# Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics.
# This journal is © the Owner Societies 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
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# Crystallographic Data Centre (CCDC).
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# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
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data_crt1501
_database_code_depnum_ccdc_archive 'CCDC 1498195'
_audit_update_record             
;
2016-08-08 deposited with the CCDC.
2016-09-26 downloaded from the CCDC.
;
_audit_creation_date             2015-12-02
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
_shelxl_version_number           2014/6
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C8 H12 Ag N4, C6 F18 P'
_chemical_formula_sum            'C14 H12 Ag F18 N4 P'
_chemical_formula_weight         717.12
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   17.6078(6)
_cell_length_b                   15.0214(5)
_cell_length_c                   18.0740(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     4780.5(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9883
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.53
_cell_measurement_theta_min      2.53
_shelx_estimated_absorpt_T_max   0.763
_shelx_estimated_absorpt_T_min   0.721
_exptl_absorpt_coefficient_mu    1.062
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_correction_T_min  0.6670
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0526 before and 0.0444 after correction.
The Ratio of minimum to maximum transmission is 0.8943.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.993
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2784
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.27
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0402
_diffrn_reflns_av_unetI/netI     0.0234
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            72757
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.729
_diffrn_reflns_theta_min         2.108
_diffrn_ambient_temperature      100.15
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.987
_diffrn_source                   'fine-focus sealed tube'
_diffrn_radiation_monochromator  'Triumph curved graphite'
_diffrn_measurement_device_type  'Bruker Smart APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 83.33
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4548
_reflns_number_total             6118
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_refine_diff_density_max         0.746
_refine_diff_density_min         -0.473
_refine_diff_density_rms         0.075
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.145
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     573
_refine_ls_number_reflns         6118
_refine_ls_number_restraints     37
_refine_ls_R_factor_all          0.0687
_refine_ls_R_factor_gt           0.0426
_refine_ls_restrained_S_all      1.158
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0343P)²+6.1280P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0873
_refine_ls_wR_factor_ref         0.0990
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C13A-C14A \\sim C13-C14
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
C10 \\sim C10A: within 2A with sigma of 0.005 and sigma for terminal atoms of
0.01
Uanis(C10) \\sim Ueq, Uanis(C14A) \\sim Ueq, Uanis(F16A) \\sim Ueq, Uanis(F17A)
\\sim Ueq, Uanis(F18A) \\sim Ueq: with sigma of 0.005 and sigma for terminal
atoms of 0.01
4. Others
 Sof(P1A)=Sof(C9A)=Sof(C10A)=Sof(C11A)=Sof(C12A)=Sof(C13A)=Sof(C14A)=Sof(F1A)=
 Sof(F2A)=Sof(F3A)=Sof(F4A)=Sof(F5A)=Sof(F6A)=Sof(F7A)=Sof(F8A)=Sof(F9A)=
 Sof(F10A)=Sof(F11A)=Sof(F12A)=Sof(F13A)=Sof(F14A)=Sof(F15A)=Sof(F16A)=
 Sof(F17A)=Sof(F18A)=1-FVAR(1)
 Sof(P1)=Sof(C9)=Sof(C10)=Sof(C11)=Sof(C12)=Sof(C13)=Sof(C14)=Sof(F1)=Sof(F2)=
 Sof(F3)=Sof(F4)=Sof(F5)=Sof(F6)=Sof(F7)=Sof(F8)=Sof(F9)=Sof(F10)=Sof(F11)=
 Sof(F12)=Sof(F13)=Sof(F14)=Sof(F15)=Sof(F16)=Sof(F17)=Sof(F18)=FVAR(1)
5.a Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C4(H4A,H4B,H4C), C6(H6A,H6B,H6C), C8(H8A,H8B,H8C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.01149(2) 0.22037(2) 0.24047(2) 0.04094(9) Uani 1 1 d . . . . .
N1 N -0.05282(17) 0.09476(18) 0.27109(16) 0.0457(7) Uani 1 1 d . . . . .
N2 N 0.13556(16) 0.21751(17) 0.27704(14) 0.0369(6) Uani 1 1 d . . . . .
N3 N 0.00993(18) 0.2386(2) 0.11467(18) 0.0528(8) Uani 1 1 d . . . . .
N4 N -0.04292(16) 0.34834(18) 0.28536(16) 0.0443(7) Uani 1 1 d . . . . .
C1 C -0.08239(18) 0.0309(2) 0.28846(18) 0.0375(7) Uani 1 1 d . . . . .
C2 C -0.1193(2) -0.0510(2) 0.31090(18) 0.0425(8) Uani 1 1 d . . . . .
H2A H -0.1329 -0.0856 0.2669 0.064 Uiso 1 1 calc GR . . . .
H2B H -0.1653 -0.0370 0.3391 0.064 Uiso 1 1 calc GR . . . .
H2C H -0.0845 -0.0858 0.3419 0.064 Uiso 1 1 calc GR . . . .
C3 C 0.19845(18) 0.21724(18) 0.29018(15) 0.0304(6) Uani 1 1 d . . . . .
C4 C 0.27953(18) 0.2167(2) 0.30649(17) 0.0402(7) Uani 1 1 d . . . . .
H4A H 0.3031 0.1644 0.2836 0.060 Uiso 1 1 calc GR . . . .
H4B H 0.2871 0.2144 0.3602 0.060 Uiso 1 1 calc GR . . . .
H4C H 0.3029 0.2709 0.2867 0.060 Uiso 1 1 calc GR . . . .
C5 C 0.0112(2) 0.2477(2) 0.0525(2) 0.0468(8) Uani 1 1 d . . . . .
C6 C 0.0132(2) 0.2600(3) -0.0271(2) 0.0559(10) Uani 1 1 d . . . . .
H6A H -0.0128 0.3155 -0.0400 0.084 Uiso 1 1 calc GR . . . .
H6B H -0.0123 0.2098 -0.0513 0.084 Uiso 1 1 calc GR . . . .
H6C H 0.0661 0.2628 -0.0438 0.084 Uiso 1 1 calc GR . . . .
C7 C -0.07293(19) 0.4127(2) 0.29874(19) 0.0421(8) Uani 1 1 d . . . . .
C8 C -0.1122(2) 0.4955(2) 0.3161(2) 0.0613(11) Uani 1 1 d . . . . .
H8A H -0.0785 0.5342 0.3449 0.092 Uiso 1 1 calc GR . . . .
H8B H -0.1579 0.4824 0.3451 0.092 Uiso 1 1 calc GR . . . .
H8C H -0.1266 0.5255 0.2701 0.092 Uiso 1 1 calc GR . . . .
P1 P 0.28583(8) 0.07973(8) 0.00547(7) 0.0257(3) Uani 0.5346(16) 1 d . . P A 1
C9 C 0.2419(4) 0.1606(6) 0.0769(4) 0.0283(16) Uani 0.5346(16) 1 d . . P A 1
C10 C 0.2716(10) 0.2552(12) 0.0780(12) 0.027(2) Uani 0.5346(16) 1 d . U P A 1
C11 C 0.1993(3) 0.0848(4) -0.0628(3) 0.0320(12) Uani 0.5346(16) 1 d . . P A 1
C12 C 0.1286(5) 0.0235(6) -0.0569(4) 0.0416(18) Uani 0.5346(16) 1 d . . P A 1
C13 C 0.3404(4) -0.0113(4) -0.0495(4) 0.0399(15) Uani 0.5346(16) 1 d D . P A 1
C14 C 0.4072(6) 0.0113(7) -0.1027(7) 0.054(3) Uani 0.5346(16) 1 d D . P A 1
F1 F 0.3215(2) 0.1607(2) -0.04285(19) 0.0359(8) Uani 0.5346(16) 1 d . . P A 1
F2 F 0.36006(17) 0.0817(2) 0.05816(18) 0.0326(7) Uani 0.5346(16) 1 d . . P A 1
F3 F 0.2466(5) 0.0005(8) 0.0542(4) 0.0240(14) Uani 0.5346(16) 1 d . . P A 1
F4 F 0.2585(9) 0.1284(9) 0.1409(7) 0.049(4) Uani 0.5346(16) 1 d . . P A 1
F5 F 0.16506(18) 0.1614(2) 0.07661(17) 0.0356(7) Uani 0.5346(16) 1 d . . P A 1
F6 F 0.2431(3) 0.3007(2) 0.0146(2) 0.0464(9) Uani 0.5346(16) 1 d . . P A 1
F7 F 0.3405(2) 0.2688(2) 0.0822(2) 0.0483(9) Uani 0.5346(16) 1 d . . P A 1
F8 F 0.2345(3) 0.3025(2) 0.1335(2) 0.0509(10) Uani 0.5346(16) 1 d . . P A 1
F9 F 0.1708(3) 0.1697(3) -0.0633(2) 0.0422(9) Uani 0.5346(16) 1 d . . P A 1
F10 F 0.2256(2) 0.0733(3) -0.13359(18) 0.0460(9) Uani 0.5346(16) 1 d . . P A 1
F11 F 0.0805(2) 0.0443(3) -0.1112(2) 0.0634(12) Uani 0.5346(16) 1 d . . P A 1
F12 F 0.0937(2) 0.0353(3) 0.0068(2) 0.0526(10) Uani 0.5346(16) 1 d . . P A 1
F13 F 0.1470(2) -0.0615(3) -0.0633(2) 0.0499(10) Uani 0.5346(16) 1 d . . P A 1
F14 F 0.2942(2) -0.0655(2) -0.08891(19) 0.0382(8) Uani 0.5346(16) 1 d . . P A 1
F15 F 0.3756(2) -0.0693(2) 0.00475(18) 0.0422(8) Uani 0.5346(16) 1 d . . P A 1
F16 F 0.3771(3) 0.0618(3) -0.1532(2) 0.0608(11) Uani 0.5346(16) 1 d . . P A 1
F17 F 0.4372(2) -0.0609(3) -0.1237(2) 0.0694(13) Uani 0.5346(16) 1 d . . P A 1
F18 F 0.4592(3) 0.0578(4) -0.0613(3) 0.0632(14) Uani 0.5346(16) 1 d . . P A 1
P1A P 0.22851(9) 0.09489(9) -0.00965(8) 0.0253(4) Uani 0.4654(16) 1 d . . P A 2
C9A C 0.2748(5) 0.1612(8) 0.0695(5) 0.031(2) Uani 0.4654(16) 1 d . . P A 2
C10A C 0.2586(11) 0.2676(12) 0.0717(14) 0.026(2) Uani 0.4654(16) 1 d . U P A 2
C11A C 0.1689(7) 0.0269(6) -0.0791(5) 0.051(2) Uani 0.4654(16) 1 d . . P A 2
C12A C 0.0909(8) -0.0109(7) -0.0553(5) 0.069(4) Uani 0.4654(16) 1 d . . P A 2
C13A C 0.3211(4) 0.0838(5) -0.0680(4) 0.0436(17) Uani 0.4654(16) 1 d D . P A 2
C14A C 0.3828(7) 0.0106(8) -0.0546(7) 0.070(3) Uani 0.4654(16) 1 d D U P A 2
F1A F 0.2126(3) 0.1861(3) -0.0553(2) 0.0297(9) Uani 0.4654(16) 1 d . . P A 2
F2A F 0.15009(19) 0.1098(2) 0.03573(19) 0.0296(8) Uani 0.4654(16) 1 d . . P A 2
F3A F 0.2473(7) 0.0031(9) 0.0326(5) 0.031(2) Uani 0.4654(16) 1 d . . P A 2
F4A F 0.2497(10) 0.1332(8) 0.1415(8) 0.040(3) Uani 0.4654(16) 1 d . . P A 2
F5A F 0.3517(2) 0.1462(3) 0.0767(2) 0.0447(10) Uani 0.4654(16) 1 d . . P A 2
F6A F 0.3010(3) 0.3022(3) 0.0187(2) 0.0473(11) Uani 0.4654(16) 1 d . . P A 2
F7A F 0.1935(2) 0.2854(2) 0.0731(3) 0.0481(11) Uani 0.4654(16) 1 d . . P A 2
F8A F 0.2957(4) 0.2932(3) 0.1374(3) 0.0612(14) Uani 0.4654(16) 1 d . . P A 2
F9A F 0.1522(4) 0.0742(3) -0.1422(2) 0.0731(18) Uani 0.4654(16) 1 d . . P A 2
F10A F 0.2104(4) -0.0466(3) -0.1020(3) 0.0772(19) Uani 0.4654(16) 1 d . . P A 2
F11A F 0.0411(3) 0.0526(4) -0.0464(3) 0.0729(17) Uani 0.4654(16) 1 d . . P A 2
F12A F 0.0983(3) -0.0574(3) 0.0073(3) 0.0608(13) Uani 0.4654(16) 1 d . . P A 2
F13A F 0.0649(5) -0.0650(4) -0.1072(4) 0.112(3) Uani 0.4654(16) 1 d . . P A 2
F14A F 0.3030(3) 0.0784(3) -0.1411(2) 0.0579(13) Uani 0.4654(16) 1 d . . P A 2
F15A F 0.3614(3) 0.1614(3) -0.0622(3) 0.0454(11) Uani 0.4654(16) 1 d . . P A 2
F16A F 0.3520(5) -0.0699(4) -0.0699(4) 0.099(2) Uani 0.4654(16) 1 d . U P A 2
F17A F 0.4405(6) 0.0264(8) -0.0977(7) 0.105(4) Uani 0.4654(16) 1 d . U P A 2
F18A F 0.4076(3) 0.0080(4) 0.0121(3) 0.0826(19) Uani 0.4654(16) 1 d . U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.269(3) . ?
Ag1 N2 2.283(3) . ?
Ag1 N3 2.290(3) . ?
Ag1 N4 2.296(3) . ?
N1 C1 1.136(4) . ?
N2 C3 1.133(4) . ?
N3 C5 1.131(5) . ?
N4 C7 1.128(4) . ?
C1 C2 1.449(4) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 C4 1.458(4) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 C6 1.452(6) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.457(4) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
P1 C9 1.934(8) . ?
P1 C11 1.963(5) . ?
P1 C13 1.943(6) . ?
P1 F1 1.623(4) . ?
P1 F2 1.617(3) . ?
P1 F3 1.633(9) . ?
C9 C10 1.51(2) . ?
C9 F4 1.287(15) . ?
C9 F5 1.354(8) . ?
C10 F6 1.424(18) . ?
C10 F7 1.233(19) . ?
C10 F8 1.39(2) . ?
C11 C12 1.552(11) . ?
C11 F9 1.370(7) . ?
C11 F10 1.371(6) . ?
C12 F11 1.334(8) . ?
C12 F12 1.317(9) . ?
C12 F13 1.322(10) . ?
C13 C14 1.556(12) . ?
C13 F14 1.354(7) . ?
C13 F15 1.452(8) . ?
C14 F16 1.300(12) . ?
C14 F17 1.265(14) . ?
C14 F18 1.375(14) . ?
P1A C9A 1.925(10) . ?
P1A C11A 1.929(9) . ?
P1A C13A 1.948(7) . ?
P1A F1A 1.623(4) . ?
P1A F2A 1.621(4) . ?
P1A F3A 1.611(12) . ?
C9A C10A 1.62(2) . ?
C9A F4A 1.438(16) . ?
C9A F5A 1.379(9) . ?
C10A F6A 1.32(2) . ?
C10A F7A 1.18(2) . ?
C10A F8A 1.41(2) . ?
C11A C12A 1.548(15) . ?
C11A F9A 1.375(9) . ?
C11A F10A 1.388(12) . ?
C12A F11A 1.305(14) . ?
C12A F12A 1.336(11) . ?
C12A F13A 1.322(10) . ?
C13A C14A 1.565(12) . ?
C13A F14A 1.362(9) . ?
C13A F15A 1.368(9) . ?
C14A F16A 1.354(15) . ?
C14A F17A 1.301(15) . ?
C14A F18A 1.282(13) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N2 113.03(10) . . ?
N1 Ag1 N3 109.60(12) . . ?
N1 Ag1 N4 113.69(10) . . ?
N2 Ag1 N3 107.53(10) . . ?
N2 Ag1 N4 108.22(10) . . ?
N3 Ag1 N4 104.24(11) . . ?
C1 N1 Ag1 176.9(3) . . ?
C3 N2 Ag1 175.2(2) . . ?
C5 N3 Ag1 178.1(3) . . ?
C7 N4 Ag1 171.4(3) . . ?
N1 C1 C2 179.3(4) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N2 C3 C4 179.5(3) . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
N3 C5 C6 179.6(5) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
N4 C7 C8 179.6(4) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C9 P1 C11 94.9(3) . . ?
C9 P1 C13 168.6(3) . . ?
C13 P1 C11 95.1(3) . . ?
F1 P1 C9 92.5(3) . . ?
F1 P1 C11 86.2(2) . . ?
F1 P1 C13 93.5(3) . . ?
F1 P1 F3 177.6(4) . . ?
F2 P1 C9 85.3(3) . . ?
F2 P1 C11 175.6(2) . . ?
F2 P1 C13 85.1(2) . . ?
F2 P1 F1 89.45(19) . . ?
F2 P1 F3 92.2(3) . . ?
F3 P1 C9 85.9(4) . . ?
F3 P1 C11 92.2(4) . . ?
F3 P1 C13 88.4(4) . . ?
C10 C9 P1 117.4(9) . . ?
F4 C9 P1 105.9(9) . . ?
F4 C9 C10 105.3(11) . . ?
F4 C9 F5 103.5(9) . . ?
F5 C9 P1 113.7(5) . . ?
F5 C9 C10 109.7(8) . . ?
F6 C10 C9 108.6(13) . . ?
F7 C10 C9 119.8(12) . . ?
F7 C10 F6 108.4(15) . . ?
F7 C10 F8 109.3(15) . . ?
F8 C10 C9 109.1(14) . . ?
F8 C10 F6 99.7(10) . . ?
C12 C11 P1 123.8(4) . . ?
F9 C11 P1 108.9(4) . . ?
F9 C11 C12 105.0(5) . . ?
F9 C11 F10 103.7(4) . . ?
F10 C11 P1 108.6(4) . . ?
F10 C11 C12 105.1(5) . . ?
F11 C12 C11 108.6(7) . . ?
F12 C12 C11 110.8(6) . . ?
F12 C12 F11 108.4(6) . . ?
F12 C12 F13 108.8(8) . . ?
F13 C12 C11 111.7(6) . . ?
F13 C12 F11 108.5(7) . . ?
C14 C13 P1 122.4(6) . . ?
F14 C13 P1 113.3(5) . . ?
F14 C13 C14 105.0(6) . . ?
F14 C13 F15 104.5(5) . . ?
F15 C13 P1 106.8(4) . . ?
F15 C13 C14 103.0(6) . . ?
F16 C14 C13 104.7(8) . . ?
F16 C14 F18 110.9(8) . . ?
F17 C14 C13 108.4(7) . . ?
F17 C14 F16 117.4(11) . . ?
F17 C14 F18 108.7(9) . . ?
F18 C14 C13 106.1(9) . . ?
C9A P1A C11A 171.3(4) . . ?
C9A P1A C13A 95.3(3) . . ?
C11A P1A C13A 93.3(5) . . ?
F1A P1A C9A 90.8(4) . . ?
F1A P1A C11A 91.2(3) . . ?
F1A P1A C13A 86.6(3) . . ?
F2A P1A C9A 85.0(3) . . ?
F2A P1A C11A 86.5(4) . . ?
F2A P1A C13A 176.3(3) . . ?
F2A P1A F1A 89.6(2) . . ?
F3A P1A C9A 90.2(5) . . ?
F3A P1A C11A 88.2(5) . . ?
F3A P1A C13A 90.7(5) . . ?
F3A P1A F1A 177.2(4) . . ?
F3A P1A F2A 93.0(4) . . ?
C10A C9A P1A 117.0(9) . . ?
F4A C9A P1A 113.0(7) . . ?
F4A C9A C10A 102.3(12) . . ?
F5A C9A P1A 113.6(7) . . ?
F5A C9A C10A 109.4(10) . . ?
F5A C9A F4A 99.7(10) . . ?
F6A C10A C9A 105.7(14) . . ?
F6A C10A F8A 104.0(14) . . ?
F7A C10A C9A 113.2(15) . . ?
F7A C10A F6A 118.4(16) . . ?
F7A C10A F8A 111.8(18) . . ?
F8A C10A C9A 102.0(12) . . ?
C12A C11A P1A 119.8(6) . . ?
F9A C11A P1A 112.5(6) . . ?
F9A C11A C12A 103.3(9) . . ?
F9A C11A F10A 106.0(7) . . ?
F10A C11A P1A 109.2(7) . . ?
F10A C11A C12A 105.0(8) . . ?
F11A C12A C11A 111.2(8) . . ?
F11A C12A F12A 110.1(10) . . ?
F11A C12A F13A 107.7(11) . . ?
F12A C12A C11A 109.9(10) . . ?
F13A C12A C11A 109.7(9) . . ?
F13A C12A F12A 108.2(7) . . ?
C14A C13A P1A 123.9(6) . . ?
F14A C13A P1A 109.5(5) . . ?
F14A C13A C14A 105.7(7) . . ?
F14A C13A F15A 104.2(5) . . ?
F15A C13A P1A 108.6(4) . . ?
F15A C13A C14A 103.1(7) . . ?
F16A C14A C13A 108.5(9) . . ?
F17A C14A C13A 108.8(10) . . ?
F17A C14A F16A 110.6(11) . . ?
F18A C14A C13A 113.8(9) . . ?
F18A C14A F16A 107.5(10) . . ?
F18A C14A F17A 107.6(11) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C9 C10 F6 73.3(12) . . . . ?
P1 C9 C10 F7 -51.9(19) . . . . ?
P1 C9 C10 F8 -178.9(7) . . . . ?
P1 C11 C12 F11 179.7(4) . . . . ?
P1 C11 C12 F12 60.7(7) . . . . ?
P1 C11 C12 F13 -60.7(7) . . . . ?
P1 C13 C14 F16 -61.5(10) . . . . ?
P1 C13 C14 F17 172.4(6) . . . . ?
P1 C13 C14 F18 55.8(9) . . . . ?
F4 C9 C10 F6 -169.2(13) . . . . ?
F4 C9 C10 F7 66(2) . . . . ?
F4 C9 C10 F8 -61.4(14) . . . . ?
F5 C9 C10 F6 -58.5(14) . . . . ?
F5 C9 C10 F7 176.3(14) . . . . ?
F5 C9 C10 F8 49.3(13) . . . . ?
F9 C11 C12 F11 54.1(7) . . . . ?
F9 C11 C12 F12 -64.9(6) . . . . ?
F9 C11 C12 F13 173.7(5) . . . . ?
F10 C11 C12 F11 -55.0(7) . . . . ?
F10 C11 C12 F12 -173.9(5) . . . . ?
F10 C11 C12 F13 64.6(7) . . . . ?
F14 C13 C14 F16 69.5(9) . . . . ?
F14 C13 C14 F17 -56.6(9) . . . . ?
F14 C13 C14 F18 -173.2(7) . . . . ?
F15 C13 C14 F16 178.6(7) . . . . ?
F15 C13 C14 F17 52.5(9) . . . . ?
F15 C13 C14 F18 -64.1(8) . . . . ?
P1A C9A C10A F6A -75.2(13) . . . . ?
P1A C9A C10A F7A 56(2) . . . . ?
P1A C9A C10A F8A 176.3(8) . . . . ?
P1A C11A C12A F11A 69.6(10) . . . . ?
P1A C11A C12A F12A -52.5(11) . . . . ?
P1A C11A C12A F13A -171.4(7) . . . . ?
P1A C13A C14A F16A 65.6(11) . . . . ?
P1A C13A C14A F17A -174.0(9) . . . . ?
P1A C13A C14A F18A -54.1(13) . . . . ?
F4A C9A C10A F6A 160.8(13) . . . . ?
F4A C9A C10A F7A -68.0(19) . . . . ?
F4A C9A C10A F8A 52.3(15) . . . . ?
F5A C9A C10A F6A 55.7(15) . . . . ?
F5A C9A C10A F7A -173.1(14) . . . . ?
F5A C9A C10A F8A -52.7(15) . . . . ?
F9A C11A C12A F11A -56.4(9) . . . . ?
F9A C11A C12A F12A -178.6(7) . . . . ?
F9A C11A C12A F13A 62.6(10) . . . . ?
F10A C11A C12A F11A -167.4(7) . . . . ?
F10A C11A C12A F12A 70.5(9) . . . . ?
F10A C11A C12A F13A -48.3(11) . . . . ?
F14A C13A C14A F16A -61.8(10) . . . . ?
F14A C13A C14A F17A 58.6(12) . . . . ?
F14A C13A C14A F18A 178.6(9) . . . . ?
F15A C13A C14A F16A -170.9(8) . . . . ?
F15A C13A C14A F17A -50.5(12) . . . . ?
F15A C13A C14A F18A 69.4(11) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: acetonitrile'
_chemical_properties_physical    
', Air-sensitive,Moisture-sensitive,Light-sensitive'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_crt1403
_database_code_depnum_ccdc_archive 'CCDC 1498196'
_audit_update_record             
;
2016-08-08 deposited with the CCDC.
2016-09-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C6 F18 P, C4 H6 Ag N2'
_chemical_formula_sum            'C10 H6 Ag F18 N2 P'
_chemical_formula_weight         635.01

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   9.6624(19)
_cell_length_b                   14.990(3)
_cell_length_c                   12.850(3)
_cell_angle_alpha                90
_cell_angle_beta                 93.695(3)
_cell_angle_gamma                90
_cell_volume                     1857.3(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9939
_cell_measurement_theta_min      2.51
_cell_measurement_theta_max      28.60

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.271
_exptl_crystal_F_000             1216
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.120
_exptl_absorpt_coefficient_mu    1.347
_shelx_estimated_absorpt_T_min   0.738
_shelx_estimated_absorpt_T_max   0.855
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.697
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_process_details   'SADABS, Bruker-AXS, 2009'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'ImuS micro-focus tube'
_diffrn_radiation_monochromator  'Quazar focussing montel optics'
_diffrn_measurement_device_type  'Bruker Kappa APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 83.33
_diffrn_reflns_number            29076
_diffrn_reflns_av_unetI/netI     0.0230
_diffrn_reflns_av_R_equivalents  0.0342
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.090
_diffrn_reflns_theta_max         28.677
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             4778
_reflns_number_gt                3951
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_molecular_graphics    'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_publication_material  'SHELXTL 6.12 (Bruker AXS, 2002)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0239P)²+0.7294P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4778
_refine_ls_number_parameters     508
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0340
_refine_ls_R_factor_gt           0.0227
_refine_ls_wR_factor_ref         0.0552
_refine_ls_wR_factor_gt          0.0494
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_restrained_S_all      1.067
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.84921(2) 0.41167(2) 0.56124(2) 0.02839(5) Uani 1 1 d . . . A 4
N1 N 0.75821(18) 0.41646(11) 0.70463(13) 0.0288(4) Uani 1 1 d . . . A 4
N2 N 0.95088(17) 0.40448(11) 0.42207(13) 0.0289(4) Uani 1 1 d . . . A 4
C1 C 0.7034(2) 0.41081(13) 0.77933(16) 0.0280(4) Uani 1 1 d . . . A 4
C2 C 0.6333(2) 0.40321(16) 0.87610(19) 0.0421(5) Uani 1 1 d . . . A 4
H2A H 0.5602 0.3579 0.8679 0.063 Uiso 1 1 calc R U . A 4
H2B H 0.5920 0.4608 0.8926 0.063 Uiso 1 1 calc R U . A 4
H2C H 0.7005 0.3858 0.9328 0.063 Uiso 1 1 calc R U . A 4
C3 C 0.9905(2) 0.39125(13) 0.34245(16) 0.0288(4) Uani 1 1 d . . . A 4
C4 C 1.0409(3) 0.37370(18) 0.24045(17) 0.0454(6) Uani 1 1 d . . . A 4
H4A H 1.1327 0.3458 0.2487 0.068 Uiso 1 1 calc R U . A 4
H4B H 1.0477 0.4300 0.2023 0.068 Uiso 1 1 calc R U . A 4
H4C H 0.9765 0.3335 0.2015 0.068 Uiso 1 1 calc R U . A 4
P1 P 0.51987(5) 0.26334(3) 0.42067(3) 0.01991(10) Uani 1 1 d . . . B 4
C5 C 0.3631(4) 0.3331(2) 0.4476(3) 0.0213(7) Uani 0.5357(9) 1 d . . P C 1
C6 C 0.3271(13) 0.3537(9) 0.5672(11) 0.0233(17) Uani 0.5357(9) 1 d . U P C 1
C7 C 0.6962(3) 0.1957(2) 0.4121(3) 0.0216(7) Uani 0.5357(9) 1 d . . P C 1
C8 C 0.6919(18) 0.0919(8) 0.4150(10) 0.030(2) Uani 0.5357(9) 1 d . . P C 1
C9 C 0.5021(3) 0.2856(2) 0.2686(2) 0.0211(7) Uani 0.5357(9) 1 d . . P C 1
C10 C 0.5721(4) 0.3646(3) 0.2146(3) 0.0280(8) Uani 0.5357(9) 1 d . . P C 1
F1 F 0.43151(19) 0.17508(13) 0.39837(15) 0.0246(4) Uani 0.5357(9) 1 d . . P C 1
F2 F 0.5415(2) 0.24116(14) 0.54261(15) 0.0240(4) Uani 0.5357(9) 1 d . . P C 1
F3 F 0.61999(18) 0.35389(12) 0.43576(13) 0.0196(4) Uani 0.5357(9) 1 d . . P C 1
F4 F 0.3567(9) 0.4127(6) 0.3963(7) 0.043(3) Uani 0.5357(9) 1 d . . P C 1
F5 F 0.24176(19) 0.28895(14) 0.41952(16) 0.0282(5) Uani 0.5357(9) 1 d . . P C 1
F6 F 0.4550(2) 0.40283(16) 0.60442(17) 0.0386(6) Uani 0.5357(9) 1 d . . P C 1
F7 F 0.2375(9) 0.4173(5) 0.5640(6) 0.0355(11) Uani 0.5357(9) 1 d . . P C 1
F8 F 0.3154(3) 0.29193(19) 0.6209(2) 0.0420(6) Uani 0.5357(9) 1 d . . P C 1
F9 F 0.7842(2) 0.21746(14) 0.49589(15) 0.0267(4) Uani 0.5357(9) 1 d . . P C 1
F10 F 0.7694(2) 0.21533(14) 0.32761(15) 0.0262(4) Uani 0.5357(9) 1 d . . P C 1
F11 F 0.6265(3) 0.06407(16) 0.4986(2) 0.0403(6) Uani 0.5357(9) 1 d . . P C 1
F12 F 0.6217(3) 0.05957(15) 0.3304(2) 0.0424(6) Uani 0.5357(9) 1 d . . P C 1
F13 F 0.8166(3) 0.05827(17) 0.4209(2) 0.0408(6) Uani 0.5357(9) 1 d . . P C 1
F14 F 0.5415(2) 0.21062(14) 0.21648(15) 0.0266(5) Uani 0.5357(9) 1 d . . P C 1
F15 F 0.3637(2) 0.29524(14) 0.23988(15) 0.0273(5) Uani 0.5357(9) 1 d . . P C 1
F16 F 0.5393(6) 0.3619(4) 0.1121(4) 0.0444(12) Uani 0.5357(9) 1 d . . P C 1
F17 F 0.7095(2) 0.36206(15) 0.22801(16) 0.0313(5) Uani 0.5357(9) 1 d . . P C 1
F18 F 0.5306(2) 0.44304(15) 0.24976(17) 0.0348(5) Uani 0.5357(9) 1 d . . P C 1
C5A C 0.4294(4) 0.3683(3) 0.4804(3) 0.0235(8) Uani 0.4643(9) 1 d . . P C 2
C6A C 0.3492(15) 0.3653(11) 0.5587(14) 0.026(2) Uani 0.4643(9) 1 d . U P C 2
C7A C 0.5793(4) 0.1468(3) 0.3778(3) 0.0265(9) Uani 0.4643(9) 1 d . . P C 2
C8A C 0.708(2) 0.1111(10) 0.4326(14) 0.040(3) Uani 0.4643(9) 1 d . . P C 2
C9A C 0.5850(4) 0.3277(3) 0.3058(3) 0.0230(8) Uani 0.4643(9) 1 d . . P C 2
C10A C 0.5062(6) 0.3357(3) 0.1989(4) 0.0272(9) Uani 0.4643(9) 1 d . . P C 2
F1A F 0.3673(2) 0.24298(14) 0.35529(16) 0.0210(5) Uani 0.4643(9) 1 d . . P C 2
F2A F 0.4603(3) 0.20856(17) 0.52220(18) 0.0272(5) Uani 0.4643(9) 1 d . . P C 2
F3A F 0.6596(2) 0.28327(16) 0.48751(18) 0.0288(5) Uani 0.4643(9) 1 d . . P C 2
F4A F 0.5259(3) 0.42627(16) 0.5239(2) 0.0333(6) Uani 0.4643(9) 1 d . . P C 2
F5A F 0.3570(7) 0.4126(6) 0.3988(6) 0.0163(19) Uani 0.4643(9) 1 d . . P C 2
F6A F 0.2671(11) 0.4362(6) 0.5855(7) 0.0422(16) Uani 0.4643(9) 1 d . . P C 2
F7A F 0.3908(4) 0.3292(2) 0.6551(2) 0.0395(7) Uani 0.4643(9) 1 d . . P C 2
F8A F 0.2264(3) 0.29896(18) 0.5372(2) 0.0371(6) Uani 0.4643(9) 1 d . . P C 2
F9A F 0.4803(3) 0.08364(15) 0.3975(2) 0.0316(6) Uani 0.4643(9) 1 d . . P C 2
F10A F 0.5934(3) 0.14075(16) 0.27379(18) 0.0308(6) Uani 0.4643(9) 1 d . . P C 2
F11A F 0.7061(4) 0.1027(2) 0.5341(2) 0.0465(8) Uani 0.4643(9) 1 d . . P C 2
F12A F 0.8237(3) 0.1577(2) 0.4114(2) 0.0498(8) Uani 0.4643(9) 1 d . . P C 2
F13A F 0.7352(4) 0.0258(2) 0.3959(3) 0.0519(9) Uani 0.4643(9) 1 d . . P C 2
F14A F 0.7121(2) 0.29283(17) 0.28593(19) 0.0316(6) Uani 0.4643(9) 1 d . . P C 2
F15A F 0.6129(3) 0.41420(16) 0.3358(2) 0.0318(6) Uani 0.4643(9) 1 d . . P C 2
F16A F 0.5822(6) 0.3798(5) 0.1323(5) 0.0425(13) Uani 0.4643(9) 1 d . . P C 2
F17A F 0.4741(3) 0.25816(17) 0.15539(19) 0.0361(6) Uani 0.4643(9) 1 d . . P C 2
F18A F 0.3880(3) 0.38177(18) 0.20493(19) 0.0358(6) Uani 0.4643(9) 1 d . . P C 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.0934(17) . ?
Ag1 N2 2.0980(17) . ?
N1 C1 1.129(3) . ?
N2 C3 1.133(3) . ?
C1 C2 1.458(3) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 C4 1.451(3) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 F4 1.364(10) . ?
C5 F5 1.373(4) . ?
C5 C6 1.628(14) . ?
C6 F8 1.164(14) . ?
C6 F7 1.286(16) . ?
C6 F6 1.491(13) . ?
C7 F10 1.365(4) . ?
C7 F9 1.368(4) . ?
C7 C8 1.557(12) . ?
C8 F13 1.304(18) . ?
C8 F12 1.335(13) . ?
C8 F11 1.346(14) . ?
C9 F15 1.372(4) . ?
C9 F14 1.374(4) . ?
C9 C10 1.549(5) . ?
C10 F17 1.328(5) . ?
C10 F18 1.332(5) . ?
C10 F16 1.335(7) . ?
C5A C6A 1.310(16) . ?
C5A F4A 1.367(5) . ?
C5A F5A 1.391(9) . ?
C6A F6A 1.383(19) . ?
C6A F7A 1.386(17) . ?
C6A F8A 1.559(15) . ?
C7A F10A 1.356(5) . ?
C7A F9A 1.381(5) . ?
C7A C8A 1.49(2) . ?
C8A F11A 1.313(19) . ?
C8A F12A 1.360(19) . ?
C8A F13A 1.394(14) . ?
C9A F14A 1.373(4) . ?
C9A F15A 1.375(4) . ?
C9A C10A 1.532(6) . ?
C10A F17A 1.318(5) . ?
C10A F16A 1.338(8) . ?
C10A F18A 1.341(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N2 176.75(6) . . ?
C1 N1 Ag1 172.95(17) . . ?
C3 N2 Ag1 169.43(16) . . ?
N1 C1 C2 179.6(2) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N2 C3 C4 179.6(2) . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
F4 C5 F5 106.5(5) . . ?
F4 C5 C6 106.5(6) . . ?
F5 C5 C6 96.2(5) . . ?
F8 C6 F7 121.2(11) . . ?
F8 C6 F6 108.2(10) . . ?
F7 C6 F6 100.8(9) . . ?
F8 C6 C5 116.2(10) . . ?
F7 C6 C5 107.2(10) . . ?
F6 C6 C5 100.0(7) . . ?
F10 C7 F9 104.3(3) . . ?
F10 C7 C8 104.6(6) . . ?
F9 C7 C8 103.6(6) . . ?
F13 C8 F12 109.1(9) . . ?
F13 C8 F11 108.3(12) . . ?
F12 C8 F11 107.3(9) . . ?
F13 C8 C7 111.2(9) . . ?
F12 C8 C7 110.8(11) . . ?
F11 C8 C7 110.1(8) . . ?
F15 C9 F14 104.6(2) . . ?
F15 C9 C10 104.2(3) . . ?
F14 C9 C10 105.3(3) . . ?
F17 C10 F18 107.5(4) . . ?
F17 C10 F16 107.4(4) . . ?
F18 C10 F16 107.7(4) . . ?
F17 C10 C9 112.5(3) . . ?
F18 C10 C9 111.9(3) . . ?
F16 C10 C9 109.6(4) . . ?
C6A C5A F4A 97.5(8) . . ?
C6A C5A F5A 107.6(8) . . ?
F4A C5A F5A 107.6(4) . . ?
C5A C6A F6A 122.8(13) . . ?
C5A C6A F7A 123.2(12) . . ?
F6A C6A F7A 102.5(12) . . ?
C5A C6A F8A 111.5(12) . . ?
F6A C6A F8A 95.3(9) . . ?
F7A C6A F8A 94.8(9) . . ?
F10A C7A F9A 104.4(3) . . ?
F10A C7A C8A 107.9(8) . . ?
F9A C7A C8A 103.6(7) . . ?
F11A C8A F12A 108.2(11) . . ?
F11A C8A F13A 105.3(13) . . ?
F12A C8A F13A 103.2(13) . . ?
F11A C8A C7A 116.0(14) . . ?
F12A C8A C7A 113.2(13) . . ?
F13A C8A C7A 109.9(9) . . ?
F14A C9A F15A 104.5(3) . . ?
F14A C9A C10A 105.2(3) . . ?
F15A C9A C10A 104.7(3) . . ?
F17A C10A F16A 106.8(4) . . ?
F17A C10A F18A 107.5(4) . . ?
F16A C10A F18A 106.7(5) . . ?
F17A C10A C9A 113.6(4) . . ?
F16A C10A C9A 110.5(5) . . ?
F18A C10A C9A 111.4(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F4 C5 C6 F8 173.4(9) . . . . ?
F5 C5 C6 F8 64.1(10) . . . . ?
F4 C5 C6 F7 34.2(10) . . . . ?
F5 C5 C6 F7 -75.1(8) . . . . ?
F4 C5 C6 F6 -70.4(8) . . . . ?
F5 C5 C6 F6 -179.7(6) . . . . ?
F10 C7 C8 F13 57.5(9) . . . . ?
F9 C7 C8 F13 -51.5(9) . . . . ?
F10 C7 C8 F12 -64.0(11) . . . . ?
F9 C7 C8 F12 -173.0(8) . . . . ?
F10 C7 C8 F11 177.5(9) . . . . ?
F9 C7 C8 F11 68.5(11) . . . . ?
F15 C9 C10 F17 -175.5(3) . . . . ?
F14 C9 C10 F17 -65.7(4) . . . . ?
F15 C9 C10 F18 63.3(4) . . . . ?
F14 C9 C10 F18 173.1(3) . . . . ?
F15 C9 C10 F16 -56.1(5) . . . . ?
F14 C9 C10 F16 53.7(5) . . . . ?
F4A C5A C6A F6A 70.9(14) . . . . ?
F5A C5A C6A F6A -40.2(16) . . . . ?
F4A C5A C6A F7A -65.9(14) . . . . ?
F5A C5A C6A F7A -177.0(11) . . . . ?
F4A C5A C6A F8A -177.3(8) . . . . ?
F5A C5A C6A F8A 71.6(11) . . . . ?
F10A C7A C8A F11A -172.7(8) . . . . ?
F9A C7A C8A F11A -62.4(10) . . . . ?
F10A C7A C8A F12A 61.3(10) . . . . ?
F9A C7A C8A F12A 171.7(8) . . . . ?
F10A C7A C8A F13A -53.5(14) . . . . ?
F9A C7A C8A F13A 56.9(13) . . . . ?
F14A C9A C10A F17A 68.0(4) . . . . ?
F15A C9A C10A F17A 177.9(3) . . . . ?
F14A C9A C10A F16A -52.0(5) . . . . ?
F15A C9A C10A F16A 57.9(5) . . . . ?
F14A C9A C10A F18A -170.4(3) . . . . ?
F15A C9A C10A F18A -60.6(4) . . . . ?

_refine_diff_density_max         0.418
_refine_diff_density_min         -0.332
_refine_diff_density_rms         0.064

_shelxl_version_number           2014/6

_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: acetonitrile'
_chemical_properties_physical    
', Air-sensitive,Moisture-sensitive,Hygroscopic,Heat-sensitive,Oxygen-sensitive,Light-sensitive'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_crt1404
_database_code_depnum_ccdc_archive 'CCDC 1498197'
_audit_update_record             
;
2016-08-08 deposited with the CCDC.
2016-09-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C6 F18 P, C10 H10 Ag N2'
_chemical_formula_sum            'C16 H10 Ag F18 N2 P'
_chemical_formula_weight         711.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.8087(16)
_cell_length_b                   10.5095(14)
_cell_length_c                   16.822(2)
_cell_angle_alpha                90
_cell_angle_beta                 100.596(2)
_cell_angle_gamma                90
_cell_volume                     2225.8(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9985
_cell_measurement_theta_min      2.30
_cell_measurement_theta_max      28.67

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.122
_exptl_crystal_F_000             1376
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.140
_exptl_absorpt_coefficient_mu    1.137
_shelx_estimated_absorpt_T_min   0.822
_shelx_estimated_absorpt_T_max   0.857
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.702
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_process_details   'SADABS, Bruker-AXS, 2008'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'ImuS micro-focus tube'
_diffrn_radiation_monochromator  'Quazar focussing montel optics'
_diffrn_measurement_device_type  'Bruker Kappa APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean 83.33
_diffrn_reflns_number            37563
_diffrn_reflns_av_unetI/netI     0.0176
_diffrn_reflns_av_R_equivalents  0.0284
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         2.296
_diffrn_reflns_theta_max         28.674
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5744
_reflns_number_gt                5109
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_molecular_graphics    'SHELXTL 6.12 (Bruker AXS, 2002)'
_computing_publication_material  'SHELXTL 6.12 (Bruker AXS, 2002)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0182P)²+1.8271P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5744
_refine_ls_number_parameters     343
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0243
_refine_ls_R_factor_gt           0.0194
_refine_ls_wR_factor_ref         0.0466
_refine_ls_wR_factor_gt          0.0438
_refine_ls_goodness_of_fit_ref   0.964
_refine_ls_restrained_S_all      0.964
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.43289(2) 0.45219(2) 0.57578(2) 0.02119(4) Uani 1 1 d . . . . .
N1 N 0.57008(10) 0.33803(12) 0.59817(7) 0.0175(2) Uani 1 1 d . . . . .
N2 N 0.28760(10) 0.55142(12) 0.54992(8) 0.0200(3) Uani 1 1 d . . . . .
C1 C 0.65248(12) 0.36284(15) 0.65771(9) 0.0217(3) Uani 1 1 d . . . . .
H1 H 0.6490 0.4348 0.6913 0.026 Uiso 1 1 calc R U . . .
C2 C 0.74233(13) 0.28753(17) 0.67200(10) 0.0260(3) Uani 1 1 d . . . . .
H2 H 0.7994 0.3076 0.7147 0.031 Uiso 1 1 calc R U . . .
C3 C 0.74830(13) 0.18264(16) 0.62354(10) 0.0257(3) Uani 1 1 d . . . . .
H3 H 0.8096 0.1299 0.6320 0.031 Uiso 1 1 calc R U . . .
C4 C 0.66319(14) 0.15613(15) 0.56257(10) 0.0268(3) Uani 1 1 d . . . . .
H4 H 0.6650 0.0846 0.5283 0.032 Uiso 1 1 calc R U . . .
C5 C 0.57576(13) 0.23467(15) 0.55207(9) 0.0231(3) Uani 1 1 d . . . . .
H5 H 0.5170 0.2150 0.5106 0.028 Uiso 1 1 calc R U . . .
C6 C 0.21557(13) 0.51770(15) 0.48469(9) 0.0224(3) Uani 1 1 d . . . . .
H6 H 0.2342 0.4544 0.4495 0.027 Uiso 1 1 calc R U . . .
C7 C 0.11564(14) 0.57140(17) 0.46683(11) 0.0290(4) Uani 1 1 d . . . . .
H7 H 0.0665 0.5451 0.4204 0.035 Uiso 1 1 calc R U . . .
C8 C 0.08820(14) 0.66376(17) 0.51740(12) 0.0308(4) Uani 1 1 d . . . . .
H8 H 0.0199 0.7022 0.5063 0.037 Uiso 1 1 calc R U . . .
C9 C 0.16155(14) 0.69961(17) 0.58458(11) 0.0305(4) Uani 1 1 d . . . . .
H9 H 0.1446 0.7633 0.6202 0.037 Uiso 1 1 calc R U . . .
C10 C 0.26018(13) 0.64120(16) 0.59909(10) 0.0260(3) Uani 1 1 d . . . . .
H10 H 0.3103 0.6655 0.6455 0.031 Uiso 1 1 calc R U . . .
P1 P 0.26656(3) 0.21653(3) 0.73547(2) 0.01435(7) Uani 1 1 d . . . . .
F1 F 0.31393(7) 0.31011(8) 0.67342(5) 0.01834(17) Uani 1 1 d . . . . .
F2 F 0.36684(7) 0.12199(8) 0.73685(5) 0.02085(18) Uani 1 1 d . . . . .
F3 F 0.21533(7) 0.12731(8) 0.79748(5) 0.01955(17) Uani 1 1 d . . . . .
F4 F 0.29588(7) 0.35945(9) 0.87748(5) 0.02361(19) Uani 1 1 d . . . . .
F5 F 0.40278(7) 0.19961(9) 0.87905(5) 0.0257(2) Uani 1 1 d . . . . .
F6 F 0.49755(8) 0.42345(10) 0.89030(6) 0.0321(2) Uani 1 1 d . . . . .
F7 F 0.51308(8) 0.32547(11) 0.78046(6) 0.0331(2) Uani 1 1 d . . . . .
F8 F 0.41019(8) 0.48917(9) 0.77652(6) 0.0289(2) Uani 1 1 d . . . . .
F9 F 0.21885(8) -0.01446(8) 0.66789(6) 0.0272(2) Uani 1 1 d . . . . .
F10 F 0.08683(7) 0.11595(9) 0.63676(5) 0.02407(19) Uani 1 1 d . . . . .
F11 F 0.32579(8) 0.11363(10) 0.56434(6) 0.0284(2) Uani 1 1 d . . . . .
F12 F 0.17281(8) 0.03459(9) 0.51344(6) 0.0296(2) Uani 1 1 d . . . . .
F13 F 0.19022(8) 0.23710(9) 0.52964(5) 0.0258(2) Uani 1 1 d . . . . .
F14 F 0.10505(7) 0.35465(9) 0.64812(5) 0.02376(19) Uani 1 1 d . . . . .
F15 F 0.19286(7) 0.45752(8) 0.75017(6) 0.02445(19) Uani 1 1 d . . . . .
F16 F 0.00335(8) 0.21761(10) 0.75243(6) 0.0317(2) Uani 1 1 d . . . . .
F17 F -0.00941(8) 0.42120(11) 0.75568(8) 0.0413(3) Uani 1 1 d . . . . .
F18 F 0.09043(8) 0.32208(13) 0.85318(6) 0.0397(3) Uani 1 1 d . . . . .
C11 C 0.35325(12) 0.29527(14) 0.82994(9) 0.0187(3) Uani 1 1 d . . . . .
C12 C 0.44445(12) 0.38495(16) 0.81799(9) 0.0233(3) Uani 1 1 d . . . . .
C13 C 0.19463(12) 0.10997(14) 0.64774(9) 0.0182(3) Uani 1 1 d . . . . .
C14 C 0.22178(12) 0.12500(15) 0.56268(9) 0.0209(3) Uani 1 1 d . . . . .
C15 C 0.15149(12) 0.34044(14) 0.72770(9) 0.0187(3) Uani 1 1 d . . . . .
C16 C 0.05815(13) 0.32379(18) 0.77334(10) 0.0277(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.1037(12) . ?
Ag1 N2 2.1077(13) . ?
N1 C1 1.340(2) . ?
N1 C5 1.3444(19) . ?
N2 C10 1.343(2) . ?
N2 C6 1.345(2) . ?
C1 C2 1.381(2) . ?
C1 H1 0.9500 . ?
C2 C3 1.381(2) . ?
C2 H2 0.9500 . ?
C3 C4 1.381(2) . ?
C3 H3 0.9500 . ?
C4 C5 1.376(2) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.380(2) . ?
C6 H6 0.9500 . ?
C7 C8 1.378(3) . ?
C7 H7 0.9500 . ?
C8 C9 1.382(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.385(2) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
P1 F2 1.6207(9) . ?
P1 F3 1.6278(9) . ?
P1 F1 1.6302(9) . ?
P1 C13 1.9445(15) . ?
P1 C11 1.9478(16) . ?
P1 C15 1.9530(15) . ?
F4 C11 1.3604(17) . ?
F5 C11 1.3794(17) . ?
F6 C12 1.3421(18) . ?
F7 C12 1.3289(19) . ?
F8 C12 1.3291(18) . ?
F9 C13 1.3721(17) . ?
F10 C13 1.3604(17) . ?
F11 C14 1.3327(18) . ?
F12 C14 1.3385(18) . ?
F13 C14 1.3333(17) . ?
F14 C15 1.3693(17) . ?
F15 C15 1.3652(17) . ?
F16 C16 1.331(2) . ?
F17 C16 1.338(2) . ?
F18 C16 1.3306(19) . ?
C11 C12 1.543(2) . ?
C13 C14 1.541(2) . ?
C15 C16 1.545(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N2 174.80(5) . . ?
C1 N1 C5 118.00(13) . . ?
C1 N1 Ag1 122.68(10) . . ?
C5 N1 Ag1 119.31(10) . . ?
C10 N2 C6 118.02(14) . . ?
C10 N2 Ag1 122.77(11) . . ?
C6 N2 Ag1 119.03(10) . . ?
N1 C1 C2 122.36(14) . . ?
N1 C1 H1 118.8 . . ?
C2 C1 H1 118.8 . . ?
C1 C2 C3 119.30(15) . . ?
C1 C2 H2 120.3 . . ?
C3 C2 H2 120.3 . . ?
C4 C3 C2 118.52(15) . . ?
C4 C3 H3 120.7 . . ?
C2 C3 H3 120.7 . . ?
C5 C4 C3 119.14(15) . . ?
C5 C4 H4 120.4 . . ?
C3 C4 H4 120.4 . . ?
N1 C5 C4 122.66(15) . . ?
N1 C5 H5 118.7 . . ?
C4 C5 H5 118.7 . . ?
N2 C6 C7 122.64(15) . . ?
N2 C6 H6 118.7 . . ?
C7 C6 H6 118.7 . . ?
C8 C7 C6 119.02(16) . . ?
C8 C7 H7 120.5 . . ?
C6 C7 H7 120.5 . . ?
C7 C8 C9 118.97(16) . . ?
C7 C8 H8 120.5 . . ?
C9 C8 H8 120.5 . . ?
C8 C9 C10 118.95(16) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
N2 C10 C9 122.40(16) . . ?
N2 C10 H10 118.8 . . ?
C9 C10 H10 118.8 . . ?
F2 P1 F3 92.84(5) . . ?
F2 P1 F1 89.52(5) . . ?
F3 P1 F1 177.63(5) . . ?
F2 P1 C13 85.50(6) . . ?
F3 P1 C13 87.94(6) . . ?
F1 P1 C13 92.39(6) . . ?
F2 P1 C11 85.26(6) . . ?
F3 P1 C11 87.61(6) . . ?
F1 P1 C11 92.44(6) . . ?
C13 P1 C11 169.53(6) . . ?
F2 P1 C15 174.93(6) . . ?
F3 P1 C15 92.22(6) . . ?
F1 P1 C15 85.41(6) . . ?
C13 P1 C15 94.98(6) . . ?
C11 P1 C15 94.66(6) . . ?
F4 C11 F5 104.35(11) . . ?
F4 C11 C12 106.11(12) . . ?
F5 C11 C12 104.32(12) . . ?
F4 C11 P1 113.69(10) . . ?
F5 C11 P1 108.02(10) . . ?
C12 C11 P1 119.02(10) . . ?
F8 C12 F7 108.76(13) . . ?
F8 C12 F6 106.89(13) . . ?
F7 C12 F6 107.64(13) . . ?
F8 C12 C11 112.77(12) . . ?
F7 C12 C11 110.94(13) . . ?
F6 C12 C11 109.63(12) . . ?
F10 C13 F9 104.79(11) . . ?
F10 C13 C14 105.42(12) . . ?
F9 C13 C14 104.34(11) . . ?
F10 C13 P1 113.82(10) . . ?
F9 C13 P1 107.90(9) . . ?
C14 C13 P1 119.29(10) . . ?
F11 C14 F13 108.26(13) . . ?
F11 C14 F12 107.59(12) . . ?
F13 C14 F12 107.31(12) . . ?
F11 C14 C13 111.51(12) . . ?
F13 C14 C13 112.00(12) . . ?
F12 C14 C13 109.98(13) . . ?
F15 C15 F14 104.43(11) . . ?
F15 C15 C16 105.12(12) . . ?
F14 C15 C16 105.15(12) . . ?
F15 C15 P1 109.43(10) . . ?
F14 C15 P1 108.96(9) . . ?
C16 C15 P1 122.32(11) . . ?
F18 C16 F16 107.84(15) . . ?
F18 C16 F17 107.62(14) . . ?
F16 C16 F17 107.14(13) . . ?
F18 C16 C15 112.20(13) . . ?
F16 C16 C15 112.48(13) . . ?
F17 C16 C15 109.33(15) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 1.0(2) . . . . ?
Ag1 N1 C1 C2 -179.94(12) . . . . ?
N1 C1 C2 C3 0.0(2) . . . . ?
C1 C2 C3 C4 -0.5(2) . . . . ?
C2 C3 C4 C5 0.1(2) . . . . ?
C1 N1 C5 C4 -1.5(2) . . . . ?
Ag1 N1 C5 C4 179.39(13) . . . . ?
C3 C4 C5 N1 1.0(3) . . . . ?
C10 N2 C6 C7 -0.1(2) . . . . ?
Ag1 N2 C6 C7 175.13(12) . . . . ?
N2 C6 C7 C8 0.3(3) . . . . ?
C6 C7 C8 C9 -0.1(3) . . . . ?
C7 C8 C9 C10 -0.2(3) . . . . ?
C6 N2 C10 C9 -0.3(2) . . . . ?
Ag1 N2 C10 C9 -175.34(13) . . . . ?
C8 C9 C10 N2 0.5(3) . . . . ?
F4 C11 C12 F8 -65.36(16) . . . . ?
F5 C11 C12 F8 -175.24(12) . . . . ?
P1 C11 C12 F8 64.31(16) . . . . ?
F4 C11 C12 F7 172.35(11) . . . . ?
F5 C11 C12 F7 62.47(15) . . . . ?
P1 C11 C12 F7 -57.97(15) . . . . ?
F4 C11 C12 F6 53.61(16) . . . . ?
F5 C11 C12 F6 -56.28(16) . . . . ?
P1 C11 C12 F6 -176.72(10) . . . . ?
F10 C13 C14 F11 -176.49(12) . . . . ?
F9 C13 C14 F11 -66.38(15) . . . . ?
P1 C13 C14 F11 54.09(16) . . . . ?
F10 C13 C14 F13 62.02(15) . . . . ?
F9 C13 C14 F13 172.13(12) . . . . ?
P1 C13 C14 F13 -67.40(15) . . . . ?
F10 C13 C14 F12 -57.22(15) . . . . ?
F9 C13 C14 F12 52.89(15) . . . . ?
P1 C13 C14 F12 173.36(10) . . . . ?
F15 C15 C16 F18 -63.51(17) . . . . ?
F14 C15 C16 F18 -173.43(13) . . . . ?
P1 C15 C16 F18 61.85(18) . . . . ?
F15 C15 C16 F16 174.68(13) . . . . ?
F14 C15 C16 F16 64.77(17) . . . . ?
P1 C15 C16 F16 -59.96(17) . . . . ?
F15 C15 C16 F17 55.80(15) . . . . ?
F14 C15 C16 F17 -54.11(16) . . . . ?
P1 C15 C16 F17 -178.84(10) . . . . ?

_refine_diff_density_max         0.506
_refine_diff_density_min         -0.261
_refine_diff_density_rms         0.058

_shelxl_version_number           2014/6





#===END OF ALL DATA


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: pyridine'
_chemical_properties_physical    
', Air-sensitive,Moisture-sensitive,Hygroscopic,Heat-sensitive,Oxygen-sensitive,Light-sensitive'
