# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1470000'
_audit_update_record             
;
2016-03-22 deposited with the CCDC.
2016-06-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C68 H72 F36 N14 O2 P6 Pt2'
_chemical_formula_weight         2377.39

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.3083(17)
_cell_length_b                   9.9603(16)
_cell_length_c                   25.244(4)
_cell_angle_alpha                95.668(12)
_cell_angle_beta                 93.889(13)
_cell_angle_gamma                104.959(13)
_cell_volume                     2239.5(7)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    200
_cell_measurement_theta_min      4.685
_cell_measurement_theta_max      25.795

_exptl_crystal_description       plate
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.763
_exptl_crystal_F_000             1164
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.190
_exptl_crystal_size_min          0.020
_exptl_absorpt_coefficient_mu    3.353
_shelx_estimated_absorpt_T_min   0.539
_shelx_estimated_absorpt_T_max   0.936
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6973
_exptl_absorpt_correction_T_max  1.0
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker Kappa APEXII CCD'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            34134
_diffrn_reflns_av_unetI/netI     0.0442
_diffrn_reflns_av_R_equivalents  0.0386
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         0.814
_diffrn_reflns_theta_max         26.371
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             9143
_reflns_number_gt                8222
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0495P)²+5.1218P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9143
_refine_ls_number_parameters     652
_refine_ls_number_restraints     69
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0351
_refine_ls_wR_factor_ref         0.0953
_refine_ls_wR_factor_gt          0.0888
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_restrained_S_all      1.098
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6766(6) 0.5909(5) 0.7740(2) 0.0234(11) Uani 1 1 d . . . . .
H1 H 0.7346 0.5279 0.7812 0.028 Uiso 1 1 calc R U . . .
C2 C 0.5843(5) 0.5648(5) 0.72678(19) 0.0210(10) Uani 1 1 d . . . . .
H2 H 0.5792 0.4844 0.7023 0.025 Uiso 1 1 calc R U . . .
C3 C 0.4988(5) 0.6559(5) 0.71488(19) 0.0197(10) Uani 1 1 d . . . . .
C4 C 0.5085(6) 0.7695(5) 0.7534(2) 0.0236(11) Uani 1 1 d . . . . .
H4 H 0.4498 0.8327 0.7475 0.028 Uiso 1 1 calc R U . . .
C5 C 0.6026(6) 0.7907(5) 0.7999(2) 0.0239(11) Uani 1 1 d . . . . .
H5 H 0.6078 0.8692 0.8254 0.029 Uiso 1 1 calc R U . . .
C6 C 0.4084(5) 0.6385(5) 0.66272(19) 0.0204(10) Uani 1 1 d . . . . .
C7 C 0.4507(6) 0.5731(5) 0.6174(2) 0.0245(11) Uani 1 1 d . . . . .
H7 H 0.5319 0.5321 0.6206 0.029 Uiso 1 1 calc R U . . .
C8 C 0.3753(6) 0.5675(5) 0.5677(2) 0.0255(11) Uani 1 1 d . . . . .
H8 H 0.4048 0.5218 0.5371 0.031 Uiso 1 1 calc R U . . .
C9 C 0.2573(6) 0.6278(5) 0.56187(19) 0.0236(11) Uani 1 1 d . . . . .
C10 C 0.2116(6) 0.6883(5) 0.60746(19) 0.0231(10) Uani 1 1 d . . . . .
H10 H 0.1291 0.7276 0.6043 0.028 Uiso 1 1 calc R U . . .
C11 C 0.2842(6) 0.6922(5) 0.65725(19) 0.0228(10) Uani 1 1 d . . . . .
H11 H 0.2496 0.7317 0.6881 0.027 Uiso 1 1 calc R U . . .
C12 C 0.1149(6) 0.5439(5) 0.4154(2) 0.0247(11) Uani 1 1 d . . . . .
H12 H 0.1129 0.4756 0.3861 0.030 Uiso 1 1 calc R U . . .
C13 C 0.1810(6) 0.5331(5) 0.4643(2) 0.0254(11) Uani 1 1 d . . . . .
H13 H 0.2237 0.4575 0.4687 0.031 Uiso 1 1 calc R U . . .
C14 C 0.1858(6) 0.6339(5) 0.50830(19) 0.0237(11) Uani 1 1 d . . . . .
C15 C 0.1204(6) 0.7418(5) 0.4988(2) 0.0287(12) Uani 1 1 d . . . . .
H15 H 0.1207 0.8120 0.5273 0.034 Uiso 1 1 calc R U . . .
C16 C 0.0558(6) 0.7475(5) 0.4491(2) 0.0276(12) Uani 1 1 d . . . . .
H16 H 0.0121 0.8219 0.4435 0.033 Uiso 1 1 calc R U . . .
C17 C -0.0171(6) 0.6603(5) 0.35575(19) 0.0231(11) Uani 1 1 d . . . . .
C18 C 0.0521(6) 0.6352(6) 0.3108(2) 0.0280(11) Uani 1 1 d . . . . .
H18 H 0.1429 0.6084 0.3136 0.034 Uiso 1 1 calc R U . . .
C19 C -0.0127(6) 0.6496(6) 0.2612(2) 0.0319(12) Uani 1 1 d . . . . .
H19 H 0.0343 0.6324 0.2299 0.038 Uiso 1 1 calc R U . . .
C20 C -0.1459(6) 0.6889(5) 0.2568(2) 0.0255(11) Uani 1 1 d . . . . .
C21 C -0.2142(6) 0.7113(5) 0.3030(2) 0.0256(11) Uani 1 1 d . . . . .
H21 H -0.3058 0.7368 0.3005 0.031 Uiso 1 1 calc R U . . .
C22 C -0.1502(6) 0.6969(5) 0.3527(2) 0.0258(11) Uani 1 1 d . . . . .
H22 H -0.1974 0.7120 0.3841 0.031 Uiso 1 1 calc R U . . .
C23 C -0.2117(6) 0.7094(6) 0.2026(2) 0.0300(12) Uani 1 1 d . . . . .
H23A H -0.3157 0.7148 0.2053 0.036 Uiso 1 1 calc R U . . .
H23B H -0.2145 0.6273 0.1766 0.036 Uiso 1 1 calc R U . . .
C24 C 0.0397(6) 0.9578(5) 0.12164(18) 0.0201(10) Uani 1 1 d . . . . .
H24 H 0.0945 0.9517 0.0915 0.024 Uiso 1 1 calc R U . . .
C25 C -0.0446(6) 0.8361(5) 0.13835(19) 0.0235(11) Uani 1 1 d . . . . .
H25 H -0.0482 0.7481 0.1192 0.028 Uiso 1 1 calc R U . . .
C26 C -0.1229(5) 0.8410(5) 0.18219(19) 0.0224(10) Uani 1 1 d . . . . .
C27 C -0.1160(7) 0.9721(6) 0.2078(2) 0.0354(13) Uani 1 1 d . . . . .
H27 H -0.1696 0.9806 0.2381 0.043 Uiso 1 1 calc R U . . .
C28 C -0.0319(6) 1.0903(6) 0.1895(2) 0.0318(12) Uani 1 1 d . . . . .
H28 H -0.0287 1.1794 0.2076 0.038 Uiso 1 1 calc R U . . .
C29 C 0.8152(6) 0.5219(6) 0.9455(2) 0.0319(12) Uani 1 1 d . . . . .
H29A H 0.7581 0.4528 0.9672 0.038 Uiso 1 1 calc R U . . .
H29B H 0.8853 0.4793 0.9265 0.038 Uiso 1 1 calc R U . . .
C30 C 0.8985(6) 0.6500(5) 0.9803(2) 0.0281(12) Uani 1 1 d . . . . .
H30A H 0.9792 0.6299 1.0031 0.034 Uiso 1 1 calc R U . . .
H30B H 0.8305 0.6829 1.0038 0.034 Uiso 1 1 calc R U . . .
C31 C 0.5833(7) 0.9026(7) 1.0583(3) 0.0450(16) Uani 1 1 d . . . . .
H31A H 0.6105 0.8617 1.0900 0.068 Uiso 1 1 calc R U . . .
H31B H 0.4995 0.8351 1.0365 0.068 Uiso 1 1 calc R U . . .
H31C H 0.5540 0.9880 1.0695 0.068 Uiso 1 1 calc R U . . .
C32 C 0.7105(6) 0.9365(5) 1.0271(2) 0.0268(11) Uani 1 1 d . . . . .
C33 C 0.4687(16) 1.0372(9) 0.6457(5) 0.143(6) Uani 1 1 d . . . . .
H33A H 0.3628 1.0288 0.6496 0.215 Uiso 1 1 calc R U . . .
H33B H 0.5167 1.0178 0.6788 0.215 Uiso 1 1 calc R U . . .
H33C H 0.4778 0.9698 0.6159 0.215 Uiso 1 1 calc R U . . .
C34 C 0.5408(7) 1.1778(7) 0.6351(3) 0.0417(15) Uani 1 1 d . . . . .
N1 N 0.0456(4) 1.0836(4) 0.14700(15) 0.0182(8) Uani 1 1 d . . . . .
N2 N 0.0529(5) 0.6496(4) 0.40791(16) 0.0240(9) Uani 1 1 d . . . . .
N3 N 0.6867(4) 0.7035(4) 0.81027(16) 0.0210(9) Uani 1 1 d . . . . .
N4 N 0.7105(4) 0.5627(4) 0.90592(16) 0.0210(9) Uani 1 1 d . . . . .
H4A H 0.6315 0.5796 0.9222 0.025 Uiso 1 1 calc R U . . .
H4B H 0.6752 0.4924 0.8786 0.025 Uiso 1 1 calc R U . . .
N5 N 0.9639(4) 0.7611(4) 0.94619(16) 0.0219(9) Uani 1 1 d . . . . .
H5A H 1.0557 0.7541 0.9381 0.026 Uiso 1 1 calc R U . . .
H5B H 0.9749 0.8472 0.9645 0.026 Uiso 1 1 calc R U . . .
N6 N 0.8121(5) 0.9632(5) 1.00358(19) 0.0310(10) Uani 1 1 d . . . . .
N7 N 0.5932(6) 1.2870(5) 0.6273(2) 0.0389(12) Uani 1 1 d . . . . .
F1 F 0.5944(4) 0.2662(3) 0.76328(13) 0.0434(9) Uani 1 1 d . . . . .
F2 F 0.4821(4) 0.0736(3) 0.80053(14) 0.0392(8) Uani 1 1 d . . . . .
F3 F 0.7249(4) 0.1115(3) 0.78263(13) 0.0366(8) Uani 1 1 d . . . . .
F4 F 0.6669(4) 0.1320(3) 0.86805(13) 0.0357(8) Uani 1 1 d . . . . .
F5 F 0.7791(3) 0.3264(3) 0.83156(13) 0.0326(7) Uani 1 1 d . . . . .
F6 F 0.5383(3) 0.2878(3) 0.84902(13) 0.0321(7) Uani 1 1 d . . . . .
F7 F 0.2462(4) 0.7378(5) 0.88401(15) 0.0561(11) Uani 1 1 d . . . . .
F8 F 0.1862(5) 0.5289(4) 0.9153(2) 0.0721(14) Uani 1 1 d . . . . .
F9 F 0.3894(4) 0.5867(4) 0.86831(14) 0.0456(9) Uani 1 1 d . . . . .
F10 F 0.4199(5) 0.5783(5) 0.95761(18) 0.0770(15) Uani 1 1 d . . . . .
F11 F 0.4778(4) 0.7815(4) 0.92499(16) 0.0559(11) Uani 1 1 d . . . . .
F12 F 0.2748(4) 0.7238(4) 0.97137(14) 0.0419(8) Uani 1 1 d . . . . .
F13A F 0.5362(10) 0.8038(9) 0.5005(3) 0.067(2) Uani 0.590(3) 1 d . . P A 1
F14A F 0.7273(9) 0.9391(8) 0.4655(3) 0.070(2) Uani 0.590(3) 1 d . . P A 1
F15A F 0.7387(8) 0.7356(7) 0.4793(3) 0.061(2) Uani 0.590(3) 1 d . . P A 1
F16A F 0.7016(8) 0.7754(7) 0.5656(2) 0.0585(19) Uani 0.590(3) 1 d . . P A 1
F17A F 0.8868(7) 0.9214(6) 0.5312(3) 0.059(2) Uani 0.590(3) 1 d . . P A 1
F18A F 0.6880(8) 0.9943(7) 0.5516(3) 0.0528(17) Uani 0.590(3) 1 d . . P A 1
F13B F 0.7160(9) 0.7981(10) 0.6338(4) 0.051(2) Uani 0.410(3) 1 d . U P A 2
F14B F 0.9131(11) 0.7952(9) 0.5886(3) 0.049(2) Uani 0.410(3) 1 d . U P A 2
F15B F 1.0616(9) 0.9484(9) 0.6530(4) 0.053(2) Uani 0.410(3) 1 d . U P A 2
F16B F 0.8582(10) 0.9977(9) 0.6139(4) 0.0505(19) Uani 0.410(3) 1 d . U P A 2
F17B F 0.8530(10) 0.9610(9) 0.6874(4) 0.0428(16) Uani 0.410(3) 1 d . U P A 2
F18B F 0.9192(12) 0.7359(9) 0.6768(4) 0.0251(16) Uani 0.410(3) 1 d . U P A 2
Pt1 Pt 0.82730(2) 0.73880(2) 0.87742(2) 0.01537(7) Uani 1 1 d . . . . .
P1 P 0.63145(16) 0.19824(13) 0.81547(6) 0.0256(3) Uani 1 1 d . . . . .
P2 P 0.33163(16) 0.65462(15) 0.91922(6) 0.0292(3) Uani 1 1 d . . . . .
P3A P 0.7093(3) 0.8629(3) 0.51463(12) 0.0394(7) Uani 0.590(3) 1 d . . P A 1
P3B P 0.8880(4) 0.8738(4) 0.64438(16) 0.0299(9) Uani 0.410(3) 1 d . U P A 2
O1A O 0.9005(15) 0.810(2) 0.6783(4) 0.158(10) Uani 0.590(3) 1 d . U P A 1
O1B O 0.569(2) 0.900(2) 0.5222(9) 0.098(6) Uani 0.410(3) 1 d . . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N3 1.356(6) . ?
C1 C2 1.382(7) . ?
C1 H1 0.9500 . ?
C2 C3 1.393(7) . ?
C2 H2 0.9500 . ?
C3 C4 1.397(7) . ?
C3 C6 1.484(6) . ?
C4 C5 1.382(7) . ?
C4 H4 0.9500 . ?
C5 N3 1.343(6) . ?
C5 H5 0.9500 . ?
C6 C7 1.391(7) . ?
C6 C11 1.398(7) . ?
C7 C8 1.385(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.387(7) . ?
C8 H8 0.9500 . ?
C9 C10 1.389(7) . ?
C9 C14 1.480(7) . ?
C10 C11 1.378(7) . ?
C10 H10 0.9500 . ?
C11 H11 0.9500 . ?
C12 N2 1.347(6) . ?
C12 C13 1.370(7) . ?
C12 H12 0.9500 . ?
C13 C14 1.412(7) . ?
C13 H13 0.9500 . ?
C14 C15 1.397(7) . ?
C15 C16 1.368(7) . ?
C15 H15 0.9500 . ?
C16 N2 1.347(6) . ?
C16 H16 0.9500 . ?
C17 C18 1.377(7) . ?
C17 C22 1.377(7) . ?
C17 N2 1.455(6) . ?
C18 C19 1.388(7) . ?
C18 H18 0.9500 . ?
C19 C20 1.394(8) . ?
C19 H19 0.9500 . ?
C20 C21 1.392(7) . ?
C20 C23 1.513(7) . ?
C21 C22 1.389(7) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C26 1.517(7) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 N1 1.336(6) . ?
C24 C25 1.385(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.369(7) . ?
C25 H25 0.9500 . ?
C26 C27 1.382(8) . ?
C27 C28 1.376(8) . ?
C27 H27 0.9500 . ?
C28 N1 1.338(7) . ?
C28 H28 0.9500 . ?
C29 C30 1.475(8) . ?
C29 N4 1.506(6) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 N5 1.499(6) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.453(8) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 N6 1.137(7) . ?
C33 C34 1.449(10) . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 N7 1.114(8) . ?
N1 Pt1 2.035(4) 2_676 ?
N3 Pt1 2.013(4) . ?
N4 Pt1 2.036(4) . ?
N4 H4A 0.9100 . ?
N4 H4B 0.9100 . ?
N5 Pt1 2.039(4) . ?
N5 H5A 0.9100 . ?
N5 H5B 0.9100 . ?
F1 P1 1.596(3) . ?
F2 P1 1.601(3) . ?
F3 P1 1.592(3) . ?
F4 P1 1.591(3) . ?
F5 P1 1.612(3) . ?
F6 P1 1.617(3) . ?
F7 P2 1.581(4) . ?
F8 P2 1.579(4) . ?
F9 P2 1.584(4) . ?
F10 P2 1.598(4) . ?
F11 P2 1.587(4) . ?
F12 P2 1.610(4) . ?
F13A P3A 1.569(9) . ?
F14A P3A 1.513(7) . ?
F15A P3A 1.571(7) . ?
F16A P3A 1.620(7) . ?
F17A P3A 1.614(7) . ?
F18A P3A 1.595(7) . ?
F13B P3B 1.575(9) . ?
F14B P3B 1.603(9) . ?
F15B P3B 1.584(9) . ?
F16B P3B 1.589(9) . ?
F17B P3B 1.432(9) . ?
F18B P3B 1.743(10) . ?
Pt1 N1 2.035(4) 2_676 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 C1 C2 122.0(4) . . ?
N3 C1 H1 119.0 . . ?
C2 C1 H1 119.0 . . ?
C1 C2 C3 120.3(4) . . ?
C1 C2 H2 119.9 . . ?
C3 C2 H2 119.9 . . ?
C2 C3 C4 116.7(4) . . ?
C2 C3 C6 122.0(4) . . ?
C4 C3 C6 121.2(4) . . ?
C5 C4 C3 120.6(4) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
N3 C5 C4 121.9(4) . . ?
N3 C5 H5 119.1 . . ?
C4 C5 H5 119.1 . . ?
C7 C6 C11 118.5(4) . . ?
C7 C6 C3 119.9(4) . . ?
C11 C6 C3 121.5(4) . . ?
C8 C7 C6 120.4(5) . . ?
C8 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
C7 C8 C9 120.9(5) . . ?
C7 C8 H8 119.5 . . ?
C9 C8 H8 119.5 . . ?
C8 C9 C10 118.5(4) . . ?
C8 C9 C14 121.1(5) . . ?
C10 C9 C14 120.4(5) . . ?
C11 C10 C9 121.0(5) . . ?
C11 C10 H10 119.5 . . ?
C9 C10 H10 119.5 . . ?
C10 C11 C6 120.5(5) . . ?
C10 C11 H11 119.8 . . ?
C6 C11 H11 119.8 . . ?
N2 C12 C13 121.3(5) . . ?
N2 C12 H12 119.3 . . ?
C13 C12 H12 119.3 . . ?
C12 C13 C14 120.2(5) . . ?
C12 C13 H13 119.9 . . ?
C14 C13 H13 119.9 . . ?
C15 C14 C13 116.7(4) . . ?
C15 C14 C9 121.1(5) . . ?
C13 C14 C9 122.3(4) . . ?
C16 C15 C14 120.7(5) . . ?
C16 C15 H15 119.6 . . ?
C14 C15 H15 119.6 . . ?
N2 C16 C15 121.2(5) . . ?
N2 C16 H16 119.4 . . ?
C15 C16 H16 119.4 . . ?
C18 C17 C22 121.7(4) . . ?
C18 C17 N2 119.1(5) . . ?
C22 C17 N2 119.2(4) . . ?
C17 C18 C19 119.0(5) . . ?
C17 C18 H18 120.5 . . ?
C19 C18 H18 120.5 . . ?
C18 C19 C20 120.9(5) . . ?
C18 C19 H19 119.6 . . ?
C20 C19 H19 119.6 . . ?
C21 C20 C19 118.6(5) . . ?
C21 C20 C23 121.3(5) . . ?
C19 C20 C23 120.0(5) . . ?
C22 C21 C20 120.9(5) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C17 C22 C21 119.0(5) . . ?
C17 C22 H22 120.5 . . ?
C21 C22 H22 120.5 . . ?
C20 C23 C26 112.4(4) . . ?
C20 C23 H23A 109.1 . . ?
C26 C23 H23A 109.1 . . ?
C20 C23 H23B 109.1 . . ?
C26 C23 H23B 109.1 . . ?
H23A C23 H23B 107.9 . . ?
N1 C24 C25 121.4(4) . . ?
N1 C24 H24 119.3 . . ?
C25 C24 H24 119.3 . . ?
C26 C25 C24 120.8(5) . . ?
C26 C25 H25 119.6 . . ?
C24 C25 H25 119.6 . . ?
C25 C26 C27 117.0(5) . . ?
C25 C26 C23 122.0(5) . . ?
C27 C26 C23 121.0(5) . . ?
C28 C27 C26 120.2(5) . . ?
C28 C27 H27 119.9 . . ?
C26 C27 H27 119.9 . . ?
N1 C28 C27 122.1(5) . . ?
N1 C28 H28 119.0 . . ?
C27 C28 H28 119.0 . . ?
C30 C29 N4 107.6(4) . . ?
C30 C29 H29A 110.2 . . ?
N4 C29 H29A 110.2 . . ?
C30 C29 H29B 110.2 . . ?
N4 C29 H29B 110.2 . . ?
H29A C29 H29B 108.5 . . ?
C29 C30 N5 109.2(4) . . ?
C29 C30 H30A 109.8 . . ?
N5 C30 H30A 109.8 . . ?
C29 C30 H30B 109.8 . . ?
N5 C30 H30B 109.8 . . ?
H30A C30 H30B 108.3 . . ?
C32 C31 H31A 109.5 . . ?
C32 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C32 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N6 C32 C31 178.6(6) . . ?
C34 C33 H33A 109.5 . . ?
C34 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C34 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N7 C34 C33 178.2(8) . . ?
C24 N1 C28 118.5(4) . . ?
C24 N1 Pt1 120.9(3) . 2_676 ?
C28 N1 Pt1 120.6(3) . 2_676 ?
C16 N2 C12 119.9(4) . . ?
C16 N2 C17 119.1(4) . . ?
C12 N2 C17 121.0(4) . . ?
C5 N3 C1 118.5(4) . . ?
C5 N3 Pt1 121.4(3) . . ?
C1 N3 Pt1 120.2(3) . . ?
C29 N4 Pt1 107.6(3) . . ?
C29 N4 H4A 110.2 . . ?
Pt1 N4 H4A 110.2 . . ?
C29 N4 H4B 110.2 . . ?
Pt1 N4 H4B 110.2 . . ?
H4A N4 H4B 108.5 . . ?
C30 N5 Pt1 109.9(3) . . ?
C30 N5 H5A 109.7 . . ?
Pt1 N5 H5A 109.7 . . ?
C30 N5 H5B 109.7 . . ?
Pt1 N5 H5B 109.7 . . ?
H5A N5 H5B 108.2 . . ?
N3 Pt1 N1 90.89(16) . 2_676 ?
N3 Pt1 N4 92.82(16) . . ?
N1 Pt1 N4 176.27(15) 2_676 . ?
N3 Pt1 N5 176.22(16) . . ?
N1 Pt1 N5 92.73(16) 2_676 . ?
N4 Pt1 N5 83.56(16) . . ?
F4 P1 F3 90.50(18) . . ?
F4 P1 F1 179.1(2) . . ?
F3 P1 F1 90.43(19) . . ?
F4 P1 F2 89.98(19) . . ?
F3 P1 F2 91.01(18) . . ?
F1 P1 F2 90.0(2) . . ?
F4 P1 F5 89.97(19) . . ?
F3 P1 F5 90.72(18) . . ?
F1 P1 F5 90.00(19) . . ?
F2 P1 F5 178.27(19) . . ?
F4 P1 F6 89.49(17) . . ?
F3 P1 F6 179.3(2) . . ?
F1 P1 F6 89.58(18) . . ?
F2 P1 F6 89.67(17) . . ?
F5 P1 F6 88.61(17) . . ?
F8 P2 F7 90.7(3) . . ?
F8 P2 F9 92.2(2) . . ?
F7 P2 F9 92.1(2) . . ?
F8 P2 F11 178.4(3) . . ?
F7 P2 F11 90.2(2) . . ?
F9 P2 F11 89.2(2) . . ?
F8 P2 F10 91.1(3) . . ?
F7 P2 F10 176.5(3) . . ?
F9 P2 F10 90.8(2) . . ?
F11 P2 F10 88.0(3) . . ?
F8 P2 F12 88.2(2) . . ?
F7 P2 F12 88.5(2) . . ?
F9 P2 F12 179.3(2) . . ?
F11 P2 F12 90.4(2) . . ?
F10 P2 F12 88.6(2) . . ?
F14A P3A F13A 92.6(4) . . ?
F14A P3A F15A 86.7(4) . . ?
F13A P3A F15A 91.2(5) . . ?
F14A P3A F18A 93.6(4) . . ?
F13A P3A F18A 91.6(5) . . ?
F15A P3A F18A 177.2(4) . . ?
F14A P3A F17A 89.4(4) . . ?
F13A P3A F17A 178.0(5) . . ?
F15A P3A F17A 89.2(4) . . ?
F18A P3A F17A 88.0(4) . . ?
F14A P3A F16A 175.0(5) . . ?
F13A P3A F16A 90.5(4) . . ?
F15A P3A F16A 89.3(4) . . ?
F18A P3A F16A 90.2(4) . . ?
F17A P3A F16A 87.5(4) . . ?
F17B P3B F13B 87.8(6) . . ?
F17B P3B F15B 94.0(5) . . ?
F13B P3B F15B 178.1(6) . . ?
F17B P3B F16B 79.1(5) . . ?
F13B P3B F16B 88.6(5) . . ?
F15B P3B F16B 91.0(5) . . ?
F17B P3B F14B 168.3(6) . . ?
F13B P3B F14B 89.1(6) . . ?
F15B P3B F14B 89.0(5) . . ?
F16B P3B F14B 89.6(5) . . ?
F17B P3B F18B 101.7(5) . . ?
F13B P3B F18B 90.9(5) . . ?
F15B P3B F18B 89.6(5) . . ?
F16B P3B F18B 179.0(6) . . ?
F14B P3B F18B 89.6(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 C1 C2 C3 0.5(8) . . . . ?
C1 C2 C3 C4 -1.9(7) . . . . ?
C1 C2 C3 C6 174.7(5) . . . . ?
C2 C3 C4 C5 2.0(7) . . . . ?
C6 C3 C4 C5 -174.7(5) . . . . ?
C3 C4 C5 N3 -0.6(8) . . . . ?
C2 C3 C6 C7 -27.1(7) . . . . ?
C4 C3 C6 C7 149.4(5) . . . . ?
C2 C3 C6 C11 155.9(5) . . . . ?
C4 C3 C6 C11 -27.6(7) . . . . ?
C11 C6 C7 C8 3.0(7) . . . . ?
C3 C6 C7 C8 -174.1(5) . . . . ?
C6 C7 C8 C9 0.6(8) . . . . ?
C7 C8 C9 C10 -3.0(8) . . . . ?
C7 C8 C9 C14 174.1(5) . . . . ?
C8 C9 C10 C11 1.8(7) . . . . ?
C14 C9 C10 C11 -175.3(5) . . . . ?
C9 C10 C11 C6 1.8(8) . . . . ?
C7 C6 C11 C10 -4.2(7) . . . . ?
C3 C6 C11 C10 172.9(4) . . . . ?
N2 C12 C13 C14 -0.3(8) . . . . ?
C12 C13 C14 C15 0.2(8) . . . . ?
C12 C13 C14 C9 -179.3(5) . . . . ?
C8 C9 C14 C15 -150.5(5) . . . . ?
C10 C9 C14 C15 26.5(7) . . . . ?
C8 C9 C14 C13 28.9(7) . . . . ?
C10 C9 C14 C13 -154.0(5) . . . . ?
C13 C14 C15 C16 -0.1(8) . . . . ?
C9 C14 C15 C16 179.4(5) . . . . ?
C14 C15 C16 N2 0.2(9) . . . . ?
C22 C17 C18 C19 1.2(8) . . . . ?
N2 C17 C18 C19 -178.1(5) . . . . ?
C17 C18 C19 C20 0.0(8) . . . . ?
C18 C19 C20 C21 -1.0(8) . . . . ?
C18 C19 C20 C23 177.7(5) . . . . ?
C19 C20 C21 C22 0.9(7) . . . . ?
C23 C20 C21 C22 -177.7(5) . . . . ?
C18 C17 C22 C21 -1.3(8) . . . . ?
N2 C17 C22 C21 178.0(4) . . . . ?
C20 C21 C22 C17 0.2(7) . . . . ?
C21 C20 C23 C26 106.6(6) . . . . ?
C19 C20 C23 C26 -72.0(7) . . . . ?
N1 C24 C25 C26 -1.1(7) . . . . ?
C24 C25 C26 C27 1.4(7) . . . . ?
C24 C25 C26 C23 -177.8(4) . . . . ?
C20 C23 C26 C25 112.8(5) . . . . ?
C20 C23 C26 C27 -66.4(7) . . . . ?
C25 C26 C27 C28 -0.8(8) . . . . ?
C23 C26 C27 C28 178.4(5) . . . . ?
C26 C27 C28 N1 -0.1(9) . . . . ?
N4 C29 C30 N5 -50.8(6) . . . . ?
C25 C24 N1 C28 0.2(7) . . . . ?
C25 C24 N1 Pt1 179.0(3) . . . 2_676 ?
C27 C28 N1 C24 0.4(8) . . . . ?
C27 C28 N1 Pt1 -178.5(4) . . . 2_676 ?
C15 C16 N2 C12 -0.3(8) . . . . ?
C15 C16 N2 C17 -180.0(5) . . . . ?
C13 C12 N2 C16 0.3(8) . . . . ?
C13 C12 N2 C17 -180.0(5) . . . . ?
C18 C17 N2 C16 137.1(5) . . . . ?
C22 C17 N2 C16 -42.2(7) . . . . ?
C18 C17 N2 C12 -42.6(7) . . . . ?
C22 C17 N2 C12 138.1(5) . . . . ?
C4 C5 N3 C1 -0.9(8) . . . . ?
C4 C5 N3 Pt1 178.4(4) . . . . ?
C2 C1 N3 C5 0.9(7) . . . . ?
C2 C1 N3 Pt1 -178.3(4) . . . . ?
C30 C29 N4 Pt1 45.1(5) . . . . ?
C29 C30 N5 Pt1 32.1(5) . . . . ?

_refine_diff_density_max         2.124
_refine_diff_density_min         -0.856
_refine_diff_density_rms         0.155

