# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2a
_database_code_depnum_ccdc_archive 'CCDC 1472548'
_audit_update_record             
;
2016-05-25 deposited with the CCDC.
2016-05-26 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT602_2a                  
;
PROBLEM:VERY LARGE Solvent Accessible VOID(S) in Structure
RESPONSE:The crystal has large solvent accessible voids since 
a large number of disordered solvent molecules which could 
not be located.
;
_vrf_PLAT306_2a                  
;
PROBLEM: Isolated Oxygen Atom (H-atoms Missing ?) ....... O1S
RESPONSE: This is due to no attempt was made to 
locate hydrogen atoms of solvent molecules.
;

_vrf_PLAT342_2a                  
;
PROBLEM:Low Bond Precision on C-C Bonds .......... 0.0286 Ang.
RESPONSE:This is due to the poor quality of 
this crystal, however, it represents the best possible 
data after multiple attempts.
;
_vrf_PLAT369_2a                  
;
PROBLEM:Long C(sp2)-C(sp2) Bond C533 - C537 ... 1.57 Ang.
RESPONSE:This is due to the poor quality of this crystal, 
however, it represents the best possible 
data after multiple attempts.
;
_vrf_PLAT420_2a                  
;
PROBLEM:D-H Without Acceptor O12 - H12
RESPONSE:The hydrogen atoms of organic ligands were generated 
geometrically. The hydrogen could not 
be accurately located by the present data. 
Even the quality of this crystal is poor, however, 
it represents the best possible data after multiple attempts.
;
_vrf_PLAT431_2a                  
;
PROBLEM:Short Inter HL..A Contact F24 .. O5S .. 2.63 Ang.
RESPONSE:This is due to the poor quality of this crystal,
 however, it represents the best possible data 
after multiple attempts.
;
# end Validation Reply Form
_audit_creation_date             2016-05-12
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'2(C54.5 H42 Ag Au3 N3 O6 P3), 4(B F4), 2(C O), 3(O)'
_chemical_formula_sum            'C111 H98 Ag2 Au6 B4 F16 N6 O17 P6'
_chemical_formula_weight         3718.55
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.9788(9)
_cell_length_b                   16.3669(9)
_cell_length_c                   29.5491(12)
_cell_angle_alpha                78.976(4)
_cell_angle_beta                 80.628(4)
_cell_angle_gamma                61.755(6)
_cell_volume                     6658.6(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    102(3)
_cell_measurement_reflns_used    13900
_cell_measurement_theta_min      3.7040
_cell_measurement_theta_max      28.6790
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    7.024
_exptl_absorpt_correction_T_min  0.28147
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.855
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3528
_exptl_crystal_size_max          0.75
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.19
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0858
_diffrn_reflns_av_unetI/netI     0.1186
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            46649
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         3.407
_diffrn_ambient_temperature      102(3)
_diffrn_detector_area_resol_mean 10.4741
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                16155
_reflns_number_total             23372
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max         5.294
_refine_diff_density_min         -3.309
_refine_diff_density_rms         0.319
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1294
_refine_ls_number_reflns         23372
_refine_ls_number_restraints     604
_refine_ls_R_factor_all          0.1069
_refine_ls_R_factor_gt           0.0801
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1364P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2243
_refine_ls_wR_factor_ref         0.2524
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups
2. Restrained distances
 B1-F11 = B1-F12 = B1-F13 = B1-F14
 1.35 with sigma of 0.02
 F11-F12 = F11-F13 = F11-F14 = F12-F13 = F12-F14 = F13-F14
 2.25 with sigma of 0.02
 B3-F31 = B3-F32 = B3-F33 = B3-F34
 1.35 with sigma of 0.02
 F31-F32 = F31-F33 = F31-F34 = F32-F33 = F32-F34 = F33-F34
 2.25 with sigma of 0.02
 B2-F21 = B2-F22 = B2-F23 = B2-F24
 1.35 with sigma of 0.02
 F21-F22 = F21-F23 = F21-F24 = F22-F23 = F22-F24 = F23-F24
 2.25 with sigma of 0.02
 B4-F41 = B4-F42 = B4-F43 = B4-F44
 1.35 with sigma of 0.02
 F41-F42 = F41-F43 = F41-F44 = F42-F43 = F42-F44 = F43-F44
 2.25 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
C111 \\sim C112 \\sim C113 \\sim C114 \\sim C115 \\sim C116: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C211 \\sim C212 \\sim C213 \\sim C214 \\sim C215 \\sim C216: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C221 \\sim C222 \\sim C223 \\sim C224 \\sim C225 \\sim C226: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
O21 \\sim O22 \\sim C231 \\sim C232 \\sim C233 \\sim C234 \\sim C235 \\sim N236
\\sim C237: within 2A with sigma of 0.001 and sigma for terminal atoms of 0.002
C321 \\sim C322 \\sim C323 \\sim C324 \\sim C325 \\sim C326: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C311 \\sim C312 \\sim C313 \\sim C314 \\sim C315 \\sim C316: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C411 \\sim C412 \\sim C413 \\sim C414 \\sim C415 \\sim C416: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C421 \\sim C422 \\sim C423 \\sim C424 \\sim C425 \\sim C426: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
O41 \\sim O42 \\sim N436 \\sim C435 \\sim C431 \\sim C432 \\sim C433 \\sim C434
\\sim C437: within 2A with sigma of 0.001 and sigma for terminal atoms of 0.002
C611 \\sim C612 \\sim C613 \\sim C614 \\sim C615 \\sim C616: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C621 \\sim C622 \\sim C623 \\sim C624 \\sim C625 \\sim C626: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C634 \\sim C633 \\sim C632 \\sim N636 \\sim C635 \\sim C637 \\sim O61 \\sim
O62: within 2A with sigma of 0.001 and sigma for terminal atoms of 0.002
C121 \\sim C122 \\sim C123 \\sim C124 \\sim C125 \\sim C126: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002
C131 \\sim C132 \\sim C133 \\sim C134 \\sim C135 \\sim N136 \\sim C137 \\sim
O11 \\sim O12: within 2A with sigma of 0.001 and sigma for terminal atoms of
0.002
4. Others
 Fixed Uiso: F41(0.3) F42(0.3) F43(0.3) F44(0.3) B4(0.3)
5.a Aromatic/amide H refined with riding coordinates:
 C112(H112), C116(H116), C115(H115), C114(H114), C113(H113), C122(H122),
 C123(H123), C124(H124), C125(H125), C126(H126), C132(H132), C134(H134),
 C135(H135), C216(H216), C215(H215), C214(H214), C213(H213), C212(H212),
 C224(H224), C223(H223), C222(H222), C226(H226), C225(H225), C232(H232),
 C234(H234), C235(H235), C316(H316), C315(H315), C314(H314), C313(H313),
 C312(H312), C326(H326), C325(H325), C324(H324), C323(H323), C322(H322),
 C332(H332), C334(H334), C335(H335), C412(H412), C413(H413), C414(H414),
 C415(H415), C416(H416), C422(H422), C423(H423), C424(H424), C425(H425),
 C426(H426), C432(H432), C434(H434), C435(H435), C512(H512), C513(H513),
 C514(H514), C515(H515), C516(H516), C522(H522), C523(H523), C524(H524),
 C525(H525), C526(H526), C532(H532), C534(H534), C535(H535), C612(H612),
 C613(H613), C614(H614), C615(H615), C616(H616), C626(H626), C622(H622),
 C623(H623), C625(H625), C624(H624), C632(H632), C634(H634), C635(H635)
5.b Fitted hexagon refined as free rotating group:
 C112(C111,C116,C115,C114,C113), C121(C122,C123,C124,C125,C126), C211(C216,
 C215,C214,C213,C212), C224(C223,C222,C221,C226,C225), C311(C316,C315,C314,C313,
 C312), C321(C326,C325,C324,C323,C322), C626(C621,C622,C623,C625,C624)
5.c Tetrahedral OH refined with riding coordinates:
 O12(H12), O21(H21), O42(H42), O62(H62)
5.d Idealised tetrahedral OH refined as rotating group:
 O31(H31), O52(H52)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.55911(5) 0.07718(5) 0.51892(2) 0.0518(2) Uani 1 1 d . . . . .
Au2 Au 0.38174(5) 0.12528(4) 0.47616(2) 0.0508(2) Uani 1 1 d . . . . .
Au3 Au 0.57046(4) 0.00346(5) 0.43321(2) 0.04760(19) Uani 1 1 d . . . . .
Ag1 Ag 0.39853(9) 0.04276(10) 0.39423(4) 0.0526(3) Uani 1 1 d . . . . .
P1 P 0.6276(5) 0.1514(5) 0.54345(18) 0.0857(18) Uani 1 1 d . . . . .
P2 P 0.2611(4) 0.2561(3) 0.44389(17) 0.0653(13) Uani 1 1 d . . . . .
P3 P 0.6389(3) 0.0125(3) 0.36000(14) 0.0530(11) Uani 1 1 d . . . . .
O11 O 0.4919(13) -0.3354(12) 0.2691(6) 0.115(3) Uani 1 1 d . U . . .
O12 O 0.4724(13) -0.4114(12) 0.3431(6) 0.118(3) Uani 1 1 d . U . . .
H12 H 0.4820 -0.4549 0.3286 0.177 Uiso 1 1 calc R . . . .
O21 O -0.1025(10) 0.2883(12) 0.3642(7) 0.114(3) Uani 1 1 d . U . . .
H21 H -0.1620 0.3210 0.3661 0.171 Uiso 1 1 calc R . . . .
O22 O -0.1098(11) 0.3746(13) 0.4151(7) 0.116(3) Uani 1 1 d . U . . .
O31 O 0.4666(9) 0.3388(9) 0.1929(4) 0.071(4) Uani 1 1 d . . . . .
H31 H 0.4848 0.3422 0.1646 0.107 Uiso 1 1 calc GR . . . .
O32 O 0.6149(10) 0.2682(8) 0.2077(4) 0.072(4) Uani 1 1 d . . . . .
C1 C 0.5000 0.0000 0.5000 0.052(6) Uani 1 2 d S T P . .
C112 C 0.8028(13) 0.0081(16) 0.5146(6) 0.130(3) Uani 1 1 d . U . . .
H112 H 0.7678 0.0004 0.4941 0.156 Uiso 1 1 calc R . . . .
C111 C 0.7573(10) 0.0797(14) 0.5422(7) 0.130(3) Uani 1 1 d G U . . .
C116 C 0.8085(13) 0.0909(14) 0.5723(7) 0.130(3) Uani 1 1 d G U . . .
H116 H 0.7774 0.1398 0.5911 0.156 Uiso 1 1 calc R . . . .
C115 C 0.9052(13) 0.0306(16) 0.5747(6) 0.130(3) Uani 1 1 d G U . . .
H115 H 0.9402 0.0382 0.5952 0.156 Uiso 1 1 calc R . . . .
C114 C 0.9507(10) -0.0410(14) 0.5471(7) 0.130(3) Uani 1 1 d G U . . .
H114 H 1.0167 -0.0822 0.5487 0.157 Uiso 1 1 calc R . . . .
C113 C 0.8995(13) -0.0522(14) 0.5170(6) 0.130(3) Uani 1 1 d G U . . .
H113 H 0.9305 -0.1011 0.4982 0.157 Uiso 1 1 calc R . . . .
C121 C 0.598(2) 0.2622(13) 0.5129(7) 0.178(5) Uani 1 1 d . U . . .
C122 C 0.504(2) 0.3225(18) 0.5032(8) 0.178(5) Uani 1 1 d G U . . .
H122 H 0.4542 0.3080 0.5176 0.214 Uiso 1 1 calc R . . . .
C123 C 0.4832(17) 0.4040(16) 0.4725(9) 0.179(5) Uani 1 1 d G U . . .
H123 H 0.4192 0.4452 0.4659 0.214 Uiso 1 1 calc R . . . .
C124 C 0.556(2) 0.4253(14) 0.4514(7) 0.179(5) Uani 1 1 d G U . . .
H124 H 0.5420 0.4810 0.4303 0.214 Uiso 1 1 calc R . . . .
C125 C 0.650(2) 0.3650(19) 0.4610(9) 0.179(5) Uani 1 1 d G U . . .
H125 H 0.6998 0.3795 0.4466 0.215 Uiso 1 1 calc R . . . .
C126 C 0.6708(18) 0.2835(16) 0.4918(9) 0.179(5) Uani 1 1 d G U . . .
H126 H 0.7348 0.2423 0.4984 0.214 Uiso 1 1 calc R . . . .
C131 C 0.4086(19) -0.1656(18) 0.3964(9) 0.106(3) Uani 1 1 d . U . . .
N136 N 0.4179(15) -0.0962(14) 0.3711(7) 0.106(3) Uani 1 1 d . U . . .
C132 C 0.4314(18) -0.2490(17) 0.3824(9) 0.107(3) Uani 1 1 d . U . . .
H132 H 0.4279 -0.2996 0.4030 0.129 Uiso 1 1 calc R . . . .
C133 C 0.4615(19) -0.2546(18) 0.3334(9) 0.109(3) Uani 1 1 d . U . . .
C134 C 0.4653(19) -0.1785(17) 0.3061(9) 0.108(3) Uani 1 1 d . U . . .
H134 H 0.4818 -0.1801 0.2738 0.129 Uiso 1 1 calc R . . . .
C135 C 0.4463(18) -0.1020(17) 0.3242(9) 0.107(3) Uani 1 1 d . U . . .
H135 H 0.4523 -0.0512 0.3049 0.128 Uiso 1 1 calc R . . . .
C137 C 0.478(2) -0.3415(19) 0.3133(10) 0.112(3) Uani 1 1 d . U . . .
C211 C 0.1867(14) 0.3388(12) 0.4815(6) 0.138(4) Uani 1 1 d . U . . .
C216 C 0.1744(14) 0.4297(13) 0.4779(6) 0.138(4) Uani 1 1 d G U . . .
H216 H 0.2048 0.4534 0.4524 0.165 Uiso 1 1 calc R . . . .
C215 C 0.1178(14) 0.4858(10) 0.5118(7) 0.138(4) Uani 1 1 d G U . . .
H215 H 0.1094 0.5479 0.5093 0.165 Uiso 1 1 calc R . . . .
C214 C 0.0734(13) 0.4510(12) 0.5491(6) 0.138(4) Uani 1 1 d G U . . .
H214 H 0.0347 0.4894 0.5722 0.165 Uiso 1 1 calc R . . . .
C213 C 0.0857(14) 0.3602(13) 0.5527(6) 0.138(4) Uani 1 1 d G U . . .
H213 H 0.0553 0.3364 0.5782 0.166 Uiso 1 1 calc R . . . .
C212 C 0.1423(15) 0.3041(10) 0.5188(7) 0.138(4) Uani 1 1 d G U . . .
H212 H 0.1507 0.2420 0.5212 0.165 Uiso 1 1 calc R . . . .
C224 C 0.3762(11) 0.4186(11) 0.3280(5) 0.103(3) Uani 1 1 d . U . . .
H224 H 0.3998 0.4520 0.3041 0.124 Uiso 1 1 calc R . . . .
C223 C 0.2834(11) 0.4318(10) 0.3291(5) 0.103(3) Uani 1 1 d G U . . .
H223 H 0.2435 0.4743 0.3058 0.124 Uiso 1 1 calc R . . . .
C222 C 0.2489(9) 0.3828(11) 0.3641(6) 0.103(3) Uani 1 1 d G U . . .
H222 H 0.1855 0.3919 0.3648 0.123 Uiso 1 1 calc R . . . .
C221 C 0.3073(11) 0.3207(11) 0.3981(5) 0.102(3) Uani 1 1 d G U . . .
C226 C 0.4002(11) 0.3075(10) 0.3971(5) 0.103(3) Uani 1 1 d G U . . .
H226 H 0.4401 0.2650 0.4204 0.123 Uiso 1 1 calc R . . . .
C225 C 0.4346(9) 0.3564(11) 0.3620(6) 0.103(3) Uani 1 1 d G U . . .
H225 H 0.4981 0.3474 0.3613 0.123 Uiso 1 1 calc R . . . .
N236 N 0.2378(12) 0.1480(15) 0.3953(8) 0.107(2) Uani 1 1 d . U . . .
C231 C 0.1858(15) 0.2280(19) 0.4178(10) 0.107(2) Uani 1 1 d . U . . .
C232 C 0.0844(15) 0.2804(19) 0.4178(10) 0.108(2) Uani 1 1 d . U . . .
H232 H 0.0509 0.3308 0.4357 0.130 Uiso 1 1 calc R . . . .
C233 C 0.0356(16) 0.2589(19) 0.3924(11) 0.109(2) Uani 1 1 d . U . . .
C234 C 0.0858(15) 0.1773(18) 0.3697(10) 0.108(2) Uani 1 1 d . U . . .
H234 H 0.0540 0.1579 0.3528 0.130 Uiso 1 1 calc R . . . .
C235 C 0.1878(15) 0.1253(19) 0.3735(10) 0.108(2) Uani 1 1 d . U . . .
H235 H 0.2214 0.0701 0.3590 0.129 Uiso 1 1 calc R . . . .
C237 C -0.0644(17) 0.313(2) 0.3934(11) 0.111(2) Uani 1 1 d . U . . .
C311 C 0.7358(8) 0.0426(11) 0.3572(5) 0.087(3) Uani 1 1 d . U . . .
C316 C 0.7186(7) 0.1194(10) 0.3776(5) 0.088(3) Uani 1 1 d G U . . .
H316 H 0.6569 0.1560 0.3916 0.105 Uiso 1 1 calc R . . . .
C315 C 0.7916(9) 0.1428(9) 0.3777(5) 0.088(3) Uani 1 1 d G U . . .
H315 H 0.7798 0.1954 0.3917 0.106 Uiso 1 1 calc R . . . .
C314 C 0.8818(8) 0.0894(10) 0.3574(5) 0.088(3) Uani 1 1 d G U . . .
H314 H 0.9317 0.1054 0.3574 0.106 Uiso 1 1 calc R . . . .
C313 C 0.8991(7) 0.0125(10) 0.3369(5) 0.088(3) Uani 1 1 d G U . . .
H313 H 0.9608 -0.0241 0.3230 0.106 Uiso 1 1 calc R . . . .
C312 C 0.8261(9) -0.0109(9) 0.3368(5) 0.088(3) Uani 1 1 d G U . . .
H312 H 0.8379 -0.0634 0.3229 0.106 Uiso 1 1 calc R . . . .
C321 C 0.6841(14) -0.0924(8) 0.3351(4) 0.105(3) Uani 1 1 d . U . . .
C326 C 0.7239(13) -0.1759(9) 0.3646(3) 0.105(3) Uani 1 1 d G U . . .
H326 H 0.7283 -0.1750 0.3962 0.126 Uiso 1 1 calc R . . . .
C325 C 0.7574(13) -0.2608(8) 0.3479(4) 0.105(3) Uani 1 1 d G U . . .
H325 H 0.7847 -0.3178 0.3680 0.126 Uiso 1 1 calc R . . . .
C324 C 0.7510(13) -0.2621(8) 0.3017(4) 0.105(3) Uani 1 1 d G U . . .
H324 H 0.7739 -0.3201 0.2903 0.126 Uiso 1 1 calc R . . . .
C323 C 0.7111(13) -0.1787(9) 0.2723(3) 0.105(3) Uani 1 1 d G U . . .
H323 H 0.7067 -0.1796 0.2407 0.126 Uiso 1 1 calc R . . . .
C322 C 0.6777(13) -0.0938(8) 0.2890(4) 0.104(3) Uani 1 1 d G U . . .
H322 H 0.6504 -0.0368 0.2688 0.125 Uiso 1 1 calc R . . . .
N336 N 0.4617(11) 0.1173(11) 0.3299(4) 0.064(4) Uani 1 1 d . . . . .
C331 C 0.5530(10) 0.1068(11) 0.3197(4) 0.044(4) Uani 1 1 d . . . . .
C332 C 0.5766(11) 0.1576(11) 0.2861(5) 0.043(4) Uani 1 1 d . . . . .
H332 H 0.6397 0.1508 0.2816 0.052 Uiso 1 1 calc R . . . .
C333 C 0.5080(12) 0.2222(12) 0.2567(5) 0.054(4) Uani 1 1 d . . . . .
C334 C 0.4144(13) 0.2362(14) 0.2673(6) 0.065(5) Uani 1 1 d . . . . .
H334 H 0.3640 0.2841 0.2501 0.078 Uiso 1 1 calc R . . . .
C335 C 0.3985(13) 0.1795(13) 0.3025(6) 0.064(5) Uani 1 1 d . . . . .
H335 H 0.3359 0.1850 0.3080 0.076 Uiso 1 1 calc R . . . .
C337 C 0.5354(12) 0.2813(12) 0.2154(6) 0.056(5) Uani 1 1 d . . . . .
Au4 Au 0.93371(3) -0.02058(3) 0.06612(2) 0.03302(16) Uani 1 1 d . . . . .
Au5 Au 0.86413(3) 0.08810(3) -0.02477(2) 0.03334(17) Uani 1 1 d . . . . .
Au6 Au 0.99590(3) -0.11452(3) -0.02023(2) 0.03280(16) Uani 1 1 d . . . . .
Ag2 Ag 0.80714(7) 0.17887(7) 0.05748(4) 0.0347(3) Uani 1 1 d . . . . .
P4 P 0.8569(3) -0.0246(3) 0.13777(13) 0.0416(9) Uani 1 1 d . . . . .
P5 P 0.7133(2) 0.1838(3) -0.04518(12) 0.0375(9) Uani 1 1 d . . . . .
P6 P 0.9850(3) -0.2287(3) -0.04789(15) 0.0459(10) Uani 1 1 d . . . . .
O41 O 0.5153(7) -0.0097(8) 0.2168(4) 0.0542(17) Uani 1 1 d . U . . .
O42 O 0.4043(7) 0.1311(7) 0.1894(4) 0.0511(17) Uani 1 1 d . U . . .
H42 H 0.3672 0.1175 0.2092 0.077 Uiso 1 1 calc R . . . .
O51 O 0.5680(11) 0.6288(8) -0.0781(5) 0.086(5) Uani 1 1 d . . . . .
O52 O 0.5378(10) 0.5479(10) -0.1225(5) 0.074(4) Uani 1 1 d . . . . .
H52 H 0.5163 0.5088 -0.1153 0.110 Uiso 1 1 calc GR . . . .
O61 O 0.8229(11) 0.4358(12) 0.2260(5) 0.099(3) Uani 1 1 d . U . . .
O62 O 0.9689(11) 0.4036(12) 0.1904(5) 0.099(3) Uani 1 1 d . U . . .
H62 H 0.9700 0.4338 0.2101 0.148 Uiso 1 1 calc R . . . .
C2 C 1.0000 0.0000 0.0000 0.029(4) Uani 1 2 d S T P . .
C411 C 0.8737(18) -0.1378(14) 0.1646(9) 0.097(3) Uani 1 1 d . U . . .
C412 C 0.8442(17) -0.1889(14) 0.1443(9) 0.097(3) Uani 1 1 d . U . . .
H412 H 0.8141 -0.1630 0.1162 0.116 Uiso 1 1 calc R . . . .
C413 C 0.8581(17) -0.2732(14) 0.1640(8) 0.097(3) Uani 1 1 d . U . . .
H413 H 0.8307 -0.3043 0.1521 0.116 Uiso 1 1 calc R . . . .
C414 C 0.9108(17) -0.3166(15) 0.2009(9) 0.097(3) Uani 1 1 d . U . . .
H414 H 0.9292 -0.3810 0.2110 0.117 Uiso 1 1 calc R . . . .
C415 C 0.9372(17) -0.2700(14) 0.2229(9) 0.097(3) Uani 1 1 d . U . . .
H415 H 0.9652 -0.2977 0.2515 0.117 Uiso 1 1 calc R . . . .
C416 C 0.9239(17) -0.1839(14) 0.2046(8) 0.097(3) Uani 1 1 d . U . . .
H416 H 0.9486 -0.1532 0.2187 0.116 Uiso 1 1 calc R . . . .
C421 C 0.8888(11) 0.0295(13) 0.1747(6) 0.0585(19) Uani 1 1 d . U . . .
C422 C 0.9763(11) 0.0253(13) 0.1694(6) 0.0592(19) Uani 1 1 d . U . . .
H422 H 1.0206 -0.0060 0.1453 0.071 Uiso 1 1 calc R . . . .
C423 C 1.0026(11) 0.0639(12) 0.1970(6) 0.0597(19) Uani 1 1 d . U . . .
H423 H 1.0662 0.0554 0.1938 0.072 Uiso 1 1 calc R . . . .
C424 C 0.9398(11) 0.1142(12) 0.2288(6) 0.0593(19) Uani 1 1 d . U . . .
H424 H 0.9590 0.1428 0.2473 0.071 Uiso 1 1 calc R . . . .
C425 C 0.8469(11) 0.1259(12) 0.2356(6) 0.0590(19) Uani 1 1 d . U . . .
H425 H 0.8028 0.1597 0.2591 0.071 Uiso 1 1 calc R . . . .
C426 C 0.8222(11) 0.0854(12) 0.2061(6) 0.0587(19) Uani 1 1 d . U . . .
H426 H 0.7579 0.0964 0.2077 0.070 Uiso 1 1 calc R . . . .
N436 N 0.7031(8) 0.1292(9) 0.1059(4) 0.0449(13) Uani 1 1 d . U . . .
C431 C 0.7278(10) 0.0502(11) 0.1338(5) 0.0450(13) Uani 1 1 d . U . . .
C432 C 0.6625(10) 0.0240(11) 0.1621(5) 0.0455(13) Uani 1 1 d . U . . .
H432 H 0.6830 -0.0335 0.1821 0.055 Uiso 1 1 calc R . . . .
C433 C 0.5641(10) 0.0876(11) 0.1591(5) 0.0465(12) Uani 1 1 d . U . . .
C434 C 0.5407(11) 0.1661(11) 0.1306(5) 0.0459(13) Uani 1 1 d . U . . .
H434 H 0.4751 0.2088 0.1282 0.055 Uiso 1 1 calc R . . . .
C435 C 0.6094(10) 0.1883(11) 0.1039(5) 0.0452(13) Uani 1 1 d . U . . .
H435 H 0.5899 0.2460 0.0840 0.054 Uiso 1 1 calc R . . . .
C437 C 0.4912(11) 0.0630(12) 0.1920(5) 0.0489(13) Uani 1 1 d . U . . .
C511 C 0.6938(9) 0.1944(11) -0.1040(5) 0.051(4) Uani 1 1 d . . . . .
C512 C 0.6104(10) 0.2226(12) -0.1224(5) 0.052(4) Uani 1 1 d . . . . .
H512 H 0.5539 0.2460 -0.1022 0.062 Uiso 1 1 calc R . . . .
C513 C 0.5997(12) 0.2207(13) -0.1673(7) 0.075(6) Uani 1 1 d . . . . .
H513 H 0.5397 0.2351 -0.1769 0.090 Uiso 1 1 calc R . . . .
C514 C 0.6815(12) 0.1964(14) -0.1983(6) 0.080(7) Uani 1 1 d . . . . .
H514 H 0.6763 0.1985 -0.2302 0.096 Uiso 1 1 calc R . . . .
C515 C 0.7675(13) 0.1701(15) -0.1837(6) 0.076(6) Uani 1 1 d . . . . .
H515 H 0.8232 0.1510 -0.2046 0.091 Uiso 1 1 calc R . . . .
C516 C 0.7726(13) 0.1715(13) -0.1383(7) 0.068(5) Uani 1 1 d . . . . .
H516 H 0.8329 0.1563 -0.1288 0.082 Uiso 1 1 calc R . . . .
C521 C 0.6265(11) 0.1497(11) -0.0129(5) 0.048(4) Uani 1 1 d . . . . .
C522 C 0.6588(12) 0.0526(11) 0.0037(6) 0.057(5) Uani 1 1 d . . . . .
H522 H 0.7241 0.0085 0.0000 0.069 Uiso 1 1 calc R . . . .
C523 C 0.5904(15) 0.0258(15) 0.0256(8) 0.078(6) Uani 1 1 d . . . . .
H523 H 0.6094 -0.0389 0.0353 0.094 Uiso 1 1 calc R . . . .
C524 C 0.4992(14) 0.0864(15) 0.0337(9) 0.080(7) Uani 1 1 d . . . . .
H524 H 0.4559 0.0646 0.0503 0.097 Uiso 1 1 calc R . . . .
C525 C 0.4684(12) 0.1757(17) 0.0191(6) 0.068(6) Uani 1 1 d . . . . .
H525 H 0.4022 0.2168 0.0234 0.082 Uiso 1 1 calc R . . . .
C526 C 0.5289(9) 0.2113(11) -0.0023(5) 0.048(4) Uani 1 1 d . . . . .
H526 H 0.5058 0.2770 -0.0101 0.057 Uiso 1 1 calc R . . . .
N536 N 0.6963(8) 0.3073(9) 0.0077(4) 0.048(3) Uani 1 1 d . . . . .
C531 C 0.6732(9) 0.3038(11) -0.0332(4) 0.042(4) Uani 1 1 d . . . . .
C532 C 0.6320(9) 0.3825(9) -0.0641(4) 0.033(3) Uani 1 1 d . . . . .
H532 H 0.6203 0.3781 -0.0938 0.040 Uiso 1 1 calc R . . . .
C533 C 0.6082(9) 0.4668(12) -0.0517(5) 0.050(4) Uani 1 1 d . . . . .
C534 C 0.6320(10) 0.4738(10) -0.0106(5) 0.042(3) Uani 1 1 d . . . . .
H534 H 0.6201 0.5323 -0.0030 0.051 Uiso 1 1 calc R . . . .
C535 C 0.6746(10) 0.3906(9) 0.0196(5) 0.043(4) Uani 1 1 d . . . . .
H535 H 0.6885 0.3934 0.0492 0.051 Uiso 1 1 calc R . . . .
C537 C 0.5646(12) 0.5581(13) -0.0872(6) 0.062(5) Uani 1 1 d . . . . .
C611 C 0.9940(16) -0.3261(14) -0.0063(8) 0.078(2) Uani 1 1 d . U . . .
C612 C 1.0821(16) -0.4106(13) -0.0087(8) 0.079(2) Uani 1 1 d . U . . .
H612 H 1.1312 -0.4161 -0.0327 0.094 Uiso 1 1 calc R . . . .
C613 C 1.0914(16) -0.4843(14) 0.0264(7) 0.079(2) Uani 1 1 d . U . . .
H613 H 1.1500 -0.5403 0.0269 0.095 Uiso 1 1 calc R . . . .
C614 C 1.0230(16) -0.4798(14) 0.0586(8) 0.079(2) Uani 1 1 d . U . . .
H614 H 1.0336 -0.5312 0.0822 0.095 Uiso 1 1 calc R . . . .
C615 C 0.9333(16) -0.3987(13) 0.0586(7) 0.079(2) Uani 1 1 d . U . . .
H615 H 0.8827 -0.3982 0.0806 0.095 Uiso 1 1 calc R . . . .
C616 C 0.9191(16) -0.3199(14) 0.0266(7) 0.079(2) Uani 1 1 d . U . . .
H616 H 0.8604 -0.2642 0.0271 0.094 Uiso 1 1 calc R . . . .
C626 C 0.8255(9) -0.2326(8) -0.0743(5) 0.087(3) Uani 1 1 d . U . . .
H626 H 0.8502 -0.2954 -0.0596 0.105 Uiso 1 1 calc R . . . .
C621 C 0.8726(7) -0.1801(10) -0.0734(5) 0.087(3) Uani 1 1 d G U . . .
C622 C 0.8365(9) -0.0882(10) -0.0948(5) 0.087(3) Uani 1 1 d G U . . .
H622 H 0.8687 -0.0523 -0.0942 0.104 Uiso 1 1 calc R . . . .
C623 C 0.7532(9) -0.0487(8) -0.1172(5) 0.088(3) Uani 1 1 d G U . . .
H623 H 0.7285 0.0142 -0.1318 0.105 Uiso 1 1 calc R . . . .
C625 C 0.7060(7) -0.1011(10) -0.1180(5) 0.088(3) Uani 1 1 d G U . . .
H625 H 0.6491 -0.0741 -0.1333 0.105 Uiso 1 1 calc R . . . .
C624 C 0.7422(8) -0.1931(10) -0.0966(5) 0.087(3) Uani 1 1 d G U . . .
H624 H 0.7100 -0.2289 -0.0972 0.105 Uiso 1 1 calc R . . . .
C631 C 0.9274(10) 0.2742(10) 0.0969(5) 0.043(3) Uani 1 1 d . . . . .
N636 N 0.8485(12) 0.2584(13) 0.1013(6) 0.086(2) Uani 1 1 d . U . . .
C632 C 0.9392(16) 0.3189(17) 0.1262(8) 0.091(2) Uani 1 1 d . U . . .
H632 H 0.9941 0.3289 0.1216 0.109 Uiso 1 1 calc R . . . .
C633 C 0.8744(16) 0.3509(18) 0.1627(8) 0.091(2) Uani 1 1 d . U . . .
C634 C 0.7906(16) 0.3385(17) 0.1683(8) 0.089(2) Uani 1 1 d . U . . .
H634 H 0.7428 0.3632 0.1926 0.107 Uiso 1 1 calc R . . . .
C635 C 0.7802(15) 0.2905(16) 0.1381(7) 0.088(2) Uani 1 1 d . U . . .
H635 H 0.7262 0.2790 0.1424 0.105 Uiso 1 1 calc R . . . .
C637 C 0.8898(17) 0.3996(18) 0.1964(8) 0.094(2) Uani 1 1 d . U . . .
F11 F 0.998(2) 0.542(2) 0.6572(8) 0.281(15) Uiso 1 1 d D . . . .
F12 F 0.892(2) 0.6279(17) 0.7107(13) 0.36(2) Uiso 1 1 d D . . . .
F13 F 1.036(2) 0.520(2) 0.7296(10) 0.303(16) Uiso 1 1 d D . . . .
F14 F 0.9301(15) 0.4764(15) 0.7140(8) 0.201(9) Uiso 1 1 d D . . . .
B1 B 0.9647(19) 0.5411(19) 0.7030(10) 0.31(4) Uiso 1 1 d D . . . .
F21 F 0.8637(8) 0.0971(9) 0.7153(5) 0.106(4) Uiso 1 1 d D . . . .
F22 F 0.7569(10) 0.0889(11) 0.6774(5) 0.149(6) Uiso 1 1 d D . . . .
F23 F 0.8967(8) -0.0345(9) 0.6897(5) 0.113(4) Uiso 1 1 d D . . . .
F24 F 0.7844(9) 0.0170(9) 0.7493(4) 0.115(4) Uiso 1 1 d D . . . .
B2 B 0.8235(13) 0.0427(13) 0.7077(6) 0.098(8) Uiso 1 1 d D . . . .
F31 F 0.672(2) 0.6174(19) 0.1219(8) 0.312(17) Uiso 1 1 d D . . . .
F32 F 0.7008(13) 0.6394(12) 0.0441(7) 0.180(8) Uiso 1 1 d D . . . .
F33 F 0.5837(11) 0.6003(14) 0.0783(8) 0.195(9) Uiso 1 1 d D . . . .
F34 F 0.7312(9) 0.4989(9) 0.0790(5) 0.110(4) Uiso 1 1 d D . . . .
B3 B 0.6719(16) 0.5914(15) 0.0808(8) 0.175(19) Uiso 1 1 d D . . . .
F41 F 0.514(2) 0.3831(19) 0.8353(10) 0.300 Uiso 1 1 d D . . . .
F42 F 0.496(2) 0.479(2) 0.7679(9) 0.300 Uiso 1 1 d D . . . .
F43 F 0.416(2) 0.5313(19) 0.8360(10) 0.300 Uiso 1 1 d D . . . .
F44 F 0.3778(19) 0.448(2) 0.7996(11) 0.300 Uiso 1 1 d D . . . .
B4 B 0.4509(19) 0.462(2) 0.8093(9) 0.300 Uiso 1 1 d D . . . .
O4S O 0.3093(12) 0.2002(13) 0.9162(7) 0.115(6) Uiso 1 1 d . . . . .
C4S C 0.393(3) 0.163(3) 0.8812(16) 0.184(16) Uiso 1 1 d . . . . .
O5S O 0.2764(10) 0.1088(10) 0.2446(5) 0.086(4) Uiso 1 1 d . . . . .
C5S C 0.172(2) 0.203(3) 0.2350(13) 0.152(12) Uiso 1 1 d . . . . .
O1S O 0.8864(17) 0.3053(18) -0.0938(9) 0.175(9) Uiso 1 1 d . . . . .
O2S O -0.364(3) 0.382(4) 0.3145(18) 0.35(2) Uiso 1 1 d . . . . .
O3S O 0.712(4) 0.400(4) 0.7896(18) 0.36(2) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Au2 2.9870(9) . ?
Au1 Au2 2.9650(9) 2_656 ?
Au1 Au3 2.9913(10) 2_656 ?
Au1 Au3 2.9520(8) . ?
Au1 Ag1 2.8776(14) 2_656 ?
Au1 P1 2.248(5) . ?
Au1 C1 2.0908(6) . ?
Au2 Au1 2.9649(9) 2_656 ?
Au2 Au3 3.0297(9) 2_656 ?
Au2 Au3 2.9514(10) . ?
Au2 Ag1 2.9076(12) . ?
Au2 P2 2.263(5) . ?
Au2 C1 2.1178(7) . ?
Au3 Au1 2.9913(10) 2_656 ?
Au3 Au2 3.0298(9) 2_656 ?
Au3 Ag1 2.8918(13) . ?
Au3 P3 2.271(4) . ?
Au3 C1 2.1118(6) . ?
Ag1 Au1 2.8775(14) 2_656 ?
Ag1 N136 2.366(19) . ?
Ag1 N236 2.318(18) . ?
Ag1 N336 2.403(14) . ?
P1 C111 1.834(16) . ?
P1 C121 1.740(18) . ?
P1 C131 1.80(3) 2_656 ?
P2 C211 1.760(13) . ?
P2 C221 1.832(12) . ?
P2 C231 1.79(2) . ?
P3 C311 1.819(10) . ?
P3 C321 1.774(10) . ?
P3 C331 1.874(15) . ?
O11 C137 1.28(3) . ?
O12 H12 0.8400 . ?
O12 C137 1.33(3) . ?
O21 H21 0.8400 . ?
O21 C237 1.34(3) . ?
O22 C237 1.17(3) . ?
O31 H31 0.8400 . ?
O31 C337 1.247(18) . ?
O32 C337 1.17(2) . ?
C1 Au1 2.0908(6) 2_656 ?
C1 Au2 2.1179(7) 2_656 ?
C1 Au3 2.1118(6) 2_656 ?
C112 H112 0.9500 . ?
C112 C111 1.3900 . ?
C112 C113 1.3900 . ?
C111 C116 1.3900 . ?
C116 H116 0.9500 . ?
C116 C115 1.3900 . ?
C115 H115 0.9500 . ?
C115 C114 1.3900 . ?
C114 H114 0.9500 . ?
C114 C113 1.3900 . ?
C113 H113 0.9500 . ?
C121 C122 1.3900 . ?
C121 C126 1.3900 . ?
C122 H122 0.9500 . ?
C122 C123 1.3900 . ?
C123 H123 0.9500 . ?
C123 C124 1.3900 . ?
C124 H124 0.9500 . ?
C124 C125 1.3900 . ?
C125 H125 0.9500 . ?
C125 C126 1.3900 . ?
C126 H126 0.9500 . ?
C131 P1 1.80(3) 2_656 ?
C131 N136 1.29(3) . ?
C131 C132 1.37(3) . ?
N136 C135 1.39(3) . ?
C132 H132 0.9500 . ?
C132 C133 1.46(4) . ?
C133 C134 1.37(4) . ?
C133 C137 1.54(3) . ?
C134 H134 0.9500 . ?
C134 C135 1.34(3) . ?
C135 H135 0.9500 . ?
C211 C216 1.3900 . ?
C211 C212 1.3900 . ?
C216 H216 0.9500 . ?
C216 C215 1.3900 . ?
C215 H215 0.9500 . ?
C215 C214 1.3900 . ?
C214 H214 0.9500 . ?
C214 C213 1.3900 . ?
C213 H213 0.9500 . ?
C213 C212 1.3900 . ?
C212 H212 0.9500 . ?
C224 H224 0.9500 . ?
C224 C223 1.3900 . ?
C224 C225 1.3900 . ?
C223 H223 0.9500 . ?
C223 C222 1.3900 . ?
C222 H222 0.9500 . ?
C222 C221 1.3900 . ?
C221 C226 1.3900 . ?
C226 H226 0.9500 . ?
C226 C225 1.3900 . ?
C225 H225 0.9500 . ?
N236 C231 1.40(3) . ?
N236 C235 1.32(3) . ?
C231 C232 1.43(3) . ?
C232 H232 0.9500 . ?
C232 C233 1.36(3) . ?
C233 C234 1.42(3) . ?
C233 C237 1.41(3) . ?
C234 H234 0.9500 . ?
C234 C235 1.45(3) . ?
C235 H235 0.9500 . ?
C311 C316 1.3900 . ?
C311 C312 1.3900 . ?
C316 H316 0.9500 . ?
C316 C315 1.3900 . ?
C315 H315 0.9500 . ?
C315 C314 1.3900 . ?
C314 H314 0.9500 . ?
C314 C313 1.3900 . ?
C313 H313 0.9500 . ?
C313 C312 1.3900 . ?
C312 H312 0.9500 . ?
C321 C326 1.3900 . ?
C321 C322 1.3900 . ?
C326 H326 0.9500 . ?
C326 C325 1.3900 . ?
C325 H325 0.9500 . ?
C325 C324 1.3900 . ?
C324 H324 0.9500 . ?
C324 C323 1.3900 . ?
C323 H323 0.9500 . ?
C323 C322 1.3900 . ?
C322 H322 0.9500 . ?
N336 C331 1.37(2) . ?
N336 C335 1.30(2) . ?
C331 C332 1.29(2) . ?
C332 H332 0.9500 . ?
C332 C333 1.39(2) . ?
C333 C334 1.39(2) . ?
C333 C337 1.55(3) . ?
C334 H334 0.9500 . ?
C334 C335 1.33(2) . ?
C335 H335 0.9500 . ?
Au4 Au5 3.0001(7) 2_755 ?
Au4 Au5 2.9812(7) . ?
Au4 Au6 3.0149(7) . ?
Au4 Au6 2.9502(8) 2_755 ?
Au4 Ag2 2.9004(10) . ?
Au4 P4 2.274(4) . ?
Au4 C2 2.1129(5) . ?
Au5 Au4 3.0001(7) 2_755 ?
Au5 Au6 3.0102(7) 2_755 ?
Au5 Au6 2.9601(7) . ?
Au5 Ag2 2.8850(11) . ?
Au5 P5 2.273(3) . ?
Au5 C2 2.1165(5) . ?
Au6 Au4 2.9502(8) 2_755 ?
Au6 Au5 3.0103(7) 2_755 ?
Au6 Ag2 2.8990(11) 2_755 ?
Au6 P6 2.265(4) . ?
Au6 C2 2.1053(5) . ?
Ag2 Au6 2.8989(11) 2_755 ?
Ag2 N436 2.352(13) . ?
Ag2 N536 2.421(12) . ?
Ag2 N636 2.354(15) . ?
P4 C411 1.78(2) . ?
P4 C421 1.791(17) . ?
P4 C431 1.845(15) . ?
P5 C511 1.777(15) . ?
P5 C521 1.800(18) . ?
P5 C531 1.842(17) . ?
P6 C611 1.78(2) . ?
P6 C621 1.813(10) . ?
P6 C631 1.838(15) 2_755 ?
O41 C437 1.195(18) . ?
O42 H42 0.8400 . ?
O42 C437 1.309(18) . ?
O51 C537 1.26(2) . ?
O52 H52 0.8400 . ?
O52 C537 1.26(2) . ?
O61 C637 1.25(2) . ?
O62 H62 0.8400 . ?
O62 C637 1.28(3) . ?
C2 Au4 2.1129(5) 2_755 ?
C2 Au5 2.1165(5) 2_755 ?
C2 Au6 2.1053(5) 2_755 ?
C411 C412 1.39(4) . ?
C411 C416 1.42(3) . ?
C412 H412 0.9500 . ?
C412 C413 1.32(3) . ?
C413 H413 0.9500 . ?
C413 C414 1.36(3) . ?
C414 H414 0.9500 . ?
C414 C415 1.33(3) . ?
C415 H415 0.9500 . ?
C415 C416 1.34(3) . ?
C416 H416 0.9500 . ?
C421 C422 1.35(2) . ?
C421 C426 1.38(2) . ?
C422 H422 0.9500 . ?
C422 C423 1.34(2) . ?
C423 H423 0.9500 . ?
C423 C424 1.33(2) . ?
C424 H424 0.9500 . ?
C424 C425 1.39(2) . ?
C425 H425 0.9500 . ?
C425 C426 1.39(2) . ?
C426 H426 0.9500 . ?
N436 C431 1.312(19) . ?
N436 C435 1.348(18) . ?
C431 C432 1.40(2) . ?
C432 H432 0.9500 . ?
C432 C433 1.42(2) . ?
C433 C434 1.32(2) . ?
C433 C437 1.54(2) . ?
C434 H434 0.9500 . ?
C434 C435 1.40(2) . ?
C435 H435 0.9500 . ?
C511 C512 1.36(2) . ?
C511 C516 1.43(2) . ?
C512 H512 0.9500 . ?
C512 C513 1.37(2) . ?
C513 H513 0.9500 . ?
C513 C514 1.40(2) . ?
C514 H514 0.9500 . ?
C514 C515 1.35(3) . ?
C515 H515 0.9500 . ?
C515 C516 1.36(2) . ?
C516 H516 0.9500 . ?
C521 C522 1.43(2) . ?
C521 C526 1.42(2) . ?
C522 H522 0.9500 . ?
C522 C523 1.39(3) . ?
C523 H523 0.9500 . ?
C523 C524 1.33(3) . ?
C524 H524 0.9500 . ?
C524 C525 1.31(3) . ?
C525 H525 0.9500 . ?
C525 C526 1.37(2) . ?
C526 H526 0.9500 . ?
N536 C531 1.339(18) . ?
N536 C535 1.342(19) . ?
C531 C532 1.366(19) . ?
C532 H532 0.9500 . ?
C532 C533 1.35(2) . ?
C533 C534 1.37(2) . ?
C533 C537 1.57(2) . ?
C534 H534 0.9500 . ?
C534 C535 1.405(19) . ?
C535 H535 0.9500 . ?
C611 C612 1.44(3) . ?
C611 C616 1.39(3) . ?
C612 H612 0.9500 . ?
C612 C613 1.40(3) . ?
C613 H613 0.9500 . ?
C613 C614 1.31(3) . ?
C614 H614 0.9500 . ?
C614 C615 1.42(3) . ?
C615 H615 0.9500 . ?
C615 C616 1.39(3) . ?
C616 H616 0.9500 . ?
C626 H626 0.9500 . ?
C626 C621 1.3900 . ?
C626 C624 1.3900 . ?
C621 C622 1.3900 . ?
C622 H622 0.9500 . ?
C622 C623 1.3900 . ?
C623 H623 0.9500 . ?
C623 C625 1.3900 . ?
C625 H625 0.9500 . ?
C625 C624 1.3900 . ?
C624 H624 0.9500 . ?
C631 P6 1.838(15) 2_755 ?
C631 N636 1.38(2) . ?
C631 C632 1.32(2) . ?
N636 C635 1.39(2) . ?
C632 H632 0.9500 . ?
C632 C633 1.36(3) . ?
C633 C634 1.43(3) . ?
C633 C637 1.50(3) . ?
C634 H634 0.9500 . ?
C634 C635 1.37(3) . ?
C635 H635 0.9500 . ?
F11 B1 1.372(18) . ?
F12 B1 1.375(18) . ?
F13 B1 1.366(18) . ?
F14 B1 1.377(18) . ?
F21 B2 1.386(16) . ?
F22 B2 1.340(16) . ?
F23 B2 1.379(16) . ?
F24 B2 1.370(16) . ?
F31 B3 1.360(17) . ?
F32 B3 1.365(17) . ?
F33 B3 1.359(18) . ?
F34 B3 1.359(18) . ?
F41 B4 1.389(18) . ?
F42 B4 1.366(18) . ?
F43 B4 1.348(18) . ?
F44 B4 1.371(18) . ?
O4S C4S 1.50(4) . ?
O5S C5S 1.67(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au2 Au1 Au2 90.74(3) 2_656 . ?
Au2 Au1 Au3 59.40(2) 2_656 2_656 ?
Au2 Au1 Au3 60.90(2) . 2_656 ?
Au3 Au1 Au2 59.59(2) . . ?
Au3 Au1 Au2 61.60(2) . 2_656 ?
Au3 Au1 Au3 90.57(2) . 2_656 ?
Ag1 Au1 Au2 59.67(3) 2_656 2_656 ?
Ag1 Au1 Au2 119.90(4) 2_656 . ?
Ag1 Au1 Au3 59.01(3) 2_656 2_656 ?
Ag1 Au1 Au3 121.26(3) 2_656 . ?
P1 Au1 Au2 130.71(19) . 2_656 ?
P1 Au1 Au2 138.47(19) . . ?
P1 Au1 Au3 132.75(15) . 2_656 ?
P1 Au1 Au3 136.45(15) . . ?
P1 Au1 Ag1 86.01(15) . 2_656 ?
C1 Au1 Au2 45.585(18) . 2_656 ?
C1 Au1 Au2 45.154(18) . . ?
C1 Au1 Au3 44.904(17) . 2_656 ?
C1 Au1 Au3 45.669(17) . . ?
C1 Au1 Ag1 89.89(3) . 2_656 ?
C1 Au1 P1 175.76(17) . . ?
Au1 Au2 Au1 89.26(3) 2_656 . ?
Au1 Au2 Au3 58.99(2) 2_656 2_656 ?
Au1 Au2 Au3 59.62(2) . 2_656 ?
Au3 Au2 Au1 60.74(2) . 2_656 ?
Au3 Au2 Au1 59.61(2) . . ?
Au3 Au2 Au3 89.84(2) . 2_656 ?
Ag1 Au2 Au1 58.67(3) . 2_656 ?
Ag1 Au2 Au1 118.70(4) . . ?
Ag1 Au2 Au3 117.65(3) . 2_656 ?
Ag1 Au2 Au3 59.15(3) . . ?
P2 Au2 Au1 133.33(13) . 2_656 ?
P2 Au2 Au1 136.95(13) . . ?
P2 Au2 Au3 140.89(14) . 2_656 ?
P2 Au2 Au3 129.22(14) . . ?
P2 Au2 Ag1 86.72(12) . . ?
C1 Au2 Au1 44.422(18) . . ?
C1 Au2 Au1 44.841(18) . 2_656 ?
C1 Au2 Au3 45.667(18) . . ?
C1 Au2 Au3 44.169(17) . 2_656 ?
C1 Au2 Ag1 88.55(3) . . ?
C1 Au2 P2 174.64(13) . . ?
Au1 Au3 Au1 89.43(2) . 2_656 ?
Au1 Au3 Au2 59.41(2) . 2_656 ?
Au1 Au3 Au2 59.48(2) 2_656 2_656 ?
Au2 Au3 Au1 60.79(2) . . ?
Au2 Au3 Au1 59.85(2) . 2_656 ?
Au2 Au3 Au2 90.16(2) . 2_656 ?
Ag1 Au3 Au1 58.53(3) . 2_656 ?
Ag1 Au3 Au1 120.40(3) . . ?
Ag1 Au3 Au2 118.01(4) . 2_656 ?
Ag1 Au3 Au2 59.67(3) . . ?
P3 Au3 Au1 134.73(12) . 2_656 ?
P3 Au3 Au1 135.71(12) . . ?
P3 Au3 Au2 138.48(12) . 2_656 ?
P3 Au3 Au2 131.34(12) . . ?
P3 Au3 Ag1 88.36(11) . . ?
C1 Au3 Au1 45.087(17) . . ?
C1 Au3 Au1 44.339(17) . 2_656 ?
C1 Au3 Au2 45.834(18) . . ?
C1 Au3 Au2 44.329(18) . 2_656 ?
C1 Au3 Ag1 89.08(3) . . ?
C1 Au3 P3 177.06(12) . . ?
Au1 Ag1 Au2 61.66(3) 2_656 . ?
Au1 Ag1 Au3 62.46(3) 2_656 . ?
Au3 Ag1 Au2 61.18(3) . . ?
N136 Ag1 Au1 80.7(5) . 2_656 ?
N136 Ag1 Au2 141.7(6) . . ?
N136 Ag1 Au3 108.7(5) . . ?
N136 Ag1 N336 106.5(7) . . ?
N236 Ag1 Au1 110.5(6) . 2_656 ?
N236 Ag1 Au2 81.2(5) . . ?
N236 Ag1 Au3 140.8(5) . . ?
N236 Ag1 N136 107.7(7) . . ?
N236 Ag1 N336 100.6(7) . . ?
N336 Ag1 Au1 144.3(3) . 2_656 ?
N336 Ag1 Au2 108.2(4) . . ?
N336 Ag1 Au3 82.4(3) . . ?
C111 P1 Au1 110.8(7) . . ?
C121 P1 Au1 112.8(9) . . ?
C121 P1 C111 111.2(13) . . ?
C121 P1 C131 107.3(12) . 2_656 ?
C131 P1 Au1 110.5(10) 2_656 . ?
C131 P1 C111 103.7(10) 2_656 . ?
C211 P2 Au2 115.8(7) . . ?
C211 P2 C221 104.4(10) . . ?
C211 P2 C231 107.1(11) . . ?
C221 P2 Au2 110.8(6) . . ?
C231 P2 Au2 111.2(9) . . ?
C231 P2 C221 107.0(12) . . ?
C311 P3 Au3 111.9(5) . . ?
C311 P3 C331 104.9(7) . . ?
C321 P3 Au3 113.2(5) . . ?
C321 P3 C311 107.9(8) . . ?
C321 P3 C331 106.1(7) . . ?
C331 P3 Au3 112.2(5) . . ?
C137 O12 H12 109.5 . . ?
C237 O21 H21 109.5 . . ?
C337 O31 H31 109.5 . . ?
Au1 C1 Au1 180.0 . 2_656 ?
Au1 C1 Au2 90.43(3) 2_656 2_656 ?
Au1 C1 Au2 89.58(3) 2_656 . ?
Au1 C1 Au2 90.42(3) . . ?
Au1 C1 Au2 89.58(3) . 2_656 ?
Au1 C1 Au3 90.76(2) . 2_656 ?
Au1 C1 Au3 90.76(2) 2_656 . ?
Au1 C1 Au3 89.24(2) 2_656 2_656 ?
Au1 C1 Au3 89.24(2) . . ?
Au2 C1 Au2 180.0 . 2_656 ?
Au3 C1 Au2 88.50(3) 2_656 2_656 ?
Au3 C1 Au2 91.50(3) 2_656 . ?
Au3 C1 Au2 88.50(3) . . ?
Au3 C1 Au2 91.50(3) . 2_656 ?
Au3 C1 Au3 180.0 2_656 . ?
C111 C112 H112 120.0 . . ?
C111 C112 C113 120.0 . . ?
C113 C112 H112 120.0 . . ?
C112 C111 P1 119.9(12) . . ?
C112 C111 C116 120.0 . . ?
C116 C111 P1 119.8(12) . . ?
C111 C116 H116 120.0 . . ?
C115 C116 C111 120.0 . . ?
C115 C116 H116 120.0 . . ?
C116 C115 H115 120.0 . . ?
C114 C115 C116 120.0 . . ?
C114 C115 H115 120.0 . . ?
C115 C114 H114 120.0 . . ?
C115 C114 C113 120.0 . . ?
C113 C114 H114 120.0 . . ?
C112 C113 H113 120.0 . . ?
C114 C113 C112 120.0 . . ?
C114 C113 H113 120.0 . . ?
C122 C121 P1 120.4(19) . . ?
C122 C121 C126 120.0 . . ?
C126 C121 P1 118.7(19) . . ?
C121 C122 H122 120.0 . . ?
C123 C122 C121 120.0 . . ?
C123 C122 H122 120.0 . . ?
C122 C123 H123 120.0 . . ?
C122 C123 C124 120.0 . . ?
C124 C123 H123 120.0 . . ?
C123 C124 H124 120.0 . . ?
C123 C124 C125 120.0 . . ?
C125 C124 H124 120.0 . . ?
C124 C125 H125 120.0 . . ?
C126 C125 C124 120.0 . . ?
C126 C125 H125 120.0 . . ?
C121 C126 H126 120.0 . . ?
C125 C126 C121 120.0 . . ?
C125 C126 H126 120.0 . . ?
N136 C131 P1 114.9(17) . 2_656 ?
N136 C131 C132 126(3) . . ?
C132 C131 P1 119(2) . 2_656 ?
C131 N136 Ag1 128.3(16) . . ?
C131 N136 C135 118(2) . . ?
C135 N136 Ag1 113.1(18) . . ?
C131 C132 H132 122.4 . . ?
C131 C132 C133 115(3) . . ?
C133 C132 H132 122.4 . . ?
C132 C133 C137 119(3) . . ?
C134 C133 C132 119(2) . . ?
C134 C133 C137 122(2) . . ?
C133 C134 H134 119.4 . . ?
C135 C134 C133 121(3) . . ?
C135 C134 H134 119.4 . . ?
N136 C135 H135 119.7 . . ?
C134 C135 N136 121(3) . . ?
C134 C135 H135 119.7 . . ?
O11 C137 O12 128(2) . . ?
O11 C137 C133 115(3) . . ?
O12 C137 C133 117(2) . . ?
C216 C211 P2 126.1(12) . . ?
C216 C211 C212 120.0 . . ?
C212 C211 P2 113.8(12) . . ?
C211 C216 H216 120.0 . . ?
C215 C216 C211 120.0 . . ?
C215 C216 H216 120.0 . . ?
C216 C215 H215 120.0 . . ?
C216 C215 C214 120.0 . . ?
C214 C215 H215 120.0 . . ?
C215 C214 H214 120.0 . . ?
C213 C214 C215 120.0 . . ?
C213 C214 H214 120.0 . . ?
C214 C213 H213 120.0 . . ?
C214 C213 C212 120.0 . . ?
C212 C213 H213 120.0 . . ?
C211 C212 H212 120.0 . . ?
C213 C212 C211 120.0 . . ?
C213 C212 H212 120.0 . . ?
C223 C224 H224 120.0 . . ?
C223 C224 C225 120.0 . . ?
C225 C224 H224 120.0 . . ?
C224 C223 H223 120.0 . . ?
C224 C223 C222 120.0 . . ?
C222 C223 H223 120.0 . . ?
C223 C222 H222 120.0 . . ?
C221 C222 C223 120.0 . . ?
C221 C222 H222 120.0 . . ?
C222 C221 P2 119.4(9) . . ?
C222 C221 C226 120.0 . . ?
C226 C221 P2 120.6(9) . . ?
C221 C226 H226 120.0 . . ?
C221 C226 C225 120.0 . . ?
C225 C226 H226 120.0 . . ?
C224 C225 H225 120.0 . . ?
C226 C225 C224 120.0 . . ?
C226 C225 H225 120.0 . . ?
C231 N236 Ag1 130.0(14) . . ?
C235 N236 Ag1 114.0(15) . . ?
C235 N236 C231 115.9(19) . . ?
N236 C231 P2 112.3(15) . . ?
N236 C231 C232 122(2) . . ?
C232 C231 P2 125.6(17) . . ?
C231 C232 H232 119.7 . . ?
C233 C232 C231 121(2) . . ?
C233 C232 H232 119.7 . . ?
C232 C233 C234 119(2) . . ?
C232 C233 C237 119(2) . . ?
C237 C233 C234 122(2) . . ?
C233 C234 H234 121.5 . . ?
C233 C234 C235 117(2) . . ?
C235 C234 H234 121.5 . . ?
N236 C235 C234 126(2) . . ?
N236 C235 H235 117.2 . . ?
C234 C235 H235 117.2 . . ?
O21 C237 C233 112(2) . . ?
O22 C237 O21 123(2) . . ?
O22 C237 C233 125(2) . . ?
C316 C311 P3 118.1(8) . . ?
C316 C311 C312 120.0 . . ?
C312 C311 P3 121.8(8) . . ?
C311 C316 H316 120.0 . . ?
C315 C316 C311 120.0 . . ?
C315 C316 H316 120.0 . . ?
C316 C315 H315 120.0 . . ?
C314 C315 C316 120.0 . . ?
C314 C315 H315 120.0 . . ?
C315 C314 H314 120.0 . . ?
C315 C314 C313 120.0 . . ?
C313 C314 H314 120.0 . . ?
C314 C313 H313 120.0 . . ?
C314 C313 C312 120.0 . . ?
C312 C313 H313 120.0 . . ?
C311 C312 H312 120.0 . . ?
C313 C312 C311 120.0 . . ?
C313 C312 H312 120.0 . . ?
C326 C321 P3 116.9(7) . . ?
C326 C321 C322 120.0 . . ?
C322 C321 P3 123.1(7) . . ?
C321 C326 H326 120.0 . . ?
C321 C326 C325 120.0 . . ?
C325 C326 H326 120.0 . . ?
C326 C325 H325 120.0 . . ?
C324 C325 C326 120.0 . . ?
C324 C325 H325 120.0 . . ?
C325 C324 H324 120.0 . . ?
C325 C324 C323 120.0 . . ?
C323 C324 H324 120.0 . . ?
C324 C323 H323 120.0 . . ?
C322 C323 C324 120.0 . . ?
C322 C323 H323 120.0 . . ?
C321 C322 H322 120.0 . . ?
C323 C322 C321 120.0 . . ?
C323 C322 H322 120.0 . . ?
C331 N336 Ag1 129.2(10) . . ?
C335 N336 Ag1 114.3(13) . . ?
C335 N336 C331 116.4(15) . . ?
N336 C331 P3 112.8(11) . . ?
C332 C331 P3 123.7(12) . . ?
C332 C331 N336 123.5(14) . . ?
C331 C332 H332 120.6 . . ?
C331 C332 C333 118.8(15) . . ?
C333 C332 H332 120.6 . . ?
C332 C333 C334 118.5(16) . . ?
C332 C333 C337 119.8(15) . . ?
C334 C333 C337 121.6(15) . . ?
C333 C334 H334 121.4 . . ?
C335 C334 C333 117.1(17) . . ?
C335 C334 H334 121.4 . . ?
N336 C335 C334 125.3(18) . . ?
N336 C335 H335 117.4 . . ?
C334 C335 H335 117.4 . . ?
O31 C337 C333 113.2(16) . . ?
O32 C337 O31 127.0(19) . . ?
O32 C337 C333 119.8(15) . . ?
Au5 Au4 Au5 90.10(2) . 2_755 ?
Au5 Au4 Au6 59.161(17) . . ?
Au5 Au4 Au6 60.062(16) 2_755 . ?
Au6 Au4 Au5 59.657(18) 2_755 2_755 ?
Au6 Au4 Au5 60.993(18) 2_755 . ?
Au6 Au4 Au6 89.79(2) 2_755 . ?
Ag2 Au4 Au5 119.02(3) . 2_755 ?
Ag2 Au4 Au5 58.73(2) . . ?
Ag2 Au4 Au6 59.40(3) . 2_755 ?
Ag2 Au4 Au6 117.88(3) . . ?
P4 Au4 Au5 131.94(9) . . ?
P4 Au4 Au5 137.27(9) . 2_755 ?
P4 Au4 Au6 128.14(11) . 2_755 ?
P4 Au4 Au6 141.95(11) . . ?
P4 Au4 Ag2 85.00(9) . . ?
C2 Au4 Au5 45.229(14) . . ?
C2 Au4 Au5 44.868(14) . 2_755 ?
C2 Au4 Au6 44.277(14) . . ?
C2 Au4 Au6 45.516(15) . 2_755 ?
C2 Au4 Ag2 88.75(3) . . ?
C2 Au4 P4 173.18(10) . . ?
Au4 Au5 Au4 89.90(2) . 2_755 ?
Au4 Au5 Au6 60.214(17) 2_755 2_755 ?
Au4 Au5 Au6 58.995(18) . 2_755 ?
Au6 Au5 Au4 60.987(17) . . ?
Au6 Au5 Au4 59.334(18) . 2_755 ?
Au6 Au5 Au6 89.696(19) . 2_755 ?
Ag2 Au5 Au4 59.24(2) . . ?
Ag2 Au5 Au4 119.08(3) . 2_755 ?
Ag2 Au5 Au6 120.22(3) . . ?
Ag2 Au5 Au6 58.86(2) . 2_755 ?
P5 Au5 Au4 139.72(10) . 2_755 ?
P5 Au5 Au4 130.34(10) . . ?
P5 Au5 Au6 136.05(10) . . ?
P5 Au5 Au6 133.90(10) . 2_755 ?
P5 Au5 Ag2 86.69(9) . . ?
C2 Au5 Au4 44.769(14) . 2_755 ?
C2 Au5 Au4 45.133(14) . . ?
C2 Au5 Au6 45.327(14) . . ?
C2 Au5 Au6 44.369(14) . 2_755 ?
C2 Au5 Ag2 89.10(3) . . ?
C2 Au5 P5 175.26(10) . . ?
Au4 Au6 Au4 90.21(2) 2_755 . ?
Au4 Au6 Au5 60.009(18) 2_755 2_755 ?
Au4 Au6 Au5 61.008(18) 2_755 . ?
Au5 Au6 Au4 59.852(16) . . ?
Au5 Au6 Au4 59.725(17) 2_755 . ?
Au5 Au6 Au5 90.303(19) . 2_755 ?
Ag2 Au6 Au4 118.14(3) 2_755 . ?
Ag2 Au6 Au4 59.45(2) 2_755 2_755 ?
Ag2 Au6 Au5 120.42(3) 2_755 . ?
Ag2 Au6 Au5 58.41(2) 2_755 2_755 ?
P6 Au6 Au4 130.84(11) . 2_755 ?
P6 Au6 Au4 138.65(11) . . ?
P6 Au6 Au5 139.39(11) . 2_755 ?
P6 Au6 Au5 130.11(11) . . ?
P6 Au6 Ag2 91.80(10) . 2_755 ?
C2 Au6 Au4 44.481(14) . . ?
C2 Au6 Au4 45.726(15) . 2_755 ?
C2 Au6 Au5 44.667(14) . 2_755 ?
C2 Au6 Au5 45.635(14) . . ?
C2 Au6 Ag2 88.94(3) . 2_755 ?
C2 Au6 P6 174.67(12) . . ?
Au5 Ag2 Au4 62.03(2) . . ?
Au5 Ag2 Au6 62.72(2) . 2_755 ?
Au6 Ag2 Au4 61.16(2) 2_755 . ?
N436 Ag2 Au4 82.3(3) . . ?
N436 Ag2 Au5 108.3(3) . . ?
N436 Ag2 Au6 142.6(3) . 2_755 ?
N436 Ag2 N536 100.6(4) . . ?
N436 Ag2 N636 107.1(5) . . ?
N536 Ag2 Au4 143.0(3) . . ?
N536 Ag2 Au5 82.5(3) . . ?
N536 Ag2 Au6 113.0(3) . 2_755 ?
N636 Ag2 Au4 112.8(5) . . ?
N636 Ag2 Au5 143.0(4) . . ?
N636 Ag2 Au6 82.4(4) . 2_755 ?
N636 Ag2 N536 101.6(6) . . ?
C411 P4 Au4 115.0(7) . . ?
C411 P4 C421 110.4(11) . . ?
C411 P4 C431 107.6(10) . . ?
C421 P4 Au4 110.1(6) . . ?
C421 P4 C431 104.1(7) . . ?
C431 P4 Au4 109.0(5) . . ?
C511 P5 Au5 116.6(4) . . ?
C511 P5 C521 104.4(8) . . ?
C511 P5 C531 105.8(7) . . ?
C521 P5 Au5 113.2(5) . . ?
C521 P5 C531 104.8(7) . . ?
C531 P5 Au5 110.9(4) . . ?
C611 P6 Au6 115.1(7) . . ?
C611 P6 C621 108.2(9) . . ?
C611 P6 C631 107.6(8) . 2_755 ?
C621 P6 Au6 109.5(5) . . ?
C621 P6 C631 102.4(6) . 2_755 ?
C631 P6 Au6 113.2(5) 2_755 . ?
C437 O42 H42 109.5 . . ?
C537 O52 H52 109.5 . . ?
C637 O62 H62 109.5 . . ?
Au4 C2 Au4 180.00(3) 2_755 . ?
Au4 C2 Au5 90.36(2) 2_755 . ?
Au4 C2 Au5 89.64(2) 2_755 2_755 ?
Au4 C2 Au5 89.64(2) . . ?
Au4 C2 Au5 90.36(2) . 2_755 ?
Au5 C2 Au5 180.0 . 2_755 ?
Au6 C2 Au4 91.24(2) . . ?
Au6 C2 Au4 91.24(2) 2_755 2_755 ?
Au6 C2 Au4 88.76(2) 2_755 . ?
Au6 C2 Au4 88.76(2) . 2_755 ?
Au6 C2 Au5 90.96(2) 2_755 . ?
Au6 C2 Au5 90.97(2) . 2_755 ?
Au6 C2 Au5 89.03(2) 2_755 2_755 ?
Au6 C2 Au5 89.04(2) . . ?
Au6 C2 Au6 180.0 2_755 . ?
C412 C411 P4 120(2) . . ?
C412 C411 C416 116(2) . . ?
C416 C411 P4 123(2) . . ?
C411 C412 H412 120.0 . . ?
C413 C412 C411 120(3) . . ?
C413 C412 H412 120.0 . . ?
C412 C413 H413 119.3 . . ?
C412 C413 C414 121(3) . . ?
C414 C413 H413 119.3 . . ?
C413 C414 H414 119.6 . . ?
C415 C414 C413 121(2) . . ?
C415 C414 H414 119.6 . . ?
C414 C415 H415 120.3 . . ?
C414 C415 C416 119(3) . . ?
C416 C415 H415 120.3 . . ?
C411 C416 H416 119.5 . . ?
C415 C416 C411 121(3) . . ?
C415 C416 H416 119.5 . . ?
C422 C421 P4 120.9(13) . . ?
C422 C421 C426 117.3(16) . . ?
C426 C421 P4 121.4(13) . . ?
C421 C422 H422 118.9 . . ?
C423 C422 C421 122.2(16) . . ?
C423 C422 H422 118.9 . . ?
C422 C423 H423 119.9 . . ?
C424 C423 C422 120.3(16) . . ?
C424 C423 H423 119.9 . . ?
C423 C424 H424 119.1 . . ?
C423 C424 C425 121.8(17) . . ?
C425 C424 H424 119.1 . . ?
C424 C425 H425 121.9 . . ?
C424 C425 C426 116.2(15) . . ?
C426 C425 H425 121.9 . . ?
C421 C426 C425 121.7(16) . . ?
C421 C426 H426 119.2 . . ?
C425 C426 H426 119.2 . . ?
C431 N436 Ag2 126.3(10) . . ?
C431 N436 C435 118.1(14) . . ?
C435 N436 Ag2 115.6(10) . . ?
N436 C431 P4 116.1(12) . . ?
N436 C431 C432 124.0(14) . . ?
C432 C431 P4 119.8(12) . . ?
C431 C432 H432 121.6 . . ?
C431 C432 C433 116.8(15) . . ?
C433 C432 H432 121.6 . . ?
C432 C433 C437 117.7(14) . . ?
C434 C433 C432 118.4(15) . . ?
C434 C433 C437 123.8(14) . . ?
C433 C434 H434 119.1 . . ?
C433 C434 C435 121.8(15) . . ?
C435 C434 H434 119.1 . . ?
N436 C435 C434 120.9(15) . . ?
N436 C435 H435 119.5 . . ?
C434 C435 H435 119.5 . . ?
O41 C437 O42 126.4(15) . . ?
O41 C437 C433 121.7(14) . . ?
O42 C437 C433 111.9(14) . . ?
C512 C511 P5 128.3(11) . . ?
C512 C511 C516 112.2(14) . . ?
C516 C511 P5 119.5(12) . . ?
C511 C512 H512 116.8 . . ?
C511 C512 C513 126.4(14) . . ?
C513 C512 H512 116.8 . . ?
C512 C513 H513 121.6 . . ?
C512 C513 C514 116.8(16) . . ?
C514 C513 H513 121.6 . . ?
C513 C514 H514 119.5 . . ?
C515 C514 C513 121.1(16) . . ?
C515 C514 H514 119.5 . . ?
C514 C515 H515 120.8 . . ?
C514 C515 C516 118.4(15) . . ?
C516 C515 H515 120.8 . . ?
C511 C516 H516 117.7 . . ?
C515 C516 C511 124.7(17) . . ?
C515 C516 H516 117.7 . . ?
C522 C521 P5 117.2(12) . . ?
C526 C521 P5 125.5(13) . . ?
C526 C521 C522 117.3(17) . . ?
C521 C522 H522 121.5 . . ?
C523 C522 C521 116.9(17) . . ?
C523 C522 H522 121.5 . . ?
C522 C523 H523 118.5 . . ?
C524 C523 C522 123(2) . . ?
C524 C523 H523 118.5 . . ?
C523 C524 H524 119.6 . . ?
C525 C524 C523 121(2) . . ?
C525 C524 H524 119.6 . . ?
C524 C525 H525 119.1 . . ?
C524 C525 C526 121.7(19) . . ?
C526 C525 H525 119.1 . . ?
C521 C526 H526 120.1 . . ?
C525 C526 C521 119.7(17) . . ?
C525 C526 H526 120.1 . . ?
C531 N536 Ag2 127.2(9) . . ?
C531 N536 C535 119.2(13) . . ?
C535 N536 Ag2 111.9(9) . . ?
N536 C531 P5 113.4(10) . . ?
N536 C531 C532 121.8(15) . . ?
C532 C531 P5 124.6(11) . . ?
C531 C532 H532 120.5 . . ?
C533 C532 C531 119.0(13) . . ?
C533 C532 H532 120.5 . . ?
C532 C533 C534 121.2(14) . . ?
C532 C533 C537 120.1(14) . . ?
C534 C533 C537 118.2(17) . . ?
C533 C534 H534 121.5 . . ?
C533 C534 C535 117.1(15) . . ?
C535 C534 H534 121.5 . . ?
N536 C535 C534 121.5(13) . . ?
N536 C535 H535 119.3 . . ?
C534 C535 H535 119.3 . . ?
O51 C537 C533 116.0(18) . . ?
O52 C537 O51 129.1(17) . . ?
O52 C537 C533 114.6(17) . . ?
C612 C611 P6 116.5(15) . . ?
C616 C611 P6 121.3(17) . . ?
C616 C611 C612 122(2) . . ?
C611 C612 H612 122.0 . . ?
C613 C612 C611 116.1(19) . . ?
C613 C612 H612 122.0 . . ?
C612 C613 H613 118.5 . . ?
C614 C613 C612 123(2) . . ?
C614 C613 H613 118.5 . . ?
C613 C614 H614 119.7 . . ?
C613 C614 C615 121(2) . . ?
C615 C614 H614 119.7 . . ?
C614 C615 H615 119.8 . . ?
C616 C615 C614 120.5(19) . . ?
C616 C615 H615 119.8 . . ?
C611 C616 C615 117(2) . . ?
C611 C616 H616 121.3 . . ?
C615 C616 H616 121.3 . . ?
C621 C626 H626 120.0 . . ?
C621 C626 C624 120.0 . . ?
C624 C626 H626 120.0 . . ?
C626 C621 P6 122.5(8) . . ?
C622 C621 P6 117.4(8) . . ?
C622 C621 C626 120.0 . . ?
C621 C622 H622 120.0 . . ?
C623 C622 C621 120.0 . . ?
C623 C622 H622 120.0 . . ?
C622 C623 H623 120.0 . . ?
C622 C623 C625 120.0 . . ?
C625 C623 H623 120.0 . . ?
C623 C625 H625 120.0 . . ?
C623 C625 C624 120.0 . . ?
C624 C625 H625 120.0 . . ?
C626 C624 H624 120.0 . . ?
C625 C624 C626 120.0 . . ?
C625 C624 H624 120.0 . . ?
N636 C631 P6 115.8(11) . 2_755 ?
C632 C631 P6 122.0(14) . 2_755 ?
C632 C631 N636 122.2(16) . . ?
C631 N636 Ag2 131.1(11) . . ?
C631 N636 C635 118.3(15) . . ?
C635 N636 Ag2 110.5(13) . . ?
C631 C632 H632 119.3 . . ?
C631 C632 C633 121(2) . . ?
C633 C632 H632 119.3 . . ?
C632 C633 C634 118.9(19) . . ?
C632 C633 C637 121(2) . . ?
C634 C633 C637 120.3(18) . . ?
C633 C634 H634 120.5 . . ?
C635 C634 C633 119.1(19) . . ?
C635 C634 H634 120.5 . . ?
N636 C635 H635 119.9 . . ?
C634 C635 N636 120(2) . . ?
C634 C635 H635 119.9 . . ?
O61 C637 O62 126(2) . . ?
O61 C637 C633 117(2) . . ?
O62 C637 C633 116.5(18) . . ?
F11 B1 F12 109.9(18) . . ?
F11 B1 F14 108.7(17) . . ?
F12 B1 F14 109.1(17) . . ?
F13 B1 F11 109.4(17) . . ?
F13 B1 F12 108.0(17) . . ?
F13 B1 F14 111.6(18) . . ?
F22 B2 F21 111.5(15) . . ?
F22 B2 F23 109.2(14) . . ?
F22 B2 F24 110.3(14) . . ?
F23 B2 F21 106.4(13) . . ?
F24 B2 F21 108.3(14) . . ?
F24 B2 F23 111.0(14) . . ?
F31 B3 F32 112.4(17) . . ?
F33 B3 F31 107.6(16) . . ?
F33 B3 F32 113.7(17) . . ?
F33 B3 F34 104.3(15) . . ?
F34 B3 F31 111.8(17) . . ?
F34 B3 F32 106.9(16) . . ?
F42 B4 F41 109.8(17) . . ?
F42 B4 F44 107.2(17) . . ?
F43 B4 F41 105.6(17) . . ?
F43 B4 F42 114.1(19) . . ?
F43 B4 F44 109.7(18) . . ?
F44 B4 F41 110.4(18) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C111 C112 20.5(12) . . . . ?
Au1 P1 C111 C116 -153.2(9) . . . . ?
Au1 P1 C121 C122 44.5(15) . . . . ?
Au1 P1 C121 C126 -124.9(12) . . . . ?
Au2 P2 C211 C216 117.3(11) . . . . ?
Au2 P2 C211 C212 -58.9(11) . . . . ?
Au2 P2 C221 C222 158.1(7) . . . . ?
Au2 P2 C221 C226 -21.5(11) . . . . ?
Au2 P2 C231 N236 -39(2) . . . . ?
Au2 P2 C231 C232 143(3) . . . . ?
Au3 P3 C311 C316 -50.5(9) . . . . ?
Au3 P3 C311 C312 127.2(7) . . . . ?
Au3 P3 C321 C326 -36.0(12) . . . . ?
Au3 P3 C321 C322 141.5(9) . . . . ?
Au3 P3 C331 N336 -34.8(13) . . . . ?
Au3 P3 C331 C332 144.4(12) . . . . ?
Ag1 N136 C135 C134 176.4(19) . . . . ?
Ag1 N236 C231 P2 7(3) . . . . ?
Ag1 N236 C231 C232 -174(2) . . . . ?
Ag1 N236 C235 C234 179(2) . . . . ?
Ag1 N336 C331 P3 5.9(19) . . . . ?
Ag1 N336 C331 C332 -173.3(12) . . . . ?
Ag1 N336 C335 C334 173.1(17) . . . . ?
P1 C111 C116 C115 173.7(14) . . . . ?
P1 C121 C122 C123 -169.3(17) . . . . ?
P1 C121 C126 C125 169.5(17) . . . . ?
P1 C131 N136 Ag1 2(3) 2_656 . . . ?
P1 C131 N136 C135 179.5(17) 2_656 . . . ?
P1 C131 C132 C133 -178.9(17) 2_656 . . . ?
P2 C211 C216 C215 -176.0(16) . . . . ?
P2 C211 C212 C213 176.5(14) . . . . ?
P2 C221 C226 C225 179.6(13) . . . . ?
P2 C231 C232 C233 172(3) . . . . ?
P3 C311 C316 C315 177.7(11) . . . . ?
P3 C311 C312 C313 -177.6(11) . . . . ?
P3 C321 C326 C325 177.5(14) . . . . ?
P3 C321 C322 C323 -177.4(15) . . . . ?
P3 C331 C332 C333 176.5(12) . . . . ?
C112 C111 C116 C115 0.0 . . . . ?
C111 P1 C121 C122 169.7(13) . . . . ?
C111 P1 C121 C126 0.3(15) . . . . ?
C111 C112 C113 C114 0.0 . . . . ?
C111 C116 C115 C114 0.0 . . . . ?
C116 C115 C114 C113 0.0 . . . . ?
C115 C114 C113 C112 0.0 . . . . ?
C113 C112 C111 P1 -173.7(14) . . . . ?
C113 C112 C111 C116 0.0 . . . . ?
C121 P1 C111 C112 -105.9(13) . . . . ?
C121 P1 C111 C116 80.5(13) . . . . ?
C121 C122 C123 C124 0.0 . . . . ?
C122 C121 C126 C125 0.0 . . . . ?
C122 C123 C124 C125 0.0 . . . . ?
C123 C124 C125 C126 0.0 . . . . ?
C124 C125 C126 C121 0.0 . . . . ?
C126 C121 C122 C123 0.0 . . . . ?
C131 P1 C111 C112 139.1(14) 2_656 . . . ?
C131 P1 C111 C116 -34.6(15) 2_656 . . . ?
C131 P1 C121 C122 -77.5(16) 2_656 . . . ?
C131 P1 C121 C126 113.1(14) 2_656 . . . ?
C131 N136 C135 C134 -1(4) . . . . ?
C131 C132 C133 C134 1(4) . . . . ?
C131 C132 C133 C137 -173(2) . . . . ?
N136 C131 C132 C133 -5(4) . . . . ?
C132 C131 N136 Ag1 -171.8(19) . . . . ?
C132 C131 N136 C135 5(4) . . . . ?
C132 C133 C134 C135 3(4) . . . . ?
C132 C133 C137 O11 171(2) . . . . ?
C132 C133 C137 O12 -6(4) . . . . ?
C133 C134 C135 N136 -3(4) . . . . ?
C134 C133 C137 O11 -3(4) . . . . ?
C134 C133 C137 O12 -180(2) . . . . ?
C137 C133 C134 C135 177(2) . . . . ?
C211 P2 C221 C222 -76.6(11) . . . . ?
C211 P2 C221 C226 103.9(11) . . . . ?
C211 P2 C231 N236 -166(2) . . . . ?
C211 P2 C231 C232 15(3) . . . . ?
C211 C216 C215 C214 0.0 . . . . ?
C216 C211 C212 C213 0.0 . . . . ?
C216 C215 C214 C213 0.0 . . . . ?
C215 C214 C213 C212 0.0 . . . . ?
C214 C213 C212 C211 0.0 . . . . ?
C212 C211 C216 C215 0.0 . . . . ?
C224 C223 C222 C221 0.0 . . . . ?
C223 C224 C225 C226 0.0 . . . . ?
C223 C222 C221 P2 -179.6(13) . . . . ?
C223 C222 C221 C226 0.0 . . . . ?
C222 C221 C226 C225 0.0 . . . . ?
C221 P2 C211 C216 -4.9(14) . . . . ?
C221 P2 C211 C212 178.9(9) . . . . ?
C221 P2 C231 N236 82(2) . . . . ?
C221 P2 C231 C232 -96(3) . . . . ?
C221 C226 C225 C224 0.0 . . . . ?
C225 C224 C223 C222 0.0 . . . . ?
N236 C231 C232 C233 -6(5) . . . . ?
C231 P2 C211 C216 -118.1(15) . . . . ?
C231 P2 C211 C212 65.7(15) . . . . ?
C231 P2 C221 C222 36.7(13) . . . . ?
C231 P2 C221 C226 -142.8(11) . . . . ?
C231 N236 C235 C234 2(5) . . . . ?
C231 C232 C233 C234 6(5) . . . . ?
C231 C232 C233 C237 -180(3) . . . . ?
C232 C233 C234 C235 -3(4) . . . . ?
C232 C233 C237 O21 175(3) . . . . ?
C232 C233 C237 O22 -1(5) . . . . ?
C233 C234 C235 N236 -1(5) . . . . ?
C234 C233 C237 O21 -11(5) . . . . ?
C234 C233 C237 O22 172(3) . . . . ?
C235 N236 C231 P2 -177(2) . . . . ?
C235 N236 C231 C232 1(4) . . . . ?
C237 C233 C234 C235 -176(3) . . . . ?
C311 P3 C321 C326 88.5(11) . . . . ?
C311 P3 C321 C322 -94.1(11) . . . . ?
C311 P3 C331 N336 -156.5(12) . . . . ?
C311 P3 C331 C332 22.7(15) . . . . ?
C311 C316 C315 C314 0.0 . . . . ?
C316 C311 C312 C313 0.0 . . . . ?
C316 C315 C314 C313 0.0 . . . . ?
C315 C314 C313 C312 0.0 . . . . ?
C314 C313 C312 C311 0.0 . . . . ?
C312 C311 C316 C315 0.0 . . . . ?
C321 P3 C311 C316 -175.7(8) . . . . ?
C321 P3 C311 C312 2.0(10) . . . . ?
C321 P3 C331 N336 89.4(13) . . . . ?
C321 P3 C331 C332 -91.5(15) . . . . ?
C321 C326 C325 C324 0.0 . . . . ?
C326 C321 C322 C323 0.0 . . . . ?
C326 C325 C324 C323 0.0 . . . . ?
C325 C324 C323 C322 0.0 . . . . ?
C324 C323 C322 C321 0.0 . . . . ?
C322 C321 C326 C325 0.0 . . . . ?
N336 C331 C332 C333 -4(2) . . . . ?
C331 P3 C311 C316 71.4(9) . . . . ?
C331 P3 C311 C312 -110.9(8) . . . . ?
C331 P3 C321 C326 -159.5(10) . . . . ?
C331 P3 C321 C322 17.9(13) . . . . ?
C331 N336 C335 C334 -4(3) . . . . ?
C331 C332 C333 C334 6(2) . . . . ?
C331 C332 C333 C337 -178.0(15) . . . . ?
C332 C333 C334 C335 -7(3) . . . . ?
C332 C333 C337 O31 -177.4(15) . . . . ?
C332 C333 C337 O32 4(3) . . . . ?
C333 C334 C335 N336 6(3) . . . . ?
C334 C333 C337 O31 -2(3) . . . . ?
C334 C333 C337 O32 179.3(18) . . . . ?
C335 N336 C331 P3 -177.9(14) . . . . ?
C335 N336 C331 C332 3(3) . . . . ?
C337 C333 C334 C335 177.6(17) . . . . ?
Au4 P4 C411 C412 -61(2) . . . . ?
Au4 P4 C411 C416 113.1(18) . . . . ?
Au4 P4 C421 C422 -31.9(18) . . . . ?
Au4 P4 C421 C426 141.0(15) . . . . ?
Au4 P4 C431 N436 -39.7(12) . . . . ?
Au4 P4 C431 C432 144.3(11) . . . . ?
Au5 P5 C511 C512 159.0(15) . . . . ?
Au5 P5 C511 C516 -21.1(17) . . . . ?
Au5 P5 C521 C522 -28.7(13) . . . . ?
Au5 P5 C521 C526 150.9(11) . . . . ?
Au5 P5 C531 N536 -43.0(11) . . . . ?
Au5 P5 C531 C532 131.1(12) . . . . ?
Au6 P6 C611 C612 -105.6(15) . . . . ?
Au6 P6 C611 C616 74.7(19) . . . . ?
Au6 P6 C621 C626 -150.3(6) . . . . ?
Au6 P6 C621 C622 33.2(7) . . . . ?
Ag2 N436 C431 P4 4.3(17) . . . . ?
Ag2 N436 C431 C432 -180.0(10) . . . . ?
Ag2 N436 C435 C434 179.3(11) . . . . ?
Ag2 N536 C531 P5 13.2(16) . . . . ?
Ag2 N536 C531 C532 -161.1(11) . . . . ?
Ag2 N536 C535 C534 163.6(12) . . . . ?
Ag2 N636 C635 C634 180(2) . . . . ?
P4 C411 C412 C413 179.1(18) . . . . ?
P4 C411 C416 C415 -178.2(18) . . . . ?
P4 C421 C422 C423 -179.0(15) . . . . ?
P4 C421 C426 C425 178.6(15) . . . . ?
P4 C431 C432 C433 176.4(11) . . . . ?
P5 C511 C512 C513 -172.8(17) . . . . ?
P5 C511 C516 C515 174.8(17) . . . . ?
P5 C521 C522 C523 -175.4(13) . . . . ?
P5 C521 C526 C525 174.3(12) . . . . ?
P5 C531 C532 C533 -178.0(11) . . . . ?
P6 C611 C612 C613 175.1(16) . . . . ?
P6 C611 C616 C615 -178.2(15) . . . . ?
P6 C621 C622 C623 176.6(9) . . . . ?
P6 C631 N636 Ag2 2(2) 2_755 . . . ?
P6 C631 N636 C635 179.3(17) 2_755 . . . ?
P6 C631 C632 C633 -179(2) 2_755 . . . ?
C411 P4 C421 C422 96.1(18) . . . . ?
C411 P4 C421 C426 -91.0(18) . . . . ?
C411 P4 C431 N436 -165.0(14) . . . . ?
C411 P4 C431 C432 19.0(15) . . . . ?
C411 C412 C413 C414 -8(4) . . . . ?
C412 C411 C416 C415 -3(3) . . . . ?
C412 C413 C414 C415 11(4) . . . . ?
C413 C414 C415 C416 -10(4) . . . . ?
C414 C415 C416 C411 6(4) . . . . ?
C416 C411 C412 C413 4(3) . . . . ?
C421 P4 C411 C412 173.4(17) . . . . ?
C421 P4 C411 C416 -12(2) . . . . ?
C421 P4 C431 N436 77.7(13) . . . . ?
C421 P4 C431 C432 -98.2(13) . . . . ?
C421 C422 C423 C424 -5(3) . . . . ?
C422 C421 C426 C425 -8(3) . . . . ?
C422 C423 C424 C425 2(3) . . . . ?
C423 C424 C425 C426 -2(3) . . . . ?
C424 C425 C426 C421 6(3) . . . . ?
C426 C421 C422 C423 8(3) . . . . ?
N436 C431 C432 C433 1(2) . . . . ?
C431 P4 C411 C412 60(2) . . . . ?
C431 P4 C411 C416 -125.2(19) . . . . ?
C431 P4 C421 C422 -148.6(16) . . . . ?
C431 P4 C421 C426 24.2(18) . . . . ?
C431 N436 C435 C434 0(2) . . . . ?
C431 C432 C433 C434 0(2) . . . . ?
C431 C432 C433 C437 -176.5(13) . . . . ?
C432 C433 C434 C435 -1(2) . . . . ?
C432 C433 C437 O41 -5(2) . . . . ?
C432 C433 C437 O42 173.4(13) . . . . ?
C433 C434 C435 N436 1(2) . . . . ?
C434 C433 C437 O41 178.9(16) . . . . ?
C434 C433 C437 O42 -3(2) . . . . ?
C435 N436 C431 P4 -176.4(10) . . . . ?
C435 N436 C431 C432 -1(2) . . . . ?
C437 C433 C434 C435 175.5(14) . . . . ?
C511 P5 C521 C522 99.2(12) . . . . ?
C511 P5 C521 C526 -81.2(14) . . . . ?
C511 P5 C531 N536 -170.5(11) . . . . ?
C511 P5 C531 C532 3.6(14) . . . . ?
C511 C512 C513 C514 -7(3) . . . . ?
C512 C511 C516 C515 -5(3) . . . . ?
C512 C513 C514 C515 4(3) . . . . ?
C513 C514 C515 C516 -3(4) . . . . ?
C514 C515 C516 C511 3(3) . . . . ?
C516 C511 C512 C513 7(3) . . . . ?
C521 P5 C511 C512 33.2(18) . . . . ?
C521 P5 C511 C516 -146.8(15) . . . . ?
C521 P5 C531 N536 79.5(11) . . . . ?
C521 P5 C531 C532 -106.4(13) . . . . ?
C521 C522 C523 C524 -4(3) . . . . ?
C522 C521 C526 C525 -6(2) . . . . ?
C522 C523 C524 C525 3(3) . . . . ?
C523 C524 C525 C526 -4(3) . . . . ?
C524 C525 C526 C521 6(3) . . . . ?
C526 C521 C522 C523 5(2) . . . . ?
N536 C531 C532 C533 -4(2) . . . . ?
C531 P5 C511 C512 -77.1(18) . . . . ?
C531 P5 C511 C516 102.8(15) . . . . ?
C531 P5 C521 C522 -149.7(11) . . . . ?
C531 P5 C521 C526 29.9(14) . . . . ?
C531 N536 C535 C534 -3(2) . . . . ?
C531 C532 C533 C534 6(2) . . . . ?
C531 C532 C533 C537 177.4(14) . . . . ?
C532 C533 C534 C535 -5(2) . . . . ?
C532 C533 C537 O51 -161.7(16) . . . . ?
C532 C533 C537 O52 13(2) . . . . ?
C533 C534 C535 N536 4(2) . . . . ?
C534 C533 C537 O51 10(2) . . . . ?
C534 C533 C537 O52 -174.8(14) . . . . ?
C535 N536 C531 P5 177.2(11) . . . . ?
C535 N536 C531 C532 3(2) . . . . ?
C537 C533 C534 C535 -177.2(14) . . . . ?
C611 P6 C621 C626 -24.2(9) . . . . ?
C611 P6 C621 C622 159.3(8) . . . . ?
C611 C612 C613 C614 3(3) . . . . ?
C612 C611 C616 C615 2(3) . . . . ?
C612 C613 C614 C615 2(3) . . . . ?
C613 C614 C615 C616 -5(3) . . . . ?
C614 C615 C616 C611 3(3) . . . . ?
C616 C611 C612 C613 -5(3) . . . . ?
C626 C621 C622 C623 0.0 . . . . ?
C621 P6 C611 C612 131.7(15) . . . . ?
C621 P6 C611 C616 -48.1(19) . . . . ?
C621 C626 C624 C625 0.0 . . . . ?
C621 C622 C623 C625 0.0 . . . . ?
C622 C623 C625 C624 0.0 . . . . ?
C623 C625 C624 C626 0.0 . . . . ?
C624 C626 C621 P6 -176.4(9) . . . . ?
C624 C626 C621 C622 0.0 . . . . ?
C631 P6 C611 C612 21.7(18) 2_755 . . . ?
C631 P6 C611 C616 -158.1(17) 2_755 . . . ?
C631 P6 C621 C626 89.3(8) 2_755 . . . ?
C631 P6 C621 C622 -87.2(8) 2_755 . . . ?
C631 N636 C635 C634 2(4) . . . . ?
C631 C632 C633 C634 -2(4) . . . . ?
C631 C632 C633 C637 179(2) . . . . ?
N636 C631 C632 C633 1(4) . . . . ?
C632 C631 N636 Ag2 -178.0(17) . . . . ?
C632 C631 N636 C635 -1(3) . . . . ?
C632 C633 C634 C635 3(4) . . . . ?
C632 C633 C637 O61 172(3) . . . . ?
C632 C633 C637 O62 -4(4) . . . . ?
C633 C634 C635 N636 -3(4) . . . . ?
C634 C633 C637 O61 -7(4) . . . . ?
C634 C633 C637 O62 176(3) . . . . ?
C637 C633 C634 C635 -177(2) . . . . ?

_shelx_SHELXL_version_number     2014/8
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2b
_database_code_depnum_ccdc_archive 'CCDC 1472549'
_audit_update_record             
;
2016-05-25 deposited with the CCDC.
2016-05-26 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT601_2b                  
;
PROBLEM:VERY LARGE Solvent Accessible VOID(S) in Structure
RESPONSE:The crystal has large solvent accessible voids since a 
large number of disordered solvent molecules
 and counter-anions which could not be located.
;
_vrf_PLAT043_2b                  
;
PROBLEM: Calculated and Reported Mol. Weight Differ by .. 538.56
RESPONSE: The counter-anions were not resolved because of the weak 
data and high symmetry of 2b. 
The correct chemical formula reported in CIF includes 
counter-ions for charge balance.
;
_vrf_PLAT044_2b                  
;
PROBLEM: Calculated and Reported Density Dx Differ by .. 0.1120
RESPONSE: The counter-anions were not resolved because of the weak data 
and high symmetry of 2b.
 The correct chemical formula reported in CIF includes 
counter-ions for charge balance.
;
_vrf_PLAT220_2b                  
;
PROBLEM: Large Non-Solvent C Ueq(max)/Ueq(min) Range 6.8 Ratio
RESPONSE: One of the acetonitrile molecules was modeled as 
disordered over two positions.
;
_vrf_PLAT417_2b                  
;
PROBLEM: Short Inter D-H..H-D H12 .. H12 .. 1.99 Ang.
RESPONSE:Alerts of short H .. H contact involving 
oxhydryl H-atoms often arise from the
fact that they involve H-atoms at not optimal calculated positions.
;
_vrf_PLAT420_2b                  
;
PROBLEM: D-H Without Acceptor O12 - H12 
RESPONSE:The hydrogen atoms of organic ligands were generated geometrically.
The hydrogen could not be accurately located by the present data.
 Even the quality of this crystal is poor, however, it represents 
the best possible data after multiple attempts.
;
# end Validation Reply Form
_audit_creation_date             2016-05-12
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C109 H84 Ag2 Au6 N6 O12 P6, 6(C2 N), 3(C1.5 N)'
_chemical_formula_sum            'C121 H102 Ag2 Au6 B4 F16 N12 O12 P6'
_chemical_formula_weight         3846.74
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           167
_space_group_name_H-M_alt        'R -3 c'
_space_group_name_Hall           '-R 3 2"c'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z+1/2'
'x-y, -y, -z+1/2'
'-x, -x+y, -z+1/2'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+5/6'
'x-y+2/3, -y+1/3, -z+5/6'
'-x+2/3, -x+y+1/3, -z+5/6'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+7/6'
'x-y+1/3, -y+2/3, -z+7/6'
'-x+1/3, -x+y+2/3, -z+7/6'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z-1/2'
'-x+y, y, z-1/2'
'x, x-y, z-1/2'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z-1/6'
'-x+y+2/3, y+1/3, z-1/6'
'x+2/3, x-y+1/3, z-1/6'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+1/6'
'-x+y+1/3, y+2/3, z+1/6'
'x+1/3, x-y+2/3, z+1/6'

_cell_length_a                   23.7002(5)
_cell_length_b                   23.7002(5)
_cell_length_c                   49.407(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     24033.9(19)
_cell_formula_units_Z            6
_cell_measurement_temperature    102(3)
_cell_measurement_reflns_used    5972
_cell_measurement_theta_min      4.1900
_cell_measurement_theta_max      69.3690
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    13.129
_exptl_absorpt_correction_T_min  0.54858
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.595
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             10980
_exptl_crystal_size_max          0.04
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0694
_diffrn_reflns_av_unetI/netI     0.0578
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       56
_diffrn_reflns_limit_l_min       -59
_diffrn_reflns_number            17217
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         70.238
_diffrn_reflns_theta_min         3.730
_diffrn_ambient_temperature      102(3)
_diffrn_detector_area_resol_mean 10.4741
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   'sealed X-ray tube'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4097
_reflns_number_total             4998
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max         1.782
_refine_diff_density_min         -3.689
_refine_diff_density_rms         0.225
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     249
_refine_ls_number_reflns         4998
_refine_ls_number_restraints     9
_refine_ls_R_factor_all          0.0695
_refine_ls_R_factor_gt           0.0568
_refine_ls_restrained_S_all      1.075
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0953P)²+279.2459P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1531
_refine_ls_wR_factor_ref         0.1696
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups
2. Restrained distances
 C7S-N3S
 1.15 with sigma of 0.02
 N1S-C2S
 1.15 with sigma of 0.02
 C5S-C7S
 1.5 with sigma of 0.02
 C2S-C1S
 1.4 with sigma of 0.02
 C5S-C7S
 1.4 with sigma of 0.02
 C6S-C7S
 1.4 with sigma of 0.02
 N2S-C3S
 2.53 with sigma of 0.02
 C1S-N1S
 2.5 with sigma of 0.02
 C3S-C4S
 1.4 with sigma of 0.02
3. Others
 Fixed Sof: N1S(0.5) C1S(0.5) C2S(0.5) C3S(0.25) N3S(0.5) C5S(0.25) C6S(0.25)
 C7S(0.5)
4.a Aromatic/amide H refined with riding coordinates:
 C112(H112), C113(H113), C114(H114), C115(H115), C116(H116), C122(H122),
 C123(H123), C124(H124), C125(H125), C126(H126), C133(H133), C135(H135),
 C136(H136)
4.b Tetrahedral OH refined with riding coordinates:
 O12(H12)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.59380(2) 0.32842(2) 0.05559(2) 0.02940(16) Uani 1 1 d . . . . .
Ag2 Ag 0.6667 0.3333 0.00773(2) 0.0296(2) Uani 1 3 d S T P . .
P1 P 0.51861(11) 0.32174(11) 0.02538(4) 0.0306(4) Uani 1 1 d . . . . .
O11 O 0.3319(5) 0.1305(11) -0.0383(3) 0.187(11) Uani 1 1 d . . . . .
O12 O 0.3848(4) 0.1160(4) -0.07028(16) 0.059(2) Uani 1 1 d . . . . .
H12 H 0.3663 0.0763 -0.0685 0.089 Uiso 1 1 calc R . . . .
N131 N 0.5641(3) 0.2732(4) -0.01208(13) 0.0311(15) Uani 1 1 d . . . . .
C1 C 0.6667 0.3333 0.0833 0.014(3) Uani 1 6 d S T P . .
C111 C 0.4397(5) 0.2913(5) 0.04085(19) 0.043(2) Uani 1 1 d . . . . .
C112 C 0.4272(6) 0.2569(7) 0.0644(2) 0.063(3) Uani 1 1 d . . . . .
H112 H 0.4580 0.2474 0.0713 0.075 Uiso 1 1 calc R . . . .
C113 C 0.3694(8) 0.2362(9) 0.0781(3) 0.083(5) Uani 1 1 d . . . . .
H113 H 0.3624 0.2139 0.0943 0.100 Uiso 1 1 calc R . . . .
C114 C 0.3236(7) 0.2475(9) 0.0685(3) 0.088(5) Uani 1 1 d . . . . .
H114 H 0.2840 0.2312 0.0775 0.105 Uiso 1 1 calc R . . . .
C115 C 0.3357(6) 0.2844(7) 0.0445(4) 0.080(4) Uani 1 1 d . . . . .
H115 H 0.3051 0.2949 0.0382 0.096 Uiso 1 1 calc R . . . .
C116 C 0.3929(5) 0.3047(6) 0.0306(3) 0.056(3) Uani 1 1 d . . . . .
H116 H 0.4004 0.3273 0.0144 0.067 Uiso 1 1 calc R . . . .
C121 C 0.5408(5) 0.3986(5) 0.00899(18) 0.040(2) Uani 1 1 d . . . . .
C122 C 0.5832(5) 0.4552(5) 0.0215(2) 0.047(2) Uani 1 1 d . . . . .
H122 H 0.6009 0.4545 0.0382 0.056 Uiso 1 1 calc R . . . .
C123 C 0.6004(6) 0.5145(5) 0.0091(2) 0.058(3) Uani 1 1 d . . . . .
H123 H 0.6287 0.5535 0.0177 0.069 Uiso 1 1 calc R . . . .
C124 C 0.5751(7) 0.5151(6) -0.0159(3) 0.064(3) Uani 1 1 d . . . . .
H124 H 0.5872 0.5548 -0.0242 0.077 Uiso 1 1 calc R . . . .
C125 C 0.5329(7) 0.4590(6) -0.0286(2) 0.056(3) Uani 1 1 d . . . . .
H125 H 0.5156 0.4602 -0.0454 0.068 Uiso 1 1 calc R . . . .
C126 C 0.5158(6) 0.4005(6) -0.0167(2) 0.051(2) Uani 1 1 d . . . . .
H126 H 0.4876 0.3618 -0.0255 0.061 Uiso 1 1 calc R . . . .
C132 C 0.5078(4) 0.2666(4) -0.00255(15) 0.0275(16) Uani 1 1 d . . . . .
C133 C 0.4486(5) 0.2238(5) -0.01383(18) 0.042(2) Uani 1 1 d . . . . .
H133 H 0.4105 0.2191 -0.0063 0.050 Uiso 1 1 calc R . . . .
C134 C 0.4457(5) 0.1881(5) -0.03616(18) 0.044(2) Uani 1 1 d . . . . .
C135 C 0.5029(5) 0.1956(5) -0.04645(16) 0.039(2) Uani 1 1 d . . . . .
H135 H 0.5026 0.1723 -0.0616 0.047 Uiso 1 1 calc R . . . .
C136 C 0.5612(5) 0.2386(5) -0.03385(17) 0.040(2) Uani 1 1 d . . . . .
H136 H 0.5998 0.2434 -0.0409 0.047 Uiso 1 1 calc R . . . .
C137 C 0.3815(6) 0.1409(6) -0.0490(2) 0.061(3) Uani 1 1 d . . . . .
N1S N 0.730(2) 0.685(2) 0.0182(8) 0.135(13) Uiso 0.5 1 d D . . . .
C1S C 0.850(2) 0.729(3) 0.0186(11) 0.151(19) Uiso 0.5 1 d D . . . .
C2S C 0.783(2) 0.702(3) 0.0221(9) 0.134(16) Uiso 0.5 1 d D . . . .
N2S N 0.6667 0.5240(10) 0.0833 0.103(6) Uiso 1 2 d DS T P . .
C3S C 0.700(3) 0.6416(14) 0.0832(14) 0.086(17) Uiso 0.25 1 d D . . . .
C4S C 0.6667 0.5723(14) 0.0833 0.126(10) Uiso 1 2 d DS T P . .
N3S N 0.5573(19) 0.370(2) -0.0853(8) 0.127(12) Uiso 0.5 1 d D . . . .
C5S C 0.446(3) 0.283(3) -0.0975(15) 0.10(2) Uiso 0.25 1 d D . . . .
C6S C 0.435(3) 0.309(4) -0.0780(16) 0.11(2) Uiso 0.25 1 d D . . . .
C7S C 0.501(2) 0.340(3) -0.0862(11) 0.151(19) Uiso 0.5 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Au1 2.7490(6) 17_554 ?
Au1 Au1 2.8954(6) 2_655 ?
Au1 Au1 2.8954(6) 3_665 ?
Au1 Ag2 2.8957(8) . ?
Au1 P1 2.268(2) . ?
Au1 C1 2.1619(3) . ?
Ag2 Au1 2.8955(8) 2_655 ?
Ag2 Au1 2.8955(8) 3_665 ?
Ag2 N131 2.331(7) 3_665 ?
Ag2 N131 2.331(7) . ?
Ag2 N131 2.331(7) 2_655 ?
P1 C111 1.803(10) . ?
P1 C121 1.815(10) . ?
P1 C132 1.828(8) . ?
O11 C137 1.198(17) . ?
O12 H12 0.8200 . ?
O12 C137 1.226(14) . ?
N131 C132 1.349(11) . ?
N131 C136 1.334(11) . ?
C1 Au1 2.1617(3) 17_554 ?
C1 Au1 2.1619(3) 16_544 ?
C1 Au1 2.1619(3) 2_655 ?
C1 Au1 2.1619(3) 3_665 ?
C1 Au1 2.1618(3) 18_654 ?
C111 C112 1.364(16) . ?
C111 C116 1.393(15) . ?
C112 H112 0.9300 . ?
C112 C113 1.380(18) . ?
C113 H113 0.9300 . ?
C113 C114 1.33(2) . ?
C114 H114 0.9300 . ?
C114 C115 1.41(2) . ?
C115 H115 0.9300 . ?
C115 C116 1.376(17) . ?
C116 H116 0.9300 . ?
C121 C122 1.358(15) . ?
C121 C126 1.410(13) . ?
C122 H122 0.9300 . ?
C122 C123 1.395(15) . ?
C123 H123 0.9300 . ?
C123 C124 1.372(18) . ?
C124 H124 0.9300 . ?
C124 C125 1.356(19) . ?
C125 H125 0.9300 . ?
C125 C126 1.368(15) . ?
C126 H126 0.9300 . ?
C132 C133 1.373(13) . ?
C133 H133 0.9300 . ?
C133 C134 1.372(14) . ?
C134 C135 1.373(15) . ?
C134 C137 1.506(14) . ?
C135 H135 0.9300 . ?
C135 C136 1.389(13) . ?
C136 H136 0.9300 . ?
N1S C2S 1.138(17) . ?
C1S C2S 1.383(18) . ?
N2S C4S 1.15(3) . ?
C3S C3S 1.35(13) 18_654 ?
C3S C4S 1.424(18) . ?
C4S C3S 1.424(18) 18_654 ?
N3S C7S 1.153(19) . ?
C5S C6S 1.24(10) . ?
C5S C7S 1.454(14) . ?
C6S C7S 1.41(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au1 Au1 Au1 91.879(6) 17_554 2_655 ?
Au1 Au1 Au1 60.0 2_655 3_665 ?
Au1 Au1 Au1 87.681(9) 17_554 3_665 ?
Au1 Au1 Ag2 60.000(10) 2_655 . ?
Au1 Au1 Ag2 144.266(12) 17_554 . ?
Au1 Au1 Ag2 60.000(10) 3_665 . ?
P1 Au1 Au1 131.26(6) . 3_665 ?
P1 Au1 Au1 130.13(6) . 2_655 ?
P1 Au1 Au1 131.35(5) . 17_554 ?
P1 Au1 Ag2 84.12(5) . . ?
C1 Au1 Au1 47.961(7) . 2_655 ?
C1 Au1 Au1 47.960(6) . 3_665 ?
C1 Au1 Au1 50.518(9) . 17_554 ?
C1 Au1 Ag2 94.091(16) . . ?
C1 Au1 P1 178.01(6) . . ?
Au1 Ag2 Au1 60.00(2) 2_655 3_665 ?
Au1 Ag2 Au1 60.00(2) 3_665 . ?
Au1 Ag2 Au1 60.00(2) 2_655 . ?
N131 Ag2 Au1 84.24(16) 2_655 2_655 ?
N131 Ag2 Au1 143.75(17) . 3_665 ?
N131 Ag2 Au1 84.24(16) . . ?
N131 Ag2 Au1 108.81(17) . 2_655 ?
N131 Ag2 Au1 143.75(17) 2_655 . ?
N131 Ag2 Au1 143.75(17) 3_665 2_655 ?
N131 Ag2 Au1 108.81(17) 3_665 . ?
N131 Ag2 Au1 108.81(17) 2_655 3_665 ?
N131 Ag2 Au1 84.24(16) 3_665 3_665 ?
N131 Ag2 N131 103.63(19) 2_655 3_665 ?
N131 Ag2 N131 103.63(19) 2_655 . ?
N131 Ag2 N131 103.63(19) . 3_665 ?
C111 P1 Au1 111.7(3) . . ?
C111 P1 C121 108.2(5) . . ?
C111 P1 C132 106.7(4) . . ?
C121 P1 Au1 113.6(3) . . ?
C121 P1 C132 104.3(4) . . ?
C132 P1 Au1 111.8(3) . . ?
C137 O12 H12 109.5 . . ?
C132 N131 Ag2 126.4(5) . . ?
C136 N131 Ag2 115.6(6) . . ?
C136 N131 C132 117.9(7) . . ?
Au1 C1 Au1 84.078(13) 2_655 3_665 ?
Au1 C1 Au1 84.080(13) 16_544 18_654 ?
Au1 C1 Au1 84.082(13) 16_544 17_554 ?
Au1 C1 Au1 84.079(13) 2_655 . ?
Au1 C1 Au1 129.532(18) 3_665 17_554 ?
Au1 C1 Au1 84.081(13) 3_665 . ?
Au1 C1 Au1 78.963(18) 3_665 18_654 ?
Au1 C1 Au1 78.961(18) 2_655 16_544 ?
Au1 C1 Au1 139.574(18) 2_655 17_554 ?
Au1 C1 Au1 139.573(18) 3_665 16_544 ?
Au1 C1 Au1 78.961(18) . 17_554 ?
Au1 C1 Au1 129.529(18) . 16_544 ?
Au1 C1 Au1 84.083(13) 18_654 17_554 ?
Au1 C1 Au1 129.528(18) 2_655 18_654 ?
Au1 C1 Au1 139.578(18) . 18_654 ?
C112 C111 P1 118.2(8) . . ?
C112 C111 C116 119.1(10) . . ?
C116 C111 P1 122.6(8) . . ?
C111 C112 H112 119.6 . . ?
C111 C112 C113 120.7(12) . . ?
C113 C112 H112 119.6 . . ?
C112 C113 H113 119.3 . . ?
C114 C113 C112 121.3(13) . . ?
C114 C113 H113 119.3 . . ?
C113 C114 H114 120.3 . . ?
C113 C114 C115 119.3(11) . . ?
C115 C114 H114 120.3 . . ?
C114 C115 H115 120.2 . . ?
C116 C115 C114 119.6(12) . . ?
C116 C115 H115 120.2 . . ?
C111 C116 H116 120.1 . . ?
C115 C116 C111 119.7(12) . . ?
C115 C116 H116 120.1 . . ?
C122 C121 P1 119.3(7) . . ?
C122 C121 C126 119.6(10) . . ?
C126 C121 P1 121.2(8) . . ?
C121 C122 H122 120.2 . . ?
C121 C122 C123 119.7(11) . . ?
C123 C122 H122 120.2 . . ?
C122 C123 H123 120.2 . . ?
C124 C123 C122 119.7(11) . . ?
C124 C123 H123 120.2 . . ?
C123 C124 H124 119.3 . . ?
C125 C124 C123 121.4(10) . . ?
C125 C124 H124 119.3 . . ?
C124 C125 H125 120.3 . . ?
C124 C125 C126 119.5(11) . . ?
C126 C125 H125 120.3 . . ?
C121 C126 H126 119.9 . . ?
C125 C126 C121 120.2(11) . . ?
C125 C126 H126 119.9 . . ?
N131 C132 P1 113.8(6) . . ?
N131 C132 C133 122.0(8) . . ?
C133 C132 P1 124.1(7) . . ?
C132 C133 H133 120.0 . . ?
C134 C133 C132 120.0(10) . . ?
C134 C133 H133 120.0 . . ?
C133 C134 C135 118.4(9) . . ?
C133 C134 C137 121.2(10) . . ?
C135 C134 C137 120.4(9) . . ?
C134 C135 H135 120.5 . . ?
C134 C135 C136 119.1(8) . . ?
C136 C135 H135 120.5 . . ?
N131 C136 C135 122.6(9) . . ?
N131 C136 H136 118.7 . . ?
C135 C136 H136 118.7 . . ?
O11 C137 O12 125.0(11) . . ?
O11 C137 C134 119.2(11) . . ?
O12 C137 C134 115.8(11) . . ?
N1S C2S C1S 162(5) . . ?
C3S C3S C4S 62(3) 18_654 . ?
N2S C4S C3S 152(3) . . ?
N2S C4S C3S 152(3) . 18_654 ?
C3S C4S C3S 57(6) 18_654 . ?
C6S C5S C7S 63(2) . . ?
C5S C6S C7S 66(3) . . ?
N3S C7S C5S 145(7) . . ?
N3S C7S C6S 161(7) . . ?
C6S C7S C5S 51(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C111 C112 -20.8(10) . . . . ?
Au1 P1 C111 C116 155.4(9) . . . . ?
Au1 P1 C121 C122 -23.7(9) . . . . ?
Au1 P1 C121 C126 154.9(8) . . . . ?
Au1 P1 C132 N131 -42.6(6) . . . . ?
Au1 P1 C132 C133 139.8(7) . . . . ?
Ag2 N131 C132 P1 10.5(9) . . . . ?
Ag2 N131 C132 C133 -171.9(6) . . . . ?
Ag2 N131 C136 C135 173.9(7) . . . . ?
P1 C111 C112 C113 175.7(12) . . . . ?
P1 C111 C116 C115 -174.9(10) . . . . ?
P1 C121 C122 C123 -179.8(8) . . . . ?
P1 C121 C126 C125 179.7(9) . . . . ?
P1 C132 C133 C134 174.7(7) . . . . ?
N131 C132 C133 C134 -2.7(13) . . . . ?
C111 P1 C121 C122 101.0(9) . . . . ?
C111 P1 C121 C126 -80.4(9) . . . . ?
C111 P1 C132 N131 -165.0(6) . . . . ?
C111 P1 C132 C133 17.4(8) . . . . ?
C111 C112 C113 C114 2(3) . . . . ?
C112 C111 C116 C115 1.3(18) . . . . ?
C112 C113 C114 C115 -3(3) . . . . ?
C113 C114 C115 C116 4(3) . . . . ?
C114 C115 C116 C111 -3(2) . . . . ?
C116 C111 C112 C113 -1(2) . . . . ?
C121 P1 C111 C112 -146.6(10) . . . . ?
C121 P1 C111 C116 29.5(11) . . . . ?
C121 P1 C132 N131 80.6(7) . . . . ?
C121 P1 C132 C133 -97.0(8) . . . . ?
C121 C122 C123 C124 -1.3(18) . . . . ?
C122 C121 C126 C125 -1.8(17) . . . . ?
C122 C123 C124 C125 1.0(19) . . . . ?
C123 C124 C125 C126 -1(2) . . . . ?
C124 C125 C126 C121 1.4(19) . . . . ?
C126 C121 C122 C123 1.7(16) . . . . ?
C132 P1 C111 C112 101.7(10) . . . . ?
C132 P1 C111 C116 -82.2(10) . . . . ?
C132 P1 C121 C122 -145.7(8) . . . . ?
C132 P1 C121 C126 32.9(10) . . . . ?
C132 N131 C136 C135 -1.4(13) . . . . ?
C132 C133 C134 C135 1.0(14) . . . . ?
C132 C133 C134 C137 -179.8(10) . . . . ?
C133 C134 C135 C136 0.4(15) . . . . ?
C133 C134 C137 O11 -6(2) . . . . ?
C133 C134 C137 O12 173.5(11) . . . . ?
C134 C135 C136 N131 -0.2(15) . . . . ?
C135 C134 C137 O11 173.0(18) . . . . ?
C135 C134 C137 O12 -7.2(17) . . . . ?
C136 N131 C132 P1 -174.8(7) . . . . ?
C136 N131 C132 C133 2.9(12) . . . . ?
C137 C134 C135 C136 -178.8(10) . . . . ?
C3S C3S C4S N2S 180.002(1) 18_654 . . . ?
C5S C6S C7S N3S -150(23) . . . . ?
C6S C5S C7S N3S 164(13) . . . . ?

_shelx_SHELXL_version_number     2014/8
_olex2_submission_special_instructions 'No special instructions were received'
#=======================================END
