# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_audit_block_doi                 10.5517/cc1jf7gn
_database_code_depnum_ccdc_archive 'CCDC 1412901'
_audit_update_record             
;
2015-07-15 deposited with the CCDC.
2015-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C36 H92 Cl2 Eu2 O20 Ti4 '
_chemical_formula_sum            'C36 H92 Cl2 Eu2 O20 Ti4'
_chemical_formula_weight         1411.52

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ti Ti 0.2776 0.4457 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.9475(7)
_cell_length_b                   18.9968(13)
_cell_length_c                   12.7731(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 92.489(2)
_cell_angle_gamma                90.00
_cell_volume                     2896.3(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9859
_cell_measurement_theta_min      2.52
_cell_measurement_theta_max      24.98

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.619
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1432
_exptl_absorpt_coefficient_mu    2.812
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4961
_exptl_absorpt_correction_T_max  0.6464
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            26482
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_av_sigmaI/netI    0.0237
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.14
_diffrn_reflns_theta_max         25.04
_reflns_number_total             5091
_reflns_number_gt                4712
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0349P)²+3.8544P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5091
_refine_ls_number_parameters     289
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0257
_refine_ls_R_factor_gt           0.0230
_refine_ls_wR_factor_ref         0.0636
_refine_ls_wR_factor_gt          0.0615
_refine_ls_goodness_of_fit_ref   1.008
_refine_ls_restrained_S_all      1.008
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.618940(11) 0.041182(7) 0.081643(10) 0.01856(6) Uani 1 1 d . . .
Ti1 Ti 0.50411(4) 0.16414(3) -0.07412(4) 0.02087(12) Uani 1 1 d . . .
Ti2 Ti 0.60936(4) 0.04525(2) -0.17723(4) 0.02031(12) Uani 1 1 d . . .
Cl1 Cl 0.77222(7) 0.11153(4) 0.20048(7) 0.0411(2) Uani 1 1 d . . .
O1 O 0.73441(19) -0.05390(11) 0.15585(19) 0.0348(5) Uani 1 1 d . . .
H1 H 0.7272 -0.0882 0.1133 0.042 Uiso 1 1 d R . .
O2 O 0.49645(16) 0.06009(10) -0.06741(14) 0.0184(4) Uani 1 1 d . . .
O3 O 0.52259(17) 0.15539(10) 0.07662(15) 0.0246(4) Uani 1 1 d . . .
O4 O 0.67280(16) 0.12183(10) -0.07017(15) 0.0230(4) Uani 1 1 d . . .
O5 O 0.52918(18) 0.13373(11) -0.22702(15) 0.0289(5) Uani 1 1 d . . .
O6 O 0.68666(16) -0.01472(10) -0.07680(15) 0.0242(4) Uani 1 1 d . . .
O7 O 0.35098(17) 0.17905(10) -0.09662(16) 0.0276(5) Uani 1 1 d . . .
O8 O 0.55056(19) 0.25306(11) -0.08802(19) 0.0356(5) Uani 1 1 d . . .
O9 O 0.70809(18) 0.04856(11) -0.27857(17) 0.0289(5) Uani 1 1 d . . .
O10 O 0.50441(18) -0.02414(11) -0.22941(15) 0.0258(4) Uani 1 1 d . . .
C1 C 0.8445(4) -0.0607(3) 0.2040(4) 0.0663(13) Uani 1 1 d . . .
H1A H 0.8842 -0.0179 0.1910 0.080 Uiso 1 1 d R . .
H1B H 0.8832 -0.0982 0.1704 0.080 Uiso 1 1 d R . .
C1' C 0.8422(7) -0.0739(4) 0.3123(5) 0.135(3) Uani 1 1 d . . .
H1'A H 0.9191 -0.0767 0.3371 0.161 Uiso 1 1 d R . .
H1'B H 0.8059 -0.0360 0.3474 0.161 Uiso 1 1 d R . .
H1'C H 0.8049 -0.1174 0.3265 0.161 Uiso 1 1 d R . .
C3 C 0.5423(3) 0.21217(17) 0.1483(3) 0.0372(8) Uani 1 1 d . . .
H3A H 0.6016 0.2412 0.1238 0.045 Uiso 1 1 d R . .
H3B H 0.5660 0.1937 0.2156 0.045 Uiso 1 1 d R . .
C3' C 0.4397(4) 0.2559(2) 0.1612(3) 0.0566(11) Uani 1 1 d . . .
H3'A H 0.4558 0.2935 0.2096 0.068 Uiso 1 1 d R . .
H3'B H 0.4167 0.2751 0.0941 0.068 Uiso 1 1 d R . .
H3'C H 0.3807 0.2271 0.1868 0.068 Uiso 1 1 d R . .
C4 C 0.7684(3) 0.16658(17) -0.0801(3) 0.0339(7) Uani 1 1 d . . .
H4A H 0.7691 0.2017 -0.0260 0.041 Uiso 1 1 d R . .
H4B H 0.7625 0.1902 -0.1465 0.041 Uiso 1 1 d R . .
C4' C 0.8767(3) 0.1269(2) -0.0719(3) 0.0436(9) Uani 1 1 d . . .
H4'A H 0.9387 0.1584 -0.0789 0.052 Uiso 1 1 d R . .
H4'B H 0.8833 0.1039 -0.0050 0.052 Uiso 1 1 d R . .
H4'C H 0.8767 0.0923 -0.1267 0.052 Uiso 1 1 d R . .
C5' C 0.4572(4) 0.2185(3) -0.3546(3) 0.0694(14) Uani 1 1 d . . .
H5'A H 0.4762 0.2437 -0.4164 0.083 Uiso 1 1 d R . .
H5'B H 0.3939 0.1886 -0.3705 0.083 Uiso 1 1 d R . .
H5'C H 0.4388 0.2513 -0.3008 0.083 Uiso 1 1 d R . .
C5 C 0.5457(5) 0.1745(3) -0.3165(3) 0.0705(14) Uani 1 1 d . . .
H5A H 0.5646 0.1429 -0.3716 0.085 Uiso 1 1 d R . .
H5B H 0.6089 0.2049 -0.3027 0.085 Uiso 1 1 d R . .
C6 C 0.7421(3) -0.07842(16) -0.1036(3) 0.0321(7) Uani 1 1 d . . .
H6A H 0.7167 -0.0924 -0.1728 0.038 Uiso 1 1 d R . .
H6B H 0.7219 -0.1148 -0.0559 0.038 Uiso 1 1 d R . .
C6' C 0.8666(3) -0.0700(2) -0.1014(4) 0.0562(11) Uani 1 1 d . . .
H6'A H 0.8998 -0.1140 -0.1200 0.067 Uiso 1 1 d R . .
H6'B H 0.8874 -0.0343 -0.1501 0.067 Uiso 1 1 d R . .
H6'C H 0.8926 -0.0570 -0.0319 0.067 Uiso 1 1 d R . .
C7 C 0.2861(3) 0.23957(18) -0.1251(3) 0.0390(8) Uani 1 1 d . . .
H7A H 0.2598 0.2348 -0.1968 0.047 Uiso 1 1 d R . .
H7B H 0.3323 0.2809 -0.1196 0.047 Uiso 1 1 d R . .
C7' C 0.1872(3) 0.2478(2) -0.0590(3) 0.0486(9) Uani 1 1 d . . .
H7'A H 0.1445 0.2885 -0.0802 0.058 Uiso 1 1 d R . .
H7'B H 0.1407 0.2066 -0.0654 0.058 Uiso 1 1 d R . .
H7'C H 0.2138 0.2531 0.0125 0.058 Uiso 1 1 d R . .
C8 C 0.6117(4) 0.3153(2) -0.1063(5) 0.0707(14) Uani 1 1 d . . .
H8A H 0.6485 0.3109 -0.1714 0.085 Uiso 1 1 d R . .
H8B H 0.6685 0.3203 -0.0513 0.085 Uiso 1 1 d R . .
C8' C 0.5431(5) 0.3779(2) -0.1096(5) 0.0848(17) Uani 1 1 d . . .
H8'A H 0.5887 0.4185 -0.1215 0.102 Uiso 1 1 d R . .
H8'B H 0.4871 0.3735 -0.1655 0.102 Uiso 1 1 d R . .
H8'C H 0.5073 0.3831 -0.0442 0.102 Uiso 1 1 d R . .
C9' C 0.7595(5) 0.0539(3) -0.4577(3) 0.0690(14) Uani 1 1 d . . .
H9'A H 0.8162 0.0712 -0.5020 0.083 Uiso 1 1 d R . .
H9'B H 0.7547 0.0036 -0.4640 0.083 Uiso 1 1 d R . .
H9'C H 0.6886 0.0745 -0.4786 0.083 Uiso 1 1 d R . .
C9 C 0.7861(4) 0.0733(3) -0.3477(3) 0.0607(12) Uani 1 1 d . . .
H9A H 0.8577 0.0534 -0.3276 0.073 Uiso 1 1 d R . .
H9B H 0.7923 0.1236 -0.3420 0.073 Uiso 1 1 d R . .
C10 C 0.4817(4) -0.0436(2) -0.3365(3) 0.0460(10) Uani 1 1 d . . .
H10D H 0.4860 -0.0022 -0.3793 0.055 Uiso 1 1 d R . .
H10E H 0.4069 -0.0618 -0.3441 0.055 Uiso 1 1 d R . .
C10' C 0.5625(4) -0.0965(2) -0.3740(3) 0.0647(13) Uani 1 1 d . . .
H10A H 0.5451 -0.1082 -0.4460 0.078 Uiso 1 1 d R . .
H10B H 0.6372 -0.0780 -0.3673 0.078 Uiso 1 1 d R . .
H10C H 0.5574 -0.1381 -0.3317 0.078 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.3691(19) 3_655 ?
Eu1 O2 2.3777(18) . ?
Eu1 O1 2.439(2) . ?
Eu1 O6 2.454(2) . ?
Eu1 O3 2.4557(19) . ?
Eu1 O10 2.466(2) 3_655 ?
Eu1 O4 2.5749(19) . ?
Eu1 Cl1 2.6838(8) . ?
Eu1 Ti2 3.3046(6) . ?
Eu1 Ti1 3.3256(5) . ?
Eu1 Ti2 3.4519(6) 3_655 ?
Eu1 Eu1 3.7896(3) 3_655 ?
Eu1 H1 2.7981 . ?
Ti1 O8 1.789(2) . ?
Ti1 O7 1.861(2) . ?
Ti1 O3 1.936(2) . ?
Ti1 O2 1.9808(19) . ?
Ti1 O5 2.071(2) . ?
Ti1 O4 2.168(2) . ?
Ti1 Ti2 2.9260(7) . ?
Ti2 O9 1.790(2) . ?
Ti2 O10 1.919(2) . ?
Ti2 O6 1.922(2) . ?
Ti2 O2 2.0079(19) . ?
Ti2 O5 2.023(2) . ?
Ti2 O4 2.115(2) . ?
Ti2 Eu1 3.4520(6) 3_655 ?
O1 C1 1.434(5) . ?
O1 H1 0.8499 . ?
O2 Eu1 2.3692(19) 3_655 ?
O3 C3 1.428(4) . ?
O4 C4 1.434(3) . ?
O5 C5 1.402(5) . ?
O6 C6 1.429(4) . ?
O7 C7 1.425(4) . ?
O8 C8 1.414(4) . ?
O9 C9 1.393(4) . ?
O10 C10 1.431(4) . ?
O10 Eu1 2.466(2) 3_655 ?
C1 C1' 1.407(8) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9599 . ?
C1' H1'A 0.9600 . ?
C1' H1'B 0.9599 . ?
C1' H1'C 0.9602 . ?
C3 C3' 1.495(5) . ?
C3 H3A 0.9601 . ?
C3 H3B 0.9600 . ?
C3' H3'A 0.9598 . ?
C3' H3'B 0.9600 . ?
C3' H3'C 0.9600 . ?
C4 C4' 1.496(5) . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9599 . ?
C4' H4'A 0.9598 . ?
C4' H4'B 0.9600 . ?
C4' H4'C 0.9601 . ?
C5' C5 1.416(6) . ?
C5' H5'A 0.9600 . ?
C5' H5'B 0.9601 . ?
C5' H5'C 0.9600 . ?
C5 H5A 0.9601 . ?
C5 H5B 0.9601 . ?
C6 C6' 1.495(5) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9599 . ?
C6' H6'A 0.9601 . ?
C6' H6'B 0.9599 . ?
C6' H6'C 0.9599 . ?
C7 C7' 1.490(5) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9599 . ?
C7' H7'A 0.9598 . ?
C7' H7'B 0.9601 . ?
C7' H7'C 0.9600 . ?
C8 C8' 1.444(6) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8' H8'A 0.9599 . ?
C8' H8'B 0.9600 . ?
C8' H8'C 0.9599 . ?
C9' C9 1.475(6) . ?
C9' H9'A 0.9600 . ?
C9' H9'B 0.9601 . ?
C9' H9'C 0.9600 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C10 C10' 1.489(6) . ?
C10 H10D 0.9599 . ?
C10 H10E 0.9600 . ?
C10' H10A 0.9600 . ?
C10' H10B 0.9600 . ?
C10' H10C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O2 74.06(7) 3_655 . ?
O2 Eu1 O1 75.28(7) 3_655 . ?
O2 Eu1 O1 137.81(7) . . ?
O2 Eu1 O6 78.28(6) 3_655 . ?
O2 Eu1 O6 67.57(6) . . ?
O1 Eu1 O6 78.39(7) . . ?
O2 Eu1 O3 116.41(7) 3_655 . ?
O2 Eu1 O3 64.79(6) . . ?
O1 Eu1 O3 157.06(7) . . ?
O6 Eu1 O3 122.13(6) . . ?
O2 Eu1 O10 65.61(6) 3_655 3_655 ?
O2 Eu1 O10 105.38(7) . 3_655 ?
O1 Eu1 O10 87.25(8) . 3_655 ?
O6 Eu1 O10 143.51(7) . 3_655 ?
O3 Eu1 O10 80.85(7) . 3_655 ?
O2 Eu1 O4 126.09(6) 3_655 . ?
O2 Eu1 O4 58.15(6) . . ?
O1 Eu1 O4 125.28(7) . . ?
O6 Eu1 O4 62.24(6) . . ?
O3 Eu1 O4 65.59(6) . . ?
O10 Eu1 O4 146.28(7) 3_655 . ?
O2 Eu1 Cl1 145.92(5) 3_655 . ?
O2 Eu1 Cl1 139.36(5) . . ?
O1 Eu1 Cl1 77.79(5) . . ?
O6 Eu1 Cl1 116.15(5) . . ?
O3 Eu1 Cl1 83.25(5) . . ?
O10 Eu1 Cl1 92.77(5) 3_655 . ?
O4 Eu1 Cl1 86.73(5) . . ?
O2 Eu1 Ti2 86.99(5) 3_655 . ?
O2 Eu1 Ti2 37.05(5) . . ?
O1 Eu1 Ti2 113.61(6) . . ?
O6 Eu1 Ti2 35.22(5) . . ?
O3 Eu1 Ti2 87.56(5) . . ?
O10 Eu1 Ti2 140.63(5) 3_655 . ?
O4 Eu1 Ti2 39.78(4) . . ?
Cl1 Eu1 Ti2 123.19(2) . . ?
O2 Eu1 Ti1 107.51(5) 3_655 . ?
O2 Eu1 Ti1 36.03(5) . . ?
O1 Eu1 Ti1 164.62(6) . . ?
O6 Eu1 Ti1 87.29(5) . . ?
O3 Eu1 Ti1 35.22(5) . . ?
O10 Eu1 Ti1 107.78(5) 3_655 . ?
O4 Eu1 Ti1 40.68(4) . . ?
Cl1 Eu1 Ti1 104.02(2) . . ?
Ti2 Eu1 Ti1 52.374(12) . . ?
O2 Eu1 Ti2 34.39(5) 3_655 3_655 ?
O2 Eu1 Ti2 83.50(5) . 3_655 ?
O1 Eu1 Ti2 87.28(6) . 3_655 ?
O6 Eu1 Ti2 112.32(5) . 3_655 ?
O3 Eu1 Ti2 93.03(5) . 3_655 ?
O10 Eu1 Ti2 32.77(5) 3_655 3_655 ?
O4 Eu1 Ti2 140.95(4) . 3_655 ?
Cl1 Eu1 Ti2 124.55(2) . 3_655 ?
Ti2 Eu1 Ti2 111.808(11) . 3_655 ?
Ti1 Eu1 Ti2 103.526(13) . 3_655 ?
O2 Eu1 Eu1 37.11(4) 3_655 3_655 ?
O2 Eu1 Eu1 36.95(4) . 3_655 ?
O1 Eu1 Eu1 107.82(5) . 3_655 ?
O6 Eu1 Eu1 68.51(5) . 3_655 ?
O3 Eu1 Eu1 90.63(5) . 3_655 ?
O10 Eu1 Eu1 84.73(5) 3_655 3_655 ?
O4 Eu1 Eu1 92.13(4) . 3_655 ?
Cl1 Eu1 Eu1 173.69(2) . 3_655 ?
Ti2 Eu1 Eu1 57.750(10) . 3_655 ?
Ti1 Eu1 Eu1 71.378(10) . 3_655 ?
Ti2 Eu1 Eu1 54.058(10) 3_655 3_655 ?
O2 Eu1 H1 64.0 3_655 . ?
O2 Eu1 H1 120.9 . . ?
O1 Eu1 H1 17.0 . . ?
O6 Eu1 H1 64.7 . . ?
O3 Eu1 H1 173.2 . . ?
O10 Eu1 H1 93.6 3_655 . ?
O4 Eu1 H1 120.1 . . ?
Cl1 Eu1 H1 93.2 . . ?
Ti2 Eu1 H1 99.3 . . ?
Ti1 Eu1 H1 151.6 . . ?
Ti2 Eu1 H1 84.2 3_655 . ?
Eu1 Eu1 H1 92.7 3_655 . ?
O8 Ti1 O7 98.51(10) . . ?
O8 Ti1 O3 99.05(10) . . ?
O7 Ti1 O3 103.63(9) . . ?
O8 Ti1 O2 164.05(10) . . ?
O7 Ti1 O2 96.41(8) . . ?
O3 Ti1 O2 82.81(8) . . ?
O8 Ti1 O5 96.41(10) . . ?
O7 Ti1 O5 94.49(9) . . ?
O3 Ti1 O5 154.05(8) . . ?
O2 Ti1 O5 76.78(8) . . ?
O8 Ti1 O4 93.45(9) . . ?
O7 Ti1 O4 165.11(9) . . ?
O3 Ti1 O4 83.06(8) . . ?
O2 Ti1 O4 70.96(7) . . ?
O5 Ti1 O4 75.29(8) . . ?
O8 Ti1 Ti2 122.88(8) . . ?
O7 Ti1 Ti2 119.13(7) . . ?
O3 Ti1 Ti2 110.41(6) . . ?
O2 Ti1 Ti2 43.17(6) . . ?
O5 Ti1 Ti2 43.74(6) . . ?
O4 Ti1 Ti2 46.14(5) . . ?
O8 Ti1 Eu1 126.92(8) . . ?
O7 Ti1 Eu1 125.20(6) . . ?
O3 Ti1 Eu1 47.03(6) . . ?
O2 Ti1 Eu1 44.91(5) . . ?
O5 Ti1 Eu1 107.18(6) . . ?
O4 Ti1 Eu1 50.72(5) . . ?
Ti2 Ti1 Eu1 63.444(14) . . ?
O9 Ti2 O10 102.37(9) . . ?
O9 Ti2 O6 101.01(9) . . ?
O10 Ti2 O6 96.46(9) . . ?
O9 Ti2 O2 169.81(9) . . ?
O10 Ti2 O2 83.70(8) . . ?
O6 Ti2 O2 86.26(8) . . ?
O9 Ti2 O5 93.52(9) . . ?
O10 Ti2 O5 99.68(9) . . ?
O6 Ti2 O5 155.42(9) . . ?
O2 Ti2 O5 77.27(8) . . ?
O9 Ti2 O4 102.39(9) . . ?
O10 Ti2 O4 155.20(8) . . ?
O6 Ti2 O4 80.08(8) . . ?
O2 Ti2 O4 71.60(8) . . ?
O5 Ti2 O4 77.48(8) . . ?
O9 Ti2 Ti1 127.45(7) . . ?
O10 Ti2 Ti1 113.54(7) . . ?
O6 Ti2 Ti1 111.13(6) . . ?
O2 Ti2 Ti1 42.46(5) . . ?
O5 Ti2 Ti1 45.04(6) . . ?
O4 Ti2 Ti1 47.68(5) . . ?
O9 Ti2 Eu1 136.82(8) . . ?
O10 Ti2 Eu1 108.98(6) . . ?
O6 Ti2 Eu1 47.42(6) . . ?
O2 Ti2 Eu1 45.52(5) . . ?
O5 Ti2 Eu1 109.22(6) . . ?
O4 Ti2 Eu1 51.18(5) . . ?
Ti1 Ti2 Eu1 64.183(14) . . ?
O9 Ti2 Eu1 145.92(7) . 3_655 ?
O10 Ti2 Eu1 44.07(6) . 3_655 ?
O6 Ti2 Eu1 81.15(6) . 3_655 ?
O2 Ti2 Eu1 41.80(5) . 3_655 ?
O5 Ti2 Eu1 97.80(6) . 3_655 ?
O4 Ti2 Eu1 111.41(5) . 3_655 ?
Ti1 Ti2 Eu1 81.157(17) . 3_655 ?
Eu1 Ti2 Eu1 68.193(11) . 3_655 ?
C1 O1 Eu1 136.6(2) . . ?
C1 O1 H1 105.7 . . ?
Eu1 O1 H1 106.2 . . ?
Ti1 O2 Ti2 94.37(8) . . ?
Ti1 O2 Eu1 146.60(9) . 3_655 ?
Ti2 O2 Eu1 103.81(8) . 3_655 ?
Ti1 O2 Eu1 99.06(8) . . ?
Ti2 O2 Eu1 97.43(7) . . ?
Eu1 O2 Eu1 105.94(7) 3_655 . ?
C3 O3 Ti1 125.56(19) . . ?
C3 O3 Eu1 125.92(18) . . ?
Ti1 O3 Eu1 97.75(8) . . ?
C4 O4 Ti2 127.98(18) . . ?
C4 O4 Ti1 121.44(18) . . ?
Ti2 O4 Ti1 86.17(7) . . ?
C4 O4 Eu1 130.18(18) . . ?
Ti2 O4 Eu1 89.05(7) . . ?
Ti1 O4 Eu1 88.60(7) . . ?
C5 O5 Ti2 129.3(2) . . ?
C5 O5 Ti1 130.2(2) . . ?
Ti2 O5 Ti1 91.22(8) . . ?
C6 O6 Ti2 123.81(18) . . ?
C6 O6 Eu1 137.52(18) . . ?
Ti2 O6 Eu1 97.35(8) . . ?
C7 O7 Ti1 133.0(2) . . ?
C8 O8 Ti1 165.9(3) . . ?
C9 O9 Ti2 161.8(3) . . ?
C10 O10 Ti2 127.1(2) . . ?
C10 O10 Eu1 127.1(2) . 3_655 ?
Ti2 O10 Eu1 103.16(8) . 3_655 ?
C1' C1 O1 112.4(5) . . ?
C1' C1 H1A 110.6 . . ?
O1 C1 H1A 107.5 . . ?
C1' C1 H1B 109.8 . . ?
O1 C1 H1B 109.1 . . ?
H1A C1 H1B 107.4 . . ?
C1 C1' H1'A 106.0 . . ?
C1 C1' H1'B 110.8 . . ?
H1'A C1' H1'B 109.5 . . ?
C1 C1' H1'C 111.6 . . ?
H1'A C1' H1'C 109.5 . . ?
H1'B C1' H1'C 109.5 . . ?
O3 C3 C3' 112.1(3) . . ?
O3 C3 H3A 109.1 . . ?
C3' C3 H3A 109.7 . . ?
O3 C3 H3B 109.4 . . ?
C3' C3 H3B 108.4 . . ?
H3A C3 H3B 108.0 . . ?
C3 C3' H3'A 110.1 . . ?
C3 C3' H3'B 108.5 . . ?
H3'A C3' H3'B 109.5 . . ?
C3 C3' H3'C 109.8 . . ?
H3'A C3' H3'C 109.5 . . ?
H3'B C3' H3'C 109.5 . . ?
O4 C4 C4' 112.6(3) . . ?
O4 C4 H4A 109.2 . . ?
C4' C4 H4A 108.6 . . ?
O4 C4 H4B 109.1 . . ?
C4' C4 H4B 109.1 . . ?
H4A C4 H4B 108.0 . . ?
C4 C4' H4'A 110.4 . . ?
C4 C4' H4'B 109.2 . . ?
H4'A C4' H4'B 109.5 . . ?
C4 C4' H4'C 108.8 . . ?
H4'A C4' H4'C 109.5 . . ?
H4'B C4' H4'C 109.5 . . ?
C5 C5' H5'A 112.2 . . ?
C5 C5' H5'B 107.1 . . ?
H5'A C5' H5'B 109.5 . . ?
C5 C5' H5'C 109.2 . . ?
H5'A C5' H5'C 109.5 . . ?
H5'B C5' H5'C 109.5 . . ?
O5 C5 C5' 118.4(4) . . ?
O5 C5 H5A 107.3 . . ?
C5' C5 H5A 108.2 . . ?
O5 C5 H5B 108.7 . . ?
C5' C5 H5B 106.2 . . ?
H5A C5 H5B 107.6 . . ?
O6 C6 C6' 112.1(3) . . ?
O6 C6 H6A 108.9 . . ?
C6' C6 H6A 108.8 . . ?
O6 C6 H6B 109.0 . . ?
C6' C6 H6B 110.0 . . ?
H6A C6 H6B 107.8 . . ?
C6 C6' H6'A 108.9 . . ?
C6 C6' H6'B 110.4 . . ?
H6'A C6' H6'B 109.5 . . ?
C6 C6' H6'C 109.1 . . ?
H6'A C6' H6'C 109.5 . . ?
H6'B C6' H6'C 109.5 . . ?
O7 C7 C7' 112.1(3) . . ?
O7 C7 H7A 108.6 . . ?
C7' C7 H7A 108.3 . . ?
O7 C7 H7B 109.7 . . ?
C7' C7 H7B 109.9 . . ?
H7A C7 H7B 108.1 . . ?
C7 C7' H7'A 110.5 . . ?
C7 C7' H7'B 109.7 . . ?
H7'A C7' H7'B 109.5 . . ?
C7 C7' H7'C 108.2 . . ?
H7'A C7' H7'C 109.5 . . ?
H7'B C7' H7'C 109.5 . . ?
O8 C8 C8' 113.4(4) . . ?
O8 C8 H8A 109.2 . . ?
C8' C8 H8A 109.1 . . ?
O8 C8 H8B 108.4 . . ?
C8' C8 H8B 108.7 . . ?
H8A C8 H8B 107.9 . . ?
C8 C8' H8'A 109.9 . . ?
C8 C8' H8'B 109.1 . . ?
H8'A C8' H8'B 109.5 . . ?
C8 C8' H8'C 109.4 . . ?
H8'A C8' H8'C 109.5 . . ?
H8'B C8' H8'C 109.5 . . ?
C9 C9' H9'A 110.3 . . ?
C9 C9' H9'B 109.9 . . ?
H9'A C9' H9'B 109.5 . . ?
C9 C9' H9'C 108.2 . . ?
H9'A C9' H9'C 109.5 . . ?
H9'B C9' H9'C 109.5 . . ?
O9 C9 C9' 113.4(4) . . ?
O9 C9 H9A 108.1 . . ?
C9' C9 H9A 108.0 . . ?
O9 C9 H9B 109.8 . . ?
C9' C9 H9B 109.6 . . ?
H9A C9 H9B 107.9 . . ?
O10 C10 C10' 112.6(3) . . ?
O10 C10 H10D 108.7 . . ?
C10' C10 H10D 108.5 . . ?
O10 C10 H10E 109.1 . . ?
C10' C10 H10E 109.7 . . ?
H10D C10 H10E 108.1 . . ?
C10 C10' H10A 110.4 . . ?
C10 C10' H10B 109.6 . . ?
H10A C10' H10B 109.5 . . ?
C10 C10' H10C 108.4 . . ?
H10A C10' H10C 109.5 . . ?
H10B C10' H10C 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        25.04
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         1.497
_refine_diff_density_min         -0.660
_refine_diff_density_rms         0.079
