# Electronic Supplementary Material (ESI) for Green Chemistry.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1045185'
_audit_update_record             
;
2015-01-23 deposited with the CCDC.
2015-05-14 downloaded from the CCDC.
;
#==========================================================


_audit_creation_method           SHELXL-97
_chemical_name_systematic        3
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C49 H42 Au2 Cl2 N2 O4 P4 S2'
_chemical_formula_sum            'C49 H42 Au2 Cl2 N2 O4 P4 S2'
_chemical_formula_weight         1375.37

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0180 0.0090 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4200 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3640 0.7020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0310 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0490 0.0320 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2960 0.4330 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3330 0.5570 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/c 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   25.848(2)
_cell_length_b                   11.2564(5)
_cell_length_c                   20.6909(16)
_cell_angle_alpha                90.00
_cell_angle_beta                 122.413(11)
_cell_angle_gamma                90.00
_cell_volume                     5082.2(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    297(14)
_cell_measurement_reflns_used    6519
_cell_measurement_theta_min      4.4640
_cell_measurement_theta_max      68.8700

_exptl_crystal_description       block
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_size_max          0.2000
_exptl_crystal_size_mid          0.0400
_exptl_crystal_size_min          0.0200
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_diffrn    1.797
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             2280
_exptl_absorpt_coefficient_mu    13.989
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.29165
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;


_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      297(14)
_diffrn_radiation_wavelength     1.54180
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'Nova (Cu) X-ray Source'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'Xcalibur, Onyx, Nova'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean 8.2640
_diffrn_standards_number         6313
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            12034
_diffrn_reflns_av_R_equivalents  0.0352
_diffrn_reflns_av_sigmaI/netI    0.0368
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         4.48
_diffrn_reflns_theta_max         69.56
_reflns_number_total             4673
_reflns_number_gt                4020
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0536P)²+23.0145P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4673
_refine_ls_number_parameters     298
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0497
_refine_ls_R_factor_gt           0.0428
_refine_ls_wR_factor_ref         0.1241
_refine_ls_wR_factor_gt          0.1171
_refine_ls_goodness_of_fit_ref   1.129
_refine_ls_restrained_S_all      1.129
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5000 0.6647(7) 0.7500 0.0437(17) Uani 1 2 d S . .
C2 C 0.3695(3) 0.6448(6) 0.6811(3) 0.0469(13) Uani 1 1 d . . .
C3 C 0.3114(3) 0.6921(8) 0.6383(5) 0.073(2) Uani 1 1 d . . .
H3 H 0.3059 0.7741 0.6351 0.088 Uiso 1 1 calc R . .
C4 C 0.2617(4) 0.6176(10) 0.6004(7) 0.100(3) Uani 1 1 d . . .
H4 H 0.2225 0.6498 0.5712 0.120 Uiso 1 1 calc R . .
C5 C 0.2688(4) 0.4974(9) 0.6051(7) 0.090(3) Uani 1 1 d . . .
H5 H 0.2347 0.4481 0.5790 0.107 Uiso 1 1 calc R . .
C6 C 0.3265(4) 0.4490(7) 0.6483(5) 0.073(2) Uani 1 1 d . . .
H6 H 0.3314 0.3670 0.6522 0.088 Uiso 1 1 calc R . .
C7 C 0.3776(4) 0.5230(6) 0.6861(4) 0.0577(16) Uani 1 1 d . . .
H7 H 0.4168 0.4906 0.7145 0.069 Uiso 1 1 calc R . .
C8 C 0.4202(3) 0.8682(5) 0.6712(3) 0.0449(13) Uani 1 1 d . . .
C9 C 0.4221(4) 0.9829(6) 0.6962(5) 0.070(2) Uani 1 1 d . . .
H9 H 0.4278 0.9960 0.7440 0.084 Uiso 1 1 calc R . .
C10 C 0.4154(5) 1.0780(7) 0.6501(6) 0.090(3) Uani 1 1 d . . .
H10 H 0.4167 1.1552 0.6669 0.108 Uiso 1 1 calc R . .
C11 C 0.4069(5) 1.0588(9) 0.5800(6) 0.088(3) Uani 1 1 d . . .
H11 H 0.4028 1.1233 0.5495 0.106 Uiso 1 1 calc R . .
C12 C 0.4045(4) 0.9466(9) 0.5541(5) 0.076(2) Uani 1 1 d . . .
H12 H 0.3982 0.9350 0.5059 0.092 Uiso 1 1 calc R . .
C13 C 0.4113(3) 0.8485(7) 0.5998(4) 0.0589(17) Uani 1 1 d . . .
H13 H 0.4098 0.7715 0.5824 0.071 Uiso 1 1 calc R . .
C14 C 0.3569(3) 0.6083(7) 0.8811(4) 0.0562(16) Uani 1 1 d . . .
C15 C 0.3565(4) 0.4877(7) 0.8741(6) 0.077(2) Uani 1 1 d . . .
H15 H 0.3707 0.4528 0.8456 0.092 Uiso 1 1 calc R . .
C16 C 0.3351(4) 0.4184(9) 0.9096(6) 0.091(3) Uani 1 1 d . . .
H16 H 0.3340 0.3363 0.9039 0.109 Uiso 1 1 calc R . .
C17 C 0.3158(6) 0.4664(12) 0.9522(7) 0.104(4) Uani 1 1 d . . .
H17 H 0.3016 0.4184 0.9761 0.125 Uiso 1 1 calc R . .
C18 C 0.3172(6) 0.5877(12) 0.9602(7) 0.111(4) Uani 1 1 d . . .
H18 H 0.3047 0.6215 0.9907 0.133 Uiso 1 1 calc R . .
C19 C 0.3370(5) 0.6609(9) 0.9234(5) 0.088(3) Uani 1 1 d . . .
H19 H 0.3368 0.7431 0.9276 0.106 Uiso 1 1 calc R . .
C20 C 0.3921(3) 0.9703(6) 0.8647(4) 0.0537(15) Uani 1 1 d . . .
C21 C 0.3318(4) 0.9663(9) 0.8100(6) 0.090(3) Uani 1 1 d . . .
H21 H 0.3095 0.8969 0.8012 0.108 Uiso 1 1 calc R . .
C22 C 0.3041(5) 1.0667(11) 0.7677(8) 0.119(4) Uani 1 1 d . . .
H22 H 0.2628 1.0647 0.7292 0.142 Uiso 1 1 calc R . .
C23 C 0.3365(6) 1.1694(9) 0.7813(7) 0.104(3) Uani 1 1 d . . .
H23 H 0.3171 1.2371 0.7527 0.125 Uiso 1 1 calc R . .
C24 C 0.3973(5) 1.1724(8) 0.8369(6) 0.085(3) Uani 1 1 d . . .
H24 H 0.4195 1.2421 0.8461 0.101 Uiso 1 1 calc R . .
C25 C 0.4259(4) 1.0718(7) 0.8796(5) 0.070(2) Uani 1 1 d . . .
H25 H 0.4673 1.0730 0.9177 0.084 Uiso 1 1 calc R . .
Au1 Au 0.513027(15) 0.51581(3) 0.913782(18) 0.06322(14) Uani 1 1 d . . .
Cl1 Cl 0.52206(13) 0.3566(2) 0.85423(15) 0.0910(7) Uani 1 1 d . . .
N1 N 0.4411(2) 0.7950(4) 0.8093(3) 0.0459(11) Uani 1 1 d . . .
O1 O 0.3745(2) 0.6762(4) 0.8393(2) 0.0535(10) Uani 1 1 d . . .
O2 O 0.4228(2) 0.8704(4) 0.9107(3) 0.0602(12) Uani 1 1 d . . .
P1 P 0.43301(7) 0.74556(12) 0.73267(8) 0.0395(3) Uani 1 1 d . . .
P2 P 0.43488(7) 0.75519(13) 0.87614(9) 0.0454(3) Uani 1 1 d . . .
S1 S 0.50423(9) 0.68076(17) 0.97012(10) 0.0648(4) Uani 1 1 d . . .
H1 H 0.490(3) 0.617(6) 0.710(4) 0.056(19) Uiso 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 P1 1.814(4) . ?
C1 P1 1.814(4) 2_656 ?
C1 H1 0.90(7) . ?
C2 C3 1.378(10) . ?
C2 C7 1.383(9) . ?
C2 P1 1.800(6) . ?
C3 C4 1.376(12) . ?
C3 H3 0.9300 . ?
C4 C5 1.363(14) . ?
C4 H4 0.9300 . ?
C5 C6 1.374(14) . ?
C5 H5 0.9300 . ?
C6 C7 1.393(11) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C8 C9 1.382(10) . ?
C8 C13 1.386(9) . ?
C8 P1 1.784(6) . ?
C9 C10 1.383(11) . ?
C9 H9 0.9300 . ?
C10 C11 1.362(14) . ?
C10 H10 0.9300 . ?
C11 C12 1.360(15) . ?
C11 H11 0.9300 . ?
C12 C13 1.402(11) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 C19 1.365(11) . ?
C14 C15 1.364(11) . ?
C14 O1 1.401(7) . ?
C15 C16 1.377(12) . ?
C15 H15 0.9300 . ?
C16 C17 1.339(16) . ?
C16 H16 0.9300 . ?
C17 C18 1.373(18) . ?
C17 H17 0.9300 . ?
C18 C19 1.393(13) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C21 1.349(12) . ?
C20 C25 1.369(11) . ?
C20 O2 1.411(9) . ?
C21 C22 1.372(15) . ?
C21 H21 0.9300 . ?
C22 C23 1.364(17) . ?
C22 H22 0.9300 . ?
C23 C24 1.362(15) . ?
C23 H23 0.9300 . ?
C24 C25 1.381(13) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
Au1 Cl1 2.257(2) . ?
Au1 S1 2.268(2) . ?
N1 P2 1.543(5) . ?
N1 P1 1.584(5) . ?
O1 P2 1.591(5) . ?
O2 P2 1.591(5) . ?
P2 S1 1.990(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 C1 P1 119.7(5) . 2_656 ?
P1 C1 H1 111(4) . . ?
P1 C1 H1 105(4) 2_656 . ?
C3 C2 C7 120.0(7) . . ?
C3 C2 P1 118.1(5) . . ?
C7 C2 P1 121.9(5) . . ?
C4 C3 C2 119.7(8) . . ?
C4 C3 H3 120.2 . . ?
C2 C3 H3 120.2 . . ?
C5 C4 C3 121.0(9) . . ?
C5 C4 H4 119.5 . . ?
C3 C4 H4 119.5 . . ?
C4 C5 C6 119.9(8) . . ?
C4 C5 H5 120.1 . . ?
C6 C5 H5 120.1 . . ?
C5 C6 C7 120.0(8) . . ?
C5 C6 H6 120.0 . . ?
C7 C6 H6 120.0 . . ?
C2 C7 C6 119.4(8) . . ?
C2 C7 H7 120.3 . . ?
C6 C7 H7 120.3 . . ?
C9 C8 C13 120.1(6) . . ?
C9 C8 P1 120.0(5) . . ?
C13 C8 P1 119.8(5) . . ?
C8 C9 C10 119.8(8) . . ?
C8 C9 H9 120.1 . . ?
C10 C9 H9 120.1 . . ?
C11 C10 C9 120.1(9) . . ?
C11 C10 H10 119.9 . . ?
C9 C10 H10 119.9 . . ?
C12 C11 C10 120.9(7) . . ?
C12 C11 H11 119.5 . . ?
C10 C11 H11 119.5 . . ?
C11 C12 C13 120.2(8) . . ?
C11 C12 H12 119.9 . . ?
C13 C12 H12 119.9 . . ?
C8 C13 C12 118.8(7) . . ?
C8 C13 H13 120.6 . . ?
C12 C13 H13 120.6 . . ?
C19 C14 C15 121.1(7) . . ?
C19 C14 O1 121.2(7) . . ?
C15 C14 O1 117.5(7) . . ?
C14 C15 C16 119.2(9) . . ?
C14 C15 H15 120.4 . . ?
C16 C15 H15 120.4 . . ?
C17 C16 C15 121.5(10) . . ?
C17 C16 H16 119.3 . . ?
C15 C16 H16 119.3 . . ?
C16 C17 C18 119.1(9) . . ?
C16 C17 H17 120.5 . . ?
C18 C17 H17 120.5 . . ?
C17 C18 C19 121.1(10) . . ?
C17 C18 H18 119.5 . . ?
C19 C18 H18 119.5 . . ?
C14 C19 C18 118.0(10) . . ?
C14 C19 H19 121.0 . . ?
C18 C19 H19 121.0 . . ?
C21 C20 C25 121.8(8) . . ?
C21 C20 O2 121.2(7) . . ?
C25 C20 O2 116.9(7) . . ?
C20 C21 C22 118.7(9) . . ?
C20 C21 H21 120.6 . . ?
C22 C21 H21 120.6 . . ?
C23 C22 C21 120.9(10) . . ?
C23 C22 H22 119.5 . . ?
C21 C22 H22 119.5 . . ?
C22 C23 C24 119.8(9) . . ?
C22 C23 H23 120.1 . . ?
C24 C23 H23 120.1 . . ?
C23 C24 C25 120.0(9) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 H24 120.0 . . ?
C20 C25 C24 118.8(8) . . ?
C20 C25 H25 120.6 . . ?
C24 C25 H25 120.6 . . ?
Cl1 Au1 S1 177.60(7) . . ?
P2 N1 P1 140.7(3) . . ?
C14 O1 P2 124.7(4) . . ?
C20 O2 P2 121.4(4) . . ?
N1 P1 C8 108.4(3) . . ?
N1 P1 C2 113.8(3) . . ?
C8 P1 C2 107.7(3) . . ?
N1 P1 C1 112.2(2) . . ?
C8 P1 C1 108.8(3) . . ?
C2 P1 C1 105.7(3) . . ?
N1 P2 O1 106.2(3) . . ?
N1 P2 O2 107.9(3) . . ?
O1 P2 O2 107.1(3) . . ?
N1 P2 S1 121.8(2) . . ?
O1 P2 S1 111.78(19) . . ?
O2 P2 S1 101.2(2) . . ?
P2 S1 Au1 97.38(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 C2 C3 C4 -0.3(12) . . . . ?
P1 C2 C3 C4 -177.6(8) . . . . ?
C2 C3 C4 C5 0.6(17) . . . . ?
C3 C4 C5 C6 0.1(18) . . . . ?
C4 C5 C6 C7 -1.1(16) . . . . ?
C3 C2 C7 C6 -0.7(11) . . . . ?
P1 C2 C7 C6 176.5(6) . . . . ?
C5 C6 C7 C2 1.4(12) . . . . ?
C13 C8 C9 C10 -0.5(13) . . . . ?
P1 C8 C9 C10 176.6(7) . . . . ?
C8 C9 C10 C11 0.1(15) . . . . ?
C9 C10 C11 C12 0.5(16) . . . . ?
C10 C11 C12 C13 -0.7(14) . . . . ?
C9 C8 C13 C12 0.3(11) . . . . ?
P1 C8 C13 C12 -176.8(5) . . . . ?
C11 C12 C13 C8 0.3(12) . . . . ?
C19 C14 C15 C16 0.8(14) . . . . ?
O1 C14 C15 C16 -175.1(8) . . . . ?
C14 C15 C16 C17 -1.5(16) . . . . ?
C15 C16 C17 C18 0.3(18) . . . . ?
C16 C17 C18 C19 1.4(19) . . . . ?
C15 C14 C19 C18 0.9(15) . . . . ?
O1 C14 C19 C18 176.7(9) . . . . ?
C17 C18 C19 C14 -2.0(18) . . . . ?
C25 C20 C21 C22 0.9(15) . . . . ?
O2 C20 C21 C22 179.0(10) . . . . ?
C20 C21 C22 C23 -1(2) . . . . ?
C21 C22 C23 C24 1(2) . . . . ?
C22 C23 C24 C25 -0.4(17) . . . . ?
C21 C20 C25 C24 -0.5(12) . . . . ?
O2 C20 C25 C24 -178.6(7) . . . . ?
C23 C24 C25 C20 0.2(13) . . . . ?
C19 C14 O1 P2 70.4(9) . . . . ?
C15 C14 O1 P2 -113.7(7) . . . . ?
C21 C20 O2 P2 69.3(9) . . . . ?
C25 C20 O2 P2 -112.5(6) . . . . ?
P2 N1 P1 C8 156.5(5) . . . . ?
P2 N1 P1 C2 36.7(7) . . . . ?
P2 N1 P1 C1 -83.3(6) . . . . ?
C9 C8 P1 N1 3.4(7) . . . . ?
C13 C8 P1 N1 -179.5(5) . . . . ?
C9 C8 P1 C2 126.9(6) . . . . ?
C13 C8 P1 C2 -56.0(6) . . . . ?
C9 C8 P1 C1 -118.9(6) . . . . ?
C13 C8 P1 C1 58.2(6) . . . . ?
C3 C2 P1 N1 77.9(6) . . . . ?
C7 C2 P1 N1 -99.3(6) . . . . ?
C3 C2 P1 C8 -42.3(6) . . . . ?
C7 C2 P1 C8 140.4(5) . . . . ?
C3 C2 P1 C1 -158.4(5) . . . . ?
C7 C2 P1 C1 24.3(6) . . . . ?
P1 C1 P1 N1 -78.4(2) 2_656 . . . ?
P1 C1 P1 C8 41.6(2) 2_656 . . . ?
P1 C1 P1 C2 157.0(2) 2_656 . . . ?
P1 N1 P2 O1 -40.5(6) . . . . ?
P1 N1 P2 O2 -155.1(5) . . . . ?
P1 N1 P2 S1 88.9(6) . . . . ?
C14 O1 P2 N1 170.2(5) . . . . ?
C14 O1 P2 O2 -74.7(6) . . . . ?
C14 O1 P2 S1 35.3(6) . . . . ?
C20 O2 P2 N1 29.8(6) . . . . ?
C20 O2 P2 O1 -84.1(5) . . . . ?
C20 O2 P2 S1 158.7(5) . . . . ?
N1 P2 S1 Au1 -63.3(2) . . . . ?
O1 P2 S1 Au1 63.62(19) . . . . ?
O2 P2 S1 Au1 177.30(19) . . . . ?
Cl1 Au1 S1 P2 53(2) . . . . ?

_diffrn_measured_fraction_theta_max 0.976
_diffrn_reflns_theta_full        69.56
_diffrn_measured_fraction_theta_full 0.976
_refine_diff_density_max         0.970
_refine_diff_density_min         -1.960
_refine_diff_density_rms         0.133
#===END


_exptl_crystal_recrystallization_method 'Bi-phasic media '
