# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_bn_as1_120
_database_code_depnum_ccdc_archive 'CCDC 1491065'
_audit_update_record             
;
2016-07-06 deposited with the CCDC.
2016-08-16 downloaded from the CCDC.
;

_audit_creation_date             2016-07-06T11:07:16-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'

#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#

_chemical_formula_moiety         '(Fe C6 N6), (Ni C10 N4 H24), 6(H2 O)'
_chemical_formula_sum            'C16 H36 Fe N10 Ni O6'
_chemical_formula_weight         579.11

#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 2/m'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_Int_Tables_number      12
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   10.2754(3)
_cell_length_b                   16.2306(4)
_cell_length_c                   8.8043(3)
_cell_angle_alpha                90
_cell_angle_beta                 111.265(3)
_cell_angle_gamma                90
_cell_volume                     1368.37(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    3520
_cell_measurement_theta_min      4.073
_cell_measurement_theta_max      28.046

#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#

_exptl_crystal_description       irregular
_exptl_crystal_colour            green
_exptl_crystal_size_max          0.309
_exptl_crystal_size_mid          0.216
_exptl_crystal_size_min          0.13
_exptl_crystal_density_diffrn    1.406
_exptl_crystal_F_000             608
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-10 -11 -4 0.1239
-12 -1 -2 0.1275
12 -10 -7 0.1257
-4 16 9 0.081
6 -20 -5 0.0756
3 -22 -2 0.0601
4 10 9 0.0934
-3 22 2 0.0696
-2 -16 9 0.0975
4 21 -4 0.1006
5 10 -11 0.1247
0 -5 -11 0.0954
-5 -1 12 0.0997
11 14 -4 0.1291
-13 -5 8 0.1623
14 1 -5 0.1364
-5 12 10 0.0888
12 -13 -3 0.1082
1 -14 -9 0.0889
-11 1 -4 0.1184
8 -20 -3 0.0768
-5 20 6 0.0728
4 -22 -1 0.0591
-5 20 -2 0.0721
1 -21 5 0.082
-3 8 -9 0.0962
-2 -14 10 0.0977
-4 -10 -9 0.1
-10 -14 -2 0.1334
2 -2 -12 0.1091


#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#

_exptl_absorpt_coefficient_mu    1.265
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
        (compiled Mar 27 2014,17:12:48)
Numerical absorption correction based on gaussian integration over
                        a multifaceted crystal model
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_correction_T_min  0.761
_exptl_absorpt_correction_T_max  0.874
_shelx_estimated_absorpt_T_min   0.696
_shelx_estimated_absorpt_T_max   0.853

#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#

_diffrn_source                   'SuperNova (Mo) X-ray Source'
_diffrn_ambient_temperature      120(2)
_diffrn_ambient_environment      N~2~
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            Atlas
_diffrn_detector_area_resol_mean 10.3756
_diffrn_orient_matrix_ub_11      0.0142113
_diffrn_orient_matrix_ub_12      -0.039342
_diffrn_orient_matrix_ub_13      0.0373713
_diffrn_orient_matrix_ub_21      -0.0592985
_diffrn_orient_matrix_ub_22      0.0036668
_diffrn_orient_matrix_ub_23      0.02271
_diffrn_orient_matrix_ub_31      -0.0420384
_diffrn_orient_matrix_ub_32      -0.0186131
_diffrn_orient_matrix_ub_33      -0.0746214
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_reflns_av_R_equivalents  0.0366
_diffrn_reflns_av_unetI/netI     0.0502
_diffrn_reflns_number            8656
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         3.531
_diffrn_reflns_theta_max         28.666
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.945
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.945
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.945
_reflns_Friedel_coverage         0
_reflns_number_total             1722
_reflns_number_gt                1368
_reflns_threshold_expression     'I > 2σ(I)'

#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#

_computing_data_collection       
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
        (compiled Mar 27 2014,17:12:48)
;
_computing_cell_refinement       
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
        (compiled Mar 27 2014,17:12:48)
;
_computing_data_reduction        
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
        (compiled Mar 27 2014,17:12:48)
;
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'

#----------------------------------------------------------------------------#
#                   STRUCTURE SOLUTION                                       #
#----------------------------------------------------------------------------#

_atom_sites_solution_hydrogens   mixed

#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0241P)²+2.3556P] where P=(Fo²+2Fc²)/3'
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_number_reflns         1722
_refine_ls_number_parameters     98
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0462
_refine_ls_R_factor_gt           0.0307
_refine_ls_wR_factor_ref         0.0731
_refine_ls_wR_factor_gt          0.0654
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_restrained_S_all      1.067
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_diff_density_max         0.467
_refine_diff_density_min         -0.324
_refine_diff_density_rms         0.069

#----------------------------------------------------------------------------#
#                   CONSTRAINTS AND RESTRAINTS                               #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ni1 Ni 0.5 0.5 0.5 0.01243(13) Uani 1 4 d S T P . .
Fe1 Fe 1 0.5 0.5 0.01350(14) Uani 1 4 d S T P . .
N2 N 0.6955(2) 0.5 0.4816(3) 0.0169(5) Uani 1 2 d S T P . .
C2 C 0.8079(3) 0.5 0.4842(3) 0.0144(5) Uani 1 2 d S T P . .
N3 N 0.55916(17) 0.58876(11) 0.6648(2) 0.0189(4) Uani 1 1 d . . . . .
C1 C 0.96209(19) 0.58455(12) 0.3318(2) 0.0185(4) Uani 1 1 d . . . . .
N1 N 0.93915(19) 0.63214(12) 0.2325(2) 0.0289(4) Uani 1 1 d . . . . .
C5 C 0.6840(3) 0.5 0.9024(4) 0.0311(7) Uani 1 2 d S T P . .
H5B H 0.7642 0.5 1.0073 0.037 Uiso 1 2 calc R U P . .
H5A H 0.5974 0.5 0.9274 0.037 Uiso 1 2 calc R U P . .
C3 C 0.5632(2) 0.66627(13) 0.5767(3) 0.0272(5) Uani 1 1 d . . . . .
H3B H 0.6492 0.6685 0.5509 0.033 Uiso 1 1 calc R U . . .
H3A H 0.5619 0.7147 0.6446 0.033 Uiso 1 1 calc R U . . .
C4 C 0.6884(2) 0.57766(15) 0.8104(3) 0.0284(5) Uani 1 1 d . . . . .
H4A H 0.7006 0.6257 0.8836 0.034 Uiso 1 1 calc R U . . .
H4B H 0.7698 0.5755 0.7757 0.034 Uiso 1 1 calc R U . . .
O2 O 1 0.72702(14) 0 0.0281(5) Uani 1 2 d S T P . .
O1 O 0.3667(2) 0.64693(16) 0.7974(3) 0.0642(8) Uani 1 1 d . . . . .
H3 H 0.493(4) 0.594(2) 0.697(5) 0.096 Uiso 1 1 d . U . . .
H2A H 0.975(4) 0.695(2) 0.059(4) 0.096 Uiso 1 1 d . U . . .
H1A H 0.387(4) 0.685(3) 0.849(5) 0.096 Uiso 1 1 d . U . . .
H1B H 0.290(4) 0.644(3) 0.788(5) 0.096 Uiso 1 1 d . U . . .



#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ni1 N3 1.9776(17) 5_666 ?
Ni1 N3 1.9776(16) 6_565 ?
Ni1 N3 1.9776(17) 2_656 ?
Ni1 N3 1.9776(17) . ?
Ni1 N2 2.073(2) . ?
Ni1 N2 2.073(2) 5_666 ?
Fe1 C2 1.928(3) 5_766 ?
Fe1 C2 1.928(3) . ?
Fe1 C1 1.952(2) . ?
Fe1 C1 1.952(2) 6_565 ?
Fe1 C1 1.952(2) 2_756 ?
Fe1 C1 1.952(2) 5_766 ?
N2 C2 1.147(3) . ?
N3 C4 1.485(3) . ?
N3 C3 1.486(3) . ?
N3 H3 0.83(4) . ?
C1 N1 1.125(3) . ?
C5 C4 1.508(3) 6_565 ?
C5 C4 1.508(3) . ?
C5 H5B 0.99 . ?
C5 H5A 0.99 . ?
C3 C3 1.497(4) 2_656 ?
C3 H3B 0.99 . ?
C3 H3A 0.99 . ?
C4 H4A 0.99 . ?
C4 H4B 0.99 . ?
O2 H2A 0.84(3) . ?
O1 H1A 0.75(4) . ?
O1 H1B 0.76(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ni1 N3 86.48(10) 5_666 6_565 ?
N3 Ni1 N3 93.52(10) 5_666 2_656 ?
N3 Ni1 N3 180 6_565 2_656 ?
N3 Ni1 N3 180 5_666 . ?
N3 Ni1 N3 93.52(10) 6_565 . ?
N3 Ni1 N3 86.48(10) 2_656 . ?
N3 Ni1 N2 89.50(6) 5_666 . ?
N3 Ni1 N2 90.50(6) 6_565 . ?
N3 Ni1 N2 89.50(6) 2_656 . ?
N3 Ni1 N2 90.50(6) . . ?
N3 Ni1 N2 90.50(6) 5_666 5_666 ?
N3 Ni1 N2 89.50(6) 6_565 5_666 ?
N3 Ni1 N2 90.50(6) 2_656 5_666 ?
N3 Ni1 N2 89.50(6) . 5_666 ?
N2 Ni1 N2 180 . 5_666 ?
C2 Fe1 C2 180 5_766 . ?
C2 Fe1 C1 88.40(8) 5_766 . ?
C2 Fe1 C1 91.60(8) . . ?
C2 Fe1 C1 88.40(8) 5_766 6_565 ?
C2 Fe1 C1 91.60(8) . 6_565 ?
C1 Fe1 C1 89.34(11) . 6_565 ?
C2 Fe1 C1 91.60(8) 5_766 2_756 ?
C2 Fe1 C1 88.40(8) . 2_756 ?
C1 Fe1 C1 90.66(11) . 2_756 ?
C1 Fe1 C1 180 6_565 2_756 ?
C2 Fe1 C1 91.60(8) 5_766 5_766 ?
C2 Fe1 C1 88.40(8) . 5_766 ?
C1 Fe1 C1 180.00(11) . 5_766 ?
C1 Fe1 C1 90.66(11) 6_565 5_766 ?
C1 Fe1 C1 89.34(11) 2_756 5_766 ?
C2 N2 Ni1 174.7(2) . . ?
N2 C2 Fe1 177.2(2) . . ?
C4 N3 C3 111.56(16) . . ?
C4 N3 Ni1 119.06(14) . . ?
C3 N3 Ni1 107.04(12) . . ?
C4 N3 H3 108(3) . . ?
C3 N3 H3 106(3) . . ?
Ni1 N3 H3 105(3) . . ?
N1 C1 Fe1 178.64(19) . . ?
C4 C5 C4 113.4(3) 6_565 . ?
C4 C5 H5B 108.9 6_565 . ?
C4 C5 H5B 108.9 . . ?
C4 C5 H5A 108.9 6_565 . ?
C4 C5 H5A 108.9 . . ?
H5B C5 H5A 107.7 . . ?
N3 C3 C3 106.95(13) . 2_656 ?
N3 C3 H3B 110.3 . . ?
C3 C3 H3B 110.3 2_656 . ?
N3 C3 H3A 110.3 . . ?
C3 C3 H3A 110.3 2_656 . ?
H3B C3 H3A 108.6 . . ?
N3 C4 C5 111.92(19) . . ?
N3 C4 H4A 109.2 . . ?
C5 C4 H4A 109.2 . . ?
N3 C4 H4B 109.2 . . ?
C5 C4 H4B 109.2 . . ?
H4A C4 H4B 107.9 . . ?
H1A O1 H1B 100(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 N3 C3 C3 173.56(19) . . . 2_656 ?
Ni1 N3 C3 C3 41.7(2) . . . 2_656 ?
C3 N3 C4 C5 178.86(18) . . . . ?
Ni1 N3 C4 C5 -55.7(2) . . . . ?
C4 C5 C4 N3 68.0(3) 6_565 . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N3 H3 O1 0.83(4) 2.01(4) 2.800(2) 159(4) .
O2 H2A N1 0.84(3) 1.97(3) 2.808(2) 169(4) .
O1 H1A O2 0.75(4) 2.01(4) 2.734(3) 162(4) 7_666
O1 H1B N1 0.76(4) 2.30(4) 3.066(3) 178(4) 2_656

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_nicr
_database_code_depnum_ccdc_archive 'CCDC 1491755'
_audit_update_record             
;
2016-07-08 deposited with the CCDC.
2016-08-16 downloaded from the CCDC.
;

_audit_creation_date             2016-07-08T22:14:31-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'

#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#

_chemical_formula_sum            'C16 H36 Cr N10 Ni O6'
_chemical_formula_weight         575.26

#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 2/m'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_Int_Tables_number      12
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   10.5579(5)
_cell_length_b                   16.3314(6)
_cell_length_c                   8.8748(4)
_cell_angle_alpha                90
_cell_angle_beta                 112.254(3)
_cell_angle_gamma                90
_cell_volume                     1416.26(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    1883
_cell_measurement_theta_min      3.52
_cell_measurement_theta_max      23.47

#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#

_exptl_crystal_description       block
_exptl_crystal_colour            green
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.07
_exptl_crystal_density_diffrn    1.349
_exptl_crystal_F_000             604

#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#

_exptl_absorpt_coefficient_mu    1.094
_exptl_absorpt_correction_type   none

#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#

_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_reflns_av_R_equivalents  0.0628
_diffrn_reflns_av_unetI/netI     0.0426
_diffrn_reflns_number            6570
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_theta_min         3.518
_diffrn_reflns_theta_max         24.806
_diffrn_reflns_theta_full        24.806
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_reflns_Friedel_coverage         0
_reflns_number_total             1265
_reflns_number_gt                979
_reflns_threshold_expression     'I > 2σ(I)'

#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#

_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'

#----------------------------------------------------------------------------#
#                   STRUCTURE SOLUTION                                       #
#----------------------------------------------------------------------------#

_atom_sites_solution_hydrogens   mixed

#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0110P)²+4.2646P] where P=(Fo²+2Fc²)/3'
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_number_reflns         1265
_refine_ls_number_parameters     95
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0585
_refine_ls_R_factor_gt           0.0367
_refine_ls_wR_factor_ref         0.0679
_refine_ls_wR_factor_gt          0.0618
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_diff_density_max         0.316
_refine_diff_density_min         -0.427
_refine_diff_density_rms         0.069

#----------------------------------------------------------------------------#
#                   CONSTRAINTS AND RESTRAINTS                               #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cr1 Cr 0.5 0.5 0 0.0116(2) Uani 1 4 d S T P . .
Ni1 Ni 0 0.5 0 0.0100(2) Uani 1 4 d S T P . .
C2 C 0.2995(5) 0.5 -0.0162(5) 0.0162(10) Uani 1 2 d S T P . .
C1 C 0.5435(3) 0.58897(19) 0.1797(4) 0.0174(7) Uani 1 1 d . . . . .
C3 C 0.0619(3) 0.66550(17) 0.0775(4) 0.0232(7) Uani 1 1 d . . . . .
H3A H 0.1462 0.6682 0.0537 0.028 Uiso 1 1 calc R U . . .
H3B H 0.0601 0.7134 0.1451 0.028 Uiso 1 1 calc R U . . .
C4 C 0.1849(3) 0.5770(2) 0.3116(4) 0.0253(8) Uani 1 1 d . . . . .
H4A H 0.1971 0.6249 0.3842 0.03 Uiso 1 1 calc R U . . .
H4B H 0.2647 0.5746 0.279 0.03 Uiso 1 1 calc R U . . .
C5 C 0.1806(5) 0.5 0.4037(5) 0.0282(11) Uani 1 2 d S T P . .
H5A H 0.0958 0.5 0.4266 0.034 Uiso 1 2 calc R U P . .
H5B H 0.2594 0.5 0.5093 0.034 Uiso 1 2 calc R U P . .
N2 N 0.1917(4) 0.5 -0.0152(4) 0.0141(8) Uani 1 2 d S T P . .
N1 N 0.5705(3) 0.63713(16) 0.2803(3) 0.0263(6) Uani 1 1 d . . . . .
N3 N 0.0586(3) 0.58824(15) 0.1643(3) 0.0176(6) Uani 1 1 d . . . . .
H3 H -0.0173 0.5948 0.2046 0.021 Uiso 1 1 calc R U . . .
O1 O 0.6302(3) 0.8550(2) 0.7067(4) 0.0684(12) Uani 1 1 d . . . . .
H1B H 0.701(6) 0.862(3) 0.728(7) 0.103 Uiso 1 1 d . U . . .
H1A H 0.602(5) 0.817(3) 0.648(6) 0.103 Uiso 1 1 d . U . . .
O2 O 0.5 0.73187(17) 0.5 0.0279(8) Uani 1 2 d S T P . .
H2A H 0.523(4) 0.701(2) 0.443(4) 0.042 Uiso 1 1 d . U . . .



#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cr1 C2 2.066(5) 5_665 ?
Cr1 C2 2.066(5) . ?
Cr1 C1 2.076(3) 5_665 ?
Cr1 C1 2.076(3) 6_565 ?
Cr1 C1 2.076(3) 2_655 ?
Cr1 C1 2.076(3) . ?
Ni1 N3 1.976(2) . ?
Ni1 N3 1.976(2) 5_565 ?
Ni1 N3 1.976(2) 6_565 ?
Ni1 N3 1.976(2) 2 ?
Ni1 N2 2.078(4) 5_565 ?
Ni1 N2 2.078(4) . ?
C2 N2 1.142(4) . ?
C1 N1 1.142(4) . ?
C3 N3 1.486(4) . ?
C3 C3 1.496(6) 2 ?
C3 H3A 0.99 . ?
C3 H3B 0.99 . ?
C4 N3 1.483(4) . ?
C4 C5 1.510(4) . ?
C4 H4A 0.99 . ?
C4 H4B 0.99 . ?
C5 C4 1.510(4) 6_565 ?
C5 H5A 0.99 . ?
C5 H5B 0.99 . ?
N3 H3 1 . ?
O1 H1B 0.71(5) . ?
O1 H1A 0.79(5) . ?
O2 H2A 0.82(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Cr1 C2 180 5_665 . ?
C2 Cr1 C1 88.65(12) 5_665 5_665 ?
C2 Cr1 C1 91.35(12) . 5_665 ?
C2 Cr1 C1 91.35(12) 5_665 6_565 ?
C2 Cr1 C1 88.65(12) . 6_565 ?
C1 Cr1 C1 91.18(17) 5_665 6_565 ?
C2 Cr1 C1 88.65(12) 5_665 2_655 ?
C2 Cr1 C1 91.35(12) . 2_655 ?
C1 Cr1 C1 88.82(17) 5_665 2_655 ?
C1 Cr1 C1 180.00(12) 6_565 2_655 ?
C2 Cr1 C1 91.35(12) 5_665 . ?
C2 Cr1 C1 88.65(12) . . ?
C1 Cr1 C1 180 5_665 . ?
C1 Cr1 C1 88.82(17) 6_565 . ?
C1 Cr1 C1 91.18(17) 2_655 . ?
N3 Ni1 N3 180.00(18) . 5_565 ?
N3 Ni1 N3 93.68(15) . 6_565 ?
N3 Ni1 N3 86.32(15) 5_565 6_565 ?
N3 Ni1 N3 86.32(15) . 2 ?
N3 Ni1 N3 93.68(15) 5_565 2 ?
N3 Ni1 N3 180.00(10) 6_565 2 ?
N3 Ni1 N2 89.58(10) . 5_565 ?
N3 Ni1 N2 90.42(10) 5_565 5_565 ?
N3 Ni1 N2 89.58(10) 6_565 5_565 ?
N3 Ni1 N2 90.42(10) 2 5_565 ?
N3 Ni1 N2 90.42(10) . . ?
N3 Ni1 N2 89.58(10) 5_565 . ?
N3 Ni1 N2 90.42(10) 6_565 . ?
N3 Ni1 N2 89.58(10) 2 . ?
N2 Ni1 N2 180 5_565 . ?
N2 C2 Cr1 175.9(3) . . ?
N1 C1 Cr1 178.4(3) . . ?
N3 C3 C3 107.1(2) . 2 ?
N3 C3 H3A 110.3 . . ?
C3 C3 H3A 110.3 2 . ?
N3 C3 H3B 110.3 . . ?
C3 C3 H3B 110.3 2 . ?
H3A C3 H3B 108.6 . . ?
N3 C4 C5 112.2(3) . . ?
N3 C4 H4A 109.2 . . ?
C5 C4 H4A 109.2 . . ?
N3 C4 H4B 109.2 . . ?
C5 C4 H4B 109.2 . . ?
H4A C4 H4B 107.9 . . ?
C4 C5 C4 112.8(4) . 6_565 ?
C4 C5 H5A 109 . . ?
C4 C5 H5A 109 6_565 . ?
C4 C5 H5B 109 . . ?
C4 C5 H5B 109 6_565 . ?
H5A C5 H5B 107.8 . . ?
C2 N2 Ni1 177.0(3) . . ?
C4 N3 C3 111.9(2) . . ?
C4 N3 Ni1 119.09(19) . . ?
C3 N3 Ni1 107.39(18) . . ?
C4 N3 H3 105.9 . . ?
C3 N3 H3 105.9 . . ?
Ni1 N3 H3 105.9 . . ?
H1B O1 H1A 113(6) . . ?


####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1491756'
_audit_update_record             
;
2016-07-08 deposited with the CCDC.
2016-08-16 downloaded from the CCDC.
;


# 5. CHEMICAL DATA

_chemical_name_systematic        
; ?
;
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_formula_iupac          ?
_chemical_formula_sum            'C16 Cr N10 Ni'
_chemical_formula_weight         442.95
_chemical_melting_point          ?
_chemical_compound_source        ?
_chemical_absolute_configuration .

#=======================================================================

# 6. POWDER SPECIMEN AND CRYSTAL DATA

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21 1'
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_Int_Tables_number      4

loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y+1/2,-z



_cell_length_a                   9.8002(14)
_cell_length_b                   11.9983(17)
_cell_length_c                   10.1260(11)
_cell_angle_alpha                90
_cell_angle_beta                 102.646(19)
_cell_angle_gamma                90
_cell_volume                     1161.8(3)
_cell_measurement_reflns_used    2171
_cell_measurement_theta_min      3.001
_cell_measurement_theta_max      59.987


_cell_formula_units_Z            2
_cell_measurement_temperature    293
_cell_special_details            
; ?
;

_exptl_crystal_density_diffrn    1.266
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             436.0

_pd_spec_size_axial              ?
_pd_spec_size_equat              ?
_pd_spec_size_thick              ?
_pd_spec_mounting                ?
_pd_spec_mount_mode              ?
_pd_spec_shape                   ?
_pd_char_particle_morphology     ?
_pd_char_colour                  green
_pd_prep_cool_rate               ?
_pd_prep_pressure                ?
_pd_prep_temperature             ?

_exptl_absorpt_coefficient_mu    5.032
_exptl_absorpt_correction_type   ?
_exptl_absorpt_process_details   '(Jana2006; Petricek, Dusek, Palatinus 2014)'
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
#=======================================================================

# 7. EXPERIMENTAL DATA

_exptl_special_details           ?
_pd_instr_location               
; ?
;
_pd_calibration_special_details  
; ?
;

_diffrn_ambient_temperature      293
_diffrn_source                   ?
_diffrn_source_target            ?
_diffrn_source_type              ?
_diffrn_radiation_type           'CuKa radiation'
_diffrn_radiation_wavelength     1.5418
_diffrn_radiation_monochromator  ?
_diffrn_measurement_device       ?
_diffrn_measurement_device_type  'PANalytical X?Pert PRO MPD'
_diffrn_detector                 ?
_diffrn_detector_type            ?

_pd_meas_scan_method             ?
_pd_meas_special_details         
; ?
;
_pd_meas_number_of_points        2171
_pd_meas_2theta_range_min        3.001
_pd_meas_2theta_range_max        59.987
_pd_meas_2theta_range_inc        0.026

_diffrn_radiation_probe          X-ray

#=======================================================================

# 8. REFINEMENT DATA

_pd_proc_ls_special_details      
; ?
;
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_background_function  '8 Legendre polynoms'
_pd_proc_ls_pref_orient_corr     'March & Dollase'
_pd_proc_ls_prof_R_factor        0.0973
_pd_proc_ls_prof_wR_factor       0.1338
_pd_proc_ls_prof_wR_expected     0.0397

_refine_special_details          
; ?
;

_refine_ls_R_factor_gt           0.1852
_refine_ls_wR_factor_gt          0.1839
_refine_ls_R_factor_all          0.2233
_refine_ls_wR_factor_all         0.1895
_refine_ls_goodness_of_fit_all   3.37
_refine_ls_restrained_S_gt       ?
_refine_ls_restrained_S_all      ?
_refine_ls_number_parameters     23
_refine_ls_number_restraints     0
_refine_ls_number_constraints    1
_refine_ls_weighting_scheme      sigma
_refine_ls_weighting_details     ?
_refine_ls_hydrogen_treatment    ?
_refine_ls_shift/su_max          0.0903
_refine_ls_shift/su_mean         0.0204
_refine_diff_density_max         ?
_refine_diff_density_min         ?
_refine_ls_extinction_method     ?
_refine_ls_extinction_coef       ?

_pd_proc_2theta_range_min        8.017
_pd_proc_2theta_range_max        59.987
_pd_proc_2theta_range_inc        0.026
_pd_proc_wavelength              ?

_pd_block_diffractogram_id       ?

loop_
_pd_proc_info_excluded_regions
'from 2.998 to 8.000'
_pd_proc_info_data_reduction     ?

loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C 0.0181 0.0091 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Cr -0.1635 2.4439 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
N 0.0311 0.0180 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Ni -3.0029 0.5091 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_structure_solution    ?
_computing_structure_refinement  '(Jana2000; Petricek and Dusek, 2000)'
_computing_molecular_graphics    ?
_computing_publication_material  '(Jana2000; Petricek and Dusek, 2000)'



#=======================================================================

# 9. ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_adp_type
_atom_site_U_iso_or_equiv
_atom_site_site_symmetry_multiplicity
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N -0.068(2) 0.887(5) 1.225(8) Uiso 0.0172(18) 2 1 d . . .
C1 C 0.0485(19) 0.881(4) 1.225(7) Uiso 0.0172(18) 2 1 d . . .
Cr1 Cr 0.2602(18) 0.867(3) 1.246(4) Uiso 0.0172(18) 2 1 d . . .
C2 C 0.216(3) 1.034(3) 1.253(7) Uiso 0.0172(18) 2 1 d . . .
N2 N 0.194(5) 1.128(3) 1.251(8) Uiso 0.0172(18) 2 1 d . . .
C3 C 0.237(3) 0.897(4) 1.437(6) Uiso 0.0172(18) 2 1 d . . .
N3 N 0.230(5) 0.907(5) 1.546(7) Uiso 0.0172(18) 2 1 d . . .
C4 C 0.264(3) 0.904(4) 1.051(6) Uiso 0.0172(18) 2 1 d . . .
C5 C 0.474(2) 0.879(4) 1.294(7) Uiso 0.0172(18) 2 1 d . . .
C6 C 0.288(3) 0.698(3) 1.241(7) Uiso 0.0172(18) 2 1 d . . .
N4 N 0.266(5) 0.917(5) 0.941(7) Uiso 0.0172(18) 2 1 d . . .
N5 N 0.592(2) 0.878(5) 1.308(8) Uiso 0.0172(18) 2 1 d . . .
N6 N 0.309(5) 0.606(3) 1.230(8) Uiso 0.0172(18) 2 1 d . . .
C7 C 0.454(6) 0.723(4) 0.761(5) Uiso 0.010(10) 2 1 d . . .
C8 C 0.298(7) 0.701(2) 0.706(5) Uiso 0.010(10) 2 1 d . . .
N7 N 0.210(5) 0.776(2) 0.767(4) Uiso 0.010(10) 2 1 d . . .
C9 C 0.057(5) 0.759(4) 0.718(5) Uiso 0.010(10) 2 1 d . . .
C10 C -0.018(3) 0.853(5) 0.767(5) Uiso 0.010(10) 2 1 d . . .
N8 N 0.029(2) 0.959(4) 0.716(5) Uiso 0.010(10) 2 1 d . . .
C11 C -0.023(4) 1.059(5) 0.775(5) Uiso 0.010(10) 2 1 d . . .
C12 C 0.033(6) 1.167(4) 0.727(5) Uiso 0.010(10) 2 1 d . . .
C13 C 0.189(7) 1.189(2) 0.781(5) Uiso 0.010(10) 2 1 d . . .
N9 N 0.277(5) 1.114(2) 0.720(4) Uiso 0.010(10) 2 1 d . . .
Ni1 Ni 0.243(2) 0.945(2) 0.744(4) Uiso 0.010(10) 2 1 d . . .
N10 N 0.458(2) 0.931(4) 0.771(5) Uiso 0.010(10) 2 1 d . . .
C14 C 0.505(3) 1.037(5) 0.721(5) Uiso 0.010(10) 2 1 d . . .
C15 C 0.430(5) 1.131(4) 0.770(5) Uiso 0.010(10) 2 1 d . . .
C16 C 0.510(4) 0.830(5) 0.712(5) Uiso 0.010(10) 2 1 d . . .


# 10. MOLECULAR GEOMETRY


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
N1 C1 . . 1.14(4) ?
C1 Cr1 . . 2.05(3) ?
Cr1 C2 . . 2.05(5) ?
Cr1 C3 . . 2.03(9) ?
Cr1 C4 . . 2.03(9) ?
Cr1 C5 . . 2.04(3) ?
Cr1 C6 . . 2.05(5) ?
C2 N2 . . 1.14(5) ?
C3 N3 . . 1.13(9) ?
N3 Ni1 . 1_556 2.03(8) ?
C4 N4 . . 1.13(9) ?
C5 N5 . . 1.14(3) ?
C6 N6 . . 1.14(5) ?
N4 Nii . . 1.99(8) ?
C7 C8 . . 1.52(8) ?
C7 C16 . . 1.52(8) ?
C8 N7 . . 1.48(7) ?
N7 C9 . . 1.49(7) ?
N7 Ni1 . . 2.08(4) ?
C9 C10 . . 1.49(7) ?
C10 N8 . . 1.48(7) ?
N8 C11 . . 1.48(7) ?
N8 Ni1 . . 2.06(3) ?
C11 C12 . . 1.53(8) ?
C12 C13 . . 1.52(8) ?
C13 N9 . . 1.47(7) ?
N9 Ni1 . . 2.08(4) ?
N9 C15 . . 1.49(7) ?
Ni1 N10 . . 2.07(3) ?
N10 C14 . . 1.48(7) ?
N10 C16 . . 1.49(7) ?
C14 C15 . . 1.49(7) ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N1 C1 Cr1 . . . 174(7) ?
C1 Cr1 C2 . . . 72.9(18) ?
C1 Cr1 C3 . . . 76(3) ?
C1 Cr1 C4 . . . 97(3) ?
C1 Cr1 C5 . . . 168(4) ?
C1 Cr1 C6 . . . 102.3(19) ?
C2 Cr1 C3 . . . 74(3) ?
C2 Cr1 C4 . . . 83(3) ?
C2 Cr1 C5 . . . 98.1(19) ?
C2 Cr1 C6 . . . 175(2) ?
C3 Cr1 C4 . . . 157(3) ?
C3 Cr1 C5 . . . 95(3) ?
C3 Cr1 C6 . . . 104(3) ?
C4 Cr1 C5 . . . 89(3) ?
C4 Cr1 C6 . . . 99(3) ?
C5 Cr1 C6 . . . 86.4(18) ?
Cr1 C2 N2 . . . 176(7) ?
Cr1 C3 N3 . . . 175(4) ?
C3 N3 Ni1 . . 1_556 170(5) ?
Cr1 C4 N4 . . . 176(5) ?
Cr1 C5 N5 . . . 172(7) ?
Cr1 C6 N6 . . . 174(7) ?
C4 N4 Ni1 . . . 173(4) ?
C8 C7 C16 . . . 116(4) ?
C7 C8 N7 . . . 112(4) ?
C8 N7 C9 . . . 114(4) ?
C8 N7 Ni1 . . . 115(3) ?
C9 N7 Ni1 . . . 106(3) ?
N7 C9 C10 . . . 109(3) ?
C9 C10 N8 . . . 109(4) ?
C10 N8 C11 . . . 113(4) ?
C10 N8 Ni1 . . . 106(3) ?
C11 N8 Ni1 . . . 116(3) ?
N8 C11 C12 . . . 112(4) ?
C11 C12 C13 . . . 116(4) ?
C12 C13 N9 . . . 112(4) ?
C13 N9 Ni1 . . . 115(3) ?
C13 N9 C15 . . . 115(4) ?
Ni1 N9 C15 . . . 105(3) ?
N3 Ni1 N4 1_554 . . 157(3) ?
N3 Ni1 N7 1_554 . . 85(2) ?
N3 Ni1 N8 1_554 . . 92(2) ?
N3 Ni1 N9 1_554 . . 95(3) ?
N3 Ni1 N10 1_554 . . 88(2) ?
N4 Ni1 N7 . . . 73(2) ?
N4 Ni1 N8 . . . 92(2) ?
N4 Ni1 N9 . . . 107(3) ?
N4 Ni1 N10 . . . 88(2) ?
N7 Ni1 N8 . . . 85(2) ?
N7 Ni1 N9 . . . 180.0(5) ?
N7 Ni1 N10 . . . 95(2) ?
N8 Ni1 N9 . . . 95(2) ?
N8 Ni1 N10 . . . 180(3) ?
N9 Ni1 N10 . . . 85(2) ?
Ni1 N10 C14 . . . 106(3) ?
Ni1 N10 C16 . . . 116(3) ?
C14 N10 C16 . . . 114(4) ?
N10 C14 C15 . . . 109(4) ?
N9 C15 C14 . . . 109(3) ?
C7 C16 N10 . . . 112(4) ?


#=======================================================================

# 11. POWDER PROFILE

loop_
_pd_proc_point_id
_pd_proc_2theta_corrected
_pd_proc_intensity_net
_pd_calc_intensity_net
_pd_proc_ls_weight
1 8.0412 535.00 632.54 23.13
2 8.0674 539.00 630.74 23.22
3 8.0937 539.00 628.96 23.22
4 8.1200 588.00 627.21 24.25
5 8.1462 531.00 625.48 23.04
6 8.1725 593.00 623.78 24.35
7 8.1987 538.00 622.11 23.19
8 8.2250 591.00 620.46 24.31
9 8.2513 587.00 618.84 24.23
10 8.2775 530.00 617.27 23.02
11 8.3038 575.00 615.71 23.98
12 8.3300 543.00 614.17 23.30
13 8.3563 579.00 612.65 24.06
14 8.3826 556.00 611.15 23.58
15 8.4088 576.00 609.68 24.00
16 8.4351 605.00 608.24 24.60
17 8.4613 571.00 606.82 23.90
18 8.4876 595.00 605.42 24.39
19 8.5139 594.00 604.05 24.37
20 8.5401 593.00 602.71 24.35
21 8.5664 637.00 601.50 25.24
22 8.5926 525.00 600.27 22.91
23 8.6189 587.00 599.03 24.23
24 8.6452 584.00 597.81 24.17
25 8.6714 578.00 596.62 24.04
26 8.6977 585.00 595.47 24.19
27 8.7240 565.00 594.37 23.77
28 8.7502 574.00 593.32 23.96
29 8.7765 549.00 592.35 23.43
30 8.8027 580.00 591.48 24.08
31 8.8290 577.00 590.87 24.02
32 8.8553 600.00 591.12 24.49
33 8.8815 604.00 594.05 24.58
34 8.9078 616.00 601.79 24.82
35 8.9340 614.00 611.31 24.78
36 8.9603 617.00 611.51 24.84
37 8.9866 596.00 601.24 24.41
38 9.0128 568.00 591.11 23.83
39 9.0391 560.00 585.77 23.66
40 9.0653 573.00 583.69 23.94
41 9.0916 644.00 582.98 25.38
42 9.1179 718.00 583.19 26.80
43 9.1441 660.00 585.62 25.69
44 9.1704 701.00 595.52 26.48
45 9.1966 674.00 621.73 25.96
46 9.2229 691.00 661.66 26.29
47 9.2492 658.00 679.65 25.65
48 9.2754 629.00 651.89 25.08
49 9.3017 635.00 612.03 25.20
50 9.3279 653.00 587.85 25.55
51 9.3542 609.00 578.13 24.68
52 9.3805 564.00 574.47 23.75
53 9.4067 574.00 572.56 23.96
54 9.4330 604.00 571.18 24.58
55 9.4592 621.00 570.06 24.92
56 9.4855 555.00 569.09 23.56
57 9.5118 591.00 568.23 24.31
58 9.5380 579.00 567.45 24.06
59 9.5643 601.00 566.73 24.52
60 9.5905 570.00 566.05 23.87
61 9.6168 628.00 565.42 25.06
62 9.6431 551.00 564.78 23.47
63 9.6693 520.00 564.20 22.80
64 9.6956 550.00 563.65 23.45
65 9.7219 540.00 563.12 23.24
66 9.7481 607.00 562.62 24.64
67 9.7744 561.00 562.14 23.69
68 9.8006 571.00 561.67 23.90
69 9.8269 566.00 561.23 23.79
70 9.8532 535.00 560.80 23.13
71 9.8794 560.00 560.39 23.66
72 9.9057 559.00 560.00 23.64
73 9.9319 559.00 559.52 23.64
74 9.9582 564.00 559.12 23.75
75 9.9845 565.00 558.78 23.77
76 10.0107 611.00 558.46 24.72
77 10.0370 534.00 558.16 23.11
78 10.0632 569.00 557.87 23.85
79 10.0895 565.00 557.59 23.77
80 10.1158 539.00 557.33 23.22
81 10.1420 548.00 557.08 23.41
82 10.1683 539.00 556.84 23.22
83 10.1945 535.00 556.62 23.13
84 10.2208 553.00 556.41 23.52
85 10.2471 550.00 556.21 23.45
86 10.2733 559.00 556.03 23.64
87 10.2996 585.00 555.85 24.19
88 10.3258 594.00 555.70 24.37
89 10.3521 576.00 555.55 24.00
90 10.3784 563.00 555.42 23.73
91 10.4046 561.00 555.30 23.69
92 10.4309 576.00 555.19 24.00
93 10.4571 579.00 555.09 24.06
94 10.4834 587.00 555.01 24.23
95 10.5097 641.00 554.94 25.32
96 10.5359 603.00 554.88 24.56
97 10.5622 541.00 554.83 23.26
98 10.5885 568.00 554.79 23.83
99 10.6147 606.00 554.77 24.62
100 10.6410 584.00 554.75 24.17
101 10.6672 507.00 554.75 22.52
102 10.6935 577.00 555.16 24.02
103 10.7198 539.00 555.42 23.22
104 10.7460 557.00 555.50 23.60
105 10.7723 605.00 555.60 24.60
106 10.7985 583.00 555.72 24.15
107 10.8248 643.00 555.86 25.36
108 10.8511 567.00 556.02 23.81
109 10.8773 558.00 556.21 23.62
110 10.9036 575.00 557.32 23.98
111 10.9298 534.00 559.34 23.11
112 10.9561 530.00 559.84 23.02
113 10.9824 583.00 560.42 24.15
114 11.0086 535.00 561.09 23.13
115 11.0349 568.00 561.86 23.83
116 11.0611 620.00 562.77 24.90
117 11.0874 599.00 563.85 24.47
118 11.1137 621.00 565.16 24.92
119 11.1399 636.00 576.64 25.22
120 11.1662 669.00 599.75 25.86
121 11.1924 615.00 605.03 24.80
122 11.2187 715.00 611.68 26.74
123 11.2450 759.00 620.75 27.55
124 11.2712 839.00 636.39 28.97
125 11.2975 1001.00 673.16 31.64
126 11.3237 1291.00 759.13 35.93
127 11.3500 1728.00 900.01 41.57
128 11.3763 2063.00 1004.87 45.42
129 11.4025 1930.00 967.84 43.93
130 11.4288 1456.00 857.64 38.16
131 11.4551 1153.00 785.80 33.96
132 11.4813 922.00 784.85 30.36
133 11.5076 1044.00 869.33 32.31
134 11.5338 1180.00 1120.88 34.35
135 11.5601 1558.00 1630.32 39.47
136 11.5864 2033.00 2212.10 45.09
137 11.6126 2163.00 2311.22 46.51
138 11.6389 1810.00 1913.35 42.54
139 11.6651 1392.00 1515.08 37.31
140 11.6914 1502.00 1418.38 38.76
141 11.7177 2075.00 1709.92 45.55
142 11.7439 3175.00 2833.83 56.35
143 11.7702 5731.00 5982.23 75.70
144 11.7964 10244.00 11894.00 101.21
145 11.8227 16330.00 17392.80 127.79
146 11.8490 16134.00 16479.60 127.02
147 11.8752 10105.00 10642.90 100.52
148 11.9015 4580.00 5293.99 67.68
149 11.9277 2266.00 2566.92 47.60
150 11.9540 1565.00 1556.32 39.56
151 11.9803 1105.00 1192.47 33.24
152 12.0065 954.00 1018.67 30.89
153 12.0328 947.00 911.87 30.77
154 12.0590 907.00 839.30 30.12
155 12.0853 857.00 787.30 29.27
156 12.1116 828.00 749.15 28.77
157 12.1378 824.00 720.47 28.71
158 12.1641 825.00 698.32 28.72
159 12.1903 805.00 680.88 28.37
160 12.2166 755.00 666.94 27.48
161 12.2429 688.00 655.63 26.23
162 12.2691 620.00 646.36 24.90
163 12.2954 594.00 637.06 24.37
164 12.3216 591.00 629.95 24.31
165 12.3479 582.00 624.72 24.12
166 12.3742 640.00 620.31 25.30
167 12.4004 583.00 616.56 24.15
168 12.4267 576.00 613.37 24.00
169 12.4530 574.00 610.63 23.96
170 12.4792 565.00 608.29 23.77
171 12.5055 616.00 606.28 24.82
172 12.5317 545.00 586.17 23.35
173 12.5580 540.00 576.80 23.24
174 12.5843 548.00 577.32 23.41
175 12.6105 576.00 577.86 24.00
176 12.6368 538.00 578.39 23.19
177 12.6630 516.00 578.93 22.72
178 12.6893 556.00 579.47 23.58
179 12.7156 547.00 580.02 23.39
180 12.7418 567.00 580.57 23.81
181 12.7681 543.00 581.12 23.30
182 12.7943 561.00 581.68 23.69
183 12.8206 613.00 582.24 24.76
184 12.8469 543.00 582.81 23.30
185 12.8731 572.00 583.39 23.92
186 12.8994 579.00 583.99 24.06
187 12.9256 547.00 584.56 23.39
188 12.9519 566.00 585.14 23.79
189 12.9782 592.00 585.73 24.33
190 13.0044 558.00 586.31 23.62
191 13.0307 631.00 586.90 25.12
192 13.0569 621.00 587.50 24.92
193 13.0832 583.00 588.09 24.15
194 13.1095 607.00 588.70 24.64
195 13.1357 677.00 589.30 26.02
196 13.1620 659.00 589.91 25.67
197 13.1882 698.00 590.53 26.42
198 13.2145 783.00 591.15 27.98
199 13.2408 784.00 591.78 28.00
200 13.2670 807.00 592.41 28.41
201 13.2933 762.00 593.06 27.60
202 13.3196 779.00 593.73 27.91
203 13.3458 637.00 594.41 25.24
204 13.3721 641.00 595.12 25.32
205 13.3983 647.00 595.89 25.44
206 13.4246 653.00 596.74 25.55
207 13.4509 538.00 597.85 23.19
208 13.4771 611.00 599.82 24.72
209 13.5034 596.00 604.12 24.41
210 13.5296 598.00 612.26 24.45
211 13.5559 698.00 620.53 26.42
212 13.5822 684.00 621.45 26.15
213 13.6084 667.00 615.73 25.83
214 13.6347 626.00 609.22 25.02
215 13.6609 604.00 605.70 24.58
216 13.6872 563.00 604.69 23.73
217 13.7135 537.00 604.79 23.17
218 13.7397 575.00 605.27 23.98
219 13.7660 542.00 605.88 23.28
220 13.7922 567.00 606.58 23.81
221 13.8185 542.00 607.33 23.28
222 13.8448 578.00 608.16 24.04
223 13.8710 559.00 609.04 23.64
224 13.8973 549.00 610.02 23.43
225 13.9235 551.00 611.09 23.47
226 13.9498 575.00 612.30 23.98
227 13.9761 549.00 613.71 23.43
228 14.0023 582.00 615.40 24.12
229 14.0286 557.00 617.53 23.60
230 14.0548 586.00 621.96 24.21
231 14.0811 600.00 626.28 24.49
232 14.1074 529.00 637.84 23.00
233 14.1336 601.00 659.44 24.52
234 14.1599 665.00 715.20 25.79
235 14.1861 689.00 819.98 26.25
236 14.2124 822.00 926.66 28.67
237 14.2387 863.00 929.66 29.38
238 14.2649 731.00 840.44 27.04
239 14.2912 680.00 738.67 26.08
240 14.3175 589.00 678.45 24.27
241 14.3437 553.00 654.42 23.52
242 14.3700 616.00 647.18 24.82
243 14.3962 559.00 645.72 23.64
244 14.4225 599.00 646.51 24.47
245 14.4488 565.00 648.76 23.77
246 14.4750 569.00 652.38 23.85
247 14.5013 577.00 657.55 24.02
248 14.5275 555.00 664.72 23.56
249 14.5538 631.00 674.73 25.12
250 14.5801 644.00 689.07 25.38
251 14.6063 737.00 710.81 27.15
252 14.6326 808.00 749.25 28.43
253 14.6588 984.00 841.63 31.37
254 14.6851 1470.00 1102.13 38.34
255 14.7114 2336.00 1705.65 48.33
256 14.7376 3731.00 2609.91 61.08
257 14.7639 4627.00 3131.02 68.02
258 14.7901 4105.00 2765.95 64.07
259 14.8164 2739.00 1947.19 52.34
260 14.8427 1658.00 1263.86 40.72
261 14.8689 1097.00 915.18 33.12
262 14.8952 825.00 779.37 28.72
263 14.9214 722.00 727.56 26.87
264 14.9477 647.00 701.90 25.44
265 14.9740 639.00 686.22 25.28
266 15.0002 575.00 675.81 23.98
267 15.0265 612.00 668.52 24.74
268 15.0527 637.00 663.27 25.24
269 15.0790 601.00 659.42 24.52
270 15.1053 585.00 656.56 24.19
271 15.1315 578.00 654.42 24.04
272 15.1578 566.00 652.81 23.79
273 15.1841 568.00 651.60 23.83
274 15.2103 595.00 650.71 24.39
275 15.2366 519.00 650.05 22.78
276 15.2628 558.00 649.60 23.62
277 15.2891 552.00 649.29 23.49
278 15.3154 578.00 649.12 24.04
279 15.3416 546.00 649.05 23.37
280 15.3679 576.00 649.09 24.00
281 15.3941 577.00 649.17 24.02
282 15.4204 574.00 649.32 23.96
283 15.4467 595.00 649.52 24.39
284 15.4729 567.00 646.78 23.81
285 15.4992 553.00 647.26 23.52
286 15.5254 572.00 646.35 23.92
287 15.5517 552.00 646.95 23.49
288 15.5780 566.00 647.54 23.79
289 15.6042 560.00 648.14 23.66
290 15.6305 616.00 648.74 24.82
291 15.6567 647.00 649.34 25.44
292 15.6830 576.00 649.93 24.00
293 15.7093 564.00 650.53 23.75
294 15.7355 587.00 651.14 24.23
295 15.7618 555.00 651.75 23.56
296 15.7880 602.00 652.37 24.54
297 15.8143 632.00 653.00 25.14
298 15.8406 586.00 653.66 24.21
299 15.8668 658.00 654.35 25.65
300 15.8931 654.00 655.13 25.57
301 15.9193 688.00 656.14 26.23
302 15.9456 674.00 657.92 25.96
303 15.9719 828.00 661.60 28.77
304 15.9981 860.00 667.82 29.33
305 16.0244 987.00 673.85 31.42
306 16.0506 1033.00 674.36 32.14
307 16.0769 975.00 670.38 31.23
308 16.1032 894.00 665.42 29.90
309 16.1294 735.00 662.41 27.11
310 16.1557 704.00 661.34 26.53
311 16.1820 644.00 661.26 25.38
312 16.2082 642.00 661.53 25.34
313 16.2345 626.00 661.91 25.02
314 16.2607 629.00 662.34 25.08
315 16.2870 638.00 662.80 25.26
316 16.3133 614.00 663.27 24.78
317 16.3395 590.00 663.75 24.29
318 16.3658 567.00 664.24 23.81
319 16.3920 585.00 664.73 24.19
320 16.4183 637.00 665.22 25.24
321 16.4446 593.00 665.72 24.35
322 16.4708 590.00 666.21 24.29
323 16.4971 607.00 666.71 24.64
324 16.5233 577.00 667.20 24.02
325 16.5496 569.00 667.68 23.85
326 16.5759 605.00 668.17 24.60
327 16.6021 616.00 668.66 24.82
328 16.6284 587.00 669.15 24.23
329 16.6546 590.00 669.63 24.29
330 16.6809 591.00 670.10 24.31
331 16.7072 573.00 670.58 23.94
332 16.7334 616.00 671.05 24.82
333 16.7597 601.00 671.50 24.52
334 16.7859 592.00 671.96 24.33
335 16.8122 576.00 672.43 24.00
336 16.8385 600.00 672.89 24.49
337 16.8647 624.00 673.35 24.98
338 16.8910 580.00 673.81 24.08
339 16.9172 583.00 674.27 24.15
340 16.9435 666.00 674.72 25.81
341 16.9698 634.00 675.17 25.18
342 16.9960 631.00 675.61 25.12
343 17.0223 620.00 676.06 24.90
344 17.0486 561.00 676.50 23.69
345 17.0748 616.00 676.94 24.82
346 17.1011 604.00 677.38 24.58
347 17.1273 565.00 677.82 23.77
348 17.1536 611.00 678.27 24.72
349 17.1799 596.00 678.74 24.41
350 17.2061 659.00 679.30 25.67
351 17.2324 609.00 691.02 24.68
352 17.2586 602.00 697.96 24.54
353 17.2849 617.00 700.06 24.84
354 17.3112 618.00 701.86 24.86
355 17.3374 650.00 703.59 25.50
356 17.3637 646.00 705.55 25.42
357 17.3899 664.00 707.96 25.77
358 17.4162 621.00 710.87 24.92
359 17.4425 631.00 714.22 25.12
360 17.4687 632.00 718.04 25.14
361 17.4950 645.00 722.44 25.40
362 17.5212 642.00 727.60 25.34
363 17.5475 624.00 733.73 24.98
364 17.5738 685.00 741.11 26.17
365 17.6000 680.00 750.15 26.08
366 17.6263 632.00 761.29 25.14
367 17.6525 690.00 775.28 26.27
368 17.6788 690.00 793.29 26.27
369 17.7051 667.00 817.02 25.83
370 17.7313 733.00 849.24 27.07
371 17.7576 779.00 894.59 27.91
372 17.7838 834.00 962.00 28.88
373 17.8101 982.00 1077.06 31.34
374 17.8364 1270.00 1329.66 35.64
375 17.8626 1757.00 2009.26 41.92
376 17.8889 3139.00 3612.76 56.03
377 17.9151 5907.00 6239.37 76.86
378 17.9414 8286.00 8328.22 91.03
379 17.9677 8159.00 7925.34 90.33
380 17.9939 5996.00 5965.47 77.43
381 18.0202 3540.00 3650.46 59.50
382 18.0465 1798.00 2112.60 42.40
383 18.0727 1155.00 1388.14 33.99
384 18.0990 975.00 1100.33 31.23
385 18.1252 833.00 976.33 28.86
386 18.1515 754.00 907.91 27.46
387 18.1778 734.00 863.76 27.09
388 18.2040 745.00 834.14 27.29
389 18.2303 722.00 815.86 26.87
390 18.2565 775.00 808.70 27.84
391 18.2828 732.00 810.91 27.06
392 18.3091 764.00 812.44 27.64
393 18.3353 791.00 804.31 28.12
394 18.3616 836.00 792.12 28.91
395 18.3878 912.00 782.45 30.20
396 18.4141 986.00 783.58 31.40
397 18.4404 992.00 807.09 31.50
398 18.4666 1012.00 884.78 31.81
399 18.4929 1101.00 1064.33 33.18
400 18.5191 1346.00 1333.86 36.69
401 18.5454 1623.00 1501.72 40.29
402 18.5717 1500.00 1423.29 38.73
403 18.5979 1375.00 1215.61 37.08
404 18.6242 1002.00 990.74 31.65
405 18.6504 832.00 848.08 28.84
406 18.6767 779.00 771.71 27.91
407 18.7030 734.00 745.50 27.09
408 18.7292 699.00 729.02 26.44
409 18.7555 782.00 722.26 27.96
410 18.7817 736.00 717.22 27.13
411 18.8080 748.00 713.33 27.35
412 18.8343 664.00 710.36 25.77
413 18.8605 737.00 708.30 27.15
414 18.8868 742.00 706.91 27.24
415 18.9131 851.00 705.94 29.17
416 18.9393 833.00 705.25 28.86
417 18.9656 784.00 704.74 28.00
418 18.9918 777.00 704.38 27.87
419 19.0181 814.00 705.11 28.53
420 19.0444 720.00 704.99 26.83
421 19.0706 753.00 707.11 27.44
422 19.0969 759.00 707.37 27.55
423 19.1231 734.00 707.77 27.09
424 19.1494 685.00 708.31 26.17
425 19.1757 682.00 709.02 26.12
426 19.2019 744.00 709.94 27.28
427 19.2282 697.00 711.16 26.40
428 19.2544 695.00 712.92 26.36
429 19.2807 715.00 714.38 26.74
430 19.3070 707.00 719.29 26.59
431 19.3332 715.00 729.90 26.74
432 19.3595 726.00 755.44 26.94
433 19.3857 725.00 799.10 26.93
434 19.4120 731.00 840.51 27.04
435 19.4383 764.00 842.88 27.64
436 19.4645 762.00 818.25 27.60
437 19.4908 766.00 783.42 27.68
438 19.5170 737.00 757.75 27.15
439 19.5433 754.00 747.84 27.46
440 19.5696 767.00 749.56 27.69
441 19.5958 819.00 759.26 28.62
442 19.6221 853.00 778.72 29.21
443 19.6483 1071.00 822.96 32.73
444 19.6746 1359.00 940.30 36.86
445 19.7009 1753.00 1214.63 41.87
446 19.7271 2636.00 1667.52 51.34
447 19.7534 3397.00 2047.96 58.28
448 19.7796 3337.00 2006.18 57.77
449 19.8059 2920.00 1710.39 54.04
450 19.8322 2173.00 1317.11 46.62
451 19.8584 1637.00 1019.43 40.46
452 19.8847 1224.00 870.31 34.99
453 19.9110 1055.00 823.31 32.48
454 19.9372 911.00 831.09 30.18
455 19.9635 827.00 855.84 28.76
456 19.9897 861.00 854.23 29.34
457 20.0160 819.00 827.03 28.62
458 20.0423 826.00 789.45 28.74
459 20.0685 796.00 756.61 28.21
460 20.0948 840.00 738.58 28.98
461 20.1210 892.00 733.21 29.87
462 20.1473 959.00 734.74 30.97
463 20.1736 1009.00 735.20 31.76
464 20.1998 1011.00 731.15 31.80
465 20.2261 963.00 724.95 31.03
466 20.2523 876.00 718.52 29.60
467 20.2786 848.00 714.01 29.12
468 20.3049 835.00 711.49 28.90
469 20.3311 784.00 710.13 28.00
470 20.3574 777.00 709.31 27.87
471 20.3836 707.00 708.76 26.59
472 20.4099 780.00 708.47 27.93
473 20.4362 725.00 708.58 26.93
474 20.4624 733.00 709.73 27.07
475 20.4887 724.00 713.15 26.91
476 20.5149 755.00 717.60 27.48
477 20.5412 718.00 723.76 26.80
478 20.5675 791.00 722.91 28.12
479 20.5937 728.00 718.82 26.98
480 20.6200 765.00 712.91 27.66
481 20.6462 725.00 707.80 26.93
482 20.6725 731.00 704.87 27.04
483 20.6988 765.00 703.51 27.66
484 20.7250 727.00 702.71 26.96
485 20.7513 729.00 702.35 27.00
486 20.7776 714.00 702.02 26.72
487 20.8038 742.00 701.81 27.24
488 20.8301 699.00 701.63 26.44
489 20.8563 722.00 701.47 26.87
490 20.8826 769.00 701.31 27.73
491 20.9089 718.00 701.14 26.80
492 20.9351 711.00 701.00 26.66
493 20.9614 754.00 700.85 27.46
494 20.9876 721.00 700.72 26.85
495 21.0139 707.00 700.58 26.59
496 21.0402 715.00 700.44 26.74
497 21.0664 738.00 700.30 27.17
498 21.0927 701.00 700.16 26.48
499 21.1189 701.00 700.02 26.48
500 21.1452 727.00 699.88 26.96
501 21.1715 695.00 699.73 26.36
502 21.1977 785.00 699.58 28.02
503 21.2240 754.00 699.54 27.46
504 21.2502 713.00 699.39 26.70
505 21.2765 744.00 699.30 27.28
506 21.3028 706.00 699.12 26.57
507 21.3290 763.00 698.98 27.62
508 21.3553 699.00 698.82 26.44
509 21.3815 661.00 698.67 25.71
510 21.4078 735.00 698.52 27.11
511 21.4341 745.00 698.37 27.29
512 21.4603 783.00 698.23 27.98
513 21.4866 735.00 698.08 27.11
514 21.5128 715.00 697.94 26.74
515 21.5391 726.00 697.80 26.94
516 21.5654 753.00 697.67 27.44
517 21.5916 763.00 697.58 27.62
518 21.6179 706.00 697.47 26.57
519 21.6442 790.00 697.40 28.11
520 21.6704 764.00 697.34 27.64
521 21.6967 722.00 697.32 26.87
522 21.7229 827.00 697.35 28.76
523 21.7492 743.00 697.47 27.26
524 21.7755 692.00 697.71 26.31
525 21.8017 748.00 698.16 27.35
526 21.8280 754.00 699.02 27.46
527 21.8542 734.00 701.02 27.09
528 21.8805 716.00 706.40 26.76
529 21.9068 719.00 719.37 26.81
530 21.9330 785.00 742.12 28.02
531 21.9593 708.00 764.63 26.61
532 21.9855 735.00 766.16 27.11
533 22.0118 730.00 753.32 27.02
534 22.0381 759.00 734.31 27.55
535 22.0643 743.00 715.79 27.26
536 22.0906 731.00 704.27 27.04
537 22.1168 748.00 698.74 27.35
538 22.1431 726.00 696.32 26.94
539 22.1694 718.00 695.12 26.80
540 22.1956 747.00 694.42 27.33
541 22.2219 736.00 694.11 27.13
542 22.2481 706.00 694.50 26.57
543 22.2744 730.00 696.36 27.02
544 22.3007 730.00 700.34 27.02
545 22.3269 723.00 705.05 26.89
546 22.3532 685.00 706.04 26.17
547 22.3794 718.00 703.40 26.80
548 22.4057 757.00 699.42 27.51
549 22.4320 758.00 695.06 27.53
550 22.4582 719.00 692.35 26.81
551 22.4845 758.00 690.67 27.53
552 22.5107 757.00 690.54 27.51
553 22.5370 714.00 690.03 26.72
554 22.5633 727.00 689.76 26.96
555 22.5895 782.00 689.45 27.96
556 22.6158 710.00 689.38 26.65
557 22.6421 763.00 689.18 27.62
558 22.6683 709.00 689.02 26.63
559 22.6946 721.00 688.90 26.85
560 22.7208 708.00 688.73 26.61
561 22.7471 714.00 688.75 26.72
562 22.7734 751.00 688.86 27.40
563 22.7996 723.00 689.38 26.89
564 22.8259 752.00 690.13 27.42
565 22.8521 739.00 691.21 27.18
566 22.8784 707.00 691.74 26.59
567 22.9047 733.00 692.16 27.07
568 22.9309 726.00 692.73 26.94
569 22.9572 756.00 693.71 27.50
570 22.9834 728.00 695.42 26.98
571 23.0097 724.00 698.20 26.91
572 23.0360 764.00 702.72 27.64
573 23.0622 869.00 710.21 29.48
574 23.0885 827.00 726.54 28.76
575 23.1147 895.00 766.69 29.92
576 23.1410 1017.00 856.33 31.89
577 23.1673 1213.00 1001.19 34.83
578 23.1935 1332.00 1125.70 36.50
579 23.2198 1374.00 1123.09 37.07
580 23.2460 1308.00 1065.76 36.17
581 23.2723 1198.00 991.72 34.61
582 23.2986 1121.00 922.92 33.48
583 23.3248 1013.00 863.00 31.83
584 23.3511 937.00 815.15 30.61
585 23.3773 790.00 777.21 28.11
586 23.4036 842.00 744.96 29.02
587 23.4299 753.00 724.81 27.44
588 23.4561 722.00 720.05 26.87
589 23.4824 747.00 732.81 27.33
590 23.5087 731.00 766.03 27.04
591 23.5349 714.00 810.05 26.72
592 23.5612 750.00 827.89 27.39
593 23.5874 740.00 812.03 27.20
594 23.6137 753.00 786.00 27.44
595 23.6400 720.00 753.95 26.83
596 23.6662 740.00 732.45 27.20
597 23.6925 653.00 731.53 25.55
598 23.7187 739.00 756.96 27.18
599 23.7450 738.00 808.46 27.17
600 23.7713 817.00 859.81 28.58
601 23.7975 820.00 864.57 28.64
602 23.8238 774.00 842.53 27.82
603 23.8500 815.00 814.15 28.55
604 23.8763 802.00 793.72 28.32
605 23.9026 858.00 812.87 29.29
606 23.9288 871.00 891.82 29.51
607 23.9551 1060.00 1023.89 32.56
608 23.9813 1159.00 1154.31 34.04
609 24.0076 1233.00 1190.06 35.11
610 24.0339 1196.00 1199.72 34.58
611 24.0601 1143.00 1249.92 33.81
612 24.0864 1058.00 1325.43 32.53
613 24.1126 963.00 1322.65 31.03
614 24.1389 892.00 1210.10 29.87
615 24.1652 822.00 1080.65 28.67
616 24.1914 766.00 931.06 27.68
617 24.2177 727.00 811.79 26.96
618 24.2439 694.00 743.88 26.34
619 24.2702 735.00 711.83 27.11
620 24.2965 669.00 696.71 25.86
621 24.3227 649.00 687.91 25.48
622 24.3490 704.00 682.07 26.53
623 24.3752 667.00 677.63 25.83
624 24.4015 686.00 674.27 26.19
625 24.4278 653.00 671.57 25.55
626 24.4540 665.00 669.34 25.79
627 24.4803 650.00 667.46 25.50
628 24.5066 629.00 665.83 25.08
629 24.5328 638.00 664.40 25.26
630 24.5591 629.00 662.86 25.08
631 24.5853 628.00 661.72 25.06
632 24.6116 619.00 660.54 24.88
633 24.6379 623.00 659.58 24.96
634 24.6641 647.00 658.68 25.44
635 24.6904 602.00 657.83 24.54
636 24.7166 611.00 656.96 24.72
637 24.7429 615.00 656.19 24.80
638 24.7692 639.00 654.82 25.28
639 24.7954 630.00 654.16 25.10
640 24.8217 606.00 653.16 24.62
641 24.8479 538.00 652.57 23.19
642 24.8742 639.00 651.13 25.28
643 24.9005 631.00 650.70 25.12
644 24.9267 651.00 650.00 25.51
645 24.9530 627.00 650.15 25.04
646 24.9792 662.00 650.89 25.73
647 25.0055 648.00 651.90 25.46
648 25.0318 731.00 651.91 27.04
649 25.0580 644.00 650.80 25.38
650 25.0843 673.00 649.42 25.94
651 25.1105 645.00 647.78 25.40
652 25.1368 612.00 646.31 24.74
653 25.1631 627.00 645.23 25.04
654 25.1893 623.00 644.44 24.96
655 25.2156 589.00 643.80 24.27
656 25.2418 606.00 643.20 24.62
657 25.2681 612.00 642.63 24.74
658 25.2944 594.00 642.07 24.37
659 25.3206 596.00 641.51 24.41
660 25.3469 609.00 640.95 24.68
661 25.3732 612.00 640.40 24.74
662 25.3994 565.00 639.85 23.77
663 25.4257 625.00 639.29 25.00
664 25.4519 626.00 638.74 25.02
665 25.4782 601.00 638.19 24.52
666 25.5045 589.00 637.64 24.27
667 25.5307 636.00 637.08 25.22
668 25.5570 622.00 636.53 24.94
669 25.5832 606.00 635.97 24.62
670 25.6095 615.00 635.41 24.80
671 25.6358 567.00 634.86 23.81
672 25.6620 613.00 634.30 24.76
673 25.6883 608.00 633.74 24.66
674 25.7145 579.00 633.18 24.06
675 25.7408 605.00 632.62 24.60
676 25.7671 553.00 632.06 23.52
677 25.7933 603.00 631.49 24.56
678 25.8196 574.00 630.93 23.96
679 25.8458 549.00 630.36 23.43
680 25.8721 625.00 630.10 25.00
681 25.8984 551.00 629.69 23.47
682 25.9246 570.00 629.15 23.87
683 25.9509 576.00 628.62 24.00
684 25.9771 624.00 628.10 24.98
685 26.0034 580.00 627.58 24.08
686 26.0297 622.00 627.06 24.94
687 26.0559 606.00 626.55 24.62
688 26.0822 661.00 626.06 25.71
689 26.1084 633.00 625.59 25.16
690 26.1347 602.00 625.11 24.54
691 26.1610 578.00 624.66 24.04
692 26.1872 595.00 624.26 24.39
693 26.2135 570.00 623.86 23.87
694 26.2398 556.00 623.49 23.58
695 26.2660 605.00 623.18 24.60
696 26.2923 661.00 623.01 25.71
697 26.3185 642.00 622.87 25.34
698 26.3448 649.00 622.90 25.48
699 26.3711 712.00 623.15 26.68
700 26.3973 762.00 623.84 27.60
701 26.4236 737.00 625.25 27.15
702 26.4498 895.00 627.57 29.92
703 26.4761 949.00 630.96 30.81
704 26.5024 898.00 637.74 29.97
705 26.5286 824.00 654.89 28.71
706 26.5549 770.00 690.36 27.75
707 26.5811 805.00 741.11 28.37
708 26.6074 750.00 773.58 27.39
709 26.6337 643.00 760.24 25.36
710 26.6599 652.00 734.82 25.53
711 26.6862 655.00 702.69 25.59
712 26.7124 616.00 666.49 24.82
713 26.7387 641.00 641.12 25.32
714 26.7650 647.00 627.98 25.44
715 26.7912 589.00 622.87 24.27
716 26.8175 599.00 622.49 24.47
717 26.8437 607.00 625.30 24.64
718 26.8700 647.00 628.65 25.44
719 26.8963 633.00 628.14 25.16
720 26.9225 624.00 625.55 24.98
721 26.9488 597.00 623.85 24.43
722 26.9750 573.00 624.10 23.94
723 27.0013 583.00 629.81 24.15
724 27.0276 516.00 640.90 22.72
725 27.0538 561.00 648.09 23.69
726 27.0801 583.00 643.73 24.15
727 27.1063 520.00 636.60 22.80
728 27.1326 572.00 628.05 23.92
729 27.1589 588.00 618.30 24.25
730 27.1851 571.00 611.46 23.90
731 27.2114 562.00 608.41 23.71
732 27.2377 572.00 608.98 23.92
733 27.2639 542.00 613.45 23.28
734 27.2902 552.00 621.59 23.49
735 27.3164 592.00 627.39 24.33
736 27.3427 575.00 626.43 23.98
737 27.3690 564.00 626.06 23.75
738 27.3952 579.00 626.08 24.06
739 27.4215 554.00 625.39 23.54
740 27.4477 575.00 621.10 23.98
741 27.4740 592.00 615.26 24.33
742 27.5003 540.00 610.68 23.24
743 27.5265 577.00 605.67 24.02
744 27.5528 663.00 601.48 25.75
745 27.5790 651.00 599.24 25.51
746 27.6053 762.00 598.73 27.60
747 27.6316 821.00 598.97 28.65
748 27.6578 823.00 598.70 28.69
749 27.6841 752.00 597.97 27.42
750 27.7103 729.00 597.40 27.00
751 27.7366 681.00 597.01 26.10
752 27.7629 625.00 596.79 25.00
753 27.7891 570.00 597.18 23.87
754 27.8154 578.00 598.26 24.04
755 27.8416 593.00 600.12 24.35
756 27.8679 579.00 603.33 24.06
757 27.8942 569.00 608.71 23.85
758 27.9204 588.00 617.78 24.25
759 27.9467 550.00 633.32 23.45
760 27.9729 589.00 662.92 24.27
761 27.9992 714.00 728.36 26.72
762 28.0255 827.00 856.09 28.76
763 28.0517 934.00 1026.09 30.56
764 28.0780 1093.00 1112.77 33.06
765 28.1043 1016.00 1054.72 31.87
766 28.1305 949.00 975.61 30.81
767 28.1568 849.00 878.55 29.14
768 28.1830 749.00 762.93 27.37
769 28.2093 639.00 678.87 25.28
770 28.2356 587.00 634.97 24.23
771 28.2618 574.00 616.89 23.96
772 28.2881 605.00 607.93 24.60
773 28.3143 597.00 604.29 24.43
774 28.3406 531.00 605.35 23.04
775 28.3669 550.00 614.31 23.45
776 28.3931 545.00 634.63 23.35
777 28.4194 583.00 662.36 24.15
778 28.4456 563.00 675.67 23.73
779 28.4719 585.00 664.94 24.19
780 28.4982 619.00 651.51 24.88
781 28.5244 536.00 635.64 23.15
782 28.5507 551.00 616.61 23.47
783 28.5769 569.00 603.35 23.85
784 28.6032 515.00 597.58 22.69
785 28.6295 548.00 597.24 23.41
786 28.6557 563.00 599.66 23.73
787 28.6820 552.00 602.75 23.49
788 28.7082 579.00 606.15 24.06
789 28.7345 598.00 610.57 24.45
790 28.7608 603.00 617.44 24.56
791 28.7870 683.00 628.66 26.13
792 28.8133 676.00 648.74 26.00
793 28.8395 840.00 691.35 28.98
794 28.8658 931.00 791.13 30.51
795 28.8921 1266.00 1008.79 35.58
796 28.9183 1713.00 1368.69 41.39
797 28.9446 2116.00 1730.14 46.00
798 28.9708 2322.00 1785.15 48.19
799 28.9971 2239.00 1608.82 47.32
800 29.0234 1960.00 1435.97 44.27
801 29.0496 1663.00 1206.81 40.78
802 29.0759 1268.00 967.32 35.61
803 29.1022 985.00 802.72 31.38
804 29.1284 822.00 715.58 28.67
805 29.1547 772.00 682.44 27.78
806 29.1809 675.00 676.77 25.98
807 29.2072 674.00 682.42 25.96
808 29.2335 689.00 676.60 26.25
809 29.2597 664.00 656.99 25.77
810 29.2860 624.00 640.42 24.98
811 29.3122 596.00 622.43 24.41
812 29.3385 542.00 603.01 23.28
813 29.3648 533.00 588.59 23.09
814 29.3910 542.00 580.12 23.28
815 29.4173 559.00 575.79 23.64
816 29.4435 593.00 573.44 24.35
817 29.4698 536.00 572.32 23.15
818 29.4961 538.00 572.38 23.19
819 29.5223 549.00 573.72 23.43
820 29.5486 540.00 576.73 23.24
821 29.5748 610.00 582.07 24.70
822 29.6011 563.00 590.77 23.73
823 29.6274 667.00 604.84 25.83
824 29.6536 705.00 632.53 26.55
825 29.6799 763.00 698.54 27.62
826 29.7061 931.00 839.31 30.51
827 29.7324 1065.00 1062.26 32.63
828 29.7587 1233.00 1258.25 35.11
829 29.7849 1190.00 1246.34 34.50
830 29.8112 1173.00 1134.51 34.25
831 29.8374 950.00 1034.65 30.82
832 29.8637 878.00 890.50 29.63
833 29.8900 735.00 745.22 27.11
834 29.9162 661.00 650.36 25.71
835 29.9425 567.00 601.68 23.81
836 29.9688 602.00 579.04 24.54
837 29.9950 564.00 567.20 23.75
838 30.0213 535.00 559.61 23.13
839 30.0475 535.00 554.68 23.13
840 30.0738 544.00 550.76 23.32
841 30.1001 536.00 547.66 23.15
842 30.1263 494.00 545.27 22.23
843 30.1526 446.00 543.36 21.12
844 30.1788 555.00 541.88 23.56
845 30.2051 475.00 540.83 21.79
846 30.2314 524.00 540.35 22.89
847 30.2576 495.00 540.51 22.25
848 30.2839 499.00 540.95 22.34
849 30.3101 484.00 540.77 22.00
850 30.3364 480.00 540.23 21.91
851 30.3627 600.00 540.19 24.49
852 30.3889 541.00 540.62 23.26
853 30.4152 594.00 542.11 24.37
854 30.4414 609.00 546.66 24.68
855 30.4677 748.00 558.81 27.35
856 30.4940 853.00 585.73 29.21
857 30.5202 991.00 630.45 31.48
858 30.5465 1115.00 674.48 33.39
859 30.5727 1171.00 676.86 34.22
860 30.5990 1045.00 655.35 32.33
861 30.6253 1103.00 639.39 33.21
862 30.6515 894.00 619.46 29.90
863 30.6778 744.00 606.00 27.28
864 30.7040 681.00 618.90 26.10
865 30.7303 610.00 657.20 24.70
866 30.7566 587.00 686.18 24.23
867 30.7828 612.00 671.20 24.74
868 30.8091 503.00 645.63 22.43
869 30.8354 587.00 623.92 24.23
870 30.8616 610.00 591.92 24.70
871 30.8879 645.00 561.23 25.40
872 30.9141 712.00 541.64 26.68
873 30.9404 685.00 531.55 26.17
874 30.9667 731.00 526.41 27.04
875 30.9929 667.00 523.39 25.83
876 31.0192 659.00 521.34 25.67
877 31.0454 673.00 519.82 25.94
878 31.0717 604.00 518.73 24.58
879 31.0980 602.00 518.14 24.54
880 31.1242 648.00 518.19 25.46
881 31.1505 630.00 519.18 25.10
882 31.1767 609.00 522.09 24.68
883 31.2030 647.00 529.03 25.44
884 31.2293 660.00 541.88 25.69
885 31.2555 720.00 559.64 26.83
886 31.2818 768.00 573.71 27.71
887 31.3080 820.00 570.48 28.64
888 31.3343 682.00 560.72 26.12
889 31.3606 730.00 554.32 27.02
890 31.3868 737.00 547.49 27.15
891 31.4131 738.00 542.53 27.17
892 31.4393 741.00 540.41 27.22
893 31.4656 733.00 536.83 27.07
894 31.4919 751.00 531.57 27.40
895 31.5181 709.00 526.43 26.63
896 31.5444 678.00 520.93 26.04
897 31.5706 606.00 515.07 24.62
898 31.5969 586.00 510.99 24.21
899 31.6232 523.00 509.83 22.87
900 31.6494 607.00 512.07 24.64
901 31.6757 569.00 517.60 23.85
902 31.7020 567.00 522.83 23.81
903 31.7282 614.00 522.61 24.78
904 31.7545 537.00 519.85 23.17
905 31.7807 528.00 517.10 22.98
906 31.8070 510.00 512.97 22.58
907 31.8333 554.00 508.81 23.54
908 31.8595 529.00 506.71 23.00
909 31.8858 488.00 508.04 22.09
910 31.9120 521.00 513.68 22.83
911 31.9383 492.00 521.89 22.18
912 31.9646 509.00 525.90 22.56
913 31.9908 522.00 524.02 22.85
914 32.0171 484.00 524.64 22.00
915 32.0433 486.00 529.29 22.05
916 32.0696 458.00 534.07 21.40
917 32.0959 481.00 535.27 21.93
918 32.1221 454.00 536.29 21.31
919 32.1484 478.00 544.74 21.86
920 32.1746 464.00 553.38 21.54
921 32.2009 452.00 547.55 21.26
922 32.2272 431.00 534.57 20.76
923 32.2534 450.00 525.71 21.21
924 32.2797 435.00 517.18 20.86
925 32.3059 469.00 507.57 21.66
926 32.3322 446.00 501.52 21.12
927 32.3585 465.00 499.51 21.56
928 32.3847 465.00 498.28 21.56
929 32.4110 435.00 495.57 20.86
930 32.4372 454.00 493.06 21.31
931 32.4635 474.00 491.04 21.77
932 32.4898 405.00 488.46 20.12
933 32.5160 443.00 485.99 21.05
934 32.5423 479.00 484.14 21.89
935 32.5686 457.00 482.93 21.38
936 32.5948 473.00 482.05 21.75
937 32.6211 449.00 481.33 21.19
938 32.6473 475.00 480.70 21.79
939 32.6736 442.00 480.12 21.02
940 32.6999 429.00 479.61 20.71
941 32.7261 434.00 479.12 20.83
942 32.7524 439.00 478.68 20.95
943 32.7786 451.00 478.24 21.24
944 32.8049 427.00 477.92 20.66
945 32.8312 455.00 477.71 21.33
946 32.8574 455.00 477.69 21.33
947 32.8837 505.00 478.18 22.47
948 32.9099 487.00 479.83 22.07
949 32.9362 474.00 483.82 21.77
950 32.9625 540.00 490.36 23.24
951 32.9887 507.00 496.42 22.52
952 33.0150 537.00 496.24 23.17
953 33.0412 498.00 493.22 22.32
954 33.0675 534.00 492.63 23.11
955 33.0938 453.00 492.69 21.28
956 33.1200 466.00 491.21 21.59
957 33.1463 436.00 487.17 20.88
958 33.1725 475.00 482.62 21.79
959 33.1988 462.00 479.79 21.49
960 33.2251 434.00 477.19 20.83
961 33.2513 435.00 474.06 20.86
962 33.2776 415.00 471.56 20.37
963 33.3038 425.00 470.05 20.62
964 33.3301 417.00 469.46 20.42
965 33.3564 408.00 469.86 20.20
966 33.3826 414.00 471.21 20.35
967 33.4089 426.00 472.90 20.64
968 33.4351 433.00 472.99 20.81
969 33.4614 409.00 471.35 20.22
970 33.4877 405.00 469.90 20.12
971 33.5139 412.00 468.59 20.30
972 33.5402 494.00 466.73 22.23
973 33.5664 418.00 464.94 20.44
974 33.5927 397.00 463.64 19.92
975 33.6190 449.00 462.76 21.19
976 33.6452 436.00 462.10 20.88
977 33.6715 451.00 461.55 21.24
978 33.6978 467.00 461.05 21.61
979 33.7240 423.00 460.57 20.57
980 33.7503 415.00 460.12 20.37
981 33.7765 420.00 459.68 20.49
982 33.8028 423.00 459.27 20.57
983 33.8291 425.00 458.84 20.62
984 33.8553 450.00 458.49 21.21
985 33.8816 433.00 458.17 20.81
986 33.9078 394.00 457.89 19.85
987 33.9341 354.00 457.74 18.81
988 33.9604 414.00 457.78 20.35
989 33.9866 431.00 458.41 20.76
990 34.0129 431.00 460.35 20.76
991 34.0391 414.00 464.31 20.35
992 34.0654 420.00 469.85 20.49
993 34.0917 432.00 473.05 20.78
994 34.1179 429.00 470.73 20.71
995 34.1442 396.00 467.44 19.90
996 34.1704 444.00 465.30 21.07
997 34.1967 404.00 462.39 20.10
998 34.2230 401.00 458.41 20.02
999 34.2492 416.00 456.08 20.40
1000 34.2755 457.00 454.29 21.38
1001 34.3017 447.00 453.27 21.14
1002 34.3280 396.00 452.62 19.90
1003 34.3543 383.00 452.14 19.57
1004 34.3805 399.00 451.73 19.98
1005 34.4068 403.00 451.40 20.07
1006 34.4330 411.00 451.14 20.27
1007 34.4593 384.00 450.92 19.60
1008 34.4856 363.00 450.74 19.05
1009 34.5118 439.00 450.64 20.95
1010 34.5381 449.00 450.88 21.19
1011 34.5644 449.00 451.46 21.19
1012 34.5906 420.00 451.72 20.49
1013 34.6169 423.00 452.12 20.57
1014 34.6431 468.00 452.86 21.63
1015 34.6694 442.00 454.40 21.02
1016 34.6957 424.00 456.87 20.59
1017 34.7219 427.00 460.54 20.66
1018 34.7482 492.00 464.33 22.18
1019 34.7744 485.00 466.55 22.02
1020 34.8007 484.00 469.05 22.00
1021 34.8270 480.00 474.83 21.91
1022 34.8532 518.00 486.97 22.76
1023 34.8795 516.00 513.73 22.72
1024 34.9057 542.00 568.45 23.28
1025 34.9320 533.00 654.56 23.09
1026 34.9583 592.00 739.71 24.33
1027 34.9845 565.00 748.23 23.77
1028 35.0108 599.00 698.30 24.47
1029 35.0370 565.00 663.68 23.77
1030 35.0633 534.00 634.89 23.11
1031 35.0896 574.00 583.10 23.96
1032 35.1158 480.00 534.73 21.91
1033 35.1421 499.00 507.20 22.34
1034 35.1683 519.00 498.15 22.78
1035 35.1946 531.00 502.64 23.04
1036 35.2209 528.00 526.79 22.98
1037 35.2471 566.00 577.38 23.79
1038 35.2734 563.00 643.51 23.73
1039 35.2996 606.00 675.41 24.62
1040 35.3259 632.00 649.67 25.14
1041 35.3522 590.00 624.12 24.29
1042 35.3784 639.00 618.02 25.28
1043 35.4047 653.00 598.55 25.55
1044 35.4310 649.00 560.91 25.48
1045 35.4572 604.00 527.85 24.58
1046 35.4835 551.00 505.89 23.47
1047 35.5097 541.00 491.18 23.26
1048 35.5360 539.00 480.68 23.22
1049 35.5623 468.00 471.96 21.63
1050 35.5885 456.00 464.67 21.35
1051 35.6148 484.00 458.25 22.00
1052 35.6410 481.00 454.20 21.93
1053 35.6673 476.00 451.95 21.82
1054 35.6936 421.00 450.09 20.52
1055 35.7198 443.00 448.86 21.05
1056 35.7461 439.00 448.59 20.95
1057 35.7723 398.00 449.32 19.95
1058 35.7986 475.00 451.11 21.79
1059 35.8249 460.00 453.69 21.45
1060 35.8511 457.00 458.98 21.38
1061 35.8774 450.00 469.16 21.21
1062 35.9036 511.00 490.95 22.61
1063 35.9299 536.00 536.99 23.15
1064 35.9562 535.00 614.84 23.13
1065 35.9824 668.00 703.59 25.85
1066 36.0087 626.00 730.92 25.02
1067 36.0349 665.00 688.09 25.79
1068 36.0612 623.00 653.34 24.96
1069 36.0875 600.00 636.20 24.49
1070 36.1137 566.00 599.17 23.79
1071 36.1400 557.00 556.35 23.60
1072 36.1662 556.00 537.72 23.58
1073 36.1925 658.00 554.71 25.65
1074 36.2188 822.00 612.81 28.67
1075 36.2450 996.00 708.47 31.56
1076 36.2713 1099.00 812.95 33.15
1077 36.2976 1019.00 916.48 31.92
1078 36.3238 995.00 1035.08 31.54
1079 36.3501 1022.00 1060.86 31.97
1080 36.3763 916.00 954.80 30.27
1081 36.4026 752.00 851.84 27.42
1082 36.4289 697.00 787.15 26.40
1083 36.4551 620.00 698.02 24.90
1084 36.4814 493.00 600.49 22.20
1085 36.5076 494.00 533.26 22.23
1086 36.5339 456.00 497.99 21.35
1087 36.5602 429.00 480.62 20.71
1088 36.5864 484.00 470.00 22.00
1089 36.6127 439.00 464.94 20.95
1090 36.6389 427.00 463.75 20.66
1091 36.6652 429.00 461.06 20.71
1092 36.6915 422.00 456.24 20.54
1093 36.7177 444.00 451.60 21.07
1094 36.7440 417.00 447.29 20.42
1095 36.7702 424.00 442.68 20.59
1096 36.7965 430.00 439.90 20.74
1097 36.8228 458.00 436.56 21.40
1098 36.8490 424.00 433.78 20.59
1099 36.8753 426.00 432.07 20.64
1100 36.9015 438.00 431.34 20.93
1101 36.9278 399.00 431.40 19.98
1102 36.9541 444.00 432.07 21.07
1103 36.9803 442.00 434.20 21.02
1104 37.0066 454.00 439.00 21.31
1105 37.0328 475.00 449.81 21.79
1106 37.0591 524.00 470.09 22.89
1107 37.0854 575.00 499.73 23.98
1108 37.1116 603.00 524.66 24.56
1109 37.1379 539.00 525.40 23.22
1110 37.1641 604.00 510.39 24.58
1111 37.1904 563.00 500.01 23.73
1112 37.2167 524.00 493.57 22.89
1113 37.2429 519.00 481.77 22.78
1114 37.2692 535.00 469.77 23.13
1115 37.2955 467.00 462.80 21.61
1116 37.3217 454.00 461.63 21.31
1117 37.3480 478.00 467.62 21.86
1118 37.3742 548.00 484.74 23.41
1119 37.4005 540.00 516.41 23.24
1120 37.4268 568.00 562.74 23.83
1121 37.4530 594.00 616.56 24.37
1122 37.4793 599.00 679.39 24.47
1123 37.5055 712.00 746.54 26.68
1124 37.5318 766.00 830.90 27.68
1125 37.5581 839.00 960.35 28.97
1126 37.5843 872.00 1059.81 29.53
1127 37.6106 934.00 999.26 30.56
1128 37.6368 887.00 877.55 29.78
1129 37.6631 755.00 811.29 27.48
1130 37.6894 747.00 762.83 27.33
1131 37.7156 709.00 679.45 26.63
1132 37.7419 630.00 606.89 25.10
1133 37.7681 615.00 571.48 24.80
1134 37.7944 557.00 558.99 23.60
1135 37.8207 565.00 557.60 23.77
1136 37.8469 579.00 565.21 24.06
1137 37.8732 527.00 559.37 22.96
1138 37.8994 586.00 538.50 24.21
1139 37.9257 579.00 526.75 24.06
1140 37.9520 541.00 532.64 23.26
1141 37.9782 549.00 550.08 23.43
1142 38.0045 555.00 573.20 23.56
1143 38.0307 556.00 573.92 23.58
1144 38.0570 536.00 544.67 23.15
1145 38.0833 557.00 521.01 23.60
1146 38.1095 513.00 510.82 22.65
1147 38.1358 536.00 494.06 23.15
1148 38.1620 505.00 468.67 22.47
1149 38.1883 501.00 448.35 22.38
1150 38.2146 459.00 436.91 21.42
1151 38.2408 422.00 432.97 20.54
1152 38.2671 416.00 435.36 20.40
1153 38.2934 412.00 444.71 20.30
1154 38.3196 411.00 461.10 20.27
1155 38.3459 411.00 476.64 20.27
1156 38.3721 442.00 476.82 21.02
1157 38.3984 425.00 466.75 20.62
1158 38.4247 403.00 461.81 20.07
1159 38.4509 408.00 460.42 20.20
1160 38.4772 402.00 458.07 20.05
1161 38.5034 416.00 459.10 20.40
1162 38.5297 439.00 472.91 20.95
1163 38.5560 482.00 503.12 21.95
1164 38.5822 495.00 546.61 22.25
1165 38.6085 568.00 597.02 23.83
1166 38.6347 543.00 657.18 23.30
1167 38.6610 584.00 688.15 24.17
1168 38.6873 607.00 653.49 24.64
1169 38.7135 578.00 606.32 24.04
1170 38.7398 523.00 582.53 22.87
1171 38.7660 524.00 558.16 22.89
1172 38.7923 521.00 514.43 22.83
1173 38.8186 509.00 472.63 22.56
1174 38.8448 422.00 445.49 20.54
1175 38.8711 414.00 431.10 20.35
1176 38.8973 424.00 422.56 20.59
1177 38.9236 424.00 416.59 20.59
1178 38.9499 436.00 412.34 20.88
1179 38.9761 424.00 409.27 20.59
1180 39.0024 376.00 407.30 19.39
1181 39.0286 395.00 405.91 19.87
1182 39.0549 445.00 404.89 21.09
1183 39.0812 425.00 404.12 20.62
1184 39.1074 400.00 403.58 20.00
1185 39.1337 425.00 403.29 20.62
1186 39.1600 417.00 403.42 20.42
1187 39.1862 398.00 404.25 19.95
1188 39.2125 433.00 406.00 20.81
1189 39.2387 448.00 408.69 21.17
1190 39.2650 428.00 410.58 20.69
1191 39.2913 501.00 410.38 22.38
1192 39.3175 474.00 410.79 21.77
1193 39.3438 550.00 414.52 23.45
1194 39.3700 564.00 421.67 23.75
1195 39.3963 638.00 429.63 25.26
1196 39.4226 693.00 432.43 26.32
1197 39.4488 616.00 427.25 24.82
1198 39.4751 596.00 422.55 24.41
1199 39.5013 602.00 422.43 24.54
1200 39.5276 548.00 423.34 23.41
1201 39.5539 500.00 424.50 22.36
1202 39.5801 442.00 427.25 21.02
1203 39.6064 433.00 426.35 20.81
1204 39.6326 414.00 421.69 20.35
1205 39.6589 436.00 420.03 20.88
1206 39.6852 370.00 422.05 19.24
1207 39.7114 408.00 422.11 20.20
1208 39.7377 424.00 417.48 20.59
1209 39.7639 411.00 412.19 20.27
1210 39.7902 416.00 408.85 20.40
1211 39.8165 366.00 406.66 19.13
1212 39.8427 432.00 404.88 20.78
1213 39.8690 384.00 402.74 19.60
1214 39.8952 380.00 401.22 19.49
1215 39.9215 385.00 400.42 19.62
1216 39.9478 406.00 400.32 20.15
1217 39.9740 393.00 400.88 19.82
1218 40.0003 390.00 402.28 19.75
1219 40.0266 405.00 405.29 20.12
1220 40.0528 456.00 411.34 21.35
1221 40.0791 468.00 421.60 21.63
1222 40.1053 531.00 434.46 23.04
1223 40.1316 562.00 441.67 23.71
1224 40.1579 529.00 439.09 23.00
1225 40.1841 538.00 436.88 23.19
1226 40.2104 545.00 441.95 23.35
1227 40.2366 514.00 453.68 22.67
1228 40.2629 462.00 472.94 21.49
1229 40.2892 501.00 508.09 22.38
1230 40.3154 510.00 553.62 22.58
1231 40.3417 512.00 572.96 22.63
1232 40.3679 469.00 549.47 21.66
1233 40.3942 474.00 524.06 21.77
1234 40.4205 444.00 517.17 21.07
1235 40.4467 441.00 512.04 21.00
1236 40.4730 471.00 497.81 21.70
1237 40.4992 444.00 496.44 21.07
1238 40.5255 461.00 526.34 21.47
1239 40.5518 473.00 586.85 21.75
1240 40.5780 467.00 641.57 21.61
1241 40.6043 451.00 631.97 21.24
1242 40.6305 466.00 588.00 21.59
1243 40.6568 486.00 565.52 22.05
1244 40.6831 468.00 559.23 21.63
1245 40.7093 467.00 531.08 21.61
1246 40.7356 412.00 487.48 20.30
1247 40.7618 433.00 453.84 20.81
1248 40.7881 401.00 434.80 20.02
1249 40.8144 423.00 425.56 20.57
1250 40.8406 398.00 423.30 19.95
1251 40.8669 408.00 427.93 20.20
1252 40.8932 418.00 439.84 20.44
1253 40.9194 472.00 456.93 21.73
1254 40.9457 507.00 477.66 22.52
1255 40.9719 514.00 502.20 22.67
1256 40.9982 489.00 512.33 22.11
1257 41.0245 513.00 495.73 22.65
1258 41.0507 444.00 474.82 21.07
1259 41.0770 483.00 464.35 21.98
1260 41.1032 469.00 455.62 21.66
1261 41.1295 404.00 438.53 20.10
1262 41.1558 428.00 420.88 20.69
1263 41.1820 471.00 408.96 21.70
1264 41.2083 410.00 402.41 20.25
1265 41.2345 406.00 400.20 20.15
1266 41.2608 440.00 399.66 20.98
1267 41.2871 392.00 400.15 19.80
1268 41.3133 423.00 400.99 20.57
1269 41.3396 434.00 403.36 20.83
1270 41.3658 426.00 408.29 20.64
1271 41.3921 448.00 413.98 21.17
1272 41.4184 406.00 414.89 20.15
1273 41.4446 380.00 411.33 19.49
1274 41.4709 418.00 408.33 20.44
1275 41.4971 446.00 408.10 21.12
1276 41.5234 414.00 407.33 20.35
1277 41.5497 409.00 405.02 20.22
1278 41.5759 421.00 403.57 20.52
1279 41.6022 418.00 405.32 20.44
1280 41.6284 426.00 411.53 20.64
1281 41.6547 453.00 424.39 21.28
1282 41.6810 468.00 444.76 21.63
1283 41.7072 447.00 467.15 21.14
1284 41.7335 464.00 480.83 21.54
1285 41.7597 469.00 492.32 21.66
1286 41.7860 478.00 505.16 21.86
1287 41.8123 494.00 504.00 22.23
1288 41.8385 537.00 490.24 23.17
1289 41.8648 556.00 480.99 23.58
1290 41.8911 566.00 487.69 23.79
1291 41.9173 639.00 509.58 25.28
1292 41.9436 680.00 550.85 26.08
1293 41.9698 675.00 604.34 25.98
1294 41.9961 699.00 622.58 26.44
1295 42.0224 694.00 587.93 26.34
1296 42.0486 698.00 556.56 26.42
1297 42.0749 615.00 553.01 24.80
1298 42.1011 623.00 551.38 24.96
1299 42.1274 702.00 525.70 26.50
1300 42.1537 648.00 501.43 25.46
1301 42.1799 746.00 497.60 27.31
1302 42.2062 751.00 504.79 27.40
1303 42.2324 760.00 503.58 27.57
1304 42.2587 752.00 491.52 27.42
1305 42.2850 676.00 478.12 26.00
1306 42.3112 633.00 466.86 25.16
1307 42.3375 657.00 454.35 25.63
1308 42.3637 615.00 439.87 24.80
1309 42.3900 516.00 425.38 22.72
1310 42.4163 451.00 413.22 21.24
1311 42.4425 442.00 404.22 21.02
1312 42.4688 467.00 398.52 21.61
1313 42.4950 411.00 394.65 20.27
1314 42.5213 465.00 392.04 21.56
1315 42.5476 422.00 390.62 20.54
1316 42.5738 397.00 390.29 19.92
1317 42.6001 421.00 390.16 20.52
1318 42.6263 430.00 390.02 20.74
1319 42.6526 406.00 389.06 20.15
1320 42.6789 387.00 387.50 19.67
1321 42.7051 367.00 386.49 19.16
1322 42.7314 401.00 386.11 20.02
1323 42.7576 383.00 385.64 19.57
1324 42.7839 350.00 384.85 18.71
1325 42.8102 401.00 384.29 20.02
1326 42.8364 386.00 384.10 19.65
1327 42.8627 382.00 384.42 19.54
1328 42.8890 371.00 385.20 19.26
1329 42.9152 369.00 387.85 19.21
1330 42.9415 410.00 392.40 20.25
1331 42.9677 348.00 398.02 18.65
1332 42.9940 425.00 400.41 20.62
1333 43.0203 397.00 398.18 19.92
1334 43.0465 374.00 395.31 19.34
1335 43.0728 385.00 394.78 19.62
1336 43.0990 357.00 395.35 18.89
1337 43.1253 372.00 395.22 19.29
1338 43.1516 362.00 395.06 19.03
1339 43.1778 367.00 394.95 19.16
1340 43.2041 425.00 394.14 20.62
1341 43.2303 351.00 394.93 18.74
1342 43.2566 395.00 399.81 19.87
1343 43.2829 424.00 409.12 20.59
1344 43.3091 410.00 419.13 20.25
1345 43.3354 439.00 421.65 20.95
1346 43.3616 423.00 414.58 20.57
1347 43.3879 432.00 407.90 20.78
1348 43.4142 406.00 406.24 20.15
1349 43.4404 398.00 406.45 19.95
1350 43.4667 397.00 403.73 19.92
1351 43.4929 377.00 399.99 19.42
1352 43.5192 419.00 396.83 20.47
1353 43.5455 376.00 395.00 19.39
1354 43.5717 372.00 395.53 19.29
1355 43.5980 375.00 397.71 19.36
1356 43.6242 411.00 401.50 20.27
1357 43.6505 445.00 407.57 21.09
1358 43.6768 425.00 415.51 20.62
1359 43.7030 422.00 424.31 20.54
1360 43.7293 475.00 430.81 21.79
1361 43.7556 443.00 434.86 21.05
1362 43.7818 456.00 444.79 21.35
1363 43.8081 451.00 461.40 21.24
1364 43.8343 456.00 472.66 21.35
1365 43.8606 424.00 462.59 20.59
1366 43.8869 433.00 443.58 20.81
1367 43.9131 428.00 432.36 20.69
1368 43.9394 426.00 428.59 20.64
1369 43.9656 434.00 422.68 20.83
1370 43.9919 411.00 412.62 20.27
1371 44.0182 428.00 405.12 20.69
1372 44.0444 402.00 401.82 20.05
1373 44.0707 391.00 400.68 19.77
1374 44.0969 423.00 399.34 20.57
1375 44.1232 421.00 396.53 20.52
1376 44.1495 408.00 394.46 20.20
1377 44.1757 403.00 394.21 20.07
1378 44.2020 400.00 395.72 20.00
1379 44.2282 451.00 398.53 21.24
1380 44.2545 449.00 403.30 21.19
1381 44.2808 413.00 409.20 20.32
1382 44.3070 465.00 414.97 21.56
1383 44.3333 433.00 416.72 20.81
1384 44.3595 428.00 411.94 20.69
1385 44.3858 457.00 406.90 21.38
1386 44.4121 423.00 405.13 20.57
1387 44.4383 400.00 405.66 20.00
1388 44.4646 417.00 403.67 20.42
1389 44.4908 466.00 398.15 21.59
1390 44.5171 401.00 392.52 20.02
1391 44.5434 434.00 389.75 20.83
1392 44.5696 424.00 389.59 20.59
1393 44.5959 367.00 391.45 19.16
1394 44.6222 392.00 395.74 19.80
1395 44.6484 420.00 405.45 20.49
1396 44.6747 389.00 421.56 19.72
1397 44.7009 398.00 438.15 19.95
1398 44.7272 431.00 439.49 20.76
1399 44.7535 426.00 427.32 20.64
1400 44.7797 409.00 418.13 20.22
1401 44.8060 412.00 416.24 20.30
1402 44.8322 392.00 414.41 19.80
1403 44.8585 443.00 405.81 21.05
1404 44.8848 394.00 395.52 19.85
1405 44.9110 387.00 388.00 19.67
1406 44.9373 398.00 383.47 19.95
1407 44.9635 369.00 381.04 19.21
1408 44.9898 380.00 379.76 19.49
1409 45.0161 383.00 379.13 19.57
1410 45.0423 373.00 378.89 19.31
1411 45.0686 414.00 378.92 20.35
1412 45.0948 381.00 379.36 19.52
1413 45.1211 426.00 379.99 20.64
1414 45.1474 376.00 381.08 19.39
1415 45.1736 366.00 382.94 19.13
1416 45.1999 417.00 386.56 20.42
1417 45.2261 388.00 393.72 19.70
1418 45.2524 417.00 407.05 20.42
1419 45.2787 431.00 427.26 20.76
1420 45.3049 457.00 447.68 21.38
1421 45.3312 453.00 452.01 21.28
1422 45.3574 439.00 441.98 20.95
1423 45.3837 436.00 434.05 20.88
1424 45.4100 447.00 432.72 21.14
1425 45.4362 464.00 433.21 21.54
1426 45.4625 443.00 429.66 21.05
1427 45.4888 413.00 429.29 20.32
1428 45.5150 432.00 441.26 20.78
1429 45.5413 454.00 468.62 21.31
1430 45.5675 465.00 502.87 21.56
1431 45.5938 510.00 513.48 22.58
1432 45.6201 454.00 489.81 21.31
1433 45.6463 454.00 465.36 21.31
1434 45.6726 444.00 457.26 21.07
1435 45.6988 428.00 456.99 20.69
1436 45.7251 437.00 445.02 20.90
1437 45.7514 385.00 424.88 19.62
1438 45.7776 442.00 408.89 21.02
1439 45.8039 426.00 401.94 20.64
1440 45.8301 396.00 403.14 19.90
1441 45.8564 415.00 408.97 20.37
1442 45.8827 386.00 412.03 19.65
1443 45.9089 380.00 407.10 19.49
1444 45.9352 386.00 400.22 19.65
1445 45.9614 423.00 396.98 20.57
1446 45.9877 412.00 396.64 20.30
1447 46.0140 359.00 394.82 18.95
1448 46.0402 413.00 390.24 20.32
1449 46.0665 409.00 386.17 20.22
1450 46.0927 376.00 384.11 19.39
1451 46.1190 349.00 384.23 18.68
1452 46.1453 399.00 386.91 19.98
1453 46.1715 372.00 393.33 19.29
1454 46.1978 418.00 404.76 20.44
1455 46.2240 406.00 420.58 20.15
1456 46.2503 405.00 434.69 20.12
1457 46.2766 392.00 440.08 19.80
1458 46.3028 372.00 436.71 19.29
1459 46.3291 417.00 429.34 20.42
1460 46.3553 396.00 425.56 19.90
1461 46.3816 349.00 424.94 18.68
1462 46.4079 402.00 425.54 20.05
1463 46.4341 389.00 429.07 19.72
1464 46.4604 363.00 442.73 19.05
1465 46.4866 381.00 473.34 19.52
1466 46.5129 358.00 514.55 18.92
1467 46.5392 398.00 536.03 19.95
1468 46.5654 422.00 515.53 20.54
1469 46.5917 376.00 486.92 19.39
1470 46.6180 388.00 477.28 19.70
1471 46.6442 378.00 484.36 19.44
1472 46.6705 423.00 484.64 20.57
1473 46.6967 389.00 467.29 19.72
1474 46.7230 420.00 445.27 20.49
1475 46.7493 394.00 432.42 19.85
1476 46.7755 390.00 432.54 19.75
1477 46.8018 397.00 437.96 19.92
1478 46.8280 375.00 436.64 19.36
1479 46.8543 404.00 430.15 20.10
1480 46.8806 407.00 426.21 20.17
1481 46.9068 354.00 426.85 18.81
1482 46.9331 408.00 428.26 20.20
1483 46.9593 418.00 423.29 20.44
1484 46.9856 432.00 414.08 20.78
1485 47.0119 444.00 407.35 21.07
1486 47.0381 426.00 405.35 20.64
1487 47.0644 442.00 406.67 21.02
1488 47.0906 464.00 407.94 21.54
1489 47.1169 465.00 406.56 21.56
1490 47.1432 455.00 401.02 21.33
1491 47.1694 481.00 395.39 21.93
1492 47.1957 473.00 393.06 21.75
1493 47.2219 438.00 394.33 20.93
1494 47.2482 435.00 396.96 20.86
1495 47.2745 466.00 401.40 21.59
1496 47.3007 467.00 411.70 21.61
1497 47.3270 426.00 429.53 20.64
1498 47.3532 480.00 450.49 21.91
1499 47.3795 487.00 462.35 22.07
1500 47.4058 544.00 456.14 23.32
1501 47.4320 501.00 444.14 22.38
1502 47.4583 510.00 439.23 22.58
1503 47.4846 502.00 442.21 22.41
1504 47.5108 491.00 443.67 22.16
1505 47.5371 443.00 440.35 21.05
1506 47.5633 448.00 440.93 21.17
1507 47.5896 499.00 451.78 22.34
1508 47.6159 524.00 473.41 22.89
1509 47.6421 480.00 490.45 21.91
1510 47.6684 520.00 482.45 22.80
1511 47.6946 495.00 460.99 22.25
1512 47.7209 470.00 447.01 21.68
1513 47.7472 421.00 444.30 20.52
1514 47.7734 451.00 442.12 21.24
1515 47.7997 392.00 430.52 19.80
1516 47.8259 376.00 415.43 19.39
1517 47.8522 456.00 403.70 21.35
1518 47.8785 449.00 397.06 21.19
1519 47.9047 399.00 394.59 19.98
1520 47.9310 401.00 395.13 20.02
1521 47.9572 453.00 397.05 21.28
1522 47.9835 436.00 400.09 20.88
1523 48.0098 466.00 407.84 21.59
1524 48.0360 485.00 426.01 22.02
1525 48.0623 531.00 461.44 23.04
1526 48.0885 547.00 516.98 23.39
1527 48.1148 628.00 578.12 25.06
1528 48.1411 617.00 600.27 24.84
1529 48.1673 663.00 572.98 25.75
1530 48.1936 646.00 543.95 25.42
1531 48.2198 618.00 539.89 24.86
1532 48.2461 664.00 551.60 25.77
1533 48.2724 635.00 543.25 25.20
1534 48.2986 568.00 505.27 23.83
1535 48.3249 506.00 465.11 22.49
1536 48.3512 505.00 438.43 22.47
1537 48.3774 500.00 424.46 22.36
1538 48.4037 486.00 415.27 22.05
1539 48.4299 466.00 405.38 21.59
1540 48.4562 449.00 397.34 21.19
1541 48.4825 475.00 392.13 21.79
1542 48.5087 398.00 390.54 19.95
1543 48.5350 397.00 393.27 19.92
1544 48.5612 457.00 400.64 21.38
1545 48.5875 422.00 412.20 20.54
1546 48.6138 381.00 428.80 19.52
1547 48.6400 449.00 448.29 21.19
1548 48.6663 419.00 456.25 20.47
1549 48.6925 398.00 443.73 19.95
1550 48.7188 406.00 427.51 20.15
1551 48.7451 391.00 419.60 19.77
1552 48.7713 427.00 419.41 20.66
1553 48.7976 414.00 416.76 20.35
1554 48.8238 409.00 406.28 20.22
1555 48.8501 366.00 395.33 19.13
1556 48.8764 404.00 388.53 20.10
1557 48.9026 395.00 386.81 19.87
1558 48.9289 424.00 390.55 20.59
1559 48.9551 420.00 400.64 20.49
1560 48.9814 454.00 417.44 21.31
1561 49.0077 482.00 436.96 21.95
1562 49.0339 423.00 448.73 20.57
1563 49.0602 501.00 452.07 22.38
1564 49.0864 476.00 460.07 21.82
1565 49.1127 478.00 470.10 21.86
1566 49.1390 508.00 471.52 22.54
1567 49.1652 486.00 468.84 22.05
1568 49.1915 491.00 471.82 22.16
1569 49.2178 484.00 483.19 22.00
1570 49.2440 480.00 486.05 21.91
1571 49.2703 479.00 467.80 21.89
1572 49.2965 420.00 448.13 20.49
1573 49.3228 452.00 441.59 21.26
1574 49.3491 448.00 444.43 21.17
1575 49.3753 422.00 440.45 20.54
1576 49.4016 481.00 424.21 21.93
1577 49.4278 441.00 408.40 21.00
1578 49.4541 413.00 399.38 20.32
1579 49.4804 448.00 395.66 21.17
1580 49.5066 441.00 392.92 21.00
1581 49.5329 424.00 389.83 20.59
1582 49.5591 429.00 387.01 20.71
1583 49.5854 360.00 383.95 18.97
1584 49.6117 403.00 382.02 20.07
1585 49.6379 381.00 382.08 19.52
1586 49.6642 333.00 381.24 18.25
1587 49.6904 372.00 378.00 19.29
1588 49.7167 357.00 374.10 18.89
1589 49.7430 393.00 371.31 19.82
1590 49.7692 361.00 369.94 19.00
1591 49.7955 345.00 368.35 18.57
1592 49.8217 354.00 366.00 18.81
1593 49.8480 348.00 363.89 18.65
1594 49.8743 362.00 362.48 19.03
1595 49.9005 382.00 361.72 19.54
1596 49.9268 340.00 361.53 18.44
1597 49.9530 345.00 361.75 18.57
1598 49.9793 328.00 362.27 18.11
1599 50.0056 340.00 362.64 18.44
1600 50.0318 363.00 362.20 19.05
1601 50.0581 375.00 361.37 19.36
1602 50.0843 361.00 361.13 19.00
1603 50.1106 354.00 361.61 18.81
1604 50.1369 375.00 362.40 19.36
1605 50.1631 402.00 362.79 20.05
1606 50.1894 382.00 362.05 19.54
1607 50.2157 308.00 361.18 17.55
1608 50.2419 354.00 360.98 18.81
1609 50.2682 372.00 361.34 19.29
1610 50.2944 326.00 362.03 18.06
1611 50.3207 376.00 362.00 19.39
1612 50.3470 339.00 361.53 18.41
1613 50.3732 349.00 361.57 18.68
1614 50.3995 375.00 362.80 19.36
1615 50.4257 372.00 365.46 19.29
1616 50.4520 337.00 368.80 18.36
1617 50.4783 399.00 370.96 19.98
1618 50.5045 305.00 370.74 17.46
1619 50.5308 395.00 369.63 19.87
1620 50.5570 327.00 368.40 18.08
1621 50.5833 377.00 367.37 19.42
1622 50.6096 382.00 366.49 19.54
1623 50.6358 360.00 365.15 18.97
1624 50.6621 350.00 363.66 18.71
1625 50.6883 310.00 362.33 17.61
1626 50.7146 342.00 360.96 18.49
1627 50.7409 356.00 360.00 18.87
1628 50.7671 361.00 359.58 19.00
1629 50.7934 346.00 359.66 18.60
1630 50.8196 413.00 360.19 20.32
1631 50.8459 308.00 361.23 17.55
1632 50.8722 382.00 362.89 19.54
1633 50.8984 342.00 365.36 18.49
1634 50.9247 357.00 369.22 18.89
1635 50.9509 336.00 376.26 18.33
1636 50.9772 317.00 388.55 17.80
1637 51.0035 382.00 405.60 19.54
1638 51.0297 342.00 419.54 18.49
1639 51.0560 389.00 418.26 19.72
1640 51.0822 362.00 408.16 19.03
1641 51.1085 372.00 401.31 19.29
1642 51.1348 379.00 400.20 19.47
1643 51.1610 366.00 402.05 19.13
1644 51.1873 375.00 400.71 19.36
1645 51.2136 359.00 396.98 18.95
1646 51.2398 405.00 397.26 20.12
1647 51.2661 381.00 403.86 19.52
1648 51.2923 398.00 415.65 19.95
1649 51.3186 411.00 427.85 20.27
1650 51.3449 396.00 430.06 19.90
1651 51.3711 392.00 420.11 19.80
1652 51.3974 410.00 410.54 20.25
1653 51.4236 389.00 409.54 19.72
1654 51.4499 368.00 415.60 19.18
1655 51.4762 405.00 419.12 20.12
1656 51.5024 390.00 410.93 19.75
1657 51.5287 361.00 397.02 19.00
1658 51.5549 358.00 385.92 18.92
1659 51.5812 366.00 379.57 19.13
1660 51.6075 358.00 376.74 18.92
1661 51.6337 370.00 373.79 19.24
1662 51.6600 379.00 369.72 19.47
1663 51.6862 353.00 366.25 18.79
1664 51.7125 382.00 363.71 19.54
1665 51.7388 345.00 362.07 18.57
1666 51.7650 296.00 361.91 17.20
1667 51.7913 393.00 363.33 19.82
1668 51.8175 346.00 367.00 18.60
1669 51.8438 367.00 373.42 19.16
1670 51.8701 373.00 381.61 19.31
1671 51.8963 367.00 386.95 19.16
1672 51.9226 350.00 385.62 18.71
1673 51.9488 355.00 382.78 18.84
1674 51.9751 344.00 383.48 18.55
1675 52.0014 365.00 387.30 19.10
1676 52.0276 381.00 391.92 19.52
1677 52.0539 359.00 394.79 18.95
1678 52.0802 376.00 393.70 19.39
1679 52.1064 372.00 387.61 19.29
1680 52.1327 350.00 380.28 18.71
1681 52.1589 346.00 375.33 18.60
1682 52.1852 423.00 373.54 20.57
1683 52.2115 352.00 373.59 18.76
1684 52.2377 369.00 371.90 19.21
1685 52.2640 351.00 369.03 18.74
1686 52.2902 375.00 366.93 19.36
1687 52.3165 391.00 366.23 19.77
1688 52.3428 386.00 367.48 19.65
1689 52.3690 391.00 371.27 19.77
1690 52.3953 359.00 379.26 18.95
1691 52.4215 381.00 394.52 19.52
1692 52.4478 385.00 420.44 19.62
1693 52.4741 442.00 457.33 21.02
1694 52.5003 410.00 493.51 20.25
1695 52.5266 482.00 507.94 21.95
1696 52.5528 467.00 494.43 21.61
1697 52.5791 424.00 471.23 20.59
1698 52.6054 442.00 454.83 21.02
1699 52.6316 442.00 449.92 21.02
1700 52.6579 442.00 446.58 21.02
1701 52.6841 433.00 434.10 20.81
1702 52.7104 390.00 414.78 19.75
1703 52.7367 416.00 395.61 20.40
1704 52.7629 378.00 381.17 19.44
1705 52.7892 429.00 372.51 20.71
1706 52.8154 370.00 368.43 19.24
1707 52.8417 384.00 367.68 19.60
1708 52.8680 367.00 369.36 19.16
1709 52.8942 391.00 373.07 19.77
1710 52.9205 383.00 378.05 19.57
1711 52.9468 384.00 385.54 19.60
1712 52.9730 418.00 398.88 20.44
1713 52.9993 405.00 416.84 20.12
1714 53.0255 395.00 427.74 19.87
1715 53.0518 380.00 420.39 19.49
1716 53.0781 435.00 406.06 20.86
1717 53.1043 373.00 398.05 19.31
1718 53.1306 399.00 399.19 19.98
1719 53.1568 380.00 403.38 19.49
1720 53.1831 345.00 399.76 18.57
1721 53.2094 363.00 389.31 19.05
1722 53.2356 378.00 381.14 19.44
1723 53.2619 365.00 379.11 19.10
1724 53.2881 391.00 382.44 19.77
1725 53.3144 422.00 386.55 20.54
1726 53.3407 347.00 386.00 18.63
1727 53.3669 382.00 383.53 19.54
1728 53.3932 346.00 385.00 18.60
1729 53.4194 363.00 391.04 19.05
1730 53.4457 367.00 396.58 19.16
1731 53.4720 379.00 393.62 19.47
1732 53.4982 398.00 384.21 19.95
1733 53.5245 388.00 377.14 19.70
1734 53.5507 389.00 374.47 19.72
1735 53.5770 331.00 375.02 18.19
1736 53.6033 385.00 375.01 19.62
1737 53.6295 382.00 373.59 19.54
1738 53.6558 361.00 373.87 19.00
1739 53.6820 387.00 376.80 19.67
1740 53.7083 368.00 382.28 19.18
1741 53.7346 353.00 388.65 18.79
1742 53.7608 355.00 392.56 18.84
1743 53.7871 355.00 395.65 18.84
1744 53.8134 357.00 398.37 18.89
1745 53.8396 378.00 396.50 19.44
1746 53.8659 320.00 390.58 17.89
1747 53.8921 361.00 384.11 19.00
1748 53.9184 401.00 378.89 20.02
1749 53.9447 374.00 375.92 19.34
1750 53.9709 343.00 373.28 18.52
1751 53.9972 388.00 368.68 19.70
1752 54.0234 390.00 363.87 19.75
1753 54.0497 382.00 360.55 19.54
1754 54.0760 343.00 359.08 18.52
1755 54.1022 340.00 358.97 18.44
1756 54.1285 360.00 359.60 18.97
1757 54.1547 374.00 361.18 19.34
1758 54.1810 379.00 365.18 19.47
1759 54.2073 383.00 372.96 19.57
1760 54.2335 398.00 385.77 19.95
1761 54.2598 377.00 402.68 19.42
1762 54.2860 390.00 418.67 19.75
1763 54.3123 400.00 430.73 20.00
1764 54.3386 396.00 437.33 19.90
1765 54.3648 423.00 432.60 20.57
1766 54.3911 415.00 423.10 20.37
1767 54.4173 471.00 418.12 21.70
1768 54.4436 421.00 419.01 20.52
1769 54.4699 395.00 424.19 19.87
1770 54.4961 414.00 425.90 20.35
1771 54.5224 444.00 417.61 21.07
1772 54.5486 398.00 407.86 19.95
1773 54.5749 406.00 406.85 20.15
1774 54.6012 430.00 416.72 20.74
1775 54.6274 421.00 430.48 20.52
1776 54.6537 418.00 432.62 20.44
1777 54.6799 433.00 421.77 20.81
1778 54.7062 410.00 410.36 20.25
1779 54.7325 448.00 403.16 21.17
1780 54.7587 445.00 401.71 21.09
1781 54.7850 456.00 402.03 21.35
1782 54.8113 445.00 397.32 21.09
1783 54.8375 446.00 390.69 21.12
1784 54.8638 458.00 387.53 21.40
1785 54.8900 445.00 389.27 21.09
1786 54.9163 467.00 396.53 21.61
1787 54.9426 407.00 404.54 20.17
1788 54.9688 410.00 403.19 20.25
1789 54.9951 402.00 392.43 20.05
1790 55.0213 363.00 382.95 19.05
1791 55.0476 377.00 379.88 19.42
1792 55.0739 372.00 382.24 19.29
1793 55.1001 377.00 384.43 19.42
1794 55.1264 373.00 379.91 19.31
1795 55.1526 392.00 371.41 19.80
1796 55.1789 379.00 364.52 19.47
1797 55.2052 397.00 360.65 19.92
1798 55.2314 381.00 359.18 19.52
1799 55.2577 352.00 358.88 18.76
1800 55.2839 375.00 359.41 19.36
1801 55.3102 370.00 361.79 19.24
1802 55.3365 378.00 366.90 19.44
1803 55.3627 386.00 374.52 19.65
1804 55.3890 419.00 380.89 20.47
1805 55.4152 388.00 381.60 19.70
1806 55.4415 388.00 378.07 19.70
1807 55.4678 402.00 374.00 20.05
1808 55.4940 381.00 372.74 19.52
1809 55.5203 370.00 375.47 19.24
1810 55.5465 391.00 379.80 19.77
1811 55.5728 394.00 384.18 19.85
1812 55.5991 404.00 390.57 20.10
1813 55.6253 433.00 401.05 20.81
1814 55.6516 426.00 414.35 20.64
1815 55.6778 437.00 423.98 20.90
1816 55.7041 413.00 426.72 20.32
1817 55.7304 424.00 431.55 20.59
1818 55.7566 374.00 442.54 19.34
1819 55.7829 442.00 447.49 21.02
1820 55.8092 379.00 437.45 19.47
1821 55.8354 407.00 420.83 20.17
1822 55.8617 399.00 406.04 19.98
1823 55.8879 398.00 398.82 19.95
1824 55.9142 394.00 397.16 19.85
1825 55.9405 399.00 392.56 19.98
1826 55.9667 381.00 383.79 19.52
1827 55.9930 351.00 376.17 18.74
1828 56.0192 350.00 370.97 18.71
1829 56.0455 354.00 367.95 18.81
1830 56.0718 377.00 367.25 19.42
1831 56.0980 342.00 366.88 18.49
1832 56.1243 326.00 365.02 18.06
1833 56.1505 324.00 362.75 18.00
1834 56.1768 363.00 361.22 19.05
1835 56.2031 334.00 360.74 18.28
1836 56.2293 354.00 361.53 18.81
1837 56.2556 358.00 363.35 18.92
1838 56.2818 369.00 366.57 19.21
1839 56.3081 362.00 372.31 19.03
1840 56.3344 377.00 378.58 19.42
1841 56.3606 375.00 379.31 19.36
1842 56.3869 370.00 373.67 19.24
1843 56.4131 378.00 368.02 19.44
1844 56.4394 364.00 366.15 19.08
1845 56.4657 399.00 367.99 19.98
1846 56.4919 372.00 370.18 19.29
1847 56.5182 380.00 368.93 19.49
1848 56.5444 381.00 365.72 19.52
1849 56.5707 394.00 364.22 19.85
1850 56.5970 373.00 365.21 19.31
1851 56.6232 393.00 366.72 19.82
1852 56.6495 376.00 367.27 19.39
1853 56.6758 388.00 367.43 19.70
1854 56.7020 343.00 368.08 18.52
1855 56.7283 377.00 368.72 19.42
1856 56.7545 422.00 367.64 20.54
1857 56.7808 432.00 365.51 20.78
1858 56.8071 423.00 364.40 20.57
1859 56.8333 392.00 364.76 19.80
1860 56.8596 402.00 367.45 20.05
1861 56.8858 398.00 372.77 19.95
1862 56.9121 421.00 379.98 20.52
1863 56.9384 409.00 386.42 20.22
1864 56.9646 433.00 387.02 20.81
1865 56.9909 437.00 384.07 20.90
1866 57.0171 446.00 385.08 21.12
1867 57.0434 479.00 392.02 21.89
1868 57.0697 450.00 399.89 21.21
1869 57.0959 450.00 399.79 21.21
1870 57.1222 444.00 390.75 21.07
1871 57.1484 456.00 380.09 21.35
1872 57.1747 462.00 373.42 21.49
1873 57.2010 422.00 371.05 20.54
1874 57.2272 403.00 369.70 20.07
1875 57.2535 390.00 365.76 19.75
1876 57.2797 416.00 360.18 20.40
1877 57.3060 344.00 355.30 18.55
1878 57.3323 367.00 351.95 19.16
1879 57.3585 357.00 349.83 18.89
1880 57.3848 362.00 348.71 19.03
1881 57.4110 372.00 348.29 19.29
1882 57.4373 358.00 348.74 18.92
1883 57.4636 380.00 350.47 19.49
1884 57.4898 363.00 354.00 19.05
1885 57.5161 359.00 359.58 18.95
1886 57.5424 376.00 365.92 19.39
1887 57.5686 377.00 368.61 19.42
1888 57.5949 368.00 365.39 19.18
1889 57.6211 383.00 360.70 19.57
1890 57.6474 379.00 358.49 19.47
1891 57.6737 350.00 359.78 18.71
1892 57.6999 370.00 364.08 19.24
1893 57.7262 365.00 369.26 19.10
1894 57.7524 375.00 374.01 19.36
1895 57.7787 401.00 377.90 20.02
1896 57.8050 379.00 376.70 19.47
1897 57.8312 392.00 369.85 19.80
1898 57.8575 355.00 363.28 18.84
1899 57.8837 395.00 360.27 19.87
1900 57.9100 397.00 361.10 19.92
1901 57.9363 366.00 364.10 19.13
1902 57.9625 350.00 365.90 18.71
1903 57.9888 394.00 365.83 19.85
1904 58.0150 380.00 365.15 19.49
1905 58.0413 418.00 362.89 20.44
1906 58.0676 385.00 358.64 19.62
1907 58.0938 382.00 354.99 19.54
1908 58.1201 387.00 353.37 19.67
1909 58.1463 411.00 353.69 20.27
1910 58.1726 383.00 354.86 19.57
1911 58.1989 400.00 355.38 20.00
1912 58.2251 400.00 354.95 20.00
1913 58.2514 387.00 354.87 19.67
1914 58.2776 338.00 356.64 18.38
1915 58.3039 382.00 361.31 19.54
1916 58.3302 356.00 369.12 18.87
1917 58.3564 379.00 378.39 19.47
1918 58.3827 371.00 385.46 19.26
1919 58.4090 393.00 387.79 19.82
1920 58.4352 365.00 386.52 19.10
1921 58.4615 359.00 381.75 18.95
1922 58.4877 380.00 377.12 19.49
1923 58.5140 349.00 375.37 18.68
1924 58.5403 375.00 375.47 19.36
1925 58.5665 360.00 375.83 18.97
1926 58.5928 350.00 375.26 18.71
1927 58.6190 417.00 372.11 20.42
1928 58.6453 348.00 366.91 18.65
1929 58.6716 365.00 363.10 19.10
1930 58.6978 360.00 362.25 18.97
1931 58.7241 349.00 364.99 18.68
1932 58.7503 358.00 371.89 18.92
1933 58.7766 414.00 383.66 20.35
1934 58.8029 385.00 400.73 19.62
1935 58.8291 424.00 421.64 20.59
1936 58.8554 364.00 437.85 19.08
1937 58.8816 403.00 439.13 20.07
1938 58.9079 378.00 426.10 19.44
1939 58.9342 359.00 411.38 18.95
1940 58.9604 373.00 404.64 19.31
1941 58.9867 377.00 406.16 19.42
1942 59.0129 383.00 408.78 19.57
1943 59.0392 365.00 405.14 19.10
1944 59.0655 416.00 394.37 20.40
1945 59.0917 384.00 382.26 19.60
1946 59.1180 381.00 373.53 19.52
1947 59.1442 346.00 369.61 18.60
1948 59.1705 375.00 368.73 19.36
1949 59.1968 353.00 370.11 18.79
1950 59.2230 383.00 373.41 19.57
1951 59.2493 370.00 378.65 19.24
1952 59.2755 373.00 387.82 19.31
1953 59.3018 392.00 402.05 19.80
1954 59.3281 432.00 416.35 20.78
1955 59.3543 407.00 422.33 20.17
1956 59.3806 404.00 423.33 20.10
1957 59.4068 428.00 427.08 20.69
1958 59.4331 468.00 433.27 21.63
1959 59.4594 473.00 434.70 21.75
1960 59.4856 421.00 427.17 20.52
1961 59.5119 434.00 414.39 20.83
1962 59.5382 428.00 402.45 20.69
1963 59.5644 424.00 396.14 20.59
1964 59.5907 414.00 394.65 20.35
1965 59.6169 401.00 393.69 20.02
1966 59.6432 403.00 390.42 20.07
1967 59.6695 388.00 387.56 19.70
1968 59.6957 399.00 385.95 19.98
1969 59.7220 363.00 383.19 19.05
1970 59.7482 375.00 379.70 19.36
1971 59.7745 382.00 378.14 19.54
1972 59.8008 400.00 381.04 20.00
1973 59.8270 427.00 389.24 20.66
1974 59.8533 360.00 401.09 18.97
1975 59.8795 357.00 411.74 18.89
1976 59.9058 358.00 418.54 18.92
1977 59.9321 374.00 426.29 19.34
1978 59.9583 368.00 437.45 19.18
1979 59.9846 386.00 448.10 19.65
1980 60.0108 360.00 448.24 18.97
