# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1400052'
_audit_update_record             
;
2015-05-09 deposited with the CCDC.
2015-10-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C105 H87 Eu6 N5 O60'
_chemical_formula_weight         3290.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.0089(9)
_cell_length_b                   15.8110(11)
_cell_length_c                   21.2396(17)
_cell_angle_alpha                109.579(7)
_cell_angle_beta                 92.652(7)
_cell_angle_gamma                105.907(7)
_cell_volume                     3310.7(4)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.650
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1610
_exptl_absorpt_coefficient_mu    20.799
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.3238
_exptl_absorpt_correction_T_max  0.3684
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            21607
_diffrn_reflns_av_R_equivalents  0.0872
_diffrn_reflns_av_sigmaI/netI    0.1564
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         3.11
_diffrn_reflns_theta_max         67.25
_reflns_number_total             11843
_reflns_number_gt                6579
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1319P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11843
_refine_ls_number_parameters     812
_refine_ls_number_restraints     2400
_refine_ls_R_factor_all          0.1376
_refine_ls_R_factor_gt           0.0869
_refine_ls_wR_factor_ref         0.2518
_refine_ls_wR_factor_gt          0.2214
_refine_ls_goodness_of_fit_ref   0.943
_refine_ls_restrained_S_all      0.878
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.33463(7) 0.76111(5) 0.74193(4) 0.0333(2) Uani 1 1 d U . .
Eu2 Eu 0.65649(7) 0.37232(5) 0.90135(5) 0.0370(2) Uani 1 1 d U . .
Eu3 Eu 0.91397(7) 0.50531(5) 0.76757(5) 0.0342(2) Uani 1 1 d U . .
N1 N 1.0418(12) 1.0259(9) 0.8975(7) 0.054(3) Uani 1 1 d U . .
N2 N -0.0256(12) 0.1017(8) 0.7295(7) 0.055(3) Uani 1 1 d U . .
O1 O 0.2848(9) 0.5980(6) 0.7149(5) 0.045(2) Uani 1 1 d U . .
O2 O 0.0991(9) 0.5015(6) 0.7150(6) 0.048(2) Uani 1 1 d U . .
O3 O 0.6523(9) 0.3923(7) 0.7965(5) 0.051(2) Uani 1 1 d U . .
O4 O 0.6845(9) 0.4921(7) 0.7438(5) 0.049(2) Uani 1 1 d U . .
O5 O -0.4489(9) -0.1264(6) 0.7490(6) 0.053(2) Uani 1 1 d U . .
O6 O -0.4625(9) -0.2726(7) 0.7227(6) 0.051(2) Uani 1 1 d U . .
O7 O -0.0735(9) -0.3606(6) 0.7424(6) 0.049(2) Uani 1 1 d U . .
O8 O 0.1153(9) -0.2674(7) 0.7377(6) 0.055(2) Uani 1 1 d U . .
O9 O 0.7157(9) 0.5362(7) 0.9323(5) 0.046(2) Uani 1 1 d U . .
O10 O 0.8685(9) 0.5814(6) 0.8733(5) 0.044(2) Uani 1 1 d U . .
O11 O 0.3383(9) 0.6403(7) 0.8878(6) 0.055(3) Uani 1 1 d U . .
H11 H 0.2638 0.6338 0.8750 0.082 Uiso 1 1 calc R . .
O12 O 0.3781(9) 0.7593(7) 0.8482(6) 0.050(2) Uani 1 1 d U . .
O13 O 0.8637(10) 1.3842(8) 0.8951(6) 0.058(2) Uani 1 1 d U . .
O14 O 0.9943(9) 1.4223(7) 0.8275(6) 0.049(2) Uani 1 1 d U . .
O15 O 1.4504(8) 1.4146(6) 0.9053(5) 0.037(2) Uani 1 1 d U . .
O16 O 1.4416(9) 1.2684(6) 0.8896(6) 0.054(2) Uani 1 1 d U . .
O17 O 0.8519(10) 0.3413(7) 0.6888(6) 0.053(2) Uani 1 1 d U . .
O18 O 0.8449(10) 0.4399(7) 0.6388(6) 0.054(2) Uani 1 1 d U . .
O19 O 0.6998(10) 0.2934(7) 0.3820(6) 0.054(2) Uani 1 1 d U . .
O20 O 0.7066(10) 0.1504(7) 0.3276(5) 0.048(2) Uani 1 1 d U . .
O23 O 0.3252(12) 0.9091(8) 0.8253(6) 0.074(4) Uani 1 1 d U . .
H23A H 0.3591 0.9541 0.8121 0.111 Uiso 1 1 d R . .
H23B H 0.2476 0.9058 0.8289 0.111 Uiso 1 1 d R . .
O24 O 0.6331(9) 0.4338(6) 1.0175(5) 0.046(2) Uani 1 1 d U . .
H24A H 0.6462 0.4929 1.0296 0.068 Uiso 1 1 d R . .
H24C H 0.6874 0.4232 1.0412 0.068 Uiso 1 1 d R . .
O25 O 0.6910(12) 0.2625(8) 0.9525(6) 0.070(3) Uani 1 1 d U . .
H25A H 0.7033 0.2890 0.9953 0.105 Uiso 1 1 d R . .
H25B H 0.6254 0.2139 0.9403 0.105 Uiso 1 1 d R . .
O26 O 1.0938(8) 0.6240(6) 0.8490(6) 0.051(3) Uani 1 1 d U . .
H26A H 1.1627 0.6239 0.8325 0.077 Uiso 1 1 d R . .
H26C H 1.0976 0.6112 0.8847 0.077 Uiso 1 1 d R . .
O27 O 0.6476(16) 0.2224(9) 0.8111(7) 0.108(5) Uani 1 1 d U . .
H27A H 0.6328 0.2265 0.7728 0.162 Uiso 1 1 d R . .
H27C H 0.5874 0.1782 0.8150 0.162 Uiso 1 1 d R . .
O28 O 0.627(2) 0.0611(13) 0.8322(10) 0.161(6) Uani 1 1 d U . .
H28D H 0.5959 0.0074 0.8007 0.194 Uiso 1 1 d R . .
H28B H 0.7039 0.0701 0.8470 0.194 Uiso 1 1 d R . .
O29 O 0.3726(19) 0.0739(12) 0.8166(10) 0.153(5) Uani 1 1 d U . .
H29C H 0.3944 0.1268 0.8492 0.184 Uiso 1 1 d R . .
H29A H 0.4280 0.0719 0.7900 0.184 Uiso 1 1 d R . .
O30 O 0.7153(16) 0.1759(11) 0.6961(8) 0.121(4) Uani 1 1 d U . .
H30C H 0.7585 0.2275 0.6930 0.145 Uiso 1 1 d R . .
H30B H 0.6521 0.1480 0.6643 0.145 Uiso 1 1 d R . .
O31 O 0.567(2) 0.1233(14) 0.9698(11) 0.175(7) Uani 1 1 d U . .
H31D H 0.6022 0.1009 0.9943 0.210 Uiso 1 1 d R . .
H31A H 0.5401 0.0827 0.9301 0.210 Uiso 1 1 d R . .
O32 O 0.362(2) 0.9737(14) 0.9611(11) 0.169(7) Uani 1 1 d U . .
H32B H 0.4207 1.0264 0.9741 0.203 Uiso 1 1 d R . .
H32C H 0.3515 0.9473 0.9183 0.203 Uiso 1 1 d R . .
C1 C 0.2173(12) 0.5228(9) 0.7182(7) 0.035(2) Uani 1 1 d U . .
C2 C 0.2795(12) 0.4518(8) 0.7225(7) 0.035(2) Uani 1 1 d U . .
C3 C 0.4120(12) 0.4728(9) 0.7361(7) 0.040(2) Uani 1 1 d U . .
H3 H 0.4640 0.5320 0.7395 0.047 Uiso 1 1 calc R . .
C4 C 0.4677(12) 0.4088(9) 0.7444(7) 0.037(2) Uani 1 1 d U . .
C5 C 0.3869(12) 0.3184(9) 0.7384(7) 0.038(2) Uani 1 1 d U . .
H5 H 0.4230 0.2740 0.7436 0.046 Uiso 1 1 calc R . .
C6 C 0.2565(12) 0.2958(8) 0.7248(7) 0.036(2) Uani 1 1 d U . .
C7 C 0.2059(13) 0.3644(9) 0.7189(7) 0.040(2) Uani 1 1 d U . .
H7 H 0.1175 0.3505 0.7120 0.048 Uiso 1 1 calc R . .
C8 C 0.1723(13) 0.2014(9) 0.7234(8) 0.041(3) Uani 1 1 d U . .
C9 C 0.2228(15) 0.1291(9) 0.7176(8) 0.051(3) Uani 1 1 d U . .
H9 H 0.3088 0.1377 0.7140 0.061 Uiso 1 1 calc R . .
C10 C 0.1475(15) 0.0461(10) 0.7170(8) 0.052(3) Uani 1 1 d U . .
H10 H 0.1838 -0.0019 0.7123 0.063 Uiso 1 1 calc R . .
C11 C 0.0254(14) 0.0287(9) 0.7229(8) 0.044(3) Uani 1 1 d U . .
C13 C 0.0463(14) 0.1846(10) 0.7290(8) 0.047(3) Uani 1 1 d U . .
H13 H 0.0091 0.2319 0.7325 0.056 Uiso 1 1 calc R . .
C14 C -0.0536(12) -0.0637(8) 0.7263(7) 0.036(2) Uani 1 1 d U . .
C15 C 0.0030(13) -0.1298(9) 0.7299(8) 0.042(2) Uani 1 1 d U . .
H15 H 0.0909 -0.1165 0.7307 0.050 Uiso 1 1 calc R . .
C16 C -0.0666(13) -0.2155(9) 0.7325(8) 0.043(3) Uani 1 1 d U . .
C17 C -0.1954(13) -0.2346(9) 0.7345(8) 0.044(3) Uani 1 1 d U . .
H17 H -0.2427 -0.2920 0.7365 0.052 Uiso 1 1 calc R . .
C18 C -0.2549(13) -0.1679(9) 0.7335(8) 0.041(3) Uani 1 1 d U . .
C19 C -0.1865(13) -0.0838(9) 0.7292(8) 0.043(3) Uani 1 1 d U . .
H19 H -0.2274 -0.0399 0.7281 0.052 Uiso 1 1 calc R . .
C20 C 0.6149(13) 0.4345(9) 0.7628(8) 0.040(2) Uani 1 1 d U . .
C21 C 0.0010(13) -0.2855(9) 0.7389(8) 0.043(3) Uani 1 1 d U . .
C22 C -0.4001(13) -0.1922(9) 0.7349(8) 0.044(3) Uani 1 1 d U . .
C23 C 0.7776(13) 0.5930(10) 0.9067(8) 0.044(3) Uani 1 1 d U . .
C24 C 0.7330(13) 0.6743(9) 0.9095(8) 0.040(2) Uani 1 1 d U . .
C25 C 0.8161(13) 0.7609(9) 0.9149(8) 0.041(3) Uani 1 1 d U . .
H25 H 0.9039 0.7711 0.9204 0.049 Uiso 1 1 calc R . .
C26 C 0.7682(14) 0.8324(10) 0.9120(8) 0.044(3) Uani 1 1 d U . .
C27 C 0.6379(13) 0.8153(9) 0.9003(8) 0.041(2) Uani 1 1 d U . .
H27 H 0.6063 0.8627 0.8969 0.049 Uiso 1 1 calc R . .
C28 C 0.5519(13) 0.7276(10) 0.8935(8) 0.043(3) Uani 1 1 d U . .
C29 C 0.6021(13) 0.6588(10) 0.9007(8) 0.042(3) Uani 1 1 d U . .
H29 H 0.5471 0.6017 0.8995 0.051 Uiso 1 1 calc R . .
C30 C 0.8521(13) 0.9270(9) 0.9172(8) 0.041(3) Uani 1 1 d U . .
C31 C 0.9788(14) 0.9426(10) 0.9002(8) 0.045(3) Uani 1 1 d U . .
H31 H 1.0167 0.8949 0.8912 0.054 Uiso 1 1 calc R . .
C33 C 0.9911(13) 1.1017(9) 0.9180(8) 0.043(3) Uani 1 1 d U . .
C34 C 0.8805(14) 1.0863(10) 0.9409(8) 0.052(3) Uani 1 1 d U . .
H34 H 0.8488 1.1372 0.9572 0.062 Uiso 1 1 calc R . .
C35 C 0.8102(14) 1.0032(9) 0.9427(8) 0.046(3) Uani 1 1 d U . .
H35 H 0.7346 0.9980 0.9610 0.055 Uiso 1 1 calc R . .
C36 C 1.0617(14) 1.1931(9) 0.9096(8) 0.044(3) Uani 1 1 d U . .
C37 C 1.1857(13) 1.2220(9) 0.9105(8) 0.042(3) Uani 1 1 d U . .
H37 H 1.2345 1.1863 0.9189 0.050 Uiso 1 1 calc R . .
C38 C 1.2464(12) 1.3032(9) 0.8993(8) 0.039(3) Uani 1 1 d U . .
C39 C 1.1760(12) 1.3573(9) 0.8854(7) 0.039(2) Uani 1 1 d U . .
H39 H 1.2164 1.4112 0.8767 0.047 Uiso 1 1 calc R . .
C40 C 1.0426(12) 1.3298(9) 0.8847(8) 0.039(3) Uani 1 1 d U . .
C41 C 0.9872(14) 1.2476(10) 0.8984(8) 0.045(3) Uani 1 1 d U . .
H41 H 0.9000 1.2290 0.9000 0.054 Uiso 1 1 calc R . .
C42 C 0.4117(13) 0.7064(10) 0.8737(8) 0.043(3) Uani 1 1 d U . .
C43 C 1.3896(13) 1.3324(9) 0.8983(8) 0.039(3) Uani 1 1 d U . .
C44 C 0.9613(13) 1.3839(10) 0.8671(8) 0.042(3) Uani 1 1 d U . .
C45 C 0.8457(16) 0.3588(11) 0.6342(9) 0.055(3) Uani 1 1 d U . .
C46 C 0.8364(16) 0.2841(11) 0.5686(9) 0.054(3) Uani 1 1 d U . .
C47 C 0.8864(16) 0.2102(11) 0.5654(9) 0.057(3) Uani 1 1 d U . .
H47 H 0.9220 0.2067 0.6047 0.069 Uiso 1 1 calc R . .
C48 C 0.8816(17) 0.1435(11) 0.5034(9) 0.057(3) Uani 1 1 d U . .
C49 C 0.8349(16) 0.1468(11) 0.4461(9) 0.057(3) Uani 1 1 d U . .
H49 H 0.8380 0.1019 0.4051 0.069 Uiso 1 1 calc R . .
C50 C 0.7798(16) 0.2189(11) 0.4470(8) 0.052(3) Uani 1 1 d U . .
C51 C 0.7869(15) 0.2868(11) 0.5091(8) 0.052(3) Uani 1 1 d U . .
H51 H 0.7566 0.3368 0.5108 0.062 Uiso 1 1 calc R . .
C52 C 0.7256(15) 0.2204(11) 0.3819(8) 0.049(3) Uani 1 1 d U . .
C53 C 0.9414(17) 0.0694(11) 0.5022(9) 0.059(3) Uani 1 1 d U . .
C54 C 1.013(3) 0.0361(19) 0.4520(14) 0.060(3) Uani 0.276(8) 1 d PU . 1
H54 H 1.0287 0.0638 0.4196 0.072 Uiso 0.276(8) 1 calc PR . 1
N3 N 1.013(3) 0.0361(19) 0.4520(14) 0.060(3) Uani 0.276(8) 1 d PU . 1
C55 C 0.944(3) 0.031(2) 0.5502(16) 0.059(4) Uani 0.551(15) 1 d PU . 1
H55 H 0.9049 0.0549 0.5871 0.071 Uiso 0.551(15) 1 d PR . 1
C54' C 0.886(4) -0.026(2) 0.4572(18) 0.063(4) Uani 0.224(8) 1 d PU . 2
H54' H 0.8046 -0.0458 0.4332 0.076 Uiso 0.224(8) 1 calc PR . 2
N3' N 0.886(4) -0.026(2) 0.4572(18) 0.063(4) Uani 0.224(8) 1 d PU . 2
C55' C 1.053(4) 0.083(3) 0.5496(19) 0.059(4) Uani 0.449(15) 1 d PU . 2
H55' H 1.0840 0.1407 0.5853 0.070 Uiso 0.449(15) 1 d PR . 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O12 2.297(11) . ?
Eu1 O8 2.324(10) 1_565 ?
Eu1 O1 2.342(9) . ?
Eu1 O23 2.448(11) . ?
Eu1 O20 2.453(9) 2_666 ?
Eu1 O19 2.453(11) 2_666 ?
Eu1 O6 2.456(9) 1_665 ?
Eu1 O5 2.516(10) 1_665 ?
Eu1 C52 2.811(16) 2_666 ?
Eu1 C22 2.834(14) 1_665 ?
Eu2 O13 2.251(11) 1_545 ?
Eu2 O9 2.338(9) . ?
Eu2 O3 2.351(11) . ?
Eu2 O24 2.385(10) . ?
Eu2 O16 2.428(10) 1_445 ?
Eu2 O25 2.435(11) . ?
Eu2 O27 2.472(13) . ?
Eu2 O15 2.533(8) 1_445 ?
Eu2 C43 2.824(13) 1_445 ?
Eu3 O10 2.317(10) . ?
Eu3 O7 2.325(9) 1_665 ?
Eu3 O2 2.374(9) 1_655 ?
Eu3 O14 2.403(9) 1_545 ?
Eu3 O26 2.430(9) . ?
Eu3 O17 2.450(10) . ?
Eu3 O4 2.490(10) . ?
Eu3 O18 2.571(11) . ?
Eu3 C45 2.899(17) . ?
Eu3 O3 3.154(10) . ?
Eu3 C20 3.159(14) . ?
N1 C31 1.332(17) . ?
N1 C33 1.406(17) . ?
N2 C13 1.337(17) . ?
N2 C11 1.385(17) . ?
O1 C1 1.244(15) . ?
O2 C1 1.244(15) . ?
O2 Eu3 2.374(9) 1_455 ?
O3 C20 1.253(16) . ?
O4 C20 1.214(16) . ?
O5 C22 1.255(16) . ?
O5 Eu1 2.516(10) 1_445 ?
O6 C22 1.200(15) . ?
O6 Eu1 2.456(9) 1_445 ?
O7 C21 1.271(16) . ?
O7 Eu3 2.325(9) 1_445 ?
O8 C21 1.215(16) . ?
O8 Eu1 2.324(10) 1_545 ?
O9 C23 1.262(16) . ?
O10 C23 1.271(17) . ?
O11 C42 1.267(16) . ?
O12 C42 1.258(16) . ?
O13 C44 1.253(16) . ?
O13 Eu2 2.251(10) 1_565 ?
O14 C44 1.209(16) . ?
O14 Eu3 2.403(9) 1_565 ?
O15 C43 1.243(15) . ?
O15 Eu2 2.533(8) 1_665 ?
O16 C43 1.261(15) . ?
O16 Eu2 2.428(10) 1_665 ?
O17 C45 1.283(19) . ?
O18 C45 1.255(17) . ?
O19 C52 1.262(16) . ?
O19 Eu1 2.453(11) 2_666 ?
O20 C52 1.263(17) . ?
O20 Eu1 2.453(9) 2_666 ?
C1 C2 1.491(15) . ?
C2 C7 1.370(17) . ?
C2 C3 1.397(17) . ?
C3 C4 1.371(17) . ?
C4 C5 1.421(17) . ?
C4 C20 1.555(18) . ?
C5 C6 1.373(18) . ?
C6 C7 1.385(17) . ?
C6 C8 1.516(17) . ?
C8 C13 1.358(19) . ?
C8 C9 1.375(18) . ?
C9 C10 1.342(19) . ?
C10 C11 1.32(2) . ?
C11 C14 1.509(17) . ?
C14 C15 1.377(16) . ?
C14 C19 1.418(18) . ?
C15 C16 1.381(18) . ?
C16 C17 1.372(18) . ?
C16 C21 1.531(18) . ?
C17 C18 1.391(18) . ?
C18 C19 1.372(18) . ?
C18 C22 1.542(18) . ?
C22 Eu1 2.834(14) 1_445 ?
C23 C24 1.481(18) . ?
C24 C29 1.387(18) . ?
C24 C25 1.387(18) . ?
C25 C26 1.389(18) . ?
C26 C27 1.380(19) . ?
C26 C30 1.492(18) . ?
C27 C28 1.404(18) . ?
C28 C29 1.395(18) . ?
C28 C42 1.495(18) . ?
C30 C35 1.360(19) . ?
C30 C31 1.43(2) . ?
C33 C34 1.32(2) . ?
C33 C36 1.515(18) . ?
C34 C35 1.343(19) . ?
C36 C37 1.312(19) . ?
C36 C41 1.406(19) . ?
C37 C38 1.378(18) . ?
C38 C39 1.391(17) . ?
C38 C43 1.520(18) . ?
C39 C40 1.410(18) . ?
C40 C41 1.408(18) . ?
C40 C44 1.508(16) . ?
C43 Eu2 2.824(13) 1_665 ?
C45 C46 1.47(2) . ?
C46 C51 1.37(2) . ?
C46 C47 1.40(2) . ?
C47 C48 1.37(2) . ?
C48 C49 1.32(2) . ?
C48 C53 1.486(19) . ?
C49 C50 1.426(19) . ?
C50 C51 1.38(2) . ?
C50 C52 1.49(2) . ?
C52 Eu1 2.811(16) 2_666 ?
C53 C55 1.35(3) . ?
C53 C54 1.40(3) . ?
C53 C54' 1.43(4) . ?
C53 C55' 1.47(4) . ?
C54 C55 1.27(3) 2_756 ?
C55 N3 1.27(3) 2_756 ?
C55 C54 1.27(3) 2_756 ?
C54' C55' 1.24(4) 2_756 ?
C55' N3' 1.24(4) 2_756 ?
C55' C54' 1.24(4) 2_756 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O12 Eu1 O8 97.7(4) . 1_565 ?
O12 Eu1 O1 80.8(4) . . ?
O8 Eu1 O1 84.4(3) 1_565 . ?
O12 Eu1 O23 71.4(4) . . ?
O8 Eu1 O23 78.8(4) 1_565 . ?
O1 Eu1 O23 144.9(4) . . ?
O12 Eu1 O20 147.8(3) . 2_666 ?
O8 Eu1 O20 78.6(4) 1_565 2_666 ?
O1 Eu1 O20 129.8(4) . 2_666 ?
O23 Eu1 O20 76.6(4) . 2_666 ?
O12 Eu1 O19 159.0(3) . 2_666 ?
O8 Eu1 O19 87.9(4) 1_565 2_666 ?
O1 Eu1 O19 79.7(3) . 2_666 ?
O23 Eu1 O19 129.6(4) . 2_666 ?
O20 Eu1 O19 53.1(3) 2_666 2_666 ?
O12 Eu1 O6 85.7(4) . 1_665 ?
O8 Eu1 O6 158.5(3) 1_565 1_665 ?
O1 Eu1 O6 75.1(3) . 1_665 ?
O23 Eu1 O6 122.1(4) . 1_665 ?
O20 Eu1 O6 109.5(4) 2_666 1_665 ?
O19 Eu1 O6 82.0(4) 2_666 1_665 ?
O12 Eu1 O5 93.8(4) . 1_665 ?
O8 Eu1 O5 148.7(3) 1_565 1_665 ?
O1 Eu1 O5 126.3(3) . 1_665 ?
O23 Eu1 O5 77.5(4) . 1_665 ?
O20 Eu1 O5 76.2(3) 2_666 1_665 ?
O19 Eu1 O5 91.6(4) 2_666 1_665 ?
O6 Eu1 O5 51.2(3) 1_665 1_665 ?
O12 Eu1 C52 174.3(4) . 2_666 ?
O8 Eu1 C52 80.0(4) 1_565 2_666 ?
O1 Eu1 C52 104.1(4) . 2_666 ?
O23 Eu1 C52 102.9(4) . 2_666 ?
O20 Eu1 C52 26.7(4) 2_666 2_666 ?
O19 Eu1 C52 26.6(3) 2_666 2_666 ?
O6 Eu1 C52 98.4(4) 1_665 2_666 ?
O5 Eu1 C52 85.7(4) 1_665 2_666 ?
O12 Eu1 C22 89.1(4) . 1_665 ?
O8 Eu1 C22 172.4(4) 1_565 1_665 ?
O1 Eu1 C22 100.1(3) . 1_665 ?
O23 Eu1 C22 100.4(4) . 1_665 ?
O20 Eu1 C22 93.9(4) 2_666 1_665 ?
O19 Eu1 C22 86.9(4) 2_666 1_665 ?
O6 Eu1 C22 24.9(3) 1_665 1_665 ?
O5 Eu1 C22 26.3(3) 1_665 1_665 ?
C52 Eu1 C22 93.0(5) 2_666 1_665 ?
O13 Eu2 O9 87.4(4) 1_545 . ?
O13 Eu2 O3 85.2(4) 1_545 . ?
O9 Eu2 O3 77.0(3) . . ?
O13 Eu2 O24 108.5(4) 1_545 . ?
O9 Eu2 O24 73.8(3) . . ?
O3 Eu2 O24 146.9(3) . . ?
O13 Eu2 O16 146.7(4) 1_545 1_445 ?
O9 Eu2 O16 125.9(3) . 1_445 ?
O3 Eu2 O16 101.2(4) . 1_445 ?
O24 Eu2 O16 83.9(4) . 1_445 ?
O13 Eu2 O25 77.3(4) 1_545 . ?
O9 Eu2 O25 136.1(4) . . ?
O3 Eu2 O25 140.4(4) . . ?
O24 Eu2 O25 72.8(3) . . ?
O16 Eu2 O25 77.2(4) 1_445 . ?
O13 Eu2 O27 76.6(5) 1_545 . ?
O9 Eu2 O27 144.9(5) . . ?
O3 Eu2 O27 70.7(4) . . ?
O24 Eu2 O27 140.9(4) . . ?
O16 Eu2 O27 74.9(5) 1_445 . ?
O25 Eu2 O27 70.7(5) . . ?
O13 Eu2 O15 160.1(3) 1_545 1_445 ?
O9 Eu2 O15 73.8(3) . 1_445 ?
O3 Eu2 O15 84.3(3) . 1_445 ?
O24 Eu2 O15 72.9(3) . 1_445 ?
O16 Eu2 O15 52.5(3) 1_445 1_445 ?
O25 Eu2 O15 120.9(3) . 1_445 ?
O27 Eu2 O15 115.4(4) . 1_445 ?
O13 Eu2 C43 172.5(4) 1_545 1_445 ?
O9 Eu2 C43 99.7(4) . 1_445 ?
O3 Eu2 C43 93.8(4) . 1_445 ?
O24 Eu2 C43 76.3(4) . 1_445 ?
O16 Eu2 C43 26.4(3) 1_445 1_445 ?
O25 Eu2 C43 99.1(4) . 1_445 ?
O27 Eu2 C43 96.0(5) . 1_445 ?
O15 Eu2 C43 26.1(3) 1_445 1_445 ?
O10 Eu3 O7 88.7(3) . 1_665 ?
O10 Eu3 O2 137.0(4) . 1_655 ?
O7 Eu3 O2 85.8(3) 1_665 1_655 ?
O10 Eu3 O14 82.0(3) . 1_545 ?
O7 Eu3 O14 151.9(4) 1_665 1_545 ?
O2 Eu3 O14 83.3(3) 1_655 1_545 ?
O10 Eu3 O26 63.9(3) . . ?
O7 Eu3 O26 77.2(3) 1_665 . ?
O2 Eu3 O26 73.4(4) 1_655 . ?
O14 Eu3 O26 74.9(3) 1_545 . ?
O10 Eu3 O17 134.9(3) . . ?
O7 Eu3 O17 127.7(4) 1_665 . ?
O2 Eu3 O17 78.2(3) 1_655 . ?
O14 Eu3 O17 74.9(4) 1_545 . ?
O26 Eu3 O17 140.4(3) . . ?
O10 Eu3 O4 77.0(3) . . ?
O7 Eu3 O4 77.9(3) 1_665 . ?
O2 Eu3 O4 142.1(4) 1_655 . ?
O14 Eu3 O4 124.9(3) 1_545 . ?
O26 Eu3 O4 133.5(3) . . ?
O17 Eu3 O4 85.2(3) . . ?
O10 Eu3 O18 147.1(3) . . ?
O7 Eu3 O18 76.5(3) 1_665 . ?
O2 Eu3 O18 71.8(4) 1_655 . ?
O14 Eu3 O18 123.6(3) 1_545 . ?
O26 Eu3 O18 137.3(4) . . ?
O17 Eu3 O18 51.3(3) . . ?
O4 Eu3 O18 71.3(3) . . ?
O10 Eu3 C45 152.3(4) . . ?
O7 Eu3 C45 101.8(4) 1_665 . ?
O2 Eu3 C45 70.0(4) 1_655 . ?
O14 Eu3 C45 98.6(4) 1_545 . ?
O26 Eu3 C45 143.3(4) . . ?
O17 Eu3 C45 26.1(4) . . ?
O4 Eu3 C45 80.2(4) . . ?
O18 Eu3 C45 25.6(4) . . ?
O10 Eu3 O3 67.6(3) . . ?
O7 Eu3 O3 119.5(3) 1_665 . ?
O2 Eu3 O3 148.2(3) 1_655 . ?
O14 Eu3 O3 81.2(3) 1_545 . ?
O26 Eu3 O3 128.0(3) . . ?
O17 Eu3 O3 71.0(3) . . ?
O4 Eu3 O3 43.7(3) . . ?
O18 Eu3 O3 94.2(3) . . ?
C45 Eu3 O3 85.1(4) . . ?
O10 Eu3 C20 72.3(4) . . ?
O7 Eu3 C20 98.1(3) 1_665 . ?
O2 Eu3 C20 150.7(4) 1_655 . ?
O14 Eu3 C20 104.1(4) 1_545 . ?
O26 Eu3 C20 135.9(4) . . ?
O17 Eu3 C20 76.6(3) . . ?
O4 Eu3 C20 20.8(3) . . ?
O18 Eu3 C20 80.9(4) . . ?
C45 Eu3 C20 80.8(4) . . ?
O3 Eu3 C20 22.9(3) . . ?
C31 N1 C33 120.6(13) . . ?
C13 N2 C11 121.0(13) . . ?
C1 O1 Eu1 150.8(9) . . ?
C1 O2 Eu3 150.7(10) . 1_455 ?
C20 O3 Eu2 144.5(10) . . ?
C20 O3 Eu3 78.8(8) . . ?
Eu2 O3 Eu3 116.2(4) . . ?
C20 O4 Eu3 112.4(9) . . ?
C22 O5 Eu1 91.1(8) . 1_445 ?
C22 O6 Eu1 95.4(8) . 1_445 ?
C21 O7 Eu3 145.4(9) . 1_445 ?
C21 O8 Eu1 175.1(11) . 1_545 ?
C23 O9 Eu2 133.8(9) . . ?
C23 O10 Eu3 143.5(10) . . ?
C42 O12 Eu1 137.2(10) . . ?
C44 O13 Eu2 156.4(11) . 1_565 ?
C44 O14 Eu3 138.7(9) . 1_565 ?
C43 O15 Eu2 90.1(7) . 1_665 ?
C43 O16 Eu2 94.6(8) . 1_665 ?
C45 O17 Eu3 96.9(9) . . ?
C45 O18 Eu3 92.0(10) . . ?
C52 O19 Eu1 92.7(9) . 2_666 ?
C52 O20 Eu1 92.7(9) . 2_666 ?
O1 C1 O2 123.5(11) . . ?
O1 C1 C2 118.7(11) . . ?
O2 C1 C2 117.7(11) . . ?
C7 C2 C3 117.3(11) . . ?
C7 C2 C1 119.9(11) . . ?
C3 C2 C1 122.6(11) . . ?
C4 C3 C2 122.0(12) . . ?
C3 C4 C5 118.3(12) . . ?
C3 C4 C20 121.6(12) . . ?
C5 C4 C20 120.1(11) . . ?
C6 C5 C4 120.9(11) . . ?
C5 C6 C7 118.0(12) . . ?
C5 C6 C8 119.8(11) . . ?
C7 C6 C8 121.9(12) . . ?
C2 C7 C6 123.4(12) . . ?
C13 C8 C9 117.2(13) . . ?
C13 C8 C6 122.4(12) . . ?
C9 C8 C6 120.4(13) . . ?
C10 C9 C8 119.9(15) . . ?
C11 C10 C9 123.8(14) . . ?
C10 C11 N2 116.6(13) . . ?
C10 C11 C14 122.0(12) . . ?
N2 C11 C14 121.3(13) . . ?
N2 C13 C8 121.5(13) . . ?
C15 C14 C19 117.7(12) . . ?
C15 C14 C11 120.5(12) . . ?
C19 C14 C11 121.7(11) . . ?
C14 C15 C16 122.1(13) . . ?
C17 C16 C15 119.7(13) . . ?
C17 C16 C21 119.9(12) . . ?
C15 C16 C21 120.3(12) . . ?
C16 C17 C18 119.8(13) . . ?
C19 C18 C17 120.6(12) . . ?
C19 C18 C22 121.0(11) . . ?
C17 C18 C22 118.4(12) . . ?
C18 C19 C14 120.1(11) . . ?
O4 C20 O3 124.9(13) . . ?
O4 C20 C4 119.1(12) . . ?
O3 C20 C4 116.0(12) . . ?
O4 C20 Eu3 46.8(7) . . ?
O3 C20 Eu3 78.3(8) . . ?
C4 C20 Eu3 164.8(10) . . ?
O8 C21 O7 126.7(13) . . ?
O8 C21 C16 119.2(12) . . ?
O7 C21 C16 114.0(12) . . ?
O6 C22 O5 122.2(13) . . ?
O6 C22 C18 119.5(12) . . ?
O5 C22 C18 118.3(12) . . ?
O6 C22 Eu1 59.6(7) . 1_445 ?
O5 C22 Eu1 62.6(7) . 1_445 ?
C18 C22 Eu1 177.7(10) . 1_445 ?
O9 C23 O10 124.9(13) . . ?
O9 C23 C24 117.8(13) . . ?
O10 C23 C24 117.0(13) . . ?
C29 C24 C25 120.0(12) . . ?
C29 C24 C23 117.3(12) . . ?
C25 C24 C23 122.5(13) . . ?
C24 C25 C26 120.0(13) . . ?
C27 C26 C25 119.7(13) . . ?
C27 C26 C30 117.4(12) . . ?
C25 C26 C30 122.7(13) . . ?
C26 C27 C28 121.2(12) . . ?
C29 C28 C27 118.0(13) . . ?
C29 C28 C42 121.1(13) . . ?
C27 C28 C42 120.7(12) . . ?
C24 C29 C28 120.8(13) . . ?
C35 C30 C31 117.9(13) . . ?
C35 C30 C26 119.0(13) . . ?
C31 C30 C26 123.0(12) . . ?
N1 C31 C30 119.6(13) . . ?
C34 C33 N1 116.9(13) . . ?
C34 C33 C36 124.2(13) . . ?
N1 C33 C36 118.8(12) . . ?
C33 C34 C35 125.2(15) . . ?
C34 C35 C30 118.6(14) . . ?
C37 C36 C41 119.3(13) . . ?
C37 C36 C33 123.9(13) . . ?
C41 C36 C33 116.8(13) . . ?
C36 C37 C38 122.5(13) . . ?
C37 C38 C39 120.1(12) . . ?
C37 C38 C43 121.0(12) . . ?
C39 C38 C43 118.8(12) . . ?
C38 C39 C40 119.4(12) . . ?
C41 C40 C39 117.5(12) . . ?
C41 C40 C44 121.1(12) . . ?
C39 C40 C44 121.4(12) . . ?
C36 C41 C40 121.0(13) . . ?
O12 C42 O11 126.5(13) . . ?
O12 C42 C28 116.8(13) . . ?
O11 C42 C28 116.6(12) . . ?
O15 C43 O16 122.6(12) . . ?
O15 C43 C38 121.4(11) . . ?
O16 C43 C38 116.0(12) . . ?
O15 C43 Eu2 63.7(7) . 1_665 ?
O16 C43 Eu2 59.0(7) . 1_665 ?
C38 C43 Eu2 174.2(10) . 1_665 ?
O14 C44 O13 125.6(13) . . ?
O14 C44 C40 118.3(12) . . ?
O13 C44 C40 116.2(13) . . ?
O18 C45 O17 118.0(15) . . ?
O18 C45 C46 122.1(16) . . ?
O17 C45 C46 119.9(14) . . ?
O18 C45 Eu3 62.4(9) . . ?
O17 C45 Eu3 57.0(8) . . ?
C46 C45 Eu3 169.0(12) . . ?
C51 C46 C47 118.1(15) . . ?
C51 C46 C45 122.0(14) . . ?
C47 C46 C45 119.8(15) . . ?
C48 C47 C46 118.8(16) . . ?
C49 C48 C47 122.9(15) . . ?
C49 C48 C53 120.0(15) . . ?
C47 C48 C53 116.9(15) . . ?
C48 C49 C50 120.2(16) . . ?
C51 C50 C49 116.7(15) . . ?
C51 C50 C52 123.8(13) . . ?
C49 C50 C52 119.4(14) . . ?
C46 C51 C50 123.1(14) . . ?
O19 C52 O20 120.5(15) . . ?
O19 C52 C50 118.6(14) . . ?
O20 C52 C50 120.8(13) . . ?
O19 C52 Eu1 60.7(8) . 2_666 ?
O20 C52 Eu1 60.7(8) . 2_666 ?
C50 C52 Eu1 170.5(11) . 2_666 ?
C55 C53 C54 111.1(19) . . ?
C55 C53 C54' 84(2) . . ?
C54 C53 C54' 64(2) . . ?
C55 C53 C55' 52(2) . . ?
C54 C53 C55' 85(2) . . ?
C54' C53 C55' 113(2) . . ?
C55 C53 C48 126(2) . . ?
C54 C53 C48 122.6(18) . . ?
C54' C53 C48 121.7(19) . . ?
C55' C53 C48 124.9(19) . . ?
C55 C54 C53 121(3) 2_756 . ?
N3 C55 C54 0(3) 2_756 2_756 ?
N3 C55 C53 127(3) 2_756 . ?
C54 C55 C53 127(3) 2_756 . ?
C55' C54' C53 120(3) 2_756 . ?
N3' C55' C54' 0(3) 2_756 2_756 ?
N3' C55' C53 125(3) 2_756 . ?
C54' C55' C53 125(3) 2_756 . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        67.25
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         2.485
_refine_diff_density_min         -1.334
_refine_diff_density_rms         0.206
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.238 0.443 0.500 709 242 ' '
_platon_squeeze_details          
;
;
