?
O2 K1 O1 120.57(5) 17_567 3 ?
O2 K1 O1 120.57(5) 2_565 3 ?
O2 K1 O1 93.67(4) 18_447 3 ?
O2 K1 O1 55.07(5) 1_655 3 ?
O1 K1 O1 120.0 2 3 ?
O2 K1 O1 93.67(5) 16_657 . ?
O2 K1 O1 120.57(5) 3_445 . ?
O2 K1 O1 55.07(5) 17_567 . ?
O2 K1 O1 55.07(5) 2_565 . ?
O2 K1 O1 120.57(5) 18_447 . ?
O2 K1 O1 93.67(5) 1_655 . ?
O1 K1 O1 120.000(1) 2 . ?
O1 K1 O1 120.000(2) 3 . ?
O2 K1 O1 55.07(5) 16_657 2_665 ?
O2 K1 O1 120.57(5) 3_445 2_665 ?
O2 K1 O1 93.67(5) 17_567 2_665 ?
O2 K1 O1 93.67(5) 2_565 2_665 ?
O2 K1 O1 120.57(5) 18_447 2_665 ?
O2 K1 O1 55.07(5) 1_655 2_665 ?
O1 K1 O1 168.28(14) 2 2_665 ?
O1 K1 O1 48.28(14) 3 2_665 ?
O1 K1 O1 71.72(14) . 2_665 ?
O2 K1 O1 93.67(4) 16_657 1_545 ?
O2 K1 O1 55.07(5) 3_445 1_545 ?
O2 K1 O1 120.57(5) 17_567 1_545 ?
O2 K1 O1 120.57(5) 2_565 1_545 ?
O2 K1 O1 55.07(5) 18_447 1_545 ?
O2 K1 O1 93.67(4) 1_655 1_545 ?
O1 K1 O1 48.28(14) 2 1_545 ?
O1 K1 O1 71.72(14) 3 1_545 ?
O1 K1 O1 168.28(14) . 1_545 ?
O1 K1 O1 120.0 2_665 1_545 ?
O2 K1 O1 120.57(5) 16_657 3_455 ?
O2 K1 O1 93.67(5) 3_445 3_455 ?
O2 K1 O1 55.07(5) 17_567 3_455 ?
O2 K1 O1 55.07(5) 2_565 3_455 ?
O2 K1 O1 93.67(5) 18_447 3_455 ?
O2 K1 O1 120.57(5) 1_655 3_455 ?
O1 K1 O1 71.72(14) 2 3_455 ?
O1 K1 O1 168.28(14) 3 3_455 ?
O1 K1 O1 48.28(14) . 3_455 ?
O1 K1 O1 120.000(1) 2_665 3_455 ?
O1 K1 O1 120.000(2) 1_545 3_455 ?
O1 K2 O1 76.72(9) 3_565 . ?
O1 K2 O1 76.72(9) 3_565 2_665 ?
O1 K2 O1 76.72(9) . 2_665 ?
O1 K2 O2 96.15(6) 3_565 3_455 ?
O1 K2 O2 56.20(7) . 3_455 ?
O1 K2 O2 132.56(8) 2_665 3_455 ?
O1 K2 O2 56.20(7) 3_565 1_665 ?
O1 K2 O2 96.15(6) . 1_665 ?
O1 K2 O2 132.56(8) 2_665 1_665 ?
O2 K2 O2 64.62(10) 3_455 1_665 ?
O1 K2 O2 132.56(8) 3_565 2_565 ?
O1 K2 O2 56.20(7) . 2_565 ?
O1 K2 O2 96.15(6) 2_665 2_565 ?
O2 K2 O2 54.59(10) 3_455 2_565 ?
O2 K2 O2 118.84(2) 1_665 2_565 ?
O1 K2 O2 56.20(7) 3_565 2_675 ?
O1 K2 O2 132.56(8) . 2_675 ?
O1 K2 O2 96.15(6) 2_665 2_675 ?
O2 K2 O2 118.84(2) 3_455 2_675 ?
O2 K2 O2 54.59(10) 1_665 2_675 ?
O2 K2 O2 166.55(12) 2_565 2_675 ?
O1 K2 O2 132.56(8) 3_565 1_655 ?
O1 K2 O2 96.15(6) . 1_655 ?
O1 K2 O2 56.20(7) 2_665 1_655 ?
O2 K2 O2 118.84(2) 3_455 1_655 ?
O2 K2 O2 166.55(13) 1_665 1_655 ?
O2 K2 O2 64.62(10) 2_565 1_655 ?
O2 K2 O2 118.84(2) 2_675 1_655 ?
O1 K2 O2 96.15(6) 3_565 3 ?
O1 K2 O2 132.56(8) . 3 ?
O1 K2 O2 56.20(7) 2_665 3 ?
O2 K2 O2 166.55(12) 3_455 3 ?
O2 K2 O2 118.84(2) 1_665 3 ?
O2 K2 O2 118.84(2) 2_565 3 ?
O2 K2 O2 64.62(10) 2_675 3 ?
O2 K2 O2 54.59(10) 1_655 3 ?
O1 K2 Te1 34.63(5) 3_565 1_665 ?
O1 K2 Te1 103.71(4) . 1_665 ?
O1 K2 Te1 103.71(4) 2_665 1_665 ?
O2 K2 Te1 93.52(5) 3_455 1_665 ?
O2 K2 Te1 31.62(5) 1_665 1_665 ?
O2 K2 Te1 147.62(5) 2_565 1_665 ?
O2 K2 Te1 31.62(5) 2_675 1_665 ?
O2 K2 Te1 147.62(5) 1_655 1_665 ?
O2 K2 Te1 93.52(5) 3 1_665 ?
O1 K2 Te1 103.71(4) 3_565 . ?
O1 K2 Te1 34.63(5) . . ?
O1 K2 Te1 103.71(4) 2_665 . ?
O2 K2 Te1 31.62(5) 3_455 . ?
O2 K2 Te1 93.52(5) 1_665 . ?
O2 K2 Te1 31.62(5) 2_565 . ?
O2 K2 Te1 147.62(5) 2_675 . ?
O2 K2 Te1 93.52(5) 1_655 . ?
O2 K2 Te1 147.62(5) 3 . ?
Te1 K2 Te1 117.278(16) 1_665 . ?
O1 K2 Te1 103.71(4) 3_565 1_655 ?
O1 K2 Te1 103.71(4) . 1_655 ?
O1 K2 Te1 34.63(5) 2_665 1_655 ?
O2 K2 Te1 147.62(5) 3_455 1_655 ?
O2 K2 Te1 147.62(5) 1_665 1_655 ?
O2 K2 Te1 93.52(5) 2_565 1_655 ?
O2 K2 Te1 93.52(5) 2_675 1_655 ?
O2 K2 Te1 31.62(5) 1_655 1_655 ?
O2 K2 Te1 31.62(5) 3 1_655 ?
Te1 K2 Te1 117.278(16) 1_665 1_655 ?
Te1 K2 Te1 117.278(16) . 1_655 ?
O2 La1 O2 180.0 13_456 1_655 ?
O2 La1 O2 87.49(10) 13_456 14_546 ?
O2 La1 O2 92.51(10) 1_655 14_546 ?
O2 La1 O2 92.51(10) 13_456 2_565 ?
O2 La1 O2 87.49(10) 1_655 2_565 ?
O2 La1 O2 180.00(12) 14_546 2_565 ?
O2 La1 O2 87.49(10) 13_456 15_666 ?
O2 La1 O2 92.51(10) 1_655 15_666 ?
O2 La1 O2 87.49(10) 14_546 15_666 ?
O2 La1 O2 92.51(10) 2_565 15_666 ?
O2 La1 O2 92.51(10) 13_456 3_445 ?
O2 La1 O2 87.49(10) 1_655 3_445 ?
O2 La1 O2 92.51(10) 14_546 3_445 ?
O2 La1 O2 87.49(10) 2_565 3_445 ?
O2 La1 O2 180.00(10) 15_666 3_445 ?
O2 La1 K1 52.98(7) 13_456 13_556 ?
O2 La1 K1 127.02(7) 1_655 13_556 ?
O2 La1 K1 52.98(7) 14_546 13_556 ?
O2 La1 K1 127.02(7) 2_565 13_556 ?
O2 La1 K1 52.98(7) 15_666 13_556 ?
O2 La1 K1 127.02(7) 3_445 13_556 ?
O2 La1 K1 127.02(7) 13_456 . ?
O2 La1 K1 52.98(7) 1_655 . ?
O2 La1 K1 127.02(7) 14_546 . ?
O2 La1 K1 52.98(7) 2_565 . ?
O2 La1 K1 127.02(7) 15_666 . ?
O2 La1 K1 52.98(7) 3_445 . ?
K1 La1 K1 180.0 13_556 . ?
O2 La1 K2 128.793(14) 13_456 1_545 ?
O2 La1 K2 51.207(14) 1_655 1_545 ?
O2 La1 K2 63.61(7) 14_546 1_545 ?
O2 La1 K2 116.39(7) 2_565 1_545 ?
O2 La1 K2 128.793(14) 15_666 1_545 ?
O2 La1 K2 51.207(14) 3_445 1_545 ?
K1 La1 K2 116.59(2) 13_556 1_545 ?
K1 La1 K2 63.41(2) . 1_545 ?
O2 La1 K2 51.207(14) 13_456 13_566 ?
O2 La1 K2 128.793(14) 1_655 13_566 ?
O2 La1 K2 116.39(7) 14_546 13_566 ?
O2 La1 K2 63.61(7) 2_565 13_566 ?
O2 La1 K2 51.207(14) 15_666 13_566 ?
O2 La1 K2 128.793(14) 3_445 13_566 ?
K1 La1 K2 63.41(2) 13_556 13_566 ?
K1 La1 K2 116.59(2) . 13_566 ?
K2 La1 K2 180.00(4) 1_545 13_566 ?
O2 La1 K2 128.793(14) 13_456 . ?
O2 La1 K2 51.207(14) 1_655 . ?
O2 La1 K2 128.793(14) 14_546 . ?
O2 La1 K2 51.207(14) 2_565 . ?
O2 La1 K2 63.61(8) 15_666 . ?
O2 La1 K2 116.39(8) 3_445 . ?
K1 La1 K2 116.59(2) 13_556 . ?
K1 La1 K2 63.41(2) . . ?
K2 La1 K2 101.50(3) 1_545 . ?
K2 La1 K2 78.50(3) 13_566 . ?
O2 La1 K2 51.207(14) 13_456 13_556 ?
O2 La1 K2 128.793(14) 1_655 13_556 ?
O2 La1 K2 51.207(14) 14_546 13_556 ?
O2 La1 K2 128.793(14) 2_565 13_556 ?
O2 La1 K2 116.39(8) 15_666 13_556 ?
O2 La1 K2 63.61(8) 3_445 13_556 ?
K1 La1 K2 63.41(2) 13_556 13_556 ?
K1 La1 K2 116.59(2) . 13_556 ?
K2 La1 K2 78.50(3) 1_545 13_556 ?
K2 La1 K2 101.50(3) 13_566 13_556 ?
K2 La1 K2 180.0 . 13_556 ?
O2 Te1 O2 97.52(12) 2_565 . ?
O2 Te1 O2 97.52(12) 2_565 3_455 ?
O2 Te1 O2 97.52(12) . 3_455 ?
O2 Te1 O1 92.18(9) 2_565 . ?
O2 Te1 O1 165.24(12) . . ?
O2 Te1 O1 92.18(9) 3_455 . ?
O2 Te1 O1 92.18(9) 2_565 3_455 ?
O2 Te1 O1 92.18(9) . 3_455 ?
O2 Te1 O1 165.24(12) 3_455 3_455 ?
O1 Te1 O1 76.29(12) . 3_455 ?
O2 Te1 O1 165.24(11) 2_565 2_565 ?
O2 Te1 O1 92.18(9) . 2_565 ?
O2 Te1 O1 92.18(9) 3_455 2_565 ?
O1 Te1 O1 76.29(12) . 2_565 ?
O1 Te1 O1 76.29(12) 3_455 2_565 ?
O2 Te1 Te1 119.74(9) 2_565 16_557 ?
O2 Te1 Te1 119.74(9) . 16_557 ?
O2 Te1 Te1 119.74(9) 3_455 16_557 ?
O1 Te1 Te1 45.50(8) . 16_557 ?
O1 Te1 Te1 45.50(8) 3_455 16_557 ?
O1 Te1 Te1 45.50(8) 2_565 16_557 ?
O2 Te1 K2 59.284(17) 2_565 1_445 ?
O2 Te1 K2 59.284(17) . 1_445 ?
O2 Te1 K2 140.67(10) 3_455 1_445 ?
O1 Te1 K2 117.94(3) . 1_445 ?
O1 Te1 K2 54.10(8) 3_455 1_445 ?
O1 Te1 K2 117.94(3) 2_565 1_445 ?
Te1 Te1 K2 99.60(3) 16_557 1_445 ?
O2 Te1 K2 59.284(17) 2_565 . ?
O2 Te1 K2 140.67(10) . . ?
O2 Te1 K2 59.284(17) 3_455 . ?
O1 Te1 K2 54.10(8) . . ?
O1 Te1 K2 117.94(3) 3_455 . ?
O1 Te1 K2 117.94(3) 2_565 . ?
Te1 Te1 K2 99.60(3) 16_557 . ?
K2 Te1 K2 117.278(16) 1_445 . ?
O2 Te1 K2 140.67(10) 2_565 1_455 ?
O2 Te1 K2 59.284(17) . 1_455 ?
O2 Te1 K2 59.284(17) 3_455 1_455 ?
O1 Te1 K2 117.94(3) . 1_455 ?
O1 Te1 K2 117.94(3) 3_455 1_455 ?
O1 Te1 K2 54.10(8) 2_565 1_455 ?
Te1 Te1 K2 99.60(3) 16_557 1_455 ?
K2 Te1 K2 117.278(16) 1_445 1_455 ?
K2 Te1 K2 117.278(16) . 1_455 ?
O2 Te1 K1 51.74(9) 2_565 . ?
O2 Te1 K1 126.04(5) . . ?
O2 Te1 K1 126.04(5) 3_455 . ?
O1 Te1 K1 53.614(7) . . ?
O1 Te1 K1 53.614(7) 3_455 . ?
O1 Te1 K1 113.50(8) 2_565 . ?
Te1 Te1 K1 68.000(7) 16_557 . ?
K2 Te1 K1 66.756(14) 1_445 . ?
K2 Te1 K1 66.756(14) . . ?
K2 Te1 K1 167.60(3) 1_455 . ?
O2 Te1 K1 126.04(1) 2_565 1_565 ?
O2 Te1 K1 126.04(1) . 1_565 ?
O2 Te1 K1 51.74(9) 3_455 1_565 ?
O1 Te1 K1 53.614(6) . 1_565 ?
O1 Te1 K1 113.50(8) 3_455 1_565 ?
O1 Te1 K1 53.614(7) 2_565 1_565 ?
Te1 Te1 K1 68.000(7) 16_557 1_565 ?
K2 Te1 K1 167.60(3) 1_445 1_565 ?
K2 Te1 K1 66.756(14) . 1_565 ?
K2 Te1 K1 66.756(14) 1_455 1_565 ?
K1 Te1 K1 106.828(8) . 1_565 ?
Te1 O1 Te1 89.00(15) . 16_557 ?
Te1 O1 K2 179.72(12) . 16_557 ?
Te1 O1 K2 91.28(4) 16_557 16_557 ?
Te1 O1 K2 91.28(4) . . ?
Te1 O1 K2 179.72(15) 16_557 . ?
K2 O1 K2 88.45(11) 16_557 . ?
Te1 O1 K1 94.18(4) . . ?
Te1 O1 K1 94.18(4) 16_557 . ?
K2 O1 K1 85.80(5) 16_557 . ?
K2 O1 K1 85.80(5) . . ?
Te1 O1 K1 94.18(4) . 1_565 ?
Te1 O1 K1 94.18(4) 16_557 1_565 ?
K2 O1 K1 85.80(5) 16_557 1_565 ?
K2 O1 K1 85.80(5) . 1_565 ?
K1 O1 K1 168.28(14) . 1_565 ?
Te1 O2 La1 172.71(16) . 1_455 ?
Te1 O2 K1 99.13(12) . 1_455 ?
La1 O2 K1 88.15(8) 1_455 1_455 ?
Te1 O2 K2 89.10(5) . 1_445 ?
La1 O2 K2 91.74(5) 1_455 1_445 ?
K1 O2 K2 83.57(6) 1_455 1_445 ?
Te1 O2 K2 89.10(5) . 1_455 ?
La1 O2 K2 91.74(5) 1_455 1_455 ?
K1 O2 K2 83.57(6) 1_455 1_455 ?
K2 O2 K2 166.55(12) 1_445 1_455 ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        31.41
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         1.078
_refine_diff_density_min         -0.751
_refine_diff_density_rms         0.165
