# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ReSNSCl3
_database_code_depnum_ccdc_archive 'CCDC 1441290'
_audit_update_record             
;
2015-12-08 deposited with the CCDC.
2016-01-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C19 H33 Cl3 N Rh S2'
_chemical_melting_point          ?

_exptl_crystal_description       Plate
_exptl_crystal_colour            Orange

_diffrn_ambient_temperature      173(2)
_chemical_formula_weight         548.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_int_tables_number      19

_chemical_absolute_configuration ad

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'

_cell_length_a                   8.2408(13)
_cell_length_b                   12.5927(19)
_cell_length_c                   23.083(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     2395.4(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9957
_cell_measurement_theta_min      2.4
_cell_measurement_theta_max      27.4
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.522
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1128
_exptl_absorpt_coefficient_mu    1.227
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.77
_exptl_absorpt_correction_T_max  0.89
_exptl_absorpt_process_details   
;
 Data were corrected for decay and absorption using the program SADABS 
 (Sheldrick, G. M. (2003). SADABS. Version 2.10. University of
 Göttingen, Germany).
;

_exptl_special_details           
; 
 ? 
;
_diffrn_radiation_probe          ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite

_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0.0
_diffrn_reflns_number            28087
_diffrn_reflns_av_R_equivalents  0.0320
_diffrn_reflns_av_sigmaI/netI    0.0258
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_theta_min         1.76
_diffrn_reflns_theta_max         27.49
_reflns_number_total             5486
_reflns_number_gt                5213
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 (Bruker AXS, 2008)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2008)'
_computing_data_reduction        'APEX2 (Bruker AXS, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'X-SEED, Barbour, 2001'
_computing_publication_material  'CIFTAB (Sheldrick, 1997)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. One hexyl side chain proved 
 to be partially disordered.  The disorder was modelled and the occupancy 
 refined to approximately 27%.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0292P)²+0.8507P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.01(2)
_refine_ls_number_reflns         5486
_refine_ls_number_parameters     256
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0268
_refine_ls_R_factor_gt           0.0245
_refine_ls_wR_factor_ref         0.0578
_refine_ls_wR_factor_gt          0.0567
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.57034(2) 0.273365(15) 0.332823(9) 0.02303(5) Uani 1 1 d . A .
Cl1 Cl 0.33468(7) 0.37936(5) 0.33117(3) 0.03226(14) Uani 1 1 d . . .
Cl2 Cl 0.46529(8) 0.17183(6) 0.40922(3) 0.03363(15) Uani 1 1 d . . .
Cl3 Cl 0.68579(8) 0.37043(5) 0.25627(3) 0.03195(15) Uani 1 1 d . . .
S1 S 0.71890(9) 0.39060(6) 0.39002(3) 0.03254(16) Uani 1 1 d . . .
S2 S 0.45459(8) 0.14015(5) 0.27722(3) 0.02779(14) Uani 1 1 d . . .
N1 N 0.7716(2) 0.18300(16) 0.33291(11) 0.0257(4) Uani 1 1 d . . .
C1 C 0.9181(4) 0.3370(2) 0.37144(16) 0.0426(8) Uani 1 1 d . A .
H1A H 0.9666 0.3816 0.3407 0.051 Uiso 1 1 calc R . .
H1B H 0.9893 0.3417 0.4059 0.051 Uiso 1 1 calc R . .
C2 C 0.9144(3) 0.2236(2) 0.35099(12) 0.0308(6) Uani 1 1 d . A .
C3 C 1.0559(3) 0.1639(2) 0.34762(13) 0.0362(7) Uani 1 1 d . . .
H3 H 1.1552 0.1918 0.3619 0.043 Uiso 1 1 calc R A .
C4 C 1.0509(3) 0.0643(2) 0.32342(14) 0.0381(7) Uani 1 1 d . A .
H4 H 1.1474 0.0235 0.3197 0.046 Uiso 1 1 calc R . .
C5 C 0.9040(4) 0.0237(2) 0.30445(13) 0.0350(7) Uani 1 1 d . . .
H5 H 0.8993 -0.0446 0.2871 0.042 Uiso 1 1 calc R A .
C6 C 0.7645(3) 0.0831(2) 0.31096(12) 0.0273(6) Uani 1 1 d . A .
C7 C 0.6013(3) 0.0398(2) 0.29691(13) 0.0335(7) Uani 1 1 d . A .
H7A H 0.5601 0.0002 0.3309 0.040 Uiso 1 1 calc R . .
H7B H 0.6120 -0.0111 0.2645 0.040 Uiso 1 1 calc R . .
C8 C 0.7027(5) 0.3559(3) 0.46627(14) 0.0501(9) Uani 0.731(7) 1 d P A 1
H8A H 0.7133 0.2781 0.4712 0.060 Uiso 0.731(7) 1 calc PR A 1
H8B H 0.7904 0.3907 0.4885 0.060 Uiso 0.731(7) 1 calc PR A 1
C9 C 0.5330(8) 0.3938(5) 0.4891(2) 0.0571(17) Uani 0.731(7) 1 d P A 1
H9A H 0.4468 0.3625 0.4646 0.068 Uiso 0.731(7) 1 calc PR A 1
H9B H 0.5174 0.3674 0.5291 0.068 Uiso 0.731(7) 1 calc PR A 1
C10 C 0.5160(8) 0.5133(5) 0.4887(3) 0.080(2) Uani 0.731(7) 1 d P A 1
H10A H 0.5205 0.5403 0.4485 0.096 Uiso 0.731(7) 1 calc PR A 1
H10B H 0.6057 0.5461 0.5110 0.096 Uiso 0.731(7) 1 calc PR A 1
C11 C 0.3509(7) 0.5416(5) 0.5166(2) 0.0922(18) Uani 0.731(7) 1 d P A 1
H11A H 0.3498 0.5060 0.5549 0.111 Uiso 0.731(7) 1 calc PR A 1
H11B H 0.3549 0.6188 0.5246 0.111 Uiso 0.731(7) 1 calc PR A 1
C12 C 0.1907(7) 0.5216(4) 0.4909(2) 0.0783(14) Uani 1 1 d . . .
H12A H 0.1671 0.4446 0.4933 0.094 Uiso 1 1 calc R A 1
H12B H 0.1943 0.5411 0.4494 0.094 Uiso 1 1 calc R A 1
C13 C 0.0535(6) 0.5822(4) 0.5197(2) 0.0855(15) Uani 1 1 d . A .
H13A H 0.0387 0.5560 0.5593 0.128 Uiso 1 1 calc R . .
H13B H -0.0469 0.5716 0.4977 0.128 Uiso 1 1 calc R . .
H13C H 0.0802 0.6580 0.5207 0.128 Uiso 1 1 calc R . .
C14 C 0.5026(4) 0.1532(3) 0.20084(13) 0.0376(7) Uani 1 1 d . A .
H14A H 0.6140 0.1815 0.1967 0.045 Uiso 1 1 calc R . .
H14B H 0.4994 0.0822 0.1824 0.045 Uiso 1 1 calc R . .
C15 C 0.3862(4) 0.2253(3) 0.17038(15) 0.0505(8) Uani 1 1 d . . .
H15A H 0.4159 0.2294 0.1289 0.061 Uiso 1 1 calc R A .
H15B H 0.3952 0.2976 0.1870 0.061 Uiso 1 1 calc R . .
C16 C 0.2055(5) 0.1859(3) 0.17588(17) 0.0611(10) Uani 1 1 d . A .
H16A H 0.2013 0.1083 0.1694 0.073 Uiso 1 1 calc R . .
H16B H 0.1656 0.2003 0.2156 0.073 Uiso 1 1 calc R . .
C17 C 0.0971(5) 0.2406(3) 0.13278(17) 0.0633(11) Uani 1 1 d . . .
H17A H 0.1304 0.2198 0.0932 0.076 Uiso 1 1 calc R A .
H17B H 0.1117 0.3184 0.1364 0.076 Uiso 1 1 calc R . .
C18 C -0.0796(5) 0.2141(5) 0.1410(2) 0.0901(16) Uani 1 1 d . A .
H18A H -0.1106 0.2281 0.1817 0.108 Uiso 1 1 calc R . .
H18B H -0.0967 0.1376 0.1332 0.108 Uiso 1 1 calc R . .
C19 C -0.1879(6) 0.2793(5) 0.10084(19) 0.0849(15) Uani 1 1 d . . .
H19A H -0.1815 0.3545 0.1117 0.127 Uiso 1 1 calc R A .
H19B H -0.3004 0.2548 0.1044 0.127 Uiso 1 1 calc R . .
H19C H -0.1514 0.2705 0.0607 0.127 Uiso 1 1 calc R . .
C10' C 0.4300(15) 0.4444(8) 0.4820(5) 0.038(3) Uani 0.269(7) 1 d PD A 2
H10C H 0.3782 0.3768 0.4936 0.046 Uiso 0.269(7) 1 calc PR A 2
H10D H 0.4152 0.4541 0.4398 0.046 Uiso 0.269(7) 1 calc PR A 2
C9' C 0.6140(18) 0.4429(12) 0.4974(5) 0.042(3) Uani 0.269(7) 1 d P A 2
H9'1 H 0.6629 0.5121 0.4871 0.051 Uiso 0.269(7) 1 calc PR A 2
H9'2 H 0.6266 0.4329 0.5397 0.051 Uiso 0.269(7) 1 calc PR A 2
C8' C 0.7027(5) 0.3559(3) 0.46627(14) 0.0501(9) Uani 0.269(7) 1 d P A 2
H8'1 H 0.6431 0.2881 0.4705 0.060 Uiso 0.269(7) 1 calc PR A 2
H8'2 H 0.8123 0.3468 0.4831 0.060 Uiso 0.269(7) 1 calc PR A 2
C11' C 0.3509(7) 0.5416(5) 0.5166(2) 0.0922(18) Uani 0.269(7) 1 d PD A 2
H11C H 0.3529 0.5321 0.5592 0.111 Uiso 0.269(7) 1 calc PR A 2
H11D H 0.3970 0.6114 0.5058 0.111 Uiso 0.269(7) 1 calc PR A 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N1 2.011(2) . ?
Rh1 S2 2.3176(7) . ?
Rh1 S1 2.3283(7) . ?
Rh1 Cl2 2.3439(7) . ?
Rh1 Cl3 2.3497(7) . ?
Rh1 Cl1 2.3568(7) . ?
S1 C8 1.819(3) . ?
S1 C1 1.826(3) . ?
S2 C7 1.807(3) . ?
S2 C14 1.814(3) . ?
N1 C2 1.349(3) . ?
N1 C6 1.357(3) . ?
C1 C2 1.504(4) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.389(4) . ?
C3 C4 1.374(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.385(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.380(4) . ?
C5 H5 0.9500 . ?
C6 C7 1.487(4) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.568(7) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.511(9) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C11 1.548(8) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C12 1.469(6) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 C13 1.517(6) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 C15 1.496(4) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.575(5) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C17 1.504(5) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.506(6) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C19 1.526(7) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C10' C9' 1.56(2) . ?
C10' H10C 0.9900 . ?
C10' H10D 0.9900 . ?
C9' H9'1 0.9900 . ?
C9' H9'2 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Rh1 S2 86.01(7) . . ?
N1 Rh1 S1 85.68(7) . . ?
S2 Rh1 S1 171.63(3) . . ?
N1 Rh1 Cl2 89.72(7) . . ?
S2 Rh1 Cl2 82.52(3) . . ?
S1 Rh1 Cl2 96.52(3) . . ?
N1 Rh1 Cl3 87.77(7) . . ?
S2 Rh1 Cl3 97.28(3) . . ?
S1 Rh1 Cl3 83.32(3) . . ?
Cl2 Rh1 Cl3 177.50(3) . . ?
N1 Rh1 Cl1 179.12(8) . . ?
S2 Rh1 Cl1 93.54(3) . . ?
S1 Rh1 Cl1 94.78(3) . . ?
Cl2 Rh1 Cl1 90.96(3) . . ?
Cl3 Rh1 Cl1 91.54(3) . . ?
C8 S1 C1 101.80(17) . . ?
C8 S1 Rh1 110.95(13) . . ?
C1 S1 Rh1 96.03(10) . . ?
C7 S2 C14 99.31(14) . . ?
C7 S2 Rh1 95.25(10) . . ?
C14 S2 Rh1 112.53(11) . . ?
C2 N1 C6 120.3(2) . . ?
C2 N1 Rh1 120.35(18) . . ?
C6 N1 Rh1 119.22(17) . . ?
C2 C1 S1 114.0(2) . . ?
C2 C1 H1A 108.8 . . ?
S1 C1 H1A 108.8 . . ?
C2 C1 H1B 108.8 . . ?
S1 C1 H1B 108.8 . . ?
H1A C1 H1B 107.7 . . ?
N1 C2 C3 120.7(3) . . ?
N1 C2 C1 118.3(2) . . ?
C3 C2 C1 120.9(3) . . ?
C4 C3 C2 119.4(3) . . ?
C4 C3 H3 120.3 . . ?
C2 C3 H3 120.3 . . ?
C3 C4 C5 119.4(3) . . ?
C3 C4 H4 120.3 . . ?
C5 C4 H4 120.3 . . ?
C6 C5 C4 119.6(3) . . ?
C6 C5 H5 120.2 . . ?
C4 C5 H5 120.2 . . ?
N1 C6 C5 120.5(3) . . ?
N1 C6 C7 117.4(2) . . ?
C5 C6 C7 122.1(2) . . ?
C6 C7 S2 113.80(19) . . ?
C6 C7 H7A 108.8 . . ?
S2 C7 H7A 108.8 . . ?
C6 C7 H7B 108.8 . . ?
S2 C7 H7B 108.8 . . ?
H7A C7 H7B 107.7 . . ?
C9 C8 S1 108.5(3) . . ?
C9 C8 H8A 110.0 . . ?
S1 C8 H8A 110.0 . . ?
C9 C8 H8B 110.0 . . ?
S1 C8 H8B 110.0 . . ?
H8A C8 H8B 108.4 . . ?
C10 C9 C8 112.6(6) . . ?
C10 C9 H9A 109.1 . . ?
C8 C9 H9A 109.1 . . ?
C10 C9 H9B 109.1 . . ?
C8 C9 H9B 109.1 . . ?
H9A C9 H9B 107.8 . . ?
C9 C10 C11 108.0(5) . . ?
C9 C10 H10A 110.1 . . ?
C11 C10 H10A 110.1 . . ?
C9 C10 H10B 110.1 . . ?
C11 C10 H10B 110.1 . . ?
H10A C10 H10B 108.4 . . ?
C12 C11 C10 125.6(4) . . ?
C12 C11 H11A 105.9 . . ?
C10 C11 H11A 105.9 . . ?
C12 C11 H11B 105.9 . . ?
C10 C11 H11B 105.9 . . ?
H11A C11 H11B 106.2 . . ?
C11 C12 C13 113.9(4) . . ?
C11 C12 H12A 108.8 . . ?
C13 C12 H12A 108.8 . . ?
C11 C12 H12B 108.8 . . ?
C13 C12 H12B 108.8 . . ?
H12A C12 H12B 107.7 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C15 C14 S2 111.8(2) . . ?
C15 C14 H14A 109.3 . . ?
S2 C14 H14A 109.3 . . ?
C15 C14 H14B 109.3 . . ?
S2 C14 H14B 109.3 . . ?
H14A C14 H14B 107.9 . . ?
C14 C15 C16 112.2(3) . . ?
C14 C15 H15A 109.2 . . ?
C16 C15 H15A 109.2 . . ?
C14 C15 H15B 109.2 . . ?
C16 C15 H15B 109.2 . . ?
H15A C15 H15B 107.9 . . ?
C17 C16 C15 111.4(3) . . ?
C17 C16 H16A 109.4 . . ?
C15 C16 H16A 109.4 . . ?
C17 C16 H16B 109.4 . . ?
C15 C16 H16B 109.4 . . ?
H16A C16 H16B 108.0 . . ?
C16 C17 C18 113.0(4) . . ?
C16 C17 H17A 109.0 . . ?
C18 C17 H17A 109.0 . . ?
C16 C17 H17B 109.0 . . ?
C18 C17 H17B 109.0 . . ?
H17A C17 H17B 107.8 . . ?
C17 C18 C19 111.8(4) . . ?
C17 C18 H18A 109.3 . . ?
C19 C18 H18A 109.3 . . ?
C17 C18 H18B 109.3 . . ?
C19 C18 H18B 109.3 . . ?
H18A C18 H18B 107.9 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C9' C10' H10C 110.3 . . ?
C9' C10' H10D 110.3 . . ?
H10C C10' H10D 108.6 . . ?
C10' C9' H9'1 109.2 . . ?
C10' C9' H9'2 109.2 . . ?
H9'1 C9' H9'2 107.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Rh1 S1 C8 -86.96(14) . . . . ?
S2 Rh1 S1 C8 -80.6(2) . . . . ?
Cl2 Rh1 S1 C8 2.27(13) . . . . ?
Cl3 Rh1 S1 C8 -175.22(13) . . . . ?
Cl1 Rh1 S1 C8 93.79(13) . . . . ?
N1 Rh1 S1 C1 18.15(14) . . . . ?
S2 Rh1 S1 C1 24.5(2) . . . . ?
Cl2 Rh1 S1 C1 107.37(12) . . . . ?
Cl3 Rh1 S1 C1 -70.11(12) . . . . ?
Cl1 Rh1 S1 C1 -161.11(12) . . . . ?
N1 Rh1 S2 C7 18.65(12) . . . . ?
S1 Rh1 S2 C7 12.3(2) . . . . ?
Cl2 Rh1 S2 C7 -71.60(10) . . . . ?
Cl3 Rh1 S2 C7 105.89(10) . . . . ?
Cl1 Rh1 S2 C7 -162.10(10) . . . . ?
N1 Rh1 S2 C14 -83.70(13) . . . . ?
S1 Rh1 S2 C14 -90.1(2) . . . . ?
Cl2 Rh1 S2 C14 -173.95(11) . . . . ?
Cl3 Rh1 S2 C14 3.54(11) . . . . ?
Cl1 Rh1 S2 C14 95.55(11) . . . . ?
S2 Rh1 N1 C2 167.2(2) . . . . ?
S1 Rh1 N1 C2 -13.7(2) . . . . ?
Cl2 Rh1 N1 C2 -110.2(2) . . . . ?
Cl3 Rh1 N1 C2 69.8(2) . . . . ?
Cl1 Rh1 N1 C2 108(4) . . . . ?
S2 Rh1 N1 C6 -8.4(2) . . . . ?
S1 Rh1 N1 C6 170.7(2) . . . . ?
Cl2 Rh1 N1 C6 74.2(2) . . . . ?
Cl3 Rh1 N1 C6 -105.8(2) . . . . ?
Cl1 Rh1 N1 C6 -68(4) . . . . ?
C8 S1 C1 C2 89.4(3) . . . . ?
Rh1 S1 C1 C2 -23.5(2) . . . . ?
C6 N1 C2 C3 -0.2(4) . . . . ?
Rh1 N1 C2 C3 -175.8(2) . . . . ?
C6 N1 C2 C1 176.2(3) . . . . ?
Rh1 N1 C2 C1 0.6(4) . . . . ?
S1 C1 C2 N1 18.2(4) . . . . ?
S1 C1 C2 C3 -165.5(2) . . . . ?
N1 C2 C3 C4 2.7(4) . . . . ?
C1 C2 C3 C4 -173.6(3) . . . . ?
C2 C3 C4 C5 -2.0(4) . . . . ?
C3 C4 C5 C6 -1.0(4) . . . . ?
C2 N1 C6 C5 -2.9(4) . . . . ?
Rh1 N1 C6 C5 172.7(2) . . . . ?
C2 N1 C6 C7 174.5(3) . . . . ?
Rh1 N1 C6 C7 -9.9(3) . . . . ?
C4 C5 C6 N1 3.6(4) . . . . ?
C4 C5 C6 C7 -173.8(3) . . . . ?
N1 C6 C7 S2 28.9(3) . . . . ?
C5 C6 C7 S2 -153.7(2) . . . . ?
C14 S2 C7 C6 84.7(2) . . . . ?
Rh1 S2 C7 C6 -29.2(2) . . . . ?
C1 S1 C8 C9 -178.3(3) . . . . ?
Rh1 S1 C8 C9 -77.0(3) . . . . ?
S1 C8 C9 C10 -65.7(5) . . . . ?
C8 C9 C10 C11 -175.4(4) . . . . ?
C9 C10 C11 C12 -69.9(9) . . . . ?
C10 C11 C12 C13 -164.9(6) . . . . ?
C7 S2 C14 C15 174.2(2) . . . . ?
Rh1 S2 C14 C15 -86.1(2) . . . . ?
S2 C14 C15 C16 -58.2(4) . . . . ?
C14 C15 C16 C17 -164.7(3) . . . . ?
C15 C16 C17 C18 -173.7(4) . . . . ?
C16 C17 C18 C19 174.1(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.585
_refine_diff_density_min         -0.342
_refine_diff_density_rms         0.059

