# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1417165'
_audit_update_record             
;
2015-08-06 deposited with the CCDC.
2016-03-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C54 H8 Ag16 N110 O27'
_chemical_formula_weight         4355.62

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Hexagonal
_symmetry_space_group_name_H-M   p63/m

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x-y, x, z+1/2'
'-y, x-y, z'
'-x, -y, z+1/2'
'-x+y, -x, z'
'y, -x+y, z+1/2'
'-x, -y, -z'
'-x+y, -x, -z-1/2'
'y, -x+y, -z'
'x, y, -z-1/2'
'x-y, x, -z'
'-y, x-y, -z-1/2'

_cell_length_a                   15.3657(4)
_cell_length_b                   15.3657(4)
_cell_length_c                   17.7122(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_volume                     3621.66(17)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3524
_cell_measurement_theta_min      1.96
_cell_measurement_theta_max      25.10

_exptl_crystal_description       block
_exptl_crystal_colour            pink
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.997
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2070
_exptl_absorpt_coefficient_mu    2.204
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7973
_exptl_absorpt_correction_T_max  0.9019
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX SMART II'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            11190
_diffrn_reflns_av_R_equivalents  0.0325
_diffrn_reflns_av_sigmaI/netI    0.0253
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         3.27
_diffrn_reflns_theta_max         24.99
_reflns_number_total             2199
_reflns_number_gt                1879
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0751P)²+28.6916P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         2199
_refine_ls_number_parameters     222
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0605
_refine_ls_R_factor_gt           0.0524
_refine_ls_wR_factor_ref         0.1447
_refine_ls_wR_factor_gt          0.1395
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.62724(4) 0.55254(5) 0.05940(4) 0.0397(3) Uani 1 1 d . . .
Ag2 Ag 0.6667 0.3333 0.12984(5) 0.0314(3) Uani 1 3 d S . .
N1 N 0.4245(5) 0.3426(5) -0.0149(5) 0.0507(18) Uani 1 1 d . . .
N2 N 0.5100(5) 0.3829(5) 0.0249(4) 0.0450(17) Uani 1 1 d . . .
N3 N 0.5248(5) 0.3108(5) 0.0492(4) 0.0438(17) Uani 1 1 d . . .
N4 N 0.4496(5) 0.2225(5) 0.0261(4) 0.0433(16) Uani 1 1 d . . .
N5 N 0.2385(10) 0.0743(10) -0.0202(10) 0.072(4) Uani 0.50 1 d P A 1
N6 N 0.165(2) 0.090(2) -0.1260(14) 0.079(7) Uani 0.50 1 d P A 1
N7 N 0.6292(7) 0.5209(7) 0.1886(5) 0.062(2) Uani 1 1 d . . .
N8 N 0.6413(6) 0.4464(6) 0.2134(4) 0.059(2) Uani 1 1 d . . .
N9 N 0.548(2) 0.653(2) 0.3012(15) 0.108(8) Uani 0.50 1 d P . .
N10 N 0.6258(18) 0.8010(16) 0.2500 0.118(6) Uani 1 2 d S . .
N11 N 0.292(3) 0.082(2) -0.073(2) 0.061(9) Uani 0.25 1 d P . 2
N12 N 0.141(6) 0.078(6) -0.095(4) 0.060(15) Uani 0.25 1 d P . 2
N13 N 0.2520(11) 0.1783(11) -0.1126(10) 0.071(4) Uani 0.25 1 d P A 1
N14 N 0.1568(12) 0.0262(12) -0.0672(9) 0.083(4) Uani 0.25 1 d P A 1
N15 N 1.0000 0.0000 0.7500 0.24(3) Uani 1 6 d S . .
H15A H 1.0115 0.0549 0.7237 0.292 Uiso 0.17 1 d PR . .
H15B H 0.9434 -0.0177 0.7763 0.292 Uiso 0.17 1 d PR . .
H15C H 1.0516 0.0142 0.7813 0.292 Uiso 0.17 1 d PR . .
H15D H 0.9915 -0.0498 0.7187 0.292 Uiso 0.17 1 d PR . .
O1 O 0.2707(10) 0.2471(10) -0.1623(10) 0.065(4) Uani 0.50 1 d P . 1
O2 O 0.1568(12) 0.0262(12) -0.0672(9) 0.083(4) Uani 0.50 1 d P A 1
O3 O 0.547(2) 0.7431(18) 0.2984(14) 0.127(8) Uani 0.50 1 d P . .
O4 O 0.1857(19) 0.2393(19) -0.0450(19) 0.057(7) Uani 0.25 1 d P . 2
O5 O 0.196(3) 0.029(3) -0.104(2) 0.058(9) Uani 0.25 1 d P . 2
O6 O 0.165(2) 0.090(2) -0.1260(14) 0.079(7) Uani 0.25 1 d P A 1
C1 C 0.3895(6) 0.2445(7) -0.0127(6) 0.051(2) Uani 1 1 d . A .
C2 C 0.2976(7) 0.1701(7) -0.0474(6) 0.059(3) Uani 1 1 d . . .
C3 C 0.2520(11) 0.1783(11) -0.1126(10) 0.071(4) Uani 0.50 1 d P A 1
C4 C 0.6226(15) 0.5653(14) 0.2500 0.082(5) Uani 1 2 d S . .
C5 C 0.6210(18) 0.6607(17) 0.2500 0.095(6) Uani 1 2 d S . .
C6 C 0.671(3) 0.752(2) 0.2141(16) 0.093(8) Uani 0.50 1 d P . .
C7 C 0.208(3) 0.169(3) -0.061(3) 0.059(10) Uani 0.25 1 d P . 2
C8 C 0.2385(10) 0.0743(10) -0.0202(10) 0.072(4) Uani 0.25 1 d P A 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.265(7) 7_665 ?
Ag1 N4 2.331(6) 5_665 ?
Ag1 N7 2.342(8) . ?
Ag1 N2 2.391(7) . ?
Ag2 N8 2.457(8) 5_665 ?
Ag2 N8 2.457(8) 3_655 ?
Ag2 N8 2.457(8) . ?
Ag2 N3 2.481(6) 3_655 ?
Ag2 N3 2.481(6) 5_665 ?
Ag2 N3 2.481(6) . ?
N1 C1 1.324(11) . ?
N1 N2 1.339(9) . ?
N1 Ag1 2.265(7) 7_665 ?
N2 N3 1.310(9) . ?
N3 N4 1.333(9) . ?
N4 C1 1.323(10) . ?
N4 Ag1 2.331(6) 3_655 ?
N5 N14 1.373(19) . ?
N5 C2 1.374(17) . ?
N6 N13 1.37(3) . ?
N6 N14 1.40(3) . ?
N7 C4 1.315(12) . ?
N7 N8 1.323(11) . ?
N8 N8 1.297(15) 10_556 ?
N9 O3 1.38(3) . ?
N9 C5 1.41(3) . ?
N9 C6 1.76(4) 10_556 ?
N9 N9 1.81(5) 10_556 ?
N10 O3 1.38(3) 10_556 ?
N10 O3 1.38(3) . ?
N10 C6 1.40(3) . ?
N10 C6 1.40(3) 10_556 ?
N11 C2 1.39(4) . ?
N11 O5 1.39(5) . ?
N12 C7 1.38(10) . ?
N12 O5 1.39(8) . ?
N13 O1 1.29(2) . ?
N13 C2 1.389(18) . ?
N15 H15A 0.8999 . ?
N15 H15B 0.8999 . ?
N15 H15C 0.9001 . ?
N15 H15D 0.9001 . ?
O1 C6 1.28(3) 7_665 ?
O3 O3 1.71(5) 10_556 ?
O3 C6 1.85(4) 10_556 ?
O4 C8 1.20(3) 11 ?
O4 C7 1.33(5) . ?
C1 C2 1.437(13) . ?
C2 C7 1.38(4) . ?
C4 N7 1.315(12) 10_556 ?
C4 C5 1.48(3) . ?
C5 C6 1.38(3) 10_556 ?
C5 C6 1.38(3) . ?
C5 N9 1.41(3) 10_556 ?
C6 C6 1.27(6) 10_556 ?
C6 O1 1.28(3) 7_665 ?
C6 N9 1.76(4) 10_556 ?
C6 O3 1.85(4) 10_556 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N4 127.1(3) 7_665 5_665 ?
N1 Ag1 N7 122.2(3) 7_665 . ?
N4 Ag1 N7 97.6(3) 5_665 . ?
N1 Ag1 N2 110.2(2) 7_665 . ?
N4 Ag1 N2 97.2(2) 5_665 . ?
N7 Ag1 N2 96.0(3) . . ?
N8 Ag2 N8 87.5(3) 5_665 3_655 ?
N8 Ag2 N8 87.5(3) 5_665 . ?
N8 Ag2 N8 87.5(3) 3_655 . ?
N8 Ag2 N3 92.0(3) 5_665 3_655 ?
N8 Ag2 N3 90.3(2) 3_655 3_655 ?
N8 Ag2 N3 177.8(3) . 3_655 ?
N8 Ag2 N3 90.3(2) 5_665 5_665 ?
N8 Ag2 N3 177.8(3) 3_655 5_665 ?
N8 Ag2 N3 92.0(3) . 5_665 ?
N3 Ag2 N3 90.2(2) 3_655 5_665 ?
N8 Ag2 N3 177.8(3) 5_665 . ?
N8 Ag2 N3 92.0(3) 3_655 . ?
N8 Ag2 N3 90.3(2) . . ?
N3 Ag2 N3 90.2(3) 3_655 . ?
N3 Ag2 N3 90.2(2) 5_665 . ?
C1 N1 N2 104.9(6) . . ?
C1 N1 Ag1 137.2(6) . 7_665 ?
N2 N1 Ag1 117.8(5) . 7_665 ?
N3 N2 N1 109.1(6) . . ?
N3 N2 Ag1 118.9(5) . . ?
N1 N2 Ag1 132.0(5) . . ?
N2 N3 N4 109.3(6) . . ?
N2 N3 Ag2 125.7(5) . . ?
N4 N3 Ag2 124.9(5) . . ?
C1 N4 N3 105.1(6) . . ?
C1 N4 Ag1 135.1(6) . 3_655 ?
N3 N4 Ag1 119.8(5) . 3_655 ?
N14 N5 C2 107.5(13) . . ?
N13 N6 N14 105(2) . . ?
C4 N7 N8 104.8(9) . . ?
C4 N7 Ag1 133.5(8) . . ?
N8 N7 Ag1 121.7(6) . . ?
N8 N8 N7 109.4(5) 10_556 . ?
N8 N8 Ag2 127.02(18) 10_556 . ?
N7 N8 Ag2 123.5(6) . . ?
O3 N9 C5 107(2) . . ?
O3 N9 C6 71.0(18) . 10_556 ?
C5 N9 C6 50.0(14) . 10_556 ?
O3 N9 N9 87.9(16) . 10_556 ?
C5 N9 N9 49.8(13) . 10_556 ?
C6 N9 N9 81.1(13) 10_556 10_556 ?
O3 N10 O3 77(2) 10_556 . ?
O3 N10 C6 83.4(18) 10_556 . ?
O3 N10 C6 116(2) . . ?
O3 N10 C6 116(2) 10_556 10_556 ?
O3 N10 C6 83.4(18) . 10_556 ?
C6 N10 C6 54(2) . 10_556 ?
C2 N11 O5 103(3) . . ?
C7 N12 O5 104(5) . . ?
O1 N13 N6 113.4(17) . . ?
O1 N13 C2 136.4(13) . . ?
N6 N13 C2 110.2(16) . . ?
N5 N14 N6 109.8(17) . . ?
H15A N15 H15B 104.9 . . ?
H15A N15 H15C 110.8 . . ?
H15B N15 H15C 110.8 . . ?
H15A N15 H15D 110.8 . . ?
H15B N15 H15D 110.8 . . ?
H15C N15 H15D 108.9 . . ?
C6 O1 N13 111.3(17) 7_665 . ?
N10 O3 N9 103(2) . . ?
N10 O3 O3 51.7(12) . 10_556 ?
N9 O3 O3 92.1(16) . 10_556 ?
N10 O3 C6 48.8(13) . 10_556 ?
N9 O3 C6 64.1(17) . 10_556 ?
O3 O3 C6 83.1(12) 10_556 10_556 ?
C8 O4 C7 113(3) 11 . ?
N11 O5 N12 113(4) . . ?
N4 C1 N1 111.6(7) . . ?
N4 C1 C2 123.6(8) . . ?
N1 C1 C2 124.8(8) . . ?
N5 C2 C7 86(2) . . ?
N5 C2 N13 107.2(11) . . ?
C7 C2 N13 47(2) . . ?
N5 C2 N11 51.7(17) . . ?
C7 C2 N11 110(2) . . ?
N13 C2 N11 92.0(17) . . ?
N5 C2 C1 124.2(10) . . ?
C7 C2 C1 131(2) . . ?
N13 C2 C1 128.6(10) . . ?
N11 C2 C1 118.1(15) . . ?
N7 C4 N7 111.6(14) . 10_556 ?
N7 C4 C5 124.0(7) . . ?
N7 C4 C5 124.0(7) 10_556 . ?
C6 C5 C6 55(3) 10_556 . ?
C6 C5 N9 113(2) 10_556 10_556 ?
C6 C5 N9 78.5(17) . 10_556 ?
C6 C5 N9 78.5(17) 10_556 . ?
C6 C5 N9 113(2) . . ?
N9 C5 N9 80(3) 10_556 . ?
C6 C5 C4 137.4(18) 10_556 . ?
C6 C5 C4 137.4(18) . . ?
N9 C5 C4 109.3(18) 10_556 . ?
N9 C5 C4 109.3(18) . . ?
C6 C6 O1 135.9(14) 10_556 7_665 ?
C6 C6 C5 62.5(13) 10_556 . ?
O1 C6 C5 112(2) 7_665 . ?
C6 C6 N10 63.1(11) 10_556 . ?
O1 C6 N10 149(2) 7_665 . ?
C5 C6 N10 99(2) . . ?
C6 C6 N9 98.9(13) 10_556 10_556 ?
O1 C6 N9 110(2) 7_665 10_556 ?
C5 C6 N9 51.4(15) . 10_556 ?
N10 C6 N9 86(2) . 10_556 ?
C6 C6 O3 96.9(12) 10_556 10_556 ?
O1 C6 O3 127(2) 7_665 10_556 ?
C5 C6 O3 87(2) . 10_556 ?
N10 C6 O3 47.8(13) . 10_556 ?
N9 C6 O3 45.0(13) 10_556 10_556 ?
O4 C7 C2 128(3) . . ?
O4 C7 N12 123(4) . . ?
C2 C7 N12 109(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 N1 N2 N3 0.4(10) . . . . ?
Ag1 N1 N2 N3 176.6(5) 7_665 . . . ?
C1 N1 N2 Ag1 -177.2(6) . . . . ?
Ag1 N1 N2 Ag1 -1.1(10) 7_665 . . . ?
N1 Ag1 N2 N3 -176.5(6) 7_665 . . . ?
N4 Ag1 N2 N3 49.5(7) 5_665 . . . ?
N7 Ag1 N2 N3 -48.9(7) . . . . ?
N1 Ag1 N2 N1 1.0(10) 7_665 . . . ?
N4 Ag1 N2 N1 -133.0(8) 5_665 . . . ?
N7 Ag1 N2 N1 128.6(8) . . . . ?
N1 N2 N3 N4 -0.2(10) . . . . ?
Ag1 N2 N3 N4 177.8(5) . . . . ?
N1 N2 N3 Ag2 -178.0(6) . . . . ?
Ag1 N2 N3 Ag2 0.0(9) . . . . ?
N8 Ag2 N3 N2 58(7) 5_665 . . . ?
N8 Ag2 N3 N2 133.9(7) 3_655 . . . ?
N8 Ag2 N3 N2 46.4(7) . . . . ?
N3 Ag2 N3 N2 -135.7(6) 3_655 . . . ?
N3 Ag2 N3 N2 -45.5(8) 5_665 . . . ?
N8 Ag2 N3 N4 -119(6) 5_665 . . . ?
N8 Ag2 N3 N4 -43.5(7) 3_655 . . . ?
N8 Ag2 N3 N4 -131.0(7) . . . . ?
N3 Ag2 N3 N4 46.8(8) 3_655 . . . ?
N3 Ag2 N3 N4 137.0(6) 5_665 . . . ?
N2 N3 N4 C1 -0.1(10) . . . . ?
Ag2 N3 N4 C1 177.7(6) . . . . ?
N2 N3 N4 Ag1 -179.2(5) . . . 3_655 ?
Ag2 N3 N4 Ag1 -1.4(9) . . . 3_655 ?
N1 Ag1 N7 C4 -14.7(16) 7_665 . . . ?
N4 Ag1 N7 C4 128.7(15) 5_665 . . . ?
N2 Ag1 N7 C4 -133.1(15) . . . . ?
N1 Ag1 N7 N8 167.2(7) 7_665 . . . ?
N4 Ag1 N7 N8 -49.4(8) 5_665 . . . ?
N2 Ag1 N7 N8 48.7(8) . . . . ?
C4 N7 N8 N8 0.3(12) . . . 10_556 ?
Ag1 N7 N8 N8 178.9(4) . . . 10_556 ?
C4 N7 N8 Ag2 -177.3(10) . . . . ?
Ag1 N7 N8 Ag2 1.3(11) . . . . ?
N8 Ag2 N8 N8 -43.80(12) 5_665 . . 10_556 ?
N8 Ag2 N8 N8 43.80(12) 3_655 . . 10_556 ?
N3 Ag2 N8 N8 32(7) 3_655 . . 10_556 ?
N3 Ag2 N8 N8 -134.1(2) 5_665 . . 10_556 ?
N3 Ag2 N8 N8 135.8(2) . . . 10_556 ?
N8 Ag2 N8 N7 133.3(9) 5_665 . . . ?
N8 Ag2 N8 N7 -139.1(9) 3_655 . . . ?
N3 Ag2 N8 N7 -151(6) 3_655 . . . ?
N3 Ag2 N8 N7 43.1(8) 5_665 . . . ?
N3 Ag2 N8 N7 -47.1(8) . . . . ?
N14 N6 N13 O1 -179.7(19) . . . . ?
N14 N6 N13 C2 0(3) . . . . ?
C2 N5 N14 N6 2(3) . . . . ?
N13 N6 N14 N5 -1(3) . . . . ?
N6 N13 O1 C6 -95(2) . . . 7_665 ?
C2 N13 O1 C6 86(3) . . . 7_665 ?
O3 N10 O3 N9 82(2) 10_556 . . . ?
C6 N10 O3 N9 7(3) . . . . ?
C6 N10 O3 N9 -37(2) 10_556 . . . ?
C6 N10 O3 O3 -75.4(18) . . . 10_556 ?
C6 N10 O3 O3 -119.3(18) 10_556 . . 10_556 ?
O3 N10 O3 C6 119.3(18) 10_556 . . 10_556 ?
C6 N10 O3 C6 44(2) . . . 10_556 ?
C5 N9 O3 N10 -5(3) . . . . ?
C6 N9 O3 N10 30.2(18) 10_556 . . . ?
N9 N9 O3 N10 -51.1(15) 10_556 . . . ?
C5 N9 O3 O3 46.5(18) . . . 10_556 ?
C6 N9 O3 O3 81.3(12) 10_556 . . 10_556 ?
N9 N9 O3 O3 0.000(9) 10_556 . . 10_556 ?
C5 N9 O3 C6 -34.8(18) . . . 10_556 ?
N9 N9 O3 C6 -81.3(12) 10_556 . . 10_556 ?
C2 N11 O5 N12 -3(6) . . . . ?
C7 N12 O5 N11 4(7) . . . . ?
N3 N4 C1 N1 0.4(11) . . . . ?
Ag1 N4 C1 N1 179.3(6) 3_655 . . . ?
N3 N4 C1 C2 -179.4(9) . . . . ?
Ag1 N4 C1 C2 -0.5(16) 3_655 . . . ?
N2 N1 C1 N4 -0.5(11) . . . . ?
Ag1 N1 C1 N4 -175.5(7) 7_665 . . . ?
N2 N1 C1 C2 179.3(10) . . . . ?
Ag1 N1 C1 C2 4.3(17) 7_665 . . . ?
N14 N5 C2 C7 40(3) . . . . ?
N14 N5 C2 N13 -1.6(19) . . . . ?
N14 N5 C2 N11 -80(2) . . . . ?
N14 N5 C2 C1 178.9(13) . . . . ?
O1 N13 C2 N5 -180(2) . . . . ?
N6 N13 C2 N5 1(2) . . . . ?
O1 N13 C2 C7 114(4) . . . . ?
N6 N13 C2 C7 -65(3) . . . . ?
O1 N13 C2 N11 -129(3) . . . . ?
N6 N13 C2 N11 51(2) . . . . ?
O1 N13 C2 C1 0(3) . . . . ?
N6 N13 C2 C1 -179.4(16) . . . . ?
O5 N11 C2 N5 68(3) . . . . ?
O5 N11 C2 C7 2(4) . . . . ?
O5 N11 C2 N13 -42(3) . . . . ?
O5 N11 C2 C1 -179(2) . . . . ?
N4 C1 C2 N5 30.4(18) . . . . ?
N1 C1 C2 N5 -149.4(13) . . . . ?
N4 C1 C2 C7 149(3) . . . . ?
N1 C1 C2 C7 -31(3) . . . . ?
N4 C1 C2 N13 -149.0(13) . . . . ?
N1 C1 C2 N13 31.3(19) . . . . ?
N4 C1 C2 N11 -30(2) . . . . ?
N1 C1 C2 N11 150(2) . . . . ?
N8 N7 C4 N7 0(2) . . . 10_556 ?
Ag1 N7 C4 N7 -178.9(5) . . . 10_556 ?
N8 N7 C4 C5 172.2(18) . . . . ?
Ag1 N7 C4 C5 -6(3) . . . . ?
O3 N9 C5 C6 45(2) . . . 10_556 ?
N9 N9 C5 C6 116.4(19) 10_556 . . 10_556 ?
O3 N9 C5 C6 1(3) . . . . ?
C6 N9 C5 C6 -43(2) 10_556 . . . ?
N9 N9 C5 C6 73.0(17) 10_556 . . . ?
O3 N9 C5 N9 -72(3) . . . 10_556 ?
C6 N9 C5 N9 -116.4(19) 10_556 . . 10_556 ?
O3 N9 C5 C4 -178.8(18) . . . . ?
C6 N9 C5 C4 136.4(18) 10_556 . . . ?
N9 N9 C5 C4 -107(2) 10_556 . . . ?
N7 C4 C5 C6 -129(2) . . . 10_556 ?
N7 C4 C5 C6 43(4) 10_556 . . 10_556 ?
N7 C4 C5 C6 -43(4) . . . . ?
N7 C4 C5 C6 129(2) 10_556 . . . ?
N7 C4 C5 N9 51(3) . . . 10_556 ?
N7 C4 C5 N9 -137(2) 10_556 . . 10_556 ?
N7 C4 C5 N9 137(2) . . . . ?
N7 C4 C5 N9 -51(3) 10_556 . . . ?
N9 C5 C6 C6 129.5(15) 10_556 . . 10_556 ?
N9 C5 C6 C6 55.4(15) . . . 10_556 ?
C4 C5 C6 C6 -124(3) . . . 10_556 ?
C6 C5 C6 O1 131.6(17) 10_556 . . 7_665 ?
N9 C5 C6 O1 -99(2) 10_556 . . 7_665 ?
N9 C5 C6 O1 -173(2) . . . 7_665 ?
C4 C5 C6 O1 7(4) . . . 7_665 ?
C6 C5 C6 N10 -53(2) 10_556 . . . ?
N9 C5 C6 N10 76.6(19) 10_556 . . . ?
N9 C5 C6 N10 2(3) . . . . ?
C4 C5 C6 N10 -177.3(19) . . . . ?
C6 C5 C6 N9 -129.5(15) 10_556 . . 10_556 ?
N9 C5 C6 N9 -74(3) . . . 10_556 ?
C4 C5 C6 N9 106(2) . . . 10_556 ?
C6 C5 C6 O3 -99.3(13) 10_556 . . 10_556 ?
N9 C5 C6 O3 30.2(15) 10_556 . . 10_556 ?
N9 C5 C6 O3 -44(2) . . . 10_556 ?
C4 C5 C6 O3 136(2) . . . 10_556 ?
O3 N10 C6 C6 -129.9(16) 10_556 . . 10_556 ?
O3 N10 C6 C6 -58.4(15) . . . 10_556 ?
O3 N10 C6 O1 95(5) 10_556 . . 7_665 ?
O3 N10 C6 O1 166(4) . . . 7_665 ?
C6 N10 C6 O1 -136(4) 10_556 . . 7_665 ?
O3 N10 C6 C5 -77(2) 10_556 . . . ?
O3 N10 C6 C5 -6(3) . . . . ?
C6 N10 C6 C5 53(2) 10_556 . . . ?
O3 N10 C6 N9 -27.5(16) 10_556 . . 10_556 ?
O3 N10 C6 N9 44(2) . . . 10_556 ?
C6 N10 C6 N9 102.3(14) 10_556 . . 10_556 ?
O3 N10 C6 O3 71(3) . . . 10_556 ?
C6 N10 C6 O3 129.9(16) 10_556 . . 10_556 ?
C8 O4 C7 C2 -79(5) 11 . . . ?
C8 O4 C7 N12 100(6) 11 . . . ?
N5 C2 C7 O4 134(5) . . . . ?
N13 C2 C7 O4 -108(5) . . . . ?
N11 C2 C7 O4 180(4) . . . . ?
C1 C2 C7 O4 0(7) . . . . ?
N5 C2 C7 N12 -46(4) . . . . ?
N13 C2 C7 N12 73(5) . . . . ?
N11 C2 C7 N12 0(5) . . . . ?
C1 C2 C7 N12 -179(3) . . . . ?
O5 N12 C7 O4 178(5) . . . . ?
O5 N12 C7 C2 -2(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        24.99
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         1.307
_refine_diff_density_min         -1.539
_refine_diff_density_rms         0.158
