# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1057865'
_audit_update_record             
;
2015-04-05 deposited with the CCDC.
2015-08-28 downloaded from the CCDC.
;
_audit_creation_date             2015-03-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C104 H70 N2 O20 Rh4, 3(C4 H9 N O), 2(C2.5 H4.5 N O0.5), 2(H2 O), 2(O)'
_chemical_formula_sum            'C121 H110 N7 O28 Rh4'
_chemical_formula_weight         2521.80
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'

_cell_length_a                   14.3649(9)
_cell_length_b                   15.5751(10)
_cell_length_c                   16.3871(12)
_cell_angle_alpha                72.966(7)
_cell_angle_beta                 73.450(6)
_cell_angle_gamma                68.665(6)
_cell_volume                     3199.2(4)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    7184
_cell_measurement_temperature    150.00(10)
_cell_measurement_theta_max      64.8320
_cell_measurement_theta_min      3.3340
_exptl_absorpt_coefficient_mu    4.685
_exptl_absorpt_correction_T_max  0.7995
_exptl_absorpt_correction_T_min  0.6033
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            green
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.309
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1289
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0417
_diffrn_reflns_av_unetI/netI     0.0514
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            20800
_diffrn_reflns_theta_full        65.37
_diffrn_reflns_theta_max         65.37
_diffrn_reflns_theta_min         3.12
_diffrn_ambient_temperature      150.00(10)
_diffrn_detector_area_resol_mean 10.6525
_diffrn_measured_fraction_theta_full 0.964
_diffrn_measured_fraction_theta_max 0.964
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   'SuperNova (Cu) X-ray Source'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                7175
_reflns_number_total             10596
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max         1.427
_refine_diff_density_min         -0.786
_refine_diff_density_rms         0.115
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     749
_refine_ls_number_reflns         10596
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0905
_refine_ls_R_factor_gt           0.0591
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1049P)²+6.2428P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1697
_refine_ls_wR_factor_ref         0.1986
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, {H54A,H54B,H54C} of C54, All C(H,H) groups
 At 1.5 times of:
  All O(H) groups, {H56A,H56B,H56C} of C56, {H57A,H57B,H57C} of C57, {H1AA,
  H1AB,H1AC} of C1A, {H1BA,H1BB,H1BC} of C1B, {H1CA,H1CB,H1CC} of C1C, {H49A,
  H49B,H49C} of C49, {H51A,H51B,H51C} of C51, {H53A,H53B,H53C} of C53, {H58A,
  H58B,H58C} of C58, {H60A,H60B,H60C} of C60, {H61A,H61B,H61C} of C61, All O(H,
  H) groups
2. Restrained distances
 C1C-C1D
 1.53 with sigma of 0.04
3. Others
 Fixed Sof: O13(0.5) N2(0.5) C1A(0.5) H1AA(0.5) H1AB(0.5) H1AC(0.5) C1B(0.5)
 H1BA(0.5) H1BB(0.5) H1BC(0.5) C1C(0.5) H1CA(0.5) H1CB(0.5) H1CC(0.5) C1D(0.5)
 O14(0.5) C58(0.5) H58A(0.5) H58B(0.5) H58C(0.5) C60(0.5) H60A(0.5) H60B(0.5)
 H60C(0.5) C61(0.5) H61A(0.5) H61B(0.5) H61C(0.5)
4.a Free rotating group:
 O11(H11A,H11B)
4.b Secondary CH2 refined with riding coordinates:
 C4(H4A,H4B)
4.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C7(H7), C11(H11), C12(H12), C13(H13), C15(H15), C18(H18),
 C19(H19), C20(H20), C22(H22), C26(H26), C27(H27), C28(H28), C30(H30), C36(H36),
  C37(H37), C38(H38), C39(H39), C42(H42), C43(H43), C44(H44), C46(H46)
4.d Idealised Me refined as rotating group:
 C54(H54A,H54B,H54C), C56(H56A,H56B,H56C), C57(H57A,H57B,H57C), C1A(H1AA,H1AB,
 H1AC), C1B(H1BA,H1BB,H1BC), C1C(H1CA,H1CB,H1CC), C49(H49A,H49B,H49C), C51(H51A,
 H51B,H51C), C53(H53A,H53B,H53C), C58(H58A,H58B,H58C), C60(H60A,H60B,H60C),
 C61(H61A,H61B,H61C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_refinement_flags_posn
Rh1 Rh 0.67803(3) 0.72386(3) 0.34714(3) 0.04559(17) Uani 1 d . . .
Rh2 Rh 0.77763(4) 0.66035(4) 0.22182(3) 0.04862(18) Uani 1 d . . .
O1 O 0.6999(3) 0.8498(3) 0.2822(3) 0.0501(10) Uani 1 d . . .
O2 O 0.7955(4) 0.7892(3) 0.1641(3) 0.0536(11) Uani 1 d . . .
O3 O 0.8084(3) 0.6814(3) 0.3925(3) 0.0430(9) Uani 1 d . . .
O4 O 0.9028(3) 0.6220(3) 0.2739(3) 0.0469(10) Uani 1 d . . .
O5 O 0.6601(3) 0.5948(3) 0.4050(3) 0.0506(11) Uani 1 d . . .
O6 O 0.7564(3) 0.5340(3) 0.2868(3) 0.0530(11) Uani 1 d . . .
O7 O 0.5528(3) 0.7613(4) 0.2957(3) 0.0564(11) Uani 1 d . . .
O8 O 0.6475(4) 0.6996(4) 0.1782(3) 0.0613(13) Uani 1 d . . .
O9 O 0.8683(4) 0.6079(4) 0.0950(3) 0.0645(14) Uani 1 d . . .
H9 H 0.834(8) 0.627(7) 0.057(7) 0.097 Uiso 1 d . . R
O10 O 0.5781(3) 0.7953(3) 0.4584(3) 0.0517(11) Uani 1 d . . .
N1 N 0.4911(7) 0.8196(5) 0.5860(5) 0.085(2) Uani 1 d . . .
C1 C 0.5641(6) 0.7381(6) 0.2246(5) 0.0623(19) Uani 1 d . . .
C2 C 0.4683(6) 0.7554(6) 0.1951(5) 0.066(2) Uani 1 d . . .
C3 C 0.3748(6) 0.8000(8) 0.2389(6) 0.086(3) Uani 1 d . . .
H3 H 0.3695 0.8252 0.2855 0.104 Uiso 1 calc . . R
C4 C 0.2875(6) 0.8073(8) 0.2130(6) 0.091(3) Uani 1 d . . .
H4A H 0.2447 0.7801 0.2637 0.109 Uiso 1 calc . . R
H4B H 0.2511 0.8740 0.1980 0.109 Uiso 1 calc . . R
C5 C 0.2940(7) 0.7685(8) 0.1457(6) 0.084(3) Uani 1 d . . .
H5 H 0.2347 0.7722 0.1305 0.101 Uiso 1 calc . . R
C6 C 0.3879(6) 0.7239(6) 0.1005(5) 0.066(2) Uani 1 d . . .
C7 C 0.4757(6) 0.7165(6) 0.1259(5) 0.0643(19) Uani 1 d . . .
H7 H 0.5395 0.6856 0.0967 0.077 Uiso 1 calc . . R
C8 C 0.3977(6) 0.6812(6) 0.0314(5) 0.0639(19) Uani 1 d . . .
C9 C 0.4124(6) 0.6429(5) -0.0272(5) 0.0613(18) Uani 1 d . . .
C10 C 0.4306(6) 0.5977(5) -0.0974(5) 0.0585(17) Uani 1 d . . .
C11 C 0.3499(6) 0.5885(6) -0.1213(5) 0.066(2) Uani 1 d . . .
H11 H 0.2834 0.6132 -0.0924 0.080 Uiso 1 calc . . R
C12 C 0.3675(6) 0.5433(7) -0.1874(6) 0.076(2) Uani 1 d . . .
H12 H 0.3131 0.5357 -0.2016 0.091 Uiso 1 calc . . R
C13 C 0.4649(6) 0.5092(6) -0.2326(6) 0.070(2) Uani 1 d . . .
H13 H 0.4757 0.4800 -0.2780 0.084 Uiso 1 calc . . R
C14 C 0.5469(6) 0.5179(5) -0.2110(5) 0.0623(19) Uani 1 d . . .
C15 C 0.5289(6) 0.5613(5) -0.1423(5) 0.0602(18) Uani 1 d . . .
H15 H 0.5837 0.5659 -0.1263 0.072 Uiso 1 calc . . R
C16 C 0.7530(5) 0.8559(5) 0.2046(4) 0.0538(16) Uani 1 d . . .
C17 C 0.7646(5) 0.9495(5) 0.1568(4) 0.0551(16) Uani 1 d . . .
C18 C 0.7144(6) 1.0287(5) 0.1937(5) 0.0638(19) Uani 1 d . . .
H18 H 0.6738 1.0234 0.2493 0.077 Uiso 1 calc . . R
C19 C 0.7255(6) 1.1145(5) 0.1473(5) 0.067(2) Uani 1 d . . .
H19 H 0.6918 1.1673 0.1717 0.080 Uiso 1 calc . . R
C20 C 0.7861(6) 1.1238(5) 0.0646(5) 0.065(2) Uani 1 d . . .
H20 H 0.7926 1.1826 0.0342 0.078 Uiso 1 calc . . R
C21 C 0.8368(6) 1.0465(5) 0.0271(5) 0.0620(19) Uani 1 d . . .
C22 C 0.8245(6) 0.9592(5) 0.0737(5) 0.0601(18) Uani 1 d . . .
H22 H 0.8571 0.9068 0.0486 0.072 Uiso 1 calc . . R
C23 C 0.8989(6) 1.0529(5) -0.0591(5) 0.064(2) Uani 1 d . . .
C24 C 0.9514(6) 1.0558(5) -0.1305(5) 0.0597(18) Uani 1 d . . .
C25 C 1.0136(6) 1.0556(5) -0.2155(5) 0.0569(17) Uani 1 d . . .
C26 C 1.0358(7) 1.1368(5) -0.2678(5) 0.068(2) Uani 1 d . . .
H26 H 1.0072 1.1930 -0.2483 0.082 Uiso 1 calc . . R
C27 C 1.1000(7) 1.1345(6) -0.3485(5) 0.073(2) Uani 1 d . . .
H27 H 1.1138 1.1892 -0.3832 0.088 Uiso 1 calc . . R
C28 C 1.1436(6) 1.0514(5) -0.3779(5) 0.0622(19) Uani 1 d . . .
H28 H 1.1879 1.0500 -0.4317 0.075 Uiso 1 calc . . R
C29 C 1.1214(6) 0.9704(5) -0.3274(5) 0.0570(17) Uani 1 d . . .
C30 C 1.0570(6) 0.9726(5) -0.2456(5) 0.0555(17) Uani 1 d . . .
H30 H 1.0432 0.9178 -0.2110 0.067 Uiso 1 calc . . R
C31 C 1.1686(6) 0.8839(6) -0.3575(5) 0.0619(18) Uani 1 d . . .
C32 C 1.2132(6) 0.8135(6) -0.3852(5) 0.066(2) Uani 1 d . . .
C33 C 1.2706(6) 0.7306(6) -0.4208(5) 0.0633(19) Uani 1 d . . .
C34 C 0.7025(5) 0.5291(5) 0.3636(5) 0.0528(16) Uani 1 d . . .
C35 C 0.6889(5) 0.4350(5) 0.4114(4) 0.0512(16) Uani 1 d . . .
C36 C 0.7434(6) 0.3562(5) 0.3767(5) 0.0565(17) Uani 1 d . . .
H36 H 0.7895 0.3610 0.3239 0.068 Uiso 1 calc . . R
C37 C 0.6221(5) 0.4265(5) 0.4910(5) 0.0573(17) Uani 1 d . . .
H37 H 0.5872 0.4793 0.5154 0.069 Uiso 1 calc . . R
C38 C 0.6063(6) 0.3407(6) 0.5351(5) 0.065(2) Uani 1 d . . .
H38 H 0.5595 0.3363 0.5875 0.078 Uiso 1 calc . . R
C39 C 0.6613(6) 0.2618(6) 0.5000(5) 0.067(2) Uani 1 d . . .
H39 H 0.6526 0.2035 0.5296 0.080 Uiso 1 calc . . R
C40 C 0.8921(5) 0.6408(4) 0.3466(4) 0.0455(14) Uani 1 d . . .
C41 C 0.9861(5) 0.6152(4) 0.3811(4) 0.0487(15) Uani 1 d . . .
C42 C 0.9793(6) 0.6222(6) 0.4649(5) 0.0632(19) Uani 1 d . . .
H42 H 0.9157 0.6412 0.5007 0.076 Uiso 1 calc . . R
C43 C 1.0673(7) 0.6007(7) 0.4952(6) 0.081(3) Uani 1 d . . .
H43 H 1.0633 0.6039 0.5520 0.098 Uiso 1 calc . . R
C44 C 1.1606(7) 0.5748(7) 0.4413(6) 0.082(3) Uani 1 d . . .
H44 H 1.2194 0.5615 0.4619 0.099 Uiso 1 calc . . R
C45 C 1.1692(5) 0.5679(6) 0.3568(5) 0.0614(18) Uani 1 d . . .
C46 C 1.0802(5) 0.5877(5) 0.3276(5) 0.0534(16) Uani 1 d . . .
H46 H 1.0841 0.5824 0.2716 0.064 Uiso 1 calc . . R
C47 C 1.2680(6) 0.5404(6) 0.3011(6) 0.073(2) Uani 1 d . . .
C48 C 1.3520(6) 0.5159(6) 0.2586(6) 0.068(2) Uani 1 d . . .
C54 C 0.6203(9) 0.6711(7) 0.5733(6) 0.097(3) Uani 1 d . . .
H54A H 0.6715 0.6430 0.5283 0.116 Uiso 1 calc . . GR
H54B H 0.5741 0.6344 0.5998 0.116 Uiso 1 calc . . GR
H54C H 0.6524 0.6729 0.6165 0.116 Uiso 1 calc . . GR
C55 C 0.5624(7) 0.7696(6) 0.5345(5) 0.070(2) Uani 1 d . . .
C56 C 0.4593(11) 0.7898(9) 0.6781(7) 0.133(5) Uani 1 d . . .
H56A H 0.4831 0.7222 0.6942 0.199 Uiso 1 calc . . GR
H56B H 0.3862 0.8112 0.6936 0.199 Uiso 1 calc . . GR
H56C H 0.4873 0.8158 0.7083 0.199 Uiso 1 calc . . GR
C57 C 0.4316(8) 0.9120(7) 0.5513(7) 0.086(3) Uani 1 d . . .
H57A H 0.4379 0.9567 0.5775 0.129 Uiso 1 calc . . GR
H57B H 0.3613 0.9144 0.5634 0.129 Uiso 1 calc . . GR
H57C H 0.4554 0.9272 0.4894 0.129 Uiso 1 calc . . GR
O13 O 0.7679(16) 0.7298(11) -0.0446(11) 0.116(7) Uani 0.50 d . . .
N2 N 0.635(3) 0.816(3) -0.0906(17) 0.185(16) Uani 0.50 d . . .
C1A C 0.631(3) 0.749(3) -0.1322(18) 0.181(18) Uani 0.50 d . . .
H1AA H 0.5833 0.7173 -0.0953 0.272 Uiso 0.50 calc . . GR
H1AB H 0.6973 0.7044 -0.1429 0.272 Uiso 0.50 calc . . GR
H1AC H 0.6094 0.7816 -0.1865 0.272 Uiso 0.50 calc . . GR
C1B C 0.533(3) 0.907(3) -0.094(2) 0.20(2) Uani 0.50 d . . .
H1BA H 0.5191 0.9264 -0.1521 0.305 Uiso 0.50 calc . . GR
H1BB H 0.5432 0.9576 -0.0798 0.305 Uiso 0.50 calc . . GR
H1BC H 0.4763 0.8899 -0.0536 0.305 Uiso 0.50 calc . . GR
C1C C 0.669(2) 0.8820(18) -0.0045(16) 0.125(9) Uani 0.50 d . . D
H1CA H 0.6707 0.9400 -0.0457 0.188 Uiso 0.50 calc . . GR
H1CB H 0.7201 0.8647 0.0299 0.188 Uiso 0.50 calc . . GR
H1CC H 0.6032 0.8902 0.0330 0.188 Uiso 0.50 calc . . GR
C1D C 0.692(5) 0.802(4) -0.0544(18) 0.28(4) Uani 0.50 d . . D
O15 O 0.9021(7) 0.4233(7) 0.0913(6) 0.134(3) Uiso 1 d . . .
N3 N 0.9231(10) 0.3346(10) -0.0010(9) 0.144(4) Uiso 1 d . . .
C49 C 0.9409(10) 0.3031(9) -0.0786(9) 0.119(4) Uiso 1 d . . .
H49A H 0.8797 0.3287 -0.1018 0.178 Uiso 1 calc . . GR
H49B H 0.9603 0.2355 -0.0660 0.178 Uiso 1 calc . . GR
H49C H 0.9946 0.3238 -0.1206 0.178 Uiso 1 calc . . GR
C50 C 0.8979(12) 0.4071(12) 0.0043(10) 0.133(5) Uiso 1 d . . .
C51 C 0.8627(11) 0.4836(9) -0.0615(8) 0.119(4) Uani 1 d . . .
H51A H 0.9181 0.4884 -0.1102 0.179 Uiso 1 calc . . GR
H51B H 0.8363 0.5407 -0.0398 0.179 Uiso 1 calc . . GR
H51C H 0.8098 0.4744 -0.0796 0.179 Uiso 1 calc . . GR
C53 C 0.9736(18) 0.2542(17) 0.0830(15) 0.228(10) Uiso 1 d . . .
H53A H 0.9392 0.2069 0.1050 0.342 Uiso 1 calc . . GR
H53B H 0.9652 0.2851 0.1285 0.342 Uiso 1 calc . . GR
H53C H 1.0449 0.2249 0.0628 0.342 Uiso 1 calc . . GR
O14 O 1.2969(10) 0.9832(12) -0.6257(11) 0.104(5) Uani 0.50 d . . .
N4 N 1.175(2) 1.129(2) -0.619(2) 0.319(14) Uiso 1 d . . .
C58 C 1.1209(15) 0.9746(19) -0.5978(15) 0.106(7) Uani 0.50 d . . .
H58A H 1.0934 0.9896 -0.6490 0.159 Uiso 0.50 calc . . GR
H58B H 1.0671 0.9954 -0.5508 0.159 Uiso 0.50 calc . . GR
H58C H 1.1517 0.9077 -0.5821 0.159 Uiso 0.50 calc . . GR
C59 C 1.202(2) 1.025(2) -0.6164(19) 0.243(12) Uiso 1 d . . .
C60 C 1.0571(16) 1.171(2) -0.600(2) 0.145(12) Uani 0.50 d . . .
H60A H 1.0374 1.2147 -0.5624 0.218 Uiso 0.50 calc . . GR
H60B H 1.0272 1.1210 -0.5710 0.218 Uiso 0.50 calc . . GR
H60C H 1.0339 1.2028 -0.6532 0.218 Uiso 0.50 calc . . GR
C61 C 1.256(2) 1.1615(19) -0.6083(17) 0.127(10) Uani 0.50 d . . .
H61A H 1.2645 1.2145 -0.6545 0.191 Uiso 0.50 calc . . GR
H61B H 1.3197 1.1111 -0.6105 0.191 Uiso 0.50 calc . . GR
H61C H 1.2371 1.1797 -0.5532 0.191 Uiso 0.50 calc . . GR
O11 O 0.4897(8) 0.9947(7) 0.3099(8) 0.143(3) Uani 1 d . . .
H11A H 0.4257 1.0037 0.3259 0.214 Uiso 1 d . . G
H11B H 0.5209 0.9359 0.3201 0.214 Uiso 1 d . . G
O12 O 0.9864(11) 0.4121(10) 0.2515(9) 0.215(6) Uani 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Rh2 2.3936(6) . ?
Rh1 O1 2.029(4) . ?
Rh1 O3 2.025(4) . ?
Rh1 O5 2.032(4) . ?
Rh1 O7 2.025(5) . ?
Rh1 O10 2.272(4) . ?
Rh2 O2 2.027(5) . ?
Rh2 O4 2.028(4) . ?
Rh2 O6 2.030(5) . ?
Rh2 O8 2.013(5) . ?
Rh2 O9 2.316(5) . ?
O1 C16 1.280(8) . ?
O2 C16 1.267(8) . ?
O3 C40 1.273(7) . ?
O4 C40 1.263(8) . ?
O5 C34 1.263(8) . ?
O6 C34 1.274(8) . ?
O7 C1 1.268(9) . ?
O8 C1 1.265(9) . ?
O9 H9 0.83(10) . ?
O10 C55 1.173(9) . ?
N1 C55 1.297(10) . ?
N1 C56 1.433(13) . ?
N1 C57 1.424(12) . ?
C1 C2 1.495(11) . ?
C2 C3 1.366(11) . ?
C2 C7 1.396(11) . ?
C3 H3 0.9300 . ?
C3 C4 1.391(12) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C4 C5 1.372(12) . ?
C5 H5 0.9300 . ?
C5 C6 1.379(12) . ?
C6 C7 1.395(11) . ?
C6 C8 1.424(11) . ?
C7 H7 0.9300 . ?
C8 C9 1.205(11) . ?
C9 C10 1.433(11) . ?
C10 C11 1.389(11) . ?
C10 C15 1.388(11) . ?
C11 H11 0.9300 . ?
C11 C12 1.378(12) . ?
C12 H12 0.9300 . ?
C12 C13 1.373(11) . ?
C13 H13 0.9300 . ?
C13 C14 1.384(11) . ?
C14 C15 1.393(11) . ?
C14 C48 1.425(11) 2_765 ?
C15 H15 0.9300 . ?
C16 C17 1.482(10) . ?
C17 C18 1.397(10) . ?
C17 C22 1.386(10) . ?
C18 H18 0.9300 . ?
C18 C19 1.370(11) . ?
C19 H19 0.9300 . ?
C19 C20 1.385(11) . ?
C20 H20 0.9300 . ?
C20 C21 1.377(11) . ?
C21 C22 1.397(11) . ?
C21 C23 1.437(11) . ?
C22 H22 0.9300 . ?
C23 C24 1.196(10) . ?
C24 C25 1.425(10) . ?
C25 C26 1.391(10) . ?
C25 C30 1.384(10) . ?
C26 H26 0.9300 . ?
C26 C27 1.382(11) . ?
C27 H27 0.9300 . ?
C27 C28 1.378(11) . ?
C28 H28 0.9300 . ?
C28 C29 1.382(10) . ?
C29 C30 1.397(10) . ?
C29 C31 1.433(10) . ?
C30 H30 0.9300 . ?
C31 C32 1.198(10) . ?
C32 C33 1.442(10) . ?
C33 C36 1.389(11) 2_765 ?
C33 C39 1.388(11) 2_765 ?
C34 C35 1.500(10) . ?
C35 C36 1.377(9) . ?
C35 C37 1.386(10) . ?
C36 C33 1.389(11) 2_765 ?
C36 H36 0.9300 . ?
C37 H37 0.9300 . ?
C37 C38 1.385(11) . ?
C38 H38 0.9300 . ?
C38 C39 1.384(11) . ?
C39 C33 1.388(11) 2_765 ?
C39 H39 0.9300 . ?
C40 C41 1.488(9) . ?
C41 C42 1.382(10) . ?
C41 C46 1.379(10) . ?
C42 H42 0.9300 . ?
C42 C43 1.383(11) . ?
C43 H43 0.9300 . ?
C43 C44 1.371(13) . ?
C44 H44 0.9300 . ?
C44 C45 1.388(12) . ?
C45 C46 1.389(10) . ?
C45 C47 1.442(12) . ?
C46 H46 0.9300 . ?
C47 C48 1.196(11) . ?
C48 C14 1.425(11) 2_765 ?
C54 H54A 0.9600 . ?
C54 H54B 0.9600 . ?
C54 H54C 0.9600 . ?
C54 C55 1.500(13) . ?
C56 H56A 0.9600 . ?
C56 H56B 0.9600 . ?
C56 H56C 0.9600 . ?
C57 H57A 0.9600 . ?
C57 H57B 0.9600 . ?
C57 H57C 0.9600 . ?
O13 C1D 1.26(7) . ?
N2 C1A 1.43(4) . ?
N2 C1B 1.63(5) . ?
N2 C1D 1.07(5) . ?
C1A H1AA 0.9600 . ?
C1A H1AB 0.9600 . ?
C1A H1AC 0.9600 . ?
C1B H1BA 0.9600 . ?
C1B H1BB 0.9600 . ?
C1B H1BC 0.9600 . ?
C1C H1CA 0.9600 . ?
C1C H1CB 0.9600 . ?
C1C H1CC 0.9600 . ?
C1C C1D 1.57(3) . ?
O15 C50 1.539(18) . ?
N3 C49 1.420(17) . ?
N3 C50 1.075(17) . ?
N3 C53 1.70(2) . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50 C51 1.400(18) . ?
C51 H51A 0.9600 . ?
C51 H51B 0.9600 . ?
C51 H51C 0.9600 . ?
C53 H53A 0.9600 . ?
C53 H53B 0.9600 . ?
C53 H53C 0.9600 . ?
O14 C59 1.26(3) . ?
N4 C59 1.51(4) . ?
N4 C60 1.55(3) . ?
N4 C61 1.51(4) . ?
C58 H58A 0.9600 . ?
C58 H58B 0.9600 . ?
C58 H58C 0.9600 . ?
C58 C59 1.54(4) . ?
C60 H60A 0.9600 . ?
C60 H60B 0.9600 . ?
C60 H60C 0.9600 . ?
C61 H61A 0.9600 . ?
C61 H61B 0.9600 . ?
C61 H61C 0.9600 . ?
O11 H11A 0.8507 . ?
O11 H11B 0.8503 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Rh1 Rh2 88.67(12) . . ?
O1 Rh1 O5 176.37(16) . . ?
O1 Rh1 O10 87.58(17) . . ?
O3 Rh1 Rh2 87.90(11) . . ?
O3 Rh1 O1 91.48(17) . . ?
O3 Rh1 O5 89.00(17) . . ?
O3 Rh1 O7 176.25(17) . . ?
O3 Rh1 O10 95.06(16) . . ?
O5 Rh1 Rh2 87.75(12) . . ?
O5 Rh1 O10 95.96(17) . . ?
O7 Rh1 Rh2 88.42(13) . . ?
O7 Rh1 O1 89.1(2) . . ?
O7 Rh1 O5 90.2(2) . . ?
O7 Rh1 O10 88.66(17) . . ?
O10 Rh1 Rh2 175.28(13) . . ?
O2 Rh2 Rh1 87.73(13) . . ?
O2 Rh2 O4 90.55(18) . . ?
O2 Rh2 O6 176.43(16) . . ?
O2 Rh2 O9 89.55(19) . . ?
O4 Rh2 Rh1 88.34(12) . . ?
O4 Rh2 O6 88.51(18) . . ?
O4 Rh2 O9 94.28(18) . . ?
O6 Rh2 Rh1 88.80(12) . . ?
O6 Rh2 O9 93.96(19) . . ?
O8 Rh2 Rh1 87.90(13) . . ?
O8 Rh2 O2 90.3(2) . . ?
O8 Rh2 O4 176.10(17) . . ?
O8 Rh2 O6 90.4(2) . . ?
O8 Rh2 O9 89.52(19) . . ?
O9 Rh2 Rh1 176.24(16) . . ?
C16 O1 Rh1 118.3(4) . . ?
C16 O2 Rh2 119.6(4) . . ?
C40 O3 Rh1 119.0(4) . . ?
C40 O4 Rh2 118.6(4) . . ?
C34 O5 Rh1 118.8(4) . . ?
C34 O6 Rh2 117.5(4) . . ?
C1 O7 Rh1 117.8(5) . . ?
C1 O8 Rh2 119.0(4) . . ?
Rh2 O9 H9 113(7) . . ?
C55 O10 Rh1 133.5(5) . . ?
C55 N1 C56 126.4(9) . . ?
C55 N1 C57 120.0(8) . . ?
C57 N1 C56 113.5(8) . . ?
O7 C1 C2 116.0(7) . . ?
O8 C1 O7 126.7(7) . . ?
O8 C1 C2 117.3(7) . . ?
C3 C2 C1 121.6(7) . . ?
C3 C2 C7 120.1(7) . . ?
C7 C2 C1 118.0(7) . . ?
C2 C3 H3 120.4 . . ?
C2 C3 C4 119.3(8) . . ?
C4 C3 H3 120.4 . . ?
C3 C4 H4A 107.1 . . ?
C3 C4 H4B 107.1 . . ?
H4A C4 H4B 106.8 . . ?
C5 C4 C3 121.1(8) . . ?
C5 C4 H4A 107.1 . . ?
C5 C4 H4B 107.1 . . ?
C4 C5 H5 119.9 . . ?
C4 C5 C6 120.3(8) . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C7 119.0(8) . . ?
C5 C6 C8 121.9(8) . . ?
C7 C6 C8 119.0(7) . . ?
C2 C7 H7 119.9 . . ?
C6 C7 C2 120.3(7) . . ?
C6 C7 H7 119.9 . . ?
C9 C8 C6 176.0(8) . . ?
C8 C9 C10 179.5(9) . . ?
C11 C10 C9 120.5(7) . . ?
C15 C10 C9 121.0(7) . . ?
C15 C10 C11 118.5(7) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 C10 120.5(7) . . ?
C12 C11 H11 119.7 . . ?
C11 C12 H12 119.8 . . ?
C13 C12 C11 120.4(7) . . ?
C13 C12 H12 119.8 . . ?
C12 C13 H13 119.7 . . ?
C12 C13 C14 120.5(8) . . ?
C14 C13 H13 119.7 . . ?
C13 C14 C15 118.7(7) . . ?
C13 C14 C48 120.7(8) . 2_765 ?
C15 C14 C48 120.5(7) . 2_765 ?
C10 C15 C14 121.3(7) . . ?
C10 C15 H15 119.4 . . ?
C14 C15 H15 119.4 . . ?
O1 C16 C17 117.5(6) . . ?
O2 C16 O1 125.7(7) . . ?
O2 C16 C17 116.8(6) . . ?
C18 C17 C16 120.8(6) . . ?
C22 C17 C16 119.9(7) . . ?
C22 C17 C18 119.3(7) . . ?
C17 C18 H18 120.3 . . ?
C19 C18 C17 119.4(7) . . ?
C19 C18 H18 120.3 . . ?
C18 C19 H19 119.4 . . ?
C18 C19 C20 121.2(7) . . ?
C20 C19 H19 119.4 . . ?
C19 C20 H20 119.8 . . ?
C21 C20 C19 120.5(7) . . ?
C21 C20 H20 119.8 . . ?
C20 C21 C22 118.6(7) . . ?
C20 C21 C23 122.5(7) . . ?
C22 C21 C23 118.9(7) . . ?
C17 C22 C21 121.1(7) . . ?
C17 C22 H22 119.4 . . ?
C21 C22 H22 119.4 . . ?
C24 C23 C21 178.3(8) . . ?
C23 C24 C25 177.7(8) . . ?
C26 C25 C24 121.2(7) . . ?
C30 C25 C24 119.8(7) . . ?
C30 C25 C26 118.9(7) . . ?
C25 C26 H26 119.7 . . ?
C27 C26 C25 120.5(7) . . ?
C27 C26 H26 119.7 . . ?
C26 C27 H27 119.8 . . ?
C28 C27 C26 120.3(7) . . ?
C28 C27 H27 119.8 . . ?
C27 C28 H28 120.0 . . ?
C27 C28 C29 120.0(7) . . ?
C29 C28 H28 120.0 . . ?
C28 C29 C30 119.7(7) . . ?
C28 C29 C31 119.7(7) . . ?
C30 C29 C31 120.6(7) . . ?
C25 C30 C29 120.6(7) . . ?
C25 C30 H30 119.7 . . ?
C29 C30 H30 119.7 . . ?
C32 C31 C29 175.9(8) . . ?
C31 C32 C33 177.4(8) . . ?
C36 C33 C32 120.2(7) 2_765 . ?
C36 C33 C39 120.2(7) 2_765 2_765 ?
C39 C33 C32 119.6(7) 2_765 . ?
O5 C34 O6 127.1(7) . . ?
O5 C34 C35 115.9(6) . . ?
O6 C34 C35 117.0(6) . . ?
C36 C35 C34 120.2(6) . . ?
C36 C35 C37 119.5(7) . . ?
C37 C35 C34 120.2(6) . . ?
C33 C36 H36 120.1 2_765 . ?
C35 C36 C33 119.9(7) . 2_765 ?
C35 C36 H36 120.1 . . ?
C35 C37 H37 119.4 . . ?
C38 C37 C35 121.2(7) . . ?
C38 C37 H37 119.4 . . ?
C37 C38 H38 120.5 . . ?
C37 C38 C39 119.0(7) . . ?
C39 C38 H38 120.5 . . ?
C33 C39 H39 119.9 2_765 . ?
C38 C39 C33 120.1(7) . 2_765 ?
C38 C39 H39 119.9 . . ?
O3 C40 C41 116.7(6) . . ?
O4 C40 O3 126.1(6) . . ?
O4 C40 C41 117.1(5) . . ?
C42 C41 C40 120.3(6) . . ?
C46 C41 C40 119.4(6) . . ?
C46 C41 C42 120.3(6) . . ?
C41 C42 H42 120.2 . . ?
C43 C42 C41 119.7(7) . . ?
C43 C42 H42 120.2 . . ?
C42 C43 H43 120.1 . . ?
C44 C43 C42 119.7(8) . . ?
C44 C43 H43 120.1 . . ?
C43 C44 H44 119.2 . . ?
C43 C44 C45 121.5(8) . . ?
C45 C44 H44 119.2 . . ?
C44 C45 C47 120.6(7) . . ?
C46 C45 C44 118.2(7) . . ?
C46 C45 C47 121.1(7) . . ?
C41 C46 C45 120.6(7) . . ?
C41 C46 H46 119.7 . . ?
C45 C46 H46 119.7 . . ?
C48 C47 C45 176.8(9) . . ?
C47 C48 C14 177.0(10) . 2_765 ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C55 C54 H54A 109.5 . . ?
C55 C54 H54B 109.5 . . ?
C55 C54 H54C 109.5 . . ?
O10 C55 N1 122.8(9) . . ?
O10 C55 C54 118.6(7) . . ?
N1 C55 C54 118.3(8) . . ?
N1 C56 H56A 109.5 . . ?
N1 C56 H56B 109.5 . . ?
N1 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
N1 C57 H57A 109.5 . . ?
N1 C57 H57B 109.5 . . ?
N1 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C1A N2 C1B 110(4) . . ?
C1D N2 C1A 123(5) . . ?
C1D N2 C1B 126(4) . . ?
N2 C1A H1AA 109.5 . . ?
N2 C1A H1AB 109.5 . . ?
N2 C1A H1AC 109.5 . . ?
H1AA C1A H1AB 109.5 . . ?
H1AA C1A H1AC 109.5 . . ?
H1AB C1A H1AC 109.5 . . ?
N2 C1B H1BA 109.5 . . ?
N2 C1B H1BB 109.5 . . ?
N2 C1B H1BC 109.5 . . ?
H1BA C1B H1BB 109.5 . . ?
H1BA C1B H1BC 109.5 . . ?
H1BB C1B H1BC 109.5 . . ?
H1CA C1C H1CB 109.5 . . ?
H1CA C1C H1CC 109.5 . . ?
H1CB C1C H1CC 109.5 . . ?
C1D C1C H1CA 109.5 . . ?
C1D C1C H1CB 109.5 . . ?
C1D C1C H1CC 109.5 . . ?
O13 C1D C1C 120(3) . . ?
N2 C1D O13 128(4) . . ?
N2 C1D C1C 112(5) . . ?
C49 N3 C53 116.8(14) . . ?
C50 N3 C49 125.4(16) . . ?
C50 N3 C53 115.9(17) . . ?
N3 C49 H49A 109.5 . . ?
N3 C49 H49B 109.5 . . ?
N3 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
N3 C50 O15 115.4(16) . . ?
N3 C50 C51 124.1(18) . . ?
C51 C50 O15 120.5(14) . . ?
C50 C51 H51A 109.5 . . ?
C50 C51 H51B 109.5 . . ?
C50 C51 H51C 109.5 . . ?
H51A C51 H51B 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
N3 C53 H53A 109.5 . . ?
N3 C53 H53B 109.5 . . ?
N3 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C59 N4 C60 109(3) . . ?
C61 N4 C59 116(3) . . ?
C61 N4 C60 131(3) . . ?
H58A C58 H58B 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C59 C58 H58A 109.5 . . ?
C59 C58 H58B 109.5 . . ?
C59 C58 H58C 109.5 . . ?
O14 C59 N4 113(3) . . ?
O14 C59 C58 124(3) . . ?
N4 C59 C58 123(3) . . ?
N4 C60 H60A 109.5 . . ?
N4 C60 H60B 109.5 . . ?
N4 C60 H60C 109.5 . . ?
H60A C60 H60B 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
N4 C61 H61A 109.5 . . ?
N4 C61 H61B 109.5 . . ?
N4 C61 H61C 109.5 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
H11A O11 H11B 109.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 Rh2 O2 C16 -1.5(5) . . . . ?
Rh1 Rh2 O4 C40 -0.2(4) . . . . ?
Rh1 Rh2 O6 C34 0.8(5) . . . . ?
Rh1 Rh2 O8 C1 -1.6(6) . . . . ?
Rh1 O1 C16 O2 -1.3(9) . . . . ?
Rh1 O1 C16 C17 177.5(5) . . . . ?
Rh1 O3 C40 O4 -1.3(8) . . . . ?
Rh1 O3 C40 C41 177.2(4) . . . . ?
Rh1 O5 C34 O6 -0.8(9) . . . . ?
Rh1 O5 C34 C35 178.0(4) . . . . ?
Rh1 O7 C1 O8 -5.6(11) . . . . ?
Rh1 O7 C1 C2 172.0(5) . . . . ?
Rh1 O10 C55 N1 -170.5(6) . . . . ?
Rh1 O10 C55 C54 3.4(13) . . . . ?
Rh2 Rh1 O1 C16 0.0(5) . . . . ?
Rh2 Rh1 O3 C40 0.8(4) . . . . ?
Rh2 Rh1 O5 C34 1.1(5) . . . . ?
Rh2 Rh1 O7 C1 3.1(5) . . . . ?
Rh2 Rh1 O10 C55 176.2(12) . . . . ?
Rh2 O2 C16 O1 2.1(9) . . . . ?
Rh2 O2 C16 C17 -176.8(4) . . . . ?
Rh2 O4 C40 O3 0.9(8) . . . . ?
Rh2 O4 C40 C41 -177.6(4) . . . . ?
Rh2 O6 C34 O5 -0.2(9) . . . . ?
Rh2 O6 C34 C35 -179.0(4) . . . . ?
Rh2 O8 C1 O7 4.9(11) . . . . ?
Rh2 O8 C1 C2 -172.7(6) . . . . ?
O1 Rh1 Rh2 O2 0.63(19) . . . . ?
O1 Rh1 Rh2 O4 91.24(18) . . . . ?
O1 Rh1 Rh2 O6 179.79(18) . . . . ?
O1 Rh1 Rh2 O8 -89.8(2) . . . . ?
O1 Rh1 Rh2 O9 -43(2) . . . . ?
O1 Rh1 O3 C40 -87.8(4) . . . . ?
O1 Rh1 O5 C34 11(3) . . . . ?
O1 Rh1 O7 C1 91.8(6) . . . . ?
O1 Rh1 O10 C55 -146.4(7) . . . . ?
O1 C16 C17 C18 -3.5(10) . . . . ?
O1 C16 C17 C22 177.6(7) . . . . ?
O2 Rh2 O4 C40 87.5(4) . . . . ?
O2 Rh2 O6 C34 14(3) . . . . ?
O2 Rh2 O8 C1 -89.3(6) . . . . ?
O2 C16 C17 C18 175.4(7) . . . . ?
O2 C16 C17 C22 -3.5(10) . . . . ?
O3 Rh1 Rh2 O2 -90.90(18) . . . . ?
O3 Rh1 Rh2 O4 -0.29(16) . . . . ?
O3 Rh1 Rh2 O6 88.26(18) . . . . ?
O3 Rh1 Rh2 O8 178.67(19) . . . . ?
O3 Rh1 Rh2 O9 -135(2) . . . . ?
O3 Rh1 O1 C16 87.9(5) . . . . ?
O3 Rh1 O5 C34 -86.8(5) . . . . ?
O3 Rh1 O7 C1 -7(3) . . . . ?
O3 Rh1 O10 C55 -55.1(7) . . . . ?
O3 C40 C41 C42 9.8(9) . . . . ?
O3 C40 C41 C46 -167.8(6) . . . . ?
O4 Rh2 O2 C16 -89.8(5) . . . . ?
O4 Rh2 O6 C34 89.2(5) . . . . ?
O4 Rh2 O8 C1 14(3) . . . . ?
O4 C40 C41 C42 -171.5(6) . . . . ?
O4 C40 C41 C46 10.8(9) . . . . ?
O5 Rh1 Rh2 O2 -179.99(18) . . . . ?
O5 Rh1 Rh2 O4 -89.37(18) . . . . ?
O5 Rh1 Rh2 O6 -0.83(19) . . . . ?
O5 Rh1 Rh2 O8 89.6(2) . . . . ?
O5 Rh1 Rh2 O9 136(2) . . . . ?
O5 Rh1 O1 C16 -10(3) . . . . ?
O5 Rh1 O3 C40 88.6(4) . . . . ?
O5 Rh1 O7 C1 -84.6(6) . . . . ?
O5 Rh1 O10 C55 34.4(7) . . . . ?
O5 C34 C35 C36 -171.0(6) . . . . ?
O5 C34 C35 C37 8.4(9) . . . . ?
O6 Rh2 O2 C16 -15(3) . . . . ?
O6 Rh2 O4 C40 -89.0(4) . . . . ?
O6 Rh2 O8 C1 87.2(6) . . . . ?
O6 C34 C35 C36 8.0(10) . . . . ?
O6 C34 C35 C37 -172.7(6) . . . . ?
O7 Rh1 Rh2 O2 89.8(2) . . . . ?
O7 Rh1 Rh2 O4 -179.61(19) . . . . ?
O7 Rh1 Rh2 O6 -91.1(2) . . . . ?
O7 Rh1 Rh2 O8 -0.7(2) . . . . ?
O7 Rh1 Rh2 O9 46(2) . . . . ?
O7 Rh1 O1 C16 -88.4(5) . . . . ?
O7 Rh1 O3 C40 11(3) . . . . ?
O7 Rh1 O5 C34 89.5(5) . . . . ?
O7 Rh1 O10 C55 124.4(7) . . . . ?
O7 C1 C2 C3 4.8(13) . . . . ?
O7 C1 C2 C7 -169.2(8) . . . . ?
O8 Rh2 O2 C16 86.4(5) . . . . ?
O8 Rh2 O4 C40 -16(3) . . . . ?
O8 Rh2 O6 C34 -87.1(5) . . . . ?
O8 C1 C2 C3 -177.3(9) . . . . ?
O8 C1 C2 C7 8.7(12) . . . . ?
O9 Rh2 O2 C16 175.9(5) . . . . ?
O9 Rh2 O4 C40 177.1(4) . . . . ?
O9 Rh2 O6 C34 -176.6(5) . . . . ?
O9 Rh2 O8 C1 -178.9(6) . . . . ?
O10 Rh1 Rh2 O2 38.1(14) . . . . ?
O10 Rh1 Rh2 O4 128.7(14) . . . . ?
O10 Rh1 Rh2 O6 -142.8(14) . . . . ?
O10 Rh1 Rh2 O8 -52.4(14) . . . . ?
O10 Rh1 Rh2 O9 -6(3) . . . . ?
O10 Rh1 O1 C16 -177.1(5) . . . . ?
O10 Rh1 O3 C40 -175.5(4) . . . . ?
O10 Rh1 O5 C34 178.2(5) . . . . ?
O10 Rh1 O7 C1 179.4(6) . . . . ?
C1 C2 C3 C4 -174.7(10) . . . . ?
C1 C2 C7 C6 174.8(8) . . . . ?
C2 C3 C4 C5 1.6(18) . . . . ?
C3 C2 C7 C6 0.7(14) . . . . ?
C3 C4 C5 C6 -2.1(18) . . . . ?
C4 C5 C6 C7 1.9(15) . . . . ?
C4 C5 C6 C8 178.8(9) . . . . ?
C5 C6 C7 C2 -1.2(13) . . . . ?
C5 C6 C8 C9 -174(12) . . . . ?
C6 C8 C9 C10 -52(100) . . . . ?
C7 C2 C3 C4 -0.9(16) . . . . ?
C7 C6 C8 C9 3(13) . . . . ?
C8 C6 C7 C2 -178.1(8) . . . . ?
C8 C9 C10 C11 -140(100) . . . . ?
C8 C9 C10 C15 41(100) . . . . ?
C9 C10 C11 C12 -178.5(8) . . . . ?
C9 C10 C15 C14 -179.5(7) . . . . ?
C10 C11 C12 C13 -2.1(14) . . . . ?
C11 C10 C15 C14 1.2(12) . . . . ?
C11 C12 C13 C14 1.5(14) . . . . ?
C12 C13 C14 C15 0.4(13) . . . . ?
C12 C13 C14 C48 -178.9(8) . . . 2_765 ?
C13 C14 C15 C10 -1.8(12) . . . . ?
C15 C10 C11 C12 0.8(12) . . . . ?
C16 C17 C18 C19 -179.0(7) . . . . ?
C16 C17 C22 C21 180.0(7) . . . . ?
C17 C18 C19 C20 -0.4(13) . . . . ?
C18 C17 C22 C21 1.0(12) . . . . ?
C18 C19 C20 C21 0.0(14) . . . . ?
C19 C20 C21 C22 0.9(13) . . . . ?
C19 C20 C21 C23 178.8(8) . . . . ?
C20 C21 C22 C17 -1.4(12) . . . . ?
C20 C21 C23 C24 174(100) . . . . ?
C21 C23 C24 C25 24(50) . . . . ?
C22 C17 C18 C19 -0.1(12) . . . . ?
C22 C21 C23 C24 -8(33) . . . . ?
C23 C21 C22 C17 -179.4(7) . . . . ?
C23 C24 C25 C26 168(22) . . . . ?
C23 C24 C25 C30 -16(23) . . . . ?
C24 C25 C26 C27 177.0(8) . . . . ?
C24 C25 C30 C29 -177.5(7) . . . . ?
C25 C26 C27 C28 -0.6(14) . . . . ?
C26 C25 C30 C29 -0.5(12) . . . . ?
C26 C27 C28 C29 1.4(14) . . . . ?
C27 C28 C29 C30 -1.8(12) . . . . ?
C27 C28 C29 C31 -178.8(8) . . . . ?
C28 C29 C30 C25 1.3(12) . . . . ?
C28 C29 C31 C32 32(13) . . . . ?
C29 C31 C32 C33 -7(32) . . . . ?
C30 C25 C26 C27 0.1(13) . . . . ?
C30 C29 C31 C32 -145(13) . . . . ?
C31 C29 C30 C25 178.3(7) . . . . ?
C31 C32 C33 C36 156(21) . . . 2_765 ?
C31 C32 C33 C39 -25(22) . . . 2_765 ?
C34 C35 C36 C33 -179.2(7) . . . 2_765 ?
C34 C35 C37 C38 178.2(7) . . . . ?
C35 C37 C38 C39 2.4(12) . . . . ?
C36 C35 C37 C38 -2.4(11) . . . . ?
C37 C35 C36 C33 1.4(11) . . . 2_765 ?
C37 C38 C39 C33 -1.4(13) . . . 2_765 ?
C40 C41 C42 C43 -178.1(7) . . . . ?
C40 C41 C46 C45 176.8(6) . . . . ?
C41 C42 C43 C44 1.5(14) . . . . ?
C42 C41 C46 C45 -0.9(11) . . . . ?
C42 C43 C44 C45 -1.1(16) . . . . ?
C43 C44 C45 C46 -0.3(14) . . . . ?
C43 C44 C45 C47 -179.9(9) . . . . ?
C44 C45 C46 C41 1.3(12) . . . . ?
C44 C45 C47 C48 17(18) . . . . ?
C45 C47 C48 C14 47(31) . . . 2_765 ?
C46 C41 C42 C43 -0.5(12) . . . . ?
C46 C45 C47 C48 -162(17) . . . . ?
C47 C45 C46 C41 -179.1(7) . . . . ?
C48 C14 C15 C10 177.6(7) 2_765 . . . ?
C56 N1 C55 O10 172.5(11) . . . . ?
C56 N1 C55 C54 -1.4(17) . . . . ?
C57 N1 C55 O10 -3.4(15) . . . . ?
C57 N1 C55 C54 -177.4(9) . . . . ?
C1A N2 C1D O13 4(6) . . . . ?
C1A N2 C1D C1C -172(2) . . . . ?
C1B N2 C1D O13 174(3) . . . . ?
C1B N2 C1D C1C -1(5) . . . . ?
C49 N3 C50 O15 -169.8(12) . . . . ?
C49 N3 C50 C51 10(3) . . . . ?
C53 N3 C50 O15 -6(2) . . . . ?
C53 N3 C50 C51 174.1(15) . . . . ?
C60 N4 C59 O14 -175(2) . . . . ?
C60 N4 C59 C58 1(4) . . . . ?
C61 N4 C59 O14 -15(4) . . . . ?
C61 N4 C59 C58 161(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'

