# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_2015074_0m
_database_code_depnum_ccdc_archive 'CCDC 1049041'
_audit_update_record             
;
2015-02-12 deposited with the CCDC.
2016-06-30 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C22 H26 F6 N2 Rh Sb'
_chemical_formula_weight         657.12

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.6576(2)
_cell_length_b                   14.5099(2)
_cell_length_c                   13.4160(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 106.5230(10)
_cell_angle_gamma                90.00
_cell_volume                     2362.24(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       prism
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.848
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1288
_exptl_absorpt_coefficient_mu    1.901
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            20964
_diffrn_reflns_av_R_equivalents  0.0181
_diffrn_reflns_av_sigmaI/netI    0.0159
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.95
_diffrn_reflns_theta_max         27.64
_reflns_number_total             5487
_reflns_number_gt                5151
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0359P)²+5.7451P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5487
_refine_ls_number_parameters     295
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0280
_refine_ls_wR_factor_ref         0.0745
_refine_ls_wR_factor_gt          0.0733
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_restrained_S_all      1.056
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.341376(16) 0.803625(14) 0.225988(15) 0.01535(6) Uani 1 1 d . . .
Sb1 Sb 0.656925(16) 0.160378(15) 0.179556(15) 0.02528(7) Uani 1 1 d . . .
F1 F 0.78586(17) 0.23027(17) 0.22357(18) 0.0470(5) Uani 1 1 d . . .
F2 F 0.52765(16) 0.08923(15) 0.13428(18) 0.0419(5) Uani 1 1 d . . .
F3 F 0.72307(19) 0.06207(19) 0.26491(18) 0.0519(6) Uani 1 1 d . . .
F4 F 0.58554(16) 0.25605(13) 0.09239(16) 0.0330(4) Uani 1 1 d . . .
F5 F 0.70773(16) 0.11143(14) 0.07280(15) 0.0333(4) Uani 1 1 d . . .
F6 F 0.6080(2) 0.2094(2) 0.28769(17) 0.0603(8) Uani 1 1 d . . .
C9 C 0.3744(2) 0.61963(19) 0.1459(2) 0.0190(5) Uani 1 1 d . . .
N2 N 0.4674(2) 0.83781(16) 0.16314(19) 0.0206(5) Uani 1 1 d . . .
C14 C 0.3312(2) 0.93539(19) 0.2983(2) 0.0196(5) Uani 1 1 d . . .
C15 C 0.3089(2) 0.86443(19) 0.3624(2) 0.0212(5) Uani 1 1 d . . .
C11 C 0.2140(2) 0.8151(2) 0.3022(3) 0.0243(6) Uani 1 1 d . . .
C16 C 0.1564(3) 0.7397(2) 0.3420(3) 0.0378(8) Uani 1 1 d . . .
H16A H 0.2097 0.7030 0.3912 0.057 Uiso 1 1 calc R . .
H16B H 0.1168 0.7017 0.2851 0.057 Uiso 1 1 calc R . .
H16C H 0.1057 0.7661 0.3753 0.057 Uiso 1 1 calc R . .
C12 C 0.1720(2) 0.8637(2) 0.2040(2) 0.0241(6) Uani 1 1 d . . .
C17 C 0.0681(3) 0.8388(3) 0.1223(3) 0.0416(9) Uani 1 1 d . . .
H17A H 0.0711 0.8621 0.0562 0.062 Uiso 1 1 calc R . .
H17B H 0.0062 0.8652 0.1398 0.062 Uiso 1 1 calc R . .
H17C H 0.0604 0.7729 0.1186 0.062 Uiso 1 1 calc R . .
C13 C 0.2435(2) 0.93665(19) 0.2009(2) 0.0212(5) Uani 1 1 d . . .
C18 C 0.2337(3) 1.0052(2) 0.1156(3) 0.0345(7) Uani 1 1 d . . .
H18A H 0.1889 0.9799 0.0513 0.052 Uiso 1 1 calc R . .
H18B H 0.3056 1.0191 0.1093 0.052 Uiso 1 1 calc R . .
H18C H 0.2001 1.0606 0.1314 0.052 Uiso 1 1 calc R . .
C20 C 0.3723(3) 0.8460(2) 0.4732(2) 0.0319(7) Uani 1 1 d . . .
H20A H 0.3448 0.8845 0.5183 0.048 Uiso 1 1 calc R . .
H20B H 0.4489 0.8591 0.4828 0.048 Uiso 1 1 calc R . .
H20C H 0.3639 0.7824 0.4893 0.048 Uiso 1 1 calc R . .
C19 C 0.4216(3) 1.0053(2) 0.3306(3) 0.0296(6) Uani 1 1 d . . .
H19A H 0.3941 1.0596 0.3555 0.044 Uiso 1 1 calc R . .
H19B H 0.4475 1.0208 0.2721 0.044 Uiso 1 1 calc R . .
H19C H 0.4812 0.9801 0.3850 0.044 Uiso 1 1 calc R . .
N1 N 0.30485(19) 0.69442(16) 0.11943(18) 0.0185(4) Uani 1 1 d . . .
C4 C 0.3696(2) 0.5450(2) 0.0766(2) 0.0233(6) Uani 1 1 d . . .
C3 C 0.2879(3) 0.5482(2) -0.0204(2) 0.0280(6) Uani 1 1 d . . .
H3 H 0.2813 0.5002 -0.0677 0.034 Uiso 1 1 calc R . .
C2 C 0.2189(3) 0.6222(2) -0.0443(2) 0.0284(6) Uani 1 1 d . . .
H2 H 0.1640 0.6243 -0.1074 0.034 Uiso 1 1 calc R . .
C1 C 0.2313(2) 0.6954(2) 0.0269(2) 0.0245(6) Uani 1 1 d . . .
H1 H 0.1858 0.7466 0.0081 0.029 Uiso 1 1 calc R . .
C5 C 0.4489(3) 0.4743(2) 0.1073(3) 0.0286(7) Uani 1 1 d . . .
H5 H 0.4476 0.4244 0.0634 0.034 Uiso 1 1 calc R . .
C6 C 0.5274(3) 0.4787(2) 0.2010(3) 0.0295(7) Uani 1 1 d . . .
H6 H 0.5800 0.4323 0.2197 0.035 Uiso 1 1 calc R . .
C7 C 0.5298(2) 0.5529(2) 0.2700(2) 0.0248(6) Uani 1 1 d . . .
H7 H 0.5835 0.5543 0.3339 0.030 Uiso 1 1 calc R . .
C8 C 0.4537(2) 0.62309(19) 0.2438(2) 0.0202(5) Uani 1 1 d . . .
C10 C 0.4501(2) 0.70540(19) 0.3112(2) 0.0214(5) Uani 1 1 d . . .
H10A H 0.5232 0.7319 0.3367 0.026 Uiso 1 1 calc R . .
H10B H 0.4263 0.6863 0.3707 0.026 Uiso 1 1 calc R . .
C21 C 0.5409(2) 0.8559(2) 0.1343(2) 0.0233(6) Uani 1 1 d . . .
C22 C 0.6357(3) 0.8785(3) 0.0973(3) 0.0356(7) Uani 1 1 d . . .
H22A H 0.6696 0.8227 0.0832 0.053 Uiso 1 1 calc R . .
H22B H 0.6881 0.9133 0.1496 0.053 Uiso 1 1 calc R . .
H22C H 0.6118 0.9144 0.0348 0.053 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N2 2.066(2) . ?
Rh1 C10 2.083(3) . ?
Rh1 N1 2.096(2) . ?
Rh1 C11 2.147(3) . ?
Rh1 C14 2.165(3) . ?
Rh1 C15 2.174(3) . ?
Rh1 C12 2.254(3) . ?
Rh1 C13 2.267(3) . ?
Sb1 F1 1.869(2) . ?
Sb1 F5 1.8689(18) . ?
Sb1 F3 1.871(2) . ?
Sb1 F6 1.872(2) . ?
Sb1 F4 1.8735(18) . ?
Sb1 F2 1.883(2) . ?
C9 N1 1.378(4) . ?
C9 C8 1.409(4) . ?
C9 C4 1.417(4) . ?
N2 C21 1.135(4) . ?
C14 C15 1.420(4) . ?
C14 C13 1.454(4) . ?
C14 C19 1.498(4) . ?
C15 C11 1.434(4) . ?
C15 C20 1.498(4) . ?
C11 C12 1.456(4) . ?
C11 C16 1.495(4) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C12 C13 1.401(4) . ?
C12 C17 1.497(4) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C13 C18 1.495(4) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
N1 C1 1.323(4) . ?
C4 C5 1.412(4) . ?
C4 C3 1.414(5) . ?
C3 C2 1.364(5) . ?
C3 H3 0.9300 . ?
C2 C1 1.407(4) . ?
C2 H2 0.9300 . ?
C1 H1 0.9300 . ?
C5 C6 1.364(5) . ?
C5 H5 0.9300 . ?
C6 C7 1.415(4) . ?
C6 H6 0.9300 . ?
C7 C8 1.377(4) . ?
C7 H7 0.9300 . ?
C8 C10 1.507(4) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C21 C22 1.460(4) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Rh1 C10 85.54(10) . . ?
N2 Rh1 N1 87.09(9) . . ?
C10 Rh1 N1 80.81(10) . . ?
N2 Rh1 C11 161.35(10) . . ?
C10 Rh1 C11 105.04(12) . . ?
N1 Rh1 C11 109.48(10) . . ?
N2 Rh1 C14 97.03(10) . . ?
C10 Rh1 C14 118.20(11) . . ?
N1 Rh1 C14 160.73(10) . . ?
C11 Rh1 C14 64.51(10) . . ?
N2 Rh1 C15 126.80(10) . . ?
C10 Rh1 C15 93.95(11) . . ?
N1 Rh1 C15 145.43(10) . . ?
C11 Rh1 C15 38.77(11) . . ?
C14 Rh1 C15 38.21(10) . . ?
N2 Rh1 C12 132.04(11) . . ?
C10 Rh1 C12 142.34(12) . . ?
N1 Rh1 C12 100.71(10) . . ?
C11 Rh1 C12 38.54(12) . . ?
C14 Rh1 C12 62.72(10) . . ?
C15 Rh1 C12 63.46(11) . . ?
N2 Rh1 C13 100.84(10) . . ?
C10 Rh1 C13 155.80(11) . . ?
N1 Rh1 C13 122.52(10) . . ?
C11 Rh1 C13 63.38(11) . . ?
C14 Rh1 C13 38.23(10) . . ?
C15 Rh1 C13 63.44(10) . . ?
C12 Rh1 C13 36.10(11) . . ?
F1 Sb1 F5 89.34(10) . . ?
F1 Sb1 F3 91.25(12) . . ?
F5 Sb1 F3 89.30(10) . . ?
F1 Sb1 F6 90.01(12) . . ?
F5 Sb1 F6 179.21(10) . . ?
F3 Sb1 F6 90.26(12) . . ?
F1 Sb1 F4 91.03(10) . . ?
F5 Sb1 F4 90.76(9) . . ?
F3 Sb1 F4 177.72(10) . . ?
F6 Sb1 F4 89.71(11) . . ?
F1 Sb1 F2 179.40(11) . . ?
F5 Sb1 F2 90.07(10) . . ?
F3 Sb1 F2 88.63(10) . . ?
F6 Sb1 F2 90.57(12) . . ?
F4 Sb1 F2 89.10(9) . . ?
N1 C9 C8 116.4(2) . . ?
N1 C9 C4 121.9(3) . . ?
C8 C9 C4 121.6(3) . . ?
C21 N2 Rh1 175.9(2) . . ?
C15 C14 C13 108.7(2) . . ?
C15 C14 C19 125.6(3) . . ?
C13 C14 C19 125.2(3) . . ?
C15 C14 Rh1 71.24(15) . . ?
C13 C14 Rh1 74.68(15) . . ?
C19 C14 Rh1 126.1(2) . . ?
C14 C15 C11 107.4(3) . . ?
C14 C15 C20 126.0(3) . . ?
C11 C15 C20 126.6(3) . . ?
C14 C15 Rh1 70.55(15) . . ?
C11 C15 Rh1 69.60(16) . . ?
C20 C15 Rh1 125.9(2) . . ?
C15 C11 C12 107.4(2) . . ?
C15 C11 C16 125.4(3) . . ?
C12 C11 C16 126.0(3) . . ?
C15 C11 Rh1 71.63(16) . . ?
C12 C11 Rh1 74.73(16) . . ?
C16 C11 Rh1 128.5(2) . . ?
C11 C16 H16A 109.5 . . ?
C11 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C11 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C13 C12 C11 108.7(3) . . ?
C13 C12 C17 127.0(3) . . ?
C11 C12 C17 124.3(3) . . ?
C13 C12 Rh1 72.43(16) . . ?
C11 C12 Rh1 66.73(16) . . ?
C17 C12 Rh1 127.4(2) . . ?
C12 C17 H17A 109.5 . . ?
C12 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C12 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C12 C13 C14 107.4(2) . . ?
C12 C13 C18 127.7(3) . . ?
C14 C13 C18 124.9(3) . . ?
C12 C13 Rh1 71.48(16) . . ?
C14 C13 Rh1 67.09(15) . . ?
C18 C13 Rh1 127.1(2) . . ?
C13 C18 H18A 109.5 . . ?
C13 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C13 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C15 C20 H20A 109.5 . . ?
C15 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C15 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C14 C19 H19A 109.5 . . ?
C14 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C14 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C1 N1 C9 118.5(2) . . ?
C1 N1 Rh1 126.3(2) . . ?
C9 N1 Rh1 114.76(18) . . ?
C5 C4 C3 124.5(3) . . ?
C5 C4 C9 118.0(3) . . ?
C3 C4 C9 117.5(3) . . ?
C2 C3 C4 119.6(3) . . ?
C2 C3 H3 120.2 . . ?
C4 C3 H3 120.2 . . ?
C3 C2 C1 119.6(3) . . ?
C3 C2 H2 120.2 . . ?
C1 C2 H2 120.2 . . ?
N1 C1 C2 122.8(3) . . ?
N1 C1 H1 118.6 . . ?
C2 C1 H1 118.6 . . ?
C6 C5 C4 120.4(3) . . ?
C6 C5 H5 119.8 . . ?
C4 C5 H5 119.8 . . ?
C5 C6 C7 120.9(3) . . ?
C5 C6 H6 119.6 . . ?
C7 C6 H6 119.6 . . ?
C8 C7 C6 120.8(3) . . ?
C8 C7 H7 119.6 . . ?
C6 C7 H7 119.6 . . ?
C7 C8 C9 118.2(3) . . ?
C7 C8 C10 124.8(3) . . ?
C9 C8 C10 116.9(2) . . ?
C8 C10 Rh1 109.90(19) . . ?
C8 C10 H10A 109.7 . . ?
Rh1 C10 H10A 109.7 . . ?
C8 C10 H10B 109.7 . . ?
Rh1 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
N2 C21 C22 179.6(3) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C10 Rh1 N2 C21 -40(3) . . . . ?
N1 Rh1 N2 C21 -121(3) . . . . ?
C11 Rh1 N2 C21 86(3) . . . . ?
C14 Rh1 N2 C21 78(3) . . . . ?
C15 Rh1 N2 C21 52(3) . . . . ?
C12 Rh1 N2 C21 137(3) . . . . ?
C13 Rh1 N2 C21 117(3) . . . . ?
N2 Rh1 C14 C15 -145.00(17) . . . . ?
C10 Rh1 C14 C15 -56.3(2) . . . . ?
N1 Rh1 C14 C15 113.6(3) . . . . ?
C11 Rh1 C14 C15 37.74(17) . . . . ?
C12 Rh1 C14 C15 80.92(18) . . . . ?
C13 Rh1 C14 C15 116.4(2) . . . . ?
N2 Rh1 C14 C13 98.61(16) . . . . ?
C10 Rh1 C14 C13 -172.69(16) . . . . ?
N1 Rh1 C14 C13 -2.8(4) . . . . ?
C11 Rh1 C14 C13 -78.65(18) . . . . ?
C15 Rh1 C14 C13 -116.4(2) . . . . ?
C12 Rh1 C14 C13 -35.46(16) . . . . ?
N2 Rh1 C14 C19 -24.1(3) . . . . ?
C10 Rh1 C14 C19 64.6(3) . . . . ?
N1 Rh1 C14 C19 -125.5(3) . . . . ?
C11 Rh1 C14 C19 158.7(3) . . . . ?
C15 Rh1 C14 C19 120.9(3) . . . . ?
C12 Rh1 C14 C19 -158.2(3) . . . . ?
C13 Rh1 C14 C19 -122.7(3) . . . . ?
C13 C14 C15 C11 5.7(3) . . . . ?
C19 C14 C15 C11 178.4(3) . . . . ?
Rh1 C14 C15 C11 -60.10(19) . . . . ?
C13 C14 C15 C20 -173.4(3) . . . . ?
C19 C14 C15 C20 -0.7(5) . . . . ?
Rh1 C14 C15 C20 120.8(3) . . . . ?
C13 C14 C15 Rh1 65.82(19) . . . . ?
C19 C14 C15 Rh1 -121.5(3) . . . . ?
N2 Rh1 C15 C14 45.3(2) . . . . ?
C10 Rh1 C15 C14 132.69(17) . . . . ?
N1 Rh1 C15 C14 -147.79(18) . . . . ?
C11 Rh1 C15 C14 -118.1(2) . . . . ?
C12 Rh1 C15 C14 -78.83(18) . . . . ?
C13 Rh1 C15 C14 -38.30(16) . . . . ?
N2 Rh1 C15 C11 163.38(16) . . . . ?
C10 Rh1 C15 C11 -109.24(18) . . . . ?
N1 Rh1 C15 C11 -29.7(3) . . . . ?
C14 Rh1 C15 C11 118.1(2) . . . . ?
C12 Rh1 C15 C11 39.25(17) . . . . ?
C13 Rh1 C15 C11 79.77(18) . . . . ?
N2 Rh1 C15 C20 -75.6(3) . . . . ?
C10 Rh1 C15 C20 11.8(3) . . . . ?
N1 Rh1 C15 C20 91.3(3) . . . . ?
C11 Rh1 C15 C20 121.0(3) . . . . ?
C14 Rh1 C15 C20 -120.9(3) . . . . ?
C12 Rh1 C15 C20 160.3(3) . . . . ?
C13 Rh1 C15 C20 -159.2(3) . . . . ?
C14 C15 C11 C12 -6.0(3) . . . . ?
C20 C15 C11 C12 173.1(3) . . . . ?
Rh1 C15 C11 C12 -66.73(19) . . . . ?
C14 C15 C11 C16 -174.6(3) . . . . ?
C20 C15 C11 C16 4.5(5) . . . . ?
Rh1 C15 C11 C16 124.7(3) . . . . ?
C14 C15 C11 Rh1 60.70(19) . . . . ?
C20 C15 C11 Rh1 -120.2(3) . . . . ?
N2 Rh1 C11 C15 -45.7(4) . . . . ?
C10 Rh1 C11 C15 77.24(18) . . . . ?
N1 Rh1 C11 C15 162.64(16) . . . . ?
C14 Rh1 C11 C15 -37.20(16) . . . . ?
C12 Rh1 C11 C15 -114.7(2) . . . . ?
C13 Rh1 C11 C15 -79.95(17) . . . . ?
N2 Rh1 C11 C12 69.0(4) . . . . ?
C10 Rh1 C11 C12 -168.05(17) . . . . ?
N1 Rh1 C11 C12 -82.65(17) . . . . ?
C14 Rh1 C11 C12 77.50(17) . . . . ?
C15 Rh1 C11 C12 114.7(2) . . . . ?
C13 Rh1 C11 C12 34.76(16) . . . . ?
N2 Rh1 C11 C16 -166.8(3) . . . . ?
C10 Rh1 C11 C16 -43.9(3) . . . . ?
N1 Rh1 C11 C16 41.5(3) . . . . ?
C14 Rh1 C11 C16 -158.3(4) . . . . ?
C15 Rh1 C11 C16 -121.1(4) . . . . ?
C12 Rh1 C11 C16 124.2(4) . . . . ?
C13 Rh1 C11 C16 159.0(4) . . . . ?
C15 C11 C12 C13 4.1(3) . . . . ?
C16 C11 C12 C13 172.6(3) . . . . ?
Rh1 C11 C12 C13 -60.5(2) . . . . ?
C15 C11 C12 C17 -174.9(3) . . . . ?
C16 C11 C12 C17 -6.4(5) . . . . ?
Rh1 C11 C12 C17 120.5(3) . . . . ?
C15 C11 C12 Rh1 64.65(19) . . . . ?
C16 C11 C12 Rh1 -126.8(3) . . . . ?
N2 Rh1 C12 C13 -36.2(2) . . . . ?
C10 Rh1 C12 C13 139.20(19) . . . . ?
N1 Rh1 C12 C13 -132.01(17) . . . . ?
C11 Rh1 C12 C13 120.1(2) . . . . ?
C14 Rh1 C12 C13 37.55(16) . . . . ?
C15 Rh1 C12 C13 80.61(18) . . . . ?
N2 Rh1 C12 C11 -156.30(16) . . . . ?
C10 Rh1 C12 C11 19.1(3) . . . . ?
N1 Rh1 C12 C11 107.90(17) . . . . ?
C14 Rh1 C12 C11 -82.54(18) . . . . ?
C15 Rh1 C12 C11 -39.48(17) . . . . ?
C13 Rh1 C12 C11 -120.1(2) . . . . ?
N2 Rh1 C12 C17 87.3(3) . . . . ?
C10 Rh1 C12 C17 -97.3(3) . . . . ?
N1 Rh1 C12 C17 -8.5(3) . . . . ?
C11 Rh1 C12 C17 -116.4(4) . . . . ?
C14 Rh1 C12 C17 161.1(4) . . . . ?
C15 Rh1 C12 C17 -155.9(4) . . . . ?
C13 Rh1 C12 C17 123.5(4) . . . . ?
C11 C12 C13 C14 -0.6(3) . . . . ?
C17 C12 C13 C14 178.4(3) . . . . ?
Rh1 C12 C13 C14 -57.65(18) . . . . ?
C11 C12 C13 C18 -180.0(3) . . . . ?
C17 C12 C13 C18 -1.0(5) . . . . ?
Rh1 C12 C13 C18 123.0(3) . . . . ?
C11 C12 C13 Rh1 57.03(19) . . . . ?
C17 C12 C13 Rh1 -124.0(3) . . . . ?
C15 C14 C13 C12 -3.2(3) . . . . ?
C19 C14 C13 C12 -175.9(3) . . . . ?
Rh1 C14 C13 C12 60.41(19) . . . . ?
C15 C14 C13 C18 176.2(3) . . . . ?
C19 C14 C13 C18 3.5(4) . . . . ?
Rh1 C14 C13 C18 -120.2(3) . . . . ?
C15 C14 C13 Rh1 -63.59(19) . . . . ?
C19 C14 C13 Rh1 123.7(3) . . . . ?
N2 Rh1 C13 C12 153.47(17) . . . . ?
C10 Rh1 C13 C12 -103.1(3) . . . . ?
N1 Rh1 C13 C12 60.0(2) . . . . ?
C11 Rh1 C13 C12 -37.08(18) . . . . ?
C14 Rh1 C13 C12 -118.9(2) . . . . ?
C15 Rh1 C13 C12 -80.65(19) . . . . ?
N2 Rh1 C13 C14 -87.61(16) . . . . ?
C10 Rh1 C13 C14 15.9(3) . . . . ?
N1 Rh1 C13 C14 178.91(15) . . . . ?
C11 Rh1 C13 C14 81.85(18) . . . . ?
C15 Rh1 C13 C14 38.28(16) . . . . ?
C12 Rh1 C13 C14 118.9(2) . . . . ?
N2 Rh1 C13 C18 29.8(3) . . . . ?
C10 Rh1 C13 C18 133.2(3) . . . . ?
N1 Rh1 C13 C18 -63.7(3) . . . . ?
C11 Rh1 C13 C18 -160.8(3) . . . . ?
C14 Rh1 C13 C18 117.4(3) . . . . ?
C15 Rh1 C13 C18 155.6(3) . . . . ?
C12 Rh1 C13 C18 -123.7(4) . . . . ?
C8 C9 N1 C1 178.0(2) . . . . ?
C4 C9 N1 C1 0.6(4) . . . . ?
C8 C9 N1 Rh1 5.2(3) . . . . ?
C4 C9 N1 Rh1 -172.17(19) . . . . ?
N2 Rh1 N1 C1 -94.5(2) . . . . ?
C10 Rh1 N1 C1 179.5(2) . . . . ?
C11 Rh1 N1 C1 76.7(2) . . . . ?
C14 Rh1 N1 C1 8.5(4) . . . . ?
C15 Rh1 N1 C1 95.9(3) . . . . ?
C12 Rh1 N1 C1 37.7(2) . . . . ?
C13 Rh1 N1 C1 6.5(3) . . . . ?
N2 Rh1 N1 C9 77.58(19) . . . . ?
C10 Rh1 N1 C9 -8.37(19) . . . . ?
C11 Rh1 N1 C9 -111.17(19) . . . . ?
C14 Rh1 N1 C9 -179.4(3) . . . . ?
C15 Rh1 N1 C9 -91.9(2) . . . . ?
C12 Rh1 N1 C9 -150.14(19) . . . . ?
C13 Rh1 N1 C9 178.59(17) . . . . ?
N1 C9 C4 C5 175.7(2) . . . . ?
C8 C9 C4 C5 -1.6(4) . . . . ?
N1 C9 C4 C3 -2.0(4) . . . . ?
C8 C9 C4 C3 -179.2(2) . . . . ?
C5 C4 C3 C2 -176.6(3) . . . . ?
C9 C4 C3 C2 0.9(4) . . . . ?
C4 C3 C2 C1 1.4(4) . . . . ?
C9 N1 C1 C2 1.9(4) . . . . ?
Rh1 N1 C1 C2 173.7(2) . . . . ?
C3 C2 C1 N1 -2.9(5) . . . . ?
C3 C4 C5 C6 177.4(3) . . . . ?
C9 C4 C5 C6 -0.1(4) . . . . ?
C4 C5 C6 C7 1.2(4) . . . . ?
C5 C6 C7 C8 -0.7(4) . . . . ?
C6 C7 C8 C9 -0.9(4) . . . . ?
C6 C7 C8 C10 -179.3(3) . . . . ?
N1 C9 C8 C7 -175.4(2) . . . . ?
C4 C9 C8 C7 2.0(4) . . . . ?
N1 C9 C8 C10 3.2(3) . . . . ?
C4 C9 C8 C10 -179.4(2) . . . . ?
C7 C8 C10 Rh1 168.7(2) . . . . ?
C9 C8 C10 Rh1 -9.8(3) . . . . ?
N2 Rh1 C10 C8 -78.49(19) . . . . ?
N1 Rh1 C10 C8 9.28(18) . . . . ?
C11 Rh1 C10 C8 117.12(19) . . . . ?
C14 Rh1 C10 C8 -174.08(17) . . . . ?
C15 Rh1 C10 C8 154.86(19) . . . . ?
C12 Rh1 C10 C8 104.9(2) . . . . ?
C13 Rh1 C10 C8 174.9(2) . . . . ?
Rh1 N2 C21 C22 77(54) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.64
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         3.765
_refine_diff_density_min         -0.769
_refine_diff_density_rms         0.106
