# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 990410'
_audit_update_record             
;
2016-10-01 deposited with the CCDC.
2016-10-13 downloaded from the CCDC.
;
_audit_creation_date             2016-09-30
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.09.09 svn.r3337 for OlexSys, GUI svn.r5227)
;
_shelxl_version_number           2013-2
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C12 H6 Ag4 N2 O12, 2(H4 N), 2.75(H2 O)'
_chemical_formula_sum            'C12 H19.50 Ag4 N4 O14.75'
_chemical_formula_weight         887.29
_chemical_melting_point          ?
_chemical_oxdiff_formula         C2H2O2N2Ag2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.6914(9)
_cell_length_b                   17.9225(16)
_cell_length_c                   13.0999(12)
_cell_angle_alpha                90
_cell_angle_beta                 109.831(10)
_cell_angle_gamma                90
_cell_volume                     2140.4(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    3253
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.1359
_cell_measurement_theta_min      3.1923
_shelx_estimated_absorpt_T_max   0.541
_shelx_estimated_absorpt_T_min   0.511
_exptl_absorpt_coefficient_mu    3.690
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.54602
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.753
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1702
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.19
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0328
_diffrn_reflns_av_unetI/netI     0.0414
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.842
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            10373
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.842
_diffrn_reflns_theta_full        25.250
_diffrn_reflns_theta_max         29.200
_diffrn_reflns_theta_min         3.223
_diffrn_ambient_temperature      293.15
_diffrn_detector_area_resol_mean 16.2312
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.842
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -69.00  -25.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.2945  124.0000  -21.0000 44

#__ type_ start__ end____ width___ exp.time_
  2 omega   15.00   76.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       19.9508 -124.0000 -158.0000 61

#__ type_ start__ end____ width___ exp.time_
  3 omega  -29.00   89.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       19.9508    0.0000  150.0000 118

#__ type_ start__ end____ width___ exp.time_
  4 omega  -10.00   15.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       19.9508   77.0000 -150.0000 25
;
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0673847000
_diffrn_orient_matrix_UB_12      -0.0191535000
_diffrn_orient_matrix_UB_13      0.0100502000
_diffrn_orient_matrix_UB_21      0.0380581000
_diffrn_orient_matrix_UB_22      0.0345240000
_diffrn_orient_matrix_UB_23      0.0094654000
_diffrn_orient_matrix_UB_31      0.0087699000
_diffrn_orient_matrix_UB_32      -0.0023749000
_diffrn_orient_matrix_UB_33      0.0558846000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3944
_reflns_number_total             4885
_reflns_odcompleteness_completeness 99.76
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.881
_refine_diff_density_min         -1.322
_refine_diff_density_rms         0.167
_refine_ls_extinction_coef       0.0134(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     328
_refine_ls_number_reflns         4885
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0516
_refine_ls_R_factor_gt           0.0395
_refine_ls_restrained_S_all      1.083
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0379P)²+1.4801P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0908
_refine_ls_wR_factor_ref         0.0977
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All N(H,H,H) groups, {H2WA,H2WB} of O2W, {H3WA,H3WB} of O3W, All N(H,H,H,H)
  groups
 At 1.5 times of:
  {H1WA,H1WB} of O1W
2. Others
 Fixed Sof: O3W(0.75) H3WA(0.75) H3WB(0.75)
3.a Riding coordinates:
 N1(H1A,H1B,H1C,H1D), N2(H2A,H2B,H2C,H2D)
3.b Free rotating group:
 O1W(H1WA,H1WB), O2W(H2WA,H2WB), O3W(H3WA,H3WB)
3.c Idealised Me refined as rotating group:
 N4(H4A,H4B,H4C), N3(H3A,H3B,H3C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.24216(3) 0.43041(2) 0.49217(3) 0.03181(13) Uani 1 1 d . . . . .
Ag2 Ag 0.73641(4) 0.06083(2) 0.72763(3) 0.02954(13) Uani 1 1 d . . . . .
Ag3 Ag 0.76916(5) 0.06896(2) 0.50492(3) 0.03772(14) Uani 1 1 d . . . . .
Ag4 Ag -0.23571(4) 0.06459(2) 0.26512(3) 0.03214(12) Uani 1 1 d . . . . .
O1 O -0.1164(3) 0.32111(16) 0.3406(2) 0.0236(6) Uani 1 1 d . . . . .
O2 O -0.0313(3) 0.37030(16) 0.5071(2) 0.0261(7) Uani 1 1 d . . . . .
O3 O 0.1871(3) 0.44392(15) 0.4018(2) 0.0257(7) Uani 1 1 d . . . . .
O4 O 0.3188(3) 0.44370(15) 0.5785(2) 0.0259(7) Uani 1 1 d . . . . .
O5 O 0.5434(3) 0.37139(17) 0.4729(2) 0.0286(7) Uani 1 1 d . . . . .
O6 O 0.6322(3) 0.32005(16) 0.6384(2) 0.0255(6) Uani 1 1 d . . . . .
O7 O 0.6241(3) 0.16979(15) 0.5216(2) 0.0233(6) Uani 1 1 d . . . . .
O8 O 0.5450(3) 0.12911(15) 0.6535(2) 0.0228(6) Uani 1 1 d . . . . .
O9 O 0.3337(3) 0.05605(16) 0.4374(2) 0.0320(7) Uani 1 1 d . . . . .
O10 O 0.1845(4) 0.05247(16) 0.5333(2) 0.0318(7) Uani 1 1 d . . . . .
O11 O -0.0349(3) 0.12876(16) 0.3258(2) 0.0232(6) Uani 1 1 d . . . . .
O12 O -0.1111(3) 0.17386(15) 0.4562(2) 0.0217(6) Uani 1 1 d . . . . .
C1 C 0.1233(4) 0.2878(2) 0.4578(3) 0.0143(7) Uani 1 1 d . . . . .
C2 C 0.2568(4) 0.3271(2) 0.4894(3) 0.0131(7) Uani 1 1 d . . . . .
C3 C 0.3916(4) 0.2883(2) 0.5214(3) 0.0138(7) Uani 1 1 d . . . . .
C4 C 0.3911(4) 0.2101(2) 0.5245(3) 0.0129(7) Uani 1 1 d . . . . .
C5 C 0.2569(4) 0.1704(2) 0.4883(3) 0.0139(7) Uani 1 1 d . . . . .
C6 C 0.1239(4) 0.2100(2) 0.4531(3) 0.0149(7) Uani 1 1 d . . . . .
C7 C -0.0196(4) 0.3302(2) 0.4320(3) 0.0162(8) Uani 1 1 d . . . . .
C8 C 0.2549(4) 0.4110(2) 0.4897(3) 0.0164(8) Uani 1 1 d . . . . .
C9 C 0.5341(4) 0.3303(2) 0.5478(3) 0.0165(8) Uani 1 1 d . . . . .
C10 C 0.5323(4) 0.1658(2) 0.5694(3) 0.0151(7) Uani 1 1 d . . . . .
C11 C 0.2587(4) 0.0871(2) 0.4859(3) 0.0180(8) Uani 1 1 d . . . . .
C12 C -0.0193(4) 0.1671(2) 0.4090(3) 0.0149(7) Uani 1 1 d . . . . .
N1 N 0.9159(4) 0.24976(19) 0.1565(3) 0.0316(9) Uani 1 1 d . . . . .
H1A H 0.9150 0.2769 0.2141 0.038 Uiso 1 1 d R . . . .
H1B H 0.8607 0.2084 0.1485 0.038 Uiso 1 1 d R . . . .
H1C H 0.8835 0.2775 0.0958 0.038 Uiso 1 1 d R . . . .
H1D H 1.0088 0.2366 0.1651 0.038 Uiso 1 1 d R . . . .
N2 N 0.6061(4) 0.24804(19) 0.8277(3) 0.0291(9) Uani 1 1 d . . . . .
H2A H 0.5176 0.2260 0.8010 0.035 Uiso 1 1 d R . . . .
H2B H 0.5927 0.2710 0.7639 0.035 Uiso 1 1 d R . . . .
H2C H 0.6922 0.2269 0.8321 0.035 Uiso 1 1 d R . . . .
H2D H 0.6338 0.2748 0.8894 0.035 Uiso 1 1 d R . . . .
N4 N 0.9006(4) -0.0211(2) 0.8009(3) 0.0255(8) Uani 1 1 d . . . . .
H4A H 0.8684 -0.0518 0.8413 0.031 Uiso 1 1 calc GR . . . .
H4B H 0.9821 0.0014 0.8426 0.031 Uiso 1 1 calc GR . . . .
H4C H 0.9197 -0.0471 0.7494 0.031 Uiso 1 1 calc GR . . . .
N3 N -0.4028(4) -0.0185(2) 0.2198(3) 0.0310(9) Uani 1 1 d . . . . .
H3A H -0.3750 -0.0557 0.1862 0.037 Uiso 1 1 calc GR . . . .
H3B H -0.4855 0.0014 0.1754 0.037 Uiso 1 1 calc GR . . . .
H3C H -0.4176 -0.0359 0.2789 0.037 Uiso 1 1 calc GR . . . .
O1W O 1.0360(4) 0.0963(3) 0.6738(3) 0.0661(13) Uani 1 1 d . . . . .
H1WA H 1.0817 0.0841 0.6312 0.099 Uiso 1 1 d G . . . .
H1WB H 1.0970 0.1023 0.7374 0.099 Uiso 1 1 d G . . . .
O2W O 0.4065(7) 0.1314(3) 0.2786(4) 0.098(2) Uani 1 1 d . . . . .
H2WA H 0.3738 0.1168 0.2130 0.118 Uiso 1 1 d G . . . .
H2WB H 0.3964 0.1034 0.3280 0.118 Uiso 1 1 d G . . . .
O3W O 0.2541(7) 0.2624(4) 0.2395(4) 0.086(3) Uani 0.75 1 d . . P . .
H3WA H 0.2817 0.2860 0.1936 0.104 Uiso 0.75 1 d G . P . .
H3WB H 0.2579 0.2687 0.3048 0.104 Uiso 0.75 1 d G . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O2 2.259(3) . ?
Ag1 O4 2.456(3) 3_566 ?
Ag1 O5 2.268(3) 1_455 ?
Ag2 Ag3 3.0434(5) . ?
Ag2 O8 2.159(3) . ?
Ag2 N4 2.139(3) . ?
Ag3 Ag4 3.1268(6) 1_655 ?
Ag3 O7 2.345(3) . ?
Ag3 O10 2.311(3) 3_656 ?
Ag3 O12 2.406(3) 1_655 ?
Ag4 Ag3 3.1267(6) 1_455 ?
Ag4 O11 2.166(3) . ?
Ag4 N3 2.131(4) . ?
O1 C7 1.256(4) . ?
O2 C7 1.255(4) . ?
O3 C8 1.262(4) . ?
O4 Ag1 2.456(3) 3_566 ?
O4 C8 1.262(4) . ?
O5 Ag1 2.268(3) 1_655 ?
O5 C9 1.255(4) . ?
O6 C9 1.257(4) . ?
O7 C10 1.251(4) . ?
O8 C10 1.253(4) . ?
O9 C11 1.247(5) . ?
O10 Ag3 2.311(3) 3_656 ?
O10 C11 1.261(5) . ?
O11 C12 1.254(4) . ?
O12 Ag3 2.406(3) 1_455 ?
O12 C12 1.250(4) . ?
C1 C2 1.406(5) . ?
C1 C6 1.397(5) . ?
C1 C7 1.513(5) . ?
C2 C3 1.412(5) . ?
C2 C8 1.504(5) . ?
C3 C4 1.402(5) . ?
C3 C9 1.506(5) . ?
C4 C5 1.415(5) . ?
C4 C10 1.517(5) . ?
C5 C6 1.405(5) . ?
C5 C11 1.493(6) . ?
C6 C12 1.518(5) . ?
N1 H1A 0.9001 . ?
N1 H1B 0.9000 . ?
N1 H1C 0.9002 . ?
N1 H1D 0.8999 . ?
N2 H2A 0.9000 . ?
N2 H2B 0.9001 . ?
N2 H2C 0.9000 . ?
N2 H2D 0.9002 . ?
N4 H4A 0.8900 . ?
N4 H4B 0.8900 . ?
N4 H4C 0.8900 . ?
N3 H3A 0.8900 . ?
N3 H3B 0.8900 . ?
N3 H3C 0.8900 . ?
O1W H1WA 0.8503 . ?
O1W H1WB 0.8501 . ?
O2W H2WA 0.8499 . ?
O2W H2WB 0.8498 . ?
O3W H3WA 0.8500 . ?
O3W H3WB 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Ag1 O4 128.29(10) . 3_566 ?
O2 Ag1 O5 123.70(12) . 1_455 ?
O5 Ag1 O4 103.76(10) 1_455 3_566 ?
O8 Ag2 Ag3 83.96(7) . . ?
N4 Ag2 Ag3 99.18(9) . . ?
N4 Ag2 O8 170.47(13) . . ?
Ag2 Ag3 Ag4 172.314(18) . 1_655 ?
O7 Ag3 Ag2 71.74(6) . . ?
O7 Ag3 Ag4 107.92(6) . 1_655 ?
O7 Ag3 O12 77.34(10) . 1_655 ?
O10 Ag3 Ag2 104.71(7) 3_656 . ?
O10 Ag3 Ag4 72.32(7) 3_656 1_655 ?
O10 Ag3 O7 155.87(11) 3_656 . ?
O10 Ag3 O12 122.11(10) 3_656 1_655 ?
O12 Ag3 Ag2 120.53(6) 1_655 . ?
O12 Ag3 Ag4 66.27(6) 1_655 1_655 ?
O11 Ag4 Ag3 84.98(7) . 1_455 ?
N3 Ag4 Ag3 92.78(9) . 1_455 ?
N3 Ag4 O11 167.56(13) . . ?
C7 O2 Ag1 121.7(2) . . ?
C8 O4 Ag1 95.1(2) . 3_566 ?
C9 O5 Ag1 119.6(2) . 1_655 ?
C10 O7 Ag3 123.6(2) . . ?
C10 O8 Ag2 120.4(2) . . ?
C11 O10 Ag3 99.9(3) . 3_656 ?
C12 O11 Ag4 116.0(2) . . ?
C12 O12 Ag3 122.9(2) . 1_455 ?
C2 C1 C7 119.7(3) . . ?
C6 C1 C2 119.7(3) . . ?
C6 C1 C7 120.5(3) . . ?
C1 C2 C3 120.5(4) . . ?
C1 C2 C8 119.4(3) . . ?
C3 C2 C8 120.2(3) . . ?
C2 C3 C9 120.4(3) . . ?
C4 C3 C2 119.2(3) . . ?
C4 C3 C9 120.3(3) . . ?
C3 C4 C5 120.3(3) . . ?
C3 C4 C10 121.5(3) . . ?
C5 C4 C10 118.2(3) . . ?
C4 C5 C11 119.6(3) . . ?
C6 C5 C4 119.5(4) . . ?
C6 C5 C11 120.9(3) . . ?
C1 C6 C5 120.5(3) . . ?
C1 C6 C12 120.3(3) . . ?
C5 C6 C12 119.2(3) . . ?
O1 C7 C1 118.6(3) . . ?
O2 C7 O1 125.7(4) . . ?
O2 C7 C1 115.6(3) . . ?
O3 C8 O4 124.4(4) . . ?
O3 C8 C2 118.0(3) . . ?
O4 C8 C2 117.6(3) . . ?
O5 C9 O6 126.2(4) . . ?
O5 C9 C3 114.7(3) . . ?
O6 C9 C3 119.0(3) . . ?
O7 C10 O8 126.6(3) . . ?
O7 C10 C4 118.5(3) . . ?
O8 C10 C4 114.9(3) . . ?
O9 C11 O10 124.1(4) . . ?
O9 C11 C5 118.0(3) . . ?
O10 C11 C5 117.9(3) . . ?
O11 C12 C6 115.6(3) . . ?
O12 C12 O11 126.0(3) . . ?
O12 C12 C6 118.4(3) . . ?
H1A N1 H1B 111.7 . . ?
H1A N1 H1C 110.0 . . ?
H1A N1 H1D 109.3 . . ?
H1B N1 H1C 109.8 . . ?
H1B N1 H1D 109.1 . . ?
H1C N1 H1D 106.9 . . ?
H2A N2 H2B 91.3 . . ?
H2A N2 H2C 125.5 . . ?
H2A N2 H2D 122.5 . . ?
H2B N2 H2C 95.3 . . ?
H2B N2 H2D 119.7 . . ?
H2C N2 H2D 100.3 . . ?
Ag2 N4 H4A 109.5 . . ?
Ag2 N4 H4B 109.5 . . ?
Ag2 N4 H4C 109.5 . . ?
H4A N4 H4B 109.5 . . ?
H4A N4 H4C 109.5 . . ?
H4B N4 H4C 109.5 . . ?
Ag4 N3 H3A 109.5 . . ?
Ag4 N3 H3B 109.5 . . ?
Ag4 N3 H3C 109.5 . . ?
H3A N3 H3B 109.5 . . ?
H3A N3 H3C 109.5 . . ?
H3B N3 H3C 109.5 . . ?
H1WA O1W H1WB 109.5 . . ?
H2WA O2W H2WB 119.3 . . ?
H3WA O3W H3WB 136.8 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1A O1 0.90 1.95 2.839(4) 168.4 1_655
N1 H1B O6 0.90 2.23 2.956(5) 137.2 4_565
N1 H1C O12 0.90 2.04 2.892(4) 157.0 4_665
N2 H2A O3W 0.90 2.41 3.215(7) 148.5 4_566
N2 H2B O6 0.90 2.01 2.882(4) 161.8 .
N2 H2D O12 0.90 2.50 3.029(5) 118.0 4_666
N4 H4A O4 0.89 2.39 3.113(4) 139.1 2_646
N4 H4B O3 0.89 2.11 2.980(5) 164.6 4_666
N4 H4C O11 0.89 2.26 3.104(4) 158.5 3_656
N3 H3A O3 0.89 2.46 3.101(5) 129.0 2_545
N3 H3B O4 0.89 2.13 3.019(5) 175.3 4_465
N3 H3C O8 0.89 2.42 3.184(4) 144.4 3_556
O1W H1WA O10 0.85 1.96 2.805(5) 178.0 1_655
O1W H1WB O3 0.85 2.19 2.936(5) 146.0 4_666
O2W H2WA O4 0.85 1.98 2.809(5) 164.3 4_565
O2W H2WB O9 0.85 1.93 2.765(5) 166.0 .

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 O2 C7 O1 3.4(5) . . . . ?
Ag1 O2 C7 C1 -174.5(2) . . . . ?
Ag1 O4 C8 O3 3.4(4) 3_566 . . . ?
Ag1 O4 C8 C2 -175.1(3) 3_566 . . . ?
Ag1 O5 C9 O6 3.4(5) 1_655 . . . ?
Ag1 O5 C9 C3 -174.3(2) 1_655 . . . ?
Ag2 O8 C10 O7 -2.3(5) . . . . ?
Ag2 O8 C10 C4 178.8(2) . . . . ?
Ag3 O7 C10 O8 37.0(5) . . . . ?
Ag3 O7 C10 C4 -144.2(3) . . . . ?
Ag3 O10 C11 O9 -1.5(4) 3_656 . . . ?
Ag3 O10 C11 C5 178.7(2) 3_656 . . . ?
Ag3 O12 C12 O11 49.2(5) 1_455 . . . ?
Ag3 O12 C12 C6 -132.3(3) 1_455 . . . ?
Ag4 O11 C12 O12 -3.3(5) . . . . ?
Ag4 O11 C12 C6 178.1(2) . . . . ?
C1 C2 C3 C4 -1.9(5) . . . . ?
C1 C2 C3 C9 175.7(3) . . . . ?
C1 C2 C8 O3 -58.1(4) . . . . ?
C1 C2 C8 O4 120.5(4) . . . . ?
C1 C6 C12 O11 118.1(4) . . . . ?
C1 C6 C12 O12 -60.6(5) . . . . ?
C2 C1 C6 C5 5.3(5) . . . . ?
C2 C1 C6 C12 -174.3(3) . . . . ?
C2 C1 C7 O1 123.8(4) . . . . ?
C2 C1 C7 O2 -58.2(4) . . . . ?
C2 C3 C4 C5 4.6(5) . . . . ?
C2 C3 C4 C10 -173.5(3) . . . . ?
C2 C3 C9 O5 -56.9(5) . . . . ?
C2 C3 C9 O6 125.2(4) . . . . ?
C3 C2 C8 O3 122.3(4) . . . . ?
C3 C2 C8 O4 -59.1(4) . . . . ?
C3 C4 C5 C6 -2.3(5) . . . . ?
C3 C4 C5 C11 176.3(3) . . . . ?
C3 C4 C10 O7 -63.8(5) . . . . ?
C3 C4 C10 O8 115.2(4) . . . . ?
C4 C3 C9 O5 120.7(4) . . . . ?
C4 C3 C9 O6 -57.2(5) . . . . ?
C4 C5 C6 C1 -2.7(5) . . . . ?
C4 C5 C6 C12 176.9(3) . . . . ?
C4 C5 C11 O9 -52.7(5) . . . . ?
C4 C5 C11 O10 127.1(4) . . . . ?
C5 C4 C10 O7 118.0(4) . . . . ?
C5 C4 C10 O8 -63.0(4) . . . . ?
C5 C6 C12 O11 -61.5(4) . . . . ?
C5 C6 C12 O12 119.8(4) . . . . ?
C6 C1 C2 C3 -3.0(5) . . . . ?
C6 C1 C2 C8 177.4(3) . . . . ?
C6 C1 C7 O1 -57.9(5) . . . . ?
C6 C1 C7 O2 120.2(4) . . . . ?
C6 C5 C11 O9 126.0(4) . . . . ?
C6 C5 C11 O10 -54.3(5) . . . . ?
C7 C1 C2 C3 175.4(3) . . . . ?
C7 C1 C2 C8 -4.2(5) . . . . ?
C7 C1 C6 C5 -173.0(3) . . . . ?
C7 C1 C6 C12 7.4(5) . . . . ?
C8 C2 C3 C4 177.6(3) . . . . ?
C8 C2 C3 C9 -4.7(5) . . . . ?
C9 C3 C4 C5 -173.0(3) . . . . ?
C9 C3 C4 C10 8.8(5) . . . . ?
C10 C4 C5 C6 175.9(3) . . . . ?
C10 C4 C5 C11 -5.5(5) . . . . ?
C11 C5 C6 C1 178.7(3) . . . . ?
C11 C5 C6 C12 -1.7(5) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
