# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
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data_mf997
_audit_block_doi                 10.5517/cc1khdbs
_database_code_depnum_ccdc_archive 'CCDC 1444765'
_audit_update_record             
;
2015-12-29 deposited with the CCDC.
2016-02-16 downloaded from the CCDC.
;
_audit_creation_date             2014-10-06
_audit_creation_method           
;
Olex2 1.2
(compiled 2014.09.19 svn.r3010 for OlexSys, GUI svn.r4874)
;
_shelxl_version_number           2012-9
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C20 H38 N2 O P Ru'
_chemical_formula_sum            'C20 H38 N2 O P Ru'
_chemical_formula_weight         454.56
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_H-M_alt        'P 1 21/m 1'
_space_group_name_Hall           '-P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'

_cell_length_a                   9.6117(8)
_cell_length_b                   11.6787(10)
_cell_length_c                   10.5243(10)
_cell_angle_alpha                90
_cell_angle_beta                 111.025(2)
_cell_angle_gamma                90
_cell_volume                     1102.72(17)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    8834
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.066
_cell_measurement_theta_min      2.711
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.794
_exptl_absorpt_correction_T_max  0.7460
_exptl_absorpt_correction_T_min  0.6650
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0569 before and 0.0406 after correction.
The Ratio of minimum to maximum transmission is 0.8914.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            'clear red'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.369
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rectangular
_exptl_crystal_F_000             478
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_av_unetI/netI     0.0258
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            11859
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         27.924
_diffrn_reflns_theta_min         2.073
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_special_details          ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2486
_reflns_number_total             2769
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    ?
_refine_diff_density_max         0.400
_refine_diff_density_min         -0.424
_refine_diff_density_rms         0.067
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     185
_refine_ls_number_reflns         2769
_refine_ls_number_restraints     212
_refine_ls_R_factor_all          0.0298
_refine_ls_R_factor_gt           0.0244
_refine_ls_restrained_S_all      1.027
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0257P)²+0.7398P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0560
_refine_ls_wR_factor_ref         0.0586
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C12-C13
 1.54 with sigma of 0.01
 C14-C15
 1.54 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(C13) = Uanis(C15)
Uanis(C11B) = Uanis(C11)
Uanis(C9B) = Uanis(C11B)
Uanis(C10B) = Uanis(C9B)
4. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Sof(C9)=Sof(H9A)=Sof(H9B)=Sof(H9C)=Sof(C10)=Sof(H10D)=Sof(H10E)=Sof(H10F)=
 Sof(C11)=Sof(H11D)=Sof(H11E)=Sof(H11F)=1-FVAR(1)
 Sof(C9B)=Sof(H9BA)=Sof(H9BB)=Sof(H9BC)=Sof(C10B)=Sof(H10A)=Sof(H10B)=
 Sof(H10C)=Sof(C11B)=Sof(H11A)=Sof(H11B)=Sof(H11C)=FVAR(1)
 Fixed Sof: C5(0.5) H5A(0.5) H5B(0.5) C4(0.5) H4A(0.5) H4B(0.5) N1(0.5)
 C6(0.5) H6A(0.5) H6B(0.5) C7(0.5) H7A(0.5) H7B(0.5) C12(0.5) H12A(0.5)
 H12B(0.5) C13(0.5) H13A(0.5) H13B(0.5) H13C(0.5) C14(0.5) H14(0.5) C15(0.5)
 H15A(0.5) H15B(0.5) H15C(0.5) C3(0.5) H3A(0.5) H3B(0.5) H50(0.5)
6.a Secondary CH2 refined with riding coordinates:
 C5(H5A,H5B), C4(H4A,H4B), C6(H6A,H6B), C7(H7A,H7B), C12(H12A,H12B), C3(H3A,H3B)
6.b Aromatic/amide H refined with riding coordinates:
 C14(H14)
6.c Idealised Me refined as rotating group:
 C9B(H9BA,H9BB,H9BC), C10B(H10A,H10B,H10C), C11B(H11A,H11B,H11C), C9(H9A,H9B,
 H9C), C10(H10D,H10E,H10F), C11(H11D,H11E,H11F), C13(H13A,H13B,H13C), C15(H15A,
 H15B,H15C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru01 Ru 0.20668(2) 0.2500 0.51566(2) 0.01661(7) Uani 1 2 d S T P . .
P1 P 0.40306(6) 0.2500 0.71919(6) 0.01403(13) Uani 1 2 d S T P A .
O1 O 0.3979(2) 0.2500 0.3435(2) 0.0405(6) Uani 1 2 d S T P . .
N2 N -0.0252(2) 0.2500 0.3621(2) 0.0266(5) Uani 1 2 d S T P A .
C1 C 0.1558(3) 0.2500 0.7763(3) 0.0205(5) Uani 1 2 d S T P . .
C2 C 0.3065(3) 0.2500 0.8369(3) 0.0227(5) Uani 1 2 d S T P A .
C5 C 0.0809(4) 0.2625(15) 0.8799(3) 0.021(2) Uani 0.5 1 d . . . A -1
H5A H 0.0208 0.3315 0.8632 0.025 Uiso 0.5 1 calc R . . A -1
H5B H 0.0178 0.1971 0.8771 0.025 Uiso 0.5 1 calc R . . A -1
C8 C 0.5211(2) 0.38309(16) 0.75578(19) 0.0218(4) Uani 1 1 d . . . . .
C16 C 0.3220(3) 0.2500 0.4085(3) 0.0249(6) Uani 1 2 d S T P . .
C4 C 0.2063(5) 0.2691(14) 1.0130(4) 0.050(4) Uani 0.5 1 d . . . A -1
H4A H 0.1879 0.2184 1.0783 0.060 Uiso 0.5 1 calc R . . A -1
H4B H 0.2162 0.3466 1.0482 0.060 Uiso 0.5 1 calc R . . A -1
C9B C 0.4277(6) 0.4834(4) 0.7638(5) 0.0329(6) Uani 0.530(5) 1 d . . . B 1
H9BA H 0.3389 0.4855 0.6839 0.049 Uiso 0.530(5) 1 calc GR . . B 1
H9BB H 0.4832 0.5528 0.7695 0.049 Uiso 0.530(5) 1 calc GR . . B 1
H9BC H 0.4012 0.4763 0.8431 0.049 Uiso 0.530(5) 1 calc GR . . B 1
C10B C 0.5829(6) 0.4049(5) 0.6408(6) 0.0329(6) Uani 0.530(5) 1 d . . . B 1
H10A H 0.6446 0.3418 0.6359 0.049 Uiso 0.530(5) 1 calc GR . . B 1
H10B H 0.6408 0.4741 0.6597 0.049 Uiso 0.530(5) 1 calc GR . . B 1
H10C H 0.5015 0.4126 0.5555 0.049 Uiso 0.530(5) 1 calc GR . . B 1
C11B C 0.6600(5) 0.3777(4) 0.8933(5) 0.0329(6) Uani 0.530(5) 1 d . . . B 1
H11A H 0.6277 0.3557 0.9662 0.049 Uiso 0.530(5) 1 calc GR . . B 1
H11B H 0.7066 0.4516 0.9125 0.049 Uiso 0.530(5) 1 calc GR . . B 1
H11C H 0.7302 0.3225 0.8849 0.049 Uiso 0.530(5) 1 calc GR . . B 1
C9 C 0.3982(6) 0.4783(4) 0.6980(7) 0.0351(13) Uani 0.470(5) 1 d . . . B 2
H9A H 0.3480 0.4670 0.6019 0.053 Uiso 0.470(5) 1 calc GR . . B 2
H9B H 0.4444 0.5525 0.7138 0.053 Uiso 0.470(5) 1 calc GR . . B 2
H9C H 0.3274 0.4735 0.7429 0.053 Uiso 0.470(5) 1 calc GR . . B 2
C10 C 0.6242(5) 0.3878(5) 0.6778(5) 0.0251(11) Uani 0.470(5) 1 d . . . B 2
H10D H 0.7055 0.3357 0.7175 0.038 Uiso 0.470(5) 1 calc GR . . B 2
H10E H 0.6623 0.4642 0.6810 0.038 Uiso 0.470(5) 1 calc GR . . B 2
H10F H 0.5709 0.3665 0.5848 0.038 Uiso 0.470(5) 1 calc GR . . B 2
C11 C 0.6026(6) 0.4064(5) 0.9067(5) 0.0329(6) Uani 0.470(5) 1 d . . . B 2
H11D H 0.5316 0.4125 0.9513 0.049 Uiso 0.470(5) 1 calc GR . . B 2
H11E H 0.6574 0.4767 0.9177 0.049 Uiso 0.470(5) 1 calc GR . . B 2
H11F H 0.6703 0.3446 0.9463 0.049 Uiso 0.470(5) 1 calc GR . . B 2
N1 N 0.0857(3) 0.2326(7) 0.6393(3) 0.0187(17) Uani 0.5 1 d . . . A -1
C6 C -0.0757(3) 0.2301(6) 0.5785(4) 0.0283(19) Uani 0.5 1 d . . . A -1
H6A H -0.1162 0.3066 0.5746 0.034 Uiso 0.5 1 calc R . . A -1
H6B H -0.1168 0.1818 0.6313 0.034 Uiso 0.5 1 calc R . . A -1
C7 C -0.1129(4) 0.1820(4) 0.4361(4) 0.0279(8) Uani 0.5 1 d . . . A -1
H7A H -0.2191 0.1885 0.3857 0.033 Uiso 0.5 1 calc R . . A -1
H7B H -0.0860 0.1017 0.4412 0.033 Uiso 0.5 1 calc R . . A -1
C12 C -0.0493(5) 0.1775(4) 0.2325(4) 0.0369(10) Uani 0.5 1 d D . . A -1
H12A H 0.0025 0.2140 0.1794 0.044 Uiso 0.5 1 calc R . . A -1
H12B H -0.1547 0.1769 0.1777 0.044 Uiso 0.5 1 calc R . . A -1
C13 C 0.0062(10) 0.0511(7) 0.2621(9) 0.0403(8) Uani 0.5 1 d D . . A -1
H13A H 0.0097 0.0170 0.1804 0.060 Uiso 0.5 1 calc GR . . A -1
H13B H -0.0610 0.0086 0.2931 0.060 Uiso 0.5 1 calc GR . . A -1
H13C H 0.1040 0.0502 0.3311 0.060 Uiso 0.5 1 calc GR . . A -1
C14 C -0.0834(5) 0.3585(4) 0.3282(5) 0.0361(10) Uani 0.5 1 d D . . A -1
H14 H -0.1563 0.3892 0.3571 0.043 Uiso 0.5 1 calc R . . A -1
C15 C -0.0140(10) 0.4249(7) 0.2357(9) 0.0403(8) Uani 0.5 1 d D . . A -1
H15A H -0.0433 0.3885 0.1482 0.060 Uiso 0.5 1 calc GR . . A -1
H15B H 0.0927 0.4241 0.2775 0.060 Uiso 0.5 1 calc GR . . A -1
H15C H -0.0488 0.5026 0.2248 0.060 Uiso 0.5 1 calc GR . . A -1
C3 C 0.3526(4) 0.2324(10) 0.9901(3) 0.032(2) Uani 0.5 1 d . . . A -1
H3A H 0.4361 0.2810 1.0404 0.038 Uiso 0.5 1 calc R . . A -1
H3B H 0.3779 0.1531 1.0154 0.038 Uiso 0.5 1 calc R . . A -1
H50 H 0.225(6) 0.122(6) 0.498(6) 0.070(19) Uiso 0.5 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru01 P1 2.2912(6) . ?
Ru01 N2 2.235(2) . ?
Ru01 C16 1.844(3) . ?
Ru01 N1 2.042(3) . ?
P1 C2 1.795(3) . ?
P1 C8 1.8810(18) . ?
P1 C8 1.8809(18) 4_565 ?
O1 C16 1.165(3) . ?
N2 C7 1.555(4) . ?
N2 C12 1.550(4) . ?
N2 C14 1.380(4) . ?
C1 C2 1.357(4) . ?
C1 C5 1.513(4) . ?
C1 N1 1.371(4) . ?
C2 C3 1.525(4) . ?
C5 C4 1.486(5) . ?
C8 C9B 1.497(6) . ?
C8 C10B 1.548(7) . ?
C8 C11B 1.580(5) . ?
C8 C9 1.577(5) . ?
C8 C10 1.497(5) . ?
C8 C11 1.523(5) . ?
C4 C3 1.569(8) . ?
N1 C6 1.450(4) . ?
C6 C7 1.518(6) . ?
C12 C13 1.562(6) . ?
C14 C15 1.568(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ru01 P1 161.70(7) . . ?
C16 Ru01 P1 95.59(8) . . ?
C16 Ru01 N2 102.71(10) . . ?
C16 Ru01 N1 174.0(2) . . ?
N1 Ru01 P1 82.58(8) . . ?
N1 Ru01 N2 79.21(10) . . ?
C2 P1 Ru01 100.87(9) . . ?
C2 P1 C8 106.38(8) . 4_565 ?
C2 P1 C8 106.38(8) . . ?
C8 P1 Ru01 115.18(6) 4_565 . ?
C8 P1 Ru01 115.18(6) . . ?
C8 P1 C8 111.44(12) 4_565 . ?
C7 N2 Ru01 102.52(17) . . ?
C12 N2 Ru01 115.57(19) . . ?
C12 N2 C7 103.0(2) . . ?
C14 N2 Ru01 113.18(19) . . ?
C14 N2 C7 110.9(3) . . ?
C14 N2 C12 110.8(3) . . ?
C2 C1 C5 111.4(2) . . ?
C2 C1 N1 122.2(2) . . ?
N1 C1 C5 126.2(3) . . ?
C1 C2 P1 113.89(19) . . ?
C1 C2 C3 110.7(2) . . ?
C3 C2 P1 134.7(2) . . ?
C4 C5 C1 104.4(3) . . ?
C9B C8 P1 109.2(2) . . ?
C9B C8 C10B 108.7(3) . . ?
C9B C8 C11B 107.8(3) . . ?
C10B C8 P1 110.4(2) . . ?
C10B C8 C11B 106.7(3) . . ?
C11B C8 P1 113.83(19) . . ?
C9 C8 P1 101.0(2) . . ?
C10 C8 P1 112.8(2) . . ?
C10 C8 C9 108.3(3) . . ?
C10 C8 C11 111.8(3) . . ?
C11 C8 P1 114.1(2) . . ?
C11 C8 C9 108.1(3) . . ?
O1 C16 Ru01 178.4(2) . . ?
C5 C4 C3 108.0(5) . . ?
C1 N1 Ru01 118.6(2) . . ?
C1 N1 C6 120.7(3) . . ?
C6 N1 Ru01 119.0(2) . . ?
N1 C6 C7 106.2(3) . . ?
C6 C7 N2 109.1(3) . . ?
N2 C12 C13 114.1(5) . . ?
N2 C14 C15 113.0(5) . . ?
C2 C3 C4 100.9(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ru01 P1 C2 C1 0.000(1) . . . . ?
Ru01 P1 C2 C3 169.1(6) . . . . ?
Ru01 P1 C8 C9B 62.4(3) . . . . ?
Ru01 P1 C8 C10B -57.1(3) . . . . ?
Ru01 P1 C8 C11B -177.1(2) . . . . ?
Ru01 P1 C8 C9 38.7(3) . . . . ?
Ru01 P1 C8 C10 -76.7(2) . . . . ?
Ru01 P1 C8 C11 154.3(3) . . . . ?
Ru01 N2 C7 C6 49.0(3) . . . . ?
Ru01 N2 C12 C13 52.6(5) . . . . ?
Ru01 N2 C14 C15 73.4(4) . . . . ?
Ru01 N1 C6 C7 28.2(8) . . . . ?
P1 C2 C3 C4 169.9(6) . . . . ?
C1 C2 C3 C4 -20.8(9) . . . . ?
C1 C5 C4 C3 -12.8(15) . . . . ?
C1 N1 C6 C7 -166.9(6) . . . . ?
C2 P1 C8 C9B -48.5(3) . . . . ?
C2 P1 C8 C10B -167.9(3) . . . . ?
C2 P1 C8 C11B 72.1(3) . . . . ?
C2 P1 C8 C9 -72.1(3) . . . . ?
C2 P1 C8 C10 172.5(2) . . . . ?
C2 P1 C8 C11 43.5(3) . . . . ?
C2 C1 C5 C4 -0.5(13) . . . . ?
C2 C1 N1 Ru01 -16.7(6) . . . . ?
C2 C1 N1 C6 178.3(5) . . . . ?
C5 C1 C2 P1 -174.0(7) . . . . ?
C5 C1 C2 C3 14.2(9) . . . . ?
C5 C1 N1 Ru01 168.0(8) . . . . ?
C5 C1 N1 C6 3.1(12) . . . . ?
C5 C4 C3 C2 19.9(13) . . . . ?
C8 P1 C2 C1 -120.54(6) 4_565 . . . ?
C8 P1 C2 C1 120.54(6) . . . . ?
C8 P1 C2 C3 48.5(6) 4_565 . . . ?
C8 P1 C2 C3 -70.4(6) . . . . ?
C8 P1 C8 C9B -164.0(2) 4_565 . . . ?
C8 P1 C8 C10B 76.5(3) 4_565 . . . ?
C8 P1 C8 C11B -43.5(3) 4_565 . . . ?
C8 P1 C8 C9 172.3(2) 4_565 . . . ?
C8 P1 C8 C10 56.9(3) 4_565 . . . ?
C8 P1 C8 C11 -72.0(3) 4_565 . . . ?
N1 C1 C2 P1 10.1(4) . . . . ?
N1 C1 C2 C3 -161.6(6) . . . . ?
N1 C1 C5 C4 175.1(9) . . . . ?
N1 C6 C7 N2 -51.4(6) . . . . ?
C7 N2 C12 C13 -58.4(5) . . . . ?
C7 N2 C14 C15 -172.0(4) . . . . ?
C12 N2 C7 C6 169.3(3) . . . . ?
C12 N2 C14 C15 -58.2(5) . . . . ?
C14 N2 C7 C6 -72.1(4) . . . . ?
C14 N2 C12 C13 -177.0(5) . . . . ?

_olex2_submission_original_sample_id {[NNP]PBut}RuH(CO)
_olex2_submission_special_instructions 'No special instructions were received'
