# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_c2byc
_database_code_depnum_ccdc_archive 'CCDC 1440867'
_audit_update_record             
;
2016-05-17 deposited with the CCDC.
2016-05-20 downloaded from the CCDC.
;
_audit_creation_date             2015-12-07
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
_shelxl_version_number           2014-3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C152 H200 Cu6 Dy8 N80 O12, 6(O), 9(C H4 O)'
_chemical_formula_sum            'C161 H236 Cu6 Dy8 N80 O27'
_chemical_formula_weight         5405.52
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   24.673(12)
_cell_length_b                   42.718(9)
_cell_length_c                   24.298(5)
_cell_angle_alpha                90
_cell_angle_beta                 90.01(4)
_cell_angle_gamma                90
_cell_volume                     25610(15)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    18000
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.754
_cell_measurement_theta_min      0.953
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.854
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.402
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             10720
_exptl_crystal_size_max          0.1010
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.050
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0461
_diffrn_reflns_av_unetI/netI     0.0231
_diffrn_reflns_Laue_measured_fraction_full 0.932
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       50
_diffrn_reflns_limit_k_min       -50
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            155733
_diffrn_reflns_point_group_measured_fraction_full 0.932
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         24.754
_diffrn_reflns_theta_min         0.953
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.932
_diffrn_measured_fraction_theta_max 0.987
_diffrn_radiation_type           
'silicon double crystal monochromated synchrotron'
_diffrn_source                   'Australian Synchrotron MX1'
_diffrn_measurement_device_type  'ADSC Quantum Detector'
_diffrn_measurement_method       'π  scans'
_diffrn_radiation_wavelength     0.71073
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                16971
_reflns_number_total             21649
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_data_collection       'BlueIce (McPhillips, et al., 2002)'
_computing_cell_refinement       'XDS (Kabsch, 1993)'
_computing_data_reduction        'XDS (Kabsch, 1993)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         2.514
_refine_diff_density_min         -0.779
_refine_diff_density_rms         0.180
_refine_ls_extinction_coef       0.000273(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1286
_refine_ls_number_reflns         21649
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0741
_refine_ls_R_factor_gt           0.0589
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0945P)²+322.3011P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1652
_refine_ls_wR_factor_ref         0.1779
_refine_special_details          
;
The strucutre has large solvent accessble voids due to the counter-anions 
(nitrates) extremely disordered in these voids. There is not enough electron 
density to actually model them. In addition, the coordinated water molecules 
inside the cage has many possible hydrogen bonds which could not be 
modelled properly causing some B alerts. The disordered methanol and water 
molecules in the crystal lattice also contributed to some B alerts in the CheckCIF.
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups, All O(H,H) groups
2. Others
 Fixed Sof: O14(0.5) O18(0.5) O15(0.5) O19(0.5) O13(0.5) H13(0.5) C81(0.5)
 H81A(0.5) H81B(0.5) H81C(0.5)
3.a Rotating group:
 O5(H5A,H5B), O6(H6A,H6B)
3.b Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C2(H2A,H2B), C7(H7A,H7B), C8(H8A,H8B), C13(H13A,H13B), C14(H14A,
 H14B), C20(H20A,H20B), C21(H21A,H21B), C26(H26A,H26B), C27(H27A,H27B),
 C32(H32A,H32B), C33(H33A,H33B), C39(H39A,H39B), C40(H40A,H40B), C45(H45A,H45B),
  C46(H46A,H46B), C51(H51A,H51B), C52(H52A,H52B), C58(H58A,H58B), C59(H59A,
 H59B), C64(H64A,H64B), C65(H65A,H65B), C70(H70A,H70B), C71(H71A,H71B)
3.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C6(H6), C9(H9), C11(H11), C12(H12), C15(H15), C17(H17),
 C18(H18), C22(H22), C24(H24), C25(H25), C28(H28), C30(H30), C31(H31), C34(H34),
  C36(H36), C37(H37), C41(H41), C43(H43), C44(H44), C47(H47), C49(H49),
 C50(H50), C53(H53), C55(H55), C56(H56), C60(H60), C62(H62), C63(H63), C66(H66),
  C68(H68), C69(H69), C72(H72), C74(H74), C75(H75)
3.d Idealised Me refined as rotating group:
 C19(H19A,H19B,H19C), C38(H38A,H38B,H38C), C57(H57A,H57B,H57C), C76(H76A,H76B,
 H76C), C77(H77A,H77B,H77C), C78(H78A,H78B,H78C), C79(H79A,H79B,H79C), C80(H80A,
 H80B,H80C), C81(H81A,H81B,H81C)
3.e Idealised tetrahedral OH refined as rotating group:
 O9(H9A), O10(H10), O11(H11A), O12(H12A), O13(H13)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.08660(2) 0.40725(2) 0.49517(2) 0.03724(12) Uani 1 1 d . . . . .
Dy2 Dy -0.24217(2) 0.18189(2) 0.33943(2) 0.03893(12) Uani 1 1 d . . . . .
Dy3 Dy 0.09179(2) 0.18181(2) 0.49383(2) 0.03898(12) Uani 1 1 d . . . . .
Dy4 Dy 0.24179(2) 0.40828(2) 0.15958(2) 0.04249(13) Uani 1 1 d . . . . .
Cu1 Cu 0.0000 0.14724(3) 0.2500 0.0350(3) Uani 1 2 d S T P . .
Cu2 Cu 0.0000 0.44576(3) 0.2500 0.0398(3) Uani 1 2 d S T P . .
Cu3 Cu -0.08167(4) 0.29435(2) 0.42875(4) 0.0400(2) Uani 1 1 d . . . . .
Cu4 Cu 0.17845(4) 0.29596(2) 0.33314(4) 0.0397(2) Uani 1 1 d . . . . .
O1 O 0.0136(2) 0.41599(13) 0.5446(2) 0.0497(14) Uani 1 1 d . . . . .
O2 O -0.2272(2) 0.16788(13) 0.4244(2) 0.0502(14) Uani 1 1 d . . . . .
O3 O 0.1761(2) 0.16879(13) 0.4795(2) 0.0487(13) Uani 1 1 d . . . . .
O4 O 0.2855(3) 0.42227(14) 0.2346(3) 0.0580(16) Uani 1 1 d . . . . .
O5 O -0.0422(4) 0.29451(16) 0.3420(4) 0.094(3) Uani 1 1 d . . . . .
H5A H -0.0052 0.2995 0.3341 0.140 Uiso 1 1 d GR . . . .
H5B H -0.0598 0.2896 0.3081 0.140 Uiso 1 1 d GR . . . .
O6 O 0.0927(4) 0.29532(16) 0.2906(4) 0.095(3) Uani 1 1 d . . . . .
H6A H 0.0593 0.2950 0.3090 0.142 Uiso 1 1 d GR . . . .
H6B H 0.0861 0.2955 0.2526 0.142 Uiso 1 1 d GR . . . .
N1 N 0.1355(3) 0.42994(16) 0.5843(3) 0.0488(17) Uani 1 1 d . . . . .
N2 N 0.0839(3) 0.46519(15) 0.5014(3) 0.0444(16) Uani 1 1 d . . . . .
N3 N 0.0616(3) 0.43184(14) 0.4088(3) 0.0386(14) Uani 1 1 d . . . . .
N4 N 0.0288(3) 0.44820(14) 0.3262(3) 0.0426(15) Uani 1 1 d . . . . .
N5 N 0.1844(3) 0.42047(15) 0.4827(3) 0.0426(15) Uani 1 1 d . . . . .
N6 N 0.1360(2) 0.37208(13) 0.4309(2) 0.0347(13) Uani 1 1 d . . . . .
N7 N 0.1699(3) 0.33546(14) 0.3742(3) 0.0389(14) Uani 1 1 d . . . . .
N8 N 0.1106(3) 0.36601(15) 0.5614(3) 0.0462(16) Uani 1 1 d . . . . .
N9 N 0.0327(3) 0.35932(13) 0.4803(2) 0.0370(14) Uani 1 1 d . . . . .
N10 N -0.0216(3) 0.31831(14) 0.4629(3) 0.0436(15) Uani 1 1 d . . . . .
N11 N -0.3401(3) 0.15767(16) 0.3607(3) 0.0462(16) Uani 1 1 d . . . . .
N12 N -0.2458(3) 0.12402(15) 0.3347(3) 0.0495(17) Uani 1 1 d . . . . .
N13 N -0.1598(3) 0.15969(14) 0.3010(3) 0.0407(15) Uani 1 1 d . . . . .
N14 N -0.0768(3) 0.14503(14) 0.2731(3) 0.0384(14) Uani 1 1 d . . . . .
N15 N -0.3068(3) 0.22135(15) 0.3751(3) 0.0424(15) Uani 1 1 d . . . . .
N16 N -0.1957(3) 0.22878(14) 0.3755(3) 0.0378(14) Uani 1 1 d . . . . .
N17 N -0.1468(2) 0.26987(13) 0.4052(3) 0.0380(14) Uani 1 1 d . . . . .
N18 N -0.3021(3) 0.17294(17) 0.2569(3) 0.0507(18) Uani 1 1 d . . . . .
N19 N -0.2286(2) 0.21980(14) 0.2627(3) 0.0381(14) Uani 1 1 d . . . . .
N20 N -0.2054(3) 0.25618(14) 0.1992(3) 0.0419(15) Uani 1 1 d . . . . .
N21 N 0.1137(3) 0.15688(17) 0.5926(3) 0.0490(17) Uani 1 1 d . . . . .
N22 N 0.0101(3) 0.17156(17) 0.5531(3) 0.0517(18) Uani 1 1 d . . . . .
N23 N 0.0144(2) 0.21930(14) 0.4791(3) 0.0384(14) Uani 1 1 d . . . . .
N24 N -0.0488(3) 0.25425(14) 0.4556(3) 0.0397(14) Uani 1 1 d . . . . .
N25 N 0.0887(3) 0.12343(16) 0.4972(3) 0.0515(18) Uani 1 1 d . . . . .
N26 N 0.0537(3) 0.15954(14) 0.4115(3) 0.0400(14) Uani 1 1 d . . . . .
N27 N 0.0231(3) 0.14482(14) 0.3276(3) 0.0383(14) Uani 1 1 d . . . . .
N28 N 0.1242(3) 0.22095(16) 0.5606(3) 0.0444(15) Uani 1 1 d . . . . .
N29 N 0.1257(2) 0.22943(13) 0.4477(2) 0.0363(13) Uani 1 1 d . . . . .
N30 N 0.1542(3) 0.27133(13) 0.3986(3) 0.0400(14) Uani 1 1 d . . . . .
N31 N 0.3293(3) 0.43239(18) 0.1100(3) 0.0552(18) Uani 1 1 d . . . . .
N32 N 0.2320(3) 0.41784(16) 0.0597(3) 0.0499(17) Uani 1 1 d . . . . .
N33 N 0.1814(3) 0.37011(14) 0.1120(3) 0.0415(15) Uani 1 1 d . . . . .
N34 N 0.1227(3) 0.33405(14) 0.0802(3) 0.0398(14) Uani 1 1 d . . . . .
N35 N 0.2429(3) 0.46664(16) 0.1546(3) 0.0525(18) Uani 1 1 d . . . . .
N36 N 0.1550(3) 0.43124(14) 0.1854(3) 0.0444(15) Uani 1 1 d . . . . .
N37 N 0.0745(3) 0.44678(14) 0.2194(3) 0.0407(14) Uani 1 1 d . . . . .
N38 N 0.3117(3) 0.36909(17) 0.1407(3) 0.0528(18) Uani 1 1 d . . . . .
N39 N 0.2296(3) 0.36120(14) 0.2176(3) 0.0396(14) Uani 1 1 d . . . . .
N40 N 0.2119(3) 0.31984(14) 0.2720(3) 0.0435(15) Uani 1 1 d . . . . .
C1 C 0.1009(4) 0.45726(19) 0.6005(4) 0.055(2) Uani 1 1 d . . . . .
H1A H 0.1162 0.4672 0.6328 0.066 Uiso 1 1 calc R . . . .
H1B H 0.0648 0.4499 0.6098 0.066 Uiso 1 1 calc R . . . .
C2 C 0.0970(4) 0.48135(19) 0.5533(3) 0.053(2) Uani 1 1 d . . . . .
H2A H 0.0690 0.4966 0.5616 0.063 Uiso 1 1 calc R . . . .
H2B H 0.1312 0.4923 0.5496 0.063 Uiso 1 1 calc R . . . .
C3 C 0.0622(3) 0.48024(18) 0.4620(3) 0.0453(19) Uani 1 1 d . . . . .
H3 H 0.0538 0.5014 0.4654 0.054 Uiso 1 1 calc R . . . .
C4 C 0.0511(3) 0.46345(17) 0.4116(3) 0.0408(17) Uani 1 1 d . . . . .
C5 C 0.0324(3) 0.47337(18) 0.3599(3) 0.0453(19) Uani 1 1 d . . . . .
H5 H 0.0239 0.4939 0.3503 0.054 Uiso 1 1 calc R . . . .
C6 C 0.0469(3) 0.42398(18) 0.3574(3) 0.0423(18) Uani 1 1 d . . . . .
H6 H 0.0490 0.4036 0.3443 0.051 Uiso 1 1 calc R . . . .
C7 C 0.1929(4) 0.4395(2) 0.5757(4) 0.054(2) Uani 1 1 d . . . . .
H7A H 0.2163 0.4231 0.5897 0.065 Uiso 1 1 calc R . . . .
H7B H 0.1998 0.4583 0.5971 0.065 Uiso 1 1 calc R . . . .
C8 C 0.2080(4) 0.4460(2) 0.5160(4) 0.054(2) Uani 1 1 d . . . . .
H8A H 0.1936 0.4660 0.5044 0.065 Uiso 1 1 calc R . . . .
H8B H 0.2471 0.4463 0.5118 0.065 Uiso 1 1 calc R . . . .
C9 C 0.2137(3) 0.40452(17) 0.4502(4) 0.0443(19) Uani 1 1 d . . . . .
H9 H 0.2502 0.4095 0.4457 0.053 Uiso 1 1 calc R . . . .
C10 C 0.1905(3) 0.37893(16) 0.4204(3) 0.0367(16) Uani 1 1 d . . . . .
C11 C 0.2110(3) 0.35711(17) 0.3862(3) 0.0423(18) Uani 1 1 d . . . . .
H11 H 0.2463 0.3565 0.3729 0.051 Uiso 1 1 calc R . . . .
C12 C 0.1265(3) 0.34627(17) 0.4021(3) 0.0375(16) Uani 1 1 d . . . . .
H12 H 0.0928 0.3365 0.4012 0.045 Uiso 1 1 calc R . . . .
C13 C 0.1308(4) 0.40606(19) 0.6278(3) 0.054(2) Uani 1 1 d . . . . .
H13A H 0.0936 0.4052 0.6408 0.065 Uiso 1 1 calc R . . . .
H13B H 0.1537 0.4117 0.6587 0.065 Uiso 1 1 calc R . . . .
C14 C 0.1479(4) 0.3735(2) 0.6055(4) 0.055(2) Uani 1 1 d . . . . .
H14A H 0.1848 0.3742 0.5919 0.066 Uiso 1 1 calc R . . . .
H14B H 0.1458 0.3579 0.6344 0.066 Uiso 1 1 calc R . . . .
C15 C 0.0843(4) 0.34048(19) 0.5603(4) 0.051(2) Uani 1 1 d . . . . .
H15 H 0.0907 0.3251 0.5867 0.061 Uiso 1 1 calc R . . . .
C16 C 0.0443(3) 0.33558(17) 0.5177(3) 0.0399(17) Uani 1 1 d . . . . .
C17 C 0.0108(3) 0.31075(19) 0.5065(3) 0.0455(19) Uani 1 1 d . . . . .
H17 H 0.0102 0.2919 0.5255 0.055 Uiso 1 1 calc R . . . .
C18 C -0.0065(3) 0.34781(18) 0.4493(3) 0.0420(18) Uani 1 1 d . . . . .
H18 H -0.0224 0.3590 0.4207 0.050 Uiso 1 1 calc R . . . .
C19 C -0.0202(4) 0.3974(3) 0.5783(4) 0.069(3) Uani 1 1 d . . . . .
H19A H -0.0386 0.3822 0.5560 0.103 Uiso 1 1 calc GR . . . .
H19B H -0.0463 0.4105 0.5963 0.103 Uiso 1 1 calc GR . . . .
H19C H 0.0015 0.3869 0.6054 0.103 Uiso 1 1 calc GR . . . .
C20 C -0.3278(4) 0.1276(2) 0.3899(4) 0.053(2) Uani 1 1 d . . . . .
H20A H -0.3615 0.1170 0.3985 0.064 Uiso 1 1 calc R . . . .
H20B H -0.3096 0.1323 0.4243 0.064 Uiso 1 1 calc R . . . .
C21 C -0.2925(4) 0.1061(2) 0.3559(4) 0.060(2) Uani 1 1 d . . . . .
H21A H -0.2799 0.0888 0.3784 0.072 Uiso 1 1 calc R . . . .
H21B H -0.3133 0.0976 0.3255 0.072 Uiso 1 1 calc R . . . .
C22 C -0.2023(4) 0.10928(19) 0.3204(4) 0.052(2) Uani 1 1 d . . . . .
H22 H -0.2006 0.0875 0.3220 0.062 Uiso 1 1 calc R . . . .
C23 C -0.1567(3) 0.12716(17) 0.3022(3) 0.0413(17) Uani 1 1 d . . . . .
C24 C -0.1058(3) 0.11834(19) 0.2848(4) 0.0479(19) Uani 1 1 d . . . . .
H24 H -0.0933 0.0979 0.2815 0.058 Uiso 1 1 calc R . . . .
C25 C -0.1109(3) 0.16896(17) 0.2838(3) 0.0382(16) Uani 1 1 d . . . . .
H25 H -0.1013 0.1899 0.2796 0.046 Uiso 1 1 calc R . . . .
C26 C -0.3751(4) 0.1524(2) 0.3128(4) 0.056(2) Uani 1 1 d . . . . .
H26A H -0.3998 0.1699 0.3090 0.068 Uiso 1 1 calc R . . . .
H26B H -0.3967 0.1337 0.3190 0.068 Uiso 1 1 calc R . . . .
C27 C -0.3433(4) 0.1485(2) 0.2591(4) 0.062(3) Uani 1 1 d . . . . .
H27A H -0.3263 0.1281 0.2579 0.074 Uiso 1 1 calc R . . . .
H27B H -0.3675 0.1504 0.2278 0.074 Uiso 1 1 calc R . . . .
C28 C -0.2984(4) 0.1911(2) 0.2153(3) 0.051(2) Uani 1 1 d . . . . .
H28 H -0.3210 0.1883 0.1851 0.061 Uiso 1 1 calc R . . . .
C29 C -0.2590(3) 0.21576(18) 0.2157(3) 0.0418(18) Uani 1 1 d . . . . .
C30 C -0.2444(3) 0.23783(19) 0.1766(3) 0.0454(19) Uani 1 1 d . . . . .
H30 H -0.2588 0.2397 0.1414 0.054 Uiso 1 1 calc R . . . .
C31 C -0.1981(3) 0.24484(16) 0.2503(3) 0.0388(17) Uani 1 1 d . . . . .
H31 H -0.1739 0.2537 0.2751 0.047 Uiso 1 1 calc R . . . .
C32 C -0.3675(3) 0.1794(2) 0.3993(4) 0.051(2) Uani 1 1 d . . . . .
H32A H -0.3508 0.1777 0.4353 0.061 Uiso 1 1 calc R . . . .
H32B H -0.4053 0.1735 0.4028 0.061 Uiso 1 1 calc R . . . .
C33 C -0.3638(3) 0.2133(2) 0.3794(4) 0.052(2) Uani 1 1 d . . . . .
H33A H -0.3812 0.2155 0.3438 0.063 Uiso 1 1 calc R . . . .
H33B H -0.3817 0.2271 0.4053 0.063 Uiso 1 1 calc R . . . .
C34 C -0.2877(3) 0.24624(19) 0.3943(3) 0.0460(19) Uani 1 1 d . . . . .
H34 H -0.3110 0.2610 0.4095 0.055 Uiso 1 1 calc R . . . .
C35 C -0.2310(3) 0.25239(18) 0.3933(3) 0.0418(17) Uani 1 1 d . . . . .
C36 C -0.2005(3) 0.27708(17) 0.4115(3) 0.0406(17) Uani 1 1 d . . . . .
H36 H -0.2140 0.2957 0.4259 0.049 Uiso 1 1 calc R . . . .
C37 C -0.1462(3) 0.24099(17) 0.3838(3) 0.0391(17) Uani 1 1 d . . . . .
H37 H -0.1144 0.2303 0.3755 0.047 Uiso 1 1 calc R . . . .
C38 C -0.2260(4) 0.1832(2) 0.4750(4) 0.057(2) Uani 1 1 d . . . . .
H38A H -0.1982 0.1989 0.4746 0.085 Uiso 1 1 calc GR . . . .
H38B H -0.2185 0.1683 0.5037 0.085 Uiso 1 1 calc GR . . . .
H38C H -0.2605 0.1929 0.4817 0.085 Uiso 1 1 calc GR . . . .
C39 C 0.0648(4) 0.1507(2) 0.6270(4) 0.059(2) Uani 1 1 d . . . . .
H39A H 0.0599 0.1680 0.6524 0.071 Uiso 1 1 calc R . . . .
H39B H 0.0710 0.1320 0.6487 0.071 Uiso 1 1 calc R . . . .
C40 C 0.0133(4) 0.1465(2) 0.5938(4) 0.061(3) Uani 1 1 d . . . . .
H40A H 0.0136 0.1263 0.5755 0.073 Uiso 1 1 calc R . . . .
H40B H -0.0180 0.1472 0.6180 0.073 Uiso 1 1 calc R . . . .
C41 C -0.0322(3) 0.1889(2) 0.5490(4) 0.054(2) Uani 1 1 d . . . . .
H41 H -0.0624 0.1851 0.5709 0.065 Uiso 1 1 calc R . . . .
C42 C -0.0321(3) 0.2142(2) 0.5104(3) 0.0465(19) Uani 1 1 d . . . . .
C43 C -0.0707(3) 0.23530(18) 0.4945(3) 0.0457(19) Uani 1 1 d . . . . .
H43 H -0.1059 0.2365 0.5081 0.055 Uiso 1 1 calc R . . . .
C44 C 0.0021(3) 0.24334(16) 0.4486(3) 0.0386(17) Uani 1 1 d . . . . .
H44 H 0.0265 0.2523 0.4239 0.046 Uiso 1 1 calc R . . . .
C45 C 0.1428(4) 0.1277(2) 0.5796(4) 0.057(2) Uani 1 1 d . . . . .
H45A H 0.1521 0.1172 0.6138 0.069 Uiso 1 1 calc R . . . .
H45B H 0.1763 0.1328 0.5609 0.069 Uiso 1 1 calc R . . . .
C46 C 0.1109(4) 0.1057(2) 0.5445(4) 0.059(2) Uani 1 1 d . . . . .
H46A H 0.1341 0.0889 0.5314 0.071 Uiso 1 1 calc R . . . .
H46B H 0.0816 0.0965 0.5657 0.071 Uiso 1 1 calc R . . . .
C47 C 0.0739(4) 0.10900(19) 0.4539(4) 0.048(2) Uani 1 1 d . . . . .
H47 H 0.0755 0.0873 0.4522 0.058 Uiso 1 1 calc R . . . .
C48 C 0.0544(3) 0.12690(17) 0.4071(3) 0.0430(18) Uani 1 1 d . . . . .
C49 C 0.0353(4) 0.11793(19) 0.3562(3) 0.0478(19) Uani 1 1 d . . . . .
H49 H 0.0314 0.0975 0.3435 0.057 Uiso 1 1 calc R . . . .
C50 C 0.0340(3) 0.16863(17) 0.3623(3) 0.0378(16) Uani 1 1 d . . . . .
H50 H 0.0284 0.1895 0.3531 0.045 Uiso 1 1 calc R . . . .
C51 C 0.1503(4) 0.1797(2) 0.6214(4) 0.053(2) Uani 1 1 d . . . . .
H51A H 0.1860 0.1789 0.6047 0.063 Uiso 1 1 calc R . . . .
H51B H 0.1539 0.1736 0.6597 0.063 Uiso 1 1 calc R . . . .
C52 C 0.1286(4) 0.2127(2) 0.6182(3) 0.051(2) Uani 1 1 d . . . . .
H52A H 0.0934 0.2139 0.6358 0.062 Uiso 1 1 calc R . . . .
H52B H 0.1530 0.2270 0.6369 0.062 Uiso 1 1 calc R . . . .
C53 C 0.1419(3) 0.24687(19) 0.5419(4) 0.0466(19) Uani 1 1 d . . . . .
H53 H 0.1547 0.2619 0.5663 0.056 Uiso 1 1 calc R . . . .
C54 C 0.1425(3) 0.25320(17) 0.4839(3) 0.0383(16) Uani 1 1 d . . . . .
C55 C 0.1590(3) 0.27844(18) 0.4535(3) 0.0410(17) Uani 1 1 d . . . . .
H55 H 0.1714 0.2973 0.4677 0.049 Uiso 1 1 calc R . . . .
C56 C 0.1341(3) 0.24179(18) 0.3980(3) 0.0409(17) Uani 1 1 d . . . . .
H56 H 0.1269 0.2310 0.3656 0.049 Uiso 1 1 calc R . . . .
C57 C 0.2256(3) 0.1849(2) 0.4813(4) 0.058(2) Uani 1 1 d . . . . .
H57A H 0.2282 0.1986 0.4501 0.087 Uiso 1 1 calc GR . . . .
H57B H 0.2550 0.1701 0.4804 0.087 Uiso 1 1 calc GR . . . .
H57C H 0.2276 0.1970 0.5145 0.087 Uiso 1 1 calc GR . . . .
C58 C 0.3227(4) 0.4383(2) 0.0494(4) 0.062(3) Uani 1 1 d . . . . .
H58A H 0.3377 0.4208 0.0291 0.075 Uiso 1 1 calc R . . . .
H58B H 0.3430 0.4569 0.0393 0.075 Uiso 1 1 calc R . . . .
C59 C 0.2630(4) 0.4427(2) 0.0326(4) 0.059(2) Uani 1 1 d . . . . .
H59A H 0.2501 0.4631 0.0443 0.070 Uiso 1 1 calc R . . . .
H59B H 0.2592 0.4412 -0.0070 0.070 Uiso 1 1 calc R . . . .
C60 C 0.2003(4) 0.40065(19) 0.0304(4) 0.049(2) Uani 1 1 d . . . . .
H60 H 0.1962 0.4045 -0.0070 0.058 Uiso 1 1 calc R . . . .
C61 C 0.1715(3) 0.37563(17) 0.0563(3) 0.0390(17) Uani 1 1 d . . . . .
C62 C 0.1360(3) 0.35396(17) 0.0371(3) 0.0411(17) Uani 1 1 d . . . . .
H62 H 0.1229 0.3527 0.0013 0.049 Uiso 1 1 calc R . . . .
C63 C 0.1515(3) 0.34512(17) 0.1230(3) 0.0385(17) Uani 1 1 d . . . . .
H63 H 0.1505 0.3359 0.1577 0.046 Uiso 1 1 calc R . . . .
C64 C 0.3404(4) 0.4615(2) 0.1406(4) 0.061(2) Uani 1 1 d . . . . .
H64A H 0.3714 0.4720 0.1243 0.073 Uiso 1 1 calc R . . . .
H64B H 0.3496 0.4563 0.1783 0.073 Uiso 1 1 calc R . . . .
C65 C 0.2926(4) 0.4835(2) 0.1403(4) 0.064(3) Uani 1 1 d . . . . .
H65A H 0.2987 0.5002 0.1666 0.076 Uiso 1 1 calc R . . . .
H65B H 0.2888 0.4928 0.1041 0.076 Uiso 1 1 calc R . . . .
C66 C 0.2024(4) 0.48098(19) 0.1744(3) 0.049(2) Uani 1 1 d . . . . .
H66 H 0.2037 0.5026 0.1794 0.059 Uiso 1 1 calc R . . . .
C67 C 0.1546(4) 0.46374(17) 0.1890(3) 0.0442(19) Uani 1 1 d . . . . .
C68 C 0.1054(4) 0.47296(19) 0.2098(3) 0.0473(19) Uani 1 1 d . . . . .
H68 H 0.0947 0.4935 0.2164 0.057 Uiso 1 1 calc R . . . .
C69 C 0.1063(3) 0.42286(18) 0.2038(3) 0.0439(18) Uani 1 1 d . . . . .
H69 H 0.0952 0.4021 0.2056 0.053 Uiso 1 1 calc R . . . .
C70 C 0.3738(4) 0.4099(2) 0.1183(5) 0.066(3) Uani 1 1 d . . . . .
H70A H 0.3860 0.4110 0.1562 0.080 Uiso 1 1 calc R . . . .
H70B H 0.4040 0.4155 0.0948 0.080 Uiso 1 1 calc R . . . .
C71 C 0.3566(4) 0.3768(2) 0.1056(4) 0.063(3) Uani 1 1 d . . . . .
H71A H 0.3459 0.3751 0.0673 0.076 Uiso 1 1 calc R . . . .
H71B H 0.3865 0.3625 0.1121 0.076 Uiso 1 1 calc R . . . .
C72 C 0.3095(4) 0.3429(2) 0.1676(4) 0.054(2) Uani 1 1 d . . . . .
H72 H 0.3353 0.3275 0.1612 0.065 Uiso 1 1 calc R . . . .
C73 C 0.2679(3) 0.33770(18) 0.2069(3) 0.0426(18) Uani 1 1 d . . . . .
C74 C 0.2563(4) 0.31268(18) 0.2407(3) 0.0474(19) Uani 1 1 d . . . . .
H74 H 0.2756 0.2940 0.2420 0.057 Uiso 1 1 calc R . . . .
C75 C 0.1980(3) 0.34966(17) 0.2558(3) 0.0420(18) Uani 1 1 d . . . . .
H75 H 0.1689 0.3606 0.2707 0.050 Uiso 1 1 calc R . . . .
C76 C 0.3170(6) 0.4048(3) 0.2729(5) 0.089(4) Uani 1 1 d . . . . .
H76A H 0.3447 0.3935 0.2536 0.133 Uiso 1 1 calc GR . . . .
H76B H 0.2941 0.3904 0.2922 0.133 Uiso 1 1 calc GR . . . .
H76C H 0.3336 0.4189 0.2988 0.133 Uiso 1 1 calc GR . . . .
O16 O 0.0000 0.38788(18) 0.2500 0.061(2) Uani 1 2 d S T P . .
O14 O 0.3135(7) 0.4555(4) 0.3925(8) 0.100(5) Uiso 0.5 1 d . . . . .
O9 O 0.1989(3) 0.12755(18) 0.4026(3) 0.077(2) Uani 1 1 d . . . . .
H9A H 0.1954 0.1391 0.4293 0.115 Uiso 1 1 calc GR . . . .
C77 C 0.1894(6) 0.1451(3) 0.3525(5) 0.095(4) Uani 1 1 d . . . . .
H77A H 0.2169 0.1401 0.3260 0.142 Uiso 1 1 calc GR . . . .
H77B H 0.1905 0.1671 0.3605 0.142 Uiso 1 1 calc GR . . . .
H77C H 0.1545 0.1398 0.3378 0.142 Uiso 1 1 calc GR . . . .
O18 O -0.1413(6) 0.0645(4) 0.4154(7) 0.080(4) Uiso 0.5 1 d . . . . .
O10 O 0.2400(4) 0.4604(2) 0.3028(4) 0.106(3) Uani 1 1 d . . . . .
H10 H 0.2538 0.4476 0.2819 0.159 Uiso 1 1 calc GR . . . .
C78 C 0.1924(6) 0.4476(3) 0.3256(5) 0.088(4) Uani 1 1 d . . . . .
H78A H 0.1623 0.4520 0.3019 0.132 Uiso 1 1 calc GR . . . .
H78B H 0.1860 0.4566 0.3611 0.132 Uiso 1 1 calc GR . . . .
H78C H 0.1965 0.4253 0.3293 0.132 Uiso 1 1 calc GR . . . .
O15 O 0.2643(8) 0.5219(5) 0.2856(8) 0.105(6) Uiso 0.5 1 d . . . . .
O11 O -0.0636(3) 0.44825(16) 0.4963(3) 0.0711(19) Uani 1 1 d . . . . .
H11A H -0.0540 0.4339 0.5165 0.107 Uiso 1 1 calc GR . . . .
C79 C -0.0764(5) 0.4359(2) 0.4427(5) 0.071(3) Uani 1 1 d . . . . .
H79A H -0.0577 0.4478 0.4151 0.106 Uiso 1 1 calc GR . . . .
H79B H -0.1148 0.4373 0.4366 0.106 Uiso 1 1 calc GR . . . .
H79C H -0.0653 0.4144 0.4407 0.106 Uiso 1 1 calc GR . . . .
O17 O 0.0000 0.20453(19) 0.2500 0.070(3) Uani 1 2 d S T P . .
O12 O -0.1529(4) 0.12499(19) 0.4478(3) 0.084(2) Uani 1 1 d . . . . .
H12A H -0.1765 0.1378 0.4554 0.127 Uiso 1 1 calc GR . . . .
C80 C -0.1004(6) 0.1416(3) 0.4389(6) 0.098(4) Uani 1 1 d . . . . .
H80A H -0.0904 0.1401 0.4008 0.147 Uiso 1 1 calc GR . . . .
H80B H -0.0728 0.1321 0.4612 0.147 Uiso 1 1 calc GR . . . .
H80C H -0.1043 0.1632 0.4488 0.147 Uiso 1 1 calc GR . . . .
O19 O 0.1712(5) 0.0683(3) 0.3905(6) 0.065(3) Uiso 0.5 1 d . . . . .
O13 O -0.1435(5) 0.4465(3) 0.5709(5) 0.052(3) Uiso 0.5 1 d . . . . .
H13 H -0.1272 0.4476 0.5416 0.079 Uiso 0.5 1 calc GR . . . .
C81 C -0.1712(7) 0.4736(4) 0.5797(7) 0.048(4) Uiso 0.5 1 d . . . . .
H81A H -0.1729 0.4854 0.5461 0.073 Uiso 0.5 1 calc GR . . . .
H81B H -0.1529 0.4857 0.6073 0.073 Uiso 0.5 1 calc GR . . . .
H81C H -0.2072 0.4688 0.5919 0.073 Uiso 0.5 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.197(6) . ?
Dy1 N1 2.662(7) . ?
Dy1 N2 2.481(7) . ?
Dy1 N3 2.427(6) . ?
Dy1 N5 2.496(7) . ?
Dy1 N6 2.487(6) . ?
Dy1 N8 2.457(7) . ?
Dy1 N9 2.468(6) . ?
Dy2 O2 2.181(6) . ?
Dy2 N11 2.679(6) . ?
Dy2 N12 2.476(7) . ?
Dy2 N13 2.430(6) . ?
Dy2 N15 2.477(6) . ?
Dy2 N16 2.469(6) . ?
Dy2 N18 2.522(7) . ?
Dy2 N19 2.493(6) . ?
Dy3 O3 2.182(6) . ?
Dy3 N21 2.680(7) . ?
Dy3 N22 2.517(7) . ?
Dy3 N23 2.518(6) . ?
Dy3 N25 2.497(7) . ?
Dy3 N26 2.407(6) . ?
Dy3 N28 2.463(7) . ?
Dy3 N29 2.468(6) . ?
Dy4 O4 2.201(6) . ?
Dy4 N31 2.679(7) . ?
Dy4 N32 2.473(7) . ?
Dy4 N33 2.493(6) . ?
Dy4 N35 2.496(7) . ?
Dy4 N36 2.438(7) . ?
Dy4 N38 2.446(7) . ?
Dy4 N39 2.474(6) . ?
Cu1 N14 1.978(6) . ?
Cu1 N14 1.978(6) 2 ?
Cu1 N27 1.972(6) 2 ?
Cu1 N27 1.972(6) . ?
Cu2 N4 1.987(6) . ?
Cu2 N4 1.987(6) 2 ?
Cu2 N37 1.983(7) . ?
Cu2 N37 1.983(7) 2 ?
Cu3 O5 2.322(8) . ?
Cu3 N10 1.984(7) . ?
Cu3 N17 2.000(6) . ?
Cu3 N24 2.004(6) . ?
Cu3 N34 1.987(6) 2 ?
Cu4 O6 2.355(9) . ?
Cu4 N7 1.972(6) . ?
Cu4 N20 1.987(6) 2 ?
Cu4 N30 1.998(6) . ?
Cu4 N40 1.983(7) . ?
O1 C19 1.411(11) . ?
O2 C38 1.393(10) . ?
O3 C57 1.403(10) . ?
O4 C76 1.423(13) . ?
O5 H5A 0.9562 . ?
O5 H5B 0.9557 . ?
O6 H6A 0.9384 . ?
O6 H6B 0.9381 . ?
N1 C1 1.499(11) . ?
N1 C7 1.489(11) . ?
N1 C13 1.474(11) . ?
N2 C2 1.472(10) . ?
N2 C3 1.272(10) . ?
N3 C4 1.377(9) . ?
N3 C6 1.342(10) . ?
N4 C5 1.353(10) . ?
N4 C6 1.358(10) . ?
N5 C8 1.477(10) . ?
N5 C9 1.270(10) . ?
N6 C10 1.399(9) . ?
N6 C12 1.327(9) . ?
N7 C11 1.402(10) . ?
N7 C12 1.349(9) . ?
N8 C14 1.451(11) . ?
N8 C15 1.268(10) . ?
N9 C16 1.392(9) . ?
N9 C18 1.321(10) . ?
N10 C17 1.366(10) . ?
N10 C18 1.355(10) . ?
N11 C20 1.497(11) . ?
N11 C26 1.467(11) . ?
N11 C32 1.481(11) . ?
N12 C21 1.477(10) . ?
N12 C22 1.293(11) . ?
N13 C23 1.392(10) . ?
N13 C25 1.337(9) . ?
N14 C24 1.376(10) . ?
N14 C25 1.349(9) . ?
N15 C33 1.451(10) . ?
N15 C34 1.253(10) . ?
N16 C35 1.401(10) . ?
N16 C37 1.343(10) . ?
N17 C36 1.369(10) . ?
N17 C37 1.339(9) . ?
N18 C27 1.457(10) . ?
N18 C28 1.275(11) . ?
N19 C29 1.376(10) . ?
N19 C31 1.341(9) . ?
N20 Cu4 1.986(6) 2 ?
N20 C30 1.357(10) . ?
N20 C31 1.345(10) . ?
N21 C39 1.492(11) . ?
N21 C45 1.472(12) . ?
N21 C51 1.500(11) . ?
N22 C40 1.461(10) . ?
N22 C41 1.282(11) . ?
N23 C42 1.391(10) . ?
N23 C44 1.303(9) . ?
N24 C43 1.356(10) . ?
N24 C44 1.352(10) . ?
N25 C46 1.481(10) . ?
N25 C47 1.274(11) . ?
N26 C48 1.398(10) . ?
N26 C50 1.346(9) . ?
N27 C49 1.376(10) . ?
N27 C50 1.349(10) . ?
N28 C52 1.447(10) . ?
N28 C53 1.274(10) . ?
N29 C54 1.407(9) . ?
N29 C56 1.334(10) . ?
N30 C55 1.375(10) . ?
N30 C56 1.356(10) . ?
N31 C58 1.503(12) . ?
N31 C64 1.475(12) . ?
N31 C70 1.472(12) . ?
N32 C59 1.466(10) . ?
N32 C60 1.287(11) . ?
N33 C61 1.395(10) . ?
N33 C63 1.325(9) . ?
N34 Cu3 1.987(6) 2 ?
N34 C62 1.388(10) . ?
N34 C63 1.346(10) . ?
N35 C65 1.466(11) . ?
N35 C66 1.265(11) . ?
N36 C67 1.391(10) . ?
N36 C69 1.329(10) . ?
N37 C68 1.373(10) . ?
N37 C69 1.344(10) . ?
N38 C71 1.439(11) . ?
N38 C72 1.296(11) . ?
N39 C73 1.403(10) . ?
N39 C75 1.309(10) . ?
N40 C74 1.368(10) . ?
N40 C75 1.376(10) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C1 C2 1.544(12) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 H3 0.9300 . ?
C3 C4 1.445(11) . ?
C4 C5 1.403(11) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 C8 1.524(13) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 H9 0.9300 . ?
C9 C10 1.430(10) . ?
C10 C11 1.346(11) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 C14 1.551(12) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 H15 0.9300 . ?
C15 C16 1.446(12) . ?
C16 C17 1.373(11) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 C21 1.513(12) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 H22 0.9300 . ?
C22 C23 1.430(11) . ?
C23 C24 1.377(11) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C26 C27 1.532(12) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 H28 0.9300 . ?
C28 C29 1.436(11) . ?
C29 C30 1.386(11) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C32 C33 1.530(12) . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C34 H34 0.9300 . ?
C34 C35 1.423(11) . ?
C35 C36 1.369(11) . ?
C36 H36 0.9300 . ?
C37 H37 0.9300 . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C39 C40 1.517(12) . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C41 H41 0.9300 . ?
C41 C42 1.432(12) . ?
C42 C43 1.368(11) . ?
C43 H43 0.9300 . ?
C44 H44 0.9300 . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C45 C46 1.495(13) . ?
C46 H46A 0.9700 . ?
C46 H46B 0.9700 . ?
C47 H47 0.9300 . ?
C47 C48 1.450(11) . ?
C48 C49 1.380(11) . ?
C49 H49 0.9300 . ?
C50 H50 0.9300 . ?
C51 H51A 0.9700 . ?
C51 H51B 0.9700 . ?
C51 C52 1.511(13) . ?
C52 H52A 0.9700 . ?
C52 H52B 0.9700 . ?
C53 H53 0.9300 . ?
C53 C54 1.435(11) . ?
C54 C55 1.369(11) . ?
C55 H55 0.9300 . ?
C56 H56 0.9300 . ?
C57 H57A 0.9600 . ?
C57 H57B 0.9600 . ?
C57 H57C 0.9600 . ?
C58 H58A 0.9700 . ?
C58 H58B 0.9700 . ?
C58 C59 1.539(14) . ?
C59 H59A 0.9700 . ?
C59 H59B 0.9700 . ?
C60 H60 0.9300 . ?
C60 C61 1.429(11) . ?
C61 C62 1.358(11) . ?
C62 H62 0.9300 . ?
C63 H63 0.9300 . ?
C64 H64A 0.9700 . ?
C64 H64B 0.9700 . ?
C64 C65 1.507(14) . ?
C65 H65A 0.9700 . ?
C65 H65B 0.9700 . ?
C66 H66 0.9300 . ?
C66 C67 1.437(12) . ?
C67 C68 1.373(12) . ?
C68 H68 0.9300 . ?
C69 H69 0.9300 . ?
C70 H70A 0.9700 . ?
C70 H70B 0.9700 . ?
C70 C71 1.506(14) . ?
C71 H71A 0.9700 . ?
C71 H71B 0.9700 . ?
C72 H72 0.9300 . ?
C72 C73 1.420(12) . ?
C73 C74 1.377(11) . ?
C74 H74 0.9300 . ?
C75 H75 0.9300 . ?
C76 H76A 0.9600 . ?
C76 H76B 0.9600 . ?
C76 H76C 0.9600 . ?
O9 H9A 0.8200 . ?
O9 C77 1.451(14) . ?
C77 H77A 0.9600 . ?
C77 H77B 0.9600 . ?
C77 H77C 0.9600 . ?
O10 H10 0.8200 . ?
O10 C78 1.408(15) . ?
C78 H78A 0.9600 . ?
C78 H78B 0.9600 . ?
C78 H78C 0.9600 . ?
O11 H11A 0.8200 . ?
O11 C79 1.439(13) . ?
C79 H79A 0.9600 . ?
C79 H79B 0.9600 . ?
C79 H79C 0.9600 . ?
O12 H12A 0.8200 . ?
O12 C80 1.491(15) . ?
C80 H80A 0.9600 . ?
C80 H80B 0.9600 . ?
C80 H80C 0.9600 . ?
O13 H13 0.8200 . ?
O13 C81 1.361(19) . ?
C81 H81A 0.9600 . ?
C81 H81B 0.9600 . ?
C81 H81C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 N1 82.2(2) . . ?
O1 Dy1 N2 77.0(2) . . ?
O1 Dy1 N3 101.0(2) . . ?
O1 Dy1 N5 145.1(2) . . ?
O1 Dy1 N6 148.0(2) . . ?
O1 Dy1 N8 87.8(2) . . ?
O1 Dy1 N9 77.3(2) . . ?
N2 Dy1 N1 66.4(2) . . ?
N2 Dy1 N5 78.9(2) . . ?
N2 Dy1 N6 130.9(2) . . ?
N3 Dy1 N1 131.4(2) . . ?
N3 Dy1 N2 67.3(2) . . ?
N3 Dy1 N5 92.4(2) . . ?
N3 Dy1 N6 81.0(2) . . ?
N3 Dy1 N8 159.6(2) . . ?
N3 Dy1 N9 95.5(2) . . ?
N5 Dy1 N1 65.1(2) . . ?
N6 Dy1 N1 120.6(2) . . ?
N6 Dy1 N5 65.6(2) . . ?
N8 Dy1 N1 67.6(2) . . ?
N8 Dy1 N2 133.0(2) . . ?
N8 Dy1 N5 90.5(2) . . ?
N8 Dy1 N6 82.0(2) . . ?
N8 Dy1 N9 68.4(2) . . ?
N9 Dy1 N1 131.7(2) . . ?
N9 Dy1 N2 145.3(2) . . ?
N9 Dy1 N5 133.7(2) . . ?
N9 Dy1 N6 70.8(2) . . ?
O2 Dy2 N11 82.2(2) . . ?
O2 Dy2 N12 77.1(2) . . ?
O2 Dy2 N13 96.6(2) . . ?
O2 Dy2 N15 87.9(2) . . ?
O2 Dy2 N16 78.9(2) . . ?
O2 Dy2 N18 144.2(2) . . ?
O2 Dy2 N19 149.7(2) . . ?
N12 Dy2 N11 65.8(2) . . ?
N12 Dy2 N15 132.3(2) . . ?
N12 Dy2 N18 77.9(2) . . ?
N12 Dy2 N19 128.2(2) . . ?
N13 Dy2 N11 132.7(2) . . ?
N13 Dy2 N12 67.8(2) . . ?
N13 Dy2 N15 159.8(2) . . ?
N13 Dy2 N16 93.7(2) . . ?
N13 Dy2 N18 97.2(2) . . ?
N13 Dy2 N19 81.6(2) . . ?
N15 Dy2 N11 67.3(2) . . ?
N15 Dy2 N18 90.3(2) . . ?
N15 Dy2 N19 84.6(2) . . ?
N16 Dy2 N11 131.6(2) . . ?
N16 Dy2 N12 147.5(2) . . ?
N16 Dy2 N15 67.8(2) . . ?
N16 Dy2 N18 132.7(2) . . ?
N16 Dy2 N19 71.1(2) . . ?
N18 Dy2 N11 64.3(2) . . ?
N19 Dy2 N11 121.1(2) . . ?
N19 Dy2 N18 65.3(2) . . ?
O3 Dy3 N21 81.3(2) . . ?
O3 Dy3 N22 144.2(2) . . ?
O3 Dy3 N23 149.7(2) . . ?
O3 Dy3 N25 77.3(2) . . ?
O3 Dy3 N26 98.0(2) . . ?
O3 Dy3 N28 88.2(2) . . ?
O3 Dy3 N29 79.3(2) . . ?
N22 Dy3 N21 65.2(2) . . ?
N22 Dy3 N23 65.4(2) . . ?
N23 Dy3 N21 122.2(2) . . ?
N25 Dy3 N21 65.1(2) . . ?
N25 Dy3 N22 77.5(2) . . ?
N25 Dy3 N23 128.1(2) . . ?
N26 Dy3 N21 131.7(2) . . ?
N26 Dy3 N22 95.4(2) . . ?
N26 Dy3 N23 80.6(2) . . ?
N26 Dy3 N25 67.7(2) . . ?
N26 Dy3 N28 160.5(2) . . ?
N26 Dy3 N29 94.6(2) . . ?
N28 Dy3 N21 67.3(2) . . ?
N28 Dy3 N22 90.1(2) . . ?
N28 Dy3 N23 84.7(2) . . ?
N28 Dy3 N25 131.8(2) . . ?
N28 Dy3 N29 68.3(2) . . ?
N29 Dy3 N21 131.7(2) . . ?
N29 Dy3 N22 132.4(2) . . ?
N29 Dy3 N23 70.7(2) . . ?
N29 Dy3 N25 148.0(2) . . ?
O4 Dy4 N31 82.7(2) . . ?
O4 Dy4 N32 144.7(2) . . ?
O4 Dy4 N33 148.7(2) . . ?
O4 Dy4 N35 76.3(2) . . ?
O4 Dy4 N36 96.2(2) . . ?
O4 Dy4 N38 89.7(3) . . ?
O4 Dy4 N39 79.0(2) . . ?
N32 Dy4 N31 64.8(2) . . ?
N32 Dy4 N33 66.1(2) . . ?
N32 Dy4 N35 77.8(2) . . ?
N32 Dy4 N39 132.9(2) . . ?
N33 Dy4 N31 121.7(2) . . ?
N33 Dy4 N35 129.6(2) . . ?
N35 Dy4 N31 65.5(2) . . ?
N36 Dy4 N31 132.0(2) . . ?
N36 Dy4 N32 95.8(2) . . ?
N36 Dy4 N33 81.8(2) . . ?
N36 Dy4 N35 67.7(2) . . ?
N36 Dy4 N38 160.5(2) . . ?
N36 Dy4 N39 94.2(2) . . ?
N38 Dy4 N31 67.1(2) . . ?
N38 Dy4 N32 89.9(2) . . ?
N38 Dy4 N33 83.5(2) . . ?
N38 Dy4 N35 131.8(2) . . ?
N38 Dy4 N39 68.7(2) . . ?
N39 Dy4 N31 131.8(2) . . ?
N39 Dy4 N33 70.1(2) . . ?
N39 Dy4 N35 147.2(2) . . ?
N14 Cu1 N14 174.5(3) 2 . ?
N27 Cu1 N14 90.2(3) . . ?
N27 Cu1 N14 90.2(3) 2 2 ?
N27 Cu1 N14 89.6(3) 2 . ?
N27 Cu1 N14 89.6(3) . 2 ?
N27 Cu1 N27 174.0(3) . 2 ?
N4 Cu2 N4 174.0(4) 2 . ?
N37 Cu2 N4 91.0(3) 2 2 ?
N37 Cu2 N4 88.9(3) . 2 ?
N37 Cu2 N4 91.0(3) . . ?
N37 Cu2 N4 88.9(3) 2 . ?
N37 Cu2 N37 177.5(4) 2 . ?
N10 Cu3 O5 93.7(3) . . ?
N10 Cu3 N17 171.7(3) . . ?
N10 Cu3 N24 90.2(2) . . ?
N10 Cu3 N34 89.2(3) . 2 ?
N17 Cu3 O5 94.6(3) . . ?
N17 Cu3 N24 88.3(2) . . ?
N24 Cu3 O5 97.4(3) . . ?
N34 Cu3 O5 96.5(3) 2 . ?
N34 Cu3 N17 90.3(2) 2 . ?
N34 Cu3 N24 166.2(3) 2 . ?
N7 Cu4 O6 97.8(3) . . ?
N7 Cu4 N20 165.4(3) . 2 ?
N7 Cu4 N30 90.9(2) . . ?
N7 Cu4 N40 89.1(2) . . ?
N20 Cu4 O6 96.7(3) 2 . ?
N20 Cu4 N30 87.9(2) 2 . ?
N30 Cu4 O6 94.3(3) . . ?
N40 Cu4 O6 92.9(3) . . ?
N40 Cu4 N20 90.2(3) . 2 ?
N40 Cu4 N30 172.7(3) . . ?
C19 O1 Dy1 134.8(6) . . ?
C38 O2 Dy2 135.3(5) . . ?
C57 O3 Dy3 134.5(6) . . ?
C76 O4 Dy4 131.9(6) . . ?
Cu3 O5 H5A 125.8 . . ?
Cu3 O5 H5B 126.2 . . ?
H5A O5 H5B 108.0 . . ?
Cu4 O6 H6A 125.5 . . ?
Cu4 O6 H6B 126.0 . . ?
H6A O6 H6B 108.5 . . ?
C1 N1 Dy1 103.8(5) . . ?
C7 N1 Dy1 114.6(5) . . ?
C7 N1 C1 111.4(7) . . ?
C13 N1 Dy1 107.2(5) . . ?
C13 N1 C1 107.8(7) . . ?
C13 N1 C7 111.5(7) . . ?
C2 N2 Dy1 120.9(5) . . ?
C3 N2 Dy1 118.0(5) . . ?
C3 N2 C2 120.0(7) . . ?
C4 N3 Dy1 115.5(5) . . ?
C6 N3 Dy1 139.9(5) . . ?
C6 N3 C4 103.9(6) . . ?
C5 N4 Cu2 128.9(5) . . ?
C5 N4 C6 104.3(6) . . ?
C6 N4 Cu2 126.7(5) . . ?
C8 N5 Dy1 118.8(5) . . ?
C9 N5 Dy1 120.3(5) . . ?
C9 N5 C8 120.7(7) . . ?
C10 N6 Dy1 117.4(4) . . ?
C12 N6 Dy1 138.3(5) . . ?
C12 N6 C10 104.4(6) . . ?
C11 N7 Cu4 126.4(5) . . ?
C12 N7 Cu4 129.2(5) . . ?
C12 N7 C11 104.1(6) . . ?
C14 N8 Dy1 118.6(5) . . ?
C15 N8 Dy1 118.7(6) . . ?
C15 N8 C14 121.9(7) . . ?
C16 N9 Dy1 113.4(5) . . ?
C18 N9 Dy1 141.9(5) . . ?
C18 N9 C16 104.6(6) . . ?
C17 N10 Cu3 129.8(5) . . ?
C18 N10 Cu3 125.6(5) . . ?
C18 N10 C17 104.4(7) . . ?
C20 N11 Dy2 103.9(5) . . ?
C26 N11 Dy2 115.9(5) . . ?
C26 N11 C20 111.3(7) . . ?
C26 N11 C32 109.3(7) . . ?
C32 N11 Dy2 106.9(5) . . ?
C32 N11 C20 109.2(6) . . ?
C21 N12 Dy2 122.0(5) . . ?
C22 N12 Dy2 117.9(5) . . ?
C22 N12 C21 119.3(7) . . ?
C23 N13 Dy2 115.3(5) . . ?
C25 N13 Dy2 139.4(5) . . ?
C25 N13 C23 104.6(6) . . ?
C24 N14 Cu1 126.7(5) . . ?
C25 N14 Cu1 128.0(5) . . ?
C25 N14 C24 105.2(6) . . ?
C33 N15 Dy2 119.2(5) . . ?
C34 N15 Dy2 117.7(5) . . ?
C34 N15 C33 122.7(7) . . ?
C35 N16 Dy2 113.9(5) . . ?
C37 N16 Dy2 142.3(5) . . ?
C37 N16 C35 103.8(6) . . ?
C36 N17 Cu3 128.9(5) . . ?
C37 N17 Cu3 125.8(5) . . ?
C37 N17 C36 105.1(6) . . ?
C27 N18 Dy2 119.2(6) . . ?
C28 N18 Dy2 119.7(6) . . ?
C28 N18 C27 120.9(8) . . ?
C29 N19 Dy2 117.7(5) . . ?
C31 N19 Dy2 139.6(5) . . ?
C31 N19 C29 102.7(6) . . ?
C30 N20 Cu4 124.9(5) . 2 ?
C31 N20 Cu4 128.9(5) . 2 ?
C31 N20 C30 105.0(6) . . ?
C39 N21 Dy3 114.2(5) . . ?
C39 N21 C51 109.8(7) . . ?
C45 N21 Dy3 104.1(5) . . ?
C45 N21 C39 111.3(7) . . ?
C45 N21 C51 110.9(7) . . ?
C51 N21 Dy3 106.3(5) . . ?
C40 N22 Dy3 118.2(6) . . ?
C41 N22 Dy3 120.4(6) . . ?
C41 N22 C40 121.4(8) . . ?
C42 N23 Dy3 116.6(5) . . ?
C44 N23 Dy3 139.3(5) . . ?
C44 N23 C42 104.1(6) . . ?
C43 N24 Cu3 125.2(5) . . ?
C44 N24 Cu3 129.0(5) . . ?
C44 N24 C43 104.6(6) . . ?
C46 N25 Dy3 121.8(6) . . ?
C47 N25 Dy3 117.7(5) . . ?
C47 N25 C46 119.9(7) . . ?
C48 N26 Dy3 116.8(5) . . ?
C50 N26 Dy3 139.8(5) . . ?
C50 N26 C48 103.0(6) . . ?
C49 N27 Cu1 126.1(5) . . ?
C50 N27 Cu1 128.0(5) . . ?
C50 N27 C49 105.7(6) . . ?
C52 N28 Dy3 119.8(5) . . ?
C53 N28 Dy3 117.8(5) . . ?
C53 N28 C52 122.0(7) . . ?
C54 N29 Dy3 114.2(4) . . ?
C56 N29 Dy3 142.2(5) . . ?
C56 N29 C54 103.6(6) . . ?
C55 N30 Cu4 129.1(5) . . ?
C56 N30 Cu4 126.3(5) . . ?
C56 N30 C55 104.3(6) . . ?
C58 N31 Dy4 114.7(5) . . ?
C64 N31 Dy4 104.3(5) . . ?
C64 N31 C58 111.9(7) . . ?
C70 N31 Dy4 106.7(5) . . ?
C70 N31 C58 109.0(8) . . ?
C70 N31 C64 110.1(8) . . ?
C59 N32 Dy4 120.6(6) . . ?
C60 N32 Dy4 120.5(5) . . ?
C60 N32 C59 118.9(7) . . ?
C61 N33 Dy4 116.3(5) . . ?
C63 N33 Dy4 140.0(5) . . ?
C63 N33 C61 103.6(6) . . ?
C62 N34 Cu3 124.1(5) . 2 ?
C63 N34 Cu3 130.8(5) . 2 ?
C63 N34 C62 104.1(6) . . ?
C65 N35 Dy4 120.7(6) . . ?
C66 N35 Dy4 117.2(5) . . ?
C66 N35 C65 120.9(8) . . ?
C67 N36 Dy4 115.1(5) . . ?
C69 N36 Dy4 140.5(5) . . ?
C69 N36 C67 103.9(7) . . ?
C68 N37 Cu2 126.6(5) . . ?
C69 N37 Cu2 129.2(5) . . ?
C69 N37 C68 104.3(7) . . ?
C71 N38 Dy4 119.8(6) . . ?
C72 N38 Dy4 117.8(6) . . ?
C72 N38 C71 122.0(8) . . ?
C73 N39 Dy4 113.2(5) . . ?
C75 N39 Dy4 141.5(5) . . ?
C75 N39 C73 105.2(6) . . ?
C74 N40 Cu4 129.4(5) . . ?
C74 N40 C75 104.3(6) . . ?
C75 N40 Cu4 125.9(5) . . ?
N1 C1 H1A 109.4 . . ?
N1 C1 H1B 109.4 . . ?
N1 C1 C2 111.1(7) . . ?
H1A C1 H1B 108.0 . . ?
C2 C1 H1A 109.4 . . ?
C2 C1 H1B 109.4 . . ?
N2 C2 C1 109.7(6) . . ?
N2 C2 H2A 109.7 . . ?
N2 C2 H2B 109.7 . . ?
C1 C2 H2A 109.7 . . ?
C1 C2 H2B 109.7 . . ?
H2A C2 H2B 108.2 . . ?
N2 C3 H3 121.1 . . ?
N2 C3 C4 117.9(7) . . ?
C4 C3 H3 121.1 . . ?
N3 C4 C3 119.5(7) . . ?
N3 C4 C5 108.3(6) . . ?
C5 C4 C3 132.1(7) . . ?
N4 C5 C4 108.8(7) . . ?
N4 C5 H5 125.6 . . ?
C4 C5 H5 125.6 . . ?
N3 C6 N4 114.7(6) . . ?
N3 C6 H6 122.7 . . ?
N4 C6 H6 122.7 . . ?
N1 C7 H7A 108.6 . . ?
N1 C7 H7B 108.6 . . ?
N1 C7 C8 114.6(7) . . ?
H7A C7 H7B 107.6 . . ?
C8 C7 H7A 108.6 . . ?
C8 C7 H7B 108.6 . . ?
N5 C8 C7 107.0(7) . . ?
N5 C8 H8A 110.3 . . ?
N5 C8 H8B 110.3 . . ?
C7 C8 H8A 110.3 . . ?
C7 C8 H8B 110.3 . . ?
H8A C8 H8B 108.6 . . ?
N5 C9 H9 120.1 . . ?
N5 C9 C10 119.8(7) . . ?
C10 C9 H9 120.1 . . ?
N6 C10 C9 116.9(6) . . ?
C11 C10 N6 109.1(6) . . ?
C11 C10 C9 133.7(7) . . ?
N7 C11 H11 125.8 . . ?
C10 C11 N7 108.3(7) . . ?
C10 C11 H11 125.8 . . ?
N6 C12 N7 114.1(7) . . ?
N6 C12 H12 123.0 . . ?
N7 C12 H12 123.0 . . ?
N1 C13 H13A 109.6 . . ?
N1 C13 H13B 109.6 . . ?
N1 C13 C14 110.4(7) . . ?
H13A C13 H13B 108.1 . . ?
C14 C13 H13A 109.6 . . ?
C14 C13 H13B 109.6 . . ?
N8 C14 C13 106.4(7) . . ?
N8 C14 H14A 110.4 . . ?
N8 C14 H14B 110.4 . . ?
C13 C14 H14A 110.4 . . ?
C13 C14 H14B 110.4 . . ?
H14A C14 H14B 108.6 . . ?
N8 C15 H15 120.4 . . ?
N8 C15 C16 119.1(8) . . ?
C16 C15 H15 120.4 . . ?
N9 C16 C15 120.2(7) . . ?
C17 C16 N9 108.0(7) . . ?
C17 C16 C15 131.7(7) . . ?
N10 C17 C16 108.8(7) . . ?
N10 C17 H17 125.6 . . ?
C16 C17 H17 125.6 . . ?
N9 C18 N10 114.1(7) . . ?
N9 C18 H18 123.0 . . ?
N10 C18 H18 123.0 . . ?
O1 C19 H19A 109.5 . . ?
O1 C19 H19B 109.5 . . ?
O1 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N11 C20 H20A 109.2 . . ?
N11 C20 H20B 109.2 . . ?
N11 C20 C21 112.3(7) . . ?
H20A C20 H20B 107.9 . . ?
C21 C20 H20A 109.2 . . ?
C21 C20 H20B 109.2 . . ?
N12 C21 C20 108.9(7) . . ?
N12 C21 H21A 109.9 . . ?
N12 C21 H21B 109.9 . . ?
C20 C21 H21A 109.9 . . ?
C20 C21 H21B 109.9 . . ?
H21A C21 H21B 108.3 . . ?
N12 C22 H22 120.8 . . ?
N12 C22 C23 118.5(7) . . ?
C23 C22 H22 120.8 . . ?
N13 C23 C22 119.7(7) . . ?
C24 C23 N13 108.5(7) . . ?
C24 C23 C22 131.8(7) . . ?
N14 C24 C23 108.2(7) . . ?
N14 C24 H24 125.9 . . ?
C23 C24 H24 125.9 . . ?
N13 C25 N14 113.5(6) . . ?
N13 C25 H25 123.2 . . ?
N14 C25 H25 123.2 . . ?
N11 C26 H26A 109.0 . . ?
N11 C26 H26B 109.0 . . ?
N11 C26 C27 113.0(7) . . ?
H26A C26 H26B 107.8 . . ?
C27 C26 H26A 109.0 . . ?
C27 C26 H26B 109.0 . . ?
N18 C27 C26 108.1(7) . . ?
N18 C27 H27A 110.1 . . ?
N18 C27 H27B 110.1 . . ?
C26 C27 H27A 110.1 . . ?
C26 C27 H27B 110.1 . . ?
H27A C27 H27B 108.4 . . ?
N18 C28 H28 120.4 . . ?
N18 C28 C29 119.3(8) . . ?
C29 C28 H28 120.4 . . ?
N19 C29 C28 117.9(7) . . ?
N19 C29 C30 110.0(7) . . ?
C30 C29 C28 132.2(8) . . ?
N20 C30 C29 107.5(7) . . ?
N20 C30 H30 126.3 . . ?
C29 C30 H30 126.3 . . ?
N19 C31 N20 114.8(7) . . ?
N19 C31 H31 122.6 . . ?
N20 C31 H31 122.6 . . ?
N11 C32 H32A 109.3 . . ?
N11 C32 H32B 109.3 . . ?
N11 C32 C33 111.5(7) . . ?
H32A C32 H32B 108.0 . . ?
C33 C32 H32A 109.3 . . ?
C33 C32 H32B 109.3 . . ?
N15 C33 C32 107.7(7) . . ?
N15 C33 H33A 110.2 . . ?
N15 C33 H33B 110.2 . . ?
C32 C33 H33A 110.2 . . ?
C32 C33 H33B 110.2 . . ?
H33A C33 H33B 108.5 . . ?
N15 C34 H34 119.3 . . ?
N15 C34 C35 121.4(7) . . ?
C35 C34 H34 119.3 . . ?
N16 C35 C34 118.9(7) . . ?
C36 C35 N16 108.2(7) . . ?
C36 C35 C34 132.6(7) . . ?
N17 C36 C35 108.8(6) . . ?
N17 C36 H36 125.6 . . ?
C35 C36 H36 125.6 . . ?
N16 C37 H37 123.0 . . ?
N17 C37 N16 114.0(7) . . ?
N17 C37 H37 123.0 . . ?
O2 C38 H38A 109.5 . . ?
O2 C38 H38B 109.5 . . ?
O2 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N21 C39 H39A 108.8 . . ?
N21 C39 H39B 108.8 . . ?
N21 C39 C40 113.6(7) . . ?
H39A C39 H39B 107.7 . . ?
C40 C39 H39A 108.8 . . ?
C40 C39 H39B 108.8 . . ?
N22 C40 C39 108.6(7) . . ?
N22 C40 H40A 110.0 . . ?
N22 C40 H40B 110.0 . . ?
C39 C40 H40A 110.0 . . ?
C39 C40 H40B 110.0 . . ?
H40A C40 H40B 108.4 . . ?
N22 C41 H41 120.5 . . ?
N22 C41 C42 119.0(8) . . ?
C42 C41 H41 120.5 . . ?
N23 C42 C41 118.5(7) . . ?
C43 C42 N23 108.5(7) . . ?
C43 C42 C41 132.9(8) . . ?
N24 C43 C42 108.2(7) . . ?
N24 C43 H43 125.9 . . ?
C42 C43 H43 125.9 . . ?
N23 C44 N24 114.5(7) . . ?
N23 C44 H44 122.7 . . ?
N24 C44 H44 122.7 . . ?
N21 C45 H45A 108.9 . . ?
N21 C45 H45B 108.9 . . ?
N21 C45 C46 113.5(7) . . ?
H45A C45 H45B 107.7 . . ?
C46 C45 H45A 108.9 . . ?
C46 C45 H45B 108.9 . . ?
N25 C46 C45 108.3(7) . . ?
N25 C46 H46A 110.0 . . ?
N25 C46 H46B 110.0 . . ?
C45 C46 H46A 110.0 . . ?
C45 C46 H46B 110.0 . . ?
H46A C46 H46B 108.4 . . ?
N25 C47 H47 120.4 . . ?
N25 C47 C48 119.1(7) . . ?
C48 C47 H47 120.4 . . ?
N26 C48 C47 118.1(7) . . ?
C49 C48 N26 109.9(7) . . ?
C49 C48 C47 132.0(7) . . ?
N27 C49 C48 107.2(7) . . ?
N27 C49 H49 126.4 . . ?
C48 C49 H49 126.4 . . ?
N26 C50 N27 114.2(6) . . ?
N26 C50 H50 122.9 . . ?
N27 C50 H50 122.9 . . ?
N21 C51 H51A 109.3 . . ?
N21 C51 H51B 109.3 . . ?
N21 C51 C52 111.7(7) . . ?
H51A C51 H51B 107.9 . . ?
C52 C51 H51A 109.3 . . ?
C52 C51 H51B 109.3 . . ?
N28 C52 C51 107.6(7) . . ?
N28 C52 H52A 110.2 . . ?
N28 C52 H52B 110.2 . . ?
C51 C52 H52A 110.2 . . ?
C51 C52 H52B 110.2 . . ?
H52A C52 H52B 108.5 . . ?
N28 C53 H53 119.4 . . ?
N28 C53 C54 121.1(7) . . ?
C54 C53 H53 119.4 . . ?
N29 C54 C53 118.4(7) . . ?
C55 C54 N29 108.5(6) . . ?
C55 C54 C53 133.0(7) . . ?
N30 C55 H55 125.5 . . ?
C54 C55 N30 109.0(7) . . ?
C54 C55 H55 125.5 . . ?
N29 C56 N30 114.6(7) . . ?
N29 C56 H56 122.7 . . ?
N30 C56 H56 122.7 . . ?
O3 C57 H57A 109.5 . . ?
O3 C57 H57B 109.5 . . ?
O3 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
N31 C58 H58A 109.1 . . ?
N31 C58 H58B 109.1 . . ?
N31 C58 C59 112.6(7) . . ?
H58A C58 H58B 107.8 . . ?
C59 C58 H58A 109.1 . . ?
C59 C58 H58B 109.1 . . ?
N32 C59 C58 107.0(7) . . ?
N32 C59 H59A 110.3 . . ?
N32 C59 H59B 110.3 . . ?
C58 C59 H59A 110.3 . . ?
C58 C59 H59B 110.3 . . ?
H59A C59 H59B 108.6 . . ?
N32 C60 H60 120.5 . . ?
N32 C60 C61 119.1(8) . . ?
C61 C60 H60 120.5 . . ?
N33 C61 C60 117.8(7) . . ?
C62 C61 N33 109.4(7) . . ?
C62 C61 C60 132.8(8) . . ?
N34 C62 H62 126.0 . . ?
C61 C62 N34 108.1(7) . . ?
C61 C62 H62 126.0 . . ?
N33 C63 N34 114.9(7) . . ?
N33 C63 H63 122.6 . . ?
N34 C63 H63 122.6 . . ?
N31 C64 H64A 109.2 . . ?
N31 C64 H64B 109.2 . . ?
N31 C64 C65 112.2(8) . . ?
H64A C64 H64B 107.9 . . ?
C65 C64 H64A 109.2 . . ?
C65 C64 H64B 109.2 . . ?
N35 C65 C64 110.4(7) . . ?
N35 C65 H65A 109.6 . . ?
N35 C65 H65B 109.6 . . ?
C64 C65 H65A 109.6 . . ?
C64 C65 H65B 109.6 . . ?
H65A C65 H65B 108.1 . . ?
N35 C66 H66 120.2 . . ?
N35 C66 C67 119.6(8) . . ?
C67 C66 H66 120.2 . . ?
N36 C67 C66 119.3(8) . . ?
C68 C67 N36 108.4(7) . . ?
C68 C67 C66 132.1(7) . . ?
N37 C68 H68 125.7 . . ?
C67 C68 N37 108.6(7) . . ?
C67 C68 H68 125.7 . . ?
N36 C69 N37 114.7(7) . . ?
N36 C69 H69 122.6 . . ?
N37 C69 H69 122.6 . . ?
N31 C70 H70A 109.2 . . ?
N31 C70 H70B 109.2 . . ?
N31 C70 C71 112.0(8) . . ?
H70A C70 H70B 107.9 . . ?
C71 C70 H70A 109.2 . . ?
C71 C70 H70B 109.2 . . ?
N38 C71 C70 108.0(8) . . ?
N38 C71 H71A 110.1 . . ?
N38 C71 H71B 110.1 . . ?
C70 C71 H71A 110.1 . . ?
C70 C71 H71B 110.1 . . ?
H71A C71 H71B 108.4 . . ?
N38 C72 H72 119.9 . . ?
N38 C72 C73 120.3(8) . . ?
C73 C72 H72 119.9 . . ?
N39 C73 C72 119.9(7) . . ?
C74 C73 N39 107.8(7) . . ?
C74 C73 C72 132.2(8) . . ?
N40 C74 C73 108.9(7) . . ?
N40 C74 H74 125.6 . . ?
C73 C74 H74 125.6 . . ?
N39 C75 N40 113.8(7) . . ?
N39 C75 H75 123.1 . . ?
N40 C75 H75 123.1 . . ?
O4 C76 H76A 109.5 . . ?
O4 C76 H76B 109.5 . . ?
O4 C76 H76C 109.5 . . ?
H76A C76 H76B 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C77 O9 H9A 109.5 . . ?
O9 C77 H77A 109.5 . . ?
O9 C77 H77B 109.5 . . ?
O9 C77 H77C 109.5 . . ?
H77A C77 H77B 109.5 . . ?
H77A C77 H77C 109.5 . . ?
H77B C77 H77C 109.5 . . ?
C78 O10 H10 109.5 . . ?
O10 C78 H78A 109.5 . . ?
O10 C78 H78B 109.5 . . ?
O10 C78 H78C 109.5 . . ?
H78A C78 H78B 109.5 . . ?
H78A C78 H78C 109.5 . . ?
H78B C78 H78C 109.5 . . ?
C79 O11 H11A 109.5 . . ?
O11 C79 H79A 109.5 . . ?
O11 C79 H79B 109.5 . . ?
O11 C79 H79C 109.5 . . ?
H79A C79 H79B 109.5 . . ?
H79A C79 H79C 109.5 . . ?
H79B C79 H79C 109.5 . . ?
C80 O12 H12A 109.5 . . ?
O12 C80 H80A 109.5 . . ?
O12 C80 H80B 109.5 . . ?
O12 C80 H80C 109.5 . . ?
H80A C80 H80B 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C81 O13 H13 109.5 . . ?
O13 C81 H81A 109.5 . . ?
O13 C81 H81B 109.5 . . ?
O13 C81 H81C 109.5 . . ?
H81A C81 H81B 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 N1 C1 C2 -58.3(8) . . . . ?
Dy1 N1 C7 C8 20.9(9) . . . . ?
Dy1 N1 C13 C14 48.8(8) . . . . ?
Dy1 N2 C2 C1 -10.3(10) . . . . ?
Dy1 N2 C3 C4 -12.8(10) . . . . ?
Dy1 N3 C4 C3 8.1(9) . . . . ?
Dy1 N3 C4 C5 -174.5(5) . . . . ?
Dy1 N3 C6 N4 170.1(6) . . . . ?
Dy1 N5 C8 C7 50.4(8) . . . . ?
Dy1 N5 C9 C10 0.3(10) . . . . ?
Dy1 N6 C10 C9 3.5(8) . . . . ?
Dy1 N6 C10 C11 178.3(5) . . . . ?
Dy1 N6 C12 N7 -177.2(5) . . . . ?
Dy1 N8 C14 C13 43.1(9) . . . . ?
Dy1 N8 C15 C16 4.8(11) . . . . ?
Dy1 N9 C16 C15 0.6(9) . . . . ?
Dy1 N9 C16 C17 177.9(5) . . . . ?
Dy1 N9 C18 N10 -177.1(6) . . . . ?
Dy2 N11 C20 C21 -57.7(8) . . . . ?
Dy2 N11 C26 C27 24.0(10) . . . . ?
Dy2 N11 C32 C33 48.8(8) . . . . ?
Dy2 N12 C21 C20 -12.3(11) . . . . ?
Dy2 N12 C22 C23 -7.1(11) . . . . ?
Dy2 N13 C23 C22 5.6(10) . . . . ?
Dy2 N13 C23 C24 -173.5(5) . . . . ?
Dy2 N13 C25 N14 170.7(6) . . . . ?
Dy2 N15 C33 C32 39.3(9) . . . . ?
Dy2 N15 C34 C35 2.9(11) . . . . ?
Dy2 N16 C35 C34 6.2(9) . . . . ?
Dy2 N16 C35 C36 -179.2(5) . . . . ?
Dy2 N16 C37 N17 178.4(6) . . . . ?
Dy2 N18 C27 C26 48.8(10) . . . . ?
Dy2 N18 C28 C29 1.8(11) . . . . ?
Dy2 N19 C29 C28 3.2(9) . . . . ?
Dy2 N19 C29 C30 -177.1(5) . . . . ?
Dy2 N19 C31 N20 176.4(5) . . . . ?
Dy3 N21 C39 C40 24.3(10) . . . . ?
Dy3 N21 C45 C46 -58.5(8) . . . . ?
Dy3 N21 C51 C52 48.4(8) . . . . ?
Dy3 N22 C40 C39 49.9(10) . . . . ?
Dy3 N22 C41 C42 -0.1(12) . . . . ?
Dy3 N23 C42 C41 1.5(10) . . . . ?
Dy3 N23 C42 C43 -176.1(5) . . . . ?
Dy3 N23 C44 N24 176.3(5) . . . . ?
Dy3 N25 C46 C45 -11.2(11) . . . . ?
Dy3 N25 C47 C48 -6.2(11) . . . . ?
Dy3 N26 C48 C47 4.8(10) . . . . ?
Dy3 N26 C48 C49 -175.2(5) . . . . ?
Dy3 N26 C50 N27 172.4(5) . . . . ?
Dy3 N28 C52 C51 39.7(9) . . . . ?
Dy3 N28 C53 C54 0.6(10) . . . . ?
Dy3 N29 C54 C53 4.1(8) . . . . ?
Dy3 N29 C54 C55 -178.5(5) . . . . ?
Dy3 N29 C56 N30 178.7(5) . . . . ?
Dy4 N31 C58 C59 24.2(9) . . . . ?
Dy4 N31 C64 C65 -57.5(8) . . . . ?
Dy4 N31 C70 C71 47.3(9) . . . . ?
Dy4 N32 C59 C58 50.6(9) . . . . ?
Dy4 N32 C60 C61 -1.0(11) . . . . ?
Dy4 N33 C61 C60 5.5(9) . . . . ?
Dy4 N33 C61 C62 -176.9(5) . . . . ?
Dy4 N33 C63 N34 175.8(5) . . . . ?
Dy4 N35 C65 C64 -10.5(11) . . . . ?
Dy4 N35 C66 C67 -11.3(10) . . . . ?
Dy4 N36 C67 C66 3.9(9) . . . . ?
Dy4 N36 C67 C68 -173.2(5) . . . . ?
Dy4 N36 C69 N37 170.4(6) . . . . ?
Dy4 N38 C71 C70 39.5(10) . . . . ?
Dy4 N38 C72 C73 -0.5(12) . . . . ?
Dy4 N39 C73 C72 2.4(9) . . . . ?
Dy4 N39 C73 C74 -178.9(5) . . . . ?
Dy4 N39 C75 N40 178.1(6) . . . . ?
Cu1 N14 C24 C23 176.7(5) . . . . ?
Cu1 N14 C25 N13 -177.1(5) . . . . ?
Cu1 N27 C49 C48 174.4(5) . . . . ?
Cu1 N27 C50 N26 -174.2(5) . . . . ?
Cu2 N4 C5 C4 174.9(6) . . . . ?
Cu2 N4 C6 N3 -176.7(5) . . . . ?
Cu2 N37 C68 C67 179.4(5) . . . . ?
Cu2 N37 C69 N36 -179.1(5) . . . . ?
Cu3 N10 C17 C16 -175.9(6) . . . . ?
Cu3 N10 C18 N9 176.3(5) . . . . ?
Cu3 N17 C36 C35 -175.1(5) . . . . ?
Cu3 N17 C37 N16 175.0(5) . . . . ?
Cu3 N24 C43 C42 -167.2(6) . . . . ?
Cu3 N24 C44 N23 168.1(5) . . . . ?
Cu3 N34 C62 C61 -169.7(5) 2 . . . ?
Cu3 N34 C63 N33 169.1(5) 2 . . . ?
Cu4 N7 C11 C10 -172.7(5) . . . . ?
Cu4 N7 C12 N6 172.3(5) . . . . ?
Cu4 N20 C30 C29 -169.0(5) 2 . . . ?
Cu4 N20 C31 N19 169.7(5) 2 . . . ?
Cu4 N30 C55 C54 -172.9(5) . . . . ?
Cu4 N30 C56 N29 173.9(5) . . . . ?
Cu4 N40 C74 C73 -173.8(6) . . . . ?
Cu4 N40 C75 N39 174.1(5) . . . . ?
N1 C1 C2 N2 48.2(10) . . . . ?
N1 C7 C8 N5 -44.2(10) . . . . ?
N1 C13 C14 N8 -61.7(10) . . . . ?
N2 C3 C4 N3 3.2(12) . . . . ?
N2 C3 C4 C5 -173.5(9) . . . . ?
N3 C4 C5 N4 3.0(10) . . . . ?
N5 C9 C10 N6 -2.6(11) . . . . ?
N5 C9 C10 C11 -175.7(8) . . . . ?
N6 C10 C11 N7 -0.4(9) . . . . ?
N8 C15 C16 N9 -3.7(12) . . . . ?
N8 C15 C16 C17 179.7(9) . . . . ?
N9 C16 C17 N10 0.1(9) . . . . ?
N11 C20 C21 N12 49.0(11) . . . . ?
N11 C26 C27 N18 -45.5(11) . . . . ?
N11 C32 C33 N15 -59.5(9) . . . . ?
N12 C22 C23 N13 0.9(13) . . . . ?
N12 C22 C23 C24 179.9(9) . . . . ?
N13 C23 C24 N14 0.5(9) . . . . ?
N15 C34 C35 N16 -6.4(12) . . . . ?
N15 C34 C35 C36 -179.4(9) . . . . ?
N16 C35 C36 N17 0.6(9) . . . . ?
N18 C28 C29 N19 -3.4(13) . . . . ?
N18 C28 C29 C30 177.1(9) . . . . ?
N19 C29 C30 N20 -1.0(9) . . . . ?
N21 C39 C40 N22 -46.9(11) . . . . ?
N21 C45 C46 N25 48.7(11) . . . . ?
N21 C51 C52 N28 -59.4(9) . . . . ?
N22 C41 C42 N23 -1.0(14) . . . . ?
N22 C41 C42 C43 176.0(10) . . . . ?
N23 C42 C43 N24 -2.3(10) . . . . ?
N25 C47 C48 N26 1.0(12) . . . . ?
N25 C47 C48 C49 -178.9(9) . . . . ?
N26 C48 C49 N27 0.9(10) . . . . ?
N28 C53 C54 N29 -3.3(11) . . . . ?
N28 C53 C54 C55 -180.0(9) . . . . ?
N29 C54 C55 N30 -1.3(9) . . . . ?
N31 C58 C59 N32 -45.7(10) . . . . ?
N31 C64 C65 N35 47.9(11) . . . . ?
N31 C70 C71 N38 -58.6(11) . . . . ?
N32 C60 C61 N33 -3.1(12) . . . . ?
N32 C60 C61 C62 180.0(9) . . . . ?
N33 C61 C62 N34 -0.3(9) . . . . ?
N35 C66 C67 N36 5.1(12) . . . . ?
N35 C66 C67 C68 -178.6(9) . . . . ?
N36 C67 C68 N37 -0.2(9) . . . . ?
N38 C72 C73 N39 -1.4(13) . . . . ?
N38 C72 C73 C74 -179.7(9) . . . . ?
N39 C73 C74 N40 0.2(9) . . . . ?
C1 N1 C7 C8 -96.6(8) . . . . ?
C1 N1 C13 C14 160.0(7) . . . . ?
C2 N2 C3 C4 178.9(8) . . . . ?
C3 N2 C2 C1 157.7(8) . . . . ?
C3 C4 C5 N4 179.9(9) . . . . ?
C4 N3 C6 N4 1.4(9) . . . . ?
C5 N4 C6 N3 0.4(9) . . . . ?
C6 N3 C4 C3 -180.0(7) . . . . ?
C6 N3 C4 C5 -2.6(9) . . . . ?
C6 N4 C5 C4 -2.0(9) . . . . ?
C7 N1 C1 C2 65.6(9) . . . . ?
C7 N1 C13 C14 -77.5(9) . . . . ?
C8 N5 C9 C10 176.8(7) . . . . ?
C9 N5 C8 C7 -126.2(8) . . . . ?
C9 C10 C11 N7 173.1(8) . . . . ?
C10 N6 C12 N7 0.7(8) . . . . ?
C11 N7 C12 N6 -0.9(8) . . . . ?
C12 N6 C10 C9 -174.9(7) . . . . ?
C12 N6 C10 C11 -0.1(8) . . . . ?
C12 N7 C11 C10 0.8(8) . . . . ?
C13 N1 C1 C2 -171.8(7) . . . . ?
C13 N1 C7 C8 143.0(7) . . . . ?
C14 N8 C15 C16 174.8(8) . . . . ?
C15 N8 C14 C13 -126.9(9) . . . . ?
C15 C16 C17 N10 177.0(8) . . . . ?
C16 N9 C18 N10 -0.4(9) . . . . ?
C17 N10 C18 N9 0.4(9) . . . . ?
C18 N9 C16 C15 -177.2(7) . . . . ?
C18 N9 C16 C17 0.2(8) . . . . ?
C18 N10 C17 C16 -0.3(9) . . . . ?
C20 N11 C26 C27 -94.4(9) . . . . ?
C20 N11 C32 C33 160.6(7) . . . . ?
C21 N12 C22 C23 -177.4(8) . . . . ?
C22 N12 C21 C20 157.6(9) . . . . ?
C22 C23 C24 N14 -178.6(9) . . . . ?
C23 N13 C25 N14 0.9(9) . . . . ?
C24 N14 C25 N13 -0.6(9) . . . . ?
C25 N13 C23 C22 178.4(8) . . . . ?
C25 N13 C23 C24 -0.8(9) . . . . ?
C25 N14 C24 C23 0.0(9) . . . . ?
C26 N11 C20 C21 67.7(9) . . . . ?
C26 N11 C32 C33 -77.4(8) . . . . ?
C27 N18 C28 C29 177.1(8) . . . . ?
C28 N18 C27 C26 -126.6(9) . . . . ?
C28 C29 C30 N20 178.6(9) . . . . ?
C29 N19 C31 N20 -2.2(9) . . . . ?
C30 N20 C31 N19 1.6(9) . . . . ?
C31 N19 C29 C28 -177.8(7) . . . . ?
C31 N19 C29 C30 1.9(8) . . . . ?
C31 N20 C30 C29 -0.3(9) . . . . ?
C32 N11 C20 C21 -171.5(7) . . . . ?
C32 N11 C26 C27 144.9(8) . . . . ?
C33 N15 C34 C35 175.1(8) . . . . ?
C34 N15 C33 C32 -132.7(8) . . . . ?
C34 C35 C36 N17 174.2(8) . . . . ?
C35 N16 C37 N17 0.2(9) . . . . ?
C36 N17 C37 N16 0.2(9) . . . . ?
C37 N16 C35 C34 -175.1(7) . . . . ?
C37 N16 C35 C36 -0.5(8) . . . . ?
C37 N17 C36 C35 -0.5(9) . . . . ?
C39 N21 C45 C46 65.0(10) . . . . ?
C39 N21 C51 C52 -75.6(8) . . . . ?
C40 N22 C41 C42 176.8(9) . . . . ?
C41 N22 C40 C39 -127.1(10) . . . . ?
C41 C42 C43 N24 -179.5(10) . . . . ?
C42 N23 C44 N24 -1.6(9) . . . . ?
C43 N24 C44 N23 0.2(9) . . . . ?
C44 N23 C42 C41 180.0(8) . . . . ?
C44 N23 C42 C43 2.3(9) . . . . ?
C44 N24 C43 C42 1.3(9) . . . . ?
C45 N21 C39 C40 -93.3(9) . . . . ?
C45 N21 C51 C52 161.0(7) . . . . ?
C46 N25 C47 C48 -177.4(8) . . . . ?
C47 N25 C46 C45 159.7(9) . . . . ?
C47 C48 C49 N27 -179.1(9) . . . . ?
C48 N26 C50 N27 -0.8(9) . . . . ?
C49 N27 C50 N26 1.4(9) . . . . ?
C50 N26 C48 C47 179.9(7) . . . . ?
C50 N26 C48 C49 -0.1(9) . . . . ?
C50 N27 C49 C48 -1.3(9) . . . . ?
C51 N21 C39 C40 143.5(8) . . . . ?
C51 N21 C45 C46 -172.4(7) . . . . ?
C52 N28 C53 C54 173.2(8) . . . . ?
C53 N28 C52 C51 -132.7(8) . . . . ?
C53 C54 C55 N30 175.7(8) . . . . ?
C54 N29 C56 N30 -0.7(9) . . . . ?
C55 N30 C56 N29 0.0(9) . . . . ?
C56 N29 C54 C53 -176.3(7) . . . . ?
C56 N29 C54 C55 1.2(8) . . . . ?
C56 N30 C55 C54 0.8(8) . . . . ?
C58 N31 C64 C65 67.0(10) . . . . ?
C58 N31 C70 C71 -77.1(10) . . . . ?
C59 N32 C60 C61 177.7(8) . . . . ?
C60 N32 C59 C58 -128.1(9) . . . . ?
C60 C61 C62 N34 176.8(8) . . . . ?
C61 N33 C63 N34 -0.7(9) . . . . ?
C62 N34 C63 N33 0.5(9) . . . . ?
C63 N33 C61 C60 -177.0(7) . . . . ?
C63 N33 C61 C62 0.6(8) . . . . ?
C63 N34 C62 C61 -0.1(8) . . . . ?
C64 N31 C58 C59 -94.3(9) . . . . ?
C64 N31 C70 C71 159.9(8) . . . . ?
C65 N35 C66 C67 -178.8(8) . . . . ?
C66 N35 C65 C64 156.5(9) . . . . ?
C66 C67 C68 N37 -176.7(8) . . . . ?
C67 N36 C69 N37 -0.5(9) . . . . ?
C68 N37 C69 N36 0.5(9) . . . . ?
C69 N36 C67 C66 177.5(7) . . . . ?
C69 N36 C67 C68 0.4(9) . . . . ?
C69 N37 C68 C67 -0.2(9) . . . . ?
C70 N31 C58 C59 143.7(8) . . . . ?
C70 N31 C64 C65 -171.6(8) . . . . ?
C71 N38 C72 C73 172.5(9) . . . . ?
C72 N38 C71 C70 -133.3(10) . . . . ?
C72 C73 C74 N40 178.7(9) . . . . ?
C73 N39 C75 N40 -0.2(9) . . . . ?
C74 N40 C75 N39 0.3(9) . . . . ?
C75 N39 C73 C72 -178.7(8) . . . . ?
C75 N39 C73 C74 0.0(9) . . . . ?
C75 N40 C74 C73 -0.3(9) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
