# Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_as50m
_database_code_depnum_ccdc_archive 'CCDC 1019649'
_audit_update_record             
;
2014-08-18 deposited with the CCDC.
2015-12-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C35 H25 Cl F6 N2 O2 Pt S2'
_chemical_formula_sum            'C35 H25 Cl F6 N2 O2 Pt S2'
_chemical_formula_weight         914.23

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.4868(14)
_cell_length_b                   15.2064(16)
_cell_length_c                   17.7733(19)
_cell_angle_alpha                90.00
_cell_angle_beta                 107.750(2)
_cell_angle_gamma                90.00
_cell_volume                     3471.5(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    294(2)
_cell_measurement_reflns_used    7518
_cell_measurement_theta_min      2.41
_cell_measurement_theta_max      26.79

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.749
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1784
_exptl_absorpt_coefficient_mu    4.306
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.65
_exptl_absorpt_correction_T_max  0.89
_exptl_absorpt_process_details   'SABABS; Bruker,2001'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      294(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_device       'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_method       'ω scan'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            32599
_diffrn_reflns_av_R_equivalents  0.0397
_diffrn_reflns_av_sigmaI/netI    0.0304
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         1.67
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6105
_reflns_number_gt                5390
_reflns_threshold_expression     I>2σ(I)

_computing_data_collection       'SMART (Bruker, 2001)'
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_reduction        SAINT
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL/PC (Sheldrick, 1990)'
_computing_publication_material  SHELXL97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0410P)²+4.4470P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6105
_refine_ls_number_parameters     445
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0338
_refine_ls_R_factor_gt           0.0293
_refine_ls_wR_factor_ref         0.0774
_refine_ls_wR_factor_gt          0.0735
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_restrained_S_all      1.018
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3595(4) 0.1117(3) 0.4630(3) 0.0534(11) Uani 1 1 d . . .
C2 C 0.2807(4) 0.0751(4) 0.4007(3) 0.0814(18) Uani 1 1 d . . .
H2 H 0.2130 0.0728 0.4034 0.098 Uiso 1 1 calc R . .
C3 C 0.3026(6) 0.0423(5) 0.3352(4) 0.098(2) Uani 1 1 d . . .
H3 H 0.2492 0.0186 0.2939 0.118 Uiso 1 1 calc R . .
C4 C 0.4027(6) 0.0439(4) 0.3300(4) 0.0885(19) Uani 1 1 d . . .
H4 H 0.4158 0.0213 0.2854 0.106 Uiso 1 1 calc R . .
C5 C 0.4825(5) 0.0784(4) 0.3896(3) 0.0749(16) Uani 1 1 d . . .
H5 H 0.5501 0.0789 0.3865 0.090 Uiso 1 1 calc R . .
C6 C 0.4598(4) 0.1132(3) 0.4555(3) 0.0585(12) Uani 1 1 d . . .
C7 C 0.4536(3) 0.1777(3) 0.5812(3) 0.0523(11) Uani 1 1 d . . .
C8 C 0.3558(3) 0.1504(3) 0.5360(3) 0.0453(10) Uani 1 1 d . . .
C9 C 0.4700(3) 0.2076(3) 0.6606(3) 0.0520(10) Uani 1 1 d . . .
C10 C 0.3901(3) 0.2266(3) 0.7646(2) 0.0456(9) Uani 1 1 d . . .
C11 C 0.4276(4) 0.1628(3) 0.8214(3) 0.0579(12) Uani 1 1 d . . .
H11 H 0.4554 0.1110 0.8086 0.069 Uiso 1 1 calc R . .
C12 C 0.4238(4) 0.1761(3) 0.8976(3) 0.0576(12) Uani 1 1 d . . .
H12 H 0.4511 0.1340 0.9362 0.069 Uiso 1 1 calc R . .
C13 C 0.3798(3) 0.2514(3) 0.9163(3) 0.0529(11) Uani 1 1 d . . .
C14 C 0.3437(4) 0.3163(3) 0.8596(3) 0.0546(11) Uani 1 1 d . . .
H14 H 0.3168 0.3685 0.8726 0.065 Uiso 1 1 calc R . .
C15 C 0.3478(3) 0.3031(3) 0.7837(3) 0.0503(10) Uani 1 1 d . . .
H15 H 0.3221 0.3459 0.7454 0.060 Uiso 1 1 calc R . .
C16 C 0.2263(4) 0.3521(3) 0.5012(3) 0.0506(10) Uani 1 1 d . . .
C17 C 0.2788(4) 0.3396(3) 0.4448(3) 0.0589(12) Uani 1 1 d . . .
H17 H 0.3074 0.2850 0.4399 0.071 Uiso 1 1 calc R . .
C18 C 0.2880(5) 0.4082(4) 0.3971(3) 0.0732(15) Uani 1 1 d . . .
H18 H 0.3229 0.3996 0.3599 0.088 Uiso 1 1 calc R . .
C19 C 0.2457(5) 0.4908(4) 0.4037(3) 0.0806(18) Uani 1 1 d . . .
H19 H 0.2533 0.5364 0.3710 0.097 Uiso 1 1 calc R . .
C20 C 0.1928(5) 0.5058(4) 0.4577(3) 0.0729(15) Uani 1 1 d . . .
H20 H 0.1650 0.5608 0.4621 0.087 Uiso 1 1 calc R . .
C21 C 0.1822(4) 0.4357(3) 0.5058(3) 0.0572(12) Uani 1 1 d . . .
C22 C 0.1457(3) 0.3298(3) 0.5986(3) 0.0473(10) Uani 1 1 d . . .
C23 C 0.1104(3) 0.2762(3) 0.6511(2) 0.0471(10) Uani 1 1 d . . .
C24 C 0.2064(3) 0.2917(3) 0.5571(2) 0.0436(9) Uani 1 1 d . . .
C25 C 0.1080(3) 0.1307(3) 0.7052(2) 0.0446(9) Uani 1 1 d . . .
C26 C 0.0394(6) 0.0665(6) 0.6687(3) 0.112(3) Uani 1 1 d . . .
H26 H 0.0168 0.0633 0.6138 0.135 Uiso 1 1 calc R . .
C27 C 0.0032(7) 0.0066(6) 0.7120(4) 0.127(3) Uani 1 1 d . . .
H27 H -0.0437 -0.0366 0.6863 0.153 Uiso 1 1 calc R . .
C28 C 0.0353(5) 0.0101(4) 0.7917(3) 0.0735(15) Uani 1 1 d . . .
C29 C 0.1128(4) 0.0652(4) 0.8279(3) 0.0755(16) Uani 1 1 d . . .
H29 H 0.1427 0.0624 0.8824 0.091 Uiso 1 1 calc R . .
C30 C 0.1483(4) 0.1265(4) 0.7842(3) 0.0770(16) Uani 1 1 d . . .
H30 H 0.2009 0.1653 0.8100 0.092 Uiso 1 1 calc R . .
C31 C 0.0200(5) -0.0524(4) 0.9102(3) 0.0831(17) Uani 1 1 d . . .
H31A H 0.0927 -0.0665 0.9306 0.125 Uiso 1 1 calc R . .
H31B H -0.0200 -0.0963 0.9269 0.125 Uiso 1 1 calc R . .
H31C H 0.0076 0.0040 0.9298 0.125 Uiso 1 1 calc R . .
C32 C 0.3082(7) 0.3215(6) 1.0073(4) 0.120(3) Uani 1 1 d . . .
H32A H 0.3357 0.3792 1.0046 0.180 Uiso 1 1 calc R . .
H32B H 0.3012 0.3123 1.0589 0.180 Uiso 1 1 calc R . .
H32C H 0.2413 0.3161 0.9682 0.180 Uiso 1 1 calc R . .
C33 C 0.5796(4) 0.2302(4) 0.7133(3) 0.0714(14) Uani 1 1 d . . .
C34 C 0.0380(4) 0.3125(4) 0.6959(3) 0.0635(13) Uani 1 1 d . . .
C35 C 0.1179(3) 0.1272(3) 0.4999(3) 0.0535(11) Uani 1 1 d . . .
H35A H 0.0555 0.1426 0.5121 0.080 Uiso 1 1 calc R . .
H35B H 0.1204 0.0646 0.4936 0.080 Uiso 1 1 calc R . .
H35C H 0.1182 0.1557 0.4518 0.080 Uiso 1 1 calc R . .
N1 N 0.3879(3) 0.2108(2) 0.6843(2) 0.0459(8) Uani 1 1 d . . .
N2 N 0.1426(3) 0.1949(2) 0.6590(2) 0.0439(8) Uani 1 1 d . . .
O1 O 0.3769(3) 0.2577(3) 0.99290(19) 0.0686(9) Uani 1 1 d . . .
O2 O -0.0090(5) -0.0502(4) 0.8296(2) 0.120(2) Uani 1 1 d . . .
F1 F -0.0447(3) 0.2649(4) 0.6870(3) 0.147(2) Uani 1 1 d . . .
F2 F 0.0014(5) 0.3880(4) 0.6710(4) 0.188(3) Uani 1 1 d . . .
F3 F 0.0814(3) 0.3177(3) 0.7694(2) 0.1247(17) Uani 1 1 d . . .
F4 F 0.5828(3) 0.2830(3) 0.7727(2) 0.0910(10) Uani 1 1 d . . .
F5 F 0.6339(3) 0.2701(3) 0.6718(2) 0.1099(14) Uani 1 1 d . . .
F6 F 0.6291(3) 0.1578(3) 0.7422(3) 0.1237(17) Uani 1 1 d . . .
S1 S 0.55072(11) 0.16057(10) 0.53615(9) 0.0736(4) Uani 1 1 d . . .
S2 S 0.11575(10) 0.44065(8) 0.57482(8) 0.0610(3) Uani 1 1 d . . .
Cl1 Cl 0.28661(10) 0.02232(7) 0.64302(8) 0.0618(3) Uani 1 1 d . . .
Pt1 Pt 0.247601(11) 0.167756(10) 0.591810(9) 0.03965(7) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.395(7) . ?
C1 C6 1.400(6) . ?
C1 C8 1.438(6) . ?
C2 C3 1.379(7) . ?
C2 H2 0.9300 . ?
C3 C4 1.381(9) . ?
C3 H3 0.9300 . ?
C4 C5 1.364(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.401(7) . ?
C5 H5 0.9300 . ?
C6 S1 1.734(5) . ?
C7 C8 1.382(7) . ?
C7 C9 1.434(7) . ?
C7 S1 1.751(5) . ?
C8 Pt1 2.017(4) . ?
C9 N1 1.300(6) . ?
C9 C33 1.529(7) . ?
C10 C11 1.380(6) . ?
C10 C15 1.383(6) . ?
C10 N1 1.438(5) . ?
C11 C12 1.385(7) . ?
C11 H11 0.9300 . ?
C12 C13 1.375(7) . ?
C12 H12 0.9300 . ?
C13 O1 1.378(5) . ?
C13 C14 1.389(7) . ?
C14 C15 1.381(7) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C16 C17 1.405(7) . ?
C16 C21 1.416(6) . ?
C16 C24 1.437(6) . ?
C17 C18 1.374(7) . ?
C17 H17 0.9300 . ?
C18 C19 1.399(9) . ?
C18 H18 0.9300 . ?
C19 C20 1.378(8) . ?
C19 H19 0.9300 . ?
C20 C21 1.401(7) . ?
C20 H20 0.9300 . ?
C21 S2 1.727(5) . ?
C22 C24 1.386(6) . ?
C22 C23 1.425(6) . ?
C22 S2 1.755(4) . ?
C23 N2 1.303(5) . ?
C23 C34 1.539(6) . ?
C24 Pt1 2.008(4) . ?
C25 C30 1.343(6) . ?
C25 C26 1.366(8) . ?
C25 N2 1.441(6) . ?
C26 C27 1.374(9) . ?
C26 H26 0.9300 . ?
C27 C28 1.350(8) . ?
C27 H27 0.9300 . ?
C28 C29 1.341(7) . ?
C28 O2 1.377(6) . ?
C29 C30 1.389(7) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 O2 1.366(7) . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
C32 O1 1.418(7) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 F6 1.309(6) . ?
C33 F4 1.317(6) . ?
C33 F5 1.332(7) . ?
C34 F3 1.260(6) . ?
C34 F2 1.274(6) . ?
C34 F1 1.298(7) . ?
C35 Pt1 2.090(4) . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
N1 Pt1 2.194(3) . ?
N2 Pt1 2.152(3) . ?
Cl1 Pt1 2.3884(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 117.1(4) . . ?
C2 C1 C8 130.6(4) . . ?
C6 C1 C8 112.3(4) . . ?
C3 C2 C1 120.5(5) . . ?
C3 C2 H2 119.8 . . ?
C1 C2 H2 119.8 . . ?
C2 C3 C4 121.0(6) . . ?
C2 C3 H3 119.5 . . ?
C4 C3 H3 119.5 . . ?
C5 C4 C3 120.8(5) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
C4 C5 C6 118.2(5) . . ?
C4 C5 H5 120.9 . . ?
C6 C5 H5 120.9 . . ?
C1 C6 C5 122.5(5) . . ?
C1 C6 S1 112.8(3) . . ?
C5 C6 S1 124.7(4) . . ?
C8 C7 C9 120.1(4) . . ?
C8 C7 S1 113.8(4) . . ?
C9 C7 S1 125.8(4) . . ?
C7 C8 C1 111.0(4) . . ?
C7 C8 Pt1 112.3(3) . . ?
C1 C8 Pt1 136.6(3) . . ?
N1 C9 C7 116.1(4) . . ?
N1 C9 C33 123.6(4) . . ?
C7 C9 C33 120.3(4) . . ?
C11 C10 C15 119.8(4) . . ?
C11 C10 N1 120.1(4) . . ?
C15 C10 N1 119.9(4) . . ?
C10 C11 C12 119.8(4) . . ?
C10 C11 H11 120.1 . . ?
C12 C11 H11 120.1 . . ?
C13 C12 C11 120.4(4) . . ?
C13 C12 H12 119.8 . . ?
C11 C12 H12 119.8 . . ?
C12 C13 O1 116.2(4) . . ?
C12 C13 C14 119.9(4) . . ?
O1 C13 C14 124.0(4) . . ?
C15 C14 C13 119.7(4) . . ?
C15 C14 H14 120.2 . . ?
C13 C14 H14 120.2 . . ?
C14 C15 C10 120.3(4) . . ?
C14 C15 H15 119.8 . . ?
C10 C15 H15 119.8 . . ?
C17 C16 C21 118.4(4) . . ?
C17 C16 C24 130.3(4) . . ?
C21 C16 C24 111.3(4) . . ?
C18 C17 C16 119.8(5) . . ?
C18 C17 H17 120.1 . . ?
C16 C17 H17 120.1 . . ?
C17 C18 C19 121.0(6) . . ?
C17 C18 H18 119.5 . . ?
C19 C18 H18 119.5 . . ?
C20 C19 C18 121.1(5) . . ?
C20 C19 H19 119.4 . . ?
C18 C19 H19 119.4 . . ?
C19 C20 C21 118.0(5) . . ?
C19 C20 H20 121.0 . . ?
C21 C20 H20 121.0 . . ?
C20 C21 C16 121.7(5) . . ?
C20 C21 S2 124.9(4) . . ?
C16 C21 S2 113.5(3) . . ?
C24 C22 C23 118.6(4) . . ?
C24 C22 S2 113.8(3) . . ?
C23 C22 S2 127.6(3) . . ?
N2 C23 C22 116.5(4) . . ?
N2 C23 C34 121.9(4) . . ?
C22 C23 C34 121.6(4) . . ?
C22 C24 C16 111.5(4) . . ?
C22 C24 Pt1 112.5(3) . . ?
C16 C24 Pt1 136.0(3) . . ?
C30 C25 C26 117.5(5) . . ?
C30 C25 N2 122.0(4) . . ?
C26 C25 N2 120.2(4) . . ?
C25 C26 C27 120.8(5) . . ?
C25 C26 H26 119.6 . . ?
C27 C26 H26 119.6 . . ?
C28 C27 C26 120.5(6) . . ?
C28 C27 H27 119.8 . . ?
C26 C27 H27 119.8 . . ?
C29 C28 C27 118.8(5) . . ?
C29 C28 O2 124.9(5) . . ?
C27 C28 O2 116.0(5) . . ?
C28 C29 C30 120.1(5) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C25 C30 C29 121.3(5) . . ?
C25 C30 H30 119.4 . . ?
C29 C30 H30 119.4 . . ?
O2 C31 H31A 109.5 . . ?
O2 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
O2 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
O1 C32 H32A 109.5 . . ?
O1 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
O1 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
F6 C33 F4 108.0(5) . . ?
F6 C33 F5 107.5(5) . . ?
F4 C33 F5 106.1(5) . . ?
F6 C33 C9 109.5(5) . . ?
F4 C33 C9 114.7(5) . . ?
F5 C33 C9 110.8(4) . . ?
F3 C34 F2 108.2(6) . . ?
F3 C34 F1 105.8(6) . . ?
F2 C34 F1 103.5(6) . . ?
F3 C34 C23 113.0(4) . . ?
F2 C34 C23 112.5(5) . . ?
F1 C34 C23 113.1(5) . . ?
Pt1 C35 H35A 109.5 . . ?
Pt1 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
Pt1 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C9 N1 C10 124.5(4) . . ?
C9 N1 Pt1 111.8(3) . . ?
C10 N1 Pt1 123.0(3) . . ?
C23 N2 C25 123.2(4) . . ?
C23 N2 Pt1 112.1(3) . . ?
C25 N2 Pt1 124.6(3) . . ?
C13 O1 C32 116.3(4) . . ?
C31 O2 C28 120.1(5) . . ?
C6 S1 C7 90.0(2) . . ?
C21 S2 C22 89.9(2) . . ?
C24 Pt1 C8 98.39(17) . . ?
C24 Pt1 C35 87.09(18) . . ?
C8 Pt1 C35 97.78(18) . . ?
C24 Pt1 N2 79.82(15) . . ?
C8 Pt1 N2 174.46(15) . . ?
C35 Pt1 N2 87.39(15) . . ?
C24 Pt1 N1 92.59(14) . . ?
C8 Pt1 N1 79.63(16) . . ?
C35 Pt1 N1 177.32(15) . . ?
N2 Pt1 N1 95.18(13) . . ?
C24 Pt1 Cl1 173.90(12) . . ?
C8 Pt1 Cl1 87.58(12) . . ?
C35 Pt1 Cl1 93.39(14) . . ?
N2 Pt1 Cl1 94.12(10) . . ?
N1 Pt1 Cl1 87.21(10) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -0.1(9) . . . . ?
C8 C1 C2 C3 179.3(6) . . . . ?
C1 C2 C3 C4 0.7(11) . . . . ?
C2 C3 C4 C5 -0.2(12) . . . . ?
C3 C4 C5 C6 -0.9(10) . . . . ?
C2 C1 C6 C5 -1.1(8) . . . . ?
C8 C1 C6 C5 179.4(5) . . . . ?
C2 C1 C6 S1 179.7(4) . . . . ?
C8 C1 C6 S1 0.3(5) . . . . ?
C4 C5 C6 C1 1.6(8) . . . . ?
C4 C5 C6 S1 -179.4(5) . . . . ?
C9 C7 C8 C1 -171.9(4) . . . . ?
S1 C7 C8 C1 1.7(5) . . . . ?
C9 C7 C8 Pt1 4.5(5) . . . . ?
S1 C7 C8 Pt1 178.1(2) . . . . ?
C2 C1 C8 C7 179.4(6) . . . . ?
C6 C1 C8 C7 -1.3(6) . . . . ?
C2 C1 C8 Pt1 4.2(9) . . . . ?
C6 C1 C8 Pt1 -176.4(4) . . . . ?
C8 C7 C9 N1 -3.1(7) . . . . ?
S1 C7 C9 N1 -175.9(3) . . . . ?
C8 C7 C9 C33 174.6(4) . . . . ?
S1 C7 C9 C33 1.9(7) . . . . ?
C15 C10 C11 C12 -0.6(7) . . . . ?
N1 C10 C11 C12 -176.1(4) . . . . ?
C10 C11 C12 C13 2.0(8) . . . . ?
C11 C12 C13 O1 178.2(5) . . . . ?
C11 C12 C13 C14 -3.2(7) . . . . ?
C12 C13 C14 C15 2.9(7) . . . . ?
O1 C13 C14 C15 -178.6(4) . . . . ?
C13 C14 C15 C10 -1.6(7) . . . . ?
C11 C10 C15 C14 0.4(7) . . . . ?
N1 C10 C15 C14 175.9(4) . . . . ?
C21 C16 C17 C18 1.2(7) . . . . ?
C24 C16 C17 C18 179.9(5) . . . . ?
C16 C17 C18 C19 0.0(8) . . . . ?
C17 C18 C19 C20 -0.5(8) . . . . ?
C18 C19 C20 C21 -0.3(8) . . . . ?
C19 C20 C21 C16 1.6(8) . . . . ?
C19 C20 C21 S2 -178.1(4) . . . . ?
C17 C16 C21 C20 -2.0(7) . . . . ?
C24 C16 C21 C20 179.1(4) . . . . ?
C17 C16 C21 S2 177.7(4) . . . . ?
C24 C16 C21 S2 -1.2(5) . . . . ?
C24 C22 C23 N2 3.2(6) . . . . ?
S2 C22 C23 N2 179.4(3) . . . . ?
C24 C22 C23 C34 -176.7(4) . . . . ?
S2 C22 C23 C34 -0.5(6) . . . . ?
C23 C22 C24 C16 174.1(4) . . . . ?
S2 C22 C24 C16 -2.7(5) . . . . ?
C23 C22 C24 Pt1 -7.5(5) . . . . ?
S2 C22 C24 Pt1 175.7(2) . . . . ?
C17 C16 C24 C22 -176.3(5) . . . . ?
C21 C16 C24 C22 2.5(5) . . . . ?
C17 C16 C24 Pt1 5.8(8) . . . . ?
C21 C16 C24 Pt1 -175.4(3) . . . . ?
C30 C25 C26 C27 8.0(12) . . . . ?
N2 C25 C26 C27 -177.9(7) . . . . ?
C25 C26 C27 C28 -0.2(15) . . . . ?
C26 C27 C28 C29 -8.6(14) . . . . ?
C26 C27 C28 O2 177.2(9) . . . . ?
C27 C28 C29 C30 9.4(11) . . . . ?
O2 C28 C29 C30 -176.9(7) . . . . ?
C26 C25 C30 C29 -7.2(10) . . . . ?
N2 C25 C30 C29 178.9(5) . . . . ?
C28 C29 C30 C25 -1.5(10) . . . . ?
N1 C9 C33 F6 97.5(6) . . . . ?
C7 C9 C33 F6 -80.1(6) . . . . ?
N1 C9 C33 F4 -24.1(8) . . . . ?
C7 C9 C33 F4 158.4(5) . . . . ?
N1 C9 C33 F5 -144.1(5) . . . . ?
C7 C9 C33 F5 38.3(7) . . . . ?
N2 C23 C34 F3 68.0(7) . . . . ?
C22 C23 C34 F3 -112.1(6) . . . . ?
N2 C23 C34 F2 -169.0(6) . . . . ?
C22 C23 C34 F2 10.9(8) . . . . ?
N2 C23 C34 F1 -52.2(7) . . . . ?
C22 C23 C34 F1 127.7(5) . . . . ?
C7 C9 N1 C10 170.6(4) . . . . ?
C33 C9 N1 C10 -7.1(7) . . . . ?
C7 C9 N1 Pt1 0.1(5) . . . . ?
C33 C9 N1 Pt1 -177.5(4) . . . . ?
C11 C10 N1 C9 -71.1(6) . . . . ?
C15 C10 N1 C9 113.5(5) . . . . ?
C11 C10 N1 Pt1 98.4(4) . . . . ?
C15 C10 N1 Pt1 -77.1(5) . . . . ?
C22 C23 N2 C25 -175.4(4) . . . . ?
C34 C23 N2 C25 4.5(6) . . . . ?
C22 C23 N2 Pt1 2.5(5) . . . . ?
C34 C23 N2 Pt1 -177.6(3) . . . . ?
C30 C25 N2 C23 -80.5(6) . . . . ?
C26 C25 N2 C23 105.7(6) . . . . ?
C30 C25 N2 Pt1 101.9(5) . . . . ?
C26 C25 N2 Pt1 -71.9(6) . . . . ?
C12 C13 O1 C32 -163.4(6) . . . . ?
C14 C13 O1 C32 18.0(8) . . . . ?
C29 C28 O2 C31 5.2(11) . . . . ?
C27 C28 O2 C31 179.0(8) . . . . ?
C1 C6 S1 C7 0.6(4) . . . . ?
C5 C6 S1 C7 -178.5(5) . . . . ?
C8 C7 S1 C6 -1.4(4) . . . . ?
C9 C7 S1 C6 171.8(4) . . . . ?
C20 C21 S2 C22 179.5(4) . . . . ?
C16 C21 S2 C22 -0.2(4) . . . . ?
C24 C22 S2 C21 1.7(4) . . . . ?
C23 C22 S2 C21 -174.7(4) . . . . ?
C22 C24 Pt1 C8 -168.2(3) . . . . ?
C16 C24 Pt1 C8 9.7(5) . . . . ?
C22 C24 Pt1 C35 94.3(3) . . . . ?
C16 C24 Pt1 C35 -87.8(4) . . . . ?
C22 C24 Pt1 N2 6.5(3) . . . . ?
C16 C24 Pt1 N2 -175.7(4) . . . . ?
C22 C24 Pt1 N1 -88.3(3) . . . . ?
C16 C24 Pt1 N1 89.5(4) . . . . ?
C7 C8 Pt1 C24 87.9(3) . . . . ?
C1 C8 Pt1 C24 -97.0(5) . . . . ?
C7 C8 Pt1 C35 176.1(3) . . . . ?
C1 C8 Pt1 C35 -8.8(5) . . . . ?
C7 C8 Pt1 N1 -3.2(3) . . . . ?
C1 C8 Pt1 N1 171.9(5) . . . . ?
C7 C8 Pt1 Cl1 -90.8(3) . . . . ?
C1 C8 Pt1 Cl1 84.3(5) . . . . ?
C23 N2 Pt1 C24 -5.0(3) . . . . ?
C25 N2 Pt1 C24 172.8(3) . . . . ?
C23 N2 Pt1 C35 -92.6(3) . . . . ?
C25 N2 Pt1 C35 85.3(3) . . . . ?
C23 N2 Pt1 N1 86.7(3) . . . . ?
C25 N2 Pt1 N1 -95.5(3) . . . . ?
C23 N2 Pt1 Cl1 174.2(3) . . . . ?
C25 N2 Pt1 Cl1 -7.9(3) . . . . ?
C9 N1 Pt1 C24 -96.3(3) . . . . ?
C10 N1 Pt1 C24 93.0(3) . . . . ?
C9 N1 Pt1 C8 1.7(3) . . . . ?
C10 N1 Pt1 C8 -168.9(3) . . . . ?
C9 N1 Pt1 N2 -176.3(3) . . . . ?
C10 N1 Pt1 N2 13.0(3) . . . . ?
C9 N1 Pt1 Cl1 89.8(3) . . . . ?
C10 N1 Pt1 Cl1 -80.9(3) . . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         0.857
_refine_diff_density_min         -1.185
_refine_diff_density_rms         0.084
