# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 962684'
_audit_update_record             
;
2016-04-15 deposited with the CCDC.
2016-04-19 downloaded from the CCDC.
;
_audit_creation_date             2013-09-12
_audit_creation_method           
;
  Olex2 1.2
  (compiled Dec  5 2012 16:20:19, GUI svn.r4385)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C98 H72 Dy2 N4 O12, 2(C H Cl3)'
_chemical_formula_sum            'C100 H74 Cl6 Dy2 N4 O12'
_chemical_formula_weight         2061.33
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C40 H27 N3 Dy1'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x, -y-1/2, z-1/2'

_cell_length_a                   20.8489(3)
_cell_length_b                   19.5533(3)
_cell_length_c                   22.3388(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 98.1311(16)
_cell_angle_gamma                90.00
_cell_volume                     9015.2(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    29911
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.3540
_cell_measurement_theta_min      2.7840
_exptl_absorpt_coefficient_mu    1.887
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.86124
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_diffrn    1.519
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4128
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0294
_diffrn_reflns_av_unetI/netI     0.0323
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            68071
_diffrn_reflns_theta_full        28.52
_diffrn_reflns_theta_max         28.52
_diffrn_reflns_theta_min         2.78
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.3914
_diffrn_measured_fraction_theta_full 0.9968
_diffrn_measured_fraction_theta_max 0.8693
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -77.00  -13.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -        8.7950    0.0000  -30.0000 64

#__ type_ start__ end____ width___ exp.time_
  2 omega   38.00   88.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -        8.7950    0.0000  -30.0000 50

#__ type_ start__ end____ width___ exp.time_
  3 omega  -24.00   35.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -        8.7950  -38.0000    0.0000 59

#__ type_ start__ end____ width___ exp.time_
  4 omega    0.00   26.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -       -9.6544  -99.0000   90.0000 26

#__ type_ start__ end____ width___ exp.time_
  5 omega   31.00   66.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -       -9.6544   38.0000    0.0000 35

#__ type_ start__ end____ width___ exp.time_
  6 omega  -39.00  -12.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -       -9.6544  -57.0000   60.0000 27

#__ type_ start__ end____ width___ exp.time_
  7 omega  -35.00   10.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -       -9.6544   38.0000    0.0000 45
;
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0068261000
_diffrn_orient_matrix_UB_12      -0.0081827000
_diffrn_orient_matrix_UB_13      -0.0311817000
_diffrn_orient_matrix_UB_21      0.0324678000
_diffrn_orient_matrix_UB_22      0.0078217000
_diffrn_orient_matrix_UB_23      -0.0035981000
_diffrn_orient_matrix_UB_31      0.0089812000
_diffrn_orient_matrix_UB_32      -0.0344564000
_diffrn_orient_matrix_UB_33      0.0065896000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                15942
_reflns_number_total             19915
_reflns_odcompleteness_completeness 99.68
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     24.97
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material  
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution    'SUPERFLIP, J. Appl. Cryst. (2007) 40, 786-790'
_refine_diff_density_max         1.191
_refine_diff_density_min         -1.102
_refine_diff_density_rms         0.089
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1117
_refine_ls_number_reflns         19915
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0461
_refine_ls_R_factor_gt           0.0302
_refine_ls_restrained_S_all      1.069
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0225P)²+12.9034P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0637
_refine_ls_wR_factor_ref         0.0727
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  H94 of C94, H95 of C95, H96 of C96, H65 of C65, H64 of C64, H61 of C61, H60
  of C60, H58 of C58, H57 of C57, H56 of C56, H53 of C53, H52 of C52, H51 of
  C51, H50 of C50, H49 of C49, H48 of C48, H67 of C67, H68 of C68, H66 of C66,
  H89 of C89, H88 of C88, H87 of C87, H85 of C85, H83 of C83, H82 of C82, H81
  of C81, H79 of C79, H78 of C78, H77 of C77, H76 of C76, H75 of C75, H74 of
  C74, H73 of C73, H72 of C72, H90 of C90, H91 of C91, H92 of C92, H93 of C93,
  H1 of C1, H2 of C2, H3 of C3, H98 of C98, H102 of C102, H99 of C99, H103 of
  C103, H4 of C4, H7 of C7, H8 of C8, H9 of C9, H10 of C10, H12 of C12, H13 of
  C13, H14 of C14, H15 of C15, H18 of C18, H19 of C19, H21 of C21, H22 of C22,
  H23 of C23, H26 of C26, H27 of C27, H29 of C29, H30 of C30, H35 of C35, H36
  of C36, H38 of C38, H39 of C39, H41 of C41, H42 of C42, H44 of C44, H104 of
  C104, H106 of C106, H110 of C110, H111 of C111
2.a Ternary CH refined with riding coordinates:
 C13(H13), C29(H29)
2.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C7(H7), C8(H8), C9(H9), C10(H10), C12(H12),
 C14(H14), C15(H15), C18(H18), C19(H19), C21(H21), C22(H22), C23(H23), C26(H26),
  C27(H27), C30(H30), C35(H35), C36(H36), C38(H38), C39(H39), C41(H41),
 C42(H42), C44(H44), C48(H48), C49(H49), C50(H50), C51(H51), C52(H52), C53(H53),
  C56(H56), C57(H57), C58(H58), C60(H60), C61(H61), C64(H64), C65(H65),
 C66(H66), C67(H67), C68(H68), C72(H72), C73(H73), C74(H74), C75(H75), C76(H76),
  C77(H77), C78(H78), C79(H79), C81(H81), C82(H82), C83(H83), C85(H85),
 C87(H87), C88(H88), C89(H89), C90(H90), C91(H91), C92(H92), C93(H93), C94(H94),
  C95(H95), C96(H96), C98(H98), C99(H99), C102(H102), C103(H103), C104(H104),
 C106(H106), C110(H110), C111(H111)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.871734(6) 0.655921(6) 0.246652(6) 0.01732(4) Uani 1 1 d . . .
Dy2 Dy 0.630093(6) 0.426478(6) 0.254738(6) 0.02048(4) Uani 1 1 d . . .
Cl2 Cl 0.42730(7) 0.24409(7) 0.66113(7) 0.0852(4) Uani 1 1 d . . .
Cl4 Cl 0.12673(5) 0.76833(5) 0.32905(6) 0.0673(3) Uani 1 1 d . . .
Cl6 Cl 0.01706(5) 0.85731(5) 0.32202(5) 0.0601(3) Uani 1 1 d . . .
Cl3 Cl 0.43017(6) 0.12928(6) 0.58228(5) 0.0643(3) Uani 1 1 d . . .
Cl5 Cl 0.04638(7) 0.76517(6) 0.42316(6) 0.0763(4) Uani 1 1 d . . .
Cl1 Cl 0.54673(8) 0.20557(9) 0.61921(9) 0.1068(6) Uani 1 1 d . . .
O9 O 0.54762(9) 0.35282(10) 0.26925(10) 0.0255(4) Uani 1 1 d . . .
O7 O 0.56684(10) 0.49136(10) 0.31134(10) 0.0303(5) Uani 1 1 d . . .
O11 O 0.55140(9) 0.46894(10) 0.18187(9) 0.0267(5) Uani 1 1 d . . .
O5 O 0.83385(10) 0.64086(10) 0.33993(9) 0.0271(5) Uani 1 1 d . . .
O6 O 0.93895(9) 0.58804(10) 0.19970(9) 0.0239(4) Uani 1 1 d . . .
O1 O 0.83515(9) 0.66342(10) 0.14497(9) 0.0249(4) Uani 1 1 d . . .
O12 O 0.67153(10) 0.42846(10) 0.16464(10) 0.0280(5) Uani 1 1 d . . .
O3 O 0.95903(9) 0.63744(10) 0.31910(9) 0.0264(4) Uani 1 1 d . . .
O2 O 0.94323(9) 0.73639(10) 0.21867(10) 0.0256(4) Uani 1 1 d . . .
O10 O 0.67280(10) 0.31703(10) 0.25362(10) 0.0271(5) Uani 1 1 d . . .
O8 O 0.66936(10) 0.41005(10) 0.35487(9) 0.0278(5) Uani 1 1 d . . .
N3 N 0.66581(11) 0.55186(12) 0.24788(11) 0.0223(5) Uani 1 1 d . . .
N1 N 0.83737(11) 0.52921(11) 0.25514(11) 0.0215(5) Uani 1 1 d . . .
N2 N 0.74881(11) 0.62978(11) 0.23148(11) 0.0201(5) Uani 1 1 d . . .
N4 N 0.75379(11) 0.45165(11) 0.27087(11) 0.0230(5) Uani 1 1 d . . .
C1 C 1.01613(17) 0.50381(17) 0.08540(15) 0.0379(8) Uani 1 1 d . . .
H1 H 0.9867 0.5119 0.0508 0.046 Uiso 1 1 calc R . .
C2 C 0.42186(16) 0.59533(16) 0.02818(15) 0.0335(7) Uani 1 1 d . . .
H2 H 0.4152 0.6134 -0.0107 0.040 Uiso 1 1 calc R . .
C3 C 0.85425(17) 0.68901(15) -0.01147(14) 0.0338(7) Uani 1 1 d . . .
H3 H 0.8986 0.6816 -0.0096 0.041 Uiso 1 1 calc R . .
C4 C 0.91636(15) 0.61217(15) 0.09604(13) 0.0276(7) Uani 1 1 d . . .
H4 H 0.9314 0.6071 0.0590 0.033 Uiso 1 1 calc R . .
C5 C 0.63785(14) 0.40212(15) 0.39913(14) 0.0273(7) Uani 1 1 d . . .
C6 C 0.82958(13) 0.81794(13) 0.22830(13) 0.0207(6) Uani 1 1 d . . .
C7 C 0.8186(2) 0.71158(16) -0.06528(15) 0.0422(9) Uani 1 1 d . . .
H7 H 0.8389 0.7192 -0.0992 0.051 Uiso 1 1 calc R . .
C8 C 0.63975(14) 0.66733(15) 0.22367(14) 0.0264(6) Uani 1 1 d . . .
H8 H 0.6092 0.7021 0.2166 0.032 Uiso 1 1 calc R . .
C9 C 0.39030(15) 0.32764(16) 0.35800(15) 0.0319(7) Uani 1 1 d . . .
H9 H 0.3558 0.3580 0.3505 0.038 Uiso 1 1 calc R . .
C10 C 0.63397(17) 0.31097(16) 0.47858(15) 0.0342(7) Uani 1 1 d . . .
H10 H 0.5890 0.3108 0.4703 0.041 Uiso 1 1 calc R . .
C11 C 0.48792(15) 0.51670(16) 0.37359(15) 0.0313(7) Uani 1 1 d . . .
C12 C 0.86219(15) 0.41254(15) 0.27792(15) 0.0309(7) Uani 1 1 d . . .
H12 H 0.8924 0.3773 0.2844 0.037 Uiso 1 1 calc R . .
C13 C 0.04705(17) 0.77687(18) 0.34550(18) 0.0434(9) Uani 1 1 d . . .
H13 H 0.0199 0.7417 0.3233 0.052 Uiso 1 1 calc R . .
C14 C 0.62221(14) 0.60189(14) 0.23792(14) 0.0257(6) Uani 1 1 d . . .
H14 H 0.5790 0.5925 0.2406 0.031 Uiso 1 1 calc R . .
C15 C 0.87887(13) 0.83443(14) 0.19508(13) 0.0234(6) Uani 1 1 d . . .
H15 H 0.8756 0.8753 0.1736 0.028 Uiso 1 1 calc R . .
C16 C 0.49135(14) 0.53791(14) 0.10792(14) 0.0250(6) Uani 1 1 d . . .
C17 C 0.98349(13) 0.81616(14) 0.15437(13) 0.0239(6) Uani 1 1 d . . .
C18 C 0.98650(14) 0.88213(15) 0.13168(15) 0.0285(7) Uani 1 1 d . . .
H18 H 0.9568 0.9148 0.1405 0.034 Uiso 1 1 calc R . .
C19 C 1.07692(18) 0.85178(18) 0.08240(18) 0.0429(9) Uani 1 1 d . . .
H19 H 1.1077 0.8636 0.0579 0.051 Uiso 1 1 calc R . .
C20 C 0.82439(15) 0.67739(14) 0.03938(13) 0.0268(7) Uani 1 1 d . . .
C21 C 0.60527(14) 0.25839(15) 0.31428(15) 0.0277(7) Uani 1 1 d . . .
H21 H 0.6033 0.2205 0.3391 0.033 Uiso 1 1 calc R . .
C22 C 0.49205(14) 0.23677(15) 0.37892(14) 0.0276(7) Uani 1 1 d . . .
H22 H 0.5259 0.2055 0.3858 0.033 Uiso 1 1 calc R . .
C23 C 1.03301(16) 0.89952(17) 0.09624(16) 0.0358(8) Uani 1 1 d . . .
H23 H 1.0347 0.9439 0.0816 0.043 Uiso 1 1 calc R . .
C24 C 1.00697(14) 0.53435(14) 0.13940(13) 0.0231(6) Uani 1 1 d . . .
C25 C 0.66299(14) 0.26954(14) 0.28992(14) 0.0253(6) Uani 1 1 d . . .
C26 C 0.75929(17) 0.20135(18) 0.26916(18) 0.0422(8) Uani 1 1 d . . .
H26 H 0.7518 0.2158 0.2291 0.051 Uiso 1 1 calc R . .
C27 C 0.72302(18) 0.71200(18) -0.01780(17) 0.0447(9) Uani 1 1 d . . .
H27 H 0.6787 0.7197 -0.0199 0.054 Uiso 1 1 calc R . .
C28 C 0.93322(13) 0.79314(14) 0.19192(13) 0.0207(6) Uani 1 1 d . . .
C29 C 0.47482(19) 0.1772(2) 0.63944(19) 0.0502(10) Uani 1 1 d . . .
H29 H 0.4854 0.1471 0.6745 0.060 Uiso 1 1 calc R . .
C30 C 0.92283(15) 0.60237(15) 0.40892(14) 0.0293(7) Uani 1 1 d . . .
H30 H 0.9352 0.5844 0.4474 0.035 Uiso 1 1 calc R . .
C31 C 0.77584(13) 0.51286(13) 0.25780(12) 0.0191(6) Uani 1 1 d . . .
C32 C 0.71743(15) 0.46913(15) 0.08174(14) 0.0288(7) Uani 1 1 d . . .
C33 C 0.77702(13) 0.86850(14) 0.23465(13) 0.0219(6) Uani 1 1 d . . .
C34 C 0.71869(14) 0.22247(14) 0.30956(15) 0.0274(7) Uani 1 1 d . . .
C35 C 0.44038(16) 0.23154(17) 0.41118(16) 0.0357(8) Uani 1 1 d . . .
H35 H 0.4400 0.1972 0.4400 0.043 Uiso 1 1 calc R . .
C36 C 0.7530(2) 0.72251(18) -0.06790(16) 0.0469(10) Uani 1 1 d . . .
H36 H 0.7289 0.7371 -0.1038 0.056 Uiso 1 1 calc R . .
C37 C 1.03815(14) 0.58592(14) 0.38954(14) 0.0251(6) Uani 1 1 d . . .
C38 C 0.39801(17) 0.5360(2) 0.42840(18) 0.0485(10) Uani 1 1 d . . .
H38 H 0.3746 0.5237 0.4592 0.058 Uiso 1 1 calc R . .
C39 C 0.78467(16) 0.16001(17) 0.38830(19) 0.0414(9) Uani 1 1 d . . .
H39 H 0.7936 0.1471 0.4287 0.050 Uiso 1 1 calc R . .
C40 C 0.49398(13) 0.28851(14) 0.33605(13) 0.0220(6) Uani 1 1 d . . .
C41 C 0.70405(14) 0.67902(14) 0.22041(14) 0.0256(6) Uani 1 1 d . . .
H41 H 0.7170 0.7225 0.2102 0.031 Uiso 1 1 calc R . .
C42 C 1.06854(19) 0.46149(18) 0.08227(16) 0.0440(9) Uani 1 1 d . . .
H42 H 1.0738 0.4409 0.0458 0.053 Uiso 1 1 calc R . .
C43 C 0.66910(15) 0.35631(15) 0.44872(14) 0.0274(6) Uani 1 1 d . . .
C44 C 1.07513(18) 0.78652(18) 0.10495(19) 0.0457(9) Uani 1 1 d . . .
H44 H 1.1050 0.7541 0.0959 0.055 Uiso 1 1 calc R . .
C46 C 0.54748(14) 0.47868(15) 0.36142(14) 0.0274(7) Uani 1 1 d . . .
C47 C 0.72698(13) 0.56847(13) 0.24492(12) 0.0189(6) Uani 1 1 d . . .
C48 C 0.73230(15) 0.20172(16) 0.36906(16) 0.0333(7) Uani 1 1 d . . .
H48 H 0.7057 0.2161 0.3967 0.040 Uiso 1 1 calc R . .
C49 C 0.82786(17) 0.63253(16) 0.49660(14) 0.0325(7) Uani 1 1 d . . .
H49 H 0.8694 0.6484 0.5101 0.039 Uiso 1 1 calc R . .
C50 C 0.73898(15) 0.85959(16) 0.27992(15) 0.0321(7) Uani 1 1 d . . .
H50 H 0.7452 0.8213 0.3048 0.038 Uiso 1 1 calc R . .
C51 C 0.68122(17) 0.96327(18) 0.25186(18) 0.0414(9) Uani 1 1 d . . .
H51 H 0.6495 0.9950 0.2578 0.050 Uiso 1 1 calc R . .
C52 C 0.37334(16) 0.59861(16) 0.06364(16) 0.0357(8) Uani 1 1 d . . .
H52 H 0.3337 0.6183 0.0486 0.043 Uiso 1 1 calc R . .
C53 C 0.75849(16) 0.68998(16) 0.03593(15) 0.0342(7) Uani 1 1 d . . .
H53 H 0.7380 0.6836 0.0699 0.041 Uiso 1 1 calc R . .
C54 C 0.96995(14) 0.61033(14) 0.37126(13) 0.0250(6) Uani 1 1 d . . .
C55 C 0.95112(13) 0.58055(13) 0.14624(13) 0.0215(6) Uani 1 1 d . . .
C56 C 0.48072(15) 0.56520(15) 0.04990(14) 0.0285(7) Uani 1 1 d . . .
H56 H 0.5133 0.5632 0.0255 0.034 Uiso 1 1 calc R . .
C57 C 0.60685(14) 0.50606(15) 0.10279(14) 0.0276(7) Uani 1 1 d . . .
H57 H 0.6054 0.5360 0.0703 0.033 Uiso 1 1 calc R . .
C58 C 0.44209(15) 0.54233(16) 0.14361(15) 0.0325(7) Uani 1 1 d . . .
H58 H 0.4487 0.5247 0.1827 0.039 Uiso 1 1 calc R . .
C59 C 0.81153(16) 0.61251(15) 0.43690(14) 0.0286(7) Uani 1 1 d . . .
C60 C 0.44193(14) 0.33361(14) 0.32623(14) 0.0262(6) Uani 1 1 d . . .
H60 H 0.4420 0.3683 0.2978 0.031 Uiso 1 1 calc R . .
C61 C 0.57873(15) 0.43298(15) 0.40447(15) 0.0298(7) Uani 1 1 d . . .
H61 H 0.5590 0.4228 0.4382 0.036 Uiso 1 1 calc R . .
C62 C 0.55279(14) 0.50197(14) 0.13287(13) 0.0238(6) Uani 1 1 d . . .
C64 C 1.08232(16) 0.59270(16) 0.34912(15) 0.0328(7) Uani 1 1 d . . .
H64 H 1.0691 0.6125 0.3115 0.039 Uiso 1 1 calc R . .
C65 C 0.38339(16) 0.57254(17) 0.12191(17) 0.0372(8) Uani 1 1 d . . .
H65 H 0.3508 0.5753 0.1463 0.045 Uiso 1 1 calc R . .
C66 C 0.69153(17) 0.90692(19) 0.28893(17) 0.0420(9) Uani 1 1 d . . .
H66 H 0.6668 0.9005 0.3200 0.050 Uiso 1 1 calc R . .
C67 C 0.79753(14) 0.40144(15) 0.28099(15) 0.0291(7) Uani 1 1 d . . .
H67 H 0.7839 0.3579 0.2903 0.035 Uiso 1 1 calc R . .
C68 C 1.05943(16) 0.55585(16) 0.44552(15) 0.0332(7) Uani 1 1 d . . .
H68 H 1.0307 0.5507 0.4735 0.040 Uiso 1 1 calc R . .
C69 C 0.85765(15) 0.62000(14) 0.39191(13) 0.0260(6) Uani 1 1 d . . .
C70 C 0.86029(14) 0.65103(14) 0.09751(13) 0.0231(6) Uani 1 1 d . . .
C71 C 0.66323(14) 0.46744(15) 0.11887(13) 0.0255(6) Uani 1 1 d . . .
C72 C 0.73627(17) 0.35600(18) 0.46244(17) 0.0402(8) Uani 1 1 d . . .
H72 H 0.7607 0.3857 0.4423 0.048 Uiso 1 1 calc R . .
C73 C 0.45271(16) 0.4990(2) 0.41986(16) 0.0404(8) Uani 1 1 d . . .
H73 H 0.4660 0.4623 0.4451 0.048 Uiso 1 1 calc R . .
C74 C 1.05127(15) 0.52056(15) 0.18998(14) 0.0289(7) Uani 1 1 d . . .
H74 H 1.0455 0.5396 0.2270 0.035 Uiso 1 1 calc R . .
C75 C 0.78274(19) 0.62897(17) 0.53609(16) 0.0399(8) Uani 1 1 d . . .
H75 H 0.7937 0.6440 0.5757 0.048 Uiso 1 1 calc R . .
C76 C 0.38911(16) 0.27716(16) 0.40087(16) 0.0343(7) Uani 1 1 d . . .
H76 H 0.3544 0.2737 0.4226 0.041 Uiso 1 1 calc R . .
C77 C 1.02922(16) 0.76890(16) 0.14099(17) 0.0372(8) Uani 1 1 d . . .
H77 H 1.0288 0.7248 0.1566 0.045 Uiso 1 1 calc R . .
C78 C 0.76572(14) 0.92583(14) 0.19724(14) 0.0258(6) Uani 1 1 d . . .
H78 H 0.7905 0.9326 0.1662 0.031 Uiso 1 1 calc R . .
C79 C 1.11293(16) 0.44954(17) 0.13270(17) 0.0384(8) Uani 1 1 d . . .
H79 H 1.1487 0.4218 0.1303 0.046 Uiso 1 1 calc R . .
C81 C 0.7222(2) 0.60357(18) 0.51757(17) 0.0472(10) Uani 1 1 d . . .
H81 H 0.6923 0.6009 0.5446 0.057 Uiso 1 1 calc R . .
C82 C 0.66512(19) 0.26566(17) 0.52068(16) 0.0405(8) Uani 1 1 d . . .
H82 H 0.6410 0.2346 0.5399 0.049 Uiso 1 1 calc R . .
C83 C 0.71803(15) 0.97251(16) 0.20592(17) 0.0351(8) Uani 1 1 d . . .
H83 H 0.7108 1.0103 0.1806 0.042 Uiso 1 1 calc R . .
C85 C 0.88034(14) 0.47817(15) 0.26473(15) 0.0294(7) Uani 1 1 d . . .
H85 H 0.9237 0.4872 0.2624 0.035 Uiso 1 1 calc R . .
C86 C 0.55094(13) 0.30035(14) 0.30373(13) 0.0226(6) Uani 1 1 d . . .
C87 C 1.10411(16) 0.47876(16) 0.18643(17) 0.0373(8) Uani 1 1 d . . .
H87 H 1.1338 0.4705 0.2208 0.045 Uiso 1 1 calc R . .
C88 C 1.12255(18) 0.53372(16) 0.45986(16) 0.0396(8) Uani 1 1 d . . .
H88 H 1.1361 0.5138 0.4973 0.048 Uiso 1 1 calc R . .
C89 C 1.16565(18) 0.54107(17) 0.41886(17) 0.0427(9) Uani 1 1 d . . .
H89 H 1.2082 0.5260 0.4286 0.051 Uiso 1 1 calc R . .
C90 C 0.41163(19) 0.60767(19) 0.3458(2) 0.0542(11) Uani 1 1 d . . .
H90 H 0.3979 0.6443 0.3207 0.065 Uiso 1 1 calc R . .
C91 C 0.82086(19) 0.4668(2) 0.01503(19) 0.0489(10) Uani 1 1 d . . .
H91 H 0.8552 0.4656 -0.0074 0.059 Uiso 1 1 calc R . .
C92 C 1.14581(17) 0.57068(18) 0.36346(17) 0.0420(9) Uani 1 1 d . . .
H92 H 1.1748 0.5759 0.3358 0.050 Uiso 1 1 calc R . .
C93 C 0.71808(17) 0.51167(18) 0.03192(16) 0.0384(8) Uani 1 1 d . . .
H93 H 0.6837 0.5414 0.0206 0.046 Uiso 1 1 calc R . .
C94 C 0.37802(18) 0.5903(2) 0.3920(2) 0.0517(11) Uani 1 1 d . . .
H94 H 0.3417 0.6154 0.3985 0.062 Uiso 1 1 calc R . .
C95 C 0.76962(19) 0.5101(2) -0.00100(18) 0.0469(9) Uani 1 1 d . . .
H95 H 0.7694 0.5387 -0.0343 0.056 Uiso 1 1 calc R . .
C96 C 0.46603(18) 0.57093(18) 0.33638(19) 0.0445(9) Uani 1 1 d . . .
H96 H 0.4882 0.5828 0.3046 0.053 Uiso 1 1 calc R . .
C98 C 0.74948(17) 0.58746(18) 0.41828(16) 0.0402(8) Uani 1 1 d . . .
H98 H 0.7376 0.5744 0.3782 0.048 Uiso 1 1 calc R . .
C99 C 0.7055(2) 0.5819(2) 0.45856(19) 0.0532(10) Uani 1 1 d . . .
H99 H 0.6647 0.5636 0.4461 0.064 Uiso 1 1 calc R . .
C102 C 0.77013(18) 0.4261(2) 0.09755(19) 0.0491(10) Uani 1 1 d . . .
H102 H 0.7711 0.3975 0.1309 0.059 Uiso 1 1 calc R . .
C103 C 0.82341(18) 0.13778(18) 0.3476(2) 0.0468(10) Uani 1 1 d . . .
H103 H 0.8580 0.1087 0.3601 0.056 Uiso 1 1 calc R . .
C104 C 0.7315(2) 0.26632(19) 0.53426(16) 0.0457(9) Uani 1 1 d . . .
H104 H 0.7522 0.2359 0.5627 0.055 Uiso 1 1 calc R . .
C106 C 0.8210(2) 0.4253(2) 0.0644(2) 0.0619(12) Uani 1 1 d . . .
H106 H 0.8559 0.3962 0.0757 0.074 Uiso 1 1 calc R . .
C110 C 0.76729(19) 0.3121(2) 0.50573(18) 0.0499(10) Uani 1 1 d . . .
H110 H 0.8121 0.3134 0.5155 0.060 Uiso 1 1 calc R . .
C111 C 0.81129(19) 0.1583(2) 0.2886(2) 0.0534(11) Uani 1 1 d . . .
H111 H 0.8380 0.1435 0.2612 0.064 Uiso 1 1 calc R . .
O4 O 0.82548(9) 0.76112(9) 0.25556(9) 0.0233(4) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O5 2.349(2) . ?
Dy1 O6 2.2895(19) . ?
Dy1 O1 2.296(2) . ?
Dy1 O3 2.2868(19) . ?
Dy1 O2 2.3134(19) . ?
Dy1 N1 2.594(2) . ?
Dy1 N2 2.588(2) . ?
Dy1 O4 2.2924(18) . ?
Dy2 O9 2.3008(19) . ?
Dy2 O7 2.328(2) . ?
Dy2 O11 2.2968(19) . ?
Dy2 O12 2.300(2) . ?
Dy2 O10 2.3194(19) . ?
Dy2 O8 2.293(2) . ?
Dy2 N3 2.573(2) . ?
Dy2 N4 2.600(2) . ?
Cl2 C29 1.750(4) . ?
Cl4 C13 1.759(4) . ?
Cl6 C13 1.746(4) . ?
Cl3 C29 1.743(4) . ?
Cl5 C13 1.752(4) . ?
Cl1 C29 1.718(4) . ?
O9 C86 1.279(3) . ?
O7 C46 1.267(4) . ?
O11 C62 1.275(3) . ?
O5 C69 1.264(4) . ?
O6 C55 1.264(3) . ?
O1 C70 1.271(3) . ?
O12 C71 1.267(4) . ?
O3 C54 1.271(3) . ?
O2 C28 1.264(3) . ?
O10 C25 1.268(4) . ?
O8 C5 1.272(4) . ?
N3 C14 1.333(4) . ?
N3 C47 1.327(3) . ?
N1 C31 1.331(3) . ?
N1 C85 1.338(4) . ?
N2 C41 1.339(3) . ?
N2 C47 1.332(3) . ?
N4 C31 1.329(3) . ?
N4 C67 1.337(4) . ?
C1 C24 1.383(4) . ?
C1 C42 1.380(5) . ?
C2 C52 1.372(5) . ?
C2 C56 1.386(4) . ?
C3 C7 1.393(4) . ?
C3 C20 1.389(5) . ?
C4 C55 1.391(4) . ?
C4 C70 1.399(4) . ?
C5 C43 1.500(4) . ?
C5 C61 1.393(4) . ?
C6 C15 1.388(4) . ?
C6 C33 1.497(4) . ?
C6 O4 1.276(3) . ?
C7 C36 1.377(5) . ?
C8 C14 1.380(4) . ?
C8 C41 1.372(4) . ?
C9 C60 1.376(4) . ?
C9 C76 1.378(5) . ?
C10 C43 1.381(4) . ?
C10 C82 1.385(5) . ?
C11 C46 1.505(4) . ?
C11 C73 1.393(5) . ?
C11 C96 1.384(5) . ?
C12 C67 1.377(4) . ?
C12 C85 1.382(4) . ?
C15 C28 1.401(4) . ?
C16 C56 1.390(4) . ?
C16 C58 1.389(4) . ?
C16 C62 1.498(4) . ?
C17 C18 1.391(4) . ?
C17 C28 1.501(4) . ?
C17 C77 1.390(4) . ?
C18 C23 1.378(4) . ?
C19 C23 1.373(5) . ?
C19 C44 1.374(5) . ?
C20 C53 1.387(4) . ?
C20 C70 1.496(4) . ?
C21 C25 1.406(4) . ?
C21 C86 1.392(4) . ?
C22 C35 1.382(4) . ?
C22 C40 1.398(4) . ?
C24 C55 1.498(4) . ?
C24 C74 1.381(4) . ?
C25 C34 1.498(4) . ?
C26 C34 1.385(5) . ?
C26 C111 1.392(5) . ?
C27 C36 1.372(6) . ?
C27 C53 1.386(4) . ?
C30 C54 1.390(4) . ?
C30 C69 1.401(4) . ?
C31 C47 1.490(4) . ?
C32 C71 1.494(4) . ?
C32 C93 1.391(5) . ?
C32 C102 1.389(5) . ?
C33 C50 1.382(4) . ?
C33 C78 1.398(4) . ?
C34 C48 1.380(5) . ?
C35 C76 1.386(5) . ?
C37 C54 1.501(4) . ?
C37 C64 1.384(5) . ?
C37 C68 1.396(4) . ?
C38 C73 1.386(5) . ?
C38 C94 1.366(6) . ?
C39 C48 1.382(4) . ?
C39 C103 1.370(5) . ?
C40 C60 1.392(4) . ?
C40 C86 1.492(4) . ?
C42 C79 1.373(5) . ?
C43 C72 1.391(4) . ?
C44 C77 1.379(5) . ?
C46 C61 1.404(4) . ?
C49 C59 1.385(4) . ?
C49 C75 1.379(5) . ?
C50 C66 1.390(5) . ?
C51 C66 1.377(5) . ?
C51 C83 1.378(5) . ?
C52 C65 1.386(5) . ?
C57 C62 1.394(4) . ?
C57 C71 1.400(4) . ?
C58 C65 1.383(4) . ?
C59 C69 1.493(4) . ?
C59 C98 1.391(5) . ?
C64 C92 1.386(5) . ?
C68 C88 1.379(5) . ?
C72 C110 1.384(5) . ?
C74 C87 1.383(4) . ?
C75 C81 1.365(5) . ?
C78 C83 1.383(4) . ?
C79 C87 1.365(5) . ?
C81 C99 1.381(6) . ?
C82 C104 1.375(5) . ?
C88 C89 1.378(5) . ?
C89 C92 1.376(5) . ?
C90 C94 1.368(6) . ?
C90 C96 1.384(5) . ?
C91 C95 1.371(6) . ?
C91 C106 1.369(6) . ?
C93 C95 1.386(5) . ?
C98 C99 1.376(5) . ?
C102 C106 1.376(5) . ?
C103 C111 1.366(6) . ?
C104 C110 1.377(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 N1 71.60(7) . . ?
O5 Dy1 N2 68.93(7) . . ?
O6 Dy1 O5 129.65(7) . . ?
O6 Dy1 O1 73.92(7) . . ?
O6 Dy1 O2 79.10(7) . . ?
O6 Dy1 N1 70.91(7) . . ?
O6 Dy1 N2 118.98(7) . . ?
O6 Dy1 O4 148.46(7) . . ?
O1 Dy1 O5 141.18(7) . . ?
O1 Dy1 O2 79.97(7) . . ?
O1 Dy1 N1 94.40(7) . . ?
O1 Dy1 N2 72.47(7) . . ?
O3 Dy1 O5 71.71(7) . . ?
O3 Dy1 O6 75.83(7) . . ?
O3 Dy1 O1 146.10(7) . . ?
O3 Dy1 O2 79.62(7) . . ?
O3 Dy1 N1 89.87(7) . . ?
O3 Dy1 N2 137.37(7) . . ?
O3 Dy1 O4 112.51(7) . . ?
O2 Dy1 O5 129.44(7) . . ?
O2 Dy1 N1 149.85(7) . . ?
O2 Dy1 N2 139.72(7) . . ?
N2 Dy1 N1 62.76(7) . . ?
O4 Dy1 O5 80.62(7) . . ?
O4 Dy1 O1 86.77(7) . . ?
O4 Dy1 O2 73.04(7) . . ?
O4 Dy1 N1 136.63(7) . . ?
O4 Dy1 N2 76.56(7) . . ?
O9 Dy2 O7 76.85(7) . . ?
O9 Dy2 O10 73.72(7) . . ?
O9 Dy2 N3 146.43(7) . . ?
O9 Dy2 N4 147.71(7) . . ?
O7 Dy2 N3 72.78(7) . . ?
O7 Dy2 N4 116.65(8) . . ?
O11 Dy2 O9 81.54(7) . . ?
O11 Dy2 O7 77.60(7) . . ?
O11 Dy2 O12 72.11(7) . . ?
O11 Dy2 O10 124.24(7) . . ?
O11 Dy2 N3 78.30(7) . . ?
O11 Dy2 N4 128.67(7) . . ?
O12 Dy2 O9 120.97(7) . . ?
O12 Dy2 O7 141.06(7) . . ?
O12 Dy2 O10 79.27(7) . . ?
O12 Dy2 N3 77.53(7) . . ?
O12 Dy2 N4 68.29(8) . . ?
O10 Dy2 O7 139.16(7) . . ?
O10 Dy2 N3 139.79(7) . . ?
O10 Dy2 N4 78.54(7) . . ?
O8 Dy2 O9 86.89(7) . . ?
O8 Dy2 O7 72.43(7) . . ?
O8 Dy2 O11 149.61(7) . . ?
O8 Dy2 O12 136.83(7) . . ?
O8 Dy2 O10 78.27(7) . . ?
O8 Dy2 N3 97.19(7) . . ?
O8 Dy2 N4 71.40(7) . . ?
N3 Dy2 N4 62.49(7) . . ?
C86 O9 Dy2 127.53(17) . . ?
C46 O7 Dy2 130.46(19) . . ?
C62 O11 Dy2 133.71(18) . . ?
C69 O5 Dy1 135.9(2) . . ?
C55 O6 Dy1 135.86(17) . . ?
C70 O1 Dy1 134.00(18) . . ?
C71 O12 Dy2 133.68(19) . . ?
C54 O3 Dy1 137.40(19) . . ?
C28 O2 Dy1 130.95(17) . . ?
C25 O10 Dy2 124.87(19) . . ?
C5 O8 Dy2 128.54(18) . . ?
C14 N3 Dy2 120.87(18) . . ?
C47 N3 Dy2 121.63(17) . . ?
C47 N3 C14 116.7(2) . . ?
C31 N1 Dy1 120.69(17) . . ?
C31 N1 C85 116.2(2) . . ?
C85 N1 Dy1 122.59(18) . . ?
C41 N2 Dy1 122.25(18) . . ?
C47 N2 Dy1 120.79(17) . . ?
C47 N2 C41 115.9(2) . . ?
C31 N4 Dy2 120.46(17) . . ?
C31 N4 C67 116.7(2) . . ?
C67 N4 Dy2 121.59(18) . . ?
C42 C1 C24 120.7(3) . . ?
C52 C2 C56 120.4(3) . . ?
C20 C3 C7 120.8(3) . . ?
C55 C4 C70 124.4(3) . . ?
O8 C5 C43 115.4(3) . . ?
O8 C5 C61 125.1(3) . . ?
C61 C5 C43 119.5(3) . . ?
C15 C6 C33 120.3(2) . . ?
O4 C6 C15 124.2(3) . . ?
O4 C6 C33 115.5(2) . . ?
C36 C7 C3 119.4(3) . . ?
C41 C8 C14 117.3(3) . . ?
C60 C9 C76 120.8(3) . . ?
C43 C10 C82 120.6(3) . . ?
C73 C11 C46 123.1(3) . . ?
C96 C11 C46 118.7(3) . . ?
C96 C11 C73 118.2(3) . . ?
C67 C12 C85 117.2(3) . . ?
Cl6 C13 Cl4 109.4(2) . . ?
Cl6 C13 Cl5 111.3(2) . . ?
Cl5 C13 Cl4 109.5(2) . . ?
N3 C14 C8 121.5(3) . . ?
C6 C15 C28 123.9(3) . . ?
C56 C16 C62 122.8(3) . . ?
C58 C16 C56 118.5(3) . . ?
C58 C16 C62 118.6(3) . . ?
C18 C17 C28 123.6(3) . . ?
C18 C17 C77 118.1(3) . . ?
C77 C17 C28 118.4(3) . . ?
C23 C18 C17 120.7(3) . . ?
C23 C19 C44 119.7(3) . . ?
C3 C20 C70 122.6(3) . . ?
C53 C20 C3 118.7(3) . . ?
C53 C20 C70 118.6(3) . . ?
C86 C21 C25 124.3(3) . . ?
C35 C22 C40 120.7(3) . . ?
C19 C23 C18 120.5(3) . . ?
C1 C24 C55 123.7(3) . . ?
C74 C24 C1 118.1(3) . . ?
C74 C24 C55 118.3(3) . . ?
O10 C25 C21 125.8(3) . . ?
O10 C25 C34 116.7(3) . . ?
C21 C25 C34 117.5(3) . . ?
C34 C26 C111 119.8(4) . . ?
C36 C27 C53 120.2(3) . . ?
O2 C28 C15 124.2(3) . . ?
O2 C28 C17 116.5(2) . . ?
C15 C28 C17 119.3(2) . . ?
Cl3 C29 Cl2 109.9(2) . . ?
Cl1 C29 Cl2 112.4(2) . . ?
Cl1 C29 Cl3 112.1(2) . . ?
C54 C30 C69 123.3(3) . . ?
N1 C31 C47 116.9(2) . . ?
N4 C31 N1 126.2(2) . . ?
N4 C31 C47 116.8(2) . . ?
C93 C32 C71 123.4(3) . . ?
C102 C32 C71 118.6(3) . . ?
C102 C32 C93 118.0(3) . . ?
C50 C33 C6 119.3(3) . . ?
C50 C33 C78 118.2(3) . . ?
C78 C33 C6 122.4(3) . . ?
C26 C34 C25 120.8(3) . . ?
C48 C34 C25 120.5(3) . . ?
C48 C34 C26 118.6(3) . . ?
C22 C35 C76 120.4(3) . . ?
C27 C36 C7 120.4(3) . . ?
C64 C37 C54 119.0(3) . . ?
C64 C37 C68 117.9(3) . . ?
C68 C37 C54 123.1(3) . . ?
C94 C38 C73 120.7(4) . . ?
C103 C39 C48 119.7(4) . . ?
C22 C40 C86 123.1(3) . . ?
C60 C40 C22 118.0(3) . . ?
C60 C40 C86 118.8(3) . . ?
N2 C41 C8 122.1(3) . . ?
C79 C42 C1 120.5(3) . . ?
C10 C43 C5 122.4(3) . . ?
C10 C43 C72 118.5(3) . . ?
C72 C43 C5 119.0(3) . . ?
C19 C44 C77 120.2(3) . . ?
O7 C46 C11 115.9(3) . . ?
O7 C46 C61 123.7(3) . . ?
C61 C46 C11 120.4(3) . . ?
N3 C47 N2 126.4(2) . . ?
N3 C47 C31 116.6(2) . . ?
N2 C47 C31 117.0(2) . . ?
C34 C48 C39 121.2(3) . . ?
C75 C49 C59 120.3(3) . . ?
C33 C50 C66 121.1(3) . . ?
C66 C51 C83 119.8(3) . . ?
C2 C52 C65 120.0(3) . . ?
C27 C53 C20 120.4(3) . . ?
O3 C54 C30 123.5(3) . . ?
O3 C54 C37 115.0(3) . . ?
C30 C54 C37 121.6(3) . . ?
O6 C55 C4 124.0(3) . . ?
O6 C55 C24 115.4(2) . . ?
C4 C55 C24 120.6(3) . . ?
C2 C56 C16 120.4(3) . . ?
C62 C57 C71 123.5(3) . . ?
C65 C58 C16 121.0(3) . . ?
C49 C59 C69 121.8(3) . . ?
C49 C59 C98 118.6(3) . . ?
C98 C59 C69 119.6(3) . . ?
C9 C60 C40 121.0(3) . . ?
C5 C61 C46 123.2(3) . . ?
O11 C62 C16 115.8(3) . . ?
O11 C62 C57 124.1(3) . . ?
C57 C62 C16 120.1(3) . . ?
C37 C64 C92 121.4(3) . . ?
C58 C65 C52 119.7(3) . . ?
C51 C66 C50 120.0(3) . . ?
N4 C67 C12 121.7(3) . . ?
C88 C68 C37 120.8(3) . . ?
O5 C69 C30 124.6(3) . . ?
O5 C69 C59 116.3(3) . . ?
C30 C69 C59 119.0(3) . . ?
O1 C70 C4 124.6(3) . . ?
O1 C70 C20 116.4(3) . . ?
C4 C70 C20 118.9(3) . . ?
O12 C71 C32 115.7(3) . . ?
O12 C71 C57 123.0(3) . . ?
C57 C71 C32 121.3(3) . . ?
C110 C72 C43 120.9(3) . . ?
C38 C73 C11 120.2(4) . . ?
C24 C74 C87 121.0(3) . . ?
C81 C75 C49 120.6(3) . . ?
C9 C76 C35 119.2(3) . . ?
C44 C77 C17 120.9(3) . . ?
C83 C78 C33 120.6(3) . . ?
C87 C79 C42 119.4(3) . . ?
C75 C81 C99 119.9(4) . . ?
C104 C82 C10 120.3(3) . . ?
C51 C83 C78 120.3(3) . . ?
N1 C85 C12 122.0(3) . . ?
O9 C86 C21 123.3(3) . . ?
O9 C86 C40 115.9(2) . . ?
C21 C86 C40 120.7(3) . . ?
C79 C87 C74 120.3(3) . . ?
C68 C88 C89 120.2(3) . . ?
C92 C89 C88 120.0(3) . . ?
C94 C90 C96 120.3(4) . . ?
C106 C91 C95 119.3(4) . . ?
C89 C92 C64 119.6(4) . . ?
C95 C93 C32 120.5(3) . . ?
C38 C94 C90 119.7(4) . . ?
C91 C95 C93 120.6(4) . . ?
C90 C96 C11 120.9(4) . . ?
C99 C98 C59 120.6(3) . . ?
C98 C99 C81 119.9(4) . . ?
C106 C102 C32 120.8(4) . . ?
C111 C103 C39 120.0(3) . . ?
C82 C104 C110 119.9(3) . . ?
C91 C106 C102 120.8(4) . . ?
C104 C110 C72 119.8(3) . . ?
C103 C111 C26 120.6(4) . . ?
C6 O4 Dy1 133.05(18) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O5 C69 C30 4.7(4) . . . . ?
Dy1 O5 C69 C59 -173.77(18) . . . . ?
Dy1 O6 C55 C4 -7.7(4) . . . . ?
Dy1 O6 C55 C24 172.17(18) . . . . ?
Dy1 O1 C70 C4 16.4(4) . . . . ?
Dy1 O1 C70 C20 -166.93(18) . . . . ?
Dy1 O3 C54 C30 -23.0(5) . . . . ?
Dy1 O3 C54 C37 156.1(2) . . . . ?
Dy1 O2 C28 C15 28.8(4) . . . . ?
Dy1 O2 C28 C17 -150.80(19) . . . . ?
Dy1 N1 C31 N4 -169.6(2) . . . . ?
Dy1 N1 C31 C47 10.4(3) . . . . ?
Dy1 N1 C85 C12 170.4(2) . . . . ?
Dy1 N2 C41 C8 -167.4(2) . . . . ?
Dy1 N2 C47 N3 169.1(2) . . . . ?
Dy1 N2 C47 C31 -11.0(3) . . . . ?
Dy2 O9 C86 C21 -34.3(4) . . . . ?
Dy2 O9 C86 C40 141.8(2) . . . . ?
Dy2 O7 C46 C11 -156.83(19) . . . . ?
Dy2 O7 C46 C61 23.9(4) . . . . ?
Dy2 O11 C62 C16 -162.35(18) . . . . ?
Dy2 O11 C62 C57 17.5(4) . . . . ?
Dy2 O12 C71 C32 155.7(2) . . . . ?
Dy2 O12 C71 C57 -25.2(4) . . . . ?
Dy2 O10 C25 C21 34.7(4) . . . . ?
Dy2 O10 C25 C34 -143.6(2) . . . . ?
Dy2 O8 C5 C43 147.3(2) . . . . ?
Dy2 O8 C5 C61 -33.6(4) . . . . ?
Dy2 N3 C14 C8 -168.5(2) . . . . ?
Dy2 N3 C47 N2 168.3(2) . . . . ?
Dy2 N3 C47 C31 -11.6(3) . . . . ?
Dy2 N4 C31 N1 -169.1(2) . . . . ?
Dy2 N4 C31 C47 11.0(3) . . . . ?
Dy2 N4 C67 C12 167.2(2) . . . . ?
O9 Dy2 O7 C46 53.8(2) . . . . ?
O9 Dy2 O11 C62 -155.0(3) . . . . ?
O9 Dy2 O12 C71 100.7(3) . . . . ?
O9 Dy2 O10 C25 -42.6(2) . . . . ?
O9 Dy2 O8 C5 -36.1(2) . . . . ?
O9 Dy2 N3 C14 -18.5(3) . . . . ?
O9 Dy2 N3 C47 171.83(18) . . . . ?
O9 Dy2 N4 C31 -170.78(18) . . . . ?
O9 Dy2 N4 C67 22.4(3) . . . . ?
O7 Dy2 O9 C86 -107.7(2) . . . . ?
O7 Dy2 O11 C62 126.7(3) . . . . ?
O7 Dy2 O12 C71 -8.0(3) . . . . ?
O7 Dy2 O10 C25 2.9(3) . . . . ?
O7 Dy2 O8 C5 41.0(2) . . . . ?
O7 Dy2 N3 C14 -44.7(2) . . . . ?
O7 Dy2 N3 C47 145.6(2) . . . . ?
O7 Dy2 N4 C31 -62.2(2) . . . . ?
O7 Dy2 N4 C67 130.9(2) . . . . ?
O7 C46 C61 C5 6.6(5) . . . . ?
O11 Dy2 O9 C86 173.1(2) . . . . ?
O11 Dy2 O7 C46 137.9(3) . . . . ?
O11 Dy2 O12 C71 32.7(3) . . . . ?
O11 Dy2 O10 C25 -110.0(2) . . . . ?
O11 Dy2 O8 C5 31.3(3) . . . . ?
O11 Dy2 N3 C14 35.8(2) . . . . ?
O11 Dy2 N3 C47 -133.9(2) . . . . ?
O11 Dy2 N4 C31 33.2(2) . . . . ?
O11 Dy2 N4 C67 -133.7(2) . . . . ?
O5 Dy1 O6 C55 159.8(2) . . . . ?
O5 Dy1 O1 C70 -154.0(2) . . . . ?
O5 Dy1 O3 C54 22.1(3) . . . . ?
O5 Dy1 O2 C28 -95.8(3) . . . . ?
O5 Dy1 N1 C31 64.2(2) . . . . ?
O5 Dy1 N1 C85 -107.2(2) . . . . ?
O5 Dy1 N2 C41 99.7(2) . . . . ?
O5 Dy1 N2 C47 -68.2(2) . . . . ?
O5 Dy1 O4 C6 165.3(2) . . . . ?
O6 Dy1 O5 C69 40.0(3) . . . . ?
O6 Dy1 O1 C70 -19.4(2) . . . . ?
O6 Dy1 O3 C54 -118.8(3) . . . . ?
O6 Dy1 O2 C28 131.1(3) . . . . ?
O6 Dy1 N1 C31 -150.1(2) . . . . ?
O6 Dy1 N1 C85 38.6(2) . . . . ?
O6 Dy1 N2 C41 -135.7(2) . . . . ?
O6 Dy1 N2 C47 56.4(2) . . . . ?
O6 Dy1 O4 C6 0.0(3) . . . . ?
O1 Dy1 O5 C69 157.2(2) . . . . ?
O1 Dy1 O6 C55 15.3(2) . . . . ?
O1 Dy1 O3 C54 -146.2(3) . . . . ?
O1 Dy1 O2 C28 55.7(2) . . . . ?
O1 Dy1 N1 C31 -78.8(2) . . . . ?
O1 Dy1 N1 C85 109.9(2) . . . . ?
O1 Dy1 N2 C41 -76.2(2) . . . . ?
O1 Dy1 N2 C47 115.9(2) . . . . ?
O1 Dy1 O4 C6 -51.5(2) . . . . ?
O12 Dy2 O9 C86 110.0(2) . . . . ?
O12 Dy2 O7 C46 177.3(2) . . . . ?
O12 Dy2 O11 C62 -28.5(2) . . . . ?
O12 Dy2 O10 C25 -169.6(2) . . . . ?
O12 Dy2 O8 C5 -170.2(2) . . . . ?
O12 Dy2 N3 C14 109.8(2) . . . . ?
O12 Dy2 N3 C47 -59.9(2) . . . . ?
O12 Dy2 N4 C31 75.2(2) . . . . ?
O12 Dy2 N4 C67 -91.6(2) . . . . ?
O3 Dy1 O5 C69 -12.5(3) . . . . ?
O3 Dy1 O6 C55 -149.2(3) . . . . ?
O3 Dy1 O1 C70 8.2(3) . . . . ?
O3 Dy1 O2 C28 -151.5(3) . . . . ?
O3 Dy1 N1 C31 134.9(2) . . . . ?
O3 Dy1 N1 C85 -36.4(2) . . . . ?
O3 Dy1 N2 C41 123.4(2) . . . . ?
O3 Dy1 N2 C47 -44.5(2) . . . . ?
O3 Dy1 O4 C6 99.7(2) . . . . ?
O2 Dy1 O5 C69 -71.3(3) . . . . ?
O2 Dy1 O6 C55 -67.3(3) . . . . ?
O2 Dy1 O1 C70 62.0(2) . . . . ?
O2 Dy1 O3 C54 159.9(3) . . . . ?
O2 Dy1 N1 C31 -156.34(19) . . . . ?
O2 Dy1 N1 C85 32.3(3) . . . . ?
O2 Dy1 N2 C41 -27.1(3) . . . . ?
O2 Dy1 N2 C47 165.02(18) . . . . ?
O2 Dy1 O4 C6 29.0(2) . . . . ?
O10 Dy2 O9 C86 43.6(2) . . . . ?
O10 Dy2 O7 C46 9.1(3) . . . . ?
O10 Dy2 O11 C62 -91.3(3) . . . . ?
O10 Dy2 O12 C71 164.2(3) . . . . ?
O10 Dy2 O8 C5 -110.2(2) . . . . ?
O10 Dy2 N3 C14 166.0(2) . . . . ?
O10 Dy2 N3 C47 -3.7(3) . . . . ?
O10 Dy2 N4 C31 158.1(2) . . . . ?
O10 Dy2 N4 C67 -8.7(2) . . . . ?
O10 C25 C34 C26 -39.0(4) . . . . ?
O10 C25 C34 C48 138.1(3) . . . . ?
O8 Dy2 O9 C86 -35.1(2) . . . . ?
O8 Dy2 O7 C46 -37.1(2) . . . . ?
O8 Dy2 O11 C62 136.2(2) . . . . ?
O8 Dy2 O12 C71 -136.1(2) . . . . ?
O8 Dy2 O10 C25 47.5(2) . . . . ?
O8 Dy2 N3 C14 -113.7(2) . . . . ?
O8 Dy2 N3 C47 76.6(2) . . . . ?
O8 Dy2 N4 C31 -120.5(2) . . . . ?
O8 Dy2 N4 C67 72.6(2) . . . . ?
O8 C5 C43 C10 -140.9(3) . . . . ?
O8 C5 C43 C72 34.6(4) . . . . ?
O8 C5 C61 C46 -1.8(5) . . . . ?
N3 Dy2 O9 C86 -133.4(2) . . . . ?
N3 Dy2 O7 C46 -140.7(3) . . . . ?
N3 Dy2 O11 C62 52.0(3) . . . . ?
N3 Dy2 O12 C71 -48.9(3) . . . . ?
N3 Dy2 O10 C25 134.8(2) . . . . ?
N3 Dy2 O8 C5 110.4(2) . . . . ?
N3 Dy2 N4 C31 -11.6(2) . . . . ?
N3 Dy2 N4 C67 -178.5(3) . . . . ?
N1 Dy1 O5 C69 83.7(3) . . . . ?
N1 Dy1 O6 C55 115.9(3) . . . . ?
N1 Dy1 O1 C70 -88.1(2) . . . . ?
N1 Dy1 O3 C54 -48.5(3) . . . . ?
N1 Dy1 O2 C28 137.1(2) . . . . ?
N1 Dy1 N2 C41 179.2(2) . . . . ?
N1 Dy1 N2 C47 11.28(19) . . . . ?
N1 Dy1 O4 C6 -144.5(2) . . . . ?
N1 C31 C47 N3 -179.7(2) . . . . ?
N1 C31 C47 N2 0.4(4) . . . . ?
N2 Dy1 O5 C69 150.8(3) . . . . ?
N2 Dy1 O6 C55 74.1(3) . . . . ?
N2 Dy1 O1 C70 -147.7(3) . . . . ?
N2 Dy1 O3 C54 -1.2(3) . . . . ?
N2 Dy1 O2 C28 8.7(3) . . . . ?
N2 Dy1 N1 C31 -11.1(2) . . . . ?
N2 Dy1 N1 C85 177.6(3) . . . . ?
N2 Dy1 O4 C6 -124.2(2) . . . . ?
N4 Dy2 O9 C86 11.8(3) . . . . ?
N4 Dy2 O7 C46 -94.8(3) . . . . ?
N4 Dy2 O11 C62 12.4(3) . . . . ?
N4 Dy2 O12 C71 -114.0(3) . . . . ?
N4 Dy2 O10 C25 120.7(2) . . . . ?
N4 Dy2 O8 C5 168.1(3) . . . . ?
N4 Dy2 N3 C14 -178.4(2) . . . . ?
N4 Dy2 N3 C47 11.9(2) . . . . ?
N4 C31 C47 N3 0.2(4) . . . . ?
N4 C31 C47 N2 -179.6(2) . . . . ?
C1 C24 C55 O6 160.1(3) . . . . ?
C1 C24 C55 C4 -20.0(4) . . . . ?
C1 C24 C74 C87 1.6(5) . . . . ?
C1 C42 C79 C87 1.4(6) . . . . ?
C2 C52 C65 C58 -1.0(5) . . . . ?
C3 C7 C36 C27 0.7(5) . . . . ?
C3 C20 C53 C27 1.7(5) . . . . ?
C3 C20 C70 O1 157.5(3) . . . . ?
C3 C20 C70 C4 -25.7(4) . . . . ?
C5 C43 C72 C110 -176.7(3) . . . . ?
C6 C15 C28 O2 0.3(5) . . . . ?
C6 C15 C28 C17 179.9(3) . . . . ?
C6 C33 C50 C66 177.3(3) . . . . ?
C6 C33 C78 C83 -177.9(3) . . . . ?
C7 C3 C20 C53 -1.2(4) . . . . ?
C7 C3 C20 C70 178.0(3) . . . . ?
C10 C43 C72 C110 -1.0(5) . . . . ?
C10 C82 C104 C110 -0.3(6) . . . . ?
C11 C46 C61 C5 -172.5(3) . . . . ?
C14 N3 C47 N2 -1.8(4) . . . . ?
C14 N3 C47 C31 178.3(3) . . . . ?
C14 C8 C41 N2 -1.1(5) . . . . ?
C15 C6 C33 C50 -162.7(3) . . . . ?
C15 C6 C33 C78 15.7(4) . . . . ?
C15 C6 O4 Dy1 -18.2(4) . . . . ?
C16 C58 C65 C52 0.2(5) . . . . ?
C17 C18 C23 C19 0.4(5) . . . . ?
C18 C17 C28 O2 -167.3(3) . . . . ?
C18 C17 C28 C15 13.1(4) . . . . ?
C18 C17 C77 C44 -1.7(5) . . . . ?
C19 C44 C77 C17 1.0(6) . . . . ?
C20 C3 C7 C36 0.1(5) . . . . ?
C21 C25 C34 C26 142.6(3) . . . . ?
C21 C25 C34 C48 -40.4(4) . . . . ?
C22 C35 C76 C9 0.1(5) . . . . ?
C22 C40 C60 C9 0.3(4) . . . . ?
C22 C40 C86 O9 -174.8(3) . . . . ?
C22 C40 C86 C21 1.4(4) . . . . ?
C23 C19 C44 C77 0.4(6) . . . . ?
C24 C1 C42 C79 -0.7(6) . . . . ?
C24 C74 C87 C79 -0.9(5) . . . . ?
C25 C21 C86 O9 1.8(5) . . . . ?
C25 C21 C86 C40 -174.2(3) . . . . ?
C25 C34 C48 C39 -178.0(3) . . . . ?
C26 C34 C48 C39 -0.9(5) . . . . ?
C28 C17 C18 C23 -178.4(3) . . . . ?
C28 C17 C77 C44 177.7(3) . . . . ?
C31 N1 C85 C12 -1.3(5) . . . . ?
C31 N4 C67 C12 -0.1(5) . . . . ?
C32 C93 C95 C91 -0.2(6) . . . . ?
C32 C102 C106 C91 -0.1(7) . . . . ?
C33 C6 C15 C28 173.2(3) . . . . ?
C33 C6 O4 Dy1 162.56(18) . . . . ?
C33 C50 C66 C51 0.9(5) . . . . ?
C33 C78 C83 C51 0.4(5) . . . . ?
C34 C26 C111 C103 -1.2(6) . . . . ?
C35 C22 C40 C60 -1.1(4) . . . . ?
C35 C22 C40 C86 174.6(3) . . . . ?
C36 C27 C53 C20 -1.0(5) . . . . ?
C37 C64 C92 C89 0.3(5) . . . . ?
C37 C68 C88 C89 0.0(5) . . . . ?
C39 C103 C111 C26 -0.7(6) . . . . ?
C40 C22 C35 C76 0.9(5) . . . . ?
C41 N2 C47 N3 0.5(4) . . . . ?
C41 N2 C47 C31 -179.6(3) . . . . ?
C41 C8 C14 N3 -0.3(5) . . . . ?
C42 C1 C24 C55 -179.7(3) . . . . ?
C42 C1 C24 C74 -0.8(5) . . . . ?
C42 C79 C87 C74 -0.6(5) . . . . ?
C43 C5 C61 C46 177.3(3) . . . . ?
C43 C10 C82 C104 1.4(5) . . . . ?
C43 C72 C110 C104 2.2(6) . . . . ?
C44 C19 C23 C18 -1.1(6) . . . . ?
C46 C11 C73 C38 -179.6(3) . . . . ?
C46 C11 C96 C90 -179.8(3) . . . . ?
C47 N3 C14 C8 1.6(4) . . . . ?
C47 N2 C41 C8 1.0(4) . . . . ?
C48 C39 C103 C111 1.8(6) . . . . ?
C49 C59 C69 O5 -138.5(3) . . . . ?
C49 C59 C69 C30 43.0(4) . . . . ?
C49 C59 C98 C99 -0.8(5) . . . . ?
C49 C75 C81 C99 -0.7(5) . . . . ?
C50 C33 C78 C83 0.6(4) . . . . ?
C52 C2 C56 C16 0.0(5) . . . . ?
C53 C20 C70 O1 -23.3(4) . . . . ?
C53 C20 C70 C4 153.6(3) . . . . ?
C53 C27 C36 C7 -0.2(5) . . . . ?
C54 C30 C69 O5 4.5(5) . . . . ?
C54 C30 C69 C59 -177.1(3) . . . . ?
C54 C37 C64 C92 -179.6(3) . . . . ?
C54 C37 C68 C88 179.4(3) . . . . ?
C55 C4 C70 O1 1.6(5) . . . . ?
C55 C4 C70 C20 -174.9(3) . . . . ?
C55 C24 C74 C87 -179.5(3) . . . . ?
C56 C2 C52 C65 0.9(5) . . . . ?
C56 C16 C58 C65 0.7(5) . . . . ?
C56 C16 C62 O11 -167.7(3) . . . . ?
C56 C16 C62 C57 12.5(4) . . . . ?
C58 C16 C56 C2 -0.8(4) . . . . ?
C58 C16 C62 O11 10.3(4) . . . . ?
C58 C16 C62 C57 -169.6(3) . . . . ?
C59 C49 C75 C81 2.2(5) . . . . ?
C59 C98 C99 C81 2.3(6) . . . . ?
C60 C9 C76 C35 -0.9(5) . . . . ?
C60 C40 C86 O9 0.8(4) . . . . ?
C60 C40 C86 C21 177.1(3) . . . . ?
C61 C5 C43 C10 39.9(4) . . . . ?
C61 C5 C43 C72 -144.6(3) . . . . ?
C62 C16 C56 C2 177.2(3) . . . . ?
C62 C16 C58 C65 -177.4(3) . . . . ?
C62 C57 C71 O12 -4.5(5) . . . . ?
C62 C57 C71 C32 174.4(3) . . . . ?
C64 C37 C54 O3 -1.7(4) . . . . ?
C64 C37 C54 C30 177.4(3) . . . . ?
C64 C37 C68 C88 0.0(4) . . . . ?
C66 C51 C83 C78 -0.7(5) . . . . ?
C67 N4 C31 N1 -1.6(4) . . . . ?
C67 N4 C31 C47 178.5(3) . . . . ?
C67 C12 C85 N1 -0.1(5) . . . . ?
C68 C37 C54 O3 178.9(3) . . . . ?
C68 C37 C54 C30 -2.0(4) . . . . ?
C68 C37 C64 C92 -0.2(5) . . . . ?
C68 C88 C89 C92 0.1(5) . . . . ?
C69 C30 C54 O3 3.6(5) . . . . ?
C69 C30 C54 C37 -175.3(3) . . . . ?
C69 C59 C98 C99 -178.2(3) . . . . ?
C70 C4 C55 O6 -6.1(5) . . . . ?
C70 C4 C55 C24 174.1(3) . . . . ?
C70 C20 C53 C27 -177.6(3) . . . . ?
C71 C32 C93 C95 -179.2(3) . . . . ?
C71 C32 C102 C106 179.4(4) . . . . ?
C71 C57 C62 O11 8.2(5) . . . . ?
C71 C57 C62 C16 -171.9(3) . . . . ?
C73 C11 C46 O7 166.4(3) . . . . ?
C73 C11 C46 C61 -14.3(5) . . . . ?
C73 C11 C96 C90 1.6(5) . . . . ?
C73 C38 C94 C90 1.2(6) . . . . ?
C74 C24 C55 O6 -18.8(4) . . . . ?
C74 C24 C55 C4 161.1(3) . . . . ?
C75 C49 C59 C69 175.9(3) . . . . ?
C75 C49 C59 C98 -1.4(5) . . . . ?
C75 C81 C99 C98 -1.5(6) . . . . ?
C76 C9 C60 C40 0.7(5) . . . . ?
C77 C17 C18 C23 0.9(5) . . . . ?
C77 C17 C28 O2 13.4(4) . . . . ?
C77 C17 C28 C15 -166.2(3) . . . . ?
C78 C33 C50 C66 -1.2(5) . . . . ?
C82 C10 C43 C5 174.7(3) . . . . ?
C82 C10 C43 C72 -0.8(5) . . . . ?
C82 C104 C110 C72 -1.6(6) . . . . ?
C83 C51 C66 C50 0.0(5) . . . . ?
C85 N1 C31 N4 2.3(4) . . . . ?
C85 N1 C31 C47 -177.7(3) . . . . ?
C85 C12 C67 N4 0.9(5) . . . . ?
C86 C21 C25 O10 -2.9(5) . . . . ?
C86 C21 C25 C34 175.4(3) . . . . ?
C86 C40 C60 C9 -175.5(3) . . . . ?
C88 C89 C92 C64 -0.3(5) . . . . ?
C93 C32 C71 O12 -176.5(3) . . . . ?
C93 C32 C71 C57 4.5(5) . . . . ?
C93 C32 C102 C106 -0.6(6) . . . . ?
C94 C38 C73 C11 -0.4(5) . . . . ?
C94 C90 C96 C11 -0.8(6) . . . . ?
C95 C91 C106 C102 0.7(7) . . . . ?
C96 C11 C46 O7 -12.1(4) . . . . ?
C96 C11 C46 C61 167.1(3) . . . . ?
C96 C11 C73 C38 -1.1(5) . . . . ?
C96 C90 C94 C38 -0.7(6) . . . . ?
C98 C59 C69 O5 38.8(4) . . . . ?
C98 C59 C69 C30 -139.7(3) . . . . ?
C102 C32 C71 O12 3.5(4) . . . . ?
C102 C32 C71 C57 -175.5(3) . . . . ?
C102 C32 C93 C95 0.8(5) . . . . ?
C103 C39 C48 C34 -1.0(5) . . . . ?
C106 C91 C95 C93 -0.6(6) . . . . ?
C111 C26 C34 C25 179.1(3) . . . . ?
C111 C26 C34 C48 2.0(5) . . . . ?
O4 Dy1 O5 C69 -130.0(3) . . . . ?
O4 Dy1 O6 C55 -39.1(3) . . . . ?
O4 Dy1 O1 C70 135.3(2) . . . . ?
O4 Dy1 O3 C54 93.3(3) . . . . ?
O4 Dy1 O2 C28 -34.0(2) . . . . ?
O4 Dy1 N1 C31 11.2(3) . . . . ?
O4 Dy1 N1 C85 -160.2(2) . . . . ?
O4 Dy1 N2 C41 14.7(2) . . . . ?
O4 Dy1 N2 C47 -153.2(2) . . . . ?
O4 C6 C15 C28 -6.0(5) . . . . ?
O4 C6 C33 C50 16.6(4) . . . . ?
O4 C6 C33 C78 -165.0(3) . . . . ?

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 962685'
_audit_update_record             
;
2016-04-15 deposited with the CCDC.
2016-04-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C102 H75 Dy2 N6 O12'
_chemical_formula_weight         1901.68

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.3403(5)
_cell_length_b                   13.7896(5)
_cell_length_c                   15.0024(6)
_cell_angle_alpha                63.104(4)
_cell_angle_beta                 69.918(4)
_cell_angle_gamma                64.260(4)
_cell_volume                     2179.67(14)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    13523
_cell_measurement_theta_min      3.0830
_cell_measurement_theta_max      28.4830

_exptl_crystal_description       block
_exptl_crystal_colour            ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.449
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             957
_exptl_absorpt_coefficient_mu    1.768
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            19672
_diffrn_reflns_av_R_equivalents  0.0331
_diffrn_reflns_av_unetI/netI     0.0448
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.84
_diffrn_reflns_theta_max         28.41
_reflns_number_total             8995
_reflns_number_gt                8227
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0210P)²+0.8651P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8995
_refine_ls_number_parameters     550
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0302
_refine_ls_R_factor_gt           0.0255
_refine_ls_wR_factor_ref         0.0590
_refine_ls_wR_factor_gt          0.0556
_refine_ls_goodness_of_fit_ref   1.012
_refine_ls_restrained_S_all      1.012
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.206872(8) 0.756073(9) 0.114735(8) 0.01786(4) Uani 1 1 d . . .
O1 O 0.07940(13) 0.67479(15) 0.24426(12) 0.0243(4) Uani 1 1 d . . .
O2 O 0.34222(13) 0.59959(14) 0.19798(12) 0.0241(4) Uani 1 1 d . . .
O3 O 0.27123(15) 0.90981(15) 0.04147(13) 0.0298(4) Uani 1 1 d . . .
O4 O 0.36016(13) 0.71167(15) -0.01062(13) 0.0251(4) Uani 1 1 d . . .
O5 O 0.14895(13) 0.66698(15) 0.05296(13) 0.0251(4) Uani 1 1 d . . .
O6 O 0.20584(14) 0.80476(15) 0.24306(13) 0.0271(4) Uani 1 1 d . . .
N1 N 0.12367(16) 0.90290(17) -0.05034(15) 0.0213(4) Uani 1 1 d . . .
N2 N 0.01426(16) 0.92346(17) 0.13049(15) 0.0215(4) Uani 1 1 d . . .
N3 N 0.6681(3) 0.9681(3) -0.5637(3) 0.0748(10) Uani 1 1 d . . .
C1 C 0.1978(2) 0.9659(3) 0.3835(2) 0.0393(7) Uani 1 1 d . . .
H1A H 0.2328 1.0187 0.3343 0.047 Uiso 1 1 calc R . .
C2 C 0.1321(2) 0.8096(3) 0.4333(2) 0.0358(6) Uani 1 1 d . . .
H2A H 0.1234 0.7560 0.4176 0.043 Uiso 1 1 calc R . .
C3 C -0.0849(2) 0.6704(3) -0.0198(2) 0.0373(7) Uani 1 1 d . . .
H3A H -0.1430 0.6835 0.0340 0.045 Uiso 1 1 calc R . .
C4 C -0.1354(2) 0.6101(3) 0.5211(2) 0.0370(7) Uani 1 1 d . . .
H4A H -0.1336 0.6325 0.5702 0.044 Uiso 1 1 calc R . .
C6 C 0.6206(2) 0.3091(2) 0.4221(2) 0.0355(6) Uani 1 1 d . . .
H6A H 0.6599 0.2590 0.4753 0.043 Uiso 1 1 calc R . .
C7 C 0.6531(2) 0.2878(2) 0.3329(2) 0.0370(7) Uani 1 1 d . . .
H7A H 0.7122 0.2213 0.3275 0.044 Uiso 1 1 calc R . .
C8 C -0.1412(2) 0.5452(2) 0.3740(2) 0.0326(6) Uani 1 1 d . . .
H8A H -0.1438 0.5230 0.3250 0.039 Uiso 1 1 calc R . .
C9 C 0.0941(2) 0.8096(3) 0.5318(2) 0.0427(7) Uani 1 1 d . . .
H9A H 0.0595 0.7568 0.5816 0.051 Uiso 1 1 calc R . .
C10 C 0.2805(2) 0.9794(2) 0.0691(2) 0.0296(6) Uani 1 1 d . . .
C11 C 0.1828(2) 0.8889(2) 0.3578(2) 0.0298(6) Uani 1 1 d . . .
C12 C 0.5151(2) 0.8022(2) -0.1747(2) 0.0312(6) Uani 1 1 d . . .
H12A H 0.4466 0.8557 -0.1581 0.037 Uiso 1 1 calc R . .
C13 C -0.0730(2) 0.6434(2) 0.4245(2) 0.0295(6) Uani 1 1 d . . .
H13A H -0.0292 0.6879 0.4095 0.035 Uiso 1 1 calc R . .
C14 C 0.5293(2) 0.4054(2) 0.4316(2) 0.0331(6) Uani 1 1 d . . .
H14A H 0.5056 0.4187 0.4923 0.040 Uiso 1 1 calc R . .
C15 C 0.7181(2) 0.6436(3) -0.2267(2) 0.0315(6) Uani 1 1 d . . .
H15A H 0.7854 0.5901 -0.2451 0.038 Uiso 1 1 calc R . .
C16 C -0.0181(2) 0.6387(2) 0.1643(2) 0.0294(6) Uani 1 1 d . . .
H16A H -0.0834 0.6250 0.1717 0.035 Uiso 1 1 calc R . .
C17 C 0.0258(2) 0.6503(2) -0.01578(19) 0.0277(6) Uani 1 1 d . . .
C18 C 0.00058(19) 0.6437(2) 0.24761(19) 0.0245(5) Uani 1 1 d . . .
C19 C -0.0418(2) 0.9337(2) 0.22122(19) 0.0267(5) Uani 1 1 d . . .
H19A H -0.0142 0.8778 0.2798 0.032 Uiso 1 1 calc R . .
C20 C -0.0743(2) 0.6116(2) 0.34947(19) 0.0253(5) Uani 1 1 d . . .
C21 C 0.1392(2) 0.9748(2) -0.22902(19) 0.0277(6) Uani 1 1 d . . .
H21A H 0.1778 0.9683 -0.2918 0.033 Uiso 1 1 calc R . .
C22 C 0.5986(2) 0.3640(2) 0.2521(2) 0.0278(6) Uani 1 1 d . . .
H22A H 0.6222 0.3498 0.1918 0.033 Uiso 1 1 calc R . .
C23 C 0.2165(2) 0.8873(2) 0.2514(2) 0.0266(5) Uani 1 1 d . . .
C24 C 0.0549(2) 0.6528(2) 0.07042(19) 0.0234(5) Uani 1 1 d . . .
C25 C 0.1772(2) 0.8938(2) -0.14135(19) 0.0261(5) Uani 1 1 d . . .
H25A H 0.2420 0.8307 -0.1450 0.031 Uiso 1 1 calc R . .
C26 C 0.64695(19) 0.6082(2) -0.13507(19) 0.0231(5) Uani 1 1 d . . .
H26A H 0.6677 0.5318 -0.0911 0.028 Uiso 1 1 calc R . .
C27 C 0.4734(2) 0.4815(2) 0.35154(19) 0.0263(5) Uani 1 1 d . . .
H27A H 0.4121 0.5460 0.3585 0.032 Uiso 1 1 calc R . .
C28 C 0.50777(18) 0.4628(2) 0.26039(18) 0.0203(5) Uani 1 1 d . . .
C29 C 0.51007(19) 0.5716(2) 0.07545(18) 0.0211(5) Uani 1 1 d . . .
H29A H 0.5866 0.5285 0.0663 0.025 Uiso 1 1 calc R . .
C30 C 0.54375(19) 0.6882(2) -0.10924(18) 0.0210(5) Uani 1 1 d . . .
C31 C 0.46482(18) 0.6550(2) -0.01027(18) 0.0193(5) Uani 1 1 d . . .
C32 C -0.02986(18) 1.00519(19) 0.05052(17) 0.0177(5) Uani 1 1 d . . .
C33 C 0.44750(18) 0.5483(2) 0.17472(18) 0.0196(5) Uani 1 1 d . . .
C34 C 0.3217(2) 1.0735(2) -0.0151(2) 0.0347(6) Uani 1 1 d . . .
C35 C 0.4226(4) 1.2070(3) -0.0812(3) 0.0683(12) Uani 1 1 d . . .
H35A H 0.4649 1.2388 -0.0713 0.082 Uiso 1 1 calc R . .
C36 C 0.3992(4) 1.2446(3) -0.1757(3) 0.0726(13) Uani 1 1 d . . .
H36A H 0.4250 1.3020 -0.2295 0.087 Uiso 1 1 calc R . .
C37 C 0.3372(3) 1.1970(3) -0.1909(3) 0.0599(10) Uani 1 1 d . . .
H37A H 0.3200 1.2233 -0.2547 0.072 Uiso 1 1 calc R . .
C38 C 0.3840(3) 1.1225(3) -0.0005(3) 0.0507(9) Uani 1 1 d . . .
H38A H 0.3995 1.0983 0.0636 0.061 Uiso 1 1 calc R . .
C39 C -0.1091(3) 0.6713(3) -0.1023(2) 0.0456(8) Uani 1 1 d . . .
H39A H -0.1833 0.6851 -0.1039 0.055 Uiso 1 1 calc R . .
C40 C 0.0863(3) 0.6316(3) -0.1798(2) 0.0477(8) Uani 1 1 d . . .
H40A H 0.1441 0.6181 -0.2336 0.057 Uiso 1 1 calc R . .
C41 C -0.0237(3) 0.6516(3) -0.1827(2) 0.0464(8) Uani 1 1 d . . .
H41A H -0.0401 0.6518 -0.2382 0.056 Uiso 1 1 calc R . .
C42 C 0.5880(3) 0.8367(3) -0.2647(2) 0.0405(7) Uani 1 1 d . . .
H42A H 0.5688 0.9134 -0.3081 0.049 Uiso 1 1 calc R . .
C43 C 0.1605(2) 0.9644(3) 0.4828(3) 0.0453(8) Uani 1 1 d . . .
H43A H 0.1715 1.0158 0.4996 0.054 Uiso 1 1 calc R . .
C44 C 0.1079(2) 0.8882(3) 0.5559(2) 0.0448(8) Uani 1 1 d . . .
H44A H 0.0816 0.8892 0.6216 0.054 Uiso 1 1 calc R . .
C45 C 0.3007(3) 1.1102(3) -0.1111(2) 0.0433(7) Uani 1 1 d . . .
H45A H 0.2616 1.0761 -0.1223 0.052 Uiso 1 1 calc R . .
C46 C 0.6896(2) 0.7571(3) -0.2903(2) 0.0395(7) Uani 1 1 d . . .
H46A H 0.7386 0.7807 -0.3507 0.047 Uiso 1 1 calc R . .
C47 C 0.1105(2) 0.6316(3) -0.0978(2) 0.0378(7) Uani 1 1 d . . .
H47A H 0.1847 0.6188 -0.0971 0.045 Uiso 1 1 calc R . .
C48 C -0.2040(2) 0.5121(3) 0.4713(2) 0.0385(7) Uani 1 1 d . . .
H48A H -0.2487 0.4683 0.4867 0.046 Uiso 1 1 calc R . .
C49 C -0.2007(2) 0.5435(3) 0.5450(2) 0.0390(7) Uani 1 1 d . . .
H49A H -0.2421 0.5202 0.6103 0.047 Uiso 1 1 calc R . .
C50 C 0.2526(2) 0.9739(3) 0.1694(2) 0.0361(7) Uani 1 1 d . . .
H50A H 0.2586 1.0310 0.1822 0.043 Uiso 1 1 calc R . .
C52 C 0.6261(3) 0.9048(3) -0.5446(3) 0.0531(9) Uani 1 1 d . . .
C51 C 0.5700(3) 0.8227(4) -0.5178(4) 0.0752(12) Uani 1 1 d D . .
H51C H 0.5067 0.8601 -0.5550 0.113 Uiso 1 1 d RD . .
H51B H 0.6235 0.7694 -0.5447 0.113 Uiso 1 1 d RD . .
H51A H 0.5470 0.8044 -0.4537 0.113 Uiso 1 1 d RD . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O2 2.2808(17) . ?
Dy1 O3 2.2943(16) . ?
Dy1 O6 2.3022(17) . ?
Dy1 O5 2.3046(16) . ?
Dy1 O1 2.3108(15) . ?
Dy1 O4 2.3253(15) . ?
Dy1 N1 2.620(2) . ?
Dy1 N2 2.6289(19) . ?
O1 C18 1.276(3) . ?
O2 C33 1.272(3) . ?
O3 C10 1.267(3) . ?
O4 C31 1.270(3) . ?
O5 C24 1.274(3) . ?
O6 C23 1.270(3) . ?
N1 C32 1.339(3) 2_575 ?
N1 C25 1.340(3) . ?
N2 C32 1.320(3) . ?
N2 C19 1.347(3) . ?
N3 C52 1.117(4) . ?
C1 C11 1.388(4) . ?
C1 C43 1.393(4) . ?
C1 H1A 0.9300 . ?
C2 C9 1.388(4) . ?
C2 C11 1.390(4) . ?
C2 H2A 0.9300 . ?
C3 C39 1.376(4) . ?
C3 C17 1.396(4) . ?
C3 H3A 0.9300 . ?
C4 C13 1.380(4) . ?
C4 C49 1.383(4) . ?
C4 H4A 0.9300 . ?
C6 C7 1.383(4) . ?
C6 C14 1.383(4) . ?
C6 H6A 0.9300 . ?
C7 C22 1.375(4) . ?
C7 H7A 0.9300 . ?
C8 C48 1.388(4) . ?
C8 C20 1.397(3) . ?
C8 H8A 0.9300 . ?
C9 C44 1.383(4) . ?
C9 H9A 0.9300 . ?
C10 C50 1.396(4) . ?
C10 C34 1.497(4) . ?
C11 C23 1.510(4) . ?
C12 C42 1.384(4) . ?
C12 C30 1.386(4) . ?
C12 H12A 0.9300 . ?
C13 C20 1.388(4) . ?
C13 H13A 0.9300 . ?
C14 C27 1.376(4) . ?
C14 H14A 0.9300 . ?
C15 C46 1.374(4) . ?
C15 C26 1.389(3) . ?
C15 H15A 0.9300 . ?
C16 C18 1.391(4) . ?
C16 C24 1.394(3) . ?
C16 H16A 0.9300 . ?
C17 C47 1.392(4) . ?
C17 C24 1.490(4) . ?
C18 C20 1.501(3) . ?
C19 C21 1.378(3) 2_575 ?
C19 H19A 0.9300 . ?
C21 C25 1.368(4) . ?
C21 C19 1.378(3) 2_575 ?
C21 H21A 0.9300 . ?
C22 C28 1.399(3) . ?
C22 H22A 0.9300 . ?
C23 C50 1.391(4) . ?
C25 H25A 0.9300 . ?
C26 C30 1.402(3) . ?
C26 H26A 0.9300 . ?
C27 C28 1.390(3) . ?
C27 H27A 0.9300 . ?
C28 C33 1.484(3) . ?
C29 C31 1.390(3) . ?
C29 C33 1.402(3) . ?
C29 H29A 0.9300 . ?
C30 C31 1.501(3) . ?
C32 N1 1.339(3) 2_575 ?
C32 C32 1.490(4) 2_575 ?
C34 C45 1.379(4) . ?
C34 C38 1.394(4) . ?
C35 C36 1.370(6) . ?
C35 C38 1.380(5) . ?
C35 H35A 0.9300 . ?
C36 C37 1.379(5) . ?
C36 H36A 0.9300 . ?
C37 C45 1.383(4) . ?
C37 H37A 0.9300 . ?
C38 H38A 0.9300 . ?
C39 C41 1.382(4) . ?
C39 H39A 0.9300 . ?
C40 C47 1.375(4) . ?
C40 C41 1.383(4) . ?
C40 H40A 0.9300 . ?
C41 H41A 0.9300 . ?
C42 C46 1.386(4) . ?
C42 H42A 0.9300 . ?
C43 C44 1.366(5) . ?
C43 H43A 0.9300 . ?
C44 H44A 0.9300 . ?
C45 H45A 0.9300 . ?
C46 H46A 0.9300 . ?
C47 H47A 0.9300 . ?
C48 C49 1.377(4) . ?
C48 H48A 0.9300 . ?
C49 H49A 0.9300 . ?
C50 H50A 0.9300 . ?
C52 C51 1.456(5) . ?
C51 H51C 0.9873 . ?
C51 H51B 0.9092 . ?
C51 H51A 0.8526 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Dy1 O3 107.60(6) . . ?
O2 Dy1 O6 77.26(6) . . ?
O3 Dy1 O6 72.16(6) . . ?
O2 Dy1 O5 99.15(6) . . ?
O3 Dy1 O5 134.07(6) . . ?
O6 Dy1 O5 151.75(6) . . ?
O2 Dy1 O1 85.27(6) . . ?
O3 Dy1 O1 144.57(6) . . ?
O6 Dy1 O1 79.13(6) . . ?
O5 Dy1 O1 72.64(6) . . ?
O2 Dy1 O4 73.92(6) . . ?
O3 Dy1 O4 75.30(6) . . ?
O6 Dy1 O4 126.76(6) . . ?
O5 Dy1 O4 77.28(6) . . ?
O1 Dy1 O4 139.91(6) . . ?
O2 Dy1 N1 152.25(6) . . ?
O3 Dy1 N1 69.53(6) . . ?
O6 Dy1 N1 124.77(6) . . ?
O5 Dy1 N1 69.49(6) . . ?
O1 Dy1 N1 113.44(6) . . ?
O4 Dy1 N1 78.81(6) . . ?
O2 Dy1 N2 146.31(6) . . ?
O3 Dy1 N2 80.06(6) . . ?
O6 Dy1 N2 74.09(6) . . ?
O5 Dy1 N2 97.75(6) . . ?
O1 Dy1 N2 72.33(6) . . ?
O4 Dy1 N2 138.57(6) . . ?
N1 Dy1 N2 61.43(6) . . ?
C18 O1 Dy1 134.37(16) . . ?
C33 O2 Dy1 135.87(15) . . ?
C10 O3 Dy1 137.77(16) . . ?
C31 O4 Dy1 133.25(15) . . ?
C24 O5 Dy1 132.12(14) . . ?
C23 O6 Dy1 137.63(16) . . ?
C32 N1 C25 115.9(2) 2_575 . ?
C32 N1 Dy1 122.65(15) 2_575 . ?
C25 N1 Dy1 121.34(16) . . ?
C32 N2 C19 116.2(2) . . ?
C32 N2 Dy1 122.44(14) . . ?
C19 N2 Dy1 121.23(17) . . ?
C11 C1 C43 120.1(3) . . ?
C11 C1 H1A 119.9 . . ?
C43 C1 H1A 119.9 . . ?
C9 C2 C11 120.7(3) . . ?
C9 C2 H2A 119.6 . . ?
C11 C2 H2A 119.6 . . ?
C39 C3 C17 120.9(3) . . ?
C39 C3 H3A 119.6 . . ?
C17 C3 H3A 119.6 . . ?
C13 C4 C49 120.3(3) . . ?
C13 C4 H4A 119.9 . . ?
C49 C4 H4A 119.9 . . ?
C7 C6 C14 119.6(3) . . ?
C7 C6 H6A 120.2 . . ?
C14 C6 H6A 120.2 . . ?
C22 C7 C6 120.6(2) . . ?
C22 C7 H7A 119.7 . . ?
C6 C7 H7A 119.7 . . ?
C48 C8 C20 120.3(3) . . ?
C48 C8 H8A 119.8 . . ?
C20 C8 H8A 119.8 . . ?
C44 C9 C2 119.9(3) . . ?
C44 C9 H9A 120.0 . . ?
C2 C9 H9A 120.0 . . ?
O3 C10 C50 124.3(2) . . ?
O3 C10 C34 115.2(2) . . ?
C50 C10 C34 120.5(2) . . ?
C1 C11 C2 118.7(3) . . ?
C1 C11 C23 123.8(3) . . ?
C2 C11 C23 117.6(2) . . ?
C42 C12 C30 120.2(2) . . ?
C42 C12 H12A 119.9 . . ?
C30 C12 H12A 119.9 . . ?
C4 C13 C20 121.2(2) . . ?
C4 C13 H13A 119.4 . . ?
C20 C13 H13A 119.4 . . ?
C27 C14 C6 120.2(2) . . ?
C27 C14 H14A 119.9 . . ?
C6 C14 H14A 119.9 . . ?
C46 C15 C26 120.4(2) . . ?
C46 C15 H15A 119.8 . . ?
C26 C15 H15A 119.8 . . ?
C18 C16 C24 124.2(2) . . ?
C18 C16 H16A 117.9 . . ?
C24 C16 H16A 117.9 . . ?
C47 C17 C3 118.0(3) . . ?
C47 C17 C24 119.4(2) . . ?
C3 C17 C24 122.6(2) . . ?
O1 C18 C16 124.1(2) . . ?
O1 C18 C20 115.7(2) . . ?
C16 C18 C20 120.3(2) . . ?
N2 C19 C21 121.4(2) . 2_575 ?
N2 C19 H19A 119.3 . . ?
C21 C19 H19A 119.3 2_575 . ?
C13 C20 C8 118.2(2) . . ?
C13 C20 C18 119.2(2) . . ?
C8 C20 C18 122.5(2) . . ?
C25 C21 C19 117.9(2) . 2_575 ?
C25 C21 H21A 121.1 . . ?
C19 C21 H21A 121.1 2_575 . ?
C7 C22 C28 120.1(2) . . ?
C7 C22 H22A 120.0 . . ?
C28 C22 H22A 120.0 . . ?
O6 C23 C50 123.8(2) . . ?
O6 C23 C11 115.4(2) . . ?
C50 C23 C11 120.8(2) . . ?
O5 C24 C16 123.3(2) . . ?
O5 C24 C17 116.3(2) . . ?
C16 C24 C17 120.4(2) . . ?
N1 C25 C21 121.9(2) . . ?
N1 C25 H25A 119.1 . . ?
C21 C25 H25A 119.1 . . ?
C15 C26 C30 119.6(2) . . ?
C15 C26 H26A 120.2 . . ?
C30 C26 H26A 120.2 . . ?
C14 C27 C28 120.6(2) . . ?
C14 C27 H27A 119.7 . . ?
C28 C27 H27A 119.7 . . ?
C27 C28 C22 118.9(2) . . ?
C27 C28 C33 119.2(2) . . ?
C22 C28 C33 121.9(2) . . ?
C31 C29 C33 124.1(2) . . ?
C31 C29 H29A 118.0 . . ?
C33 C29 H29A 118.0 . . ?
C12 C30 C26 119.5(2) . . ?
C12 C30 C31 118.7(2) . . ?
C26 C30 C31 121.8(2) . . ?
O4 C31 C29 124.7(2) . . ?
O4 C31 C30 116.2(2) . . ?
C29 C31 C30 119.0(2) . . ?
N2 C32 N1 126.8(2) . 2_575 ?
N2 C32 C32 117.2(2) . 2_575 ?
N1 C32 C32 116.0(3) 2_575 2_575 ?
O2 C33 C29 124.6(2) . . ?
O2 C33 C28 116.6(2) . . ?
C29 C33 C28 118.7(2) . . ?
C45 C34 C38 118.9(3) . . ?
C45 C34 C10 119.0(2) . . ?
C38 C34 C10 122.1(3) . . ?
C36 C35 C38 120.7(3) . . ?
C36 C35 H35A 119.6 . . ?
C38 C35 H35A 119.6 . . ?
C35 C36 C37 119.8(3) . . ?
C35 C36 H36A 120.1 . . ?
C37 C36 H36A 120.1 . . ?
C36 C37 C45 119.8(4) . . ?
C36 C37 H37A 120.1 . . ?
C45 C37 H37A 120.1 . . ?
C35 C38 C34 119.9(3) . . ?
C35 C38 H38A 120.0 . . ?
C34 C38 H38A 120.0 . . ?
C3 C39 C41 120.4(3) . . ?
C3 C39 H39A 119.8 . . ?
C41 C39 H39A 119.8 . . ?
C47 C40 C41 120.3(3) . . ?
C47 C40 H40A 119.8 . . ?
C41 C40 H40A 119.8 . . ?
C39 C41 C40 119.4(3) . . ?
C39 C41 H41A 120.3 . . ?
C40 C41 H41A 120.3 . . ?
C12 C42 C46 120.2(3) . . ?
C12 C42 H42A 119.9 . . ?
C46 C42 H42A 119.9 . . ?
C44 C43 C1 120.8(3) . . ?
C44 C43 H43A 119.6 . . ?
C1 C43 H43A 119.6 . . ?
C43 C44 C9 119.7(3) . . ?
C43 C44 H44A 120.1 . . ?
C9 C44 H44A 120.1 . . ?
C34 C45 C37 120.7(3) . . ?
C34 C45 H45A 119.6 . . ?
C37 C45 H45A 119.6 . . ?
C15 C46 C42 120.1(2) . . ?
C15 C46 H46A 119.9 . . ?
C42 C46 H46A 119.9 . . ?
C40 C47 C17 121.0(3) . . ?
C40 C47 H47A 119.5 . . ?
C17 C47 H47A 119.5 . . ?
C49 C48 C8 120.7(3) . . ?
C49 C48 H48A 119.7 . . ?
C8 C48 H48A 119.7 . . ?
C48 C49 C4 119.4(2) . . ?
C48 C49 H49A 120.3 . . ?
C4 C49 H49A 120.3 . . ?
C23 C50 C10 123.4(2) . . ?
C23 C50 H50A 118.3 . . ?
C10 C50 H50A 118.3 . . ?
N3 C52 C51 178.9(4) . . ?
C52 C51 H51C 109.4 . . ?
C52 C51 H51B 103.1 . . ?
H51C C51 H51B 106.6 . . ?
C52 C51 H51A 104.3 . . ?
H51C C51 H51A 112.0 . . ?
H51B C51 H51A 120.8 . . ?

_diffrn_measured_fraction_theta_max 0.821
_diffrn_reflns_theta_full        26.50
_diffrn_measured_fraction_theta_full 0.945
_refine_diff_density_max         0.937
_refine_diff_density_min         -0.971
_refine_diff_density_rms         0.080
