# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 971294'
_audit_update_record             
;
2015-05-15 deposited with the CCDC.
2015-05-19 downloaded from the CCDC.
;

# start Validation Reply Form

_vrf_PLAT342_shelx               
;
PROBLEM: Low Bond Precision on C-C Bonds .........0.0232 Ang
RESPONSE: The quality of this crystal was poor.
;

# end Validation Reply Form

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C40 H30 Ag6 N14 O41 Si W12'
_chemical_formula_weight         4244.29

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.376(3)
_cell_length_b                   15.058(3)
_cell_length_c                   18.787(4)
_cell_angle_alpha                86.58(3)
_cell_angle_beta                 85.60(3)
_cell_angle_gamma                87.20(3)
_cell_volume                     3481.1(13)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    15269
_cell_measurement_theta_min      3.1140
_cell_measurement_theta_max      28.6260

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    4.049
_exptl_crystal_F_000             3760
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.070
_exptl_absorpt_coefficient_mu    21.496
_shelx_estimated_absorpt_T_min   0.121
_shelx_estimated_absorpt_T_max   0.315
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.108
_exptl_absorpt_correction_T_max  0.324
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   
;
The Rint value before the absorption correction is 0.031, and the Rint value after 
the absorption correction is 0.029.
;
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean 15.9737
_diffrn_reflns_number            30842
_diffrn_reflns_av_unetI/netI     0.0473
_diffrn_reflns_av_R_equivalents  0.0295
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.980
_diffrn_reflns_theta_max         29.139
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.850
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.850
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.850
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             15928
_reflns_number_gt                13913
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  'Diamond 3.1'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+210.1236P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef       0.000143(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         15928
_refine_ls_number_parameters     1067
_refine_ls_number_restraints     936
_refine_ls_R_factor_all          0.0662
_refine_ls_R_factor_gt           0.0569
_refine_ls_wR_factor_ref         0.1135
_refine_ls_wR_factor_gt          0.1091
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_restrained_S_all      1.067
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.27198(5) -0.51164(5) 1.92878(4) 0.03539(17) Uani 1 1 d . . . . .
W2 W 0.09833(5) -0.32800(4) 1.87942(4) 0.02859(15) Uani 1 1 d . . . . .
W3 W 0.21157(5) -0.45323(5) 2.10684(3) 0.02855(15) Uani 1 1 d . . . . .
W4 W -0.17943(5) -0.32596(4) 1.94026(3) 0.02778(15) Uani 1 1 d . . . . .
W5 W -0.05936(5) -0.45931(5) 2.18205(3) 0.02899(15) Uani 1 1 d . . . . .
W6 W 0.01911(5) -0.28244(4) 2.05824(3) 0.02286(13) Uani 1 1 d . . . . .
W7 W 0.45845(5) -1.22035(4) 1.56882(5) 0.03496(18) Uani 1 1 d . . . . .
W8 W 0.53634(5) -1.05928(5) 1.68170(4) 0.02964(15) Uani 1 1 d . . . . .
W9 W 0.67711(6) -1.17674(4) 1.44136(4) 0.02924(15) Uani 1 1 d . . . . .
W10 W 0.59324(5) -0.84352(4) 1.61022(3) 0.02267(13) Uani 1 1 d . . . . .
W11 W 0.76561(5) -1.02686(4) 1.55945(3) 0.02358(13) Uani 1 1 d . . . . .
W12 W 0.72660(6) -0.95459(5) 1.37969(4) 0.03724(19) Uani 1 1 d . . . . .
Si1 Si 0.0000 -0.5000 2.0000 0.0181(11) Uani 1 2 d S . P . .
Si2 Si 0.5000 -1.0000 1.5000 0.0157(10) Uani 1 2 d S . P . .
O1 O -0.0804(19) -0.5230(16) 2.0723(13) 0.036(4) Uani 0.5 1 d . U P . .
O2 O 0.0107(16) -0.6043(14) 2.0204(12) 0.028(4) Uani 0.5 1 d . U P . .
O3 O 0.126(2) -0.5256(16) 2.0191(14) 0.039(4) Uani 0.5 1 d . U P . .
O4 O 0.0289(19) -0.4434(17) 2.0652(14) 0.041(3) Uani 0.5 1 d . U P . .
O5 O -0.2640(14) -0.3795(10) 2.0202(8) 0.064(3) Uani 1 1 d . U . . .
O6 O 0.2259(13) -0.3941(10) 1.8981(9) 0.064(3) Uani 1 1 d . U . . .
O7 O 0.2012(13) -0.5514(9) 1.8535(9) 0.062(3) Uani 1 1 d . U . . .
O8 O -0.0696(12) -0.5813(10) 2.1866(9) 0.061(3) Uani 1 1 d . U . . .
O9 O 0.2828(13) -0.4595(10) 2.0186(8) 0.061(3) Uani 1 1 d . U . . .
O10 O -0.2185(15) -0.4190(11) 1.8870(8) 0.069(4) Uani 1 1 d . U . . .
O11 O -0.0478(11) -0.3384(10) 2.1389(8) 0.056(3) Uani 1 1 d . U . . .
O12 O 0.3094(11) -0.4300(8) 2.1602(8) 0.046(3) Uani 1 1 d . U . . .
O13 O 0.0971(12) -0.2727(11) 1.9658(8) 0.060(3) Uani 1 1 d . U . . .
O14 O 0.0301(11) -0.1801(9) 2.0851(9) 0.057(4) Uani 1 1 d . U . . .
O15 O 0.1547(11) -0.3399(11) 2.0845(8) 0.061(3) Uani 1 1 d . U . . .
O16 O 0.0922(11) -0.4673(10) 2.1802(8) 0.057(3) Uani 1 1 d . U . . .
O17 O -0.1093(11) -0.2696(11) 2.0135(7) 0.058(3) Uani 1 1 d . U . . .
O18 O 0.1401(12) -0.2485(10) 1.8209(6) 0.052(3) Uani 1 1 d . U . . .
O19 O -0.0566(11) -0.3060(11) 1.8793(7) 0.054(3) Uani 1 1 d . U . . .
O20 O -0.0881(12) -0.4373(9) 2.2679(7) 0.049(3) Uani 1 1 d . U . . .
O21 O -0.2623(11) -0.2410(8) 1.9135(7) 0.041(3) Uani 1 1 d . U . . .
O22 O 0.4015(10) -0.5155(8) 1.8943(7) 0.041(3) Uani 1 1 d . U . . .
O23 O 0.4578(19) -1.0623(15) 1.5740(13) 0.037(3) Uani 0.5 1 d . U P . .
O24 O 0.571(2) -0.9841(15) 1.5611(13) 0.036(3) Uani 0.5 1 d . U P . .
O25 O 0.628(2) -1.0329(16) 1.4816(14) 0.043(3) Uani 0.5 1 d . U P . .
O26 O 0.5049(19) -1.1010(15) 1.4759(13) 0.036(3) Uani 0.5 1 d . U P . .
O27 O 0.8906(11) -1.0389(9) 1.5855(9) 0.056(4) Uani 1 1 d . U . . .
O28 O 0.8319(9) -0.9351(7) 1.3212(6) 0.034(3) Uani 1 1 d . U . . .
O29 O 0.7641(10) -1.2604(8) 1.4145(7) 0.041(3) Uani 1 1 d . U . . .
O30 O 0.3922(12) -1.2194(11) 1.4790(8) 0.063(3) Uani 1 1 d . U . . .
O31 O 0.7925(14) -0.9682(9) 1.4657(8) 0.059(3) Uani 1 1 d . U . . .
O32 O 0.6368(11) -0.7686(9) 1.6651(8) 0.050(3) Uani 1 1 d . U . . .
O33 O 0.6780(13) -0.8383(10) 1.3963(10) 0.070(3) Uani 1 1 d . U . . .
O34 O 0.6831(11) -1.0699(8) 1.6389(8) 0.050(3) Uani 1 1 d . U . . .
O35 O 0.5591(11) -1.1890(11) 1.3856(8) 0.060(3) Uani 1 1 d . U . . .
O36 O 0.5537(11) -0.9358(8) 1.6785(8) 0.052(3) Uani 1 1 d . U . . .
O37 O 0.7246(14) -1.0814(9) 1.3797(8) 0.057(3) Uani 1 1 d . U . . .
O38 O 0.4350(10) -1.3247(7) 1.5994(7) 0.039(3) Uani 1 1 d . U . . .
O39 O 0.6144(13) -0.9584(10) 1.3151(10) 0.067(3) Uani 1 1 d . U . . .
O40 O 0.7224(11) -0.9087(8) 1.5874(8) 0.049(3) Uani 1 1 d . U . . .
O41 O 0.7576(14) -1.1336(9) 1.5139(8) 0.059(3) Uani 1 1 d . U . . .
O42 O 0.5550(12) -1.0868(9) 1.7673(7) 0.050(3) Uani 1 1 d . U . . .
O43 O 0.5940(11) -1.2350(10) 1.5188(8) 0.056(3) Uani 1 1 d . U . . .
O44 O 0.5214(12) -1.1749(10) 1.6459(9) 0.058(3) Uani 1 1 d . U . . .
Ag1 Ag 1.13612(11) -0.73130(10) 1.71511(9) 0.0435(3) Uani 1 1 d . . . . .
Ag2 Ag 1.24898(14) -0.85684(10) 1.21265(9) 0.0499(4) Uani 1 1 d . . . . .
Ag3 Ag 1.60300(13) -0.76583(13) 1.83217(10) 0.0579(5) Uani 1 1 d . . . . .
Ag4 Ag 0.78404(11) -0.52909(8) 1.69553(7) 0.0355(3) Uani 1 1 d . . . . .
Ag5 Ag 0.58530(11) -0.60462(10) 1.65788(8) 0.0404(3) Uani 1 1 d . . . . .
Ag6 Ag 0.49825(13) -0.49512(11) 1.78020(9) 0.0530(4) Uani 1 1 d . . . . .
N1 N 1.3000(11) -0.7015(9) 1.7399(7) 0.028(3) Uani 1 1 d . . . . .
C1 C 1.3649(12) -0.7464(10) 1.7873(8) 0.024(3) Uani 1 1 d . . . . .
N2 N 1.3566(10) -0.6344(9) 1.7099(6) 0.025(3) Uani 1 1 d . . . . .
C2 C 1.3286(12) -0.8241(9) 1.8305(8) 0.023(3) Uani 1 1 d . . . . .
N3 N 1.4527(11) -0.6379(8) 1.7374(7) 0.027(3) Uani 1 1 d . . . . .
C3 C 1.2781(16) -0.8914(11) 1.7988(9) 0.036(4) Uani 1 1 d . . . . .
H3A H 1.2759 -0.8895 1.7494 0.044 Uiso 1 1 calc R U . . .
N4 N 1.4583(11) -0.7090(8) 1.7858(8) 0.029(3) Uani 1 1 d . . . . .
C4 C 1.2306(15) -0.9618(10) 1.8408(8) 0.032(4) Uani 1 1 d . . . . .
H4A H 1.1959 -1.0058 1.8198 0.038 Uiso 1 1 calc R U . . .
C5 C 1.2369(12) -0.9638(10) 1.9132(9) 0.027(3) Uani 1 1 d . . . . .
N5 N 1.2172(12) -1.0555(9) 2.0297(8) 0.032(3) Uani 1 1 d . . . . .
C6 C 1.2909(13) -0.9002(11) 1.9458(8) 0.030(3) Uani 1 1 d . . . . .
H6A H 1.2974 -0.9048 1.9949 0.036 Uiso 1 1 calc R U . . .
N6 N 1.2952(11) -1.1242(10) 2.1222(7) 0.034(3) Uani 1 1 d . . . . .
C7 C 1.3352(13) -0.8295(11) 1.9040(9) 0.031(4) Uani 1 1 d . . . . .
H7A H 1.3694 -0.7857 1.9255 0.038 Uiso 1 1 calc R U . . .
N7 N 1.3922(11) -1.2567(10) 2.0429(8) 0.037(3) Uani 1 1 d . . . . .
N8 N 1.2991(12) -0.7308(9) 1.2489(8) 0.032(3) Uani 1 1 d . . . . .
N9 N 1.3880(11) -0.6891(9) 1.2197(7) 0.031(3) Uani 1 1 d . . . . .
N10 N 1.3823(11) -0.6083(9) 1.2422(8) 0.035(3) Uani 1 1 d . . . . .
C21 C 1.2412(13) -0.6733(10) 1.2884(8) 0.025(3) Uani 1 1 d . . . . .
C20 C 1.4534(14) -1.3163(13) 2.0048(10) 0.039(4) Uani 1 1 d . . . . .
H20A H 1.4796 -1.3675 2.0291 0.047 Uiso 1 1 calc R U . . .
C22 C 1.1466(12) -0.6929(10) 1.3343(8) 0.025(3) Uani 1 1 d . . . . .
C23 C 1.0545(13) -0.7281(11) 1.3089(8) 0.030(3) Uani 1 1 d . . . . .
H23A H 1.0538 -0.7380 1.2606 0.036 Uiso 1 1 calc R U . . .
C24 C 0.9658(13) -0.7480(11) 1.3544(8) 0.030(3) Uani 1 1 d . . . . .
H24A H 0.9048 -0.7701 1.3369 0.036 Uiso 1 1 calc R U . . .
C25 C 0.9679(11) -0.7350(9) 1.4257(7) 0.019(3) Uani 1 1 d . . . . .
C26 C 1.0556(12) -0.6984(12) 1.4530(9) 0.031(4) Uani 1 1 d . . . . .
H26A H 1.0552 -0.6881 1.5014 0.038 Uiso 1 1 calc R U . . .
C27 C 1.1438(15) -0.6776(12) 1.4061(9) 0.037(4) Uani 1 1 d . . . . .
H27A H 1.2030 -0.6525 1.4236 0.045 Uiso 1 1 calc R U . . .
C28 C 0.8675(12) -0.7597(11) 1.4754(8) 0.028(3) Uani 1 1 d . . . . .
H28A H 0.8030 -0.7360 1.4533 0.033 Uiso 1 1 calc R U . . .
H28B H 0.8641 -0.8240 1.4796 0.033 Uiso 1 1 calc R U . . .
C29 C 0.9173(12) -0.7709(9) 1.6031(8) 0.023(3) Uani 1 1 d . . . . .
C30 C 0.9794(12) -0.8501(10) 1.6073(9) 0.027(3) Uani 1 1 d . . . . .
H30A H 0.9968 -0.8833 1.5675 0.032 Uiso 1 1 calc R U . . .
C31 C 1.0144(13) -0.8770(11) 1.6740(11) 0.038(4) Uani 1 1 d . . . . .
H31A H 1.0565 -0.9295 1.6794 0.045 Uiso 1 1 calc R U . . .
C32 C 0.9870(12) -0.8263(11) 1.7330(10) 0.032(4) Uani 1 1 d . . . . .
H32A H 1.0085 -0.8471 1.7776 0.039 Uiso 1 1 calc R U . . .
C33 C 0.9288(13) -0.7461(10) 1.7268(9) 0.027(3) Uani 1 1 d . . . . .
H33A H 0.9138 -0.7117 1.7662 0.033 Uiso 1 1 calc R U . . .
C34 C 0.8938(12) -0.7183(10) 1.6616(8) 0.024(3) Uani 1 1 d . . . . .
C35 C 0.8189(12) -0.6507(10) 1.5716(8) 0.025(3) Uani 1 1 d . . . . .
C36 C 0.7579(13) -0.5816(10) 1.5270(8) 0.025(3) Uani 1 1 d . . . . .
C37 C 0.7998(15) -0.5520(13) 1.4603(10) 0.044(5) Uani 1 1 d . . . . .
H37A H 0.8645 -0.5771 1.4406 0.053 Uiso 1 1 calc R U . . .
C38 C 0.7448(15) -0.4849(14) 1.4232(10) 0.047(5) Uani 1 1 d . . . . .
H38A H 0.7677 -0.4671 1.3765 0.056 Uiso 1 1 calc R U . . .
C39 C 0.6533(15) -0.4442(12) 1.4583(11) 0.040(4) Uani 1 1 d . . . . .
H39A H 0.6163 -0.3961 1.4364 0.048 Uiso 1 1 calc R U . . .
C40 C 0.6191(13) -0.4766(11) 1.5259(10) 0.033(4) Uani 1 1 d . . . . .
H40A H 0.5580 -0.4492 1.5487 0.039 Uiso 1 1 calc R U . . .
C8 C 1.1776(14) -1.0368(11) 1.9591(9) 0.033(4) Uani 1 1 d . . . . .
H8A H 1.1011 -1.0191 1.9648 0.039 Uiso 1 1 calc R U . . .
H8B H 1.1841 -1.0912 1.9336 0.039 Uiso 1 1 calc R U . . .
C9 C 1.1744(12) -1.0136(12) 2.0915(9) 0.032(4) Uani 1 1 d . . . . .
C10 C 1.0970(14) -0.9462(12) 2.0999(9) 0.035(4) Uani 1 1 d . . . . .
H10A H 1.0642 -0.9178 2.0612 0.042 Uiso 1 1 calc R U . . .
C11 C 1.0711(17) -0.9235(14) 2.1677(11) 0.048(5) Uani 1 1 d . . . . .
H11A H 1.0190 -0.8778 2.1758 0.057 Uiso 1 1 calc R U . . .
N11 N 1.2911(10) -0.5967(8) 1.2860(7) 0.029(3) Uani 1 1 d . . . . .
C12 C 1.1191(16) -0.9657(12) 2.2263(10) 0.042(4) Uani 1 1 d . . . . .
H12A H 1.0981 -0.9476 2.2720 0.050 Uiso 1 1 calc R U . . .
N12 N 0.8663(10) -0.7270(8) 1.5463(7) 0.024(3) Uani 1 1 d . . . . .
C13 C 1.1952(16) -1.0321(13) 2.2180(9) 0.041(4) Uani 1 1 d . . . . .
H13A H 1.2277 -1.0596 2.2571 0.049 Uiso 1 1 calc R U . . .
N13 N 0.8327(11) -0.6439(8) 1.6391(7) 0.027(3) Uani 1 1 d . . . . .
C14 C 1.2237(12) -1.0584(11) 2.1485(9) 0.029(3) Uani 1 1 d . . . . .
N14 N 0.6692(11) -0.5457(9) 1.5608(7) 0.031(3) Uani 1 1 d . . . . .
C15 C 1.2899(13) -1.1234(10) 2.0531(10) 0.031(4) Uani 1 1 d . . . . .
C16 C 1.3559(14) -1.1839(12) 2.0066(10) 0.037(4) Uani 1 1 d . . . . .
C17 C 1.3787(18) -1.1661(14) 1.9338(11) 0.056(6) Uani 1 1 d . . . . .
H17A H 1.3521 -1.1139 1.9110 0.067 Uiso 1 1 calc R U . . .
C18 C 1.442(2) -1.2282(15) 1.8959(14) 0.071(8) Uani 1 1 d . . . . .
H18A H 1.4599 -1.2179 1.8471 0.085 Uiso 1 1 calc R U . . .
C19 C 1.4800(17) -1.3061(12) 1.9314(12) 0.051(5) Uani 1 1 d . . . . .
H19A H 1.5212 -1.3497 1.9072 0.062 Uiso 1 1 calc R U . . .
OW1 O 0.3439(17) -0.4108(15) 1.7317(10) 0.095(6) Uani 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O22 1.682(12) . ?
W1 O5 1.851(16) 2_549 ?
W1 O7 1.863(15) . ?
W1 O6 1.903(16) . ?
W1 O9 1.919(15) . ?
W1 O3 2.39(3) . ?
W1 O1 2.40(2) 2_549 ?
W2 O18 1.650(13) . ?
W2 O13 1.867(15) . ?
W2 O6 1.869(15) . ?
W2 O19 1.930(14) . ?
W2 O8 1.962(15) 2_549 ?
W2 O1 2.38(2) 2_549 ?
W2 O2 2.43(2) 2_549 ?
W3 O12 1.692(13) . ?
W3 O9 1.822(15) . ?
W3 O15 1.851(15) . ?
W3 O10 1.919(16) 2_549 ?
W3 O16 1.952(14) . ?
W3 O3 2.37(2) . ?
W3 O4 2.44(2) . ?
W4 O21 1.679(12) . ?
W4 O19 1.856(14) . ?
W4 O10 1.872(15) . ?
W4 O5 1.923(14) . ?
W4 O17 1.940(15) . ?
W4 O3 2.40(2) 2_549 ?
W4 O2 2.44(2) 2_549 ?
W5 O20 1.674(13) . ?
W5 O8 1.843(15) . ?
W5 O16 1.871(14) . ?
W5 O7 1.921(14) 2_549 ?
W5 O11 1.956(14) . ?
W5 O1 2.36(2) . ?
W5 O4 2.38(3) . ?
W6 O14 1.665(13) . ?
W6 O11 1.848(14) . ?
W6 O17 1.850(14) . ?
W6 O13 1.922(15) . ?
W6 O15 1.934(14) . ?
W6 O2 2.38(2) 2_549 ?
W6 O4 2.42(3) . ?
W7 O38 1.672(11) . ?
W7 O43 1.869(14) . ?
W7 O44 1.876(15) . ?
W7 O30 1.931(16) . ?
W7 O33 1.953(16) 2_638 ?
W7 O23 2.39(2) . ?
W7 O26 2.49(2) . ?
W8 O42 1.667(13) . ?
W8 O39 1.868(16) 2_638 ?
W8 O36 1.879(13) . ?
W8 O44 1.925(14) . ?
W8 O34 1.932(13) . ?
W8 O23 2.32(3) . ?
W8 O24 2.49(2) . ?
W9 O29 1.691(11) . ?
W9 O37 1.877(14) . ?
W9 O35 1.884(15) . ?
W9 O41 1.910(15) . ?
W9 O43 1.911(14) . ?
W9 O25 2.37(3) . ?
W9 O26 2.43(2) . ?
W10 O32 1.705(13) . ?
W10 O40 1.869(13) . ?
W10 O30 1.877(14) 2_638 ?
W10 O36 1.889(13) . ?
W10 O35 1.922(14) 2_638 ?
W10 O26 2.31(2) 2_638 ?
W10 O24 2.39(2) . ?
W11 O27 1.657(13) . ?
W11 O34 1.846(13) . ?
W11 O41 1.876(14) . ?
W11 O40 1.924(12) . ?
W11 O31 1.936(15) . ?
W11 O25 2.33(3) . ?
W11 O24 2.46(2) . ?
W12 O28 1.665(11) . ?
W12 O33 1.860(15) . ?
W12 O31 1.861(16) . ?
W12 O37 1.911(14) . ?
W12 O39 1.919(15) . ?
W12 O23 2.39(2) 2_638 ?
W12 O25 2.46(3) . ?
Si1 O2 1.60(2) 2_549 ?
Si1 O2 1.60(2) . ?
Si1 O4 1.61(3) . ?
Si1 O4 1.61(3) 2_549 ?
Si1 O3 1.64(2) 2_549 ?
Si1 O3 1.64(2) . ?
Si1 O1 1.65(2) 2_549 ?
Si1 O1 1.65(2) . ?
Si2 O24 1.54(3) . ?
Si2 O24 1.54(2) 2_638 ?
Si2 O26 1.61(2) 2_638 ?
Si2 O26 1.61(2) . ?
Si2 O25 1.66(3) 2_638 ?
Si2 O25 1.66(3) . ?
Si2 O23 1.69(2) . ?
Si2 O23 1.69(2) 2_638 ?
O1 W2 2.38(2) 2_549 ?
O1 W1 2.40(2) 2_549 ?
O2 O4 1.81(3) 2_549 ?
O2 W6 2.38(2) 2_549 ?
O2 W2 2.43(2) 2_549 ?
O2 W4 2.44(2) 2_549 ?
O3 W4 2.40(2) 2_549 ?
O4 O2 1.81(3) 2_549 ?
O5 W1 1.851(16) 2_549 ?
O7 W5 1.921(14) 2_549 ?
O8 W2 1.962(14) 2_549 ?
O10 W3 1.919(16) 2_549 ?
O22 Ag6 2.384(13) . ?
O23 W12 2.39(2) 2_638 ?
O24 O26 1.70(3) 2_638 ?
O24 O25 1.78(3) . ?
O26 O24 1.70(3) 2_638 ?
O26 W10 2.31(2) 2_638 ?
O30 W10 1.877(14) 2_638 ?
O32 Ag5 2.519(14) . ?
O33 W7 1.953(16) 2_638 ?
O35 W10 1.922(14) 2_638 ?
O39 W8 1.868(16) 2_638 ?
O42 Ag2 2.578(14) 2_738 ?
Ag1 N1 2.188(13) . ?
Ag1 C32 2.382(15) . ?
Ag1 C33 2.577(15) . ?
Ag2 N8 2.188(14) . ?
Ag2 C12 2.341(18) 1_554 ?
Ag2 O42 2.578(14) 2_738 ?
Ag2 C11 2.68(2) 1_554 ?
Ag3 N4 2.168(13) . ?
Ag3 N6 2.203(14) 2_839 ?
Ag3 N7 2.396(15) 2_839 ?
Ag4 N11 2.105(12) 2_748 ?
Ag4 N13 2.119(12) . ?
Ag4 Ag5 2.912(2) . ?
Ag5 N3 2.188(14) 1_455 ?
Ag5 N14 2.190(14) . ?
Ag5 Ag6 3.010(2) . ?
Ag6 N10 2.200(14) 2_748 ?
Ag6 OW1 2.45(2) . ?
Ag6 N3 2.446(13) 1_455 ?
N1 N2 1.330(18) . ?
N1 C1 1.371(19) . ?
C1 N4 1.308(19) . ?
C1 C2 1.45(2) . ?
N2 N3 1.330(17) . ?
C2 C7 1.39(2) . ?
C2 C3 1.40(2) . ?
N3 N4 1.366(18) . ?
N3 Ag5 2.188(13) 1_655 ?
N3 Ag6 2.446(12) 1_655 ?
C3 C4 1.41(2) . ?
C3 H3A 0.9300 . ?
C4 C5 1.37(2) . ?
C4 H4A 0.9300 . ?
C5 C6 1.39(2) . ?
C5 C8 1.54(2) . ?
N5 C15 1.40(2) . ?
N5 C9 1.41(2) . ?
N5 C8 1.46(2) . ?
C6 C7 1.39(2) . ?
C6 H6A 0.9300 . ?
N6 C15 1.30(2) . ?
N6 C14 1.38(2) . ?
N6 Ag3 2.204(14) 2_839 ?
C7 H7A 0.9300 . ?
N7 C16 1.33(2) . ?
N7 C20 1.35(2) . ?
N7 Ag3 2.396(15) 2_839 ?
N8 C21 1.323(19) . ?
N8 N9 1.356(19) . ?
N9 N10 1.308(19) . ?
N10 N11 1.355(18) . ?
N10 Ag6 2.200(14) 2_748 ?
C21 N11 1.332(19) . ?
C21 C22 1.43(2) . ?
C20 C19 1.39(3) . ?
C20 H20A 0.9300 . ?
C22 C27 1.38(2) . ?
C22 C23 1.41(2) . ?
C23 C24 1.37(2) . ?
C23 H23A 0.9300 . ?
C24 C25 1.37(2) . ?
C24 H24A 0.9300 . ?
C25 C26 1.39(2) . ?
C25 C28 1.54(2) . ?
C26 C27 1.39(2) . ?
C26 H26A 0.9300 . ?
C27 H27A 0.9300 . ?
C28 N12 1.446(19) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 C30 1.39(2) . ?
C29 N12 1.397(19) . ?
C29 C34 1.40(2) . ?
C30 C31 1.39(2) . ?
C30 H30A 0.9300 . ?
C31 C32 1.39(3) . ?
C31 H31A 0.9300 . ?
C32 C33 1.38(2) . ?
C32 H32A 0.9300 . ?
C33 C34 1.37(2) . ?
C33 H33A 0.9300 . ?
C34 N13 1.385(19) . ?
C35 N13 1.304(19) . ?
C35 N12 1.359(19) . ?
C35 C36 1.51(2) . ?
C36 N14 1.33(2) . ?
C36 C37 1.38(2) . ?
C37 C38 1.38(2) . ?
C37 H37A 0.9300 . ?
C38 C39 1.40(3) . ?
C38 H38A 0.9300 . ?
C39 C40 1.38(3) . ?
C39 H39A 0.9300 . ?
C40 N14 1.35(2) . ?
C40 H40A 0.9300 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.37(2) . ?
C9 C14 1.40(2) . ?
C10 C11 1.35(3) . ?
C10 H10A 0.9300 . ?
C11 C12 1.40(3) . ?
C11 Ag2 2.68(2) 1_556 ?
C11 H11A 0.9300 . ?
N11 Ag4 2.105(12) 2_748 ?
C12 C13 1.35(3) . ?
C12 Ag2 2.341(18) 1_556 ?
C12 H12A 0.9300 . ?
C13 C14 1.40(2) . ?
C13 H13A 0.9300 . ?
C15 C16 1.47(2) . ?
C16 C17 1.39(3) . ?
C17 C18 1.39(3) . ?
C17 H17A 0.9300 . ?
C18 C19 1.39(3) . ?
C18 H18A 0.9300 . ?
C19 H19A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O22 W1 O5 101.7(7) . 2_549 ?
O22 W1 O7 101.0(7) . . ?
O5 W1 O7 92.7(7) 2_549 . ?
O22 W1 O6 101.1(7) . . ?
O5 W1 O6 156.9(7) 2_549 . ?
O7 W1 O6 87.3(6) . . ?
O22 W1 O9 102.5(7) . . ?
O5 W1 O9 87.1(6) 2_549 . ?
O7 W1 O9 156.0(7) . . ?
O6 W1 O9 83.7(7) . . ?
O22 W1 O3 156.9(8) . . ?
O5 W1 O3 63.6(8) 2_549 . ?
O7 W1 O3 97.5(8) . . ?
O6 W1 O3 93.5(8) . . ?
O9 W1 O3 61.0(7) . . ?
O22 W1 O1 155.3(7) . 2_549 ?
O5 W1 O1 97.7(8) 2_549 2_549 ?
O7 W1 O1 62.7(8) . 2_549 ?
O6 W1 O1 61.9(8) . 2_549 ?
O9 W1 O1 93.6(8) . 2_549 ?
O3 W1 O1 47.7(8) . 2_549 ?
O18 W2 O13 102.2(7) . . ?
O18 W2 O6 103.5(8) . . ?
O13 W2 O6 91.6(7) . . ?
O18 W2 O19 100.1(7) . . ?
O13 W2 O19 89.7(6) . . ?
O6 W2 O19 155.5(7) . . ?
O18 W2 O8 99.4(7) . 2_549 ?
O13 W2 O8 158.0(7) . 2_549 ?
O6 W2 O8 87.5(6) . 2_549 ?
O19 W2 O8 82.2(6) . 2_549 ?
O18 W2 O1 156.2(8) . 2_549 ?
O13 W2 O1 97.7(8) . 2_549 ?
O6 W2 O1 62.7(8) . 2_549 ?
O19 W2 O1 92.8(8) . 2_549 ?
O8 W2 O1 62.5(8) 2_549 2_549 ?
O18 W2 O2 157.2(7) . 2_549 ?
O13 W2 O2 63.9(7) . 2_549 ?
O6 W2 O2 95.2(7) . 2_549 ?
O19 W2 O2 63.7(6) . 2_549 ?
O8 W2 O2 94.3(7) 2_549 2_549 ?
O1 W2 O2 46.1(8) 2_549 2_549 ?
O12 W3 O9 104.0(7) . . ?
O12 W3 O15 100.8(7) . . ?
O9 W3 O15 92.0(7) . . ?
O12 W3 O10 101.7(7) . 2_549 ?
O9 W3 O10 87.2(6) . 2_549 ?
O15 W3 O10 156.9(8) . 2_549 ?
O12 W3 O16 98.5(7) . . ?
O9 W3 O16 157.0(7) . . ?
O15 W3 O16 88.4(6) . . ?
O10 W3 O16 83.6(6) 2_549 . ?
O12 W3 O3 158.6(8) . . ?
O9 W3 O3 62.5(8) . . ?
O15 W3 O3 96.4(8) . . ?
O10 W3 O3 62.9(8) 2_549 . ?
O16 W3 O3 94.6(8) . . ?
O12 W3 O4 155.2(8) . . ?
O9 W3 O4 96.0(8) . . ?
O15 W3 O4 63.6(8) . . ?
O10 W3 O4 93.5(8) 2_549 . ?
O16 W3 O4 63.7(8) . . ?
O3 W3 O4 46.0(8) . . ?
O21 W4 O19 100.8(7) . . ?
O21 W4 O10 102.7(7) . . ?
O19 W4 O10 91.9(6) . . ?
O21 W4 O5 102.1(7) . . ?
O19 W4 O5 156.6(7) . . ?
O10 W4 O5 87.3(6) . . ?
O21 W4 O17 99.7(7) . . ?
O19 W4 O17 88.0(6) . . ?
O10 W4 O17 157.2(8) . . ?
O5 W4 O17 83.9(6) . . ?
O21 W4 O3 158.1(8) . 2_549 ?
O19 W4 O3 96.3(8) . 2_549 ?
O10 W4 O3 62.9(8) . 2_549 ?
O5 W4 O3 62.6(8) . 2_549 ?
O17 W4 O3 94.4(8) . 2_549 ?
O21 W4 O2 155.6(7) . 2_549 ?
O19 W4 O2 64.4(7) . 2_549 ?
O10 W4 O2 97.3(8) . 2_549 ?
O5 W4 O2 92.5(8) . 2_549 ?
O17 W4 O2 62.2(7) . 2_549 ?
O3 W4 O2 46.1(8) 2_549 2_549 ?
O20 W5 O8 101.0(7) . . ?
O20 W5 O16 99.3(7) . . ?
O8 W5 O16 92.9(6) . . ?
O20 W5 O7 101.3(7) . 2_549 ?
O8 W5 O7 88.5(6) . 2_549 ?
O16 W5 O7 158.7(7) . 2_549 ?
O20 W5 O11 100.3(7) . . ?
O8 W5 O11 158.3(7) . . ?
O16 W5 O11 88.0(6) . . ?
O7 W5 O11 83.1(6) 2_549 . ?
O20 W5 O1 157.2(8) . . ?
O8 W5 O1 64.3(8) . . ?
O16 W5 O1 98.7(8) . . ?
O7 W5 O1 62.9(8) 2_549 . ?
O11 W5 O1 94.1(8) . . ?
O20 W5 O4 156.8(8) . . ?
O8 W5 O4 97.8(8) . . ?
O16 W5 O4 66.0(8) . . ?
O7 W5 O4 92.7(8) 2_549 . ?
O11 W5 O4 62.8(8) . . ?
O1 W5 O4 45.8(8) . . ?
O14 W6 O11 101.5(8) . . ?
O14 W6 O17 101.3(8) . . ?
O11 W6 O17 92.3(6) . . ?
O14 W6 O13 100.5(7) . . ?
O11 W6 O13 157.3(7) . . ?
O17 W6 O13 88.8(6) . . ?
O14 W6 O15 101.6(8) . . ?
O11 W6 O15 88.2(6) . . ?
O17 W6 O15 156.6(7) . . ?
O13 W6 O15 82.0(6) . . ?
O14 W6 O2 158.1(8) . 2_549 ?
O11 W6 O2 95.8(8) . 2_549 ?
O17 W6 O2 64.5(7) . 2_549 ?
O13 W6 O2 64.4(7) . 2_549 ?
O15 W6 O2 92.2(7) . 2_549 ?
O14 W6 O4 157.4(9) . . ?
O11 W6 O4 63.2(8) . . ?
O17 W6 O4 96.2(8) . . ?
O13 W6 O4 94.1(8) . . ?
O15 W6 O4 63.2(8) . . ?
O2 W6 O4 44.4(8) 2_549 . ?
O38 W7 O43 101.6(6) . . ?
O38 W7 O44 101.9(7) . . ?
O43 W7 O44 91.3(7) . . ?
O38 W7 O30 99.5(7) . . ?
O43 W7 O30 88.8(6) . . ?
O44 W7 O30 158.1(7) . . ?
O38 W7 O33 99.2(7) . 2_638 ?
O43 W7 O33 158.9(7) . 2_638 ?
O44 W7 O33 87.4(6) . 2_638 ?
O30 W7 O33 84.7(7) . 2_638 ?
O38 W7 O23 155.9(7) . . ?
O43 W7 O23 97.2(7) . . ?
O44 W7 O23 62.5(8) . . ?
O30 W7 O23 95.8(8) . . ?
O33 W7 O23 63.7(8) 2_638 . ?
O38 W7 O26 155.3(7) . . ?
O43 W7 O26 64.4(7) . . ?
O44 W7 O26 98.9(8) . . ?
O30 W7 O26 61.6(7) . . ?
O33 W7 O26 94.9(8) 2_638 . ?
O23 W7 O26 48.4(8) . . ?
O42 W8 O39 101.2(8) . 2_638 ?
O42 W8 O36 101.0(7) . . ?
O39 W8 O36 91.0(6) 2_638 . ?
O42 W8 O44 100.8(7) . . ?
O39 W8 O44 88.8(6) 2_638 . ?
O36 W8 O44 157.8(7) . . ?
O42 W8 O34 101.3(7) . . ?
O39 W8 O34 157.3(7) 2_638 . ?
O36 W8 O34 86.9(6) . . ?
O44 W8 O34 84.8(6) . . ?
O42 W8 O23 156.9(8) . . ?
O39 W8 O23 63.6(8) 2_638 . ?
O36 W8 O23 96.8(8) . . ?
O44 W8 O23 63.4(8) . . ?
O34 W8 O23 94.2(7) . . ?
O42 W8 O24 157.5(8) . . ?
O39 W8 O24 95.5(8) 2_638 . ?
O36 W8 O24 63.4(7) . . ?
O44 W8 O24 94.5(7) . . ?
O34 W8 O24 63.5(7) . . ?
O23 W8 O24 45.6(8) . . ?
O29 W9 O37 101.4(7) . . ?
O29 W9 O35 102.3(7) . . ?
O37 W9 O35 90.2(6) . . ?
O29 W9 O41 99.1(7) . . ?
O37 W9 O41 88.8(6) . . ?
O35 W9 O41 158.4(7) . . ?
O29 W9 O43 101.4(7) . . ?
O37 W9 O43 157.0(7) . . ?
O35 W9 O43 87.3(6) . . ?
O41 W9 O43 85.3(6) . . ?
O29 W9 O25 155.3(8) . . ?
O37 W9 O25 64.7(8) . . ?
O35 W9 O25 98.3(8) . . ?
O41 W9 O25 62.0(8) . . ?
O43 W9 O25 93.0(8) . . ?
O29 W9 O26 158.1(7) . . ?
O37 W9 O26 93.6(7) . . ?
O35 W9 O26 61.5(8) . . ?
O41 W9 O26 97.0(8) . . ?
O43 W9 O26 65.2(7) . . ?
O25 W9 O26 46.5(8) . . ?
O32 W10 O40 101.0(7) . . ?
O32 W10 O30 101.5(8) . 2_638 ?
O40 W10 O30 89.9(6) . 2_638 ?
O32 W10 O36 100.0(7) . . ?
O40 W10 O36 88.7(6) . . ?
O30 W10 O36 158.4(7) 2_638 . ?
O32 W10 O35 100.3(7) . 2_638 ?
O40 W10 O35 158.6(7) . 2_638 ?
O30 W10 O35 88.3(6) 2_638 2_638 ?
O36 W10 O35 85.2(6) . 2_638 ?
O32 W10 O26 158.7(8) . 2_638 ?
O40 W10 O26 96.3(8) . 2_638 ?
O30 W10 O26 66.0(8) 2_638 2_638 ?
O36 W10 O26 92.7(8) . 2_638 ?
O35 W10 O26 63.6(8) 2_638 2_638 ?
O32 W10 O24 158.8(8) . . ?
O40 W10 O24 65.0(7) . . ?
O30 W10 O24 94.5(8) 2_638 . ?
O36 W10 O24 65.4(7) . . ?
O35 W10 O24 93.9(8) 2_638 . ?
O26 W10 O24 42.2(8) 2_638 . ?
O27 W11 O34 102.6(7) . . ?
O27 W11 O41 100.1(7) . . ?
O34 W11 O41 91.8(6) . . ?
O27 W11 O40 102.0(7) . . ?
O34 W11 O40 87.7(6) . . ?
O41 W11 O40 157.4(7) . . ?
O27 W11 O31 100.7(7) . . ?
O34 W11 O31 156.4(7) . . ?
O41 W11 O31 87.8(6) . . ?
O40 W11 O31 83.8(6) . . ?
O27 W11 O25 156.5(9) . . ?
O34 W11 O25 94.8(8) . . ?
O41 W11 O25 63.3(8) . . ?
O40 W11 O25 94.2(8) . . ?
O31 W11 O25 64.0(8) . . ?
O27 W11 O24 159.8(8) . . ?
O34 W11 O24 65.1(7) . . ?
O41 W11 O24 96.4(8) . . ?
O40 W11 O24 63.0(7) . . ?
O31 W11 O24 91.4(8) . . ?
O25 W11 O24 43.6(8) . . ?
O28 W12 O33 100.0(7) . . ?
O28 W12 O31 101.9(7) . . ?
O33 W12 O31 92.6(7) . . ?
O28 W12 O37 100.7(6) . . ?
O33 W12 O37 158.7(8) . . ?
O31 W12 O37 88.3(6) . . ?
O28 W12 O39 99.7(7) . . ?
O33 W12 O39 87.9(7) . . ?
O31 W12 O39 158.0(8) . . ?
O37 W12 O39 83.5(7) . . ?
O28 W12 O23 154.8(7) . 2_638 ?
O33 W12 O23 64.8(8) . 2_638 ?
O31 W12 O23 98.9(8) . 2_638 ?
O37 W12 O23 94.0(8) . 2_638 ?
O39 W12 O23 61.5(8) . 2_638 ?
O28 W12 O25 155.4(7) . . ?
O33 W12 O25 99.4(8) . . ?
O31 W12 O25 62.1(8) . . ?
O37 W12 O25 62.4(7) . . ?
O39 W12 O25 96.1(8) . . ?
O23 W12 O25 49.5(8) 2_638 . ?
O2 Si1 O2 180.0(4) 2_549 . ?
O2 Si1 O4 69.0(12) 2_549 . ?
O2 Si1 O4 111.0(12) . . ?
O2 Si1 O4 111.0(12) 2_549 2_549 ?
O2 Si1 O4 69.0(12) . 2_549 ?
O4 Si1 O4 179.999(11) . 2_549 ?
O2 Si1 O3 71.5(11) 2_549 2_549 ?
O2 Si1 O3 108.5(11) . 2_549 ?
O4 Si1 O3 109.3(12) . 2_549 ?
O4 Si1 O3 70.7(12) 2_549 2_549 ?
O2 Si1 O3 108.5(11) 2_549 . ?
O2 Si1 O3 71.5(11) . . ?
O4 Si1 O3 70.7(12) . . ?
O4 Si1 O3 109.3(12) 2_549 . ?
O3 Si1 O3 180.0(17) 2_549 . ?
O2 Si1 O1 71.0(12) 2_549 2_549 ?
O2 Si1 O1 109.0(11) . 2_549 ?
O4 Si1 O1 111.1(12) . 2_549 ?
O4 Si1 O1 68.9(12) 2_549 2_549 ?
O3 Si1 O1 108.0(12) 2_549 2_549 ?
O3 Si1 O1 72.0(12) . 2_549 ?
O2 Si1 O1 109.0(11) 2_549 . ?
O2 Si1 O1 71.0(12) . . ?
O4 Si1 O1 68.9(12) . . ?
O4 Si1 O1 111.1(12) 2_549 . ?
O3 Si1 O1 72.0(12) 2_549 . ?
O3 Si1 O1 108.0(12) . . ?
O1 Si1 O1 180.0(16) 2_549 . ?
O24 Si2 O24 180.0 . 2_638 ?
O24 Si2 O26 65.3(12) . 2_638 ?
O24 Si2 O26 114.7(12) 2_638 2_638 ?
O24 Si2 O26 114.7(12) . . ?
O24 Si2 O26 65.3(12) 2_638 . ?
O26 Si2 O26 180.0 2_638 . ?
O24 Si2 O25 112.2(13) . 2_638 ?
O24 Si2 O25 67.8(13) 2_638 2_638 ?
O26 Si2 O25 70.9(12) 2_638 2_638 ?
O26 Si2 O25 109.1(12) . 2_638 ?
O24 Si2 O25 67.8(13) . . ?
O24 Si2 O25 112.2(13) 2_638 . ?
O26 Si2 O25 109.1(12) 2_638 . ?
O26 Si2 O25 70.9(12) . . ?
O25 Si2 O25 180.0 2_638 . ?
O24 Si2 O23 70.6(12) . . ?
O24 Si2 O23 109.4(12) 2_638 . ?
O26 Si2 O23 105.5(12) 2_638 . ?
O26 Si2 O23 74.5(12) . . ?
O25 Si2 O23 74.6(12) 2_638 . ?
O25 Si2 O23 105.4(12) . . ?
O24 Si2 O23 109.4(12) . 2_638 ?
O24 Si2 O23 70.6(12) 2_638 2_638 ?
O26 Si2 O23 74.6(12) 2_638 2_638 ?
O26 Si2 O23 105.4(12) . 2_638 ?
O25 Si2 O23 105.4(12) 2_638 2_638 ?
O25 Si2 O23 74.6(12) . 2_638 ?
O23 Si2 O23 180.0(11) . 2_638 ?
Si1 O1 W5 121.9(12) . . ?
Si1 O1 W2 121.4(12) . 2_549 ?
W5 O1 W2 96.3(9) . 2_549 ?
Si1 O1 W1 119.6(12) . 2_549 ?
W5 O1 W1 95.8(9) . 2_549 ?
W2 O1 W1 95.5(8) 2_549 2_549 ?
Si1 O2 O4 55.7(11) . 2_549 ?
Si1 O2 W6 124.5(12) . 2_549 ?
O4 O2 W6 68.8(11) 2_549 2_549 ?
Si1 O2 W2 121.4(11) . 2_549 ?
O4 O2 W2 130.1(13) 2_549 2_549 ?
W6 O2 W2 94.1(7) 2_549 2_549 ?
Si1 O2 W4 121.3(11) . 2_549 ?
O4 O2 W4 133.1(13) 2_549 2_549 ?
W6 O2 W4 94.6(7) 2_549 2_549 ?
W2 O2 W4 93.2(7) 2_549 2_549 ?
Si1 O3 W3 122.5(13) . . ?
Si1 O3 W1 120.5(13) . . ?
W3 O3 W1 95.4(9) . . ?
Si1 O3 W4 121.0(13) . 2_549 ?
W3 O3 W4 95.8(9) . 2_549 ?
W1 O3 W4 94.9(9) . 2_549 ?
Si1 O4 O2 55.2(10) . 2_549 ?
Si1 O4 W5 123.3(13) . . ?
O2 O4 W5 134.6(14) 2_549 . ?
Si1 O4 W6 122.0(13) . . ?
O2 O4 W6 66.8(10) 2_549 . ?
W5 O4 W6 95.5(9) . . ?
Si1 O4 W3 120.6(13) . . ?
O2 O4 W3 126.7(14) 2_549 . ?
W5 O4 W3 94.5(9) . . ?
W6 O4 W3 93.7(9) . . ?
W1 O5 W4 138.6(9) 2_549 . ?
W2 O6 W1 139.7(9) . . ?
W1 O7 W5 138.4(9) . 2_549 ?
W5 O8 W2 136.6(9) . 2_549 ?
W3 O9 W1 140.8(9) . . ?
W4 O10 W3 138.1(10) . 2_549 ?
W6 O11 W5 138.0(9) . . ?
W2 O13 W6 136.9(9) . . ?
W3 O15 W6 139.0(9) . . ?
W5 O16 W3 135.6(9) . . ?
W6 O17 W4 138.3(9) . . ?
W4 O19 W2 138.2(8) . . ?
W1 O22 Ag6 138.1(7) . . ?
Si2 O23 W8 122.9(13) . . ?
Si2 O23 W12 118.9(12) . 2_638 ?
W8 O23 W12 97.2(9) . 2_638 ?
Si2 O23 W7 119.1(12) . . ?
W8 O23 W7 97.3(9) . . ?
W12 O23 W7 95.6(8) 2_638 . ?
Si2 O24 O26 59.4(12) . 2_638 ?
Si2 O24 O25 59.3(12) . . ?
O26 O24 O25 99.6(17) 2_638 . ?
Si2 O24 W10 125.7(13) . . ?
O26 O24 W10 66.3(11) 2_638 . ?
O25 O24 W10 132.5(14) . . ?
Si2 O24 W11 123.7(13) . . ?
O26 O24 W11 135.7(14) 2_638 . ?
O25 O24 W11 64.4(11) . . ?
W10 O24 W11 93.6(8) . . ?
Si2 O24 W8 120.9(12) . . ?
O26 O24 W8 126.5(15) 2_638 . ?
O25 O24 W8 127.5(14) . . ?
W10 O24 W8 92.3(8) . . ?
W11 O24 W8 91.5(8) . . ?
Si2 O25 O24 52.8(11) . . ?
Si2 O25 W11 124.7(14) . . ?
O24 O25 W11 71.9(12) . . ?
Si2 O25 W9 121.7(13) . . ?
O24 O25 W9 138.4(15) . . ?
W11 O25 W9 97.0(10) . . ?
Si2 O25 W12 116.8(13) . . ?
O24 O25 W12 126.1(14) . . ?
W11 O25 W12 95.5(9) . . ?
W9 O25 W12 94.2(9) . . ?
Si2 O26 O24 55.2(11) . 2_638 ?
Si2 O26 W10 126.6(13) . 2_638 ?
O24 O26 W10 71.4(12) 2_638 2_638 ?
Si2 O26 W9 120.9(12) . . ?
O24 O26 W9 134.7(15) 2_638 . ?
W10 O26 W9 96.8(9) 2_638 . ?
Si2 O26 W7 117.7(12) . . ?
O24 O26 W7 131.8(15) 2_638 . ?
W10 O26 W7 95.0(8) 2_638 . ?
W9 O26 W7 91.9(8) . . ?
W10 O30 W7 136.8(9) 2_638 . ?
W12 O31 W11 138.2(9) . . ?
W10 O32 Ag5 124.3(8) . . ?
W12 O33 W7 135.9(10) . 2_638 ?
W11 O34 W8 139.5(8) . . ?
W9 O35 W10 137.6(10) . 2_638 ?
W8 O36 W10 138.4(8) . . ?
W9 O37 W12 138.3(9) . . ?
W8 O39 W12 137.3(10) 2_638 . ?
W10 O40 W11 137.6(8) . . ?
W11 O41 W9 137.3(9) . . ?
W8 O42 Ag2 112.9(6) . 2_738 ?
W7 O43 W9 138.3(8) . . ?
W7 O44 W8 136.5(9) . . ?
N1 Ag1 C32 148.7(5) . . ?
N1 Ag1 C33 161.1(5) . . ?
C32 Ag1 C33 32.0(5) . . ?
N8 Ag2 C12 145.9(6) . 1_554 ?
N8 Ag2 O42 84.9(5) . 2_738 ?
C12 Ag2 O42 115.4(6) 1_554 2_738 ?
N8 Ag2 C11 138.3(6) . 1_554 ?
C12 Ag2 C11 31.4(6) 1_554 1_554 ?
O42 Ag2 C11 136.8(6) 2_738 1_554 ?
N4 Ag3 N6 154.0(5) . 2_839 ?
N4 Ag3 N7 114.0(5) . 2_839 ?
N6 Ag3 N7 72.9(5) 2_839 2_839 ?
N11 Ag4 N13 157.9(5) 2_748 . ?
N11 Ag4 Ag5 93.8(4) 2_748 . ?
N13 Ag4 Ag5 73.8(4) . . ?
N3 Ag5 N14 159.4(5) 1_455 . ?
N3 Ag5 O32 85.7(4) 1_455 . ?
N14 Ag5 O32 107.7(5) . . ?
N3 Ag5 Ag4 122.5(3) 1_455 . ?
N14 Ag5 Ag4 71.1(4) . . ?
O32 Ag5 Ag4 101.3(3) . . ?
N3 Ag5 Ag6 53.3(3) 1_455 . ?
N14 Ag5 Ag6 122.4(3) . . ?
O32 Ag5 Ag6 126.3(3) . . ?
Ag4 Ag5 Ag6 79.55(6) . . ?
N10 Ag6 O22 121.9(5) 2_748 . ?
N10 Ag6 OW1 97.2(6) 2_748 . ?
O22 Ag6 OW1 91.5(5) . . ?
N10 Ag6 N3 140.2(5) 2_748 1_455 ?
O22 Ag6 N3 95.3(4) . 1_455 ?
OW1 Ag6 N3 95.2(6) . 1_455 ?
N10 Ag6 Ag5 94.4(4) 2_748 . ?
O22 Ag6 Ag5 138.9(3) . . ?
OW1 Ag6 Ag5 103.0(5) . . ?
N3 Ag6 Ag5 45.9(3) 1_455 . ?
N2 N1 C1 106.4(12) . . ?
N2 N1 Ag1 125.2(10) . . ?
C1 N1 Ag1 128.4(10) . . ?
N4 C1 N1 110.1(13) . . ?
N4 C1 C2 128.2(14) . . ?
N1 C1 C2 121.7(13) . . ?
N1 N2 N3 108.3(12) . . ?
C7 C2 C3 119.0(14) . . ?
C7 C2 C1 120.9(14) . . ?
C3 C2 C1 119.9(14) . . ?
N2 N3 N4 109.1(12) . . ?
N2 N3 Ag5 112.8(9) . 1_655 ?
N4 N3 Ag5 123.2(10) . 1_655 ?
N2 N3 Ag6 112.7(9) . 1_655 ?
N4 N3 Ag6 115.6(9) . 1_655 ?
Ag5 N3 Ag6 80.8(4) 1_655 1_655 ?
C2 C3 C4 120.9(15) . . ?
C2 C3 H3A 119.6 . . ?
C4 C3 H3A 119.6 . . ?
C1 N4 N3 106.1(12) . . ?
C1 N4 Ag3 126.1(11) . . ?
N3 N4 Ag3 126.5(10) . . ?
C5 C4 C3 118.3(15) . . ?
C5 C4 H4A 120.8 . . ?
C3 C4 H4A 120.8 . . ?
C4 C5 C6 122.1(15) . . ?
C4 C5 C8 117.9(14) . . ?
C6 C5 C8 119.9(14) . . ?
C15 N5 C9 106.1(14) . . ?
C15 N5 C8 129.4(15) . . ?
C9 N5 C8 123.9(14) . . ?
C5 C6 C7 119.1(15) . . ?
C5 C6 H6A 120.5 . . ?
C7 C6 H6A 120.5 . . ?
C15 N6 C14 108.2(14) . . ?
C15 N6 Ag3 114.9(11) . 2_839 ?
C14 N6 Ag3 136.4(11) . 2_839 ?
C2 C7 C6 120.5(15) . . ?
C2 C7 H7A 119.7 . . ?
C6 C7 H7A 119.7 . . ?
C16 N7 C20 116.4(16) . . ?
C16 N7 Ag3 112.2(12) . 2_839 ?
C20 N7 Ag3 126.8(12) . 2_839 ?
C21 N8 N9 107.4(13) . . ?
C21 N8 Ag2 128.0(11) . . ?
N9 N8 Ag2 123.0(10) . . ?
N10 N9 N8 107.5(12) . . ?
N9 N10 N11 109.7(12) . . ?
N9 N10 Ag6 127.5(11) . 2_748 ?
N11 N10 Ag6 122.7(10) . 2_748 ?
N8 C21 N11 109.6(13) . . ?
N8 C21 C22 125.6(14) . . ?
N11 C21 C22 124.3(13) . . ?
N7 C20 C19 124.3(17) . . ?
N7 C20 H20A 117.9 . . ?
C19 C20 H20A 117.9 . . ?
C27 C22 C23 117.8(14) . . ?
C27 C22 C21 120.0(15) . . ?
C23 C22 C21 122.2(14) . . ?
C24 C23 C22 121.0(14) . . ?
C24 C23 H23A 119.5 . . ?
C22 C23 H23A 119.5 . . ?
C25 C24 C23 119.4(14) . . ?
C25 C24 H24A 120.3 . . ?
C23 C24 H24A 120.3 . . ?
C24 C25 C26 121.7(14) . . ?
C24 C25 C28 117.9(13) . . ?
C26 C25 C28 120.3(13) . . ?
C25 C26 C27 118.0(15) . . ?
C25 C26 H26A 121.0 . . ?
C27 C26 H26A 121.0 . . ?
C22 C27 C26 122.0(16) . . ?
C22 C27 H27A 119.0 . . ?
C26 C27 H27A 119.0 . . ?
N12 C28 C25 114.4(12) . . ?
N12 C28 H28A 108.7 . . ?
C25 C28 H28A 108.7 . . ?
N12 C28 H28B 108.7 . . ?
C25 C28 H28B 108.7 . . ?
H28A C28 H28B 107.6 . . ?
C30 C29 N12 131.5(14) . . ?
C30 C29 C34 122.5(14) . . ?
N12 C29 C34 106.0(13) . . ?
C29 C30 C31 116.6(15) . . ?
C29 C30 H30A 121.7 . . ?
C31 C30 H30A 121.7 . . ?
C30 C31 C32 120.7(15) . . ?
C30 C31 H31A 119.6 . . ?
C32 C31 H31A 119.6 . . ?
C33 C32 C31 121.6(16) . . ?
C33 C32 Ag1 81.8(10) . . ?
C31 C32 Ag1 96.6(11) . . ?
C33 C32 H32A 119.2 . . ?
C31 C32 H32A 119.2 . . ?
Ag1 C32 H32A 91.5 . . ?
C34 C33 C32 118.5(16) . . ?
C34 C33 Ag1 105.8(10) . . ?
C32 C33 Ag1 66.2(9) . . ?
C34 C33 H33A 120.7 . . ?
C32 C33 H33A 120.7 . . ?
Ag1 C33 H33A 97.5 . . ?
C33 C34 N13 132.1(14) . . ?
C33 C34 C29 119.9(14) . . ?
N13 C34 C29 107.9(13) . . ?
N13 C35 N12 112.1(14) . . ?
N13 C35 C36 123.7(14) . . ?
N12 C35 C36 124.2(13) . . ?
N14 C36 C37 124.1(15) . . ?
N14 C36 C35 114.4(14) . . ?
C37 C36 C35 121.1(15) . . ?
C36 C37 C38 119.3(16) . . ?
C36 C37 H37A 120.4 . . ?
C38 C37 H37A 120.4 . . ?
C37 C38 C39 117.7(16) . . ?
C37 C38 H38A 121.2 . . ?
C39 C38 H38A 121.2 . . ?
C40 C39 C38 118.8(16) . . ?
C40 C39 H39A 120.6 . . ?
C38 C39 H39A 120.6 . . ?
N14 C40 C39 123.6(16) . . ?
N14 C40 H40A 118.2 . . ?
C39 C40 H40A 118.2 . . ?
N5 C8 C5 114.6(13) . . ?
N5 C8 H8A 108.6 . . ?
C5 C8 H8A 108.6 . . ?
N5 C8 H8B 108.6 . . ?
C5 C8 H8B 108.6 . . ?
H8A C8 H8B 107.6 . . ?
C10 C9 C14 123.4(16) . . ?
C10 C9 N5 130.7(16) . . ?
C14 C9 N5 105.8(15) . . ?
C11 C10 C9 115.8(17) . . ?
C11 C10 H10A 122.1 . . ?
C9 C10 H10A 122.1 . . ?
C10 C11 C12 122.8(19) . . ?
C10 C11 Ag2 106.4(13) . 1_556 ?
C12 C11 Ag2 60.9(11) . 1_556 ?
C10 C11 H11A 118.6 . . ?
C12 C11 H11A 118.6 . . ?
Ag2 C11 H11A 102.3 1_556 . ?
C21 N11 N10 105.8(12) . . ?
C21 N11 Ag4 125.7(10) . 2_748 ?
N10 N11 Ag4 123.2(10) . 2_748 ?
C13 C12 C11 121.4(18) . . ?
C13 C12 Ag2 92.3(13) . 1_556 ?
C11 C12 Ag2 87.7(12) . 1_556 ?
C13 C12 H12A 119.3 . . ?
C11 C12 H12A 119.3 . . ?
Ag2 C12 H12A 90.0 1_556 . ?
C35 N12 C29 106.5(12) . . ?
C35 N12 C28 129.0(13) . . ?
C29 N12 C28 124.5(12) . . ?
C12 C13 C14 117.7(17) . . ?
C12 C13 H13A 121.1 . . ?
C14 C13 H13A 121.1 . . ?
C35 N13 C34 107.4(13) . . ?
C35 N13 Ag4 123.5(11) . . ?
C34 N13 Ag4 128.7(10) . . ?
N6 C14 C9 108.9(15) . . ?
N6 C14 C13 132.2(16) . . ?
C9 C14 C13 118.9(16) . . ?
C36 N14 C40 116.3(14) . . ?
C36 N14 Ag5 124.6(11) . . ?
C40 N14 Ag5 118.1(11) . . ?
N6 C15 N5 110.9(15) . . ?
N6 C15 C16 123.7(15) . . ?
N5 C15 C16 125.4(16) . . ?
N7 C16 C17 124.3(17) . . ?
N7 C16 C15 112.0(16) . . ?
C17 C16 C15 123.8(16) . . ?
C18 C17 C16 118.2(19) . . ?
C18 C17 H17A 120.9 . . ?
C16 C17 H17A 120.9 . . ?
C17 C18 C19 119(2) . . ?
C17 C18 H18A 120.3 . . ?
C19 C18 H18A 120.3 . . ?
C18 C19 C20 117.4(18) . . ?
C18 C19 H19A 121.3 . . ?
C20 C19 H19A 121.3 . . ?

_refine_diff_density_max         3.106
_refine_diff_density_min         -2.856
_refine_diff_density_rms         0.316



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 993238'
_audit_update_record             
;
2015-05-07 deposited with the CCDC.
2015-05-19 downloaded from the CCDC.
;

# start Validation Reply Form

_vrf_PLAT430_shelx               
;
PROBLEM: Short Inter D...A Contact  N5 ..  N8 .. 2.78 Ang
RESPONSE: there should be strong hydrogen bond between the two
nitrogens. Because of the disorderd nitrogen atom (N5), the 
hydrogen atom has not been added.

;
# end Validation Reply Form

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C40 H31 Ag2 N14 O40 P W12'
_chemical_formula_weight         3800.70

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   14.152(3)
_cell_length_b                   13.751(3)
_cell_length_c                   16.745(3)
_cell_angle_alpha                90
_cell_angle_beta                 93.81(3)
_cell_angle_gamma                90
_cell_volume                     3251.4(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6699
_cell_measurement_theta_min      2.246
_cell_measurement_theta_max      35.119

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.882
_exptl_crystal_F_000             3372
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.090
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    21.848
_shelx_estimated_absorpt_T_min   0.244
_shelx_estimated_absorpt_T_max   0.408
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.088
_exptl_absorpt_correction_T_max  0.301
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   
;
The Rint value before the absorption correction is 0.0271, and the Rint value after 
the absorption correction is 0.0236.
;
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed X-ray tube'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean 15.9737
_diffrn_reflns_number            12870
_diffrn_reflns_av_unetI/netI     0.0304
_diffrn_reflns_av_R_equivalents  0.0236
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.825
_diffrn_reflns_theta_max         25.747
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.983
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.983
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             6116
_reflns_number_gt                5547
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  'Diamond 3.1'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0476P)²+57.8120P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6116
_refine_ls_number_parameters     514
_refine_ls_number_restraints     538
_refine_ls_R_factor_all          0.0474
_refine_ls_R_factor_gt           0.0432
_refine_ls_wR_factor_ref         0.1086
_refine_ls_wR_factor_gt          0.1055
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W -0.02215(4) 1.10493(4) 0.80609(3) 0.03969(13) Uani 1 1 d . . . . .
W2 W -0.19006(4) 1.01966(4) 1.12875(3) 0.04246(13) Uani 1 1 d . . . . .
W3 W 0.00446(4) 1.25894(4) 0.97770(4) 0.04620(14) Uani 1 1 d . U . . .
W4 W -0.02401(4) 0.84683(4) 0.82812(3) 0.04356(14) Uani 1 1 d . . . . .
W5 W -0.21396(4) 0.86857(4) 0.95539(3) 0.04748(15) Uani 1 1 d . . . . .
W6 W -0.21076(4) 1.12689(4) 0.93574(3) 0.04365(14) Uani 1 1 d . . . . .
P1 P 0.0000 1.0000 1.0000 0.0259(7) Uani 1 2 d S . P . .
O18 O -0.0426(11) 0.9002(12) 0.9635(10) 0.039(3) Uani 0.5 1 d . U P . .
O19 O 0.0255(12) 0.9926(12) 0.9151(10) 0.040(3) Uani 0.5 1 d . U P . .
O21 O -0.1081(12) 1.0075(11) 1.0064(10) 0.037(3) Uani 0.5 1 d . U P . .
O22 O -0.0388(12) 1.0818(12) 0.9485(10) 0.040(3) Uani 0.5 1 d . U P . .
Ag1 Ag -0.00629(15) 1.26820(15) 0.61000(13) 0.0494(5) Uani 0.5 1 d . . P A 2
Ag2 Ag 0.04750(18) 1.38142(17) 0.45969(17) 0.0651(7) Uani 0.5 1 d . . P B 1
O16 O -0.0338(7) 0.7764(7) 0.7452(6) 0.053(2) Uani 1 1 d . U . . .
O15 O -0.3142(6) 0.8050(7) 0.9350(6) 0.049(2) Uani 1 1 d . U . . .
O14 O 0.0059(7) 1.3798(6) 0.9657(6) 0.053(2) Uani 1 1 d . U . . .
O13 O -0.3097(7) 1.1878(8) 0.9042(6) 0.055(2) Uani 1 1 d . U . . .
O12 O -0.0492(7) 0.9728(7) 0.7833(7) 0.053(2) Uani 1 1 d . U . . .
O11 O 0.1039(6) 0.8810(7) 0.8325(7) 0.054(2) Uani 1 1 d . U . . .
O10 O -0.2774(8) 1.0290(8) 1.1900(7) 0.063(3) Uani 1 1 d . U . . .
O9 O -0.1453(7) 1.1173(8) 0.8402(7) 0.060(2) Uani 1 1 d . U . . .
O8 O -0.2319(9) 0.9161(7) 1.0602(6) 0.063(2) Uani 1 1 d . U . . .
O7 O -0.2475(9) 0.9942(7) 0.9176(6) 0.062(2) Uani 1 1 d . U . . .
O6 O -0.1072(7) 0.9315(7) 1.1856(7) 0.059(2) Uani 1 1 d . U . . .
O5 O -0.1261(7) 1.2291(8) 0.9663(7) 0.059(2) Uani 1 1 d . U . . .
O4 O 0.0125(7) 1.2146(8) 0.8714(7) 0.061(2) Uani 1 1 d . U . . .
O3 O -0.2326(9) 1.1068(8) 1.0458(6) 0.064(2) Uani 1 1 d . U . . .
O2 O 0.0041(7) 0.7545(10) 0.9093(7) 0.072(3) Uani 1 1 d . U . . .
O1 O -0.1496(8) 0.8473(9) 0.8614(7) 0.070(2) Uani 1 1 d . U . . .
O20 O -0.0348(8) 1.1563(8) 0.7140(6) 0.062(3) Uani 1 1 d . U . . .
O17 O 0.1351(8) 1.2283(10) 0.9937(7) 0.072(3) Uani 1 1 d . U . . .
C7 C 0.0882(4) 1.1302(7) 0.4827(4) 0.050(3) Uani 1 1 d DG . . . .
N1 N 0.1159(6) 1.1822(6) 0.5537(5) 0.060(3) Uani 1 1 d G . . . .
C5 C 0.2058(6) 1.1467(7) 0.5831(4) 0.056(4) Uani 1 1 d G . . . .
C6 C 0.2337(5) 1.0729(6) 0.5303(5) 0.053(3) Uani 1 1 d DG . . . .
N2 N 0.1611(5) 1.0626(6) 0.4682(4) 0.053(3) Uani 1 1 d DG . . . .
C13 C 0.1754(11) 0.9837(11) 0.4140(8) 0.073(5) Uani 1 1 d D U . . .
H13A H 0.1152 0.9673 0.3861 0.088 Uiso 1 1 calc R U . . .
H13B H 0.1969 0.9271 0.4447 0.088 Uiso 1 1 calc R U . . .
C1 C 0.3162(11) 1.0302(13) 0.5467(10) 0.064(4) Uani 1 1 d . . . . .
H1A H 0.3395 0.9838 0.5127 0.076 Uiso 1 1 calc R U . . .
C2 C 0.3667(12) 1.0577(13) 0.6172(11) 0.066(4) Uani 1 1 d . . . . .
H2A H 0.4239 1.0269 0.6315 0.079 Uiso 1 1 calc R U . . .
C3 C 0.3354(14) 1.1277(13) 0.6654(11) 0.071(5) Uani 1 1 d . . . . .
H3A H 0.3726 1.1435 0.7115 0.085 Uiso 1 1 calc R U . . .
C4 C 0.2526(14) 1.1764(11) 0.6506(10) 0.065(4) Uani 1 1 d . . . . .
H4A H 0.2310 1.2248 0.6836 0.078 Uiso 1 1 calc R U . . .
C8 C -0.0044(5) 1.1393(8) 0.4320(5) 0.057(4) Uani 1 1 d DG . . . .
N8 N -0.0457(7) 1.2310(7) 0.4276(7) 0.101(7) Uani 1 1 d G . . . .
C9 C -0.1332(8) 1.2439(8) 0.3861(8) 0.089(6) Uani 1 1 d G U . . .
H9A H -0.1609 1.3052 0.3832 0.107 Uiso 1 1 calc R U . . .
C10 C -0.1794(6) 1.1650(11) 0.3491(8) 0.096(6) Uani 1 1 d G U . . .
H10A H -0.2379 1.1737 0.3213 0.115 Uiso 1 1 calc R U . . .
C11 C -0.1380(8) 1.0733(9) 0.3535(8) 0.098(7) Uani 1 1 d G U . . .
H11A H -0.1689 1.0206 0.3287 0.118 Uiso 1 1 calc R U . . .
C12 C -0.0505(8) 1.0605(6) 0.3949(7) 0.082(6) Uani 1 1 d G . . . .
H12A H -0.0229 0.9991 0.3979 0.098 Uiso 1 1 calc R U . . .
C14 C 0.2452(6) 1.0057(7) 0.3540(5) 0.049(3) Uani 1 1 d G . . . .
C15 C 0.2944(7) 0.9246(5) 0.3297(6) 0.059(4) Uani 1 1 d G . . . .
H15A H 0.2805 0.8634 0.3496 0.071 Uiso 1 1 calc R U . . .
C16 C 0.3642(7) 0.9348(7) 0.2757(6) 0.071(5) Uani 1 1 d G . . . .
H16A H 0.3971 0.8805 0.2595 0.085 Uiso 1 1 calc R U . . .
C17 C 0.3849(6) 1.0262(8) 0.2460(5) 0.065(5) Uani 1 1 d G . . . .
C18 C 0.3358(7) 1.1074(6) 0.2703(6) 0.060(4) Uani 1 1 d G . . . .
H18A H 0.3496 1.1686 0.2505 0.072 Uiso 1 1 calc R U . . .
C19 C 0.2659(7) 1.0971(6) 0.3243(6) 0.061(4) Uani 1 1 d G . . . .
H19A H 0.2331 1.1515 0.3406 0.073 Uiso 1 1 calc R U . . .
C20 C 0.4529(11) 0.9999(11) 0.1877(8) 0.035(5) Uani 0.5 1 d G U P C 2
N4 N 0.4870(11) 0.9107(8) 0.1580(9) 0.045(5) Uani 0.5 1 d G U P C 2
N5 N 0.5406(11) 0.9320(10) 0.0914(9) 0.042(5) Uani 0.5 1 d G . P C 2
N6 N 0.5396(12) 1.0343(11) 0.0799(9) 0.050(6) Uani 0.5 1 d G U P C 2
N7 N 0.4854(11) 1.0763(8) 0.1395(10) 0.042(5) Uani 0.5 1 d G . P C 2
C21 C 0.4488(10) 1.0667(11) 0.1896(9) 0.032(4) Uani 0.5 1 d G U P C 1
N9 N 0.4810(11) 1.0102(9) 0.1258(9) 0.035(4) Uani 0.5 1 d G . P C 1
N10 N 0.5443(12) 1.0683(13) 0.0839(9) 0.057(7) Uani 0.5 1 d G U P C 1
N11 N 0.5512(12) 1.1606(11) 0.1218(12) 0.060(6) Uani 0.5 1 d G U P C 1
N12 N 0.4922(12) 1.1596(10) 0.1871(11) 0.064(7) Uani 0.5 1 d G . P C 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O20 1.694(10) . ?
W1 O9 1.878(10) . ?
W1 O12 1.891(9) . ?
W1 O6 1.894(10) 3_577 ?
W1 O4 1.908(10) . ?
W1 O22 2.432(17) . ?
W1 O19 2.452(17) . ?
W2 O10 1.664(10) . ?
W2 O6 1.898(10) . ?
W2 O8 1.899(10) . ?
W2 O3 1.901(10) . ?
W2 O11 1.916(9) 3_577 ?
W2 O21 2.426(16) . ?
W2 O19 2.493(16) 3_577 ?
W3 O14 1.675(9) . ?
W3 O5 1.890(10) . ?
W3 O4 1.892(10) . ?
W3 O17 1.898(10) . ?
W3 O2 1.912(11) 3_577 ?
W3 O18 2.446(16) 3_577 ?
W4 O16 1.691(10) . ?
W4 O11 1.866(9) . ?
W4 O2 1.883(10) . ?
W4 O1 1.898(11) . ?
W4 O12 1.911(9) . ?
W4 O18 2.413(17) . ?
W5 O15 1.681(9) . ?
W5 O7 1.889(10) . ?
W5 O1 1.892(12) . ?
W5 O17 1.902(11) 3_577 ?
W5 O8 1.906(11) . ?
W5 O18 2.459(16) . ?
W6 O13 1.686(9) . ?
W6 O5 1.896(10) . ?
W6 O9 1.906(10) . ?
W6 O3 1.909(11) . ?
W6 O7 1.916(10) . ?
W6 O21 2.445(17) . ?
W6 O22 2.507(17) . ?
P1 O19 1.494(17) . ?
P1 O19 1.494(17) 3_577 ?
P1 O22 1.500(17) 3_577 ?
P1 O22 1.500(17) . ?
P1 O21 1.545(17) . ?
P1 O21 1.545(17) 3_577 ?
P1 O18 1.604(18) . ?
P1 O18 1.604(18) 3_577 ?
O18 O19 1.82(2) . ?
O18 W3 2.446(16) 3_577 ?
O19 O22 1.65(2) . ?
O19 O21 1.70(2) 3_577 ?
O19 W2 2.493(16) 3_577 ?
O21 O19 1.70(2) 3_577 ?
O21 O22 1.75(2) . ?
Ag1 N7 2.20(11) 4_586 ?
Ag1 N1 2.345(7) . ?
Ag1 O20 2.379(10) . ?
Ag2 N10 2.20(12) 4_586 ?
Ag2 N9 2.30(9) 2 ?
Ag2 O13 2.470(11) 4_685 ?
Ag2 N8 2.493(9) . ?
O13 Ag2 2.470(11) 4_586 ?
O11 W2 1.916(9) 3_577 ?
O6 W1 1.894(10) 3_577 ?
O2 W3 1.912(11) 3_577 ?
O17 W5 1.902(11) 3_577 ?
C7 N1 1.4200 . ?
C7 N2 1.4200 . ?
C7 C8 1.519(5) . ?
N1 C5 1.4200 . ?
C5 C4 1.335(17) . ?
C5 C6 1.4200 . ?
C6 C1 1.319(19) . ?
C6 N2 1.4200 . ?
N2 C13 1.438(8) . ?
C13 C14 1.487(18) . ?
C1 C2 1.39(2) . ?
C2 C3 1.35(2) . ?
C3 C4 1.36(3) . ?
C8 N8 1.3900 . ?
C8 C12 1.3900 . ?
N8 C9 1.3900 . ?
C9 C10 1.3900 . ?
C10 C11 1.3900 . ?
C11 C12 1.3900 . ?
C14 C15 1.3900 . ?
C14 C19 1.3900 . ?
C15 C16 1.3900 . ?
C16 C17 1.3900 . ?
C17 C18 1.3900 . ?
C17 C21 1.460(13) . ?
C17 C20 1.461(12) . ?
C18 C19 1.3900 . ?
C20 N7 1.4200 . ?
C20 N4 1.4200 . ?
N4 N5 1.4200 . ?
N5 N6 1.4200 . ?
N6 N7 1.4200 . ?
N7 Ag1 2.200(12) 4_685 ?
C21 N9 1.4200 . ?
C21 N12 1.4200 . ?
N9 N10 1.4200 . ?
N9 Ag2 2.296(12) 2_545 ?
N10 N11 1.4200 . ?
N10 Ag2 2.195(16) 4_685 ?
N11 N12 1.4200 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O20 W1 O9 101.2(6) . . ?
O20 W1 O12 102.1(5) . . ?
O9 W1 O12 88.2(4) . . ?
O20 W1 O6 102.7(6) . 3_577 ?
O9 W1 O6 156.0(5) . 3_577 ?
O12 W1 O6 86.7(4) . 3_577 ?
O20 W1 O4 101.5(5) . . ?
O9 W1 O4 87.9(4) . . ?
O12 W1 O4 156.4(5) . . ?
O6 W1 O4 87.5(4) 3_577 . ?
O20 W1 O22 159.2(6) . . ?
O9 W1 O22 64.0(5) . . ?
O12 W1 O22 92.3(5) . . ?
O6 W1 O22 92.8(5) 3_577 . ?
O4 W1 O22 65.1(5) . . ?
O20 W1 O19 161.3(6) . . ?
O9 W1 O19 92.6(5) . . ?
O12 W1 O19 65.6(5) . . ?
O6 W1 O19 64.0(5) 3_577 . ?
O4 W1 O19 91.4(6) . . ?
O22 W1 O19 39.4(6) . . ?
O10 W2 O6 101.5(5) . . ?
O10 W2 O8 102.5(6) . . ?
O6 W2 O8 88.9(5) . . ?
O10 W2 O3 100.9(6) . . ?
O6 W2 O3 157.5(5) . . ?
O8 W2 O3 87.7(4) . . ?
O10 W2 O11 102.6(5) . 3_577 ?
O6 W2 O11 85.9(4) . 3_577 ?
O8 W2 O11 154.9(5) . 3_577 ?
O3 W2 O11 87.8(4) . 3_577 ?
O10 W2 O21 160.5(6) . . ?
O6 W2 O21 93.7(5) . . ?
O8 W2 O21 65.5(5) . . ?
O3 W2 O21 64.7(6) . . ?
O11 W2 O21 90.3(5) 3_577 . ?
O10 W2 O19 159.1(6) . 3_577 ?
O6 W2 O19 63.0(5) . 3_577 ?
O8 W2 O19 91.8(6) . 3_577 ?
O3 W2 O19 94.8(6) . 3_577 ?
O11 W2 O19 64.0(5) 3_577 3_577 ?
O21 W2 O19 40.4(6) . 3_577 ?
O14 W3 O5 102.9(5) . . ?
O14 W3 O4 101.8(5) . . ?
O5 W3 O4 87.4(4) . . ?
O14 W3 O17 102.6(6) . . ?
O5 W3 O17 154.5(6) . . ?
O4 W3 O17 86.7(5) . . ?
O14 W3 O2 102.5(5) . 3_577 ?
O5 W3 O2 87.3(5) . 3_577 ?
O4 W3 O2 155.6(6) . 3_577 ?
O17 W3 O2 87.9(4) . 3_577 ?
O14 W3 O18 158.8(6) . 3_577 ?
O5 W3 O18 92.0(5) . 3_577 ?
O4 W3 O18 93.7(5) . 3_577 ?
O17 W3 O18 63.7(5) . 3_577 ?
O2 W3 O18 62.7(6) 3_577 3_577 ?
O16 W4 O11 101.7(5) . . ?
O16 W4 O2 102.1(6) . . ?
O11 W4 O2 89.1(5) . . ?
O16 W4 O1 102.5(6) . . ?
O11 W4 O1 155.8(5) . . ?
O2 W4 O1 87.0(4) . . ?
O16 W4 O12 101.2(5) . . ?
O11 W4 O12 86.7(4) . . ?
O2 W4 O12 156.8(5) . . ?
O1 W4 O12 87.6(5) . . ?
O16 W4 O18 159.6(5) . . ?
O11 W4 O18 93.0(5) . . ?
O2 W4 O18 63.8(6) . . ?
O1 W4 O18 63.9(6) . . ?
O12 W4 O18 93.7(5) . . ?
O15 W5 O7 102.6(5) . . ?
O15 W5 O1 101.4(5) . . ?
O7 W5 O1 89.3(5) . . ?
O15 W5 O17 100.9(5) . 3_577 ?
O7 W5 O17 156.5(6) . 3_577 ?
O1 W5 O17 87.9(5) . 3_577 ?
O15 W5 O8 101.7(5) . . ?
O7 W5 O8 87.0(5) . . ?
O1 W5 O8 156.9(5) . . ?
O17 W5 O8 86.4(5) 3_577 . ?
O15 W5 O18 156.7(5) . . ?
O7 W5 O18 94.7(5) . . ?
O1 W5 O18 63.0(5) . . ?
O17 W5 O18 63.4(5) 3_577 . ?
O8 W5 O18 94.6(6) . . ?
O13 W6 O5 102.3(5) . . ?
O13 W6 O9 102.2(5) . . ?
O5 W6 O9 86.8(4) . . ?
O13 W6 O3 101.0(5) . . ?
O5 W6 O3 89.2(5) . . ?
O9 W6 O3 156.8(5) . . ?
O13 W6 O7 102.3(5) . . ?
O5 W6 O7 155.4(5) . . ?
O9 W6 O7 86.8(5) . . ?
O3 W6 O7 87.4(4) . . ?
O13 W6 O21 160.0(5) . . ?
O5 W6 O21 91.3(5) . . ?
O9 W6 O21 93.1(5) . . ?
O3 W6 O21 64.2(5) . . ?
O7 W6 O21 65.4(5) . . ?
O13 W6 O22 158.6(5) . . ?
O5 W6 O22 64.4(5) . . ?
O9 W6 O22 62.0(5) . . ?
O3 W6 O22 95.8(5) . . ?
O7 W6 O22 91.7(5) . . ?
O21 W6 O22 41.5(5) . . ?
O19 P1 O19 180.0 . 3_577 ?
O19 P1 O22 113.2(9) . 3_577 ?
O19 P1 O22 66.8(9) 3_577 3_577 ?
O19 P1 O22 66.8(9) . . ?
O19 P1 O22 113.2(9) 3_577 . ?
O22 P1 O22 180.0 3_577 . ?
O19 P1 O21 112.0(9) . . ?
O19 P1 O21 68.0(9) 3_577 . ?
O22 P1 O21 109.7(9) 3_577 . ?
O22 P1 O21 70.3(9) . . ?
O19 P1 O21 68.0(9) . 3_577 ?
O19 P1 O21 112.0(9) 3_577 3_577 ?
O22 P1 O21 70.3(9) 3_577 3_577 ?
O22 P1 O21 109.7(9) . 3_577 ?
O21 P1 O21 180.0(12) . 3_577 ?
O19 P1 O18 71.7(9) . . ?
O19 P1 O18 108.3(9) 3_577 . ?
O22 P1 O18 72.0(9) 3_577 . ?
O22 P1 O18 108.0(9) . . ?
O21 P1 O18 74.6(8) . . ?
O21 P1 O18 105.4(8) 3_577 . ?
O19 P1 O18 108.3(9) . 3_577 ?
O19 P1 O18 71.7(9) 3_577 3_577 ?
O22 P1 O18 108.0(9) 3_577 3_577 ?
O22 P1 O18 72.0(9) . 3_577 ?
O21 P1 O18 105.4(8) . 3_577 ?
O21 P1 O18 74.6(8) 3_577 3_577 ?
O18 P1 O18 180.0 . 3_577 ?
P1 O18 O19 51.3(7) . . ?
P1 O18 W4 123.9(8) . . ?
O19 O18 W4 72.5(8) . . ?
P1 O18 W3 123.0(9) . 3_577 ?
O19 O18 W3 134.0(10) . 3_577 ?
W4 O18 W3 94.1(6) . 3_577 ?
P1 O18 W5 121.1(8) . . ?
O19 O18 W5 130.5(10) . . ?
W4 O18 W5 93.6(6) . . ?
W3 O18 W5 93.1(6) 3_577 . ?
P1 O19 O22 56.8(8) . . ?
P1 O19 O21 57.4(8) . 3_577 ?
O22 O19 O21 96.0(12) . 3_577 ?
P1 O19 O18 56.9(8) . . ?
O22 O19 O18 92.7(11) . . ?
O21 O19 O18 90.8(11) 3_577 . ?
P1 O19 W1 126.4(9) . . ?
O22 O19 W1 69.6(8) . . ?
O21 O19 W1 135.8(10) 3_577 . ?
O18 O19 W1 130.1(10) . . ?
P1 O19 W2 125.1(9) . 3_577 ?
O22 O19 W2 134.2(11) . 3_577 ?
O21 O19 W2 67.7(8) 3_577 3_577 ?
O18 O19 W2 128.2(10) . 3_577 ?
W1 O19 W2 92.3(5) . 3_577 ?
P1 O21 O19 54.6(8) . 3_577 ?
P1 O21 O22 53.6(8) . . ?
O19 O21 O22 92.7(11) 3_577 . ?
P1 O21 W2 126.5(9) . . ?
O19 O21 W2 71.9(8) 3_577 . ?
O22 O21 W2 138.0(10) . . ?
P1 O21 W6 124.8(9) . . ?
O19 O21 W6 136.9(10) 3_577 . ?
O22 O21 W6 71.2(8) . . ?
W2 O21 W6 93.5(6) . . ?
P1 O22 O19 56.4(8) . . ?
P1 O22 O21 56.0(8) . . ?
O19 O22 O21 95.5(11) . . ?
P1 O22 W1 127.3(9) . . ?
O19 O22 W1 70.9(8) . . ?
O21 O22 W1 135.4(10) . . ?
P1 O22 W6 123.4(9) . . ?
O19 O22 W6 135.3(11) . . ?
O21 O22 W6 67.4(8) . . ?
W1 O22 W6 92.4(6) . . ?
N7 Ag1 N1 129(2) 4_586 . ?
N7 Ag1 O20 116.8(18) 4_586 . ?
N1 Ag1 O20 97.7(4) . . ?
N10 Ag2 N9 110(3) 4_586 2 ?
N10 Ag2 O13 123(3) 4_586 4_685 ?
N9 Ag2 O13 100(2) 2 4_685 ?
N10 Ag2 N8 115(2) 4_586 . ?
N9 Ag2 N8 116(3) 2 . ?
O13 Ag2 N8 91.9(3) 4_685 . ?
W6 O13 Ag2 112.0(5) . 4_586 ?
W1 O12 W4 139.6(6) . . ?
W4 O11 W2 141.9(6) . 3_577 ?
W1 O9 W6 140.7(7) . . ?
W2 O8 W5 139.4(6) . . ?
W5 O7 W6 139.3(6) . . ?
W1 O6 W2 140.1(7) 3_577 . ?
W3 O5 W6 141.7(6) . . ?
W3 O4 W1 139.9(6) . . ?
W2 O3 W6 137.1(7) . . ?
W4 O2 W3 139.1(7) . 3_577 ?
W5 O1 W4 139.2(7) . . ?
W1 O20 Ag1 157.4(6) . . ?
W3 O17 W5 139.1(7) . 3_577 ?
N1 C7 N2 108.0 . . ?
N1 C7 C8 127.3(7) . . ?
N2 C7 C8 124.6(7) . . ?
C7 N1 C5 108.0 . . ?
C7 N1 Ag1 114.9(5) . . ?
C5 N1 Ag1 134.5(5) . . ?
C4 C5 C6 127.1(11) . . ?
C4 C5 N1 124.9(11) . . ?
C6 C5 N1 108.0 . . ?
C1 C6 N2 134.2(9) . . ?
C1 C6 C5 117.8(9) . . ?
N2 C6 C5 108.0 . . ?
C6 N2 C7 108.0 . . ?
C6 N2 C13 114.3(6) . . ?
C7 N2 C13 137.4(6) . . ?
N2 C13 C14 113.6(12) . . ?
C6 C1 C2 117.0(15) . . ?
C3 C2 C1 122.1(18) . . ?
C2 C3 C4 123.7(17) . . ?
C5 C4 C3 112.2(15) . . ?
N8 C8 C12 120.0 . . ?
N8 C8 C7 116.7(8) . . ?
C12 C8 C7 123.2(8) . . ?
C8 N8 C9 120.0 . . ?
C8 N8 Ag2 121.8(6) . . ?
C9 N8 Ag2 116.3(6) . . ?
N8 C9 C10 120.0 . . ?
C11 C10 C9 120.0 . . ?
C12 C11 C10 120.0 . . ?
C11 C12 C8 120.0 . . ?
C15 C14 C19 120.0 . . ?
C15 C14 C13 113.7(8) . . ?
C19 C14 C13 126.3(8) . . ?
C16 C15 C14 120.0 . . ?
C15 C16 C17 120.0 . . ?
C16 C17 C18 120.0 . . ?
C16 C17 C21 136.9(9) . . ?
C18 C17 C21 103.1(9) . . ?
C16 C17 C20 100.3(9) . . ?
C18 C17 C20 139.4(9) . . ?
C19 C18 C17 120.0 . . ?
C18 C19 C14 120.0 . . ?
N7 C20 N4 108.0 . . ?
N7 C20 C17 116.7(11) . . ?
N4 C20 C17 134.6(11) . . ?
N5 N4 C20 108.0 . . ?
N6 N5 N4 108.0 . . ?
N5 N6 N7 108.0 . . ?
C20 N7 N6 108.0 . . ?
C20 N7 Ag1 150.6(8) . 4_685 ?
N6 N7 Ag1 101.4(8) . 4_685 ?
N9 C21 N12 108.0 . . ?
N9 C21 C17 121.5(11) . . ?
N12 C21 C17 130.5(11) . . ?
C21 N9 N10 108.0 . . ?
C21 N9 Ag2 147.0(8) . 2_545 ?
N10 N9 Ag2 102.5(8) . 2_545 ?
N11 N10 N9 108.0 . . ?
N11 N10 Ag2 97.9(10) . 4_685 ?
N9 N10 Ag2 134.3(10) . 4_685 ?
N12 N11 N10 108.0 . . ?
N11 N12 C21 108.0 . . ?

_refine_diff_density_max         2.492
_refine_diff_density_min         -1.521
_refine_diff_density_rms         0.260



