# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_xb8089_0m
_database_code_depnum_ccdc_archive 'CCDC 1057778'
_audit_update_record             
;
2015-04-03 deposited with the CCDC.
2015-07-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C2 H3 Ag N4'
_chemical_formula_sum            'C2 H3 Ag N4'
_chemical_formula_weight         190.95

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 2/c'
_symmetry_space_group_name_Hall  '-C 2yc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   10.0809(19)
_cell_length_b                   11.449(2)
_cell_length_c                   7.5369(15)
_cell_angle_alpha                90.00
_cell_angle_beta                 100.493(3)
_cell_angle_gamma                90.00
_cell_volume                     855.3(3)
_cell_formula_units_Z            8
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    1256
_cell_measurement_theta_min      2.72
_cell_measurement_theta_max      26.69

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.17
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.966
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             720
_exptl_absorpt_coefficient_mu    4.549
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            2308
_diffrn_reflns_av_R_equivalents  0.0188
_diffrn_reflns_av_sigmaI/netI    0.0233
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_theta_min         2.72
_diffrn_reflns_theta_max         26.69
_reflns_number_total             905
_reflns_number_gt                778
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         905
_refine_ls_number_parameters     72
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_gt           0.0315
_refine_ls_wR_factor_ref         0.1121
_refine_ls_wR_factor_gt          0.1065
_refine_ls_goodness_of_fit_ref   0.913
_refine_ls_restrained_S_all      0.912
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.12833(3) 0.11966(3) 1.12541(5) 0.0377(3) Uani 1 1 d . . .
C2 C 0.8792(3) 0.2580(4) 0.8819(4) 0.0287(11) Uani 1 1 d . . .
N2 N 0.9306(4) 0.1555(3) 0.9361(5) 0.0305(8) Uani 1 1 d . . .
C1 C 0.7624(5) 0.1304(3) 0.7164(7) 0.0253(9) Uani 1 1 d . . .
H1 H 0.6982 0.0950 0.6286 0.030 Uiso 1 1 calc R . .
N1 N 0.8540(4) 0.0760(3) 0.8286(6) 0.0307(8) Uani 1 1 d . . .
N3 N 0.7742(3) 0.2453(3) 0.7459(5) 0.0282(8) Uani 1 1 d . . .
N4 N 0.9309(6) 0.3716(4) 0.9561(9) 0.0486(13) Uani 1 1 d D . .
H4A H 0.846(5) 0.419(6) 0.944(11) 0.08(3) Uiso 1 1 d D . .
H4B H 0.932(15) 0.436(8) 0.866(14) 0.20(6) Uiso 1 1 d D . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.0362(3) 0.0222(3) 0.0462(4) 0.00009(11) -0.0147(2) -0.00286(11)
C2 0.023(2) 0.031(3) 0.028(2) -0.0017(16) -0.0039(18) 0.0054(17)
N2 0.030(2) 0.0207(18) 0.036(2) 0.0027(16) -0.0082(17) -0.0006(15)
C1 0.020(2) 0.019(2) 0.031(2) -0.0018(13) -0.0090(18) -0.0016(14)
N1 0.0261(18) 0.023(2) 0.037(2) -0.0028(16) -0.0087(16) -0.0004(15)
N3 0.0256(16) 0.0181(17) 0.0369(18) 0.0028(15) -0.0050(13) 0.0020(14)
N4 0.045(3) 0.037(3) 0.056(3) -0.0045(19) -0.011(3) 0.0018(19)

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N3 2.212(3) 8_556 ?
Ag1 N2 2.267(4) . ?
Ag1 N1 2.269(4) 5_757 ?
C2 N2 1.318(6) . ?
C2 N3 1.341(5) . ?
C2 N4 1.472(7) . ?
N2 N1 1.361(6) . ?
C1 N1 1.293(6) . ?
C1 N3 1.335(4) . ?
C1 H1 0.9300 . ?
N1 Ag1 2.269(4) 5_757 ?
N3 Ag1 2.212(3) 8_455 ?
N4 H4A 1.003(10) . ?
N4 H4B 1.002(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ag1 N2 125.06(13) 8_556 . ?
N3 Ag1 N1 126.86(13) 8_556 5_757 ?
N2 Ag1 N1 108.07(13) . 5_757 ?
N2 C2 N3 110.5(4) . . ?
N2 C2 N4 125.3(4) . . ?
N3 C2 N4 124.2(4) . . ?
C2 N2 N1 105.2(4) . . ?
C2 N2 Ag1 127.4(3) . . ?
N1 N2 Ag1 126.3(3) . . ?
N1 C1 N3 109.5(4) . . ?
N1 C1 H1 125.2 . . ?
N3 C1 H1 125.2 . . ?
C1 N1 N2 109.1(4) . . ?
C1 N1 Ag1 127.0(3) . 5_757 ?
N2 N1 Ag1 123.3(3) . 5_757 ?
C1 N3 C2 105.6(4) . . ?
C1 N3 Ag1 126.0(3) . 8_455 ?
C2 N3 Ag1 127.7(3) . 8_455 ?
C2 N4 H4A 102(5) . . ?
C2 N4 H4B 116(9) . . ?
H4A N4 H4B 70(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 C2 N2 N1 0.1(4) . . . . ?
N4 C2 N2 N1 -178.5(4) . . . . ?
N3 C2 N2 Ag1 168.7(3) . . . . ?
N4 C2 N2 Ag1 -10.0(6) . . . . ?
N3 Ag1 N2 C2 -2.2(4) 8_556 . . . ?
N1 Ag1 N2 C2 176.7(3) 5_757 . . . ?
N3 Ag1 N2 N1 164.1(3) 8_556 . . . ?
N1 Ag1 N2 N1 -17.0(4) 5_757 . . . ?
N3 C1 N1 N2 -0.5(5) . . . . ?
N3 C1 N1 Ag1 171.2(3) . . . 5_757 ?
C2 N2 N1 C1 0.2(5) . . . . ?
Ag1 N2 N1 C1 -168.5(3) . . . . ?
C2 N2 N1 Ag1 -171.8(3) . . . 5_757 ?
Ag1 N2 N1 Ag1 19.4(5) . . . 5_757 ?
N1 C1 N3 C2 0.5(5) . . . . ?
N1 C1 N3 Ag1 -170.2(3) . . . 8_455 ?
N2 C2 N3 C1 -0.4(5) . . . . ?
N4 C2 N3 C1 178.3(4) . . . . ?
N2 C2 N3 Ag1 170.1(2) . . . 8_455 ?
N4 C2 N3 Ag1 -11.2(6) . . . 8_455 ?

_diffrn_measured_fraction_theta_max 0.988
_diffrn_reflns_theta_full        26.69
_diffrn_measured_fraction_theta_full 0.988
_refine_diff_density_max         0.807
_refine_diff_density_min         -1.176
_refine_diff_density_rms         0.179
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_xb8323_0m
_database_code_depnum_ccdc_archive 'CCDC 1059721'
_audit_update_record             
;
2015-04-15 deposited with the CCDC.
2015-07-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C2 H Ag N4 O2'
_chemical_formula_sum            'C2 H Ag N4 O2'
_chemical_formula_weight         220.94

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   3.6019(7)
_cell_length_b                   11.273(2)
_cell_length_c                   11.600(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 93.389(3)
_cell_angle_gamma                90.00
_cell_volume                     470.16(16)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    1164
_cell_measurement_theta_min      2.52
_cell_measurement_theta_max      27.59

_exptl_crystal_description       needle
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.09
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.121
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             416
_exptl_absorpt_coefficient_mu    4.192
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.611
_exptl_absorpt_correction_T_max  0.686
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            2084
_diffrn_reflns_av_R_equivalents  0.0312
_diffrn_reflns_av_sigmaI/netI    0.0362
_diffrn_reflns_limit_h_min       -3
_diffrn_reflns_limit_h_max       4
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.52
_diffrn_reflns_theta_max         25.03
_reflns_number_total             832
_reflns_number_gt                731
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0300P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0102(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         832
_refine_ls_number_parameters     83
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0294
_refine_ls_R_factor_gt           0.0244
_refine_ls_wR_factor_ref         0.0580
_refine_ls_wR_factor_gt          0.0556
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N4 N 0.4395(8) 0.9370(2) 0.6537(2) 0.0286(7) Uani 1 1 d . . .
N3 N 0.3109(8) 0.7685(2) 0.7447(2) 0.0279(7) Uani 1 1 d . . .
Ag1 Ag 0.33633(9) 0.87929(2) 0.37666(2) 0.03934(19) Uani 1 1 d . . .
C3 C 0.4509(10) 0.8783(3) 0.7529(3) 0.0293(8) Uani 1 1 d . . .
H3 H 0.5477 0.9106 0.8221 0.035 Uiso 1 1 calc R . .
C4 C 0.2084(10) 0.7650(3) 0.6323(3) 0.0243(7) Uani 1 1 d . . .
O2 O -0.0392(9) 0.5798(3) 0.6405(3) 0.0528(8) Uani 1 1 d . . .
N2 N 0.2776(8) 0.8611(2) 0.5728(2) 0.0272(7) Uani 1 1 d . . .
N1 N 0.0194(8) 0.6643(3) 0.5793(3) 0.0305(7) Uani 1 1 d . . .
O1 O -0.0832(9) 0.6722(3) 0.4783(3) 0.0572(9) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
N4 0.0431(18) 0.0224(15) 0.0204(15) -0.0028(12) 0.0016(13) -0.0033(12)
N3 0.0405(17) 0.0227(14) 0.0200(15) 0.0008(12) -0.0018(13) 0.0024(12)
Ag1 0.0696(3) 0.0266(2) 0.0215(2) -0.00204(10) 0.00011(15) -0.00727(12)
C3 0.040(2) 0.027(2) 0.0201(19) -0.0011(14) -0.0034(15) 0.0027(15)
C4 0.0298(18) 0.0223(18) 0.0211(19) -0.0014(13) 0.0036(14) 0.0010(12)
O2 0.078(2) 0.0314(15) 0.0479(18) 0.0063(14) -0.0026(16) -0.0192(14)
N2 0.0415(16) 0.0239(15) 0.0162(15) -0.0009(12) 0.0016(13) -0.0034(12)
N1 0.0358(16) 0.0275(17) 0.0281(17) -0.0030(14) 0.0024(14) -0.0006(13)
O1 0.089(2) 0.0481(19) 0.0324(17) -0.0057(13) -0.0131(16) -0.0200(16)

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N4 C3 1.326(4) . ?
N4 N2 1.374(4) . ?
N4 Ag1 2.258(3) 3_676 ?
N3 C4 1.335(4) . ?
N3 C3 1.338(4) . ?
N3 Ag1 2.261(3) 4_576 ?
Ag1 N4 2.258(3) 3_676 ?
Ag1 N3 2.261(3) 4_575 ?
Ag1 N2 2.307(3) . ?
C3 H3 0.9300 . ?
C4 N2 1.316(4) . ?
C4 N1 1.442(4) . ?
O2 N1 1.214(4) . ?
N1 O1 1.211(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C3 N4 N2 105.8(3) . . ?
C3 N4 Ag1 126.9(2) . 3_676 ?
N2 N4 Ag1 127.3(2) . 3_676 ?
C4 N3 C3 100.3(3) . . ?
C4 N3 Ag1 129.6(2) . 4_576 ?
C3 N3 Ag1 129.3(2) . 4_576 ?
N4 Ag1 N3 124.81(10) 3_676 4_575 ?
N4 Ag1 N2 106.86(9) 3_676 . ?
N3 Ag1 N2 126.87(10) 4_575 . ?
N4 C3 N3 114.1(3) . . ?
N4 C3 H3 123.0 . . ?
N3 C3 H3 123.0 . . ?
N2 C4 N3 115.9(3) . . ?
N2 C4 N1 121.6(3) . . ?
N3 C4 N1 122.4(3) . . ?
C4 N2 N4 103.9(3) . . ?
C4 N2 Ag1 128.4(2) . . ?
N4 N2 Ag1 123.9(2) . . ?
O1 N1 O2 124.7(3) . . ?
O1 N1 C4 117.7(3) . . ?
O2 N1 C4 117.6(3) . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.03
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.671
_refine_diff_density_min         -0.585
_refine_diff_density_rms         0.131
