# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_d
_database_code_depnum_ccdc_archive 'CCDC 1400353'
_audit_update_record             
;
2015-05-12 deposited with the CCDC.
2015-12-21 downloaded from the CCDC.
;
_audit_creation_date             2014-08-27
_audit_creation_method           
;
  Olex2 1.2
  (compiled Dec  5 2012 16:20:19, GUI svn.r4385)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C74 H66 Dy4 N6 O16, 2(C H2 Cl2)'
_chemical_formula_sum            'C76 H70 Cl4 Dy4 N6 O16'
_chemical_formula_weight         2115.18
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x, -y-1/2, z-1/2'

_cell_length_a                   12.1469(5)
_cell_length_b                   24.8920(10)
_cell_length_c                   13.3583(6)
_cell_angle_alpha                90.00
_cell_angle_beta                 106.209(4)
_cell_angle_gamma                90.00
_cell_volume                     3878.5(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    ?
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      ?
_cell_measurement_theta_min      ?
_exptl_absorpt_coefficient_mu    4.015
_exptl_absorpt_correction_T_max  0.5659
_exptl_absorpt_correction_T_min  0.5006
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.811
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2056
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.1011
_diffrn_reflns_av_unetI/netI     0.0915
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            23054
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.92
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                5625
_reflns_number_total             7922
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material  
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max         1.313
_refine_diff_density_min         -1.384
_refine_diff_density_rms         0.152
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     486
_refine_ls_number_reflns         7922
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0762
_refine_ls_R_factor_gt           0.0475
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.020
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0304P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0916
_refine_ls_wR_factor_ref         0.1071
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  H44 of C44, H43 of C43, H41 of C41, H34 of C34, H33 of C33, H32 of C32, H31
  of C31, {H1GA,H1GB} of C1G, H45 of C45, H46 of C46, H6 of C6, H1 of C1, H2A
  of C2, H11 of C11, H16 of C16, H1A of C1A, H1B of C1B, H1E of C1E, H10 of C10,
   H19 of C19, H20 of C20
 At 1.5 times of:
  {H17A,H17B,H17C} of C17, {H1CA,H1CB,H1CC} of C1C, {H1DA,H1DB,H1DC} of C1D,
  {H1FA,H1FB,H1FC} of C1F
2.a Secondary CH2 refined with riding coordinates:
 C1G(H1GA,H1GB)
2.b Aromatic/amide H refined with riding coordinates:
 C10(H10), C19(H19), C20(H20), C31(H31), C32(H32), C33(H33), C34(H34),
 C41(H41), C43(H43), C44(H44), C45(H45), C46(H46), C6(H6), C1(H1), C2(H2A),
 C11(H11), C16(H16), C1A(H1A), C1B(H1B), C1E(H1E)
2.c Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C), C1C(H1CA,H1CB,H1CC), C1D(H1DA,H1DB,H1DC), C1F(H1FA,H1FB,
 H1FC)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.11916(3) 0.529491(14) 0.11197(2) 0.03415(11) Uani 1 1 d . . .
Dy2 Dy 0.14034(3) 0.391780(14) 0.05381(2) 0.03565(11) Uani 1 1 d . . .
O3 O 0.0582(3) 0.61367(18) 0.0351(3) 0.0332(10) Uani 1 1 d . . .
O4 O 0.1585(4) 0.3063(2) -0.0050(4) 0.0561(14) Uani 1 1 d . . .
O5 O 0.2398(4) 0.4001(2) -0.0700(4) 0.0504(14) Uani 1 1 d . . .
O1 O 0.2675(4) 0.4619(2) 0.1350(3) 0.0414(12) Uani 1 1 d . . .
O8 O 0.0776(4) 0.4725(2) -0.0338(4) 0.0320(11) Uani 1 1 d . . .
O2 O 0.0667(4) 0.4442(2) 0.1676(3) 0.0402(12) Uani 1 1 d . . .
N2 N 0.0612(5) 0.3363(3) 0.1757(4) 0.0432(15) Uani 1 1 d . . .
N3 N 0.2461(5) 0.5670(3) 0.0057(4) 0.0393(14) Uani 1 1 d . . .
C3 C 0.3680(6) 0.4527(3) 0.2032(5) 0.0405(18) Uani 1 1 d . . .
C5 C 0.3294(6) 0.6541(4) -0.0168(5) 0.047(2) Uani 1 1 d . . .
C8 C -0.0085(6) 0.4225(3) 0.2106(5) 0.0385(17) Uani 1 1 d . . .
C9 C 0.3990(6) 0.3984(3) 0.2303(5) 0.0420(18) Uani 1 1 d . . .
C10 C 0.3334(6) 0.5438(3) -0.0178(6) 0.051(2) Uani 1 1 d . . .
H10 H 0.3380 0.5065 -0.0156 0.062 Uiso 1 1 calc R . .
C12 C -0.0928(7) 0.3392(4) 0.2610(6) 0.054(2) Uani 1 1 d . . .
C14 C 0.2408(6) 0.6209(3) 0.0022(5) 0.0395(17) Uani 1 1 d . . .
C18 C 0.1432(5) 0.6450(3) 0.0240(5) 0.0355(17) Uani 1 1 d . . .
C19 C 0.2283(7) 0.7325(3) 0.0121(6) 0.056(2) Uani 1 1 d . . .
H19 H 0.2241 0.7697 0.0168 0.067 Uiso 1 1 calc R . .
C20 C -0.0835(6) 0.4517(4) 0.2499(5) 0.051(2) Uani 1 1 d . . .
H20 H -0.0823 0.4891 0.2477 0.061 Uiso 1 1 calc R . .
C23 C -0.0120(6) 0.3648(3) 0.2165(5) 0.0449(19) Uani 1 1 d . . .
C31 C 0.2733(8) 0.3130(4) -0.1202(7) 0.074(3) Uani 1 1 d . . .
H31 H 0.3080 0.2930 -0.1618 0.089 Uiso 1 1 calc R . .
C32 C 0.0581(7) 0.2837(4) 0.1834(6) 0.057(2) Uani 1 1 d . . .
H32 H 0.1083 0.2638 0.1568 0.069 Uiso 1 1 calc R . .
C33 C 0.3206(7) 0.7102(4) -0.0113(7) 0.064(2) Uani 1 1 d . . .
H33 H 0.3775 0.7321 -0.0235 0.077 Uiso 1 1 calc R . .
C34 C 0.5308(7) 0.3321(4) 0.3273(7) 0.068(3) Uani 1 1 d . . .
H34 H 0.5984 0.3230 0.3772 0.082 Uiso 1 1 calc R . .
C37 C 0.2809(7) 0.3689(4) -0.1229(6) 0.061(2) Uani 1 1 d . . .
C41 C 0.5432(7) 0.4795(5) 0.3285(7) 0.073(3) Uani 1 1 d . . .
H41 H 0.5919 0.5075 0.3592 0.087 Uiso 1 1 calc R . .
C43 C -0.0145(8) 0.2559(4) 0.2284(7) 0.069(3) Uani 1 1 d . . .
H43 H -0.0104 0.2186 0.2335 0.083 Uiso 1 1 calc R . .
C44 C 0.1398(6) 0.7012(3) 0.0293(5) 0.0461(19) Uani 1 1 d . . .
H44 H 0.0778 0.7179 0.0444 0.055 Uiso 1 1 calc R . .
C45 C 0.4194(7) 0.5724(4) -0.0460(7) 0.065(3) Uani 1 1 d . . .
H45 H 0.4770 0.5541 -0.0654 0.078 Uiso 1 1 calc R . .
C46 C 0.4181(7) 0.6256(4) -0.0447(6) 0.066(3) Uani 1 1 d . . .
H46 H 0.4760 0.6446 -0.0623 0.079 Uiso 1 1 calc R . .
O7 O 0.2592(4) 0.5797(2) 0.2236(4) 0.0499(13) Uani 1 1 d . . .
O6 O 0.0465(4) 0.5611(2) 0.2441(4) 0.0523(14) Uani 1 1 d . . .
N1 N 0.3278(5) 0.3587(3) 0.1790(5) 0.0465(16) Uani 1 1 d . . .
C6 C 0.3614(7) 0.3085(4) 0.2013(6) 0.059(2) Uani 1 1 d . . .
H6 H 0.3145 0.2815 0.1641 0.070 Uiso 1 1 calc R . .
C7 C 0.5038(6) 0.3858(4) 0.3075(6) 0.055(2) Uani 1 1 d . . .
C1 C 0.5735(7) 0.4286(5) 0.3590(7) 0.074(3) Uani 1 1 d . . .
H1 H 0.6393 0.4218 0.4130 0.089 Uiso 1 1 calc R . .
C2 C -0.1609(8) 0.4257(4) 0.2929(7) 0.075(3) Uani 1 1 d . . .
H2A H -0.2103 0.4462 0.3195 0.090 Uiso 1 1 calc R . .
C4 C 0.2175(7) 0.2858(4) -0.0596(6) 0.061(2) Uani 1 1 d . . .
C11 C 0.4407(6) 0.4919(4) 0.2520(6) 0.056(2) Uani 1 1 d . . .
H11 H 0.4224 0.5276 0.2347 0.068 Uiso 1 1 calc R . .
C13 C 0.0729(7) 0.5965(4) 0.3127(6) 0.055(2) Uani 1 1 d . . .
C15 C 0.2634(7) 0.6154(4) 0.2919(6) 0.059(2) Uani 1 1 d . . .
C16 C -0.1665(8) 0.3719(5) 0.2972(7) 0.077(3) Uani 1 1 d . . .
H16 H -0.2208 0.3561 0.3250 0.093 Uiso 1 1 calc R . .
C17 C 0.3408(8) 0.3928(5) -0.1969(7) 0.093(4) Uani 1 1 d . . .
H17A H 0.3295 0.3701 -0.2569 0.140 Uiso 1 1 calc R . .
H17B H 0.4213 0.3959 -0.1627 0.140 Uiso 1 1 calc R . .
H17C H 0.3097 0.4278 -0.2184 0.140 Uiso 1 1 calc R . .
C1A C -0.0905(8) 0.2828(4) 0.2642(6) 0.069(3) Uani 1 1 d . . .
H1A H -0.1420 0.2642 0.2915 0.083 Uiso 1 1 calc R . .
C1B C 0.1755(7) 0.6244(4) 0.3371(6) 0.064(2) Uani 1 1 d . . .
H1B H 0.1862 0.6512 0.3875 0.077 Uiso 1 1 calc R . .
C1C C 0.2229(9) 0.2239(4) -0.0532(7) 0.092(3) Uani 1 1 d . . .
H1CA H 0.2727 0.2133 0.0131 0.138 Uiso 1 1 calc R . .
H1CB H 0.2519 0.2102 -0.1079 0.138 Uiso 1 1 calc R . .
H1CC H 0.1474 0.2099 -0.0607 0.138 Uiso 1 1 calc R . .
C1D C 0.3734(8) 0.6486(5) 0.3231(10) 0.122(5) Uani 1 1 d . . .
H1DA H 0.3742 0.6733 0.2681 0.183 Uiso 1 1 calc R . .
H1DB H 0.4385 0.6251 0.3350 0.183 Uiso 1 1 calc R . .
H1DC H 0.3766 0.6682 0.3857 0.183 Uiso 1 1 calc R . .
C1E C 0.4609(7) 0.2927(4) 0.2757(7) 0.074(3) Uani 1 1 d . . .
H1E H 0.4787 0.2566 0.2894 0.089 Uiso 1 1 calc R . .
C1F C -0.0148(8) 0.6094(4) 0.3707(7) 0.084(3) Uani 1 1 d . . .
H1FA H -0.0804 0.6262 0.3238 0.126 Uiso 1 1 calc R . .
H1FB H 0.0184 0.6334 0.4273 0.126 Uiso 1 1 calc R . .
H1FC H -0.0381 0.5769 0.3975 0.126 Uiso 1 1 calc R . .
Cl1 Cl 0.1616(3) 0.48951(19) 0.4896(3) 0.1350(14) Uani 1 1 d . . .
Cl2 Cl 0.3175(5) 0.40795(19) 0.4729(4) 0.186(2) Uani 1 1 d . . .
C1G C 0.2351(10) 0.4640(8) 0.4166(7) 0.159(8) Uani 1 1 d . . .
H1GA H 0.2857 0.4914 0.4027 0.191 Uiso 1 1 calc R . .
H1GB H 0.1829 0.4534 0.3504 0.191 Uiso 1 1 calc R . .
H2 H 0.107(5) 0.471(3) -0.072(5) 0.03(2) Uiso 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Dy1 3.8275(6) 3_565 ?
Dy1 Dy2 3.5400(5) . ?
Dy1 Dy2 3.8449(5) 3_565 ?
Dy1 O3 2.360(4) . ?
Dy1 O1 2.422(5) . ?
Dy1 O8 2.326(5) 3_565 ?
Dy1 O8 2.347(5) . ?
Dy1 O2 2.393(5) . ?
Dy1 N3 2.547(6) . ?
Dy1 O7 2.295(5) . ?
Dy1 O6 2.320(5) . ?
Dy2 Dy1 3.8449(5) 3_565 ?
Dy2 O3 2.376(4) 3_565 ?
Dy2 O4 2.301(5) . ?
Dy2 O5 2.314(5) . ?
Dy2 O1 2.381(5) . ?
Dy2 O8 2.344(5) . ?
Dy2 O2 2.361(5) . ?
Dy2 N2 2.522(6) . ?
Dy2 N1 2.556(6) . ?
Dy2 H2 2.55(7) . ?
O3 Dy2 2.376(4) 3_565 ?
O3 C18 1.334(7) . ?
O4 C4 1.263(9) . ?
O5 C37 1.243(9) . ?
O1 C3 1.324(7) . ?
O8 Dy1 2.326(4) 3_565 ?
O8 H2 0.70(6) . ?
O2 C8 1.323(8) . ?
N2 C23 1.364(9) . ?
N2 C32 1.314(10) . ?
N3 C10 1.320(9) . ?
N3 C14 1.344(9) . ?
C3 C9 1.422(11) . ?
C3 C11 1.355(11) . ?
C5 C14 1.434(10) . ?
C5 C33 1.405(11) . ?
C5 C46 1.424(11) . ?
C8 C20 1.378(10) . ?
C8 C23 1.442(11) . ?
C9 N1 1.364(10) . ?
C9 C7 1.431(9) . ?
C10 H10 0.9300 . ?
C10 C45 1.399(11) . ?
C12 C23 1.431(10) . ?
C12 C16 1.393(12) . ?
C12 C1A 1.406(13) . ?
C14 C18 1.429(9) . ?
C18 C44 1.403(10) . ?
C19 H19 0.9300 . ?
C19 C33 1.364(11) . ?
C19 C44 1.398(10) . ?
C20 H20 0.9300 . ?
C20 C2 1.391(11) . ?
C31 H31 0.9300 . ?
C31 C37 1.398(13) . ?
C31 C4 1.370(12) . ?
C32 H32 0.9300 . ?
C32 C43 1.384(11) . ?
C33 H33 0.9300 . ?
C34 H34 0.9300 . ?
C34 C7 1.384(13) . ?
C34 C1E 1.355(13) . ?
C37 C17 1.505(12) . ?
C41 H41 0.9300 . ?
C41 C1 1.350(14) . ?
C41 C11 1.407(10) . ?
C43 H43 0.9300 . ?
C43 C1A 1.332(12) . ?
C44 H44 0.9300 . ?
C45 H45 0.9300 . ?
C45 C46 1.325(13) . ?
C46 H46 0.9300 . ?
O7 C15 1.263(9) . ?
O6 C13 1.246(9) . ?
N1 C6 1.323(10) . ?
C6 H6 0.9300 . ?
C6 C1E 1.391(10) . ?
C7 C1 1.415(13) . ?
C1 H1 0.9300 . ?
C2 H2A 0.9300 . ?
C2 C16 1.343(13) . ?
C4 C1C 1.544(13) . ?
C11 H11 0.9300 . ?
C13 C1B 1.384(11) . ?
C13 C1F 1.517(10) . ?
C15 C1B 1.384(11) . ?
C15 C1D 1.526(11) . ?
C16 H16 0.9300 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C1A H1A 0.9300 . ?
C1B H1B 0.9300 . ?
C1C H1CA 0.9600 . ?
C1C H1CB 0.9600 . ?
C1C H1CC 0.9600 . ?
C1D H1DA 0.9600 . ?
C1D H1DB 0.9600 . ?
C1D H1DC 0.9600 . ?
C1E H1E 0.9300 . ?
C1F H1FA 0.9600 . ?
C1F H1FB 0.9600 . ?
C1F H1FC 0.9600 . ?
Cl1 C1G 1.624(12) . ?
Cl2 C1G 1.758(15) . ?
C1G H1GA 0.9700 . ?
C1G H1GB 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Dy1 Dy1 Dy2 54.954(10) 3_565 3_565 ?
Dy2 Dy1 Dy1 62.773(10) . 3_565 ?
Dy2 Dy1 Dy2 117.727(10) . 3_565 ?
O3 Dy1 Dy1 85.60(10) . 3_565 ?
O3 Dy1 Dy2 142.88(10) . . ?
O3 Dy1 Dy2 35.86(10) . 3_565 ?
O3 Dy1 O1 143.55(15) . . ?
O3 Dy1 O2 147.57(15) . . ?
O3 Dy1 N3 66.25(17) . . ?
O1 Dy1 Dy1 101.89(11) . 3_565 ?
O1 Dy1 Dy2 42.07(11) . . ?
O1 Dy1 Dy2 152.70(10) . 3_565 ?
O1 Dy1 N3 77.34(18) . . ?
O8 Dy1 Dy1 35.20(12) 3_565 3_565 ?
O8 Dy1 Dy1 34.84(11) . 3_565 ?
O8 Dy1 Dy2 90.52(12) 3_565 . ?
O8 Dy1 Dy2 83.00(11) . 3_565 ?
O8 Dy1 Dy2 34.73(12) 3_565 3_565 ?
O8 Dy1 Dy2 40.97(11) . . ?
O8 Dy1 O3 101.91(15) . . ?
O8 Dy1 O3 70.46(15) 3_565 . ?
O8 Dy1 O1 70.45(15) . . ?
O8 Dy1 O1 132.58(16) 3_565 . ?
O8 Dy1 O8 70.0(2) 3_565 . ?
O8 Dy1 O2 73.00(16) . . ?
O8 Dy1 O2 77.92(16) 3_565 . ?
O8 Dy1 N3 77.44(17) . . ?
O8 Dy1 N3 117.65(17) 3_565 . ?
O2 Dy1 Dy1 72.15(10) . 3_565 ?
O2 Dy1 Dy2 41.52(11) . . ?
O2 Dy1 Dy2 112.59(10) . 3_565 ?
O2 Dy1 O1 66.25(16) . . ?
O2 Dy1 N3 138.88(18) . . ?
N3 Dy1 Dy1 98.55(12) . 3_565 ?
N3 Dy1 Dy2 91.08(13) . 3_565 ?
N3 Dy1 Dy2 98.07(14) . . ?
O7 Dy1 Dy1 168.17(13) . 3_565 ?
O7 Dy1 Dy2 115.86(13) . 3_565 ?
O7 Dy1 Dy2 125.76(13) . . ?
O7 Dy1 O3 83.37(17) . . ?
O7 Dy1 O1 84.63(17) . . ?
O7 Dy1 O8 141.78(18) . 3_565 ?
O7 Dy1 O8 144.82(17) . . ?
O7 Dy1 O2 119.67(17) . . ?
O7 Dy1 N3 73.03(18) . . ?
O7 Dy1 O6 71.99(18) . . ?
O6 Dy1 Dy1 111.06(12) . 3_565 ?
O6 Dy1 Dy2 80.81(13) . 3_565 ?
O6 Dy1 Dy2 124.19(14) . . ?
O6 Dy1 O3 83.68(17) . . ?
O6 Dy1 O1 124.54(17) . . ?
O6 Dy1 O8 142.83(17) . . ?
O6 Dy1 O8 77.72(17) . 3_565 ?
O6 Dy1 O2 82.77(18) . . ?
O6 Dy1 N3 135.85(19) . . ?
Dy1 Dy2 Dy1 62.273(10) . 3_565 ?
Dy1 Dy2 H2 52.1(15) . . ?
Dy1 Dy2 H2 43.4(14) 3_565 . ?
O3 Dy2 Dy1 35.59(11) 3_565 3_565 ?
O3 Dy2 Dy1 92.24(11) 3_565 . ?
O3 Dy2 O1 135.09(15) 3_565 . ?
O3 Dy2 N2 76.97(16) 3_565 . ?
O3 Dy2 N1 154.59(18) 3_565 . ?
O3 Dy2 H2 76.4(15) 3_565 . ?
O4 Dy2 Dy1 172.11(14) . . ?
O4 Dy2 Dy1 114.59(12) . 3_565 ?
O4 Dy2 O3 87.55(16) . 3_565 ?
O4 Dy2 O5 73.70(19) . . ?
O4 Dy2 O1 136.18(17) . . ?
O4 Dy2 O8 132.19(18) . . ?
O4 Dy2 O2 145.22(18) . . ?
O4 Dy2 N2 78.7(2) . . ?
O4 Dy2 N1 76.87(19) . . ?
O4 Dy2 H2 120.3(15) . . ?
O5 Dy2 Dy1 92.91(12) . 3_565 ?
O5 Dy2 Dy1 98.91(14) . . ?
O5 Dy2 O3 107.93(16) . 3_565 ?
O5 Dy2 O1 81.85(17) . . ?
O5 Dy2 O8 74.24(18) . . ?
O5 Dy2 O2 141.08(18) . . ?
O5 Dy2 N2 151.6(2) . . ?
O5 Dy2 N1 87.04(18) . . ?
O5 Dy2 H2 58.6(14) . . ?
O1 Dy2 Dy1 102.24(11) . 3_565 ?
O1 Dy2 Dy1 42.96(11) . . ?
O1 Dy2 N2 115.03(17) . . ?
O1 Dy2 N1 65.90(19) . . ?
O1 Dy2 H2 72.2(15) . . ?
O8 Dy2 Dy1 41.04(12) . . ?
O8 Dy2 Dy1 34.44(11) . 3_565 ?
O8 Dy2 O3 69.90(16) . 3_565 ?
O8 Dy2 O1 71.22(16) . . ?
O8 Dy2 O2 73.64(17) . . ?
O8 Dy2 N2 131.52(19) . . ?
O8 Dy2 N1 135.13(19) . . ?
O8 Dy2 H2 15.7(14) . . ?
O2 Dy2 Dy1 72.04(10) . 3_565 ?
O2 Dy2 Dy1 42.22(12) . . ?
O2 Dy2 O3 80.73(15) . 3_565 ?
O2 Dy2 O1 67.41(16) . . ?
O2 Dy2 N2 66.79(19) . . ?
O2 Dy2 N1 100.69(17) . . ?
O2 Dy2 H2 88.6(15) . . ?
N2 Dy2 Dy1 104.60(13) . 3_565 ?
N2 Dy2 Dy1 108.94(15) . . ?
N2 Dy2 N1 80.34(18) . . ?
N2 Dy2 H2 146.2(14) . . ?
N1 Dy2 Dy1 168.04(15) . 3_565 ?
N1 Dy2 Dy1 105.90(15) . . ?
N1 Dy2 H2 128.8(15) . . ?
Dy1 O3 Dy2 108.56(17) . 3_565 ?
C18 O3 Dy1 114.1(4) . . ?
C18 O3 Dy2 133.4(4) . 3_565 ?
C4 O4 Dy2 133.9(6) . . ?
C37 O5 Dy2 136.3(6) . . ?
Dy2 O1 Dy1 94.97(15) . . ?
C3 O1 Dy1 135.9(4) . . ?
C3 O1 Dy2 122.9(4) . . ?
Dy1 O8 Dy1 110.0(2) 3_565 . ?
Dy1 O8 Dy2 110.83(19) 3_565 . ?
Dy1 O8 H2 110(5) 3_565 . ?
Dy1 O8 H2 126(6) . . ?
Dy2 O8 Dy1 97.99(17) . . ?
Dy2 O8 H2 99(6) . . ?
Dy2 O2 Dy1 96.26(15) . . ?
C8 O2 Dy1 140.6(5) . . ?
C8 O2 Dy2 119.1(5) . . ?
C23 N2 Dy2 112.5(5) . . ?
C32 N2 Dy2 128.4(6) . . ?
C32 N2 C23 116.8(7) . . ?
C10 N3 Dy1 128.6(5) . . ?
C10 N3 C14 117.6(7) . . ?
C14 N3 Dy1 110.8(5) . . ?
O1 C3 C9 117.9(7) . . ?
O1 C3 C11 124.0(8) . . ?
C11 C3 C9 118.1(7) . . ?
C33 C5 C14 119.4(8) . . ?
C33 C5 C46 125.7(8) . . ?
C46 C5 C14 114.9(8) . . ?
O2 C8 C20 124.1(8) . . ?
O2 C8 C23 117.7(7) . . ?
C20 C8 C23 118.2(7) . . ?
C3 C9 C7 120.7(7) . . ?
N1 C9 C3 118.3(6) . . ?
N1 C9 C7 121.1(8) . . ?
N3 C10 H10 118.3 . . ?
N3 C10 C45 123.4(8) . . ?
C45 C10 H10 118.3 . . ?
C16 C12 C23 117.8(9) . . ?
C16 C12 C1A 125.7(9) . . ?
C1A C12 C23 116.6(9) . . ?
N3 C14 C5 123.3(7) . . ?
N3 C14 C18 116.5(7) . . ?
C18 C14 C5 120.1(7) . . ?
O3 C18 C14 119.3(7) . . ?
O3 C18 C44 122.9(7) . . ?
C44 C18 C14 117.8(7) . . ?
C33 C19 H19 119.0 . . ?
C33 C19 C44 121.9(8) . . ?
C44 C19 H19 119.0 . . ?
C8 C20 H20 119.8 . . ?
C8 C20 C2 120.4(9) . . ?
C2 C20 H20 119.8 . . ?
N2 C23 C8 117.7(7) . . ?
N2 C23 C12 122.3(8) . . ?
C12 C23 C8 120.0(8) . . ?
C37 C31 H31 118.2 . . ?
C4 C31 H31 118.2 . . ?
C4 C31 C37 123.6(9) . . ?
N2 C32 H32 117.7 . . ?
N2 C32 C43 124.6(9) . . ?
C43 C32 H32 117.7 . . ?
C5 C33 H33 120.1 . . ?
C19 C33 C5 119.8(8) . . ?
C19 C33 H33 120.1 . . ?
C7 C34 H34 119.3 . . ?
C1E C34 H34 119.3 . . ?
C1E C34 C7 121.4(8) . . ?
O5 C37 C31 124.5(8) . . ?
O5 C37 C17 118.1(9) . . ?
C31 C37 C17 117.3(9) . . ?
C1 C41 H41 118.8 . . ?
C1 C41 C11 122.4(9) . . ?
C11 C41 H41 118.8 . . ?
C32 C43 H43 120.2 . . ?
C1A C43 C32 119.6(9) . . ?
C1A C43 H43 120.2 . . ?
C18 C44 H44 119.5 . . ?
C19 C44 C18 120.9(7) . . ?
C19 C44 H44 119.5 . . ?
C10 C45 H45 120.2 . . ?
C46 C45 C10 119.6(9) . . ?
C46 C45 H45 120.2 . . ?
C5 C46 H46 119.6 . . ?
C45 C46 C5 120.9(8) . . ?
C45 C46 H46 119.6 . . ?
C15 O7 Dy1 136.5(5) . . ?
C13 O6 Dy1 136.4(5) . . ?
C9 N1 Dy2 114.9(5) . . ?
C6 N1 Dy2 127.9(6) . . ?
C6 N1 C9 117.2(7) . . ?
N1 C6 H6 117.2 . . ?
N1 C6 C1E 125.5(9) . . ?
C1E C6 H6 117.2 . . ?
C34 C7 C9 117.7(8) . . ?
C34 C7 C1 123.8(8) . . ?
C1 C7 C9 118.5(8) . . ?
C41 C1 C7 119.0(8) . . ?
C41 C1 H1 120.5 . . ?
C7 C1 H1 120.5 . . ?
C20 C2 H2A 119.0 . . ?
C16 C2 C20 122.0(9) . . ?
C16 C2 H2A 119.0 . . ?
O4 C4 C31 126.6(9) . . ?
O4 C4 C1C 113.1(9) . . ?
C31 C4 C1C 120.3(9) . . ?
C3 C11 C41 121.2(9) . . ?
C3 C11 H11 119.4 . . ?
C41 C11 H11 119.4 . . ?
O6 C13 C1B 123.9(8) . . ?
O6 C13 C1F 116.9(8) . . ?
C1B C13 C1F 119.2(7) . . ?
O7 C15 C1B 123.2(8) . . ?
O7 C15 C1D 115.7(8) . . ?
C1B C15 C1D 121.1(8) . . ?
C12 C16 H16 119.2 . . ?
C2 C16 C12 121.5(9) . . ?
C2 C16 H16 119.2 . . ?
C37 C17 H17A 109.5 . . ?
C37 C17 H17B 109.5 . . ?
C37 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C12 C1A H1A 120.0 . . ?
C43 C1A C12 120.1(9) . . ?
C43 C1A H1A 120.0 . . ?
C13 C1B H1B 117.6 . . ?
C15 C1B C13 124.7(7) . . ?
C15 C1B H1B 117.6 . . ?
C4 C1C H1CA 109.5 . . ?
C4 C1C H1CB 109.5 . . ?
C4 C1C H1CC 109.5 . . ?
H1CA C1C H1CB 109.5 . . ?
H1CA C1C H1CC 109.5 . . ?
H1CB C1C H1CC 109.5 . . ?
C15 C1D H1DA 109.5 . . ?
C15 C1D H1DB 109.5 . . ?
C15 C1D H1DC 109.5 . . ?
H1DA C1D H1DB 109.5 . . ?
H1DA C1D H1DC 109.5 . . ?
H1DB C1D H1DC 109.5 . . ?
C34 C1E C6 117.0(9) . . ?
C34 C1E H1E 121.5 . . ?
C6 C1E H1E 121.5 . . ?
C13 C1F H1FA 109.5 . . ?
C13 C1F H1FB 109.5 . . ?
C13 C1F H1FC 109.5 . . ?
H1FA C1F H1FB 109.5 . . ?
H1FA C1F H1FC 109.5 . . ?
H1FB C1F H1FC 109.5 . . ?
Cl1 C1G Cl2 113.4(7) . . ?
Cl1 C1G H1GA 108.9 . . ?
Cl1 C1G H1GB 108.9 . . ?
Cl2 C1G H1GA 108.9 . . ?
Cl2 C1G H1GB 108.9 . . ?
H1GA C1G H1GB 107.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 Dy1 Dy2 O3 -19.94(10) 3_565 . . 3_565 ?
Dy1 Dy1 Dy2 O4 68.4(9) 3_565 . . . ?
Dy1 Dy1 Dy2 O5 88.60(12) 3_565 . . . ?
Dy1 Dy1 Dy2 O1 156.34(16) 3_565 . . . ?
Dy1 Dy1 Dy2 O8 35.39(18) 3_565 . . . ?
Dy1 Dy1 Dy2 O2 -93.50(15) 3_565 . . . ?
Dy1 Dy1 Dy2 N2 -96.93(13) 3_565 . . . ?
Dy1 Dy1 Dy2 N1 178.05(14) 3_565 . . . ?
Dy1 Dy1 O3 Dy2 28.74(14) 3_565 . . 3_565 ?
Dy1 Dy1 O3 C18 -131.9(4) 3_565 . . . ?
Dy1 Dy1 O1 Dy2 -21.39(14) 3_565 . . . ?
Dy1 Dy1 O1 C3 -172.2(6) 3_565 . . . ?
Dy1 Dy1 O8 Dy2 -115.7(3) 3_565 . . . ?
Dy1 Dy1 O2 Dy2 68.82(11) 3_565 . . . ?
Dy1 Dy1 O2 C8 -85.9(6) 3_565 . . . ?
Dy1 Dy1 N3 C10 -92.6(6) 3_565 . . . ?
Dy1 Dy1 N3 C14 107.9(4) 3_565 . . . ?
Dy1 Dy1 O7 C15 87.1(10) 3_565 . . . ?
Dy1 Dy1 O6 C13 -152.2(8) 3_565 . . . ?
Dy1 Dy2 O4 C4 33.0(14) . . . . ?
Dy1 Dy2 O4 C4 97.9(7) 3_565 . . . ?
Dy1 Dy2 O5 C37 -120.3(7) 3_565 . . . ?
Dy1 Dy2 O5 C37 177.3(7) . . . . ?
Dy1 Dy2 O1 Dy1 21.32(14) 3_565 . . . ?
Dy1 Dy2 O1 C3 177.5(4) 3_565 . . . ?
Dy1 Dy2 O1 C3 156.2(5) . . . . ?
Dy1 Dy2 O8 Dy1 115.0(3) 3_565 . . . ?
Dy1 Dy2 O8 Dy1 -115.0(3) . . . 3_565 ?
Dy1 Dy2 O2 Dy1 -68.24(11) 3_565 . . . ?
Dy1 Dy2 O2 C8 93.7(4) 3_565 . . . ?
Dy1 Dy2 O2 C8 161.9(5) . . . . ?
Dy1 Dy2 N2 C23 -43.2(5) 3_565 . . . ?
Dy1 Dy2 N2 C23 22.0(5) . . . . ?
Dy1 Dy2 N2 C32 118.3(6) 3_565 . . . ?
Dy1 Dy2 N2 C32 -176.5(6) . . . . ?
Dy1 Dy2 N1 C9 -4.3(10) 3_565 . . . ?
Dy1 Dy2 N1 C9 -12.7(5) . . . . ?
Dy1 Dy2 N1 C6 173.6(4) 3_565 . . . ?
Dy1 Dy2 N1 C6 165.2(6) . . . . ?
Dy1 O3 C18 C14 33.9(7) . . . . ?
Dy1 O3 C18 C44 -148.3(5) . . . . ?
Dy1 O1 C3 C9 143.1(5) . . . . ?
Dy1 O1 C3 C11 -33.8(10) . . . . ?
Dy1 O2 C8 C20 -7.7(11) . . . . ?
Dy1 O2 C8 C23 172.3(4) . . . . ?
Dy1 N3 C10 C45 -158.3(6) . . . . ?
Dy1 N3 C14 C5 156.4(5) . . . . ?
Dy1 N3 C14 C18 -20.5(7) . . . . ?
Dy1 O7 C15 C1B 17.9(14) . . . . ?
Dy1 O7 C15 C1D -162.5(7) . . . . ?
Dy1 O6 C13 C1B -9.9(14) . . . . ?
Dy1 O6 C13 C1F 169.1(6) . . . . ?
Dy2 Dy1 Dy2 Dy1 0.0 3_565 . . 3_565 ?
Dy2 Dy1 Dy2 O3 -19.94(10) 3_565 . . 3_565 ?
Dy2 Dy1 Dy2 O4 68.4(9) 3_565 . . . ?
Dy2 Dy1 Dy2 O5 88.60(12) 3_565 . . . ?
Dy2 Dy1 Dy2 O1 156.34(16) 3_565 . . . ?
Dy2 Dy1 Dy2 O8 35.39(18) 3_565 . . . ?
Dy2 Dy1 Dy2 O2 -93.50(15) 3_565 . . . ?
Dy2 Dy1 Dy2 N2 -96.93(13) 3_565 . . . ?
Dy2 Dy1 Dy2 N1 178.05(14) 3_565 . . . ?
Dy2 Dy1 O3 Dy2 59.2(2) . . . 3_565 ?
Dy2 Dy1 O3 C18 -101.5(4) . . . . ?
Dy2 Dy1 O3 C18 -160.7(5) 3_565 . . . ?
Dy2 Dy1 O1 Dy2 -50.8(3) 3_565 . . . ?
Dy2 Dy1 O1 C3 -150.9(7) . . . . ?
Dy2 Dy1 O1 C3 158.4(5) 3_565 . . . ?
Dy2 Dy1 O8 Dy1 115.7(3) . . . 3_565 ?
Dy2 Dy1 O8 Dy1 -33.25(16) 3_565 . . 3_565 ?
Dy2 Dy1 O8 Dy2 -148.90(15) 3_565 . . . ?
Dy2 Dy1 O2 Dy2 106.87(11) 3_565 . . . ?
Dy2 Dy1 O2 C8 -47.8(6) 3_565 . . . ?
Dy2 Dy1 O2 C8 -154.7(7) . . . . ?
Dy2 Dy1 N3 C10 -147.3(6) 3_565 . . . ?
Dy2 Dy1 N3 C10 -29.1(6) . . . . ?
Dy2 Dy1 N3 C14 53.2(4) 3_565 . . . ?
Dy2 Dy1 N3 C14 171.4(4) . . . . ?
Dy2 Dy1 O7 C15 50.1(9) 3_565 . . . ?
Dy2 Dy1 O7 C15 -139.4(8) . . . . ?
Dy2 Dy1 O6 C13 137.2(8) . . . . ?
Dy2 Dy1 O6 C13 -105.5(8) 3_565 . . . ?
Dy2 O3 C18 C14 -120.6(6) 3_565 . . . ?
Dy2 O3 C18 C44 57.2(9) 3_565 . . . ?
Dy2 O4 C4 C31 -15.3(13) . . . . ?
Dy2 O4 C4 C1C 164.7(5) . . . . ?
Dy2 O5 C37 C31 1.3(13) . . . . ?
Dy2 O5 C37 C17 179.8(5) . . . . ?
Dy2 O1 C3 C9 -1.7(8) . . . . ?
Dy2 O1 C3 C11 -178.5(6) . . . . ?
Dy2 O2 C8 C20 -158.6(5) . . . . ?
Dy2 O2 C8 C23 21.4(7) . . . . ?
Dy2 N2 C23 C8 -17.3(7) . . . . ?
Dy2 N2 C23 C12 160.6(5) . . . . ?
Dy2 N2 C32 C43 -160.0(6) . . . . ?
Dy2 N1 C6 C1E -175.1(6) . . . . ?
O3 Dy1 Dy2 Dy1 -34.64(16) . . . 3_565 ?
O3 Dy1 Dy2 O3 -54.6(2) . . . 3_565 ?
O3 Dy1 Dy2 O4 33.8(9) . . . . ?
O3 Dy1 Dy2 O5 54.0(2) . . . . ?
O3 Dy1 Dy2 O1 121.7(2) . . . . ?
O3 Dy1 Dy2 O8 0.8(2) . . . . ?
O3 Dy1 Dy2 O2 -128.1(2) . . . . ?
O3 Dy1 Dy2 N2 -131.6(2) . . . . ?
O3 Dy1 Dy2 N1 143.4(2) . . . . ?
O3 Dy1 O1 Dy2 -120.2(2) . . . . ?
O3 Dy1 O1 C3 88.9(6) . . . . ?
O3 Dy1 O8 Dy1 -63.9(2) . . . 3_565 ?
O3 Dy1 O8 Dy2 -179.54(15) . . . . ?
O3 Dy1 O2 Dy2 117.7(2) . . . . ?
O3 Dy1 O2 C8 -36.9(7) . . . . ?
O3 Dy1 N3 C10 -173.9(6) . . . . ?
O3 Dy1 N3 C14 26.6(4) . . . . ?
O3 Dy1 O7 C15 65.7(8) . . . . ?
O3 Dy1 O6 C13 -69.4(8) . . . . ?
O3 Dy2 O4 C4 121.7(7) 3_565 . . . ?
O3 Dy2 O5 C37 -87.4(7) 3_565 . . . ?
O3 Dy2 O1 Dy1 5.3(3) 3_565 . . . ?
O3 Dy2 O1 C3 161.5(4) 3_565 . . . ?
O3 Dy2 O8 Dy1 118.94(19) 3_565 . . . ?
O3 Dy2 O8 Dy1 3.96(17) 3_565 . . 3_565 ?
O3 Dy2 O2 Dy1 -103.82(16) 3_565 . . . ?
O3 Dy2 O2 C8 58.1(4) 3_565 . . . ?
O3 Dy2 N2 C23 -65.9(4) 3_565 . . . ?
O3 Dy2 N2 C32 95.6(6) 3_565 . . . ?
O3 Dy2 N1 C9 -146.7(4) 3_565 . . . ?
O3 Dy2 N1 C6 31.2(9) 3_565 . . . ?
O3 C18 C44 C19 -176.8(6) . . . . ?
O4 Dy2 O5 C37 -5.5(7) . . . . ?
O4 Dy2 O1 Dy1 168.6(2) . . . . ?
O4 Dy2 O1 C3 -35.2(6) . . . . ?
O4 Dy2 O8 Dy1 70.8(3) . . . 3_565 ?
O4 Dy2 O8 Dy1 -174.20(18) . . . . ?
O4 Dy2 O2 Dy1 -175.7(2) . . . . ?
O4 Dy2 O2 C8 -13.8(6) . . . . ?
O4 Dy2 N2 C23 -156.0(5) . . . . ?
O4 Dy2 N2 C32 5.6(6) . . . . ?
O4 Dy2 N1 C9 159.7(5) . . . . ?
O4 Dy2 N1 C6 -22.4(6) . . . . ?
O5 Dy2 O4 C4 12.2(7) . . . . ?
O5 Dy2 O1 Dy1 112.54(18) . . . . ?
O5 Dy2 O1 C3 -91.3(5) . . . . ?
O5 Dy2 O8 Dy1 120.3(2) . . . 3_565 ?
O5 Dy2 O8 Dy1 -124.7(2) . . . . ?
O5 Dy2 O2 Dy1 3.3(3) . . . . ?
O5 Dy2 O2 C8 165.2(4) . . . . ?
O5 Dy2 N2 C23 -169.5(4) . . . . ?
O5 Dy2 N2 C32 -8.0(8) . . . . ?
O5 Dy2 N1 C9 85.7(5) . . . . ?
O5 Dy2 N1 C6 -96.4(7) . . . . ?
O1 Dy1 Dy2 Dy1 -156.34(16) . . . 3_565 ?
O1 Dy1 Dy2 O3 -176.28(19) . . . 3_565 ?
O1 Dy1 Dy2 O4 -87.9(9) . . . . ?
O1 Dy1 Dy2 O5 -67.7(2) . . . . ?
O1 Dy1 Dy2 O8 -120.9(2) . . . . ?
O1 Dy1 Dy2 O2 110.2(2) . . . . ?
O1 Dy1 Dy2 N2 106.7(2) . . . . ?
O1 Dy1 Dy2 N1 21.7(2) . . . . ?
O1 Dy1 O3 Dy2 132.8(2) . . . 3_565 ?
O1 Dy1 O3 C18 -27.8(5) . . . . ?
O1 Dy1 O8 Dy1 153.2(2) . . . 3_565 ?
O1 Dy1 O8 Dy2 37.57(16) . . . . ?
O1 Dy1 O2 Dy2 -43.40(14) . . . . ?
O1 Dy1 O2 C8 161.9(6) . . . . ?
O1 Dy1 N3 C10 7.7(6) . . . . ?
O1 Dy1 N3 C14 -151.7(4) . . . . ?
O1 Dy1 O7 C15 -148.8(8) . . . . ?
O1 Dy1 O6 C13 85.6(8) . . . . ?
O1 Dy2 O4 C4 -46.6(8) . . . . ?
O1 Dy2 O5 C37 137.7(7) . . . . ?
O1 Dy2 O8 Dy1 -38.12(16) . . . . ?
O1 Dy2 O8 Dy1 -153.1(2) . . . 3_565 ?
O1 Dy2 O2 Dy1 43.86(15) . . . . ?
O1 Dy2 O2 C8 -154.2(5) . . . . ?
O1 Dy2 N2 C23 68.1(5) . . . . ?
O1 Dy2 N2 C32 -130.4(6) . . . . ?
O1 Dy2 N1 C9 3.3(4) . . . . ?
O1 Dy2 N1 C6 -178.8(7) . . . . ?
O1 C3 C9 N1 5.0(10) . . . . ?
O1 C3 C9 C7 -176.7(6) . . . . ?
O1 C3 C11 C41 176.0(7) . . . . ?
O8 Dy1 Dy2 Dy1 -35.39(18) . . . 3_565 ?
O8 Dy1 Dy2 Dy1 22.53(12) 3_565 . . 3_565 ?
O8 Dy1 Dy2 O3 2.59(15) 3_565 . . 3_565 ?
O8 Dy1 Dy2 O3 -55.3(2) . . . 3_565 ?
O8 Dy1 Dy2 O4 90.9(9) 3_565 . . . ?
O8 Dy1 Dy2 O4 33.0(9) . . . . ?
O8 Dy1 Dy2 O5 111.13(17) 3_565 . . . ?
O8 Dy1 Dy2 O5 53.2(2) . . . . ?
O8 Dy1 Dy2 O1 178.9(2) 3_565 . . . ?
O8 Dy1 Dy2 O1 120.9(2) . . . . ?
O8 Dy1 Dy2 O8 57.9(3) 3_565 . . . ?
O8 Dy1 Dy2 O2 -128.9(2) . . . . ?
O8 Dy1 Dy2 O2 -70.97(19) 3_565 . . . ?
O8 Dy1 Dy2 N2 -74.40(17) 3_565 . . . ?
O8 Dy1 Dy2 N2 -132.3(2) . . . . ?
O8 Dy1 Dy2 N1 142.7(2) . . . . ?
O8 Dy1 Dy2 N1 -159.43(18) 3_565 . . . ?
O8 Dy1 O3 Dy2 59.7(2) . . . 3_565 ?
O8 Dy1 O3 Dy2 -3.87(16) 3_565 . . 3_565 ?
O8 Dy1 O3 C18 -101.0(4) . . . . ?
O8 Dy1 O3 C18 -164.5(5) 3_565 . . . ?
O8 Dy1 O1 Dy2 -1.5(3) 3_565 . . . ?
O8 Dy1 O1 Dy2 -36.63(15) . . . . ?
O8 Dy1 O1 C3 172.5(6) . . . . ?
O8 Dy1 O1 C3 -152.4(5) 3_565 . . . ?
O8 Dy1 O8 Dy1 0.0 3_565 . . 3_565 ?
O8 Dy1 O8 Dy2 -115.7(3) 3_565 . . . ?
O8 Dy1 O2 Dy2 104.82(17) 3_565 . . . ?
O8 Dy1 O2 Dy2 32.25(15) . . . . ?
O8 Dy1 O2 C8 -122.4(6) . . . . ?
O8 Dy1 O2 C8 -49.9(6) 3_565 . . . ?
O8 Dy1 N3 C10 -124.0(6) 3_565 . . . ?
O8 Dy1 N3 C10 -64.7(6) . . . . ?
O8 Dy1 N3 C14 76.6(5) 3_565 . . . ?
O8 Dy1 N3 C14 135.8(4) . . . . ?
O8 Dy1 O7 C15 19.5(10) 3_565 . . . ?
O8 Dy1 O7 C15 167.0(7) . . . . ?
O8 Dy1 O6 C13 -140.7(8) 3_565 . . . ?
O8 Dy1 O6 C13 -170.8(7) . . . . ?
O8 Dy2 O4 C4 61.9(7) . . . . ?
O8 Dy2 O5 C37 -149.6(8) . . . . ?
O8 Dy2 O1 Dy1 36.50(16) . . . . ?
O8 Dy2 O1 C3 -167.3(5) . . . . ?
O8 Dy2 O2 Dy1 -32.18(15) . . . . ?
O8 Dy2 O2 C8 129.7(5) . . . . ?
O8 Dy2 N2 C23 -18.4(5) . . . . ?
O8 Dy2 N2 C32 143.1(6) . . . . ?
O8 Dy2 N1 C9 21.7(6) . . . . ?
O8 Dy2 N1 C6 -160.4(6) . . . . ?
O2 Dy1 Dy2 Dy1 93.50(15) . . . 3_565 ?
O2 Dy1 Dy2 O3 73.56(18) . . . 3_565 ?
O2 Dy1 Dy2 O4 161.9(9) . . . . ?
O2 Dy1 Dy2 O5 -177.90(19) . . . . ?
O2 Dy1 Dy2 O1 -110.2(2) . . . . ?
O2 Dy1 Dy2 O8 128.9(2) . . . . ?
O2 Dy1 Dy2 N2 -3.4(2) . . . . ?
O2 Dy1 Dy2 N1 -88.5(2) . . . . ?
O2 Dy1 O3 Dy2 -17.3(4) . . . 3_565 ?
O2 Dy1 O3 C18 -178.0(4) . . . . ?
O2 Dy1 O1 Dy2 42.83(15) . . . . ?
O2 Dy1 O1 C3 -108.0(6) . . . . ?
O2 Dy1 O8 Dy1 83.0(2) . . . 3_565 ?
O2 Dy1 O8 Dy2 -32.66(15) . . . . ?
O2 Dy1 N3 C10 -20.0(7) . . . . ?
O2 Dy1 N3 C14 -179.5(4) . . . . ?
O2 Dy1 O7 C15 -90.1(8) . . . . ?
O2 Dy1 O6 C13 140.2(8) . . . . ?
O2 Dy2 O4 C4 -168.4(6) . . . . ?
O2 Dy2 O5 C37 175.0(7) . . . . ?
O2 Dy2 O1 Dy1 -43.09(15) . . . . ?
O2 Dy2 O1 C3 113.1(5) . . . . ?
O2 Dy2 O8 Dy1 33.03(16) . . . . ?
O2 Dy2 O8 Dy1 -81.9(2) . . . 3_565 ?
O2 Dy2 N2 C23 19.5(4) . . . . ?
O2 Dy2 N2 C32 -179.0(7) . . . . ?
O2 Dy2 N1 C9 -55.8(5) . . . . ?
O2 Dy2 N1 C6 122.1(6) . . . . ?
O2 C8 C20 C2 179.3(7) . . . . ?
O2 C8 C23 N2 -1.1(9) . . . . ?
O2 C8 C23 C12 -179.1(6) . . . . ?
N2 Dy2 O4 C4 -161.1(7) . . . . ?
N2 Dy2 O5 C37 8.4(9) . . . . ?
N2 Dy2 O1 Dy1 -91.4(2) . . . . ?
N2 Dy2 O1 C3 64.8(5) . . . . ?
N2 Dy2 O8 Dy1 -45.9(3) . . . 3_565 ?
N2 Dy2 O8 Dy1 69.1(3) . . . . ?
N2 Dy2 O2 Dy1 176.5(2) . . . . ?
N2 Dy2 O2 C8 -21.6(4) . . . . ?
N2 Dy2 N1 C9 -119.8(5) . . . . ?
N2 Dy2 N1 C6 58.1(6) . . . . ?
N2 C32 C43 C1A 2.3(13) . . . . ?
N3 Dy1 Dy2 Dy1 -95.51(12) . . . 3_565 ?
N3 Dy1 Dy2 O3 -115.45(16) . . . 3_565 ?
N3 Dy1 Dy2 O4 -27.1(9) . . . . ?
N3 Dy1 Dy2 O5 -6.90(17) . . . . ?
N3 Dy1 Dy2 O1 60.8(2) . . . . ?
N3 Dy1 Dy2 O8 -60.1(2) . . . . ?
N3 Dy1 Dy2 O2 171.00(19) . . . . ?
N3 Dy1 Dy2 N2 167.56(18) . . . . ?
N3 Dy1 Dy2 N1 82.54(18) . . . . ?
N3 Dy1 O3 Dy2 130.1(2) . . . 3_565 ?
N3 Dy1 O3 C18 -30.6(4) . . . . ?
N3 Dy1 O1 Dy2 -117.61(18) . . . . ?
N3 Dy1 O1 C3 91.5(6) . . . . ?
N3 Dy1 O8 Dy1 -125.9(2) . . . 3_565 ?
N3 Dy1 O8 Dy2 118.4(2) . . . . ?
N3 Dy1 O2 Dy2 -13.6(3) . . . . ?
N3 Dy1 O2 C8 -168.3(6) . . . . ?
N3 Dy1 O7 C15 132.8(9) . . . . ?
N3 Dy1 O6 C13 -23.5(9) . . . . ?
N3 C10 C45 C46 3.4(13) . . . . ?
N3 C14 C18 O3 -7.2(9) . . . . ?
N3 C14 C18 C44 174.9(6) . . . . ?
C3 C9 N1 Dy2 -5.5(8) . . . . ?
C3 C9 N1 C6 176.3(7) . . . . ?
C3 C9 C7 C34 -177.6(7) . . . . ?
C3 C9 C7 C1 2.4(11) . . . . ?
C5 C14 C18 O3 175.8(6) . . . . ?
C5 C14 C18 C44 -2.1(9) . . . . ?
C8 C20 C2 C16 -0.5(14) . . . . ?
C9 C3 C11 C41 -0.8(11) . . . . ?
C9 N1 C6 C1E 2.8(12) . . . . ?
C9 C7 C1 C41 -4.6(14) . . . . ?
C10 N3 C14 C5 -5.5(10) . . . . ?
C10 N3 C14 C18 177.6(6) . . . . ?
C10 C45 C46 C5 -1.1(13) . . . . ?
C14 N3 C10 C45 0.0(11) . . . . ?
C14 C5 C33 C19 0.0(12) . . . . ?
C14 C5 C46 C45 -3.8(11) . . . . ?
C14 C18 C44 C19 1.0(10) . . . . ?
C20 C8 C23 N2 178.9(6) . . . . ?
C20 C8 C23 C12 0.9(10) . . . . ?
C20 C2 C16 C12 1.6(15) . . . . ?
C23 N2 C32 C43 0.9(11) . . . . ?
C23 C8 C20 C2 -0.8(11) . . . . ?
C23 C12 C16 C2 -1.4(13) . . . . ?
C23 C12 C1A C43 0.9(12) . . . . ?
C32 N2 C23 C8 178.9(6) . . . . ?
C32 N2 C23 C12 -3.2(10) . . . . ?
C32 C43 C1A C12 -3.1(13) . . . . ?
C33 C5 C14 N3 -175.2(7) . . . . ?
C33 C5 C14 C18 1.6(10) . . . . ?
C33 C5 C46 C45 178.9(8) . . . . ?
C33 C19 C44 C18 0.6(12) . . . . ?
C34 C7 C1 C41 175.3(9) . . . . ?
C37 C31 C4 O4 5.9(15) . . . . ?
C37 C31 C4 C1C -174.1(8) . . . . ?
C44 C19 C33 C5 -1.1(12) . . . . ?
C46 C5 C14 N3 7.4(10) . . . . ?
C46 C5 C14 C18 -175.8(6) . . . . ?
C46 C5 C33 C19 177.1(8) . . . . ?
O7 Dy1 Dy2 Dy1 -170.37(16) . . . 3_565 ?
O7 Dy1 Dy2 O3 169.69(19) . . . 3_565 ?
O7 Dy1 Dy2 O4 -101.9(9) . . . . ?
O7 Dy1 Dy2 O5 -81.8(2) . . . . ?
O7 Dy1 Dy2 O1 -14.0(2) . . . . ?
O7 Dy1 Dy2 O8 -135.0(2) . . . . ?
O7 Dy1 Dy2 O2 96.1(2) . . . . ?
O7 Dy1 Dy2 N2 92.7(2) . . . . ?
O7 Dy1 Dy2 N1 7.7(2) . . . . ?
O7 Dy1 O3 Dy2 -155.6(2) . . . 3_565 ?
O7 Dy1 O3 C18 43.8(4) . . . . ?
O7 Dy1 O1 Dy2 168.60(18) . . . . ?
O7 Dy1 O1 C3 17.8(6) . . . . ?
O7 Dy1 O8 Dy1 -159.3(2) . . . 3_565 ?
O7 Dy1 O8 Dy2 85.0(3) . . . . ?
O7 Dy1 O2 Dy2 -111.79(18) . . . . ?
O7 Dy1 O2 C8 93.5(6) . . . . ?
O7 Dy1 N3 C10 95.9(6) . . . . ?
O7 Dy1 N3 C14 -63.5(4) . . . . ?
O7 Dy1 O6 C13 15.7(8) . . . . ?
O7 C15 C1B C13 -0.9(15) . . . . ?
O6 Dy1 Dy2 Dy1 97.99(15) . . . 3_565 ?
O6 Dy1 Dy2 O3 78.05(18) . . . 3_565 ?
O6 Dy1 Dy2 O4 166.4(9) . . . . ?
O6 Dy1 Dy2 O5 -173.41(19) . . . . ?
O6 Dy1 Dy2 O1 -105.7(2) . . . . ?
O6 Dy1 Dy2 O8 133.4(2) . . . . ?
O6 Dy1 Dy2 O2 4.5(2) . . . . ?
O6 Dy1 Dy2 N2 1.06(19) . . . . ?
O6 Dy1 Dy2 N1 -84.0(2) . . . . ?
O6 Dy1 O3 Dy2 -83.04(19) . . . 3_565 ?
O6 Dy1 O3 C18 116.3(4) . . . . ?
O6 Dy1 O1 Dy2 104.8(2) . . . . ?
O6 Dy1 O1 C3 -46.0(6) . . . . ?
O6 Dy1 O8 Dy1 31.4(4) . . . 3_565 ?
O6 Dy1 O8 Dy2 -84.3(3) . . . . ?
O6 Dy1 O2 Dy2 -176.26(17) . . . . ?
O6 Dy1 O2 C8 29.1(6) . . . . ?
O6 Dy1 N3 C10 134.8(6) . . . . ?
O6 Dy1 N3 C14 -24.7(5) . . . . ?
O6 Dy1 O7 C15 -19.8(8) . . . . ?
O6 C13 C1B C15 -2.7(15) . . . . ?
N1 Dy2 O4 C4 -78.5(7) . . . . ?
N1 Dy2 O5 C37 71.7(7) . . . . ?
N1 Dy2 O1 Dy1 -157.1(2) . . . . ?
N1 Dy2 O1 C3 -0.9(4) . . . . ?
N1 Dy2 O8 Dy1 -170.8(2) . . . 3_565 ?
N1 Dy2 O8 Dy1 -55.8(3) . . . . ?
N1 Dy2 O2 Dy1 101.94(18) . . . . ?
N1 Dy2 O2 C8 -96.1(4) . . . . ?
N1 Dy2 N2 C23 125.6(5) . . . . ?
N1 Dy2 N2 C32 -72.9(6) . . . . ?
N1 C9 C7 C34 0.7(11) . . . . ?
N1 C9 C7 C1 -179.3(7) . . . . ?
N1 C6 C1E C34 -2.0(14) . . . . ?
C7 C9 N1 Dy2 176.1(5) . . . . ?
C7 C9 N1 C6 -2.0(10) . . . . ?
C7 C34 C1E C6 0.6(14) . . . . ?
C1 C41 C11 C3 -1.5(14) . . . . ?
C4 C31 C37 O5 1.1(15) . . . . ?
C4 C31 C37 C17 -177.4(8) . . . . ?
C11 C3 C9 N1 -178.0(6) . . . . ?
C11 C3 C9 C7 0.3(10) . . . . ?
C11 C41 C1 C7 4.3(15) . . . . ?
C16 C12 C23 N2 -177.8(7) . . . . ?
C16 C12 C23 C8 0.1(11) . . . . ?
C16 C12 C1A C43 -179.0(9) . . . . ?
C1A C12 C23 N2 2.3(10) . . . . ?
C1A C12 C23 C8 -179.8(7) . . . . ?
C1A C12 C16 C2 178.5(9) . . . . ?
C1D C15 C1B C13 179.5(10) . . . . ?
C1E C34 C7 C9 0.0(14) . . . . ?
C1E C34 C7 C1 -179.9(9) . . . . ?
C1F C13 C1B C15 178.3(9) . . . . ?

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1400355'
_audit_update_record             
;
2015-05-12 deposited with the CCDC.
2015-12-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C119 H90 Cl10 Dy4 N6 O16'
_chemical_formula_weight         2864.47

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           ?
_symmetry_space_group_name_H-M   'P -1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.9004(5)
_cell_length_b                   15.1696(6)
_cell_length_c                   16.5072(6)
_cell_angle_alpha                110.993(4)
_cell_angle_beta                 104.394(3)
_cell_angle_gamma                106.271(3)
_cell_volume                     2873.37(19)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.655
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1408
_exptl_absorpt_coefficient_mu    2.869
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  0.5976
_exptl_absorpt_correction_T_max  0.6567
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            23048
_diffrn_reflns_av_R_equivalents  0.0448
_diffrn_reflns_av_sigmaI/netI    0.0682
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.14
_diffrn_reflns_theta_max         28.91
_reflns_number_total             12905
_reflns_number_gt                9351
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0369P)²+2.6623P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         12905
_refine_ls_number_parameters     740
_refine_ls_number_restraints     64
_refine_ls_R_factor_all          0.0699
_refine_ls_R_factor_gt           0.0427
_refine_ls_wR_factor_ref         0.1084
_refine_ls_wR_factor_gt          0.0917
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_restrained_S_all      1.055
_refine_ls_shift/su_max          0.022
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.134575(19) 0.009623(18) 0.485260(17) 0.03198(8) Uani 1 1 d . . .
Dy2 Dy 0.14940(2) 0.151137(18) 0.715996(17) 0.03529(8) Uani 1 1 d . . .
O6 O 0.2827(3) 0.0240(3) 0.4428(3) 0.0448(10) Uani 1 1 d . . .
O8 O 0.0457(3) 0.1052(2) 0.5610(2) 0.0309(7) Uani 1 1 d . . .
O3 O 0.2641(3) 0.1586(3) 0.6309(3) 0.0416(9) Uani 1 1 d . . .
O7 O 0.1475(3) -0.1466(3) 0.4400(3) 0.0490(10) Uani 1 1 d . . .
O5 O 0.1680(3) 0.3101(3) 0.7212(3) 0.0487(10) Uani 1 1 d . . .
O4 O 0.1410(3) 0.2495(3) 0.8569(3) 0.0526(11) Uani 1 1 d . . .
N3 N 0.3496(4) 0.2608(4) 0.8209(4) 0.0585(14) Uani 1 1 d . . .
N2 N -0.1610(4) -0.1506(4) 0.5677(4) 0.0458(12) Uani 1 1 d . . .
N1 N 0.1779(4) 0.0488(4) 0.8055(3) 0.0520(13) Uani 1 1 d . . .
C1 C 0.2025(6) 0.0792(6) 0.8967(5) 0.068(2) Uani 1 1 d . . .
H1A H 0.2276 0.1494 0.9367 0.082 Uiso 1 1 calc R . .
C2 C 0.1924(7) 0.0112(7) 0.9350(6) 0.087(3) Uani 1 1 d . . .
H2A H 0.2139 0.0365 0.9999 0.105 Uiso 1 1 calc R . .
C3 C 0.1518(7) -0.0904(7) 0.8794(6) 0.080(2) Uani 1 1 d . . .
H3A H 0.1419 -0.1361 0.9051 0.096 Uiso 1 1 calc R . .
C4 C 0.1241(6) -0.1281(6) 0.7817(5) 0.0610(18) Uani 1 1 d . . .
C5 C 0.0846(7) -0.2328(6) 0.7189(6) 0.078(2) Uani 1 1 d . . .
H5A H 0.0731 -0.2820 0.7407 0.093 Uiso 1 1 calc R . .
C6 C 0.0630(6) -0.2627(5) 0.6261(6) 0.071(2) Uani 1 1 d . . .
H6A H 0.0358 -0.3327 0.5846 0.085 Uiso 1 1 calc R . .
C7 C 0.0807(5) -0.1900(4) 0.5913(5) 0.0507(15) Uani 1 1 d . . .
H7A H 0.0663 -0.2126 0.5275 0.061 Uiso 1 1 calc R . .
C8 C 0.1191(5) -0.0861(4) 0.6502(4) 0.0414(13) Uani 1 1 d . . .
C9 C 0.1410(5) -0.0546(5) 0.7473(4) 0.0483(15) Uani 1 1 d . . .
C10 C -0.2161(5) -0.2497(5) 0.5157(5) 0.0596(18) Uani 1 1 d . . .
H10A H -0.2307 -0.2772 0.4516 0.072 Uiso 1 1 calc R . .
C11 C -0.2546(6) -0.3170(6) 0.5514(7) 0.077(2) Uani 1 1 d . . .
H11A H -0.2926 -0.3877 0.5117 0.092 Uiso 1 1 calc R . .
C12 C -0.2362(6) -0.2788(6) 0.6433(7) 0.079(2) Uani 1 1 d . . .
H12A H -0.2612 -0.3232 0.6674 0.094 Uiso 1 1 calc R . .
C13 C -0.1790(6) -0.1716(6) 0.7035(6) 0.0616(18) Uani 1 1 d . . .
C14 C -0.1615(7) -0.1246(8) 0.7983(7) 0.090(3) Uani 1 1 d . . .
H14A H -0.1874 -0.1639 0.8266 0.107 Uiso 1 1 calc R . .
C15 C -0.1064(7) -0.0212(8) 0.8484(6) 0.091(3) Uani 1 1 d . . .
H15A H -0.0963 0.0102 0.9115 0.110 Uiso 1 1 calc R . .
C16 C -0.0640(6) 0.0407(6) 0.8100(5) 0.073(2) Uani 1 1 d . . .
H16A H -0.0257 0.1117 0.8477 0.088 Uiso 1 1 calc R . .
C17 C -0.0781(5) -0.0018(5) 0.7177(4) 0.0470(14) Uani 1 1 d . . .
C18 C -0.1399(5) -0.1109(5) 0.6615(5) 0.0462(14) Uani 1 1 d . . .
C19 C 0.3942(6) 0.3102(6) 0.9131(5) 0.079(2) Uani 1 1 d . . .
H19A H 0.3501 0.2982 0.9455 0.095 Uiso 1 1 calc R . .
C20 C 0.5025(7) 0.3795(7) 0.9661(6) 0.104(3) Uani 1 1 d . . .
H20A H 0.5302 0.4111 1.0316 0.124 Uiso 1 1 calc R . .
C21 C 0.5659(7) 0.3992(8) 0.9194(7) 0.106(3) Uani 1 1 d . . .
H21A H 0.6379 0.4470 0.9535 0.127 Uiso 1 1 calc R . .
C22 C 0.5260(6) 0.3496(6) 0.8211(6) 0.075(2) Uani 1 1 d . . .
C23 C 0.5870(6) 0.3673(7) 0.7695(7) 0.093(3) Uani 1 1 d . . .
H23A H 0.6597 0.4139 0.8002 0.112 Uiso 1 1 calc R . .
C24 C 0.5414(6) 0.3172(6) 0.6752(7) 0.083(3) Uani 1 1 d . . .
H24A H 0.5834 0.3300 0.6415 0.099 Uiso 1 1 calc R . .
C25 C 0.4316(5) 0.2454(5) 0.6254(5) 0.0600(18) Uani 1 1 d . . .
H25A H 0.4024 0.2116 0.5599 0.072 Uiso 1 1 calc R . .
C26 C 0.3681(4) 0.2257(4) 0.6738(4) 0.0416(13) Uani 1 1 d . . .
C27 C 0.4149(5) 0.2790(5) 0.7737(5) 0.0544(16) Uani 1 1 d . . .
C28 C 0.1153(8) 0.2975(8) 1.0232(6) 0.104(3) Uani 1 1 d . . .
H28A H 0.1268 0.2385 0.9944 0.125 Uiso 1 1 calc R . .
C29 C 0.0910(10) 0.3147(12) 1.1049(7) 0.150(5) Uani 1 1 d . . .
H29A H 0.0825 0.2663 1.1276 0.180 Uiso 1 1 calc R . .
C30 C 0.0807(11) 0.4047(12) 1.1488(8) 0.141(5) Uani 1 1 d . . .
H30A H 0.0686 0.4193 1.2042 0.169 Uiso 1 1 calc R . .
C31 C 0.0876(9) 0.4732(10) 1.1139(8) 0.123(4) Uani 1 1 d . . .
H31A H 0.0799 0.5339 1.1447 0.148 Uiso 1 1 calc R . .
C32 C 0.1064(7) 0.4523(7) 1.0314(6) 0.089(3) Uani 1 1 d . . .
H32A H 0.1084 0.4983 1.0061 0.106 Uiso 1 1 calc R . .
C33 C 0.1221(6) 0.3642(6) 0.9864(5) 0.0651(19) Uani 1 1 d . . .
C34 C 0.1437(5) 0.3389(5) 0.8975(4) 0.0479(15) Uani 1 1 d . . .
C35 C 0.1672(5) 0.4127(5) 0.8664(4) 0.0588(18) Uani 1 1 d . . .
H35A H 0.1746 0.4784 0.9049 0.071 Uiso 1 1 calc R . .
C36 C 0.1806(5) 0.3966(4) 0.7822(4) 0.0480(15) Uani 1 1 d . . .
C37 C 0.2120(5) 0.4846(4) 0.7592(5) 0.0551(16) Uani 1 1 d . . .
C38 C 0.2577(7) 0.5876(6) 0.8257(6) 0.089(3) Uani 1 1 d . . .
H38A H 0.2709 0.6041 0.8886 0.107 Uiso 1 1 calc R . .
C39 C 0.2839(9) 0.6660(7) 0.8012(9) 0.114(4) Uani 1 1 d . . .
H39A H 0.3139 0.7345 0.8471 0.137 Uiso 1 1 calc R . .
C40 C 0.2664(8) 0.6440(7) 0.7121(9) 0.106(3) Uani 1 1 d . . .
H40A H 0.2844 0.6973 0.6958 0.127 Uiso 1 1 calc R . .
C41 C 0.2221(7) 0.5436(7) 0.6442(7) 0.089(3) Uani 1 1 d . . .
H41A H 0.2101 0.5286 0.5819 0.107 Uiso 1 1 calc R . .
C42 C 0.1951(6) 0.4642(6) 0.6680(6) 0.070(2) Uani 1 1 d . . .
H42A H 0.1650 0.3959 0.6214 0.084 Uiso 1 1 calc R . .
C43 C 0.0881(5) -0.3620(5) 0.3739(4) 0.0524(16) Uani 1 1 d . . .
H43A H 0.0298 -0.3462 0.3526 0.063 Uiso 1 1 calc R . .
C44 C 0.0681(6) -0.4589(5) 0.3692(5) 0.0631(19) Uani 1 1 d . . .
H44A H -0.0031 -0.5076 0.3442 0.076 Uiso 1 1 calc R . .
C45 C 0.1526(7) -0.4829(6) 0.4010(5) 0.071(2) Uani 1 1 d . . .
H45A H 0.1396 -0.5481 0.3973 0.085 Uiso 1 1 calc R . .
C46 C 0.2567(7) -0.4100(6) 0.4385(6) 0.072(2) Uani 1 1 d . . .
H46A H 0.3146 -0.4255 0.4614 0.086 Uiso 1 1 calc R . .
C47 C 0.2766(6) -0.3152(5) 0.4429(5) 0.0603(18) Uani 1 1 d . . .
H47A H 0.3482 -0.2668 0.4687 0.072 Uiso 1 1 calc R . .
C48 C 0.1924(5) -0.2888(4) 0.4096(4) 0.0427(13) Uani 1 1 d . . .
C49 C 0.2131(5) -0.1836(4) 0.4173(4) 0.0407(13) Uani 1 1 d . . .
C50 C 0.2986(5) -0.1343(5) 0.3990(5) 0.0520(16) Uani 1 1 d . . .
H50A H 0.3393 -0.1701 0.3784 0.062 Uiso 1 1 calc R . .
C51 C 0.3273(4) -0.0344(4) 0.4095(4) 0.0387(12) Uani 1 1 d . . .
C52 C 0.4153(5) 0.0099(5) 0.3797(4) 0.0465(14) Uani 1 1 d . . .
C53 C 0.4944(5) -0.0295(5) 0.3725(5) 0.0562(17) Uani 1 1 d . . .
H53A H 0.4942 -0.0835 0.3869 0.067 Uiso 1 1 calc R . .
C54 C 0.5737(5) 0.0134(6) 0.3434(6) 0.073(2) Uani 1 1 d . . .
H54A H 0.6279 -0.0108 0.3405 0.088 Uiso 1 1 calc R . .
C55 C 0.5729(7) 0.0899(6) 0.3195(6) 0.087(3) Uani 1 1 d . . .
H55A H 0.6255 0.1173 0.2994 0.104 Uiso 1 1 calc R . .
C56 C 0.4935(6) 0.1270(6) 0.3249(6) 0.087(3) Uani 1 1 d . . .
H56A H 0.4915 0.1783 0.3072 0.104 Uiso 1 1 calc R . .
C57 C 0.4169(5) 0.0877(5) 0.3567(5) 0.0630(19) Uani 1 1 d . . .
H57A H 0.3654 0.1151 0.3626 0.076 Uiso 1 1 calc R . .
O2 O -0.0355(3) 0.0514(3) 0.6764(3) 0.0421(9) Uani 1 1 d . . .
O1 O 0.1367(3) -0.0132(3) 0.6224(3) 0.0401(9) Uani 1 1 d . . .
Cl1 Cl 0.4915(3) 0.4329(3) 1.3565(3) 0.1952(19) Uani 1 1 d . . .
Cl2 Cl 0.3968(4) 0.3307(6) 1.1609(4) 0.318(4) Uani 1 1 d . . .
C58 C 0.4926(10) 0.4291(11) 1.2500(11) 0.169(6) Uani 1 1 d . . .
H58A H 0.4874 0.4909 1.2483 0.203 Uiso 1 1 calc R . .
H58B H 0.5615 0.4297 1.2467 0.203 Uiso 1 1 calc R . .
C60 C 0.260(4) 0.841(3) 1.158(2) 0.069(12) Uani 0.179(9) 1 d PDU A 1
H60A H 0.1867 0.8190 1.1561 0.083 Uiso 0.179(9) 1 calc PR A 1
H60B H 0.3080 0.8976 1.2204 0.083 Uiso 0.179(9) 1 calc PR A 1
Cl6 Cl 0.265(3) 0.882(2) 1.077(2) 0.227(16) Uani 0.179(9) 1 d PDU A 1
Cl5 Cl 0.299(3) 0.742(2) 1.137(2) 0.243(17) Uani 0.179(9) 1 d PDU A 1
Cl3 Cl 0.1823(13) 0.7406(12) 1.1313(11) 0.493(9) Uani 0.821(9) 1 d PDU A 2
Cl4 Cl 0.3313(13) 0.8313(14) 1.0756(12) 0.555(11) Uani 0.821(9) 1 d PDU A 2
C59 C 0.1891(11) 0.7565(11) 1.0397(9) 0.128(5) Uani 0.821(9) 1 d PDU A 2
H59A H 0.1461 0.7935 1.0253 0.154 Uiso 0.821(9) 1 calc PR A 2
H59B H 0.1638 0.6905 0.9848 0.154 Uiso 0.821(9) 1 calc PR A 2
Cl8 Cl 0.514(2) 0.9121(17) 1.0508(18) 0.508(13) Uani 0.50 1 d PDU . .
C61 C 0.455(2) 0.9750(17) 0.9722(16) 0.215(15) Uani 0.50 1 d PDU . .
H61A H 0.4993 0.9935 0.9392 0.258 Uiso 0.50 1 calc PR . .
H61B H 0.3794 0.9327 0.9288 0.258 Uiso 0.50 1 calc PR . .
Cl7 Cl 0.4709(18) 1.0858(16) 1.0746(15) 0.471(12) Uani 0.50 1 d PDU . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O7 2.290(4) . ?
Dy1 O6 2.314(3) . ?
Dy1 O8 2.355(3) 2_556 ?
Dy1 O2 2.359(4) 2_556 ?
Dy1 O8 2.380(3) . ?
Dy1 O1 2.404(4) . ?
Dy1 O3 2.409(4) . ?
Dy1 N2 2.556(5) 2_556 ?
Dy1 Dy2 3.5583(4) . ?
Dy1 Dy1 3.8359(5) 2_556 ?
Dy1 Dy2 3.8531(4) 2_556 ?
Dy2 O5 2.319(4) . ?
Dy2 O4 2.323(4) . ?
Dy2 O8 2.331(3) . ?
Dy2 O1 2.344(3) . ?
Dy2 O2 2.366(4) . ?
Dy2 O3 2.379(4) . ?
Dy2 N1 2.538(5) . ?
Dy2 N3 2.541(5) . ?
Dy2 Dy1 3.8531(5) 2_556 ?
O6 C51 1.264(6) . ?
O8 Dy1 2.355(3) 2_556 ?
O3 C26 1.333(6) . ?
O7 C49 1.262(6) . ?
O5 C36 1.267(6) . ?
O4 C34 1.264(7) . ?
N3 C19 1.310(8) . ?
N3 C27 1.369(8) . ?
N2 C10 1.299(7) . ?
N2 C18 1.362(7) . ?
N2 Dy1 2.556(5) 2_556 ?
N1 C1 1.324(8) . ?
N1 C9 1.369(7) . ?
C1 C2 1.384(10) . ?
C1 H1A 0.9300 . ?
C2 C3 1.333(11) . ?
C2 H2A 0.9300 . ?
C3 C4 1.409(10) . ?
C3 H3A 0.9300 . ?
C4 C5 1.396(10) . ?
C4 C9 1.412(8) . ?
C5 C6 1.357(10) . ?
C5 H5A 0.9300 . ?
C6 C7 1.407(8) . ?
C6 H6A 0.9300 . ?
C7 C8 1.374(8) . ?
C7 H7A 0.9300 . ?
C8 O1 1.326(6) . ?
C8 C9 1.420(8) . ?
C10 C11 1.399(9) . ?
C10 H10A 0.9300 . ?
C11 C12 1.340(11) . ?
C11 H11A 0.9300 . ?
C12 C13 1.411(10) . ?
C12 H12A 0.9300 . ?
C13 C14 1.389(11) . ?
C13 C18 1.409(8) . ?
C14 C15 1.347(11) . ?
C14 H14A 0.9300 . ?
C15 C16 1.391(10) . ?
C15 H15A 0.9300 . ?
C16 C17 1.362(8) . ?
C16 H16A 0.9300 . ?
C17 O2 1.338(6) . ?
C17 C18 1.431(8) . ?
C19 C20 1.392(10) . ?
C19 H19A 0.9300 . ?
C20 C21 1.347(12) . ?
C20 H20A 0.9300 . ?
C21 C22 1.397(11) . ?
C21 H21A 0.9300 . ?
C22 C23 1.384(11) . ?
C22 C27 1.419(9) . ?
C23 C24 1.339(11) . ?
C23 H23A 0.9300 . ?
C24 C25 1.413(9) . ?
C24 H24A 0.9300 . ?
C25 C26 1.371(8) . ?
C25 H25A 0.9300 . ?
C26 C27 1.419(8) . ?
C28 C33 1.349(11) . ?
C28 C29 1.422(11) . ?
C28 H28A 0.9300 . ?
C29 C30 1.365(16) . ?
C29 H29A 0.9300 . ?
C30 C31 1.349(16) . ?
C30 H30A 0.9300 . ?
C31 C32 1.392(12) . ?
C31 H31A 0.9300 . ?
C32 C33 1.385(10) . ?
C32 H32A 0.9300 . ?
C33 C34 1.506(9) . ?
C34 C35 1.384(9) . ?
C35 C36 1.392(9) . ?
C35 H35A 0.9300 . ?
C36 C37 1.495(8) . ?
C37 C42 1.366(9) . ?
C37 C38 1.385(9) . ?
C38 C39 1.374(11) . ?
C38 H38A 0.9300 . ?
C39 C40 1.327(13) . ?
C39 H39A 0.9300 . ?
C40 C41 1.366(12) . ?
C40 H40A 0.9300 . ?
C41 C42 1.380(10) . ?
C41 H41A 0.9300 . ?
C42 H42A 0.9300 . ?
C43 C48 1.374(8) . ?
C43 C44 1.387(8) . ?
C43 H43A 0.9300 . ?
C44 C45 1.363(10) . ?
C44 H44A 0.9300 . ?
C45 C46 1.366(10) . ?
C45 H45A 0.9300 . ?
C46 C47 1.357(9) . ?
C46 H46A 0.9300 . ?
C47 C48 1.390(8) . ?
C47 H47A 0.9300 . ?
C48 C49 1.491(7) . ?
C49 C50 1.381(8) . ?
C50 C51 1.387(8) . ?
C50 H50A 0.9300 . ?
C51 C52 1.505(7) . ?
C52 C57 1.360(8) . ?
C52 C53 1.401(8) . ?
C53 C54 1.397(9) . ?
C53 H53A 0.9300 . ?
C54 C55 1.356(10) . ?
C54 H54A 0.9300 . ?
C55 C56 1.380(10) . ?
C55 H55A 0.9300 . ?
C56 C57 1.383(9) . ?
C56 H56A 0.9300 . ?
C57 H57A 0.9300 . ?
O2 Dy1 2.359(4) 2_556 ?
Cl1 C58 1.743(13) . ?
Cl2 C58 1.583(15) . ?
C58 H58A 0.9700 . ?
C58 H58B 0.9700 . ?
C60 Cl6 1.670(19) . ?
C60 Cl5 1.696(19) . ?
C60 H60A 0.9700 . ?
C60 H60B 0.9700 . ?
Cl3 C59 1.635(13) . ?
Cl4 C59 1.795(14) . ?
C59 H59A 0.9700 . ?
C59 H59B 0.9700 . ?
Cl8 C61 1.843(19) 2_677 ?
Cl8 C61 2.017(19) . ?
Cl8 Cl7 2.14(2) 2_677 ?
C61 Cl7 1.815(18) . ?
C61 H61A 0.9700 . ?
C61 H61B 0.9700 . ?
Cl7 C61 1.715(18) 2_677 ?
Cl7 Cl8 2.14(2) 2_677 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Dy1 O6 72.31(13) . . ?
O7 Dy1 O8 77.97(12) . 2_556 ?
O6 Dy1 O8 141.60(12) . 2_556 ?
O7 Dy1 O2 85.54(14) . 2_556 ?
O6 Dy1 O2 84.19(13) . 2_556 ?
O8 Dy1 O2 69.59(12) 2_556 2_556 ?
O7 Dy1 O8 142.44(12) . . ?
O6 Dy1 O8 143.98(12) . . ?
O8 Dy1 O8 71.78(12) 2_556 . ?
O2 Dy1 O8 103.71(12) 2_556 . ?
O7 Dy1 O1 80.51(13) . . ?
O6 Dy1 O1 120.44(13) . . ?
O8 Dy1 O1 76.69(12) 2_556 . ?
O2 Dy1 O1 145.51(12) 2_556 . ?
O8 Dy1 O1 71.40(11) . . ?
O7 Dy1 O3 121.36(14) . . ?
O6 Dy1 O3 84.16(13) . . ?
O8 Dy1 O3 132.90(11) 2_556 . ?
O2 Dy1 O3 145.32(13) 2_556 . ?
O8 Dy1 O3 69.32(11) . . ?
O1 Dy1 O3 66.57(12) . . ?
O7 Dy1 N2 136.94(14) . 2_556 ?
O6 Dy1 N2 73.34(14) . 2_556 ?
O8 Dy1 N2 116.98(13) 2_556 2_556 ?
O2 Dy1 N2 65.83(15) 2_556 2_556 ?
O8 Dy1 N2 78.08(13) . 2_556 ?
O1 Dy1 N2 140.42(14) . 2_556 ?
O3 Dy1 N2 79.54(15) . 2_556 ?
O7 Dy1 Dy2 120.94(10) . . ?
O6 Dy1 Dy2 124.80(10) . . ?
O8 Dy1 Dy2 91.24(8) 2_556 . ?
O2 Dy1 Dy2 144.09(9) 2_556 . ?
O8 Dy1 Dy2 40.43(8) . . ?
O1 Dy1 Dy2 40.82(8) . . ?
O3 Dy1 Dy2 41.67(8) . . ?
N2 Dy1 Dy2 99.86(11) 2_556 . ?
O7 Dy1 Dy1 111.33(9) . 2_556 ?
O6 Dy1 Dy1 169.39(10) . 2_556 ?
O8 Dy1 Dy1 36.10(8) 2_556 2_556 ?
O2 Dy1 Dy1 86.15(9) 2_556 2_556 ?
O8 Dy1 Dy1 35.67(8) . 2_556 ?
O1 Dy1 Dy1 70.17(9) . 2_556 ?
O3 Dy1 Dy1 101.47(8) . 2_556 ?
N2 Dy1 Dy1 98.65(10) 2_556 2_556 ?
Dy2 Dy1 Dy1 62.679(9) . 2_556 ?
O7 Dy1 Dy2 83.53(10) . 2_556 ?
O6 Dy1 Dy2 116.84(10) . 2_556 ?
O8 Dy1 Dy2 34.48(8) 2_556 2_556 ?
O2 Dy1 Dy2 35.44(8) 2_556 2_556 ?
O8 Dy1 Dy2 83.93(8) . 2_556 ?
O1 Dy1 Dy2 111.17(9) . 2_556 ?
O3 Dy1 Dy2 152.60(8) . 2_556 ?
N2 Dy1 Dy2 89.52(11) 2_556 2_556 ?
Dy2 Dy1 Dy2 117.811(8) . 2_556 ?
Dy1 Dy1 Dy2 55.132(8) 2_556 2_556 ?
O5 Dy2 O4 73.47(14) . . ?
O5 Dy2 O8 77.42(12) . . ?
O4 Dy2 O8 130.76(13) . . ?
O5 Dy2 O1 143.58(13) . . ?
O4 Dy2 O1 142.86(13) . . ?
O8 Dy2 O1 73.32(12) . . ?
O5 Dy2 O2 109.33(14) . . ?
O4 Dy2 O2 83.45(14) . . ?
O8 Dy2 O2 69.87(12) . . ?
O1 Dy2 O2 80.38(13) . . ?
O5 Dy2 O3 82.22(13) . . ?
O4 Dy2 O3 140.38(14) . . ?
O8 Dy2 O3 70.65(12) . . ?
O1 Dy2 O3 68.01(12) . . ?
O2 Dy2 O3 134.84(12) . . ?
O5 Dy2 N1 148.14(15) . . ?
O4 Dy2 N1 78.49(15) . . ?
O8 Dy2 N1 133.72(14) . . ?
O1 Dy2 N1 66.27(14) . . ?
O2 Dy2 N1 81.77(15) . . ?
O3 Dy2 N1 111.62(15) . . ?
O5 Dy2 N3 78.63(16) . . ?
O4 Dy2 N3 78.24(17) . . ?
O8 Dy2 N3 132.97(15) . . ?
O1 Dy2 N3 106.33(16) . . ?
O2 Dy2 N3 157.05(16) . . ?
O3 Dy2 N3 66.44(15) . . ?
N1 Dy2 N3 81.13(18) . . ?
O5 Dy2 Dy1 101.56(9) . . ?
O4 Dy2 Dy1 172.19(11) . . ?
O8 Dy2 Dy1 41.46(8) . . ?
O1 Dy2 Dy1 42.10(9) . . ?
O2 Dy2 Dy1 92.74(9) . . ?
O3 Dy2 Dy1 42.32(9) . . ?
N1 Dy2 Dy1 107.78(11) . . ?
N3 Dy2 Dy1 107.00(13) . . ?
O5 Dy2 Dy1 97.07(10) . 2_556 ?
O4 Dy2 Dy1 111.91(11) . 2_556 ?
O8 Dy2 Dy1 34.89(8) . 2_556 ?
O1 Dy2 Dy1 70.25(9) . 2_556 ?
O2 Dy2 Dy1 35.31(9) . 2_556 ?
O3 Dy2 Dy1 101.61(9) . 2_556 ?
N1 Dy2 Dy1 107.33(12) . 2_556 ?
N3 Dy2 Dy1 167.62(13) . 2_556 ?
Dy1 Dy2 Dy1 62.189(8) . 2_556 ?
C51 O6 Dy1 137.3(3) . . ?
Dy2 O8 Dy1 110.62(13) . 2_556 ?
Dy2 O8 Dy1 98.11(12) . . ?
Dy1 O8 Dy1 108.22(12) 2_556 . ?
C26 O3 Dy2 121.0(3) . . ?
C26 O3 Dy1 142.5(3) . . ?
Dy2 O3 Dy1 96.01(12) . . ?
C49 O7 Dy1 137.3(4) . . ?
C36 O5 Dy2 135.7(4) . . ?
C34 O4 Dy2 136.1(4) . . ?
C19 N3 C27 117.3(6) . . ?
C19 N3 Dy2 127.8(5) . . ?
C27 N3 Dy2 114.5(4) . . ?
C10 N2 C18 118.0(5) . . ?
C10 N2 Dy1 127.8(5) . 2_556 ?
C18 N2 Dy1 111.5(4) . 2_556 ?
C1 N1 C9 118.0(6) . . ?
C1 N1 Dy2 127.8(4) . . ?
C9 N1 Dy2 112.7(4) . . ?
N1 C1 C2 122.9(7) . . ?
N1 C1 H1A 118.5 . . ?
C2 C1 H1A 118.5 . . ?
C3 C2 C1 120.3(8) . . ?
C3 C2 H2A 119.8 . . ?
C1 C2 H2A 119.8 . . ?
C2 C3 C4 119.6(7) . . ?
C2 C3 H3A 120.2 . . ?
C4 C3 H3A 120.2 . . ?
C5 C4 C3 123.4(7) . . ?
C5 C4 C9 119.2(7) . . ?
C3 C4 C9 117.4(7) . . ?
C6 C5 C4 119.8(6) . . ?
C6 C5 H5A 120.1 . . ?
C4 C5 H5A 120.1 . . ?
C5 C6 C7 121.4(7) . . ?
C5 C6 H6A 119.3 . . ?
C7 C6 H6A 119.3 . . ?
C8 C7 C6 121.0(6) . . ?
C8 C7 H7A 119.5 . . ?
C6 C7 H7A 119.5 . . ?
O1 C8 C7 124.4(5) . . ?
O1 C8 C9 117.8(5) . . ?
C7 C8 C9 117.8(5) . . ?
N1 C9 C4 121.6(6) . . ?
N1 C9 C8 117.6(5) . . ?
C4 C9 C8 120.8(6) . . ?
N2 C10 C11 123.3(7) . . ?
N2 C10 H10A 118.4 . . ?
C11 C10 H10A 118.4 . . ?
C12 C11 C10 119.4(7) . . ?
C12 C11 H11A 120.3 . . ?
C10 C11 H11A 120.3 . . ?
C11 C12 C13 120.4(7) . . ?
C11 C12 H12A 119.8 . . ?
C13 C12 H12A 119.8 . . ?
C14 C13 C18 119.9(7) . . ?
C14 C13 C12 124.3(7) . . ?
C18 C13 C12 115.8(7) . . ?
C15 C14 C13 118.8(7) . . ?
C15 C14 H14A 120.6 . . ?
C13 C14 H14A 120.6 . . ?
C14 C15 C16 122.8(8) . . ?
C14 C15 H15A 118.6 . . ?
C16 C15 H15A 118.6 . . ?
C17 C16 C15 120.6(7) . . ?
C17 C16 H16A 119.7 . . ?
C15 C16 H16A 119.7 . . ?
O2 C17 C16 124.3(6) . . ?
O2 C17 C18 117.7(5) . . ?
C16 C17 C18 117.9(6) . . ?
N2 C18 C13 123.1(6) . . ?
N2 C18 C17 117.0(5) . . ?
C13 C18 C17 119.9(6) . . ?
N3 C19 C20 124.8(8) . . ?
N3 C19 H19A 117.6 . . ?
C20 C19 H19A 117.6 . . ?
C21 C20 C19 117.8(8) . . ?
C21 C20 H20A 121.1 . . ?
C19 C20 H20A 121.1 . . ?
C20 C21 C22 121.5(8) . . ?
C20 C21 H21A 119.2 . . ?
C22 C21 H21A 119.2 . . ?
C23 C22 C21 124.1(7) . . ?
C23 C22 C27 119.7(7) . . ?
C21 C22 C27 116.3(8) . . ?
C24 C23 C22 119.9(7) . . ?
C24 C23 H23A 120.0 . . ?
C22 C23 H23A 120.0 . . ?
C23 C24 C25 122.1(7) . . ?
C23 C24 H24A 118.9 . . ?
C25 C24 H24A 118.9 . . ?
C26 C25 C24 119.9(7) . . ?
C26 C25 H25A 120.1 . . ?
C24 C25 H25A 120.1 . . ?
O3 C26 C25 122.8(6) . . ?
O3 C26 C27 118.6(5) . . ?
C25 C26 C27 118.6(5) . . ?
N3 C27 C26 117.9(5) . . ?
N3 C27 C22 122.3(6) . . ?
C26 C27 C22 119.7(6) . . ?
C33 C28 C29 121.9(10) . . ?
C33 C28 H28A 119.0 . . ?
C29 C28 H28A 119.0 . . ?
C30 C29 C28 117.7(12) . . ?
C30 C29 H29A 121.2 . . ?
C28 C29 H29A 121.2 . . ?
C31 C30 C29 121.6(11) . . ?
C31 C30 H30A 119.2 . . ?
C29 C30 H30A 119.2 . . ?
C30 C31 C32 119.6(11) . . ?
C30 C31 H31A 120.2 . . ?
C32 C31 H31A 120.2 . . ?
C33 C32 C31 121.0(10) . . ?
C33 C32 H32A 119.5 . . ?
C31 C32 H32A 119.5 . . ?
C28 C33 C32 118.0(8) . . ?
C28 C33 C34 119.0(7) . . ?
C32 C33 C34 123.0(8) . . ?
O4 C34 C35 124.2(6) . . ?
O4 C34 C33 116.0(6) . . ?
C35 C34 C33 119.8(6) . . ?
C34 C35 C36 125.4(6) . . ?
C34 C35 H35A 117.3 . . ?
C36 C35 H35A 117.3 . . ?
O5 C36 C35 124.1(6) . . ?
O5 C36 C37 115.8(6) . . ?
C35 C36 C37 120.1(6) . . ?
C42 C37 C38 117.2(7) . . ?
C42 C37 C36 119.3(6) . . ?
C38 C37 C36 123.5(7) . . ?
C39 C38 C37 121.5(9) . . ?
C39 C38 H38A 119.2 . . ?
C37 C38 H38A 119.2 . . ?
C40 C39 C38 120.1(9) . . ?
C40 C39 H39A 119.9 . . ?
C38 C39 H39A 119.9 . . ?
C39 C40 C41 120.3(9) . . ?
C39 C40 H40A 119.9 . . ?
C41 C40 H40A 119.9 . . ?
C40 C41 C42 120.1(9) . . ?
C40 C41 H41A 119.9 . . ?
C42 C41 H41A 119.9 . . ?
C37 C42 C41 120.8(7) . . ?
C37 C42 H42A 119.6 . . ?
C41 C42 H42A 119.6 . . ?
C48 C43 C44 121.2(6) . . ?
C48 C43 H43A 119.4 . . ?
C44 C43 H43A 119.4 . . ?
C45 C44 C43 120.1(7) . . ?
C45 C44 H44A 119.9 . . ?
C43 C44 H44A 119.9 . . ?
C44 C45 C46 119.2(7) . . ?
C44 C45 H45A 120.4 . . ?
C46 C45 H45A 120.4 . . ?
C47 C46 C45 120.9(7) . . ?
C47 C46 H46A 119.6 . . ?
C45 C46 H46A 119.6 . . ?
C46 C47 C48 121.4(7) . . ?
C46 C47 H47A 119.3 . . ?
C48 C47 H47A 119.3 . . ?
C43 C48 C47 117.2(6) . . ?
C43 C48 C49 120.8(5) . . ?
C47 C48 C49 121.9(6) . . ?
O7 C49 C50 124.7(5) . . ?
O7 C49 C48 115.3(5) . . ?
C50 C49 C48 120.0(5) . . ?
C49 C50 C51 123.7(5) . . ?
C49 C50 H50A 118.1 . . ?
C51 C50 H50A 118.1 . . ?
O6 C51 C50 123.7(5) . . ?
O6 C51 C52 116.2(5) . . ?
C50 C51 C52 120.1(5) . . ?
C57 C52 C53 119.0(6) . . ?
C57 C52 C51 119.7(5) . . ?
C53 C52 C51 121.3(5) . . ?
C54 C53 C52 119.1(7) . . ?
C54 C53 H53A 120.4 . . ?
C52 C53 H53A 120.4 . . ?
C55 C54 C53 121.0(7) . . ?
C55 C54 H54A 119.5 . . ?
C53 C54 H54A 119.5 . . ?
C54 C55 C56 119.6(7) . . ?
C54 C55 H55A 120.2 . . ?
C56 C55 H55A 120.2 . . ?
C55 C56 C57 120.0(7) . . ?
C55 C56 H56A 120.0 . . ?
C57 C56 H56A 120.0 . . ?
C52 C57 C56 121.2(6) . . ?
C52 C57 H57A 119.4 . . ?
C56 C57 H57A 119.4 . . ?
C17 O2 Dy1 116.8(3) . 2_556 ?
C17 O2 Dy2 128.8(4) . . ?
Dy1 O2 Dy2 109.25(13) 2_556 . ?
C8 O1 Dy2 120.7(3) . . ?
C8 O1 Dy1 141.3(3) . . ?
Dy2 O1 Dy1 97.08(12) . . ?
Cl2 C58 Cl1 113.2(8) . . ?
Cl2 C58 H58A 108.9 . . ?
Cl1 C58 H58A 108.9 . . ?
Cl2 C58 H58B 108.9 . . ?
Cl1 C58 H58B 108.9 . . ?
H58A C58 H58B 107.7 . . ?
Cl6 C60 Cl5 109.6(16) . . ?
Cl6 C60 H60A 109.7 . . ?
Cl5 C60 H60A 109.7 . . ?
Cl6 C60 H60B 109.7 . . ?
Cl5 C60 H60B 109.7 . . ?
H60A C60 H60B 108.2 . . ?
Cl3 C59 Cl4 103.7(9) . . ?
Cl3 C59 H59A 111.0 . . ?
Cl4 C59 H59A 111.0 . . ?
Cl3 C59 H59B 111.0 . . ?
Cl4 C59 H59B 111.0 . . ?
H59A C59 H59B 109.0 . . ?
C61 Cl8 C61 35.3(19) 2_677 . ?
C61 Cl8 Cl7 53.5(8) 2_677 2_677 ?
C61 Cl8 Cl7 48.6(7) . 2_677 ?
Cl7 C61 Cl8 92.7(12) . . ?
Cl7 C61 H61A 113.2 . . ?
Cl8 C61 H61A 113.2 . . ?
Cl7 C61 H61B 113.2 . . ?
Cl8 C61 H61B 113.2 . . ?
H61A C61 H61B 110.5 . . ?
C61 Cl7 C61 39(2) 2_677 . ?
C61 Cl7 Cl8 61.8(9) 2_677 2_677 ?
C61 Cl7 Cl8 54.7(8) . 2_677 ?

_diffrn_measured_fraction_theta_max 0.851
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.394
_refine_diff_density_min         -0.847
_refine_diff_density_rms         0.121
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_000
_database_code_depnum_ccdc_archive 'CCDC 1400356'
_audit_update_record             
;
2015-05-12 deposited with the CCDC.
2015-12-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C75 H43 Cl3 Dy4 F24 N6 O16'
_chemical_formula_weight         2496.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           ?
_symmetry_space_group_name_H-M   'P 21/n'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.1652(2)
_cell_length_b                   24.7100(3)
_cell_length_c                   13.1956(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 101.6242(18)
_cell_angle_gamma                90.00
_cell_volume                     4204.65(13)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.972
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2388
_exptl_absorpt_coefficient_mu    3.729
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  0.5226
_exptl_absorpt_correction_T_max  0.5868
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            38878
_diffrn_reflns_av_R_equivalents  0.0284
_diffrn_reflns_av_sigmaI/netI    0.0277
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.93
_diffrn_reflns_theta_max         29.20
_reflns_number_total             10078
_reflns_number_gt                8403
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0286P)²+2.1418P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10078
_refine_ls_number_parameters     707
_refine_ls_number_restraints     170
_refine_ls_R_factor_all          0.0366
_refine_ls_R_factor_gt           0.0259
_refine_ls_wR_factor_ref         0.0624
_refine_ls_wR_factor_gt          0.0577
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.093
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.075619(12) 0.027640(5) 0.902810(12) 0.03323(5) Uani 1 1 d . . .
Dy2 Dy 0.021389(11) 0.103885(5) 1.137850(12) 0.03345(5) Uani 1 1 d . . .
C27 C 0.3015(3) 0.05135(14) 1.0526(3) 0.0441(8) Uani 1 1 d . . .
O3 O 0.13850(18) 0.09548(8) 1.02351(19) 0.0418(5) Uani 1 1 d . . .
N3 N 0.2500(2) 0.00617(11) 1.0108(2) 0.0398(6) Uani 1 1 d . . .
C20 C 0.4048(3) -0.04464(17) 1.0687(4) 0.0658(12) Uani 1 1 d . . .
H20 H 0.4367 -0.0784 1.0777 0.079 Uiso 1 1 calc R . .
C19 C 0.3018(3) -0.03990(15) 1.0180(3) 0.0521(9) Uani 1 1 d . . .
H19 H 0.2678 -0.0706 0.9878 0.062 Uiso 1 1 calc R . .
C26 C 0.2419(3) 0.09967(13) 1.0508(3) 0.0449(8) Uani 1 1 d . . .
C22 C 0.4089(3) 0.05123(17) 1.0958(3) 0.0566(10) Uani 1 1 d . . .
O8 O -0.04725(18) 0.04930(8) 0.99968(17) 0.0311(5) Uani 1 1 d . . .
O1 O 0.07747(18) 0.01696(8) 1.18533(18) 0.0415(5) Uani 1 1 d . . .
O2 O 0.11306(18) -0.05149(8) 0.81833(18) 0.0411(5) Uani 1 1 d . . .
O4 O -0.13174(18) 0.15087(9) 1.05608(19) 0.0448(6) Uani 1 1 d . . .
O5 O 0.06383(18) 0.19562(9) 1.1285(2) 0.0459(6) Uani 1 1 d . . .
O7 O 0.1930(2) 0.06851(10) 0.8144(2) 0.0587(7) Uani 1 1 d . . .
O6 O -0.0027(2) 0.10625(9) 0.8190(2) 0.0544(7) Uani 1 1 d . . .
N1 N 0.1861(2) 0.10347(11) 1.2690(2) 0.0475(7) Uani 1 1 d . . .
N2 N -0.0498(2) 0.14282(11) 1.2861(2) 0.0459(7) Uani 1 1 d . . .
C29 C 0.0123(3) 0.23807(12) 1.1113(3) 0.0414(8) Uani 1 1 d . . .
C8 C 0.1717(3) 0.00785(14) 1.2429(3) 0.0431(8) Uani 1 1 d . . .
C9 C 0.2299(3) 0.05347(14) 1.2890(3) 0.0460(8) Uani 1 1 d . . .
C17 C -0.1704(3) 0.06987(14) 1.2464(3) 0.0439(8) Uani 1 1 d . . .
C18 C -0.1380(3) 0.11823(15) 1.3027(3) 0.0466(8) Uani 1 1 d . . .
C13 C -0.1955(4) 0.13889(19) 1.3738(3) 0.0677(12) Uani 1 1 d . . .
C4 C 0.3300(3) 0.04629(18) 1.3520(3) 0.0613(11) Uani 1 1 d . . .
C31 C -0.1570(3) 0.19924(13) 1.0548(3) 0.0453(8) Uani 1 1 d . . .
C25 C 0.2938(3) 0.14692(16) 1.0782(4) 0.0662(12) Uani 1 1 d . . .
H25 H 0.2575 0.1794 1.0731 0.079 Uiso 1 1 calc R . .
C30 C -0.0926(3) 0.24337(13) 1.0808(3) 0.0469(9) Uani 1 1 d . . .
H30 H -0.1216 0.2778 1.0775 0.056 Uiso 1 1 calc R . .
C7 C 0.2164(3) -0.04203(16) 1.2603(3) 0.0596(11) Uani 1 1 d . . .
H7 H 0.1802 -0.0723 1.2305 0.072 Uiso 1 1 calc R . .
C23 C 0.4579(4) 0.10083(19) 1.1248(4) 0.0783(15) Uani 1 1 d . . .
H23 H 0.5289 0.1020 1.1512 0.094 Uiso 1 1 calc R . .
C24 C 0.4019(4) 0.1468(2) 1.1142(4) 0.0824(16) Uani 1 1 d . . .
H24 H 0.4357 0.1796 1.1313 0.099 Uiso 1 1 calc R . .
C34 C 0.0336(4) 0.14811(15) 0.7890(3) 0.0640(12) Uani 1 1 d . . .
C1 C 0.2408(3) 0.14587(16) 1.3091(3) 0.0628(11) Uani 1 1 d . . .
H1 H 0.2121 0.1800 1.2940 0.075 Uiso 1 1 calc R . .
C3 C 0.3825(4) 0.0936(2) 1.3932(4) 0.0764(14) Uani 1 1 d . . .
H3 H 0.4482 0.0910 1.4350 0.092 Uiso 1 1 calc R . .
C10 C -0.0194(4) 0.18690(17) 1.3400(3) 0.0656(12) Uani 1 1 d . . .
H10 H 0.0409 0.2038 1.3298 0.079 Uiso 1 1 calc R . .
C21 C 0.4576(3) 0.00054(19) 1.1044(4) 0.0686(12) Uani 1 1 d . . .
H21 H 0.5275 -0.0020 1.1353 0.082 Uiso 1 1 calc R . .
C36 C 0.2033(4) 0.11528(18) 0.7833(4) 0.0722(13) Uani 1 1 d . . .
C28 C 0.0768(4) 0.28979(16) 1.1283(4) 0.0644(12) Uani 1 1 d . . .
C5 C 0.3710(4) -0.0057(2) 1.3665(4) 0.0827(15) Uani 1 1 d . . .
H5 H 0.4368 -0.0110 1.4069 0.099 Uiso 1 1 calc R . .
C6 C 0.3147(4) -0.04879(19) 1.3214(4) 0.0802(15) Uani 1 1 d . . .
H6 H 0.3427 -0.0834 1.3318 0.096 Uiso 1 1 calc R . .
C2 C 0.3386(4) 0.1426(2) 1.3725(4) 0.0750(13) Uani 1 1 d . . .
H2 H 0.3731 0.1737 1.4002 0.090 Uiso 1 1 calc R . .
C12 C -0.1584(5) 0.1862(2) 1.4269(4) 0.0917(17) Uani 1 1 d . . .
H12 H -0.1945 0.2014 1.4737 0.110 Uiso 1 1 calc R . .
C14 C -0.2850(4) 0.1112(2) 1.3871(4) 0.0901(17) Uani 1 1 d . . .
H14 H -0.3240 0.1243 1.4332 0.108 Uiso 1 1 calc R . .
C32 C -0.2739(4) 0.20958(18) 1.0223(5) 0.0742(14) Uani 1 1 d . . .
C11 C -0.0713(5) 0.2097(2) 1.4108(4) 0.0893(17) Uani 1 1 d . . .
H11 H -0.0461 0.2409 1.4467 0.107 Uiso 1 1 calc R . .
C15 C -0.3142(4) 0.0655(2) 1.3332(4) 0.0875(17) Uani 1 1 d . . .
H15 H -0.3733 0.0473 1.3432 0.105 Uiso 1 1 calc R . .
C35 C 0.1315(4) 0.15613(18) 0.7716(5) 0.0871(17) Uani 1 1 d . . .
H35 H 0.1498 0.1902 0.7513 0.105 Uiso 1 1 calc R . .
C33 C -0.0418(6) 0.1963(2) 0.7712(7) 0.0944(18) Uani 1 1 d . . .
F1 F -0.3145(9) 0.2144(10) 1.1068(11) 0.146(6) Uani 0.50 1 d PU . .
F1' F -0.3248(9) 0.1786(7) 1.069(2) 0.142(6) Uani 0.50 1 d PU . .
F2 F -0.2940(11) 0.2531(5) 0.9649(15) 0.125(6) Uani 0.50 1 d PU . .
F2' F -0.3022(10) 0.2577(5) 1.0319(18) 0.129(7) Uani 0.50 1 d PU . .
F3 F -0.3211(10) 0.1726(4) 0.9660(17) 0.118(7) Uani 0.50 1 d PU . .
F3' F -0.3079(15) 0.1941(11) 0.9274(14) 0.185(9) Uani 0.50 1 d PU . .
F4' F 0.0367(12) 0.3313(5) 1.0772(14) 0.113(7) Uani 0.50 1 d PU . .
F4 F 0.1224(17) 0.2956(7) 1.0495(14) 0.156(7) Uani 0.50 1 d PU . .
F5' F 0.1657(9) 0.2849(4) 1.108(2) 0.124(6) Uani 0.50 1 d PU . .
F5 F 0.1472(13) 0.2880(5) 1.2069(15) 0.124(6) Uani 0.50 1 d PU . .
F6' F 0.0899(18) 0.3043(7) 1.2256(10) 0.145(7) Uani 0.50 1 d PU . .
F6 F 0.0241(12) 0.3330(5) 1.1326(17) 0.124(7) Uani 0.50 1 d PU . .
F7' F 0.3760(9) 0.0935(8) 0.791(2) 0.161(9) Uani 0.50 1 d PU . .
F7 F 0.339(2) 0.0868(8) 0.704(2) 0.185(8) Uani 0.50 1 d PU . .
F8' F 0.3384(15) 0.1767(7) 0.7754(15) 0.141(7) Uani 0.50 1 d PU . .
F8 F 0.3829(12) 0.1301(11) 0.8479(15) 0.172(6) Uani 0.50 1 d PU . .
F9' F 0.2953(11) 0.1268(11) 0.6498(11) 0.162(6) Uani 0.50 1 d PU . .
F9 F 0.3186(18) 0.1687(9) 0.711(3) 0.207(13) Uani 0.50 1 d PU . .
F10 F -0.059(2) 0.2129(9) 0.8478(12) 0.180(9) Uani 0.50 1 d PU . .
F10' F -0.1243(10) 0.1904(5) 0.8145(16) 0.117(5) Uani 0.50 1 d PU . .
F11' F 0.0035(10) 0.2435(4) 0.816(2) 0.152(5) Uani 0.50 1 d PU . .
F11 F -0.0123(15) 0.2311(7) 0.709(2) 0.164(8) Uani 0.50 1 d PU . .
F12' F -0.0749(17) 0.2088(9) 0.6808(8) 0.139(6) Uani 0.50 1 d PU . .
F12 F -0.1286(12) 0.1764(5) 0.705(2) 0.174(6) Uani 0.50 1 d PU . .
C37 C 0.3093(6) 0.1267(3) 0.7562(9) 0.115(3) Uani 1 1 d . . .
C16 C -0.2580(3) 0.04486(17) 1.2627(3) 0.0620(11) Uani 1 1 d . . .
H16 H -0.2808 0.0135 1.2262 0.074 Uiso 1 1 calc R . .
H8 H -0.096(3) 0.0586(14) 0.972(3) 0.040(11) Uiso 1 1 d . . .
Cl2 Cl 0.1062(8) 0.0549(4) 1.5030(7) 0.280(4) Uani 0.50 1 d PDU . .
C38 C 0.0315(16) -0.0005(8) 1.5262(16) 0.184(8) Uani 0.50 1 d PDU . .
H38A H 0.0720 -0.0176 1.5883 0.221 Uiso 0.50 1 calc PR . .
Cl1 Cl 0.0083(9) -0.0525(4) 1.4339(8) 0.278(4) Uani 0.50 1 d PDU . .
Cl3 Cl -0.0702(8) 0.0183(4) 1.5584(8) 0.270(4) Uani 0.50 1 d PU . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O8 2.317(2) . ?
Dy1 O7 2.345(2) . ?
Dy1 O3 2.345(2) . ?
Dy1 O2 2.352(2) . ?
Dy1 O6 2.366(2) . ?
Dy1 O8 2.367(2) 3_557 ?
Dy1 O1 2.384(2) 3_557 ?
Dy1 N3 2.503(3) . ?
Dy1 Dy2 3.49357(19) 3_557 ?
Dy1 Dy1 3.8036(3) 3_557 ?
Dy1 Dy2 3.8172(2) . ?
Dy2 O8 2.301(2) . ?
Dy2 O1 2.316(2) . ?
Dy2 O5 2.344(2) . ?
Dy2 O2 2.357(2) 3_557 ?
Dy2 O3 2.374(2) . ?
Dy2 O4 2.387(2) . ?
Dy2 N1 2.486(3) . ?
Dy2 N2 2.523(3) . ?
Dy2 Dy1 3.49357(19) 3_557 ?
C27 N3 1.364(4) . ?
C27 C22 1.414(5) . ?
C27 C26 1.427(5) . ?
O3 C26 1.340(4) . ?
N3 C19 1.321(4) . ?
C20 C21 1.349(6) . ?
C20 C19 1.390(5) . ?
C20 H20 0.9300 . ?
C19 H19 0.9300 . ?
C26 C25 1.365(5) . ?
C22 C21 1.401(6) . ?
C22 C23 1.402(6) . ?
O8 Dy1 2.367(2) 3_557 ?
O8 H8 0.71(4) . ?
O1 C8 1.337(4) . ?
O1 Dy1 2.384(2) 3_557 ?
O2 C17 1.329(4) 3_557 ?
O2 Dy2 2.357(2) 3_557 ?
O4 C31 1.240(4) . ?
O5 C29 1.245(4) . ?
O7 C36 1.243(4) . ?
O6 C34 1.238(4) . ?
N1 C1 1.320(5) . ?
N1 C9 1.367(4) . ?
N2 C10 1.319(5) . ?
N2 C18 1.367(5) . ?
C29 C30 1.364(5) . ?
C29 C28 1.526(5) . ?
C8 C7 1.365(5) . ?
C8 C9 1.428(5) . ?
C9 C4 1.421(5) . ?
C17 O2 1.329(4) 3_557 ?
C17 C16 1.363(5) . ?
C17 C18 1.426(5) . ?
C18 C13 1.415(5) . ?
C13 C12 1.398(6) . ?
C13 C14 1.403(6) . ?
C4 C5 1.391(6) . ?
C4 C3 1.411(6) . ?
C31 C30 1.382(5) . ?
C31 C32 1.534(6) . ?
C25 C24 1.405(6) . ?
C25 H25 0.9300 . ?
C30 H30 0.9300 . ?
C7 C6 1.391(6) . ?
C7 H7 0.9300 . ?
C23 C24 1.347(7) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C34 C35 1.368(6) . ?
C34 C33 1.537(7) . ?
C1 C2 1.390(6) . ?
C1 H1 0.9300 . ?
C3 C2 1.344(6) . ?
C3 H3 0.9300 . ?
C10 C11 1.383(6) . ?
C10 H10 0.9300 . ?
C21 H21 0.9300 . ?
C36 C35 1.370(6) . ?
C36 C37 1.535(7) . ?
C28 F5 1.245(13) . ?
C28 F5' 1.260(12) . ?
C28 F6 1.282(12) . ?
C28 F4' 1.282(11) . ?
C28 F4 1.310(14) . ?
C28 F6' 1.310(14) . ?
C5 C6 1.364(7) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C2 H2 0.9300 . ?
C12 C11 1.341(7) . ?
C12 H12 0.9300 . ?
C14 C15 1.348(7) . ?
C14 H14 0.9300 . ?
C32 F1' 1.254(13) . ?
C32 F3 1.260(13) . ?
C32 F2' 1.261(11) . ?
C32 F3' 1.299(17) . ?
C32 F2 1.310(12) . ?
C32 F1 1.336(13) . ?
C11 H11 0.9300 . ?
C15 C16 1.397(6) . ?
C15 H15 0.9300 . ?
C35 H35 0.9300 . ?
C33 F10 1.157(13) . ?
C33 F12' 1.225(12) . ?
C33 F11 1.305(12) . ?
C33 F10' 1.333(14) . ?
C33 F12 1.381(15) . ?
C33 F11' 1.387(13) . ?
F1 F1' 1.014(16) . ?
F1 F2' 1.49(2) . ?
F1' F3 1.37(2) . ?
F2 F2' 0.920(17) . ?
F2 F3' 1.54(2) . ?
F3 F3' 0.78(2) . ?
F4' F6 0.784(19) . ?
F4' F4 1.53(2) . ?
F4 F5' 0.897(19) . ?
F5' F5 1.38(2) . ?
F5 F6' 0.931(18) . ?
F6' F6 1.53(2) . ?
F7' F7 1.16(2) . ?
F7' F8 1.17(2) . ?
F7' C37 1.222(14) . ?
F7 F9' 1.29(2) . ?
F7 C37 1.307(17) . ?
F8' F9 0.87(4) . ?
F8' C37 1.303(17) . ?
F8' F8 1.54(3) . ?
F8 C37 1.391(18) . ?
F9' F9 1.31(3) . ?
F9' C37 1.379(17) . ?
F9 C37 1.219(15) . ?
F10 F10' 1.04(3) . ?
F10 F11' 1.25(2) . ?
F10' F12 1.47(2) . ?
F11' F11 1.423(19) . ?
F11 F12' 0.997(17) . ?
F12' F12 1.158(18) . ?
C16 H16 0.9300 . ?
Cl2 C38 1.747(17) . ?
Cl2 Cl1 1.864(13) 3_558 ?
Cl2 Cl3 1.998(13) 3_558 ?
Cl2 C38 2.23(2) 3_558 ?
C38 Cl3 1.55(2) . ?
C38 Cl1 1.755(17) . ?
C38 H38A 0.9800 . ?
Cl1 Cl3 1.165(12) 3_558 ?
Cl1 C38 1.54(2) 3_558 ?
Cl1 Cl2 1.864(13) 3_558 ?
Cl3 Cl1 1.165(12) 3_558 ?
Cl3 C38 1.39(2) 3_558 ?
Cl3 Cl2 1.998(13) 3_558 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Dy1 O7 141.12(8) . . ?
O8 Dy1 O3 69.54(8) . . ?
O7 Dy1 O3 81.50(9) . . ?
O8 Dy1 O2 133.61(7) . . ?
O7 Dy1 O2 84.27(8) . . ?
O3 Dy1 O2 146.84(8) . . ?
O8 Dy1 O6 77.36(9) . . ?
O7 Dy1 O6 71.51(9) . . ?
O3 Dy1 O6 77.97(9) . . ?
O2 Dy1 O6 125.05(9) . . ?
O8 Dy1 O8 71.43(9) . 3_557 ?
O7 Dy1 O8 143.96(8) . 3_557 ?
O3 Dy1 O8 106.12(8) . 3_557 ?
O2 Dy1 O8 70.19(8) . 3_557 ?
O6 Dy1 O8 144.25(9) . 3_557 ?
O8 Dy1 O1 76.14(8) . 3_557 ?
O7 Dy1 O1 122.24(9) . 3_557 ?
O3 Dy1 O1 144.06(8) . 3_557 ?
O2 Dy1 O1 67.78(8) . 3_557 ?
O6 Dy1 O1 84.58(8) . 3_557 ?
O8 Dy1 O1 71.55(8) 3_557 3_557 ?
O8 Dy1 N3 113.38(9) . . ?
O7 Dy1 N3 75.75(9) . . ?
O3 Dy1 N3 66.86(8) . . ?
O2 Dy1 N3 80.67(8) . . ?
O6 Dy1 N3 134.71(9) . . ?
O8 Dy1 N3 75.36(8) 3_557 . ?
O1 Dy1 N3 140.18(8) 3_557 . ?
O8 Dy1 Dy2 91.45(5) . 3_557 ?
O7 Dy1 Dy2 125.56(7) . 3_557 ?
O3 Dy1 Dy2 146.85(6) . 3_557 ?
O2 Dy1 Dy2 42.17(5) . 3_557 ?
O6 Dy1 Dy2 125.48(7) . 3_557 ?
O8 Dy1 Dy2 40.84(5) 3_557 3_557 ?
O1 Dy1 Dy2 41.25(5) 3_557 3_557 ?
N3 Dy1 Dy2 98.93(6) . 3_557 ?
O8 Dy1 Dy1 36.15(5) . 3_557 ?
O7 Dy1 Dy1 167.81(8) . 3_557 ?
O3 Dy1 Dy1 87.70(6) . 3_557 ?
O2 Dy1 Dy1 102.08(5) . 3_557 ?
O6 Dy1 Dy1 111.82(7) . 3_557 ?
O8 Dy1 Dy1 35.28(5) 3_557 3_557 ?
O1 Dy1 Dy1 69.94(6) 3_557 3_557 ?
N3 Dy1 Dy1 94.85(6) . 3_557 ?
Dy2 Dy1 Dy1 62.912(4) 3_557 3_557 ?
O8 Dy1 Dy2 34.13(6) . . ?
O7 Dy1 Dy2 116.21(7) . . ?
O3 Dy1 Dy2 36.26(5) . . ?
O2 Dy1 Dy2 152.49(6) . . ?
O6 Dy1 Dy2 80.74(7) . . ?
O8 Dy1 Dy2 83.04(5) 3_557 . ?
O1 Dy1 Dy2 110.27(6) 3_557 . ?
N3 Dy1 Dy2 86.68(6) . . ?
Dy2 Dy1 Dy2 117.484(4) 3_557 . ?
Dy1 Dy1 Dy2 54.571(4) 3_557 . ?
O8 Dy2 O1 73.96(8) . . ?
O8 Dy2 O5 125.79(8) . . ?
O1 Dy2 O5 147.65(8) . . ?
O8 Dy2 O2 71.22(8) . 3_557 ?
O1 Dy2 O2 68.81(8) . 3_557 ?
O5 Dy2 O2 137.98(8) . 3_557 ?
O8 Dy2 O3 69.32(8) . . ?
O1 Dy2 O3 83.01(8) . . ?
O5 Dy2 O3 81.88(8) . . ?
O2 Dy2 O3 136.38(7) 3_557 . ?
O8 Dy2 O4 76.47(8) . . ?
O1 Dy2 O4 140.11(8) . . ?
O5 Dy2 O4 72.21(8) . . ?
O2 Dy2 O4 76.73(8) 3_557 . ?
O3 Dy2 O4 110.66(8) . . ?
O8 Dy2 N1 134.19(9) . . ?
O1 Dy2 N1 67.81(9) . . ?
O5 Dy2 N1 81.78(9) . . ?
O2 Dy2 N1 114.81(9) 3_557 . ?
O3 Dy2 N1 81.66(10) . . ?
O4 Dy2 N1 148.76(8) . . ?
O8 Dy2 N2 133.61(9) . . ?
O1 Dy2 N2 106.96(9) . . ?
O5 Dy2 N2 78.57(9) . . ?
O2 Dy2 N2 66.72(8) 3_557 . ?
O3 Dy2 N2 156.38(9) . . ?
O4 Dy2 N2 75.72(9) . . ?
N1 Dy2 N2 82.53(10) . . ?
O8 Dy2 Dy1 42.27(5) . 3_557 ?
O1 Dy2 Dy1 42.74(6) . 3_557 ?
O5 Dy2 Dy1 167.22(6) . 3_557 ?
O2 Dy2 Dy1 42.04(5) 3_557 3_557 ?
O3 Dy2 Dy1 94.89(5) . 3_557 ?
O4 Dy2 Dy1 97.68(5) . 3_557 ?
N1 Dy2 Dy1 110.09(7) . 3_557 ?
N2 Dy2 Dy1 107.00(7) . 3_557 ?
O8 Dy2 Dy1 34.40(5) . . ?
O1 Dy2 Dy1 70.15(6) . . ?
O5 Dy2 Dy1 110.42(6) . . ?
O2 Dy2 Dy1 101.59(5) 3_557 . ?
O3 Dy2 Dy1 35.76(5) . . ?
O4 Dy2 Dy1 98.74(6) . . ?
N1 Dy2 Dy1 106.48(7) . . ?
N2 Dy2 Dy1 167.80(7) . . ?
Dy1 Dy2 Dy1 62.517(4) 3_557 . ?
N3 C27 C22 122.5(3) . . ?
N3 C27 C26 116.8(3) . . ?
C22 C27 C26 120.7(3) . . ?
C26 O3 Dy1 116.00(19) . . ?
C26 O3 Dy2 125.2(2) . . ?
Dy1 O3 Dy2 107.97(8) . . ?
C19 N3 C27 117.9(3) . . ?
C19 N3 Dy1 128.7(2) . . ?
C27 N3 Dy1 112.4(2) . . ?
C21 C20 C19 118.9(4) . . ?
C21 C20 H20 120.6 . . ?
C19 C20 H20 120.6 . . ?
N3 C19 C20 123.1(4) . . ?
N3 C19 H19 118.4 . . ?
C20 C19 H19 118.4 . . ?
O3 C26 C25 124.4(3) . . ?
O3 C26 C27 117.7(3) . . ?
C25 C26 C27 117.8(4) . . ?
C21 C22 C23 125.5(4) . . ?
C21 C22 C27 116.0(4) . . ?
C23 C22 C27 118.4(4) . . ?
Dy2 O8 Dy1 111.47(9) . . ?
Dy2 O8 Dy1 96.88(8) . 3_557 ?
Dy1 O8 Dy1 108.57(9) . 3_557 ?
Dy2 O8 H8 113(3) . . ?
Dy1 O8 H8 117(3) . . ?
Dy1 O8 H8 108(3) 3_557 . ?
C8 O1 Dy2 121.2(2) . . ?
C8 O1 Dy1 142.7(2) . 3_557 ?
Dy2 O1 Dy1 96.01(8) . 3_557 ?
C17 O2 Dy1 142.1(2) 3_557 . ?
C17 O2 Dy2 121.5(2) 3_557 3_557 ?
Dy1 O2 Dy2 95.79(8) . 3_557 ?
C31 O4 Dy2 132.4(2) . . ?
C29 O5 Dy2 134.2(2) . . ?
C36 O7 Dy1 133.8(3) . . ?
C34 O6 Dy1 132.5(3) . . ?
C1 N1 C9 117.7(3) . . ?
C1 N1 Dy2 127.2(3) . . ?
C9 N1 Dy2 114.4(2) . . ?
C10 N2 C18 117.1(3) . . ?
C10 N2 Dy2 127.9(3) . . ?
C18 N2 Dy2 114.5(2) . . ?
O5 C29 C30 128.1(3) . . ?
O5 C29 C28 114.4(3) . . ?
C30 C29 C28 117.6(3) . . ?
O1 C8 C7 124.5(3) . . ?
O1 C8 C9 117.8(3) . . ?
C7 C8 C9 117.7(3) . . ?
N1 C9 C4 122.1(3) . . ?
N1 C9 C8 117.5(3) . . ?
C4 C9 C8 120.4(3) . . ?
O2 C17 C16 123.7(3) 3_557 . ?
O2 C17 C18 118.2(3) 3_557 . ?
C16 C17 C18 118.1(3) . . ?
N2 C18 C13 122.1(3) . . ?
N2 C18 C17 117.6(3) . . ?
C13 C18 C17 120.2(4) . . ?
C12 C13 C14 124.2(4) . . ?
C12 C13 C18 117.0(4) . . ?
C14 C13 C18 118.8(4) . . ?
C5 C4 C3 124.4(4) . . ?
C5 C4 C9 119.0(4) . . ?
C3 C4 C9 116.5(4) . . ?
O4 C31 C30 127.5(3) . . ?
O4 C31 C32 114.5(3) . . ?
C30 C31 C32 118.0(3) . . ?
C26 C25 C24 120.5(4) . . ?
C26 C25 H25 119.8 . . ?
C24 C25 H25 119.8 . . ?
C29 C30 C31 122.1(3) . . ?
C29 C30 H30 119.0 . . ?
C31 C30 H30 119.0 . . ?
C8 C7 C6 121.7(4) . . ?
C8 C7 H7 119.2 . . ?
C6 C7 H7 119.2 . . ?
C24 C23 C22 119.8(4) . . ?
C24 C23 H23 120.1 . . ?
C22 C23 H23 120.1 . . ?
C23 C24 C25 122.1(4) . . ?
C23 C24 H24 118.9 . . ?
C25 C24 H24 118.9 . . ?
O6 C34 C35 127.8(4) . . ?
O6 C34 C33 114.6(4) . . ?
C35 C34 C33 117.6(4) . . ?
N1 C1 C2 124.0(4) . . ?
N1 C1 H1 118.0 . . ?
C2 C1 H1 118.0 . . ?
C2 C3 C4 120.7(4) . . ?
C2 C3 H3 119.7 . . ?
C4 C3 H3 119.7 . . ?
N2 C10 C11 124.4(4) . . ?
N2 C10 H10 117.8 . . ?
C11 C10 H10 117.8 . . ?
C20 C21 C22 121.0(4) . . ?
C20 C21 H21 119.5 . . ?
C22 C21 H21 119.5 . . ?
O7 C36 C35 127.1(4) . . ?
O7 C36 C37 114.4(4) . . ?
C35 C36 C37 118.5(4) . . ?
F5 C28 F5' 67.0(9) . . ?
F5 C28 F6 108.2(10) . . ?
F5' C28 F6 128.6(9) . . ?
F5 C28 F4' 128.7(9) . . ?
F5' C28 F4' 105.3(10) . . ?
F6 C28 F4' 35.6(9) . . ?
F5 C28 F4 106.4(10) . . ?
F5' C28 F4 40.8(9) . . ?
F6 C28 F4 106.5(10) . . ?
F4' C28 F4 72.5(10) . . ?
F5 C28 F6' 42.6(8) . . ?
F5' C28 F6' 107.1(10) . . ?
F6 C28 F6' 72.2(10) . . ?
F4' C28 F6' 104.8(10) . . ?
F4 C28 F6' 139.2(10) . . ?
F5 C28 C29 113.1(7) . . ?
F5' C28 C29 113.7(6) . . ?
F6 C28 C29 114.5(8) . . ?
F4' C28 C29 115.8(7) . . ?
F4 C28 C29 107.8(8) . . ?
F6' C28 C29 109.5(7) . . ?
C6 C5 C4 119.9(4) . . ?
C6 C5 H5 120.0 . . ?
C4 C5 H5 120.0 . . ?
C5 C6 C7 121.3(4) . . ?
C5 C6 H6 119.3 . . ?
C7 C6 H6 119.3 . . ?
C3 C2 C1 118.9(4) . . ?
C3 C2 H2 120.5 . . ?
C1 C2 H2 120.5 . . ?
C11 C12 C13 120.5(4) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 H12 119.8 . . ?
C15 C14 C13 120.0(4) . . ?
C15 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
F1' C32 F3 66.1(10) . . ?
F1' C32 F2' 109.2(11) . . ?
F3 C32 F2' 128.6(9) . . ?
F1' C32 F3' 100.1(11) . . ?
F3 C32 F3' 35.5(10) . . ?
F2' C32 F3' 108.8(11) . . ?
F1' C32 F2 135.8(9) . . ?
F3 C32 F2 103.7(10) . . ?
F2' C32 F2 41.9(8) . . ?
F3' C32 F2 72.2(11) . . ?
F1' C32 F1 46.0(8) . . ?
F3 C32 F1 108.9(11) . . ?
F2' C32 F1 69.8(9) . . ?
F3' C32 F1 135.5(11) . . ?
F2 C32 F1 109.9(9) . . ?
F1' C32 C31 111.5(7) . . ?
F3 C32 C31 113.1(7) . . ?
F2' C32 C31 115.4(8) . . ?
F3' C32 C31 110.6(10) . . ?
F2 C32 C31 111.9(8) . . ?
F1 C32 C31 109.2(7) . . ?
C12 C11 C10 119.0(4) . . ?
C12 C11 H11 120.5 . . ?
C10 C11 H11 120.5 . . ?
C14 C15 C16 121.6(4) . . ?
C14 C15 H15 119.2 . . ?
C16 C15 H15 119.2 . . ?
C34 C35 C36 121.8(4) . . ?
C34 C35 H35 119.1 . . ?
C36 C35 H35 119.1 . . ?
F10 C33 F12' 131.8(10) . . ?
F10 C33 F11 117.2(14) . . ?
F12' C33 F11 46.3(9) . . ?
F10 C33 F10' 48.7(14) . . ?
F12' C33 F10' 106.5(12) . . ?
F11 C33 F10' 135.6(8) . . ?
F10 C33 F12 113.0(14) . . ?
F12' C33 F12 52.4(9) . . ?
F11 C33 F12 98.6(12) . . ?
F10' C33 F12 65.7(10) . . ?
F10 C33 F11' 58.3(13) . . ?
F12' C33 F11' 103.8(10) . . ?
F11 C33 F11' 63.7(9) . . ?
F10' C33 F11' 103.1(11) . . ?
F12 C33 F11' 143.0(8) . . ?
F10 C33 C34 112.2(9) . . ?
F12' C33 C34 115.9(8) . . ?
F11 C33 C34 110.1(8) . . ?
F10' C33 C34 114.0(6) . . ?
F12 C33 C34 104.3(7) . . ?
F11' C33 C34 112.2(7) . . ?
F1' F1 C32 62.8(11) . . ?
F1' F1 F2' 108.6(18) . . ?
C32 F1 F2' 52.7(7) . . ?
F1 F1' C32 71.3(12) . . ?
F1 F1' F3 123.9(18) . . ?
C32 F1' F3 57.2(9) . . ?
F2' F2 C32 66.2(12) . . ?
F2' F2 F3' 113(2) . . ?
C32 F2 F3' 53.6(8) . . ?
F2 F2' C32 72.0(12) . . ?
F2 F2' F1 126.7(18) . . ?
C32 F2' F1 57.4(7) . . ?
F3' F3 C32 75.0(17) . . ?
F3' F3 F1' 129(2) . . ?
C32 F3 F1' 56.8(8) . . ?
F3 F3' C32 69.5(19) . . ?
F3 F3' F2 118(3) . . ?
C32 F3' F2 54.3(8) . . ?
F6 F4' C28 72.2(14) . . ?
F6 F4' F4 124(2) . . ?
C28 F4' F4 54.6(7) . . ?
F5' F4 C28 66.6(14) . . ?
F5' F4 F4' 110(2) . . ?
C28 F4 F4' 52.9(7) . . ?
F4 F5' C28 72.6(14) . . ?
F4 F5' F5 126(2) . . ?
C28 F5' F5 56.0(8) . . ?
F6' F5 C28 72.5(14) . . ?
F6' F5 F5' 126(2) . . ?
C28 F5 F5' 57.0(8) . . ?
F5 F6' C28 64.9(14) . . ?
F5 F6' F6 110.3(19) . . ?
C28 F6' F6 53.0(7) . . ?
F4' F6 C28 72.2(15) . . ?
F4' F6 F6' 122(2) . . ?
C28 F6 F6' 54.8(8) . . ?
F7 F7' F8 135(2) . . ?
F7 F7' C37 66.5(12) . . ?
F8 F7' C37 71.2(14) . . ?
F7' F7 F9' 119(2) . . ?
F7' F7 C37 59.0(12) . . ?
F9' F7 C37 64.2(12) . . ?
F9 F8' C37 64.8(18) . . ?
F9 F8' F8 116(3) . . ?
C37 F8' F8 58.0(10) . . ?
F7' F8 C37 56.2(12) . . ?
F7' F8 F8' 102(2) . . ?
C37 F8 F8' 52.6(10) . . ?
F7 F9' F9 104.1(18) . . ?
F7 F9' C37 58.6(10) . . ?
F9 F9' C37 53.9(10) . . ?
F8' F9 C37 75.3(19) . . ?
F8' F9 F9' 141(3) . . ?
C37 F9 F9' 66.1(12) . . ?
F10' F10 C33 74.5(16) . . ?
F10' F10 F11' 136(2) . . ?
C33 F10 F11' 70.1(12) . . ?
F10 F10' C33 56.7(10) . . ?
F10 F10' F12 114.0(17) . . ?
C33 F10' F12 58.7(8) . . ?
F10 F11' C33 51.7(8) . . ?
F10 F11' F11 103.3(13) . . ?
C33 F11' F11 55.4(7) . . ?
F12' F11 C33 62.6(10) . . ?
F12' F11 F11' 115.4(17) . . ?
C33 F11 F11' 60.9(9) . . ?
F11 F12' F12 141.8(18) . . ?
F11 F12' C33 71.1(13) . . ?
F12 F12' C33 70.8(9) . . ?
F12' F12 C33 56.9(9) . . ?
F12' F12 F10' 101.8(15) . . ?
C33 F12 F10' 55.6(9) . . ?
F9 C37 F7' 128.4(12) . . ?
F9 C37 F8' 40.0(16) . . ?
F7' C37 F8' 113.8(17) . . ?
F9 C37 F7 108.2(16) . . ?
F7' C37 F7 54.5(11) . . ?
F8' C37 F7 135.2(12) . . ?
F9 C37 F9' 60.1(13) . . ?
F7' C37 F9' 108.7(17) . . ?
F8' C37 F9' 99.8(11) . . ?
F7 C37 F9' 57.2(12) . . ?
F9 C37 F8 104.9(17) . . ?
F7' C37 F8 52.6(12) . . ?
F8' C37 F8 69.5(14) . . ?
F7 C37 F8 105.7(14) . . ?
F9' C37 F8 144.3(10) . . ?
F9 C37 C36 117.3(11) . . ?
F7' C37 C36 114.1(8) . . ?
F8' C37 C36 112.0(11) . . ?
F7 C37 C36 111.6(10) . . ?
F9' C37 C36 107.2(9) . . ?
F8 C37 C36 108.4(9) . . ?
C17 C16 C15 121.2(4) . . ?
C17 C16 H16 119.4 . . ?
C15 C16 H16 119.4 . . ?
C38 Cl2 Cl1 50.4(8) . 3_558 ?
C38 Cl2 Cl3 42.9(7) . 3_558 ?
Cl1 Cl2 Cl3 90.3(5) 3_558 3_558 ?
C38 Cl2 C38 24.5(13) . 3_558 ?
Cl1 Cl2 C38 49.8(6) 3_558 3_558 ?
Cl3 Cl2 C38 42.7(6) 3_558 3_558 ?
Cl3 C38 Cl2 111.2(13) . . ?
Cl3 C38 Cl1 111.7(11) . . ?
Cl2 C38 Cl1 118.5(13) . . ?
Cl3 C38 H38A 104.7 . . ?
Cl2 C38 H38A 104.7 . . ?
Cl1 C38 H38A 104.7 . . ?
Cl3 Cl1 C38 68.5(10) 3_558 3_558 ?
Cl3 Cl1 C38 52.2(8) 3_558 . ?
C38 Cl1 C38 33.3(15) 3_558 . ?
Cl3 Cl1 Cl2 126.8(9) 3_558 3_558 ?
C38 Cl1 Cl2 60.9(8) 3_558 3_558 ?
C38 Cl1 Cl2 75.9(9) . 3_558 ?
Cl1 Cl3 C38 86.3(9) 3_558 3_558 ?
Cl1 Cl3 C38 67.3(9) 3_558 . ?
C38 Cl3 C38 37.8(15) 3_558 . ?
Cl1 Cl3 Cl2 142.8(8) 3_558 3_558 ?
C38 Cl3 Cl2 58.9(8) 3_558 3_558 ?
C38 Cl3 Cl2 76.5(8) . 3_558 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O7 Dy1 Dy2 O8 145.09(12) . . . . ?
O3 Dy1 Dy2 O8 163.34(14) . . . . ?
O2 Dy1 Dy2 O8 -80.14(16) . . . . ?
O6 Dy1 Dy2 O8 81.09(12) . . . . ?
O8 Dy1 Dy2 O8 -66.92(14) 3_557 . . . ?
O1 Dy1 Dy2 O8 0.43(11) 3_557 . . . ?
N3 Dy1 Dy2 O8 -142.57(11) . . . . ?
Dy2 Dy1 Dy2 O8 -44.22(10) 3_557 . . . ?
Dy1 Dy1 Dy2 O8 -44.22(10) 3_557 . . . ?
O8 Dy1 Dy2 O1 90.41(12) . . . . ?
O7 Dy1 Dy2 O1 -124.50(10) . . . . ?
O3 Dy1 Dy2 O1 -106.25(12) . . . . ?
O2 Dy1 Dy2 O1 10.27(14) . . . . ?
O6 Dy1 Dy2 O1 171.50(9) . . . . ?
O8 Dy1 Dy2 O1 23.48(8) 3_557 . . . ?
O1 Dy1 Dy2 O1 90.84(8) 3_557 . . . ?
N3 Dy1 Dy2 O1 -52.16(9) . . . . ?
Dy2 Dy1 Dy2 O1 46.18(6) 3_557 . . . ?
Dy1 Dy1 Dy2 O1 46.18(6) 3_557 . . . ?
O8 Dy1 Dy2 O5 -124.11(12) . . . . ?
O7 Dy1 Dy2 O5 20.98(10) . . . . ?
O3 Dy1 Dy2 O5 39.23(12) . . . . ?
O2 Dy1 Dy2 O5 155.75(14) . . . . ?
O6 Dy1 Dy2 O5 -43.02(9) . . . . ?
O8 Dy1 Dy2 O5 168.96(9) 3_557 . . . ?
O1 Dy1 Dy2 O5 -123.68(8) 3_557 . . . ?
N3 Dy1 Dy2 O5 93.32(9) . . . . ?
Dy2 Dy1 Dy2 O5 -168.33(6) 3_557 . . . ?
Dy1 Dy1 Dy2 O5 -168.33(6) 3_557 . . . ?
O8 Dy1 Dy2 O2 28.21(11) . . . 3_557 ?
O7 Dy1 Dy2 O2 173.30(10) . . . 3_557 ?
O3 Dy1 Dy2 O2 -168.45(12) . . . 3_557 ?
O2 Dy1 Dy2 O2 -51.93(17) . . . 3_557 ?
O6 Dy1 Dy2 O2 109.30(9) . . . 3_557 ?
O8 Dy1 Dy2 O2 -38.72(8) 3_557 . . 3_557 ?
O1 Dy1 Dy2 O2 28.64(8) 3_557 . . 3_557 ?
N3 Dy1 Dy2 O2 -114.36(8) . . . 3_557 ?
Dy2 Dy1 Dy2 O2 -16.02(6) 3_557 . . 3_557 ?
Dy1 Dy1 Dy2 O2 -16.02(6) 3_557 . . 3_557 ?
O8 Dy1 Dy2 O3 -163.34(14) . . . . ?
O7 Dy1 Dy2 O3 -18.25(13) . . . . ?
O2 Dy1 Dy2 O3 116.53(16) . . . . ?
O6 Dy1 Dy2 O3 -82.25(12) . . . . ?
O8 Dy1 Dy2 O3 129.74(12) 3_557 . . . ?
O1 Dy1 Dy2 O3 -162.91(11) 3_557 . . . ?
N3 Dy1 Dy2 O3 54.09(12) . . . . ?
Dy2 Dy1 Dy2 O3 152.44(10) 3_557 . . . ?
Dy1 Dy1 Dy2 O3 152.44(10) 3_557 . . . ?
O8 Dy1 Dy2 O4 -49.94(11) . . . . ?
O7 Dy1 Dy2 O4 95.16(10) . . . . ?
O3 Dy1 Dy2 O4 113.40(11) . . . . ?
O2 Dy1 Dy2 O4 -130.07(14) . . . . ?
O6 Dy1 Dy2 O4 31.16(9) . . . . ?
O8 Dy1 Dy2 O4 -116.86(8) 3_557 . . . ?
O1 Dy1 Dy2 O4 -49.50(8) 3_557 . . . ?
N3 Dy1 Dy2 O4 167.49(8) . . . . ?
Dy2 Dy1 Dy2 O4 -94.16(6) 3_557 . . . ?
Dy1 Dy1 Dy2 O4 -94.16(6) 3_557 . . . ?
O8 Dy1 Dy2 N1 148.70(12) . . . . ?
O7 Dy1 Dy2 N1 -66.21(11) . . . . ?
O3 Dy1 Dy2 N1 -47.96(12) . . . . ?
O2 Dy1 Dy2 N1 68.56(14) . . . . ?
O6 Dy1 Dy2 N1 -130.21(10) . . . . ?
O8 Dy1 Dy2 N1 81.77(9) 3_557 . . . ?
O1 Dy1 Dy2 N1 149.13(9) 3_557 . . . ?
N3 Dy1 Dy2 N1 6.13(9) . . . . ?
Dy2 Dy1 Dy2 N1 104.47(7) 3_557 . . . ?
Dy1 Dy1 Dy2 N1 104.47(7) 3_557 . . . ?
O8 Dy1 Dy2 N2 12.0(3) . . . . ?
O7 Dy1 Dy2 N2 157.1(3) . . . . ?
O3 Dy1 Dy2 N2 175.4(3) . . . . ?
O2 Dy1 Dy2 N2 -68.1(3) . . . . ?
O6 Dy1 Dy2 N2 93.1(3) . . . . ?
O8 Dy1 Dy2 N2 -54.9(3) 3_557 . . . ?
O1 Dy1 Dy2 N2 12.5(3) 3_557 . . . ?
N3 Dy1 Dy2 N2 -130.5(3) . . . . ?
Dy2 Dy1 Dy2 N2 -32.2(3) 3_557 . . . ?
Dy1 Dy1 Dy2 N2 -32.2(3) 3_557 . . . ?
O8 Dy1 Dy2 Dy1 44.22(10) . . . 3_557 ?
O7 Dy1 Dy2 Dy1 -170.68(8) . . . 3_557 ?
O3 Dy1 Dy2 Dy1 -152.44(10) . . . 3_557 ?
O2 Dy1 Dy2 Dy1 -35.91(12) . . . 3_557 ?
O6 Dy1 Dy2 Dy1 125.32(7) . . . 3_557 ?
O8 Dy1 Dy2 Dy1 -22.70(6) 3_557 . . 3_557 ?
O1 Dy1 Dy2 Dy1 44.66(5) 3_557 . . 3_557 ?
N3 Dy1 Dy2 Dy1 -98.35(6) . . . 3_557 ?
Dy2 Dy1 Dy2 Dy1 0.0 3_557 . . 3_557 ?
O8 Dy1 O3 C26 156.3(3) . . . . ?
O7 Dy1 O3 C26 -50.1(2) . . . . ?
O2 Dy1 O3 C26 15.5(3) . . . . ?
O6 Dy1 O3 C26 -122.9(2) . . . . ?
O8 Dy1 O3 C26 93.8(2) 3_557 . . . ?
O1 Dy1 O3 C26 174.4(2) 3_557 . . . ?
N3 Dy1 O3 C26 28.0(2) . . . . ?
Dy2 Dy1 O3 C26 97.7(2) 3_557 . . . ?
Dy1 Dy1 O3 C26 124.2(2) 3_557 . . . ?
Dy2 Dy1 O3 C26 146.4(3) . . . . ?
O8 Dy1 O3 Dy2 9.89(8) . . . . ?
O7 Dy1 O3 Dy2 163.50(11) . . . . ?
O2 Dy1 O3 Dy2 -130.92(12) . . . . ?
O6 Dy1 O3 Dy2 90.72(11) . . . . ?
O8 Dy1 O3 Dy2 -52.62(11) 3_557 . . . ?
O1 Dy1 O3 Dy2 28.02(18) 3_557 . . . ?
N3 Dy1 O3 Dy2 -118.44(12) . . . . ?
Dy2 Dy1 O3 Dy2 -48.66(15) 3_557 . . . ?
Dy1 Dy1 O3 Dy2 -22.17(8) 3_557 . . . ?
O8 Dy2 O3 C26 -152.5(3) . . . . ?
O1 Dy2 O3 C26 -77.0(2) . . . . ?
O5 Dy2 O3 C26 74.3(2) . . . . ?
O2 Dy2 O3 C26 -126.0(2) 3_557 . . . ?
O4 Dy2 O3 C26 141.7(2) . . . . ?
N1 Dy2 O3 C26 -8.5(2) . . . . ?
N2 Dy2 O3 C26 39.9(4) . . . . ?
Dy1 Dy2 O3 C26 -118.2(2) 3_557 . . . ?
Dy1 Dy2 O3 C26 -142.5(3) . . . . ?
O8 Dy2 O3 Dy1 -9.97(8) . . . . ?
O1 Dy2 O3 Dy1 65.47(9) . . . . ?
O5 Dy2 O3 Dy1 -143.23(11) . . . . ?
O2 Dy2 O3 Dy1 16.51(17) 3_557 . . . ?
O4 Dy2 O3 Dy1 -75.79(10) . . . . ?
N1 Dy2 O3 Dy1 133.96(11) . . . . ?
N2 Dy2 O3 Dy1 -177.57(18) . . . . ?
Dy1 Dy2 O3 Dy1 24.33(9) 3_557 . . . ?
C22 C27 N3 C19 4.9(5) . . . . ?
C26 C27 N3 C19 -175.3(3) . . . . ?
C22 C27 N3 Dy1 -164.9(3) . . . . ?
C26 C27 N3 Dy1 14.9(4) . . . . ?
O8 Dy1 N3 C19 116.4(3) . . . . ?
O7 Dy1 N3 C19 -103.6(3) . . . . ?
O3 Dy1 N3 C19 169.7(3) . . . . ?
O2 Dy1 N3 C19 -17.2(3) . . . . ?
O6 Dy1 N3 C19 -148.3(3) . . . . ?
O8 Dy1 N3 C19 54.6(3) 3_557 . . . ?
O1 Dy1 N3 C19 20.1(4) 3_557 . . . ?
Dy2 Dy1 N3 C19 20.9(3) 3_557 . . . ?
Dy1 Dy1 N3 C19 84.2(3) 3_557 . . . ?
Dy2 Dy1 N3 C19 138.3(3) . . . . ?
O8 Dy1 N3 C27 -75.1(2) . . . . ?
O7 Dy1 N3 C27 64.8(2) . . . . ?
O3 Dy1 N3 C27 -21.9(2) . . . . ?
O2 Dy1 N3 C27 151.2(2) . . . . ?
O6 Dy1 N3 C27 20.2(3) . . . . ?
O8 Dy1 N3 C27 -137.0(2) 3_557 . . . ?
O1 Dy1 N3 C27 -171.5(2) 3_557 . . . ?
Dy2 Dy1 N3 C27 -170.6(2) 3_557 . . . ?
Dy1 Dy1 N3 C27 -107.3(2) 3_557 . . . ?
Dy2 Dy1 N3 C27 -53.3(2) . . . . ?
C27 N3 C19 C20 2.0(6) . . . . ?
Dy1 N3 C19 C20 169.9(3) . . . . ?
C21 C20 C19 N3 -6.1(7) . . . . ?
Dy1 O3 C26 C25 148.6(3) . . . . ?
Dy2 O3 C26 C25 -71.5(5) . . . . ?
Dy1 O3 C26 C27 -32.2(4) . . . . ?
Dy2 O3 C26 C27 107.7(3) . . . . ?
N3 C27 C26 O3 10.1(5) . . . . ?
C22 C27 C26 O3 -170.1(3) . . . . ?
N3 C27 C26 C25 -170.7(4) . . . . ?
C22 C27 C26 C25 9.1(6) . . . . ?
N3 C27 C22 C21 -7.3(6) . . . . ?
C26 C27 C22 C21 172.9(4) . . . . ?
N3 C27 C22 C23 171.9(4) . . . . ?
C26 C27 C22 C23 -7.9(6) . . . . ?
O1 Dy2 O8 Dy1 -78.15(10) . . . . ?
O5 Dy2 O8 Dy1 73.05(13) . . . . ?
O2 Dy2 O8 Dy1 -150.72(11) 3_557 . . . ?
O3 Dy2 O8 Dy1 10.32(8) . . . . ?
O4 Dy2 O8 Dy1 128.92(11) . . . . ?
N1 Dy2 O8 Dy1 -44.01(16) . . . . ?
N2 Dy2 O8 Dy1 -176.51(10) . . . . ?
Dy1 Dy2 O8 Dy1 -113.10(12) 3_557 . . . ?
O1 Dy2 O8 Dy1 34.94(8) . . . 3_557 ?
O5 Dy2 O8 Dy1 -173.86(7) . . . 3_557 ?
O2 Dy2 O8 Dy1 -37.63(8) 3_557 . . 3_557 ?
O3 Dy2 O8 Dy1 123.41(10) . . . 3_557 ?
O4 Dy2 O8 Dy1 -117.99(9) . . . 3_557 ?
N1 Dy2 O8 Dy1 69.08(14) . . . 3_557 ?
N2 Dy2 O8 Dy1 -63.41(14) . . . 3_557 ?
Dy1 Dy2 O8 Dy1 113.10(12) . . . 3_557 ?
O7 Dy1 O8 Dy2 -54.87(18) . . . . ?
O3 Dy1 O8 Dy2 -10.43(9) . . . . ?
O2 Dy1 O8 Dy2 141.06(9) . . . . ?
O6 Dy1 O8 Dy2 -92.13(10) . . . . ?
O8 Dy1 O8 Dy2 105.55(13) 3_557 . . . ?
O1 Dy1 O8 Dy2 -179.58(11) 3_557 . . . ?
N3 Dy1 O8 Dy2 41.38(12) . . . . ?
Dy2 Dy1 O8 Dy2 141.76(8) 3_557 . . . ?
Dy1 Dy1 O8 Dy2 105.55(13) 3_557 . . . ?
O7 Dy1 O8 Dy1 -160.42(12) . . . 3_557 ?
O3 Dy1 O8 Dy1 -115.98(11) . . . 3_557 ?
O2 Dy1 O8 Dy1 35.51(16) . . . 3_557 ?
O6 Dy1 O8 Dy1 162.32(11) . . . 3_557 ?
O8 Dy1 O8 Dy1 0.0 3_557 . . 3_557 ?
O1 Dy1 O8 Dy1 74.87(9) 3_557 . . 3_557 ?
N3 Dy1 O8 Dy1 -64.17(11) . . . 3_557 ?
Dy2 Dy1 O8 Dy1 36.21(8) 3_557 . . 3_557 ?
Dy2 Dy1 O8 Dy1 -105.55(13) . . . 3_557 ?
O8 Dy2 O1 C8 144.1(3) . . . . ?
O5 Dy2 O1 C8 11.1(3) . . . . ?
O2 Dy2 O1 C8 -140.2(3) 3_557 . . . ?
O3 Dy2 O1 C8 73.7(2) . . . . ?
O4 Dy2 O1 C8 -172.2(2) . . . . ?
N1 Dy2 O1 C8 -10.1(2) . . . . ?
N2 Dy2 O1 C8 -84.4(3) . . . . ?
Dy1 Dy2 O1 C8 178.7(3) 3_557 . . . ?
Dy1 Dy2 O1 C8 108.1(2) . . . . ?
O8 Dy2 O1 Dy1 -34.59(8) . . . 3_557 ?
O5 Dy2 O1 Dy1 -167.68(12) . . . 3_557 ?
O2 Dy2 O1 Dy1 41.06(8) 3_557 . . 3_557 ?
O3 Dy2 O1 Dy1 -105.01(9) . . . 3_557 ?
O4 Dy2 O1 Dy1 9.04(16) . . . 3_557 ?
N1 Dy2 O1 Dy1 171.17(12) . . . 3_557 ?
N2 Dy2 O1 Dy1 96.91(10) . . . 3_557 ?
Dy1 Dy2 O1 Dy1 -70.59(6) . . . 3_557 ?
O8 Dy1 O2 C17 171.1(3) . . . 3_557 ?
O7 Dy1 O2 C17 1.1(4) . . . 3_557 ?
O3 Dy1 O2 C17 -63.8(4) . . . 3_557 ?
O6 Dy1 O2 C17 63.7(4) . . . 3_557 ?
O8 Dy1 O2 C17 -153.1(4) 3_557 . . 3_557 ?
O1 Dy1 O2 C17 129.4(4) 3_557 . . 3_557 ?
N3 Dy1 O2 C17 -75.4(4) . . . 3_557 ?
Dy2 Dy1 O2 C17 170.1(4) 3_557 . . 3_557 ?
Dy1 Dy1 O2 C17 -168.4(3) 3_557 . . 3_557 ?
Dy2 Dy1 O2 C17 -139.1(3) . . . 3_557 ?
O8 Dy1 O2 Dy2 1.05(15) . . . 3_557 ?
O7 Dy1 O2 Dy2 -168.98(10) . . . 3_557 ?
O3 Dy1 O2 Dy2 126.19(12) . . . 3_557 ?
O6 Dy1 O2 Dy2 -106.35(10) . . . 3_557 ?
O8 Dy1 O2 Dy2 36.87(8) 3_557 . . 3_557 ?
O1 Dy1 O2 Dy2 -40.65(8) 3_557 . . 3_557 ?
N3 Dy1 O2 Dy2 114.57(9) . . . 3_557 ?
Dy1 Dy1 O2 Dy2 21.56(8) 3_557 . . 3_557 ?
Dy2 Dy1 O2 Dy2 50.82(16) . . . 3_557 ?
O8 Dy2 O4 C31 -155.0(3) . . . . ?
O1 Dy2 O4 C31 162.0(3) . . . . ?
O5 Dy2 O4 C31 -19.9(3) . . . . ?
O2 Dy2 O4 C31 131.5(3) 3_557 . . . ?
O3 Dy2 O4 C31 -93.6(3) . . . . ?
N1 Dy2 O4 C31 15.2(4) . . . . ?
N2 Dy2 O4 C31 62.5(3) . . . . ?
Dy1 Dy2 O4 C31 168.2(3) 3_557 . . . ?
Dy1 Dy2 O4 C31 -128.6(3) . . . . ?
O8 Dy2 O5 C29 72.9(3) . . . . ?
O1 Dy2 O5 C29 -167.0(3) . . . . ?
O2 Dy2 O5 C29 -29.0(4) 3_557 . . . ?
O3 Dy2 O5 C29 130.1(3) . . . . ?
O4 Dy2 O5 C29 15.2(3) . . . . ?
N1 Dy2 O5 C29 -147.3(3) . . . . ?
N2 Dy2 O5 C29 -63.3(3) . . . . ?
Dy1 Dy2 O5 C29 53.9(5) 3_557 . . . ?
Dy1 Dy2 O5 C29 108.1(3) . . . . ?
O8 Dy1 O7 C36 -15.8(5) . . . . ?
O3 Dy1 O7 C36 -57.3(4) . . . . ?
O2 Dy1 O7 C36 152.7(5) . . . . ?
O6 Dy1 O7 C36 22.7(4) . . . . ?
O8 Dy1 O7 C36 -163.1(4) 3_557 . . . ?
O1 Dy1 O7 C36 93.5(4) 3_557 . . . ?
N3 Dy1 O7 C36 -125.5(5) . . . . ?
Dy2 Dy1 O7 C36 143.6(4) 3_557 . . . ?
Dy1 Dy1 O7 C36 -85.2(6) 3_557 . . . ?
Dy2 Dy1 O7 C36 -46.6(5) . . . . ?
O8 Dy1 O6 C34 132.8(4) . . . . ?
O7 Dy1 O6 C34 -23.6(4) . . . . ?
O3 Dy1 O6 C34 61.4(4) . . . . ?
O2 Dy1 O6 C34 -92.3(4) . . . . ?
O8 Dy1 O6 C34 162.3(3) 3_557 . . . ?
O1 Dy1 O6 C34 -150.2(4) 3_557 . . . ?
N3 Dy1 O6 C34 22.3(4) . . . . ?
Dy2 Dy1 O6 C34 -144.6(4) 3_557 . . . ?
Dy1 Dy1 O6 C34 143.9(4) 3_557 . . . ?
Dy2 Dy1 O6 C34 98.2(4) . . . . ?
O8 Dy2 N1 C1 143.1(3) . . . . ?
O1 Dy2 N1 C1 178.8(4) . . . . ?
O5 Dy2 N1 C1 10.0(3) . . . . ?
O2 Dy2 N1 C1 -129.5(3) 3_557 . . . ?
O3 Dy2 N1 C1 92.9(4) . . . . ?
O4 Dy2 N1 C1 -23.5(5) . . . . ?
N2 Dy2 N1 C1 -69.4(4) . . . . ?
Dy1 Dy2 N1 C1 -174.9(3) 3_557 . . . ?
Dy1 Dy2 N1 C1 119.0(3) . . . . ?
O8 Dy2 N1 C9 -27.0(3) . . . . ?
O1 Dy2 N1 C9 8.6(2) . . . . ?
O5 Dy2 N1 C9 -160.1(3) . . . . ?
O2 Dy2 N1 C9 60.4(3) 3_557 . . . ?
O3 Dy2 N1 C9 -77.2(3) . . . . ?
O4 Dy2 N1 C9 166.3(2) . . . . ?
N2 Dy2 N1 C9 120.4(3) . . . . ?
Dy1 Dy2 N1 C9 15.0(3) 3_557 . . . ?
Dy1 Dy2 N1 C9 -51.2(3) . . . . ?
O8 Dy2 N2 C10 -154.6(3) . . . . ?
O1 Dy2 N2 C10 121.6(3) . . . . ?
O5 Dy2 N2 C10 -25.5(3) . . . . ?
O2 Dy2 N2 C10 178.7(4) 3_557 . . . ?
O3 Dy2 N2 C10 9.3(5) . . . . ?
O4 Dy2 N2 C10 -99.8(4) . . . . ?
N1 Dy2 N2 C10 57.6(3) . . . . ?
Dy1 Dy2 N2 C10 166.4(3) 3_557 . . . ?
Dy1 Dy2 N2 C10 -164.0(3) . . . . ?
O8 Dy2 N2 C18 16.9(3) . . . . ?
O1 Dy2 N2 C18 -66.9(3) . . . . ?
O5 Dy2 N2 C18 146.0(3) . . . . ?
O2 Dy2 N2 C18 -9.8(2) 3_557 . . . ?
O3 Dy2 N2 C18 -179.2(2) . . . . ?
O4 Dy2 N2 C18 71.7(2) . . . . ?
N1 Dy2 N2 C18 -130.9(3) . . . . ?
Dy1 Dy2 N2 C18 -22.1(3) 3_557 . . . ?
Dy1 Dy2 N2 C18 7.5(5) . . . . ?
Dy2 O5 C29 C30 -7.4(6) . . . . ?
Dy2 O5 C29 C28 171.9(3) . . . . ?
Dy2 O1 C8 C7 -169.2(3) . . . . ?
Dy1 O1 C8 C7 8.7(6) 3_557 . . . ?
Dy2 O1 C8 C9 10.5(4) . . . . ?
Dy1 O1 C8 C9 -171.6(2) 3_557 . . . ?
C1 N1 C9 C4 1.1(6) . . . . ?
Dy2 N1 C9 C4 172.3(3) . . . . ?
C1 N1 C9 C8 -178.2(4) . . . . ?
Dy2 N1 C9 C8 -7.1(4) . . . . ?
O1 C8 C9 N1 -1.5(5) . . . . ?
C7 C8 C9 N1 178.2(4) . . . . ?
O1 C8 C9 C4 179.2(3) . . . . ?
C7 C8 C9 C4 -1.1(6) . . . . ?
C10 N2 C18 C13 0.4(6) . . . . ?
Dy2 N2 C18 C13 -172.1(3) . . . . ?
C10 N2 C18 C17 -178.7(4) . . . . ?
Dy2 N2 C18 C17 8.8(4) . . . . ?
O2 C17 C18 N2 0.2(5) 3_557 . . . ?
C16 C17 C18 N2 179.7(4) . . . . ?
O2 C17 C18 C13 -178.9(4) 3_557 . . . ?
C16 C17 C18 C13 0.6(6) . . . . ?
N2 C18 C13 C12 0.3(7) . . . . ?
C17 C18 C13 C12 179.3(4) . . . . ?
N2 C18 C13 C14 -179.6(5) . . . . ?
C17 C18 C13 C14 -0.5(7) . . . . ?
N1 C9 C4 C5 -178.1(4) . . . . ?
C8 C9 C4 C5 1.3(6) . . . . ?
N1 C9 C4 C3 -0.2(6) . . . . ?
C8 C9 C4 C3 179.1(4) . . . . ?
Dy2 O4 C31 C30 17.4(6) . . . . ?
Dy2 O4 C31 C32 -161.2(3) . . . . ?
O3 C26 C25 C24 174.6(4) . . . . ?
C27 C26 C25 C24 -4.6(7) . . . . ?
O5 C29 C30 C31 -6.4(6) . . . . ?
C28 C29 C30 C31 174.3(4) . . . . ?
O4 C31 C30 C29 1.0(6) . . . . ?
C32 C31 C30 C29 179.5(4) . . . . ?
O1 C8 C7 C6 -179.7(4) . . . . ?
C9 C8 C7 C6 0.6(6) . . . . ?
C21 C22 C23 C24 -178.8(5) . . . . ?
C27 C22 C23 C24 2.1(7) . . . . ?
C22 C23 C24 C25 2.4(9) . . . . ?
C26 C25 C24 C23 -1.1(8) . . . . ?
Dy1 O6 C34 C35 18.5(8) . . . . ?
Dy1 O6 C34 C33 -160.7(4) . . . . ?
C9 N1 C1 C2 -1.9(7) . . . . ?
Dy2 N1 C1 C2 -171.7(4) . . . . ?
C5 C4 C3 C2 177.7(5) . . . . ?
C9 C4 C3 C2 -0.1(7) . . . . ?
C18 N2 C10 C11 -0.5(7) . . . . ?
Dy2 N2 C10 C11 170.8(4) . . . . ?
C19 C20 C21 C22 3.2(7) . . . . ?
C23 C22 C21 C20 -176.1(5) . . . . ?
C27 C22 C21 C20 3.1(7) . . . . ?
Dy1 O7 C36 C35 -16.3(9) . . . . ?
Dy1 O7 C36 C37 163.6(6) . . . . ?
O5 C29 C28 F5 -41.3(14) . . . . ?
C30 C29 C28 F5 138.1(13) . . . . ?
O5 C29 C28 F5' 32.7(14) . . . . ?
C30 C29 C28 F5' -148.0(13) . . . . ?
O5 C29 C28 F6 -165.8(11) . . . . ?
C30 C29 C28 F6 13.6(12) . . . . ?
O5 C29 C28 F4' 154.8(11) . . . . ?
C30 C29 C28 F4' -25.9(12) . . . . ?
O5 C29 C28 F4 76.0(13) . . . . ?
C30 C29 C28 F4 -104.6(13) . . . . ?
O5 C29 C28 F6' -87.0(13) . . . . ?
C30 C29 C28 F6' 92.3(13) . . . . ?
C3 C4 C5 C6 -178.5(5) . . . . ?
C9 C4 C5 C6 -0.8(8) . . . . ?
C4 C5 C6 C7 0.3(9) . . . . ?
C8 C7 C6 C5 -0.2(8) . . . . ?
C4 C3 C2 C1 -0.6(8) . . . . ?
N1 C1 C2 C3 1.6(8) . . . . ?
C14 C13 C12 C11 178.9(6) . . . . ?
C18 C13 C12 C11 -0.9(9) . . . . ?
C12 C13 C14 C15 -179.3(6) . . . . ?
C18 C13 C14 C15 0.5(9) . . . . ?
O4 C31 C32 F1' 46.7(16) . . . . ?
C30 C31 C32 F1' -132.0(15) . . . . ?
O4 C31 C32 F3 -25.5(13) . . . . ?
C30 C31 C32 F3 155.8(12) . . . . ?
O4 C31 C32 F2' 172.1(12) . . . . ?
C30 C31 C32 F2' -6.6(14) . . . . ?
O4 C31 C32 F3' -63.8(15) . . . . ?
C30 C31 C32 F3' 117.5(15) . . . . ?
O4 C31 C32 F2 -142.1(11) . . . . ?
C30 C31 C32 F2 39.1(12) . . . . ?
O4 C31 C32 F1 95.9(12) . . . . ?
C30 C31 C32 F1 -82.8(12) . . . . ?
C13 C12 C11 C10 0.8(10) . . . . ?
N2 C10 C11 C12 -0.1(9) . . . . ?
C13 C14 C15 C16 -0.6(10) . . . . ?
O6 C34 C35 C36 2.3(9) . . . . ?
C33 C34 C35 C36 -178.6(6) . . . . ?
O7 C36 C35 C34 -3.6(10) . . . . ?
C37 C36 C35 C34 176.5(7) . . . . ?
O6 C34 C33 F10 69(2) . . . . ?
C35 C34 C33 F10 -110(2) . . . . ?
O6 C34 C33 F12' -108.3(17) . . . . ?
C35 C34 C33 F12' 72.5(18) . . . . ?
O6 C34 C33 F11 -158.4(17) . . . . ?
C35 C34 C33 F11 22.3(19) . . . . ?
O6 C34 C33 F10' 15.9(15) . . . . ?
C35 C34 C33 F10' -163.3(13) . . . . ?
O6 C34 C33 F12 -53.5(14) . . . . ?
C35 C34 C33 F12 127.2(14) . . . . ?
O6 C34 C33 F11' 132.7(15) . . . . ?
C35 C34 C33 F11' -46.6(16) . . . . ?
F3 C32 F1 F1' 22.2(15) . . . . ?
F2' C32 F1 F1' 147.4(16) . . . . ?
F3' C32 F1 F1' 50.7(19) . . . . ?
F2 C32 F1 F1' 135.2(14) . . . . ?
C31 C32 F1 F1' -101.7(12) . . . . ?
F1' C32 F1 F2' -147.4(16) . . . . ?
F3 C32 F1 F2' -125.2(10) . . . . ?
F3' C32 F1 F2' -96.8(15) . . . . ?
F2 C32 F1 F2' -12.2(14) . . . . ?
C31 C32 F1 F2' 110.9(8) . . . . ?
F2' F1 F1' C32 26.9(11) . . . . ?
C32 F1 F1' F3 -23.4(13) . . . . ?
F2' F1 F1' F3 4(2) . . . . ?
F3 C32 F1' F1 -156.9(16) . . . . ?
F2' C32 F1' F1 -32.4(17) . . . . ?
F3' C32 F1' F1 -146.6(14) . . . . ?
F2 C32 F1' F1 -72(2) . . . . ?
C31 C32 F1' F1 96.4(12) . . . . ?
F2' C32 F1' F3 124.6(10) . . . . ?
F3' C32 F1' F3 10.4(13) . . . . ?
F2 C32 F1' F3 85.1(16) . . . . ?
F1 C32 F1' F3 156.9(16) . . . . ?
C31 C32 F1' F3 -106.7(9) . . . . ?
F1' C32 F2 F2' 64(3) . . . . ?
F3 C32 F2 F2' 133.6(18) . . . . ?
F3' C32 F2 F2' 150(2) . . . . ?
F1 C32 F2 F2' 17(2) . . . . ?
C31 C32 F2 F2' -104.2(17) . . . . ?
F1' C32 F2 F3' -86.2(18) . . . . ?
F3 C32 F2 F3' -16.6(16) . . . . ?
F2' C32 F2 F3' -150(2) . . . . ?
F1 C32 F2 F3' -132.8(12) . . . . ?
C31 C32 F2 F3' 105.6(11) . . . . ?
F3' F2 F2' C32 25.9(15) . . . . ?
C32 F2 F2' F1 -18.3(19) . . . . ?
F3' F2 F2' F1 8(3) . . . . ?
F1' C32 F2' F2 -138.4(18) . . . . ?
F3 C32 F2' F2 -64(2) . . . . ?
F3' C32 F2' F2 -30(2) . . . . ?
F1 C32 F2' F2 -163(2) . . . . ?
C31 C32 F2' F2 95.0(17) . . . . ?
F1' C32 F2' F1 24.2(13) . . . . ?
F3 C32 F2' F1 98.5(15) . . . . ?
F3' C32 F2' F1 132.6(12) . . . . ?
F2 C32 F2' F1 163(2) . . . . ?
C31 C32 F2' F1 -102.4(9) . . . . ?
F1' F1 F2' F2 -10(3) . . . . ?
C32 F1 F2' F2 21(2) . . . . ?
F1' F1 F2' C32 -30.3(12) . . . . ?
F1' C32 F3 F3' 162(2) . . . . ?
F2' C32 F3 F3' 66(3) . . . . ?
F2 C32 F3 F3' 28(2) . . . . ?
F1 C32 F3 F3' 145(2) . . . . ?
C31 C32 F3 F3' -94(2) . . . . ?
F2' C32 F3 F1' -96.2(14) . . . . ?
F3' C32 F3 F1' -162(2) . . . . ?
F2 C32 F3 F1' -134.3(10) . . . . ?
F1 C32 F3 F1' -17.3(11) . . . . ?
C31 C32 F3 F1' 104.3(9) . . . . ?
F1 F1' F3 F3' 4(4) . . . . ?
C32 F1' F3 F3' -22(3) . . . . ?
F1 F1' F3 C32 26.6(15) . . . . ?
F1' F3 F3' C32 19(2) . . . . ?
C32 F3 F3' F2 -25.9(18) . . . . ?
F1' F3 F3' F2 -7(4) . . . . ?
F1' C32 F3' F3 -16(2) . . . . ?
F2' C32 F3' F3 -131(2) . . . . ?
F2 C32 F3' F3 -151(2) . . . . ?
F1 C32 F3' F3 -51(3) . . . . ?
C31 C32 F3' F3 101(2) . . . . ?
F1' C32 F3' F2 135.0(9) . . . . ?
F3 C32 F3' F2 151(2) . . . . ?
F2' C32 F3' F2 20.5(15) . . . . ?
F1 C32 F3' F2 100.6(15) . . . . ?
C31 C32 F3' F2 -107.3(9) . . . . ?
F2' F2 F3' F3 1(4) . . . . ?
C32 F2 F3' F3 30(2) . . . . ?
F2' F2 F3' C32 -29.7(18) . . . . ?
F5 C28 F4' F6 -64(3) . . . . ?
F5' C28 F4' F6 -137(2) . . . . ?
F4 C28 F4' F6 -162(2) . . . . ?
F6' C28 F4' F6 -24(2) . . . . ?
C29 C28 F4' F6 97(2) . . . . ?
F5 C28 F4' F4 97.3(14) . . . . ?
F5' C28 F4' F4 24.7(12) . . . . ?
F6 C28 F4' F4 162(2) . . . . ?
F6' C28 F4' F4 137.5(10) . . . . ?
C29 C28 F4' F4 -101.7(9) . . . . ?
F5 C28 F4 F5' 15.6(17) . . . . ?
F6 C28 F4 F5' 130.8(16) . . . . ?
F4' C28 F4 F5' 141.9(18) . . . . ?
F6' C28 F4 F5' 49(2) . . . . ?
C29 C28 F4 F5' -105.9(14) . . . . ?
F5 C28 F4 F4' -126.2(9) . . . . ?
F5' C28 F4 F4' -141.9(18) . . . . ?
F6 C28 F4 F4' -11.1(14) . . . . ?
F6' C28 F4 F4' -92.6(16) . . . . ?
C29 C28 F4 F4' 112.2(8) . . . . ?
F6 F4' F4 F5' -16(4) . . . . ?
C28 F4' F4 F5' -37.0(15) . . . . ?
F6 F4' F4 C28 21(3) . . . . ?
F4' F4 F5' C28 31.5(11) . . . . ?
C28 F4 F5' F5 -16.7(17) . . . . ?
F4' F4 F5' F5 15(3) . . . . ?
F5 C28 F5' F4 -163.7(18) . . . . ?
F6 C28 F5' F4 -68(2) . . . . ?
F4' C28 F5' F4 -37.6(18) . . . . ?
F6' C28 F5' F4 -148.8(15) . . . . ?
C29 C28 F5' F4 90.1(15) . . . . ?
F6 C28 F5' F5 95.4(14) . . . . ?
F4' C28 F5' F5 126.1(9) . . . . ?
F4 C28 F5' F5 163.7(18) . . . . ?
F6' C28 F5' F5 14.9(12) . . . . ?
C29 C28 F5' F5 -106.2(8) . . . . ?
F5' C28 F5 F6' 158.7(18) . . . . ?
F6 C28 F5 F6' 33.7(18) . . . . ?
F4' C28 F5 F6' 67(2) . . . . ?
F4 C28 F5 F6' 147.7(15) . . . . ?
C29 C28 F5 F6' -94.2(15) . . . . ?
F6 C28 F5 F5' -125.0(9) . . . . ?
F4' C28 F5 F5' -91.5(13) . . . . ?
F4 C28 F5 F5' -11.0(12) . . . . ?
F6' C28 F5 F5' -158.7(18) . . . . ?
C29 C28 F5 F5' 107.1(7) . . . . ?
F4 F5' F5 F6' -6(3) . . . . ?
C28 F5' F5 F6' -25.1(19) . . . . ?
F4 F5' F5 C28 19(2) . . . . ?
F5' F5 F6' C28 22.0(16) . . . . ?
C28 F5 F6' F6 -28.2(13) . . . . ?
F5' F5 F6' F6 -6(3) . . . . ?
F5' C28 F6' F5 -20.4(17) . . . . ?
F6 C28 F6' F5 -146.4(18) . . . . ?
F4' C28 F6' F5 -131.9(15) . . . . ?
F4 C28 F6' F5 -52(2) . . . . ?
C29 C28 F6' F5 103.2(14) . . . . ?
F5 C28 F6' F6 146.4(18) . . . . ?
F5' C28 F6' F6 125.9(10) . . . . ?
F4' C28 F6' F6 14.5(14) . . . . ?
F4 C28 F6' F6 94.8(16) . . . . ?
C29 C28 F6' F6 -110.4(9) . . . . ?
F4 F4' F6 C28 -18(2) . . . . ?
C28 F4' F6 F6' 24(2) . . . . ?
F4 F4' F6 F6' 6(4) . . . . ?
F5 C28 F6 F4' 132(2) . . . . ?
F5' C28 F6 F4' 58(3) . . . . ?
F4 C28 F6 F4' 18(2) . . . . ?
F6' C28 F6 F4' 156(2) . . . . ?
C29 C28 F6 F4' -101(2) . . . . ?
F5 C28 F6 F6' -23.3(12) . . . . ?
F5' C28 F6 F6' -97.9(14) . . . . ?
F4' C28 F6 F6' -156(2) . . . . ?
F4 C28 F6 F6' -137.2(10) . . . . ?
C29 C28 F6 F6' 103.8(9) . . . . ?
F5 F6' F6 F4' 5(4) . . . . ?
C28 F6' F6 F4' -28(2) . . . . ?
F5 F6' F6 C28 32.3(16) . . . . ?
F8 F7' F7 F9' 2(3) . . . . ?
C37 F7' F7 F9' 22.8(15) . . . . ?
F8 F7' F7 C37 -21(2) . . . . ?
F7 F7' F8 C37 20(2) . . . . ?
F7 F7' F8 F8' -7(3) . . . . ?
C37 F7' F8 F8' -27.0(11) . . . . ?
F9 F8' F8 F7' -1(3) . . . . ?
C37 F8' F8 F7' 28.4(12) . . . . ?
F9 F8' F8 C37 -29(2) . . . . ?
F7' F7 F9' F9 8(2) . . . . ?
C37 F7 F9' F9 30.1(11) . . . . ?
F7' F7 F9' C37 -21.7(14) . . . . ?
F8 F8' F9 C37 27(2) . . . . ?
C37 F8' F9 F9' -11(4) . . . . ?
F8 F8' F9 F9' 17(6) . . . . ?
F7 F9' F9 F8' -21(5) . . . . ?
C37 F9' F9 F8' 11(4) . . . . ?
F7 F9' F9 C37 -31.9(11) . . . . ?
F12' C33 F10 F10' 74(2) . . . . ?
F11 C33 F10 F10' 128.2(14) . . . . ?
F12 C33 F10 F10' 14.5(14) . . . . ?
F11' C33 F10 F10' 153.7(16) . . . . ?
C34 C33 F10 F10' -103.1(13) . . . . ?
F12' C33 F10 F11' -80(2) . . . . ?
F11 C33 F10 F11' -25.5(15) . . . . ?
F10' C33 F10 F11' -153.7(16) . . . . ?
F12 C33 F10 F11' -139.2(11) . . . . ?
C34 C33 F10 F11' 103.2(10) . . . . ?
F11' F10 F10' C33 36.9(18) . . . . ?
C33 F10 F10' F12 -13.7(12) . . . . ?
F11' F10 F10' F12 23(3) . . . . ?
F12' C33 F10' F10 -131.7(15) . . . . ?
F11 C33 F10' F10 -88(2) . . . . ?
F12 C33 F10' F10 -165.3(14) . . . . ?
F11' C33 F10' F10 -22.7(15) . . . . ?
C34 C33 F10' F10 99.2(13) . . . . ?
F10 C33 F10' F12 165.3(14) . . . . ?
F12' C33 F10' F12 33.6(10) . . . . ?
F11 C33 F10' F12 77(2) . . . . ?
F11' C33 F10' F12 142.6(9) . . . . ?
C34 C33 F10' F12 -95.5(9) . . . . ?
F10' F10 F11' C33 -38.0(18) . . . . ?
F10' F10 F11' F11 -17(2) . . . . ?
C33 F10 F11' F11 21.2(11) . . . . ?
F12' C33 F11' F10 131.0(13) . . . . ?
F11 C33 F11' F10 154.7(14) . . . . ?
F10' C33 F11' F10 20.0(14) . . . . ?
F12 C33 F11' F10 87(2) . . . . ?
C34 C33 F11' F10 -103.1(11) . . . . ?
F10 C33 F11' F11 -154.7(14) . . . . ?
F12' C33 F11' F11 -23.7(12) . . . . ?
F10' C33 F11' F11 -134.7(11) . . . . ?
F12 C33 F11' F11 -68(2) . . . . ?
C34 C33 F11' F11 102.2(9) . . . . ?
F10 C33 F11 F12' -123.1(18) . . . . ?
F10' C33 F11 F12' -66(3) . . . . ?
F12 C33 F11 F12' -1.6(15) . . . . ?
F11' C33 F11 F12' -147.3(16) . . . . ?
C34 C33 F11 F12' 107.1(13) . . . . ?
F10 C33 F11 F11' 24.1(16) . . . . ?
F12' C33 F11 F11' 147.3(16) . . . . ?
F10' C33 F11 F11' 82(2) . . . . ?
F12 C33 F11 F11' 145.7(10) . . . . ?
C34 C33 F11 F11' -105.6(9) . . . . ?
F10 F11' F11 F12' 11.9(19) . . . . ?
C33 F11' F11 F12' 32.1(13) . . . . ?
F10 F11' F11 C33 -20.2(10) . . . . ?
C33 F11 F12' F12 3(3) . . . . ?
F11' F11 F12' F12 -28(4) . . . . ?
F11' F11 F12' C33 -31.5(12) . . . . ?
F10 C33 F12' F11 90(2) . . . . ?
F10' C33 F12' F11 138.4(15) . . . . ?
F12 C33 F12' F11 178.0(18) . . . . ?
F11' C33 F12' F11 29.9(16) . . . . ?
C34 C33 F12' F11 -93.6(14) . . . . ?
F10 C33 F12' F12 -88(2) . . . . ?
F11 C33 F12' F12 -178.0(18) . . . . ?
F10' C33 F12' F12 -39.6(12) . . . . ?
F11' C33 F12' F12 -148.0(11) . . . . ?
C34 C33 F12' F12 88.4(11) . . . . ?
F11 F12' F12 C33 -3(3) . . . . ?
F11 F12' F12 F10' 31(3) . . . . ?
C33 F12' F12 F10' 34.4(8) . . . . ?
F10 C33 F12 F12' 126.0(12) . . . . ?
F11 C33 F12 F12' 1.5(13) . . . . ?
F10' C33 F12 F12' 137.9(11) . . . . ?
F11' C33 F12 F12' 59(2) . . . . ?
C34 C33 F12 F12' -111.9(10) . . . . ?
F10 C33 F12 F10' -12.0(12) . . . . ?
F12' C33 F12 F10' -137.9(11) . . . . ?
F11 C33 F12 F10' -136.4(10) . . . . ?
F11' C33 F12 F10' -79(2) . . . . ?
C34 C33 F12 F10' 110.2(7) . . . . ?
F10 F10' F12 F12' -21.6(18) . . . . ?
C33 F10' F12 F12' -35.0(9) . . . . ?
F10 F10' F12 C33 13.4(12) . . . . ?
F8' F9 C37 F7' -82(4) . . . . ?
F9' F9 C37 F7' 91(3) . . . . ?
F9' F9 C37 F8' 173(3) . . . . ?
F8' F9 C37 F7 -140(3) . . . . ?
F9' F9 C37 F7 32.2(16) . . . . ?
F8' F9 C37 F9' -173(3) . . . . ?
F8' F9 C37 F8 -28(3) . . . . ?
F9' F9 C37 F8 144.7(13) . . . . ?
F8' F9 C37 C36 92(3) . . . . ?
F9' F9 C37 C36 -95.0(14) . . . . ?
F7 F7' C37 F9 -86(3) . . . . ?
F8 F7' C37 F9 79(3) . . . . ?
F7 F7' C37 F8' -129.6(15) . . . . ?
F8 F7' C37 F8' 34.9(19) . . . . ?
F8 F7' C37 F7 164.5(18) . . . . ?
F7 F7' C37 F9' -19.4(14) . . . . ?
F8 F7' C37 F9' 145.1(13) . . . . ?
F7 F7' C37 F8 -164.5(18) . . . . ?
F7 F7' C37 C36 100.1(16) . . . . ?
F8 F7' C37 C36 -95.3(13) . . . . ?
F8 F8' C37 F9 -151(3) . . . . ?
F9 F8' C37 F7' 122(3) . . . . ?
F8 F8' C37 F7' -29.0(17) . . . . ?
F9 F8' C37 F7 59(4) . . . . ?
F8 F8' C37 F7 -92(3) . . . . ?
F9 F8' C37 F9' 6(3) . . . . ?
F8 F8' C37 F9' -144.6(11) . . . . ?
F9 F8' C37 F8 151(3) . . . . ?
F9 F8' C37 C36 -107(2) . . . . ?
F8 F8' C37 C36 102.2(12) . . . . ?
F7' F7 C37 F9 124.7(17) . . . . ?
F9' F7 C37 F9 -33.3(16) . . . . ?
F9' F7 C37 F7' -158.0(16) . . . . ?
F7' F7 C37 F8' 89(2) . . . . ?
F9' F7 C37 F8' -69(3) . . . . ?
F7' F7 C37 F9' 158.0(16) . . . . ?
F7' F7 C37 F8 12.7(14) . . . . ?
F9' F7 C37 F8 -145.3(11) . . . . ?
F7' F7 C37 C36 -104.9(14) . . . . ?
F9' F7 C37 C36 97.1(11) . . . . ?
F7 F9' C37 F9 143.0(17) . . . . ?
F7 F9' C37 F7' 18.8(15) . . . . ?
F9 F9' C37 F7' -124.2(15) . . . . ?
F7 F9' C37 F8' 138.2(17) . . . . ?
F9 F9' C37 F8' -5(2) . . . . ?
F9 F9' C37 F7 -143.0(16) . . . . ?
F7 F9' C37 F8 70(2) . . . . ?
F9 F9' C37 F8 -73(2) . . . . ?
F7 F9' C37 C36 -104.9(12) . . . . ?
F9 F9' C37 C36 112.0(13) . . . . ?
F7' F8 C37 F9 -127.3(16) . . . . ?
F8' F8 C37 F9 18.8(19) . . . . ?
F8' F8 C37 F7' 146.0(16) . . . . ?
F7' F8 C37 F8' -146.0(16) . . . . ?
F7' F8 C37 F7 -13.0(15) . . . . ?
F8' F8 C37 F7 133.0(12) . . . . ?
F7' F8 C37 F9' -68(2) . . . . ?
F8' F8 C37 F9' 78(2) . . . . ?
F7' F8 C37 C36 106.7(11) . . . . ?
F8' F8 C37 C36 -107.3(12) . . . . ?
O7 C36 C37 F9 169(2) . . . . ?
C35 C36 C37 F9 -11(3) . . . . ?
O7 C36 C37 F7' -16(3) . . . . ?
C35 C36 C37 F7' 164(2) . . . . ?
O7 C36 C37 F8' -147.3(12) . . . . ?
C35 C36 C37 F8' 32.6(15) . . . . ?
O7 C36 C37 F7 43(2) . . . . ?
C35 C36 C37 F7 -136.8(18) . . . . ?
O7 C36 C37 F9' 104.2(14) . . . . ?
C35 C36 C37 F9' -75.9(14) . . . . ?
O7 C36 C37 F8 -72.6(15) . . . . ?
C35 C36 C37 F8 107.3(13) . . . . ?
O2 C17 C16 C15 178.8(4) 3_557 . . . ?
C18 C17 C16 C15 -0.7(7) . . . . ?
C14 C15 C16 C17 0.7(9) . . . . ?
Cl1 Cl2 C38 Cl3 12.6(9) 3_558 . . . ?
Cl3 Cl2 C38 Cl3 -141.7(18) 3_558 . . . ?
C38 Cl2 C38 Cl3 -66(3) 3_558 . . . ?
Cl1 Cl2 C38 Cl1 144.0(18) 3_558 . . . ?
Cl3 Cl2 C38 Cl1 -10.3(9) 3_558 . . . ?
C38 Cl2 C38 Cl1 66(2) 3_558 . . . ?
Cl3 C38 Cl1 Cl3 146.5(18) . . . 3_558 ?
Cl2 C38 Cl1 Cl3 15.3(13) . . . 3_558 ?
Cl3 C38 Cl1 C38 36.8(18) . . . 3_558 ?
Cl2 C38 Cl1 C38 -94(3) . . . 3_558 ?
Cl3 C38 Cl1 Cl2 -21.0(12) . . . 3_558 ?
Cl2 C38 Cl1 Cl2 -152.2(15) . . . 3_558 ?
Cl2 C38 Cl3 Cl1 -17.0(12) . . . 3_558 ?
Cl1 C38 Cl3 Cl1 -151.8(15) . . . 3_558 ?
Cl2 C38 Cl3 C38 98(3) . . . 3_558 ?
Cl1 C38 Cl3 C38 -36.6(15) . . . 3_558 ?
Cl2 C38 Cl3 Cl2 154.3(12) . . . 3_558 ?
Cl1 C38 Cl3 Cl2 19.5(11) . . . 3_558 ?

_diffrn_measured_fraction_theta_max 0.886
_diffrn_reflns_theta_full        26.50
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.791
_refine_diff_density_min         -0.608
_refine_diff_density_rms         0.083
