# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_audit_block_doi                 10.5517/cc14dvr4
_database_code_depnum_ccdc_archive 'CCDC 1055046'
_audit_update_record             
;
2015-03-19 deposited with the CCDC.
2015-07-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C41 H35 Cl2 N2 Pt Si2'
_chemical_formula_weight         877.88

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   20.638(3)
_cell_length_b                   10.9657(16)
_cell_length_c                   19.312(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 103.687(7)
_cell_angle_gamma                90.00
_cell_volume                     4246.3(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    6344
_cell_measurement_theta_min      2.15
_cell_measurement_theta_max      20.89

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.373
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1740
_exptl_absorpt_coefficient_mu    3.514
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.532
_exptl_absorpt_correction_T_max  0.708
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            25213
_diffrn_reflns_av_R_equivalents  0.0816
_diffrn_reflns_av_sigmaI/netI    0.1141
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         2.03
_diffrn_reflns_theta_max         24.39
_reflns_number_total             6879
_reflns_number_gt                3990
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0944P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6879
_refine_ls_number_parameters     489
_refine_ls_number_restraints     186
_refine_ls_R_factor_all          0.1326
_refine_ls_R_factor_gt           0.0691
_refine_ls_wR_factor_ref         0.1780
_refine_ls_wR_factor_gt          0.1468
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N2 N 0.5671(3) 0.3217(6) 0.5336(3) 0.0424(18) Uani 1 1 d . . .
Pt1 Pt 0.499484(16) 0.37716(3) 0.441592(14) 0.04479(12) Uani 1 1 d . . .
N1 N 0.4335(3) 0.3182(6) 0.5006(3) 0.0450(19) Uani 1 1 d . . .
C23 C 0.4313(4) 0.4255(8) 0.3585(4) 0.052(2) Uani 1 1 d . . .
C16 C 0.4648(4) 0.2762(7) 0.5663(4) 0.043(2) Uani 1 1 d . . .
C25 C 0.3429(5) 0.5060(9) 0.2440(4) 0.067(3) Uani 1 1 d . . .
C14 C 0.6729(4) 0.2787(8) 0.6140(4) 0.054(3) Uani 1 1 d . A .
C17 C 0.5358(4) 0.2773(6) 0.5838(4) 0.041(2) Uani 1 1 d . . .
C12 C 0.5718(5) 0.2342(7) 0.6504(4) 0.051(3) Uani 1 1 d . . .
C32 C 0.6096(4) 0.4602(8) 0.3633(4) 0.050(2) Uani 1 1 d . . .
C9 C 0.4298(5) 0.2310(7) 0.6146(4) 0.053(3) Uani 1 1 d . . .
C15 C 0.6322(4) 0.3234(8) 0.5490(4) 0.052(2) Uani 1 1 d . . .
H15A H 0.6532 0.3556 0.5154 0.063 Uiso 1 1 calc R . .
C6 C 0.3673(5) 0.3170(8) 0.4826(4) 0.060(3) Uani 1 1 d . . .
H6A H 0.3458 0.3471 0.4381 0.072 Uiso 1 1 calc R . .
C7 C 0.3280(5) 0.2726(9) 0.5276(4) 0.063(3) Uani 1 1 d . . .
C31 C 0.5662(4) 0.4286(8) 0.3919(4) 0.052(3) Uani 1 1 d . . .
Cl1 Cl 0.2103(3) 0.6699(6) 0.0478(3) 0.304(3) Uani 1 1 d . . .
C13 C 0.6397(5) 0.2339(8) 0.6642(4) 0.064(3) Uani 1 1 d . . .
H13A H 0.6643 0.2037 0.7075 0.077 Uiso 1 1 calc R . .
C5 C 0.2553(6) 0.2712(10) 0.5062(5) 0.085(4) Uani 1 1 d . . .
C33 C 0.6554(5) 0.5061(9) 0.3249(5) 0.067(3) Uani 1 1 d . . .
Cl2 Cl 0.7962(3) 0.6689(7) 0.2027(4) 0.359(3) Uani 1 1 d . . .
C24 C 0.3889(5) 0.4583(8) 0.3078(4) 0.058(3) Uani 1 1 d . . .
Si2 Si 0.8937(2) 0.2820(5) 0.6821(2) 0.188(3) Uani 1 1 d D . .
C29 C 0.3287(9) 0.6326(10) 0.1374(6) 0.126(6) Uani 1 1 d . . .
H29A H 0.3461 0.6834 0.1078 0.151 Uiso 1 1 calc R . .
C18 C 0.7451(6) 0.2854(11) 0.6293(5) 0.083(4) Uani 1 1 d . . .
C8 C 0.3601(5) 0.2308(7) 0.5933(4) 0.061(3) Uani 1 1 d . . .
H8A H 0.3353 0.2020 0.6244 0.073 Uiso 1 1 calc R . .
C30 C 0.3687(6) 0.5786(9) 0.1971(5) 0.078(3) Uani 1 1 d . . .
H30A H 0.4146 0.5908 0.2064 0.094 Uiso 1 1 calc R . .
C35 C 0.6754(8) 0.6314(11) 0.2280(7) 0.142(5) Uani 1 1 d . . .
H35A H 0.6590 0.6831 0.1897 0.171 Uiso 1 1 calc R . .
C34 C 0.6350(7) 0.5815(10) 0.2651(5) 0.094(4) Uani 1 1 d . . .
H34A H 0.5897 0.5982 0.2500 0.113 Uiso 1 1 calc R . .
Si1 Si 0.1060(2) 0.2522(5) 0.4804(3) 0.197(2) Uani 1 1 d DU . .
C26 C 0.2779(6) 0.4842(12) 0.2302(6) 0.110(5) Uani 1 1 d . . .
H26A H 0.2597 0.4380 0.2613 0.132 Uiso 1 1 calc R . .
C38 C 0.7219(6) 0.4841(12) 0.3454(7) 0.118(5) Uani 1 1 d . . .
H38A H 0.7394 0.4379 0.3860 0.141 Uiso 1 1 calc R . .
C4 C 0.1968(6) 0.2678(14) 0.4936(6) 0.119(5) Uani 1 1 d . B .
C19 C 0.8030(6) 0.2845(13) 0.6467(6) 0.114(5) Uani 1 1 d . A .
C36 C 0.7414(10) 0.6037(15) 0.2486(10) 0.169(7) Uani 1 1 d U . .
C37 C 0.7651(8) 0.5329(16) 0.3038(10) 0.172(7) Uani 1 1 d U . .
H37A H 0.8104 0.5143 0.3161 0.207 Uiso 1 1 calc R . .
C27 C 0.2358(7) 0.5338(15) 0.1657(8) 0.157(7) Uani 1 1 d . . .
H27A H 0.1906 0.5151 0.1525 0.189 Uiso 1 1 calc R . .
C28 C 0.2638(10) 0.6080(14) 0.1247(8) 0.155(8) Uani 1 1 d . . .
C11 C 0.5345(4) 0.1891(8) 0.7010(4) 0.054(3) Uani 1 1 d . . .
H11A H 0.5575 0.1592 0.7451 0.065 Uiso 1 1 calc R . .
C10 C 0.4682(5) 0.1904(8) 0.6846(4) 0.055(3) Uani 1 1 d . . .
H10A H 0.4456 0.1649 0.7184 0.066 Uiso 1 1 calc R . .
C20 C 0.9189(15) 0.4423(10) 0.7069(13) 0.287(8) Uani 0.558(16) 1 d PDU A 1
H20A H 0.9145 0.4902 0.6644 0.430 Uiso 0.558(16) 1 calc PR A 1
H20B H 0.9644 0.4438 0.7337 0.430 Uiso 0.558(16) 1 calc PR A 1
H20C H 0.8907 0.4754 0.7352 0.430 Uiso 0.558(16) 1 calc PR A 1
C21 C 0.9035(16) 0.1893(16) 0.7653(7) 0.270(8) Uani 0.558(16) 1 d PDU A 1
H21A H 0.8899 0.1068 0.7530 0.405 Uiso 0.558(16) 1 calc PR A 1
H21B H 0.8762 0.2232 0.7944 0.405 Uiso 0.558(16) 1 calc PR A 1
H21C H 0.9493 0.1903 0.7912 0.405 Uiso 0.558(16) 1 calc PR A 1
C22 C 0.9427(8) 0.215(2) 0.6229(9) 0.247(7) Uani 0.558(16) 1 d PDU A 1
H22A H 0.9364 0.2620 0.5800 0.371 Uiso 0.558(16) 1 calc PR A 1
H22B H 0.9281 0.1325 0.6111 0.371 Uiso 0.558(16) 1 calc PR A 1
H22C H 0.9891 0.2144 0.6468 0.371 Uiso 0.558(16) 1 calc PR A 1
C20' C 0.914(2) 0.4110(12) 0.7463(9) 0.285(8) Uani 0.442(16) 1 d PDU A 2
H20D H 0.9147 0.4858 0.7205 0.427 Uiso 0.442(16) 1 calc PR A 2
H20E H 0.9577 0.3978 0.7772 0.427 Uiso 0.442(16) 1 calc PR A 2
H20F H 0.8817 0.4158 0.7742 0.427 Uiso 0.442(16) 1 calc PR A 2
C21' C 0.9264(17) 0.1352(12) 0.7244(12) 0.274(8) Uani 0.442(16) 1 d PDU A 2
H21D H 0.9447 0.0882 0.6916 0.411 Uiso 0.442(16) 1 calc PR A 2
H21E H 0.8908 0.0904 0.7368 0.411 Uiso 0.442(16) 1 calc PR A 2
H21F H 0.9605 0.1511 0.7666 0.411 Uiso 0.442(16) 1 calc PR A 2
C22' C 0.9289(10) 0.313(3) 0.6035(8) 0.241(8) Uani 0.442(16) 1 d PDU A 2
H22D H 0.9016 0.3718 0.5732 0.362 Uiso 0.442(16) 1 calc PR A 2
H22E H 0.9299 0.2386 0.5774 0.362 Uiso 0.442(16) 1 calc PR A 2
H22F H 0.9734 0.3441 0.6193 0.362 Uiso 0.442(16) 1 calc PR A 2
C1 C 0.0835(13) 0.4006(11) 0.5141(11) 0.253(5) Uani 0.657(13) 1 d PDU B 1
H1A H 0.0953 0.4654 0.4860 0.379 Uiso 0.657(13) 1 calc PR B 1
H1B H 0.1073 0.4106 0.5629 0.379 Uiso 0.657(13) 1 calc PR B 1
H1C H 0.0364 0.4027 0.5110 0.379 Uiso 0.657(13) 1 calc PR B 1
C2 C 0.0635(12) 0.233(2) 0.3851(5) 0.241(5) Uani 0.657(13) 1 d PDU B 1
H2A H 0.0749 0.2995 0.3580 0.362 Uiso 0.657(13) 1 calc PR B 1
H2B H 0.0161 0.2310 0.3800 0.362 Uiso 0.657(13) 1 calc PR B 1
H2C H 0.0776 0.1575 0.3678 0.362 Uiso 0.657(13) 1 calc PR B 1
C3 C 0.0838(12) 0.1218(13) 0.5328(9) 0.241(5) Uani 0.657(13) 1 d PDU B 1
H3A H 0.0859 0.1479 0.5807 0.361 Uiso 0.657(13) 1 calc PR B 1
H3B H 0.1147 0.0561 0.5334 0.361 Uiso 0.657(13) 1 calc PR B 1
H3C H 0.0394 0.0945 0.5111 0.361 Uiso 0.657(13) 1 calc PR B 1
C1' C 0.0518(12) 0.3808(15) 0.4396(13) 0.241(6) Uani 0.343(13) 1 d PDU B 2
H1'A H 0.0765 0.4348 0.4164 0.362 Uiso 0.343(13) 1 calc PR B 2
H1'B H 0.0369 0.4245 0.4761 0.362 Uiso 0.343(13) 1 calc PR B 2
H1'C H 0.0139 0.3496 0.4053 0.362 Uiso 0.343(13) 1 calc PR B 2
C2' C 0.085(2) 0.1142(12) 0.4232(10) 0.244(5) Uani 0.343(13) 1 d PDU B 2
H2'A H 0.0899 0.1324 0.3760 0.365 Uiso 0.343(13) 1 calc PR B 2
H2'B H 0.0402 0.0899 0.4212 0.365 Uiso 0.343(13) 1 calc PR B 2
H2'C H 0.1151 0.0490 0.4429 0.365 Uiso 0.343(13) 1 calc PR B 2
C3' C 0.0933(15) 0.220(3) 0.5711(7) 0.228(5) Uani 0.343(13) 1 d PDU B 2
H3'A H 0.0999 0.2936 0.5989 0.342 Uiso 0.343(13) 1 calc PR B 2
H3'B H 0.1247 0.1595 0.5940 0.342 Uiso 0.343(13) 1 calc PR B 2
H3'C H 0.0487 0.1907 0.5671 0.342 Uiso 0.343(13) 1 calc PR B 2
C01 C 0.5018(4) 0.0663(10) 0.4375(4) 0.145(3) Uani 1 1 d DU . .
H01 H 0.5022 0.1135 0.3976 0.174 Uiso 1 1 calc R . .
C02 C 0.5598(4) 0.0297(8) 0.4842(4) 0.154(4) Uani 1 1 d DU . .
H02 H 0.6008 0.0444 0.4737 0.185 Uiso 1 1 calc R . .
C03 C 0.4431(4) 0.0288(9) 0.4534(4) 0.153(4) Uani 1 1 d DU . .
H03 H 0.4033 0.0438 0.4201 0.184 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N2 C15 1.307(10) . ?
N2 C17 1.374(10) . ?
N2 Pt1 2.073(6) . ?
Pt1 C31 1.938(9) . ?
Pt1 C23 1.941(8) . ?
Pt1 N1 2.074(7) . ?
N1 C6 1.328(10) . ?
N1 C16 1.360(9) . ?
C23 C24 1.203(10) . ?
C16 C9 1.400(11) . ?
C16 C17 1.423(11) . ?
C25 C26 1.327(14) . ?
C25 C30 1.403(13) . ?
C25 C24 1.463(11) . ?
C14 C13 1.403(12) . ?
C14 C15 1.422(11) . ?
C14 C18 1.449(13) . ?
C17 C12 1.406(10) . ?
C12 C13 1.363(12) . ?
C12 C11 1.466(12) . ?
C32 C31 1.211(11) . ?
C32 C33 1.423(12) . ?
C9 C8 1.400(12) . ?
C9 C10 1.465(11) . ?
C15 H15A 0.9300 . ?
C6 C7 1.408(12) . ?
C6 H6A 0.9300 . ?
C7 C8 1.365(11) . ?
C7 C5 1.460(13) . ?
Cl1 C28 1.765(15) . ?
C13 H13A 0.9300 . ?
C5 C4 1.173(14) . ?
C33 C38 1.357(14) . ?
C33 C34 1.402(13) . ?
Cl2 C36 1.746(18) . ?
Si2 C19 1.834(13) . ?
Si2 C22 1.851(9) . ?
Si2 C21' 1.858(9) . ?
Si2 C20' 1.862(9) . ?
Si2 C22' 1.862(9) . ?
Si2 C20 1.863(9) . ?
Si2 C21 1.872(9) . ?
C29 C28 1.33(2) . ?
C29 C30 1.382(14) . ?
C29 H29A 0.9300 . ?
C18 C19 1.164(14) . ?
C8 H8A 0.9300 . ?
C30 H30A 0.9300 . ?
C35 C34 1.339(16) . ?
C35 C36 1.36(2) . ?
C35 H35A 0.9300 . ?
C34 H34A 0.9300 . ?
Si1 C4 1.839(13) . ?
Si1 C1 1.852(9) . ?
Si1 C2 1.856(9) . ?
Si1 C1' 1.856(9) . ?
Si1 C2' 1.864(9) . ?
Si1 C3' 1.865(9) . ?
Si1 C3 1.870(9) . ?
C26 C27 1.445(16) . ?
C26 H26A 0.9300 . ?
C38 C37 1.438(18) . ?
C38 H38A 0.9300 . ?
C36 C37 1.32(2) . ?
C37 H37A 0.9300 . ?
C27 C28 1.36(2) . ?
C27 H27A 0.9300 . ?
C11 C10 1.330(11) . ?
C11 H11A 0.9300 . ?
C10 H10A 0.9300 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C20' H20D 0.9600 . ?
C20' H20E 0.9600 . ?
C20' H20F 0.9600 . ?
C21' H21D 0.9600 . ?
C21' H21E 0.9600 . ?
C21' H21F 0.9600 . ?
C22' H22D 0.9600 . ?
C22' H22E 0.9600 . ?
C22' H22F 0.9600 . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C1' H1'A 0.9600 . ?
C1' H1'B 0.9600 . ?
C1' H1'C 0.9600 . ?
C2' H2'A 0.9600 . ?
C2' H2'B 0.9600 . ?
C2' H2'C 0.9600 . ?
C3' H3'A 0.9600 . ?
C3' H3'B 0.9600 . ?
C3' H3'C 0.9600 . ?
C01 C02 1.376(8) . ?
C01 C03 1.381(8) . ?
C01 H01 0.9300 . ?
C02 C03 1.380(6) 3_656 ?
C02 H02 0.9300 . ?
C03 C02 1.380(6) 3_656 ?
C03 H03 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C15 N2 C17 118.3(7) . . ?
C15 N2 Pt1 129.6(6) . . ?
C17 N2 Pt1 112.1(5) . . ?
C31 Pt1 C23 88.4(3) . . ?
C31 Pt1 N2 95.6(3) . . ?
C23 Pt1 N2 176.1(3) . . ?
C31 Pt1 N1 176.0(3) . . ?
C23 Pt1 N1 95.6(3) . . ?
N2 Pt1 N1 80.4(2) . . ?
C6 N1 C16 118.2(7) . . ?
C6 N1 Pt1 128.9(5) . . ?
C16 N1 Pt1 112.9(5) . . ?
C24 C23 Pt1 178.3(8) . . ?
N1 C16 C9 122.4(8) . . ?
N1 C16 C17 117.0(7) . . ?
C9 C16 C17 120.6(7) . . ?
C26 C25 C30 119.5(9) . . ?
C26 C25 C24 122.0(10) . . ?
C30 C25 C24 118.5(9) . . ?
C13 C14 C15 116.6(8) . . ?
C13 C14 C18 121.5(8) . . ?
C15 C14 C18 121.8(8) . . ?
N2 C17 C12 122.0(8) . . ?
N2 C17 C16 117.6(7) . . ?
C12 C17 C16 120.4(8) . . ?
C13 C12 C17 118.5(8) . . ?
C13 C12 C11 123.1(7) . . ?
C17 C12 C11 118.4(8) . . ?
C31 C32 C33 173.7(9) . . ?
C16 C9 C8 117.5(7) . . ?
C16 C9 C10 118.1(8) . . ?
C8 C9 C10 124.3(8) . . ?
N2 C15 C14 123.8(8) . . ?
N2 C15 H15A 118.1 . . ?
C14 C15 H15A 118.1 . . ?
N1 C6 C7 123.3(8) . . ?
N1 C6 H6A 118.4 . . ?
C7 C6 H6A 118.4 . . ?
C8 C7 C6 117.9(9) . . ?
C8 C7 C5 119.9(9) . . ?
C6 C7 C5 122.2(8) . . ?
C32 C31 Pt1 177.5(7) . . ?
C12 C13 C14 120.8(8) . . ?
C12 C13 H13A 119.6 . . ?
C14 C13 H13A 119.6 . . ?
C4 C5 C7 175.6(11) . . ?
C38 C33 C34 115.6(10) . . ?
C38 C33 C32 122.4(10) . . ?
C34 C33 C32 122.0(9) . . ?
C23 C24 C25 173.9(10) . . ?
C19 Si2 C22 115.7(8) . . ?
C19 Si2 C21' 114.1(12) . . ?
C22 Si2 C21' 74.4(12) . . ?
C19 Si2 C20' 106.9(15) . . ?
C22 Si2 C20' 129.9(16) . . ?
C21' Si2 C20' 111.3(9) . . ?
C19 Si2 C22' 104.7(8) . . ?
C22 Si2 C22' 36.2(11) . . ?
C21' Si2 C22' 110.2(11) . . ?
C20' Si2 C22' 109.4(11) . . ?
C19 Si2 C20 106.3(11) . . ?
C22 Si2 C20 112.0(10) . . ?
C21' Si2 C20 130.9(12) . . ?
C20' Si2 C20 26.7(11) . . ?
C22' Si2 C20 84.2(12) . . ?
C19 Si2 C21 102.8(11) . . ?
C22 Si2 C21 110.5(9) . . ?
C21' Si2 C21 36.6(11) . . ?
C20' Si2 C21 83.1(9) . . ?
C22' Si2 C21 144.6(12) . . ?
C20 Si2 C21 109.0(8) . . ?
C28 C29 C30 116.3(14) . . ?
C28 C29 H29A 121.8 . . ?
C30 C29 H29A 121.8 . . ?
C19 C18 C14 174.1(12) . . ?
C7 C8 C9 120.7(9) . . ?
C7 C8 H8A 119.6 . . ?
C9 C8 H8A 119.6 . . ?
C29 C30 C25 122.5(12) . . ?
C29 C30 H30A 118.7 . . ?
C25 C30 H30A 118.7 . . ?
C34 C35 C36 117.4(14) . . ?
C34 C35 H35A 121.3 . . ?
C36 C35 H35A 121.3 . . ?
C35 C34 C33 125.3(13) . . ?
C35 C34 H34A 117.3 . . ?
C33 C34 H34A 117.3 . . ?
C4 Si1 C1 101.6(10) . . ?
C4 Si1 C2 112.0(9) . . ?
C1 Si1 C2 110.6(9) . . ?
C4 Si1 C1' 118.7(10) . . ?
C1 Si1 C1' 46.0(10) . . ?
C2 Si1 C1' 64.5(10) . . ?
C4 Si1 C2' 103.9(17) . . ?
C1 Si1 C2' 151.7(17) . . ?
C2 Si1 C2' 47.9(9) . . ?
C1' Si1 C2' 109.5(10) . . ?
C4 Si1 C3' 104.7(10) . . ?
C1 Si1 C3' 74.5(11) . . ?
C2 Si1 C3' 140.5(12) . . ?
C1' Si1 C3' 109.7(10) . . ?
C2' Si1 C3' 109.9(11) . . ?
C4 Si1 C3 111.6(9) . . ?
C1 Si1 C3 111.6(9) . . ?
C2 Si1 C3 109.3(8) . . ?
C1' Si1 C3 127.6(12) . . ?
C2' Si1 C3 69.4(11) . . ?
C3' Si1 C3 40.6(10) . . ?
C25 C26 C27 118.6(12) . . ?
C25 C26 H26A 120.7 . . ?
C27 C26 H26A 120.7 . . ?
C33 C38 C37 119.2(13) . . ?
C33 C38 H38A 120.4 . . ?
C37 C38 H38A 120.4 . . ?
C5 C4 Si1 174.7(12) . . ?
C18 C19 Si2 175.0(12) . . ?
C37 C36 C35 121.5(16) . . ?
C37 C36 Cl2 119.5(16) . . ?
C35 C36 Cl2 119.0(14) . . ?
C36 C37 C38 120.8(15) . . ?
C36 C37 H37A 119.6 . . ?
C38 C37 H37A 119.6 . . ?
C28 C27 C26 118.5(14) . . ?
C28 C27 H27A 120.8 . . ?
C26 C27 H27A 120.8 . . ?
C29 C28 C27 124.3(15) . . ?
C29 C28 Cl1 118.6(14) . . ?
C27 C28 Cl1 117.0(15) . . ?
C10 C11 C12 120.7(8) . . ?
C10 C11 H11A 119.6 . . ?
C12 C11 H11A 119.6 . . ?
C11 C10 C9 121.6(8) . . ?
C11 C10 H10A 119.2 . . ?
C9 C10 H10A 119.2 . . ?
Si2 C20 H20A 109.5 . . ?
Si2 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si2 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si2 C21 H21A 109.5 . . ?
Si2 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si2 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si2 C22 H22A 109.5 . . ?
Si2 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si2 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si2 C20' H20D 109.5 . . ?
Si2 C20' H20E 109.5 . . ?
H20D C20' H20E 109.5 . . ?
Si2 C20' H20F 109.5 . . ?
H20D C20' H20F 109.5 . . ?
H20E C20' H20F 109.5 . . ?
Si2 C21' H21D 109.5 . . ?
Si2 C21' H21E 109.5 . . ?
H21D C21' H21E 109.5 . . ?
Si2 C21' H21F 109.5 . . ?
H21D C21' H21F 109.5 . . ?
H21E C21' H21F 109.5 . . ?
Si2 C22' H22D 109.5 . . ?
Si2 C22' H22E 109.5 . . ?
H22D C22' H22E 109.5 . . ?
Si2 C22' H22F 109.5 . . ?
H22D C22' H22F 109.5 . . ?
H22E C22' H22F 109.5 . . ?
Si1 C1 H1A 109.5 . . ?
Si1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si1 C2 H2A 109.5 . . ?
Si1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si1 C3 H3A 109.5 . . ?
Si1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si1 C1' H1'A 109.5 . . ?
Si1 C1' H1'B 109.5 . . ?
H1'A C1' H1'B 109.5 . . ?
Si1 C1' H1'C 109.5 . . ?
H1'A C1' H1'C 109.5 . . ?
H1'B C1' H1'C 109.5 . . ?
Si1 C2' H2'A 109.5 . . ?
Si1 C2' H2'B 109.5 . . ?
H2'A C2' H2'B 109.5 . . ?
Si1 C2' H2'C 109.5 . . ?
H2'A C2' H2'C 109.5 . . ?
H2'B C2' H2'C 109.5 . . ?
Si1 C3' H3'A 109.5 . . ?
Si1 C3' H3'B 109.5 . . ?
H3'A C3' H3'B 109.5 . . ?
Si1 C3' H3'C 109.5 . . ?
H3'A C3' H3'C 109.5 . . ?
H3'B C3' H3'C 109.5 . . ?
C02 C01 C03 116.1(7) . . ?
C02 C01 H01 121.9 . . ?
C03 C01 H01 121.9 . . ?
C01 C02 C03 119.8(8) . 3_656 ?
C01 C02 H02 120.1 . . ?
C03 C02 H02 120.1 3_656 . ?
C02 C03 C01 123.7(9) 3_656 . ?
C02 C03 H03 118.1 3_656 . ?
C01 C03 H03 118.1 . . ?

_diffrn_measured_fraction_theta_max 0.986
_diffrn_reflns_theta_full        24.39
_diffrn_measured_fraction_theta_full 0.986
_refine_diff_density_max         3.994
_refine_diff_density_min         -2.261
_refine_diff_density_rms         0.166
