# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1494264'
_audit_update_record             
;
2016-07-18 deposited with the CCDC.
2016-08-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C16 H38 Cl8 N6 O9 W3'
_chemical_formula_weight         1293.67

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Orthorhombic
_symmetry_space_group_name_H-M   P2(1)2(1)2(1)

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   11.249(2)
_cell_length_b                   11.476(2)
_cell_length_c                   28.300(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3653.4(11)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9877
_cell_measurement_theta_min      2.285
_cell_measurement_theta_max      28.4055

_exptl_crystal_description       prism
_exptl_crystal_colour            green
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.352
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2424
_exptl_absorpt_coefficient_mu    10.055
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.2266
_exptl_absorpt_correction_T_max  0.3548
_exptl_absorpt_process_details   
; 
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption correction SADABS).
 R(int) =  0.1461 (selected reflections only, before parameter refinement)
 R(int) =  0.0744 (selected reflections only, after parameter refinement)
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            33756
_diffrn_reflns_av_R_equivalents  0.0577
_diffrn_reflns_av_sigmaI/netI    0.0524
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         1.44
_diffrn_reflns_theta_max         26.00
_reflns_number_total             7163
_reflns_number_gt                6684
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1996)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. The following restraints
 were applied (given as SHELXL lines): 
 isor .01 c4 c13 c15
 simu .01 $c $n
 dfix -2.11 .01 h3c h5c h8b h9b h13b h15b
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0275P)²+14.7450P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.007(10)
_refine_ls_number_reflns         7163
_refine_ls_number_parameters     379
_refine_ls_number_restraints     129
_refine_ls_R_factor_all          0.0406
_refine_ls_R_factor_gt           0.0357
_refine_ls_wR_factor_ref         0.0726
_refine_ls_wR_factor_gt          0.0707
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_restrained_S_all      1.069
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 1.0608(9) 0.3449(8) 0.8840(4) 0.021(2) Uani 1 1 d U . .
C2 C 1.0076(12) 0.4911(10) 0.8266(5) 0.043(3) Uani 1 1 d U . .
H2A H 1.0231 0.5737 0.8204 0.064 Uiso 1 1 calc R . .
H2B H 0.9220 0.4791 0.8308 0.064 Uiso 1 1 calc R . .
H2C H 1.0358 0.4444 0.7999 0.064 Uiso 1 1 calc R . .
C3 C 1.1688(11) 0.5400(9) 0.8801(4) 0.039(3) Uani 1 1 d U . .
H3A H 1.1529 0.6138 0.8639 0.058 Uiso 1 1 calc R . .
H3B H 1.2444 0.5078 0.8689 0.058 Uiso 1 1 calc R . .
H3C H 1.1733 0.5535 0.9142 0.058 Uiso 1 1 calc RD . .
C4 C 1.1296(9) 0.1856(8) 0.9331(4) 0.023(2) Uani 1 1 d U . .
H4A H 1.1619 0.1755 0.9650 0.035 Uiso 1 1 calc R . .
H4B H 1.1875 0.1575 0.9099 0.035 Uiso 1 1 calc R . .
H4C H 1.0557 0.1411 0.9301 0.035 Uiso 1 1 calc R . .
C5 C 1.1020(11) 0.3723(9) 0.9717(4) 0.044(3) Uani 1 1 d U . .
H5A H 1.1400 0.3239 0.9958 0.066 Uiso 1 1 calc R . .
H5B H 1.0192 0.3872 0.9806 0.066 Uiso 1 1 calc R . .
H5C H 1.1445 0.4466 0.9690 0.066 Uiso 1 1 calc RD . .
C6 C 0.8746(9) -0.3231(8) 0.9581(4) 0.0164(19) Uani 1 1 d U . .
C7 C 1.0465(10) -0.2670(9) 1.0035(4) 0.028(2) Uani 1 1 d U . .
H7A H 1.0709 -0.2620 1.0367 0.042 Uiso 1 1 calc R . .
H7B H 1.0511 -0.1895 0.9890 0.042 Uiso 1 1 calc R . .
H7C H 1.0994 -0.3206 0.9866 0.042 Uiso 1 1 calc R . .
C8 C 0.8635(9) -0.2899(8) 1.0467(3) 0.026(2) Uani 1 1 d U . .
H8A H 0.9225 -0.2818 1.0720 0.038 Uiso 1 1 calc R . .
H8B H 0.8116 -0.3563 1.0536 0.038 Uiso 1 1 calc RD . .
H8C H 0.8157 -0.2186 1.0448 0.038 Uiso 1 1 calc R . .
C9 C 0.7466(9) -0.5007(8) 0.9820(4) 0.034(3) Uani 1 1 d U . .
H9A H 0.6738 -0.5347 0.9689 0.051 Uiso 1 1 calc R . .
H9B H 0.7325 -0.4776 1.0149 0.051 Uiso 1 1 calc RD . .
H9C H 0.8108 -0.5583 0.9809 0.051 Uiso 1 1 calc R . .
C10 C 0.7177(10) -0.4003(9) 0.9078(3) 0.022(2) Uani 1 1 d U . .
H10A H 0.6520 -0.4560 0.9104 0.034 Uiso 1 1 calc R . .
H10B H 0.7724 -0.4259 0.8829 0.034 Uiso 1 1 calc R . .
H10C H 0.6861 -0.3232 0.8998 0.034 Uiso 1 1 calc R . .
C11 C 0.4261(9) 0.0505(9) 0.7883(4) 0.025(2) Uani 1 1 d U . .
C12 C 0.5751(10) 0.1780(9) 0.7522(4) 0.027(3) Uani 1 1 d U . .
H12A H 0.5925 0.2091 0.7207 0.040 Uiso 1 1 calc R . .
H12B H 0.6432 0.1327 0.7635 0.040 Uiso 1 1 calc R . .
H12C H 0.5598 0.2427 0.7740 0.040 Uiso 1 1 calc R . .
C13 C 0.4426(11) 0.0719(10) 0.7000(4) 0.043(3) Uani 1 1 d U . .
H13A H 0.4871 0.1241 0.6790 0.065 Uiso 1 1 calc R . .
H13B H 0.3573 0.0807 0.6940 0.065 Uiso 1 1 calc RD . .
H13C H 0.4663 -0.0089 0.6939 0.065 Uiso 1 1 calc R . .
C14 C 0.2765(9) -0.0648(11) 0.8279(4) 0.036(3) Uani 1 1 d U . .
H14A H 0.1926 -0.0849 0.8233 0.054 Uiso 1 1 calc R . .
H14B H 0.2861 -0.0240 0.8581 0.054 Uiso 1 1 calc R . .
H14C H 0.3244 -0.1361 0.8281 0.054 Uiso 1 1 calc R . .
C15 C 0.2038(11) 0.0695(13) 0.7696(5) 0.064(4) Uani 1 1 d U . .
H15A H 0.1345 0.0211 0.7770 0.096 Uiso 1 1 calc R . .
H15B H 0.2108 0.0780 0.7353 0.096 Uiso 1 1 calc RD . .
H15C H 0.1942 0.1465 0.7841 0.096 Uiso 1 1 calc R . .
C21 C 0.5157(12) 0.8052(10) 0.6200(4) 0.036(3) Uani 1 1 d . . .
H21A H 0.4929 0.7228 0.6150 0.043 Uiso 1 1 calc R . .
H21B H 0.4473 0.8459 0.6345 0.043 Uiso 1 1 calc R . .
Cl1 Cl 0.9145(2) 0.1417(2) 0.77642(9) 0.0208(5) Uani 1 1 d . . .
Cl2 Cl 0.8221(2) 0.2398(2) 0.92971(9) 0.0212(5) Uani 1 1 d . . .
Cl3 Cl 0.9682(2) -0.1880(2) 0.82443(9) 0.0196(5) Uani 1 1 d . . .
Cl4 Cl 0.8611(2) -0.05032(19) 0.97098(8) 0.0174(5) Uani 1 1 d . . .
Cl5 Cl 0.5587(2) 0.02792(19) 0.92476(8) 0.0190(5) Uani 1 1 d . . .
Cl6 Cl 0.6788(2) -0.0980(2) 0.77713(8) 0.0209(5) Uani 1 1 d . . .
Cl7 Cl 0.5480(3) 0.8695(3) 0.56496(11) 0.0429(8) Uani 1 1 d . . .
Cl8 Cl 0.6383(3) 0.8114(3) 0.65885(11) 0.0442(8) Uani 1 1 d . . .
N1 N 0.4687(8) 0.1019(7) 0.7498(3) 0.0234(19) Uani 1 1 d U . .
N2 N 0.3162(8) 0.0114(8) 0.7890(3) 0.027(2) Uani 1 1 d U . .
N3 N 1.0703(8) 0.4554(7) 0.8697(3) 0.0247(19) Uani 1 1 d U . .
N4 N 1.1054(7) 0.3098(7) 0.9247(3) 0.0183(17) Uani 1 1 d U . .
N5 N 0.7817(7) -0.3940(7) 0.9532(3) 0.0193(17) Uani 1 1 d U . .
N6 N 0.9255(7) -0.3095(7) 1.0008(3) 0.0165(16) Uani 1 1 d U . .
O1 O 0.9352(6) 0.0441(5) 0.8757(2) 0.0157(14) Uani 1 1 d . . .
O2 O 0.7555(6) -0.1174(5) 0.8794(2) 0.0147(15) Uani 1 1 d . . .
O3 O 0.7167(5) 0.1030(5) 0.8472(2) 0.0164(14) Uani 1 1 d . . .
O4 O 0.7699(6) 0.3302(6) 0.8299(3) 0.0188(16) Uani 1 1 d . . .
O5 O 1.0922(6) -0.1016(6) 0.9145(2) 0.0201(16) Uani 1 1 d . . .
O6 O 0.5333(6) -0.1863(6) 0.8612(2) 0.0222(16) Uani 1 1 d . . .
O7 O 1.0085(5) 0.2715(5) 0.8561(2) 0.0168(14) Uani 1 1 d . . .
O8 O 0.9175(6) -0.2735(5) 0.9215(2) 0.0158(15) Uani 1 1 d . . .
O9 O 0.4898(6) 0.0396(6) 0.8258(2) 0.0203(16) Uani 1 1 d . . .
W1 W 0.83835(4) 0.19913(3) 0.848994(15) 0.01519(9) Uani 1 1 d . . .
W2 W 0.94703(3) -0.09914(3) 0.897747(14) 0.01283(9) Uani 1 1 d . . .
W3 W 0.62238(3) -0.06483(3) 0.855312(14) 0.01388(9) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O7 1.297(11) . ?
C1 N4 1.317(12) . ?
C1 N3 1.336(12) . ?
C2 N3 1.467(14) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 N3 1.502(13) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 N4 1.471(12) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 N4 1.511(13) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 O8 1.276(11) . ?
C6 N5 1.331(12) . ?
C6 N6 1.347(12) . ?
C7 N6 1.448(13) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 N6 1.492(12) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 N5 1.524(12) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 N5 1.475(12) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 O9 1.287(12) . ?
C11 N2 1.315(14) . ?
C11 N1 1.329(13) . ?
C12 N1 1.483(13) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 N1 1.480(13) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 N2 1.474(14) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 N2 1.531(15) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C21 Cl7 1.760(11) . ?
C21 Cl8 1.766(13) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
Cl1 W1 2.321(3) . ?
Cl2 W1 2.338(3) . ?
Cl3 W2 2.324(2) . ?
Cl4 W2 2.354(2) . ?
Cl5 W3 2.347(2) . ?
Cl6 W3 2.333(2) . ?
O1 W2 1.763(6) . ?
O1 W1 2.220(6) . ?
O2 W3 1.753(6) . ?
O2 W2 2.226(6) . ?
O3 W1 1.758(6) . ?
O3 W3 2.211(6) . ?
O4 W1 1.774(7) . ?
O5 W2 1.701(7) . ?
O6 W3 1.725(7) . ?
O7 W1 2.096(6) . ?
O8 W2 2.136(6) . ?
O9 W3 2.088(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 C1 N4 120.5(9) . . ?
O7 C1 N3 117.9(9) . . ?
N4 C1 N3 121.6(9) . . ?
N3 C2 H2A 109.5 . . ?
N3 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
N3 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N3 C3 H3A 109.5 . . ?
N3 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
N3 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
N4 C4 H4A 109.5 . . ?
N4 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
N4 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
N4 C5 H5A 109.5 . . ?
N4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
N4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
O8 C6 N5 119.1(9) . . ?
O8 C6 N6 121.0(9) . . ?
N5 C6 N6 119.8(9) . . ?
N6 C7 H7A 109.5 . . ?
N6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
N6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
N6 C8 H8A 109.5 . . ?
N6 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
N6 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N5 C9 H9A 109.5 . . ?
N5 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
N5 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N5 C10 H10A 109.5 . . ?
N5 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
N5 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O9 C11 N2 118.5(10) . . ?
O9 C11 N1 121.2(10) . . ?
N2 C11 N1 120.3(10) . . ?
N1 C12 H12A 109.5 . . ?
N1 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
N1 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N1 C13 H13A 109.5 . . ?
N1 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
N1 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N2 C14 H14A 109.5 . . ?
N2 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
N2 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N2 C15 H15A 109.5 . . ?
N2 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
N2 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Cl7 C21 Cl8 111.9(6) . . ?
Cl7 C21 H21A 109.2 . . ?
Cl8 C21 H21A 109.2 . . ?
Cl7 C21 H21B 109.2 . . ?
Cl8 C21 H21B 109.2 . . ?
H21A C21 H21B 107.9 . . ?
C11 N1 C13 127.3(9) . . ?
C11 N1 C12 121.0(9) . . ?
C13 N1 C12 110.0(8) . . ?
C11 N2 C14 119.9(9) . . ?
C11 N2 C15 128.4(10) . . ?
C14 N2 C15 106.0(9) . . ?
C1 N3 C2 118.7(9) . . ?
C1 N3 C3 127.8(9) . . ?
C2 N3 C3 109.6(8) . . ?
C1 N4 C4 120.5(8) . . ?
C1 N4 C5 127.8(8) . . ?
C4 N4 C5 108.8(8) . . ?
C6 N5 C10 120.2(8) . . ?
C6 N5 C9 129.8(9) . . ?
C10 N5 C9 107.5(8) . . ?
C6 N6 C7 119.1(9) . . ?
C6 N6 C8 126.9(8) . . ?
C7 N6 C8 110.0(8) . . ?
W2 O1 W1 154.8(4) . . ?
W3 O2 W2 152.3(3) . . ?
W1 O3 W3 156.5(3) . . ?
C1 O7 W1 136.9(7) . . ?
C6 O8 W2 137.0(6) . . ?
C11 O9 W3 141.6(7) . . ?
O3 W1 O4 100.7(3) . . ?
O3 W1 O7 164.1(3) . . ?
O4 W1 O7 95.1(3) . . ?
O3 W1 O1 83.6(3) . . ?
O4 W1 O1 175.3(3) . . ?
O7 W1 O1 80.6(2) . . ?
O3 W1 Cl1 94.8(2) . . ?
O4 W1 Cl1 97.6(2) . . ?
O7 W1 Cl1 81.94(19) . . ?
O1 W1 Cl1 83.86(17) . . ?
O3 W1 Cl2 95.3(2) . . ?
O4 W1 Cl2 95.4(2) . . ?
O7 W1 Cl2 84.2(2) . . ?
O1 W1 Cl2 82.25(17) . . ?
Cl1 W1 Cl2 161.79(9) . . ?
O5 W2 O1 100.7(3) . . ?
O5 W2 O8 92.6(3) . . ?
O1 W2 O8 166.6(3) . . ?
O5 W2 O2 173.1(3) . . ?
O1 W2 O2 86.1(3) . . ?
O8 W2 O2 80.5(2) . . ?
O5 W2 Cl3 98.2(2) . . ?
O1 W2 Cl3 95.8(2) . . ?
O8 W2 Cl3 83.41(19) . . ?
O2 W2 Cl3 81.35(18) . . ?
O5 W2 Cl4 98.8(2) . . ?
O1 W2 Cl4 93.3(2) . . ?
O8 W2 Cl4 83.25(18) . . ?
O2 W2 Cl4 80.23(18) . . ?
Cl3 W2 Cl4 158.79(9) . . ?
O6 W3 O2 100.4(3) . . ?
O6 W3 O9 95.0(3) . . ?
O2 W3 O9 164.5(3) . . ?
O6 W3 O3 173.1(3) . . ?
O2 W3 O3 86.0(3) . . ?
O9 W3 O3 78.5(2) . . ?
O6 W3 Cl6 96.8(2) . . ?
O2 W3 Cl6 94.6(2) . . ?
O9 W3 Cl6 84.7(2) . . ?
O3 W3 Cl6 85.04(18) . . ?
O6 W3 Cl5 96.2(2) . . ?
O2 W3 Cl5 95.2(2) . . ?
O9 W3 Cl5 81.8(2) . . ?
O3 W3 Cl5 80.68(18) . . ?
Cl6 W3 Cl5 162.02(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O9 C11 N1 C13 145.3(10) . . . . ?
N2 C11 N1 C13 -36.1(16) . . . . ?
O9 C11 N1 C12 -18.0(15) . . . . ?
N2 C11 N1 C12 160.7(9) . . . . ?
O9 C11 N2 C14 -13.0(15) . . . . ?
N1 C11 N2 C14 168.3(10) . . . . ?
O9 C11 N2 C15 136.8(12) . . . . ?
N1 C11 N2 C15 -41.9(16) . . . . ?
O7 C1 N3 C2 8.2(15) . . . . ?
N4 C1 N3 C2 -173.4(10) . . . . ?
O7 C1 N3 C3 -147.2(10) . . . . ?
N4 C1 N3 C3 31.2(17) . . . . ?
O7 C1 N4 C4 18.6(15) . . . . ?
N3 C1 N4 C4 -159.8(10) . . . . ?
O7 C1 N4 C5 -140.2(10) . . . . ?
N3 C1 N4 C5 41.5(16) . . . . ?
O8 C6 N5 C10 -9.8(14) . . . . ?
N6 C6 N5 C10 173.7(9) . . . . ?
O8 C6 N5 C9 149.7(9) . . . . ?
N6 C6 N5 C9 -26.8(15) . . . . ?
O8 C6 N6 C7 -17.5(13) . . . . ?
N5 C6 N6 C7 158.9(9) . . . . ?
O8 C6 N6 C8 137.7(9) . . . . ?
N5 C6 N6 C8 -45.9(13) . . . . ?
N4 C1 O7 W1 84.1(12) . . . . ?
N3 C1 O7 W1 -97.5(11) . . . . ?
N5 C6 O8 W2 121.0(9) . . . . ?
N6 C6 O8 W2 -62.6(13) . . . . ?
N2 C11 O9 W3 100.0(12) . . . . ?
N1 C11 O9 W3 -81.3(14) . . . . ?
W3 O3 W1 O4 -179.4(9) . . . . ?
W3 O3 W1 O7 4.5(18) . . . . ?
W3 O3 W1 O1 -1.3(9) . . . . ?
W3 O3 W1 Cl1 81.9(9) . . . . ?
W3 O3 W1 Cl2 -82.9(9) . . . . ?
C1 O7 W1 O3 -113.9(12) . . . . ?
C1 O7 W1 O4 70.0(9) . . . . ?
C1 O7 W1 O1 -108.0(9) . . . . ?
C1 O7 W1 Cl1 166.9(9) . . . . ?
C1 O7 W1 Cl2 -25.0(9) . . . . ?
W2 O1 W1 O3 -10.5(8) . . . . ?
W2 O1 W1 O4 146(3) . . . . ?
W2 O1 W1 O7 171.2(8) . . . . ?
W2 O1 W1 Cl1 -106.0(8) . . . . ?
W2 O1 W1 Cl2 85.8(8) . . . . ?
W1 O1 W2 O5 -169.7(8) . . . . ?
W1 O1 W2 O8 4.6(18) . . . . ?
W1 O1 W2 O2 9.9(8) . . . . ?
W1 O1 W2 Cl3 90.7(8) . . . . ?
W1 O1 W2 Cl4 -70.1(8) . . . . ?
C6 O8 W2 O5 98.1(9) . . . . ?
C6 O8 W2 O1 -76.3(15) . . . . ?
C6 O8 W2 O2 -81.6(9) . . . . ?
C6 O8 W2 Cl3 -163.9(9) . . . . ?
C6 O8 W2 Cl4 -0.4(9) . . . . ?
W3 O2 W2 O5 180(100) . . . . ?
W3 O2 W2 O1 3.5(8) . . . . ?
W3 O2 W2 O8 -177.7(8) . . . . ?
W3 O2 W2 Cl3 -93.0(8) . . . . ?
W3 O2 W2 Cl4 97.5(8) . . . . ?
W2 O2 W3 O6 175.6(7) . . . . ?
W2 O2 W3 O9 -9.1(17) . . . . ?
W2 O2 W3 O3 -6.9(8) . . . . ?
W2 O2 W3 Cl6 77.8(8) . . . . ?
W2 O2 W3 Cl5 -87.1(8) . . . . ?
C11 O9 W3 O6 -67.7(11) . . . . ?
C11 O9 W3 O2 116.9(13) . . . . ?
C11 O9 W3 O3 114.6(11) . . . . ?
C11 O9 W3 Cl6 28.7(11) . . . . ?
C11 O9 W3 Cl5 -163.3(11) . . . . ?
W1 O3 W3 O6 165(2) . . . . ?
W1 O3 W3 O2 5.4(9) . . . . ?
W1 O3 W3 O9 -175.2(10) . . . . ?
W1 O3 W3 Cl6 -89.5(9) . . . . ?
W1 O3 W3 Cl5 101.4(9) . . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         2.100
_refine_diff_density_min         -1.502
_refine_diff_density_rms         0.203
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1494265'
_audit_update_record             
;
2016-07-18 deposited with the CCDC.
2016-08-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C10 H24 Cl2 N4 O4 W'
_chemical_formula_weight         519.08

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   14.211(3)
_cell_length_b                   22.418(5)
_cell_length_c                   18.094(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 113.063(3)
_cell_angle_gamma                90.00
_cell_volume                     5304(2)
_cell_formula_units_Z            12
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9808
_cell_measurement_theta_min      2.3935
_cell_measurement_theta_max      28.326

_exptl_crystal_description       prism
_exptl_crystal_colour            pale-yellow
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.11
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.950
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3024
_exptl_absorpt_coefficient_mu    6.854
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.3271
_exptl_absorpt_correction_T_max  0.5194
_exptl_absorpt_process_details   
; 
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption correction SADABS).
 R(int) =  0.1525 (selected reflections only, before parameter refinement)
 R(int) =  0.0940 (selected reflections only, after parameter refinement)
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            51807
_diffrn_reflns_av_R_equivalents  0.0830
_diffrn_reflns_av_sigmaI/netI    0.0599
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.22
_diffrn_reflns_theta_max         26.00
_reflns_number_total             10547
_reflns_number_gt                9056
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1996)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. The following restraints
 were applied (given as SHELXL lines): 
 dfix -2.1  h3c h4c h7c h10c h13c h15c h18c h20c h23c h24c h28c h30c
 eqiv $1 2-x, 1-y, 2-z
 eqiv $2 -x, 1-y, 1-z
 eqiv $3 0.5-x, -0.5+y, 1.5-z
 dfix -2.11  .01 h4a h13a_$1 h30a h30a_$2 h4b h22b_$3
 isor .02 c3 c15 c28
 simu $c $o $n
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0918P)²+40.6454P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10547
_refine_ls_number_parameters     569
_refine_ls_number_restraints     279
_refine_ls_R_factor_all          0.0646
_refine_ls_R_factor_gt           0.0544
_refine_ls_wR_factor_ref         0.1576
_refine_ls_wR_factor_gt          0.1461
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 1.01239(5) 0.40246(2) 0.77883(3) 0.01925(13) Uani 1 1 d . . .
Cl1 Cl 0.8842(3) 0.40132(15) 0.64566(19) 0.0274(7) Uani 1 1 d . . .
Cl2 Cl 1.1409(3) 0.37475(16) 0.90300(18) 0.0278(7) Uani 1 1 d . . .
O1 O 1.0837(8) 0.4532(4) 0.7555(6) 0.030(2) Uani 1 1 d . . .
O2 O 0.9474(8) 0.4471(4) 0.8201(6) 0.027(2) Uani 1 1 d . . .
O3 O 0.9282(7) 0.3246(4) 0.7941(6) 0.019(2) Uani 1 1 d U . .
C1 C 0.8991(10) 0.3084(6) 0.8515(8) 0.020(3) Uani 1 1 d U . .
N1 N 0.8272(9) 0.3393(5) 0.8651(6) 0.019(2) Uani 1 1 d U . .
N2 N 0.9438(9) 0.2611(5) 0.8947(6) 0.021(2) Uani 1 1 d U . .
C2 C 0.7592(11) 0.3786(6) 0.8040(7) 0.023(3) Uani 1 1 d U . .
H2A H 0.7113 0.3973 0.8239 0.034 Uiso 1 1 calc R . .
H2B H 0.7210 0.3555 0.7555 0.034 Uiso 1 1 calc R . .
H2C H 0.7994 0.4095 0.7915 0.034 Uiso 1 1 calc R . .
C3 C 0.8130(12) 0.3523(8) 0.9426(9) 0.047(4) Uani 1 1 d U . .
H3A H 0.7529 0.3778 0.9309 0.070 Uiso 1 1 calc R . .
H3B H 0.8738 0.3727 0.9803 0.070 Uiso 1 1 calc R . .
H3C H 0.8031 0.3147 0.9663 0.070 Uiso 1 1 calc RD . .
C4 C 0.8920(9) 0.2193(5) 0.9301(6) 0.024(3) Uani 1 1 d U . .
H4A H 0.9396 0.1876 0.9590 0.037 Uiso 1 1 calc RD . .
H4B H 0.8323 0.2018 0.8872 0.037 Uiso 1 1 calc RD . .
H4C H 0.8698 0.2410 0.9675 0.037 Uiso 1 1 calc RD . .
C5 C 1.0311(11) 0.2327(6) 0.8840(8) 0.026(3) Uani 1 1 d U . .
H5A H 1.0546 0.1985 0.9203 0.038 Uiso 1 1 calc R . .
H5B H 1.0868 0.2616 0.8962 0.038 Uiso 1 1 calc R . .
H5C H 1.0098 0.2191 0.8283 0.038 Uiso 1 1 calc R . .
O4 O 1.0726(7) 0.3269(4) 0.7362(5) 0.0171(18) Uani 1 1 d U . .
C6 C 1.0868(10) 0.3137(6) 0.6725(7) 0.019(3) Uani 1 1 d U . .
N3 N 1.0323(9) 0.2713(5) 0.6248(6) 0.020(2) Uani 1 1 d U . .
N4 N 1.1593(9) 0.3435(5) 0.6556(6) 0.020(2) Uani 1 1 d U . .
C7 C 1.0666(12) 0.2280(6) 0.5785(8) 0.031(3) Uani 1 1 d U . .
H7A H 1.0105 0.2006 0.5496 0.046 Uiso 1 1 calc R . .
H7B H 1.1251 0.2054 0.6154 0.046 Uiso 1 1 calc R . .
H7C H 1.0868 0.2496 0.5399 0.046 Uiso 1 1 calc RD . .
C8 C 0.9431(11) 0.2462(6) 0.6384(8) 0.024(3) Uani 1 1 d U . .
H8A H 0.9112 0.2146 0.5990 0.035 Uiso 1 1 calc R . .
H8B H 0.8932 0.2778 0.6324 0.035 Uiso 1 1 calc R . .
H8C H 0.9665 0.2295 0.6927 0.035 Uiso 1 1 calc R . .
C9 C 1.2387(11) 0.3763(7) 0.7162(7) 0.027(3) Uani 1 1 d U . .
H9A H 1.2834 0.3946 0.6927 0.041 Uiso 1 1 calc R . .
H9B H 1.2789 0.3493 0.7596 0.041 Uiso 1 1 calc R . .
H9C H 1.2083 0.4076 0.7376 0.041 Uiso 1 1 calc R . .
C10 C 1.1612(13) 0.3599(6) 0.5752(7) 0.037(4) Uani 1 1 d U . .
H10A H 1.2239 0.3821 0.5836 0.056 Uiso 1 1 calc R . .
H10B H 1.1016 0.3847 0.5453 0.056 Uiso 1 1 calc R . .
H10C H 1.1593 0.3235 0.5447 0.056 Uiso 1 1 calc RD . .
W2 W 0.97281(4) 1.06877(2) 0.73584(3) 0.02203(15) Uani 1 1 d . . .
Cl3 Cl 0.8438(3) 1.04638(17) 0.6092(2) 0.0315(8) Uani 1 1 d . . .
Cl4 Cl 1.1018(3) 1.06237(17) 0.8684(2) 0.0320(8) Uani 1 1 d . . .
O5 O 1.0378(8) 1.1151(4) 0.6977(7) 0.032(2) Uani 1 1 d . . .
O6 O 0.9027(9) 1.1172(4) 0.7655(7) 0.038(3) Uani 1 1 d . . .
O7 O 0.9105(7) 0.9918(4) 0.7739(5) 0.0158(18) Uani 1 1 d U . .
C11 C 0.8943(10) 0.9780(6) 0.8354(7) 0.017(3) Uani 1 1 d U . .
N5 N 0.9485(10) 0.9339(5) 0.8824(6) 0.026(3) Uani 1 1 d U . .
N6 N 0.8215(10) 1.0059(5) 0.8536(7) 0.027(3) Uani 1 1 d U . .
C12 C 1.0387(11) 0.9098(7) 0.8702(9) 0.031(3) Uani 1 1 d U . .
H12A H 1.0695 0.8776 0.9088 0.047 Uiso 1 1 calc R . .
H12B H 1.0890 0.9417 0.8785 0.047 Uiso 1 1 calc R . .
H12C H 1.0171 0.8943 0.8154 0.047 Uiso 1 1 calc R . .
C13 C 0.9028(10) 0.8896(6) 0.9185(8) 0.032(3) Uani 1 1 d U . .
H13A H 0.9548 0.8603 0.9487 0.049 Uiso 1 1 calc R . .
H13B H 0.8463 0.8693 0.8760 0.049 Uiso 1 1 calc R . .
H13C H 0.8770 0.9097 0.9549 0.049 Uiso 1 1 calc RD . .
C14 C 0.7403(11) 1.0386(6) 0.7933(8) 0.027(3) Uani 1 1 d U . .
H14A H 0.6953 1.0557 0.8172 0.040 Uiso 1 1 calc R . .
H14B H 0.7008 1.0116 0.7495 0.040 Uiso 1 1 calc R . .
H14C H 0.7695 1.0707 0.7722 0.040 Uiso 1 1 calc R . .
C15 C 0.8198(14) 1.0227(7) 0.9348(9) 0.049(5) Uani 1 1 d U . .
H15A H 0.7564 1.0442 0.9264 0.073 Uiso 1 1 calc R . .
H15B H 0.8786 1.0482 0.9641 0.073 Uiso 1 1 calc R . .
H15C H 0.8232 0.9864 0.9659 0.073 Uiso 1 1 calc RD . .
O8 O 1.0536(7) 0.9915(4) 0.7149(6) 0.023(2) Uani 1 1 d U . .
C16 C 1.0838(10) 0.9785(6) 0.6581(8) 0.020(3) Uani 1 1 d U . .
N7 N 1.0412(8) 0.9330(5) 0.6107(6) 0.021(2) Uani 1 1 d U . .
N8 N 1.1603(9) 1.0110(5) 0.6496(6) 0.024(2) Uani 1 1 d U . .
C17 C 0.9533(10) 0.9032(6) 0.6200(8) 0.024(3) Uani 1 1 d U . .
H17A H 0.9296 0.8700 0.5818 0.036 Uiso 1 1 calc R . .
H17B H 0.8976 0.9320 0.6094 0.036 Uiso 1 1 calc R . .
H17C H 0.9746 0.8879 0.6749 0.036 Uiso 1 1 calc R . .
C18 C 1.0866(12) 0.8911(6) 0.5696(8) 0.037(4) Uani 1 1 d U . .
H18A H 1.0354 0.8613 0.5395 0.056 Uiso 1 1 calc R . .
H18B H 1.1457 0.8709 0.6098 0.056 Uiso 1 1 calc R . .
H18C H 1.1085 0.9134 0.5326 0.056 Uiso 1 1 calc RD . .
C19 C 1.2281(11) 1.0477(6) 0.7136(8) 0.027(3) Uani 1 1 d U . .
H19A H 1.2776 1.0671 0.6961 0.041 Uiso 1 1 calc R . .
H19B H 1.2644 1.0228 0.7607 0.041 Uiso 1 1 calc R . .
H19C H 1.1883 1.0781 0.7275 0.041 Uiso 1 1 calc R . .
C20 C 1.1744(12) 1.0259(7) 0.5739(9) 0.039(4) Uani 1 1 d U . .
H20A H 1.2358 1.0506 0.5868 0.059 Uiso 1 1 calc R . .
H20B H 1.1146 1.0479 0.5375 0.059 Uiso 1 1 calc R . .
H20C H 1.1822 0.9890 0.5477 0.059 Uiso 1 1 calc RD . .
W3 W 0.01477(4) 0.73596(2) 0.73250(3) 0.02006(14) Uani 1 1 d . . .
Cl5 Cl -0.1153(3) 0.71352(16) 0.6058(2) 0.0307(8) Uani 1 1 d . . .
Cl6 Cl 0.1429(3) 0.72903(16) 0.8640(2) 0.0313(8) Uani 1 1 d . . .
O9 O 0.0816(8) 0.7788(4) 0.6917(7) 0.033(2) Uani 1 1 d . . .
O10 O -0.0554(8) 0.7885(4) 0.7573(6) 0.031(3) Uani 1 1 d . . .
O11 O -0.0553(7) 0.6619(4) 0.7695(5) 0.0163(18) Uani 1 1 d U . .
C21 C -0.0783(11) 0.6505(6) 0.8302(7) 0.020(3) Uani 1 1 d U . .
N9 N -0.1513(8) 0.6824(5) 0.8435(6) 0.017(2) Uani 1 1 d U . .
N10 N -0.0297(8) 0.6063(5) 0.8789(6) 0.018(2) Uani 1 1 d U . .
C22 C -0.2217(10) 0.7173(6) 0.7818(6) 0.027(3) Uani 1 1 d U . .
H22A H -0.2681 0.7374 0.8019 0.041 Uiso 1 1 calc R . .
H22B H -0.2612 0.6915 0.7364 0.041 Uiso 1 1 calc R . .
H22C H -0.1847 0.7471 0.7641 0.041 Uiso 1 1 calc R . .
C23 C -0.1617(12) 0.6966(6) 0.9200(8) 0.030(3) Uani 1 1 d U . .
H23A H -0.2227 0.7212 0.9089 0.045 Uiso 1 1 calc R . .
H23B H -0.1010 0.7184 0.9554 0.045 Uiso 1 1 calc R . .
H23C H -0.1683 0.6595 0.9463 0.045 Uiso 1 1 calc RD . .
C24 C -0.0673(11) 0.5654(6) 0.9252(8) 0.030(3) Uani 1 1 d U . .
H24A H -0.0133 0.5369 0.9547 0.046 Uiso 1 1 calc R . .
H24B H -0.1272 0.5437 0.8884 0.046 Uiso 1 1 calc R . .
H24C H -0.0863 0.5884 0.9633 0.046 Uiso 1 1 calc RD . .
C25 C 0.0583(10) 0.5777(5) 0.8666(7) 0.020(3) Uani 1 1 d U . .
H25A H 0.0867 0.5458 0.9061 0.030 Uiso 1 1 calc R . .
H25B H 0.1112 0.6077 0.8734 0.030 Uiso 1 1 calc R . .
H25C H 0.0346 0.5610 0.8123 0.030 Uiso 1 1 calc R . .
O12 O 0.0897(8) 0.6563(4) 0.7113(5) 0.020(2) Uani 1 1 d U . .
C26 C 0.1102(9) 0.6404(5) 0.6511(7) 0.014(2) Uani 1 1 d U . .
N11 N 0.1850(10) 0.6690(5) 0.6358(6) 0.025(2) Uani 1 1 d U . .
N12 N 0.0644(9) 0.5932(5) 0.6089(6) 0.024(2) Uani 1 1 d U . .
C27 C 0.2599(10) 0.7043(6) 0.6962(8) 0.025(3) Uani 1 1 d U . .
H27A H 0.3066 0.7219 0.6742 0.037 Uiso 1 1 calc R . .
H27B H 0.2986 0.6790 0.7423 0.037 Uiso 1 1 calc R . .
H27C H 0.2258 0.7361 0.7134 0.037 Uiso 1 1 calc R . .
C28 C 0.1895(14) 0.6859(8) 0.5550(9) 0.055(5) Uani 1 1 d U . .
H28A H 0.2521 0.7086 0.5646 0.082 Uiso 1 1 calc R . .
H28B H 0.1298 0.7103 0.5240 0.082 Uiso 1 1 calc R . .
H28C H 0.1893 0.6495 0.5249 0.082 Uiso 1 1 calc RD . .
C29 C -0.0239(10) 0.5674(6) 0.6204(8) 0.022(3) Uani 1 1 d U . .
H29A H -0.0497 0.5331 0.5846 0.034 Uiso 1 1 calc R . .
H29B H -0.0780 0.5974 0.6082 0.034 Uiso 1 1 calc R . .
H29C H -0.0030 0.5543 0.6763 0.034 Uiso 1 1 calc R . .
C30 C 0.1123(7) 0.5508(5) 0.5729(6) 0.031(3) Uani 1 1 d U . .
H30A H 0.0634 0.5192 0.5455 0.047 Uiso 1 1 calc RD . .
H30B H 0.1726 0.5332 0.6151 0.047 Uiso 1 1 calc R . .
H30C H 0.1330 0.5716 0.5341 0.047 Uiso 1 1 calc RD . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O1 1.684(10) . ?
W1 O2 1.718(9) . ?
W1 O4 2.172(8) . ?
W1 O3 2.194(8) . ?
W1 Cl2 2.357(4) . ?
W1 Cl1 2.385(3) . ?
O3 C1 1.311(15) . ?
C1 N2 1.323(17) . ?
C1 N1 1.334(17) . ?
N1 C2 1.447(16) . ?
N1 C3 1.522(16) . ?
N2 C5 1.473(16) . ?
N2 C4 1.482(15) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
O4 C6 1.281(14) . ?
C6 N3 1.313(17) . ?
C6 N4 1.358(17) . ?
N3 C7 1.484(15) . ?
N3 C8 1.492(17) . ?
N4 C9 1.432(17) . ?
N4 C10 1.510(15) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
W2 O6 1.696(10) . ?
W2 O5 1.704(9) . ?
W2 O7 2.171(8) . ?
W2 O8 2.191(9) . ?
W2 Cl3 2.361(4) . ?
W2 Cl4 2.386(4) . ?
O7 C11 1.260(15) . ?
C11 N5 1.334(17) . ?
C11 N6 1.356(17) . ?
N5 C13 1.472(16) . ?
N5 C12 1.486(18) . ?
N6 C14 1.440(18) . ?
N6 C15 1.525(16) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
O8 C16 1.293(16) . ?
C16 N7 1.318(17) . ?
C16 N8 1.367(18) . ?
N7 C17 1.483(16) . ?
N7 C18 1.491(17) . ?
N8 C19 1.439(17) . ?
N8 C20 1.499(18) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
W3 O9 1.708(9) . ?
W3 O10 1.713(9) . ?
W3 O11 2.172(8) . ?
W3 O12 2.190(9) . ?
W3 Cl5 2.367(4) . ?
W3 Cl6 2.368(4) . ?
O11 C21 1.288(14) . ?
C21 N10 1.327(17) . ?
C21 N9 1.356(17) . ?
N9 C22 1.409(15) . ?
N9 C23 1.483(15) . ?
N10 C24 1.475(16) . ?
N10 C25 1.497(16) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
O12 C26 1.282(14) . ?
C26 N12 1.317(16) . ?
C26 N11 1.361(17) . ?
N11 C27 1.427(17) . ?
N11 C28 1.535(16) . ?
N12 C30 1.463(16) . ?
N12 C29 1.469(17) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 W1 O2 101.2(4) . . ?
O1 W1 O4 94.5(4) . . ?
O2 W1 O4 164.2(4) . . ?
O1 W1 O3 168.7(4) . . ?
O2 W1 O3 89.8(4) . . ?
O4 W1 O3 74.6(3) . . ?
O1 W1 Cl2 95.7(4) . . ?
O2 W1 Cl2 95.0(3) . . ?
O4 W1 Cl2 82.3(3) . . ?
O3 W1 Cl2 85.8(3) . . ?
O1 W1 Cl1 92.9(4) . . ?
O2 W1 Cl1 96.7(3) . . ?
O4 W1 Cl1 83.4(3) . . ?
O3 W1 Cl1 83.1(3) . . ?
Cl2 W1 Cl1 163.83(12) . . ?
C1 O3 W1 132.6(8) . . ?
O3 C1 N2 117.6(12) . . ?
O3 C1 N1 120.2(12) . . ?
N2 C1 N1 122.1(12) . . ?
C1 N1 C2 120.4(10) . . ?
C1 N1 C3 131.0(11) . . ?
C2 N1 C3 107.2(10) . . ?
C1 N2 C5 120.1(11) . . ?
C1 N2 C4 123.9(11) . . ?
C5 N2 C4 111.8(10) . . ?
N1 C2 H2A 109.5 . . ?
N1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
N1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N1 C3 H3A 109.5 . . ?
N1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
N1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
N2 C4 H4A 109.5 . . ?
N2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
N2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
N2 C5 H5A 109.5 . . ?
N2 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
N2 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C6 O4 W1 136.2(8) . . ?
O4 C6 N3 119.8(12) . . ?
O4 C6 N4 119.4(12) . . ?
N3 C6 N4 120.8(11) . . ?
C6 N3 C7 127.2(11) . . ?
C6 N3 C8 119.1(10) . . ?
C7 N3 C8 109.5(10) . . ?
C6 N4 C9 121.3(10) . . ?
C6 N4 C10 129.6(12) . . ?
C9 N4 C10 107.8(10) . . ?
N3 C7 H7A 109.5 . . ?
N3 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
N3 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
N3 C8 H8A 109.5 . . ?
N3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
N3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N4 C9 H9A 109.5 . . ?
N4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
N4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N4 C10 H10A 109.5 . . ?
N4 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
N4 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O6 W2 O5 102.5(5) . . ?
O6 W2 O7 92.6(4) . . ?
O5 W2 O7 164.9(4) . . ?
O6 W2 O8 166.6(5) . . ?
O5 W2 O8 90.4(4) . . ?
O7 W2 O8 74.5(3) . . ?
O6 W2 Cl3 96.5(4) . . ?
O5 W2 Cl3 94.3(4) . . ?
O7 W2 Cl3 83.1(2) . . ?
O8 W2 Cl3 85.7(3) . . ?
O6 W2 Cl4 92.0(4) . . ?
O5 W2 Cl4 96.8(4) . . ?
O7 W2 Cl4 83.2(2) . . ?
O8 W2 Cl4 83.0(3) . . ?
Cl3 W2 Cl4 164.17(13) . . ?
C11 O7 W2 135.5(8) . . ?
O7 C11 N5 119.1(12) . . ?
O7 C11 N6 121.5(12) . . ?
N5 C11 N6 119.4(11) . . ?
C11 N5 C13 122.6(11) . . ?
C11 N5 C12 119.4(11) . . ?
C13 N5 C12 112.1(11) . . ?
C11 N6 C14 120.7(11) . . ?
C11 N6 C15 130.6(13) . . ?
C14 N6 C15 107.1(11) . . ?
N5 C12 H12A 109.5 . . ?
N5 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
N5 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N5 C13 H13A 109.5 . . ?
N5 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
N5 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N6 C14 H14A 109.5 . . ?
N6 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
N6 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N6 C15 H15A 109.5 . . ?
N6 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
N6 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C16 O8 W2 132.5(8) . . ?
O8 C16 N7 118.8(12) . . ?
O8 C16 N8 119.7(12) . . ?
N7 C16 N8 121.5(12) . . ?
C16 N7 C17 117.8(11) . . ?
C16 N7 C18 129.3(12) . . ?
C17 N7 C18 108.7(11) . . ?
C16 N8 C19 121.7(11) . . ?
C16 N8 C20 128.2(12) . . ?
C19 N8 C20 108.7(11) . . ?
N7 C17 H17A 109.5 . . ?
N7 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
N7 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N7 C18 H18A 109.5 . . ?
N7 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N7 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N8 C19 H19A 109.5 . . ?
N8 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
N8 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N8 C20 H20A 109.5 . . ?
N8 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
N8 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
O9 W3 O10 101.9(5) . . ?
O9 W3 O11 164.2(4) . . ?
O10 W3 O11 93.5(4) . . ?
O9 W3 O12 89.5(4) . . ?
O10 W3 O12 168.6(4) . . ?
O11 W3 O12 75.2(3) . . ?
O9 W3 Cl5 93.2(4) . . ?
O10 W3 Cl5 94.9(4) . . ?
O11 W3 Cl5 81.8(2) . . ?
O12 W3 Cl5 84.6(3) . . ?
O9 W3 Cl6 97.6(4) . . ?
O10 W3 Cl6 94.5(4) . . ?
O11 W3 Cl6 84.5(2) . . ?
O12 W3 Cl6 83.5(3) . . ?
Cl5 W3 Cl6 163.81(13) . . ?
C21 O11 W3 135.7(8) . . ?
O11 C21 N10 118.4(12) . . ?
O11 C21 N9 120.9(12) . . ?
N10 C21 N9 120.7(11) . . ?
C21 N9 C22 120.4(10) . . ?
C21 N9 C23 129.9(11) . . ?
C22 N9 C23 108.7(10) . . ?
C21 N10 C24 129.2(11) . . ?
C21 N10 C25 117.9(10) . . ?
C24 N10 C25 109.2(10) . . ?
N9 C22 H22A 109.5 . . ?
N9 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
N9 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N9 C23 H23A 109.5 . . ?
N9 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
N9 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N10 C24 H24A 109.5 . . ?
N10 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
N10 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N10 C25 H25A 109.5 . . ?
N10 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
N10 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C26 O12 W3 131.6(7) . . ?
O12 C26 N12 119.4(12) . . ?
O12 C26 N11 119.7(11) . . ?
N12 C26 N11 120.6(11) . . ?
C26 N11 C27 120.9(10) . . ?
C26 N11 C28 129.6(12) . . ?
C27 N11 C28 107.2(11) . . ?
C26 N12 C30 124.7(11) . . ?
C26 N12 C29 119.3(11) . . ?
C30 N12 C29 112.3(10) . . ?
N11 C27 H27A 109.5 . . ?
N11 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
N11 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
N11 C28 H28A 109.5 . . ?
N11 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
N11 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N12 C29 H29A 109.5 . . ?
N12 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
N12 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
N12 C30 H30A 109.5 . . ?
N12 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
N12 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 W1 O3 C1 154(2) . . . . ?
O2 W1 O3 C1 -39.2(12) . . . . ?
O4 W1 O3 C1 139.0(12) . . . . ?
Cl2 W1 O3 C1 55.8(11) . . . . ?
Cl1 W1 O3 C1 -136.0(11) . . . . ?
W1 O3 C1 N2 -111.5(12) . . . . ?
W1 O3 C1 N1 68.2(16) . . . . ?
O3 C1 N1 C2 18.8(18) . . . . ?
N2 C1 N1 C2 -161.4(12) . . . . ?
O3 C1 N1 C3 -146.5(14) . . . . ?
N2 C1 N1 C3 33(2) . . . . ?
O3 C1 N2 C5 7.0(18) . . . . ?
N1 C1 N2 C5 -172.8(12) . . . . ?
O3 C1 N2 C4 -147.8(11) . . . . ?
N1 C1 N2 C4 32.4(19) . . . . ?
O1 W1 O4 C6 -49.3(14) . . . . ?
O2 W1 O4 C6 134.4(17) . . . . ?
O3 W1 O4 C6 127.8(13) . . . . ?
Cl2 W1 O4 C6 -144.4(13) . . . . ?
Cl1 W1 O4 C6 43.1(13) . . . . ?
W1 O4 C6 N3 -112.1(13) . . . . ?
W1 O4 C6 N4 68.7(17) . . . . ?
O4 C6 N3 C7 -144.3(12) . . . . ?
N4 C6 N3 C7 34.8(19) . . . . ?
O4 C6 N3 C8 10.2(18) . . . . ?
N4 C6 N3 C8 -170.7(11) . . . . ?
O4 C6 N4 C9 18.0(18) . . . . ?
N3 C6 N4 C9 -161.1(13) . . . . ?
O4 C6 N4 C10 -147.6(13) . . . . ?
N3 C6 N4 C10 33(2) . . . . ?
O6 W2 O7 C11 -45.8(13) . . . . ?
O5 W2 O7 C11 136.9(18) . . . . ?
O8 W2 O7 C11 130.5(13) . . . . ?
Cl3 W2 O7 C11 -142.1(12) . . . . ?
Cl4 W2 O7 C11 45.9(12) . . . . ?
W2 O7 C11 N5 -113.0(13) . . . . ?
W2 O7 C11 N6 68.7(16) . . . . ?
O7 C11 N5 C13 -139.6(13) . . . . ?
N6 C11 N5 C13 38.8(18) . . . . ?
O7 C11 N5 C12 11.2(18) . . . . ?
N6 C11 N5 C12 -170.4(12) . . . . ?
O7 C11 N6 C14 19.1(19) . . . . ?
N5 C11 N6 C14 -159.3(13) . . . . ?
O7 C11 N6 C15 -144.5(14) . . . . ?
N5 C11 N6 C15 37(2) . . . . ?
O6 W2 O8 C16 157.6(19) . . . . ?
O5 W2 O8 C16 -36.8(12) . . . . ?
O7 W2 O8 C16 141.6(12) . . . . ?
Cl3 W2 O8 C16 57.5(12) . . . . ?
Cl4 W2 O8 C16 -133.6(12) . . . . ?
W2 O8 C16 N7 -113.9(12) . . . . ?
W2 O8 C16 N8 67.7(17) . . . . ?
O8 C16 N7 C17 6.3(18) . . . . ?
N8 C16 N7 C17 -175.3(12) . . . . ?
O8 C16 N7 C18 -148.1(13) . . . . ?
N8 C16 N7 C18 30(2) . . . . ?
O8 C16 N8 C19 17.9(19) . . . . ?
N7 C16 N8 C19 -160.5(13) . . . . ?
O8 C16 N8 C20 -147.5(13) . . . . ?
N7 C16 N8 C20 34(2) . . . . ?
O9 W3 O11 C21 148.5(17) . . . . ?
O10 W3 O11 C21 -44.5(13) . . . . ?
O12 W3 O11 C21 134.5(13) . . . . ?
Cl5 W3 O11 C21 -139.0(13) . . . . ?
Cl6 W3 O11 C21 49.7(13) . . . . ?
W3 O11 C21 N10 -114.4(12) . . . . ?
W3 O11 C21 N9 66.4(18) . . . . ?
O11 C21 N9 C22 16.9(18) . . . . ?
N10 C21 N9 C22 -162.3(12) . . . . ?
O11 C21 N9 C23 -150.8(13) . . . . ?
N10 C21 N9 C23 30(2) . . . . ?
O11 C21 N10 C24 -147.7(13) . . . . ?
N9 C21 N10 C24 32(2) . . . . ?
O11 C21 N10 C25 7.9(17) . . . . ?
N9 C21 N10 C25 -172.8(11) . . . . ?
O9 W3 O12 C26 -42.2(12) . . . . ?
O10 W3 O12 C26 139(2) . . . . ?
O11 W3 O12 C26 134.1(12) . . . . ?
Cl5 W3 O12 C26 51.1(11) . . . . ?
Cl6 W3 O12 C26 -139.9(12) . . . . ?
W3 O12 C26 N12 -114.2(12) . . . . ?
W3 O12 C26 N11 71.4(15) . . . . ?
O12 C26 N11 C27 17.9(18) . . . . ?
N12 C26 N11 C27 -156.5(12) . . . . ?
O12 C26 N11 C28 -142.6(14) . . . . ?
N12 C26 N11 C28 43(2) . . . . ?
O12 C26 N12 C30 -144.0(12) . . . . ?
N11 C26 N12 C30 30.4(18) . . . . ?
O12 C26 N12 C29 12.6(17) . . . . ?
N11 C26 N12 C29 -173.0(11) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         2.445
_refine_diff_density_min         -3.752
_refine_diff_density_rms         0.283

