# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_dq0215
_database_code_depnum_ccdc_archive 'CCDC 1452271'
_audit_update_record             
;
2016-02-08 deposited with the CCDC.
2016-03-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H75 Cl N4 Pu Si3'
_chemical_formula_weight         886.69

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pu Pu -9.4100 4.3056 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/n'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.0136(10)
_cell_length_b                   15.5458(12)
_cell_length_c                   20.4330(15)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.5460(10)
_cell_angle_gamma                90.00
_cell_volume                     4133.5(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(1)
_cell_measurement_reflns_used    9494
_cell_measurement_theta_min      2.86
_cell_measurement_theta_max      34.91

_exptl_crystal_description       block
_exptl_crystal_colour            green
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.430
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1816
_exptl_absorpt_coefficient_mu    1.772
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4711
_exptl_absorpt_correction_T_max  0.7769
_exptl_absorpt_process_details   'SADABS v. 2.03 (Sheldrick, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(1)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker D8 with APEXII CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            94248
_diffrn_reflns_av_R_equivalents  0.0250
_diffrn_reflns_av_sigmaI/netI    0.0190
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         2.26
_diffrn_reflns_theta_max         35.36
_reflns_number_total             17439
_reflns_number_gt                15337
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX II, v. 7.0 (Bruker AXS, 2009)'
_computing_cell_refinement       'SAINT+, v. 7.66a (Bruker AXS, 2009)'
_computing_data_reduction        'SAINT+, v. 7.66a (Bruker AXS, 2009)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL, v. 6.14, (Bruker AXS, 2000)'
_computing_publication_material  'SHELXTL, v. 6.14, (Bruker AXS, 2000)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0290P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom

_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         17439
_refine_ls_number_parameters     397
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0374
_refine_ls_R_factor_gt           0.0291
_refine_ls_wR_factor_ref         0.0838
_refine_ls_wR_factor_gt          0.0764
_refine_ls_goodness_of_fit_ref   1.904
_refine_ls_restrained_S_all      1.904
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pu1 Pu 0.617487(5) 0.381162(4) 0.254093(3) 0.01091(3) Uani 1 1 d . . .
Cl1 Cl 0.69046(4) 0.22584(3) 0.26278(3) 0.02251(10) Uani 1 1 d . . .
Si1 Si 0.35105(4) 0.31159(4) 0.25772(3) 0.01544(10) Uani 1 1 d . . .
Si2 Si 0.76208(5) 0.41875(4) 0.40523(3) 0.01774(10) Uani 1 1 d . . .
Si3 Si 0.72635(5) 0.39783(4) 0.09200(3) 0.01796(11) Uani 1 1 d . . .
N1 N 0.55901(13) 0.53955(10) 0.25364(8) 0.0143(3) Uani 1 1 d . . .
N2 N 0.44989(14) 0.38407(9) 0.27598(9) 0.0140(3) Uani 1 1 d . . .
N3 N 0.70749(13) 0.44971(11) 0.33025(8) 0.0160(3) Uani 1 1 d . . .
N4 N 0.64600(13) 0.43425(11) 0.15443(8) 0.0165(3) Uani 1 1 d . . .
C1 C 0.44784(15) 0.54175(12) 0.26682(10) 0.0171(3) Uani 1 1 d . . .
H1A H 0.4096 0.5400 0.2259 0.021 Uiso 1 1 calc R . .
H1B H 0.4306 0.5947 0.2893 0.021 Uiso 1 1 calc R . .
C2 C 0.41890(16) 0.46499(12) 0.30890(10) 0.0173(3) Uani 1 1 d . . .
H2A H 0.4530 0.4692 0.3512 0.021 Uiso 1 1 calc R . .
H2B H 0.3453 0.4648 0.3159 0.021 Uiso 1 1 calc R . .
C3 C 0.61984(16) 0.58471(12) 0.30542(10) 0.0178(3) Uani 1 1 d . . .
H3A H 0.5846 0.5815 0.3470 0.021 Uiso 1 1 calc R . .
H3B H 0.6284 0.6448 0.2940 0.021 Uiso 1 1 calc R . .
C4 C 0.72383(16) 0.54090(13) 0.31055(11) 0.0189(4) Uani 1 1 d . . .
H4A H 0.7583 0.5432 0.2687 0.023 Uiso 1 1 calc R . .
H4B H 0.7665 0.5700 0.3428 0.023 Uiso 1 1 calc R . .
C5 C 0.58355(16) 0.57674(13) 0.18838(10) 0.0182(4) Uani 1 1 d . . .
H5A H 0.6521 0.6012 0.1894 0.022 Uiso 1 1 calc R . .
H5B H 0.5352 0.6223 0.1778 0.022 Uiso 1 1 calc R . .
C6 C 0.57746(16) 0.50705(13) 0.13660(10) 0.0189(4) Uani 1 1 d . . .
H6A H 0.5072 0.4867 0.1326 0.023 Uiso 1 1 calc R . .
H6B H 0.5977 0.5305 0.0947 0.023 Uiso 1 1 calc R . .
C7 C 0.26287(18) 0.35063(15) 0.18893(12) 0.0236(4) Uani 1 1 d . . .
H7 H 0.2184 0.3020 0.1773 0.028 Uiso 1 1 calc R . .
C8 C 0.3215(2) 0.37444(18) 0.12701(14) 0.0322(6) Uani 1 1 d . . .
H8A H 0.2737 0.3819 0.0913 0.048 Uiso 1 1 calc R . .
H8B H 0.3689 0.3293 0.1166 0.048 Uiso 1 1 calc R . .
H8C H 0.3585 0.4271 0.1342 0.048 Uiso 1 1 calc R . .
C9 C 0.1910(2) 0.42552(18) 0.20711(15) 0.0366(6) Uani 1 1 d . . .
H9A H 0.2312 0.4737 0.2217 0.055 Uiso 1 1 calc R . .
H9B H 0.1460 0.4076 0.2415 0.055 Uiso 1 1 calc R . .
H9C H 0.1509 0.4419 0.1694 0.055 Uiso 1 1 calc R . .
C10 C 0.26497(17) 0.29517(14) 0.33113(12) 0.0229(4) Uani 1 1 d . . .
H10 H 0.2242 0.3479 0.3351 0.027 Uiso 1 1 calc R . .
C11 C 0.3214(2) 0.28444(18) 0.39649(12) 0.0308(5) Uani 1 1 d . . .
H11A H 0.2727 0.2858 0.4315 0.046 Uiso 1 1 calc R . .
H11B H 0.3700 0.3304 0.4021 0.046 Uiso 1 1 calc R . .
H11C H 0.3570 0.2304 0.3970 0.046 Uiso 1 1 calc R . .
C12 C 0.18742(19) 0.22184(17) 0.32097(15) 0.0332(6) Uani 1 1 d . . .
H12A H 0.2237 0.1688 0.3145 0.050 Uiso 1 1 calc R . .
H12B H 0.1454 0.2338 0.2832 0.050 Uiso 1 1 calc R . .
H12C H 0.1447 0.2171 0.3588 0.050 Uiso 1 1 calc R . .
C13 C 0.41404(17) 0.20734(14) 0.23014(11) 0.0220(4) Uani 1 1 d . . .
H13 H 0.4760 0.2238 0.2063 0.026 Uiso 1 1 calc R . .
C14 C 0.3477(2) 0.15399(17) 0.18223(16) 0.0386(7) Uani 1 1 d . . .
H14A H 0.3837 0.1023 0.1708 0.058 Uiso 1 1 calc R . .
H14B H 0.3343 0.1871 0.1434 0.058 Uiso 1 1 calc R . .
H14C H 0.2839 0.1394 0.2026 0.058 Uiso 1 1 calc R . .
C15 C 0.4499(2) 0.14944(15) 0.28693(13) 0.0274(5) Uani 1 1 d . . .
H15A H 0.3911 0.1254 0.3083 0.041 Uiso 1 1 calc R . .
H15B H 0.4891 0.1829 0.3178 0.041 Uiso 1 1 calc R . .
H15C H 0.4919 0.1038 0.2702 0.041 Uiso 1 1 calc R . .
C16 C 0.70353(19) 0.31265(15) 0.43056(11) 0.0249(4) Uani 1 1 d . . .
H16 H 0.7272 0.2700 0.3988 0.030 Uiso 1 1 calc R . .
C17 C 0.5863(2) 0.30799(16) 0.42951(13) 0.0293(5) Uani 1 1 d . . .
H17A H 0.5650 0.2493 0.4350 0.044 Uiso 1 1 calc R . .
H17B H 0.5608 0.3294 0.3884 0.044 Uiso 1 1 calc R . .
H17C H 0.5595 0.3423 0.4645 0.044 Uiso 1 1 calc R . .
C18 C 0.7443(3) 0.2825(2) 0.49810(15) 0.0466(8) Uani 1 1 d . . .
H18A H 0.7201 0.3208 0.5314 0.070 Uiso 1 1 calc R . .
H18B H 0.8181 0.2827 0.4981 0.070 Uiso 1 1 calc R . .
H18C H 0.7201 0.2253 0.5067 0.070 Uiso 1 1 calc R . .
C19 C 0.74058(19) 0.50803(16) 0.46753(11) 0.0256(4) Uani 1 1 d . . .
H19 H 0.7527 0.5621 0.4442 0.031 Uiso 1 1 calc R . .
C20 C 0.8151(2) 0.5083(2) 0.52618(14) 0.0411(7) Uani 1 1 d . . .
H20A H 0.8002 0.5565 0.5539 0.062 Uiso 1 1 calc R . .
H20B H 0.8843 0.5126 0.5108 0.062 Uiso 1 1 calc R . .
H20C H 0.8073 0.4559 0.5505 0.062 Uiso 1 1 calc R . .
C21 C 0.6296(2) 0.5122(2) 0.49131(14) 0.0358(6) Uani 1 1 d . . .
H21A H 0.6172 0.4656 0.5210 0.054 Uiso 1 1 calc R . .
H21B H 0.5835 0.5077 0.4545 0.054 Uiso 1 1 calc R . .
H21C H 0.6184 0.5659 0.5133 0.054 Uiso 1 1 calc R . .
C22 C 0.90588(19) 0.40139(18) 0.39840(13) 0.0279(5) Uani 1 1 d . . .
H22 H 0.9335 0.3982 0.4431 0.033 Uiso 1 1 calc R . .
C23 C 0.95976(19) 0.4766(2) 0.36478(14) 0.0346(6) Uani 1 1 d . . .
H23A H 1.0324 0.4660 0.3638 0.052 Uiso 1 1 calc R . .
H23B H 0.9468 0.5287 0.3886 0.052 Uiso 1 1 calc R . .
H23C H 0.9339 0.4823 0.3208 0.052 Uiso 1 1 calc R . .
C24 C 0.9327(3) 0.3166(2) 0.36481(19) 0.0473(8) Uani 1 1 d . . .
H24A H 0.9008 0.3148 0.3222 0.071 Uiso 1 1 calc R . .
H24B H 0.9081 0.2694 0.3906 0.071 Uiso 1 1 calc R . .
H24C H 1.0059 0.3122 0.3604 0.071 Uiso 1 1 calc R . .
C25 C 0.6510(2) 0.32983(16) 0.03110(11) 0.0267(5) Uani 1 1 d . . .
H25 H 0.6997 0.3101 -0.0020 0.032 Uiso 1 1 calc R . .
C26 C 0.6048(3) 0.24902(18) 0.06305(17) 0.0419(7) Uani 1 1 d . . .
H26A H 0.5536 0.2659 0.0940 0.063 Uiso 1 1 calc R . .
H26B H 0.6582 0.2174 0.0851 0.063 Uiso 1 1 calc R . .
H26C H 0.5739 0.2134 0.0299 0.063 Uiso 1 1 calc R . .
C27 C 0.5659(3) 0.38009(18) -0.00513(14) 0.0362(6) Uani 1 1 d . . .
H27A H 0.5328 0.3431 -0.0365 0.054 Uiso 1 1 calc R . .
H27B H 0.5956 0.4284 -0.0273 0.054 Uiso 1 1 calc R . .
H27C H 0.5163 0.4001 0.0258 0.054 Uiso 1 1 calc R . .
C28 C 0.7825(2) 0.49236(16) 0.04488(12) 0.0284(5) Uani 1 1 d . . .
H28 H 0.7238 0.5255 0.0282 0.034 Uiso 1 1 calc R . .
C29 C 0.8458(3) 0.5544(2) 0.08707(18) 0.0606(11) Uani 1 1 d . . .
H29A H 0.9089 0.5270 0.1002 0.091 Uiso 1 1 calc R . .
H29B H 0.8075 0.5697 0.1252 0.091 Uiso 1 1 calc R . .
H29C H 0.8609 0.6052 0.0623 0.091 Uiso 1 1 calc R . .
C30 C 0.8446(3) 0.4658(2) -0.01524(15) 0.0408(7) Uani 1 1 d . . .
H30A H 0.8670 0.5164 -0.0380 0.061 Uiso 1 1 calc R . .
H30B H 0.8024 0.4316 -0.0438 0.061 Uiso 1 1 calc R . .
H30C H 0.9034 0.4330 -0.0015 0.061 Uiso 1 1 calc R . .
C31 C 0.82894(18) 0.32651(17) 0.13025(11) 0.0244(4) Uani 1 1 d . . .
H31 H 0.7915 0.2814 0.1535 0.029 Uiso 1 1 calc R . .
C32 C 0.8961(3) 0.2793(2) 0.08090(15) 0.0500(9) Uani 1 1 d . . .
H32A H 0.9363 0.3203 0.0571 0.075 Uiso 1 1 calc R . .
H32B H 0.8531 0.2478 0.0509 0.075 Uiso 1 1 calc R . .
H32C H 0.9410 0.2403 0.1037 0.075 Uiso 1 1 calc R . .
C33 C 0.8960(3) 0.3701(2) 0.1820(2) 0.0577(11) Uani 1 1 d . . .
H33A H 0.9325 0.3272 0.2067 0.086 Uiso 1 1 calc R . .
H33B H 0.8534 0.4031 0.2108 0.086 Uiso 1 1 calc R . .
H33C H 0.9442 0.4076 0.1610 0.086 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pu1 N3 2.2122(17) . ?
Pu1 N2 2.2311(18) . ?
Pu1 N4 2.2317(17) . ?
Pu1 N1 2.5772(16) . ?
Pu1 Cl1 2.6001(5) . ?
Pu1 C4 3.063(2) . ?
Si1 N2 1.7475(17) . ?
Si1 C10 1.898(2) . ?
Si1 C13 1.904(2) . ?
Si1 C7 1.905(2) . ?
Si2 N3 1.7501(18) . ?
Si2 C16 1.891(2) . ?
Si2 C22 1.897(3) . ?
Si2 C19 1.906(2) . ?
Si3 N4 1.7511(18) . ?
Si3 C31 1.898(2) . ?
Si3 C25 1.898(2) . ?
Si3 C28 1.906(2) . ?
N1 C1 1.474(3) . ?
N1 C5 1.491(3) . ?
N1 C3 1.491(3) . ?
N2 C2 1.484(2) . ?
N3 C4 1.489(3) . ?
N4 C6 1.484(3) . ?
C1 C2 1.520(3) . ?
C3 C4 1.518(3) . ?
C5 C6 1.516(3) . ?
C7 C8 1.529(4) . ?
C7 C9 1.541(4) . ?
C10 C11 1.527(3) . ?
C10 C12 1.535(3) . ?
C13 C15 1.538(3) . ?
C13 C14 1.541(3) . ?
C16 C17 1.527(4) . ?
C16 C18 1.547(3) . ?
C19 C21 1.530(4) . ?
C19 C20 1.534(3) . ?
C22 C24 1.528(4) . ?
C22 C23 1.530(4) . ?
C25 C27 1.539(4) . ?
C25 C26 1.540(4) . ?
C28 C29 1.529(4) . ?
C28 C30 1.534(4) . ?
C31 C33 1.523(4) . ?
C31 C32 1.528(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pu1 N2 111.18(6) . . ?
N3 Pu1 N4 111.85(6) . . ?
N2 Pu1 N4 110.29(6) . . ?
N3 Pu1 N1 72.34(6) . . ?
N2 Pu1 N1 72.07(5) . . ?
N4 Pu1 N1 72.24(6) . . ?
N3 Pu1 Cl1 102.05(4) . . ?
N2 Pu1 Cl1 111.24(4) . . ?
N4 Pu1 Cl1 110.00(4) . . ?
N1 Pu1 Cl1 174.35(4) . . ?
N3 Pu1 C4 27.17(6) . . ?
N2 Pu1 C4 110.31(6) . . ?
N4 Pu1 C4 88.01(6) . . ?
N1 Pu1 C4 50.14(5) . . ?
Cl1 Pu1 C4 124.32(4) . . ?
N2 Si1 C10 110.90(9) . . ?
N2 Si1 C13 107.10(9) . . ?
C10 Si1 C13 112.24(10) . . ?
N2 Si1 C7 112.89(9) . . ?
C10 Si1 C7 105.66(11) . . ?
C13 Si1 C7 108.11(10) . . ?
N3 Si2 C16 108.55(9) . . ?
N3 Si2 C22 111.54(10) . . ?
C16 Si2 C22 107.24(12) . . ?
N3 Si2 C19 108.88(10) . . ?
C16 Si2 C19 112.97(11) . . ?
C22 Si2 C19 107.69(11) . . ?
N4 Si3 C31 108.14(9) . . ?
N4 Si3 C25 110.45(10) . . ?
C31 Si3 C25 107.55(11) . . ?
N4 Si3 C28 110.67(10) . . ?
C31 Si3 C28 112.75(12) . . ?
C25 Si3 C28 107.23(12) . . ?
C1 N1 C5 111.92(15) . . ?
C1 N1 C3 112.01(16) . . ?
C5 N1 C3 109.59(16) . . ?
C1 N1 Pu1 108.16(11) . . ?
C5 N1 Pu1 107.94(11) . . ?
C3 N1 Pu1 107.01(11) . . ?
C2 N2 Si1 116.15(13) . . ?
C2 N2 Pu1 112.23(12) . . ?
Si1 N2 Pu1 131.53(9) . . ?
C4 N3 Si2 116.14(13) . . ?
C4 N3 Pu1 110.14(12) . . ?
Si2 N3 Pu1 133.72(9) . . ?
C6 N4 Si3 115.43(13) . . ?
C6 N4 Pu1 113.65(12) . . ?
Si3 N4 Pu1 130.60(9) . . ?
N1 C1 C2 109.50(16) . . ?
N2 C2 C1 109.82(16) . . ?
N1 C3 C4 107.74(16) . . ?
N3 C4 C3 108.44(16) . . ?
N3 C4 Pu1 42.70(9) . . ?
C3 C4 Pu1 86.48(11) . . ?
N1 C5 C6 109.68(16) . . ?
N4 C6 C5 110.26(16) . . ?
C8 C7 C9 109.0(2) . . ?
C8 C7 Si1 112.71(17) . . ?
C9 C7 Si1 115.20(17) . . ?
C11 C10 C12 110.3(2) . . ?
C11 C10 Si1 115.05(16) . . ?
C12 C10 Si1 112.65(17) . . ?
C15 C13 C14 109.2(2) . . ?
C15 C13 Si1 113.79(16) . . ?
C14 C13 Si1 113.97(16) . . ?
C17 C16 C18 109.4(2) . . ?
C17 C16 Si2 116.27(16) . . ?
C18 C16 Si2 111.86(18) . . ?
C21 C19 C20 110.1(2) . . ?
C21 C19 Si2 112.82(17) . . ?
C20 C19 Si2 115.34(18) . . ?
C24 C22 C23 110.5(3) . . ?
C24 C22 Si2 112.6(2) . . ?
C23 C22 Si2 112.40(18) . . ?
C27 C25 C26 109.6(2) . . ?
C27 C25 Si3 113.41(17) . . ?
C26 C25 Si3 112.18(18) . . ?
C29 C28 C30 109.6(2) . . ?
C29 C28 Si3 114.1(2) . . ?
C30 C28 Si3 113.88(19) . . ?
C33 C31 C32 110.1(3) . . ?
C33 C31 Si3 114.9(2) . . ?
C32 C31 Si3 114.39(18) . . ?

_diffrn_measured_fraction_theta_max 0.934
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         2.936
_refine_diff_density_min         -2.509
_refine_diff_density_rms         0.222
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_decay_%        0

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_apx1791
_database_code_depnum_ccdc_archive 'CCDC 1452272'
_audit_update_record             
;
2016-02-08 deposited with the CCDC.
2016-03-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H75 Cl N4 Np Si3'
_chemical_formula_weight         884.69

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Np Np -11.4937 4.1493 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/n'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.9845(10)
_cell_length_b                   15.6008(12)
_cell_length_c                   20.4035(15)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.648(1)
_cell_angle_gamma                90.00
_cell_volume                     4132.8(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    140(1)
_cell_measurement_reflns_used    9853
_cell_measurement_theta_min      2.26
_cell_measurement_theta_max      28.46

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.422
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1812
_exptl_absorpt_coefficient_mu    2.692
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.3977
_exptl_absorpt_correction_T_max  0.7383
_exptl_absorpt_process_details   'SADABS v. 2.03 (Sheldrick, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      140(1)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker D8 with APEXII CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            47211
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_av_sigmaI/netI    0.0331
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         1.85
_diffrn_reflns_theta_max         28.58
_reflns_number_total             9786
_reflns_number_gt                8172
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX II, v. 7.0 (Bruker AXS, 2009)'
_computing_cell_refinement       'SAINT+, v. 7.66a (Bruker AXS, 2009)'
_computing_data_reduction        'SAINT+, v. 7.66a (Bruker AXS, 2009)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL, v. 6.14, (Bruker AXS, 2000)'
_computing_publication_material  'SHELXTL, v. 6.14, (Bruker AXS, 2000)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0191P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom

_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9786
_refine_ls_number_parameters     397
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0357
_refine_ls_R_factor_gt           0.0241
_refine_ls_wR_factor_ref         0.0474
_refine_ls_wR_factor_gt          0.0448
_refine_ls_goodness_of_fit_ref   1.114
_refine_ls_restrained_S_all      1.114
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Np1 Np 0.617611(7) 0.380045(5) 0.254002(4) 0.01072(3) Uani 1 1 d . . .
Cl1 Cl 0.69283(5) 0.22472(4) 0.26411(3) 0.02117(14) Uani 1 1 d . . .
Si1 Si 0.35052(5) 0.31158(4) 0.25797(3) 0.01496(14) Uani 1 1 d . . .
Si2 Si 0.76275(5) 0.41950(4) 0.40525(3) 0.01528(14) Uani 1 1 d . . .
Si3 Si 0.72455(6) 0.39775(4) 0.09189(3) 0.01672(15) Uani 1 1 d . . .
N1 N 0.55773(15) 0.53938(12) 0.25335(9) 0.0128(4) Uani 1 1 d . . .
N2 N 0.44963(15) 0.38379(12) 0.27592(9) 0.0133(4) Uani 1 1 d . . .
N3 N 0.70713(15) 0.44919(12) 0.32978(9) 0.0136(4) Uani 1 1 d . . .
N4 N 0.64519(15) 0.43382(12) 0.15444(9) 0.0150(4) Uani 1 1 d . . .
C1 C 0.44638(18) 0.54095(15) 0.26692(12) 0.0154(5) Uani 1 1 d . . .
H1A H 0.4076 0.5388 0.2260 0.018 Uiso 1 1 calc R . .
H1B H 0.4288 0.5936 0.2894 0.018 Uiso 1 1 calc R . .
C2 C 0.41873(19) 0.46436(14) 0.30930(12) 0.0156(5) Uani 1 1 d . . .
H2A H 0.4538 0.4687 0.3514 0.019 Uiso 1 1 calc R . .
H2B H 0.3451 0.4638 0.3169 0.019 Uiso 1 1 calc R . .
C3 C 0.61908(19) 0.58385(15) 0.30539(12) 0.0161(5) Uani 1 1 d . . .
H3A H 0.5840 0.5802 0.3470 0.019 Uiso 1 1 calc R . .
H3B H 0.6276 0.6439 0.2943 0.019 Uiso 1 1 calc R . .
C4 C 0.72298(19) 0.54038(14) 0.31017(12) 0.0165(5) Uani 1 1 d . . .
H4A H 0.7572 0.5429 0.2682 0.020 Uiso 1 1 calc R . .
H4B H 0.7660 0.5693 0.3424 0.020 Uiso 1 1 calc R . .
C5 C 0.58180(19) 0.57624(15) 0.18798(11) 0.0160(5) Uani 1 1 d . . .
H5A H 0.6504 0.6009 0.1889 0.019 Uiso 1 1 calc R . .
H5B H 0.5331 0.6214 0.1774 0.019 Uiso 1 1 calc R . .
C6 C 0.57577(19) 0.50682(15) 0.13653(12) 0.0173(5) Uani 1 1 d . . .
H6A H 0.5054 0.4864 0.1326 0.021 Uiso 1 1 calc R . .
H6B H 0.5957 0.5301 0.0945 0.021 Uiso 1 1 calc R . .
C7 C 0.2617(2) 0.35042(17) 0.18967(12) 0.0214(6) Uani 1 1 d . . .
H7 H 0.2172 0.3019 0.1780 0.026 Uiso 1 1 calc R . .
C8 C 0.3200(2) 0.37396(18) 0.12781(13) 0.0313(7) Uani 1 1 d . . .
H8A H 0.2723 0.3789 0.0917 0.047 Uiso 1 1 calc R . .
H8B H 0.3696 0.3302 0.1185 0.047 Uiso 1 1 calc R . .
H8C H 0.3547 0.4277 0.1343 0.047 Uiso 1 1 calc R . .
C9 C 0.1895(2) 0.42483(18) 0.20834(15) 0.0332(7) Uani 1 1 d . . .
H9A H 0.2299 0.4740 0.2205 0.050 Uiso 1 1 calc R . .
H9B H 0.1476 0.4078 0.2446 0.050 Uiso 1 1 calc R . .
H9C H 0.1460 0.4390 0.1715 0.050 Uiso 1 1 calc R . .
C10 C 0.26513(19) 0.29485(16) 0.33150(13) 0.0203(6) Uani 1 1 d . . .
H10 H 0.2240 0.3472 0.3355 0.024 Uiso 1 1 calc R . .
C11 C 0.3220(2) 0.28440(17) 0.39697(13) 0.0261(6) Uani 1 1 d . . .
H11A H 0.2735 0.2875 0.4321 0.039 Uiso 1 1 calc R . .
H11B H 0.3720 0.3293 0.4019 0.039 Uiso 1 1 calc R . .
H11C H 0.3561 0.2298 0.3981 0.039 Uiso 1 1 calc R . .
C12 C 0.1874(2) 0.22150(17) 0.32118(15) 0.0289(7) Uani 1 1 d . . .
H12A H 0.2238 0.1683 0.3167 0.043 Uiso 1 1 calc R . .
H12B H 0.1474 0.2321 0.2822 0.043 Uiso 1 1 calc R . .
H12C H 0.1426 0.2183 0.3582 0.043 Uiso 1 1 calc R . .
C13 C 0.4138(2) 0.20848(16) 0.23025(13) 0.0209(6) Uani 1 1 d . . .
H13 H 0.4758 0.2253 0.2065 0.025 Uiso 1 1 calc R . .
C14 C 0.3480(2) 0.15511(18) 0.18216(15) 0.0368(8) Uani 1 1 d . . .
H14A H 0.3852 0.1045 0.1699 0.055 Uiso 1 1 calc R . .
H14B H 0.3329 0.1886 0.1438 0.055 Uiso 1 1 calc R . .
H14C H 0.2849 0.1389 0.2028 0.055 Uiso 1 1 calc R . .
C15 C 0.4502(2) 0.15018(16) 0.28682(14) 0.0261(6) Uani 1 1 d . . .
H15A H 0.3914 0.1250 0.3075 0.039 Uiso 1 1 calc R . .
H15B H 0.4883 0.1835 0.3183 0.039 Uiso 1 1 calc R . .
H15C H 0.4935 0.1057 0.2699 0.039 Uiso 1 1 calc R . .
C16 C 0.7055(2) 0.31383(16) 0.43082(13) 0.0222(6) Uani 1 1 d . . .
H16 H 0.7298 0.2715 0.3991 0.027 Uiso 1 1 calc R . .
C17 C 0.5880(2) 0.30808(17) 0.42930(13) 0.0263(6) Uani 1 1 d . . .
H17A H 0.5674 0.2495 0.4353 0.039 Uiso 1 1 calc R . .
H17B H 0.5624 0.3285 0.3878 0.039 Uiso 1 1 calc R . .
H17C H 0.5604 0.3426 0.4638 0.039 Uiso 1 1 calc R . .
C18 C 0.7463(3) 0.28401(19) 0.49830(14) 0.0404(8) Uani 1 1 d . . .
H18A H 0.7190 0.3204 0.5319 0.061 Uiso 1 1 calc R . .
H18B H 0.8201 0.2871 0.4991 0.061 Uiso 1 1 calc R . .
H18C H 0.7250 0.2259 0.5059 0.061 Uiso 1 1 calc R . .
C19 C 0.7411(2) 0.50810(17) 0.46721(12) 0.0212(6) Uani 1 1 d . . .
H19 H 0.7525 0.5620 0.4437 0.025 Uiso 1 1 calc R . .
C20 C 0.8163(2) 0.5090(2) 0.52567(14) 0.0372(8) Uani 1 1 d . . .
H20A H 0.7999 0.5560 0.5541 0.056 Uiso 1 1 calc R . .
H20B H 0.8854 0.5155 0.5102 0.056 Uiso 1 1 calc R . .
H20C H 0.8107 0.4561 0.5494 0.056 Uiso 1 1 calc R . .
C21 C 0.6303(2) 0.51167(19) 0.49140(14) 0.0312(7) Uani 1 1 d . . .
H21A H 0.6179 0.4640 0.5200 0.047 Uiso 1 1 calc R . .
H21B H 0.5837 0.5090 0.4546 0.047 Uiso 1 1 calc R . .
H21C H 0.6197 0.5642 0.5148 0.047 Uiso 1 1 calc R . .
C22 C 0.9063(2) 0.40312(17) 0.39820(14) 0.0241(6) Uani 1 1 d . . .
H22 H 0.9342 0.4000 0.4429 0.029 Uiso 1 1 calc R . .
C23 C 0.9596(2) 0.47840(19) 0.36454(14) 0.0310(7) Uani 1 1 d . . .
H23A H 1.0326 0.4685 0.3641 0.046 Uiso 1 1 calc R . .
H23B H 0.9456 0.5303 0.3881 0.046 Uiso 1 1 calc R . .
H23C H 0.9342 0.4836 0.3204 0.046 Uiso 1 1 calc R . .
C24 C 0.9340(2) 0.3186(2) 0.36425(17) 0.0441(9) Uani 1 1 d . . .
H24A H 0.8992 0.3155 0.3226 0.066 Uiso 1 1 calc R . .
H24B H 0.9130 0.2713 0.3911 0.066 Uiso 1 1 calc R . .
H24C H 1.0070 0.3162 0.3578 0.066 Uiso 1 1 calc R . .
C25 C 0.6494(2) 0.32970(17) 0.03165(13) 0.0245(6) Uani 1 1 d . . .
H25 H 0.6983 0.3098 -0.0013 0.029 Uiso 1 1 calc R . .
C26 C 0.6036(3) 0.24953(18) 0.06370(17) 0.0419(8) Uani 1 1 d . . .
H26A H 0.5546 0.2664 0.0962 0.063 Uiso 1 1 calc R . .
H26B H 0.6576 0.2168 0.0841 0.063 Uiso 1 1 calc R . .
H26C H 0.5697 0.2152 0.0309 0.063 Uiso 1 1 calc R . .
C27 C 0.5646(2) 0.37879(19) -0.00514(14) 0.0340(7) Uani 1 1 d . . .
H27A H 0.5321 0.3416 -0.0366 0.051 Uiso 1 1 calc R . .
H27B H 0.5941 0.4270 -0.0273 0.051 Uiso 1 1 calc R . .
H27C H 0.5142 0.3986 0.0255 0.051 Uiso 1 1 calc R . .
C28 C 0.7799(2) 0.49119(17) 0.04436(13) 0.0267(6) Uani 1 1 d . . .
H28 H 0.7208 0.5234 0.0270 0.032 Uiso 1 1 calc R . .
C29 C 0.8421(3) 0.5543(2) 0.08602(17) 0.0580(11) Uani 1 1 d . . .
H29A H 0.9049 0.5275 0.1006 0.087 Uiso 1 1 calc R . .
H29B H 0.8026 0.5711 0.1233 0.087 Uiso 1 1 calc R . .
H29C H 0.8581 0.6041 0.0603 0.087 Uiso 1 1 calc R . .
C30 C 0.8433(2) 0.4647(2) -0.01521(14) 0.0400(8) Uani 1 1 d . . .
H30A H 0.8625 0.5149 -0.0395 0.060 Uiso 1 1 calc R . .
H30B H 0.8030 0.4275 -0.0428 0.060 Uiso 1 1 calc R . .
H30C H 0.9043 0.4352 -0.0007 0.060 Uiso 1 1 calc R . .
C31 C 0.8274(2) 0.32752(17) 0.13010(13) 0.0245(6) Uani 1 1 d . . .
H31 H 0.7902 0.2832 0.1542 0.029 Uiso 1 1 calc R . .
C32 C 0.8943(3) 0.2792(2) 0.08117(15) 0.0467(9) Uani 1 1 d . . .
H32A H 0.9329 0.3195 0.0558 0.070 Uiso 1 1 calc R . .
H32B H 0.8510 0.2457 0.0525 0.070 Uiso 1 1 calc R . .
H32C H 0.9408 0.2420 0.1045 0.070 Uiso 1 1 calc R . .
C33 C 0.8951(3) 0.3718(2) 0.18052(19) 0.0581(11) Uani 1 1 d . . .
H33A H 0.9339 0.3297 0.2046 0.087 Uiso 1 1 calc R . .
H33B H 0.8529 0.4038 0.2101 0.087 Uiso 1 1 calc R . .
H33C H 0.9416 0.4100 0.1588 0.087 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Np1 N3 2.2056(19) . ?
Np1 N4 2.2305(19) . ?
Np1 N2 2.2322(19) . ?
Np1 N1 2.6046(19) . ?
Np1 Cl1 2.6200(6) . ?
Np1 C4 3.067(2) . ?
Si1 N2 1.746(2) . ?
Si1 C10 1.894(3) . ?
Si1 C13 1.895(3) . ?
Si1 C7 1.898(3) . ?
Si2 N3 1.756(2) . ?
Si2 C16 1.885(3) . ?
Si2 C22 1.888(3) . ?
Si2 C19 1.896(3) . ?
Si3 N4 1.743(2) . ?
Si3 C25 1.887(3) . ?
Si3 C31 1.889(3) . ?
Si3 C28 1.897(3) . ?
N1 C1 1.475(3) . ?
N1 C5 1.489(3) . ?
N1 C3 1.491(3) . ?
N2 C2 1.487(3) . ?
N3 C4 1.493(3) . ?
N4 C6 1.495(3) . ?
C1 C2 1.520(3) . ?
C3 C4 1.512(3) . ?
C5 C6 1.510(3) . ?
C7 C8 1.524(4) . ?
C7 C9 1.542(4) . ?
C10 C11 1.527(4) . ?
C10 C12 1.538(3) . ?
C13 C15 1.539(3) . ?
C13 C14 1.539(3) . ?
C16 C17 1.528(4) . ?
C16 C18 1.541(3) . ?
C19 C21 1.527(4) . ?
C19 C20 1.533(3) . ?
C22 C23 1.530(4) . ?
C22 C24 1.534(4) . ?
C25 C27 1.532(4) . ?
C25 C26 1.535(4) . ?
C28 C29 1.526(4) . ?
C28 C30 1.532(4) . ?
C31 C33 1.513(4) . ?
C31 C32 1.529(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Np1 N4 111.45(7) . . ?
N3 Np1 N2 110.80(7) . . ?
N4 Np1 N2 109.87(7) . . ?
N3 Np1 N1 72.05(6) . . ?
N4 Np1 N1 71.78(6) . . ?
N2 Np1 N1 71.56(6) . . ?
N3 Np1 Cl1 101.78(5) . . ?
N4 Np1 Cl1 110.86(5) . . ?
N2 Np1 Cl1 111.88(5) . . ?
N1 Np1 Cl1 173.80(4) . . ?
N3 Np1 C4 27.11(6) . . ?
N4 Np1 C4 87.59(7) . . ?
N2 Np1 C4 109.67(7) . . ?
N1 Np1 C4 49.87(6) . . ?
Cl1 Np1 C4 124.10(5) . . ?
N2 Si1 C10 111.06(10) . . ?
N2 Si1 C13 106.80(11) . . ?
C10 Si1 C13 112.28(12) . . ?
N2 Si1 C7 112.85(10) . . ?
C10 Si1 C7 105.62(12) . . ?
C13 Si1 C7 108.29(11) . . ?
N3 Si2 C16 108.29(10) . . ?
N3 Si2 C22 111.43(11) . . ?
C16 Si2 C22 107.20(12) . . ?
N3 Si2 C19 109.26(10) . . ?
C16 Si2 C19 113.04(12) . . ?
C22 Si2 C19 107.64(12) . . ?
N4 Si3 C25 110.68(11) . . ?
N4 Si3 C31 107.83(11) . . ?
C25 Si3 C31 107.47(12) . . ?
N4 Si3 C28 110.91(11) . . ?
C25 Si3 C28 107.19(13) . . ?
C31 Si3 C28 112.73(13) . . ?
C1 N1 C5 112.20(18) . . ?
C1 N1 C3 112.05(18) . . ?
C5 N1 C3 110.02(18) . . ?
C1 N1 Np1 107.94(13) . . ?
C5 N1 Np1 107.91(13) . . ?
C3 N1 Np1 106.46(13) . . ?
C2 N2 Si1 116.07(15) . . ?
C2 N2 Np1 112.54(14) . . ?
Si1 N2 Np1 131.34(10) . . ?
C4 N3 Si2 115.46(15) . . ?
C4 N3 Np1 110.57(14) . . ?
Si2 N3 Np1 133.96(10) . . ?
C6 N4 Si3 115.27(15) . . ?
C6 N4 Np1 113.98(14) . . ?
Si3 N4 Np1 130.38(10) . . ?
N1 C1 C2 109.39(19) . . ?
N2 C2 C1 109.70(19) . . ?
N1 C3 C4 107.83(19) . . ?
N3 C4 C3 108.61(19) . . ?
N3 C4 Np1 42.32(10) . . ?
C3 C4 Np1 87.00(13) . . ?
N1 C5 C6 109.63(19) . . ?
N4 C6 C5 110.50(19) . . ?
C8 C7 C9 109.4(2) . . ?
C8 C7 Si1 112.42(18) . . ?
C9 C7 Si1 115.15(18) . . ?
C11 C10 C12 110.5(2) . . ?
C11 C10 Si1 115.23(18) . . ?
C12 C10 Si1 112.52(18) . . ?
C15 C13 C14 108.8(2) . . ?
C15 C13 Si1 114.08(18) . . ?
C14 C13 Si1 114.20(18) . . ?
C17 C16 C18 109.5(2) . . ?
C17 C16 Si2 116.29(17) . . ?
C18 C16 Si2 112.25(19) . . ?
C21 C19 C20 110.0(2) . . ?
C21 C19 Si2 112.89(18) . . ?
C20 C19 Si2 115.35(19) . . ?
C23 C22 C24 110.3(2) . . ?
C23 C22 Si2 112.51(18) . . ?
C24 C22 Si2 112.80(19) . . ?
C27 C25 C26 109.6(2) . . ?
C27 C25 Si3 113.68(18) . . ?
C26 C25 Si3 112.41(19) . . ?
C29 C28 C30 109.3(3) . . ?
C29 C28 Si3 114.4(2) . . ?
C30 C28 Si3 114.11(19) . . ?
C33 C31 C32 109.8(3) . . ?
C33 C31 Si3 114.8(2) . . ?
C32 C31 Si3 114.86(19) . . ?

_diffrn_measured_fraction_theta_max 0.926
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.975
_refine_diff_density_min         -0.494
_refine_diff_density_rms         0.098
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_decay_%        0

