# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1443116'
_audit_update_record             
;
2015-12-17 deposited with the CCDC.
2016-02-26 downloaded from the CCDC.
;


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H35 Ag P, F6 Sb'
_chemical_formula_sum            'C28 H35 Ag F6 P Sb'
_chemical_formula_weight         746.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   9.1981(4)
_cell_length_b                   11.3126(5)
_cell_length_c                   27.9588(13)
_cell_angle_alpha                90.00
_cell_angle_beta                 94.618(3)
_cell_angle_gamma                90.00
_cell_volume                     2899.8(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    9569
_cell_measurement_theta_min      2.28
_cell_measurement_theta_max      28.17

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.43
_exptl_crystal_size_min          0.25
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.709
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1480
_exptl_absorpt_coefficient_mu    1.716
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4267
_exptl_absorpt_correction_T_max  0.6536
_exptl_absorpt_process_details   
;
program SADABS, Bruker (2001).
;
_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
;
 Bruker-Nonius X8kappa APEX II CCD area detector
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
_diffrn_detector_area_resol_mean 8.26
_diffrn_standards_decay_%        0
_diffrn_reflns_number            28254
_diffrn_reflns_av_R_equivalents  0.0480
_diffrn_reflns_av_unetI/netI     0.0371
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_theta_min         2.32
_diffrn_reflns_theta_max         25.25
_reflns_number_total             5196
_reflns_number_gt                4344
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 Software Suite (Bruker, 2007)'
_computing_cell_refinement       'APEX2 Software Suite (Bruker, 2007)'
_computing_data_reduction        'APEX2 Software Suite (Bruker, 2007)'
_computing_structure_solution    'SIR2002 (Burla et al., 2003)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL and publCIF (Westrip, 2010)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0769P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5196
_refine_ls_number_parameters     340
_refine_ls_number_restraints     36
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0411
_refine_ls_wR_factor_ref         0.1148
_refine_ls_wR_factor_gt          0.1086
_refine_ls_goodness_of_fit_ref   1.105
_refine_ls_restrained_S_all      1.101
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.87207(3) 0.60334(3) 0.838434(11) 0.02845(12) Uani 1 1 d . . .
P1 P 0.80881(11) 0.68829(9) 0.91319(4) 0.0196(2) Uani 1 1 d . . .
C1 C 0.9691(4) 0.7475(3) 0.94895(15) 0.0226(8) Uani 1 1 d . . .
C2 C 1.1048(4) 0.7523(4) 0.92971(15) 0.0263(9) Uani 1 1 d . . .
C3 C 1.2224(5) 0.8002(4) 0.95822(18) 0.0373(11) Uani 1 1 d . . .
H3 H 1.3155 0.8035 0.9458 0.045 Uiso 1 1 calc R . .
C4 C 1.2075(6) 0.8425(4) 1.00341(19) 0.0432(13) Uani 1 1 d . . .
H4 H 1.2898 0.8736 1.0220 0.052 Uiso 1 1 calc R . .
C5 C 1.0735(5) 0.8402(4) 1.02208(18) 0.0366(11) Uani 1 1 d . . .
H5 H 1.0624 0.8702 1.0533 0.044 Uiso 1 1 calc R . .
C6 C 0.9552(5) 0.7932(4) 0.99465(16) 0.0305(10) Uani 1 1 d . . .
H6 H 0.8624 0.7922 1.0073 0.037 Uiso 1 1 calc R . .
C7 C 1.1382(4) 0.7132(4) 0.88076(15) 0.0239(9) Uani 1 1 d . . .
C8 C 1.1534(4) 0.7964(4) 0.84479(17) 0.0317(10) Uani 1 1 d . . .
H8 H 1.1278 0.8764 0.8500 0.038 Uiso 1 1 calc R . .
C9 C 1.2053(5) 0.7641(4) 0.80167(17) 0.0356(11) Uani 1 1 d . . .
H9 H 1.2141 0.8220 0.7775 0.043 Uiso 1 1 calc R . .
C10 C 1.2446(5) 0.6484(5) 0.79332(17) 0.0355(11) Uani 1 1 d . . .
H10 H 1.2822 0.6269 0.7639 0.043 Uiso 1 1 calc R . .
C11 C 1.2281(5) 0.5633(4) 0.82893(17) 0.0335(10) Uani 1 1 d . . .
H11 H 1.2535 0.4833 0.8234 0.040 Uiso 1 1 calc R . .
C12 C 1.1756(5) 0.5947(4) 0.87167(16) 0.0297(10) Uani 1 1 d . . .
H12 H 1.1642 0.5361 0.8954 0.036 Uiso 1 1 calc R . .
C13 C 0.7354(5) 0.5655(4) 0.94947(16) 0.0293(10) Uani 1 1 d . . .
C14 C 0.8512(5) 0.4680(4) 0.94811(17) 0.0330(10) Uani 1 1 d . . .
H14A H 0.8216 0.3994 0.9664 0.049 Uiso 1 1 calc R . .
H14B H 0.9451 0.4977 0.9623 0.049 Uiso 1 1 calc R . .
H14C H 0.8608 0.4446 0.9148 0.049 Uiso 1 1 calc R . .
C15 C 0.5922(5) 0.5224(4) 0.92419(19) 0.0380(11) Uani 1 1 d . . .
H15A H 0.5999 0.5218 0.8894 0.057 Uiso 1 1 calc R . .
H15B H 0.5130 0.5754 0.9318 0.057 Uiso 1 1 calc R . .
H15C H 0.5717 0.4422 0.9351 0.057 Uiso 1 1 calc R . .
C16 C 0.7134(6) 0.5898(5) 1.00218(17) 0.0418(12) Uani 1 1 d . . .
H16A H 0.6462 0.6564 1.0044 0.063 Uiso 1 1 calc R . .
H16B H 0.8074 0.6092 1.0194 0.063 Uiso 1 1 calc R . .
H16C H 0.6725 0.5195 1.0165 0.063 Uiso 1 1 calc R . .
C17 C 0.6821(4) 0.8177(4) 0.90224(16) 0.0266(9) Uani 1 1 d . . .
C18 C 0.5554(5) 0.7793(4) 0.86630(16) 0.0321(10) Uani 1 1 d . . .
H18A H 0.4934 0.8478 0.8577 0.048 Uiso 1 1 calc R . .
H18B H 0.4975 0.7185 0.8810 0.048 Uiso 1 1 calc R . .
H18C H 0.5945 0.7473 0.8374 0.048 Uiso 1 1 calc R . .
C19 C 0.7712(5) 0.9111(4) 0.8779(2) 0.0412(12) Uani 1 1 d . . .
H19A H 0.8079 0.8775 0.8489 0.062 Uiso 1 1 calc R . .
H19B H 0.8535 0.9361 0.9000 0.062 Uiso 1 1 calc R . .
H19C H 0.7091 0.9794 0.8692 0.062 Uiso 1 1 calc R . .
C20 C 0.6216(5) 0.8700(4) 0.94705(18) 0.0395(12) Uani 1 1 d . . .
H20A H 0.5617 0.9393 0.9380 0.059 Uiso 1 1 calc R . .
H20B H 0.7026 0.8935 0.9700 0.059 Uiso 1 1 calc R . .
H20C H 0.5617 0.8106 0.9618 0.059 Uiso 1 1 calc R . .
C21 C 0.7544(5) 0.5904(4) 0.75623(16) 0.0352(11) Uani 1 1 d . . .
H21 H 0.7255 0.6701 0.7607 0.042 Uiso 1 1 calc R . .
C22 C 0.8977(5) 0.5707(4) 0.75355(15) 0.0317(10) Uani 1 1 d . . .
H22 H 0.9603 0.6375 0.7567 0.038 Uiso 1 1 calc R . .
C23 C 0.9668(5) 0.4554(4) 0.74613(16) 0.0332(10) Uani 1 1 d . . .
H23 H 1.0220 0.4479 0.7190 0.040 Uiso 1 1 calc R . .
C24 C 0.9588(4) 0.3609(4) 0.77403(17) 0.0333(11) Uani 1 1 d . . .
H24 H 1.0102 0.2926 0.7651 0.040 Uiso 1 1 calc R . .
C25 C 0.8799(5) 0.3511(4) 0.81657(18) 0.0360(11) Uani 1 1 d . . .
H25 H 0.9353 0.3308 0.8456 0.043 Uiso 1 1 calc R . .
C26 C 0.7365(5) 0.3678(4) 0.81914(18) 0.0359(11) Uani 1 1 d . . .
H26 H 0.6995 0.3540 0.8494 0.043 Uiso 1 1 calc R . .
C27 C 0.6314(5) 0.4052(4) 0.78014(19) 0.0398(12) Uani 1 1 d . . .
H27 H 0.5492 0.3553 0.7735 0.048 Uiso 1 1 calc R . .
C28 C 0.6373(5) 0.5008(5) 0.75299(18) 0.0390(12) Uani 1 1 d . . .
H28 H 0.5589 0.5127 0.7292 0.047 Uiso 1 1 calc R . .
Sb1 Sb 0.29780(3) 0.17598(2) 0.871179(10) 0.03045(12) Uani 1 1 d . . .
F1 F 0.1395(4) 0.1176(4) 0.83307(17) 0.0899(14) Uani 1 1 d U . .
F2 F 0.4556(5) 0.2354(5) 0.9079(2) 0.1177(19) Uani 1 1 d U . .
F3 F 0.1824(4) 0.2994(3) 0.89076(13) 0.0658(10) Uani 1 1 d U . .
F4 F 0.2492(7) 0.0874(4) 0.92256(16) 0.1116(19) Uani 1 1 d U . .
F5 F 0.4073(5) 0.0527(4) 0.85088(15) 0.0890(14) Uani 1 1 d U . .
F6 F 0.3426(6) 0.2651(4) 0.81908(16) 0.0983(15) Uani 1 1 d U . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.4137(11) . ?
Ag1 C22 2.432(4) . ?
Ag1 C21 2.465(4) . ?
Ag1 C25 2.921(4) . ?
Ag1 C26 2.972(5) . ?
P1 C1 1.840(4) . ?
P1 C13 1.877(4) . ?
P1 C17 1.881(4) . ?
C1 C6 1.394(6) . ?
C1 C2 1.399(6) . ?
C2 C3 1.401(6) . ?
C2 C7 1.493(6) . ?
C3 C4 1.368(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.377(7) . ?
C4 H4 0.9500 . ?
C5 C6 1.386(6) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.392(6) . ?
C7 C12 1.412(6) . ?
C8 C9 1.381(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.382(7) . ?
C9 H9 0.9500 . ?
C10 C11 1.402(7) . ?
C10 H10 0.9500 . ?
C11 C12 1.371(6) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C15 1.524(6) . ?
C13 C16 1.529(6) . ?
C13 C14 1.536(6) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C19 1.530(6) . ?
C17 C20 1.530(6) . ?
C17 C18 1.539(6) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.345(7) . ?
C21 C28 1.477(7) . ?
C21 H21 0.9500 . ?
C22 C23 1.473(6) . ?
C22 H22 0.9500 . ?
C23 C24 1.329(7) . ?
C23 H23 0.9500 . ?
C24 C25 1.446(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.340(7) . ?
C25 H25 0.9500 . ?
C26 C27 1.461(7) . ?
C26 H26 0.9500 . ?
C27 C28 1.324(7) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
Sb1 F4 1.836(4) . ?
Sb1 F5 1.836(3) . ?
Sb1 F2 1.837(4) . ?
Sb1 F6 1.845(4) . ?
Sb1 F1 1.855(4) . ?
Sb1 F3 1.863(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 C22 162.66(11) . . ?
P1 Ag1 C21 135.45(12) . . ?
C22 Ag1 C21 31.88(16) . . ?
P1 Ag1 C25 125.59(11) . . ?
C22 Ag1 C25 68.98(15) . . ?
C21 Ag1 C25 76.31(15) . . ?
P1 Ag1 C26 112.78(10) . . ?
C22 Ag1 C26 76.05(15) . . ?
C21 Ag1 C26 68.36(15) . . ?
C25 Ag1 C26 26.28(13) . . ?
C1 P1 C13 106.44(19) . . ?
C1 P1 C17 105.29(18) . . ?
C13 P1 C17 114.8(2) . . ?
C1 P1 Ag1 112.16(14) . . ?
C13 P1 Ag1 107.19(14) . . ?
C17 P1 Ag1 111.01(14) . . ?
C6 C1 C2 119.3(4) . . ?
C6 C1 P1 120.3(3) . . ?
C2 C1 P1 120.4(3) . . ?
C1 C2 C3 117.9(4) . . ?
C1 C2 C7 126.6(4) . . ?
C3 C2 C7 115.4(4) . . ?
C4 C3 C2 122.1(4) . . ?
C4 C3 H3 119.0 . . ?
C2 C3 H3 119.0 . . ?
C3 C4 C5 120.2(4) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
C4 C5 C6 119.0(4) . . ?
C4 C5 H5 120.5 . . ?
C6 C5 H5 120.5 . . ?
C5 C6 C1 121.5(4) . . ?
C5 C6 H6 119.2 . . ?
C1 C6 H6 119.2 . . ?
C8 C7 C12 118.1(4) . . ?
C8 C7 C2 120.2(4) . . ?
C12 C7 C2 121.1(4) . . ?
C9 C8 C7 120.9(4) . . ?
C9 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
C8 C9 C10 120.7(4) . . ?
C8 C9 H9 119.6 . . ?
C10 C9 H9 119.6 . . ?
C9 C10 C11 119.0(4) . . ?
C9 C10 H10 120.5 . . ?
C11 C10 H10 120.5 . . ?
C12 C11 C10 120.5(4) . . ?
C12 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
C11 C12 C7 120.7(4) . . ?
C11 C12 H12 119.6 . . ?
C7 C12 H12 119.6 . . ?
C15 C13 C16 109.2(4) . . ?
C15 C13 C14 109.5(4) . . ?
C16 C13 C14 107.4(4) . . ?
C15 C13 P1 108.7(3) . . ?
C16 C13 P1 118.0(3) . . ?
C14 C13 P1 103.8(3) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C19 C17 C20 109.9(4) . . ?
C19 C17 C18 108.0(4) . . ?
C20 C17 C18 109.7(4) . . ?
C19 C17 P1 105.3(3) . . ?
C20 C17 P1 115.4(3) . . ?
C18 C17 P1 108.3(3) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 C28 126.6(4) . . ?
C22 C21 Ag1 72.7(3) . . ?
C28 C21 Ag1 111.2(3) . . ?
C22 C21 H21 116.7 . . ?
C28 C21 H21 116.7 . . ?
Ag1 C21 H21 85.9 . . ?
C21 C22 C23 126.2(4) . . ?
C21 C22 Ag1 75.4(3) . . ?
C23 C22 Ag1 110.4(3) . . ?
C21 C22 H22 116.9 . . ?
C23 C22 H22 116.9 . . ?
Ag1 C22 H22 83.9 . . ?
C24 C23 C22 125.8(4) . . ?
C24 C23 H23 117.1 . . ?
C22 C23 H23 117.1 . . ?
C23 C24 C25 126.8(4) . . ?
C23 C24 H24 116.6 . . ?
C25 C24 H24 116.6 . . ?
C26 C25 C24 126.4(5) . . ?
C26 C25 Ag1 79.0(3) . . ?
C24 C25 Ag1 96.9(3) . . ?
C26 C25 H25 116.8 . . ?
C24 C25 H25 116.8 . . ?
Ag1 C25 H25 94.5 . . ?
C25 C26 C27 126.6(5) . . ?
C25 C26 Ag1 74.7(3) . . ?
C27 C26 Ag1 96.8(3) . . ?
C25 C26 H26 116.7 . . ?
C27 C26 H26 116.7 . . ?
Ag1 C26 H26 99.3 . . ?
C28 C27 C26 127.5(4) . . ?
C28 C27 H27 116.2 . . ?
C26 C27 H27 116.2 . . ?
C27 C28 C21 126.1(4) . . ?
C27 C28 H28 117.0 . . ?
C21 C28 H28 117.0 . . ?
F4 Sb1 F5 90.1(2) . . ?
F4 Sb1 F2 89.6(3) . . ?
F5 Sb1 F2 91.3(2) . . ?
F4 Sb1 F6 178.8(3) . . ?
F5 Sb1 F6 90.5(2) . . ?
F2 Sb1 F6 91.4(3) . . ?
F4 Sb1 F1 91.5(3) . . ?
F5 Sb1 F1 88.7(2) . . ?
F2 Sb1 F1 178.9(3) . . ?
F6 Sb1 F1 87.5(2) . . ?
F4 Sb1 F3 89.92(18) . . ?
F5 Sb1 F3 178.44(19) . . ?
F2 Sb1 F3 90.26(19) . . ?
F6 Sb1 F3 89.48(18) . . ?
F1 Sb1 F3 89.79(18) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C22 Ag1 P1 C1 -108.9(4) . . . . ?
C21 Ag1 P1 C1 -145.0(2) . . . . ?
C25 Ag1 P1 C1 106.82(18) . . . . ?
C26 Ag1 P1 C1 133.26(17) . . . . ?
C22 Ag1 P1 C13 134.7(4) . . . . ?
C21 Ag1 P1 C13 98.5(2) . . . . ?
C25 Ag1 P1 C13 -9.66(19) . . . . ?
C26 Ag1 P1 C13 16.78(18) . . . . ?
C22 Ag1 P1 C17 8.6(4) . . . . ?
C21 Ag1 P1 C17 -27.5(2) . . . . ?
C25 Ag1 P1 C17 -135.71(18) . . . . ?
C26 Ag1 P1 C17 -109.27(18) . . . . ?
C13 P1 C1 C6 -58.9(4) . . . . ?
C17 P1 C1 C6 63.3(4) . . . . ?
Ag1 P1 C1 C6 -175.9(3) . . . . ?
C13 P1 C1 C2 124.1(3) . . . . ?
C17 P1 C1 C2 -113.7(3) . . . . ?
Ag1 P1 C1 C2 7.1(4) . . . . ?
C6 C1 C2 C3 1.8(6) . . . . ?
P1 C1 C2 C3 178.8(3) . . . . ?
C6 C1 C2 C7 -176.9(4) . . . . ?
P1 C1 C2 C7 0.2(6) . . . . ?
C1 C2 C3 C4 -0.5(7) . . . . ?
C7 C2 C3 C4 178.3(4) . . . . ?
C2 C3 C4 C5 -0.8(8) . . . . ?
C3 C4 C5 C6 0.7(7) . . . . ?
C4 C5 C6 C1 0.6(7) . . . . ?
C2 C1 C6 C5 -1.9(6) . . . . ?
P1 C1 C6 C5 -178.9(4) . . . . ?
C1 C2 C7 C8 102.4(5) . . . . ?
C3 C2 C7 C8 -76.3(5) . . . . ?
C1 C2 C7 C12 -86.8(5) . . . . ?
C3 C2 C7 C12 94.5(5) . . . . ?
C12 C7 C8 C9 -0.8(6) . . . . ?
C2 C7 C8 C9 170.3(4) . . . . ?
C7 C8 C9 C10 -0.5(7) . . . . ?
C8 C9 C10 C11 1.3(7) . . . . ?
C9 C10 C11 C12 -0.8(7) . . . . ?
C10 C11 C12 C7 -0.5(7) . . . . ?
C8 C7 C12 C11 1.3(6) . . . . ?
C2 C7 C12 C11 -169.7(4) . . . . ?
C1 P1 C13 C15 173.6(3) . . . . ?
C17 P1 C13 C15 57.5(4) . . . . ?
Ag1 P1 C13 C15 -66.3(3) . . . . ?
C1 P1 C13 C16 48.6(4) . . . . ?
C17 P1 C13 C16 -67.4(4) . . . . ?
Ag1 P1 C13 C16 168.8(3) . . . . ?
C1 P1 C13 C14 -70.0(3) . . . . ?
C17 P1 C13 C14 174.0(3) . . . . ?
Ag1 P1 C13 C14 50.2(3) . . . . ?
C1 P1 C17 C19 56.5(3) . . . . ?
C13 P1 C17 C19 173.2(3) . . . . ?
Ag1 P1 C17 C19 -65.1(3) . . . . ?
C1 P1 C17 C20 -64.8(4) . . . . ?
C13 P1 C17 C20 51.9(4) . . . . ?
Ag1 P1 C17 C20 173.6(3) . . . . ?
C1 P1 C17 C18 171.8(3) . . . . ?
C13 P1 C17 C18 -71.5(4) . . . . ?
Ag1 P1 C17 C18 50.2(3) . . . . ?
P1 Ag1 C21 C22 160.6(2) . . . . ?
C25 Ag1 C21 C22 -72.1(3) . . . . ?
C26 Ag1 C21 C22 -98.4(3) . . . . ?
P1 Ag1 C21 C28 -76.2(4) . . . . ?
C22 Ag1 C21 C28 123.3(5) . . . . ?
C25 Ag1 C21 C28 51.2(3) . . . . ?
C26 Ag1 C21 C28 24.8(3) . . . . ?
C28 C21 C22 C23 0.9(8) . . . . ?
Ag1 C21 C22 C23 104.8(5) . . . . ?
C28 C21 C22 Ag1 -103.9(5) . . . . ?
P1 Ag1 C22 C21 -51.5(5) . . . . ?
C25 Ag1 C22 C21 97.9(3) . . . . ?
C26 Ag1 C22 C21 71.3(3) . . . . ?
P1 Ag1 C22 C23 -175.2(2) . . . . ?
C21 Ag1 C22 C23 -123.7(5) . . . . ?
C25 Ag1 C22 C23 -25.8(3) . . . . ?
C26 Ag1 C22 C23 -52.3(3) . . . . ?
C21 C22 C23 C24 -58.1(7) . . . . ?
Ag1 C22 C23 C24 28.4(6) . . . . ?
C22 C23 C24 C25 0.9(8) . . . . ?
C23 C24 C25 C26 58.4(7) . . . . ?
C23 C24 C25 Ag1 -23.0(5) . . . . ?
P1 Ag1 C25 C26 68.0(3) . . . . ?
C22 Ag1 C25 C26 -101.2(3) . . . . ?
C21 Ag1 C25 C26 -68.7(3) . . . . ?
P1 Ag1 C25 C24 -166.1(2) . . . . ?
C22 Ag1 C25 C24 24.6(3) . . . . ?
C21 Ag1 C25 C24 57.2(3) . . . . ?
C26 Ag1 C25 C24 125.9(5) . . . . ?
C24 C25 C26 C27 -3.3(8) . . . . ?
Ag1 C25 C26 C27 87.1(5) . . . . ?
C24 C25 C26 Ag1 -90.5(5) . . . . ?
P1 Ag1 C26 C25 -125.1(3) . . . . ?
C22 Ag1 C26 C25 70.6(3) . . . . ?
C21 Ag1 C26 C25 103.2(3) . . . . ?
P1 Ag1 C26 C27 108.7(3) . . . . ?
C22 Ag1 C26 C27 -55.5(3) . . . . ?
C21 Ag1 C26 C27 -23.0(3) . . . . ?
C25 Ag1 C26 C27 -126.2(5) . . . . ?
C25 C26 C27 C28 -55.1(8) . . . . ?
Ag1 C26 C27 C28 20.9(6) . . . . ?
C26 C27 C28 C21 0.7(8) . . . . ?
C22 C21 C28 C27 55.4(8) . . . . ?
Ag1 C21 C28 C27 -28.3(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.989
_diffrn_reflns_theta_full        25.25
_diffrn_measured_fraction_theta_full 0.989
_refine_diff_density_max         1.153
_refine_diff_density_min         -1.521
_refine_diff_density_rms         0.133
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1443117'
_audit_update_record             
;
2015-12-17 deposited with the CCDC.
2016-02-26 downloaded from the CCDC.
;


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C48 H62 Ag2 P2, 2(F6 Sb), C H2 Cl2'
_chemical_formula_sum            'C49 H64 Ag2 Cl2 F12 P2 Sb2'
_chemical_formula_weight         1473.08

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_HALL  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   21.7571(19)
_cell_length_b                   10.1105(9)
_cell_length_c                   26.215(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 100.802(2)
_cell_angle_gamma                90.00
_cell_volume                     5664.6(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    9067
_cell_measurement_theta_min      3.89
_cell_measurement_theta_max      30.56

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.40
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.727
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2904
_exptl_absorpt_coefficient_mu    1.847
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4186
_exptl_absorpt_correction_T_max  0.4853
_exptl_absorpt_process_details   
;
program SADABS, Bruker (2001).
;


_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
;
 Bruker-Nonius X8kappa APEX II CCD area detector
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
_diffrn_detector_area_resol_mean 8.26
_diffrn_standards_decay_%        0
_diffrn_reflns_number            54881
_diffrn_reflns_av_R_equivalents  0.0184
_diffrn_reflns_av_unetI/netI     0.0126
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         3.92
_diffrn_reflns_theta_max         25.25
_reflns_number_total             10203
_reflns_number_gt                9787
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 Software Suite (Bruker, 2007)'
_computing_cell_refinement       'APEX2 Software Suite (Bruker, 2007)'
_computing_data_reduction        'APEX2 Software Suite (Bruker, 2007)'
_computing_structure_solution    'SIR2002 (Burla et al., 2003)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL and publCIF (Westrip, 2010)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0255P)²+15.4218P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10203
_refine_ls_number_parameters     670
_refine_ls_number_restraints     214
_refine_ls_R_factor_all          0.0346
_refine_ls_R_factor_gt           0.0330
_refine_ls_wR_factor_ref         0.0784
_refine_ls_wR_factor_gt          0.0777
_refine_ls_goodness_of_fit_ref   1.147
_refine_ls_restrained_S_all      1.286
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.500387(16) 0.65711(5) 0.829731(13) 0.04933(11) Uani 1 1 d . . .
Ag2 Ag 0.378810(16) 0.56287(3) 0.648273(11) 0.03356(9) Uani 1 1 d . . .
P1 P 0.59002(5) 0.72058(13) 0.89508(4) 0.0348(2) Uani 1 1 d . . .
P2 P 0.36606(4) 0.42333(10) 0.57152(4) 0.02326(19) Uani 1 1 d . . .
C1 C 0.56846(19) 0.7641(4) 0.95733(15) 0.0339(9) Uani 1 1 d . . .
C2 C 0.50738(18) 0.7469(4) 0.96604(15) 0.0291(8) Uani 1 1 d . . .
C3 C 0.4939(2) 0.7828(5) 1.01441(17) 0.0390(10) Uani 1 1 d . . .
H3 H 0.4530 0.7713 1.0206 0.047 Uiso 1 1 calc R . .
C4 C 0.5393(2) 0.8348(5) 1.05330(18) 0.0454(11) Uani 1 1 d . . .
H4 H 0.5290 0.8600 1.0852 0.054 Uiso 1 1 calc R . .
C5 C 0.5993(2) 0.8494(5) 1.04533(18) 0.0467(12) Uani 1 1 d . . .
H5 H 0.6306 0.8827 1.0719 0.056 Uiso 1 1 calc R . .
C6 C 0.6136(2) 0.8149(5) 0.99820(18) 0.0452(11) Uani 1 1 d . . .
H6 H 0.6549 0.8256 0.9931 0.054 Uiso 1 1 calc R . .
C7 C 0.45448(17) 0.6884(4) 0.92779(15) 0.0281(8) Uani 1 1 d . . .
C8 C 0.41741(18) 0.7664(4) 0.89020(16) 0.0336(9) Uani 1 1 d . . .
H8 H 0.4279 0.8556 0.8864 0.040 Uiso 1 1 calc R . .
C9 C 0.36508(19) 0.7132(5) 0.85830(17) 0.0364(10) Uani 1 1 d . . .
H9 H 0.3403 0.7666 0.8332 0.044 Uiso 1 1 calc R . .
C10 C 0.34940(19) 0.5826(5) 0.86336(16) 0.0355(10) Uani 1 1 d . . .
H10 H 0.3139 0.5471 0.8417 0.043 Uiso 1 1 calc R . .
C11 C 0.3856(2) 0.5037(5) 0.90007(18) 0.0413(10) Uani 1 1 d . . .
H11 H 0.3749 0.4145 0.9034 0.050 Uiso 1 1 calc R . .
C12 C 0.4380(2) 0.5564(4) 0.93208(17) 0.0388(10) Uani 1 1 d . . .
H12 H 0.4626 0.5022 0.9570 0.047 Uiso 1 1 calc R . .
C13 C 0.6471(2) 0.5794(5) 0.90992(19) 0.0450(11) Uani 1 1 d . . .
C14 C 0.6621(3) 0.5270(8) 0.8588(2) 0.084(2) Uani 1 1 d . . .
H14A H 0.6842 0.4435 0.8651 0.126 Uiso 1 1 calc R . .
H14B H 0.6882 0.5904 0.8450 0.126 Uiso 1 1 calc R . .
H14C H 0.6235 0.5139 0.8340 0.126 Uiso 1 1 calc R . .
C15 C 0.7085(3) 0.6097(7) 0.9463(3) 0.084(2) Uani 1 1 d . . .
H15A H 0.7002 0.6315 0.9805 0.126 Uiso 1 1 calc R . .
H15B H 0.7287 0.6840 0.9329 0.126 Uiso 1 1 calc R . .
H15C H 0.7356 0.5328 0.9489 0.126 Uiso 1 1 calc R . .
C16 C 0.6125(4) 0.4713(7) 0.9329(4) 0.089(2) Uani 1 1 d . . .
H16A H 0.6377 0.3916 0.9373 0.134 Uiso 1 1 calc R . .
H16B H 0.5731 0.4534 0.9097 0.134 Uiso 1 1 calc R . .
H16C H 0.6044 0.4998 0.9663 0.134 Uiso 1 1 calc R . .
C17 C 0.6223(2) 0.8767(5) 0.87140(18) 0.0442(11) Uani 1 1 d . . .
C18 C 0.5666(3) 0.9708(6) 0.8598(2) 0.0612(14) Uani 1 1 d . . .
H18A H 0.5513 0.9888 0.8916 0.092 Uiso 1 1 calc R . .
H18B H 0.5336 0.9306 0.8346 0.092 Uiso 1 1 calc R . .
H18C H 0.5795 1.0530 0.8459 0.092 Uiso 1 1 calc R . .
C19 C 0.6453(3) 0.8444(7) 0.8206(2) 0.0716(18) Uani 1 1 d . . .
H19A H 0.6145 0.7898 0.7986 0.107 Uiso 1 1 calc R . .
H19B H 0.6848 0.7973 0.8286 0.107 Uiso 1 1 calc R . .
H19C H 0.6511 0.9260 0.8025 0.107 Uiso 1 1 calc R . .
C20 C 0.6749(3) 0.9477(7) 0.9081(3) 0.0720(18) Uani 1 1 d . . .
H20A H 0.6883 1.0242 0.8906 0.108 Uiso 1 1 calc R . .
H20B H 0.7100 0.8879 0.9179 0.108 Uiso 1 1 calc R . .
H20C H 0.6600 0.9761 0.9389 0.108 Uiso 1 1 calc R . .
C21 C 0.35210(17) 0.5144(4) 0.50994(14) 0.0259(8) Uani 1 1 d . . .
C22 C 0.35577(17) 0.6533(4) 0.50884(15) 0.0275(8) Uani 1 1 d . . .
C23 C 0.35275(19) 0.7171(4) 0.46109(16) 0.0349(9) Uani 1 1 d . . .
H23 H 0.3564 0.8097 0.4603 0.042 Uiso 1 1 calc R . .
C24 C 0.3446(2) 0.6471(5) 0.41532(16) 0.0372(10) Uani 1 1 d . . .
H24 H 0.3430 0.6917 0.3836 0.045 Uiso 1 1 calc R . .
C25 C 0.3388(2) 0.5104(5) 0.41608(16) 0.0361(10) Uani 1 1 d . . .
H25 H 0.3319 0.4624 0.3848 0.043 Uiso 1 1 calc R . .
C26 C 0.34324(19) 0.4456(4) 0.46282(15) 0.0325(9) Uani 1 1 d . . .
H26 H 0.3402 0.3529 0.4631 0.039 Uiso 1 1 calc R . .
C27 C 0.36197(19) 0.7409(4) 0.55551(16) 0.0303(8) Uani 1 1 d . . .
C28 C 0.3119(2) 0.7613(4) 0.58068(18) 0.0389(10) Uani 1 1 d . . .
H28 H 0.2745 0.7140 0.5700 0.047 Uiso 1 1 calc R . .
C29 C 0.3166(3) 0.8514(5) 0.62159(19) 0.0480(12) Uani 1 1 d . . .
H29 H 0.2825 0.8649 0.6383 0.058 Uiso 1 1 calc R . .
C30 C 0.3716(3) 0.9207(4) 0.63751(19) 0.0490(13) Uani 1 1 d . . .
H30 H 0.3748 0.9823 0.6647 0.059 Uiso 1 1 calc R . .
C31 C 0.4215(3) 0.8995(5) 0.6136(2) 0.0481(12) Uani 1 1 d . . .
H31 H 0.4592 0.9451 0.6251 0.058 Uiso 1 1 calc R . .
C32 C 0.4170(2) 0.8112(4) 0.57253(19) 0.0407(10) Uani 1 1 d . . .
H32 H 0.4514 0.7987 0.5561 0.049 Uiso 1 1 calc R . .
C33 C 0.29768(19) 0.3090(4) 0.57102(15) 0.0317(9) Uani 1 1 d . . .
C34 C 0.2967(3) 0.1828(5) 0.5383(2) 0.0542(14) Uani 1 1 d . . .
H34A H 0.2600 0.1309 0.5411 0.081 Uiso 1 1 calc R . .
H34B H 0.3340 0.1312 0.5510 0.081 Uiso 1 1 calc R . .
H34C H 0.2954 0.2064 0.5023 0.081 Uiso 1 1 calc R . .
C35 C 0.2388(2) 0.3920(6) 0.5526(2) 0.0534(14) Uani 1 1 d . . .
H35A H 0.2367 0.4170 0.5166 0.080 Uiso 1 1 calc R . .
H35B H 0.2404 0.4711 0.5738 0.080 Uiso 1 1 calc R . .
H35C H 0.2021 0.3407 0.5557 0.080 Uiso 1 1 calc R . .
C36 C 0.2991(2) 0.2678(5) 0.62734(17) 0.0394(10) Uani 1 1 d . . .
H36A H 0.2936 0.3453 0.6479 0.059 Uiso 1 1 calc R . .
H36B H 0.3389 0.2265 0.6412 0.059 Uiso 1 1 calc R . .
H36C H 0.2655 0.2056 0.6287 0.059 Uiso 1 1 calc R . .
C37 C 0.44299(19) 0.3384(4) 0.57292(16) 0.0318(9) Uani 1 1 d . . .
C38 C 0.4486(2) 0.2472(6) 0.52720(19) 0.0504(13) Uani 1 1 d . . .
H38A H 0.4910 0.2134 0.5316 0.076 Uiso 1 1 calc R . .
H38B H 0.4388 0.2966 0.4950 0.076 Uiso 1 1 calc R . .
H38C H 0.4196 0.1739 0.5262 0.076 Uiso 1 1 calc R . .
C39 C 0.4594(2) 0.2610(4) 0.62411(17) 0.0380(10) Uani 1 1 d . . .
H39A H 0.4327 0.1837 0.6225 0.057 Uiso 1 1 calc R . .
H39B H 0.4531 0.3171 0.6527 0.057 Uiso 1 1 calc R . .
H39C H 0.5028 0.2332 0.6294 0.057 Uiso 1 1 calc R . .
C40 C 0.4900(2) 0.4534(5) 0.57316(19) 0.0423(11) Uani 1 1 d . . .
H40A H 0.4865 0.5140 0.6012 0.063 Uiso 1 1 calc R . .
H40B H 0.4807 0.4999 0.5403 0.063 Uiso 1 1 calc R . .
H40C H 0.5322 0.4182 0.5782 0.063 Uiso 1 1 calc R . .
C41 C 0.4270(2) 0.7658(4) 0.74698(17) 0.0384(10) Uani 1 1 d . . .
H41 H 0.4181 0.8368 0.7676 0.046 Uiso 1 1 calc R . .
C42 C 0.4834(2) 0.7642(5) 0.73418(16) 0.0387(10) Uani 1 1 d . . .
H42 H 0.5100 0.8357 0.7457 0.046 Uiso 1 1 calc R . .
C43 C 0.5081(2) 0.6616(5) 0.70384(17) 0.0410(11) Uani 1 1 d . . .
H43 H 0.5204 0.6881 0.6729 0.049 Uiso 1 1 calc R . .
C44 C 0.51443(19) 0.5344(5) 0.71647(17) 0.0384(10) Uani 1 1 d . . .
H44 H 0.5331 0.4801 0.6946 0.046 Uiso 1 1 calc R . .
C45 C 0.4953(2) 0.4707(4) 0.76096(16) 0.0354(9) Uani 1 1 d . . .
H45 H 0.5264 0.4241 0.7837 0.042 Uiso 1 1 calc R . .
C46 C 0.4378(2) 0.4719(4) 0.77268(16) 0.0349(9) Uani 1 1 d . . .
H46 H 0.4328 0.4262 0.8029 0.042 Uiso 1 1 calc R . .
C47 C 0.38188(19) 0.5372(5) 0.74317(15) 0.0332(9) Uani 1 1 d . . .
H47 H 0.3467 0.4841 0.7312 0.040 Uiso 1 1 calc R . .
C48 C 0.3772(2) 0.6673(5) 0.73201(16) 0.0347(9) Uani 1 1 d . . .
H48 H 0.3388 0.6976 0.7130 0.042 Uiso 1 1 calc R . .
Sb1 Sb 0.324794(12) 0.12435(3) 0.784521(10) 0.02861(7) Uani 1 1 d . . .
F1 F 0.26055(16) 0.2080(4) 0.73937(14) 0.0823(11) Uani 1 1 d U . .
F2 F 0.3419(2) 0.2755(4) 0.82350(16) 0.0868(12) Uani 1 1 d U . .
F3 F 0.38762(18) 0.0344(4) 0.82872(14) 0.0827(11) Uani 1 1 d U . .
F4 F 0.3075(2) -0.0292(4) 0.74521(17) 0.0922(13) Uani 1 1 d U . .
F5 F 0.38211(14) 0.1731(4) 0.74306(12) 0.0613(8) Uani 1 1 d U . .
F6 F 0.26744(16) 0.0760(4) 0.82615(13) 0.0696(9) Uani 1 1 d U . .
Sb2 Sb 0.868459(15) 0.41196(3) 0.866309(12) 0.04057(9) Uani 1 1 d D . .
F7A F 0.81418(17) 0.5496(4) 0.84079(15) 0.0815(11) Uani 0.65 1 d PDU A 1
F8A F 0.9177(4) 0.5295(7) 0.9103(3) 0.112(2) Uani 0.65 1 d PDU A 1
F9A F 0.92247(14) 0.2739(3) 0.89246(11) 0.0602(8) Uani 0.65 1 d PDU A 1
F10A F 0.8268(4) 0.2940(7) 0.8191(3) 0.120(3) Uani 0.65 1 d PDU A 1
F11A F 0.8209(3) 0.3753(7) 0.9136(3) 0.098(2) Uani 0.65 1 d PDU A 1
F12A F 0.9213(3) 0.4456(6) 0.8177(2) 0.0803(17) Uani 0.65 1 d PDU A 1
F7B F 0.81418(17) 0.5496(4) 0.84079(15) 0.0815(11) Uani 0.35 1 d PDU A 2
F8B F 0.9304(5) 0.5314(12) 0.8762(5) 0.109(4) Uani 0.35 1 d PDU A 2
F9B F 0.92247(14) 0.2739(3) 0.89246(11) 0.0602(8) Uani 0.35 1 d PDU A 2
F10B F 0.7985(4) 0.2987(10) 0.8603(5) 0.085(3) Uani 0.35 1 d PDU A 2
F11B F 0.8533(5) 0.4461(10) 0.9340(3) 0.075(3) Uani 0.35 1 d PDU A 2
F12B F 0.8760(6) 0.3782(12) 0.8010(4) 0.095(4) Uani 0.35 1 d PDU A 2
Cl1 Cl 0.81152(10) 0.9482(2) 0.77391(6) 0.0883(5) Uani 1 1 d U . .
Cl2 Cl 0.87428(14) 0.7275(2) 0.73852(14) 0.1323(10) Uani 1 1 d U . .
C49 C 0.8039(3) 0.7853(8) 0.7513(3) 0.083(2) Uani 1 1 d . . .
H49A H 0.7902 0.7289 0.7775 0.099 Uiso 1 1 calc R . .
H49B H 0.7719 0.7813 0.7196 0.099 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.4286(11) . ?
Ag1 C45 2.596(4) . ?
Ag1 C46 2.614(4) . ?
Ag1 C41 2.677(4) . ?
Ag1 C42 2.690(4) . ?
Ag2 P2 2.4303(10) . ?
Ag2 C48 2.442(4) . ?
Ag2 C47 2.490(4) . ?
P1 C1 1.834(4) . ?
P1 C17 1.880(5) . ?
P1 C13 1.885(5) . ?
P2 C21 1.834(4) . ?
P2 C37 1.875(4) . ?
P2 C33 1.882(4) . ?
C1 C2 1.401(6) . ?
C1 C6 1.407(6) . ?
C2 C3 1.402(6) . ?
C2 C7 1.499(5) . ?
C3 C4 1.384(7) . ?
C3 H3 0.9400 . ?
C4 C5 1.368(7) . ?
C4 H4 0.9400 . ?
C5 C6 1.374(6) . ?
C5 H5 0.9400 . ?
C6 H6 0.9400 . ?
C7 C12 1.391(6) . ?
C7 C8 1.395(6) . ?
C8 C9 1.388(6) . ?
C8 H8 0.9400 . ?
C9 C10 1.377(7) . ?
C9 H9 0.9400 . ?
C10 C11 1.378(6) . ?
C10 H10 0.9400 . ?
C11 C12 1.389(6) . ?
C11 H11 0.9400 . ?
C12 H12 0.9400 . ?
C13 C16 1.515(8) . ?
C13 C15 1.520(7) . ?
C13 C14 1.532(7) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C14 H14C 0.9700 . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 H16C 0.9700 . ?
C17 C18 1.526(7) . ?
C17 C20 1.529(7) . ?
C17 C19 1.544(7) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 H18C 0.9700 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 H19C 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C21 C26 1.399(6) . ?
C21 C22 1.407(6) . ?
C22 C23 1.399(6) . ?
C22 C27 1.496(6) . ?
C23 C24 1.376(6) . ?
C23 H23 0.9400 . ?
C24 C25 1.388(7) . ?
C24 H24 0.9400 . ?
C25 C26 1.377(6) . ?
C25 H25 0.9400 . ?
C26 H26 0.9400 . ?
C27 C28 1.391(6) . ?
C27 C32 1.392(6) . ?
C28 C29 1.396(7) . ?
C28 H28 0.9400 . ?
C29 C30 1.383(8) . ?
C29 H29 0.9400 . ?
C30 C31 1.367(8) . ?
C30 H30 0.9400 . ?
C31 C32 1.389(7) . ?
C31 H31 0.9400 . ?
C32 H32 0.9400 . ?
C33 C36 1.529(6) . ?
C33 C35 1.532(6) . ?
C33 C34 1.535(6) . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C34 H34C 0.9700 . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C35 H35C 0.9700 . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
C36 H36C 0.9700 . ?
C37 C38 1.536(6) . ?
C37 C39 1.537(6) . ?
C37 C40 1.547(6) . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C38 H38C 0.9700 . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C39 H39C 0.9700 . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C40 H40C 0.9700 . ?
C41 C42 1.332(6) . ?
C41 C48 1.470(6) . ?
C41 H41 0.9400 . ?
C42 C43 1.468(7) . ?
C42 H42 0.9400 . ?
C43 C44 1.328(7) . ?
C43 H43 0.9400 . ?
C44 C45 1.460(6) . ?
C44 H44 0.9400 . ?
C45 C46 1.343(6) . ?
C45 H45 0.9400 . ?
C46 C47 1.470(6) . ?
C46 H46 0.9400 . ?
C47 C48 1.347(6) . ?
C47 H47 0.9400 . ?
C48 H48 0.9400 . ?
Sb1 F2 1.838(3) . ?
Sb1 F3 1.856(3) . ?
Sb1 F1 1.857(3) . ?
Sb1 F4 1.862(3) . ?
Sb1 F5 1.867(3) . ?
Sb1 F6 1.870(3) . ?
Sb2 F12B 1.783(9) . ?
Sb2 F8B 1.792(10) . ?
Sb2 F11A 1.796(5) . ?
Sb2 F10A 1.832(6) . ?
Sb2 F8A 1.852(6) . ?
Sb2 F7A 1.866(3) . ?
Sb2 F9A 1.870(3) . ?
Sb2 F10B 1.888(8) . ?
Sb2 F11B 1.897(8) . ?
Sb2 F12A 1.899(5) . ?
Cl1 C49 1.748(8) . ?
Cl2 C49 1.731(8) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 C45 127.29(10) . . ?
P1 Ag1 C46 148.89(10) . . ?
C45 Ag1 C46 29.87(14) . . ?
P1 Ag1 C41 137.86(11) . . ?
C45 Ag1 C41 78.11(13) . . ?
C46 Ag1 C41 70.29(14) . . ?
P1 Ag1 C42 120.17(10) . . ?
C45 Ag1 C42 70.44(14) . . ?
C46 Ag1 C42 77.86(13) . . ?
C41 Ag1 C42 28.74(14) . . ?
P2 Ag2 C48 167.55(11) . . ?
P2 Ag2 C47 138.10(11) . . ?
C48 Ag2 C47 31.68(15) . . ?
C1 P1 C17 105.4(2) . . ?
C1 P1 C13 105.5(2) . . ?
C17 P1 C13 115.6(2) . . ?
C1 P1 Ag1 112.68(14) . . ?
C17 P1 Ag1 106.81(15) . . ?
C13 P1 Ag1 110.89(16) . . ?
C21 P2 C37 104.30(18) . . ?
C21 P2 C33 107.58(18) . . ?
C37 P2 C33 114.85(19) . . ?
C21 P2 Ag2 114.31(13) . . ?
C37 P2 Ag2 106.65(13) . . ?
C33 P2 Ag2 109.27(13) . . ?
C2 C1 C6 117.9(4) . . ?
C2 C1 P1 121.6(3) . . ?
C6 C1 P1 120.4(3) . . ?
C1 C2 C3 118.8(4) . . ?
C1 C2 C7 124.9(4) . . ?
C3 C2 C7 116.3(4) . . ?
C4 C3 C2 121.5(4) . . ?
C4 C3 H3 119.2 . . ?
C2 C3 H3 119.2 . . ?
C5 C4 C3 119.9(4) . . ?
C5 C4 H4 120.0 . . ?
C3 C4 H4 120.0 . . ?
C4 C5 C6 119.5(4) . . ?
C4 C5 H5 120.3 . . ?
C6 C5 H5 120.3 . . ?
C5 C6 C1 122.3(4) . . ?
C5 C6 H6 118.8 . . ?
C1 C6 H6 118.8 . . ?
C12 C7 C8 118.4(4) . . ?
C12 C7 C2 120.1(4) . . ?
C8 C7 C2 121.3(4) . . ?
C9 C8 C7 120.4(4) . . ?
C9 C8 H8 119.8 . . ?
C7 C8 H8 119.8 . . ?
C10 C9 C8 120.2(4) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C9 C10 C11 120.2(4) . . ?
C9 C10 H10 119.9 . . ?
C11 C10 H10 119.9 . . ?
C10 C11 C12 119.8(4) . . ?
C10 C11 H11 120.1 . . ?
C12 C11 H11 120.1 . . ?
C11 C12 C7 120.9(4) . . ?
C11 C12 H12 119.5 . . ?
C7 C12 H12 119.5 . . ?
C16 C13 C15 109.9(6) . . ?
C16 C13 C14 107.6(6) . . ?
C15 C13 C14 108.3(5) . . ?
C16 C13 P1 105.7(4) . . ?
C15 C13 P1 116.4(4) . . ?
C14 C13 P1 108.8(4) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C20 107.8(5) . . ?
C18 C17 C19 109.5(5) . . ?
C20 C17 C19 108.4(5) . . ?
C18 C17 P1 104.9(3) . . ?
C20 C17 P1 118.0(4) . . ?
C19 C17 P1 108.0(4) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C26 C21 C22 118.5(4) . . ?
C26 C21 P2 120.0(3) . . ?
C22 C21 P2 121.2(3) . . ?
C23 C22 C21 119.0(4) . . ?
C23 C22 C27 116.2(4) . . ?
C21 C22 C27 124.8(3) . . ?
C24 C23 C22 121.3(4) . . ?
C24 C23 H23 119.3 . . ?
C22 C23 H23 119.3 . . ?
C23 C24 C25 119.8(4) . . ?
C23 C24 H24 120.1 . . ?
C25 C24 H24 120.1 . . ?
C26 C25 C24 119.7(4) . . ?
C26 C25 H25 120.2 . . ?
C24 C25 H25 120.2 . . ?
C25 C26 C21 121.6(4) . . ?
C25 C26 H26 119.2 . . ?
C21 C26 H26 119.2 . . ?
C28 C27 C32 118.4(4) . . ?
C28 C27 C22 121.1(4) . . ?
C32 C27 C22 120.3(4) . . ?
C27 C28 C29 120.6(5) . . ?
C27 C28 H28 119.7 . . ?
C29 C28 H28 119.7 . . ?
C30 C29 C28 119.8(5) . . ?
C30 C29 H29 120.1 . . ?
C28 C29 H29 120.1 . . ?
C31 C30 C29 119.9(5) . . ?
C31 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C30 C31 C32 120.6(5) . . ?
C30 C31 H31 119.7 . . ?
C32 C31 H31 119.7 . . ?
C31 C32 C27 120.6(5) . . ?
C31 C32 H32 119.7 . . ?
C27 C32 H32 119.7 . . ?
C36 C33 C35 108.5(4) . . ?
C36 C33 C34 108.0(4) . . ?
C35 C33 C34 110.9(4) . . ?
C36 C33 P2 106.7(3) . . ?
C35 C33 P2 106.2(3) . . ?
C34 C33 P2 116.3(3) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33 C35 H35A 109.5 . . ?
C33 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C33 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C33 C36 H36A 109.5 . . ?
C33 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C33 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C38 C37 C39 109.6(4) . . ?
C38 C37 C40 107.8(4) . . ?
C39 C37 C40 109.5(3) . . ?
C38 C37 P2 117.5(3) . . ?
C39 C37 P2 108.1(3) . . ?
C40 C37 P2 104.1(3) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C37 C39 H39A 109.5 . . ?
C37 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C37 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C37 C40 H40A 109.5 . . ?
C37 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C37 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C42 C41 C48 126.4(4) . . ?
C42 C41 Ag1 76.2(3) . . ?
C48 C41 Ag1 103.7(3) . . ?
C42 C41 H41 116.8 . . ?
C48 C41 H41 116.8 . . ?
Ag1 C41 H41 90.2 . . ?
C41 C42 C43 126.3(4) . . ?
C41 C42 Ag1 75.1(3) . . ?
C43 C42 Ag1 102.7(3) . . ?
C41 C42 H42 116.8 . . ?
C43 C42 H42 116.8 . . ?
Ag1 C42 H42 92.4 . . ?
C44 C43 C42 125.5(4) . . ?
C44 C43 H43 117.3 . . ?
C42 C43 H43 117.3 . . ?
C43 C44 C45 126.5(4) . . ?
C43 C44 H44 116.8 . . ?
C45 C44 H44 116.8 . . ?
C46 C45 C44 126.6(4) . . ?
C46 C45 Ag1 75.8(3) . . ?
C44 C45 Ag1 104.6(3) . . ?
C46 C45 H45 116.7 . . ?
C44 C45 H45 116.7 . . ?
Ag1 C45 H45 89.5 . . ?
C45 C46 C47 126.7(4) . . ?
C45 C46 Ag1 74.3(2) . . ?
C47 C46 Ag1 105.7(3) . . ?
C45 C46 H46 116.6 . . ?
C47 C46 H46 116.6 . . ?
Ag1 C46 H46 90.0 . . ?
C48 C47 C46 125.1(4) . . ?
C48 C47 Ag2 72.2(2) . . ?
C46 C47 Ag2 115.9(3) . . ?
C48 C47 H47 117.4 . . ?
C46 C47 H47 117.4 . . ?
Ag2 C47 H47 81.8 . . ?
C47 C48 C41 125.5(4) . . ?
C47 C48 Ag2 76.1(2) . . ?
C41 C48 Ag2 113.5(3) . . ?
C47 C48 H48 117.2 . . ?
C41 C48 H48 117.2 . . ?
Ag2 C48 H48 80.0 . . ?
F2 Sb1 F3 90.7(2) . . ?
F2 Sb1 F1 91.4(2) . . ?
F3 Sb1 F1 177.7(2) . . ?
F2 Sb1 F4 179.8(2) . . ?
F3 Sb1 F4 89.2(2) . . ?
F1 Sb1 F4 88.7(2) . . ?
F2 Sb1 F5 90.94(17) . . ?
F3 Sb1 F5 89.92(16) . . ?
F1 Sb1 F5 90.79(15) . . ?
F4 Sb1 F5 89.19(17) . . ?
F2 Sb1 F6 88.89(18) . . ?
F3 Sb1 F6 90.09(17) . . ?
F1 Sb1 F6 89.21(16) . . ?
F4 Sb1 F6 90.98(18) . . ?
F5 Sb1 F6 179.83(18) . . ?
F12B Sb2 F8B 93.8(5) . . ?
F12B Sb2 F11A 142.3(5) . . ?
F8B Sb2 F11A 123.7(5) . . ?
F12B Sb2 F10A 49.4(5) . . ?
F8B Sb2 F10A 143.1(5) . . ?
F11A Sb2 F10A 93.2(4) . . ?
F12B Sb2 F8A 125.0(5) . . ?
F8B Sb2 F8A 31.3(4) . . ?
F11A Sb2 F8A 92.5(4) . . ?
F10A Sb2 F8A 173.8(4) . . ?
F12B Sb2 F7A 88.0(4) . . ?
F8B Sb2 F7A 87.6(4) . . ?
F11A Sb2 F7A 89.6(2) . . ?
F10A Sb2 F7A 92.5(3) . . ?
F8A Sb2 F7A 89.9(3) . . ?
F12B Sb2 F9A 92.6(4) . . ?
F8B Sb2 F9A 92.6(4) . . ?
F11A Sb2 F9A 89.8(2) . . ?
F10A Sb2 F9A 87.7(3) . . ?
F8A Sb2 F9A 90.0(3) . . ?
F7A Sb2 F9A 179.42(15) . . ?
F12B Sb2 F10B 91.2(5) . . ?
F8B Sb2 F10B 173.6(6) . . ?
F11A Sb2 F10B 51.1(4) . . ?
F10A Sb2 F10B 42.2(4) . . ?
F8A Sb2 F10B 143.6(4) . . ?
F7A Sb2 F10B 88.6(3) . . ?
F9A Sb2 F10B 91.1(3) . . ?
F12B Sb2 F11B 175.4(5) . . ?
F8B Sb2 F11B 90.0(5) . . ?
F11A Sb2 F11B 33.7(4) . . ?
F10A Sb2 F11B 126.9(4) . . ?
F8A Sb2 F11B 58.8(4) . . ?
F7A Sb2 F11B 89.5(3) . . ?
F9A Sb2 F11B 90.0(3) . . ?
F10B Sb2 F11B 84.9(4) . . ?
F12B Sb2 F12A 38.2(4) . . ?
F8B Sb2 F12A 56.1(5) . . ?
F11A Sb2 F12A 177.6(3) . . ?
F10A Sb2 F12A 87.1(3) . . ?
F8A Sb2 F12A 87.1(3) . . ?
F7A Sb2 F12A 92.76(19) . . ?
F9A Sb2 F12A 87.80(18) . . ?
F10B Sb2 F12A 129.2(4) . . ?
F11B Sb2 F12A 145.9(4) . . ?
Cl2 C49 Cl1 110.6(4) . . ?
Cl2 C49 H49A 109.5 . . ?
Cl1 C49 H49A 109.5 . . ?
Cl2 C49 H49B 109.5 . . ?
Cl1 C49 H49B 109.5 . . ?
H49A C49 H49B 108.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C45 Ag1 P1 C1 -141.4(2) . . . . ?
C46 Ag1 P1 C1 -109.4(3) . . . . ?
C41 Ag1 P1 C1 101.5(2) . . . . ?
C42 Ag1 P1 C1 131.1(2) . . . . ?
C45 Ag1 P1 C17 103.3(2) . . . . ?
C46 Ag1 P1 C17 135.3(2) . . . . ?
C41 Ag1 P1 C17 -13.8(2) . . . . ?
C42 Ag1 P1 C17 15.8(2) . . . . ?
C45 Ag1 P1 C13 -23.4(2) . . . . ?
C46 Ag1 P1 C13 8.6(3) . . . . ?
C41 Ag1 P1 C13 -140.5(2) . . . . ?
C42 Ag1 P1 C13 -110.9(2) . . . . ?
C48 Ag2 P2 C21 137.2(5) . . . . ?
C47 Ag2 P2 C21 167.67(19) . . . . ?
C48 Ag2 P2 C37 -108.1(5) . . . . ?
C47 Ag2 P2 C37 -77.6(2) . . . . ?
C48 Ag2 P2 C33 16.6(5) . . . . ?
C47 Ag2 P2 C33 47.1(2) . . . . ?
C17 P1 C1 C2 122.6(4) . . . . ?
C13 P1 C1 C2 -114.6(4) . . . . ?
Ag1 P1 C1 C2 6.5(4) . . . . ?
C17 P1 C1 C6 -58.0(4) . . . . ?
C13 P1 C1 C6 64.7(5) . . . . ?
Ag1 P1 C1 C6 -174.2(4) . . . . ?
C6 C1 C2 C3 1.0(7) . . . . ?
P1 C1 C2 C3 -179.7(3) . . . . ?
C6 C1 C2 C7 -177.0(4) . . . . ?
P1 C1 C2 C7 2.3(6) . . . . ?
C1 C2 C3 C4 0.2(7) . . . . ?
C7 C2 C3 C4 178.4(4) . . . . ?
C2 C3 C4 C5 -1.5(8) . . . . ?
C3 C4 C5 C6 1.4(8) . . . . ?
C4 C5 C6 C1 -0.2(8) . . . . ?
C2 C1 C6 C5 -1.0(8) . . . . ?
P1 C1 C6 C5 179.6(4) . . . . ?
C1 C2 C7 C12 99.1(5) . . . . ?
C3 C2 C7 C12 -79.0(5) . . . . ?
C1 C2 C7 C8 -86.6(5) . . . . ?
C3 C2 C7 C8 95.4(5) . . . . ?
C12 C7 C8 C9 0.5(6) . . . . ?
C2 C7 C8 C9 -173.9(4) . . . . ?
C7 C8 C9 C10 -0.2(6) . . . . ?
C8 C9 C10 C11 -0.1(6) . . . . ?
C9 C10 C11 C12 0.1(7) . . . . ?
C10 C11 C12 C7 0.2(7) . . . . ?
C8 C7 C12 C11 -0.5(7) . . . . ?
C2 C7 C12 C11 174.0(4) . . . . ?
C1 P1 C13 C16 58.7(5) . . . . ?
C17 P1 C13 C16 174.7(4) . . . . ?
Ag1 P1 C13 C16 -63.6(5) . . . . ?
C1 P1 C13 C15 -63.5(5) . . . . ?
C17 P1 C13 C15 52.5(5) . . . . ?
Ag1 P1 C13 C15 174.2(4) . . . . ?
C1 P1 C13 C14 173.9(4) . . . . ?
C17 P1 C13 C14 -70.1(5) . . . . ?
Ag1 P1 C13 C14 51.7(5) . . . . ?
C1 P1 C17 C18 -66.8(4) . . . . ?
C13 P1 C17 C18 177.2(3) . . . . ?
Ag1 P1 C17 C18 53.3(4) . . . . ?
C1 P1 C17 C20 53.2(5) . . . . ?
C13 P1 C17 C20 -62.8(5) . . . . ?
Ag1 P1 C17 C20 173.3(4) . . . . ?
C1 P1 C17 C19 176.5(4) . . . . ?
C13 P1 C17 C19 60.4(4) . . . . ?
Ag1 P1 C17 C19 -63.5(4) . . . . ?
C37 P2 C21 C26 64.7(3) . . . . ?
C33 P2 C21 C26 -57.7(4) . . . . ?
Ag2 P2 C21 C26 -179.3(3) . . . . ?
C37 P2 C21 C22 -109.4(3) . . . . ?
C33 P2 C21 C22 128.2(3) . . . . ?
Ag2 P2 C21 C22 6.7(4) . . . . ?
C26 C21 C22 C23 -2.3(6) . . . . ?
P2 C21 C22 C23 171.8(3) . . . . ?
C26 C21 C22 C27 176.9(4) . . . . ?
P2 C21 C22 C27 -9.0(5) . . . . ?
C21 C22 C23 C24 1.8(6) . . . . ?
C27 C22 C23 C24 -177.5(4) . . . . ?
C22 C23 C24 C25 0.5(6) . . . . ?
C23 C24 C25 C26 -2.1(6) . . . . ?
C24 C25 C26 C21 1.5(6) . . . . ?
C22 C21 C26 C25 0.7(6) . . . . ?
P2 C21 C26 C25 -173.5(3) . . . . ?
C23 C22 C27 C28 106.5(4) . . . . ?
C21 C22 C27 C28 -72.7(5) . . . . ?
C23 C22 C27 C32 -69.0(5) . . . . ?
C21 C22 C27 C32 111.8(5) . . . . ?
C32 C27 C28 C29 0.8(6) . . . . ?
C22 C27 C28 C29 -174.8(4) . . . . ?
C27 C28 C29 C30 -0.3(7) . . . . ?
C28 C29 C30 C31 -0.9(7) . . . . ?
C29 C30 C31 C32 1.6(7) . . . . ?
C30 C31 C32 C27 -1.1(7) . . . . ?
C28 C27 C32 C31 -0.1(6) . . . . ?
C22 C27 C32 C31 175.6(4) . . . . ?
C21 P2 C33 C36 -162.3(3) . . . . ?
C37 P2 C33 C36 82.1(3) . . . . ?
Ag2 P2 C33 C36 -37.7(3) . . . . ?
C21 P2 C33 C35 -46.7(4) . . . . ?
C37 P2 C33 C35 -162.3(3) . . . . ?
Ag2 P2 C33 C35 77.9(3) . . . . ?
C21 P2 C33 C34 77.1(4) . . . . ?
C37 P2 C33 C34 -38.5(4) . . . . ?
Ag2 P2 C33 C34 -158.2(3) . . . . ?
C21 P2 C37 C38 -56.5(4) . . . . ?
C33 P2 C37 C38 61.0(4) . . . . ?
Ag2 P2 C37 C38 -177.8(3) . . . . ?
C21 P2 C37 C39 178.9(3) . . . . ?
C33 P2 C37 C39 -63.6(3) . . . . ?
Ag2 P2 C37 C39 57.6(3) . . . . ?
C21 P2 C37 C40 62.5(3) . . . . ?
C33 P2 C37 C40 -180.0(3) . . . . ?
Ag2 P2 C37 C40 -58.8(3) . . . . ?
P1 Ag1 C41 C42 62.8(3) . . . . ?
C45 Ag1 C41 C42 -70.9(3) . . . . ?
C46 Ag1 C41 C42 -100.9(3) . . . . ?
P1 Ag1 C41 C48 -172.6(2) . . . . ?
C45 Ag1 C41 C48 53.8(3) . . . . ?
C46 Ag1 C41 C48 23.8(3) . . . . ?
C42 Ag1 C41 C48 124.6(4) . . . . ?
C48 C41 C42 C43 -2.0(7) . . . . ?
Ag1 C41 C42 C43 94.9(4) . . . . ?
C48 C41 C42 Ag1 -96.9(4) . . . . ?
P1 Ag1 C42 C41 -136.4(2) . . . . ?
C45 Ag1 C42 C41 101.1(3) . . . . ?
C46 Ag1 C42 C41 71.0(3) . . . . ?
P1 Ag1 C42 C43 99.0(3) . . . . ?
C45 Ag1 C42 C43 -23.5(3) . . . . ?
C46 Ag1 C42 C43 -53.6(3) . . . . ?
C41 Ag1 C42 C43 -124.6(4) . . . . ?
C41 C42 C43 C44 -59.1(7) . . . . ?
Ag1 C42 C43 C44 21.6(5) . . . . ?
C42 C43 C44 C45 3.6(7) . . . . ?
C43 C44 C45 C46 55.6(7) . . . . ?
C43 C44 C45 Ag1 -27.4(5) . . . . ?
P1 Ag1 C45 C46 146.6(2) . . . . ?
C41 Ag1 C45 C46 -71.0(3) . . . . ?
C42 Ag1 C45 C46 -99.8(3) . . . . ?
P1 Ag1 C45 C44 -88.7(3) . . . . ?
C46 Ag1 C45 C44 124.7(4) . . . . ?
C41 Ag1 C45 C44 53.7(3) . . . . ?
C42 Ag1 C45 C44 24.9(3) . . . . ?
C44 C45 C46 C47 0.2(7) . . . . ?
Ag1 C45 C46 C47 98.1(4) . . . . ?
C44 C45 C46 Ag1 -97.9(4) . . . . ?
P1 Ag1 C46 C45 -57.9(3) . . . . ?
C41 Ag1 C46 C45 100.6(3) . . . . ?
C42 Ag1 C46 C45 71.7(3) . . . . ?
P1 Ag1 C46 C47 177.57(17) . . . . ?
C45 Ag1 C46 C47 -124.5(4) . . . . ?
C41 Ag1 C46 C47 -23.9(3) . . . . ?
C42 Ag1 C46 C47 -52.8(3) . . . . ?
C45 C46 C47 C48 -57.9(7) . . . . ?
Ag1 C46 C47 C48 24.0(5) . . . . ?
C45 C46 C47 Ag2 27.9(6) . . . . ?
Ag1 C46 C47 Ag2 109.7(2) . . . . ?
P2 Ag2 C47 C48 -168.0(2) . . . . ?
P2 Ag2 C47 C46 71.0(3) . . . . ?
C48 Ag2 C47 C46 -121.0(4) . . . . ?
C46 C47 C48 C41 0.5(7) . . . . ?
Ag2 C47 C48 C41 -109.1(4) . . . . ?
C46 C47 C48 Ag2 109.6(4) . . . . ?
C42 C41 C48 C47 59.0(7) . . . . ?
Ag1 C41 C48 C47 -23.8(5) . . . . ?
C42 C41 C48 Ag2 -30.4(6) . . . . ?
Ag1 C41 C48 Ag2 -113.1(2) . . . . ?
P2 Ag2 C48 C47 40.1(6) . . . . ?
P2 Ag2 C48 C41 163.1(3) . . . . ?
C47 Ag2 C48 C41 123.0(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        25.25
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         0.991
_refine_diff_density_min         -0.829
_refine_diff_density_rms         0.082
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2a
_database_code_depnum_ccdc_archive 'CCDC 1443118'
_audit_update_record             
;
2015-12-17 deposited with the CCDC.
2016-02-26 downloaded from the CCDC.
;



# start Validation Reply Form ================================================

_vrf_PLAT971_2a                  
;
PROBLEM: Check Calcd Residual Density  1.09A From     Ag2       5.03 eA-3 
RESPONSE: This residual density maximum outside the metal atom doesn't make 
chemical sense. This might be caused by The low quality of the used crystal.
However it was without doubt the best crystal selected after a rigorous
analysis of the crystals obtained. 
;


_vrf_PLAT939_2a                  
;
PROBLEM: Large Value of Not (SHELXL) Weight Optimized S .     158.98       

RESPONSE: This indicates the presence of large outliers in the data set. 
It may be caused by reflections measured behind the beamstop.
;

# end Validation Reply Form ==================================================




_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C48 H62 Ag2 P2, 2(F6 Sb), 2(C H2 Cl2)'
_chemical_formula_sum            'C50 H66 Ag2 Cl4 F12 P2 Sb2'
_chemical_formula_weight         1558.01

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Orthorhombic
_symmetry_space_group_name_H-M   'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   24.389(4)
_cell_length_b                   15.102(3)
_cell_length_c                   32.963(6)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     12141(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    8394
_cell_measurement_theta_min      3.10
_cell_measurement_theta_max      26.67

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.30
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.705
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             6144
_exptl_absorpt_coefficient_mu    1.814
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4641
_exptl_absorpt_correction_T_max  0.6122
_exptl_absorpt_process_details   
;
program SADABS, Bruker (2001).
;


_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
;
 Bruker-Nonius X8kappa APEX II CCD area detector
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
_diffrn_detector_area_resol_mean 8.26
_diffrn_standards_decay_%        0
_diffrn_reflns_number            10632
_diffrn_reflns_av_R_equivalents  0.0835
_diffrn_reflns_av_unetI/netI     0.0536
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_theta_min         1.70
_diffrn_reflns_theta_max         25.00
_reflns_number_total             10632
_reflns_number_gt                7133
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 Software Suite (Bruker, 2007)'
_computing_cell_refinement       'APEX2 Software Suite (Bruker, 2007)'
_computing_data_reduction        'APEX2 Software Suite (Bruker, 2007)'
_computing_structure_solution    'SIR2002 (Burla et al., 2003)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL and publCIF (Westrip, 2010)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1682P)²+6.2486P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10632
_refine_ls_number_parameters     688
_refine_ls_number_restraints     146
_refine_ls_R_factor_all          0.1170
_refine_ls_R_factor_gt           0.0738
_refine_ls_wR_factor_ref         0.2574
_refine_ls_wR_factor_gt          0.2210
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_restrained_S_all      1.100
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.39885(3) 0.80952(5) 0.84852(2) 0.0474(2) Uani 1 1 d . . .
Ag2 Ag 0.59482(3) 0.85782(7) 0.88921(2) 0.0555(3) Uani 1 1 d . . .
P1 P 0.32226(9) 0.72386(16) 0.82243(8) 0.0397(6) Uani 1 1 d . . .
P2 P 0.67952(9) 0.80502(17) 0.91925(7) 0.0386(5) Uani 1 1 d . . .
C1 C 0.2580(4) 0.7599(6) 0.8459(3) 0.047(2) Uani 1 1 d . . .
C2 C 0.2578(4) 0.8190(6) 0.8792(3) 0.044(2) Uani 1 1 d . . .
C3 C 0.2078(4) 0.8383(7) 0.8988(4) 0.056(3) Uani 1 1 d . . .
H3 H 0.2076 0.8775 0.9214 0.068 Uiso 1 1 calc R . .
C4 C 0.1585(4) 0.8007(8) 0.8857(4) 0.065(3) Uani 1 1 d . . .
H4 H 0.1252 0.8139 0.8993 0.078 Uiso 1 1 calc R . .
C5 C 0.1584(4) 0.7456(9) 0.8535(5) 0.076(4) Uani 1 1 d . . .
H5 H 0.1248 0.7218 0.8438 0.091 Uiso 1 1 calc R . .
C6 C 0.2074(4) 0.7234(8) 0.8345(4) 0.067(3) Uani 1 1 d . . .
H6 H 0.2066 0.6818 0.8129 0.080 Uiso 1 1 calc R . .
C7 C 0.3061(4) 0.8652(6) 0.8969(3) 0.044(2) Uani 1 1 d . . .
C8 C 0.3231(4) 0.8477(8) 0.9365(3) 0.057(3) Uani 1 1 d . . .
H8 H 0.3071 0.7999 0.9510 0.068 Uiso 1 1 calc R . .
C9 C 0.3630(5) 0.8994(9) 0.9549(3) 0.062(3) Uani 1 1 d . . .
H9 H 0.3754 0.8849 0.9814 0.074 Uiso 1 1 calc R . .
C10 C 0.3849(4) 0.9712(8) 0.9353(4) 0.061(3) Uani 1 1 d . . .
H10 H 0.4102 1.0086 0.9489 0.073 Uiso 1 1 calc R . .
C11 C 0.3706(4) 0.9886(7) 0.8970(4) 0.054(3) Uani 1 1 d . . .
H11 H 0.3877 1.0365 0.8832 0.065 Uiso 1 1 calc R . .
C12 C 0.3314(4) 0.9382(6) 0.8767(3) 0.046(2) Uani 1 1 d . . .
H12 H 0.3215 0.9524 0.8496 0.056 Uiso 1 1 calc R . .
C13 C 0.3167(4) 0.7441(7) 0.7664(3) 0.053(3) Uani 1 1 d . . .
C14 C 0.3732(6) 0.7374(10) 0.7474(3) 0.075(4) Uani 1 1 d . . .
H14A H 0.3698 0.7385 0.7178 0.113 Uiso 1 1 calc R . .
H14B H 0.3906 0.6819 0.7558 0.113 Uiso 1 1 calc R . .
H14C H 0.3957 0.7876 0.7563 0.113 Uiso 1 1 calc R . .
C15 C 0.2954(6) 0.8394(9) 0.7628(4) 0.087(4) Uani 1 1 d . . .
H15A H 0.3231 0.8805 0.7732 0.130 Uiso 1 1 calc R . .
H15B H 0.2616 0.8456 0.7785 0.130 Uiso 1 1 calc R . .
H15C H 0.2880 0.8530 0.7342 0.130 Uiso 1 1 calc R . .
C16 C 0.2786(7) 0.6839(12) 0.7422(5) 0.112(6) Uani 1 1 d . . .
H16A H 0.2791 0.7015 0.7135 0.168 Uiso 1 1 calc R . .
H16B H 0.2411 0.6892 0.7527 0.168 Uiso 1 1 calc R . .
H16C H 0.2909 0.6224 0.7447 0.168 Uiso 1 1 calc R . .
C17 C 0.3297(4) 0.6032(7) 0.8357(4) 0.052(3) Uani 1 1 d . . .
C18 C 0.3323(6) 0.6031(10) 0.8828(4) 0.082(4) Uani 1 1 d . . .
H18A H 0.2960 0.6176 0.8938 0.123 Uiso 1 1 calc R . .
H18B H 0.3590 0.6472 0.8919 0.123 Uiso 1 1 calc R . .
H18C H 0.3434 0.5443 0.8923 0.123 Uiso 1 1 calc R . .
C19 C 0.3849(5) 0.5707(7) 0.8196(4) 0.064(3) Uani 1 1 d . . .
H19A H 0.3940 0.5139 0.8322 0.096 Uiso 1 1 calc R . .
H19B H 0.4134 0.6142 0.8260 0.096 Uiso 1 1 calc R . .
H19C H 0.3826 0.5631 0.7901 0.096 Uiso 1 1 calc R . .
C20 C 0.2842(5) 0.5421(8) 0.8204(5) 0.092(5) Uani 1 1 d . . .
H20A H 0.2862 0.5379 0.7908 0.138 Uiso 1 1 calc R . .
H20B H 0.2485 0.5662 0.8283 0.138 Uiso 1 1 calc R . .
H20C H 0.2888 0.4831 0.8323 0.138 Uiso 1 1 calc R . .
C21 C 0.7378(3) 0.8568(6) 0.8944(3) 0.037(2) Uani 1 1 d . . .
C22 C 0.7318(3) 0.9077(6) 0.8594(3) 0.0334(19) Uani 1 1 d . . .
C23 C 0.7785(4) 0.9407(7) 0.8404(3) 0.048(2) Uani 1 1 d . . .
H23 H 0.7739 0.9735 0.8161 0.057 Uiso 1 1 calc R . .
C24 C 0.8303(4) 0.9290(7) 0.8547(3) 0.049(2) Uani 1 1 d . . .
H24 H 0.8610 0.9543 0.8413 0.059 Uiso 1 1 calc R . .
C25 C 0.8367(4) 0.8779(8) 0.8901(3) 0.053(3) Uani 1 1 d . . .
H25 H 0.8723 0.8673 0.9008 0.063 Uiso 1 1 calc R . .
C26 C 0.7908(4) 0.8429(7) 0.9094(3) 0.049(2) Uani 1 1 d . . .
H26 H 0.7955 0.8088 0.9334 0.059 Uiso 1 1 calc R . .
C27 C 0.6790(3) 0.9290(6) 0.8383(3) 0.038(2) Uani 1 1 d . . .
C28 C 0.6637(4) 0.8862(7) 0.8022(3) 0.049(2) Uani 1 1 d . . .
H28 H 0.6839 0.8357 0.7937 0.059 Uiso 1 1 calc R . .
C29 C 0.6207(4) 0.9149(8) 0.7787(3) 0.061(3) Uani 1 1 d . . .
H29 H 0.6121 0.8854 0.7540 0.073 Uiso 1 1 calc R . .
C30 C 0.5893(4) 0.9885(8) 0.7914(3) 0.056(3) Uani 1 1 d . . .
H30 H 0.5596 1.0091 0.7754 0.067 Uiso 1 1 calc R . .
C31 C 0.6023(4) 1.0301(8) 0.8273(4) 0.058(3) Uani 1 1 d . . .
H31 H 0.5807 1.0787 0.8363 0.069 Uiso 1 1 calc R . .
C32 C 0.6467(4) 1.0019(6) 0.8508(3) 0.045(2) Uani 1 1 d . . .
H32 H 0.6553 1.0320 0.8753 0.054 Uiso 1 1 calc R . .
C33 C 0.6883(5) 0.6828(7) 0.9092(4) 0.057(3) Uani 1 1 d . . .
C34 C 0.6403(6) 0.6358(9) 0.9285(4) 0.075(4) Uani 1 1 d . . .
H34A H 0.6401 0.5736 0.9200 0.113 Uiso 1 1 calc R . .
H34B H 0.6061 0.6643 0.9200 0.113 Uiso 1 1 calc R . .
H34C H 0.6435 0.6390 0.9581 0.113 Uiso 1 1 calc R . .
C35 C 0.7434(6) 0.6412(9) 0.9217(5) 0.089(4) Uani 1 1 d . . .
H35A H 0.7474 0.6442 0.9512 0.133 Uiso 1 1 calc R . .
H35B H 0.7734 0.6737 0.9088 0.133 Uiso 1 1 calc R . .
H35C H 0.7444 0.5792 0.9129 0.133 Uiso 1 1 calc R . .
C36 C 0.6827(6) 0.6762(8) 0.8620(4) 0.071(3) Uani 1 1 d . . .
H36A H 0.6743 0.6150 0.8544 0.107 Uiso 1 1 calc R . .
H36B H 0.7173 0.6943 0.8493 0.107 Uiso 1 1 calc R . .
H36C H 0.6531 0.7152 0.8528 0.107 Uiso 1 1 calc R . .
C37 C 0.6815(5) 0.8380(8) 0.9741(3) 0.055(3) Uani 1 1 d . . .
C38 C 0.6955(6) 0.9348(9) 0.9765(4) 0.080(4) Uani 1 1 d . . .
H38A H 0.6683 0.9692 0.9614 0.120 Uiso 1 1 calc R . .
H38B H 0.7319 0.9447 0.9648 0.120 Uiso 1 1 calc R . .
H38C H 0.6956 0.9536 1.0050 0.120 Uiso 1 1 calc R . .
C39 C 0.7225(5) 0.7847(10) 0.9998(3) 0.075(4) Uani 1 1 d . . .
H39A H 0.7599 0.8030 0.9931 0.112 Uiso 1 1 calc R . .
H39B H 0.7181 0.7214 0.9941 0.112 Uiso 1 1 calc R . .
H39C H 0.7155 0.7958 1.0287 0.112 Uiso 1 1 calc R . .
C40 C 0.6259(5) 0.8217(10) 0.9918(3) 0.075(4) Uani 1 1 d . . .
H40A H 0.6275 0.8289 1.0213 0.113 Uiso 1 1 calc R . .
H40B H 0.6142 0.7613 0.9853 0.113 Uiso 1 1 calc R . .
H40C H 0.5997 0.8641 0.9804 0.113 Uiso 1 1 calc R . .
C41 C 0.4801(3) 0.9083(6) 0.8442(3) 0.041(2) Uani 1 1 d . . .
H41 H 0.4549 0.9516 0.8348 0.049 Uiso 1 1 calc R . .
C42 C 0.4907(4) 0.8398(7) 0.8190(3) 0.046(2) Uani 1 1 d . . .
H42 H 0.4724 0.8397 0.7936 0.055 Uiso 1 1 calc R . .
C43 C 0.5271(4) 0.7669(7) 0.8270(3) 0.046(2) Uani 1 1 d . . .
H43 H 0.5563 0.7590 0.8083 0.056 Uiso 1 1 calc R . .
C44 C 0.5246(4) 0.7083(7) 0.8581(3) 0.050(2) Uani 1 1 d . . .
H44 H 0.5513 0.6625 0.8589 0.060 Uiso 1 1 calc R . .
C45 C 0.4833(4) 0.7108(6) 0.8908(3) 0.046(2) Uani 1 1 d . . .
H45 H 0.4616 0.6592 0.8945 0.056 Uiso 1 1 calc R . .
C46 C 0.4736(4) 0.7785(7) 0.9156(3) 0.046(2) Uani 1 1 d . . .
H46 H 0.4459 0.7697 0.9354 0.055 Uiso 1 1 calc R . .
C47 C 0.5010(3) 0.8665(7) 0.9158(3) 0.047(2) Uani 1 1 d . . .
H47 H 0.5178 0.8847 0.9404 0.056 Uiso 1 1 calc R . .
C48 C 0.5038(3) 0.9219(7) 0.8845(3) 0.047(2) Uani 1 1 d . . .
H48 H 0.5232 0.9757 0.8888 0.056 Uiso 1 1 calc R . .
Sb1 Sb 0.54029(4) 0.18071(5) 0.94026(2) 0.0659(3) Uani 1 1 d . . .
F1 F 0.4807(4) 0.1323(7) 0.9150(3) 0.125(3) Uani 1 1 d U . .
F2 F 0.6067(6) 0.2225(10) 0.9626(4) 0.187(7) Uani 1 1 d U . .
F3 F 0.5111(11) 0.2892(9) 0.9385(5) 0.275(12) Uani 1 1 d U . .
F4 F 0.5175(6) 0.1565(11) 0.9910(3) 0.183(6) Uani 1 1 d U . .
F5 F 0.5765(5) 0.0697(7) 0.9378(3) 0.125(3) Uani 1 1 d U . .
F6 F 0.5688(7) 0.2032(11) 0.8890(3) 0.185(6) Uani 1 1 d U . .
Sb2 Sb 0.59438(3) 0.57892(5) 0.74649(2) 0.0551(3) Uani 1 1 d . . .
F7 F 0.5770(4) 0.4583(5) 0.7454(2) 0.092(3) Uani 1 1 d U . .
F8 F 0.5932(9) 0.5806(9) 0.6913(3) 0.251(11) Uani 1 1 d U . .
F9 F 0.6133(3) 0.6988(4) 0.7482(2) 0.0671(18) Uani 1 1 d U . .
F10 F 0.5962(4) 0.5744(5) 0.8025(2) 0.095(3) Uani 1 1 d U . .
F11 F 0.5212(3) 0.6065(7) 0.7510(4) 0.122(4) Uani 1 1 d U . .
F12 F 0.6684(4) 0.5497(6) 0.7463(5) 0.182(7) Uani 1 1 d U . .
Cl1 Cl 0.4730(2) 0.3290(4) 0.80520(18) 0.152(3) Uani 1 1 d DU . .
Cl2 Cl 0.5065(2) 0.4512(3) 0.86903(17) 0.1275(17) Uani 1 1 d DU . .
C49 C 0.5235(5) 0.3794(11) 0.8316(4) 0.100(5) Uani 1 1 d D . .
H49A H 0.5467 0.4118 0.8119 0.120 Uiso 1 1 calc R . .
H49B H 0.5467 0.3326 0.8437 0.120 Uiso 1 1 calc R . .
Cl3A Cl 0.4448(4) 0.4910(11) 0.9593(4) 0.143(5) Uani 0.55 1 d PDU A 1
Cl4A Cl 0.3547(7) 0.5825(16) 0.9904(5) 0.180(10) Uani 0.55 1 d PDU A 1
C50A C 0.4209(13) 0.551(4) 0.9995(14) 0.140(13) Uani 0.55 1 d PDU A 1
H50A H 0.4442 0.6039 1.0036 0.168 Uiso 0.55 1 calc PR A 1
H50B H 0.4226 0.5146 1.0245 0.168 Uiso 0.55 1 calc PR A 1
Cl3B Cl 0.4361(11) 0.4489(17) 0.9775(10) 0.269(16) Uani 0.45 1 d PDU B 2
Cl4B Cl 0.3420(12) 0.554(2) 0.9903(9) 0.223(15) Uani 0.45 1 d PDU B 2
C50B C 0.4118(14) 0.549(3) 0.993(3) 0.150(16) Uani 0.45 1 d PDU B 2
H50C H 0.4279 0.5964 0.9764 0.180 Uiso 0.45 1 calc PR B 2
H50D H 0.4232 0.5592 1.0218 0.180 Uiso 0.45 1 calc PR B 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.430(2) . ?
Ag1 C41 2.484(9) . ?
Ag1 C42 2.484(9) . ?
Ag2 P2 2.426(2) . ?
Ag2 C48 2.426(9) . ?
Ag2 C47 2.455(8) . ?
P1 C1 1.831(10) . ?
P1 C13 1.877(10) . ?
P1 C17 1.882(10) . ?
P2 C21 1.817(9) . ?
P2 C37 1.875(10) . ?
P2 C33 1.888(10) . ?
C1 C6 1.403(14) . ?
C1 C2 1.415(15) . ?
C2 C3 1.411(13) . ?
C2 C7 1.486(13) . ?
C3 C4 1.399(15) . ?
C3 H3 0.9500 . ?
C4 C5 1.349(18) . ?
C4 H4 0.9500 . ?
C5 C6 1.390(16) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.395(14) . ?
C7 C12 1.428(13) . ?
C8 C9 1.389(16) . ?
C8 H8 0.9500 . ?
C9 C10 1.370(18) . ?
C9 H9 0.9500 . ?
C10 C11 1.335(16) . ?
C10 H10 0.9500 . ?
C11 C12 1.394(15) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.517(18) . ?
C13 C16 1.526(15) . ?
C13 C15 1.535(17) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C19 1.529(15) . ?
C17 C20 1.529(14) . ?
C17 C18 1.552(17) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.395(13) . ?
C21 C26 1.400(12) . ?
C22 C23 1.392(13) . ?
C22 C27 1.497(12) . ?
C23 C24 1.360(14) . ?
C23 H23 0.9500 . ?
C24 C25 1.410(15) . ?
C24 H24 0.9500 . ?
C25 C26 1.393(14) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 C28 1.406(13) . ?
C27 C32 1.414(13) . ?
C28 C29 1.375(14) . ?
C28 H28 0.9500 . ?
C29 C30 1.414(17) . ?
C29 H29 0.9500 . ?
C30 C31 1.376(17) . ?
C30 H30 0.9500 . ?
C31 C32 1.398(14) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C33 C34 1.510(16) . ?
C33 C35 1.537(17) . ?
C33 C36 1.566(17) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C40 1.495(15) . ?
C37 C38 1.503(17) . ?
C37 C39 1.540(16) . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C42 1.350(13) . ?
C41 C48 1.465(14) . ?
C41 H41 0.9500 . ?
C42 C43 1.438(14) . ?
C42 H42 0.9500 . ?
C43 C44 1.356(15) . ?
C43 H43 0.9500 . ?
C44 C45 1.477(15) . ?
C44 H44 0.9500 . ?
C45 C46 1.330(14) . ?
C45 H45 0.9500 . ?
C46 C47 1.486(15) . ?
C46 H46 0.9500 . ?
C47 C48 1.330(14) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
Sb1 F3 1.788(12) . ?
Sb1 F4 1.799(8) . ?
Sb1 F1 1.828(9) . ?
Sb1 F6 1.858(10) . ?
Sb1 F2 1.887(11) . ?
Sb1 F5 1.897(10) . ?
Sb2 F8 1.818(10) . ?
Sb2 F11 1.839(9) . ?
Sb2 F10 1.847(8) . ?
Sb2 F12 1.858(10) . ?
Sb2 F9 1.869(6) . ?
Sb2 F7 1.871(7) . ?
Cl1 C49 1.689(12) . ?
Cl2 C49 1.694(13) . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
Cl3A C50A 1.71(2) . ?
Cl4A C50A 1.711(19) . ?
C50A H50A 0.9900 . ?
C50A H50B 0.9900 . ?
Cl3B C50B 1.71(2) . ?
Cl4B C50B 1.71(2) . ?
C50B H50C 0.9900 . ?
C50B H50D 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 C41 155.9(2) . . ?
P1 Ag1 C42 130.8(2) . . ?
C41 Ag1 C42 31.5(3) . . ?
P2 Ag2 C48 159.4(3) . . ?
P2 Ag2 C47 131.7(2) . . ?
C48 Ag2 C47 31.6(3) . . ?
C1 P1 C13 107.8(5) . . ?
C1 P1 C17 105.8(5) . . ?
C13 P1 C17 113.2(5) . . ?
C1 P1 Ag1 110.5(3) . . ?
C13 P1 Ag1 108.5(3) . . ?
C17 P1 Ag1 111.0(3) . . ?
C21 P2 C37 107.5(5) . . ?
C21 P2 C33 104.6(4) . . ?
C37 P2 C33 115.2(5) . . ?
C21 P2 Ag2 109.9(3) . . ?
C37 P2 Ag2 109.1(4) . . ?
C33 P2 Ag2 110.3(4) . . ?
C6 C1 C2 117.0(9) . . ?
C6 C1 P1 121.5(9) . . ?
C2 C1 P1 121.2(7) . . ?
C3 C2 C1 119.2(9) . . ?
C3 C2 C7 114.1(9) . . ?
C1 C2 C7 126.7(8) . . ?
C4 C3 C2 121.1(11) . . ?
C4 C3 H3 119.5 . . ?
C2 C3 H3 119.5 . . ?
C5 C4 C3 119.8(11) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
C4 C5 C6 120.1(11) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C5 C6 C1 122.7(12) . . ?
C5 C6 H6 118.6 . . ?
C1 C6 H6 118.6 . . ?
C8 C7 C12 117.0(9) . . ?
C8 C7 C2 120.9(9) . . ?
C12 C7 C2 121.5(9) . . ?
C9 C8 C7 120.8(11) . . ?
C9 C8 H8 119.6 . . ?
C7 C8 H8 119.6 . . ?
C10 C9 C8 120.8(11) . . ?
C10 C9 H9 119.6 . . ?
C8 C9 H9 119.6 . . ?
C11 C10 C9 120.0(10) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C12 121.7(11) . . ?
C10 C11 H11 119.2 . . ?
C12 C11 H11 119.2 . . ?
C11 C12 C7 119.6(10) . . ?
C11 C12 H12 120.2 . . ?
C7 C12 H12 120.2 . . ?
C14 C13 C16 107.4(12) . . ?
C14 C13 C15 109.7(10) . . ?
C16 C13 C15 108.2(11) . . ?
C14 C13 P1 109.2(7) . . ?
C16 C13 P1 117.5(9) . . ?
C15 C13 P1 104.7(8) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C19 C17 C20 109.2(10) . . ?
C19 C17 C18 108.2(9) . . ?
C20 C17 C18 111.0(11) . . ?
C19 C17 P1 108.4(7) . . ?
C20 C17 P1 115.9(7) . . ?
C18 C17 P1 103.8(8) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 C26 118.2(8) . . ?
C22 C21 P2 121.9(6) . . ?
C26 C21 P2 119.9(7) . . ?
C23 C22 C21 118.8(8) . . ?
C23 C22 C27 114.8(8) . . ?
C21 C22 C27 126.3(8) . . ?
C24 C23 C22 124.0(9) . . ?
C24 C23 H23 118.0 . . ?
C22 C23 H23 118.0 . . ?
C23 C24 C25 117.4(9) . . ?
C23 C24 H24 121.3 . . ?
C25 C24 H24 121.3 . . ?
C26 C25 C24 119.8(9) . . ?
C26 C25 H25 120.1 . . ?
C24 C25 H25 120.1 . . ?
C25 C26 C21 121.6(9) . . ?
C25 C26 H26 119.2 . . ?
C21 C26 H26 119.2 . . ?
C28 C27 C32 117.1(8) . . ?
C28 C27 C22 121.4(8) . . ?
C32 C27 C22 120.9(8) . . ?
C29 C28 C27 122.4(10) . . ?
C29 C28 H28 118.8 . . ?
C27 C28 H28 118.8 . . ?
C28 C29 C30 119.6(10) . . ?
C28 C29 H29 120.2 . . ?
C30 C29 H29 120.2 . . ?
C31 C30 C29 119.3(9) . . ?
C31 C30 H30 120.3 . . ?
C29 C30 H30 120.3 . . ?
C30 C31 C32 121.0(10) . . ?
C30 C31 H31 119.5 . . ?
C32 C31 H31 119.5 . . ?
C31 C32 C27 120.6(10) . . ?
C31 C32 H32 119.7 . . ?
C27 C32 H32 119.7 . . ?
C34 C33 C35 111.9(11) . . ?
C34 C33 C36 108.7(10) . . ?
C35 C33 C36 108.4(10) . . ?
C34 C33 P2 107.3(8) . . ?
C35 C33 P2 116.9(8) . . ?
C36 C33 P2 103.1(7) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33 C35 H35A 109.5 . . ?
C33 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C33 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C33 C36 H36A 109.5 . . ?
C33 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C33 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C40 C37 C38 110.3(10) . . ?
C40 C37 C39 106.6(10) . . ?
C38 C37 C39 109.3(11) . . ?
C40 C37 P2 108.0(8) . . ?
C38 C37 P2 108.5(8) . . ?
C39 C37 P2 114.1(8) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C37 C39 H39A 109.5 . . ?
C37 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C37 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C37 C40 H40A 109.5 . . ?
C37 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C37 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C42 C41 C48 126.1(9) . . ?
C42 C41 Ag1 74.3(5) . . ?
C48 C41 Ag1 110.3(6) . . ?
C42 C41 H41 117.0 . . ?
C48 C41 H41 117.0 . . ?
Ag1 C41 H41 85.2 . . ?
C41 C42 C43 126.3(9) . . ?
C41 C42 Ag1 74.2(5) . . ?
C43 C42 Ag1 110.1(6) . . ?
C41 C42 H42 116.8 . . ?
C43 C42 H42 116.8 . . ?
Ag1 C42 H42 85.4 . . ?
C44 C43 C42 127.7(9) . . ?
C44 C43 H43 116.2 . . ?
C42 C43 H43 116.2 . . ?
C43 C44 C45 124.4(9) . . ?
C43 C44 H44 117.8 . . ?
C45 C44 H44 117.8 . . ?
C46 C45 C44 126.1(9) . . ?
C46 C45 H45 116.9 . . ?
C44 C45 H45 116.9 . . ?
C45 C46 C47 127.7(9) . . ?
C45 C46 H46 116.2 . . ?
C47 C46 H46 116.2 . . ?
C48 C47 C46 125.5(9) . . ?
C48 C47 Ag2 73.0(5) . . ?
C46 C47 Ag2 111.7(6) . . ?
C48 C47 H47 117.2 . . ?
C46 C47 H47 117.2 . . ?
Ag2 C47 H47 85.2 . . ?
C47 C48 C41 126.5(9) . . ?
C47 C48 Ag2 75.4(5) . . ?
C41 C48 Ag2 111.3(6) . . ?
C47 C48 H48 116.7 . . ?
C41 C48 H48 116.7 . . ?
Ag2 C48 H48 82.9 . . ?
F3 Sb1 F4 95.4(8) . . ?
F3 Sb1 F1 92.0(8) . . ?
F4 Sb1 F1 95.5(6) . . ?
F3 Sb1 F6 87.3(9) . . ?
F4 Sb1 F6 175.9(7) . . ?
F1 Sb1 F6 87.5(6) . . ?
F3 Sb1 F2 92.7(9) . . ?
F4 Sb1 F2 88.3(7) . . ?
F1 Sb1 F2 173.6(7) . . ?
F6 Sb1 F2 88.4(6) . . ?
F3 Sb1 F5 173.9(9) . . ?
F4 Sb1 F5 90.2(6) . . ?
F1 Sb1 F5 89.8(5) . . ?
F6 Sb1 F5 87.0(7) . . ?
F2 Sb1 F5 85.0(6) . . ?
F8 Sb2 F11 93.5(8) . . ?
F8 Sb2 F10 178.6(7) . . ?
F11 Sb2 F10 87.2(4) . . ?
F8 Sb2 F12 90.9(8) . . ?
F11 Sb2 F12 175.6(6) . . ?
F10 Sb2 F12 88.4(6) . . ?
F8 Sb2 F9 91.2(4) . . ?
F11 Sb2 F9 91.0(4) . . ?
F10 Sb2 F9 90.0(3) . . ?
F12 Sb2 F9 89.4(4) . . ?
F8 Sb2 F7 89.5(4) . . ?
F11 Sb2 F7 90.1(4) . . ?
F10 Sb2 F7 89.3(4) . . ?
F12 Sb2 F7 89.4(4) . . ?
F9 Sb2 F7 178.6(4) . . ?
Cl1 C49 Cl2 119.0(9) . . ?
Cl1 C49 H49A 107.6 . . ?
Cl2 C49 H49A 107.6 . . ?
Cl1 C49 H49B 107.6 . . ?
Cl2 C49 H49B 107.6 . . ?
H49A C49 H49B 107.0 . . ?
Cl3A C50A Cl4A 109.4(15) . . ?
Cl3A C50A H50A 109.8 . . ?
Cl4A C50A H50A 109.8 . . ?
Cl3A C50A H50B 109.8 . . ?
Cl4A C50A H50B 109.8 . . ?
H50A C50A H50B 108.2 . . ?
Cl3B C50B Cl4B 111.7(18) . . ?
Cl3B C50B H50C 109.3 . . ?
Cl4B C50B H50C 109.3 . . ?
Cl3B C50B H50D 109.3 . . ?
Cl4B C50B H50D 109.3 . . ?
H50C C50B H50D 107.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C41 Ag1 P1 C1 -123.1(6) . . . . ?
C42 Ag1 P1 C1 -157.2(4) . . . . ?
C41 Ag1 P1 C13 -5.1(7) . . . . ?
C42 Ag1 P1 C13 -39.2(5) . . . . ?
C41 Ag1 P1 C17 119.9(7) . . . . ?
C42 Ag1 P1 C17 85.8(5) . . . . ?
C48 Ag2 P2 C21 -126.5(7) . . . . ?
C47 Ag2 P2 C21 -156.0(4) . . . . ?
C48 Ag2 P2 C37 -8.9(8) . . . . ?
C47 Ag2 P2 C37 -38.3(5) . . . . ?
C48 Ag2 P2 C33 118.6(8) . . . . ?
C47 Ag2 P2 C33 89.2(5) . . . . ?
C13 P1 C1 C6 58.5(10) . . . . ?
C17 P1 C1 C6 -62.8(10) . . . . ?
Ag1 P1 C1 C6 177.0(8) . . . . ?
C13 P1 C1 C2 -128.1(8) . . . . ?
C17 P1 C1 C2 110.6(8) . . . . ?
Ag1 P1 C1 C2 -9.7(9) . . . . ?
C6 C1 C2 C3 -0.2(14) . . . . ?
P1 C1 C2 C3 -173.9(7) . . . . ?
C6 C1 C2 C7 179.6(10) . . . . ?
P1 C1 C2 C7 6.0(14) . . . . ?
C1 C2 C3 C4 -0.6(15) . . . . ?
C7 C2 C3 C4 179.5(10) . . . . ?
C2 C3 C4 C5 -0.5(18) . . . . ?
C3 C4 C5 C6 3(2) . . . . ?
C4 C5 C6 C1 -4(2) . . . . ?
C2 C1 C6 C5 2.3(17) . . . . ?
P1 C1 C6 C5 176.0(10) . . . . ?
C3 C2 C7 C8 64.1(12) . . . . ?
C1 C2 C7 C8 -115.8(11) . . . . ?
C3 C2 C7 C12 -106.0(11) . . . . ?
C1 C2 C7 C12 74.1(13) . . . . ?
C12 C7 C8 C9 -0.3(14) . . . . ?
C2 C7 C8 C9 -170.8(9) . . . . ?
C7 C8 C9 C10 3.0(16) . . . . ?
C8 C9 C10 C11 -4.7(16) . . . . ?
C9 C10 C11 C12 3.7(15) . . . . ?
C10 C11 C12 C7 -1.0(14) . . . . ?
C8 C7 C12 C11 -0.7(13) . . . . ?
C2 C7 C12 C11 169.7(9) . . . . ?
C1 P1 C13 C14 165.7(8) . . . . ?
C17 P1 C13 C14 -77.7(9) . . . . ?
Ag1 P1 C13 C14 46.0(8) . . . . ?
C1 P1 C13 C16 -71.7(12) . . . . ?
C17 P1 C13 C16 44.9(13) . . . . ?
Ag1 P1 C13 C16 168.6(11) . . . . ?
C1 P1 C13 C15 48.3(9) . . . . ?
C17 P1 C13 C15 164.9(8) . . . . ?
Ag1 P1 C13 C15 -71.4(8) . . . . ?
C1 P1 C17 C19 -175.9(7) . . . . ?
C13 P1 C17 C19 66.3(8) . . . . ?
Ag1 P1 C17 C19 -56.0(8) . . . . ?
C1 P1 C17 C20 60.9(11) . . . . ?
C13 P1 C17 C20 -56.9(11) . . . . ?
Ag1 P1 C17 C20 -179.2(9) . . . . ?
C1 P1 C17 C18 -61.1(8) . . . . ?
C13 P1 C17 C18 -178.9(7) . . . . ?
Ag1 P1 C17 C18 58.8(8) . . . . ?
C37 P2 C21 C22 -127.7(8) . . . . ?
C33 P2 C21 C22 109.4(8) . . . . ?
Ag2 P2 C21 C22 -9.1(8) . . . . ?
C37 P2 C21 C26 55.0(9) . . . . ?
C33 P2 C21 C26 -67.9(9) . . . . ?
Ag2 P2 C21 C26 173.6(7) . . . . ?
C26 C21 C22 C23 1.4(13) . . . . ?
P2 C21 C22 C23 -176.0(7) . . . . ?
C26 C21 C22 C27 179.2(8) . . . . ?
P2 C21 C22 C27 1.8(12) . . . . ?
C21 C22 C23 C24 -2.2(14) . . . . ?
C27 C22 C23 C24 179.8(9) . . . . ?
C22 C23 C24 C25 2.0(15) . . . . ?
C23 C24 C25 C26 -1.0(15) . . . . ?
C24 C25 C26 C21 0.3(15) . . . . ?
C22 C21 C26 C25 -0.5(14) . . . . ?
P2 C21 C26 C25 176.9(8) . . . . ?
C23 C22 C27 C28 73.8(12) . . . . ?
C21 C22 C27 C28 -104.1(11) . . . . ?
C23 C22 C27 C32 -96.7(10) . . . . ?
C21 C22 C27 C32 85.4(12) . . . . ?
C32 C27 C28 C29 2.4(15) . . . . ?
C22 C27 C28 C29 -168.5(10) . . . . ?
C27 C28 C29 C30 -1.7(17) . . . . ?
C28 C29 C30 C31 -0.3(16) . . . . ?
C29 C30 C31 C32 1.5(16) . . . . ?
C30 C31 C32 C27 -0.8(15) . . . . ?
C28 C27 C32 C31 -1.1(14) . . . . ?
C22 C27 C32 C31 169.8(9) . . . . ?
C21 P2 C33 C34 -178.9(8) . . . . ?
C37 P2 C33 C34 63.3(10) . . . . ?
Ag2 P2 C33 C34 -60.7(9) . . . . ?
C21 P2 C33 C35 54.5(11) . . . . ?
C37 P2 C33 C35 -63.3(11) . . . . ?
Ag2 P2 C33 C35 172.6(9) . . . . ?
C21 P2 C33 C36 -64.2(8) . . . . ?
C37 P2 C33 C36 178.0(7) . . . . ?
Ag2 P2 C33 C36 54.0(8) . . . . ?
C21 P2 C37 C40 162.0(8) . . . . ?
C33 P2 C37 C40 -81.8(9) . . . . ?
Ag2 P2 C37 C40 42.9(9) . . . . ?
C21 P2 C37 C38 42.5(9) . . . . ?
C33 P2 C37 C38 158.6(8) . . . . ?
Ag2 P2 C37 C38 -76.7(9) . . . . ?
C21 P2 C37 C39 -79.6(9) . . . . ?
C33 P2 C37 C39 36.6(10) . . . . ?
Ag2 P2 C37 C39 161.3(8) . . . . ?
P1 Ag1 C41 C42 -54.3(9) . . . . ?
P1 Ag1 C41 C48 -177.5(4) . . . . ?
C42 Ag1 C41 C48 -123.3(9) . . . . ?
C48 C41 C42 C43 0.3(15) . . . . ?
Ag1 C41 C42 C43 -103.6(9) . . . . ?
C48 C41 C42 Ag1 103.9(9) . . . . ?
P1 Ag1 C42 C41 154.0(5) . . . . ?
P1 Ag1 C42 C43 -82.5(7) . . . . ?
C41 Ag1 C42 C43 123.5(9) . . . . ?
C41 C42 C43 C44 58.5(15) . . . . ?
Ag1 C42 C43 C44 -26.3(13) . . . . ?
C42 C43 C44 C45 -1.6(17) . . . . ?
C43 C44 C45 C46 -56.8(15) . . . . ?
C44 C45 C46 C47 0.9(17) . . . . ?
C45 C46 C47 C48 56.4(15) . . . . ?
C45 C46 C47 Ag2 -27.7(13) . . . . ?
P2 Ag2 C47 C48 160.7(5) . . . . ?
P2 Ag2 C47 C46 -77.1(7) . . . . ?
C48 Ag2 C47 C46 122.2(10) . . . . ?
C46 C47 C48 C41 1.1(15) . . . . ?
Ag2 C47 C48 C41 105.9(9) . . . . ?
C46 C47 C48 Ag2 -104.8(9) . . . . ?
C42 C41 C48 C47 -57.8(14) . . . . ?
Ag1 C41 C48 C47 27.2(11) . . . . ?
C42 C41 C48 Ag2 29.5(12) . . . . ?
Ag1 C41 C48 Ag2 114.4(5) . . . . ?
P2 Ag2 C48 C47 -44.5(10) . . . . ?
P2 Ag2 C48 C41 -168.4(5) . . . . ?
C47 Ag2 C48 C41 -124.0(10) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         3.825
_refine_diff_density_min         -2.716
_refine_diff_density_rms         0.251
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5
_database_code_depnum_ccdc_archive 'CCDC 1443119'
_audit_update_record             
;
2015-12-17 deposited with the CCDC.
2016-02-26 downloaded from the CCDC.
;


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C20 H29 Ag O P, F6 Sb'
_chemical_formula_sum            'C20 H29 Ag F6 O P Sb'
_chemical_formula_weight         660.02

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   7.6971(13)
_cell_length_b                   22.120(3)
_cell_length_c                   14.649(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 103.508(4)
_cell_angle_gamma                90.00
_cell_volume                     2425.1(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    5288
_cell_measurement_theta_min      2.72
_cell_measurement_theta_max      28.71

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.25
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.808
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1296
_exptl_absorpt_coefficient_mu    2.042
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4283
_exptl_absorpt_correction_T_max  0.6293
_exptl_absorpt_process_details   
; 
program SADABS, Bruker (2001). 
;

_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
; 
 Bruker-Nonius X8kappa APEX II CCD area detector 
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
_diffrn_detector_area_resol_mean 8.26
_diffrn_standards_decay_%        0
_diffrn_reflns_number            22569
_diffrn_reflns_av_R_equivalents  0.0401
_diffrn_reflns_av_unetI/netI     0.0343
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         1.70
_diffrn_reflns_theta_max         25.25
_reflns_number_total             4369
_reflns_number_gt                3889
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 Software Suite (Bruker, 2007)'
_computing_cell_refinement       'APEX2 Software Suite (Bruker, 2007)'
_computing_data_reduction        'APEX2 Software Suite (Bruker, 2007)'
_computing_structure_solution    'SIR2002 (Burla et al., 2003)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL and publCIF (Westrip, 2010)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0945P)²+6.9162P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4369
_refine_ls_number_parameters     277
_refine_ls_number_restraints     36
_refine_ls_R_factor_all          0.0532
_refine_ls_R_factor_gt           0.0480
_refine_ls_wR_factor_ref         0.1435
_refine_ls_wR_factor_gt          0.1388
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_restrained_S_all      1.107
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.48354(7) 0.07340(2) 0.68246(3) 0.04593(19) Uani 1 1 d . . .
P1 P 0.67563(17) 0.15708(6) 0.72732(9) 0.0289(3) Uani 1 1 d . . .
O1 O 0.3058(9) 0.0054(3) 0.6078(4) 0.086(2) Uani 1 1 d . . .
H1O1 H 0.2709 0.0143 0.5500 0.103 Uiso 1 1 d R . .
H2O1 H 0.2490 -0.0259 0.6177 0.103 Uiso 1 1 d R . .
C1 C 0.8223(7) 0.1475(2) 0.8445(4) 0.0300(10) Uani 1 1 d . . .
C2 C 0.7908(8) 0.1037(2) 0.9071(4) 0.0336(11) Uani 1 1 d . . .
C3 C 0.9091(10) 0.0996(3) 0.9955(5) 0.0518(16) Uani 1 1 d . . .
H3 H 0.8881 0.0703 1.0391 0.062 Uiso 1 1 calc R . .
C4 C 1.0558(9) 0.1373(4) 1.0205(5) 0.0539(17) Uani 1 1 d . . .
H4 H 1.1355 0.1334 1.0804 0.065 Uiso 1 1 calc R . .
C5 C 1.0857(8) 0.1797(3) 0.9593(4) 0.0445(14) Uani 1 1 d . . .
H5 H 1.1857 0.2060 0.9767 0.053 Uiso 1 1 calc R . .
C6 C 0.9710(7) 0.1850(3) 0.8716(4) 0.0362(12) Uani 1 1 d . . .
H6 H 0.9941 0.2146 0.8290 0.043 Uiso 1 1 calc R . .
C7 C 0.6382(8) 0.0599(3) 0.8873(4) 0.0374(12) Uani 1 1 d . . .
C8 C 0.4799(9) 0.0728(3) 0.9122(5) 0.0506(16) Uani 1 1 d . . .
H8 H 0.4674 0.1094 0.9439 0.061 Uiso 1 1 calc R . .
C9 C 0.3373(10) 0.0315(4) 0.8905(6) 0.063(2) Uani 1 1 d . . .
H9 H 0.2269 0.0410 0.9056 0.076 Uiso 1 1 calc R . .
C10 C 0.3572(12) -0.0226(4) 0.8473(5) 0.066(2) Uani 1 1 d . . .
H10 H 0.2606 -0.0503 0.8323 0.079 Uiso 1 1 calc R . .
C11 C 0.5170(13) -0.0360(4) 0.8262(5) 0.067(2) Uani 1 1 d . . .
H11 H 0.5322 -0.0737 0.7980 0.080 Uiso 1 1 calc R . .
C12 C 0.6562(10) 0.0050(3) 0.8458(5) 0.0521(16) Uani 1 1 d . . .
H12 H 0.7662 -0.0048 0.8304 0.063 Uiso 1 1 calc R . .
C13 C 0.5507(7) 0.2288(3) 0.7352(4) 0.0375(12) Uani 1 1 d . . .
C14 C 0.4321(10) 0.2430(4) 0.6376(5) 0.0581(18) Uani 1 1 d . . .
H14A H 0.3533 0.2771 0.6423 0.087 Uiso 1 1 calc R . .
H14B H 0.3597 0.2074 0.6136 0.087 Uiso 1 1 calc R . .
H14C H 0.5076 0.2535 0.5946 0.087 Uiso 1 1 calc R . .
C15 C 0.6666(9) 0.2835(3) 0.7725(5) 0.0496(15) Uani 1 1 d . . .
H15A H 0.7397 0.2942 0.7284 0.074 Uiso 1 1 calc R . .
H15B H 0.7447 0.2736 0.8337 0.074 Uiso 1 1 calc R . .
H15C H 0.5899 0.3177 0.7794 0.074 Uiso 1 1 calc R . .
C16 C 0.4308(9) 0.2154(3) 0.8031(6) 0.0564(17) Uani 1 1 d . . .
H16A H 0.3575 0.2510 0.8078 0.085 Uiso 1 1 calc R . .
H16B H 0.5054 0.2057 0.8652 0.085 Uiso 1 1 calc R . .
H16C H 0.3529 0.1810 0.7796 0.085 Uiso 1 1 calc R . .
C17 C 0.8214(8) 0.1606(3) 0.6407(4) 0.0388(12) Uani 1 1 d . . .
C18 C 0.9090(10) 0.2212(3) 0.6294(5) 0.0510(16) Uani 1 1 d . . .
H18A H 0.9731 0.2360 0.6911 0.077 Uiso 1 1 calc R . .
H18B H 0.8169 0.2505 0.6006 0.077 Uiso 1 1 calc R . .
H18C H 0.9933 0.2160 0.5891 0.077 Uiso 1 1 calc R . .
C19 C 0.7041(11) 0.1424(4) 0.5440(5) 0.0604(19) Uani 1 1 d . . .
H19A H 0.7763 0.1431 0.4970 0.091 Uiso 1 1 calc R . .
H19B H 0.6048 0.1711 0.5257 0.091 Uiso 1 1 calc R . .
H19C H 0.6566 0.1016 0.5478 0.091 Uiso 1 1 calc R . .
C20 C 0.9657(10) 0.1114(3) 0.6701(5) 0.0522(16) Uani 1 1 d . . .
H20A H 1.0320 0.1068 0.6210 0.078 Uiso 1 1 calc R . .
H20B H 0.9086 0.0730 0.6790 0.078 Uiso 1 1 calc R . .
H20C H 1.0481 0.1233 0.7290 0.078 Uiso 1 1 calc R . .
Sb1 Sb 0.14468(6) 0.102625(17) 0.36315(3) 0.04227(18) Uani 1 1 d . . .
F1 F 0.1952(12) 0.0263(4) 0.4085(7) 0.143(3) Uani 1 1 d U . .
F2 F 0.0988(11) 0.1801(4) 0.3176(7) 0.141(3) Uani 1 1 d U . .
F3 F -0.0950(8) 0.0951(3) 0.3674(5) 0.0895(16) Uani 1 1 d U . .
F4 F 0.2103(11) 0.1328(4) 0.4822(5) 0.132(3) Uani 1 1 d U . .
F5 F 0.3798(8) 0.1116(3) 0.3542(5) 0.0913(16) Uani 1 1 d U . .
F6 F 0.0750(9) 0.0687(4) 0.2452(5) 0.114(2) Uani 1 1 d U . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.152(5) . ?
Ag1 P1 2.3643(13) . ?
P1 C1 1.834(5) . ?
P1 C13 1.873(6) . ?
P1 C17 1.882(6) . ?
O1 H1O1 0.8488 . ?
O1 H2O1 0.8488 . ?
C1 C2 1.393(8) . ?
C1 C6 1.394(7) . ?
C2 C3 1.401(9) . ?
C2 C7 1.499(8) . ?
C3 C4 1.383(10) . ?
C3 H3 0.9500 . ?
C4 C5 1.354(10) . ?
C4 H4 0.9500 . ?
C5 C6 1.384(8) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.379(9) . ?
C7 C8 1.381(9) . ?
C8 C9 1.405(10) . ?
C8 H8 0.9500 . ?
C9 C10 1.379(13) . ?
C9 H9 0.9500 . ?
C10 C11 1.369(12) . ?
C10 H10 0.9500 . ?
C11 C12 1.382(10) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C15 1.525(8) . ?
C13 C16 1.535(9) . ?
C13 C14 1.539(9) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.527(9) . ?
C17 C20 1.542(9) . ?
C17 C19 1.545(8) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
Sb1 F1 1.822(7) . ?
Sb1 F4 1.825(7) . ?
Sb1 F2 1.844(8) . ?
Sb1 F6 1.845(6) . ?
Sb1 F5 1.856(6) . ?
Sb1 F3 1.868(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 P1 166.03(16) . . ?
C1 P1 C13 104.6(2) . . ?
C1 P1 C17 107.6(2) . . ?
C13 P1 C17 113.7(3) . . ?
C1 P1 Ag1 112.22(18) . . ?
C13 P1 Ag1 112.57(18) . . ?
C17 P1 Ag1 106.12(19) . . ?
Ag1 O1 H1O1 111.1 . . ?
Ag1 O1 H2O1 140.8 . . ?
H1O1 O1 H2O1 107.7 . . ?
C2 C1 C6 118.9(5) . . ?
C2 C1 P1 122.2(4) . . ?
C6 C1 P1 118.9(4) . . ?
C1 C2 C3 118.6(5) . . ?
C1 C2 C7 124.9(5) . . ?
C3 C2 C7 116.6(5) . . ?
C4 C3 C2 121.3(6) . . ?
C4 C3 H3 119.4 . . ?
C2 C3 H3 119.4 . . ?
C5 C4 C3 119.8(6) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
C4 C5 C6 120.2(6) . . ?
C4 C5 H5 119.9 . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C1 121.2(5) . . ?
C5 C6 H6 119.4 . . ?
C1 C6 H6 119.4 . . ?
C12 C7 C8 119.0(6) . . ?
C12 C7 C2 120.0(6) . . ?
C8 C7 C2 121.0(6) . . ?
C7 C8 C9 119.8(7) . . ?
C7 C8 H8 120.1 . . ?
C9 C8 H8 120.1 . . ?
C10 C9 C8 120.2(7) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C11 C10 C9 119.6(7) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C10 C11 C12 120.3(7) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C7 C12 C11 121.1(7) . . ?
C7 C12 H12 119.5 . . ?
C11 C12 H12 119.5 . . ?
C15 C13 C16 108.1(6) . . ?
C15 C13 C14 110.0(5) . . ?
C16 C13 C14 109.0(5) . . ?
C15 C13 P1 115.3(4) . . ?
C16 C13 P1 105.7(4) . . ?
C14 C13 P1 108.5(4) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C20 110.0(5) . . ?
C18 C17 C19 107.9(5) . . ?
C20 C17 C19 107.5(6) . . ?
C18 C17 P1 117.2(4) . . ?
C20 C17 P1 106.6(4) . . ?
C19 C17 P1 107.1(4) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
F1 Sb1 F4 90.1(4) . . ?
F1 Sb1 F2 178.8(4) . . ?
F4 Sb1 F2 89.6(4) . . ?
F1 Sb1 F6 87.4(4) . . ?
F4 Sb1 F6 177.2(4) . . ?
F2 Sb1 F6 92.9(4) . . ?
F1 Sb1 F5 89.8(4) . . ?
F4 Sb1 F5 88.4(3) . . ?
F2 Sb1 F5 89.0(3) . . ?
F6 Sb1 F5 93.0(3) . . ?
F1 Sb1 F3 91.9(4) . . ?
F4 Sb1 F3 93.2(3) . . ?
F2 Sb1 F3 89.3(3) . . ?
F6 Sb1 F3 85.5(3) . . ?
F5 Sb1 F3 177.7(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 Ag1 P1 C1 -158.3(9) . . . . ?
O1 Ag1 P1 C13 84.0(9) . . . . ?
O1 Ag1 P1 C17 -41.0(9) . . . . ?
C13 P1 C1 C2 107.3(5) . . . . ?
C17 P1 C1 C2 -131.4(5) . . . . ?
Ag1 P1 C1 C2 -15.0(5) . . . . ?
C13 P1 C1 C6 -73.3(5) . . . . ?
C17 P1 C1 C6 48.0(5) . . . . ?
Ag1 P1 C1 C6 164.4(4) . . . . ?
C6 C1 C2 C3 0.8(8) . . . . ?
P1 C1 C2 C3 -179.8(5) . . . . ?
C6 C1 C2 C7 -179.1(5) . . . . ?
P1 C1 C2 C7 0.3(8) . . . . ?
C1 C2 C3 C4 -0.9(10) . . . . ?
C7 C2 C3 C4 179.0(7) . . . . ?
C2 C3 C4 C5 0.9(12) . . . . ?
C3 C4 C5 C6 -0.8(11) . . . . ?
C4 C5 C6 C1 0.7(10) . . . . ?
C2 C1 C6 C5 -0.7(8) . . . . ?
P1 C1 C6 C5 179.8(5) . . . . ?
C1 C2 C7 C12 88.8(7) . . . . ?
C3 C2 C7 C12 -91.1(7) . . . . ?
C1 C2 C7 C8 -92.9(7) . . . . ?
C3 C2 C7 C8 87.2(8) . . . . ?
C12 C7 C8 C9 -3.4(10) . . . . ?
C2 C7 C8 C9 178.3(6) . . . . ?
C7 C8 C9 C10 2.2(11) . . . . ?
C8 C9 C10 C11 0.4(11) . . . . ?
C9 C10 C11 C12 -1.7(12) . . . . ?
C8 C7 C12 C11 2.1(10) . . . . ?
C2 C7 C12 C11 -179.5(6) . . . . ?
C10 C11 C12 C7 0.4(12) . . . . ?
C1 P1 C13 C15 52.5(5) . . . . ?
C17 P1 C13 C15 -64.6(5) . . . . ?
Ag1 P1 C13 C15 174.6(4) . . . . ?
C1 P1 C13 C16 -66.9(5) . . . . ?
C17 P1 C13 C16 175.9(4) . . . . ?
Ag1 P1 C13 C16 55.2(4) . . . . ?
C1 P1 C13 C14 176.3(5) . . . . ?
C17 P1 C13 C14 59.2(5) . . . . ?
Ag1 P1 C13 C14 -61.6(5) . . . . ?
C1 P1 C17 C18 -81.4(5) . . . . ?
C13 P1 C17 C18 34.0(6) . . . . ?
Ag1 P1 C17 C18 158.3(4) . . . . ?
C1 P1 C17 C20 42.3(5) . . . . ?
C13 P1 C17 C20 157.7(4) . . . . ?
Ag1 P1 C17 C20 -78.0(4) . . . . ?
C1 P1 C17 C19 157.2(5) . . . . ?
C13 P1 C17 C19 -87.4(5) . . . . ?
Ag1 P1 C17 C19 36.9(5) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1 H1O1 F1 0.85 2.04 2.880(11) 173.7 .
O1 H2O1 F3 0.85 1.98 2.826(7) 174.2 3_556

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        25.25
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         1.273
_refine_diff_density_min         -1.277
_refine_diff_density_rms         0.146


###END


