# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_g0530
_database_code_depnum_ccdc_archive 'CCDC 721072'
_audit_update_record             
;
2015-06-19 deposited with the CCDC.
2015-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C54 H51 Ag2 N15 O16'
_chemical_formula_weight         1381.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.7172(3)
_cell_length_b                   11.9846(3)
_cell_length_c                   20.1196(6)
_cell_angle_alpha                89.9760(10)
_cell_angle_beta                 81.0430(10)
_cell_angle_gamma                79.8740(10)
_cell_volume                     2746.33(13)
_cell_formula_units_Z            2
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.671
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1404
_exptl_absorpt_coefficient_mu    0.800
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  0.891
_exptl_absorpt_correction_T_max  0.938
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX II area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            26608
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_sigmaI/netI    0.0482
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         3.00
_diffrn_reflns_theta_max         27.48
_reflns_number_total             12444
_reflns_number_gt                9959
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART APEX II'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0533P)²+6.7197P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0013(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         12444
_refine_ls_number_parameters     786
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0534
_refine_ls_R_factor_gt           0.0390
_refine_ls_wR_factor_ref         0.1248
_refine_ls_wR_factor_gt          0.1120
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.39818(2) 0.56260(2) 0.785225(14) 0.02161(9) Uani 1 1 d . . .
Ag2 Ag 0.47938(2) 0.71617(2) 0.677210(14) 0.02173(9) Uani 1 1 d . . .
O1 O 0.2168(2) 0.5444(2) 0.69511(13) 0.0244(6) Uani 1 1 d . . .
O2 O 0.5954(2) 0.6685(2) 0.78713(15) 0.0246(6) Uani 1 1 d . . .
O3 O 0.6783(3) 0.7651(3) 0.63410(16) 0.0369(7) Uani 1 1 d . . .
O4 O 0.8937(3) 0.6651(3) 0.64938(18) 0.0494(9) Uani 1 1 d . . .
O5 O 1.0064(3) 0.6280(4) 0.5550(2) 0.0651(12) Uani 1 1 d . . .
O6 O 1.0212(3) 0.9479(3) 0.40927(18) 0.0448(8) Uani 1 1 d . . .
O7 O 0.8678(3) 1.0812(3) 0.41385(16) 0.0369(7) Uani 1 1 d . . .
O8 O 0.4877(2) 0.8701(2) 0.57615(15) 0.0308(6) Uani 1 1 d . . .
O9 O 0.5098(2) 1.0454(2) 0.56719(15) 0.0310(6) Uani 1 1 d . . .
O10 O -0.0854(2) 0.5847(2) 0.86562(14) 0.0281(6) Uani 1 1 d . . .
O11 O -0.2833(3) 0.6861(3) 0.94965(18) 0.0431(8) Uani 1 1 d . . .
O12 O -0.2438(3) 0.8448(3) 0.9807(2) 0.0578(11) Uani 1 1 d . . .
O13 O 0.0820(3) 0.7963(3) 1.10678(17) 0.0399(8) Uani 1 1 d . . .
O14 O 0.2269(3) 0.6563(3) 1.08139(18) 0.0448(8) Uani 1 1 d . . .
O15 O 0.2442(3) 0.4166(3) 0.8924(2) 0.0480(9) Uani 1 1 d . . .
O16 O 0.0946(3) 0.4133(3) 0.84425(19) 0.0473(9) Uani 1 1 d . . .
N1 N 0.2359(3) 0.6760(2) 0.81025(15) 0.0190(6) Uani 1 1 d . . .
N2 N 0.0598(3) 0.7803(3) 0.80869(17) 0.0232(7) Uani 1 1 d . . .
N3 N 0.4723(3) 0.5714(2) 0.61872(16) 0.0207(6) Uani 1 1 d . . .
N4 N 0.4011(3) 0.4335(3) 0.57437(16) 0.0224(6) Uani 1 1 d . . .
N5 N 0.4444(3) 0.8521(2) 0.75014(16) 0.0212(6) Uani 1 1 d . . .
N6 N 0.4666(3) 0.9572(3) 0.83693(17) 0.0241(7) Uani 1 1 d . . .
N7 N 0.5638(3) 0.4520(2) 0.76267(16) 0.0197(6) Uani 1 1 d . . .
N8 N 0.7546(3) 0.3805(2) 0.75164(16) 0.0202(6) Uani 1 1 d . . .
N9 N 0.9224(3) 0.6857(3) 0.5903(2) 0.0356(9) Uani 1 1 d . . .
N10 N 0.9181(3) 0.9892(3) 0.43150(18) 0.0297(7) Uani 1 1 d . . .
N11 N 0.5498(3) 0.9433(3) 0.56661(16) 0.0232(7) Uani 1 1 d . . .
N12 N -0.2143(3) 0.7443(3) 0.96523(18) 0.0310(8) Uani 1 1 d . . .
N13 N 0.1311(3) 0.7110(3) 1.07285(18) 0.0301(7) Uani 1 1 d . . .
N14 N 0.1426(3) 0.4548(3) 0.88470(18) 0.0282(7) Uani 1 1 d . . .
C53 C 0.5020(5) 0.3400(5) 0.9265(3) 0.0510(13) Uani 1 1 d . . .
H53A H 0.4679 0.3144 0.8890 0.061 Uiso 1 1 calc R . .
H53B H 0.4588 0.3195 0.9692 0.061 Uiso 1 1 calc R . .
H53C H 0.5846 0.3035 0.9224 0.061 Uiso 1 1 calc R . .
C1 C 0.2185(3) 0.7630(3) 0.85839(19) 0.0227(8) Uani 1 1 d . . .
C2 C 0.2888(4) 0.7857(3) 0.9040(2) 0.0274(8) Uani 1 1 d . . .
H2A H 0.3632 0.7398 0.9055 0.033 Uiso 1 1 calc R . .
C3 C 0.2459(4) 0.8785(4) 0.9475(2) 0.0357(10) Uani 1 1 d . . .
H3A H 0.2918 0.8966 0.9796 0.043 Uiso 1 1 calc R . .
C4 C 0.1360(4) 0.9466(4) 0.9451(2) 0.0372(11) Uani 1 1 d . . .
H4A H 0.1099 1.0101 0.9753 0.045 Uiso 1 1 calc R . .
C5 C 0.0658(4) 0.9241(3) 0.9007(2) 0.0332(10) Uani 1 1 d . . .
H5A H -0.0084 0.9704 0.8993 0.040 Uiso 1 1 calc R . .
C6 C 0.1079(3) 0.8301(3) 0.8573(2) 0.0245(8) Uani 1 1 d . . .
C7 C 0.1399(3) 0.6897(3) 0.78225(18) 0.0203(7) Uani 1 1 d . . .
C8 C 0.1133(3) 0.6095(3) 0.7320(2) 0.0252(8) Uani 1 1 d . . .
H8A H 0.0645 0.5577 0.7558 0.030 Uiso 1 1 calc R . .
H8B H 0.0674 0.6533 0.7002 0.030 Uiso 1 1 calc R . .
C9 C 0.2560(3) 0.5971(3) 0.6344(2) 0.0257(8) Uani 1 1 d . . .
H9A H 0.2574 0.6780 0.6433 0.031 Uiso 1 1 calc R . .
H9B H 0.2029 0.5922 0.6012 0.031 Uiso 1 1 calc R . .
C10 C 0.3766(3) 0.5354(3) 0.60809(18) 0.0205(7) Uani 1 1 d . . .
C11 C 0.5224(3) 0.4009(3) 0.56345(18) 0.0220(7) Uani 1 1 d . . .
C12 C 0.5954(4) 0.3048(3) 0.5329(2) 0.0302(9) Uani 1 1 d . . .
H12A H 0.5653 0.2454 0.5142 0.036 Uiso 1 1 calc R . .
C13 C 0.7142(4) 0.3006(4) 0.5312(2) 0.0335(9) Uani 1 1 d . . .
H13A H 0.7674 0.2367 0.5103 0.040 Uiso 1 1 calc R . .
C14 C 0.7586(4) 0.3873(4) 0.5591(2) 0.0301(9) Uani 1 1 d . . .
H14A H 0.8411 0.3808 0.5569 0.036 Uiso 1 1 calc R . .
C15 C 0.6856(3) 0.4819(3) 0.58993(19) 0.0248(8) Uani 1 1 d . . .
H15A H 0.7162 0.5404 0.6092 0.030 Uiso 1 1 calc R . .
C16 C 0.5659(3) 0.4886(3) 0.59167(18) 0.0210(7) Uani 1 1 d . . .
C17 C -0.0580(3) 0.8182(3) 0.7926(2) 0.0298(9) Uani 1 1 d . . .
H17A H -0.1119 0.8470 0.8343 0.036 Uiso 1 1 calc R . .
H17B H -0.0864 0.7528 0.7749 0.036 Uiso 1 1 calc R . .
C18 C -0.0611(4) 0.9103(5) 0.7413(3) 0.0534(15) Uani 1 1 d . . .
H18A H -0.1415 0.9329 0.7320 0.080 Uiso 1 1 calc R . .
H18B H -0.0091 0.8817 0.6996 0.080 Uiso 1 1 calc R . .
H18C H -0.0348 0.9759 0.7589 0.080 Uiso 1 1 calc R . .
C19 C 0.3166(4) 0.3673(3) 0.5558(2) 0.0299(9) Uani 1 1 d . . .
H19A H 0.3494 0.3273 0.5121 0.036 Uiso 1 1 calc R . .
H19B H 0.2437 0.4197 0.5498 0.036 Uiso 1 1 calc R . .
C20 C 0.2866(4) 0.2815(3) 0.6076(2) 0.0282(8) Uani 1 1 d . . .
H20A H 0.2291 0.2405 0.5929 0.042 Uiso 1 1 calc R . .
H20B H 0.2533 0.3206 0.6509 0.042 Uiso 1 1 calc R . .
H20C H 0.3579 0.2277 0.6126 0.042 Uiso 1 1 calc R . .
C21 C 0.3573(3) 0.9480(3) 0.75671(19) 0.0218(7) Uani 1 1 d . . .
C22 C 0.2680(3) 0.9808(3) 0.7184(2) 0.0284(8) Uani 1 1 d . . .
H22A H 0.2584 0.9354 0.6817 0.034 Uiso 1 1 calc R . .
C23 C 0.1941(4) 1.0828(3) 0.7368(2) 0.0339(10) Uani 1 1 d . . .
H23A H 0.1322 1.1077 0.7119 0.041 Uiso 1 1 calc R . .
C24 C 0.2070(4) 1.1506(3) 0.7904(3) 0.0363(10) Uani 1 1 d . . .
H24A H 0.1538 1.2199 0.8012 0.044 Uiso 1 1 calc R . .
C25 C 0.2965(4) 1.1188(3) 0.8287(2) 0.0313(9) Uani 1 1 d . . .
H25A H 0.3065 1.1652 0.8649 0.038 Uiso 1 1 calc R . .
C26 C 0.3703(3) 1.0154(3) 0.8110(2) 0.0234(8) Uani 1 1 d . . .
C27 C 0.5065(3) 0.8607(3) 0.79819(19) 0.0215(7) Uani 1 1 d . . .
C28 C 0.6111(3) 0.7750(3) 0.8087(2) 0.0286(9) Uani 1 1 d . . .
H28A H 0.6833 0.7951 0.7827 0.034 Uiso 1 1 calc R . .
H28B H 0.6193 0.7737 0.8570 0.034 Uiso 1 1 calc R . .
C29 C 0.6948(3) 0.5828(3) 0.7902(2) 0.0250(8) Uani 1 1 d . . .
H29A H 0.7125 0.5780 0.8367 0.030 Uiso 1 1 calc R . .
H29B H 0.7640 0.6011 0.7603 0.030 Uiso 1 1 calc R . .
C30 C 0.6685(3) 0.4728(3) 0.76849(18) 0.0192(7) Uani 1 1 d . . .
C31 C 0.7004(3) 0.2943(3) 0.73323(18) 0.0212(7) Uani 1 1 d . . .
C32 C 0.7448(4) 0.1831(3) 0.7095(2) 0.0266(8) Uani 1 1 d . . .
H32A H 0.8264 0.1528 0.7038 0.032 Uiso 1 1 calc R . .
C33 C 0.6644(4) 0.1203(3) 0.6950(2) 0.0305(9) Uani 1 1 d . . .
H33A H 0.6913 0.0444 0.6786 0.037 Uiso 1 1 calc R . .
C34 C 0.5438(4) 0.1639(3) 0.7034(2) 0.0286(8) Uani 1 1 d . . .
H34A H 0.4911 0.1170 0.6931 0.034 Uiso 1 1 calc R . .
C35 C 0.5003(3) 0.2740(3) 0.72650(19) 0.0248(8) Uani 1 1 d . . .
H35A H 0.4185 0.3036 0.7327 0.030 Uiso 1 1 calc R . .
C36 C 0.5809(3) 0.3399(3) 0.74029(18) 0.0195(7) Uani 1 1 d . . .
C37 C 0.5153(4) 0.9940(3) 0.8944(2) 0.0319(9) Uani 1 1 d . . .
H37A H 0.5370 0.9278 0.9222 0.038 Uiso 1 1 calc R . .
H37B H 0.4545 1.0495 0.9227 0.038 Uiso 1 1 calc R . .
C38 C 0.6216(5) 1.0472(5) 0.8723(3) 0.0466(12) Uani 1 1 d . . .
H38A H 0.6512 1.0710 0.9119 0.070 Uiso 1 1 calc R . .
H38B H 0.6001 1.1133 0.8452 0.070 Uiso 1 1 calc R . .
H38C H 0.6827 0.9918 0.8453 0.070 Uiso 1 1 calc R . .
C39 C 0.8794(3) 0.3696(3) 0.7577(2) 0.0242(8) Uani 1 1 d . . .
H39A H 0.9042 0.2979 0.7801 0.029 Uiso 1 1 calc R . .
H39B H 0.8896 0.4329 0.7865 0.029 Uiso 1 1 calc R . .
C40 C 0.9577(4) 0.3706(4) 0.6903(2) 0.0349(10) Uani 1 1 d . . .
H40A H 1.0396 0.3633 0.6972 0.052 Uiso 1 1 calc R . .
H40B H 0.9346 0.4420 0.6682 0.052 Uiso 1 1 calc R . .
H40C H 0.9496 0.3069 0.6618 0.052 Uiso 1 1 calc R . .
C41 C 0.7305(3) 0.8123(3) 0.5869(2) 0.0236(8) Uani 1 1 d . . .
C42 C 0.8547(3) 0.7805(3) 0.5613(2) 0.0257(8) Uani 1 1 d . . .
C43 C 0.9143(3) 0.8343(3) 0.5102(2) 0.0260(8) Uani 1 1 d . . .
H43A H 0.9952 0.8073 0.4943 0.031 Uiso 1 1 calc R . .
C44 C 0.8547(3) 0.9285(3) 0.4822(2) 0.0245(8) Uani 1 1 d . . .
C45 C 0.7352(3) 0.9659(3) 0.50249(19) 0.0224(7) Uani 1 1 d . . .
H45A H 0.6952 1.0311 0.4835 0.027 Uiso 1 1 calc R . .
C46 C 0.6758(3) 0.9065(3) 0.55058(19) 0.0217(7) Uani 1 1 d . . .
C47 C -0.0385(3) 0.6036(3) 0.91440(19) 0.0213(7) Uani 1 1 d . . .
C48 C -0.0928(3) 0.6902(3) 0.9667(2) 0.0226(7) Uani 1 1 d . . .
C49 C -0.0395(3) 0.7269(3) 1.01551(19) 0.0234(8) Uani 1 1 d . . .
H49A H -0.0788 0.7877 1.0455 0.028 Uiso 1 1 calc R . .
C50 C 0.0745(3) 0.6734(3) 1.02092(19) 0.0236(8) Uani 1 1 d . . .
C51 C 0.1321(3) 0.5840(3) 0.97749(19) 0.0230(8) Uani 1 1 d . . .
H51A H 0.2086 0.5466 0.9825 0.028 Uiso 1 1 calc R . .
C52 C 0.0778(3) 0.5501(3) 0.92731(19) 0.0222(7) Uani 1 1 d . . .
N15 N 0.4883(5) 0.5586(5) 0.9227(3) 0.0656(14) Uani 1 1 d . . .
C54 C 0.4941(5) 0.4622(5) 0.9250(3) 0.0512(13) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.124(3) . ?
Ag1 N7 2.134(3) . ?
Ag1 Ag2 2.9973(4) . ?
Ag2 N3 2.117(3) . ?
Ag2 N5 2.134(3) . ?
Ag2 O3 2.526(3) . ?
O1 C8 1.420(4) . ?
O1 C9 1.425(5) . ?
O2 C28 1.400(4) . ?
O2 C29 1.420(4) . ?
O3 C41 1.239(5) . ?
O4 N9 1.220(5) . ?
O5 N9 1.223(5) . ?
O6 N10 1.236(5) . ?
O7 N10 1.235(5) . ?
O8 N11 1.232(4) . ?
O9 N11 1.231(4) . ?
O10 C47 1.236(5) . ?
O11 N12 1.231(5) . ?
O12 N12 1.220(5) . ?
O13 N13 1.230(5) . ?
O14 N13 1.233(5) . ?
O15 N14 1.231(5) . ?
O16 N14 1.211(5) . ?
N1 C7 1.320(5) . ?
N1 C1 1.389(5) . ?
N2 C7 1.352(4) . ?
N2 C6 1.387(5) . ?
N2 C17 1.462(5) . ?
N3 C10 1.318(5) . ?
N3 C16 1.384(4) . ?
N4 C10 1.361(5) . ?
N4 C11 1.388(5) . ?
N4 C19 1.463(5) . ?
N5 C27 1.311(5) . ?
N5 C21 1.388(4) . ?
N6 C27 1.364(5) . ?
N6 C26 1.393(5) . ?
N6 C37 1.466(5) . ?
N7 C30 1.316(5) . ?
N7 C36 1.387(4) . ?
N8 C30 1.363(4) . ?
N8 C31 1.383(5) . ?
N8 C39 1.469(5) . ?
N9 C42 1.446(5) . ?
N10 C44 1.441(5) . ?
N11 C46 1.450(5) . ?
N12 C48 1.461(5) . ?
N13 C50 1.434(5) . ?
N14 C52 1.452(5) . ?
C53 C54 1.452(8) . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C1 C2 1.383(6) . ?
C1 C6 1.403(5) . ?
C2 C3 1.386(6) . ?
C2 H2A 0.9500 . ?
C3 C4 1.406(7) . ?
C3 H3A 0.9500 . ?
C4 C5 1.360(7) . ?
C4 H4A 0.9500 . ?
C5 C6 1.395(5) . ?
C5 H5A 0.9500 . ?
C7 C8 1.500(5) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.490(5) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C11 C12 1.387(5) . ?
C11 C16 1.402(5) . ?
C12 C13 1.379(6) . ?
C12 H12A 0.9500 . ?
C13 C14 1.396(6) . ?
C13 H13A 0.9500 . ?
C14 C15 1.377(5) . ?
C14 H14A 0.9500 . ?
C15 C16 1.386(5) . ?
C15 H15A 0.9500 . ?
C17 C18 1.510(6) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.510(6) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.396(5) . ?
C21 C26 1.401(5) . ?
C22 C23 1.382(6) . ?
C22 H22A 0.9500 . ?
C23 C24 1.393(7) . ?
C23 H23A 0.9500 . ?
C24 C25 1.395(6) . ?
C24 H24A 0.9500 . ?
C25 C26 1.392(5) . ?
C25 H25A 0.9500 . ?
C27 C28 1.496(5) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.486(5) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C31 C36 1.396(5) . ?
C31 C32 1.397(5) . ?
C32 C33 1.370(6) . ?
C32 H32A 0.9500 . ?
C33 C34 1.402(6) . ?
C33 H33A 0.9500 . ?
C34 C35 1.380(6) . ?
C34 H34A 0.9500 . ?
C35 C36 1.392(5) . ?
C35 H35A 0.9500 . ?
C37 C38 1.505(7) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.516(6) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C42 1.449(5) . ?
C41 C46 1.453(5) . ?
C42 C43 1.376(6) . ?
C43 C44 1.388(6) . ?
C43 H43A 0.9500 . ?
C44 C45 1.389(5) . ?
C45 C46 1.374(5) . ?
C45 H45A 0.9500 . ?
C47 C52 1.462(5) . ?
C47 C48 1.466(5) . ?
C48 C49 1.355(6) . ?
C49 C50 1.397(5) . ?
C49 H49A 0.9500 . ?
C50 C51 1.389(5) . ?
C51 C52 1.371(6) . ?
C51 H51A 0.9500 . ?
N15 C54 1.147(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N7 177.90(12) . . ?
N1 Ag1 Ag2 90.66(8) . . ?
N7 Ag1 Ag2 89.32(8) . . ?
N3 Ag2 N5 164.91(12) . . ?
N3 Ag2 O3 104.34(12) . . ?
N5 Ag2 O3 90.63(12) . . ?
N3 Ag2 Ag1 79.32(8) . . ?
N5 Ag2 Ag1 89.23(8) . . ?
O3 Ag2 Ag1 132.51(7) . . ?
C8 O1 C9 112.0(3) . . ?
C28 O2 C29 112.5(3) . . ?
C41 O3 Ag2 141.5(3) . . ?
C7 N1 C1 106.1(3) . . ?
C7 N1 Ag1 130.9(2) . . ?
C1 N1 Ag1 122.7(2) . . ?
C7 N2 C6 107.2(3) . . ?
C7 N2 C17 127.8(4) . . ?
C6 N2 C17 125.0(3) . . ?
C10 N3 C16 106.3(3) . . ?
C10 N3 Ag2 126.3(2) . . ?
C16 N3 Ag2 126.9(2) . . ?
C10 N4 C11 106.9(3) . . ?
C10 N4 C19 127.0(3) . . ?
C11 N4 C19 126.0(3) . . ?
C27 N5 C21 106.1(3) . . ?
C27 N5 Ag2 124.7(2) . . ?
C21 N5 Ag2 129.1(3) . . ?
C27 N6 C26 106.5(3) . . ?
C27 N6 C37 127.3(3) . . ?
C26 N6 C37 126.2(3) . . ?
C30 N7 C36 106.1(3) . . ?
C30 N7 Ag1 128.4(2) . . ?
C36 N7 Ag1 125.5(2) . . ?
C30 N8 C31 106.8(3) . . ?
C30 N8 C39 127.2(3) . . ?
C31 N8 C39 125.8(3) . . ?
O4 N9 O5 121.9(4) . . ?
O4 N9 C42 119.0(4) . . ?
O5 N9 C42 119.1(4) . . ?
O7 N10 O6 123.4(3) . . ?
O7 N10 C44 118.4(3) . . ?
O6 N10 C44 118.2(3) . . ?
O9 N11 O8 123.2(3) . . ?
O9 N11 C46 118.7(3) . . ?
O8 N11 C46 118.1(3) . . ?
O12 N12 O11 122.6(4) . . ?
O12 N12 C48 118.7(4) . . ?
O11 N12 C48 118.7(3) . . ?
O13 N13 O14 123.0(4) . . ?
O13 N13 C50 118.6(3) . . ?
O14 N13 C50 118.4(4) . . ?
O16 N14 O15 121.9(4) . . ?
O16 N14 C52 119.5(3) . . ?
O15 N14 C52 118.5(4) . . ?
C54 C53 H53A 109.5 . . ?
C54 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C54 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C2 C1 N1 130.3(4) . . ?
C2 C1 C6 121.1(4) . . ?
N1 C1 C6 108.6(3) . . ?
C1 C2 C3 117.0(4) . . ?
C1 C2 H2A 121.5 . . ?
C3 C2 H2A 121.5 . . ?
C2 C3 C4 121.5(4) . . ?
C2 C3 H3A 119.3 . . ?
C4 C3 H3A 119.3 . . ?
C5 C4 C3 121.9(4) . . ?
C5 C4 H4A 119.1 . . ?
C3 C4 H4A 119.1 . . ?
C4 C5 C6 117.0(4) . . ?
C4 C5 H5A 121.5 . . ?
C6 C5 H5A 121.5 . . ?
N2 C6 C5 132.7(4) . . ?
N2 C6 C1 105.6(3) . . ?
C5 C6 C1 121.6(4) . . ?
N1 C7 N2 112.5(3) . . ?
N1 C7 C8 125.4(3) . . ?
N2 C7 C8 121.8(3) . . ?
O1 C8 C7 112.3(3) . . ?
O1 C8 H8A 109.2 . . ?
C7 C8 H8A 109.2 . . ?
O1 C8 H8B 109.2 . . ?
C7 C8 H8B 109.2 . . ?
H8A C8 H8B 107.9 . . ?
O1 C9 C10 107.0(3) . . ?
O1 C9 H9A 110.3 . . ?
C10 C9 H9A 110.3 . . ?
O1 C9 H9B 110.3 . . ?
C10 C9 H9B 110.3 . . ?
H9A C9 H9B 108.6 . . ?
N3 C10 N4 112.2(3) . . ?
N3 C10 C9 122.9(3) . . ?
N4 C10 C9 124.7(3) . . ?
C12 C11 N4 132.0(4) . . ?
C12 C11 C16 122.3(4) . . ?
N4 C11 C16 105.6(3) . . ?
C13 C12 C11 116.2(4) . . ?
C13 C12 H12A 121.9 . . ?
C11 C12 H12A 121.9 . . ?
C12 C13 C14 122.0(4) . . ?
C12 C13 H13A 119.0 . . ?
C14 C13 H13A 119.0 . . ?
C15 C14 C13 121.5(4) . . ?
C15 C14 H14A 119.2 . . ?
C13 C14 H14A 119.2 . . ?
C14 C15 C16 117.5(4) . . ?
C14 C15 H15A 121.3 . . ?
C16 C15 H15A 121.3 . . ?
N3 C16 C15 130.7(3) . . ?
N3 C16 C11 108.9(3) . . ?
C15 C16 C11 120.4(3) . . ?
N2 C17 C18 112.3(3) . . ?
N2 C17 H17A 109.1 . . ?
C18 C17 H17A 109.1 . . ?
N2 C17 H17B 109.1 . . ?
C18 C17 H17B 109.1 . . ?
H17A C17 H17B 107.9 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N4 C19 C20 112.9(3) . . ?
N4 C19 H19A 109.0 . . ?
C20 C19 H19A 109.0 . . ?
N4 C19 H19B 109.0 . . ?
C20 C19 H19B 109.0 . . ?
H19A C19 H19B 107.8 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N5 C21 C22 129.6(4) . . ?
N5 C21 C26 109.0(3) . . ?
C22 C21 C26 121.3(3) . . ?
C23 C22 C21 116.5(4) . . ?
C23 C22 H22A 121.8 . . ?
C21 C22 H22A 121.8 . . ?
C22 C23 C24 122.5(4) . . ?
C22 C23 H23A 118.8 . . ?
C24 C23 H23A 118.8 . . ?
C23 C24 C25 121.4(4) . . ?
C23 C24 H24A 119.3 . . ?
C25 C24 H24A 119.3 . . ?
C26 C25 C24 116.4(4) . . ?
C26 C25 H25A 121.8 . . ?
C24 C25 H25A 121.8 . . ?
C25 C26 N6 132.5(4) . . ?
C25 C26 C21 121.9(4) . . ?
N6 C26 C21 105.6(3) . . ?
N5 C27 N6 112.7(3) . . ?
N5 C27 C28 123.7(3) . . ?
N6 C27 C28 123.5(3) . . ?
O2 C28 C27 108.4(3) . . ?
O2 C28 H28A 110.0 . . ?
C27 C28 H28A 110.0 . . ?
O2 C28 H28B 110.0 . . ?
C27 C28 H28B 110.0 . . ?
H28A C28 H28B 108.4 . . ?
O2 C29 C30 108.6(3) . . ?
O2 C29 H29A 110.0 . . ?
C30 C29 H29A 110.0 . . ?
O2 C29 H29B 110.0 . . ?
C30 C29 H29B 110.0 . . ?
H29A C29 H29B 108.3 . . ?
N7 C30 N8 112.3(3) . . ?
N7 C30 C29 125.8(3) . . ?
N8 C30 C29 121.9(3) . . ?
N8 C31 C36 106.0(3) . . ?
N8 C31 C32 132.0(3) . . ?
C36 C31 C32 121.9(4) . . ?
C33 C32 C31 116.4(4) . . ?
C33 C32 H32A 121.8 . . ?
C31 C32 H32A 121.8 . . ?
C32 C33 C34 122.4(4) . . ?
C32 C33 H33A 118.8 . . ?
C34 C33 H33A 118.8 . . ?
C35 C34 C33 121.1(4) . . ?
C35 C34 H34A 119.5 . . ?
C33 C34 H34A 119.5 . . ?
C34 C35 C36 117.4(4) . . ?
C34 C35 H35A 121.3 . . ?
C36 C35 H35A 121.3 . . ?
N7 C36 C35 130.4(3) . . ?
N7 C36 C31 108.8(3) . . ?
C35 C36 C31 120.8(3) . . ?
N6 C37 C38 111.8(4) . . ?
N6 C37 H37A 109.2 . . ?
C38 C37 H37A 109.2 . . ?
N6 C37 H37B 109.2 . . ?
C38 C37 H37B 109.2 . . ?
H37A C37 H37B 107.9 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N8 C39 C40 112.9(3) . . ?
N8 C39 H39A 109.0 . . ?
C40 C39 H39A 109.0 . . ?
N8 C39 H39B 109.0 . . ?
C40 C39 H39B 109.0 . . ?
H39A C39 H39B 107.8 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
O3 C41 C42 124.0(3) . . ?
O3 C41 C46 124.6(4) . . ?
C42 C41 C46 111.4(3) . . ?
C43 C42 N9 116.7(3) . . ?
C43 C42 C41 124.5(3) . . ?
N9 C42 C41 118.8(3) . . ?
C42 C43 C44 119.1(4) . . ?
C42 C43 H43A 120.5 . . ?
C44 C43 H43A 120.5 . . ?
C43 C44 C45 121.2(4) . . ?
C43 C44 N10 119.3(4) . . ?
C45 C44 N10 119.4(3) . . ?
C46 C45 C44 118.7(3) . . ?
C46 C45 H45A 120.7 . . ?
C44 C45 H45A 120.7 . . ?
C45 C46 N11 116.8(3) . . ?
C45 C46 C41 124.8(3) . . ?
N11 C46 C41 118.4(3) . . ?
O10 C47 C52 126.7(4) . . ?
O10 C47 C48 123.0(3) . . ?
C52 C47 C48 110.2(3) . . ?
C49 C48 N12 116.8(3) . . ?
C49 C48 C47 125.8(3) . . ?
N12 C48 C47 117.4(3) . . ?
C48 C49 C50 118.6(4) . . ?
C48 C49 H49A 120.7 . . ?
C50 C49 H49A 120.7 . . ?
C51 C50 C49 120.9(4) . . ?
C51 C50 N13 120.2(3) . . ?
C49 C50 N13 118.9(4) . . ?
C52 C51 C50 119.6(3) . . ?
C52 C51 H51A 120.2 . . ?
C50 C51 H51A 120.2 . . ?
C51 C52 N14 116.4(3) . . ?
C51 C52 C47 124.4(3) . . ?
N14 C52 C47 119.1(3) . . ?
N15 C54 C53 178.9(6) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag1 Ag2 N3 -115.49(12) . . . . ?
N7 Ag1 Ag2 N3 66.61(12) . . . . ?
N1 Ag1 Ag2 N5 54.63(12) . . . . ?
N7 Ag1 Ag2 N5 -123.27(12) . . . . ?
N1 Ag1 Ag2 O3 144.78(14) . . . . ?
N7 Ag1 Ag2 O3 -33.11(14) . . . . ?
N3 Ag2 O3 C41 79.1(5) . . . . ?
N5 Ag2 O3 C41 -102.8(5) . . . . ?
Ag1 Ag2 O3 C41 167.7(4) . . . . ?
N7 Ag1 N1 C7 171(3) . . . . ?
Ag2 Ag1 N1 C7 81.4(3) . . . . ?
N7 Ag1 N1 C1 -1(3) . . . . ?
Ag2 Ag1 N1 C1 -90.6(3) . . . . ?
N5 Ag2 N3 C10 29.1(6) . . . . ?
O3 Ag2 N3 C10 -158.2(3) . . . . ?
Ag1 Ag2 N3 C10 70.4(3) . . . . ?
N5 Ag2 N3 C16 -141.8(4) . . . . ?
O3 Ag2 N3 C16 30.9(3) . . . . ?
Ag1 Ag2 N3 C16 -100.6(3) . . . . ?
N3 Ag2 N5 C27 111.6(5) . . . . ?
O3 Ag2 N5 C27 -61.3(3) . . . . ?
Ag1 Ag2 N5 C27 71.2(3) . . . . ?
N3 Ag2 N5 C21 -69.9(6) . . . . ?
O3 Ag2 N5 C21 117.2(3) . . . . ?
Ag1 Ag2 N5 C21 -110.3(3) . . . . ?
N1 Ag1 N7 C30 -26(3) . . . . ?
Ag2 Ag1 N7 C30 63.4(3) . . . . ?
N1 Ag1 N7 C36 152(3) . . . . ?
Ag2 Ag1 N7 C36 -118.7(3) . . . . ?
C7 N1 C1 C2 177.0(4) . . . . ?
Ag1 N1 C1 C2 -9.3(5) . . . . ?
C7 N1 C1 C6 -0.7(4) . . . . ?
Ag1 N1 C1 C6 173.0(2) . . . . ?
N1 C1 C2 C3 -178.4(4) . . . . ?
C6 C1 C2 C3 -1.1(5) . . . . ?
C1 C2 C3 C4 -0.2(6) . . . . ?
C2 C3 C4 C5 0.8(7) . . . . ?
C3 C4 C5 C6 0.0(6) . . . . ?
C7 N2 C6 C5 -179.5(4) . . . . ?
C17 N2 C6 C5 -1.9(6) . . . . ?
C7 N2 C6 C1 -1.0(4) . . . . ?
C17 N2 C6 C1 176.6(3) . . . . ?
C4 C5 C6 N2 177.1(4) . . . . ?
C4 C5 C6 C1 -1.2(6) . . . . ?
C2 C1 C6 N2 -176.9(3) . . . . ?
N1 C1 C6 N2 1.0(4) . . . . ?
C2 C1 C6 C5 1.8(6) . . . . ?
N1 C1 C6 C5 179.7(3) . . . . ?
C1 N1 C7 N2 0.0(4) . . . . ?
Ag1 N1 C7 N2 -173.0(2) . . . . ?
C1 N1 C7 C8 -173.8(3) . . . . ?
Ag1 N1 C7 C8 13.2(5) . . . . ?
C6 N2 C7 N1 0.6(4) . . . . ?
C17 N2 C7 N1 -176.9(3) . . . . ?
C6 N2 C7 C8 174.7(3) . . . . ?
C17 N2 C7 C8 -2.8(6) . . . . ?
C9 O1 C8 C7 -91.8(4) . . . . ?
N1 C7 C8 O1 -25.7(5) . . . . ?
N2 C7 C8 O1 161.0(3) . . . . ?
C8 O1 C9 C10 168.0(3) . . . . ?
C16 N3 C10 N4 -1.0(4) . . . . ?
Ag2 N3 C10 N4 -173.4(2) . . . . ?
C16 N3 C10 C9 175.3(3) . . . . ?
Ag2 N3 C10 C9 2.9(5) . . . . ?
C11 N4 C10 N3 1.0(4) . . . . ?
C19 N4 C10 N3 178.2(3) . . . . ?
C11 N4 C10 C9 -175.3(3) . . . . ?
C19 N4 C10 C9 2.0(6) . . . . ?
O1 C9 C10 N3 -97.3(4) . . . . ?
O1 C9 C10 N4 78.6(4) . . . . ?
C10 N4 C11 C12 178.8(4) . . . . ?
C19 N4 C11 C12 1.5(7) . . . . ?
C10 N4 C11 C16 -0.5(4) . . . . ?
C19 N4 C11 C16 -177.8(3) . . . . ?
N4 C11 C12 C13 -179.8(4) . . . . ?
C16 C11 C12 C13 -0.6(6) . . . . ?
C11 C12 C13 C14 0.6(6) . . . . ?
C12 C13 C14 C15 -0.1(7) . . . . ?
C13 C14 C15 C16 -0.6(6) . . . . ?
C10 N3 C16 C15 -178.7(4) . . . . ?
Ag2 N3 C16 C15 -6.3(6) . . . . ?
C10 N3 C16 C11 0.6(4) . . . . ?
Ag2 N3 C16 C11 173.0(2) . . . . ?
C14 C15 C16 N3 179.8(4) . . . . ?
C14 C15 C16 C11 0.6(5) . . . . ?
C12 C11 C16 N3 -179.4(3) . . . . ?
N4 C11 C16 N3 0.0(4) . . . . ?
C12 C11 C16 C15 0.0(6) . . . . ?
N4 C11 C16 C15 179.3(3) . . . . ?
C7 N2 C17 C18 -96.3(5) . . . . ?
C6 N2 C17 C18 86.6(5) . . . . ?
C10 N4 C19 C20 -92.8(5) . . . . ?
C11 N4 C19 C20 84.0(5) . . . . ?
C27 N5 C21 C22 180.0(4) . . . . ?
Ag2 N5 C21 C22 1.3(6) . . . . ?
C27 N5 C21 C26 0.3(4) . . . . ?
Ag2 N5 C21 C26 -178.4(2) . . . . ?
N5 C21 C22 C23 -179.3(4) . . . . ?
C26 C21 C22 C23 0.3(6) . . . . ?
C21 C22 C23 C24 0.1(6) . . . . ?
C22 C23 C24 C25 0.2(7) . . . . ?
C23 C24 C25 C26 -1.0(6) . . . . ?
C24 C25 C26 N6 180.0(4) . . . . ?
C24 C25 C26 C21 1.5(6) . . . . ?
C27 N6 C26 C25 -178.5(4) . . . . ?
C37 N6 C26 C25 1.1(7) . . . . ?
C27 N6 C26 C21 0.2(4) . . . . ?
C37 N6 C26 C21 179.9(4) . . . . ?
N5 C21 C26 C25 178.6(3) . . . . ?
C22 C21 C26 C25 -1.2(6) . . . . ?
N5 C21 C26 N6 -0.3(4) . . . . ?
C22 C21 C26 N6 180.0(3) . . . . ?
C21 N5 C27 N6 -0.1(4) . . . . ?
Ag2 N5 C27 N6 178.6(2) . . . . ?
C21 N5 C27 C28 -179.1(4) . . . . ?
Ag2 N5 C27 C28 -0.4(5) . . . . ?
C26 N6 C27 N5 -0.1(4) . . . . ?
C37 N6 C27 N5 -179.7(4) . . . . ?
C26 N6 C27 C28 178.9(4) . . . . ?
C37 N6 C27 C28 -0.7(6) . . . . ?
C29 O2 C28 C27 175.3(3) . . . . ?
N5 C27 C28 O2 -30.2(5) . . . . ?
N6 C27 C28 O2 150.9(4) . . . . ?
C28 O2 C29 C30 178.2(3) . . . . ?
C36 N7 C30 N8 -0.4(4) . . . . ?
Ag1 N7 C30 N8 177.8(2) . . . . ?
C36 N7 C30 C29 179.2(3) . . . . ?
Ag1 N7 C30 C29 -2.6(5) . . . . ?
C31 N8 C30 N7 0.4(4) . . . . ?
C39 N8 C30 N7 -174.3(3) . . . . ?
C31 N8 C30 C29 -179.2(3) . . . . ?
C39 N8 C30 C29 6.2(6) . . . . ?
O2 C29 C30 N7 -14.6(5) . . . . ?
O2 C29 C30 N8 164.9(3) . . . . ?
C30 N8 C31 C36 -0.2(4) . . . . ?
C39 N8 C31 C36 174.5(3) . . . . ?
C30 N8 C31 C32 177.7(4) . . . . ?
C39 N8 C31 C32 -7.5(6) . . . . ?
N8 C31 C32 C33 -179.0(4) . . . . ?
C36 C31 C32 C33 -1.4(6) . . . . ?
C31 C32 C33 C34 -0.2(6) . . . . ?
C32 C33 C34 C35 0.6(7) . . . . ?
C33 C34 C35 C36 0.7(6) . . . . ?
C30 N7 C36 C35 179.2(4) . . . . ?
Ag1 N7 C36 C35 0.9(6) . . . . ?
C30 N7 C36 C31 0.2(4) . . . . ?
Ag1 N7 C36 C31 -178.0(2) . . . . ?
C34 C35 C36 N7 178.9(4) . . . . ?
C34 C35 C36 C31 -2.3(6) . . . . ?
N8 C31 C36 N7 0.0(4) . . . . ?
C32 C31 C36 N7 -178.2(3) . . . . ?
N8 C31 C36 C35 -179.1(3) . . . . ?
C32 C31 C36 C35 2.7(6) . . . . ?
C27 N6 C37 C38 79.8(5) . . . . ?
C26 N6 C37 C38 -99.8(5) . . . . ?
C30 N8 C39 C40 -107.3(4) . . . . ?
C31 N8 C39 C40 79.0(5) . . . . ?
Ag2 O3 C41 C42 -149.2(3) . . . . ?
Ag2 O3 C41 C46 31.1(7) . . . . ?
O4 N9 C42 C43 149.8(4) . . . . ?
O5 N9 C42 C43 -30.6(6) . . . . ?
O4 N9 C42 C41 -30.5(6) . . . . ?
O5 N9 C42 C41 149.1(4) . . . . ?
O3 C41 C42 C43 -178.1(4) . . . . ?
C46 C41 C42 C43 1.6(6) . . . . ?
O3 C41 C42 N9 2.2(6) . . . . ?
C46 C41 C42 N9 -178.1(3) . . . . ?
N9 C42 C43 C44 -177.6(4) . . . . ?
C41 C42 C43 C44 2.7(6) . . . . ?
C42 C43 C44 C45 -3.2(6) . . . . ?
C42 C43 C44 N10 176.3(4) . . . . ?
O7 N10 C44 C43 -170.2(4) . . . . ?
O6 N10 C44 C43 7.9(6) . . . . ?
O7 N10 C44 C45 9.2(6) . . . . ?
O6 N10 C44 C45 -172.7(4) . . . . ?
C43 C44 C45 C46 -1.0(6) . . . . ?
N10 C44 C45 C46 179.6(3) . . . . ?
C44 C45 C46 N11 -175.4(3) . . . . ?
C44 C45 C46 C41 5.9(6) . . . . ?
O9 N11 C46 C45 -36.8(5) . . . . ?
O8 N11 C46 C45 140.1(4) . . . . ?
O9 N11 C46 C41 142.0(4) . . . . ?
O8 N11 C46 C41 -41.1(5) . . . . ?
O3 C41 C46 C45 173.7(4) . . . . ?
C42 C41 C46 C45 -6.0(6) . . . . ?
O3 C41 C46 N11 -4.9(6) . . . . ?
C42 C41 C46 N11 175.4(3) . . . . ?
O12 N12 C48 C49 35.1(6) . . . . ?
O11 N12 C48 C49 -143.6(4) . . . . ?
O12 N12 C48 C47 -143.4(4) . . . . ?
O11 N12 C48 C47 37.9(5) . . . . ?
O10 C47 C48 C49 -169.5(4) . . . . ?
C52 C47 C48 C49 7.6(5) . . . . ?
O10 C47 C48 N12 8.9(5) . . . . ?
C52 C47 C48 N12 -174.0(3) . . . . ?
N12 C48 C49 C50 176.6(3) . . . . ?
C47 C48 C49 C50 -5.0(6) . . . . ?
C48 C49 C50 C51 -0.4(5) . . . . ?
C48 C49 C50 N13 -179.5(3) . . . . ?
O13 N13 C50 C51 173.9(4) . . . . ?
O14 N13 C50 C51 -6.1(5) . . . . ?
O13 N13 C50 C49 -7.0(5) . . . . ?
O14 N13 C50 C49 173.1(4) . . . . ?
C49 C50 C51 C52 2.0(5) . . . . ?
N13 C50 C51 C52 -178.9(3) . . . . ?
C50 C51 C52 N14 -178.9(3) . . . . ?
C50 C51 C52 C47 1.5(6) . . . . ?
O16 N14 C52 C51 172.2(4) . . . . ?
O15 N14 C52 C51 -5.7(5) . . . . ?
O16 N14 C52 C47 -8.2(5) . . . . ?
O15 N14 C52 C47 174.0(4) . . . . ?
O10 C47 C52 C51 171.2(4) . . . . ?
C48 C47 C52 C51 -5.7(5) . . . . ?
O10 C47 C52 N14 -8.4(6) . . . . ?
C48 C47 C52 N14 174.7(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.987
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.987
_refine_diff_density_max         0.729
_refine_diff_density_min         -0.950
_refine_diff_density_rms         0.119
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_g0531
_database_code_depnum_ccdc_archive 'CCDC 721073'
_audit_update_record             
;
2015-06-19 deposited with the CCDC.
2015-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C48 H44 Ag2 N14 O18'
_chemical_formula_weight         1320.71

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P_-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.09520(10)
_cell_length_b                   12.8978(3)
_cell_length_c                   15.0574(4)
_cell_angle_alpha                110.5830(10)
_cell_angle_beta                 102.7630(10)
_cell_angle_gamma                97.5890(10)
_cell_volume                     1224.46(5)
_cell_formula_units_Z            1
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    7749
_cell_measurement_theta_min      3.16
_cell_measurement_theta_max      27.5

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.791
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             668
_exptl_absorpt_coefficient_mu    0.895
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  0.790
_exptl_absorpt_correction_T_max  0.874
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX II area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_decay_%        0
_diffrn_reflns_number            12128
_diffrn_reflns_av_R_equivalents  0.0151
_diffrn_reflns_av_sigmaI/netI    0.0192
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         3.02
_diffrn_reflns_theta_max         27.48
_reflns_number_total             5557
_reflns_number_gt                5204
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART APEX II'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0515P)²+0.9730P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0052(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         5557
_refine_ls_number_parameters     379
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0245
_refine_ls_R_factor_gt           0.0223
_refine_ls_wR_factor_ref         0.0781
_refine_ls_wR_factor_gt          0.0731
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.031
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.66384(2) 0.735797(12) 0.156651(10) 0.01770(7) Uani 1 1 d . . .
O1 O 0.3144(2) 0.40855(12) 0.15284(10) 0.0153(3) Uani 1 1 d . . .
O2 O 0.0434(2) 0.61242(13) 0.15297(11) 0.0211(3) Uani 1 1 d . . .
O3 O 0.2723(3) 0.81388(17) 0.16226(14) 0.0376(4) Uani 1 1 d . . .
O4 O 0.1434(3) 0.93461(14) 0.25692(12) 0.0307(4) Uani 1 1 d . . .
O5 O 0.4108(3) 0.94396(13) 0.59598(12) 0.0274(4) Uani 1 1 d . . .
O6 O 0.3825(3) 0.78299(14) 0.61281(11) 0.0280(4) Uani 1 1 d . . .
O7 O -0.0645(2) 0.43372(13) 0.20130(11) 0.0210(3) Uani 1 1 d . . .
O8 O 0.1360(3) 0.43468(14) 0.33191(12) 0.0305(4) Uani 1 1 d . . .
O9 O 0.2588(3) 0.58159(17) 0.00659(14) 0.0280(4) Uani 1 1 d . . .
N1 N 0.6418(2) 0.66286(14) 0.26031(12) 0.0137(3) Uani 1 1 d . . .
N2 N 0.6434(2) 0.53988(14) 0.33328(12) 0.0146(3) Uani 1 1 d . . .
N3 N 0.2656(2) 0.17463(14) -0.07104(12) 0.0133(3) Uani 1 1 d . . .
N4 N 0.2340(2) 0.14304(13) 0.06168(12) 0.0125(3) Uani 1 1 d . . .
N5 N 0.2066(3) 0.84816(15) 0.23331(13) 0.0205(4) Uani 1 1 d . . .
N6 N 0.3664(3) 0.83903(15) 0.56119(13) 0.0187(3) Uani 1 1 d . . .
N7 N 0.0665(3) 0.48381(15) 0.27951(13) 0.0169(3) Uani 1 1 d . . .
C1 C 0.7204(3) 0.72306(16) 0.36216(14) 0.0132(3) Uani 1 1 d . . .
C2 C 0.7903(3) 0.83979(18) 0.41789(16) 0.0205(4) Uani 1 1 d . . .
H2A H 0.7910 0.8928 0.3872 0.025 Uiso 1 1 calc R . .
C3 C 0.8586(3) 0.87520(19) 0.51971(17) 0.0259(5) Uani 1 1 d . . .
H3A H 0.9066 0.9542 0.5596 0.031 Uiso 1 1 calc R . .
C4 C 0.8588(4) 0.7974(2) 0.56563(16) 0.0280(5) Uani 1 1 d . . .
H4A H 0.9071 0.8252 0.6358 0.034 Uiso 1 1 calc R . .
C5 C 0.7907(3) 0.6815(2) 0.51150(16) 0.0231(4) Uani 1 1 d . . .
H5A H 0.7909 0.6286 0.5423 0.028 Uiso 1 1 calc R . .
C6 C 0.7215(3) 0.64660(16) 0.40888(14) 0.0145(4) Uani 1 1 d . . .
C7 C 0.5983(3) 0.55424(16) 0.24662(14) 0.0141(4) Uani 1 1 d . . .
C8 C 0.5023(3) 0.45886(17) 0.14860(15) 0.0167(4) Uani 1 1 d . . .
H8A H 0.4842 0.4876 0.0951 0.020 Uiso 1 1 calc R . .
H8B H 0.5851 0.4022 0.1357 0.020 Uiso 1 1 calc R . .
C9 C 0.1898(3) 0.33269(16) 0.05801(14) 0.0152(4) Uani 1 1 d . . .
H9A H 0.1961 0.3694 0.0106 0.018 Uiso 1 1 calc R . .
H9B H 0.0512 0.3205 0.0613 0.018 Uiso 1 1 calc R . .
C10 C 0.2392(3) 0.21879(16) 0.01803(14) 0.0123(3) Uani 1 1 d . . .
C11 C 0.2528(3) 0.04169(16) -0.00486(14) 0.0128(3) Uani 1 1 d . . .
C12 C 0.2538(3) -0.06346(17) 0.00114(15) 0.0152(4) Uani 1 1 d . . .
H12A H 0.2441 -0.0756 0.0588 0.018 Uiso 1 1 calc R . .
C13 C 0.2696(3) -0.14941(17) -0.08152(16) 0.0180(4) Uani 1 1 d . . .
H13A H 0.2708 -0.2227 -0.0808 0.022 Uiso 1 1 calc R . .
C14 C 0.2841(3) -0.13062(17) -0.16668(15) 0.0188(4) Uani 1 1 d . . .
H14A H 0.2920 -0.1921 -0.2225 0.023 Uiso 1 1 calc R . .
C15 C 0.2872(3) -0.02534(18) -0.17139(14) 0.0175(4) Uani 1 1 d . . .
H15A H 0.2996 -0.0129 -0.2286 0.021 Uiso 1 1 calc R . .
C16 C 0.2713(3) 0.06183(16) -0.08843(14) 0.0131(3) Uani 1 1 d . . .
C17 C 0.6214(3) 0.43249(18) 0.34685(17) 0.0233(4) Uani 1 1 d . . .
H17A H 0.5629 0.3690 0.2823 0.035 Uiso 1 1 calc R . .
H17B H 0.5346 0.4323 0.3892 0.035 Uiso 1 1 calc R . .
H17C H 0.7520 0.4242 0.3782 0.035 Uiso 1 1 calc R . .
C18 C 0.2139(3) 0.16111(17) 0.16011(14) 0.0162(4) Uani 1 1 d . . .
H18A H 0.2039 0.2397 0.1932 0.024 Uiso 1 1 calc R . .
H18B H 0.3304 0.1471 0.1992 0.024 Uiso 1 1 calc R . .
H18C H 0.0940 0.1086 0.1540 0.024 Uiso 1 1 calc R . .
C19 C 0.1228(3) 0.65997(17) 0.24425(14) 0.0152(4) Uani 1 1 d . . .
C20 C 0.2073(3) 0.78196(17) 0.29482(15) 0.0158(4) Uani 1 1 d . . .
C21 C 0.2825(3) 0.84054(17) 0.39469(15) 0.0169(4) Uani 1 1 d . . .
H21A H 0.3279 0.9210 0.4225 0.020 Uiso 1 1 calc R . .
C22 C 0.2911(3) 0.77943(17) 0.45516(14) 0.0156(4) Uani 1 1 d . . .
C23 C 0.2246(3) 0.66269(17) 0.41502(14) 0.0158(4) Uani 1 1 d . . .
H23A H 0.2358 0.6218 0.4568 0.019 Uiso 1 1 calc R . .
C24 C 0.1418(3) 0.60531(16) 0.31412(14) 0.0146(4) Uani 1 1 d . . .
H9BO H 0.205(5) 0.599(3) 0.049(3) 0.037(8) Uiso 1 1 d . . .
H9AO H 0.175(4) 0.537(3) -0.041(2) 0.022(7) Uiso 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N3 2.1038(15) 2_665 ?
Ag N1 2.1088(16) . ?
O1 C9 1.417(2) . ?
O1 C8 1.429(2) . ?
O2 C19 1.248(2) . ?
O3 N5 1.225(3) . ?
O4 N5 1.222(2) . ?
O5 N6 1.233(2) . ?
O6 N6 1.232(2) . ?
O7 N7 1.221(2) . ?
O8 N7 1.237(2) . ?
O9 H9BO 0.80(3) . ?
O9 H9AO 0.79(3) . ?
N1 C7 1.325(2) . ?
N1 C1 1.392(2) . ?
N2 C7 1.357(2) . ?
N2 C6 1.384(3) . ?
N2 C17 1.463(2) . ?
N3 C10 1.327(2) . ?
N3 C16 1.393(2) . ?
N3 Ag 2.1038(15) 2_665 ?
N4 C10 1.357(2) . ?
N4 C11 1.384(2) . ?
N4 C18 1.459(2) . ?
N5 C20 1.464(2) . ?
N6 C22 1.441(2) . ?
N7 C24 1.447(2) . ?
C1 C2 1.395(3) . ?
C1 C6 1.398(3) . ?
C2 C3 1.384(3) . ?
C2 H2A 0.9500 . ?
C3 C4 1.405(4) . ?
C3 H3A 0.9500 . ?
C4 C5 1.383(3) . ?
C4 H4A 0.9500 . ?
C5 C6 1.396(3) . ?
C5 H5A 0.9500 . ?
C7 C8 1.488(3) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.500(3) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C11 C12 1.391(3) . ?
C11 C16 1.401(3) . ?
C12 C13 1.384(3) . ?
C12 H12A 0.9500 . ?
C13 C14 1.408(3) . ?
C13 H13A 0.9500 . ?
C14 C15 1.382(3) . ?
C14 H14A 0.9500 . ?
C15 C16 1.395(3) . ?
C15 H15A 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C24 1.451(3) . ?
C19 C20 1.457(3) . ?
C20 C21 1.363(3) . ?
C21 C22 1.395(3) . ?
C21 H21A 0.9500 . ?
C22 C23 1.379(3) . ?
C23 C24 1.379(3) . ?
C23 H23A 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ag N1 169.94(6) 2_665 . ?
C9 O1 C8 112.12(14) . . ?
H9BO O9 H9AO 105(3) . . ?
C7 N1 C1 105.72(16) . . ?
C7 N1 Ag 129.50(13) . . ?
C1 N1 Ag 123.11(13) . . ?
C7 N2 C6 107.53(16) . . ?
C7 N2 C17 127.46(17) . . ?
C6 N2 C17 124.99(17) . . ?
C10 N3 C16 106.05(15) . . ?
C10 N3 Ag 126.54(13) . 2_665 ?
C16 N3 Ag 126.57(13) . 2_665 ?
C10 N4 C11 107.18(15) . . ?
C10 N4 C18 128.13(16) . . ?
C11 N4 C18 124.68(16) . . ?
O4 N5 O3 124.36(18) . . ?
O4 N5 C20 118.06(18) . . ?
O3 N5 C20 117.56(17) . . ?
O6 N6 O5 123.09(18) . . ?
O6 N6 C22 118.58(17) . . ?
O5 N6 C22 118.32(17) . . ?
O7 N7 O8 122.29(18) . . ?
O7 N7 C24 119.57(17) . . ?
O8 N7 C24 118.13(17) . . ?
N1 C1 C2 130.41(18) . . ?
N1 C1 C6 109.19(16) . . ?
C2 C1 C6 120.40(18) . . ?
C3 C2 C1 117.3(2) . . ?
C3 C2 H2A 121.4 . . ?
C1 C2 H2A 121.4 . . ?
C2 C3 C4 121.7(2) . . ?
C2 C3 H3A 119.1 . . ?
C4 C3 H3A 119.1 . . ?
C5 C4 C3 121.8(2) . . ?
C5 C4 H4A 119.1 . . ?
C3 C4 H4A 119.1 . . ?
C4 C5 C6 116.1(2) . . ?
C4 C5 H5A 122.0 . . ?
C6 C5 H5A 122.0 . . ?
N2 C6 C5 131.77(19) . . ?
N2 C6 C1 105.45(16) . . ?
C5 C6 C1 122.78(19) . . ?
N1 C7 N2 112.11(17) . . ?
N1 C7 C8 124.41(17) . . ?
N2 C7 C8 123.43(17) . . ?
O1 C8 C7 106.48(15) . . ?
O1 C8 H8A 110.4 . . ?
C7 C8 H8A 110.4 . . ?
O1 C8 H8B 110.4 . . ?
C7 C8 H8B 110.4 . . ?
H8A C8 H8B 108.6 . . ?
O1 C9 C10 115.32(16) . . ?
O1 C9 H9A 108.4 . . ?
C10 C9 H9A 108.4 . . ?
O1 C9 H9B 108.4 . . ?
C10 C9 H9B 108.4 . . ?
H9A C9 H9B 107.5 . . ?
N3 C10 N4 112.12(16) . . ?
N3 C10 C9 123.14(17) . . ?
N4 C10 C9 124.11(17) . . ?
N4 C11 C12 131.31(17) . . ?
N4 C11 C16 106.06(16) . . ?
C12 C11 C16 122.62(18) . . ?
C13 C12 C11 116.34(18) . . ?
C13 C12 H12A 121.8 . . ?
C11 C12 H12A 121.8 . . ?
C12 C13 C14 121.44(18) . . ?
C12 C13 H13A 119.3 . . ?
C14 C13 H13A 119.3 . . ?
C15 C14 C13 121.92(18) . . ?
C15 C14 H14A 119.0 . . ?
C13 C14 H14A 119.0 . . ?
C14 C15 C16 117.05(18) . . ?
C14 C15 H15A 121.5 . . ?
C16 C15 H15A 121.5 . . ?
N3 C16 C15 130.84(18) . . ?
N3 C16 C11 108.54(16) . . ?
C15 C16 C11 120.60(18) . . ?
N2 C17 H17A 109.5 . . ?
N2 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
N2 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N4 C18 H18A 109.5 . . ?
N4 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N4 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
O2 C19 C24 126.35(19) . . ?
O2 C19 C20 122.73(18) . . ?
C24 C19 C20 110.91(17) . . ?
C21 C20 C19 125.76(18) . . ?
C21 C20 N5 116.97(18) . . ?
C19 C20 N5 117.24(17) . . ?
C20 C21 C22 118.35(19) . . ?
C20 C21 H21A 120.8 . . ?
C22 C21 H21A 120.8 . . ?
C23 C22 C21 120.91(18) . . ?
C23 C22 N6 119.35(17) . . ?
C21 C22 N6 119.73(18) . . ?
C24 C23 C22 119.92(18) . . ?
C24 C23 H23A 120.0 . . ?
C22 C23 H23A 120.0 . . ?
C23 C24 N7 115.91(17) . . ?
C23 C24 C19 123.98(18) . . ?
N7 C24 C19 120.08(17) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Ag N1 C7 -129.3(3) 2_665 . . . ?
N3 Ag N1 C1 33.8(4) 2_665 . . . ?
C7 N1 C1 C2 -179.8(2) . . . . ?
Ag N1 C1 C2 13.7(3) . . . . ?
C7 N1 C1 C6 -0.3(2) . . . . ?
Ag N1 C1 C6 -166.84(13) . . . . ?
N1 C1 C2 C3 179.2(2) . . . . ?
C6 C1 C2 C3 -0.2(3) . . . . ?
C1 C2 C3 C4 0.2(3) . . . . ?
C2 C3 C4 C5 0.0(4) . . . . ?
C3 C4 C5 C6 -0.2(3) . . . . ?
C7 N2 C6 C5 179.6(2) . . . . ?
C17 N2 C6 C5 -2.1(3) . . . . ?
C7 N2 C6 C1 -0.3(2) . . . . ?
C17 N2 C6 C1 178.01(18) . . . . ?
C4 C5 C6 N2 -179.7(2) . . . . ?
C4 C5 C6 C1 0.2(3) . . . . ?
N1 C1 C6 N2 0.4(2) . . . . ?
C2 C1 C6 N2 179.91(18) . . . . ?
N1 C1 C6 C5 -179.53(18) . . . . ?
C2 C1 C6 C5 0.0(3) . . . . ?
C1 N1 C7 N2 0.1(2) . . . . ?
Ag N1 C7 N2 165.49(13) . . . . ?
C1 N1 C7 C8 177.33(17) . . . . ?
Ag N1 C7 C8 -17.3(3) . . . . ?
C6 N2 C7 N1 0.1(2) . . . . ?
C17 N2 C7 N1 -178.12(19) . . . . ?
C6 N2 C7 C8 -177.14(17) . . . . ?
C17 N2 C7 C8 4.6(3) . . . . ?
C9 O1 C8 C7 167.37(15) . . . . ?
N1 C7 C8 O1 -116.1(2) . . . . ?
N2 C7 C8 O1 60.8(2) . . . . ?
C8 O1 C9 C10 76.7(2) . . . . ?
C16 N3 C10 N4 2.1(2) . . . . ?
Ag N3 C10 N4 -167.90(12) 2_665 . . . ?
C16 N3 C10 C9 -169.11(17) . . . . ?
Ag N3 C10 C9 20.9(3) 2_665 . . . ?
C11 N4 C10 N3 -1.7(2) . . . . ?
C18 N4 C10 N3 177.87(17) . . . . ?
C11 N4 C10 C9 169.38(17) . . . . ?
C18 N4 C10 C9 -11.0(3) . . . . ?
O1 C9 C10 N3 -127.92(19) . . . . ?
O1 C9 C10 N4 61.9(2) . . . . ?
C10 N4 C11 C12 -178.9(2) . . . . ?
C18 N4 C11 C12 1.5(3) . . . . ?
C10 N4 C11 C16 0.6(2) . . . . ?
C18 N4 C11 C16 -179.02(17) . . . . ?
N4 C11 C12 C13 178.03(19) . . . . ?
C16 C11 C12 C13 -1.4(3) . . . . ?
C11 C12 C13 C14 0.1(3) . . . . ?
C12 C13 C14 C15 1.3(3) . . . . ?
C13 C14 C15 C16 -1.2(3) . . . . ?
C10 N3 C16 C15 176.9(2) . . . . ?
Ag N3 C16 C15 -13.1(3) 2_665 . . . ?
C10 N3 C16 C11 -1.7(2) . . . . ?
Ag N3 C16 C11 168.35(12) 2_665 . . . ?
C14 C15 C16 N3 -178.51(19) . . . . ?
C14 C15 C16 C11 -0.1(3) . . . . ?
N4 C11 C16 N3 0.6(2) . . . . ?
C12 C11 C16 N3 -179.79(17) . . . . ?
N4 C11 C16 C15 -178.10(17) . . . . ?
C12 C11 C16 C15 1.5(3) . . . . ?
O2 C19 C20 C21 174.76(19) . . . . ?
C24 C19 C20 C21 -4.3(3) . . . . ?
O2 C19 C20 N5 -3.4(3) . . . . ?
C24 C19 C20 N5 177.50(17) . . . . ?
O4 N5 C20 C21 -47.6(3) . . . . ?
O3 N5 C20 C21 131.3(2) . . . . ?
O4 N5 C20 C19 130.7(2) . . . . ?
O3 N5 C20 C19 -50.3(3) . . . . ?
C19 C20 C21 C22 3.8(3) . . . . ?
N5 C20 C21 C22 -177.99(18) . . . . ?
C20 C21 C22 C23 -0.2(3) . . . . ?
C20 C21 C22 N6 -178.86(18) . . . . ?
O6 N6 C22 C23 5.1(3) . . . . ?
O5 N6 C22 C23 -174.50(19) . . . . ?
O6 N6 C22 C21 -176.23(19) . . . . ?
O5 N6 C22 C21 4.2(3) . . . . ?
C21 C22 C23 C24 -2.3(3) . . . . ?
N6 C22 C23 C24 176.33(17) . . . . ?
C22 C23 C24 N7 -176.72(18) . . . . ?
C22 C23 C24 C19 1.5(3) . . . . ?
O7 N7 C24 C23 154.91(18) . . . . ?
O8 N7 C24 C23 -23.9(3) . . . . ?
O7 N7 C24 C19 -23.4(3) . . . . ?
O8 N7 C24 C19 157.83(19) . . . . ?
O2 C19 C24 C23 -177.48(19) . . . . ?
C20 C19 C24 C23 1.5(3) . . . . ?
O2 C19 C24 N7 0.7(3) . . . . ?
C20 C19 C24 N7 179.71(16) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O9 H9BO O2 0.80(3) 2.11(4) 2.895(2) 169(3) .
O9 H9BO O3 0.80(3) 2.60(3) 3.061(3) 118(3) .
O9 H9AO O2 0.79(3) 2.18(3) 2.951(2) 166(3) 2_565
O9 H9AO O7 0.79(3) 2.55(3) 3.054(2) 123(2) 2_565

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         0.519
_refine_diff_density_min         -0.582
_refine_diff_density_rms         0.115
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_g0571
_database_code_depnum_ccdc_archive 'CCDC 1408501'
_audit_update_record             
;
2015-06-24 deposited with the CCDC.
2015-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C72 H56 Ag2 N14 O16'
_chemical_formula_weight         1589.05

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.500 189 33 ' '
_platon_squeeze_details          
;
;

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.3730(3)
_cell_length_b                   14.8244(4)
_cell_length_c                   17.3282(4)
_cell_angle_alpha                86.8670(10)
_cell_angle_beta                 89.7150(10)
_cell_angle_gamma                87.8750(10)
_cell_volume                     3427.75(14)
_cell_formula_units_Z            2
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       chip
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.09
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.540
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1616
_exptl_absorpt_coefficient_mu    0.652
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  0.910
_exptl_absorpt_correction_T_max  0.943
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX II area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            28124
_diffrn_reflns_av_R_equivalents  0.0352
_diffrn_reflns_av_sigmaI/netI    0.0520
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         3.04
_diffrn_reflns_theta_max         25.50
_reflns_number_total             12762
_reflns_number_gt                8693
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART APEX II'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0907P)²+8.4356P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0056(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         12762
_refine_ls_number_parameters     938
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0877
_refine_ls_R_factor_gt           0.0487
_refine_ls_wR_factor_ref         0.1900
_refine_ls_wR_factor_gt          0.1228
_refine_ls_goodness_of_fit_ref   1.179
_refine_ls_restrained_S_all      1.179
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.49096(3) 0.68447(3) 0.17465(3) 0.02872(16) Uani 1 1 d . . .
Ag2 Ag 0.32908(3) 0.63186(3) 0.29905(3) 0.02858(16) Uani 1 1 d . . .
O1 O 0.5178(3) 0.3851(3) 0.2416(2) 0.0302(10) Uani 1 1 d . . .
O2 O 0.3567(3) 0.8103(3) 0.2423(2) 0.0267(9) Uani 1 1 d . . .
O3 O 0.2573(3) 0.7357(3) 0.4069(3) 0.0380(11) Uani 1 1 d . . .
O4 O 0.1846(4) 0.5588(3) 0.3910(3) 0.0433(12) Uani 1 1 d . . .
O5 O 0.0309(4) 0.5950(6) 0.3673(4) 0.090(3) Uani 1 1 d . . .
O6 O -0.1168(5) 0.6822(6) 0.6161(4) 0.087(2) Uani 1 1 d . . .
O7 O -0.0479(5) 0.7901(5) 0.6741(4) 0.074(2) Uani 1 1 d . . .
O8 O 0.2457(4) 0.9188(4) 0.5756(4) 0.077(2) Uani 1 1 d . . .
O9 O 0.3460(4) 0.8440(4) 0.5047(3) 0.0611(16) Uani 1 1 d . . .
O12 O 0.6038(3) 0.7651(3) 0.0759(2) 0.0314(10) Uani 1 1 d . . .
O13 O 0.4173(4) 0.8326(3) 0.0645(3) 0.0419(12) Uani 1 1 d . . .
O14 O 0.3882(3) 0.9613(3) 0.1136(3) 0.0468(13) Uani 1 1 d . . .
O15 O 0.6378(4) 1.1773(3) 0.1204(3) 0.0468(13) Uani 1 1 d . . .
O16 O 0.7827(3) 1.1489(3) 0.0695(3) 0.0393(11) Uani 1 1 d . . .
O17 O 0.8784(3) 0.8460(3) 0.0109(3) 0.0379(11) Uani 1 1 d . . .
O18 O 0.8020(4) 0.7385(3) 0.0730(4) 0.0682(19) Uani 1 1 d . . .
N1 N 0.4538(4) 0.5662(3) 0.3581(3) 0.0260(11) Uani 1 1 d . . .
N2 N 0.5765(4) 0.4662(4) 0.3902(3) 0.0293(12) Uani 1 1 d . . .
N3 N 0.4453(4) 0.5681(3) 0.1154(3) 0.0239(10) Uani 1 1 d . . .
N4 N 0.4377(4) 0.4285(3) 0.0785(3) 0.0224(10) Uani 1 1 d . . .
N5 N 0.2151(3) 0.6799(3) 0.2187(3) 0.0260(11) Uani 1 1 d . . .
N6 N 0.1360(3) 0.7781(3) 0.1367(3) 0.0266(11) Uani 1 1 d . . .
N7 N 0.5543(4) 0.7709(3) 0.2576(3) 0.0250(11) Uani 1 1 d . . .
N8 N 0.5755(4) 0.8684(4) 0.3492(3) 0.0317(12) Uani 1 1 d . . .
N9 N 0.1084(4) 0.6052(4) 0.4015(4) 0.0415(14) Uani 1 1 d . . .
N10 N -0.0509(5) 0.7363(6) 0.6226(4) 0.0602(19) Uani 1 1 d . . .
N11 N 0.2631(4) 0.8554(4) 0.5347(3) 0.0398(14) Uani 1 1 d . . .
N12 N 0.4463(4) 0.9027(4) 0.0893(3) 0.0318(12) Uani 1 1 d . . .
N13 N 0.7003(4) 1.1247(4) 0.0921(3) 0.0328(12) Uani 1 1 d . . .
N14 N 0.8070(4) 0.8166(4) 0.0482(3) 0.0352(13) Uani 1 1 d . . .
C1 C 0.5122(4) 0.6033(4) 0.4145(3) 0.0230(12) Uani 1 1 d . . .
C2 C 0.5021(5) 0.6853(4) 0.4474(3) 0.0304(14) Uani 1 1 d . . .
H2A H 0.4489 0.7274 0.4340 0.037 Uiso 1 1 calc R . .
C3 C 0.5745(5) 0.7034(5) 0.5017(4) 0.0386(16) Uani 1 1 d . . .
H3A H 0.5701 0.7592 0.5262 0.046 Uiso 1 1 calc R . .
C4 C 0.6525(5) 0.6423(6) 0.5208(4) 0.0440(18) Uani 1 1 d . . .
H4A H 0.7005 0.6574 0.5578 0.053 Uiso 1 1 calc R . .
C5 C 0.6621(5) 0.5592(5) 0.4869(4) 0.0390(16) Uani 1 1 d . . .
H5A H 0.7151 0.5168 0.5004 0.047 Uiso 1 1 calc R . .
C6 C 0.5916(5) 0.5415(4) 0.4333(3) 0.0291(14) Uani 1 1 d . . .
C7 C 0.4933(4) 0.4862(4) 0.3473(3) 0.0253(13) Uani 1 1 d . . .
C8 C 0.4479(5) 0.4212(4) 0.2949(3) 0.0291(13) Uani 1 1 d . . .
H8A H 0.4196 0.3709 0.3268 0.035 Uiso 1 1 calc R . .
H8B H 0.3923 0.4528 0.2657 0.035 Uiso 1 1 calc R . .
C9 C 0.5563(5) 0.4511(4) 0.1872(3) 0.0281(13) Uani 1 1 d . . .
H9A H 0.6152 0.4245 0.1606 0.034 Uiso 1 1 calc R . .
H9B H 0.5786 0.5032 0.2151 0.034 Uiso 1 1 calc R . .
C10 C 0.4790(5) 0.4837(3) 0.1277(4) 0.0254(13) Uani 1 1 d . . .
C11 C 0.3714(5) 0.4811(4) 0.0330(3) 0.0250(13) Uani 1 1 d . . .
C12 C 0.3062(5) 0.4564(4) -0.0249(4) 0.0318(14) Uani 1 1 d . . .
H12A H 0.3024 0.3959 -0.0397 0.038 Uiso 1 1 calc R . .
C13 C 0.2481(5) 0.5265(4) -0.0589(4) 0.0315(14) Uani 1 1 d . . .
H13A H 0.2029 0.5140 -0.0987 0.038 Uiso 1 1 calc R . .
C14 C 0.2537(5) 0.6158(4) -0.0364(4) 0.0312(14) Uani 1 1 d . . .
H14A H 0.2122 0.6619 -0.0613 0.037 Uiso 1 1 calc R . .
C15 C 0.3178(5) 0.6379(4) 0.0207(3) 0.0285(14) Uani 1 1 d . . .
H15A H 0.3215 0.6985 0.0353 0.034 Uiso 1 1 calc R . .
C16 C 0.3775(4) 0.5687(4) 0.0567(3) 0.0244(12) Uani 1 1 d . . .
C17 C 0.6370(5) 0.3815(5) 0.3948(4) 0.0360(15) Uani 1 1 d . . .
H17A H 0.5926 0.3308 0.3870 0.043 Uiso 1 1 calc R . .
H17B H 0.6651 0.3726 0.4476 0.043 Uiso 1 1 calc R . .
C18 C 0.7221(4) 0.3769(4) 0.3371(4) 0.0282(13) Uani 1 1 d . . .
C19 C 0.7956(5) 0.4411(5) 0.3333(4) 0.0418(17) Uani 1 1 d . . .
H19A H 0.7906 0.4914 0.3650 0.050 Uiso 1 1 calc R . .
C20 C 0.8756(6) 0.4317(5) 0.2835(4) 0.0457(18) Uani 1 1 d . . .
H20A H 0.9257 0.4755 0.2817 0.055 Uiso 1 1 calc R . .
C21 C 0.8841(5) 0.3598(5) 0.2362(4) 0.0416(17) Uani 1 1 d . . .
H21A H 0.9396 0.3540 0.2021 0.050 Uiso 1 1 calc R . .
C22 C 0.8108(5) 0.2964(5) 0.2391(4) 0.0395(17) Uani 1 1 d . . .
H22A H 0.8153 0.2467 0.2067 0.047 Uiso 1 1 calc R . .
C23 C 0.7300(5) 0.3056(5) 0.2897(4) 0.0382(16) Uani 1 1 d . . .
H23A H 0.6798 0.2618 0.2915 0.046 Uiso 1 1 calc R . .
C24 C 0.4472(5) 0.3291(4) 0.0795(3) 0.0263(13) Uani 1 1 d . . .
H24A H 0.5084 0.3084 0.1081 0.032 Uiso 1 1 calc R . .
H24B H 0.4546 0.3102 0.0257 0.032 Uiso 1 1 calc R . .
C25 C 0.3590(4) 0.2847(4) 0.1160(3) 0.0258(13) Uani 1 1 d . . .
C26 C 0.2844(5) 0.3314(4) 0.1553(4) 0.0325(14) Uani 1 1 d . . .
H26A H 0.2884 0.3948 0.1594 0.039 Uiso 1 1 calc R . .
C27 C 0.2035(5) 0.2867(4) 0.1888(4) 0.0324(15) Uani 1 1 d . . .
H27A H 0.1529 0.3195 0.2153 0.039 Uiso 1 1 calc R . .
C28 C 0.1976(5) 0.1951(5) 0.1830(4) 0.0380(16) Uani 1 1 d . . .
H28A H 0.1432 0.1643 0.2064 0.046 Uiso 1 1 calc R . .
C29 C 0.2703(5) 0.1472(4) 0.1433(4) 0.0312(14) Uani 1 1 d . . .
H29A H 0.2653 0.0839 0.1389 0.037 Uiso 1 1 calc R . .
C30 C 0.3502(5) 0.1918(4) 0.1103(3) 0.0292(13) Uani 1 1 d . . .
H30A H 0.4000 0.1586 0.0832 0.035 Uiso 1 1 calc R . .
C31 C 0.1504(4) 0.6335(4) 0.1744(3) 0.0251(13) Uani 1 1 d . . .
C32 C 0.1325(5) 0.5418(4) 0.1768(4) 0.0334(14) Uani 1 1 d . . .
H32A H 0.1663 0.4999 0.2120 0.040 Uiso 1 1 calc R . .
C33 C 0.0622(5) 0.5147(5) 0.1246(4) 0.0393(16) Uani 1 1 d . . .
H33A H 0.0486 0.4524 0.1229 0.047 Uiso 1 1 calc R . .
C34 C 0.0112(5) 0.5779(5) 0.0746(4) 0.0401(16) Uani 1 1 d . . .
H34A H -0.0376 0.5568 0.0409 0.048 Uiso 1 1 calc R . .
C35 C 0.0279(4) 0.6668(4) 0.0720(4) 0.0314(14) Uani 1 1 d . . .
H35A H -0.0071 0.7087 0.0375 0.038 Uiso 1 1 calc R . .
C36 C 0.0998(4) 0.6941(4) 0.1230(3) 0.0247(12) Uani 1 1 d . . .
C37 C 0.2035(4) 0.7662(4) 0.1940(3) 0.0241(12) Uani 1 1 d . . .
C38 C 0.2552(4) 0.8395(4) 0.2294(4) 0.0260(13) Uani 1 1 d . . .
H38A H 0.2521 0.8947 0.1946 0.031 Uiso 1 1 calc R . .
H38B H 0.2227 0.8536 0.2790 0.031 Uiso 1 1 calc R . .
C39 C 0.4063(5) 0.8668(4) 0.2898(4) 0.0301(14) Uani 1 1 d . . .
H39A H 0.3742 0.8660 0.3414 0.036 Uiso 1 1 calc R . .
H39B H 0.4027 0.9297 0.2672 0.036 Uiso 1 1 calc R . .
C40 C 0.5127(5) 0.8346(4) 0.2973(3) 0.0287(13) Uani 1 1 d . . .
C41 C 0.6660(5) 0.8188(5) 0.3429(4) 0.0335(15) Uani 1 1 d . . .
C42 C 0.7551(5) 0.8202(5) 0.3834(4) 0.0434(17) Uani 1 1 d . . .
H42A H 0.7643 0.8611 0.4229 0.052 Uiso 1 1 calc R . .
C43 C 0.8290(6) 0.7593(6) 0.3635(5) 0.053(2) Uani 1 1 d . . .
H43A H 0.8903 0.7568 0.3910 0.063 Uiso 1 1 calc R . .
C44 C 0.8171(6) 0.7007(6) 0.3037(6) 0.057(2) Uani 1 1 d . . .
H44A H 0.8715 0.6617 0.2902 0.068 Uiso 1 1 calc R . .
C45 C 0.7276(5) 0.6984(5) 0.2638(4) 0.0398(16) Uani 1 1 d . . .
H45A H 0.7186 0.6577 0.2241 0.048 Uiso 1 1 calc R . .
C46 C 0.6515(5) 0.7593(5) 0.2853(4) 0.0331(15) Uani 1 1 d . . .
C47 C 0.1046(5) 0.8639(4) 0.0963(4) 0.0311(14) Uani 1 1 d . . .
H47A H 0.0726 0.8508 0.0470 0.037 Uiso 1 1 calc R . .
H47B H 0.1648 0.8988 0.0838 0.037 Uiso 1 1 calc R . .
C48 C 0.0324(5) 0.9216(4) 0.1421(4) 0.0283(13) Uani 1 1 d . . .
C49 C 0.0328(5) 1.0142(5) 0.1315(4) 0.0394(16) Uani 1 1 d . . .
H49A H 0.0796 1.0410 0.0967 0.047 Uiso 1 1 calc R . .
C50 C -0.0340(5) 1.0694(5) 0.1709(5) 0.0445(18) Uani 1 1 d . . .
H50A H -0.0316 1.1333 0.1641 0.053 Uiso 1 1 calc R . .
C51 C -0.1040(6) 1.0300(5) 0.2200(4) 0.0476(19) Uani 1 1 d . . .
H51A H -0.1508 1.0668 0.2468 0.057 Uiso 1 1 calc R . .
C52 C -0.1053(6) 0.9366(5) 0.2299(4) 0.051(2) Uani 1 1 d . . .
H52A H -0.1530 0.9096 0.2639 0.061 Uiso 1 1 calc R . .
C53 C -0.0388(5) 0.8826(5) 0.1911(4) 0.0387(16) Uani 1 1 d . . .
H53A H -0.0413 0.8187 0.1977 0.046 Uiso 1 1 calc R . .
C54 C 0.5532(6) 0.9354(5) 0.4061(4) 0.0376(16) Uani 1 1 d . . .
H54A H 0.6166 0.9520 0.4298 0.045 Uiso 1 1 calc R . .
H54B H 0.5112 0.9078 0.4475 0.045 Uiso 1 1 calc R . .
C55 C 0.4996(5) 1.0206(5) 0.3728(3) 0.0366(16) Uani 1 1 d . . .
C56 C 0.5450(7) 1.0742(6) 0.3147(4) 0.051(2) Uani 1 1 d . . .
H56A H 0.6099 1.0579 0.2963 0.062 Uiso 1 1 calc R . .
C57 C 0.4945(7) 1.1514(5) 0.2842(5) 0.053(2) Uani 1 1 d . . .
H57A H 0.5260 1.1891 0.2460 0.063 Uiso 1 1 calc R . .
C58 C 0.3993(7) 1.1739(6) 0.3086(5) 0.056(2) Uani 1 1 d . . .
H58A H 0.3644 1.2254 0.2856 0.067 Uiso 1 1 calc R . .
C59 C 0.3545(7) 1.1220(5) 0.3664(4) 0.050(2) Uani 1 1 d . . .
H59A H 0.2898 1.1389 0.3848 0.060 Uiso 1 1 calc R . .
C60 C 0.4047(6) 1.0445(5) 0.3976(4) 0.0426(18) Uani 1 1 d . . .
H60A H 0.3731 1.0077 0.4364 0.051 Uiso 1 1 calc R . .
C61 C 0.1924(5) 0.7325(4) 0.4577(4) 0.0319(15) Uani 1 1 d . . .
C62 C 0.1095(4) 0.6714(4) 0.4599(4) 0.0315(14) Uani 1 1 d . . .
C63 C 0.0319(5) 0.6736(5) 0.5099(4) 0.0402(16) Uani 1 1 d . . .
H63A H -0.0215 0.6337 0.5055 0.048 Uiso 1 1 calc R . .
C64 C 0.0306(5) 0.7341(5) 0.5674(4) 0.0380(16) Uani 1 1 d . . .
C65 C 0.1073(5) 0.7935(5) 0.5744(4) 0.0397(17) Uani 1 1 d . . .
H65A H 0.1062 0.8346 0.6146 0.048 Uiso 1 1 calc R . .
C66 C 0.1863(5) 0.7920(4) 0.5215(4) 0.0309(14) Uani 1 1 d . . .
C68 C 0.6247(5) 0.8469(4) 0.0770(3) 0.0274(13) Uani 1 1 d . . .
C69 C 0.5519(5) 0.9200(4) 0.0888(3) 0.0275(13) Uani 1 1 d . . .
C70 C 0.5779(5) 1.0083(4) 0.0968(4) 0.0303(14) Uani 1 1 d . . .
H70A H 0.5279 1.0523 0.1093 0.036 Uiso 1 1 calc R . .
C71 C 0.6759(5) 1.0333(4) 0.0866(4) 0.0271(13) Uani 1 1 d . . .
C72 C 0.7493(5) 0.9690(4) 0.0687(4) 0.0297(13) Uani 1 1 d . . .
H72A H 0.8160 0.9863 0.0587 0.036 Uiso 1 1 calc R . .
C73 C 0.7246(5) 0.8800(4) 0.0655(4) 0.0314(14) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N3 2.164(4) . ?
Ag1 N7 2.173(4) . ?
Ag1 O12 2.553(4) . ?
Ag1 Ag2 3.1364(6) . ?
Ag2 N1 2.136(5) . ?
Ag2 N5 2.146(5) . ?
Ag2 O3 2.639(4) . ?
Ag2 O4 2.717(5) . ?
O1 C8 1.422(7) . ?
O1 C9 1.430(7) . ?
O2 C39 1.394(7) . ?
O2 C38 1.423(7) . ?
O3 C61 1.235(7) . ?
O4 N9 1.227(7) . ?
O5 N9 1.215(8) . ?
O6 N10 1.223(10) . ?
O7 N10 1.231(10) . ?
O8 N11 1.223(7) . ?
O9 N11 1.231(8) . ?
O12 C68 1.255(7) . ?
O13 N12 1.223(7) . ?
O14 N12 1.235(7) . ?
O15 N13 1.240(7) . ?
O16 N13 1.227(7) . ?
O17 N14 1.230(7) . ?
O18 N14 1.217(7) . ?
N1 C7 1.303(7) . ?
N1 C1 1.402(7) . ?
N2 C7 1.355(8) . ?
N2 C6 1.398(8) . ?
N2 C17 1.468(8) . ?
N3 C10 1.320(7) . ?
N3 C16 1.365(8) . ?
N4 C10 1.347(8) . ?
N4 C11 1.380(8) . ?
N4 C24 1.474(7) . ?
N5 C37 1.329(8) . ?
N5 C31 1.385(7) . ?
N6 C37 1.345(8) . ?
N6 C36 1.386(8) . ?
N6 C47 1.466(7) . ?
N7 C40 1.303(7) . ?
N7 C46 1.390(8) . ?
N8 C40 1.361(8) . ?
N8 C41 1.400(9) . ?
N8 C54 1.458(8) . ?
N9 C62 1.448(9) . ?
N10 C64 1.447(9) . ?
N11 C66 1.445(9) . ?
N12 C69 1.444(8) . ?
N13 C71 1.413(8) . ?
N14 C73 1.461(8) . ?
C1 C2 1.372(9) . ?
C1 C6 1.404(8) . ?
C2 C3 1.396(9) . ?
C2 H2A 0.9500 . ?
C3 C4 1.385(10) . ?
C3 H3A 0.9500 . ?
C4 C5 1.396(11) . ?
C4 H4A 0.9500 . ?
C5 C6 1.369(9) . ?
C5 H5A 0.9500 . ?
C7 C8 1.506(9) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.511(9) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C11 C16 1.389(8) . ?
C11 C12 1.405(9) . ?
C12 C13 1.382(9) . ?
C12 H12A 0.9500 . ?
C13 C14 1.404(9) . ?
C13 H13A 0.9500 . ?
C14 C15 1.373(9) . ?
C14 H14A 0.9500 . ?
C15 C16 1.398(8) . ?
C15 H15A 0.9500 . ?
C17 C18 1.513(9) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C23 1.375(9) . ?
C18 C19 1.392(10) . ?
C19 C20 1.380(10) . ?
C19 H19A 0.9500 . ?
C20 C21 1.381(10) . ?
C20 H20A 0.9500 . ?
C21 C22 1.382(10) . ?
C21 H21A 0.9500 . ?
C22 C23 1.395(9) . ?
C22 H22A 0.9500 . ?
C23 H23A 0.9500 . ?
C24 C25 1.493(8) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.389(8) . ?
C25 C30 1.396(8) . ?
C26 C27 1.397(9) . ?
C26 H26A 0.9500 . ?
C27 C28 1.372(9) . ?
C27 H27A 0.9500 . ?
C28 C29 1.385(9) . ?
C28 H28A 0.9500 . ?
C29 C30 1.382(9) . ?
C29 H29A 0.9500 . ?
C30 H30A 0.9500 . ?
C31 C32 1.387(9) . ?
C31 C36 1.390(8) . ?
C32 C33 1.394(10) . ?
C32 H32A 0.9500 . ?
C33 C34 1.401(10) . ?
C33 H33A 0.9500 . ?
C34 C35 1.345(9) . ?
C34 H34A 0.9500 . ?
C35 C36 1.395(9) . ?
C35 H35A 0.9500 . ?
C37 C38 1.472(8) . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 C40 1.488(9) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C41 C46 1.386(10) . ?
C41 C42 1.388(9) . ?
C42 C43 1.369(11) . ?
C42 H42A 0.9500 . ?
C43 C44 1.401(13) . ?
C43 H43A 0.9500 . ?
C44 C45 1.387(11) . ?
C44 H44A 0.9500 . ?
C45 C46 1.398(9) . ?
C45 H45A 0.9500 . ?
C47 C48 1.516(8) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 C49 1.376(9) . ?
C48 C53 1.394(9) . ?
C49 C50 1.390(10) . ?
C49 H49A 0.9500 . ?
C50 C51 1.386(11) . ?
C50 H50A 0.9500 . ?
C51 C52 1.387(11) . ?
C51 H51A 0.9500 . ?
C52 C53 1.372(10) . ?
C52 H52A 0.9500 . ?
C53 H53A 0.9500 . ?
C54 C55 1.516(10) . ?
C54 H54A 0.9900 . ?
C54 H54B 0.9900 . ?
C55 C60 1.378(10) . ?
C55 C56 1.398(10) . ?
C56 C57 1.388(12) . ?
C56 H56A 0.9500 . ?
C57 C58 1.374(12) . ?
C57 H57A 0.9500 . ?
C58 C59 1.378(12) . ?
C58 H58A 0.9500 . ?
C59 C60 1.394(11) . ?
C59 H59A 0.9500 . ?
C60 H60A 0.9500 . ?
C61 C66 1.451(9) . ?
C61 C62 1.455(9) . ?
C62 C63 1.350(9) . ?
C63 C64 1.376(10) . ?
C63 H63A 0.9500 . ?
C64 C65 1.386(10) . ?
C65 C66 1.395(9) . ?
C65 H65A 0.9500 . ?
C68 C73 1.450(9) . ?
C68 C69 1.452(8) . ?
C69 C70 1.380(9) . ?
C70 C71 1.384(9) . ?
C70 H70A 0.9500 . ?
C71 C72 1.389(8) . ?
C72 C73 1.376(9) . ?
C72 H72A 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ag1 N7 163.34(19) . . ?
N3 Ag1 O12 103.18(16) . . ?
N7 Ag1 O12 85.47(17) . . ?
N3 Ag1 Ag2 86.15(12) . . ?
N7 Ag1 Ag2 88.13(13) . . ?
O12 Ag1 Ag2 166.27(9) . . ?
N1 Ag2 N5 167.08(18) . . ?
N1 Ag2 O3 100.84(17) . . ?
N5 Ag2 O3 92.07(17) . . ?
N1 Ag2 O4 96.71(17) . . ?
N5 Ag2 O4 88.88(17) . . ?
O3 Ag2 O4 64.48(15) . . ?
N1 Ag2 Ag1 83.43(13) . . ?
N5 Ag2 Ag1 88.92(13) . . ?
O3 Ag2 Ag1 126.13(11) . . ?
O4 Ag2 Ag1 169.25(11) . . ?
C8 O1 C9 113.8(5) . . ?
C39 O2 C38 112.3(4) . . ?
C61 O3 Ag2 137.9(5) . . ?
N9 O4 Ag2 117.6(4) . . ?
C68 O12 Ag1 124.2(3) . . ?
C7 N1 C1 106.3(5) . . ?
C7 N1 Ag2 127.6(4) . . ?
C1 N1 Ag2 126.0(4) . . ?
C7 N2 C6 106.3(5) . . ?
C7 N2 C17 127.9(6) . . ?
C6 N2 C17 125.7(5) . . ?
C10 N3 C16 107.1(5) . . ?
C10 N3 Ag1 126.8(4) . . ?
C16 N3 Ag1 126.1(4) . . ?
C10 N4 C11 106.9(5) . . ?
C10 N4 C24 127.7(5) . . ?
C11 N4 C24 124.7(5) . . ?
C37 N5 C31 105.4(5) . . ?
C37 N5 Ag2 123.1(4) . . ?
C31 N5 Ag2 130.9(4) . . ?
C37 N6 C36 107.5(5) . . ?
C37 N6 C47 126.9(5) . . ?
C36 N6 C47 125.6(5) . . ?
C40 N7 C46 105.5(5) . . ?
C40 N7 Ag1 130.8(4) . . ?
C46 N7 Ag1 123.3(4) . . ?
C40 N8 C41 105.6(5) . . ?
C40 N8 C54 128.6(6) . . ?
C41 N8 C54 125.5(6) . . ?
O5 N9 O4 122.5(6) . . ?
O5 N9 C62 118.8(6) . . ?
O4 N9 C62 118.6(6) . . ?
O6 N10 O7 124.4(7) . . ?
O6 N10 C64 117.3(8) . . ?
O7 N10 C64 118.2(8) . . ?
O8 N11 O9 120.9(7) . . ?
O8 N11 C66 120.1(6) . . ?
O9 N11 C66 119.0(6) . . ?
O13 N12 O14 122.3(5) . . ?
O13 N12 C69 119.9(5) . . ?
O14 N12 C69 117.8(5) . . ?
O16 N13 O15 122.4(5) . . ?
O16 N13 C71 119.0(5) . . ?
O15 N13 C71 118.6(5) . . ?
O18 N14 O17 123.9(5) . . ?
O18 N14 C73 118.2(6) . . ?
O17 N14 C73 118.0(5) . . ?
C2 C1 N1 130.0(5) . . ?
C2 C1 C6 122.1(6) . . ?
N1 C1 C6 107.9(5) . . ?
C1 C2 C3 116.2(6) . . ?
C1 C2 H2A 121.9 . . ?
C3 C2 H2A 121.9 . . ?
C4 C3 C2 121.9(7) . . ?
C4 C3 H3A 119.1 . . ?
C2 C3 H3A 119.1 . . ?
C3 C4 C5 121.4(7) . . ?
C3 C4 H4A 119.3 . . ?
C5 C4 H4A 119.3 . . ?
C6 C5 C4 116.8(6) . . ?
C6 C5 H5A 121.6 . . ?
C4 C5 H5A 121.6 . . ?
C5 C6 N2 132.4(6) . . ?
C5 C6 C1 121.6(6) . . ?
N2 C6 C1 106.0(5) . . ?
N1 C7 N2 113.4(6) . . ?
N1 C7 C8 122.9(5) . . ?
N2 C7 C8 123.6(5) . . ?
O1 C8 C7 113.1(5) . . ?
O1 C8 H8A 109.0 . . ?
C7 C8 H8A 109.0 . . ?
O1 C8 H8B 109.0 . . ?
C7 C8 H8B 109.0 . . ?
H8A C8 H8B 107.8 . . ?
O1 C9 C10 111.9(5) . . ?
O1 C9 H9A 109.2 . . ?
C10 C9 H9A 109.2 . . ?
O1 C9 H9B 109.2 . . ?
C10 C9 H9B 109.2 . . ?
H9A C9 H9B 107.9 . . ?
N3 C10 N4 111.5(5) . . ?
N3 C10 C9 125.6(5) . . ?
N4 C10 C9 122.9(5) . . ?
N4 C11 C16 106.2(5) . . ?
N4 C11 C12 130.0(5) . . ?
C16 C11 C12 123.8(5) . . ?
C13 C12 C11 115.2(6) . . ?
C13 C12 H12A 122.4 . . ?
C11 C12 H12A 122.4 . . ?
C12 C13 C14 122.1(6) . . ?
C12 C13 H13A 119.0 . . ?
C14 C13 H13A 119.0 . . ?
C15 C14 C13 121.4(6) . . ?
C15 C14 H14A 119.3 . . ?
C13 C14 H14A 119.3 . . ?
C14 C15 C16 118.2(6) . . ?
C14 C15 H15A 120.9 . . ?
C16 C15 H15A 120.9 . . ?
N3 C16 C11 108.4(5) . . ?
N3 C16 C15 132.3(6) . . ?
C11 C16 C15 119.3(6) . . ?
N2 C17 C18 114.9(5) . . ?
N2 C17 H17A 108.5 . . ?
C18 C17 H17A 108.5 . . ?
N2 C17 H17B 108.5 . . ?
C18 C17 H17B 108.5 . . ?
H17A C17 H17B 107.5 . . ?
C23 C18 C19 119.0(6) . . ?
C23 C18 C17 119.5(6) . . ?
C19 C18 C17 121.5(6) . . ?
C20 C19 C18 119.9(7) . . ?
C20 C19 H19A 120.0 . . ?
C18 C19 H19A 120.0 . . ?
C19 C20 C21 121.2(7) . . ?
C19 C20 H20A 119.4 . . ?
C21 C20 H20A 119.4 . . ?
C20 C21 C22 119.0(6) . . ?
C20 C21 H21A 120.5 . . ?
C22 C21 H21A 120.5 . . ?
C21 C22 C23 119.8(7) . . ?
C21 C22 H22A 120.1 . . ?
C23 C22 H22A 120.1 . . ?
C18 C23 C22 121.0(7) . . ?
C18 C23 H23A 119.5 . . ?
C22 C23 H23A 119.5 . . ?
N4 C24 C25 112.4(4) . . ?
N4 C24 H24A 109.1 . . ?
C25 C24 H24A 109.1 . . ?
N4 C24 H24B 109.1 . . ?
C25 C24 H24B 109.1 . . ?
H24A C24 H24B 107.8 . . ?
C26 C25 C30 118.0(6) . . ?
C26 C25 C24 123.3(5) . . ?
C30 C25 C24 118.7(5) . . ?
C25 C26 C27 121.1(6) . . ?
C25 C26 H26A 119.4 . . ?
C27 C26 H26A 119.4 . . ?
C28 C27 C26 119.5(6) . . ?
C28 C27 H27A 120.2 . . ?
C26 C27 H27A 120.2 . . ?
C27 C28 C29 120.4(6) . . ?
C27 C28 H28A 119.8 . . ?
C29 C28 H28A 119.8 . . ?
C30 C29 C28 119.8(6) . . ?
C30 C29 H29A 120.1 . . ?
C28 C29 H29A 120.1 . . ?
C29 C30 C25 121.1(5) . . ?
C29 C30 H30A 119.5 . . ?
C25 C30 H30A 119.5 . . ?
N5 C31 C32 129.3(6) . . ?
N5 C31 C36 109.4(5) . . ?
C32 C31 C36 121.3(6) . . ?
C31 C32 C33 116.2(6) . . ?
C31 C32 H32A 121.9 . . ?
C33 C32 H32A 121.9 . . ?
C32 C33 C34 121.0(6) . . ?
C32 C33 H33A 119.5 . . ?
C34 C33 H33A 119.5 . . ?
C35 C34 C33 123.2(7) . . ?
C35 C34 H34A 118.4 . . ?
C33 C34 H34A 118.4 . . ?
C34 C35 C36 116.0(6) . . ?
C34 C35 H35A 122.0 . . ?
C36 C35 H35A 122.0 . . ?
N6 C36 C31 105.4(5) . . ?
N6 C36 C35 132.2(6) . . ?
C31 C36 C35 122.3(6) . . ?
N5 C37 N6 112.2(5) . . ?
N5 C37 C38 122.9(5) . . ?
N6 C37 C38 124.8(5) . . ?
O2 C38 C37 108.2(4) . . ?
O2 C38 H38A 110.1 . . ?
C37 C38 H38A 110.1 . . ?
O2 C38 H38B 110.1 . . ?
C37 C38 H38B 110.1 . . ?
H38A C38 H38B 108.4 . . ?
O2 C39 C40 109.0(5) . . ?
O2 C39 H39A 109.9 . . ?
C40 C39 H39A 109.9 . . ?
O2 C39 H39B 109.9 . . ?
C40 C39 H39B 109.9 . . ?
H39A C39 H39B 108.3 . . ?
N7 C40 N8 113.6(6) . . ?
N7 C40 C39 124.5(5) . . ?
N8 C40 C39 121.8(5) . . ?
C46 C41 C42 122.4(7) . . ?
C46 C41 N8 105.8(6) . . ?
C42 C41 N8 131.8(7) . . ?
C43 C42 C41 116.4(8) . . ?
C43 C42 H42A 121.8 . . ?
C41 C42 H42A 121.8 . . ?
C42 C43 C44 122.2(7) . . ?
C42 C43 H43A 118.9 . . ?
C44 C43 H43A 118.9 . . ?
C45 C44 C43 121.5(8) . . ?
C45 C44 H44A 119.2 . . ?
C43 C44 H44A 119.2 . . ?
C44 C45 C46 116.2(8) . . ?
C44 C45 H45A 121.9 . . ?
C46 C45 H45A 121.9 . . ?
C41 C46 N7 109.4(6) . . ?
C41 C46 C45 121.3(6) . . ?
N7 C46 C45 129.3(6) . . ?
N6 C47 C48 114.0(5) . . ?
N6 C47 H47A 108.7 . . ?
C48 C47 H47A 108.7 . . ?
N6 C47 H47B 108.7 . . ?
C48 C47 H47B 108.7 . . ?
H47A C47 H47B 107.6 . . ?
C49 C48 C53 119.1(6) . . ?
C49 C48 C47 119.5(6) . . ?
C53 C48 C47 121.2(6) . . ?
C48 C49 C50 121.2(7) . . ?
C48 C49 H49A 119.4 . . ?
C50 C49 H49A 119.4 . . ?
C51 C50 C49 119.3(7) . . ?
C51 C50 H50A 120.4 . . ?
C49 C50 H50A 120.4 . . ?
C50 C51 C52 119.5(7) . . ?
C50 C51 H51A 120.2 . . ?
C52 C51 H51A 120.2 . . ?
C53 C52 C51 120.9(7) . . ?
C53 C52 H52A 119.5 . . ?
C51 C52 H52A 119.5 . . ?
C52 C53 C48 119.9(7) . . ?
C52 C53 H53A 120.0 . . ?
C48 C53 H53A 120.0 . . ?
N8 C54 C55 113.8(5) . . ?
N8 C54 H54A 108.8 . . ?
C55 C54 H54A 108.8 . . ?
N8 C54 H54B 108.8 . . ?
C55 C54 H54B 108.8 . . ?
H54A C54 H54B 107.7 . . ?
C60 C55 C56 119.3(7) . . ?
C60 C55 C54 120.5(6) . . ?
C56 C55 C54 120.1(7) . . ?
C57 C56 C55 119.4(8) . . ?
C57 C56 H56A 120.3 . . ?
C55 C56 H56A 120.3 . . ?
C58 C57 C56 120.7(8) . . ?
C58 C57 H57A 119.6 . . ?
C56 C57 H57A 119.6 . . ?
C57 C58 C59 120.2(8) . . ?
C57 C58 H58A 119.9 . . ?
C59 C58 H58A 119.9 . . ?
C58 C59 C60 119.5(8) . . ?
C58 C59 H59A 120.2 . . ?
C60 C59 H59A 120.2 . . ?
C55 C60 C59 120.8(7) . . ?
C55 C60 H60A 119.6 . . ?
C59 C60 H60A 119.6 . . ?
O3 C61 C66 124.3(6) . . ?
O3 C61 C62 124.6(6) . . ?
C66 C61 C62 111.1(5) . . ?
C63 C62 N9 117.3(6) . . ?
C63 C62 C61 125.4(6) . . ?
N9 C62 C61 117.2(5) . . ?
C62 C63 C64 119.5(7) . . ?
C62 C63 H63A 120.3 . . ?
C64 C63 H63A 120.3 . . ?
C63 C64 C65 121.1(6) . . ?
C63 C64 N10 120.4(7) . . ?
C65 C64 N10 118.5(7) . . ?
C64 C65 C66 119.0(6) . . ?
C64 C65 H65A 120.5 . . ?
C66 C65 H65A 120.5 . . ?
C65 C66 N11 114.6(6) . . ?
C65 C66 C61 123.7(6) . . ?
N11 C66 C61 121.7(6) . . ?
O12 C68 C73 123.9(5) . . ?
O12 C68 C69 124.4(6) . . ?
C73 C68 C69 111.7(5) . . ?
C70 C69 N12 116.8(5) . . ?
C70 C69 C68 123.2(6) . . ?
N12 C69 C68 119.9(5) . . ?
C69 C70 C71 120.7(5) . . ?
C69 C70 H70A 119.6 . . ?
C71 C70 H70A 119.6 . . ?
C70 C71 C72 119.8(6) . . ?
C70 C71 N13 119.9(5) . . ?
C72 C71 N13 120.3(6) . . ?
C73 C72 C71 119.5(6) . . ?
C73 C72 H72A 120.3 . . ?
C71 C72 H72A 120.3 . . ?
C72 C73 C68 124.7(6) . . ?
C72 C73 N14 115.8(6) . . ?
C68 C73 N14 119.5(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Ag1 Ag2 N1 96.15(19) . . . . ?
N7 Ag1 Ag2 N1 -68.19(19) . . . . ?
O12 Ag1 Ag2 N1 -130.4(5) . . . . ?
N3 Ag1 Ag2 N5 -73.43(19) . . . . ?
N7 Ag1 Ag2 N5 122.23(19) . . . . ?
O12 Ag1 Ag2 N5 60.0(5) . . . . ?
N3 Ag1 Ag2 O3 -165.21(19) . . . . ?
N7 Ag1 Ag2 O3 30.45(19) . . . . ?
O12 Ag1 Ag2 O3 -31.8(5) . . . . ?
N3 Ag1 Ag2 O4 4.8(6) . . . . ?
N7 Ag1 Ag2 O4 -159.5(6) . . . . ?
O12 Ag1 Ag2 O4 138.2(7) . . . . ?
N1 Ag2 O3 C61 -95.0(6) . . . . ?
N5 Ag2 O3 C61 85.1(6) . . . . ?
O4 Ag2 O3 C61 -2.7(6) . . . . ?
Ag1 Ag2 O3 C61 175.3(6) . . . . ?
N1 Ag2 O4 N9 147.1(5) . . . . ?
N5 Ag2 O4 N9 -44.6(5) . . . . ?
O3 Ag2 O4 N9 48.2(5) . . . . ?
Ag1 Ag2 O4 N9 -122.8(6) . . . . ?
N3 Ag1 O12 C68 159.7(5) . . . . ?
N7 Ag1 O12 C68 -34.7(5) . . . . ?
Ag2 Ag1 O12 C68 27.8(8) . . . . ?
N5 Ag2 N1 C7 -29.1(11) . . . . ?
O3 Ag2 N1 C7 151.2(5) . . . . ?
O4 Ag2 N1 C7 86.0(5) . . . . ?
Ag1 Ag2 N1 C7 -83.2(5) . . . . ?
N5 Ag2 N1 C1 147.9(8) . . . . ?
O3 Ag2 N1 C1 -31.8(5) . . . . ?
O4 Ag2 N1 C1 -97.0(5) . . . . ?
Ag1 Ag2 N1 C1 93.8(4) . . . . ?
N7 Ag1 N3 C10 -15.9(9) . . . . ?
O12 Ag1 N3 C10 104.1(5) . . . . ?
Ag2 Ag1 N3 C10 -86.1(5) . . . . ?
N7 Ag1 N3 C16 165.8(6) . . . . ?
O12 Ag1 N3 C16 -74.2(5) . . . . ?
Ag2 Ag1 N3 C16 95.6(4) . . . . ?
N1 Ag2 N5 C37 -118.7(8) . . . . ?
O3 Ag2 N5 C37 61.0(4) . . . . ?
O4 Ag2 N5 C37 125.4(4) . . . . ?
Ag1 Ag2 N5 C37 -65.2(4) . . . . ?
N1 Ag2 N5 C31 51.3(11) . . . . ?
O3 Ag2 N5 C31 -129.1(5) . . . . ?
O4 Ag2 N5 C31 -64.6(5) . . . . ?
Ag1 Ag2 N5 C31 104.8(5) . . . . ?
N3 Ag1 N7 C40 -122.7(7) . . . . ?
O12 Ag1 N7 C40 115.1(5) . . . . ?
Ag2 Ag1 N7 C40 -52.8(5) . . . . ?
N3 Ag1 N7 C46 49.4(9) . . . . ?
O12 Ag1 N7 C46 -72.9(5) . . . . ?
Ag2 Ag1 N7 C46 119.3(5) . . . . ?
Ag2 O4 N9 O5 101.0(8) . . . . ?
Ag2 O4 N9 C62 -82.3(7) . . . . ?
C7 N1 C1 C2 -179.0(6) . . . . ?
Ag2 N1 C1 C2 3.4(9) . . . . ?
C7 N1 C1 C6 2.8(6) . . . . ?
Ag2 N1 C1 C6 -174.7(4) . . . . ?
N1 C1 C2 C3 -178.8(6) . . . . ?
C6 C1 C2 C3 -0.9(9) . . . . ?
C1 C2 C3 C4 0.5(9) . . . . ?
C2 C3 C4 C5 -0.4(10) . . . . ?
C3 C4 C5 C6 0.8(10) . . . . ?
C4 C5 C6 N2 -178.1(6) . . . . ?
C4 C5 C6 C1 -1.2(9) . . . . ?
C7 N2 C6 C5 178.8(7) . . . . ?
C17 N2 C6 C5 1.7(11) . . . . ?
C7 N2 C6 C1 1.6(6) . . . . ?
C17 N2 C6 C1 -175.6(5) . . . . ?
C2 C1 C6 C5 1.4(9) . . . . ?
N1 C1 C6 C5 179.7(6) . . . . ?
C2 C1 C6 N2 179.0(5) . . . . ?
N1 C1 C6 N2 -2.7(6) . . . . ?
C1 N1 C7 N2 -1.9(7) . . . . ?
Ag2 N1 C7 N2 175.6(4) . . . . ?
C1 N1 C7 C8 175.5(5) . . . . ?
Ag2 N1 C7 C8 -7.0(8) . . . . ?
C6 N2 C7 N1 0.2(7) . . . . ?
C17 N2 C7 N1 177.3(5) . . . . ?
C6 N2 C7 C8 -177.2(5) . . . . ?
C17 N2 C7 C8 -0.1(9) . . . . ?
C9 O1 C8 C7 -64.5(7) . . . . ?
N1 C7 C8 O1 129.9(6) . . . . ?
N2 C7 C8 O1 -52.9(8) . . . . ?
C8 O1 C9 C10 -72.3(6) . . . . ?
C16 N3 C10 N4 1.2(6) . . . . ?
Ag1 N3 C10 N4 -177.4(3) . . . . ?
C16 N3 C10 C9 179.5(5) . . . . ?
Ag1 N3 C10 C9 0.9(8) . . . . ?
C11 N4 C10 N3 -1.5(6) . . . . ?
C24 N4 C10 N3 -172.5(5) . . . . ?
C11 N4 C10 C9 -179.8(5) . . . . ?
C24 N4 C10 C9 9.2(9) . . . . ?
O1 C9 C10 N3 120.2(6) . . . . ?
O1 C9 C10 N4 -61.7(7) . . . . ?
C10 N4 C11 C16 1.2(6) . . . . ?
C24 N4 C11 C16 172.5(5) . . . . ?
C10 N4 C11 C12 -177.1(6) . . . . ?
C24 N4 C11 C12 -5.8(9) . . . . ?
N4 C11 C12 C13 179.1(6) . . . . ?
C16 C11 C12 C13 1.1(9) . . . . ?
C11 C12 C13 C14 -0.4(9) . . . . ?
C12 C13 C14 C15 0.1(10) . . . . ?
C13 C14 C15 C16 -0.4(9) . . . . ?
C10 N3 C16 C11 -0.4(6) . . . . ?
Ag1 N3 C16 C11 178.2(4) . . . . ?
C10 N3 C16 C15 178.9(6) . . . . ?
Ag1 N3 C16 C15 -2.5(9) . . . . ?
N4 C11 C16 N3 -0.5(6) . . . . ?
C12 C11 C16 N3 177.9(5) . . . . ?
N4 C11 C16 C15 -179.8(5) . . . . ?
C12 C11 C16 C15 -1.4(9) . . . . ?
C14 C15 C16 N3 -178.1(6) . . . . ?
C14 C15 C16 C11 1.1(8) . . . . ?
C7 N2 C17 C18 90.3(8) . . . . ?
C6 N2 C17 C18 -93.2(7) . . . . ?
N2 C17 C18 C23 -126.2(7) . . . . ?
N2 C17 C18 C19 56.8(8) . . . . ?
C23 C18 C19 C20 -1.1(10) . . . . ?
C17 C18 C19 C20 175.8(6) . . . . ?
C18 C19 C20 C21 0.7(11) . . . . ?
C19 C20 C21 C22 0.1(11) . . . . ?
C20 C21 C22 C23 -0.4(10) . . . . ?
C19 C18 C23 C22 0.8(10) . . . . ?
C17 C18 C23 C22 -176.2(6) . . . . ?
C21 C22 C23 C18 -0.1(10) . . . . ?
C10 N4 C24 C25 99.2(7) . . . . ?
C11 N4 C24 C25 -70.3(7) . . . . ?
N4 C24 C25 C26 -9.4(8) . . . . ?
N4 C24 C25 C30 170.1(5) . . . . ?
C30 C25 C26 C27 0.7(9) . . . . ?
C24 C25 C26 C27 -179.8(6) . . . . ?
C25 C26 C27 C28 0.1(10) . . . . ?
C26 C27 C28 C29 -1.0(11) . . . . ?
C27 C28 C29 C30 1.0(10) . . . . ?
C28 C29 C30 C25 -0.1(10) . . . . ?
C26 C25 C30 C29 -0.7(9) . . . . ?
C24 C25 C30 C29 179.7(6) . . . . ?
C37 N5 C31 C32 -179.6(6) . . . . ?
Ag2 N5 C31 C32 9.1(9) . . . . ?
C37 N5 C31 C36 -0.2(6) . . . . ?
Ag2 N5 C31 C36 -171.5(4) . . . . ?
N5 C31 C32 C33 179.9(6) . . . . ?
C36 C31 C32 C33 0.5(9) . . . . ?
C31 C32 C33 C34 -1.8(9) . . . . ?
C32 C33 C34 C35 1.8(11) . . . . ?
C33 C34 C35 C36 -0.4(10) . . . . ?
C37 N6 C36 C31 -0.6(6) . . . . ?
C47 N6 C36 C31 -179.8(5) . . . . ?
C37 N6 C36 C35 178.3(6) . . . . ?
C47 N6 C36 C35 -0.9(10) . . . . ?
N5 C31 C36 N6 0.5(6) . . . . ?
C32 C31 C36 N6 180.0(5) . . . . ?
N5 C31 C36 C35 -178.6(5) . . . . ?
C32 C31 C36 C35 0.9(9) . . . . ?
C34 C35 C36 N6 -179.7(6) . . . . ?
C34 C35 C36 C31 -1.0(9) . . . . ?
C31 N5 C37 N6 -0.2(6) . . . . ?
Ag2 N5 C37 N6 171.9(4) . . . . ?
C31 N5 C37 C38 176.5(5) . . . . ?
Ag2 N5 C37 C38 -11.3(7) . . . . ?
C36 N6 C37 N5 0.5(6) . . . . ?
C47 N6 C37 N5 179.7(5) . . . . ?
C36 N6 C37 C38 -176.1(5) . . . . ?
C47 N6 C37 C38 3.1(9) . . . . ?
C39 O2 C38 C37 -167.5(5) . . . . ?
N5 C37 C38 O2 43.9(7) . . . . ?
N6 C37 C38 O2 -139.8(5) . . . . ?
C38 O2 C39 C40 -177.2(5) . . . . ?
C46 N7 C40 N8 1.1(7) . . . . ?
Ag1 N7 C40 N8 174.2(4) . . . . ?
C46 N7 C40 C39 -177.0(6) . . . . ?
Ag1 N7 C40 C39 -3.9(9) . . . . ?
C41 N8 C40 N7 -1.6(7) . . . . ?
C54 N8 C40 N7 -175.9(6) . . . . ?
C41 N8 C40 C39 176.6(6) . . . . ?
C54 N8 C40 C39 2.4(9) . . . . ?
O2 C39 C40 N7 7.9(8) . . . . ?
O2 C39 C40 N8 -170.1(5) . . . . ?
C40 N8 C41 C46 1.4(6) . . . . ?
C54 N8 C41 C46 175.9(6) . . . . ?
C40 N8 C41 C42 -176.6(7) . . . . ?
C54 N8 C41 C42 -2.1(11) . . . . ?
C46 C41 C42 C43 0.2(10) . . . . ?
N8 C41 C42 C43 177.8(7) . . . . ?
C41 C42 C43 C44 2.0(11) . . . . ?
C42 C43 C44 C45 -3.0(12) . . . . ?
C43 C44 C45 C46 1.6(11) . . . . ?
C42 C41 C46 N7 177.4(6) . . . . ?
N8 C41 C46 N7 -0.8(7) . . . . ?
C42 C41 C46 C45 -1.5(10) . . . . ?
N8 C41 C46 C45 -179.7(6) . . . . ?
C40 N7 C46 C41 -0.1(7) . . . . ?
Ag1 N7 C46 C41 -173.9(4) . . . . ?
C40 N7 C46 C45 178.6(7) . . . . ?
Ag1 N7 C46 C45 4.8(9) . . . . ?
C44 C45 C46 C41 0.5(10) . . . . ?
C44 C45 C46 N7 -178.1(6) . . . . ?
C37 N6 C47 C48 -77.0(7) . . . . ?
C36 N6 C47 C48 102.1(7) . . . . ?
N6 C47 C48 C49 149.5(6) . . . . ?
N6 C47 C48 C53 -34.6(9) . . . . ?
C53 C48 C49 C50 2.3(10) . . . . ?
C47 C48 C49 C50 178.3(6) . . . . ?
C48 C49 C50 C51 -1.8(11) . . . . ?
C49 C50 C51 C52 0.9(12) . . . . ?
C50 C51 C52 C53 -0.6(12) . . . . ?
C51 C52 C53 C48 1.1(12) . . . . ?
C49 C48 C53 C52 -2.0(11) . . . . ?
C47 C48 C53 C52 -177.9(7) . . . . ?
C40 N8 C54 C55 -50.4(9) . . . . ?
C41 N8 C54 C55 136.4(6) . . . . ?
N8 C54 C55 C60 117.3(7) . . . . ?
N8 C54 C55 C56 -60.7(8) . . . . ?
C60 C55 C56 C57 1.2(11) . . . . ?
C54 C55 C56 C57 179.2(7) . . . . ?
C55 C56 C57 C58 -2.1(12) . . . . ?
C56 C57 C58 C59 2.8(12) . . . . ?
C57 C58 C59 C60 -2.6(11) . . . . ?
C56 C55 C60 C59 -1.0(10) . . . . ?
C54 C55 C60 C59 -179.0(6) . . . . ?
C58 C59 C60 C55 1.7(11) . . . . ?
Ag2 O3 C61 C66 163.9(4) . . . . ?
Ag2 O3 C61 C62 -18.8(10) . . . . ?
O5 N9 C62 C63 44.2(10) . . . . ?
O4 N9 C62 C63 -132.6(7) . . . . ?
O5 N9 C62 C61 -133.4(8) . . . . ?
O4 N9 C62 C61 49.8(9) . . . . ?
O3 C61 C62 C63 -172.2(6) . . . . ?
C66 C61 C62 C63 5.4(9) . . . . ?
O3 C61 C62 N9 5.2(9) . . . . ?
C66 C61 C62 N9 -177.3(5) . . . . ?
N9 C62 C63 C64 178.7(6) . . . . ?
C61 C62 C63 C64 -4.0(10) . . . . ?
C62 C63 C64 C65 0.6(11) . . . . ?
C62 C63 C64 N10 -178.7(7) . . . . ?
O6 N10 C64 C63 0.6(11) . . . . ?
O7 N10 C64 C63 178.3(7) . . . . ?
O6 N10 C64 C65 -178.7(8) . . . . ?
O7 N10 C64 C65 -1.0(11) . . . . ?
C63 C64 C65 C66 0.7(10) . . . . ?
N10 C64 C65 C66 180.0(6) . . . . ?
C64 C65 C66 N11 -179.0(6) . . . . ?
C64 C65 C66 C61 1.3(10) . . . . ?
O8 N11 C66 C65 -17.7(9) . . . . ?
O9 N11 C66 C65 161.7(6) . . . . ?
O8 N11 C66 C61 162.0(7) . . . . ?
O9 N11 C66 C61 -18.6(9) . . . . ?
O3 C61 C66 C65 173.6(6) . . . . ?
C62 C61 C66 C65 -3.9(9) . . . . ?
O3 C61 C66 N11 -6.0(10) . . . . ?
C62 C61 C66 N11 176.4(6) . . . . ?
Ag1 O12 C68 C73 135.0(5) . . . . ?
Ag1 O12 C68 C69 -45.9(8) . . . . ?
O13 N12 C69 C70 162.5(6) . . . . ?
O14 N12 C69 C70 -15.8(8) . . . . ?
O13 N12 C69 C68 -15.0(9) . . . . ?
O14 N12 C69 C68 166.7(6) . . . . ?
O12 C68 C69 C70 173.9(6) . . . . ?
C73 C68 C69 C70 -6.9(8) . . . . ?
O12 C68 C69 N12 -8.7(9) . . . . ?
C73 C68 C69 N12 170.4(5) . . . . ?
N12 C69 C70 C71 -171.3(6) . . . . ?
C68 C69 C70 C71 6.1(9) . . . . ?
C69 C70 C71 C72 -0.4(9) . . . . ?
C69 C70 C71 N13 177.6(6) . . . . ?
O16 N13 C71 C70 -166.9(6) . . . . ?
O15 N13 C71 C70 13.8(9) . . . . ?
O16 N13 C71 C72 11.0(9) . . . . ?
O15 N13 C71 C72 -168.3(6) . . . . ?
C70 C71 C72 C73 -3.7(9) . . . . ?
N13 C71 C72 C73 178.4(6) . . . . ?
C71 C72 C73 C68 2.3(10) . . . . ?
C71 C72 C73 N14 -178.5(6) . . . . ?
O12 C68 C73 C72 -178.1(6) . . . . ?
C69 C68 C73 C72 2.7(9) . . . . ?
O12 C68 C73 N14 2.7(9) . . . . ?
C69 C68 C73 N14 -176.4(5) . . . . ?
O18 N14 C73 C72 151.9(7) . . . . ?
O17 N14 C73 C72 -26.6(9) . . . . ?
O18 N14 C73 C68 -28.9(9) . . . . ?
O17 N14 C73 C68 152.6(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.983
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 0.983
_refine_diff_density_max         1.618
_refine_diff_density_min         -1.531
_refine_diff_density_rms         0.192
