# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_MnTECP
_database_code_depnum_ccdc_archive 'CCDC 1059156'
_audit_update_record             
;
2015-04-11 deposited with the CCDC.
2015-10-30 downloaded from the CCDC.
;
_audit_creation_date             2014-05-15
_audit_creation_method           
;
Olex2 1.2
(compiled 2014.03.20 svn.r2914 for OlexSys, GUI svn.r4816)
;
_chemical_formula_moiety         'C32 H28 Cl Mn N4 O8'
_chemical_formula_sum            'C32 H28 Cl Mn N4 O8'
_chemical_formula_weight         686.99
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
_atom_type_scat_dispersion_source
C 0.01920 0.00962 2.31000 1.02000 1.58860 0.86500 20.84390 10.20750 0.56870
51.65120 0.215599998832
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
Cl 0.36843 0.69943 11.46040 7.19640 6.25560 1.64550 0.01040 1.16620 18.51940
47.77840 -9.55739974976
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
H 0.00000 0.00000 0.49300 0.32291 0.14019 0.04081 10.51090 26.12570 3.14236
57.79970 0.0030380000826
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
Mn -0.54371 2.83629 11.28190 7.35730 3.01930 2.24410 5.34090 0.34320 17.86740
83.75430 1.089599967
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
O 0.05239 0.03377 3.04850 2.28680 1.54630 0.86700 13.27710 5.70110 0.32390
32.90890 0.250800013542
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
N 0.03256 0.01839 12.21260 3.13220 2.01250 1.16630 0.00570 9.89330 28.99750
0.58260 -11.5290002823
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y+1/2,-z+1/2
3 -x,-y,-z
4 x,-y-1/2,z-1/2

_symmetry_Int_Tables_number      14
_cell_length_a                   14.9631(4)
_cell_length_b                   9.6880(3)
_cell_length_c                   21.4177(5)
_cell_angle_alpha                90
_cell_angle_beta                 100.638(2)
_cell_angle_gamma                90
_cell_volume                     3051.41(13)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4206
_cell_measurement_temperature    151(5)
_cell_measurement_theta_max      61.0200
_cell_measurement_theta_min      2.9880
_exptl_absorpt_coefficient_mu    4.831
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.20233
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.4953
_exptl_crystal_F_000             1419.8109
_diffrn_reflns_av_R_equivalents  0.0372
_diffrn_reflns_av_unetI/netI     0.0453
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            10067
_diffrn_reflns_theta_full        61.0012
_diffrn_reflns_theta_max         61.00
_diffrn_reflns_theta_min         3.00
_diffrn_ambient_temperature      151(5)
_diffrn_detector_area_resol_mean 16.0855
_diffrn_measured_fraction_theta_full 0.9867
_diffrn_measured_fraction_theta_max 0.9865
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0300845000
_diffrn_orient_matrix_UB_12      -0.1094211000
_diffrn_orient_matrix_UB_13      -0.0516746000
_diffrn_orient_matrix_UB_21      0.0458304000
_diffrn_orient_matrix_UB_22      -0.1133368000
_diffrn_orient_matrix_UB_23      0.0453895000
_diffrn_orient_matrix_UB_31      -0.0893299000
_diffrn_orient_matrix_UB_32      -0.0213770000
_diffrn_orient_matrix_UB_33      0.0249215000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Enhance Ultra (Cu) X-ray Source'
_reflns_Friedel_coverage         0.0
_reflns_limit_h_max              16
_reflns_limit_h_min              -16
_reflns_limit_k_max              10
_reflns_limit_k_min              0
_reflns_limit_l_max              24
_reflns_limit_l_min              0
_reflns_number_gt                4119
_reflns_number_total             4591
_reflns_odcompleteness_completeness 98.06
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     61.08
_reflns_threshold_expression     I>=2u(I)
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine (Bourhis et al., 2013)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2013)'
_refine_diff_density_max         0.5217
_refine_diff_density_min         -0.4362
_refine_diff_density_rms         0.0749
_refine_ls_d_res_high            0.8814
_refine_ls_d_res_low             14.7059
_refine_ls_goodness_of_fit_ref   0.9094
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_constraints    17
_refine_ls_number_parameters     481
_refine_ls_number_reflns         4591
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0454
_refine_ls_R_factor_gt           0.0409
_refine_ls_restrained_S_all      0.9094
_refine_ls_shift/su_max          0.0007
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1131
_refine_ls_wR_factor_ref         0.1197
_olex2_refinement_description    
;
;
_atom_sites_solution_primary     iterative
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_refinement_flags_posn
Mn1 Mn 0.19204(2) 0.03487(4) 0.448601(17) 0.01945(16) Uani 1.000000 .
Cl2 Cl 0.27536(4) 0.24826(6) 0.44478(3) 0.03093(19) Uani 1.000000 .
O3 O -0.12370(11) 0.21282(19) 0.54224(8) 0.0279(4) Uani 1.000000 .
O4 O -0.07942(12) 0.38920(19) 0.48712(9) 0.0331(4) Uani 1.000000 .
O5 O -0.05436(12) -0.0600(2) 0.22846(8) 0.0321(4) Uani 1.000000 .
O6 O 0.47018(13) -0.3228(2) 0.40893(11) 0.0440(5) Uani 1.000000 .
O7 O 0.48836(12) -0.1466(2) 0.34450(10) 0.0403(5) Uani 1.000000 .
O8 O 0.04421(15) 0.0547(2) 0.17975(10) 0.0420(5) Uani 1.000000 .
O9 O 0.37151(14) -0.1044(2) 0.70105(10) 0.0467(5) Uani 1.000000 .
N10 N 0.15366(13) 0.0790(2) 0.53197(9) 0.0201(4) Uani 1.000000 .
O11 O 0.34008(11) 0.1222(2) 0.70147(8) 0.0337(5) Uani 1.000000 .
N12 N 0.21760(13) -0.0412(2) 0.36550(10) 0.0223(5) Uani 1.000000 .
C13 C 0.16285(16) -0.0346(3) 0.30636(12) 0.0243(6) Uani 1.000000 .
N14 N 0.06841(12) 0.0982(2) 0.40203(9) 0.0207(4) Uani 1.000000 .
N15 N 0.30461(13) -0.0585(2) 0.49628(10) 0.0225(4) Uani 1.000000 .
C16 C 0.00658(15) 0.1894(2) 0.49214(11) 0.0205(5) Uani 1.000000 .
C17 C -0.07294(15) 0.2632(3) 0.51051(11) 0.0224(5) Uani 1.000000 .
C18 C 0.37290(16) -0.1158(3) 0.46939(13) 0.0256(5) Uani 1.000000 .
C19 C -0.06861(16) 0.2102(3) 0.37822(12) 0.0249(5) Uani 1.000000 .
C20 C 0.00457(15) 0.1697(3) 0.42755(11) 0.0214(5) Uani 1.000000 .
C21 C 0.36882(16) -0.1377(3) 0.40480(13) 0.0260(6) Uani 1.000000 .
C22 C 0.29112(16) 0.0029(3) 0.60580(12) 0.0248(5) Uani 1.000000 .
C23 C 0.15561(16) 0.1169(3) 0.63851(12) 0.0265(6) Uani 1.000000 .
C24 C 0.07458(15) 0.1437(2) 0.54061(11) 0.0207(5) Uani 1.000000 .
C25 C -0.2000(2) 0.5263(4) 0.42991(17) 0.0503(9) Uani 1.000000 .
C26 C -0.05047(17) 0.1601(3) 0.32301(12) 0.0273(6) Uani 1.000000 .
C27 C 0.20528(16) 0.0630(3) 0.59216(12) 0.0228(5) Uani 1.000000 .
C28 C 0.07614(17) 0.0224(3) 0.29334(12) 0.0238(5) Uani 1.000000 .
C29 C -0.1574(2) 0.4761(4) 0.49381(16) 0.0409(8) Uani 1.000000 .
C30 C 0.03452(16) 0.0893(3) 0.33782(11) 0.0228(5) Uani 1.000000 .
C31 C 0.33706(17) -0.0532(3) 0.56058(13) 0.0250(6) Uani 1.000000 .
C32 C -0.1855(2) 0.0462(4) 0.16090(16) 0.0411(8) Uani 1.000000 .
C33 C 0.29041(17) -0.1383(3) 0.29057(13) 0.0295(6) Uani 1.000000 .
C34 C 0.07570(16) 0.1658(3) 0.60695(12) 0.0245(5) Uani 1.000000 .
C35 C 0.29590(16) -0.1053(3) 0.35680(12) 0.0256(6) Uani 1.000000 .
C36 C 0.02184(18) 0.0103(3) 0.22713(12) 0.0278(6) Uani 1.000000 .
C37 C 0.44977(17) -0.1458(3) 0.51874(13) 0.0301(6) Uani 1.000000 .
C38 C 0.38614(19) 0.1343(4) 0.76747(14) 0.0462(8) Uani 1.000000 .
C39 C 0.44962(17) -0.2007(3) 0.38286(14) 0.0316(6) Uani 1.000000 .
C40 C 0.20849(17) -0.0963(3) 0.25976(13) 0.0283(6) Uani 1.000000 .
C41 C 0.33905(17) -0.0015(3) 0.67454(13) 0.0321(6) Uani 1.000000 .
C42 C -0.1204(2) -0.0739(4) 0.16874(15) 0.0410(7) Uani 1.000000 .
C43 C 0.42770(17) -0.1082(3) 0.57415(14) 0.0311(6) Uani 1.000000 .
C44 C 0.5554(3) -0.5293(4) 0.4204(3) 0.0848(17) Uani 1.000000 .
C45 C 0.5473(3) -0.3919(4) 0.3886(3) 0.0682(13) Uani 1.000000 .
H45a H 0.527(4) -0.429(7) 0.337(3) 0.13(2) Uiso 1.000000 .
H32a H -0.152(3) 0.125(4) 0.1533(17) 0.052(10) Uiso 1.000000 .
H29a H -0.130(3) 0.556(5) 0.517(2) 0.061(12) Uiso 1.000000 .
H37 H 0.5072(19) -0.186(3) 0.5118(13) 0.027(7) Uiso 1.000000 .
H34 H 0.0256(19) 0.205(3) 0.6253(13) 0.031(7) Uiso 1.000000 .
H19 H -0.1216(19) 0.267(3) 0.3826(13) 0.027(7) Uiso 1.000000 .
H23 H 0.1793(18) 0.115(3) 0.6851(14) 0.024(7) Uiso 1.000000 .
H40 H 0.1814(19) -0.094(3) 0.2146(16) 0.031(7) Uiso 1.000000 .
H43 H 0.462(2) -0.111(4) 0.6154(17) 0.041(8) Uiso 1.000000 .
H29b H -0.196(3) 0.426(4) 0.512(2) 0.062(11) Uiso 1.000000 .
H45b H 0.594(2) -0.331(4) 0.3996(15) 0.043(9) Uiso 1.000000 .
H42a H -0.153(2) -0.164(4) 0.1762(17) 0.054(10) Uiso 1.000000 .
H42b H -0.085(2) -0.079(4) 0.1321(19) 0.054(10) Uiso 1.000000 .
H26 H -0.0857(19) 0.164(3) 0.2792(15) 0.032(7) Uiso 1.000000 .
H32b H -0.232(3) 0.032(4) 0.124(2) 0.052(10) Uiso 1.000000 .
H33 H 0.33526(17) -0.1808(3) 0.27253(13) 0.0354(7) Uiso 1.000000 R
C1 C 0.3676(2) 0.2757(5) 0.78952(17) 0.0616(10) Uani 1.000000 .
H32c H -0.210(2) 0.051(3) 0.1981(18) 0.043(9) Uiso 1.000000 .
H25a H -0.1539(3) 0.563(2) 0.4087(5) 0.0755(13) Uiso 1.000000 GR
H25b H -0.2305(15) 0.4512(7) 0.4056(4) 0.0755(13) Uiso 1.000000 GR
H25c H -0.2432(13) 0.5974(19) 0.43402(18) 0.0755(13) Uiso 1.000000 GR
H44a H 0.571(3) -0.5169(5) 0.4656(3) 0.127(3) Uiso 1.000000 GR
H44b H 0.4985(9) -0.5772(17) 0.4101(16) 0.127(3) Uiso 1.000000 GR
H44c H 0.602(2) -0.5822(17) 0.4060(15) 0.127(3) Uiso 1.000000 GR
H38a H 0.36331(19) 0.0653(4) 0.79338(14) 0.0555(10) Uiso 1.000000 R
H38b H 0.45104(19) 0.1204(4) 0.77071(14) 0.0555(10) Uiso 1.000000 R
H1a H 0.3987(16) 0.3425(5) 0.7682(10) 0.0924(15) Uiso 1.000000 GR
H1b H 0.3034(3) 0.2934(12) 0.7800(12) 0.0924(15) Uiso 1.000000 GR
H1c H 0.3889(18) 0.2824(10) 0.8345(3) 0.0924(15) Uiso 1.000000 GR


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mn1 Cl2 2.4233(7) . ?
Mn1 N10 2.0198(19) . ?
Mn1 N12 2.027(2) . ?
Mn1 N14 2.0278(19) . ?
Mn1 N15 2.015(2) . ?
O3 C17 1.211(3) . ?
O4 C17 1.316(3) . ?
O4 C29 1.467(3) . ?
O5 C36 1.333(3) . ?
O5 C42 1.471(3) . ?
O6 C39 1.320(4) . ?
O6 C45 1.468(4) . ?
O7 C39 1.209(3) . ?
O8 C36 1.205(3) . ?
O9 C41 1.204(4) . ?
N10 C24 1.381(3) . ?
N10 C27 1.384(3) . ?
O11 C38 1.458(3) . ?
O11 C41 1.329(4) . ?
N12 C13 1.377(3) . ?
N12 C35 1.369(3) . ?
C13 C28 1.390(4) . ?
C13 C40 1.440(3) . ?
N14 C20 1.373(3) . ?
N14 C30 1.378(3) . ?
N15 C18 1.379(3) . ?
N15 C31 1.374(3) . ?
C16 C17 1.501(3) . ?
C16 C20 1.391(3) . ?
C16 C24 1.386(3) . ?
C18 C21 1.390(4) . ?
C18 C37 1.441(4) . ?
C19 C20 1.429(3) . ?
C19 C26 1.351(4) . ?
C21 C35 1.390(4) . ?
C21 C39 1.505(3) . ?
C22 C27 1.391(4) . ?
C22 C31 1.397(4) . ?
C22 C41 1.514(4) . ?
C23 C27 1.443(4) . ?
C23 C34 1.346(4) . ?
C24 C34 1.434(3) . ?
C25 C29 1.481(5) . ?
C26 C30 1.428(4) . ?
C28 C30 1.391(4) . ?
C28 C36 1.503(4) . ?
C31 C43 1.436(4) . ?
C32 C42 1.506(5) . ?
C33 C35 1.442(4) . ?
C33 C40 1.343(4) . ?
C37 C43 1.340(4) . ?
C38 C1 1.492(5) . ?
C44 C45 1.490(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N10 Mn1 Cl2 94.67(6) . . ?
N12 Mn1 Cl2 95.68(6) . . ?
N12 Mn1 N10 169.65(8) . . ?
N14 Mn1 Cl2 98.84(6) . . ?
N14 Mn1 N10 89.33(8) . . ?
N14 Mn1 N12 88.91(8) . . ?
N15 Mn1 Cl2 90.73(6) . . ?
N15 Mn1 N10 89.68(8) . . ?
N15 Mn1 N12 90.36(8) . . ?
N15 Mn1 N14 170.43(8) . . ?
C29 O4 C17 119.9(2) . . ?
C42 O5 C36 117.9(2) . . ?
C45 O6 C39 114.7(2) . . ?
C24 N10 Mn1 127.22(15) . . ?
C27 N10 Mn1 126.80(15) . . ?
C27 N10 C24 105.69(18) . . ?
C41 O11 C38 117.3(2) . . ?
C13 N12 Mn1 127.87(16) . . ?
C35 N12 Mn1 126.12(17) . . ?
C35 N12 C13 106.0(2) . . ?
C28 C13 N12 125.3(2) . . ?
C40 C13 N12 109.9(2) . . ?
C40 C13 C28 124.8(2) . . ?
C20 N14 Mn1 126.56(16) . . ?
C30 N14 Mn1 127.32(15) . . ?
C30 N14 C20 105.91(19) . . ?
C18 N15 Mn1 125.69(18) . . ?
C31 N15 Mn1 126.79(16) . . ?
C31 N15 C18 106.4(2) . . ?
C20 C16 C17 117.0(2) . . ?
C24 C16 C17 117.6(2) . . ?
C24 C16 C20 125.4(2) . . ?
O4 C17 O3 125.3(2) . . ?
C16 C17 O3 124.4(2) . . ?
C16 C17 O4 110.35(19) . . ?
C21 C18 N15 125.3(2) . . ?
C37 C18 N15 109.1(2) . . ?
C37 C18 C21 125.6(2) . . ?
C26 C19 C20 107.3(2) . . ?
C16 C20 N14 125.2(2) . . ?
C19 C20 N14 109.8(2) . . ?
C19 C20 C16 124.8(2) . . ?
C35 C21 C18 125.9(2) . . ?
C39 C21 C18 118.8(2) . . ?
C39 C21 C35 115.3(2) . . ?
C31 C22 C27 124.8(2) . . ?
C41 C22 C27 118.0(2) . . ?
C41 C22 C31 117.2(2) . . ?
C34 C23 C27 107.7(2) . . ?
C16 C24 N10 125.0(2) . . ?
C34 C24 N10 110.3(2) . . ?
C34 C24 C16 124.6(2) . . ?
C30 C26 C19 107.0(2) . . ?
C22 C27 N10 125.3(2) . . ?
C23 C27 N10 109.3(2) . . ?
C23 C27 C22 125.4(2) . . ?
C30 C28 C13 124.5(2) . . ?
C36 C28 C13 118.7(2) . . ?
C36 C28 C30 116.8(2) . . ?
C25 C29 O4 108.2(2) . . ?
C26 C30 N14 109.9(2) . . ?
C28 C30 N14 125.7(2) . . ?
C28 C30 C26 124.4(2) . . ?
C22 C31 N15 125.5(2) . . ?
C43 C31 N15 109.6(2) . . ?
C43 C31 C22 124.8(3) . . ?
C40 C33 C35 107.3(2) . . ?
C24 C34 C23 107.0(2) . . ?
C21 C35 N12 125.2(2) . . ?
C33 C35 N12 109.9(2) . . ?
C33 C35 C21 124.9(2) . . ?
O8 C36 O5 124.9(2) . . ?
C28 C36 O5 109.6(2) . . ?
C28 C36 O8 125.5(2) . . ?
C43 C37 C18 107.5(2) . . ?
C1 C38 O11 107.3(3) . . ?
O7 C39 O6 125.0(2) . . ?
C21 C39 O6 111.7(2) . . ?
C21 C39 O7 123.3(3) . . ?
C33 C40 C13 107.0(2) . . ?
O11 C41 O9 124.8(3) . . ?
C22 C41 O9 124.0(3) . . ?
C22 C41 O11 111.2(2) . . ?
C32 C42 O5 110.1(2) . . ?
C37 C43 C31 107.4(2) . . ?
C44 C45 O6 105.9(3) . . ?

_chemical_name_systematic        
'5,10,15,20-tetrakis(ethyloxycarbonyl)porphyrin manganese(III) chloride '
_chemical_name_common            MnTECP
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Dichloromethane and hexane'
_exptl_crystal_preparation       'Magnetic properties'
