# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_takipt_0m
_database_code_depnum_ccdc_archive 'CCDC 1434542'
_audit_update_record             
;
2016-01-28 deposited with the CCDC.
2016-02-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C30 H23 N2 O2 Pt'
_chemical_formula_weight         638.59

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Pbca

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.407(3)
_cell_length_b                   15.984(3)
_cell_length_c                   18.826(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     4635.9(13)
_cell_formula_units_Z            8
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    4421
_cell_measurement_theta_min      3.65
_cell_measurement_theta_max      27.98

_exptl_crystal_description       prism
_exptl_crystal_colour            'deep green'
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.830
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2488
_exptl_absorpt_coefficient_mu    6.085
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.5813
_exptl_absorpt_correction_T_max  0.8880
_exptl_absorpt_process_details   
;
SADABS Sheldrick 1996
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            23531
_diffrn_reflns_av_unetI/netI     0.0447
_diffrn_reflns_av_R_equivalents  0.0574
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.13
_diffrn_reflns_theta_max         27.59
_reflns_number_total             5193
_reflns_number_gt                3800
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0316P)²+18.6729P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5193
_refine_ls_number_parameters     319
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0558
_refine_ls_R_factor_gt           0.0324
_refine_ls_wR_factor_ref         0.0851
_refine_ls_wR_factor_gt          0.0714
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_restrained_S_all      1.043
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt -0.154802(12) 0.035484(11) 0.516966(10) 0.01641(7) Uani 1 1 d . . .
O1 O -0.2109(2) -0.0373(2) 0.4460(2) 0.0218(8) Uani 1 1 d . . .
O2 O -0.0907(2) -0.0682(2) 0.5394(2) 0.0237(8) Uani 1 1 d . . .
N1 N -0.2271(3) 0.1316(2) 0.4905(2) 0.0191(9) Uani 1 1 d . . .
C1 C -0.2733(3) -0.0186(3) 0.4024(3) 0.0231(11) Uani 1 1 d . . .
C2 C -0.3172(4) 0.0608(3) 0.4001(3) 0.0240(12) Uani 1 1 d . . .
C3 C -0.2924(3) 0.1306(3) 0.4424(3) 0.0204(11) Uani 1 1 d . . .
C4 C -0.2222(4) 0.2110(3) 0.5198(3) 0.0215(11) Uani 1 1 d . . .
C5 C -0.2874(3) 0.2621(3) 0.4867(3) 0.0241(12) Uani 1 1 d . . .
H1 H -0.2984 0.3196 0.4960 0.029 Uiso 1 1 calc R . .
C6 C -0.3299(4) 0.2130(3) 0.4398(3) 0.0289(13) Uani 1 1 d . . .
H2 H -0.3766 0.2300 0.4102 0.035 Uiso 1 1 calc R . .
C7 C -0.1637(3) 0.2363(3) 0.5721(3) 0.0193(11) Uani 1 1 d . . .
C8 C -0.1008(3) 0.1841(3) 0.6029(3) 0.0198(11) Uani 1 1 d . . .
N2 N -0.0890(3) 0.1000(2) 0.5875(2) 0.0198(9) Uani 1 1 d . . .
C9 C -0.0211(4) 0.0707(3) 0.6263(3) 0.0226(11) Uani 1 1 d . . .
C10 C 0.0124(4) 0.1393(3) 0.6686(3) 0.0253(12) Uani 1 1 d . . .
H3 H 0.0603 0.1368 0.7003 0.030 Uiso 1 1 calc R . .
C11 C -0.0368(4) 0.2074(3) 0.6549(3) 0.0233(11) Uani 1 1 d . . .
H4 H -0.0303 0.2611 0.6758 0.028 Uiso 1 1 calc R . .
C12 C 0.0091(3) -0.0139(3) 0.6273(3) 0.0197(11) Uani 1 1 d . . .
C13 C -0.0293(3) -0.0784(3) 0.5848(3) 0.0190(10) Uani 1 1 d . . .
C14 C 0.0010(4) -0.1628(3) 0.5930(3) 0.0276(13) Uani 1 1 d . . .
H5 H -0.0254 -0.2064 0.5663 0.033 Uiso 1 1 calc R . .
C15 C 0.0668(4) -0.1810(4) 0.6384(3) 0.0325(14) Uani 1 1 d . . .
H6 H 0.0858 -0.2373 0.6435 0.039 Uiso 1 1 calc R . .
C16 C 0.1071(4) -0.1177(4) 0.6778(3) 0.0307(13) Uani 1 1 d . . .
H7 H 0.1543 -0.1309 0.7083 0.037 Uiso 1 1 calc R . .
C17 C 0.0788(4) -0.0368(3) 0.6726(3) 0.0262(12) Uani 1 1 d . . .
H8 H 0.1066 0.0053 0.7001 0.031 Uiso 1 1 calc R . .
C18 C -0.1655(3) 0.3268(3) 0.5945(3) 0.0231(11) Uani 1 1 d . . .
C19 C -0.2206(4) 0.3536(3) 0.6492(3) 0.0272(12) Uani 1 1 d . . .
C20 C -0.2204(4) 0.4382(3) 0.6678(3) 0.0316(14) Uani 1 1 d . . .
H9 H -0.2580 0.4574 0.7043 0.038 Uiso 1 1 calc R . .
C21 C -0.1657(4) 0.4950(3) 0.6336(4) 0.0319(14) Uani 1 1 d . . .
C22 C -0.1132(4) 0.4670(3) 0.5803(4) 0.0320(14) Uani 1 1 d . . .
H10 H -0.0761 0.5058 0.5570 0.038 Uiso 1 1 calc R . .
C23 C -0.1121(4) 0.3835(3) 0.5589(3) 0.0276(12) Uani 1 1 d . . .
C24 C -0.0538(4) 0.3576(4) 0.4984(4) 0.0415(17) Uani 1 1 d . . .
H11 H -0.0022 0.3294 0.5173 0.062 Uiso 1 1 calc R . .
H12 H -0.0360 0.4072 0.4715 0.062 Uiso 1 1 calc R . .
H13 H -0.0852 0.3192 0.4669 0.062 Uiso 1 1 calc R . .
C25 C -0.1656(5) 0.5866(4) 0.6564(4) 0.049(2) Uani 1 1 d . . .
H14 H -0.1091 0.6007 0.6770 0.073 Uiso 1 1 calc R . .
H15 H -0.2113 0.5957 0.6918 0.073 Uiso 1 1 calc R . .
H16 H -0.1764 0.6222 0.6149 0.073 Uiso 1 1 calc R . .
C26 C -0.2799(4) 0.2946(4) 0.6872(4) 0.0374(15) Uani 1 1 d . . .
H17 H -0.3084 0.3239 0.7265 0.056 Uiso 1 1 calc R . .
H18 H -0.2462 0.2475 0.7060 0.056 Uiso 1 1 calc R . .
H19 H -0.3239 0.2735 0.6541 0.056 Uiso 1 1 calc R . .
C27 C -0.3870(4) 0.0677(4) 0.3518(3) 0.0300(13) Uani 1 1 d . . .
H20 H -0.4179 0.1191 0.3501 0.036 Uiso 1 1 calc R . .
C28 C -0.4123(4) 0.0054(4) 0.3076(3) 0.0338(14) Uani 1 1 d . . .
H21 H -0.4607 0.0127 0.2769 0.041 Uiso 1 1 calc R . .
C29 C -0.3658(4) -0.0704(4) 0.3080(3) 0.0340(14) Uani 1 1 d . . .
H22 H -0.3812 -0.1134 0.2756 0.041 Uiso 1 1 calc R . .
C30 C -0.2988(4) -0.0829(3) 0.3544(3) 0.0281(13) Uani 1 1 d . . .
H23 H -0.2691 -0.1349 0.3547 0.034 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 1.962(4) . ?
Pt1 N2 1.963(4) . ?
Pt1 O1 1.971(3) . ?
Pt1 O2 1.975(3) . ?
O1 C1 1.299(6) . ?
O2 C13 1.285(6) . ?
N1 C3 1.354(7) . ?
N1 C4 1.386(6) . ?
C1 C30 1.423(7) . ?
C1 C2 1.439(7) . ?
C2 C27 1.412(8) . ?
C2 C3 1.422(7) . ?
C3 C6 1.439(7) . ?
C4 C7 1.394(7) . ?
C4 C5 1.437(7) . ?
C5 C6 1.351(8) . ?
C5 H1 0.9500 . ?
C6 H2 0.9500 . ?
C7 C8 1.404(7) . ?
C7 C18 1.507(7) . ?
C8 N2 1.387(6) . ?
C8 C11 1.437(7) . ?
N2 C9 1.360(7) . ?
C9 C12 1.430(7) . ?
C9 C10 1.449(7) . ?
C10 C11 1.352(7) . ?
C10 H3 0.9500 . ?
C11 H4 0.9500 . ?
C12 C17 1.420(8) . ?
C12 C13 1.433(7) . ?
C13 C14 1.435(7) . ?
C14 C15 1.359(8) . ?
C14 H5 0.9500 . ?
C15 C16 1.400(9) . ?
C15 H6 0.9500 . ?
C16 C17 1.368(8) . ?
C16 H7 0.9500 . ?
C17 H8 0.9500 . ?
C18 C23 1.396(8) . ?
C18 C19 1.401(8) . ?
C19 C20 1.398(7) . ?
C19 C26 1.496(8) . ?
C20 C21 1.396(9) . ?
C20 H9 0.9500 . ?
C21 C22 1.365(9) . ?
C21 C25 1.525(8) . ?
C22 C23 1.394(7) . ?
C22 H10 0.9500 . ?
C23 C24 1.509(9) . ?
C24 H11 0.9800 . ?
C24 H12 0.9800 . ?
C24 H13 0.9800 . ?
C25 H14 0.9800 . ?
C25 H15 0.9800 . ?
C25 H16 0.9800 . ?
C26 H17 0.9800 . ?
C26 H18 0.9800 . ?
C26 H19 0.9800 . ?
C27 C28 1.356(8) . ?
C27 H20 0.9500 . ?
C28 C29 1.406(9) . ?
C28 H21 0.9500 . ?
C29 C30 1.367(8) . ?
C29 H22 0.9500 . ?
C30 H23 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 N2 93.07(17) . . ?
N1 Pt1 O1 92.33(16) . . ?
N2 Pt1 O1 174.20(15) . . ?
N1 Pt1 O2 174.48(16) . . ?
N2 Pt1 O2 92.16(16) . . ?
O1 Pt1 O2 82.51(15) . . ?
C1 O1 Pt1 128.1(3) . . ?
C13 O2 Pt1 128.1(3) . . ?
C3 N1 C4 108.5(4) . . ?
C3 N1 Pt1 125.7(3) . . ?
C4 N1 Pt1 125.8(4) . . ?
O1 C1 C30 116.1(5) . . ?
O1 C1 C2 124.7(5) . . ?
C30 C1 C2 119.2(5) . . ?
C27 C2 C3 120.2(5) . . ?
C27 C2 C1 116.5(5) . . ?
C3 C2 C1 123.3(5) . . ?
N1 C3 C2 125.6(5) . . ?
N1 C3 C6 108.1(4) . . ?
C2 C3 C6 126.2(5) . . ?
N1 C4 C7 125.6(5) . . ?
N1 C4 C5 108.1(5) . . ?
C7 C4 C5 126.3(5) . . ?
C6 C5 C4 107.0(4) . . ?
C6 C5 H1 126.5 . . ?
C4 C5 H1 126.5 . . ?
C5 C6 C3 108.4(5) . . ?
C5 C6 H2 125.8 . . ?
C3 C6 H2 125.8 . . ?
C4 C7 C8 124.5(4) . . ?
C4 C7 C18 117.7(4) . . ?
C8 C7 C18 117.8(4) . . ?
N2 C8 C7 125.4(5) . . ?
N2 C8 C11 107.7(4) . . ?
C7 C8 C11 127.0(4) . . ?
C9 N2 C8 108.8(4) . . ?
C9 N2 Pt1 125.5(3) . . ?
C8 N2 Pt1 125.7(3) . . ?
N2 C9 C12 125.6(5) . . ?
N2 C9 C10 108.0(4) . . ?
C12 C9 C10 126.3(5) . . ?
C11 C10 C9 107.7(5) . . ?
C11 C10 H3 126.2 . . ?
C9 C10 H3 126.2 . . ?
C10 C11 C8 107.9(5) . . ?
C10 C11 H4 126.1 . . ?
C8 C11 H4 126.1 . . ?
C17 C12 C9 119.8(5) . . ?
C17 C12 C13 117.5(5) . . ?
C9 C12 C13 122.6(5) . . ?
O2 C13 C12 125.7(4) . . ?
O2 C13 C14 115.4(5) . . ?
C12 C13 C14 118.9(5) . . ?
C15 C14 C13 120.7(5) . . ?
C15 C14 H5 119.6 . . ?
C13 C14 H5 119.6 . . ?
C14 C15 C16 120.6(5) . . ?
C14 C15 H6 119.7 . . ?
C16 C15 H6 119.7 . . ?
C17 C16 C15 120.3(5) . . ?
C17 C16 H7 119.9 . . ?
C15 C16 H7 119.9 . . ?
C16 C17 C12 121.8(5) . . ?
C16 C17 H8 119.1 . . ?
C12 C17 H8 119.1 . . ?
C23 C18 C19 120.7(5) . . ?
C23 C18 C7 118.6(5) . . ?
C19 C18 C7 120.7(5) . . ?
C20 C19 C18 118.6(5) . . ?
C20 C19 C26 119.4(6) . . ?
C18 C19 C26 122.0(5) . . ?
C21 C20 C19 121.0(6) . . ?
C21 C20 H9 119.5 . . ?
C19 C20 H9 119.5 . . ?
C22 C21 C20 119.0(5) . . ?
C22 C21 C25 121.4(6) . . ?
C20 C21 C25 119.7(6) . . ?
C21 C22 C23 122.2(6) . . ?
C21 C22 H10 118.9 . . ?
C23 C22 H10 118.9 . . ?
C22 C23 C18 118.4(6) . . ?
C22 C23 C24 119.2(5) . . ?
C18 C23 C24 122.3(5) . . ?
C23 C24 H11 109.5 . . ?
C23 C24 H12 109.5 . . ?
H11 C24 H12 109.5 . . ?
C23 C24 H13 109.5 . . ?
H11 C24 H13 109.5 . . ?
H12 C24 H13 109.5 . . ?
C21 C25 H14 109.5 . . ?
C21 C25 H15 109.5 . . ?
H14 C25 H15 109.5 . . ?
C21 C25 H16 109.5 . . ?
H14 C25 H16 109.5 . . ?
H15 C25 H16 109.5 . . ?
C19 C26 H17 109.5 . . ?
C19 C26 H18 109.5 . . ?
H17 C26 H18 109.5 . . ?
C19 C26 H19 109.5 . . ?
H17 C26 H19 109.5 . . ?
H18 C26 H19 109.5 . . ?
C28 C27 C2 123.8(6) . . ?
C28 C27 H20 118.1 . . ?
C2 C27 H20 118.1 . . ?
C27 C28 C29 118.8(6) . . ?
C27 C28 H21 120.6 . . ?
C29 C28 H21 120.6 . . ?
C30 C29 C28 120.9(6) . . ?
C30 C29 H22 119.5 . . ?
C28 C29 H22 119.5 . . ?
C29 C30 C1 120.6(5) . . ?
C29 C30 H23 119.7 . . ?
C1 C30 H23 119.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Pt1 O1 C1 -0.9(4) . . . . ?
N2 Pt1 O1 C1 -159.5(15) . . . . ?
O2 Pt1 O1 C1 177.1(4) . . . . ?
N1 Pt1 O2 C13 -162.0(16) . . . . ?
N2 Pt1 O2 C13 -0.6(4) . . . . ?
O1 Pt1 O2 C13 177.1(4) . . . . ?
N2 Pt1 N1 C3 -178.2(4) . . . . ?
O1 Pt1 N1 C3 3.9(4) . . . . ?
O2 Pt1 N1 C3 -17(2) . . . . ?
N2 Pt1 N1 C4 -0.9(4) . . . . ?
O1 Pt1 N1 C4 -178.8(4) . . . . ?
O2 Pt1 N1 C4 160.5(16) . . . . ?
Pt1 O1 C1 C30 177.4(4) . . . . ?
Pt1 O1 C1 C2 -3.1(8) . . . . ?
O1 C1 C2 C27 -176.4(5) . . . . ?
C30 C1 C2 C27 3.1(8) . . . . ?
O1 C1 C2 C3 5.0(9) . . . . ?
C30 C1 C2 C3 -175.5(5) . . . . ?
C4 N1 C3 C2 179.0(5) . . . . ?
Pt1 N1 C3 C2 -3.3(8) . . . . ?
C4 N1 C3 C6 1.1(6) . . . . ?
Pt1 N1 C3 C6 178.8(4) . . . . ?
C27 C2 C3 N1 179.8(5) . . . . ?
C1 C2 C3 N1 -1.6(9) . . . . ?
C27 C2 C3 C6 -2.6(9) . . . . ?
C1 C2 C3 C6 176.0(5) . . . . ?
C3 N1 C4 C7 179.2(5) . . . . ?
Pt1 N1 C4 C7 1.5(8) . . . . ?
C3 N1 C4 C5 -1.2(6) . . . . ?
Pt1 N1 C4 C5 -178.9(4) . . . . ?
N1 C4 C5 C6 0.9(6) . . . . ?
C7 C4 C5 C6 -179.6(5) . . . . ?
C4 C5 C6 C3 -0.2(7) . . . . ?
N1 C3 C6 C5 -0.6(7) . . . . ?
C2 C3 C6 C5 -178.5(5) . . . . ?
N1 C4 C7 C8 -0.2(9) . . . . ?
C5 C4 C7 C8 -179.7(5) . . . . ?
N1 C4 C7 C18 176.8(5) . . . . ?
C5 C4 C7 C18 -2.7(8) . . . . ?
C4 C7 C8 N2 -1.7(9) . . . . ?
C18 C7 C8 N2 -178.8(5) . . . . ?
C4 C7 C8 C11 177.6(5) . . . . ?
C18 C7 C8 C11 0.5(8) . . . . ?
C7 C8 N2 C9 178.7(5) . . . . ?
C11 C8 N2 C9 -0.7(6) . . . . ?
C7 C8 N2 Pt1 2.1(7) . . . . ?
C11 C8 N2 Pt1 -177.3(3) . . . . ?
N1 Pt1 N2 C9 -176.8(4) . . . . ?
O1 Pt1 N2 C9 -18.2(19) . . . . ?
O2 Pt1 N2 C9 4.9(4) . . . . ?
N1 Pt1 N2 C8 -0.8(4) . . . . ?
O1 Pt1 N2 C8 157.8(14) . . . . ?
O2 Pt1 N2 C8 -179.0(4) . . . . ?
C8 N2 C9 C12 177.4(5) . . . . ?
Pt1 N2 C9 C12 -6.0(8) . . . . ?
C8 N2 C9 C10 0.0(6) . . . . ?
Pt1 N2 C9 C10 176.6(3) . . . . ?
N2 C9 C10 C11 0.8(6) . . . . ?
C12 C9 C10 C11 -176.7(5) . . . . ?
C9 C10 C11 C8 -1.2(6) . . . . ?
N2 C8 C11 C10 1.2(6) . . . . ?
C7 C8 C11 C10 -178.2(5) . . . . ?
N2 C9 C12 C17 -177.5(5) . . . . ?
C10 C9 C12 C17 -0.4(8) . . . . ?
N2 C9 C12 C13 1.3(9) . . . . ?
C10 C9 C12 C13 178.3(5) . . . . ?
Pt1 O2 C13 C12 -3.3(8) . . . . ?
Pt1 O2 C13 C14 175.8(4) . . . . ?
C17 C12 C13 O2 -177.5(5) . . . . ?
C9 C12 C13 O2 3.7(8) . . . . ?
C17 C12 C13 C14 3.3(8) . . . . ?
C9 C12 C13 C14 -175.5(5) . . . . ?
O2 C13 C14 C15 178.7(5) . . . . ?
C12 C13 C14 C15 -2.1(8) . . . . ?
C13 C14 C15 C16 -0.5(9) . . . . ?
C14 C15 C16 C17 1.9(9) . . . . ?
C15 C16 C17 C12 -0.6(9) . . . . ?
C9 C12 C17 C16 176.8(5) . . . . ?
C13 C12 C17 C16 -2.1(8) . . . . ?
C4 C7 C18 C23 -90.7(6) . . . . ?
C8 C7 C18 C23 86.6(6) . . . . ?
C4 C7 C18 C19 88.4(7) . . . . ?
C8 C7 C18 C19 -94.4(6) . . . . ?
C23 C18 C19 C20 -0.6(8) . . . . ?
C7 C18 C19 C20 -179.6(5) . . . . ?
C23 C18 C19 C26 178.8(6) . . . . ?
C7 C18 C19 C26 -0.3(8) . . . . ?
C18 C19 C20 C21 -0.9(9) . . . . ?
C26 C19 C20 C21 179.8(6) . . . . ?
C19 C20 C21 C22 1.3(9) . . . . ?
C19 C20 C21 C25 -178.6(6) . . . . ?
C20 C21 C22 C23 -0.1(9) . . . . ?
C25 C21 C22 C23 179.8(6) . . . . ?
C21 C22 C23 C18 -1.3(9) . . . . ?
C21 C22 C23 C24 178.6(6) . . . . ?
C19 C18 C23 C22 1.7(8) . . . . ?
C7 C18 C23 C22 -179.3(5) . . . . ?
C19 C18 C23 C24 -178.2(5) . . . . ?
C7 C18 C23 C24 0.9(8) . . . . ?
C3 C2 C27 C28 177.2(6) . . . . ?
C1 C2 C27 C28 -1.5(9) . . . . ?
C2 C27 C28 C29 -1.7(10) . . . . ?
C27 C28 C29 C30 3.2(10) . . . . ?
C28 C29 C30 C1 -1.5(10) . . . . ?
O1 C1 C30 C29 177.8(5) . . . . ?
C2 C1 C30 C29 -1.8(9) . . . . ?

_diffrn_measured_fraction_theta_max 0.967
_diffrn_reflns_theta_full        27.59
_diffrn_measured_fraction_theta_full 0.967
_refine_diff_density_max         1.880
_refine_diff_density_min         -1.713
_refine_diff_density_rms         0.168
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_EtDpPt
_database_code_depnum_ccdc_archive 'CCDC 1434543'
_audit_update_record             
;
2016-01-29 deposited with the CCDC.
2016-02-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C29 H29 N2 O2 Pt'
_chemical_formula_weight         632.63

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           Pn21a
_symmetry_space_group_name_H-M   Pn21a

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x+1/2, y+1/2, z+1/2'
'x+1/2, y, -z+1/2'

_cell_length_a                   9.3473(4)
_cell_length_b                   12.3349(5)
_cell_length_c                   20.0843(8)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2315.68(16)
_cell_formula_units_Z            4
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    1968
_cell_measurement_theta_min      6.18
_cell_measurement_theta_max      28.24

_exptl_crystal_description       block
_exptl_crystal_colour            'deep green'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.815
_exptl_crystal_F_000             1244
_exptl_transmission_factor_min   0.486
_exptl_transmission_factor_max   0.833
_exptl_crystal_size_max          0.420
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.030
_exptl_absorpt_coefficient_mu    6.090
_shelx_estimated_absorpt_T_min   0.184
_shelx_estimated_absorpt_T_max   0.838
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.4408
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   
;
SADABS Sheldrick 1996
;
_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            33742
_diffrn_reflns_av_unetI/netI     0.0506
_diffrn_reflns_av_R_equivalents  0.0535
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.937
_diffrn_reflns_theta_max         32.846
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.957
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.957
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.957
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             7761
_reflns_number_gt                6753
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.923
_reflns_Friedel_fraction_max     0.956
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0405P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.030(10)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         7761
_refine_ls_number_parameters     312
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0396
_refine_ls_R_factor_gt           0.0319
_refine_ls_wR_factor_ref         0.0763
_refine_ls_wR_factor_gt          0.0727
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_restrained_S_all      1.019
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.91958(2) 0.25028(5) 0.19359(2) 0.01524(6) Uani 1 1 d . . . . .
N1 N 1.0530(4) 0.1306(4) 0.2111(2) 0.0152(8) Uani 1 1 d . . . . .
C2 C 1.2125(5) -0.0105(5) 0.2007(2) 0.0165(10) Uani 1 1 d . . . . .
C3 C 1.0980(5) 0.0984(5) 0.2733(2) 0.0161(10) Uani 1 1 d . . . . .
C4 C 1.1999(5) 0.0119(5) 0.2673(2) 0.0162(9) Uani 1 1 d . . . . .
C5 C 1.0444(6) 0.1429(5) 0.3323(2) 0.0192(11) Uani 1 1 d . . . . .
H1 H 1.0827 0.1144 0.3725 0.023 Uiso 1 1 calc R U . . .
C6 C 0.9436(5) 0.2226(4) 0.3392(2) 0.0181(13) Uani 1 1 d . . . . .
C7 C 1.1204(5) 0.0652(5) 0.1653(2) 0.0172(10) Uani 1 1 d . . . . .
O1 O 0.9538(4) 0.2388(5) 0.09683(15) 0.0216(9) Uani 1 1 d . . . . .
C11 C 0.8917(5) 0.2638(7) 0.4015(2) 0.0184(14) Uani 1 1 d . . . . .
N2 N 0.8781(4) 0.2780(4) 0.28834(19) 0.0157(10) Uani 1 1 d . . . . .
C13 C 0.9414(5) 0.2258(5) 0.4677(2) 0.0220(15) Uani 1 1 d . . . . .
H10 H 0.9582 0.1466 0.4656 0.026 Uiso 1 1 calc R U . . .
H11 H 0.8650 0.2390 0.5008 0.026 Uiso 1 1 calc R U . . .
C9 C 1.0988(5) 0.0757(5) 0.0943(3) 0.0193(11) Uani 1 1 d . . . . .
C10 C 1.0251(6) 0.1655(5) 0.0648(2) 0.0210(11) Uani 1 1 d . . . . .
C15 C 1.1503(6) -0.0054(5) 0.0497(2) 0.0228(11) Uani 1 1 d . . . . .
H2 H 1.1894 -0.0703 0.0677 0.027 Uiso 1 1 calc R U . . .
C16 C 1.0884(6) 0.1016(6) -0.0457(3) 0.0255(13) Uani 1 1 d . . . . .
H3 H 1.0917 0.1130 -0.0925 0.031 Uiso 1 1 calc R U . . .
C17 C 1.0283(6) 0.1776(5) -0.0054(2) 0.0233(11) Uani 1 1 d . . . . .
H4 H 0.9873 0.2406 -0.0248 0.028 Uiso 1 1 calc R U . . .
C18 C 1.1453(6) 0.0069(5) -0.0183(2) 0.0251(12) Uani 1 1 d . . . . .
H5 H 1.1804 -0.0489 -0.0466 0.030 Uiso 1 1 calc R U . . .
O2 O 0.7881(4) 0.3655(3) 0.16629(17) 0.0218(8) Uani 1 1 d . . . . .
C19 C 0.7877(5) 0.3534(5) 0.3150(2) 0.0145(9) Uani 1 1 d . . . . .
C29 C 1.2788(5) -0.0394(5) 0.3245(3) 0.0194(11) Uani 1 1 d . . . . .
H12 H 1.2978 0.0169 0.3585 0.023 Uiso 1 1 calc R U . . .
H13 H 1.3724 -0.0659 0.3082 0.023 Uiso 1 1 calc R U . . .
C20 C 0.7180(6) 0.4071(5) 0.4420(2) 0.0216(11) Uani 1 1 d . . . . .
H14 H 0.6176 0.4194 0.4283 0.026 Uiso 1 1 calc R U . . .
H15 H 0.7165 0.3635 0.4834 0.026 Uiso 1 1 calc R U . . .
C21 C 0.6068(7) 0.4991(7) 0.3053(2) 0.0277(15) Uani 1 1 d . . . . .
H6 H 0.6003 0.4999 0.3525 0.033 Uiso 1 1 calc R U . . .
C22 C 0.6203(6) 0.5022(6) 0.1680(3) 0.0261(12) Uani 1 1 d . . . . .
H7 H 0.6244 0.5034 0.1208 0.031 Uiso 1 1 calc R U . . .
C23 C 0.7035(5) 0.4241(5) 0.2752(2) 0.0169(10) Uani 1 1 d . . . . .
C24 C 0.7874(7) 0.5156(5) 0.4566(3) 0.0304(14) Uani 1 1 d . . . . .
H18 H 0.7867 0.5602 0.4162 0.046 Uiso 1 1 calc R U . . .
H19 H 0.8864 0.5040 0.4711 0.046 Uiso 1 1 calc R U . . .
H20 H 0.7340 0.5526 0.4919 0.046 Uiso 1 1 calc R U . . .
C25 C 0.7078(6) 0.4281(6) 0.2034(2) 0.0196(11) Uani 1 1 d . . . . .
C26 C 0.7940(5) 0.3431(5) 0.3880(2) 0.0185(10) Uani 1 1 d . . . . .
C27 C 0.5308(7) 0.5715(6) 0.2000(3) 0.0250(12) Uani 1 1 d . . . . .
H8 H 0.4738 0.6209 0.1753 0.030 Uiso 1 1 calc R U . . .
C28 C 0.5230(6) 0.5698(6) 0.2704(3) 0.0277(13) Uani 1 1 d . . . . .
H9 H 0.4599 0.6175 0.2931 0.033 Uiso 1 1 calc R U . . .
C30 C 1.2000(6) -0.1340(6) 0.3579(3) 0.0298(13) Uani 1 1 d . . . . .
H21 H 1.1752 -0.1884 0.3243 0.045 Uiso 1 1 calc R U . . .
H22 H 1.1124 -0.1071 0.3791 0.045 Uiso 1 1 calc R U . . .
H23 H 1.2619 -0.1669 0.3917 0.045 Uiso 1 1 calc R U . . .
C31 C 1.3089(6) -0.0973(6) 0.1740(3) 0.0284(13) Uani 1 1 d . . . . .
H16 H 1.3914 -0.1063 0.2044 0.034 Uiso 1 1 calc R U . . .
H17 H 1.3463 -0.0744 0.1301 0.034 Uiso 1 1 calc R U . . .
C1 C 1.2326(8) -0.2058(6) 0.1665(3) 0.0423(18) Uani 1 1 d . . . . .
H24 H 1.1421 -0.1951 0.1427 0.063 Uiso 1 1 calc R U . . .
H25 H 1.2133 -0.2363 0.2106 0.063 Uiso 1 1 calc R U . . .
H26 H 1.2933 -0.2558 0.1412 0.063 Uiso 1 1 calc R U . . .
C32 C 1.0783(5) 0.2816(6) 0.4908(3) 0.0314(16) Uani 1 1 d . . . . .
H27 H 1.0583 0.3581 0.5002 0.047 Uiso 1 1 calc R U . . .
H28 H 1.1510 0.2763 0.4558 0.047 Uiso 1 1 calc R U . . .
H29 H 1.1134 0.2462 0.5313 0.047 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 O2 1.957(4) . ?
Pt1 N1 1.964(5) . ?
Pt1 N2 1.972(4) . ?
Pt1 O1 1.975(3) . ?
N1 C7 1.376(7) . ?
N1 C3 1.377(7) . ?
C2 C4 1.372(6) . ?
C2 C7 1.456(8) . ?
C2 C31 1.498(8) . ?
C3 C5 1.399(7) . ?
C3 C4 1.435(8) . ?
C4 C29 1.505(7) . ?
C5 C6 1.369(7) . ?
C5 H1 0.9500 . ?
C6 N2 1.373(7) . ?
C6 C11 1.435(7) . ?
C7 C9 1.445(7) . ?
O1 C10 1.294(7) . ?
C11 C26 1.365(9) . ?
C11 C13 1.484(7) . ?
N2 C19 1.366(7) . ?
C13 C32 1.526(7) . ?
C13 H10 0.9900 . ?
C13 H11 0.9900 . ?
C9 C15 1.426(8) . ?
C9 C10 1.434(8) . ?
C10 C17 1.418(7) . ?
C15 C18 1.376(7) . ?
C15 H2 0.9500 . ?
C16 C17 1.360(8) . ?
C16 C18 1.397(9) . ?
C16 H3 0.9500 . ?
C17 H4 0.9500 . ?
C18 H5 0.9500 . ?
O2 C25 1.310(7) . ?
C19 C23 1.421(7) . ?
C19 C26 1.474(6) . ?
C29 C30 1.534(8) . ?
C29 H12 0.9900 . ?
C29 H13 0.9900 . ?
C20 C24 1.516(9) . ?
C20 C26 1.519(7) . ?
C20 H14 0.9900 . ?
C20 H15 0.9900 . ?
C21 C28 1.366(9) . ?
C21 C23 1.429(8) . ?
C21 H6 0.9500 . ?
C22 C27 1.358(9) . ?
C22 C25 1.417(8) . ?
C22 H7 0.9500 . ?
C23 C25 1.442(7) . ?
C24 H18 0.9800 . ?
C24 H19 0.9800 . ?
C24 H20 0.9800 . ?
C27 C28 1.415(7) . ?
C27 H8 0.9500 . ?
C28 H9 0.9500 . ?
C30 H21 0.9800 . ?
C30 H22 0.9800 . ?
C30 H23 0.9800 . ?
C31 C1 1.524(10) . ?
C31 H16 0.9900 . ?
C31 H17 0.9900 . ?
C1 H24 0.9800 . ?
C1 H25 0.9800 . ?
C1 H26 0.9800 . ?
C32 H27 0.9800 . ?
C32 H28 0.9800 . ?
C32 H29 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Pt1 N1 174.01(16) . . ?
O2 Pt1 N2 91.22(16) . . ?
N1 Pt1 N2 94.71(18) . . ?
O2 Pt1 O1 82.99(17) . . ?
N1 Pt1 O1 91.12(19) . . ?
N2 Pt1 O1 173.8(2) . . ?
C7 N1 C3 107.3(5) . . ?
C7 N1 Pt1 127.7(4) . . ?
C3 N1 Pt1 125.0(4) . . ?
C4 C2 C7 107.2(5) . . ?
C4 C2 C31 123.0(5) . . ?
C7 C2 C31 129.7(4) . . ?
N1 C3 C5 123.1(5) . . ?
N1 C3 C4 110.0(4) . . ?
C5 C3 C4 126.9(5) . . ?
C2 C4 C3 106.8(5) . . ?
C2 C4 C29 128.2(5) . . ?
C3 C4 C29 125.1(4) . . ?
C6 C5 C3 127.8(5) . . ?
C6 C5 H1 116.1 . . ?
C3 C5 H1 116.1 . . ?
C5 C6 N2 126.1(4) . . ?
C5 C6 C11 125.1(5) . . ?
N2 C6 C11 108.8(5) . . ?
N1 C7 C9 122.9(5) . . ?
N1 C7 C2 108.7(4) . . ?
C9 C7 C2 128.4(5) . . ?
C10 O1 Pt1 128.5(4) . . ?
C26 C11 C6 107.8(4) . . ?
C26 C11 C13 127.9(5) . . ?
C6 C11 C13 124.3(5) . . ?
C19 N2 C6 108.9(4) . . ?
C19 N2 Pt1 128.1(3) . . ?
C6 N2 Pt1 123.0(3) . . ?
C11 C13 C32 113.1(5) . . ?
C11 C13 H10 109.0 . . ?
C32 C13 H10 109.0 . . ?
C11 C13 H11 109.0 . . ?
C32 C13 H11 109.0 . . ?
H10 C13 H11 107.8 . . ?
C15 C9 C10 116.4(5) . . ?
C15 C9 C7 120.6(5) . . ?
C10 C9 C7 123.0(5) . . ?
O1 C10 C17 115.6(5) . . ?
O1 C10 C9 125.6(5) . . ?
C17 C10 C9 118.9(5) . . ?
C18 C15 C9 122.3(6) . . ?
C18 C15 H2 118.8 . . ?
C9 C15 H2 118.8 . . ?
C17 C16 C18 120.0(5) . . ?
C17 C16 H3 120.0 . . ?
C18 C16 H3 120.0 . . ?
C16 C17 C10 121.9(6) . . ?
C16 C17 H4 119.1 . . ?
C10 C17 H4 119.1 . . ?
C15 C18 C16 119.8(5) . . ?
C15 C18 H5 120.1 . . ?
C16 C18 H5 120.1 . . ?
C25 O2 Pt1 128.9(3) . . ?
N2 C19 C23 122.7(4) . . ?
N2 C19 C26 107.8(4) . . ?
C23 C19 C26 129.5(5) . . ?
C4 C29 C30 114.7(4) . . ?
C4 C29 H12 108.6 . . ?
C30 C29 H12 108.6 . . ?
C4 C29 H13 108.6 . . ?
C30 C29 H13 108.6 . . ?
H12 C29 H13 107.6 . . ?
C24 C20 C26 113.4(5) . . ?
C24 C20 H14 108.9 . . ?
C26 C20 H14 108.9 . . ?
C24 C20 H15 108.9 . . ?
C26 C20 H15 108.9 . . ?
H14 C20 H15 107.7 . . ?
C28 C21 C23 123.9(5) . . ?
C28 C21 H6 118.0 . . ?
C23 C21 H6 118.0 . . ?
C27 C22 C25 121.6(5) . . ?
C27 C22 H7 119.2 . . ?
C25 C22 H7 119.2 . . ?
C19 C23 C21 120.6(4) . . ?
C19 C23 C25 124.6(5) . . ?
C21 C23 C25 114.8(5) . . ?
C20 C24 H18 109.5 . . ?
C20 C24 H19 109.5 . . ?
H18 C24 H19 109.5 . . ?
C20 C24 H20 109.5 . . ?
H18 C24 H20 109.5 . . ?
H19 C24 H20 109.5 . . ?
O2 C25 C22 115.2(5) . . ?
O2 C25 C23 124.4(5) . . ?
C22 C25 C23 120.5(5) . . ?
C11 C26 C19 106.7(4) . . ?
C11 C26 C20 122.9(4) . . ?
C19 C26 C20 130.4(5) . . ?
C22 C27 C28 119.7(5) . . ?
C22 C27 H8 120.2 . . ?
C28 C27 H8 120.2 . . ?
C21 C28 C27 119.5(5) . . ?
C21 C28 H9 120.2 . . ?
C27 C28 H9 120.2 . . ?
C29 C30 H21 109.5 . . ?
C29 C30 H22 109.5 . . ?
H21 C30 H22 109.5 . . ?
C29 C30 H23 109.5 . . ?
H21 C30 H23 109.5 . . ?
H22 C30 H23 109.5 . . ?
C2 C31 C1 112.4(5) . . ?
C2 C31 H16 109.1 . . ?
C1 C31 H16 109.1 . . ?
C2 C31 H17 109.1 . . ?
C1 C31 H17 109.1 . . ?
H16 C31 H17 107.8 . . ?
C31 C1 H24 109.5 . . ?
C31 C1 H25 109.5 . . ?
H24 C1 H25 109.5 . . ?
C31 C1 H26 109.5 . . ?
H24 C1 H26 109.5 . . ?
H25 C1 H26 109.5 . . ?
C13 C32 H27 109.5 . . ?
C13 C32 H28 109.5 . . ?
H27 C32 H28 109.5 . . ?
C13 C32 H29 109.5 . . ?
H27 C32 H29 109.5 . . ?
H28 C32 H29 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 N1 C3 C5 -176.0(5) . . . . ?
Pt1 N1 C3 C5 5.0(7) . . . . ?
C7 N1 C3 C4 1.6(6) . . . . ?
Pt1 N1 C3 C4 -177.4(3) . . . . ?
C7 C2 C4 C3 1.7(6) . . . . ?
C31 C2 C4 C3 -179.5(5) . . . . ?
C7 C2 C4 C29 -176.5(5) . . . . ?
C31 C2 C4 C29 2.3(9) . . . . ?
N1 C3 C4 C2 -2.1(6) . . . . ?
C5 C3 C4 C2 175.4(5) . . . . ?
N1 C3 C4 C29 176.2(5) . . . . ?
C5 C3 C4 C29 -6.3(9) . . . . ?
N1 C3 C5 C6 -0.3(9) . . . . ?
C4 C3 C5 C6 -177.5(5) . . . . ?
C3 C5 C6 N2 -2.6(9) . . . . ?
C3 C5 C6 C11 179.1(6) . . . . ?
C3 N1 C7 C9 180.0(5) . . . . ?
Pt1 N1 C7 C9 -1.1(8) . . . . ?
C3 N1 C7 C2 -0.5(6) . . . . ?
Pt1 N1 C7 C2 178.5(4) . . . . ?
C4 C2 C7 N1 -0.8(6) . . . . ?
C31 C2 C7 N1 -179.5(6) . . . . ?
C4 C2 C7 C9 178.7(5) . . . . ?
C31 C2 C7 C9 0.0(10) . . . . ?
C5 C6 C11 C26 179.2(5) . . . . ?
N2 C6 C11 C26 0.7(7) . . . . ?
C5 C6 C11 C13 0.3(10) . . . . ?
N2 C6 C11 C13 -178.2(6) . . . . ?
C5 C6 N2 C19 -178.0(5) . . . . ?
C11 C6 N2 C19 0.5(6) . . . . ?
C5 C6 N2 Pt1 0.3(7) . . . . ?
C11 C6 N2 Pt1 178.8(4) . . . . ?
C26 C11 C13 C32 -94.6(7) . . . . ?
C6 C11 C13 C32 84.1(8) . . . . ?
N1 C7 C9 C15 -168.7(5) . . . . ?
C2 C7 C9 C15 11.9(9) . . . . ?
N1 C7 C9 C10 10.8(8) . . . . ?
C2 C7 C9 C10 -168.6(5) . . . . ?
Pt1 O1 C10 C17 178.6(4) . . . . ?
Pt1 O1 C10 C9 -1.3(8) . . . . ?
C15 C9 C10 O1 169.7(5) . . . . ?
C7 C9 C10 O1 -9.8(9) . . . . ?
C15 C9 C10 C17 -10.1(7) . . . . ?
C7 C9 C10 C17 170.3(5) . . . . ?
C10 C9 C15 C18 7.4(8) . . . . ?
C7 C9 C15 C18 -173.0(5) . . . . ?
C18 C16 C17 C10 2.0(8) . . . . ?
O1 C10 C17 C16 -174.1(5) . . . . ?
C9 C10 C17 C16 5.8(8) . . . . ?
C9 C15 C18 C16 0.1(9) . . . . ?
C17 C16 C18 C15 -5.1(8) . . . . ?
C6 N2 C19 C23 -179.9(5) . . . . ?
Pt1 N2 C19 C23 1.9(7) . . . . ?
C6 N2 C19 C26 -1.4(6) . . . . ?
Pt1 N2 C19 C26 -179.6(3) . . . . ?
C2 C4 C29 C30 -94.4(7) . . . . ?
C3 C4 C29 C30 87.6(7) . . . . ?
N2 C19 C23 C21 177.8(6) . . . . ?
C26 C19 C23 C21 -0.3(9) . . . . ?
N2 C19 C23 C25 -2.8(9) . . . . ?
C26 C19 C23 C25 179.0(5) . . . . ?
C28 C21 C23 C19 179.7(7) . . . . ?
C28 C21 C23 C25 0.3(10) . . . . ?
Pt1 O2 C25 C22 -178.1(4) . . . . ?
Pt1 O2 C25 C23 1.0(9) . . . . ?
C27 C22 C25 O2 179.5(6) . . . . ?
C27 C22 C25 C23 0.3(10) . . . . ?
C19 C23 C25 O2 1.3(9) . . . . ?
C21 C23 C25 O2 -179.3(6) . . . . ?
C19 C23 C25 C22 -179.5(5) . . . . ?
C21 C23 C25 C22 -0.1(8) . . . . ?
C6 C11 C26 C19 -1.5(7) . . . . ?
C13 C11 C26 C19 177.3(6) . . . . ?
C6 C11 C26 C20 -178.8(5) . . . . ?
C13 C11 C26 C20 0.0(10) . . . . ?
N2 C19 C26 C11 1.8(6) . . . . ?
C23 C19 C26 C11 -179.8(6) . . . . ?
N2 C19 C26 C20 178.9(5) . . . . ?
C23 C19 C26 C20 -2.7(10) . . . . ?
C24 C20 C26 C11 96.8(7) . . . . ?
C24 C20 C26 C19 -79.8(7) . . . . ?
C25 C22 C27 C28 -0.5(11) . . . . ?
C23 C21 C28 C27 -0.6(12) . . . . ?
C22 C27 C28 C21 0.7(11) . . . . ?
C4 C2 C31 C1 91.9(7) . . . . ?
C7 C2 C31 C1 -89.6(7) . . . . ?

_refine_diff_density_max         2.741
_refine_diff_density_min         -3.518
_refine_diff_density_rms         0.187

_shelxl_version_number           2014-3

