# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_az8
_database_code_depnum_ccdc_archive 'CCDC 1409374'
_audit_update_record             
;
2015-06-29 deposited with the CCDC.
2015-09-18 downloaded from the CCDC.
;
_audit_creation_date             2014-12-09
_audit_creation_method           
;
Olex2 1.2
(compiled 2014.11.28 svn.r3107 for OlexSys, GUI svn.r4959)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C23 H17 Cl N2 Pt, 0.5(H2 O)'
_chemical_formula_sum            'C23 H18 Cl N2 O0.50 Pt'
_chemical_formula_weight         560.93
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C20 H20 N2 O2 Pt'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'I 1 2/a 1'
_space_group_name_Hall           '-I 2ya'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'

_cell_length_a                   15.5280(2)
_cell_length_b                   13.72430(10)
_cell_length_c                   17.6847(2)
_cell_angle_alpha                90
_cell_angle_beta                 100.5210(10)
_cell_angle_gamma                90
_cell_volume                     3705.44(7)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    27305
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      31.9450
_cell_measurement_theta_min      2.8770
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    7.731
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.83229
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    2.011
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2152
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.14
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0537
_diffrn_reflns_av_unetI/netI     0.0374
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.957
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            54517
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.957
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         32.353
_diffrn_reflns_theta_min         2.343
_diffrn_ambient_temperature      150(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.2833
_diffrn_detector_type            Ruby
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.957
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   35.00  106.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       17.1016  178.0000 -150.0000 71

#__ type_ start__ end____ width___ exp.time_
  2 omega  -56.00   45.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       17.1016  -57.0000 -180.0000 101

#__ type_ start__ end____ width___ exp.time_
  3 omega  -71.00  105.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       17.1016    0.0000 -180.0000 176

#__ type_ start__ end____ width___ exp.time_
  4 omega  -25.00   23.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.1954  -99.0000   90.0000 48

#__ type_ start__ end____ width___ exp.time_
  5 omega -107.00  -57.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.1954 -178.0000   60.0000 50

#__ type_ start__ end____ width___ exp.time_
  6 omega  -94.00   14.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.1954  -77.0000  -60.0000 108

#__ type_ start__ end____ width___ exp.time_
  7 omega  -15.00   93.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       17.1016   77.0000 -120.0000 108

#__ type_ start__ end____ width___ exp.time_
  8 omega  -57.00   42.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       17.1016  -38.0000    0.0000 99

#__ type_ start__ end____ width___ exp.time_
  9 omega  -25.00   23.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.1954  -99.0000  150.0000 48

#__ type_ start__ end____ width___ exp.time_
 10 omega  -25.00   23.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.1954  -99.0000   30.0000 48

#__ type_ start__ end____ width___ exp.time_
 11 omega -105.00  -53.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.1954  178.0000  -60.0000 52

#__ type_ start__ end____ width___ exp.time_
 12 omega -105.00  -53.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.1954  178.0000 -150.0000 52

#__ type_ start__ end____ width___ exp.time_
 13 omega  -25.00    0.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       17.1016  -99.0000  -60.0000 25
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Ruby, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0391054000
_diffrn_orient_matrix_UB_12      0.0047002000
_diffrn_orient_matrix_UB_13      -0.0150738000
_diffrn_orient_matrix_UB_21      0.0226187000
_diffrn_orient_matrix_UB_22      -0.0286165000
_diffrn_orient_matrix_UB_23      0.0307223000
_diffrn_orient_matrix_UB_31      -0.0108324000
_diffrn_orient_matrix_UB_32      -0.0427850000
_diffrn_orient_matrix_UB_33      -0.0222018000
_diffrn_oxdiff_twin_integration_method simultaneous
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4949
_reflns_number_total             6348
_reflns_special_details          
;
The hydrogen was located on water O1 and refined with DFIX and DANG restraints 
to give it and its symmetry equivalent hydrogen,reasonable bond lengths and 
angles of a water molecule. H1 was given thermal parameter Uiso 1.5 times 
the Ueqiv of the parent O1.

All crystals examined contained in-growths. Crystals were cut up to try and 
get a uniform piece of material.
The best crystal had some twinning. This refinement was performed on the major 
twin as no suitable twin refinement could be found. 
From Olex2, the relationship between the twin matrices and their relevant 
ratios are shown below
_cell_oxdiff_twin_id
_cell_oxdiff_twin_matrix_11
_cell_oxdiff_twin_matrix_12
_cell_oxdiff_twin_matrix_13
_cell_oxdiff_twin_matrix_21
_cell_oxdiff_twin_matrix_22
_cell_oxdiff_twin_matrix_23
_cell_oxdiff_twin_matrix_31
_cell_oxdiff_twin_matrix_32
_cell_oxdiff_twin_matrix_33
1  1.0000  0.0000  0.0000  0.0000  1.0000  0.0000  0.0000  0.0000  1.0000
2  0.9099 -0.4786  0.0182  0.3592  0.6060  0.5922 -0.4197 -0.7532  0.6582
3  0.9794  0.0938 -0.0672 -0.0682  0.9958  0.0198  0.0907 -0.0432  1.0110
_diffrn_oxdiff_twin_id
_diffrn_oxdiff_twin_ratio
_diffrn_oxdiff_twin_reflns_isolated
_diffrn_oxdiff_twin_reflns_overlapped
1 0.6040 22330 925
2 0.1891 6739 543
3 0.1494 5080 636

 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2008)'
_refine_diff_density_max         3.389
_refine_diff_density_min         -1.223
_refine_diff_density_rms         0.435
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     252
_refine_ls_number_reflns         6348
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0410
_refine_ls_R_factor_gt           0.0262
_refine_ls_restrained_S_all      1.039
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0470P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0631
_refine_ls_wR_factor_ref         0.0780
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  H20 of C20, H16 of C16, H18 of C18, H2 of C2, H4 of C4, H10 of C10, H8 of
  C8, H5 of C5, H9 of C9, H23 of C23, H21 of C21, H12 of C12, H24 of C24, H22
  of C22, H3 of C3, H15 of C15, H17 of C17
 At 1.5 times of:
  H1 of C24
2. Restrained distances
 O1-H1
 0.84 with sigma of 0.02
 H1-H1_$1
 1.4 with sigma of 0.04
3.a Ternary CH refined with riding coordinates:
 C12(H12)
3.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C8(H8), C9(H9), C10(H10), C15(H15), C16(H16),
 C17(H17), C18(H18), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 0.38594(6) 0.91802(6) 0.54778(5) 0.02587(18) Uani 1 1 d . . . . .
N1 N 0.3290(2) 0.8602(2) 0.70951(17) 0.0221(6) Uani 1 1 d . . . . .
Pt1 Pt 0.43455(2) 0.82367(2) 0.65560(2) 0.01895(5) Uani 1 1 d . . . . .
C2 C 0.2636(2) 0.9225(3) 0.6855(2) 0.0278(8) Uani 1 1 d . . . . .
H2 H 0.2551 0.9460 0.6341 0.033 Uiso 1 1 calc R . . . .
C3 C 0.2077(3) 0.9540(3) 0.7335(2) 0.0324(9) Uani 1 1 d . . . . .
H3 H 0.1624 0.9993 0.7154 0.039 Uiso 1 1 calc R . . . .
C4 C 0.2185(3) 0.9187(3) 0.8078(3) 0.0336(9) Uani 1 1 d . . . . .
H4 H 0.1802 0.9389 0.8410 0.040 Uiso 1 1 calc R . . . .
O1 O 0.2500 0.7347(4) 0.5000 0.0455(11) Uani 1 2 d DS T P . .
C5 C 0.2849(3) 0.8542(3) 0.8330(2) 0.0295(8) Uani 1 1 d . . . . .
H5 H 0.2931 0.8291 0.8839 0.035 Uiso 1 1 calc R . . . .
C6 C 0.3401(2) 0.8259(2) 0.7833(2) 0.0232(7) Uani 1 1 d . . . . .
C7 C 0.4133(2) 0.7573(3) 0.8046(2) 0.0222(7) Uani 1 1 d . . . . .
N7 N 0.46117(19) 0.7386(2) 0.74873(17) 0.0213(6) Uani 1 1 d . . . . .
C8 C 0.4319(3) 0.7106(3) 0.8756(2) 0.0284(8) Uani 1 1 d . . . . .
H8 H 0.3989 0.7252 0.9144 0.034 Uiso 1 1 calc R . . . .
C9 C 0.4988(3) 0.6429(3) 0.8890(2) 0.0305(8) Uani 1 1 d . . . . .
H9 H 0.5143 0.6126 0.9379 0.037 Uiso 1 1 calc R . . . .
C10 C 0.5425(3) 0.6201(3) 0.8301(2) 0.0304(8) Uani 1 1 d . . . . .
H10 H 0.5870 0.5717 0.8380 0.036 Uiso 1 1 calc R . . . .
C11 C 0.5225(2) 0.6667(2) 0.7596(2) 0.0226(7) Uani 1 1 d . . . . .
C12 C 0.5629(2) 0.6344(3) 0.6925(2) 0.0231(7) Uani 1 1 d . . . . .
H12 H 0.6136 0.5920 0.7147 0.028 Uiso 1 1 calc R . . . .
C13 C 0.6009(2) 0.7161(3) 0.6507(2) 0.0228(7) Uani 1 1 d . . . . .
C14 C 0.5525(2) 0.8003(3) 0.6270(2) 0.0214(7) Uani 1 1 d . . . . .
C15 C 0.5931(2) 0.8720(3) 0.5894(2) 0.0245(7) Uani 1 1 d . . . . .
H15 H 0.5621 0.9302 0.5730 0.029 Uiso 1 1 calc R . . . .
C16 C 0.6777(3) 0.8600(3) 0.5753(2) 0.0287(8) Uani 1 1 d . . . . .
H16 H 0.7035 0.9098 0.5496 0.034 Uiso 1 1 calc R . . . .
C17 C 0.7242(3) 0.7769(3) 0.5983(2) 0.0321(9) Uani 1 1 d . . . . .
H17 H 0.7818 0.7685 0.5883 0.039 Uiso 1 1 calc R . . . .
C18 C 0.6856(3) 0.7049(3) 0.6367(3) 0.0309(8) Uani 1 1 d . . . . .
H18 H 0.7176 0.6474 0.6534 0.037 Uiso 1 1 calc R . . . .
C19 C 0.4974(2) 0.5674(3) 0.6404(2) 0.0230(7) Uani 1 1 d . . . . .
C20 C 0.4551(3) 0.5921(3) 0.5675(2) 0.0289(8) Uani 1 1 d . . . . .
H20 H 0.4660 0.6537 0.5468 0.035 Uiso 1 1 calc R . . . .
C21 C 0.3966(3) 0.5281(3) 0.5239(2) 0.0357(9) Uani 1 1 d . . . . .
H21 H 0.3677 0.5466 0.4739 0.043 Uiso 1 1 calc R . . . .
C22 C 0.3804(3) 0.4383(3) 0.5528(2) 0.0316(8) Uani 1 1 d . . . . .
H22 H 0.3412 0.3943 0.5226 0.038 Uiso 1 1 calc R . . . .
C23 C 0.4210(3) 0.4128(3) 0.6253(3) 0.0335(9) Uani 1 1 d . . . . .
H23 H 0.4089 0.3513 0.6456 0.040 Uiso 1 1 calc R . . . .
C24 C 0.4799(2) 0.4759(3) 0.6700(2) 0.0288(8) Uani 1 1 d . . . . .
H24 H 0.5081 0.4572 0.7201 0.035 Uiso 1 1 calc R . . . .
H1 H 0.2936(12) 0.776(2) 0.509(3) 0.043 Uiso 1 1 d DR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 Pt1 2.3144(9) . ?
N1 Pt1 2.101(3) . ?
N1 C2 1.336(5) . ?
N1 C6 1.368(5) . ?
Pt1 N7 2.000(3) . ?
Pt1 C14 2.012(4) . ?
C2 H2 0.9500 . ?
C2 C3 1.389(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.382(6) . ?
C4 H4 0.9500 . ?
C4 C5 1.371(6) . ?
O1 H1 0.873(18) . ?
C5 H5 0.9500 . ?
C5 C6 1.391(5) . ?
C6 C7 1.471(5) . ?
C7 N7 1.364(4) . ?
C7 C8 1.391(5) . ?
N7 C11 1.361(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.382(6) . ?
C9 H9 0.9500 . ?
C9 C10 1.380(6) . ?
C10 H10 0.9500 . ?
C10 C11 1.385(5) . ?
C11 C12 1.506(5) . ?
C12 H12 1.0000 . ?
C12 C13 1.520(5) . ?
C12 C19 1.546(5) . ?
C13 C14 1.401(5) . ?
C13 C18 1.391(5) . ?
C14 C15 1.400(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.391(5) . ?
C16 H16 0.9500 . ?
C16 C17 1.371(6) . ?
C17 H17 0.9500 . ?
C17 C18 1.395(6) . ?
C18 H18 0.9500 . ?
C19 C20 1.378(5) . ?
C19 C24 1.405(5) . ?
C20 H20 0.9500 . ?
C20 C21 1.391(6) . ?
C21 H21 0.9500 . ?
C21 C22 1.375(6) . ?
C22 H22 0.9500 . ?
C22 C23 1.367(6) . ?
C23 H23 0.9500 . ?
C23 C24 1.396(6) . ?
C24 H24 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 N1 Pt1 128.2(3) . . ?
C2 N1 C6 118.7(3) . . ?
C6 N1 Pt1 112.2(2) . . ?
N1 Pt1 Cl1 94.37(9) . . ?
N7 Pt1 Cl1 173.02(9) . . ?
N7 Pt1 N1 80.03(12) . . ?
N7 Pt1 C14 93.05(13) . . ?
C14 Pt1 Cl1 93.26(11) . . ?
C14 Pt1 N1 166.58(13) . . ?
N1 C2 H2 119.1 . . ?
N1 C2 C3 121.9(4) . . ?
C3 C2 H2 119.1 . . ?
C2 C3 H3 120.3 . . ?
C4 C3 C2 119.5(4) . . ?
C4 C3 H3 120.3 . . ?
C3 C4 H4 120.4 . . ?
C5 C4 C3 119.3(4) . . ?
C5 C4 H4 120.4 . . ?
C4 C5 H5 120.4 . . ?
C4 C5 C6 119.2(4) . . ?
C6 C5 H5 120.4 . . ?
N1 C6 C5 121.5(4) . . ?
N1 C6 C7 114.9(3) . . ?
C5 C6 C7 123.6(4) . . ?
N7 C7 C6 115.6(3) . . ?
N7 C7 C8 121.1(3) . . ?
C8 C7 C6 123.3(3) . . ?
C7 N7 Pt1 115.4(2) . . ?
C11 N7 Pt1 125.0(2) . . ?
C11 N7 C7 119.6(3) . . ?
C7 C8 H8 120.3 . . ?
C9 C8 C7 119.4(4) . . ?
C9 C8 H8 120.3 . . ?
C8 C9 H9 120.6 . . ?
C10 C9 C8 118.7(4) . . ?
C10 C9 H9 120.6 . . ?
C9 C10 H10 119.5 . . ?
C9 C10 C11 121.0(4) . . ?
C11 C10 H10 119.5 . . ?
N7 C11 C10 119.8(3) . . ?
N7 C11 C12 118.9(3) . . ?
C10 C11 C12 121.1(3) . . ?
C11 C12 H12 105.8 . . ?
C11 C12 C13 114.9(3) . . ?
C11 C12 C19 108.7(3) . . ?
C13 C12 H12 105.8 . . ?
C13 C12 C19 114.9(3) . . ?
C19 C12 H12 105.8 . . ?
C14 C13 C12 121.3(3) . . ?
C18 C13 C12 118.0(3) . . ?
C18 C13 C14 120.8(3) . . ?
C13 C14 Pt1 121.3(3) . . ?
C15 C14 Pt1 121.1(3) . . ?
C15 C14 C13 117.2(3) . . ?
C14 C15 H15 119.2 . . ?
C16 C15 C14 121.6(4) . . ?
C16 C15 H15 119.2 . . ?
C15 C16 H16 119.7 . . ?
C17 C16 C15 120.6(4) . . ?
C17 C16 H16 119.7 . . ?
C16 C17 H17 120.5 . . ?
C16 C17 C18 118.9(4) . . ?
C18 C17 H17 120.5 . . ?
C13 C18 C17 120.9(4) . . ?
C13 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C20 C19 C12 124.1(3) . . ?
C20 C19 C24 118.5(4) . . ?
C24 C19 C12 117.4(3) . . ?
C19 C20 H20 119.5 . . ?
C19 C20 C21 121.0(4) . . ?
C21 C20 H20 119.5 . . ?
C20 C21 H21 119.8 . . ?
C22 C21 C20 120.3(4) . . ?
C22 C21 H21 119.8 . . ?
C21 C22 H22 120.2 . . ?
C23 C22 C21 119.6(4) . . ?
C23 C22 H22 120.2 . . ?
C22 C23 H23 119.5 . . ?
C22 C23 C24 120.9(4) . . ?
C24 C23 H23 119.5 . . ?
C19 C24 H24 120.2 . . ?
C23 C24 C19 119.7(4) . . ?
C23 C24 H24 120.2 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C2 H2 Cl1 0.95 2.78 3.352(4) 119.3 .
C5 H5 O1 0.95 2.44 3.329(4) 156.7 7_566
C10 H10 Cl1 0.95 2.90 3.565(4) 128.4 4_546
O1 H1 Cl1 0.873(18) 2.45(2) 3.294(4) 164(3) .

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C2 C3 C4 -1.3(6) . . . . ?
N1 C6 C7 N7 1.2(4) . . . . ?
N1 C6 C7 C8 -176.4(3) . . . . ?
Pt1 N1 C2 C3 -167.3(3) . . . . ?
Pt1 N1 C6 C5 170.2(3) . . . . ?
Pt1 N1 C6 C7 -10.5(4) . . . . ?
Pt1 N7 C11 C10 172.4(3) . . . . ?
Pt1 N7 C11 C12 -11.9(5) . . . . ?
Pt1 C14 C15 C16 174.3(3) . . . . ?
C2 N1 C6 C5 0.3(5) . . . . ?
C2 N1 C6 C7 179.6(3) . . . . ?
C2 C3 C4 C5 0.8(6) . . . . ?
C3 C4 C5 C6 0.2(6) . . . . ?
C4 C5 C6 N1 -0.7(6) . . . . ?
C4 C5 C6 C7 179.9(3) . . . . ?
C5 C6 C7 N7 -179.4(3) . . . . ?
C5 C6 C7 C8 3.0(6) . . . . ?
C6 N1 C2 C3 0.8(5) . . . . ?
C6 C7 N7 Pt1 9.4(4) . . . . ?
C6 C7 N7 C11 -171.4(3) . . . . ?
C6 C7 C8 C9 176.2(4) . . . . ?
C7 N7 C11 C10 -6.8(5) . . . . ?
C7 N7 C11 C12 168.9(3) . . . . ?
C7 C8 C9 C10 -3.1(6) . . . . ?
N7 C7 C8 C9 -1.3(6) . . . . ?
N7 C11 C12 C13 52.5(5) . . . . ?
N7 C11 C12 C19 -77.8(4) . . . . ?
C8 C7 N7 Pt1 -173.0(3) . . . . ?
C8 C7 N7 C11 6.3(5) . . . . ?
C8 C9 C10 C11 2.6(6) . . . . ?
C9 C10 C11 N7 2.4(6) . . . . ?
C9 C10 C11 C12 -173.2(4) . . . . ?
C10 C11 C12 C13 -131.8(4) . . . . ?
C10 C11 C12 C19 97.8(4) . . . . ?
C11 C12 C13 C14 -49.5(5) . . . . ?
C11 C12 C13 C18 130.4(4) . . . . ?
C11 C12 C19 C20 111.6(4) . . . . ?
C11 C12 C19 C24 -68.0(4) . . . . ?
C12 C13 C14 Pt1 5.8(5) . . . . ?
C12 C13 C14 C15 179.6(3) . . . . ?
C12 C13 C18 C17 179.8(4) . . . . ?
C12 C19 C20 C21 -179.8(4) . . . . ?
C12 C19 C24 C23 179.7(3) . . . . ?
C13 C12 C19 C20 -18.7(5) . . . . ?
C13 C12 C19 C24 161.7(3) . . . . ?
C13 C14 C15 C16 0.6(6) . . . . ?
C14 C13 C18 C17 -0.4(6) . . . . ?
C14 C15 C16 C17 -0.1(6) . . . . ?
C15 C16 C17 C18 -0.6(6) . . . . ?
C16 C17 C18 C13 0.8(6) . . . . ?
C18 C13 C14 Pt1 -174.0(3) . . . . ?
C18 C13 C14 C15 -0.3(5) . . . . ?
C19 C12 C13 C14 77.8(4) . . . . ?
C19 C12 C13 C18 -102.4(4) . . . . ?
C19 C20 C21 C22 -0.4(6) . . . . ?
C20 C19 C24 C23 0.1(5) . . . . ?
C20 C21 C22 C23 1.1(6) . . . . ?
C21 C22 C23 C24 -1.2(6) . . . . ?
C22 C23 C24 C19 0.6(6) . . . . ?
C24 C19 C20 C21 -0.2(6) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
