# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Compound1
_database_code_depnum_ccdc_archive 'CCDC 1471310'
_audit_update_record             
;
2016-03-30 deposited with the CCDC.
2016-05-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C64 H60 F3 N12 O52 P W12 Zn2'
_chemical_formula_sum            'C64 H60 F3 N12 O52 P W12 Zn2'
_chemical_formula_weight         4254.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -5.4734 5.5774 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn -1.5491 0.6778 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Tetragonal
_symmetry_space_group_name_H-M   P4/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y+1/2, x, z'
'-x+1/2, -y+1/2, z'
'y, -x+1/2, z'
'-x, -y, -z'
'y-1/2, -x, -z'
'x-1/2, y-1/2, -z'
'-y, x-1/2, -z'

_cell_length_a                   19.5965(3)
_cell_length_b                   19.5965(3)
_cell_length_c                   16.0780(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     6174.32(18)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    8879
_cell_measurement_theta_min      2.6480
_cell_measurement_theta_max      29.6740

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.288
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3868
_exptl_absorpt_coefficient_mu    21.289
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.42208
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   'CrystalClear (Rigaku Inc., 2007)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18135
_diffrn_reflns_av_R_equivalents  0.0320
_diffrn_reflns_av_sigmaI/netI    0.0346
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         5.29
_diffrn_reflns_theta_max         74.48
_reflns_number_total             6320
_reflns_number_gt                5155
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
'CrysAlisPro, Agilent Technologies, Version 1.171.36.32'
_computing_cell_refinement       
'CrysAlisPro, Agilent Technologies, Version 1.171.36.32'
_computing_data_reduction        
'CrysAlisPro, Agilent Technologies, Version 1.171.36.32'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97/2 (Sheldrick,1997)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0255P)²+26.3051P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    Constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6320
_refine_ls_number_parameters     336
_refine_ls_number_restraints     246
_refine_ls_R_factor_all          0.0442
_refine_ls_R_factor_gt           0.0340
_refine_ls_wR_factor_ref         0.0765
_refine_ls_wR_factor_gt          0.0727
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_restrained_S_all      1.042
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.688401(13) 0.364213(13) 0.844065(14) 0.01423(7) Uani 1 1 d U . .
W2 W 0.633612(12) 0.198393(13) 0.843794(14) 0.01395(7) Uani 1 1 d U . .
W3 W 0.577582(13) 0.309211(14) 0.993694(14) 0.01543(8) Uani 1 1 d U . .
Zn1 Zn 0.2500 0.2500 0.59339(9) 0.0150(3) Uani 1 4 d SU . .
Zn2 Zn 0.2500 0.2500 0.84311(10) 0.0232(3) Uani 1 4 d SU . .
P1 P 0.7500 0.2500 1.0000 0.0118(5) Uani 1 4 d SU . .
F1 F 0.2500 0.2500 0.4487(6) 0.058(2) Uani 1 4 d SU . .
F2 F 0.2500 0.2500 0.7200(4) 0.0286(16) Uani 1 4 d SU . .
F3 F 0.2500 0.2500 0.9789(6) 0.068(3) Uani 1 4 d SU . .
N1 N 0.2541(3) 0.3573(3) 0.5908(3) 0.0286(12) Uani 1 1 d U . .
N2 N 0.2540(3) 0.5710(3) 0.6020(3) 0.0264(12) Uani 1 1 d U . .
N3 N 0.4141(3) 0.3979(3) 0.8443(4) 0.0421(15) Uani 1 1 d U . .
O1 O 0.1374(3) 0.5678(2) 0.6171(3) 0.0353(11) Uani 1 1 d U . .
O2 O 0.3688(3) 0.5737(2) 0.5824(3) 0.0342(11) Uani 1 1 d U . .
O3 O 0.3366(2) 0.3149(2) 0.8381(3) 0.0381(11) Uani 1 1 d U . .
O4 O 0.7240(2) 0.1725(2) 0.8150(2) 0.0257(10) Uani 1 1 d U . .
O5 O 0.5859(2) 0.1575(2) 0.7709(2) 0.0290(10) Uani 1 1 d U . .
O6 O 0.5639(2) 0.2430(2) 0.9085(2) 0.0275(10) Uani 1 1 d U . .
O7 O 0.6487(2) 0.2851(2) 0.7919(2) 0.0252(9) Uani 1 1 d U . .
O8 O 0.5874(2) 0.2359(2) 1.0706(2) 0.0256(10) Uani 1 1 d U . .
O9 O 0.6897(2) 0.2708(2) 0.9451(2) 0.0211(9) Uani 1 1 d U . .
O10 O 0.6317(2) 0.3604(2) 1.0710(2) 0.0258(9) Uani 1 1 d U . .
O11 O 0.6758(2) 0.4260(2) 0.7718(3) 0.0322(11) Uani 1 1 d U . .
O12 O 0.6066(2) 0.3713(2) 0.9077(2) 0.0268(10) Uani 1 1 d U . .
O13 O 0.4972(2) 0.3373(3) 1.0124(2) 0.0357(12) Uani 1 1 d U . .
C1 C 0.2195(4) 0.3946(3) 0.5346(4) 0.0325(16) Uani 1 1 d U . .
H1 H 0.1942 0.3715 0.4928 0.039 Uiso 1 1 calc R . .
C2 C 0.2193(4) 0.4646(3) 0.5351(4) 0.0348(16) Uani 1 1 d U . .
H2 H 0.1955 0.4898 0.4938 0.042 Uiso 1 1 calc R . .
C3 C 0.2552(4) 0.4978(3) 0.5984(4) 0.0296(15) Uani 1 1 d U . .
C4 C 0.2906(3) 0.4604(3) 0.6562(4) 0.0285(14) Uani 1 1 d U . .
H4 H 0.3163 0.4824 0.6985 0.034 Uiso 1 1 calc R . .
C5 C 0.2881(3) 0.3901(3) 0.6513(4) 0.0319(15) Uani 1 1 d U . .
H5 H 0.3112 0.3640 0.6923 0.038 Uiso 1 1 calc R . .
C6 C 0.1894(3) 0.6021(3) 0.6100(4) 0.0253(14) Uani 1 1 d U . .
C7 C 0.1885(3) 0.6779(3) 0.6067(3) 0.0240(14) Uani 1 1 d U . .
C8 C 0.2506(3) 0.7140(3) 0.6067(3) 0.0212(13) Uani 1 1 d U . .
C9 C 0.3139(3) 0.6800(3) 0.6038(3) 0.0238(14) Uani 1 1 d U . .
C10 C 0.3163(3) 0.6053(3) 0.5959(4) 0.0252(14) Uani 1 1 d U . .
C11 C 0.3742(3) 0.7166(3) 0.6050(3) 0.0244(14) Uani 1 1 d U . .
H11 H 0.4167 0.6933 0.6040 0.029 Uiso 1 1 calc R . .
C12 C 0.3728(3) 0.7885(3) 0.6076(4) 0.0269(14) Uani 1 1 d U . .
H12 H 0.4143 0.8135 0.6099 0.032 Uiso 1 1 calc R . .
C13 C 0.3565(4) 0.3699(4) 0.8686(4) 0.0349(16) Uani 1 1 d U . .
C14 C 0.3173(5) 0.4061(4) 0.9346(5) 0.055(2) Uani 1 1 d U . .
H14A H 0.2723 0.3849 0.9407 0.082 Uiso 1 1 calc R . .
H14B H 0.3118 0.4541 0.9191 0.082 Uiso 1 1 calc R . .
H14C H 0.3421 0.4031 0.9875 0.082 Uiso 1 1 calc R . .
C15 C 0.4553(4) 0.3638(5) 0.7798(6) 0.059(2) Uani 1 1 d U . .
H15A H 0.4333 0.3209 0.7637 0.089 Uiso 1 1 calc R . .
H15B H 0.5010 0.3543 0.8018 0.089 Uiso 1 1 calc R . .
H15C H 0.4591 0.3936 0.7311 0.089 Uiso 1 1 calc R . .
C16 C 0.4431(5) 0.4614(4) 0.8771(6) 0.061(2) Uani 1 1 d U . .
H16A H 0.4142 0.4784 0.9223 0.092 Uiso 1 1 calc R . .
H16B H 0.4452 0.4955 0.8326 0.092 Uiso 1 1 calc R . .
H16C H 0.4891 0.4526 0.8982 0.092 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O11 1.695(4) . ?
W1 O12 1.906(4) . ?
W1 O8 1.910(4) 6_667 ?
W1 O4 1.919(4) 3_655 ?
W1 O7 1.926(4) . ?
W1 O9 2.448(4) . ?
W2 O5 1.701(4) . ?
W2 O10 1.897(4) 8_657 ?
W2 O4 1.900(4) . ?
W2 O7 1.916(4) . ?
W2 O6 1.926(4) . ?
W2 O9 2.424(4) . ?
W3 O13 1.696(5) . ?
W3 O8 1.905(4) . ?
W3 O6 1.907(4) . ?
W3 O10 1.917(4) . ?
W3 O12 1.927(4) . ?
W3 O9 2.449(4) . ?
Zn1 F2 2.036(7) . ?
Zn1 N1 2.105(5) 3 ?
Zn1 N1 2.105(5) 2 ?
Zn1 N1 2.105(5) . ?
Zn1 N1 2.105(5) 4 ?
Zn1 F1 2.326(10) . ?
Zn2 F2 1.979(7) . ?
Zn2 O3 2.123(5) 3 ?
Zn2 O3 2.123(5) . ?
Zn2 O3 2.123(5) 2 ?
Zn2 O3 2.123(5) 4 ?
Zn2 F3 2.183(10) . ?
P1 O9 1.531(4) . ?
P1 O9 1.531(4) 8_657 ?
P1 O9 1.531(4) 6_667 ?
P1 O9 1.531(4) 3_655 ?
N1 C5 1.342(8) . ?
N1 C1 1.346(8) . ?
N2 C10 1.397(8) . ?
N2 C6 1.411(8) . ?
N2 C3 1.437(8) . ?
N3 C13 1.315(9) . ?
N3 C16 1.466(10) . ?
N3 C15 1.474(10) . ?
O1 C6 1.225(8) . ?
O2 C10 1.219(7) . ?
O3 C13 1.246(8) . ?
O4 W1 1.919(4) 3_655 ?
O8 W1 1.910(4) 8_657 ?
O10 W2 1.897(4) 6_667 ?
C1 C2 1.372(9) . ?
C2 C3 1.397(9) . ?
C3 C4 1.371(9) . ?
C4 C5 1.381(9) . ?
C6 C7 1.487(8) . ?
C7 C12 1.371(9) 3_565 ?
C7 C8 1.409(9) . ?
C8 C9 1.408(8) . ?
C8 C8 1.412(12) 3_565 ?
C9 C11 1.382(9) . ?
C9 C10 1.472(8) . ?
C11 C12 1.409(9) . ?
C12 C7 1.371(9) 3_565 ?
C13 C14 1.490(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 W1 O12 101.2(2) . . ?
O11 W1 O8 102.0(2) . 6_667 ?
O12 W1 O8 89.31(18) . 6_667 ?
O11 W1 O4 103.35(19) . 3_655 ?
O12 W1 O4 155.47(17) . 3_655 ?
O8 W1 O4 85.70(17) 6_667 3_655 ?
O11 W1 O7 102.5(2) . . ?
O12 W1 O7 87.28(18) . . ?
O8 W1 O7 155.37(17) 6_667 . ?
O4 W1 O7 87.34(18) 3_655 . ?
O11 W1 O9 171.91(18) . . ?
O12 W1 O9 72.93(15) . . ?
O8 W1 O9 83.65(15) 6_667 . ?
O4 W1 O9 82.65(16) 3_655 . ?
O7 W1 O9 72.03(15) . . ?
O5 W2 O10 101.94(19) . 8_657 ?
O5 W2 O4 102.64(19) . . ?
O10 W2 O4 86.26(17) 8_657 . ?
O5 W2 O7 101.70(19) . . ?
O10 W2 O7 156.35(17) 8_657 . ?
O4 W2 O7 89.25(18) . . ?
O5 W2 O6 101.30(19) . . ?
O10 W2 O6 88.04(18) 8_657 . ?
O4 W2 O6 156.04(17) . . ?
O7 W2 O6 86.70(18) . . ?
O5 W2 O9 171.37(18) . . ?
O10 W2 O9 83.69(15) 8_657 . ?
O4 W2 O9 84.11(16) . . ?
O7 W2 O9 72.76(15) . . ?
O6 W2 O9 72.13(15) . . ?
O13 W3 O8 102.9(2) . . ?
O13 W3 O6 102.6(2) . . ?
O8 W3 O6 88.11(18) . . ?
O13 W3 O10 103.2(2) . . ?
O8 W3 O10 85.32(18) . . ?
O6 W3 O10 154.18(17) . . ?
O13 W3 O12 101.4(2) . . ?
O8 W3 O12 155.72(17) . . ?
O6 W3 O12 87.47(18) . . ?
O10 W3 O12 88.34(18) . . ?
O13 W3 O9 171.62(16) . . ?
O8 W3 O9 83.37(15) . . ?
O6 W3 O9 71.81(15) . . ?
O10 W3 O9 82.63(15) . . ?
O12 W3 O9 72.57(15) . . ?
F2 Zn1 N1 91.13(15) . 3 ?
F2 Zn1 N1 91.13(15) . 2 ?
N1 Zn1 N1 89.978(7) 3 2 ?
F2 Zn1 N1 91.13(15) . . ?
N1 Zn1 N1 177.7(3) 3 . ?
N1 Zn1 N1 89.978(6) 2 . ?
F2 Zn1 N1 91.13(15) . 4 ?
N1 Zn1 N1 89.978(6) 3 4 ?
N1 Zn1 N1 177.7(3) 2 4 ?
N1 Zn1 N1 89.978(7) . 4 ?
F2 Zn1 F1 180.000(2) . . ?
N1 Zn1 F1 88.87(15) 3 . ?
N1 Zn1 F1 88.87(15) 2 . ?
N1 Zn1 F1 88.87(15) . . ?
N1 Zn1 F1 88.87(15) 4 . ?
F2 Zn2 O3 87.82(14) . 3 ?
F2 Zn2 O3 87.82(14) . . ?
O3 Zn2 O3 175.6(3) 3 . ?
F2 Zn2 O3 87.82(14) . 2 ?
O3 Zn2 O3 89.917(11) 3 2 ?
O3 Zn2 O3 89.917(11) . 2 ?
F2 Zn2 O3 87.82(14) . 4 ?
O3 Zn2 O3 89.917(11) 3 4 ?
O3 Zn2 O3 89.917(11) . 4 ?
O3 Zn2 O3 175.6(3) 2 4 ?
F2 Zn2 F3 180.000(3) . . ?
O3 Zn2 F3 92.18(14) 3 . ?
O3 Zn2 F3 92.18(14) . . ?
O3 Zn2 F3 92.18(14) 2 . ?
O3 Zn2 F3 92.18(14) 4 . ?
O9 P1 O9 109.40(14) . 8_657 ?
O9 P1 O9 109.40(14) . 6_667 ?
O9 P1 O9 109.6(3) 8_657 6_667 ?
O9 P1 O9 109.6(3) . 3_655 ?
O9 P1 O9 109.40(14) 8_657 3_655 ?
O9 P1 O9 109.40(14) 6_667 3_655 ?
Zn2 F2 Zn1 180.0 . . ?
C5 N1 C1 118.5(6) . . ?
C5 N1 Zn1 118.9(4) . . ?
C1 N1 Zn1 122.4(4) . . ?
C10 N2 C6 125.7(5) . . ?
C10 N2 C3 117.6(6) . . ?
C6 N2 C3 116.7(5) . . ?
C13 N3 C16 125.4(7) . . ?
C13 N3 C15 119.4(6) . . ?
C16 N3 C15 115.2(6) . . ?
C13 O3 Zn2 138.9(5) . . ?
W2 O4 W1 151.0(2) . 3_655 ?
W3 O6 W2 126.6(2) . . ?
W2 O7 W1 125.9(2) . . ?
W3 O8 W1 152.1(2) . 8_657 ?
P1 O9 W2 125.6(2) . . ?
P1 O9 W1 126.1(2) . . ?
W2 O9 W1 89.26(12) . . ?
P1 O9 W3 126.2(2) . . ?
W2 O9 W3 89.31(13) . . ?
W1 O9 W3 88.44(13) . . ?
W2 O10 W3 151.8(2) 6_667 . ?
W1 O12 W3 126.0(2) . . ?
N1 C1 C2 122.7(6) . . ?
C1 C2 C3 117.9(6) . . ?
C4 C3 C2 120.0(6) . . ?
C4 C3 N2 121.0(6) . . ?
C2 C3 N2 119.1(6) . . ?
C3 C4 C5 118.4(6) . . ?
N1 C5 C4 122.4(6) . . ?
O1 C6 N2 121.3(6) . . ?
O1 C6 C7 122.7(6) . . ?
N2 C6 C7 116.0(5) . . ?
C12 C7 C8 121.1(6) 3_565 . ?
C12 C7 C6 119.4(6) 3_565 . ?
C8 C7 C6 119.4(6) . . ?
C9 C8 C8 119.2(7) . 3_565 ?
C9 C8 C7 121.7(6) . . ?
C8 C8 C7 119.2(7) 3_565 . ?
C11 C9 C8 120.5(6) . . ?
C11 C9 C10 119.4(6) . . ?
C8 C9 C10 120.1(6) . . ?
O2 C10 N2 120.4(6) . . ?
O2 C10 C9 123.2(6) . . ?
N2 C10 C9 116.4(6) . . ?
C9 C11 C12 120.2(6) . . ?
C7 C12 C11 119.8(6) 3_565 . ?
O3 C13 N3 120.8(7) . . ?
O3 C13 C14 122.1(7) . . ?
N3 C13 C14 117.1(7) . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        74.48
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.570
_refine_diff_density_min         -1.680
_refine_diff_density_rms         0.177
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.133 0.344 0.500 1942 466 ' '
_platon_squeeze_details          
;
;
