# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_sa3092
_database_code_depnum_ccdc_archive 'CCDC 1412149'
_audit_update_record             
;
2015-07-11 deposited with the CCDC.
2015-09-21 downloaded from the CCDC.
;
_audit_creation_date             2015-03-31
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            NaAnt
_chemical_name_systematic        '2-(2-naphthyl) anthracene'
_chemical_formula_moiety         'C24 H16'
_chemical_formula_sum            'C24 H16'
_chemical_formula_weight         304.37
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 1 21 1'
_space_group_name_Hall           'P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   8.2025(16)
_cell_length_b                   6.0189(12)
_cell_length_c                   15.347(3)
_cell_angle_alpha                90
_cell_angle_beta                 90.94(3)
_cell_angle_gamma                90
_cell_volume                     757.6(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    2340
_cell_measurement_temperature    173.1500
_cell_measurement_theta_max      27.4650
_cell_measurement_theta_min      2.4835
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.076
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.52817
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku Inc., 2007)'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.334
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rod
_exptl_crystal_F_000             320
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.09
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0555
_diffrn_reflns_av_unetI/netI     0.0426
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            9875
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         27.500
_diffrn_reflns_theta_min         2.483
_diffrn_ambient_temperature      173.1500
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details      
;
scan:
	Number of images: 360
	           Slice: -110.0000 - 70.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 180.0000
	             XTD: 39.9400
	          2theta: -19.9560
scan:
	Number of images: 360
	           Slice: -110.0000 - 70.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 90.0000
	             XTD: 39.9400
	          2theta: -19.9560
scan:
	Number of images: 360
	           Slice: -110.0000 - 70.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 0.0000
	             XTD: 39.9400
	          2theta: -19.9560
;
_diffrn_measurement_device       
;
Saturn724+ (2x2 bin mode)
;
_diffrn_measurement_device_details 
;
AFC10: Fixed Chi 2 circle
;
_diffrn_measurement_device_type  'Saturn724+ CCD'
_diffrn_measurement_method       'ω scans at fixed χ = 45°'
_diffrn_number_total             1904
_diffrn_orient_matrix_type       d*Trek
_diffrn_orient_matrix_UB_11      -0.1061
_diffrn_orient_matrix_UB_12      -0.0535
_diffrn_orient_matrix_UB_13      0.0273
_diffrn_orient_matrix_UB_21      0.0781
_diffrn_orient_matrix_UB_22      -0.1001
_diffrn_orient_matrix_UB_23      0.1072
_diffrn_orient_matrix_UB_31      -0.0106
_diffrn_orient_matrix_UB_32      0.0430
_diffrn_orient_matrix_UB_33      0.0478
_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Sealed Tube'
_diffrn_source_current           30.0000
_diffrn_source_power             1.5000
_diffrn_source_voltage           50.0000
_diffrn_special_details          
;
 ?
;
_reflns_Friedel_coverage         0.821
_reflns_Friedel_fraction_full    0.995
_reflns_Friedel_fraction_max     0.991
_reflns_number_gt                3035
_reflns_number_total             3459
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2007)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'CIFTAB (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2014)'
_computing_structure_solution    
;
'SHELXT (Sheldrick, 2014)'
;
_refine_diff_density_max         0.305
_refine_diff_density_min         -0.178
_refine_diff_density_rms         0.045
_refine_ls_abs_structure_details 
;
 Flack x determined using 918 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -10.0(10)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.120
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     236
_refine_ls_number_reflns         3459
_refine_ls_number_restraints     22
_refine_ls_R_factor_all          0.0796
_refine_ls_R_factor_gt           0.0717
_refine_ls_restrained_S_all      1.119
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0631P)²+0.3009P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1670
_refine_ls_wR_factor_ref         0.1725
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Rigid bond restraints
 C3, C12
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C15, C16
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C18, C23
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
3. Uiso/Uaniso restraints and constraints
C2A \\sim C1A: within 1.7A with sigma of 0.02 and sigma for terminal atoms of
0.04
Uanis(C1A) \\sim Ueq, Uanis(C2A) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
4. Others
 Sof(H3)=Sof(H14)=Sof(C2A)=Sof(H2A)=Sof(C1A)=Sof(H1A)=1-FVAR(1)
 Sof(C1)=Sof(H1)=Sof(C2)=Sof(H2)=Sof(H13)=Sof(H16)=FVAR(1)
5.a Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C6(H6), C7(H7), C8(H8), C9(H9), C11(H11),
 C13(H13), C14(H14), C16(H16), C17(H17), C19(H19), C20(H20), C21(H21), C22(H22),
  C24(H24), C2A(H2A), C1A(H1A)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8164(6) 0.0750(10) 0.0095(3) 0.0326(14) Uani 0.686(7) 1 d . . P A 1
H1 H 0.8701 -0.0296 -0.0241 0.039 Uiso 0.686(7) 1 calc R . P A 1
C2 C 0.7774(6) 0.0178(11) 0.0911(3) 0.0342(14) Uani 0.686(7) 1 d . . P A 1
H2 H 0.8047 -0.1243 0.1101 0.041 Uiso 0.686(7) 1 calc R . P A 1
C3 C 0.6995(5) 0.1561(8) 0.1485(2) 0.0363(10) Uani 1 1 d . U . . .
H3 H 0.7584 0.0549 0.1158 0.044 Uiso 0.314(7) 1 calc R . P A 2
C4 C 0.6578(4) 0.1081(8) 0.2332(2) 0.0332(9) Uani 1 1 d . . . . .
H4 H 0.6905 -0.0279 0.2563 0.040 Uiso 1 1 calc R . . . .
C5 C 0.5708(5) 0.2492(7) 0.2856(3) 0.0339(9) Uani 1 1 d . . . . .
C6 C 0.5265(4) 0.2015(8) 0.3719(2) 0.0353(10) Uani 1 1 d . . . . .
H6 H 0.5596 0.0677 0.3968 0.042 Uiso 1 1 calc R . . . .
C7 C 0.4371(5) 0.3447(7) 0.4199(2) 0.0365(10) Uani 1 1 d . . . . .
H7 H 0.4082 0.3063 0.4762 0.044 Uiso 1 1 calc R . . . .
C8 C 0.3877(5) 0.5514(9) 0.3851(2) 0.0403(11) Uani 1 1 d . . . . .
H8 H 0.3269 0.6478 0.4190 0.048 Uiso 1 1 calc R . . . .
C9 C 0.4275(4) 0.6126(8) 0.3022(2) 0.0363(9) Uani 1 1 d . . . . .
H9 H 0.3950 0.7497 0.2800 0.044 Uiso 1 1 calc R . . . .
C10 C 0.5213(4) 0.4601(6) 0.2495(2) 0.0266(8) Uani 1 1 d . . . . .
C11 C 0.5624(5) 0.5130(8) 0.1627(2) 0.0369(10) Uani 1 1 d . . . . .
H11 H 0.5303 0.6488 0.1392 0.044 Uiso 1 1 calc R . . . .
C12 C 0.6502(5) 0.3643(8) 0.1122(2) 0.0362(9) Uani 1 1 d . U . . .
C13 C 0.6971(5) 0.4206(8) 0.0237(3) 0.0408(10) Uani 1 1 d . . . . .
H13 H 0.6681 0.5589 0.0012 0.049 Uiso 0.686(7) 1 calc R . P A 1
C14 C 0.7824(5) 0.2767(8) -0.0275(2) 0.0355(9) Uani 1 1 d . . . . .
H14 H 0.8110 0.1388 -0.0046 0.043 Uiso 0.314(7) 1 calc R . P A 2
C15 C 0.8306(5) 0.3294(7) -0.1165(2) 0.0325(9) Uani 1 1 d . U . . .
C16 C 0.7876(5) 0.5398(7) -0.1547(2) 0.0375(10) Uani 1 1 d . U . . .
H16 H 0.7264 0.6392 -0.1223 0.045 Uiso 0.686(7) 1 calc R . P A 1
C17 C 0.8332(4) 0.5999(7) -0.2371(2) 0.0334(9) Uani 1 1 d . . . . .
H17 H 0.8026 0.7370 -0.2601 0.040 Uiso 1 1 calc R . . . .
C18 C 0.9280(4) 0.4494(7) -0.2871(2) 0.0266(8) Uani 1 1 d . U . . .
C19 C 0.9782(4) 0.5066(7) -0.3728(2) 0.0351(10) Uani 1 1 d . . . . .
H19 H 0.9485 0.6428 -0.3970 0.042 Uiso 1 1 calc R . . . .
C20 C 1.0707(5) 0.3594(8) -0.4196(2) 0.0393(10) Uani 1 1 d . . . . .
H20 H 1.1027 0.3960 -0.4757 0.047 Uiso 1 1 calc R . . . .
C21 C 1.1171(4) 0.1538(8) -0.3832(2) 0.0340(9) Uani 1 1 d . . . . .
H21 H 1.1806 0.0557 -0.4150 0.041 Uiso 1 1 calc R . . . .
C22 C 1.0691(4) 0.0988(7) -0.3016(2) 0.0324(9) Uani 1 1 d . . . . .
H22 H 1.1012 -0.0372 -0.2783 0.039 Uiso 1 1 calc R . . . .
C23 C 0.9726(5) 0.2409(8) -0.2515(2) 0.0379(10) Uani 1 1 d . U . . .
C24 C 0.9222(4) 0.1877(7) -0.1667(2) 0.0361(10) Uani 1 1 d . . . . .
H24 H 0.9520 0.0506 -0.1435 0.043 Uiso 1 1 calc R . . . .
C2A C 0.7132(14) 0.672(2) -0.0958(7) 0.031(3) Uani 0.314(7) 1 d . U P A 2
H2A H 0.6874 0.8154 -0.1141 0.037 Uiso 0.314(7) 1 calc R . P A 2
C1A C 0.6709(16) 0.617(2) -0.0105(8) 0.038(3) Uani 0.314(7) 1 d . U P A 2
H1A H 0.6219 0.7253 0.0235 0.045 Uiso 0.314(7) 1 calc R . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 H1 0.9300 . ?
C1 C2 1.343(7) . ?
C1 C14 1.367(7) . ?
C2 H2 0.9300 . ?
C2 C3 1.376(7) . ?
C3 H3 0.9300 . ?
C3 C4 1.380(5) . ?
C3 C12 1.427(6) . ?
C4 H4 0.9300 . ?
C4 C5 1.377(5) . ?
C5 C6 1.409(5) . ?
C5 C10 1.441(5) . ?
C6 H6 0.9300 . ?
C6 C7 1.357(5) . ?
C7 H7 0.9300 . ?
C7 C8 1.411(6) . ?
C8 H8 0.9300 . ?
C8 C9 1.368(5) . ?
C9 H9 0.9300 . ?
C9 C10 1.452(5) . ?
C10 C11 1.415(5) . ?
C11 H11 0.9300 . ?
C11 C12 1.393(5) . ?
C12 C13 1.458(5) . ?
C13 H13 0.9300 . ?
C13 C14 1.370(4) . ?
C13 C1A 1.310(14) . ?
C14 H14 0.9300 . ?
C14 C15 1.464(5) . ?
C15 C16 1.437(6) . ?
C15 C24 1.380(5) . ?
C16 H16 0.9300 . ?
C16 C17 1.374(5) . ?
C16 C2A 1.358(12) . ?
C17 H17 0.9300 . ?
C17 C18 1.426(5) . ?
C18 C19 1.428(5) . ?
C18 C23 1.414(6) . ?
C19 H19 0.9300 . ?
C19 C20 1.377(6) . ?
C20 H20 0.9300 . ?
C20 C21 1.407(6) . ?
C21 H21 0.9300 . ?
C21 C22 1.360(5) . ?
C22 H22 0.9300 . ?
C22 C23 1.403(6) . ?
C23 C24 1.408(5) . ?
C24 H24 0.9300 . ?
C2A H2A 0.9300 . ?
C2A C1A 1.399(15) . ?
C1A H1A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 H1 117.8 . . ?
C2 C1 C14 124.4(5) . . ?
C14 C1 H1 117.8 . . ?
C1 C2 H2 117.9 . . ?
C1 C2 C3 124.2(6) . . ?
C3 C2 H2 117.9 . . ?
C2 C3 C4 126.9(5) . . ?
C2 C3 C12 114.4(4) . . ?
C4 C3 H3 120.7 . . ?
C4 C3 C12 118.6(4) . . ?
C12 C3 H3 120.7 . . ?
C3 C4 H4 118.0 . . ?
C5 C4 C3 124.1(4) . . ?
C5 C4 H4 118.0 . . ?
C4 C5 C6 124.6(4) . . ?
C4 C5 C10 117.7(3) . . ?
C6 C5 C10 117.7(4) . . ?
C5 C6 H6 119.0 . . ?
C7 C6 C5 122.1(4) . . ?
C7 C6 H6 119.0 . . ?
C6 C7 H7 119.7 . . ?
C6 C7 C8 120.6(3) . . ?
C8 C7 H7 119.7 . . ?
C7 C8 H8 119.4 . . ?
C9 C8 C7 121.2(4) . . ?
C9 C8 H8 119.4 . . ?
C8 C9 H9 120.5 . . ?
C8 C9 C10 119.0(4) . . ?
C10 C9 H9 120.5 . . ?
C5 C10 C9 119.4(3) . . ?
C11 C10 C5 119.3(4) . . ?
C11 C10 C9 121.2(4) . . ?
C10 C11 H11 119.6 . . ?
C12 C11 C10 120.9(4) . . ?
C12 C11 H11 119.6 . . ?
C3 C12 C13 119.4(4) . . ?
C11 C12 C3 119.5(3) . . ?
C11 C12 C13 121.1(4) . . ?
C12 C13 H13 118.9 . . ?
C14 C13 C12 122.2(3) . . ?
C14 C13 H13 118.9 . . ?
C1A C13 C12 122.7(7) . . ?
C1A C13 C14 115.0(7) . . ?
C1 C14 C13 115.2(3) . . ?
C1 C14 C15 121.6(4) . . ?
C13 C14 H14 118.4 . . ?
C13 C14 C15 123.2(3) . . ?
C15 C14 H14 118.4 . . ?
C16 C15 C14 120.2(4) . . ?
C24 C15 C14 123.0(4) . . ?
C24 C15 C16 116.7(3) . . ?
C15 C16 H16 118.7 . . ?
C17 C16 C15 122.6(4) . . ?
C17 C16 H16 118.7 . . ?
C2A C16 C15 110.9(6) . . ?
C2A C16 C17 126.2(7) . . ?
C16 C17 H17 120.4 . . ?
C16 C17 C18 119.1(4) . . ?
C18 C17 H17 120.4 . . ?
C17 C18 C19 120.7(4) . . ?
C23 C18 C17 119.8(3) . . ?
C23 C18 C19 119.6(3) . . ?
C18 C19 H19 120.2 . . ?
C20 C19 C18 119.7(4) . . ?
C20 C19 H19 120.2 . . ?
C19 C20 H20 119.8 . . ?
C19 C20 C21 120.5(4) . . ?
C21 C20 H20 119.8 . . ?
C20 C21 H21 120.1 . . ?
C22 C21 C20 119.9(4) . . ?
C22 C21 H21 120.1 . . ?
C21 C22 H22 119.0 . . ?
C21 C22 C23 122.1(4) . . ?
C23 C22 H22 119.0 . . ?
C22 C23 C18 118.3(3) . . ?
C22 C23 C24 123.0(4) . . ?
C24 C23 C18 118.7(4) . . ?
C15 C24 C23 123.1(4) . . ?
C15 C24 H24 118.5 . . ?
C23 C24 H24 118.5 . . ?
C16 C2A H2A 116.4 . . ?
C16 C2A C1A 127.2(11) . . ?
C1A C2A H2A 116.4 . . ?
C13 C1A C2A 123.2(12) . . ?
C13 C1A H1A 118.4 . . ?
C2A C1A H1A 118.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 -179.2(5) . . . . ?
C1 C2 C3 C12 4.8(8) . . . . ?
C1 C14 C15 C16 177.6(4) . . . . ?
C1 C14 C15 C24 -4.5(6) . . . . ?
C2 C1 C14 C13 -2.6(7) . . . . ?
C2 C1 C14 C15 179.1(5) . . . . ?
C2 C3 C4 C5 -175.8(4) . . . . ?
C2 C3 C12 C11 176.5(4) . . . . ?
C2 C3 C12 C13 -5.4(6) . . . . ?
C3 C4 C5 C6 179.5(4) . . . . ?
C3 C4 C5 C10 -0.3(6) . . . . ?
C3 C12 C13 C14 2.4(6) . . . . ?
C3 C12 C13 C1A -172.7(8) . . . . ?
C4 C3 C12 C11 0.2(6) . . . . ?
C4 C3 C12 C13 178.3(4) . . . . ?
C4 C5 C6 C7 -178.3(4) . . . . ?
C4 C5 C10 C9 179.2(4) . . . . ?
C4 C5 C10 C11 0.4(5) . . . . ?
C5 C6 C7 C8 -1.4(6) . . . . ?
C5 C10 C11 C12 -0.2(5) . . . . ?
C6 C5 C10 C9 -0.7(5) . . . . ?
C6 C5 C10 C11 -179.4(4) . . . . ?
C6 C7 C8 C9 0.3(6) . . . . ?
C7 C8 C9 C10 0.5(6) . . . . ?
C8 C9 C10 C5 -0.3(5) . . . . ?
C8 C9 C10 C11 178.4(4) . . . . ?
C9 C10 C11 C12 -179.0(3) . . . . ?
C10 C5 C6 C7 1.5(6) . . . . ?
C10 C11 C12 C3 -0.1(6) . . . . ?
C10 C11 C12 C13 -178.1(4) . . . . ?
C11 C12 C13 C14 -179.5(4) . . . . ?
C11 C12 C13 C1A 5.3(9) . . . . ?
C12 C3 C4 C5 0.0(6) . . . . ?
C12 C13 C14 C1 1.7(5) . . . . ?
C12 C13 C14 C15 179.9(4) . . . . ?
C12 C13 C1A C2A -179.0(9) . . . . ?
C13 C14 C15 C16 -0.6(5) . . . . ?
C13 C14 C15 C24 177.3(4) . . . . ?
C14 C1 C2 C3 -0.7(9) . . . . ?
C14 C13 C1A C2A 5.5(15) . . . . ?
C14 C15 C16 C17 178.4(4) . . . . ?
C14 C15 C16 C2A 4.5(7) . . . . ?
C14 C15 C24 C23 -178.2(4) . . . . ?
C15 C16 C17 C18 -0.5(6) . . . . ?
C15 C16 C2A C1A -4.0(14) . . . . ?
C16 C15 C24 C23 -0.2(6) . . . . ?
C16 C17 C18 C19 -179.8(3) . . . . ?
C16 C17 C18 C23 0.5(5) . . . . ?
C16 C2A C1A C13 -1(2) . . . . ?
C17 C16 C2A C1A -177.5(9) . . . . ?
C17 C18 C19 C20 179.5(3) . . . . ?
C17 C18 C23 C22 -178.6(4) . . . . ?
C17 C18 C23 C24 -0.3(5) . . . . ?
C18 C19 C20 C21 -0.5(6) . . . . ?
C18 C23 C24 C15 0.2(6) . . . . ?
C19 C18 C23 C22 1.6(5) . . . . ?
C19 C18 C23 C24 179.9(4) . . . . ?
C19 C20 C21 C22 0.7(6) . . . . ?
C20 C21 C22 C23 0.4(6) . . . . ?
C21 C22 C23 C18 -1.5(5) . . . . ?
C21 C22 C23 C24 -179.7(4) . . . . ?
C22 C23 C24 C15 178.4(3) . . . . ?
C23 C18 C19 C20 -0.7(5) . . . . ?
C24 C15 C16 C17 0.3(6) . . . . ?
C24 C15 C16 C2A -173.5(6) . . . . ?
C2A C16 C17 C18 172.4(7) . . . . ?
C1A C13 C14 C15 -4.6(8) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Toluene'
_exptl_crystal_preparation       Luminescent
