# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_audit_block_doi                 10.5517/cc14dvq3
_database_code_depnum_ccdc_archive 'CCDC 1055045'
_audit_update_record             
;
2015-03-19 deposited with the CCDC.
2015-07-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C38.50 H33 Cl3 N2 Pt Si2'
_chemical_formula_weight         881.29

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   7.1264(4)
_cell_length_b                   38.160(2)
_cell_length_c                   14.3796(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.337(4)
_cell_angle_gamma                90.00
_cell_volume                     3886.6(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9335
_cell_measurement_theta_min      2.56
_cell_measurement_theta_max      25.63

_exptl_crystal_description       needle
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.506
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1740
_exptl_absorpt_coefficient_mu    3.906
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.687
_exptl_absorpt_correction_T_max  0.738
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            30480
_diffrn_reflns_av_R_equivalents  0.0373
_diffrn_reflns_av_sigmaI/netI    0.0292
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -45
_diffrn_reflns_limit_k_max       45
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.13
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6824
_reflns_number_gt                5668
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0555P)²+5.8947P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6824
_refine_ls_number_parameters     450
_refine_ls_number_restraints     56
_refine_ls_R_factor_all          0.0484
_refine_ls_R_factor_gt           0.0371
_refine_ls_wR_factor_ref         0.1029
_refine_ls_wR_factor_gt          0.0974
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_restrained_S_all      1.124
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.75993(3) 0.982565(6) 0.082536(16) 0.04481(10) Uani 1 1 d . . .
Si1 Si 0.8352(3) 0.76207(5) 0.02054(15) 0.0637(5) Uani 1 1 d . . .
Si2 Si 0.5939(3) 1.16416(5) -0.22181(15) 0.0627(5) Uani 1 1 d . . .
Cl2 Cl 0.6242(5) 1.20684(7) 0.2752(3) 0.1428(12) Uani 1 1 d . . .
C17 C 0.7640(8) 0.98182(15) -0.1177(4) 0.0444(13) Uani 1 1 d . . .
N1 N 0.7866(6) 0.93807(12) 0.0011(3) 0.0443(11) Uani 1 1 d . . .
C16 C 0.7858(8) 0.94578(15) -0.0919(4) 0.0452(13) Uani 1 1 d . . .
C23 C 0.7810(8) 0.95742(16) 0.2012(5) 0.0510(15) Uani 1 1 d . . .
C21 C 0.3396(12) 1.1676(2) -0.2602(6) 0.085(2) Uani 1 1 d . . .
H21A H 0.3080 1.1527 -0.3135 0.128 Uiso 1 1 calc R . .
H21B H 0.3087 1.1914 -0.2769 0.128 Uiso 1 1 calc R . .
H21C H 0.2693 1.1604 -0.2102 0.128 Uiso 1 1 calc R . .
C14 C 0.7105(8) 1.05069(16) -0.1645(5) 0.0518(15) Uani 1 1 d . . .
C24 C 0.7972(10) 0.94043(17) 0.2717(5) 0.0599(17) Uani 1 1 d . . .
C10 C 0.8036(11) 0.93091(18) -0.2556(5) 0.0663(18) Uani 1 1 d . . .
H10 H 0.8202 0.9142 -0.3010 0.080 Uiso 1 1 calc R . .
C13 C 0.7372(9) 1.02717(17) -0.2336(5) 0.0580(17) Uani 1 1 d . . .
H13 H 0.7396 1.0347 -0.2950 0.070 Uiso 1 1 calc R . .
C9 C 0.8043(9) 0.92026(16) -0.1596(5) 0.0524(15) Uani 1 1 d . . .
C12 C 0.7608(9) 0.99196(16) -0.2114(5) 0.0508(14) Uani 1 1 d . . .
C25 C 0.8114(10) 0.91929(17) 0.3545(4) 0.0552(16) Uani 1 1 d . . .
C31 C 0.7320(8) 1.02752(17) 0.1433(4) 0.0502(14) Uani 1 1 d . . .
C4 C 0.8301(10) 0.81019(17) 0.0067(5) 0.0626(17) Uani 1 1 d . . .
C32 C 0.7136(9) 1.05719(18) 0.1702(5) 0.0576(16) Uani 1 1 d . . .
C18 C 0.6820(10) 1.08729(17) -0.1825(5) 0.0595(16) Uani 1 1 d . . .
C8 C 0.8198(9) 0.88543(16) -0.1298(5) 0.0580(16) Uani 1 1 d . . .
H8 H 0.8315 0.8677 -0.1731 0.070 Uiso 1 1 calc R . .
C11 C 0.7791(10) 0.96507(19) -0.2810(5) 0.0647(18) Uani 1 1 d . . .
H11 H 0.7741 0.9713 -0.3438 0.078 Uiso 1 1 calc R . .
C7 C 0.8179(9) 0.87721(15) -0.0367(5) 0.0531(15) Uani 1 1 d . . .
C6 C 0.8025(9) 0.90486(16) 0.0267(5) 0.0543(15) Uani 1 1 d . . .
H6 H 0.8035 0.8995 0.0899 0.065 Uiso 1 1 calc R . .
C30 C 0.6646(12) 0.9170(2) 0.4097(5) 0.074(2) Uani 1 1 d . . .
H30 H 0.5575 0.9306 0.3944 0.089 Uiso 1 1 calc R . .
C26 C 0.9690(11) 0.8990(2) 0.3813(5) 0.072(2) Uani 1 1 d . . .
H26 H 1.0720 0.9002 0.3470 0.087 Uiso 1 1 calc R . .
C33 C 0.6931(9) 1.09313(17) 0.1965(5) 0.0553(16) Uani 1 1 d . . .
C2 C 0.6071(14) 0.7447(2) -0.0340(8) 0.113(4) Uani 1 1 d . . .
H2A H 0.5069 0.7534 -0.0009 0.169 Uiso 1 1 calc R . .
H2B H 0.6091 0.7196 -0.0313 0.169 Uiso 1 1 calc R . .
H2C H 0.5869 0.7521 -0.0981 0.169 Uiso 1 1 calc R . .
C36 C 0.6512(12) 1.1628(2) 0.2446(7) 0.081(2) Uani 1 1 d . . .
C29 C 0.6712(13) 0.8952(2) 0.4863(5) 0.079(2) Uani 1 1 d . . .
H29 H 0.5698 0.8940 0.5217 0.095 Uiso 1 1 calc R . .
C5 C 0.8254(10) 0.84121(18) -0.0086(5) 0.0620(17) Uani 1 1 d . . .
C1 C 0.8730(16) 0.7513(2) 0.1460(6) 0.099(3) Uani 1 1 d . . .
H1A H 0.9790 0.7643 0.1750 0.149 Uiso 1 1 calc R . .
H1B H 0.8976 0.7267 0.1535 0.149 Uiso 1 1 calc R . .
H1C H 0.7622 0.7573 0.1749 0.149 Uiso 1 1 calc R . .
C27 C 0.9765(12) 0.8769(2) 0.4579(5) 0.076(2) Uani 1 1 d . . .
H27 H 1.0828 0.8631 0.4742 0.092 Uiso 1 1 calc R . .
C19 C 0.6502(10) 1.11779(19) -0.1981(5) 0.0675(19) Uani 1 1 d . . .
C22 C 0.7348(15) 1.1795(2) -0.3135(8) 0.114(4) Uani 1 1 d . . .
H22A H 0.8660 1.1749 -0.2948 0.171 Uiso 1 1 calc R . .
H22B H 0.7162 1.2042 -0.3227 0.171 Uiso 1 1 calc R . .
H22C H 0.6958 1.1673 -0.3708 0.171 Uiso 1 1 calc R . .
C37 C 0.6699(14) 1.1548(2) 0.1538(7) 0.087(2) Uani 1 1 d . . .
H37 H 0.6671 1.1722 0.1084 0.104 Uiso 1 1 calc R . .
C38 C 0.6930(12) 1.1200(2) 0.1311(6) 0.079(2) Uani 1 1 d . . .
H38 H 0.7092 1.1143 0.0696 0.095 Uiso 1 1 calc R . .
C20 C 0.6538(14) 1.1889(3) -0.1114(7) 0.102(3) Uani 1 1 d . . .
H20A H 0.5932 1.1782 -0.0623 0.154 Uiso 1 1 calc R . .
H20B H 0.6111 1.2127 -0.1198 0.154 Uiso 1 1 calc R . .
H20C H 0.7881 1.1887 -0.0951 0.154 Uiso 1 1 calc R . .
C28 C 0.8283(12) 0.87549(18) 0.5093(5) 0.0668(19) Uani 1 1 d . . .
C35 C 0.6531(14) 1.1381(2) 0.3114(7) 0.092(3) Uani 1 1 d . . .
H35 H 0.6414 1.1444 0.3730 0.110 Uiso 1 1 calc R . .
C3 C 1.0308(15) 0.7444(2) -0.0413(8) 0.117(4) Uani 1 1 d . . .
H3A H 1.0167 0.7525 -0.1049 0.175 Uiso 1 1 calc R . .
H3B H 1.0269 0.7192 -0.0406 0.175 Uiso 1 1 calc R . .
H3C H 1.1495 0.7523 -0.0104 0.175 Uiso 1 1 calc R . .
Cl1 Cl 0.8333(4) 0.84646(6) 0.60327(15) 0.0994(8) Uani 1 1 d . . .
N2 N 0.7436(6) 1.00521(13) -0.0487(4) 0.0438(11) Uani 1 1 d . . .
C15 C 0.7172(8) 1.03867(17) -0.0718(5) 0.0519(15) Uani 1 1 d . . .
H15 H 0.7026 1.0548 -0.0248 0.062 Uiso 1 1 calc R . .
C34 C 0.6725(12) 1.1031(2) 0.2881(6) 0.080(2) Uani 1 1 d . . .
H34 H 0.6717 1.0860 0.3342 0.097 Uiso 1 1 calc R . .
Cl4 Cl 0.0000 1.0000 0.5000 0.258(4) Uani 1 2 d SDU . .
C01 C 0.1213(16) 0.9583(3) 0.5276(9) 0.020(3) Uiso 0.319(5) 1 d PDU A 1
H01A H 0.0941 0.9490 0.5874 0.024 Uiso 0.319(5) 1 calc PR A 1
H01B H 0.0913 0.9409 0.4790 0.024 Uiso 0.319(5) 1 calc PR A 1
Cl3 Cl 0.3320(18) 0.9717(4) 0.5308(8) 0.159(4) Uani 0.319(5) 1 d PDU A 1
C01' C 0.230(2) 0.9933(12) 0.570(2) 0.076(5) Uani 0.181(5) 1 d PDU A 2
H01C H 0.2294 1.0082 0.6242 0.091 Uiso 0.181(5) 1 calc PR A 2
H01D H 0.2293 0.9694 0.5921 0.091 Uiso 0.181(5) 1 calc PR A 2
Cl3' Cl 0.4621(18) 0.9997(3) 0.5280(7) 0.078(4) Uani 0.181(5) 1 d PDU . 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C31 1.945(7) . ?
Pt1 C23 1.949(6) . ?
Pt1 N2 2.067(5) . ?
Pt1 N1 2.084(5) . ?
Si1 C1 1.841(9) . ?
Si1 C4 1.847(7) . ?
Si1 C2 1.848(9) . ?
Si1 C3 1.861(9) . ?
Si2 C19 1.838(7) . ?
Si2 C22 1.838(9) . ?
Si2 C21 1.840(9) . ?
Si2 C20 1.855(9) . ?
Cl2 C36 1.752(8) . ?
C17 N2 1.354(8) . ?
C17 C12 1.399(9) . ?
C17 C16 1.429(8) . ?
N1 C6 1.321(7) . ?
N1 C16 1.368(7) . ?
C16 C9 1.394(9) . ?
C23 C24 1.198(9) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C14 C13 1.368(9) . ?
C14 C15 1.405(8) . ?
C14 C18 1.431(8) . ?
C24 C25 1.432(9) . ?
C10 C11 1.360(10) . ?
C10 C9 1.438(9) . ?
C10 H10 0.9300 . ?
C13 C12 1.387(9) . ?
C13 H13 0.9300 . ?
C9 C8 1.397(9) . ?
C12 C11 1.450(10) . ?
C25 C30 1.384(10) . ?
C25 C26 1.384(10) . ?
C31 C32 1.208(9) . ?
C4 C5 1.203(9) . ?
C32 C33 1.434(9) . ?
C18 C19 1.202(9) . ?
C8 C7 1.377(9) . ?
C8 H8 0.9300 . ?
C11 H11 0.9300 . ?
C7 C6 1.407(9) . ?
C7 C5 1.431(9) . ?
C6 H6 0.9300 . ?
C30 C29 1.377(10) . ?
C30 H30 0.9300 . ?
C26 C27 1.383(10) . ?
C26 H26 0.9300 . ?
C33 C38 1.390(10) . ?
C33 C34 1.394(10) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C36 C35 1.346(12) . ?
C36 C37 1.362(12) . ?
C29 C28 1.359(11) . ?
C29 H29 0.9300 . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C27 C28 1.355(10) . ?
C27 H27 0.9300 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C37 C38 1.381(10) . ?
C37 H37 0.9300 . ?
C38 H38 0.9300 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C28 Cl1 1.745(7) . ?
C35 C34 1.389(11) . ?
C35 H35 0.9300 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
N2 C15 1.328(8) . ?
C15 H15 0.9300 . ?
C34 H34 0.9300 . ?
Cl4 C01 1.833(11) . ?
Cl4 C01 1.833(11) 3_576 ?
Cl4 C01' 1.84(2) . ?
Cl4 C01' 1.84(2) 3_576 ?
C01 Cl3 1.582(15) . ?
C01 H01A 0.9700 . ?
C01 H01B 0.9700 . ?
C01' Cl3' 1.834(19) . ?
C01' H01C 0.9700 . ?
C01' H01D 0.9700 . ?
Cl3' Cl3' 1.02(2) 3_676 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C31 Pt1 C23 92.4(3) . . ?
C31 Pt1 N2 92.5(2) . . ?
C23 Pt1 N2 175.0(2) . . ?
C31 Pt1 N1 172.5(2) . . ?
C23 Pt1 N1 95.1(2) . . ?
N2 Pt1 N1 80.02(18) . . ?
C1 Si1 C4 109.0(4) . . ?
C1 Si1 C2 111.3(5) . . ?
C4 Si1 C2 107.7(4) . . ?
C1 Si1 C3 110.6(5) . . ?
C4 Si1 C3 108.4(4) . . ?
C2 Si1 C3 109.7(5) . . ?
C19 Si2 C22 108.3(4) . . ?
C19 Si2 C21 108.2(4) . . ?
C22 Si2 C21 111.1(5) . . ?
C19 Si2 C20 107.9(4) . . ?
C22 Si2 C20 111.1(5) . . ?
C21 Si2 C20 110.3(4) . . ?
N2 C17 C12 122.1(5) . . ?
N2 C17 C16 117.5(5) . . ?
C12 C17 C16 120.4(6) . . ?
C6 N1 C16 118.1(5) . . ?
C6 N1 Pt1 129.4(4) . . ?
C16 N1 Pt1 112.5(4) . . ?
N1 C16 C9 122.8(5) . . ?
N1 C16 C17 116.7(5) . . ?
C9 C16 C17 120.4(6) . . ?
C24 C23 Pt1 176.5(6) . . ?
Si2 C21 H21A 109.5 . . ?
Si2 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si2 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C13 C14 C15 118.8(6) . . ?
C13 C14 C18 122.5(6) . . ?
C15 C14 C18 118.7(6) . . ?
C23 C24 C25 178.0(8) . . ?
C11 C10 C9 121.0(6) . . ?
C11 C10 H10 119.5 . . ?
C9 C10 H10 119.5 . . ?
C14 C13 C12 119.4(6) . . ?
C14 C13 H13 120.3 . . ?
C12 C13 H13 120.3 . . ?
C16 C9 C8 117.4(6) . . ?
C16 C9 C10 118.9(6) . . ?
C8 C9 C10 123.7(6) . . ?
C13 C12 C17 118.6(6) . . ?
C13 C12 C11 123.0(6) . . ?
C17 C12 C11 118.4(6) . . ?
C30 C25 C26 116.5(6) . . ?
C30 C25 C24 121.6(6) . . ?
C26 C25 C24 121.8(6) . . ?
C32 C31 Pt1 172.0(6) . . ?
C5 C4 Si1 175.7(7) . . ?
C31 C32 C33 176.5(7) . . ?
C19 C18 C14 177.3(7) . . ?
C7 C8 C9 120.4(6) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 H8 119.8 . . ?
C10 C11 C12 120.7(6) . . ?
C10 C11 H11 119.6 . . ?
C12 C11 H11 119.6 . . ?
C8 C7 C6 118.0(6) . . ?
C8 C7 C5 119.3(6) . . ?
C6 C7 C5 122.7(6) . . ?
N1 C6 C7 123.3(6) . . ?
N1 C6 H6 118.4 . . ?
C7 C6 H6 118.4 . . ?
C29 C30 C25 122.4(7) . . ?
C29 C30 H30 118.8 . . ?
C25 C30 H30 118.8 . . ?
C27 C26 C25 121.4(7) . . ?
C27 C26 H26 119.3 . . ?
C25 C26 H26 119.3 . . ?
C38 C33 C34 116.5(7) . . ?
C38 C33 C32 121.2(6) . . ?
C34 C33 C32 122.3(7) . . ?
Si1 C2 H2A 109.5 . . ?
Si1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C35 C36 C37 122.1(8) . . ?
C35 C36 Cl2 119.0(7) . . ?
C37 C36 Cl2 118.8(7) . . ?
C28 C29 C30 118.9(7) . . ?
C28 C29 H29 120.6 . . ?
C30 C29 H29 120.6 . . ?
C4 C5 C7 174.1(8) . . ?
Si1 C1 H1A 109.5 . . ?
Si1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C28 C27 C26 119.6(8) . . ?
C28 C27 H27 120.2 . . ?
C26 C27 H27 120.2 . . ?
C18 C19 Si2 178.2(7) . . ?
Si2 C22 H22A 109.5 . . ?
Si2 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si2 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C36 C37 C38 118.1(8) . . ?
C36 C37 H37 121.0 . . ?
C38 C37 H37 121.0 . . ?
C37 C38 C33 122.7(8) . . ?
C37 C38 H38 118.7 . . ?
C33 C38 H38 118.7 . . ?
Si2 C20 H20A 109.5 . . ?
Si2 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si2 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C27 C28 C29 121.1(7) . . ?
C27 C28 Cl1 119.8(6) . . ?
C29 C28 Cl1 119.0(6) . . ?
C36 C35 C34 119.7(8) . . ?
C36 C35 H35 120.1 . . ?
C34 C35 H35 120.1 . . ?
Si1 C3 H3A 109.5 . . ?
Si1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C15 N2 C17 118.3(5) . . ?
C15 N2 Pt1 128.5(4) . . ?
C17 N2 Pt1 113.2(4) . . ?
N2 C15 C14 122.7(6) . . ?
N2 C15 H15 118.6 . . ?
C14 C15 H15 118.6 . . ?
C35 C34 C33 120.9(8) . . ?
C35 C34 H34 119.5 . . ?
C33 C34 H34 119.5 . . ?
C01 Cl4 C01 180.000(7) . 3_576 ?
C01 Cl4 C01' 52.5(14) . . ?
C01 Cl4 C01' 127.5(14) 3_576 . ?
C01 Cl4 C01' 127.5(14) . 3_576 ?
C01 Cl4 C01' 52.5(14) 3_576 3_576 ?
C01' Cl4 C01' 180.000(9) . 3_576 ?
Cl3 C01 Cl4 98.6(7) . . ?
Cl3 C01 H01A 112.1 . . ?
Cl4 C01 H01A 112.1 . . ?
Cl3 C01 H01B 112.1 . . ?
Cl4 C01 H01B 112.1 . . ?
H01A C01 H01B 109.7 . . ?
Cl3' C01' Cl4 125.8(16) . . ?
Cl3' C01' H01C 105.9 . . ?
Cl4 C01' H01C 105.9 . . ?
Cl3' C01' H01D 105.9 . . ?
Cl4 C01' H01D 105.9 . . ?
H01C C01' H01D 106.2 . . ?
Cl3' Cl3' C01' 147(2) 3_676 . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.803
_refine_diff_density_min         -1.088
_refine_diff_density_rms         0.100
