# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_qq
_database_code_depnum_ccdc_archive 'CCDC 1447724'
_audit_update_record             
;
2016-06-05 deposited with the CCDC.
2016-06-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C144 H162 Au24 Pd S18, 2(C7 H8)'
_chemical_formula_sum            'C158 H178 Au24 Pd S18'
_chemical_formula_weight         7487.67

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   16.1244(15)
_cell_length_b                   17.6398(17)
_cell_length_c                   17.7651(19)
_cell_angle_alpha                65.152(2)
_cell_angle_beta                 64.342(2)
_cell_angle_gamma                81.391(4)
_cell_volume                     4129.8(7)
_cell_formula_units_Z            1
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    2808
_cell_measurement_theta_min      2.27
_cell_measurement_theta_max      25.05

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.011
_exptl_crystal_F_000             3356
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.120
_exptl_absorpt_coefficient_mu    21.596
_shelx_estimated_absorpt_T_min   0.099
_shelx_estimated_absorpt_T_max   0.181
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1
_exptl_absorpt_correction_T_max  0.18
_exptl_absorpt_process_details   'SADABS; Bruker, 2008'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Smart Apex Duo'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            32450
_diffrn_reflns_av_unetI/netI     0.0673
_diffrn_reflns_av_R_equivalents  0.0457
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.273
_diffrn_reflns_theta_max         27.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             18037
_reflns_number_gt                12898
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2008)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2008)'
_computing_structure_solution    'SHELXTL (Bruker, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SHELXTL (Bruker, 2008)'
_computing_publication_material  'SHELXTL (Bruker, 2008)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.03P)²+1.22P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         18037
_refine_ls_number_parameters     908
_refine_ls_number_restraints     7
_refine_ls_R_factor_all          0.0727
_refine_ls_R_factor_gt           0.0394
_refine_ls_wR_factor_ref         0.0810
_refine_ls_wR_factor_gt          0.0724
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.06310(3) 0.62907(2) 0.38533(3) 0.02981(9) Uani 1 1 d . . . . .
Au2 Au -0.00698(3) 0.79997(2) 0.37035(3) 0.02999(9) Uani 1 1 d . . . . .
Au3 Au 0.07761(3) 0.72780(2) 0.19385(3) 0.03116(10) Uani 1 1 d . . . . .
Au4 Au 0.07939(3) 0.53335(2) 0.31450(3) 0.02888(9) Uani 1 1 d . . . . .
Au5 Au 0.29748(3) 0.64071(2) 0.40659(3) 0.03025(10) Uani 1 1 d . . . . .
Au6 Au 0.18857(3) 0.49857(2) 0.41560(3) 0.03056(10) Uani 1 1 d . . . . .
Au7 Au 0.23595(3) 0.41879(2) 0.27120(3) 0.03099(10) Uani 1 1 d . . . . .
Au8 Au 0.02297(3) 0.40164(2) 0.26981(3) 0.03129(10) Uani 1 1 d . . . . .
Au9 Au -0.11148(3) 0.45705(2) 0.43839(3) 0.02933(9) Uani 1 1 d . . . . .
Au10 Au -0.27739(3) 0.56996(2) 0.44480(3) 0.03083(10) Uani 1 1 d . . . . .
Au11 Au 0.10449(3) 0.64840(2) 0.38330(3) 0.02871(9) Uani 1 1 d . . . . .
Au12 Au 0.04664(3) 0.37106(2) 0.44236(3) 0.02930(9) Uani 1 1 d . . . . .
C1 C -0.0321(7) 0.9012(6) 0.1826(8) 0.041(3) Uani 1 1 d . . . . .
H1A H -0.0093 0.9235 0.1155 0.049 Uiso 1 1 calc R U . . .
H1B H -0.0820 0.8590 0.2090 0.049 Uiso 1 1 calc R U . . .
C2 C -0.0704(7) 0.9690(7) 0.2121(9) 0.045(3) Uani 1 1 d . . . . .
H2A H -0.0208 1.0114 0.1860 0.054 Uiso 1 1 calc R U . . .
H2B H -0.0941 0.9468 0.2792 0.054 Uiso 1 1 calc R U . . .
C3 C -0.1485(7) 1.0114(6) 0.1835(8) 0.040(3) Uani 1 1 d . U . . .
C4 C -0.1271(8) 1.0758(7) 0.0976(9) 0.050(3) Uani 1 1 d . . . . .
H4 H -0.0649 1.0929 0.0565 0.060 Uiso 1 1 calc R U . . .
C5 C -0.1998(8) 1.1148(8) 0.0733(9) 0.055(3) Uani 1 1 d . . . . .
H5 H -0.1863 1.1589 0.0150 0.066 Uiso 1 1 calc R U . . .
C6 C -0.2890(9) 1.0906(8) 0.1318(11) 0.058(4) Uani 1 1 d . . . . .
H6 H -0.3373 1.1177 0.1145 0.069 Uiso 1 1 calc R U . . .
C7 C -0.3091(9) 1.0265(8) 0.2166(10) 0.060(4) Uani 1 1 d . . . . .
H7 H -0.3714 1.0093 0.2574 0.072 Uiso 1 1 calc R U . . .
C8 C -0.2384(8) 0.9870(7) 0.2424(9) 0.049(3) Uani 1 1 d . U . . .
H8 H -0.2526 0.9431 0.3009 0.058 Uiso 1 1 calc R U . . .
C9 C 0.2942(7) 0.7651(7) 0.2109(7) 0.036(3) Uani 1 1 d . . . . .
H9A H 0.3039 0.7113 0.2037 0.044 Uiso 1 1 calc R U . . .
H9B H 0.2595 0.8006 0.1750 0.044 Uiso 1 1 calc R U . . .
C10 C 0.3906(7) 0.8093(7) 0.1710(8) 0.044(3) Uani 1 1 d . . . . .
H10A H 0.3826 0.8577 0.1877 0.053 Uiso 1 1 calc R U . . .
H10B H 0.4308 0.7698 0.1975 0.053 Uiso 1 1 calc R U . . .
C11 C 0.4337(8) 0.8376(7) 0.0724(8) 0.043(3) Uani 1 1 d . . . . .
C12 C 0.4269(8) 0.9181(7) 0.0189(8) 0.047(3) Uani 1 1 d . . . . .
H12 H 0.3939 0.9558 0.0462 0.056 Uiso 1 1 calc R U . . .
C13 C 0.4674(8) 0.9457(7) -0.0744(8) 0.046(3) Uani 1 1 d . . . . .
H13 H 0.4642 1.0026 -0.1114 0.055 Uiso 1 1 calc R U . . .
C14 C 0.5126(8) 0.8903(7) -0.1139(8) 0.051(3) Uani 1 1 d . . . . .
H14 H 0.5392 0.9089 -0.1783 0.061 Uiso 1 1 calc R U . . .
C15 C 0.5194(8) 0.8082(8) -0.0604(10) 0.055(4) Uani 1 1 d . . . . .
H15 H 0.5509 0.7702 -0.0879 0.066 Uiso 1 1 calc R U . . .
C16 C 0.4800(8) 0.7811(8) 0.0341(9) 0.057(4) Uani 1 1 d . . . . .
H16 H 0.4848 0.7248 0.0716 0.068 Uiso 1 1 calc R U . . .
C17 C 0.2029(8) 0.6164(7) 0.0750(9) 0.049(3) Uani 1 1 d . U . . .
H17A H 0.2127 0.5604 0.0732 0.059 Uiso 1 1 calc R U . . .
H17B H 0.2007 0.6556 0.0165 0.059 Uiso 1 1 calc R U . . .
C18 C 0.2890(8) 0.6410(7) 0.0763(10) 0.057(4) Uani 1 1 d . . . . .
H18A H 0.2974 0.5987 0.1305 0.069 Uiso 1 1 calc R U . . .
H18B H 0.2795 0.6952 0.0825 0.069 Uiso 1 1 calc R U . . .
C19 C 0.3780(9) 0.6488(7) -0.0098(9) 0.055(4) Uani 1 1 d . . . . .
C20 C 0.4545(9) 0.6038(8) -0.0037(10) 0.070(4) Uani 1 1 d . . . . .
H20 H 0.4524 0.5667 0.0543 0.084 Uiso 1 1 calc R U . . .
C21 C 0.5348(9) 0.6123(8) -0.0817(10) 0.056(4) Uani 1 1 d . . . . .
H21 H 0.5865 0.5801 -0.0773 0.067 Uiso 1 1 calc R U . . .
C22 C 0.5377(8) 0.6658(7) -0.1617(9) 0.048(3) Uani 1 1 d . . . . .
H22 H 0.5927 0.6715 -0.2144 0.057 Uiso 1 1 calc R U . . .
C23 C 0.4658(8) 0.7131(8) -0.1723(9) 0.058(4) Uani 1 1 d . . . . .
H23 H 0.4702 0.7508 -0.2310 0.070 Uiso 1 1 calc R U . . .
C24 C 0.3845(9) 0.7048(8) -0.0940(9) 0.058(4) Uani 1 1 d . . . . .
H24 H 0.3338 0.7383 -0.0995 0.069 Uiso 1 1 calc R U . . .
C25 C 0.4035(7) 0.5213(7) 0.2555(8) 0.045(3) Uani 1 1 d . U . . .
H25A H 0.4107 0.5323 0.1935 0.054 Uiso 1 1 calc R U . . .
H25B H 0.3855 0.5731 0.2666 0.054 Uiso 1 1 calc R U . . .
C26 C 0.4872(8) 0.4891(8) 0.2684(10) 0.061(4) Uani 1 1 d . . . . .
H26A H 0.5051 0.4369 0.2580 0.073 Uiso 1 1 calc R U . . .
H26B H 0.4810 0.4793 0.3297 0.073 Uiso 1 1 calc R U . . .
C27 C 0.5556(10) 0.5629(8) 0.1931(10) 0.063(4) Uani 1 1 d . . . . .
C28 C 0.5706(8) 0.6209(7) 0.2184(9) 0.051(3) Uani 1 1 d . . . . .
H28 H 0.5310 0.6216 0.2762 0.061 Uiso 1 1 calc R U . . .
C29 C 0.6433(7) 0.6782(7) 0.1602(9) 0.048(3) Uani 1 1 d . U . . .
H29 H 0.6527 0.7197 0.1768 0.058 Uiso 1 1 calc R U . . .
C30 C 0.7026(8) 0.6753(8) 0.0773(8) 0.047(3) Uani 1 1 d . U . . .
H30 H 0.7546 0.7130 0.0383 0.057 Uiso 1 1 calc R U . . .
C31 C 0.6861(8) 0.6178(7) 0.0516(9) 0.051(3) Uani 1 1 d . . . . .
H31 H 0.7242 0.6184 -0.0071 0.061 Uiso 1 1 calc R U . . .
C32 C 0.6150(8) 0.5597(8) 0.1104(9) 0.052(3) Uani 1 1 d . . . . .
H32 H 0.6064 0.5172 0.0945 0.062 Uiso 1 1 calc R U . . .
C33 C 0.1964(7) 0.2834(6) 0.2121(9) 0.041(3) Uani 1 1 d . . . . .
H33A H 0.2627 0.2769 0.1785 0.049 Uiso 1 1 calc R U . . .
H33B H 0.1817 0.2537 0.2779 0.049 Uiso 1 1 calc R U . . .
C34 C 0.1421(7) 0.2412(6) 0.1889(7) 0.036(3) Uani 1 1 d . . . . .
H34A H 0.0761 0.2514 0.2185 0.043 Uiso 1 1 calc R U . . .
H34B H 0.1606 0.2677 0.1222 0.043 Uiso 1 1 calc R U . . .
C35 C 0.1526(8) 0.1526(7) 0.2152(9) 0.045(3) Uani 1 1 d . . . . .
C36 C 0.2388(8) 0.1228(7) 0.1784(9) 0.049(3) Uani 1 1 d . . . . .
H36 H 0.2899 0.1611 0.1368 0.059 Uiso 1 1 calc R U . . .
C37 C 0.2517(8) 0.0376(7) 0.2014(9) 0.043(3) Uani 1 1 d . . . . .
H37 H 0.3117 0.0178 0.1782 0.051 Uiso 1 1 calc R U . . .
C38 C 0.1780(8) -0.0172(7) 0.2573(9) 0.047(3) Uani 1 1 d . . . . .
H38 H 0.1870 -0.0753 0.2720 0.056 Uiso 1 1 calc R U . . .
C39 C 0.0907(8) 0.0098(6) 0.2930(8) 0.042(3) Uani 1 1 d . . . . .
H39 H 0.0397 -0.0290 0.3312 0.051 Uiso 1 1 calc R U . . .
C40 C 0.0782(8) 0.0952(6) 0.2721(8) 0.038(3) Uani 1 1 d . . . . .
H40 H 0.0182 0.1144 0.2970 0.046 Uiso 1 1 calc R U . . .
C41 C -0.1504(8) 0.5124(7) 0.2525(8) 0.047(3) Uani 1 1 d . . . . .
H41A H -0.2155 0.5276 0.2769 0.056 Uiso 1 1 calc R U . . .
H41B H -0.1111 0.5580 0.2402 0.056 Uiso 1 1 calc R U . . .
C42 C -0.1253(9) 0.5019(8) 0.1580(9) 0.056(3) Uani 1 1 d . . . . .
H42A H -0.1450 0.5522 0.1176 0.068 Uiso 1 1 calc R U . . .
H42B H -0.0575 0.5001 0.1272 0.068 Uiso 1 1 calc R U . . .
C43 C -0.1660(10) 0.4295(9) 0.1682(10) 0.065(4) Uani 1 1 d . . . . .
C44 C -0.1163(9) 0.3683(8) 0.1400(9) 0.057(3) Uani 1 1 d . U . . .
H44 H -0.0510 0.3741 0.1115 0.069 Uiso 1 1 calc R U . . .
C45 C -0.1583(9) 0.2991(8) 0.1517(9) 0.057(3) Uani 1 1 d . U . . .
H45 H -0.1217 0.2598 0.1286 0.069 Uiso 1 1 calc R U . . .
C46 C -0.2549(9) 0.2858(9) 0.1976(11) 0.071(4) Uani 1 1 d . . . . .
H46 H -0.2842 0.2372 0.2081 0.085 Uiso 1 1 calc R U . . .
C47 C -0.3050(9) 0.3470(9) 0.2266(11) 0.066(4) Uani 1 1 d . . . . .
H47 H -0.3703 0.3413 0.2558 0.079 Uiso 1 1 calc R U . . .
C48 C -0.2607(10) 0.4168(8) 0.2135(10) 0.060(4) Uani 1 1 d . . . . .
H48 H -0.2966 0.4565 0.2363 0.072 Uiso 1 1 calc R U . . .
C49 C 0.0163(7) 0.1828(6) 0.4485(8) 0.040(3) Uani 1 1 d . . . . .
H49A H 0.0392 0.2077 0.3813 0.048 Uiso 1 1 calc R U . . .
H49B H 0.0305 0.1229 0.4666 0.048 Uiso 1 1 calc R U . . .
C50 C -0.0827(7) 0.1875(7) 0.4851(8) 0.046(3) Uani 1 1 d . . . . .
H50A H -0.0995 0.2466 0.4619 0.055 Uiso 1 1 calc R U . . .
H50B H -0.1078 0.1660 0.5523 0.055 Uiso 1 1 calc R U . . .
C51 C -0.1248(7) 0.1369(7) 0.4587(8) 0.043(3) Uani 1 1 d . . . . .
C52 C -0.1324(8) 0.0513(7) 0.5049(9) 0.050(3) Uani 1 1 d . . . . .
H52 H -0.1125 0.0252 0.5528 0.060 Uiso 1 1 calc R U . . .
C53 C -0.1698(7) 0.0035(7) 0.4807(9) 0.049(3) Uani 1 1 d . . . . .
H53 H -0.1757 -0.0556 0.5124 0.058 Uiso 1 1 calc R U . . .
C54 C -0.1978(8) 0.0412(7) 0.4120(9) 0.048(3) Uani 1 1 d . . . . .
H54 H -0.2229 0.0080 0.3959 0.058 Uiso 1 1 calc R U . . .
C55 C -0.1905(8) 0.1275(8) 0.3648(10) 0.053(3) Uani 1 1 d . . . . .
H55 H -0.2111 0.1529 0.3173 0.064 Uiso 1 1 calc R U . . .
C56 C -0.1530(7) 0.1763(7) 0.3872(8) 0.042(3) Uani 1 1 d . . . . .
H56 H -0.1465 0.2353 0.3548 0.051 Uiso 1 1 calc R U . . .
C57 C -0.3837(7) 0.4248(6) 0.4401(8) 0.037(3) Uani 1 1 d . . . . .
H57A H -0.3917 0.4747 0.3905 0.044 Uiso 1 1 calc R U . . .
H57B H -0.3240 0.4012 0.4130 0.044 Uiso 1 1 calc R U . . .
C58 C -0.4580(7) 0.3624(6) 0.4779(8) 0.037(3) Uani 1 1 d . . . . .
H58A H -0.4592 0.3526 0.4275 0.045 Uiso 1 1 calc R U . . .
H58B H -0.5177 0.3854 0.5062 0.045 Uiso 1 1 calc R U . . .
C59 C -0.4478(7) 0.2798(6) 0.5480(8) 0.037(3) Uani 1 1 d . . . . .
C60 C -0.3742(8) 0.2291(6) 0.5223(9) 0.043(3) Uani 1 1 d . . . . .
H60 H -0.3283 0.2490 0.4615 0.052 Uiso 1 1 calc R U . . .
C61 C -0.3675(8) 0.1511(7) 0.5837(9) 0.046(3) Uani 1 1 d . . . . .
H61 H -0.3167 0.1180 0.5655 0.055 Uiso 1 1 calc R U . . .
C62 C -0.4362(8) 0.1201(8) 0.6739(9) 0.048(3) Uani 1 1 d . . . . .
H62 H -0.4326 0.0658 0.7163 0.058 Uiso 1 1 calc R U . . .
C63 C -0.5098(8) 0.1706(7) 0.6999(9) 0.044(3) Uani 1 1 d . . . . .
H63 H -0.5557 0.1513 0.7607 0.053 Uiso 1 1 calc R U . . .
C64 C -0.5151(7) 0.2490(7) 0.6361(8) 0.040(3) Uani 1 1 d . . . . .
H64 H -0.5662 0.2822 0.6535 0.048 Uiso 1 1 calc R U . . .
C65 C -0.2378(7) 0.7496(6) 0.4397(8) 0.043(3) Uani 1 1 d . . . . .
H65A H -0.2274 0.7162 0.4954 0.052 Uiso 1 1 calc R U . . .
H65B H -0.2029 0.8036 0.4090 0.052 Uiso 1 1 calc R U . . .
C66 C -0.3392(7) 0.7661(7) 0.4667(9) 0.047(3) Uani 1 1 d . U . . .
H66A H -0.3493 0.7955 0.4102 0.056 Uiso 1 1 calc R U . . .
H66B H -0.3733 0.7114 0.4999 0.056 Uiso 1 1 calc R U . . .
C67 C -0.3811(7) 0.8149(7) 0.5231(9) 0.044(3) Uani 1 1 d . U . . .
C68 C -0.3380(8) 0.8248(7) 0.5709(8) 0.045(3) Uani 1 1 d . U . . .
H68 H -0.2815 0.7986 0.5687 0.054 Uiso 1 1 calc R U . . .
C69 C -0.3761(8) 0.8725(7) 0.6220(8) 0.046(3) Uani 1 1 d . . . . .
H69 H -0.3465 0.8783 0.6554 0.056 Uiso 1 1 calc R U . . .
C70 C -0.4570(8) 0.9115(7) 0.6243(9) 0.052(3) Uani 1 1 d . . . . .
H70 H -0.4824 0.9461 0.6574 0.062 Uiso 1 1 calc R U . . .
C71 C -0.5010(8) 0.9001(8) 0.5784(10) 0.056(4) Uani 1 1 d . . . . .
H71 H -0.5580 0.9256 0.5818 0.067 Uiso 1 1 calc R U . . .
C72 C -0.4645(8) 0.8531(7) 0.5279(9) 0.054(3) Uani 1 1 d . . . . .
H72 H -0.4956 0.8463 0.4962 0.065 Uiso 1 1 calc R U . . .
C1S C 0.7397(8) 0.9302(7) 0.0409(9) 0.052(3) Uani 1 1 d . . . . .
H1S1 H 0.7536 0.9713 -0.0214 0.077 Uiso 1 1 calc R U . . .
H1S2 H 0.7351 0.9590 0.0792 0.077 Uiso 1 1 calc R U . . .
H1S3 H 0.6811 0.9004 0.0653 0.077 Uiso 1 1 calc R U . . .
C2S C 0.8130(8) 0.8707(7) 0.0406(8) 0.045(3) Uani 1 1 d . . . . .
C3S C 0.8697(8) 0.8673(7) -0.0421(9) 0.051(3) Uani 1 1 d . . . . .
H3S H 0.8628 0.9050 -0.0958 0.061 Uiso 1 1 calc R U . . .
C4S C 0.9378(8) 0.8077(8) -0.0466(9) 0.055(3) Uani 1 1 d . . . . .
H4S H 0.9777 0.8055 -0.1037 0.066 Uiso 1 1 calc R U . . .
C5S C 0.9469(9) 0.7527(8) 0.0311(10) 0.060(4) Uani 1 1 d . . . . .
H5S H 0.9925 0.7119 0.0281 0.072 Uiso 1 1 calc R U . . .
C6S C 0.8892(9) 0.7567(8) 0.1145(9) 0.055(3) Uani 1 1 d . . . . .
H6S H 0.8967 0.7192 0.1680 0.066 Uiso 1 1 calc R U . . .
C7S C 0.8208(8) 0.8146(7) 0.1205(8) 0.045(3) Uani 1 1 d . . . . .
H7S H 0.7803 0.8161 0.1777 0.055 Uiso 1 1 calc R U . . .
Pd1 Pd 0.0000 0.5000 0.5000 0.0217(2) Uani 1 2 d S . P . .
S1 S 0.06095(17) 0.84987(15) 0.21420(19) 0.0311(6) Uani 1 1 d . . . . .
S2 S 0.22612(17) 0.74529(15) 0.32879(19) 0.0307(6) Uani 1 1 d . . . . .
S3 S 0.09227(18) 0.61263(15) 0.16158(19) 0.0339(6) Uani 1 1 d . U . . .
S4 S 0.31176(18) 0.42634(16) 0.3506(2) 0.0348(6) Uani 1 1 d . U . . .
S5 S 0.17728(17) 0.39335(15) 0.18727(19) 0.0320(6) Uani 1 1 d . . . . .
S6 S -0.13250(17) 0.41587(16) 0.33592(19) 0.0321(6) Uani 1 1 d . . . . .
S7 S 0.08440(17) 0.23102(15) 0.47744(19) 0.0308(6) Uani 1 1 d . . . . .
S8 S -0.37988(17) 0.45733(15) 0.52338(19) 0.0324(6) Uani 1 1 d . . . . .
S9 S -0.19376(17) 0.69476(15) 0.3647(2) 0.0331(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 S9 2.344(2) . ?
Au1 Pd1 2.7518(4) . ?
Au1 Au11 2.7570(6) . ?
Au1 Au4 2.7989(5) . ?
Au1 Au9 2.8936(6) . ?
Au1 Au3 3.0451(7) . ?
Au1 Au2 3.1482(6) . ?
Au1 Au12 3.1840(7) 2_566 ?
Au1 Au6 3.1852(6) 2_566 ?
Au1 Au10 3.3368(6) . ?
Au2 S7 2.282(3) 2_566 ?
Au2 S1 2.297(3) . ?
Au2 Au11 2.9723(5) . ?
Au2 Au12 3.2984(6) 2_566 ?
Au3 S3 2.287(3) . ?
Au3 S1 2.288(2) . ?
Au3 Au4 3.1946(6) . ?
Au3 Au11 3.2553(7) . ?
Au4 S3 2.405(3) . ?
Au4 Au12 2.7537(6) . ?
Au4 Pd1 2.7906(5) . ?
Au4 Au6 2.8618(6) . ?
Au4 Au11 2.9216(6) . ?
Au4 Au9 3.0020(6) . ?
Au4 Au7 3.0242(5) . ?
Au4 Au8 3.1087(6) . ?
Au5 S2 2.288(2) . ?
Au5 S8 2.289(2) 2_566 ?
Au5 Au9 3.1555(6) 2_566 ?
Au5 Au6 3.1834(6) . ?
Au5 Au11 3.2884(6) . ?
Au6 S4 2.323(2) . ?
Au6 Au11 2.7347(5) . ?
Au6 Au9 2.7404(6) 2_566 ?
Au6 Pd1 2.7485(5) . ?
Au6 Au10 3.1147(6) 2_566 ?
Au6 Au1 3.1852(7) 2_566 ?
Au6 Au7 3.1874(6) . ?
Au6 Au12 3.1974(6) . ?
Au7 S4 2.280(3) . ?
Au7 S5 2.287(3) . ?
Au7 Au12 3.1389(6) . ?
Au8 S6 2.288(2) . ?
Au8 S5 2.297(3) . ?
Au8 Au12 3.0650(7) . ?
Au8 Au9 3.2905(6) . ?
Au9 S6 2.382(3) . ?
Au9 Au6 2.7404(6) 2_566 ?
Au9 Au12 2.7774(5) . ?
Au9 Pd1 2.7950(4) . ?
Au9 Au11 2.9668(6) 2_566 ?
Au9 Au10 3.0770(5) . ?
Au9 Au5 3.1556(6) 2_566 ?
Au10 S8 2.298(3) . ?
Au10 S9 2.299(3) . ?
Au10 Au6 3.1147(6) 2_566 ?
Au11 S2 2.382(3) . ?
Au11 Pd1 2.7792(5) . ?
Au11 Au12 2.9103(6) 2_566 ?
Au11 Au9 2.9668(6) 2_566 ?
Au12 S7 2.334(2) . ?
Au12 Pd1 2.7506(4) . ?
Au12 Au11 2.9102(6) 2_566 ?
Au12 Au1 3.1841(7) 2_566 ?
Au12 Au2 3.2984(6) 2_566 ?
C1 C2 1.454(14) . ?
C1 S1 1.811(10) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.535(14) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C8 1.369(16) . ?
C3 C4 1.393(16) . ?
C4 C5 1.408(15) . ?
C4 H4 0.9500 . ?
C5 C6 1.359(17) . ?
C5 H5 0.9500 . ?
C6 C7 1.381(19) . ?
C6 H6 0.9500 . ?
C7 C8 1.394(16) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 C10 1.573(14) . ?
C9 S2 1.795(10) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C11 1.456(16) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C12 1.358(15) . ?
C11 C16 1.386(15) . ?
C12 C13 1.374(16) . ?
C12 H12 0.9500 . ?
C13 C14 1.378(15) . ?
C13 H13 0.9500 . ?
C14 C15 1.379(16) . ?
C14 H14 0.9500 . ?
C15 C16 1.394(18) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 C18 1.527(16) . ?
C17 S3 1.768(11) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C19 1.548(17) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C24 1.370(18) . ?
C19 C20 1.384(16) . ?
C20 C21 1.396(17) . ?
C20 H20 0.9500 . ?
C21 C22 1.319(17) . ?
C21 H21 0.9500 . ?
C22 C23 1.358(15) . ?
C22 H22 0.9500 . ?
C23 C24 1.409(17) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.459(15) . ?
C25 S4 2.011(12) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 C27 1.546(18) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.364(17) . ?
C27 C32 1.384(17) . ?
C28 C29 1.375(16) . ?
C28 H28 0.9500 . ?
C29 C30 1.384(16) . ?
C29 H29 0.9500 . ?
C30 C31 1.371(16) . ?
C30 H30 0.9500 . ?
C31 C32 1.369(16) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C33 C34 1.501(13) . ?
C33 S5 1.809(10) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 C35 1.436(14) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.385(14) . ?
C35 C40 1.394(16) . ?
C36 C37 1.389(14) . ?
C36 H36 0.9500 . ?
C37 C38 1.359(16) . ?
C37 H37 0.9500 . ?
C38 C39 1.375(14) . ?
C38 H38 0.9500 . ?
C39 C40 1.397(14) . ?
C39 H39 0.9500 . ?
C40 H40 0.9500 . ?
C41 C42 1.633(17) . ?
C41 S6 1.811(11) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C42 C43 1.431(17) . ?
C42 H42A 0.9900 . ?
C42 H42B 0.9900 . ?
C43 C44 1.381(17) . ?
C43 C48 1.385(18) . ?
C44 C45 1.380(16) . ?
C44 H44 0.9500 . ?
C45 C46 1.412(18) . ?
C45 H45 0.9500 . ?
C46 C47 1.389(17) . ?
C46 H46 0.9500 . ?
C47 C48 1.399(17) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C50 1.444(14) . ?
C49 S7 1.824(10) . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
C50 C51 1.513(16) . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C51 C52 1.376(15) . ?
C51 C56 1.401(16) . ?
C52 C53 1.394(16) . ?
C52 H52 0.9500 . ?
C53 C54 1.357(17) . ?
C53 H53 0.9500 . ?
C54 C55 1.389(16) . ?
C54 H54 0.9500 . ?
C55 C56 1.385(15) . ?
C55 H55 0.9500 . ?
C56 H56 0.9500 . ?
C57 C58 1.474(13) . ?
C57 S8 1.824(11) . ?
C57 H57A 0.9900 . ?
C57 H57B 0.9900 . ?
C58 C59 1.511(14) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 C64 1.384(16) . ?
C59 C60 1.406(13) . ?
C60 C61 1.375(15) . ?
C60 H60 0.9500 . ?
C61 C62 1.415(16) . ?
C61 H61 0.9500 . ?
C62 C63 1.404(14) . ?
C62 H62 0.9500 . ?
C63 C64 1.392(15) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C65 C66 1.511(14) . ?
C65 S9 1.808(11) . ?
C65 H65A 0.9900 . ?
C65 H65B 0.9900 . ?
C66 C67 1.472(15) . ?
C66 H66A 0.9900 . ?
C66 H66B 0.9900 . ?
C67 C68 1.381(16) . ?
C67 C72 1.395(14) . ?
C68 C69 1.384(15) . ?
C68 H68 0.9500 . ?
C69 C70 1.372(15) . ?
C69 H69 0.9500 . ?
C70 C71 1.375(17) . ?
C70 H70 0.9500 . ?
C71 C72 1.365(15) . ?
C71 H71 0.9500 . ?
C72 H72 0.9500 . ?
C1S C2S 1.458(15) . ?
C1S H1S1 0.9800 . ?
C1S H1S2 0.9800 . ?
C1S H1S3 0.9800 . ?
C2S C3S 1.376(16) . ?
C2S C7S 1.396(16) . ?
C3S C4S 1.402(15) . ?
C3S H3S 0.9500 . ?
C4S C5S 1.369(18) . ?
C4S H4S 0.9500 . ?
C5S C6S 1.393(18) . ?
C5S H5S 0.9500 . ?
C6S C7S 1.387(16) . ?
C6S H6S 0.9500 . ?
C7S H7S 0.9500 . ?
Pd1 Au6 2.7485(5) 2_566 ?
Pd1 Au12 2.7506(4) 2_566 ?
Pd1 Au1 2.7518(4) 2_566 ?
Pd1 Au11 2.7793(5) 2_566 ?
Pd1 Au4 2.7906(5) 2_566 ?
Pd1 Au9 2.7949(4) 2_566 ?
S7 Au2 2.282(3) 2_566 ?
S8 Au5 2.289(2) 2_566 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S9 Au1 Pd1 145.40(7) . . ?
S9 Au1 Au11 146.49(6) . . ?
Pd1 Au1 Au11 60.598(12) . . ?
S9 Au1 Au4 139.31(7) . . ?
Pd1 Au1 Au4 60.358(13) . . ?
Au11 Au1 Au4 63.447(14) . . ?
S9 Au1 Au9 100.24(6) . . ?
Pd1 Au1 Au9 59.288(11) . . ?
Au11 Au1 Au9 113.241(16) . . ?
Au4 Au1 Au9 63.628(15) . . ?
S9 Au1 Au3 96.87(7) . . ?
Pd1 Au1 Au3 117.325(15) . . ?
Au11 Au1 Au3 68.049(16) . . ?
Au4 Au1 Au3 66.118(15) . . ?
Au9 Au1 Au3 119.899(17) . . ?
S9 Au1 Au2 86.92(6) . . ?
Pd1 Au1 Au2 108.986(16) . . ?
Au11 Au1 Au2 60.007(13) . . ?
Au4 Au1 Au2 117.227(18) . . ?
Au9 Au1 Au2 166.962(19) . . ?
Au3 Au1 Au2 69.421(15) . . ?
S9 Au1 Au12 113.52(7) . 2_566 ?
Pd1 Au1 Au12 54.627(11) . 2_566 ?
Au11 Au1 Au12 58.132(13) . 2_566 ?
Au4 Au1 Au12 106.804(16) . 2_566 ?
Au9 Au1 Au12 104.232(16) . 2_566 ?
Au3 Au1 Au12 120.266(18) . 2_566 ?
Au2 Au1 Au12 62.782(13) . 2_566 ?
S9 Au1 Au6 90.91(7) . 2_566 ?
Pd1 Au1 Au6 54.566(11) . 2_566 ?
Au11 Au1 Au6 107.674(17) . 2_566 ?
Au4 Au1 Au6 104.668(16) . 2_566 ?
Au9 Au1 Au6 53.329(13) . 2_566 ?
Au3 Au1 Au6 170.745(15) . 2_566 ?
Au2 Au1 Au6 116.199(17) . 2_566 ?
Au12 Au1 Au6 60.265(15) 2_566 2_566 ?
S9 Au1 Au10 43.51(6) . . ?
Pd1 Au1 Au10 105.517(15) . . ?
Au11 Au1 Au10 164.662(19) . . ?
Au4 Au1 Au10 117.117(17) . . ?
Au9 Au1 Au10 58.676(12) . . ?
Au3 Au1 Au10 126.986(17) . . ?
Au2 Au1 Au10 124.730(14) . . ?
Au12 Au1 Au10 109.360(16) 2_566 . ?
Au6 Au1 Au10 56.997(13) 2_566 . ?
S7 Au2 S1 171.55(8) 2_566 . ?
S7 Au2 Au11 97.78(6) 2_566 . ?
S1 Au2 Au11 90.61(6) . . ?
S7 Au2 Au1 94.43(6) 2_566 . ?
S1 Au2 Au1 91.35(6) . . ?
Au11 Au2 Au1 53.453(13) . . ?
S7 Au2 Au12 45.02(6) 2_566 2_566 ?
S1 Au2 Au12 143.26(6) . 2_566 ?
Au11 Au2 Au12 55.008(13) . 2_566 ?
Au1 Au2 Au12 59.141(14) . 2_566 ?
S3 Au3 S1 174.76(10) . . ?
S3 Au3 Au1 89.12(7) . . ?
S1 Au3 Au1 94.19(7) . . ?
S3 Au3 Au4 48.66(7) . . ?
S1 Au3 Au4 136.45(7) . . ?
Au1 Au3 Au4 53.238(12) . . ?
S3 Au3 Au11 101.32(7) . . ?
S1 Au3 Au11 83.92(7) . . ?
Au1 Au3 Au11 51.770(14) . . ?
Au4 Au3 Au11 53.859(12) . . ?
S3 Au4 Au12 139.76(6) . . ?
S3 Au4 Pd1 151.84(6) . . ?
Au12 Au4 Pd1 59.483(13) . . ?
S3 Au4 Au1 92.85(6) . . ?
Au12 Au4 Au1 107.837(19) . . ?
Pd1 Au4 Au1 58.984(12) . . ?
S3 Au4 Au6 138.76(7) . . ?
Au12 Au4 Au6 69.383(15) . . ?
Pd1 Au4 Au6 58.173(13) . . ?
Au1 Au4 Au6 104.770(18) . . ?
S3 Au4 Au11 108.37(6) . . ?
Au12 Au4 Au11 111.86(2) . . ?
Pd1 Au4 Au11 58.173(12) . . ?
Au1 Au4 Au11 57.578(14) . . ?
Au6 Au4 Au11 56.428(13) . . ?
S3 Au4 Au9 110.59(7) . . ?
Au12 Au4 Au9 57.511(14) . . ?
Pd1 Au4 Au9 57.560(11) . . ?
Au1 Au4 Au9 59.723(14) . . ?
Au6 Au4 Au9 110.513(19) . . ?
Au11 Au4 Au9 105.618(17) . . ?
S3 Au4 Au7 97.35(6) . . ?
Au12 Au4 Au7 65.617(14) . . ?
Pd1 Au4 Au7 110.767(14) . . ?
Au1 Au4 Au7 169.428(19) . . ?
Au6 Au4 Au7 65.507(14) . . ?
Au11 Au4 Au7 115.959(17) . . ?
Au9 Au4 Au7 118.438(17) . . ?
S3 Au4 Au8 77.33(6) . . ?
Au12 Au4 Au8 62.699(16) . . ?
Pd1 Au4 Au8 113.352(16) . . ?
Au1 Au4 Au8 115.611(18) . . ?
Au6 Au4 Au8 124.132(16) . . ?
Au11 Au4 Au8 170.656(19) . . ?
Au9 Au4 Au8 65.134(14) . . ?
Au7 Au4 Au8 69.665(14) . . ?
S3 Au4 Au3 45.55(6) . . ?
Au12 Au4 Au3 168.412(18) . . ?
Pd1 Au4 Au3 111.535(14) . . ?
Au1 Au4 Au3 60.644(14) . . ?
Au6 Au4 Au3 113.276(17) . . ?
Au11 Au4 Au3 64.132(15) . . ?
Au9 Au4 Au3 112.090(15) . . ?
Au7 Au4 Au3 125.954(18) . . ?
Au8 Au4 Au3 119.542(18) . . ?
S2 Au5 S8 175.28(10) . 2_566 ?
S2 Au5 Au9 94.04(7) . 2_566 ?
S8 Au5 Au9 90.61(7) 2_566 2_566 ?
S2 Au5 Au6 92.58(7) . . ?
S8 Au5 Au6 90.97(7) 2_566 . ?
Au9 Au5 Au6 51.226(13) 2_566 . ?
S2 Au5 Au11 46.41(7) . . ?
S8 Au5 Au11 138.00(7) 2_566 . ?
Au9 Au5 Au11 54.779(14) 2_566 . ?
Au6 Au5 Au11 49.961(11) . . ?
S4 Au6 Au11 144.08(7) . . ?
S4 Au6 Au9 140.47(7) . 2_566 ?
Au11 Au6 Au9 65.622(15) . 2_566 ?
S4 Au6 Pd1 144.86(7) . . ?
Au11 Au6 Pd1 60.909(12) . . ?
Au9 Au6 Pd1 61.221(11) 2_566 . ?
S4 Au6 Au4 104.69(7) . . ?
Au11 Au6 Au4 62.890(14) . . ?
Au9 Au6 Au4 114.431(17) 2_566 . ?
Pd1 Au6 Au4 59.616(13) . . ?
S4 Au6 Au10 77.53(7) . 2_566 ?
Au11 Au6 Au10 121.998(17) . 2_566 ?
Au9 Au6 Au10 63.027(15) 2_566 2_566 ?
Pd1 Au6 Au10 111.816(17) . 2_566 ?
Au4 Au6 Au10 168.023(19) . 2_566 ?
S4 Au6 Au5 99.80(7) . . ?
Au11 Au6 Au5 67.015(15) . . ?
Au9 Au6 Au5 63.862(14) 2_566 . ?
Pd1 Au6 Au5 115.174(15) . . ?
Au4 Au6 Au5 122.856(16) . . ?
Au10 Au6 Au5 67.542(14) 2_566 . ?
S4 Au6 Au1 107.83(7) . 2_566 ?
Au11 Au6 Au1 107.945(17) . 2_566 ?
Au9 Au6 Au1 57.879(15) 2_566 2_566 ?
Pd1 Au6 Au1 54.662(10) . 2_566 ?
Au4 Au6 Au1 104.455(18) . 2_566 ?
Au10 Au6 Au1 63.952(15) 2_566 2_566 ?
Au5 Au6 Au1 115.772(18) . 2_566 ?
S4 Au6 Au7 45.62(7) . . ?
Au11 Au6 Au7 116.498(18) . . ?
Au9 Au6 Au7 166.496(19) 2_566 . ?
Pd1 Au6 Au7 107.278(15) . . ?
Au4 Au6 Au7 59.702(13) . . ?
Au10 Au6 Au7 119.843(15) 2_566 . ?
Au5 Au6 Au7 129.626(17) . . ?
Au1 Au6 Au7 110.332(17) 2_566 . ?
S4 Au6 Au12 90.54(7) . . ?
Au11 Au6 Au12 104.601(17) . . ?
Au9 Au6 Au12 107.634(17) 2_566 . ?
Pd1 Au6 Au12 54.479(11) . . ?
Au4 Au6 Au12 53.714(13) . . ?
Au10 Au6 Au12 114.918(16) 2_566 . ?
Au5 Au6 Au12 169.650(16) . . ?
Au1 Au6 Au12 59.852(14) 2_566 . ?
Au7 Au6 Au12 58.894(13) . . ?
S4 Au7 S5 169.99(8) . . ?
S4 Au7 Au4 100.92(6) . . ?
S5 Au7 Au4 89.00(6) . . ?
S4 Au7 Au12 92.84(7) . . ?
S5 Au7 Au12 92.11(7) . . ?
Au4 Au7 Au12 53.038(13) . . ?
S4 Au7 Au6 46.73(6) . . ?
S5 Au7 Au6 142.78(6) . . ?
Au4 Au7 Au6 54.792(12) . . ?
Au12 Au7 Au6 60.711(14) . . ?
S6 Au8 S5 173.15(10) . . ?
S6 Au8 Au12 92.87(7) . . ?
S5 Au8 Au12 93.84(7) . . ?
S6 Au8 Au4 96.22(6) . . ?
S5 Au8 Au4 86.77(6) . . ?
Au12 Au8 Au4 52.973(13) . . ?
S6 Au8 Au9 46.38(7) . . ?
S5 Au8 Au9 138.97(7) . . ?
Au12 Au8 Au9 51.678(13) . . ?
Au4 Au8 Au9 55.867(13) . . ?
S6 Au9 Au6 148.48(6) . 2_566 ?
S6 Au9 Au12 98.45(6) . . ?
Au6 Au9 Au12 108.356(18) 2_566 . ?
S6 Au9 Pd1 151.96(6) . . ?
Au6 Au9 Pd1 59.533(13) 2_566 . ?
Au12 Au9 Pd1 59.156(12) . . ?
S6 Au9 Au1 120.53(7) . . ?
Au6 Au9 Au1 68.791(15) 2_566 . ?
Au12 Au9 Au1 104.597(17) . . ?
Pd1 Au9 Au1 57.828(11) . . ?
S6 Au9 Au11 129.22(6) . 2_566 ?
Au6 Au9 Au11 57.099(15) 2_566 2_566 ?
Au12 Au9 Au11 60.774(14) . 2_566 ?
Pd1 Au9 Au11 57.587(12) . 2_566 ?
Au1 Au9 Au11 109.803(17) . 2_566 ?
S6 Au9 Au4 97.05(7) . . ?
Au6 Au9 Au4 111.285(17) 2_566 . ?
Au12 Au9 Au4 56.749(14) . . ?
Pd1 Au9 Au4 57.420(13) . . ?
Au1 Au9 Au4 56.649(13) . . ?
Au11 Au9 Au4 105.212(16) 2_566 . ?
S6 Au9 Au10 90.19(6) . . ?
Au6 Au9 Au10 64.440(13) 2_566 . ?
Au12 Au9 Au10 170.772(18) . . ?
Pd1 Au9 Au10 111.626(15) . . ?
Au1 Au9 Au10 67.874(14) . . ?
Au11 Au9 Au10 115.770(17) 2_566 . ?
Au4 Au9 Au10 119.162(17) . . ?
S6 Au9 Au5 89.18(7) . 2_566 ?
Au6 Au9 Au5 64.912(15) 2_566 2_566 ?
Au12 Au9 Au5 114.762(18) . 2_566 ?
Pd1 Au9 Au5 114.672(18) . 2_566 ?
Au1 Au9 Au5 126.125(16) . 2_566 ?
Au11 Au9 Au5 64.890(14) 2_566 2_566 ?
Au4 Au9 Au5 170.054(17) . 2_566 ?
Au10 Au9 Au5 68.348(14) . 2_566 ?
S6 Au9 Au8 44.06(6) . . ?
Au6 Au9 Au8 167.285(17) 2_566 . ?
Au12 Au9 Au8 59.970(14) . . ?
Pd1 Au9 Au8 108.019(15) . . ?
Au1 Au9 Au8 107.793(17) . . ?
Au11 Au9 Au8 115.329(16) 2_566 . ?
Au4 Au9 Au8 58.999(13) . . ?
Au10 Au9 Au8 126.535(17) . . ?
Au5 Au9 Au8 123.107(16) 2_566 . ?
S8 Au10 S9 171.29(8) . . ?
S8 Au10 Au9 92.44(6) . . ?
S9 Au10 Au9 96.21(6) . . ?
S8 Au10 Au6 92.55(7) . 2_566 ?
S9 Au10 Au6 93.57(7) . 2_566 ?
Au9 Au10 Au6 52.533(12) . 2_566 ?
S8 Au10 Au1 144.00(6) . . ?
S9 Au10 Au1 44.60(6) . . ?
Au9 Au10 Au1 53.449(13) . . ?
Au6 Au10 Au1 59.049(13) 2_566 . ?
S2 Au11 Au6 102.74(6) . . ?
S2 Au11 Au1 145.02(6) . . ?
Au6 Au11 Au1 109.478(18) . . ?
S2 Au11 Pd1 154.29(6) . . ?
Au6 Au11 Pd1 59.791(13) . . ?
Au1 Au11 Pd1 59.608(12) . . ?
S2 Au11 Au12 116.32(7) . 2_566 ?
Au6 Au11 Au12 104.813(18) . 2_566 ?
Au1 Au11 Au12 68.302(16) . 2_566 ?
Pd1 Au11 Au12 57.768(12) . 2_566 ?
S2 Au11 Au4 132.47(7) . . ?
Au6 Au11 Au4 60.682(14) . . ?
Au1 Au11 Au4 58.976(13) . . ?
Pd1 Au11 Au4 58.553(13) . . ?
Au12 Au11 Au4 111.089(18) 2_566 . ?
S2 Au11 Au9 97.06(7) . 2_566 ?
Au6 Au11 Au9 57.280(14) . 2_566 ?
Au1 Au11 Au9 111.486(18) . 2_566 ?
Pd1 Au11 Au9 58.100(11) . 2_566 ?
Au12 Au11 Au9 56.397(14) 2_566 2_566 ?
Au4 Au11 Au9 106.244(17) . 2_566 ?
S2 Au11 Au2 82.72(6) . . ?
Au6 Au11 Au2 172.72(2) . . ?
Au1 Au11 Au2 66.541(14) . . ?
Pd1 Au11 Au2 113.400(16) . . ?
Au12 Au11 Au2 68.201(14) 2_566 . ?
Au4 Au11 Au2 119.066(17) . . ?
Au9 Au11 Au2 117.684(17) 2_566 . ?
S2 Au11 Au3 94.15(7) . . ?
Au6 Au11 Au3 115.072(16) . . ?
Au1 Au11 Au3 60.182(14) . . ?
Pd1 Au11 Au3 110.094(15) . . ?
Au12 Au11 Au3 122.273(17) 2_566 . ?
Au4 Au11 Au3 62.008(14) . . ?
Au9 Au11 Au3 167.668(17) 2_566 . ?
Au2 Au11 Au3 68.834(13) . . ?
S2 Au11 Au5 44.09(6) . . ?
Au6 Au11 Au5 63.024(13) . . ?
Au1 Au11 Au5 170.754(18) . . ?
Pd1 Au11 Au5 111.146(14) . . ?
Au12 Au11 Au5 107.420(18) 2_566 . ?
Au4 Au11 Au5 117.457(15) . . ?
Au9 Au11 Au5 60.331(13) 2_566 . ?
Au2 Au11 Au5 120.244(16) . . ?
Au3 Au11 Au5 127.034(17) . . ?
S7 Au12 Pd1 146.51(7) . . ?
S7 Au12 Au4 147.99(7) . . ?
Pd1 Au12 Au4 60.928(13) . . ?
S7 Au12 Au9 133.95(6) . . ?
Pd1 Au12 Au9 60.740(11) . . ?
Au4 Au12 Au9 65.740(15) . . ?
S7 Au12 Au11 98.31(7) . 2_566 ?
Pd1 Au12 Au11 58.727(12) . 2_566 ?
Au4 Au12 Au11 113.674(16) . 2_566 ?
Au9 Au12 Au11 62.831(15) . 2_566 ?
S7 Au12 Au8 97.01(7) . . ?
Pd1 Au12 Au8 115.916(14) . . ?
Au4 Au12 Au8 64.328(15) . . ?
Au9 Au12 Au8 68.352(14) . . ?
Au11 Au12 Au8 124.557(18) 2_566 . ?
S7 Au12 Au7 88.20(7) . . ?
Pd1 Au12 Au7 108.572(15) . . ?
Au4 Au12 Au7 61.345(14) . . ?
Au9 Au12 Au7 121.991(18) . . ?
Au11 Au12 Au7 163.812(18) 2_566 . ?
Au8 Au12 Au7 68.759(16) . . ?
S7 Au12 Au1 92.49(7) . 2_566 ?
Pd1 Au12 Au1 54.660(10) . 2_566 ?
Au4 Au12 Au1 107.130(17) . 2_566 ?
Au9 Au12 Au1 104.883(16) . 2_566 ?
Au11 Au12 Au1 53.567(14) 2_566 2_566 ?
Au8 Au12 Au1 170.503(16) . 2_566 ?
Au7 Au12 Au1 111.632(17) . 2_566 ?
S7 Au12 Au6 118.20(6) . . ?
Pd1 Au12 Au6 54.419(11) . . ?
Au4 Au12 Au6 56.902(14) . . ?
Au9 Au12 Au6 107.314(17) . . ?
Au11 Au12 Au6 103.632(17) 2_566 . ?
Au8 Au12 Au6 114.798(17) . . ?
Au7 Au12 Au6 60.395(14) . . ?
Au1 Au12 Au6 59.884(13) 2_566 . ?
S7 Au12 Au2 43.76(7) . 2_566 ?
Pd1 Au12 Au2 104.926(17) . 2_566 ?
Au4 Au12 Au2 164.980(18) . 2_566 ?
Au9 Au12 Au2 113.261(17) . 2_566 ?
Au11 Au12 Au2 56.789(13) 2_566 2_566 ?
Au8 Au12 Au2 130.178(17) . 2_566 ?
Au7 Au12 Au2 124.046(15) . 2_566 ?
Au1 Au12 Au2 58.076(14) 2_566 2_566 ?
Au6 Au12 Au2 111.723(16) . 2_566 ?
C2 C1 S1 114.5(8) . . ?
C2 C1 H1A 108.6 . . ?
S1 C1 H1A 108.6 . . ?
C2 C1 H1B 108.6 . . ?
S1 C1 H1B 108.6 . . ?
H1A C1 H1B 107.6 . . ?
C1 C2 C3 113.0(10) . . ?
C1 C2 H2A 109.0 . . ?
C3 C2 H2A 109.0 . . ?
C1 C2 H2B 109.0 . . ?
C3 C2 H2B 109.0 . . ?
H2A C2 H2B 107.8 . . ?
C8 C3 C4 120.4(10) . . ?
C8 C3 C2 120.3(10) . . ?
C4 C3 C2 119.3(11) . . ?
C3 C4 C5 118.4(12) . . ?
C3 C4 H4 120.8 . . ?
C5 C4 H4 120.8 . . ?
C6 C5 C4 121.1(12) . . ?
C6 C5 H5 119.4 . . ?
C4 C5 H5 119.4 . . ?
C5 C6 C7 119.7(12) . . ?
C5 C6 H6 120.1 . . ?
C7 C6 H6 120.1 . . ?
C6 C7 C8 120.2(13) . . ?
C6 C7 H7 119.9 . . ?
C8 C7 H7 119.9 . . ?
C3 C8 C7 120.0(12) . . ?
C3 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C10 C9 S2 113.7(7) . . ?
C10 C9 H9A 108.8 . . ?
S2 C9 H9A 108.8 . . ?
C10 C9 H9B 108.8 . . ?
S2 C9 H9B 108.8 . . ?
H9A C9 H9B 107.7 . . ?
C11 C10 C9 110.2(9) . . ?
C11 C10 H10A 109.6 . . ?
C9 C10 H10A 109.6 . . ?
C11 C10 H10B 109.6 . . ?
C9 C10 H10B 109.6 . . ?
H10A C10 H10B 108.1 . . ?
C12 C11 C16 120.7(12) . . ?
C12 C11 C10 120.0(11) . . ?
C16 C11 C10 119.3(11) . . ?
C11 C12 C13 120.7(11) . . ?
C11 C12 H12 119.7 . . ?
C13 C12 H12 119.7 . . ?
C12 C13 C14 119.7(11) . . ?
C12 C13 H13 120.2 . . ?
C14 C13 H13 120.2 . . ?
C13 C14 C15 120.3(12) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 H14 119.9 . . ?
C14 C15 C16 119.7(11) . . ?
C14 C15 H15 120.1 . . ?
C16 C15 H15 120.1 . . ?
C11 C16 C15 119.0(12) . . ?
C11 C16 H16 120.5 . . ?
C15 C16 H16 120.5 . . ?
C18 C17 S3 121.6(9) . . ?
C18 C17 H17A 106.9 . . ?
S3 C17 H17A 106.9 . . ?
C18 C17 H17B 106.9 . . ?
S3 C17 H17B 106.9 . . ?
H17A C17 H17B 106.7 . . ?
C17 C18 C19 113.8(11) . . ?
C17 C18 H18A 108.8 . . ?
C19 C18 H18A 108.8 . . ?
C17 C18 H18B 108.8 . . ?
C19 C18 H18B 108.8 . . ?
H18A C18 H18B 107.7 . . ?
C24 C19 C20 118.3(13) . . ?
C24 C19 C18 120.2(11) . . ?
C20 C19 C18 121.4(12) . . ?
C19 C20 C21 120.9(14) . . ?
C19 C20 H20 119.6 . . ?
C21 C20 H20 119.6 . . ?
C22 C21 C20 119.0(12) . . ?
C22 C21 H21 120.5 . . ?
C20 C21 H21 120.5 . . ?
C21 C22 C23 123.1(13) . . ?
C21 C22 H22 118.4 . . ?
C23 C22 H22 118.4 . . ?
C22 C23 C24 118.3(13) . . ?
C22 C23 H23 120.9 . . ?
C24 C23 H23 120.9 . . ?
C19 C24 C23 120.4(12) . . ?
C19 C24 H24 119.8 . . ?
C23 C24 H24 119.8 . . ?
C26 C25 S4 101.7(8) . . ?
C26 C25 H25A 111.4 . . ?
S4 C25 H25A 111.4 . . ?
C26 C25 H25B 111.4 . . ?
S4 C25 H25B 111.4 . . ?
H25A C25 H25B 109.3 . . ?
C25 C26 C27 99.8(10) . . ?
C25 C26 H26A 111.8 . . ?
C27 C26 H26A 111.8 . . ?
C25 C26 H26B 111.8 . . ?
C27 C26 H26B 111.8 . . ?
H26A C26 H26B 109.5 . . ?
C28 C27 C32 120.3(13) . . ?
C28 C27 C26 117.1(13) . . ?
C32 C27 C26 120.8(12) . . ?
C27 C28 C29 119.9(12) . . ?
C27 C28 H28 120.1 . . ?
C29 C28 H28 120.1 . . ?
C28 C29 C30 119.9(12) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C31 C30 C29 119.8(12) . . ?
C31 C30 H30 120.1 . . ?
C29 C30 H30 120.1 . . ?
C32 C31 C30 120.1(12) . . ?
C32 C31 H31 120.0 . . ?
C30 C31 H31 120.0 . . ?
C31 C32 C27 119.8(12) . . ?
C31 C32 H32 120.1 . . ?
C27 C32 H32 120.1 . . ?
C34 C33 S5 116.0(8) . . ?
C34 C33 H33A 108.3 . . ?
S5 C33 H33A 108.3 . . ?
C34 C33 H33B 108.3 . . ?
S5 C33 H33B 108.3 . . ?
H33A C33 H33B 107.4 . . ?
C35 C34 C33 115.4(9) . . ?
C35 C34 H34A 108.4 . . ?
C33 C34 H34A 108.4 . . ?
C35 C34 H34B 108.4 . . ?
C33 C34 H34B 108.4 . . ?
H34A C34 H34B 107.5 . . ?
C36 C35 C40 118.1(10) . . ?
C36 C35 C34 119.3(11) . . ?
C40 C35 C34 122.5(10) . . ?
C35 C36 C37 121.1(12) . . ?
C35 C36 H36 119.4 . . ?
C37 C36 H36 119.4 . . ?
C38 C37 C36 119.6(11) . . ?
C38 C37 H37 120.2 . . ?
C36 C37 H37 120.2 . . ?
C37 C38 C39 121.2(11) . . ?
C37 C38 H38 119.4 . . ?
C39 C38 H38 119.4 . . ?
C38 C39 C40 119.1(11) . . ?
C38 C39 H39 120.4 . . ?
C40 C39 H39 120.4 . . ?
C35 C40 C39 120.8(10) . . ?
C35 C40 H40 119.6 . . ?
C39 C40 H40 119.6 . . ?
C42 C41 S6 110.4(7) . . ?
C42 C41 H41A 109.6 . . ?
S6 C41 H41A 109.6 . . ?
C42 C41 H41B 109.6 . . ?
S6 C41 H41B 109.6 . . ?
H41A C41 H41B 108.1 . . ?
C43 C42 C41 115.4(11) . . ?
C43 C42 H42A 108.4 . . ?
C41 C42 H42A 108.4 . . ?
C43 C42 H42B 108.4 . . ?
C41 C42 H42B 108.4 . . ?
H42A C42 H42B 107.5 . . ?
C44 C43 C48 117.1(14) . . ?
C44 C43 C42 124.1(13) . . ?
C48 C43 C42 118.7(12) . . ?
C45 C44 C43 122.3(13) . . ?
C45 C44 H44 118.9 . . ?
C43 C44 H44 118.9 . . ?
C44 C45 C46 120.9(13) . . ?
C44 C45 H45 119.5 . . ?
C46 C45 H45 119.5 . . ?
C47 C46 C45 116.9(14) . . ?
C47 C46 H46 121.6 . . ?
C45 C46 H46 121.6 . . ?
C46 C47 C48 121.0(13) . . ?
C46 C47 H47 119.5 . . ?
C48 C47 H47 119.5 . . ?
C43 C48 C47 121.7(13) . . ?
C43 C48 H48 119.1 . . ?
C47 C48 H48 119.1 . . ?
C50 C49 S7 120.4(8) . . ?
C50 C49 H49A 107.2 . . ?
S7 C49 H49A 107.2 . . ?
C50 C49 H49B 107.2 . . ?
S7 C49 H49B 107.2 . . ?
H49A C49 H49B 106.9 . . ?
C49 C50 C51 111.0(9) . . ?
C49 C50 H50A 109.4 . . ?
C51 C50 H50A 109.4 . . ?
C49 C50 H50B 109.4 . . ?
C51 C50 H50B 109.4 . . ?
H50A C50 H50B 108.0 . . ?
C52 C51 C56 121.1(11) . . ?
C52 C51 C50 118.3(11) . . ?
C56 C51 C50 120.6(10) . . ?
C51 C52 C53 119.2(12) . . ?
C51 C52 H52 120.4 . . ?
C53 C52 H52 120.4 . . ?
C54 C53 C52 120.0(12) . . ?
C54 C53 H53 120.0 . . ?
C52 C53 H53 120.0 . . ?
C53 C54 C55 121.3(12) . . ?
C53 C54 H54 119.3 . . ?
C55 C54 H54 119.3 . . ?
C56 C55 C54 119.7(12) . . ?
C56 C55 H55 120.2 . . ?
C54 C55 H55 120.2 . . ?
C55 C56 C51 118.6(12) . . ?
C55 C56 H56 120.7 . . ?
C51 C56 H56 120.7 . . ?
C58 C57 S8 114.1(8) . . ?
C58 C57 H57A 108.7 . . ?
S8 C57 H57A 108.7 . . ?
C58 C57 H57B 108.7 . . ?
S8 C57 H57B 108.7 . . ?
H57A C57 H57B 107.6 . . ?
C57 C58 C59 113.7(9) . . ?
C57 C58 H58A 108.8 . . ?
C59 C58 H58A 108.8 . . ?
C57 C58 H58B 108.8 . . ?
C59 C58 H58B 108.8 . . ?
H58A C58 H58B 107.7 . . ?
C64 C59 C60 118.7(10) . . ?
C64 C59 C58 120.8(9) . . ?
C60 C59 C58 120.2(11) . . ?
C61 C60 C59 121.0(12) . . ?
C61 C60 H60 119.5 . . ?
C59 C60 H60 119.5 . . ?
C60 C61 C62 120.1(11) . . ?
C60 C61 H61 119.9 . . ?
C62 C61 H61 119.9 . . ?
C63 C62 C61 119.1(12) . . ?
C63 C62 H62 120.5 . . ?
C61 C62 H62 120.5 . . ?
C64 C63 C62 119.6(12) . . ?
C64 C63 H63 120.2 . . ?
C62 C63 H63 120.2 . . ?
C59 C64 C63 121.5(10) . . ?
C59 C64 H64 119.2 . . ?
C63 C64 H64 119.2 . . ?
C66 C65 S9 113.4(8) . . ?
C66 C65 H65A 108.9 . . ?
S9 C65 H65A 108.9 . . ?
C66 C65 H65B 108.9 . . ?
S9 C65 H65B 108.9 . . ?
H65A C65 H65B 107.7 . . ?
C67 C66 C65 117.9(10) . . ?
C67 C66 H66A 107.8 . . ?
C65 C66 H66A 107.8 . . ?
C67 C66 H66B 107.8 . . ?
C65 C66 H66B 107.8 . . ?
H66A C66 H66B 107.2 . . ?
C68 C67 C72 119.0(11) . . ?
C68 C67 C66 120.7(9) . . ?
C72 C67 C66 120.3(11) . . ?
C67 C68 C69 120.7(10) . . ?
C67 C68 H68 119.6 . . ?
C69 C68 H68 119.6 . . ?
C70 C69 C68 119.8(12) . . ?
C70 C69 H69 120.1 . . ?
C68 C69 H69 120.1 . . ?
C69 C70 C71 119.5(12) . . ?
C69 C70 H70 120.3 . . ?
C71 C70 H70 120.3 . . ?
C72 C71 C70 121.5(12) . . ?
C72 C71 H71 119.3 . . ?
C70 C71 H71 119.3 . . ?
C71 C72 C67 119.5(12) . . ?
C71 C72 H72 120.2 . . ?
C67 C72 H72 120.2 . . ?
C2S C1S H1S1 109.5 . . ?
C2S C1S H1S2 109.5 . . ?
H1S1 C1S H1S2 109.5 . . ?
C2S C1S H1S3 109.5 . . ?
H1S1 C1S H1S3 109.5 . . ?
H1S2 C1S H1S3 109.5 . . ?
C3S C2S C7S 121.0(11) . . ?
C3S C2S C1S 116.4(11) . . ?
C7S C2S C1S 122.3(11) . . ?
C2S C3S C4S 119.6(12) . . ?
C2S C3S H3S 120.2 . . ?
C4S C3S H3S 120.2 . . ?
C5S C4S C3S 120.0(13) . . ?
C5S C4S H4S 120.0 . . ?
C3S C4S H4S 120.0 . . ?
C4S C5S C6S 120.0(13) . . ?
C4S C5S H5S 120.0 . . ?
C6S C5S H5S 120.0 . . ?
C7S C6S C5S 120.9(12) . . ?
C7S C6S H6S 119.6 . . ?
C5S C6S H6S 119.6 . . ?
C6S C7S C2S 118.4(11) . . ?
C6S C7S H7S 120.8 . . ?
C2S C7S H7S 120.8 . . ?
Au6 Pd1 Au6 180.0 2_566 . ?
Au6 Pd1 Au12 108.898(12) 2_566 . ?
Au6 Pd1 Au12 71.102(12) . . ?
Au6 Pd1 Au12 71.101(12) 2_566 2_566 ?
Au6 Pd1 Au12 108.899(12) . 2_566 ?
Au12 Pd1 Au12 180.0 . 2_566 ?
Au6 Pd1 Au1 70.773(13) 2_566 . ?
Au6 Pd1 Au1 109.227(13) . . ?
Au12 Pd1 Au1 109.286(14) . . ?
Au12 Pd1 Au1 70.712(14) 2_566 . ?
Au6 Pd1 Au1 109.227(13) 2_566 2_566 ?
Au6 Pd1 Au1 70.772(13) . 2_566 ?
Au12 Pd1 Au1 70.715(14) . 2_566 ?
Au12 Pd1 Au1 109.287(14) 2_566 2_566 ?
Au1 Pd1 Au1 180.0 . 2_566 ?
Au6 Pd1 Au11 120.700(12) 2_566 . ?
Au6 Pd1 Au11 59.300(12) . . ?
Au12 Pd1 Au11 116.493(14) . . ?
Au12 Pd1 Au11 63.507(14) 2_566 . ?
Au1 Pd1 Au11 59.794(13) . . ?
Au1 Pd1 Au11 120.204(13) 2_566 . ?
Au6 Pd1 Au11 59.301(12) 2_566 2_566 ?
Au6 Pd1 Au11 120.699(12) . 2_566 ?
Au12 Pd1 Au11 63.505(14) . 2_566 ?
Au12 Pd1 Au11 116.495(14) 2_566 2_566 ?
Au1 Pd1 Au11 120.206(13) . 2_566 ?
Au1 Pd1 Au11 59.796(13) 2_566 2_566 ?
Au11 Pd1 Au11 180.0 . 2_566 ?
Au6 Pd1 Au4 117.789(12) 2_566 . ?
Au6 Pd1 Au4 62.211(12) . . ?
Au12 Pd1 Au4 59.590(12) . . ?
Au12 Pd1 Au4 120.409(12) 2_566 . ?
Au1 Pd1 Au4 60.658(12) . . ?
Au1 Pd1 Au4 119.343(12) 2_566 . ?
Au11 Pd1 Au4 63.274(12) . . ?
Au11 Pd1 Au4 116.724(12) 2_566 . ?
Au6 Pd1 Au4 62.212(12) 2_566 2_566 ?
Au6 Pd1 Au4 117.789(12) . 2_566 ?
Au12 Pd1 Au4 120.411(12) . 2_566 ?
Au12 Pd1 Au4 59.590(12) 2_566 2_566 ?
Au1 Pd1 Au4 119.342(12) . 2_566 ?
Au1 Pd1 Au4 60.657(12) 2_566 2_566 ?
Au11 Pd1 Au4 116.725(12) . 2_566 ?
Au11 Pd1 Au4 63.277(12) 2_566 2_566 ?
Au4 Pd1 Au4 180.0 . 2_566 ?
Au6 Pd1 Au9 120.755(13) 2_566 2_566 ?
Au6 Pd1 Au9 59.245(13) . 2_566 ?
Au12 Pd1 Au9 119.896(11) . 2_566 ?
Au12 Pd1 Au9 60.106(11) 2_566 2_566 ?
Au1 Pd1 Au9 117.116(13) . 2_566 ?
Au1 Pd1 Au9 62.883(13) 2_566 2_566 ?
Au11 Pd1 Au9 64.313(13) . 2_566 ?
Au11 Pd1 Au9 115.688(13) 2_566 2_566 ?
Au4 Pd1 Au9 114.980(13) . 2_566 ?
Au4 Pd1 Au9 65.019(13) 2_566 2_566 ?
Au6 Pd1 Au9 59.245(13) 2_566 . ?
Au6 Pd1 Au9 120.755(13) . . ?
Au12 Pd1 Au9 60.104(11) . . ?
Au12 Pd1 Au9 119.894(12) 2_566 . ?
Au1 Pd1 Au9 62.885(13) . . ?
Au1 Pd1 Au9 117.117(13) 2_566 . ?
Au11 Pd1 Au9 115.687(14) . . ?
Au11 Pd1 Au9 64.312(13) 2_566 . ?
Au4 Pd1 Au9 65.020(13) . . ?
Au4 Pd1 Au9 114.981(13) 2_566 . ?
Au9 Pd1 Au9 180.0 2_566 . ?
C1 S1 Au3 105.2(4) . . ?
C1 S1 Au2 103.0(4) . . ?
Au3 S1 Au2 100.59(10) . . ?
C9 S2 Au5 105.2(3) . . ?
C9 S2 Au11 107.3(4) . . ?
Au5 S2 Au11 89.50(9) . . ?
C17 S3 Au3 109.1(4) . . ?
C17 S3 Au4 115.1(4) . . ?
Au3 S3 Au4 85.79(9) . . ?
C25 S4 Au7 101.2(4) . . ?
C25 S4 Au6 100.7(3) . . ?
Au7 S4 Au6 87.65(9) . . ?
C33 S5 Au7 103.0(4) . . ?
C33 S5 Au8 105.7(4) . . ?
Au7 S5 Au8 99.71(10) . . ?
C41 S6 Au8 102.6(4) . . ?
C41 S6 Au9 104.7(4) . . ?
Au8 S6 Au9 89.56(9) . . ?
C49 S7 Au2 106.2(4) . 2_566 ?
C49 S7 Au12 108.0(3) . . ?
Au2 S7 Au12 91.22(9) 2_566 . ?
C57 S8 Au5 105.8(3) . 2_566 ?
C57 S8 Au10 107.5(4) . . ?
Au5 S8 Au10 99.51(10) 2_566 . ?
C65 S9 Au10 105.4(4) . . ?
C65 S9 Au1 105.1(3) . . ?
Au10 S9 Au1 91.89(8) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
S1 C1 C2 C3 179.6(8) . . . . ?
C1 C2 C3 C8 95.0(13) . . . . ?
C1 C2 C3 C4 -86.0(14) . . . . ?
C8 C3 C4 C5 0.1(18) . . . . ?
C2 C3 C4 C5 -178.9(10) . . . . ?
C3 C4 C5 C6 -0.1(19) . . . . ?
C4 C5 C6 C7 0(2) . . . . ?
C5 C6 C7 C8 0(2) . . . . ?
C4 C3 C8 C7 0.1(18) . . . . ?
C2 C3 C8 C7 179.1(11) . . . . ?
C6 C7 C8 C3 -0.3(19) . . . . ?
S2 C9 C10 C11 -169.0(8) . . . . ?
C9 C10 C11 C12 97.3(12) . . . . ?
C9 C10 C11 C16 -81.6(13) . . . . ?
C16 C11 C12 C13 -1.2(19) . . . . ?
C10 C11 C12 C13 179.9(11) . . . . ?
C11 C12 C13 C14 2.2(19) . . . . ?
C12 C13 C14 C15 -1.7(19) . . . . ?
C13 C14 C15 C16 0(2) . . . . ?
C12 C11 C16 C15 -0.2(19) . . . . ?
C10 C11 C16 C15 178.7(11) . . . . ?
C14 C15 C16 C11 1(2) . . . . ?
S3 C17 C18 C19 -174.5(8) . . . . ?
C17 C18 C19 C24 59.7(16) . . . . ?
C17 C18 C19 C20 -124.3(14) . . . . ?
C24 C19 C20 C21 -3(2) . . . . ?
C18 C19 C20 C21 -179.1(12) . . . . ?
C19 C20 C21 C22 2(2) . . . . ?
C20 C21 C22 C23 0(2) . . . . ?
C21 C22 C23 C24 0(2) . . . . ?
C20 C19 C24 C23 3(2) . . . . ?
C18 C19 C24 C23 179.0(11) . . . . ?
C22 C23 C24 C19 -2(2) . . . . ?
S4 C25 C26 C27 178.9(8) . . . . ?
C25 C26 C27 C28 95.3(14) . . . . ?
C25 C26 C27 C32 -100.2(15) . . . . ?
C32 C27 C28 C29 2(2) . . . . ?
C26 C27 C28 C29 167.0(11) . . . . ?
C27 C28 C29 C30 -2.1(19) . . . . ?
C28 C29 C30 C31 3.2(18) . . . . ?
C29 C30 C31 C32 -4.6(18) . . . . ?
C30 C31 C32 C27 4.8(19) . . . . ?
C28 C27 C32 C31 -4(2) . . . . ?
C26 C27 C32 C31 -167.8(12) . . . . ?
S5 C33 C34 C35 -175.5(9) . . . . ?
C33 C34 C35 C36 -61.6(15) . . . . ?
C33 C34 C35 C40 122.8(12) . . . . ?
C40 C35 C36 C37 -3.5(19) . . . . ?
C34 C35 C36 C37 -179.4(11) . . . . ?
C35 C36 C37 C38 3.4(19) . . . . ?
C36 C37 C38 C39 -1.1(19) . . . . ?
C37 C38 C39 C40 -0.9(19) . . . . ?
C36 C35 C40 C39 1.5(18) . . . . ?
C34 C35 C40 C39 177.2(11) . . . . ?
C38 C39 C40 C35 0.7(18) . . . . ?
S6 C41 C42 C43 49.3(14) . . . . ?
C41 C42 C43 C44 -120.9(15) . . . . ?
C41 C42 C43 C48 55.4(17) . . . . ?
C48 C43 C44 C45 3(2) . . . . ?
C42 C43 C44 C45 179.5(13) . . . . ?
C43 C44 C45 C46 -3(2) . . . . ?
C44 C45 C46 C47 2(2) . . . . ?
C45 C46 C47 C48 -2(2) . . . . ?
C44 C43 C48 C47 -3(2) . . . . ?
C42 C43 C48 C47 -179.4(14) . . . . ?
C46 C47 C48 C43 3(2) . . . . ?
S7 C49 C50 C51 -175.0(8) . . . . ?
C49 C50 C51 C52 77.3(14) . . . . ?
C49 C50 C51 C56 -101.0(12) . . . . ?
C56 C51 C52 C53 -0.7(17) . . . . ?
C50 C51 C52 C53 -179.1(10) . . . . ?
C51 C52 C53 C54 0.3(17) . . . . ?
C52 C53 C54 C55 -0.3(18) . . . . ?
C53 C54 C55 C56 0.7(18) . . . . ?
C54 C55 C56 C51 -1.1(17) . . . . ?
C52 C51 C56 C55 1.1(17) . . . . ?
C50 C51 C56 C55 179.5(10) . . . . ?
S8 C57 C58 C59 -64.2(11) . . . . ?
C57 C58 C59 C64 120.0(11) . . . . ?
C57 C58 C59 C60 -66.4(14) . . . . ?
C64 C59 C60 C61 -1.5(17) . . . . ?
C58 C59 C60 C61 -175.3(10) . . . . ?
C59 C60 C61 C62 1.2(17) . . . . ?
C60 C61 C62 C63 -1.2(17) . . . . ?
C61 C62 C63 C64 1.7(17) . . . . ?
C60 C59 C64 C63 2.0(17) . . . . ?
C58 C59 C64 C63 175.7(10) . . . . ?
C62 C63 C64 C59 -2.1(17) . . . . ?
S9 C65 C66 C67 -176.3(9) . . . . ?
C65 C66 C67 C68 -18.0(17) . . . . ?
C65 C66 C67 C72 161.0(12) . . . . ?
C72 C67 C68 C69 -0.7(19) . . . . ?
C66 C67 C68 C69 178.3(11) . . . . ?
C67 C68 C69 C70 -0.9(19) . . . . ?
C68 C69 C70 C71 2.4(19) . . . . ?
C69 C70 C71 C72 -2(2) . . . . ?
C70 C71 C72 C67 1(2) . . . . ?
C68 C67 C72 C71 1(2) . . . . ?
C66 C67 C72 C71 -178.1(12) . . . . ?
C7S C2S C3S C4S -1.3(18) . . . . ?
C1S C2S C3S C4S -175.8(11) . . . . ?
C2S C3S C4S C5S 0.8(19) . . . . ?
C3S C4S C5S C6S -1(2) . . . . ?
C4S C5S C6S C7S 1(2) . . . . ?
C5S C6S C7S C2S -1.9(18) . . . . ?
C3S C2S C7S C6S 1.9(18) . . . . ?
C1S C2S C7S C6S 176.1(11) . . . . ?
C2 C1 S1 Au3 164.9(8) . . . . ?
C2 C1 S1 Au2 60.0(9) . . . . ?
C10 C9 S2 Au5 -71.0(7) . . . . ?
C10 C9 S2 Au11 -165.3(6) . . . . ?
C18 C17 S3 Au3 43.5(10) . . . . ?
C18 C17 S3 Au4 -50.8(10) . . . . ?
C34 C33 S5 Au7 163.2(8) . . . . ?
C34 C33 S5 Au8 59.1(9) . . . . ?
C42 C41 S6 Au8 64.4(8) . . . . ?
C42 C41 S6 Au9 157.3(7) . . . . ?
C50 C49 S7 Au2 42.5(10) . . . 2_566 ?
C50 C49 S7 Au12 -54.3(10) . . . . ?
C58 C57 S8 Au5 84.3(7) . . . 2_566 ?
C58 C57 S8 Au10 -170.1(6) . . . . ?
C66 C65 S9 Au10 -60.0(9) . . . . ?
C66 C65 S9 Au1 -156.3(8) . . . . ?

_refine_diff_density_max         1.865
_refine_diff_density_min         -1.886
_refine_diff_density_rms         0.290



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_aa
_database_code_depnum_ccdc_archive 'CCDC 1447725'
_audit_update_record             
;
2016-06-05 deposited with the CCDC.
2016-06-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C144 H162 Au24 Pt S18, 2(C7 H8)'
_chemical_formula_sum            'C158 H178 Au24 Pt S18'
_chemical_formula_weight         7576.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   16.1900(18)
_cell_length_b                   17.7140(12)
_cell_length_c                   17.8666(11)
_cell_angle_alpha                65.106(2)
_cell_angle_beta                 64.289(2)
_cell_angle_gamma                81.343(2)
_cell_volume                     4184.5(6)
_cell_formula_units_Z            1
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    9471
_cell_measurement_theta_min      2.21
_cell_measurement_theta_max      28.00

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.007
_exptl_crystal_F_000             3388
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.210
_exptl_absorpt_coefficient_mu    22.041
_shelx_estimated_absorpt_T_min   0.073
_shelx_estimated_absorpt_T_max   0.090
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.07
_exptl_absorpt_correction_T_max  0.09
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Smart Apex Duo'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            41212
_diffrn_reflns_av_unetI/netI     0.0754
_diffrn_reflns_av_R_equivalents  0.0867
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.397
_diffrn_reflns_theta_max         27.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.966
_diffrn_measured_fraction_theta_full 0.978
_diffrn_reflns_Laue_measured_fraction_max 0.966
_diffrn_reflns_Laue_measured_fraction_full 0.978
_diffrn_reflns_point_group_measured_fraction_max 0.966
_diffrn_reflns_point_group_measured_fraction_full 0.978
_reflns_number_total             17659
_reflns_number_gt                14915
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2008)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2008)'
_computing_structure_solution    'SHELXTL (Bruker, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SHELXTL (Bruker, 2008)'
_computing_publication_material  'SHELXTL (Bruker, 2008)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0120P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17659
_refine_ls_number_parameters     896
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0339
_refine_ls_R_factor_gt           0.0298
_refine_ls_wR_factor_ref         0.0752
_refine_ls_wR_factor_gt          0.0748
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_restrained_S_all      1.082
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.68857(2) -0.00216(2) 0.41562(2) 0.02535(7) Uani 1 1 d . . . . .
Au2 Au 0.73593(2) -0.08139(2) 0.27210(2) 0.02437(7) Uani 1 1 d . . . . .
Au3 Au 0.52173(2) -0.09923(2) 0.27077(2) 0.02588(7) Uani 1 1 d . . . . .
Au4 Au 0.57959(2) 0.03409(2) 0.31501(2) 0.02253(6) Uani 1 1 d . . . . .
Au5 Au 0.57788(2) 0.22708(2) 0.19293(2) 0.02582(7) Uani 1 1 d . . . . .
Au6 Au 0.49286(2) 0.29971(2) 0.37059(2) 0.02316(6) Uani 1 1 d . . . . .
Au7 Au 0.45351(2) 0.12979(2) 0.55680(2) 0.02255(6) Uani 1 1 d . . . . .
Au8 Au 0.60940(2) 0.04225(2) 0.56332(2) 0.02281(6) Uani 1 1 d . . . . .
Au9 Au 0.77668(2) -0.07018(2) 0.55558(2) 0.02583(7) Uani 1 1 d . . . . .
Au10 Au 0.79754(2) 0.14127(2) 0.40579(2) 0.02375(6) Uani 1 1 d . . . . .
Au11 Au 0.60507(2) 0.14781(2) 0.38495(2) 0.02211(6) Uani 1 1 d . . . . .
Au12 Au 0.43669(2) 0.12923(2) 0.38553(2) 0.02492(6) Uani 1 1 d . . . . .
C1 C 0.9029(7) 0.0187(7) 0.2618(7) 0.039(2) Uani 1 1 d . . . . .
H1A H 0.9046 0.0356 0.2008 0.047 Uiso 1 1 calc R U . . .
H1B H 0.8872 0.0673 0.2785 0.047 Uiso 1 1 calc R U . . .
C2 C 0.9963(7) -0.0143(7) 0.2630(6) 0.046(3) Uani 1 1 d . . . . .
H2A H 0.9930 -0.0336 0.3250 0.055 Uiso 1 1 calc R U . . .
H2B H 1.0122 -0.0619 0.2447 0.055 Uiso 1 1 calc R U . . .
C3 C 1.0694(8) 0.0563(8) 0.1970(7) 0.050(3) Uani 1 1 d . . . . .
C4 C 1.0820(9) 0.1153(8) 0.2216(7) 0.059(3) Uani 1 1 d . . . . .
H4 H 1.0444 0.1136 0.2806 0.070 Uiso 1 1 calc R U . . .
C5 C 1.1482(8) 0.1769(7) 0.1621(7) 0.051(3) Uani 1 1 d . . . . .
H5 H 1.1604 0.2148 0.1813 0.061 Uiso 1 1 calc R U . . .
C6 C 1.1973(8) 0.1842(8) 0.0741(6) 0.050(3) Uani 1 1 d . . . . .
H6 H 1.2389 0.2305 0.0312 0.060 Uiso 1 1 calc R U . . .
C7 C 1.1862(8) 0.1236(7) 0.0475(6) 0.050(3) Uani 1 1 d . . . . .
H7 H 1.2244 0.1252 -0.0114 0.060 Uiso 1 1 calc R U . . .
C8 C 1.1185(9) 0.0611(8) 0.1087(7) 0.059(3) Uani 1 1 d . . . . .
H8 H 1.1058 0.0223 0.0908 0.071 Uiso 1 1 calc R U . . .
C9 C 0.7010(6) -0.2156(6) 0.2106(6) 0.033(2) Uani 1 1 d . . . . .
H9A H 0.7661 -0.2191 0.1716 0.040 Uiso 1 1 calc R U . . .
H9B H 0.6921 -0.2464 0.2745 0.040 Uiso 1 1 calc R U . . .
C10 C 0.6373(7) -0.2579(6) 0.1904(6) 0.036(2) Uani 1 1 d . . . . .
H10A H 0.5720 -0.2511 0.2262 0.043 Uiso 1 1 calc R U . . .
H10B H 0.6494 -0.2302 0.1254 0.043 Uiso 1 1 calc R U . . .
C11 C 0.6563(7) -0.3496(6) 0.2151(6) 0.036(2) Uani 1 1 d . . . . .
C12 C 0.7429(7) -0.3790(7) 0.1793(7) 0.043(2) Uani 1 1 d . . . . .
H12 H 0.7944 -0.3410 0.1415 0.052 Uiso 1 1 calc R U . . .
C13 C 0.7554(8) -0.4636(6) 0.1978(7) 0.040(2) Uani 1 1 d . . . . .
H13 H 0.8141 -0.4840 0.1718 0.049 Uiso 1 1 calc R U . . .
C14 C 0.6764(7) -0.5181(6) 0.2575(6) 0.037(2) Uani 1 1 d . . . . .
H14 H 0.6822 -0.5764 0.2737 0.045 Uiso 1 1 calc R U . . .
C15 C 0.5929(7) -0.4874(6) 0.2914(6) 0.036(2) Uani 1 1 d . . . . .
H15 H 0.5411 -0.5252 0.3298 0.044 Uiso 1 1 calc R U . . .
C16 C 0.5798(8) -0.4041(7) 0.2726(6) 0.044(2) Uani 1 1 d . . . . .
H16 H 0.5206 -0.3842 0.2980 0.053 Uiso 1 1 calc R U . . .
C17 C 0.7037(7) 0.1212(6) 0.0743(6) 0.041(2) Uani 1 1 d . . . . .
H17A H 0.7145 0.0679 0.0666 0.049 Uiso 1 1 calc R U . . .
H17B H 0.7009 0.1641 0.0179 0.049 Uiso 1 1 calc R U . . .
C18 C 0.7858(8) 0.1414(7) 0.0775(6) 0.044(2) Uani 1 1 d . . . . .
H18A H 0.7919 0.0991 0.1325 0.053 Uiso 1 1 calc R U . . .
H18B H 0.7793 0.1962 0.0815 0.053 Uiso 1 1 calc R U . . .
C19 C 0.8757(8) 0.1443(8) -0.0093(7) 0.050(3) Uani 1 1 d . . . . .
C20 C 0.8824(9) 0.2035(8) -0.0930(7) 0.053(3) Uani 1 1 d . . . . .
H20 H 0.8317 0.2370 -0.0976 0.063 Uiso 1 1 calc R U . . .
C21 C 0.9639(9) 0.2143(8) -0.1713(7) 0.057(3) Uani 1 1 d . . . . .
H21 H 0.9673 0.2534 -0.2288 0.068 Uiso 1 1 calc R U . . .
C22 C 1.0387(8) 0.1681(7) -0.1641(8) 0.050(3) Uani 1 1 d . . . . .
H22 H 1.0949 0.1762 -0.2159 0.060 Uiso 1 1 calc R U . . .
C23 C 1.0299(9) 0.1104(8) -0.0809(7) 0.059(3) Uani 1 1 d . . . . .
H23 H 1.0804 0.0770 -0.0758 0.070 Uiso 1 1 calc R U . . .
C24 C 0.9488(8) 0.0985(7) -0.0022(7) 0.051(3) Uani 1 1 d . . . . .
H24 H 0.9455 0.0589 0.0552 0.061 Uiso 1 1 calc R U . . .
C25 C 0.4646(7) 0.3973(6) 0.1857(6) 0.036(2) Uani 1 1 d . . . . .
H25A H 0.4847 0.4172 0.1194 0.044 Uiso 1 1 calc R U . . .
H25B H 0.4149 0.3543 0.2155 0.044 Uiso 1 1 calc R U . . .
C26 C 0.4263(7) 0.4686(6) 0.2128(6) 0.035(2) Uani 1 1 d . . . . .
H26A H 0.4767 0.5096 0.1873 0.042 Uiso 1 1 calc R U . . .
H26B H 0.4008 0.4478 0.2796 0.042 Uiso 1 1 calc R U . . .
C27 C 0.3526(7) 0.5116(7) 0.1818(6) 0.041(2) Uani 1 1 d . . . . .
C28 C 0.2598(7) 0.4867(7) 0.2434(7) 0.043(2) Uani 1 1 d . . . . .
H28 H 0.2455 0.4441 0.3023 0.051 Uiso 1 1 calc R U . . .
C29 C 0.1915(8) 0.5248(8) 0.2170(8) 0.050(3) Uani 1 1 d . . . . .
H29 H 0.1295 0.5071 0.2571 0.060 Uiso 1 1 calc R U . . .
C30 C 0.2111(9) 0.5881(8) 0.1335(9) 0.059(3) Uani 1 1 d . . . . .
H30 H 0.1623 0.6149 0.1172 0.070 Uiso 1 1 calc R U . . .
C31 C 0.3026(8) 0.6141(7) 0.0712(8) 0.048(3) Uani 1 1 d . . . . .
H31 H 0.3163 0.6571 0.0126 0.058 Uiso 1 1 calc R U . . .
C32 C 0.3721(8) 0.5752(7) 0.0979(7) 0.048(3) Uani 1 1 d . . . . .
H32 H 0.4341 0.5927 0.0576 0.057 Uiso 1 1 calc R U . . .
C33 C 0.4793(7) 0.3180(6) 0.5540(5) 0.035(2) Uani 1 1 d . . . . .
H33A H 0.4641 0.3775 0.5366 0.042 Uiso 1 1 calc R U . . .
H33B H 0.4568 0.2924 0.6208 0.042 Uiso 1 1 calc R U . . .
C34 C 0.5850(7) 0.3136(6) 0.5132(6) 0.036(2) Uani 1 1 d . . . . .
H34A H 0.6019 0.2547 0.5357 0.043 Uiso 1 1 calc R U . . .
H34B H 0.6086 0.3348 0.4464 0.043 Uiso 1 1 calc R U . . .
C35 C 0.6291(6) 0.3628(6) 0.5368(6) 0.0328(19) Uani 1 1 d . . . . .
C36 C 0.6545(7) 0.3251(7) 0.6092(6) 0.041(2) Uani 1 1 d . . . . .
H36 H 0.6492 0.2663 0.6409 0.049 Uiso 1 1 calc R U . . .
C37 C 0.6875(7) 0.3735(7) 0.6345(7) 0.044(2) Uani 1 1 d . . . . .
H37 H 0.7049 0.3482 0.6839 0.053 Uiso 1 1 calc R U . . .
C38 C 0.6953(7) 0.4614(8) 0.5866(8) 0.049(3) Uani 1 1 d . . . . .
H38 H 0.7181 0.4950 0.6038 0.059 Uiso 1 1 calc R U . . .
C39 C 0.6703(7) 0.4975(7) 0.5164(7) 0.046(3) Uani 1 1 d . . . . .
H39 H 0.6764 0.5563 0.4843 0.055 Uiso 1 1 calc R U . . .
C40 C 0.6358(7) 0.4497(7) 0.4908(7) 0.040(2) Uani 1 1 d . . . . .
H40 H 0.6169 0.4757 0.4425 0.048 Uiso 1 1 calc R U . . .
C41 C 0.7954(6) 0.2681(6) 0.2074(5) 0.0333(19) Uani 1 1 d . . . . .
H41A H 0.8056 0.2154 0.1984 0.040 Uiso 1 1 calc R U . . .
H41B H 0.7617 0.3049 0.1715 0.040 Uiso 1 1 calc R U . . .
C42 C 0.8871(7) 0.3095(7) 0.1741(6) 0.041(2) Uani 1 1 d . . . . .
H42A H 0.8779 0.3581 0.1903 0.049 Uiso 1 1 calc R U . . .
H42B H 0.9253 0.2698 0.2027 0.049 Uiso 1 1 calc R U . . .
C43 C 0.9340(7) 0.3372(7) 0.0732(7) 0.040(2) Uani 1 1 d . . . . .
C44 C 0.9293(7) 0.4190(6) 0.0174(6) 0.036(2) Uani 1 1 d . . . . .
H44 H 0.8971 0.4574 0.0436 0.043 Uiso 1 1 calc R U . . .
C45 C 0.9705(8) 0.4460(7) -0.0759(7) 0.045(3) Uani 1 1 d . . . . .
H45 H 0.9661 0.5024 -0.1127 0.054 Uiso 1 1 calc R U . . .
C46 C 1.0180(8) 0.3918(8) -0.1166(7) 0.050(3) Uani 1 1 d . . . . .
H46 H 1.0461 0.4102 -0.1807 0.060 Uiso 1 1 calc R U . . .
C47 C 1.0237(8) 0.3092(7) -0.0607(7) 0.045(2) Uani 1 1 d . . . . .
H47 H 1.0566 0.2710 -0.0869 0.053 Uiso 1 1 calc R U . . .
C48 C 0.9822(8) 0.2833(7) 0.0309(7) 0.053(3) Uani 1 1 d . . . . .
H48 H 0.9861 0.2266 0.0675 0.064 Uiso 1 1 calc R U . . .
C49 C 0.8802(7) 0.0746(6) 0.5601(6) 0.038(2) Uani 1 1 d . . . . .
H49A H 0.8221 0.1018 0.5832 0.046 Uiso 1 1 calc R U . . .
H49B H 0.8839 0.0249 0.6118 0.046 Uiso 1 1 calc R U . . .
C50 C 0.9620(6) 0.1357(6) 0.5197(6) 0.0334(19) Uani 1 1 d . . . . .
H50A H 1.0194 0.1117 0.4890 0.040 Uiso 1 1 calc R U . . .
H50B H 0.9674 0.1434 0.5691 0.040 Uiso 1 1 calc R U . . .
C51 C 0.9497(6) 0.2222(6) 0.4502(6) 0.0315(19) Uani 1 1 d . . . . .
C52 C 1.0158(7) 0.2510(6) 0.3607(6) 0.038(2) Uani 1 1 d . . . . .
H52 H 1.0655 0.2173 0.3422 0.045 Uiso 1 1 calc R U . . .
C53 C 1.0082(8) 0.3289(7) 0.2991(6) 0.045(3) Uani 1 1 d . . . . .
H53 H 1.0541 0.3487 0.2388 0.054 Uiso 1 1 calc R U . . .
C54 C 0.9349(7) 0.3794(6) 0.3233(6) 0.037(2) Uani 1 1 d . . . . .
H54 H 0.9300 0.4323 0.2800 0.044 Uiso 1 1 calc R U . . .
C55 C 0.8681(7) 0.3497(7) 0.4138(6) 0.040(2) Uani 1 1 d . . . . .
H55 H 0.8185 0.3835 0.4322 0.048 Uiso 1 1 calc R U . . .
C56 C 0.8745(7) 0.2711(7) 0.4762(7) 0.040(2) Uani 1 1 d . . . . .
H56 H 0.8281 0.2506 0.5363 0.048 Uiso 1 1 calc R U . . .
C57 C 0.6501(8) -0.0150(8) 0.7525(6) 0.051(3) Uani 1 1 d . . . . .
H57A H 0.6124 -0.0606 0.7631 0.061 Uiso 1 1 calc R U . . .
H57B H 0.7152 -0.0300 0.7299 0.061 Uiso 1 1 calc R U . . .
C58 C 0.6245(8) -0.0078(7) 0.8385(7) 0.050(3) Uani 1 1 d . . . . .
H58A H 0.6432 -0.0586 0.8788 0.060 Uiso 1 1 calc R U . . .
H58B H 0.5569 -0.0063 0.8677 0.060 Uiso 1 1 calc R U . . .
C59 C 0.6687(9) 0.0728(8) 0.8308(8) 0.054(3) Uani 1 1 d . . . . .
C60 C 0.7624(9) 0.0868(8) 0.7823(8) 0.055(3) Uani 1 1 d . . . . .
H60 H 0.7978 0.0469 0.7603 0.066 Uiso 1 1 calc R U . . .
C61 C 0.8070(10) 0.1593(9) 0.7646(10) 0.072(4) Uani 1 1 d . . . . .
H61 H 0.8714 0.1686 0.7305 0.087 Uiso 1 1 calc R U . . .
C62 C 0.7524(9) 0.2175(8) 0.7993(7) 0.053(3) Uani 1 1 d . . . . .
H62 H 0.7806 0.2666 0.7885 0.063 Uiso 1 1 calc R U . . .
C63 C 0.6614(8) 0.2039(8) 0.8473(8) 0.054(3) Uani 1 1 d . . . . .
H63 H 0.6261 0.2432 0.8705 0.065 Uiso 1 1 calc R U . . .
C64 C 0.6171(10) 0.1313(8) 0.8638(8) 0.055(3) Uani 1 1 d . . . . .
H64 H 0.5526 0.1228 0.8972 0.066 Uiso 1 1 calc R U . . .
C65 C 0.2604(7) 0.2535(6) 0.4382(6) 0.039(2) Uani 1 1 d . . . . .
H65A H 0.2722 0.2226 0.4932 0.046 Uiso 1 1 calc R U . . .
H65B H 0.2931 0.3085 0.4061 0.046 Uiso 1 1 calc R U . . .
C66 C 0.1608(7) 0.2659(6) 0.4656(6) 0.038(2) Uani 1 1 d . . . . .
H66A H 0.1286 0.2105 0.4995 0.045 Uiso 1 1 calc R U . . .
H66B H 0.1494 0.2941 0.4101 0.045 Uiso 1 1 calc R U . . .
C67 C 0.1191(7) 0.3155(7) 0.5228(7) 0.039(2) Uani 1 1 d . . . . .
C68 C 0.0342(8) 0.3506(7) 0.5290(7) 0.047(3) Uani 1 1 d . . . . .
H68 H 0.0040 0.3431 0.4972 0.056 Uiso 1 1 calc R U . . .
C69 C -0.0054(8) 0.3960(7) 0.5812(7) 0.049(3) Uani 1 1 d . . . . .
H69 H -0.0637 0.4188 0.5865 0.059 Uiso 1 1 calc R U . . .
C70 C 0.0386(8) 0.4087(7) 0.6257(7) 0.051(3) Uani 1 1 d . . . . .
H70 H 0.0118 0.4419 0.6599 0.061 Uiso 1 1 calc R U . . .
C71 C 0.1230(8) 0.3728(7) 0.6204(7) 0.047(3) Uani 1 1 d . . . . .
H71 H 0.1529 0.3805 0.6523 0.056 Uiso 1 1 calc R U . . .
C72 C 0.1634(8) 0.3256(7) 0.5685(7) 0.044(2) Uani 1 1 d . . . . .
H72 H 0.2206 0.3009 0.5649 0.052 Uiso 1 1 calc R U . . .
C1S C 0.2371(8) 0.4245(7) 0.0479(7) 0.052(3) Uani 1 1 d . . . . .
H1S1 H 0.1826 0.3948 0.0614 0.078 Uiso 1 1 calc R U . . .
H1S2 H 0.2512 0.4742 -0.0087 0.078 Uiso 1 1 calc R U . . .
H1S3 H 0.2252 0.4411 0.0974 0.078 Uiso 1 1 calc R U . . .
C2S C 0.3139(8) 0.3705(7) 0.0383(6) 0.044(2) Uani 1 1 d . . . . .
C3S C 0.3195(7) 0.3142(7) 0.1191(7) 0.044(3) Uani 1 1 d . . . . .
H3S H 0.2788 0.3170 0.1753 0.053 Uiso 1 1 calc R U . . .
C4S C 0.3864(8) 0.2533(8) 0.1156(7) 0.055(3) Uani 1 1 d . . . . .
H4S H 0.3931 0.2160 0.1692 0.066 Uiso 1 1 calc R U . . .
C5S C 0.4403(8) 0.2484(8) 0.0361(7) 0.051(3) Uani 1 1 d . . . . .
H5S H 0.4836 0.2057 0.0356 0.061 Uiso 1 1 calc R U . . .
C6S C 0.4367(9) 0.3023(8) -0.0461(7) 0.058(3) Uani 1 1 d . . . . .
H6S H 0.4761 0.2970 -0.1013 0.070 Uiso 1 1 calc R U . . .
C7S C 0.3721(7) 0.3644(7) -0.0432(6) 0.039(2) Uani 1 1 d . . . . .
H7S H 0.3680 0.4028 -0.0978 0.047 Uiso 1 1 calc R U . . .
Pt1 Pt 0.5000 0.0000 0.5000 0.02123(8) Uani 1 2 d S . P . .
S1 S 0.81408(15) -0.07282(14) 0.35016(13) 0.0273(4) Uani 1 1 d . . . . .
S2 S 0.67508(14) -0.10768(13) 0.18997(12) 0.0252(4) Uani 1 1 d . . . . .
S3 S 0.59301(15) 0.11137(13) 0.16171(13) 0.02582(7) Uani 1 1 d . . . . .
S4 S 0.56044(15) 0.34905(13) 0.21365(13) 0.02582(7) Uani 1 1 d . . . . .
S5 S 0.41505(15) 0.26910(13) 0.52317(13) 0.0262(4) Uani 1 1 d . . . . .
S6 S 0.72620(13) 0.24584(12) 0.32769(12) 0.0224(4) Uani 1 1 d . . . . .
S7 S 0.87961(15) 0.04244(13) 0.47572(13) 0.0266(4) Uani 1 1 d . . . . .
S8 S 0.63426(14) 0.08448(13) 0.66254(13) 0.0259(4) Uani 1 1 d . . . . .
S9 S 0.30780(14) 0.19485(13) 0.36270(13) 0.0260(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 S1 2.338(2) . ?
Au1 Au11 2.7426(5) . ?
Au1 Pt1 2.7595(4) . ?
Au1 Au8 2.7812(4) . ?
Au1 Au4 2.8629(4) . ?
Au1 Au9 3.1273(4) . ?
Au1 Au2 3.1833(4) . ?
Au1 Au12 3.1925(5) 2_656 ?
Au1 Au7 3.2077(5) 2_656 ?
Au1 Au10 3.2099(5) . ?
Au2 S2 2.3040(17) . ?
Au2 S1 2.3101(19) . ?
Au2 Au4 3.0425(5) . ?
Au2 Au7 3.1523(5) 2_656 ?
Au3 S2 2.287(2) . ?
Au3 S8 2.306(2) 2_656 ?
Au3 Au7 3.0899(4) 2_656 ?
Au3 Au4 3.1558(4) . ?
Au3 Au8 3.2751(4) 2_656 ?
Au4 S3 2.4166(19) . ?
Au4 Au7 2.7867(5) 2_656 ?
Au4 Pt1 2.7943(3) . ?
Au4 Au12 2.8045(5) . ?
Au4 Au11 2.9337(4) . ?
Au4 Au8 2.9860(5) 2_656 ?
Au4 Au5 3.1925(5) . ?
Au5 S3 2.295(2) . ?
Au5 S4 2.298(2) . ?
Au5 Au12 3.0688(5) . ?
Au5 Au11 3.3171(4) . ?
Au6 S5 2.3009(19) . ?
Au6 S4 2.3208(19) . ?
Au6 Au11 2.9929(5) . ?
Au6 Au12 3.1552(5) . ?
Au6 Au7 3.2928(5) . ?
Au7 S5 2.335(2) . ?
Au7 Pt1 2.7682(3) . ?
Au7 Au8 2.7772(5) . ?
Au7 Au4 2.7867(5) 2_656 ?
Au7 Au11 2.9024(5) . ?
Au7 Au3 3.0899(4) 2_656 ?
Au7 Au2 3.1523(5) 2_656 ?
Au7 Au12 3.1917(4) . ?
Au7 Au1 3.2077(5) 2_656 ?
Au8 S8 2.3853(17) . ?
Au8 Pt1 2.7978(3) . ?
Au8 Au12 2.8937(5) 2_656 ?
Au8 Au11 2.9658(4) . ?
Au8 Au4 2.9860(5) 2_656 ?
Au8 Au9 3.0989(5) . ?
Au8 Au10 3.2078(5) . ?
Au8 Au3 3.2751(4) 2_656 ?
Au9 S7 2.310(2) . ?
Au9 S9 2.311(2) 2_656 ?
Au9 Au12 3.3381(6) 2_656 ?
Au10 S7 2.300(2) . ?
Au10 S6 2.300(2) . ?
Au10 Au11 3.2749(5) . ?
Au11 S6 2.3868(18) . ?
Au11 Pt1 2.7839(3) . ?
Au11 Au12 2.7896(5) . ?
Au12 S9 2.341(2) . ?
Au12 Pt1 2.7649(3) . ?
Au12 Au8 2.8936(5) 2_656 ?
Au12 Au1 3.1925(5) 2_656 ?
Au12 Au9 3.3380(6) 2_656 ?
C1 C2 1.542(14) . ?
C1 S1 1.941(10) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.533(14) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C4 1.363(16) . ?
C3 C8 1.396(14) . ?
C4 C5 1.361(16) . ?
C4 H4 0.9500 . ?
C5 C6 1.376(14) . ?
C5 H5 0.9500 . ?
C6 C7 1.405(17) . ?
C6 H6 0.9500 . ?
C7 C8 1.389(15) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 C10 1.593(12) . ?
C9 S2 1.807(9) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C11 1.515(13) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C12 1.390(14) . ?
C11 C16 1.393(13) . ?
C12 C13 1.395(14) . ?
C12 H12 0.9500 . ?
C13 C14 1.424(14) . ?
C13 H13 0.9500 . ?
C14 C15 1.355(14) . ?
C14 H14 0.9500 . ?
C15 C16 1.374(14) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 C18 1.456(14) . ?
C17 S3 1.766(10) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C19 1.588(14) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C24 1.353(16) . ?
C19 C20 1.386(15) . ?
C20 C21 1.408(15) . ?
C20 H20 0.9500 . ?
C21 C22 1.379(17) . ?
C21 H21 0.9500 . ?
C22 C23 1.362(16) . ?
C22 H22 0.9500 . ?
C23 C24 1.406(14) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.494(13) . ?
C25 S4 1.818(9) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 C27 1.501(13) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C32 1.375(12) . ?
C27 C28 1.421(14) . ?
C28 C29 1.364(15) . ?
C28 H28 0.9500 . ?
C29 C30 1.368(17) . ?
C29 H29 0.9500 . ?
C30 C31 1.411(17) . ?
C30 H30 0.9500 . ?
C31 C32 1.386(14) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C33 C34 1.547(13) . ?
C33 S5 1.818(9) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 C35 1.484(12) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.393(13) . ?
C35 C40 1.402(14) . ?
C36 C37 1.378(14) . ?
C36 H36 0.9500 . ?
C37 C38 1.420(16) . ?
C37 H37 0.9500 . ?
C38 C39 1.354(17) . ?
C38 H38 0.9500 . ?
C39 C40 1.389(14) . ?
C39 H39 0.9500 . ?
C40 H40 0.9500 . ?
C41 C42 1.514(13) . ?
C41 S6 1.833(8) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C42 C43 1.498(11) . ?
C42 H42A 0.9900 . ?
C42 H42B 0.9900 . ?
C43 C44 1.385(14) . ?
C43 C48 1.401(13) . ?
C44 C45 1.382(12) . ?
C44 H44 0.9500 . ?
C45 C46 1.386(15) . ?
C45 H45 0.9500 . ?
C46 C47 1.397(16) . ?
C46 H46 0.9500 . ?
C47 C48 1.359(13) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C50 1.546(12) . ?
C49 S7 1.827(8) . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
C50 C51 1.565(13) . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C51 C52 1.398(12) . ?
C51 C56 1.408(13) . ?
C52 C53 1.385(15) . ?
C52 H52 0.9500 . ?
C53 C54 1.398(15) . ?
C53 H53 0.9500 . ?
C54 C55 1.414(13) . ?
C54 H54 0.9500 . ?
C55 C56 1.393(14) . ?
C55 H55 0.9500 . ?
C56 H56 0.9500 . ?
C57 C58 1.464(13) . ?
C57 S8 1.895(10) . ?
C57 H57A 0.9900 . ?
C57 H57B 0.9900 . ?
C58 C59 1.621(17) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 C60 1.380(17) . ?
C59 C64 1.394(16) . ?
C60 C61 1.416(17) . ?
C60 H60 0.9500 . ?
C61 C62 1.422(16) . ?
C61 H61 0.9500 . ?
C62 C63 1.342(16) . ?
C62 H62 0.9500 . ?
C63 C64 1.424(17) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C65 C66 1.480(13) . ?
C65 S9 1.879(9) . ?
C65 H65A 0.9900 . ?
C65 H65B 0.9900 . ?
C66 C67 1.500(12) . ?
C66 H66A 0.9900 . ?
C66 H66B 0.9900 . ?
C67 C72 1.373(14) . ?
C67 C68 1.400(15) . ?
C68 C69 1.372(13) . ?
C68 H68 0.9500 . ?
C69 C70 1.371(16) . ?
C69 H69 0.9500 . ?
C70 C71 1.400(16) . ?
C70 H70 0.9500 . ?
C71 C72 1.397(13) . ?
C71 H71 0.9500 . ?
C72 H72 0.9500 . ?
C1S C2S 1.445(16) . ?
C1S H1S1 0.9800 . ?
C1S H1S2 0.9800 . ?
C1S H1S3 0.9800 . ?
C2S C3S 1.399(13) . ?
C2S C7S 1.391(14) . ?
C3S C4S 1.410(17) . ?
C3S H3S 0.9500 . ?
C4S C5S 1.338(16) . ?
C4S H4S 0.9500 . ?
C5S C6S 1.396(14) . ?
C5S H5S 0.9500 . ?
C6S C7S 1.400(17) . ?
C6S H6S 0.9500 . ?
C7S H7S 0.9500 . ?
Pt1 Au1 2.7596(4) 2_656 ?
Pt1 Au12 2.7649(3) 2_656 ?
Pt1 Au7 2.7682(3) 2_656 ?
Pt1 Au11 2.7839(3) 2_656 ?
Pt1 Au4 2.7943(3) 2_656 ?
Pt1 Au8 2.7979(3) 2_656 ?
S8 Au3 2.306(2) 2_656 ?
S9 Au9 2.311(2) 2_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S1 Au1 Au11 143.88(6) . . ?
S1 Au1 Pt1 146.21(5) . . ?
Au11 Au1 Pt1 60.792(10) . . ?
S1 Au1 Au8 140.17(5) . . ?
Au11 Au1 Au8 64.944(11) . . ?
Pt1 Au1 Au8 60.656(9) . . ?
S1 Au1 Au4 105.74(5) . . ?
Au11 Au1 Au4 63.073(11) . . ?
Pt1 Au1 Au4 59.569(11) . . ?
Au8 Au1 Au4 113.794(15) . . ?
S1 Au1 Au9 77.35(5) . . ?
Au11 Au1 Au9 120.988(12) . . ?
Pt1 Au1 Au9 111.570(13) . . ?
Au8 Au1 Au9 62.946(11) . . ?
Au4 Au1 Au9 168.281(15) . . ?
S1 Au1 Au2 46.41(5) . . ?
Au11 Au1 Au2 117.194(13) . . ?
Pt1 Au1 Au2 107.525(11) . . ?
Au8 Au1 Au2 166.171(15) . . ?
Au4 Au1 Au2 60.148(11) . . ?
Au9 Au1 Au2 120.145(13) . . ?
S1 Au1 Au12 108.49(5) . 2_656 ?
Au11 Au1 Au12 107.600(14) . 2_656 ?
Pt1 Au1 Au12 54.776(8) . 2_656 ?
Au8 Au1 Au12 57.452(11) . 2_656 ?
Au4 Au1 Au12 104.742(14) . 2_656 ?
Au9 Au1 Au12 63.757(12) . 2_656 ?
Au2 Au1 Au12 110.556(13) . 2_656 ?
S1 Au1 Au7 91.71(5) . 2_656 ?
Au11 Au1 Au7 105.125(14) . 2_656 ?
Pt1 Au1 Au7 54.654(10) . 2_656 ?
Au8 Au1 Au7 107.090(13) . 2_656 ?
Au4 Au1 Au7 54.290(10) . 2_656 ?
Au9 Au1 Au7 114.835(13) . 2_656 ?
Au2 Au1 Au7 59.104(10) . 2_656 ?
Au12 Au1 Au7 59.824(10) 2_656 2_656 ?
S1 Au1 Au10 98.84(5) . . ?
Au11 Au1 Au10 66.217(12) . . ?
Pt1 Au1 Au10 114.799(12) . . ?
Au8 Au1 Au10 64.281(11) . . ?
Au4 Au1 Au10 122.087(14) . . ?
Au9 Au1 Au10 67.694(11) . . ?
Au2 Au1 Au10 129.519(13) . . ?
Au12 Au1 Au10 115.768(12) 2_656 . ?
Au7 Au1 Au10 169.448(14) 2_656 . ?
S2 Au2 S1 170.14(8) . . ?
S2 Au2 Au4 88.69(6) . . ?
S1 Au2 Au4 101.09(5) . . ?
S2 Au2 Au7 91.16(5) . 2_656 ?
S1 Au2 Au7 93.67(5) . 2_656 ?
Au4 Au2 Au7 53.431(11) . 2_656 ?
S2 Au2 Au1 142.17(6) . . ?
S1 Au2 Au1 47.15(5) . . ?
Au4 Au2 Au1 54.697(9) . . ?
Au7 Au2 Au1 60.834(10) 2_656 . ?
S2 Au3 S8 173.80(7) . 2_656 ?
S2 Au3 Au7 93.08(5) . 2_656 ?
S8 Au3 Au7 92.91(4) 2_656 2_656 ?
S2 Au3 Au4 86.25(5) . . ?
S8 Au3 Au4 96.14(5) 2_656 . ?
Au7 Au3 Au4 52.984(9) 2_656 . ?
S2 Au3 Au8 137.86(4) . 2_656 ?
S8 Au3 Au8 46.73(4) 2_656 2_656 ?
Au7 Au3 Au8 51.642(10) 2_656 2_656 ?
Au4 Au3 Au8 55.294(10) . 2_656 ?
S3 Au4 Au7 138.58(5) . 2_656 ?
S3 Au4 Pt1 152.71(5) . . ?
Au7 Au4 Pt1 59.471(9) 2_656 . ?
S3 Au4 Au12 93.53(5) . . ?
Au7 Au4 Au12 107.872(14) 2_656 . ?
Pt1 Au4 Au12 59.185(9) . . ?
S3 Au4 Au1 139.08(5) . . ?
Au7 Au4 Au1 69.177(11) 2_656 . ?
Pt1 Au4 Au1 58.375(10) . . ?
Au12 Au4 Au1 105.404(13) . . ?
S3 Au4 Au11 109.78(5) . . ?
Au7 Au4 Au11 111.642(13) 2_656 . ?
Pt1 Au4 Au11 58.098(8) . . ?
Au12 Au4 Au11 58.122(12) . . ?
Au1 Au4 Au11 56.459(10) . . ?
S3 Au4 Au8 110.20(5) . 2_656 ?
Au7 Au4 Au8 57.392(11) 2_656 2_656 ?
Pt1 Au4 Au8 57.785(8) . 2_656 ?
Au12 Au4 Au8 59.864(12) . 2_656 ?
Au1 Au4 Au8 110.683(14) . 2_656 ?
Au11 Au4 Au8 106.030(13) . 2_656 ?
S3 Au4 Au2 96.71(5) . . ?
Au7 Au4 Au2 65.300(12) 2_656 . ?
Pt1 Au4 Au2 110.568(11) . . ?
Au12 Au4 Au2 169.534(13) . . ?
Au1 Au4 Au2 65.155(12) . . ?
Au11 Au4 Au2 115.806(13) . . ?
Au8 Au4 Au2 117.886(14) 2_656 . ?
S3 Au4 Au3 76.63(5) . . ?
Au7 Au4 Au3 62.294(10) 2_656 . ?
Pt1 Au4 Au3 112.836(12) . . ?
Au12 Au4 Au3 115.113(14) . . ?
Au1 Au4 Au3 123.626(14) . . ?
Au11 Au4 Au3 170.229(14) . . ?
Au8 Au4 Au3 64.380(10) 2_656 . ?
Au2 Au4 Au3 69.640(12) . . ?
S3 Au4 Au5 45.75(5) . . ?
Au7 Au4 Au5 168.824(15) 2_656 . ?
Pt1 Au4 Au5 112.457(11) . . ?
Au12 Au4 Au5 61.152(11) . . ?
Au1 Au4 Au5 114.351(12) . . ?
Au11 Au4 Au5 65.408(11) . . ?
Au8 Au4 Au5 112.249(13) 2_656 . ?
Au2 Au4 Au5 125.869(13) . . ?
Au3 Au4 Au5 118.903(12) . . ?
S3 Au5 S4 175.25(7) . . ?
S3 Au5 Au12 89.42(5) . . ?
S4 Au5 Au12 93.45(5) . . ?
S3 Au5 Au4 48.97(5) . . ?
S4 Au5 Au4 135.61(5) . . ?
Au12 Au5 Au4 53.175(10) . . ?
S3 Au5 Au11 101.27(5) . . ?
S4 Au5 Au11 83.48(5) . . ?
Au12 Au5 Au11 51.625(11) . . ?
Au4 Au5 Au11 53.532(8) . . ?
S5 Au6 S4 171.55(7) . . ?
S5 Au6 Au11 97.56(5) . . ?
S4 Au6 Au11 90.87(5) . . ?
S5 Au6 Au12 94.66(5) . . ?
S4 Au6 Au12 90.81(5) . . ?
Au11 Au6 Au12 53.887(11) . . ?
S5 Au6 Au7 45.16(5) . . ?
S4 Au6 Au7 143.02(5) . . ?
Au11 Au6 Au7 54.748(10) . . ?
Au12 Au6 Au7 59.292(10) . . ?
S5 Au7 Pt1 147.18(5) . . ?
S5 Au7 Au8 134.70(5) . . ?
Pt1 Au7 Au8 60.601(9) . . ?
S5 Au7 Au4 147.68(5) . 2_656 ?
Pt1 Au7 Au4 60.400(10) . 2_656 ?
Au8 Au7 Au4 64.914(12) . 2_656 ?
S5 Au7 Au11 99.29(5) . . ?
Pt1 Au7 Au11 58.749(9) . . ?
Au8 Au7 Au11 62.912(12) . . ?
Au4 Au7 Au11 113.001(14) 2_656 . ?
S5 Au7 Au3 96.66(5) . 2_656 ?
Pt1 Au7 Au3 115.641(12) . 2_656 ?
Au8 Au7 Au3 67.622(10) . 2_656 ?
Au4 Au7 Au3 64.725(10) 2_656 2_656 ?
Au11 Au7 Au3 123.656(14) . 2_656 ?
S5 Au7 Au2 87.94(5) . 2_656 ?
Pt1 Au7 Au2 108.158(11) . 2_656 ?
Au8 Au7 Au2 121.012(14) . 2_656 ?
Au4 Au7 Au2 61.268(11) 2_656 2_656 ?
Au11 Au7 Au2 163.919(11) . 2_656 ?
Au3 Au7 Au2 69.102(12) 2_656 2_656 ?
S5 Au7 Au12 93.04(5) . . ?
Pt1 Au7 Au12 54.723(8) . . ?
Au8 Au7 Au12 105.280(12) . . ?
Au4 Au7 Au12 106.616(12) 2_656 . ?
Au11 Au7 Au12 54.232(11) . . ?
Au3 Au7 Au12 170.305(14) 2_656 . ?
Au2 Au7 Au12 111.388(12) 2_656 . ?
S5 Au7 Au1 118.16(5) . 2_656 ?
Pt1 Au7 Au1 54.403(9) . 2_656 ?
Au8 Au7 Au1 106.794(14) . 2_656 ?
Au4 Au7 Au1 56.531(10) 2_656 2_656 ?
Au11 Au7 Au1 103.971(12) . 2_656 ?
Au3 Au7 Au1 114.833(13) 2_656 2_656 ?
Au2 Au7 Au1 60.059(10) 2_656 2_656 ?
Au12 Au7 Au1 59.849(9) . 2_656 ?
S5 Au7 Au6 44.33(5) . . ?
Pt1 Au7 Au6 105.114(11) . . ?
Au8 Au7 Au6 114.166(13) . . ?
Au4 Au7 Au6 164.598(12) 2_656 . ?
Au11 Au7 Au6 57.362(11) . . ?
Au3 Au7 Au6 130.143(12) 2_656 . ?
Au2 Au7 Au6 124.179(14) 2_656 . ?
Au12 Au7 Au6 58.207(10) . . ?
Au1 Au7 Au6 111.797(11) 2_656 . ?
S8 Au8 Au7 99.50(5) . . ?
S8 Au8 Au1 146.73(5) . . ?
Au7 Au8 Au1 108.170(12) . . ?
S8 Au8 Pt1 153.98(5) . . ?
Au7 Au8 Pt1 59.539(9) . . ?
Au1 Au8 Pt1 59.288(10) . . ?
S8 Au8 Au12 121.58(5) . 2_656 ?
Au7 Au8 Au12 105.671(13) . 2_656 ?
Au1 Au8 Au12 68.433(11) . 2_656 ?
Pt1 Au8 Au12 58.099(8) . 2_656 ?
S8 Au8 Au11 128.38(5) . . ?
Au7 Au8 Au11 60.607(10) . . ?
Au1 Au8 Au11 56.898(11) . . ?
Pt1 Au8 Au11 57.677(8) . . ?
Au12 Au8 Au11 109.888(11) 2_656 . ?
S8 Au8 Au4 99.00(5) . 2_656 ?
Au7 Au8 Au4 57.696(12) . 2_656 ?
Au1 Au8 Au4 111.170(12) . 2_656 ?
Pt1 Au8 Au4 57.668(9) . 2_656 ?
Au12 Au8 Au4 56.952(10) 2_656 2_656 ?
Au11 Au8 Au4 105.718(13) . 2_656 ?
S8 Au8 Au9 89.47(5) . . ?
Au7 Au8 Au9 170.844(12) . . ?
Au1 Au8 Au9 63.993(11) . . ?
Pt1 Au8 Au9 111.336(12) . . ?
Au12 Au8 Au9 67.601(12) 2_656 . ?
Au11 Au8 Au9 114.883(13) . . ?
Au4 Au8 Au9 119.341(14) 2_656 . ?
S8 Au8 Au10 87.97(5) . . ?
Au7 Au8 Au10 113.769(14) . . ?
Au1 Au8 Au10 64.356(11) . . ?
Pt1 Au8 Au10 113.753(12) . . ?
Au12 Au8 Au10 125.350(13) 2_656 . ?
Au11 Au8 Au10 63.932(11) . . ?
Au4 Au8 Au10 169.640(13) 2_656 . ?
Au9 Au8 Au10 68.055(12) . . ?
S8 Au8 Au3 44.74(5) . 2_656 ?
Au7 Au8 Au3 60.739(10) . 2_656 ?
Au1 Au8 Au3 168.181(14) . 2_656 ?
Pt1 Au8 Au3 109.305(13) . 2_656 ?
Au12 Au8 Au3 109.218(13) 2_656 2_656 ?
Au11 Au8 Au3 115.585(14) . 2_656 ?
Au4 Au8 Au3 60.329(10) 2_656 2_656 ?
Au9 Au8 Au3 126.632(12) . 2_656 ?
Au10 Au8 Au3 122.435(12) . 2_656 ?
S7 Au9 S9 171.43(7) . 2_656 ?
S7 Au9 Au8 92.84(5) . . ?
S9 Au9 Au8 95.64(5) 2_656 . ?
S7 Au9 Au1 92.22(5) . . ?
S9 Au9 Au1 93.88(5) 2_656 . ?
Au8 Au9 Au1 53.061(10) . . ?
S7 Au9 Au12 143.96(5) . 2_656 ?
S9 Au9 Au12 44.51(5) 2_656 2_656 ?
Au8 Au9 Au12 53.271(11) . 2_656 ?
Au1 Au9 Au12 59.071(10) . 2_656 ?
S7 Au10 S6 175.50(7) . . ?
S7 Au10 Au8 90.26(6) . . ?
S6 Au10 Au8 94.23(5) . . ?
S7 Au10 Au1 90.31(5) . . ?
S6 Au10 Au1 92.75(4) . . ?
Au8 Au10 Au1 51.363(9) . . ?
S7 Au10 Au11 137.27(6) . . ?
S6 Au10 Au11 46.77(5) . . ?
Au8 Au10 Au11 54.439(10) . . ?
Au1 Au10 Au11 50.026(9) . . ?
S6 Au11 Au1 103.63(5) . . ?
S6 Au11 Pt1 155.97(5) . . ?
Au1 Au11 Pt1 59.905(11) . . ?
S6 Au11 Au12 143.76(5) . . ?
Au1 Au11 Au12 109.167(14) . . ?
Pt1 Au11 Au12 59.481(9) . . ?
S6 Au11 Au7 117.14(4) . . ?
Au1 Au11 Au7 105.744(13) . . ?
Pt1 Au11 Au7 58.217(9) . . ?
Au12 Au11 Au7 68.181(12) . . ?
S6 Au11 Au4 131.69(5) . . ?
Au1 Au11 Au4 60.467(11) . . ?
Pt1 Au11 Au4 58.442(9) . . ?
Au12 Au11 Au4 58.619(10) . . ?
Au7 Au11 Au4 111.154(13) . . ?
S6 Au11 Au8 98.84(4) . . ?
Au1 Au11 Au8 58.158(10) . . ?
Pt1 Au11 Au8 58.132(8) . . ?
Au12 Au11 Au8 111.240(13) . . ?
Au7 Au11 Au8 56.480(11) . . ?
Au4 Au11 Au8 106.539(13) . . ?
S6 Au11 Au6 82.49(5) . . ?
Au1 Au11 Au6 172.914(15) . . ?
Pt1 Au11 Au6 113.147(13) . . ?
Au12 Au11 Au6 66.029(12) . . ?
Au7 Au11 Au6 67.891(12) . . ?
Au4 Au11 Au6 118.089(13) . . ?
Au8 Au11 Au6 117.835(12) . . ?
S6 Au11 Au10 44.60(5) . . ?
Au1 Au11 Au10 63.756(11) . . ?
Pt1 Au11 Au10 112.145(12) . . ?
Au12 Au11 Au10 171.614(14) . . ?
Au7 Au11 Au10 108.513(12) . . ?
Au4 Au11 Au10 117.698(13) . . ?
Au8 Au11 Au10 61.629(10) . . ?
Au6 Au11 Au10 120.539(12) . . ?
S6 Au11 Au5 93.27(4) . . ?
Au1 Au11 Au5 114.000(12) . . ?
Pt1 Au11 Au5 109.160(10) . . ?
Au12 Au11 Au5 59.591(10) . . ?
Au7 Au11 Au5 121.694(14) . . ?
Au4 Au11 Au5 61.060(10) . . ?
Au8 Au11 Au5 166.859(12) . . ?
Au6 Au11 Au5 68.671(10) . . ?
Au10 Au11 Au5 126.535(12) . . ?
S9 Au12 Pt1 146.13(5) . . ?
S9 Au12 Au11 146.76(5) . . ?
Pt1 Au12 Au11 60.158(10) . . ?
S9 Au12 Au4 138.72(5) . . ?
Pt1 Au12 Au4 60.224(10) . . ?
Au11 Au12 Au4 63.259(12) . . ?
S9 Au12 Au8 100.63(5) . 2_656 ?
Pt1 Au12 Au8 59.216(9) . 2_656 ?
Au11 Au12 Au8 112.609(14) . 2_656 ?
Au4 Au12 Au8 63.183(12) . 2_656 ?
S9 Au12 Au5 96.13(5) . . ?
Pt1 Au12 Au5 117.188(14) . . ?
Au11 Au12 Au5 68.784(12) . . ?
Au4 Au12 Au5 65.673(12) . . ?
Au8 Au12 Au5 118.731(13) 2_656 . ?
S9 Au12 Au6 87.18(5) . . ?
Pt1 Au12 Au6 108.925(11) . . ?
Au11 Au12 Au6 60.084(11) . . ?
Au4 Au12 Au6 116.918(15) . . ?
Au8 Au12 Au6 167.144(13) 2_656 . ?
Au5 Au12 Au6 69.967(11) . . ?
S9 Au12 Au7 114.37(5) . . ?
Pt1 Au12 Au7 54.819(8) . . ?
Au11 Au12 Au7 57.587(10) . . ?
Au4 Au12 Au7 106.631(13) . . ?
Au8 Au12 Au7 104.769(12) 2_656 . ?
Au5 Au12 Au7 120.489(14) . . ?
Au6 Au12 Au7 62.501(9) . . ?
S9 Au12 Au1 91.64(5) . 2_656 ?
Pt1 Au12 Au1 54.620(10) . 2_656 ?
Au11 Au12 Au1 107.094(13) . 2_656 ?
Au4 Au12 Au1 104.863(14) . 2_656 ?
Au8 Au12 Au1 54.117(10) 2_656 2_656 ?
Au5 Au12 Au1 170.520(14) . 2_656 ?
Au6 Au12 Au1 115.993(12) . 2_656 ?
Au7 Au12 Au1 60.324(10) . 2_656 ?
S9 Au12 Au9 43.80(5) . 2_656 ?
Pt1 Au12 Au9 105.567(12) . 2_656 ?
Au11 Au12 Au9 164.251(14) . 2_656 ?
Au4 Au12 Au9 117.275(14) . 2_656 ?
Au8 Au12 Au9 59.128(10) 2_656 2_656 ?
Au5 Au12 Au9 126.605(12) . 2_656 ?
Au6 Au12 Au9 124.890(13) . 2_656 ?
Au7 Au12 Au9 109.656(12) . 2_656 ?
Au1 Au12 Au9 57.173(10) 2_656 2_656 ?
C2 C1 S1 105.8(7) . . ?
C2 C1 H1A 110.6 . . ?
S1 C1 H1A 110.6 . . ?
C2 C1 H1B 110.6 . . ?
S1 C1 H1B 110.6 . . ?
H1A C1 H1B 108.7 . . ?
C3 C2 C1 108.6(9) . . ?
C3 C2 H2A 110.0 . . ?
C1 C2 H2A 110.0 . . ?
C3 C2 H2B 110.0 . . ?
C1 C2 H2B 110.0 . . ?
H2A C2 H2B 108.3 . . ?
C4 C3 C8 121.1(11) . . ?
C4 C3 C2 121.4(9) . . ?
C8 C3 C2 117.3(10) . . ?
C5 C4 C3 120.3(10) . . ?
C5 C4 H4 119.9 . . ?
C3 C4 H4 119.9 . . ?
C4 C5 C6 120.2(12) . . ?
C4 C5 H5 119.9 . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C7 120.3(10) . . ?
C5 C6 H6 119.8 . . ?
C7 C6 H6 119.8 . . ?
C8 C7 C6 118.8(10) . . ?
C8 C7 H7 120.6 . . ?
C6 C7 H7 120.6 . . ?
C7 C8 C3 118.9(12) . . ?
C7 C8 H8 120.6 . . ?
C3 C8 H8 120.6 . . ?
C10 C9 S2 111.6(7) . . ?
C10 C9 H9A 109.3 . . ?
S2 C9 H9A 109.3 . . ?
C10 C9 H9B 109.3 . . ?
S2 C9 H9B 109.3 . . ?
H9A C9 H9B 108.0 . . ?
C11 C10 C9 109.9(8) . . ?
C11 C10 H10A 109.7 . . ?
C9 C10 H10A 109.7 . . ?
C11 C10 H10B 109.7 . . ?
C9 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
C12 C11 C16 120.9(10) . . ?
C12 C11 C10 123.2(9) . . ?
C16 C11 C10 115.7(9) . . ?
C11 C12 C13 121.0(10) . . ?
C11 C12 H12 119.5 . . ?
C13 C12 H12 119.5 . . ?
C12 C13 C14 117.0(10) . . ?
C12 C13 H13 121.5 . . ?
C14 C13 H13 121.5 . . ?
C15 C14 C13 120.5(9) . . ?
C15 C14 H14 119.7 . . ?
C13 C14 H14 119.7 . . ?
C14 C15 C16 122.8(9) . . ?
C14 C15 H15 118.6 . . ?
C16 C15 H15 118.6 . . ?
C15 C16 C11 117.7(10) . . ?
C15 C16 H16 121.1 . . ?
C11 C16 H16 121.1 . . ?
C18 C17 S3 122.9(7) . . ?
C18 C17 H17A 106.6 . . ?
S3 C17 H17A 106.6 . . ?
C18 C17 H17B 106.6 . . ?
S3 C17 H17B 106.6 . . ?
H17A C17 H17B 106.6 . . ?
C17 C18 C19 111.9(8) . . ?
C17 C18 H18A 109.2 . . ?
C19 C18 H18A 109.2 . . ?
C17 C18 H18B 109.2 . . ?
C19 C18 H18B 109.2 . . ?
H18A C18 H18B 107.9 . . ?
C24 C19 C20 119.9(11) . . ?
C24 C19 C18 121.8(10) . . ?
C20 C19 C18 117.8(11) . . ?
C19 C20 C21 120.4(12) . . ?
C19 C20 H20 119.8 . . ?
C21 C20 H20 119.8 . . ?
C22 C21 C20 119.8(11) . . ?
C22 C21 H21 120.1 . . ?
C20 C21 H21 120.1 . . ?
C23 C22 C21 118.3(11) . . ?
C23 C22 H22 120.8 . . ?
C21 C22 H22 120.8 . . ?
C22 C23 C24 122.5(13) . . ?
C22 C23 H23 118.7 . . ?
C24 C23 H23 118.7 . . ?
C19 C24 C23 119.0(11) . . ?
C19 C24 H24 120.5 . . ?
C23 C24 H24 120.5 . . ?
C26 C25 S4 114.9(7) . . ?
C26 C25 H25A 108.6 . . ?
S4 C25 H25A 108.6 . . ?
C26 C25 H25B 108.6 . . ?
S4 C25 H25B 108.6 . . ?
H25A C25 H25B 107.5 . . ?
C25 C26 C27 113.5(8) . . ?
C25 C26 H26A 108.9 . . ?
C27 C26 H26A 108.9 . . ?
C25 C26 H26B 108.9 . . ?
C27 C26 H26B 108.9 . . ?
H26A C26 H26B 107.7 . . ?
C32 C27 C28 119.7(10) . . ?
C32 C27 C26 122.3(9) . . ?
C28 C27 C26 118.0(8) . . ?
C29 C28 C27 119.2(10) . . ?
C29 C28 H28 120.4 . . ?
C27 C28 H28 120.4 . . ?
C30 C29 C28 121.0(11) . . ?
C30 C29 H29 119.5 . . ?
C28 C29 H29 119.5 . . ?
C29 C30 C31 120.9(11) . . ?
C29 C30 H30 119.6 . . ?
C31 C30 H30 119.6 . . ?
C32 C31 C30 118.1(11) . . ?
C32 C31 H31 121.0 . . ?
C30 C31 H31 121.0 . . ?
C27 C32 C31 121.1(11) . . ?
C27 C32 H32 119.4 . . ?
C31 C32 H32 119.4 . . ?
C34 C33 S5 117.9(6) . . ?
C34 C33 H33A 107.8 . . ?
S5 C33 H33A 107.8 . . ?
C34 C33 H33B 107.8 . . ?
S5 C33 H33B 107.8 . . ?
H33A C33 H33B 107.2 . . ?
C35 C34 C33 112.2(8) . . ?
C35 C34 H34A 109.2 . . ?
C33 C34 H34A 109.2 . . ?
C35 C34 H34B 109.2 . . ?
C33 C34 H34B 109.2 . . ?
H34A C34 H34B 107.9 . . ?
C36 C35 C40 120.0(9) . . ?
C36 C35 C34 121.2(9) . . ?
C40 C35 C34 118.4(8) . . ?
C37 C36 C35 119.8(10) . . ?
C37 C36 H36 120.1 . . ?
C35 C36 H36 120.1 . . ?
C36 C37 C38 119.7(10) . . ?
C36 C37 H37 120.1 . . ?
C38 C37 H37 120.1 . . ?
C39 C38 C37 120.1(10) . . ?
C39 C38 H38 120.0 . . ?
C37 C38 H38 120.0 . . ?
C38 C39 C40 120.9(12) . . ?
C38 C39 H39 119.6 . . ?
C40 C39 H39 119.6 . . ?
C39 C40 C35 119.5(10) . . ?
C39 C40 H40 120.3 . . ?
C35 C40 H40 120.3 . . ?
C42 C41 S6 111.3(6) . . ?
C42 C41 H41A 109.4 . . ?
S6 C41 H41A 109.4 . . ?
C42 C41 H41B 109.4 . . ?
S6 C41 H41B 109.4 . . ?
H41A C41 H41B 108.0 . . ?
C43 C42 C41 108.5(8) . . ?
C43 C42 H42A 110.0 . . ?
C41 C42 H42A 110.0 . . ?
C43 C42 H42B 110.0 . . ?
C41 C42 H42B 110.0 . . ?
H42A C42 H42B 108.4 . . ?
C44 C43 C48 117.0(9) . . ?
C44 C43 C42 119.9(9) . . ?
C48 C43 C42 123.0(10) . . ?
C45 C44 C43 121.2(10) . . ?
C45 C44 H44 119.4 . . ?
C43 C44 H44 119.4 . . ?
C44 C45 C46 120.9(11) . . ?
C44 C45 H45 119.5 . . ?
C46 C45 H45 119.5 . . ?
C45 C46 C47 118.2(9) . . ?
C45 C46 H46 120.9 . . ?
C47 C46 H46 120.9 . . ?
C48 C47 C46 120.3(10) . . ?
C48 C47 H47 119.9 . . ?
C46 C47 H47 119.9 . . ?
C47 C48 C43 122.3(11) . . ?
C47 C48 H48 118.9 . . ?
C43 C48 H48 118.9 . . ?
C50 C49 S7 111.4(6) . . ?
C50 C49 H49A 109.4 . . ?
S7 C49 H49A 109.4 . . ?
C50 C49 H49B 109.4 . . ?
S7 C49 H49B 109.4 . . ?
H49A C49 H49B 108.0 . . ?
C49 C50 C51 111.4(7) . . ?
C49 C50 H50A 109.4 . . ?
C51 C50 H50A 109.4 . . ?
C49 C50 H50B 109.4 . . ?
C51 C50 H50B 109.4 . . ?
H50A C50 H50B 108.0 . . ?
C52 C51 C56 119.9(9) . . ?
C52 C51 C50 118.7(9) . . ?
C56 C51 C50 121.5(8) . . ?
C53 C52 C51 119.5(10) . . ?
C53 C52 H52 120.2 . . ?
C51 C52 H52 120.2 . . ?
C52 C53 C54 121.8(9) . . ?
C52 C53 H53 119.1 . . ?
C54 C53 H53 119.1 . . ?
C53 C54 C55 118.3(10) . . ?
C53 C54 H54 120.8 . . ?
C55 C54 H54 120.8 . . ?
C56 C55 C54 120.4(9) . . ?
C56 C55 H55 119.8 . . ?
C54 C55 H55 119.8 . . ?
C55 C56 C51 119.9(9) . . ?
C55 C56 H56 120.0 . . ?
C51 C56 H56 120.0 . . ?
C58 C57 S8 113.0(9) . . ?
C58 C57 H57A 109.0 . . ?
S8 C57 H57A 109.0 . . ?
C58 C57 H57B 109.0 . . ?
S8 C57 H57B 109.0 . . ?
H57A C57 H57B 107.8 . . ?
C57 C58 C59 115.4(10) . . ?
C57 C58 H58A 108.4 . . ?
C59 C58 H58A 108.4 . . ?
C57 C58 H58B 108.4 . . ?
C59 C58 H58B 108.4 . . ?
H58A C58 H58B 107.5 . . ?
C60 C59 C64 118.8(13) . . ?
C60 C59 C58 117.0(11) . . ?
C64 C59 C58 124.0(12) . . ?
C59 C60 C61 121.7(12) . . ?
C59 C60 H60 119.1 . . ?
C61 C60 H60 119.1 . . ?
C60 C61 C62 118.0(13) . . ?
C60 C61 H61 121.0 . . ?
C62 C61 H61 121.0 . . ?
C63 C62 C61 120.6(12) . . ?
C63 C62 H62 119.7 . . ?
C61 C62 H62 119.7 . . ?
C62 C63 C64 121.0(12) . . ?
C62 C63 H63 119.5 . . ?
C64 C63 H63 119.5 . . ?
C59 C64 C63 119.9(13) . . ?
C59 C64 H64 120.0 . . ?
C63 C64 H64 120.0 . . ?
C66 C65 S9 112.8(7) . . ?
C66 C65 H65A 109.0 . . ?
S9 C65 H65A 109.0 . . ?
C66 C65 H65B 109.0 . . ?
S9 C65 H65B 109.0 . . ?
H65A C65 H65B 107.8 . . ?
C65 C66 C67 115.7(9) . . ?
C65 C66 H66A 108.4 . . ?
C67 C66 H66A 108.4 . . ?
C65 C66 H66B 108.4 . . ?
C67 C66 H66B 108.4 . . ?
H66A C66 H66B 107.4 . . ?
C72 C67 C68 120.9(10) . . ?
C72 C67 C66 120.4(10) . . ?
C68 C67 C66 118.8(9) . . ?
C69 C68 C67 119.7(11) . . ?
C69 C68 H68 120.1 . . ?
C67 C68 H68 120.1 . . ?
C68 C69 C70 120.5(12) . . ?
C68 C69 H69 119.7 . . ?
C70 C69 H69 119.7 . . ?
C69 C70 C71 119.8(10) . . ?
C69 C70 H70 120.1 . . ?
C71 C70 H70 120.1 . . ?
C72 C71 C70 120.2(11) . . ?
C72 C71 H71 119.9 . . ?
C70 C71 H71 119.9 . . ?
C67 C72 C71 118.8(11) . . ?
C67 C72 H72 120.6 . . ?
C71 C72 H72 120.6 . . ?
C2S C1S H1S1 109.5 . . ?
C2S C1S H1S2 109.5 . . ?
H1S1 C1S H1S2 109.5 . . ?
C2S C1S H1S3 109.5 . . ?
H1S1 C1S H1S3 109.5 . . ?
H1S2 C1S H1S3 109.5 . . ?
C3S C2S C7S 120.0(11) . . ?
C3S C2S C1S 115.9(10) . . ?
C7S C2S C1S 123.4(10) . . ?
C2S C3S C4S 118.8(10) . . ?
C2S C3S H3S 120.6 . . ?
C4S C3S H3S 120.6 . . ?
C5S C4S C3S 119.5(10) . . ?
C5S C4S H4S 120.2 . . ?
C3S C4S H4S 120.2 . . ?
C4S C5S C6S 123.8(13) . . ?
C4S C5S H5S 118.1 . . ?
C6S C5S H5S 118.1 . . ?
C7S C6S C5S 116.9(11) . . ?
C7S C6S H6S 121.6 . . ?
C5S C6S H6S 121.6 . . ?
C6S C7S C2S 120.9(10) . . ?
C6S C7S H7S 119.5 . . ?
C2S C7S H7S 119.5 . . ?
Au1 Pt1 Au1 180.0 . 2_656 ?
Au1 Pt1 Au12 70.604(10) . 2_656 ?
Au1 Pt1 Au12 109.396(10) 2_656 2_656 ?
Au1 Pt1 Au12 109.396(11) . . ?
Au1 Pt1 Au12 70.604(11) 2_656 . ?
Au12 Pt1 Au12 180.0 2_656 . ?
Au1 Pt1 Au7 109.055(9) . . ?
Au1 Pt1 Au7 70.943(9) 2_656 . ?
Au12 Pt1 Au7 109.544(10) 2_656 . ?
Au12 Pt1 Au7 70.458(10) . . ?
Au1 Pt1 Au7 70.944(9) . 2_656 ?
Au1 Pt1 Au7 109.058(9) 2_656 2_656 ?
Au12 Pt1 Au7 70.456(9) 2_656 2_656 ?
Au12 Pt1 Au7 109.542(9) . 2_656 ?
Au7 Pt1 Au7 180.0 . 2_656 ?
Au1 Pt1 Au11 120.697(10) . 2_656 ?
Au1 Pt1 Au11 59.304(10) 2_656 2_656 ?
Au12 Pt1 Au11 60.359(11) 2_656 2_656 ?
Au12 Pt1 Au11 119.639(11) . 2_656 ?
Au7 Pt1 Au11 116.965(10) . 2_656 ?
Au7 Pt1 Au11 63.035(10) 2_656 2_656 ?
Au1 Pt1 Au11 59.303(10) . . ?
Au1 Pt1 Au11 120.696(10) 2_656 . ?
Au12 Pt1 Au11 119.641(11) 2_656 . ?
Au12 Pt1 Au11 60.361(11) . . ?
Au7 Pt1 Au11 63.034(10) . . ?
Au7 Pt1 Au11 116.965(10) 2_656 . ?
Au11 Pt1 Au11 180.0 2_656 . ?
Au1 Pt1 Au4 117.945(9) . 2_656 ?
Au1 Pt1 Au4 62.054(9) 2_656 2_656 ?
Au12 Pt1 Au4 60.592(10) 2_656 2_656 ?
Au12 Pt1 Au4 119.409(10) . 2_656 ?
Au7 Pt1 Au4 60.128(9) . 2_656 ?
Au7 Pt1 Au4 119.872(9) 2_656 2_656 ?
Au11 Pt1 Au4 63.457(8) 2_656 2_656 ?
Au11 Pt1 Au4 116.542(8) . 2_656 ?
Au1 Pt1 Au4 62.056(9) . . ?
Au1 Pt1 Au4 117.945(9) 2_656 . ?
Au12 Pt1 Au4 119.408(10) 2_656 . ?
Au12 Pt1 Au4 60.591(10) . . ?
Au7 Pt1 Au4 119.873(9) . . ?
Au7 Pt1 Au4 60.127(9) 2_656 . ?
Au11 Pt1 Au4 116.541(8) 2_656 . ?
Au11 Pt1 Au4 63.460(8) . . ?
Au4 Pt1 Au4 180.0 2_656 . ?
Au1 Pt1 Au8 60.056(11) . . ?
Au1 Pt1 Au8 119.943(11) 2_656 . ?
Au12 Pt1 Au8 62.687(10) 2_656 . ?
Au12 Pt1 Au8 117.315(10) . . ?
Au7 Pt1 Au8 59.860(10) . . ?
Au7 Pt1 Au8 120.140(10) 2_656 . ?
Au11 Pt1 Au8 115.809(10) 2_656 . ?
Au11 Pt1 Au8 64.191(10) . . ?
Au4 Pt1 Au8 64.548(10) 2_656 . ?
Au4 Pt1 Au8 115.454(10) . . ?
Au1 Pt1 Au8 119.945(11) . 2_656 ?
Au1 Pt1 Au8 60.056(11) 2_656 2_656 ?
Au12 Pt1 Au8 117.314(10) 2_656 2_656 ?
Au12 Pt1 Au8 62.684(10) . 2_656 ?
Au7 Pt1 Au8 120.139(10) . 2_656 ?
Au7 Pt1 Au8 59.862(10) 2_656 2_656 ?
Au11 Pt1 Au8 64.192(9) 2_656 2_656 ?
Au11 Pt1 Au8 115.808(9) . 2_656 ?
Au4 Pt1 Au8 115.452(10) 2_656 2_656 ?
Au4 Pt1 Au8 64.546(10) . 2_656 ?
Au8 Pt1 Au8 180.0 . 2_656 ?
C1 S1 Au2 103.7(3) . . ?
C1 S1 Au1 101.1(3) . . ?
Au2 S1 Au1 86.44(7) . . ?
C9 S2 Au3 109.0(3) . . ?
C9 S2 Au2 102.1(3) . . ?
Au3 S2 Au2 100.92(7) . . ?
C17 S3 Au5 106.0(3) . . ?
C17 S3 Au4 116.5(4) . . ?
Au5 S3 Au4 85.28(6) . . ?
C25 S4 Au5 104.5(3) . . ?
C25 S4 Au6 101.5(3) . . ?
Au5 S4 Au6 101.19(8) . . ?
C33 S5 Au6 107.7(3) . . ?
C33 S5 Au7 109.2(3) . . ?
Au6 S5 Au7 90.51(7) . . ?
C41 S6 Au10 106.1(3) . . ?
C41 S6 Au11 109.0(3) . . ?
Au10 S6 Au11 88.63(7) . . ?
C49 S7 Au10 104.8(3) . . ?
C49 S7 Au9 105.9(3) . . ?
Au10 S7 Au9 99.97(8) . . ?
C57 S8 Au3 101.2(4) . 2_656 ?
C57 S8 Au8 105.7(4) . . ?
Au3 S8 Au8 88.53(6) 2_656 . ?
C65 S9 Au9 105.2(3) . 2_656 ?
C65 S9 Au12 105.7(3) . . ?
Au9 S9 Au12 91.69(7) 2_656 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
S1 C1 C2 C3 -177.9(7) . . . . ?
C1 C2 C3 C4 82.2(15) . . . . ?
C1 C2 C3 C8 -93.6(14) . . . . ?
C8 C3 C4 C5 -5(2) . . . . ?
C2 C3 C4 C5 179.3(12) . . . . ?
C3 C4 C5 C6 6(2) . . . . ?
C4 C5 C6 C7 -6(2) . . . . ?
C5 C6 C7 C8 6.5(19) . . . . ?
C6 C7 C8 C3 -6(2) . . . . ?
C4 C3 C8 C7 5(2) . . . . ?
C2 C3 C8 C7 -179.1(12) . . . . ?
S2 C9 C10 C11 -175.8(6) . . . . ?
C9 C10 C11 C12 -56.3(11) . . . . ?
C9 C10 C11 C16 127.6(9) . . . . ?
C16 C11 C12 C13 1.8(15) . . . . ?
C10 C11 C12 C13 -174.1(9) . . . . ?
C11 C12 C13 C14 -2.3(15) . . . . ?
C12 C13 C14 C15 2.2(14) . . . . ?
C13 C14 C15 C16 -1.6(14) . . . . ?
C14 C15 C16 C11 0.9(15) . . . . ?
C12 C11 C16 C15 -1.0(15) . . . . ?
C10 C11 C16 C15 175.2(8) . . . . ?
S3 C17 C18 C19 178.8(8) . . . . ?
C17 C18 C19 C24 -125.7(12) . . . . ?
C17 C18 C19 C20 62.8(14) . . . . ?
C24 C19 C20 C21 2(2) . . . . ?
C18 C19 C20 C21 174.0(10) . . . . ?
C19 C20 C21 C22 -3(2) . . . . ?
C20 C21 C22 C23 2.5(19) . . . . ?
C21 C22 C23 C24 -2(2) . . . . ?
C20 C19 C24 C23 -1.9(19) . . . . ?
C18 C19 C24 C23 -173.2(10) . . . . ?
C22 C23 C24 C19 2(2) . . . . ?
S4 C25 C26 C27 175.1(7) . . . . ?
C25 C26 C27 C32 -87.1(13) . . . . ?
C25 C26 C27 C28 95.0(11) . . . . ?
C32 C27 C28 C29 2.1(17) . . . . ?
C26 C27 C28 C29 -180.0(10) . . . . ?
C27 C28 C29 C30 -2.2(17) . . . . ?
C28 C29 C30 C31 2.0(19) . . . . ?
C29 C30 C31 C32 -1.6(18) . . . . ?
C28 C27 C32 C31 -1.8(18) . . . . ?
C26 C27 C32 C31 -179.7(11) . . . . ?
C30 C31 C32 C27 1.6(18) . . . . ?
S5 C33 C34 C35 174.5(6) . . . . ?
C33 C34 C35 C36 97.0(11) . . . . ?
C33 C34 C35 C40 -76.3(10) . . . . ?
C40 C35 C36 C37 -0.9(15) . . . . ?
C34 C35 C36 C37 -174.0(9) . . . . ?
C35 C36 C37 C38 0.0(16) . . . . ?
C36 C37 C38 C39 0.1(16) . . . . ?
C37 C38 C39 C40 0.7(17) . . . . ?
C38 C39 C40 C35 -1.7(16) . . . . ?
C36 C35 C40 C39 1.7(14) . . . . ?
C34 C35 C40 C39 175.1(9) . . . . ?
S6 C41 C42 C43 -171.7(7) . . . . ?
C41 C42 C43 C44 97.8(11) . . . . ?
C41 C42 C43 C48 -80.9(13) . . . . ?
C48 C43 C44 C45 -0.1(16) . . . . ?
C42 C43 C44 C45 -178.8(10) . . . . ?
C43 C44 C45 C46 -0.1(17) . . . . ?
C44 C45 C46 C47 -0.3(17) . . . . ?
C45 C46 C47 C48 0.9(18) . . . . ?
C46 C47 C48 C43 -1(2) . . . . ?
C44 C43 C48 C47 0.6(18) . . . . ?
C42 C43 C48 C47 179.4(11) . . . . ?
S7 C49 C50 C51 69.8(9) . . . . ?
C49 C50 C51 C52 -120.1(9) . . . . ?
C49 C50 C51 C56 60.4(11) . . . . ?
C56 C51 C52 C53 2.3(13) . . . . ?
C50 C51 C52 C53 -177.3(8) . . . . ?
C51 C52 C53 C54 -1.5(15) . . . . ?
C52 C53 C54 C55 1.1(15) . . . . ?
C53 C54 C55 C56 -1.6(14) . . . . ?
C54 C55 C56 C51 2.5(15) . . . . ?
C52 C51 C56 C55 -2.8(14) . . . . ?
C50 C51 C56 C55 176.7(8) . . . . ?
S8 C57 C58 C59 -49.8(12) . . . . ?
C57 C58 C59 C60 -50.9(15) . . . . ?
C57 C58 C59 C64 123.9(13) . . . . ?
C64 C59 C60 C61 -1(2) . . . . ?
C58 C59 C60 C61 174.3(12) . . . . ?
C59 C60 C61 C62 1(2) . . . . ?
C60 C61 C62 C63 0(2) . . . . ?
C61 C62 C63 C64 -0.6(19) . . . . ?
C60 C59 C64 C63 -0.1(18) . . . . ?
C58 C59 C64 C63 -174.7(10) . . . . ?
C62 C63 C64 C59 0.8(19) . . . . ?
S9 C65 C66 C67 -177.5(7) . . . . ?
C65 C66 C67 C72 -19.1(14) . . . . ?
C65 C66 C67 C68 161.3(10) . . . . ?
C72 C67 C68 C69 0.2(18) . . . . ?
C66 C67 C68 C69 179.8(10) . . . . ?
C67 C68 C69 C70 1.5(18) . . . . ?
C68 C69 C70 C71 -2.2(18) . . . . ?
C69 C70 C71 C72 1.4(17) . . . . ?
C68 C67 C72 C71 -1.0(17) . . . . ?
C66 C67 C72 C71 179.4(10) . . . . ?
C70 C71 C72 C67 0.2(17) . . . . ?
C7S C2S C3S C4S 1.8(16) . . . . ?
C1S C2S C3S C4S 172.7(10) . . . . ?
C2S C3S C4S C5S -2.8(17) . . . . ?
C3S C4S C5S C6S 2(2) . . . . ?
C4S C5S C6S C7S 0(2) . . . . ?
C5S C6S C7S C2S -0.9(18) . . . . ?
C3S C2S C7S C6S 0.0(17) . . . . ?
C1S C2S C7S C6S -170.2(11) . . . . ?
C10 C9 S2 Au3 53.9(6) . . . . ?
C10 C9 S2 Au2 160.1(5) . . . . ?
C18 C17 S3 Au5 48.5(9) . . . . ?
C18 C17 S3 Au4 -44.2(10) . . . . ?
C26 C25 S4 Au5 167.4(6) . . . . ?
C26 C25 S4 Au6 62.4(7) . . . . ?
C34 C33 S5 Au6 -41.8(7) . . . . ?
C34 C33 S5 Au7 55.1(7) . . . . ?
C42 C41 S6 Au10 -69.6(7) . . . . ?
C42 C41 S6 Au11 -163.8(6) . . . . ?
C50 C49 S7 Au10 -88.3(7) . . . . ?
C50 C49 S7 Au9 166.6(6) . . . . ?
C58 C57 S8 Au3 -61.9(9) . . . 2_656 ?
C58 C57 S8 Au8 -153.5(8) . . . . ?
C66 C65 S9 Au9 -57.3(7) . . . 2_656 ?
C66 C65 S9 Au12 -153.5(6) . . . . ?

_refine_diff_density_max         2.303
_refine_diff_density_min         -2.910
_refine_diff_density_rms         0.271



