# Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics.
# This journal is © the Owner Societies 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1523132'
_audit_update_record             
;
2016-12-16 deposited with the CCDC.
2017-01-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        k161003
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C34 H27 F2 N O2 Pt Si'
_chemical_formula_sum            'C34 H27 F2 N O2 Pt Si'
_chemical_formula_weight         742.74

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.181(3)
_cell_length_b                   9.435(3)
_cell_length_c                   18.057(5)
_cell_angle_alpha                97.901(5)
_cell_angle_beta                 104.260(5)
_cell_angle_gamma                102.170(5)
_cell_volume                     1452.0(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6109
_cell_measurement_theta_min      2.327
_cell_measurement_theta_max      28.298

_exptl_crystal_description       plate
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.699
_exptl_crystal_F_000             728
_exptl_transmission_factor_min   0.359
_exptl_transmission_factor_max   0.612
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.10
_exptl_absorpt_coefficient_mu    4.918
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'SADABS (Sheldric, 1996)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD diffractometer'
_diffrn_measurement_method       ω-scans
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            10992
_diffrn_reflns_av_unetI/netI     0.0527
_diffrn_reflns_av_R_equivalents  0.0410
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.187
_diffrn_reflns_theta_max         28.316
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.802
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.802
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.802
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             4197
_reflns_number_gt                3723
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 1999)'
_computing_cell_refinement       'SMART (Bruker, 1999)'
_computing_data_reduction        'SAINT-Plus (Bruker, 1999)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0430P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4197
_refine_ls_number_parameters     370
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0358
_refine_ls_R_factor_gt           0.0300
_refine_ls_wR_factor_ref         0.0851
_refine_ls_wR_factor_gt          0.0695
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_restrained_S_all      1.030
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.31986(2) 0.59936(2) 0.45671(2) 0.03872(8) Uani 1 1 d . . . . .
Si Si 0.43985(15) 0.89880(16) 0.15338(8) 0.0315(3) Uani 1 1 d . . . . .
F1 F 0.1542(4) 0.6572(5) 0.1613(2) 0.0499(9) Uani 1 1 d . . . . .
F2 F 0.6132(4) 0.9845(5) 0.3282(2) 0.0546(10) Uani 1 1 d . . . . .
O1 O 0.3115(6) 0.5246(6) 0.5589(3) 0.0556(12) Uani 1 1 d . . . . .
O2 O 0.1252(6) 0.4474(5) 0.3957(3) 0.0512(10) Uani 1 1 d . . . . .
N1 N 0.5163(6) 0.7567(6) 0.5057(3) 0.0402(10) Uani 1 1 d . . . . .
C1 C 0.5990(8) 0.7783(8) 0.5818(4) 0.0501(14) Uani 1 1 d . . . . .
H1 H 0.5648 0.7149 0.6126 0.060 Uiso 1 1 calc R U . . .
C2 C 0.7285(9) 0.8885(10) 0.6137(4) 0.0601(17) Uani 1 1 d . . . . .
H2 H 0.7840 0.9001 0.6657 0.072 Uiso 1 1 calc R U . . .
C3 C 0.7786(9) 0.9847(10) 0.5684(4) 0.0597(17) Uani 1 1 d . . . . .
H3 H 0.8658 1.0637 0.5906 0.072 Uiso 1 1 calc R U . . .
C4 C 0.6996(7) 0.9641(8) 0.4905(4) 0.0497(14) Uani 1 1 d . . . . .
H4 H 0.7344 1.0269 0.4595 0.060 Uiso 1 1 calc R U . . .
C5 C 0.5668(7) 0.8474(7) 0.4590(3) 0.0390(11) Uani 1 1 d . . . . .
C6 C 0.4659(6) 0.8036(6) 0.3774(3) 0.0346(10) Uani 1 1 d . . . . .
C7 C 0.3378(6) 0.6833(6) 0.3657(3) 0.0365(11) Uani 1 1 d . . . . .
C8 C 0.2321(6) 0.6363(6) 0.2911(3) 0.0380(11) Uani 1 1 d . . . . .
H8 H 0.1438 0.5590 0.2814 0.046 Uiso 1 1 calc R U . . .
C9 C 0.2618(6) 0.7071(6) 0.2321(3) 0.0360(10) Uani 1 1 d . . . . .
C10 C 0.3916(6) 0.8216(6) 0.2389(3) 0.0326(10) Uani 1 1 d . . . . .
C11 C 0.4878(6) 0.8679(6) 0.3150(3) 0.0366(10) Uani 1 1 d . . . . .
C12 C 0.3399(6) 0.7651(6) 0.0578(3) 0.0369(11) Uani 1 1 d . . . . .
C13 C 0.1793(7) 0.7354(8) 0.0217(4) 0.0469(13) Uani 1 1 d . . . . .
H13 H 0.1192 0.7838 0.0455 0.056 Uiso 1 1 calc R U . . .
C14 C 0.1094(8) 0.6369(8) -0.0476(4) 0.0554(16) Uani 1 1 d . . . . .
H14 H 0.0028 0.6184 -0.0699 0.067 Uiso 1 1 calc R U . . .
C15 C 0.1955(9) 0.5650(10) -0.0845(5) 0.0635(18) Uani 1 1 d . . . . .
H15 H 0.1473 0.4976 -0.1314 0.076 Uiso 1 1 calc R U . . .
C16 C 0.3540(9) 0.5935(10) -0.0517(5) 0.066(2) Uani 1 1 d . . . . .
H16 H 0.4139 0.5472 -0.0767 0.079 Uiso 1 1 calc R U . . .
C17 C 0.4232(7) 0.6927(8) 0.0194(4) 0.0515(15) Uani 1 1 d . . . . .
H17 H 0.5297 0.7105 0.0416 0.062 Uiso 1 1 calc R U . . .
C18 C 0.6548(6) 0.9269(6) 0.1688(3) 0.0352(10) Uani 1 1 d . . . . .
C19 C 0.7403(7) 1.0427(8) 0.1450(4) 0.0499(14) Uani 1 1 d . . . . .
H19 H 0.6918 1.1114 0.1242 0.060 Uiso 1 1 calc R U . . .
C20 C 0.8983(8) 1.0576(10) 0.1519(5) 0.065(2) Uani 1 1 d . . . . .
H20 H 0.9547 1.1368 0.1366 0.078 Uiso 1 1 calc R U . . .
C21 C 0.9700(7) 0.9548(10) 0.1813(4) 0.0587(18) Uani 1 1 d . . . . .
H21 H 1.0747 0.9642 0.1853 0.070 Uiso 1 1 calc R U . . .
C22 C 0.8889(8) 0.8393(10) 0.2046(5) 0.0610(19) Uani 1 1 d . . . . .
H22 H 0.9380 0.7704 0.2246 0.073 Uiso 1 1 calc R U . . .
C23 C 0.7319(7) 0.8253(8) 0.1985(4) 0.0477(14) Uani 1 1 d . . . . .
H23 H 0.6772 0.7462 0.2145 0.057 Uiso 1 1 calc R U . . .
C24 C 0.3849(6) 1.0792(6) 0.1491(4) 0.0386(11) Uani 1 1 d . . . . .
C25 C 0.4214(8) 1.1870(8) 0.2154(4) 0.0531(15) Uani 1 1 d . . . . .
H25 H 0.4713 1.1684 0.2631 0.064 Uiso 1 1 calc R U . . .
C26 C 0.3856(10) 1.3225(9) 0.2128(5) 0.069(2) Uani 1 1 d . . . . .
H26 H 0.4106 1.3930 0.2584 0.083 Uiso 1 1 calc R U . . .
C27 C 0.3128(11) 1.3519(9) 0.1421(6) 0.071(2) Uani 1 1 d . . . . .
H27 H 0.2910 1.4433 0.1397 0.086 Uiso 1 1 calc R U . . .
C28 C 0.2732(9) 1.2465(10) 0.0761(5) 0.064(2) Uani 1 1 d . . . . .
H28 H 0.2221 1.2655 0.0287 0.077 Uiso 1 1 calc R U . . .
C29 C 0.3087(8) 1.1096(8) 0.0788(4) 0.0493(14) Uani 1 1 d . . . . .
H29 H 0.2809 1.0386 0.0332 0.059 Uiso 1 1 calc R U . . .
C30 C 0.2048(9) 0.4191(8) 0.5629(5) 0.0585(18) Uani 1 1 d . . . . .
C31 C 0.0793(11) 0.3346(9) 0.5009(5) 0.067(2) Uani 1 1 d . . . . .
H31 H 0.0104 0.2597 0.5127 0.081 Uiso 1 1 calc R U . . .
C32 C 0.0455(9) 0.3497(7) 0.4237(5) 0.0558(17) Uani 1 1 d . . . . .
C33 C 0.2182(12) 0.3858(12) 0.6434(6) 0.080(3) Uani 1 1 d . . . . .
H33A H 0.1330 0.3048 0.6411 0.120 Uiso 1 1 calc R U . . .
H33B H 0.3144 0.3600 0.6623 0.120 Uiso 1 1 calc R U . . .
H33C H 0.2157 0.4716 0.6780 0.120 Uiso 1 1 calc R U . . .
C34 C -0.0914(11) 0.2470(12) 0.3648(6) 0.083(3) Uani 1 1 d . . . . .
H34A H -0.1448 0.1778 0.3896 0.124 Uiso 1 1 calc R U . . .
H34B H -0.1603 0.3023 0.3411 0.124 Uiso 1 1 calc R U . . .
H34C H -0.0578 0.1943 0.3255 0.124 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 1.946(5) . ?
Pt1 N1 1.990(6) . ?
Pt1 O2 1.994(5) . ?
Pt1 O1 2.076(4) . ?
Si C18 1.879(5) . ?
Si C24 1.880(5) . ?
Si C12 1.883(6) . ?
Si C10 1.903(5) . ?
F1 C9 1.358(6) . ?
F2 C11 1.360(6) . ?
O1 C30 1.265(8) . ?
O2 C32 1.290(7) . ?
N1 C1 1.360(8) . ?
N1 C5 1.371(7) . ?
C1 C2 1.343(11) . ?
C1 H1 0.9300 . ?
C2 C3 1.384(11) . ?
C2 H2 0.9300 . ?
C3 C4 1.381(10) . ?
C3 H3 0.9300 . ?
C4 C5 1.394(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.483(8) . ?
C6 C11 1.389(7) . ?
C6 C7 1.403(7) . ?
C7 C8 1.402(8) . ?
C8 C9 1.385(7) . ?
C8 H8 0.9300 . ?
C9 C10 1.397(7) . ?
C10 C11 1.390(8) . ?
C12 C17 1.372(8) . ?
C12 C13 1.407(8) . ?
C13 C14 1.370(10) . ?
C13 H13 0.9300 . ?
C14 C15 1.376(11) . ?
C14 H14 0.9300 . ?
C15 C16 1.381(11) . ?
C15 H15 0.9300 . ?
C16 C17 1.394(11) . ?
C16 H16 0.9300 . ?
C17 H17 0.9300 . ?
C18 C19 1.389(8) . ?
C18 C23 1.396(7) . ?
C19 C20 1.401(9) . ?
C19 H19 0.9300 . ?
C20 C21 1.377(11) . ?
C20 H20 0.9300 . ?
C21 C22 1.363(11) . ?
C21 H21 0.9300 . ?
C22 C23 1.394(9) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 C25 1.380(10) . ?
C24 C29 1.389(8) . ?
C25 C26 1.390(10) . ?
C25 H25 0.9300 . ?
C26 C27 1.381(13) . ?
C26 H26 0.9300 . ?
C27 C28 1.360(13) . ?
C27 H27 0.9300 . ?
C28 C29 1.401(9) . ?
C28 H28 0.9300 . ?
C29 H29 0.9300 . ?
C30 C31 1.396(13) . ?
C30 C33 1.511(10) . ?
C31 C32 1.386(12) . ?
C31 H31 0.9300 . ?
C32 C34 1.481(13) . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Pt1 N1 81.1(2) . . ?
C7 Pt1 O2 92.3(2) . . ?
N1 Pt1 O2 173.28(18) . . ?
C7 Pt1 O1 175.7(2) . . ?
N1 Pt1 O1 94.9(2) . . ?
O2 Pt1 O1 91.7(2) . . ?
C18 Si C24 110.5(2) . . ?
C18 Si C12 107.0(2) . . ?
C24 Si C12 109.8(2) . . ?
C18 Si C10 107.2(2) . . ?
C24 Si C10 110.3(2) . . ?
C12 Si C10 112.0(2) . . ?
C30 O1 Pt1 123.6(5) . . ?
C32 O2 Pt1 125.4(5) . . ?
C1 N1 C5 119.7(6) . . ?
C1 N1 Pt1 123.4(4) . . ?
C5 N1 Pt1 116.9(4) . . ?
C2 C1 N1 121.9(6) . . ?
C2 C1 H1 119.0 . . ?
N1 C1 H1 119.0 . . ?
C1 C2 C3 119.3(7) . . ?
C1 C2 H2 120.4 . . ?
C3 C2 H2 120.4 . . ?
C4 C3 C2 120.3(8) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 118.8(6) . . ?
C3 C4 H4 120.6 . . ?
C5 C4 H4 120.6 . . ?
N1 C5 C4 119.8(5) . . ?
N1 C5 C6 112.2(5) . . ?
C4 C5 C6 128.0(5) . . ?
C11 C6 C7 119.7(5) . . ?
C11 C6 C5 126.9(5) . . ?
C7 C6 C5 113.4(5) . . ?
C8 C7 C6 117.9(5) . . ?
C8 C7 Pt1 125.7(4) . . ?
C6 C7 Pt1 116.4(4) . . ?
C9 C8 C7 118.7(5) . . ?
C9 C8 H8 120.6 . . ?
C7 C8 H8 120.6 . . ?
F1 C9 C8 115.8(5) . . ?
F1 C9 C10 118.2(4) . . ?
C8 C9 C10 126.0(5) . . ?
C11 C10 C9 112.5(4) . . ?
C11 C10 Si 123.1(4) . . ?
C9 C10 Si 124.3(4) . . ?
F2 C11 C6 118.2(5) . . ?
F2 C11 C10 116.8(4) . . ?
C6 C11 C10 125.0(5) . . ?
C17 C12 C13 116.7(6) . . ?
C17 C12 Si 120.6(4) . . ?
C13 C12 Si 122.7(5) . . ?
C14 C13 C12 121.5(6) . . ?
C14 C13 H13 119.3 . . ?
C12 C13 H13 119.3 . . ?
C13 C14 C15 120.5(6) . . ?
C13 C14 H14 119.7 . . ?
C15 C14 H14 119.7 . . ?
C14 C15 C16 119.7(7) . . ?
C14 C15 H15 120.2 . . ?
C16 C15 H15 120.2 . . ?
C15 C16 C17 119.1(7) . . ?
C15 C16 H16 120.5 . . ?
C17 C16 H16 120.5 . . ?
C12 C17 C16 122.5(6) . . ?
C12 C17 H17 118.8 . . ?
C16 C17 H17 118.8 . . ?
C19 C18 C23 117.4(5) . . ?
C19 C18 Si 121.2(4) . . ?
C23 C18 Si 121.2(4) . . ?
C18 C19 C20 121.0(6) . . ?
C18 C19 H19 119.5 . . ?
C20 C19 H19 119.5 . . ?
C21 C20 C19 119.8(6) . . ?
C21 C20 H20 120.1 . . ?
C19 C20 H20 120.1 . . ?
C22 C21 C20 120.6(6) . . ?
C22 C21 H21 119.7 . . ?
C20 C21 H21 119.7 . . ?
C21 C22 C23 119.6(6) . . ?
C21 C22 H22 120.2 . . ?
C23 C22 H22 120.2 . . ?
C22 C23 C18 121.6(6) . . ?
C22 C23 H23 119.2 . . ?
C18 C23 H23 119.2 . . ?
C25 C24 C29 117.7(5) . . ?
C25 C24 Si 121.2(4) . . ?
C29 C24 Si 121.1(5) . . ?
C24 C25 C26 121.9(7) . . ?
C24 C25 H25 119.1 . . ?
C26 C25 H25 119.1 . . ?
C27 C26 C25 119.6(8) . . ?
C27 C26 H26 120.2 . . ?
C25 C26 H26 120.2 . . ?
C28 C27 C26 119.7(6) . . ?
C28 C27 H27 120.2 . . ?
C26 C27 H27 120.2 . . ?
C27 C28 C29 120.7(7) . . ?
C27 C28 H28 119.7 . . ?
C29 C28 H28 119.7 . . ?
C24 C29 C28 120.5(7) . . ?
C24 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
O1 C30 C31 126.1(6) . . ?
O1 C30 C33 115.0(8) . . ?
C31 C30 C33 118.9(7) . . ?
C32 C31 C30 127.4(6) . . ?
C32 C31 H31 116.3 . . ?
C30 C31 H31 116.3 . . ?
O2 C32 C31 125.8(7) . . ?
O2 C32 C34 114.1(7) . . ?
C31 C32 C34 120.1(7) . . ?
C30 C33 H33A 109.5 . . ?
C30 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C30 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C32 C34 H34A 109.5 . . ?
C32 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C32 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 1.3(10) . . . . ?
Pt1 N1 C1 C2 -177.8(5) . . . . ?
N1 C1 C2 C3 1.1(12) . . . . ?
C1 C2 C3 C4 -2.6(12) . . . . ?
C2 C3 C4 C5 1.7(12) . . . . ?
C1 N1 C5 C4 -2.1(9) . . . . ?
Pt1 N1 C5 C4 177.1(5) . . . . ?
C1 N1 C5 C6 177.7(5) . . . . ?
Pt1 N1 C5 C6 -3.2(6) . . . . ?
C3 C4 C5 N1 0.6(10) . . . . ?
C3 C4 C5 C6 -179.1(7) . . . . ?
N1 C5 C6 C11 -177.1(5) . . . . ?
C4 C5 C6 C11 2.6(10) . . . . ?
N1 C5 C6 C7 2.3(7) . . . . ?
C4 C5 C6 C7 -178.0(6) . . . . ?
C11 C6 C7 C8 -2.6(8) . . . . ?
C5 C6 C7 C8 177.9(5) . . . . ?
C11 C6 C7 Pt1 179.0(4) . . . . ?
C5 C6 C7 Pt1 -0.5(6) . . . . ?
C6 C7 C8 C9 2.2(8) . . . . ?
Pt1 C7 C8 C9 -179.7(4) . . . . ?
C7 C8 C9 F1 -179.4(5) . . . . ?
C7 C8 C9 C10 1.6(9) . . . . ?
F1 C9 C10 C11 176.6(5) . . . . ?
C8 C9 C10 C11 -4.5(8) . . . . ?
F1 C9 C10 Si -7.1(7) . . . . ?
C8 C9 C10 Si 171.9(4) . . . . ?
C7 C6 C11 F2 180.0(5) . . . . ?
C5 C6 C11 F2 -0.6(8) . . . . ?
C7 C6 C11 C10 -0.6(8) . . . . ?
C5 C6 C11 C10 178.8(5) . . . . ?
C9 C10 C11 F2 -176.6(4) . . . . ?
Si C10 C11 F2 6.9(7) . . . . ?
C9 C10 C11 C6 3.9(8) . . . . ?
Si C10 C11 C6 -172.5(4) . . . . ?
C18 Si C12 C17 9.0(5) . . . . ?
C24 Si C12 C17 128.9(5) . . . . ?
C10 Si C12 C17 -108.3(5) . . . . ?
C18 Si C12 C13 -170.1(4) . . . . ?
C24 Si C12 C13 -50.2(5) . . . . ?
C10 Si C12 C13 72.6(5) . . . . ?
C17 C12 C13 C14 1.3(9) . . . . ?
Si C12 C13 C14 -179.6(5) . . . . ?
C12 C13 C14 C15 -0.8(11) . . . . ?
C13 C14 C15 C16 -0.5(12) . . . . ?
C14 C15 C16 C17 1.4(13) . . . . ?
C13 C12 C17 C16 -0.4(10) . . . . ?
Si C12 C17 C16 -179.6(6) . . . . ?
C15 C16 C17 C12 -0.9(13) . . . . ?
C24 Si C18 C19 -26.2(6) . . . . ?
C12 Si C18 C19 93.2(6) . . . . ?
C10 Si C18 C19 -146.4(5) . . . . ?
C24 Si C18 C23 159.2(5) . . . . ?
C12 Si C18 C23 -81.3(5) . . . . ?
C10 Si C18 C23 39.0(6) . . . . ?
C23 C18 C19 C20 -1.0(11) . . . . ?
Si C18 C19 C20 -175.8(6) . . . . ?
C18 C19 C20 C21 1.2(13) . . . . ?
C19 C20 C21 C22 -0.7(13) . . . . ?
C20 C21 C22 C23 0.1(13) . . . . ?
C21 C22 C23 C18 0.0(12) . . . . ?
C19 C18 C23 C22 0.4(10) . . . . ?
Si C18 C23 C22 175.2(6) . . . . ?
C18 Si C24 C25 -73.1(6) . . . . ?
C12 Si C24 C25 169.1(5) . . . . ?
C10 Si C24 C25 45.3(6) . . . . ?
C18 Si C24 C29 105.7(5) . . . . ?
C12 Si C24 C29 -12.1(5) . . . . ?
C10 Si C24 C29 -135.9(5) . . . . ?
C29 C24 C25 C26 -0.8(11) . . . . ?
Si C24 C25 C26 178.1(6) . . . . ?
C24 C25 C26 C27 -0.6(13) . . . . ?
C25 C26 C27 C28 1.7(14) . . . . ?
C26 C27 C28 C29 -1.4(14) . . . . ?
C25 C24 C29 C28 1.1(10) . . . . ?
Si C24 C29 C28 -177.8(5) . . . . ?
C27 C28 C29 C24 0.0(12) . . . . ?
Pt1 O1 C30 C31 1.4(10) . . . . ?
Pt1 O1 C30 C33 -178.1(6) . . . . ?
O1 C30 C31 C32 -0.7(14) . . . . ?
C33 C30 C31 C32 178.8(8) . . . . ?
Pt1 O2 C32 C31 1.2(11) . . . . ?
Pt1 O2 C32 C34 -178.0(6) . . . . ?
C30 C31 C32 O2 -0.8(14) . . . . ?
C30 C31 C32 C34 178.4(9) . . . . ?

_refine_diff_density_max         0.928
_refine_diff_density_min         -0.840
_refine_diff_density_rms         0.175

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1523133'
_audit_update_record             
;
2016-12-16 deposited with the CCDC.
2017-01-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        k161102
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C16 H13 F2 N O2 Pt'
_chemical_formula_sum            'C16 H13 F2 N O2 Pt'
_chemical_formula_weight         484.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   10.3177(9)
_cell_length_b                   7.6760(7)
_cell_length_c                   19.0308(16)
_cell_angle_alpha                90
_cell_angle_beta                 92.4020(10)
_cell_angle_gamma                90
_cell_volume                     1505.9(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5127
_cell_measurement_theta_min      2.287
_cell_measurement_theta_max      28.228

_exptl_crystal_description       plate
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    2.136
_exptl_crystal_F_000             912
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.10
_exptl_absorpt_coefficient_mu    9.345
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.145
_exptl_absorpt_correction_T_max  0.393
_exptl_absorpt_process_details   'SADABS (Sheldric, 1996)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD diffractometer'
_diffrn_measurement_method       ω-scans
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            19300
_diffrn_reflns_av_unetI/netI     0.0336
_diffrn_reflns_av_R_equivalents  0.0483
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         2.142
_diffrn_reflns_theta_max         28.303
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             3740
_reflns_number_gt                3157
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 1999)'
_computing_cell_refinement       'SMART (Bruker, 1999)'
_computing_data_reduction        'SAINT-Plus (Bruker, 1999)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0483P)²+0.6582P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         3740
_refine_ls_number_parameters     201
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0286
_refine_ls_wR_factor_ref         0.0793
_refine_ls_wR_factor_gt          0.0746
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.09997(2) 0.12954(2) 0.09396(2) 0.03468(8) Uani 1 1 d . . . . .
F1 F -0.3536(4) 0.2720(7) 0.20625(19) 0.1016(14) Uani 1 1 d . . . . .
F2 F -0.3068(3) 0.4211(5) -0.02892(17) 0.0665(8) Uani 1 1 d . . . . .
O1 O 0.1008(3) 0.0502(4) 0.19406(15) 0.0425(6) Uani 1 1 d . . . . .
O2 O 0.2877(3) 0.0371(4) 0.08230(17) 0.0504(7) Uani 1 1 d . . . . .
N1 N 0.0780(3) 0.2155(4) -0.00420(17) 0.0369(7) Uani 1 1 d . . . . .
C1 C 0.1712(5) 0.2029(7) -0.0516(3) 0.0497(11) Uani 1 1 d . . . . .
H1 H 0.2510 0.1546 -0.0378 0.060 Uiso 1 1 calc R U . . .
C2 C 0.1512(5) 0.2600(7) -0.1202(3) 0.0551(12) Uani 1 1 d . . . . .
H2 H 0.2161 0.2487 -0.1524 0.066 Uiso 1 1 calc R U . . .
C3 C 0.0351(6) 0.3330(7) -0.1399(3) 0.0532(12) Uani 1 1 d . . . . .
H3 H 0.0204 0.3734 -0.1856 0.064 Uiso 1 1 calc R U . . .
C4 C -0.0608(6) 0.3467(6) -0.0918(2) 0.0450(10) Uani 1 1 d . . . . .
H4 H -0.1404 0.3964 -0.1049 0.054 Uiso 1 1 calc R U . . .
C5 C -0.0383(4) 0.2865(5) -0.0240(2) 0.0356(8) Uani 1 1 d . . . . .
C6 C -0.1281(4) 0.2881(5) 0.0340(2) 0.0366(8) Uani 1 1 d . . . . .
C7 C -0.0777(4) 0.2174(5) 0.0978(2) 0.0362(8) Uani 1 1 d . . . . .
C8 C -0.1549(5) 0.2136(7) 0.1557(2) 0.0492(10) Uani 1 1 d . . . . .
H8 H -0.1234 0.1684 0.1984 0.059 Uiso 1 1 calc R U . . .
C9 C -0.2783(5) 0.2776(8) 0.1486(3) 0.0597(13) Uani 1 1 d . . . . .
C10 C -0.3323(5) 0.3465(8) 0.0882(3) 0.0622(14) Uani 1 1 d . . . . .
H10 H -0.4172 0.3875 0.0854 0.075 Uiso 1 1 calc R U . . .
C11 C -0.2538(5) 0.3517(6) 0.0318(3) 0.0480(11) Uani 1 1 d . . . . .
C12 C 0.1948(4) -0.0315(5) 0.2259(2) 0.0426(9) Uani 1 1 d . . . . .
C13 C 0.3125(5) -0.0766(7) 0.1977(3) 0.0521(12) Uani 1 1 d . . . . .
H13 H 0.3706 -0.1371 0.2274 0.063 Uiso 1 1 calc R U . . .
C14 C 0.3535(4) -0.0417(6) 0.1305(3) 0.0511(11) Uani 1 1 d . . . . .
C15 C 0.1650(5) -0.0819(7) 0.3000(3) 0.0544(12) Uani 1 1 d . . . . .
H15A H 0.2427 -0.1226 0.3242 0.082 Uiso 1 1 calc R U . . .
H15B H 0.1010 -0.1729 0.2989 0.082 Uiso 1 1 calc R U . . .
H15C H 0.1321 0.0176 0.3241 0.082 Uiso 1 1 calc R U . . .
C16 C 0.4865(6) -0.1020(8) 0.1110(5) 0.0755(19) Uani 1 1 d . . . . .
H16A H 0.5299 -0.1549 0.1512 0.113 Uiso 1 1 calc R U . . .
H16B H 0.5360 -0.0039 0.0959 0.113 Uiso 1 1 calc R U . . .
H16C H 0.4782 -0.1854 0.0735 0.113 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 1.958(4) . ?
Pt1 N1 1.985(3) . ?
Pt1 O1 2.000(3) . ?
Pt1 O2 2.083(3) . ?
F1 C9 1.371(5) . ?
F2 C11 1.365(6) . ?
O1 C12 1.285(5) . ?
O2 C14 1.270(6) . ?
N1 C1 1.350(6) . ?
N1 C5 1.357(5) . ?
C1 C2 1.385(7) . ?
C1 H1 0.9300 . ?
C2 C3 1.361(8) . ?
C2 H2 0.9300 . ?
C3 C4 1.380(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.380(6) . ?
C4 H4 0.9300 . ?
C5 C6 1.470(6) . ?
C6 C11 1.385(6) . ?
C6 C7 1.409(6) . ?
C7 C8 1.387(6) . ?
C8 C9 1.365(7) . ?
C8 H8 0.9300 . ?
C9 C10 1.364(8) . ?
C10 C11 1.373(8) . ?
C10 H10 0.9300 . ?
C12 C13 1.391(7) . ?
C12 C15 1.507(7) . ?
C13 C14 1.391(7) . ?
C13 H13 0.9300 . ?
C14 C16 1.509(7) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Pt1 N1 81.38(16) . . ?
C7 Pt1 O1 92.06(14) . . ?
N1 Pt1 O1 173.42(13) . . ?
C7 Pt1 O2 176.02(14) . . ?
N1 Pt1 O2 94.77(14) . . ?
O1 Pt1 O2 91.77(13) . . ?
C12 O1 Pt1 124.8(3) . . ?
C14 O2 Pt1 123.8(3) . . ?
C1 N1 C5 119.3(4) . . ?
C1 N1 Pt1 123.3(3) . . ?
C5 N1 Pt1 117.4(3) . . ?
N1 C1 C2 121.7(5) . . ?
N1 C1 H1 119.2 . . ?
C2 C1 H1 119.2 . . ?
C3 C2 C1 119.0(5) . . ?
C3 C2 H2 120.5 . . ?
C1 C2 H2 120.5 . . ?
C2 C3 C4 119.7(5) . . ?
C2 C3 H3 120.2 . . ?
C4 C3 H3 120.2 . . ?
C5 C4 C3 119.9(5) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
N1 C5 C4 120.4(4) . . ?
N1 C5 C6 111.9(3) . . ?
C4 C5 C6 127.7(4) . . ?
C11 C6 C7 118.2(4) . . ?
C11 C6 C5 126.8(4) . . ?
C7 C6 C5 115.0(4) . . ?
C8 C7 C6 119.3(4) . . ?
C8 C7 Pt1 126.3(3) . . ?
C6 C7 Pt1 114.4(3) . . ?
C9 C8 C7 118.6(4) . . ?
C9 C8 H8 120.7 . . ?
C7 C8 H8 120.7 . . ?
C10 C9 C8 124.7(4) . . ?
C10 C9 F1 117.5(5) . . ?
C8 C9 F1 117.9(4) . . ?
C9 C10 C11 116.0(5) . . ?
C9 C10 H10 122.0 . . ?
C11 C10 H10 122.0 . . ?
F2 C11 C10 116.4(5) . . ?
F2 C11 C6 120.3(4) . . ?
C10 C11 C6 123.3(5) . . ?
O1 C12 C13 126.4(4) . . ?
O1 C12 C15 112.7(4) . . ?
C13 C12 C15 120.8(4) . . ?
C14 C13 C12 127.6(5) . . ?
C14 C13 H13 116.2 . . ?
C12 C13 H13 116.2 . . ?
O2 C14 C13 125.6(4) . . ?
O2 C14 C16 115.6(5) . . ?
C13 C14 C16 118.7(5) . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 -0.2(7) . . . . ?
Pt1 N1 C1 C2 178.2(4) . . . . ?
N1 C1 C2 C3 1.0(8) . . . . ?
C1 C2 C3 C4 -0.8(8) . . . . ?
C2 C3 C4 C5 0.0(7) . . . . ?
C1 N1 C5 C4 -0.6(6) . . . . ?
Pt1 N1 C5 C4 -179.1(3) . . . . ?
C1 N1 C5 C6 179.5(4) . . . . ?
Pt1 N1 C5 C6 0.9(4) . . . . ?
C3 C4 C5 N1 0.7(6) . . . . ?
C3 C4 C5 C6 -179.4(4) . . . . ?
N1 C5 C6 C11 179.7(4) . . . . ?
C4 C5 C6 C11 -0.2(7) . . . . ?
N1 C5 C6 C7 0.0(5) . . . . ?
C4 C5 C6 C7 -179.9(4) . . . . ?
C11 C6 C7 C8 0.1(6) . . . . ?
C5 C6 C7 C8 179.8(4) . . . . ?
C11 C6 C7 Pt1 179.3(3) . . . . ?
C5 C6 C7 Pt1 -0.9(4) . . . . ?
C6 C7 C8 C9 0.5(7) . . . . ?
Pt1 C7 C8 C9 -178.6(4) . . . . ?
C7 C8 C9 C10 -0.2(9) . . . . ?
C7 C8 C9 F1 179.6(5) . . . . ?
C8 C9 C10 C11 -0.8(9) . . . . ?
F1 C9 C10 C11 179.4(5) . . . . ?
C9 C10 C11 F2 -179.7(5) . . . . ?
C9 C10 C11 C6 1.5(8) . . . . ?
C7 C6 C11 F2 -179.9(4) . . . . ?
C5 C6 C11 F2 0.4(7) . . . . ?
C7 C6 C11 C10 -1.1(7) . . . . ?
C5 C6 C11 C10 179.2(5) . . . . ?
Pt1 O1 C12 C13 1.3(6) . . . . ?
Pt1 O1 C12 C15 -177.3(3) . . . . ?
O1 C12 C13 C14 0.8(8) . . . . ?
C15 C12 C13 C14 179.2(5) . . . . ?
Pt1 O2 C14 C13 -0.8(7) . . . . ?
Pt1 O2 C14 C16 178.7(3) . . . . ?
C12 C13 C14 O2 -1.0(8) . . . . ?
C12 C13 C14 C16 179.6(5) . . . . ?

_refine_diff_density_max         2.381
_refine_diff_density_min         -1.312
_refine_diff_density_rms         0.168

