# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1505745'
_audit_update_record             
;
2016-09-22 deposited with the CCDC.
2016-11-14 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            
' [(?2-dcpm)Ag2(?2-O2CH)(η2-NO3)]2.[(?2-dcpm)2Ag4(?2-NO3)4]'
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C76 H139 Ag6 N5 O17 P6'
_chemical_formula_weight         2227.95
_chemical_oxdiff_usercomment     "Arthur's silver formate DCBM"

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   24.6390(2)
_cell_length_b                   16.08250(10)
_cell_length_c                   23.41430(10)
_cell_angle_alpha                90
_cell_angle_beta                 94.7980(10)
_cell_angle_gamma                90
_cell_volume                     9245.56(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    130.0(2)
_cell_measurement_reflns_used    42528
_cell_measurement_theta_min      4.0410
_cell_measurement_theta_max      76.9470

_exptl_crystal_description       rod
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.601
_exptl_crystal_F_000             4552
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.4939
_exptl_crystal_size_mid          0.0728
_exptl_crystal_size_min          0.0600
_exptl_absorpt_coefficient_mu    11.484
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_T_min  0.100
_exptl_absorpt_correction_T_max  0.560
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      130.0(2)
_diffrn_radiation_wavelength     1.5418
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_source         'SuperNova (Cu) X-ray Source'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            99896
_diffrn_reflns_av_unetI/netI     0.0386
_diffrn_reflns_av_R_equivalents  0.0694
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         3.285
_diffrn_reflns_theta_max         77.202
_diffrn_reflns_theta_full        67.684
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             19442
_reflns_number_gt                17121
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0680P)²+15.7699P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         19442
_refine_ls_number_parameters     995
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0506
_refine_ls_R_factor_gt           0.0449
_refine_ls_wR_factor_ref         0.1226
_refine_ls_wR_factor_gt          0.1177
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_restrained_S_all      1.039
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.20303(15) -0.5269(2) 0.46051(16) 0.0248(7) Uani 1 1 d . . . . .
H1 H 0.2373 -0.5048 0.4485 0.030 Uiso 1 1 calc R U . . .
C2 C 0.18711(17) -0.6046(3) 0.42499(16) 0.0304(8) Uani 1 1 d . . . . .
H2A H 0.1511 -0.6227 0.4334 0.036 Uiso 1 1 calc R U . . .
H2B H 0.1857 -0.5909 0.3846 0.036 Uiso 1 1 calc R U . . .
C3 C 0.22722(19) -0.6752(3) 0.43752(18) 0.0350(9) Uani 1 1 d . . . . .
H3A H 0.2623 -0.6595 0.4250 0.042 Uiso 1 1 calc R U . . .
H3B H 0.2146 -0.7240 0.4160 0.042 Uiso 1 1 calc R U . . .
C4 C 0.2337(2) -0.6965(3) 0.50093(19) 0.0381(9) Uani 1 1 d . . . . .
H4A H 0.2608 -0.7400 0.5077 0.046 Uiso 1 1 calc R U . . .
H4B H 0.1994 -0.7169 0.5129 0.046 Uiso 1 1 calc R U . . .
C5 C 0.2513(2) -0.6198(3) 0.53589(19) 0.0396(10) Uani 1 1 d . . . . .
H5A H 0.2870 -0.6020 0.5259 0.048 Uiso 1 1 calc R U . . .
H5B H 0.2542 -0.6337 0.5763 0.048 Uiso 1 1 calc R U . . .
C6 C 0.21055(18) -0.5486(3) 0.52473(17) 0.0322(8) Uani 1 1 d . . . . .
H6A H 0.2234 -0.5000 0.5463 0.039 Uiso 1 1 calc R U . . .
H6B H 0.1757 -0.5647 0.5379 0.039 Uiso 1 1 calc R U . . .
C7 C 0.17432(19) -0.3527(3) 0.48750(19) 0.0355(9) Uani 1 1 d . . . . .
H7 H 0.1760 -0.3656 0.5285 0.043 Uiso 1 1 calc R U . . .
C8 C 0.23147(19) -0.3249(3) 0.4743(2) 0.0390(9) Uani 1 1 d . . . . .
H8A H 0.2573 -0.3689 0.4847 0.047 Uiso 1 1 calc R U . . .
H8B H 0.2318 -0.3148 0.4335 0.047 Uiso 1 1 calc R U . . .
C9 C 0.2489(3) -0.2458(4) 0.5071(3) 0.0626(16) Uani 1 1 d . . . . .
H9A H 0.2528 -0.2578 0.5478 0.075 Uiso 1 1 calc R U . . .
H9B H 0.2842 -0.2282 0.4959 0.075 Uiso 1 1 calc R U . . .
C10 C 0.2092(3) -0.1770(4) 0.4961(3) 0.0638(17) Uani 1 1 d . . . . .
H10A H 0.2075 -0.1613 0.4559 0.077 Uiso 1 1 calc R U . . .
H10B H 0.2209 -0.1289 0.5189 0.077 Uiso 1 1 calc R U . . .
C11 C 0.1520(3) -0.2052(4) 0.5117(3) 0.0648(16) Uani 1 1 d . . . . .
H11A H 0.1532 -0.2176 0.5524 0.078 Uiso 1 1 calc R U . . .
H11B H 0.1258 -0.1610 0.5033 0.078 Uiso 1 1 calc R U . . .
C12 C 0.1347(2) -0.2825(3) 0.4771(3) 0.0518(12) Uani 1 1 d . . . . .
H12A H 0.0991 -0.3003 0.4871 0.062 Uiso 1 1 calc R U . . .
H12B H 0.1317 -0.2687 0.4366 0.062 Uiso 1 1 calc R U . . .
C13 C 0.14800(15) -0.4182(3) 0.37224(17) 0.0291(8) Uani 1 1 d . . . . .
H13A H 0.1557 -0.3593 0.3692 0.035 Uiso 1 1 calc R U . . .
H13B H 0.1763 -0.4485 0.3546 0.035 Uiso 1 1 calc R U . . .
C14 C 0.03381(16) -0.3687(3) 0.36477(16) 0.0289(8) Uani 1 1 d . . . . .
H14 H 0.0441 -0.3688 0.4061 0.035 Uiso 1 1 calc R U . . .
C15 C -0.02550(16) -0.4002(3) 0.35736(18) 0.0339(8) Uani 1 1 d . . . . .
H15A H -0.0380 -0.4008 0.3170 0.041 Uiso 1 1 calc R U . . .
H15B H -0.0270 -0.4567 0.3717 0.041 Uiso 1 1 calc R U . . .
C16 C -0.06305(19) -0.3447(4) 0.3897(2) 0.0448(11) Uani 1 1 d . . . . .
H16A H -0.1004 -0.3632 0.3819 0.054 Uiso 1 1 calc R U . . .
H16B H -0.0535 -0.3497 0.4305 0.054 Uiso 1 1 calc R U . . .
C17 C -0.0587(2) -0.2544(4) 0.3721(2) 0.0477(12) Uani 1 1 d . . . . .
H17A H -0.0809 -0.2205 0.3952 0.057 Uiso 1 1 calc R U . . .
H17B H -0.0726 -0.2483 0.3323 0.057 Uiso 1 1 calc R U . . .
C18 C 0.0000(2) -0.2236(3) 0.3793(2) 0.0453(11) Uani 1 1 d . . . . .
H18A H 0.0128 -0.2245 0.4197 0.054 Uiso 1 1 calc R U . . .
H18B H 0.0015 -0.1666 0.3660 0.054 Uiso 1 1 calc R U . . .
C19 C 0.03713(19) -0.2778(3) 0.3458(2) 0.0378(9) Uani 1 1 d . . . . .
H19A H 0.0744 -0.2583 0.3522 0.045 Uiso 1 1 calc R U . . .
H19B H 0.0262 -0.2735 0.3051 0.045 Uiso 1 1 calc R U . . .
C20 C 0.09031(17) -0.4016(3) 0.26038(17) 0.0322(8) Uani 1 1 d . . . . .
H20 H 0.0997 -0.3425 0.2634 0.039 Uiso 1 1 calc R U . . .
C21 C 0.1370(2) -0.4469(3) 0.2343(2) 0.0406(10) Uani 1 1 d . . . . .
H21A H 0.1301 -0.5063 0.2339 0.049 Uiso 1 1 calc R U . . .
H21B H 0.1708 -0.4369 0.2577 0.049 Uiso 1 1 calc R U . . .
C22 C 0.1426(2) -0.4162(4) 0.1729(2) 0.0500(12) Uani 1 1 d . . . . .
H22A H 0.1540 -0.3584 0.1741 0.060 Uiso 1 1 calc R U . . .
H22B H 0.1706 -0.4483 0.1562 0.060 Uiso 1 1 calc R U . . .
C23 C 0.0897(3) -0.4240(4) 0.1353(2) 0.0602(16) Uani 1 1 d . . . . .
H23A H 0.0799 -0.4822 0.1310 0.072 Uiso 1 1 calc R U . . .
H23B H 0.0944 -0.4016 0.0976 0.072 Uiso 1 1 calc R U . . .
C24 C 0.0446(2) -0.3771(5) 0.1618(2) 0.0617(17) Uani 1 1 d . . . . .
H24A H 0.0108 -0.3836 0.1379 0.074 Uiso 1 1 calc R U . . .
H24B H 0.0534 -0.3184 0.1638 0.074 Uiso 1 1 calc R U . . .
C25 C 0.0370(2) -0.4096(4) 0.2222(2) 0.0490(12) Uani 1 1 d . . . . .
H25A H 0.0086 -0.3780 0.2387 0.059 Uiso 1 1 calc R U . . .
H25B H 0.0258 -0.4674 0.2201 0.059 Uiso 1 1 calc R U . . .
C26 C -0.0079(3) -0.6483(4) 0.4447(3) 0.0588(16) Uani 1 1 d . . . . .
C27 C 0.15426(17) 0.0227(3) 0.40985(18) 0.0341(9) Uani 1 1 d . . . . .
H27 H 0.1404 -0.0327 0.4180 0.041 Uiso 1 1 calc R U . . .
C28 C 0.1049(2) 0.0804(3) 0.40158(19) 0.0419(10) Uani 1 1 d . . . . .
H28A H 0.0812 0.0622 0.3688 0.050 Uiso 1 1 calc R U . . .
H28B H 0.1169 0.1366 0.3941 0.050 Uiso 1 1 calc R U . . .
C29 C 0.0733(2) 0.0798(5) 0.4556(2) 0.0582(15) Uani 1 1 d . . . . .
H29A H 0.0427 0.1178 0.4504 0.070 Uiso 1 1 calc R U . . .
H29B H 0.0591 0.0245 0.4613 0.070 Uiso 1 1 calc R U . . .
C30 C 0.1099(3) 0.1056(4) 0.5086(2) 0.0589(15) Uani 1 1 d . . . . .
H30A H 0.1211 0.1630 0.5046 0.071 Uiso 1 1 calc R U . . .
H30B H 0.0896 0.1017 0.5422 0.071 Uiso 1 1 calc R U . . .
C31 C 0.1599(2) 0.0509(4) 0.5166(2) 0.0545(14) Uani 1 1 d . . . . .
H31A H 0.1489 -0.0053 0.5255 0.065 Uiso 1 1 calc R U . . .
H31B H 0.1835 0.0712 0.5488 0.065 Uiso 1 1 calc R U . . .
C32 C 0.1915(2) 0.0493(3) 0.46274(19) 0.0412(10) Uani 1 1 d . . . . .
H32A H 0.2217 0.0107 0.4685 0.049 Uiso 1 1 calc R U . . .
H32B H 0.2062 0.1041 0.4563 0.049 Uiso 1 1 calc R U . . .
C33 C 0.14561(16) -0.0144(2) 0.28512(18) 0.0302(8) Uani 1 1 d . . . . .
H33 H 0.1205 0.0324 0.2774 0.036 Uiso 1 1 calc R U . . .
C34 C 0.11237(19) -0.0921(3) 0.2967(2) 0.0431(11) Uani 1 1 d . . . . .
H34A H 0.0896 -0.0810 0.3277 0.052 Uiso 1 1 calc R U . . .
H34B H 0.1368 -0.1374 0.3084 0.052 Uiso 1 1 calc R U . . .
C35 C 0.0766(2) -0.1174(4) 0.2429(3) 0.0572(15) Uani 1 1 d . . . . .
H35A H 0.0564 -0.1673 0.2508 0.069 Uiso 1 1 calc R U . . .
H35B H 0.0505 -0.0735 0.2328 0.069 Uiso 1 1 calc R U . . .
C36 C 0.1106(3) -0.1335(4) 0.1928(3) 0.0603(15) Uani 1 1 d . . . . .
H36A H 0.1355 -0.1792 0.2021 0.072 Uiso 1 1 calc R U . . .
H36B H 0.0870 -0.1491 0.1593 0.072 Uiso 1 1 calc R U . . .
C37 C 0.1427(2) -0.0563(3) 0.1797(2) 0.0462(11) Uani 1 1 d . . . . .
H37A H 0.1176 -0.0121 0.1671 0.055 Uiso 1 1 calc R U . . .
H37B H 0.1654 -0.0681 0.1488 0.055 Uiso 1 1 calc R U . . .
C38 C 0.17825(18) -0.0277(3) 0.23213(19) 0.0364(9) Uani 1 1 d . . . . .
H38A H 0.1960 0.0240 0.2233 0.044 Uiso 1 1 calc R U . . .
H38B H 0.2064 -0.0689 0.2413 0.044 Uiso 1 1 calc R U . . .
C39 C 0.21282(15) 0.1205(2) 0.33197(16) 0.0260(7) Uani 1 1 d . . . . .
H39A H 0.2150 0.1510 0.3678 0.031 Uiso 1 1 calc R U . . .
H39B H 0.1838 0.1453 0.3071 0.031 Uiso 1 1 calc R U . . .
C40 C 0.26365(15) 0.2256(2) 0.25124(16) 0.0264(7) Uani 1 1 d . . . . .
H40 H 0.2983 0.2406 0.2362 0.032 Uiso 1 1 calc R U . . .
C41 C 0.22441(17) 0.2024(3) 0.19970(17) 0.0307(8) Uani 1 1 d . . . . .
H41A H 0.1897 0.1858 0.2129 0.037 Uiso 1 1 calc R U . . .
H41B H 0.2390 0.1555 0.1799 0.037 Uiso 1 1 calc R U . . .
C42 C 0.21564(19) 0.2759(3) 0.15807(18) 0.0388(9) Uani 1 1 d . . . . .
H42A H 0.2496 0.2886 0.1417 0.047 Uiso 1 1 calc R U . . .
H42B H 0.1889 0.2607 0.1270 0.047 Uiso 1 1 calc R U . . .
C43 C 0.1960(2) 0.3524(3) 0.1886(2) 0.0390(9) Uani 1 1 d . . . . .
H43A H 0.1603 0.3415 0.2016 0.047 Uiso 1 1 calc R U . . .
H43B H 0.1926 0.3987 0.1620 0.047 Uiso 1 1 calc R U . . .
C44 C 0.23549(19) 0.3756(3) 0.2399(2) 0.0385(9) Uani 1 1 d . . . . .
H44A H 0.2702 0.3915 0.2266 0.046 Uiso 1 1 calc R U . . .
H44B H 0.2213 0.4229 0.2596 0.046 Uiso 1 1 calc R U . . .
C45 C 0.24383(16) 0.3029(2) 0.28153(17) 0.0283(7) Uani 1 1 d . . . . .
H45A H 0.2098 0.2905 0.2977 0.034 Uiso 1 1 calc R U . . .
H45B H 0.2704 0.3182 0.3127 0.034 Uiso 1 1 calc R U . . .
C46 C 0.32448(15) 0.1726(2) 0.35855(16) 0.0259(7) Uani 1 1 d . . . . .
H46 H 0.3058 0.2151 0.3796 0.031 Uiso 1 1 calc R U . . .
C47 C 0.34083(17) 0.1010(3) 0.39958(18) 0.0338(8) Uani 1 1 d . . . . .
H47A H 0.3085 0.0790 0.4153 0.041 Uiso 1 1 calc R U . . .
H47B H 0.3569 0.0567 0.3785 0.041 Uiso 1 1 calc R U . . .
C48 C 0.3812(2) 0.1288(4) 0.4483(2) 0.0463(11) Uani 1 1 d . . . . .
H48A H 0.3922 0.0812 0.4720 0.056 Uiso 1 1 calc R U . . .
H48B H 0.3639 0.1686 0.4720 0.056 Uiso 1 1 calc R U . . .
C49 C 0.43178(19) 0.1685(4) 0.4258(2) 0.0466(11) Uani 1 1 d . . . . .
H49A H 0.4558 0.1885 0.4578 0.056 Uiso 1 1 calc R U . . .
H49B H 0.4513 0.1272 0.4054 0.056 Uiso 1 1 calc R U . . .
C50 C 0.41556(18) 0.2403(3) 0.3860(2) 0.0413(10) Uani 1 1 d . . . . .
H50A H 0.4478 0.2635 0.3710 0.050 Uiso 1 1 calc R U . . .
H50B H 0.3987 0.2836 0.4073 0.050 Uiso 1 1 calc R U . . .
C51 C 0.37568(16) 0.2118(3) 0.33605(18) 0.0309(8) Uani 1 1 d . . . . .
H51A H 0.3934 0.1713 0.3131 0.037 Uiso 1 1 calc R U . . .
H51B H 0.3652 0.2590 0.3118 0.037 Uiso 1 1 calc R U . . .
C52 C 0.42751(16) -0.2408(2) 0.11593(16) 0.0276(7) Uani 1 1 d . . . . .
H52 H 0.4596 -0.2701 0.1041 0.033 Uiso 1 1 calc R U . . .
C53 C 0.44412(18) -0.1520(3) 0.13503(18) 0.0335(8) Uani 1 1 d . . . . .
H53A H 0.4135 -0.1249 0.1507 0.040 Uiso 1 1 calc R U . . .
H53B H 0.4736 -0.1549 0.1651 0.040 Uiso 1 1 calc R U . . .
C54 C 0.4623(2) -0.1000(3) 0.0851(2) 0.0433(11) Uani 1 1 d . . . . .
H54A H 0.4706 -0.0439 0.0983 0.052 Uiso 1 1 calc R U . . .
H54B H 0.4953 -0.1238 0.0720 0.052 Uiso 1 1 calc R U . . .
C55 C 0.4183(2) -0.0973(3) 0.0356(2) 0.0479(12) Uani 1 1 d . . . . .
H55A H 0.4315 -0.0666 0.0038 0.057 Uiso 1 1 calc R U . . .
H55B H 0.3865 -0.0688 0.0475 0.057 Uiso 1 1 calc R U . . .
C56 C 0.4028(2) -0.1851(3) 0.0162(2) 0.0472(12) Uani 1 1 d . . . . .
H56A H 0.4340 -0.2116 0.0011 0.057 Uiso 1 1 calc R U . . .
H56B H 0.3737 -0.1825 -0.0143 0.057 Uiso 1 1 calc R U . . .
C57 C 0.38429(18) -0.2373(3) 0.06542(16) 0.0320(8) Uani 1 1 d . . . . .
H57A H 0.3511 -0.2137 0.0781 0.038 Uiso 1 1 calc R U . . .
H57B H 0.3762 -0.2933 0.0519 0.038 Uiso 1 1 calc R U . . .
C58 C 0.37890(17) -0.4024(3) 0.15370(16) 0.0296(8) Uani 1 1 d . . . . .
H58 H 0.3801 -0.4352 0.1891 0.036 Uiso 1 1 calc R U . . .
C59 C 0.31959(18) -0.4055(3) 0.12909(19) 0.0362(9) Uani 1 1 d . . . . .
H59A H 0.2969 -0.3767 0.1547 0.043 Uiso 1 1 calc R U . . .
H59B H 0.3160 -0.3773 0.0923 0.043 Uiso 1 1 calc R U . . .
C60 C 0.3003(2) -0.4952(4) 0.1215(2) 0.0493(13) Uani 1 1 d . . . . .
H60A H 0.2633 -0.4958 0.1035 0.059 Uiso 1 1 calc R U . . .
H60B H 0.3000 -0.5215 0.1588 0.059 Uiso 1 1 calc R U . . .
C61 C 0.3371(2) -0.5446(3) 0.0847(2) 0.0481(12) Uani 1 1 d . . . . .
H61A H 0.3329 -0.5236 0.0457 0.058 Uiso 1 1 calc R U . . .
H61B H 0.3259 -0.6024 0.0838 0.058 Uiso 1 1 calc R U . . .
C62 C 0.3974(3) -0.5392(3) 0.1071(2) 0.0512(13) Uani 1 1 d . . . . .
H62A H 0.4028 -0.5680 0.1435 0.061 Uiso 1 1 calc R U . . .
H62B H 0.4194 -0.5666 0.0803 0.061 Uiso 1 1 calc R U . . .
C63 C 0.41601(18) -0.4487(3) 0.11493(19) 0.0352(9) Uani 1 1 d . . . . .
H63A H 0.4149 -0.4215 0.0779 0.042 Uiso 1 1 calc R U . . .
H63B H 0.4533 -0.4473 0.1319 0.042 Uiso 1 1 calc R U . . .
C64 C 0.46256(16) -0.3165(3) 0.22530(15) 0.0279(7) Uani 1 1 d . . . . .
H64A H 0.4764 -0.3715 0.2175 0.034 Uiso 1 1 calc R U . . .
H64B H 0.4903 -0.2764 0.2174 0.034 Uiso 1 1 calc R U . . .
C65 C 0.51800(14) -0.3338(2) 0.33831(15) 0.0235(7) Uani 1 1 d . . . . .
H65 H 0.5301 -0.3880 0.3251 0.028 Uiso 1 1 calc R U . . .
C66 C 0.55862(16) -0.2670(3) 0.32221(17) 0.0302(8) Uani 1 1 d . . . . .
H66A H 0.5623 -0.2695 0.2813 0.036 Uiso 1 1 calc R U . . .
H66B H 0.5445 -0.2125 0.3308 0.036 Uiso 1 1 calc R U . . .
C67 C 0.61450(17) -0.2783(3) 0.3545(2) 0.0399(10) Uani 1 1 d . . . . .
H67A H 0.6381 -0.2329 0.3452 0.048 Uiso 1 1 calc R U . . .
H67B H 0.6306 -0.3298 0.3425 0.048 Uiso 1 1 calc R U . . .
C68 C 0.61019(18) -0.2804(3) 0.4192(2) 0.0386(10) Uani 1 1 d . . . . .
H68A H 0.6459 -0.2904 0.4387 0.046 Uiso 1 1 calc R U . . .
H68B H 0.5974 -0.2270 0.4319 0.046 Uiso 1 1 calc R U . . .
C69 C 0.5712(2) -0.3483(3) 0.43495(19) 0.0407(10) Uani 1 1 d . . . . .
H69A H 0.5681 -0.3471 0.4760 0.049 Uiso 1 1 calc R U . . .
H69B H 0.5858 -0.4020 0.4253 0.049 Uiso 1 1 calc R U . . .
C70 C 0.51493(17) -0.3372(3) 0.40348(17) 0.0324(8) Uani 1 1 d . . . . .
H70A H 0.4987 -0.2862 0.4162 0.039 Uiso 1 1 calc R U . . .
H70B H 0.4917 -0.3831 0.4129 0.039 Uiso 1 1 calc R U . . .
C71 C 0.40403(15) -0.3978(2) 0.31133(16) 0.0263(7) Uani 1 1 d . . . . .
H71 H 0.3756 -0.3941 0.2796 0.032 Uiso 1 1 calc R U . . .
C72 C 0.42969(18) -0.4838(3) 0.30640(19) 0.0335(8) Uani 1 1 d . . . . .
H72A H 0.4456 -0.4882 0.2700 0.040 Uiso 1 1 calc R U . . .
H72B H 0.4586 -0.4908 0.3367 0.040 Uiso 1 1 calc R U . . .
C73 C 0.3875(3) -0.5524(3) 0.3106(2) 0.0519(13) Uani 1 1 d . . . . .
H73A H 0.3604 -0.5488 0.2782 0.062 Uiso 1 1 calc R U . . .
H73B H 0.4051 -0.6062 0.3094 0.062 Uiso 1 1 calc R U . . .
C74 C 0.3598(3) -0.5446(4) 0.3659(3) 0.0624(16) Uani 1 1 d . . . . .
H74A H 0.3322 -0.5875 0.3672 0.075 Uiso 1 1 calc R U . . .
H74B H 0.3864 -0.5528 0.3983 0.075 Uiso 1 1 calc R U . . .
C75 C 0.3335(2) -0.4599(4) 0.3703(2) 0.0569(15) Uani 1 1 d . . . . .
H75A H 0.3173 -0.4560 0.4065 0.068 Uiso 1 1 calc R U . . .
H75B H 0.3047 -0.4540 0.3398 0.068 Uiso 1 1 calc R U . . .
C76 C 0.37446(18) -0.3891(3) 0.36632(18) 0.0373(9) Uani 1 1 d . . . . .
H76A H 0.4008 -0.3904 0.3995 0.045 Uiso 1 1 calc R U . . .
H76B H 0.3556 -0.3362 0.3661 0.045 Uiso 1 1 calc R U . . .
N1 N 0.08552(14) -0.7409(2) 0.29430(14) 0.0295(7) Uani 1 1 d . . . . .
N2 N 0.3684(2) -0.1175(3) 0.43531(18) 0.0501(11) Uani 1 1 d . . . . .
N3 N 0.24717(17) -0.2554(2) 0.29828(17) 0.0406(8) Uani 1 1 d . . . . .
N4 N 0.43535(17) -0.0190(3) 0.27893(19) 0.0424(9) Uani 1 1 d . . . . .
N5 N 0.29943(19) -0.0590(3) 0.14245(18) 0.0474(10) Uani 1 1 d . . . . .
O1 O -0.00373(14) -0.5826(2) 0.47473(15) 0.0428(8) Uani 1 1 d . . . . .
O2 O 0.0160(2) -0.6670(3) 0.40340(19) 0.0655(12) Uani 1 1 d . . . . .
O3 O 0.04560(14) -0.6967(2) 0.27634(15) 0.0446(8) Uani 1 1 d . . . . .
O4 O 0.11727(12) -0.7127(2) 0.33442(14) 0.0385(7) Uani 1 1 d . . . . .
O5 O 0.09388(14) -0.8091(2) 0.27249(14) 0.0411(7) Uani 1 1 d . . . . .
O6 O 0.34472(14) -0.1409(2) 0.38738(14) 0.0455(8) Uani 1 1 d . . . . .
O7 O 0.4202(2) -0.1272(4) 0.4395(3) 0.0944(19) Uani 1 1 d . . . . .
O8 O 0.3418(2) -0.0859(3) 0.47037(17) 0.0734(14) Uani 1 1 d . . . . .
O9 O 0.27848(14) -0.1947(2) 0.28778(15) 0.0422(7) Uani 1 1 d . . . . .
O10 O 0.2508(2) -0.3192(3) 0.2710(3) 0.0861(17) Uani 1 1 d . . . . .
O11 O 0.21604(18) -0.2452(3) 0.33620(18) 0.0592(10) Uani 1 1 d . . . . .
O12 O 0.39175(14) -0.0596(2) 0.2850(2) 0.0549(10) Uani 1 1 d . . . . .
O13 O 0.47933(17) -0.0500(3) 0.2964(3) 0.0773(14) Uani 1 1 d . . . . .
O14 O 0.43101(18) 0.0487(3) 0.2557(2) 0.0622(11) Uani 1 1 d . . . . .
O15 O 0.29763(19) -0.0900(2) 0.19153(17) 0.0553(10) Uani 1 1 d . . . . .
O16 O 0.2879(2) -0.1013(3) 0.1001(2) 0.0904(19) Uani 1 1 d . . . . .
O17 O 0.3146(3) 0.0140(3) 0.14044(19) 0.0820(17) Uani 1 1 d . . . . .
P1 P 0.14966(4) -0.44725(6) 0.44871(4) 0.02357(17) Uani 1 1 d . . . . .
P2 P 0.08153(4) -0.44096(6) 0.33316(4) 0.02524(18) Uani 1 1 d . . . . .
P3 P 0.19373(4) 0.01246(6) 0.34667(4) 0.02544(18) Uani 1 1 d . . . . .
P4 P 0.27748(4) 0.13527(5) 0.29869(4) 0.02219(17) Uani 1 1 d . . . . .
P5 P 0.40120(4) -0.29690(6) 0.17664(4) 0.02289(17) Uani 1 1 d . . . . .
P6 P 0.45047(3) -0.31009(5) 0.30152(4) 0.02116(16) Uani 1 1 d . . . . .
Ag1 Ag 0.06582(2) -0.50169(2) 0.47012(2) 0.03294(8) Uani 1 1 d . . . . .
Ag2 Ag 0.06023(2) -0.58287(2) 0.34362(2) 0.03413(8) Uani 1 1 d . . . . .
Ag3 Ag 0.26533(2) -0.08400(2) 0.35789(2) 0.03307(8) Uani 1 1 d . . . . .
Ag4 Ag 0.31544(2) 0.02256(2) 0.25311(2) 0.03388(8) Uani 1 1 d . . . . .
Ag5 Ag 0.33375(2) -0.22255(2) 0.21918(2) 0.03483(8) Uani 1 1 d . . . . .
Ag6 Ag 0.41392(2) -0.18507(2) 0.33027(2) 0.03870(8) Uani 1 1 d . . . . .
H H -0.037(3) -0.695(5) 0.459(3) 0.09(3) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.534(5) . ?
C1 C6 1.540(5) . ?
C1 P1 1.840(4) . ?
C1 H1 0.9800 . ?
C2 C3 1.517(5) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.519(6) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 C5 1.523(6) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.531(6) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C12 1.498(7) . ?
C7 C8 1.533(6) . ?
C7 P1 1.848(4) . ?
C7 H7 0.9800 . ?
C8 C9 1.528(7) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.485(9) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.553(10) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.526(8) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 P2 1.845(4) . ?
C13 P1 1.847(4) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C19 1.532(6) . ?
C14 C15 1.543(5) . ?
C14 P2 1.851(4) . ?
C14 H14 0.9800 . ?
C15 C16 1.531(6) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 C17 1.515(8) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.523(8) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 C19 1.528(6) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 C21 1.531(6) . ?
C20 C25 1.531(6) . ?
C20 P2 1.847(4) . ?
C20 H20 0.9800 . ?
C21 C22 1.538(7) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.514(9) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.519(9) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 C25 1.532(7) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 O2 1.212(7) . ?
C26 O1 1.269(6) . ?
C26 H 1.11(8) . ?
C27 C28 1.530(6) . ?
C27 C32 1.539(6) . ?
C27 P3 1.844(4) . ?
C27 H27 0.9800 . ?
C28 C29 1.540(6) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 C30 1.529(9) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 C31 1.511(8) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 C32 1.538(7) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C33 C34 1.531(6) . ?
C33 C38 1.549(6) . ?
C33 P3 1.839(4) . ?
C33 H33 0.9800 . ?
C34 C35 1.531(7) . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C35 C36 1.521(9) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 C37 1.517(8) . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
C37 C38 1.519(6) . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C39 P3 1.841(4) . ?
C39 P4 1.846(4) . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C40 C41 1.528(5) . ?
C40 C45 1.532(5) . ?
C40 P4 1.843(4) . ?
C40 H40 0.9800 . ?
C41 C42 1.536(6) . ?
C41 H41A 0.9700 . ?
C41 H41B 0.9700 . ?
C42 C43 1.523(7) . ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C43 C44 1.527(6) . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?
C44 C45 1.524(5) . ?
C44 H44A 0.9700 . ?
C44 H44B 0.9700 . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C46 C47 1.532(5) . ?
C46 C51 1.542(5) . ?
C46 P4 1.842(4) . ?
C46 H46 0.9800 . ?
C47 C48 1.517(6) . ?
C47 H47A 0.9700 . ?
C47 H47B 0.9700 . ?
C48 C49 1.532(7) . ?
C48 H48A 0.9700 . ?
C48 H48B 0.9700 . ?
C49 C50 1.517(7) . ?
C49 H49A 0.9700 . ?
C49 H49B 0.9700 . ?
C50 C51 1.533(6) . ?
C50 H50A 0.9700 . ?
C50 H50B 0.9700 . ?
C51 H51A 0.9700 . ?
C51 H51B 0.9700 . ?
C52 C57 1.525(5) . ?
C52 C53 1.542(5) . ?
C52 P5 1.846(4) . ?
C52 H52 0.9800 . ?
C53 C54 1.534(6) . ?
C53 H53A 0.9700 . ?
C53 H53B 0.9700 . ?
C54 C55 1.521(7) . ?
C54 H54A 0.9700 . ?
C54 H54B 0.9700 . ?
C55 C56 1.522(7) . ?
C55 H55A 0.9700 . ?
C55 H55B 0.9700 . ?
C56 C57 1.525(6) . ?
C56 H56A 0.9700 . ?
C56 H56B 0.9700 . ?
C57 H57A 0.9700 . ?
C57 H57B 0.9700 . ?
C58 C59 1.526(6) . ?
C58 C63 1.534(6) . ?
C58 P5 1.849(4) . ?
C58 H58 0.9800 . ?
C59 C60 1.526(7) . ?
C59 H59A 0.9700 . ?
C59 H59B 0.9700 . ?
C60 C61 1.526(8) . ?
C60 H60A 0.9700 . ?
C60 H60B 0.9700 . ?
C61 C62 1.535(8) . ?
C61 H61A 0.9700 . ?
C61 H61B 0.9700 . ?
C62 C63 1.532(6) . ?
C62 H62A 0.9700 . ?
C62 H62B 0.9700 . ?
C63 H63A 0.9700 . ?
C63 H63B 0.9700 . ?
C64 P6 1.837(4) . ?
C64 P5 1.843(4) . ?
C64 H64A 0.9700 . ?
C64 H64B 0.9700 . ?
C65 C70 1.535(5) . ?
C65 C66 1.537(5) . ?
C65 P6 1.848(4) . ?
C65 H65 0.9800 . ?
C66 C67 1.525(6) . ?
C66 H66A 0.9700 . ?
C66 H66B 0.9700 . ?
C67 C68 1.529(7) . ?
C67 H67A 0.9700 . ?
C67 H67B 0.9700 . ?
C68 C69 1.519(7) . ?
C68 H68A 0.9700 . ?
C68 H68B 0.9700 . ?
C69 C70 1.526(6) . ?
C69 H69A 0.9700 . ?
C69 H69B 0.9700 . ?
C70 H70A 0.9700 . ?
C70 H70B 0.9700 . ?
C71 C72 1.530(6) . ?
C71 C76 1.538(5) . ?
C71 P6 1.843(4) . ?
C71 H71 0.9800 . ?
C72 C73 1.525(6) . ?
C72 H72A 0.9700 . ?
C72 H72B 0.9700 . ?
C73 C74 1.518(8) . ?
C73 H73A 0.9700 . ?
C73 H73B 0.9700 . ?
C74 C75 1.515(10) . ?
C74 H74A 0.9700 . ?
C74 H74B 0.9700 . ?
C75 C76 1.529(6) . ?
C75 H75A 0.9700 . ?
C75 H75B 0.9700 . ?
C76 H76A 0.9700 . ?
C76 H76B 0.9700 . ?
N1 O5 1.233(5) . ?
N1 O4 1.256(5) . ?
N1 O3 1.257(5) . ?
N2 O8 1.204(6) . ?
N2 O6 1.277(6) . ?
N2 O7 1.281(7) . ?
N3 O10 1.216(6) . ?
N3 O11 1.232(5) . ?
N3 O9 1.280(5) . ?
N4 O14 1.218(6) . ?
N4 O13 1.231(6) . ?
N4 O12 1.275(5) . ?
N5 O16 1.217(6) . ?
N5 O17 1.235(7) . ?
N5 O15 1.257(6) . ?
O1 Ag1 2.161(3) . ?
O1 Ag1 2.485(3) 3_546 ?
O2 Ag2 2.288(4) . ?
O3 Ag2 2.423(3) . ?
O4 Ag2 2.536(3) . ?
O6 Ag3 2.217(3) . ?
O6 Ag6 2.362(3) . ?
O9 Ag5 2.236(3) . ?
O9 Ag3 2.462(3) . ?
O12 Ag6 2.324(4) . ?
O12 Ag4 2.367(3) . ?
O15 Ag4 2.333(4) . ?
O15 Ag5 2.379(4) . ?
P1 Ag1 2.3364(9) . ?
P2 Ag2 2.3591(10) . ?
P3 Ag3 2.3473(10) . ?
P4 Ag4 2.3380(9) . ?
P5 Ag5 2.3368(9) . ?
P6 Ag6 2.3255(9) . ?
Ag1 O1 2.485(3) 3_546 ?
Ag1 Ag2 3.2294(4) . ?
Ag3 Ag4 3.3148(4) . ?
Ag5 Ag6 3.1892(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 110.4(3) . . ?
C2 C1 P1 109.8(3) . . ?
C6 C1 P1 109.3(3) . . ?
C2 C1 H1 109.1 . . ?
C6 C1 H1 109.1 . . ?
P1 C1 H1 109.1 . . ?
C3 C2 C1 111.8(3) . . ?
C3 C2 H2A 109.3 . . ?
C1 C2 H2A 109.3 . . ?
C3 C2 H2B 109.3 . . ?
C1 C2 H2B 109.3 . . ?
H2A C2 H2B 107.9 . . ?
C2 C3 C4 111.8(3) . . ?
C2 C3 H3A 109.3 . . ?
C4 C3 H3A 109.3 . . ?
C2 C3 H3B 109.3 . . ?
C4 C3 H3B 109.3 . . ?
H3A C3 H3B 107.9 . . ?
C3 C4 C5 110.2(4) . . ?
C3 C4 H4A 109.6 . . ?
C5 C4 H4A 109.6 . . ?
C3 C4 H4B 109.6 . . ?
C5 C4 H4B 109.6 . . ?
H4A C4 H4B 108.1 . . ?
C4 C5 C6 111.1(4) . . ?
C4 C5 H5A 109.4 . . ?
C6 C5 H5A 109.4 . . ?
C4 C5 H5B 109.4 . . ?
C6 C5 H5B 109.4 . . ?
H5A C5 H5B 108.0 . . ?
C5 C6 C1 111.1(3) . . ?
C5 C6 H6A 109.4 . . ?
C1 C6 H6A 109.4 . . ?
C5 C6 H6B 109.4 . . ?
C1 C6 H6B 109.4 . . ?
H6A C6 H6B 108.0 . . ?
C12 C7 C8 110.1(4) . . ?
C12 C7 P1 110.9(3) . . ?
C8 C7 P1 114.3(3) . . ?
C12 C7 H7 107.1 . . ?
C8 C7 H7 107.1 . . ?
P1 C7 H7 107.1 . . ?
C9 C8 C7 111.5(5) . . ?
C9 C8 H8A 109.3 . . ?
C7 C8 H8A 109.3 . . ?
C9 C8 H8B 109.3 . . ?
C7 C8 H8B 109.3 . . ?
H8A C8 H8B 108.0 . . ?
C10 C9 C8 112.3(5) . . ?
C10 C9 H9A 109.2 . . ?
C8 C9 H9A 109.2 . . ?
C10 C9 H9B 109.2 . . ?
C8 C9 H9B 109.2 . . ?
H9A C9 H9B 107.9 . . ?
C9 C10 C11 109.8(5) . . ?
C9 C10 H10A 109.7 . . ?
C11 C10 H10A 109.7 . . ?
C9 C10 H10B 109.7 . . ?
C11 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
C12 C11 C10 109.3(5) . . ?
C12 C11 H11A 109.8 . . ?
C10 C11 H11A 109.8 . . ?
C12 C11 H11B 109.8 . . ?
C10 C11 H11B 109.8 . . ?
H11A C11 H11B 108.3 . . ?
C7 C12 C11 112.2(5) . . ?
C7 C12 H12A 109.2 . . ?
C11 C12 H12A 109.2 . . ?
C7 C12 H12B 109.2 . . ?
C11 C12 H12B 109.2 . . ?
H12A C12 H12B 107.9 . . ?
P2 C13 P1 112.2(2) . . ?
P2 C13 H13A 109.2 . . ?
P1 C13 H13A 109.2 . . ?
P2 C13 H13B 109.2 . . ?
P1 C13 H13B 109.2 . . ?
H13A C13 H13B 107.9 . . ?
C19 C14 C15 110.7(3) . . ?
C19 C14 P2 115.6(3) . . ?
C15 C14 P2 112.1(3) . . ?
C19 C14 H14 105.9 . . ?
C15 C14 H14 105.9 . . ?
P2 C14 H14 105.9 . . ?
C16 C15 C14 111.0(4) . . ?
C16 C15 H15A 109.4 . . ?
C14 C15 H15A 109.4 . . ?
C16 C15 H15B 109.4 . . ?
C14 C15 H15B 109.4 . . ?
H15A C15 H15B 108.0 . . ?
C17 C16 C15 111.4(4) . . ?
C17 C16 H16A 109.3 . . ?
C15 C16 H16A 109.3 . . ?
C17 C16 H16B 109.3 . . ?
C15 C16 H16B 109.3 . . ?
H16A C16 H16B 108.0 . . ?
C16 C17 C18 111.7(4) . . ?
C16 C17 H17A 109.3 . . ?
C18 C17 H17A 109.3 . . ?
C16 C17 H17B 109.3 . . ?
C18 C17 H17B 109.3 . . ?
H17A C17 H17B 107.9 . . ?
C17 C18 C19 111.1(4) . . ?
C17 C18 H18A 109.4 . . ?
C19 C18 H18A 109.4 . . ?
C17 C18 H18B 109.4 . . ?
C19 C18 H18B 109.4 . . ?
H18A C18 H18B 108.0 . . ?
C18 C19 C14 110.2(4) . . ?
C18 C19 H19A 109.6 . . ?
C14 C19 H19A 109.6 . . ?
C18 C19 H19B 109.6 . . ?
C14 C19 H19B 109.6 . . ?
H19A C19 H19B 108.1 . . ?
C21 C20 C25 111.4(4) . . ?
C21 C20 P2 110.8(3) . . ?
C25 C20 P2 110.4(3) . . ?
C21 C20 H20 108.0 . . ?
C25 C20 H20 108.0 . . ?
P2 C20 H20 108.0 . . ?
C20 C21 C22 110.4(4) . . ?
C20 C21 H21A 109.6 . . ?
C22 C21 H21A 109.6 . . ?
C20 C21 H21B 109.6 . . ?
C22 C21 H21B 109.6 . . ?
H21A C21 H21B 108.1 . . ?
C23 C22 C21 112.1(4) . . ?
C23 C22 H22A 109.2 . . ?
C21 C22 H22A 109.2 . . ?
C23 C22 H22B 109.2 . . ?
C21 C22 H22B 109.2 . . ?
H22A C22 H22B 107.9 . . ?
C22 C23 C24 110.2(4) . . ?
C22 C23 H23A 109.6 . . ?
C24 C23 H23A 109.6 . . ?
C22 C23 H23B 109.6 . . ?
C24 C23 H23B 109.6 . . ?
H23A C23 H23B 108.1 . . ?
C23 C24 C25 111.0(5) . . ?
C23 C24 H24A 109.4 . . ?
C25 C24 H24A 109.4 . . ?
C23 C24 H24B 109.4 . . ?
C25 C24 H24B 109.4 . . ?
H24A C24 H24B 108.0 . . ?
C20 C25 C24 110.2(4) . . ?
C20 C25 H25A 109.6 . . ?
C24 C25 H25A 109.6 . . ?
C20 C25 H25B 109.6 . . ?
C24 C25 H25B 109.6 . . ?
H25A C25 H25B 108.1 . . ?
O2 C26 O1 128.8(5) . . ?
O2 C26 H 117(4) . . ?
O1 C26 H 114(4) . . ?
C28 C27 C32 110.4(4) . . ?
C28 C27 P3 114.9(3) . . ?
C32 C27 P3 110.6(3) . . ?
C28 C27 H27 106.9 . . ?
C32 C27 H27 106.9 . . ?
P3 C27 H27 106.9 . . ?
C27 C28 C29 110.1(4) . . ?
C27 C28 H28A 109.6 . . ?
C29 C28 H28A 109.6 . . ?
C27 C28 H28B 109.6 . . ?
C29 C28 H28B 109.6 . . ?
H28A C28 H28B 108.2 . . ?
C30 C29 C28 111.1(5) . . ?
C30 C29 H29A 109.4 . . ?
C28 C29 H29A 109.4 . . ?
C30 C29 H29B 109.4 . . ?
C28 C29 H29B 109.4 . . ?
H29A C29 H29B 108.0 . . ?
C31 C30 C29 111.3(5) . . ?
C31 C30 H30A 109.4 . . ?
C29 C30 H30A 109.4 . . ?
C31 C30 H30B 109.4 . . ?
C29 C30 H30B 109.4 . . ?
H30A C30 H30B 108.0 . . ?
C30 C31 C32 111.8(4) . . ?
C30 C31 H31A 109.3 . . ?
C32 C31 H31A 109.3 . . ?
C30 C31 H31B 109.3 . . ?
C32 C31 H31B 109.3 . . ?
H31A C31 H31B 107.9 . . ?
C31 C32 C27 110.8(4) . . ?
C31 C32 H32A 109.5 . . ?
C27 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C27 C32 H32B 109.5 . . ?
H32A C32 H32B 108.1 . . ?
C34 C33 C38 110.5(4) . . ?
C34 C33 P3 111.8(3) . . ?
C38 C33 P3 108.4(3) . . ?
C34 C33 H33 108.7 . . ?
C38 C33 H33 108.7 . . ?
P3 C33 H33 108.7 . . ?
C33 C34 C35 110.6(4) . . ?
C33 C34 H34A 109.5 . . ?
C35 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C35 C34 H34B 109.5 . . ?
H34A C34 H34B 108.1 . . ?
C36 C35 C34 111.3(4) . . ?
C36 C35 H35A 109.4 . . ?
C34 C35 H35A 109.4 . . ?
C36 C35 H35B 109.4 . . ?
C34 C35 H35B 109.4 . . ?
H35A C35 H35B 108.0 . . ?
C37 C36 C35 110.3(5) . . ?
C37 C36 H36A 109.6 . . ?
C35 C36 H36A 109.6 . . ?
C37 C36 H36B 109.6 . . ?
C35 C36 H36B 109.6 . . ?
H36A C36 H36B 108.1 . . ?
C36 C37 C38 111.0(4) . . ?
C36 C37 H37A 109.4 . . ?
C38 C37 H37A 109.4 . . ?
C36 C37 H37B 109.4 . . ?
C38 C37 H37B 109.4 . . ?
H37A C37 H37B 108.0 . . ?
C37 C38 C33 112.7(4) . . ?
C37 C38 H38A 109.0 . . ?
C33 C38 H38A 109.0 . . ?
C37 C38 H38B 109.0 . . ?
C33 C38 H38B 109.0 . . ?
H38A C38 H38B 107.8 . . ?
P3 C39 P4 116.3(2) . . ?
P3 C39 H39A 108.2 . . ?
P4 C39 H39A 108.2 . . ?
P3 C39 H39B 108.2 . . ?
P4 C39 H39B 108.2 . . ?
H39A C39 H39B 107.4 . . ?
C41 C40 C45 111.0(3) . . ?
C41 C40 P4 110.9(3) . . ?
C45 C40 P4 114.3(3) . . ?
C41 C40 H40 106.7 . . ?
C45 C40 H40 106.7 . . ?
P4 C40 H40 106.7 . . ?
C40 C41 C42 111.1(4) . . ?
C40 C41 H41A 109.4 . . ?
C42 C41 H41A 109.4 . . ?
C40 C41 H41B 109.4 . . ?
C42 C41 H41B 109.4 . . ?
H41A C41 H41B 108.0 . . ?
C43 C42 C41 110.9(3) . . ?
C43 C42 H42A 109.5 . . ?
C41 C42 H42A 109.5 . . ?
C43 C42 H42B 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 108.0 . . ?
C42 C43 C44 111.1(4) . . ?
C42 C43 H43A 109.4 . . ?
C44 C43 H43A 109.4 . . ?
C42 C43 H43B 109.4 . . ?
C44 C43 H43B 109.4 . . ?
H43A C43 H43B 108.0 . . ?
C45 C44 C43 111.0(3) . . ?
C45 C44 H44A 109.4 . . ?
C43 C44 H44A 109.4 . . ?
C45 C44 H44B 109.4 . . ?
C43 C44 H44B 109.4 . . ?
H44A C44 H44B 108.0 . . ?
C44 C45 C40 110.9(3) . . ?
C44 C45 H45A 109.5 . . ?
C40 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
C40 C45 H45B 109.5 . . ?
H45A C45 H45B 108.0 . . ?
C47 C46 C51 110.0(3) . . ?
C47 C46 P4 110.4(3) . . ?
C51 C46 P4 110.7(3) . . ?
C47 C46 H46 108.6 . . ?
C51 C46 H46 108.6 . . ?
P4 C46 H46 108.6 . . ?
C48 C47 C46 111.8(4) . . ?
C48 C47 H47A 109.3 . . ?
C46 C47 H47A 109.3 . . ?
C48 C47 H47B 109.3 . . ?
C46 C47 H47B 109.3 . . ?
H47A C47 H47B 107.9 . . ?
C47 C48 C49 111.4(4) . . ?
C47 C48 H48A 109.3 . . ?
C49 C48 H48A 109.3 . . ?
C47 C48 H48B 109.3 . . ?
C49 C48 H48B 109.3 . . ?
H48A C48 H48B 108.0 . . ?
C50 C49 C48 110.5(4) . . ?
C50 C49 H49A 109.6 . . ?
C48 C49 H49A 109.6 . . ?
C50 C49 H49B 109.6 . . ?
C48 C49 H49B 109.6 . . ?
H49A C49 H49B 108.1 . . ?
C49 C50 C51 111.1(4) . . ?
C49 C50 H50A 109.4 . . ?
C51 C50 H50A 109.4 . . ?
C49 C50 H50B 109.4 . . ?
C51 C50 H50B 109.4 . . ?
H50A C50 H50B 108.0 . . ?
C50 C51 C46 110.7(3) . . ?
C50 C51 H51A 109.5 . . ?
C46 C51 H51A 109.5 . . ?
C50 C51 H51B 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 108.1 . . ?
C57 C52 C53 110.0(3) . . ?
C57 C52 P5 110.4(3) . . ?
C53 C52 P5 109.3(3) . . ?
C57 C52 H52 109.0 . . ?
C53 C52 H52 109.0 . . ?
P5 C52 H52 109.0 . . ?
C54 C53 C52 111.8(4) . . ?
C54 C53 H53A 109.3 . . ?
C52 C53 H53A 109.3 . . ?
C54 C53 H53B 109.3 . . ?
C52 C53 H53B 109.3 . . ?
H53A C53 H53B 107.9 . . ?
C55 C54 C53 111.1(4) . . ?
C55 C54 H54A 109.4 . . ?
C53 C54 H54A 109.4 . . ?
C55 C54 H54B 109.4 . . ?
C53 C54 H54B 109.4 . . ?
H54A C54 H54B 108.0 . . ?
C54 C55 C56 110.2(4) . . ?
C54 C55 H55A 109.6 . . ?
C56 C55 H55A 109.6 . . ?
C54 C55 H55B 109.6 . . ?
C56 C55 H55B 109.6 . . ?
H55A C55 H55B 108.1 . . ?
C55 C56 C57 111.7(4) . . ?
C55 C56 H56A 109.3 . . ?
C57 C56 H56A 109.3 . . ?
C55 C56 H56B 109.3 . . ?
C57 C56 H56B 109.3 . . ?
H56A C56 H56B 107.9 . . ?
C52 C57 C56 111.8(4) . . ?
C52 C57 H57A 109.2 . . ?
C56 C57 H57A 109.2 . . ?
C52 C57 H57B 109.2 . . ?
C56 C57 H57B 109.2 . . ?
H57A C57 H57B 107.9 . . ?
C59 C58 C63 111.1(3) . . ?
C59 C58 P5 113.0(3) . . ?
C63 C58 P5 116.1(3) . . ?
C59 C58 H58 105.2 . . ?
C63 C58 H58 105.2 . . ?
P5 C58 H58 105.2 . . ?
C60 C59 C58 110.8(4) . . ?
C60 C59 H59A 109.5 . . ?
C58 C59 H59A 109.5 . . ?
C60 C59 H59B 109.5 . . ?
C58 C59 H59B 109.5 . . ?
H59A C59 H59B 108.1 . . ?
C59 C60 C61 111.3(4) . . ?
C59 C60 H60A 109.4 . . ?
C61 C60 H60A 109.4 . . ?
C59 C60 H60B 109.4 . . ?
C61 C60 H60B 109.4 . . ?
H60A C60 H60B 108.0 . . ?
C60 C61 C62 112.5(4) . . ?
C60 C61 H61A 109.1 . . ?
C62 C61 H61A 109.1 . . ?
C60 C61 H61B 109.1 . . ?
C62 C61 H61B 109.1 . . ?
H61A C61 H61B 107.8 . . ?
C63 C62 C61 111.5(4) . . ?
C63 C62 H62A 109.3 . . ?
C61 C62 H62A 109.3 . . ?
C63 C62 H62B 109.3 . . ?
C61 C62 H62B 109.3 . . ?
H62A C62 H62B 108.0 . . ?
C62 C63 C58 110.2(4) . . ?
C62 C63 H63A 109.6 . . ?
C58 C63 H63A 109.6 . . ?
C62 C63 H63B 109.6 . . ?
C58 C63 H63B 109.6 . . ?
H63A C63 H63B 108.1 . . ?
P6 C64 P5 113.6(2) . . ?
P6 C64 H64A 108.9 . . ?
P5 C64 H64A 108.9 . . ?
P6 C64 H64B 108.9 . . ?
P5 C64 H64B 108.9 . . ?
H64A C64 H64B 107.7 . . ?
C70 C65 C66 110.8(3) . . ?
C70 C65 P6 110.7(3) . . ?
C66 C65 P6 108.7(3) . . ?
C70 C65 H65 108.9 . . ?
C66 C65 H65 108.9 . . ?
P6 C65 H65 108.9 . . ?
C67 C66 C65 112.0(4) . . ?
C67 C66 H66A 109.2 . . ?
C65 C66 H66A 109.2 . . ?
C67 C66 H66B 109.2 . . ?
C65 C66 H66B 109.2 . . ?
H66A C66 H66B 107.9 . . ?
C66 C67 C68 111.1(4) . . ?
C66 C67 H67A 109.4 . . ?
C68 C67 H67A 109.4 . . ?
C66 C67 H67B 109.4 . . ?
C68 C67 H67B 109.4 . . ?
H67A C67 H67B 108.0 . . ?
C69 C68 C67 110.7(4) . . ?
C69 C68 H68A 109.5 . . ?
C67 C68 H68A 109.5 . . ?
C69 C68 H68B 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 108.1 . . ?
C68 C69 C70 111.5(4) . . ?
C68 C69 H69A 109.3 . . ?
C70 C69 H69A 109.3 . . ?
C68 C69 H69B 109.3 . . ?
C70 C69 H69B 109.3 . . ?
H69A C69 H69B 108.0 . . ?
C69 C70 C65 111.5(4) . . ?
C69 C70 H70A 109.3 . . ?
C65 C70 H70A 109.3 . . ?
C69 C70 H70B 109.3 . . ?
C65 C70 H70B 109.3 . . ?
H70A C70 H70B 108.0 . . ?
C72 C71 C76 111.9(3) . . ?
C72 C71 P6 114.7(3) . . ?
C76 C71 P6 112.2(3) . . ?
C72 C71 H71 105.7 . . ?
C76 C71 H71 105.7 . . ?
P6 C71 H71 105.7 . . ?
C73 C72 C71 111.2(4) . . ?
C73 C72 H72A 109.4 . . ?
C71 C72 H72A 109.4 . . ?
C73 C72 H72B 109.4 . . ?
C71 C72 H72B 109.4 . . ?
H72A C72 H72B 108.0 . . ?
C74 C73 C72 110.7(4) . . ?
C74 C73 H73A 109.5 . . ?
C72 C73 H73A 109.5 . . ?
C74 C73 H73B 109.5 . . ?
C72 C73 H73B 109.5 . . ?
H73A C73 H73B 108.1 . . ?
C75 C74 C73 110.9(5) . . ?
C75 C74 H74A 109.5 . . ?
C73 C74 H74A 109.5 . . ?
C75 C74 H74B 109.5 . . ?
C73 C74 H74B 109.5 . . ?
H74A C74 H74B 108.0 . . ?
C74 C75 C76 112.2(5) . . ?
C74 C75 H75A 109.2 . . ?
C76 C75 H75A 109.2 . . ?
C74 C75 H75B 109.2 . . ?
C76 C75 H75B 109.2 . . ?
H75A C75 H75B 107.9 . . ?
C75 C76 C71 110.2(4) . . ?
C75 C76 H76A 109.6 . . ?
C71 C76 H76A 109.6 . . ?
C75 C76 H76B 109.6 . . ?
C71 C76 H76B 109.6 . . ?
H76A C76 H76B 108.1 . . ?
O5 N1 O4 121.0(3) . . ?
O5 N1 O3 121.1(3) . . ?
O4 N1 O3 117.8(3) . . ?
O8 N2 O6 119.3(5) . . ?
O8 N2 O7 126.4(5) . . ?
O6 N2 O7 114.2(5) . . ?
O10 N3 O11 124.7(5) . . ?
O10 N3 O9 118.0(4) . . ?
O11 N3 O9 117.3(4) . . ?
O14 N4 O13 123.5(5) . . ?
O14 N4 O12 117.6(4) . . ?
O13 N4 O12 118.8(4) . . ?
O16 N5 O17 123.5(6) . . ?
O16 N5 O15 120.0(5) . . ?
O17 N5 O15 116.5(4) . . ?
C26 O1 Ag1 120.2(3) . . ?
C26 O1 Ag1 135.8(3) . 3_546 ?
Ag1 O1 Ag1 102.89(13) . 3_546 ?
C26 O2 Ag2 129.0(4) . . ?
N1 O3 Ag2 98.1(2) . . ?
N1 O4 Ag2 92.6(2) . . ?
N2 O6 Ag3 118.5(3) . . ?
N2 O6 Ag6 106.8(3) . . ?
Ag3 O6 Ag6 127.42(15) . . ?
N3 O9 Ag5 113.5(3) . . ?
N3 O9 Ag3 108.0(2) . . ?
Ag5 O9 Ag3 138.21(15) . . ?
N4 O12 Ag6 109.1(3) . . ?
N4 O12 Ag4 109.5(3) . . ?
Ag6 O12 Ag4 141.16(16) . . ?
N5 O15 Ag4 103.8(3) . . ?
N5 O15 Ag5 124.3(3) . . ?
Ag4 O15 Ag5 118.71(19) . . ?
C1 P1 C13 106.20(17) . . ?
C1 P1 C7 107.33(19) . . ?
C13 P1 C7 104.4(2) . . ?
C1 P1 Ag1 109.89(12) . . ?
C13 P1 Ag1 110.75(13) . . ?
C7 P1 Ag1 117.59(15) . . ?
C13 P2 C20 102.84(18) . . ?
C13 P2 C14 104.15(18) . . ?
C20 P2 C14 106.32(18) . . ?
C13 P2 Ag2 109.65(13) . . ?
C20 P2 Ag2 118.11(15) . . ?
C14 P2 Ag2 114.32(14) . . ?
C33 P3 C39 103.47(18) . . ?
C33 P3 C27 107.51(19) . . ?
C39 P3 C27 103.03(19) . . ?
C33 P3 Ag3 111.22(13) . . ?
C39 P3 Ag3 116.33(12) . . ?
C27 P3 Ag3 114.29(14) . . ?
C46 P4 C40 105.95(17) . . ?
C46 P4 C39 103.31(17) . . ?
C40 P4 C39 103.48(17) . . ?
C46 P4 Ag4 110.47(12) . . ?
C40 P4 Ag4 113.37(12) . . ?
C39 P4 Ag4 119.04(12) . . ?
C64 P5 C52 103.71(17) . . ?
C64 P5 C58 103.34(18) . . ?
C52 P5 C58 109.86(18) . . ?
C64 P5 Ag5 113.59(12) . . ?
C52 P5 Ag5 112.72(13) . . ?
C58 P5 Ag5 112.88(14) . . ?
C64 P6 C71 103.34(18) . . ?
C64 P6 C65 103.19(17) . . ?
C71 P6 C65 109.15(17) . . ?
C64 P6 Ag6 115.36(13) . . ?
C71 P6 Ag6 111.49(13) . . ?
C65 P6 Ag6 113.51(12) . . ?
O1 Ag1 P1 162.80(9) . . ?
O1 Ag1 O1 77.11(13) . 3_546 ?
P1 Ag1 O1 120.07(8) . 3_546 ?
O1 Ag1 Ag2 80.17(9) . . ?
P1 Ag1 Ag2 85.72(2) . . ?
O1 Ag1 Ag2 135.74(8) 3_546 . ?
O2 Ag2 P2 139.22(10) . . ?
O2 Ag2 O3 84.15(14) . . ?
P2 Ag2 O3 133.31(10) . . ?
O2 Ag2 O4 82.01(14) . . ?
P2 Ag2 O4 131.15(8) . . ?
O3 Ag2 O4 51.39(10) . . ?
O2 Ag2 Ag1 70.36(10) . . ?
P2 Ag2 Ag1 73.22(2) . . ?
O3 Ag2 Ag1 153.45(9) . . ?
O4 Ag2 Ag1 115.42(7) . . ?
O6 Ag3 P3 160.55(10) . . ?
O6 Ag3 O9 75.35(12) . . ?
P3 Ag3 O9 122.90(9) . . ?
O6 Ag3 Ag4 94.03(10) . . ?
P3 Ag3 Ag4 84.17(2) . . ?
O9 Ag3 Ag4 78.61(8) . . ?
O15 Ag4 P4 145.28(11) . . ?
O15 Ag4 O12 82.26(15) . . ?
P4 Ag4 O12 128.77(12) . . ?
O15 Ag4 Ag3 89.64(10) . . ?
P4 Ag4 Ag3 82.81(2) . . ?
O12 Ag4 Ag3 79.24(9) . . ?
O9 Ag5 P5 154.96(10) . . ?
O9 Ag5 O15 77.29(13) . . ?
P5 Ag5 O15 127.28(10) . . ?
O9 Ag5 Ag6 75.48(9) . . ?
P5 Ag5 Ag6 91.74(2) . . ?
O15 Ag5 Ag6 104.16(11) . . ?
O12 Ag6 P6 134.50(12) . . ?
O12 Ag6 O6 81.02(13) . . ?
P6 Ag6 O6 137.65(10) . . ?
O12 Ag6 Ag5 71.71(11) . . ?
P6 Ag6 Ag5 80.15(2) . . ?
O6 Ag6 Ag5 95.24(8) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -54.0(4) . . . . ?
P1 C1 C2 C3 -174.6(3) . . . . ?
C1 C2 C3 C4 55.7(5) . . . . ?
C2 C3 C4 C5 -56.7(5) . . . . ?
C3 C4 C5 C6 57.3(5) . . . . ?
C4 C5 C6 C1 -56.8(5) . . . . ?
C2 C1 C6 C5 54.5(4) . . . . ?
P1 C1 C6 C5 175.4(3) . . . . ?
C12 C7 C8 C9 53.6(6) . . . . ?
P1 C7 C8 C9 179.1(4) . . . . ?
C7 C8 C9 C10 -55.3(7) . . . . ?
C8 C9 C10 C11 56.8(8) . . . . ?
C9 C10 C11 C12 -57.6(7) . . . . ?
C8 C7 C12 C11 -56.4(6) . . . . ?
P1 C7 C12 C11 176.1(4) . . . . ?
C10 C11 C12 C7 58.4(7) . . . . ?
C19 C14 C15 C16 -55.8(5) . . . . ?
P2 C14 C15 C16 173.5(3) . . . . ?
C14 C15 C16 C17 54.6(5) . . . . ?
C15 C16 C17 C18 -54.9(5) . . . . ?
C16 C17 C18 C19 56.3(5) . . . . ?
C17 C18 C19 C14 -57.1(5) . . . . ?
C15 C14 C19 C18 56.8(5) . . . . ?
P2 C14 C19 C18 -174.3(3) . . . . ?
C25 C20 C21 C22 54.5(6) . . . . ?
P2 C20 C21 C22 177.8(4) . . . . ?
C20 C21 C22 C23 -54.9(6) . . . . ?
C21 C22 C23 C24 56.5(7) . . . . ?
C22 C23 C24 C25 -57.9(7) . . . . ?
C21 C20 C25 C24 -56.3(6) . . . . ?
P2 C20 C25 C24 -179.8(4) . . . . ?
C23 C24 C25 C20 57.9(7) . . . . ?
C32 C27 C28 C29 -57.6(6) . . . . ?
P3 C27 C28 C29 176.5(4) . . . . ?
C27 C28 C29 C30 57.4(7) . . . . ?
C28 C29 C30 C31 -55.9(7) . . . . ?
C29 C30 C31 C32 54.8(7) . . . . ?
C30 C31 C32 C27 -55.2(7) . . . . ?
C28 C27 C32 C31 56.5(5) . . . . ?
P3 C27 C32 C31 -175.3(4) . . . . ?
C38 C33 C34 C35 -53.9(5) . . . . ?
P3 C33 C34 C35 -174.8(4) . . . . ?
C33 C34 C35 C36 58.0(6) . . . . ?
C34 C35 C36 C37 -59.0(6) . . . . ?
C35 C36 C37 C38 56.7(6) . . . . ?
C36 C37 C38 C33 -54.4(6) . . . . ?
C34 C33 C38 C37 53.0(5) . . . . ?
P3 C33 C38 C37 175.9(3) . . . . ?
C45 C40 C41 C42 55.5(4) . . . . ?
P4 C40 C41 C42 -176.3(3) . . . . ?
C40 C41 C42 C43 -55.6(5) . . . . ?
C41 C42 C43 C44 56.1(5) . . . . ?
C42 C43 C44 C45 -56.6(5) . . . . ?
C43 C44 C45 C40 56.3(5) . . . . ?
C41 C40 C45 C44 -55.9(4) . . . . ?
P4 C40 C45 C44 177.8(3) . . . . ?
C51 C46 C47 C48 55.5(5) . . . . ?
P4 C46 C47 C48 177.9(3) . . . . ?
C46 C47 C48 C49 -55.7(6) . . . . ?
C47 C48 C49 C50 56.0(6) . . . . ?
C48 C49 C50 C51 -57.0(6) . . . . ?
C49 C50 C51 C46 57.7(5) . . . . ?
C47 C46 C51 C50 -56.0(5) . . . . ?
P4 C46 C51 C50 -178.3(3) . . . . ?
C57 C52 C53 C54 -54.4(5) . . . . ?
P5 C52 C53 C54 -175.7(3) . . . . ?
C52 C53 C54 C55 56.0(5) . . . . ?
C53 C54 C55 C56 -56.3(6) . . . . ?
C54 C55 C56 C57 56.7(6) . . . . ?
C53 C52 C57 C56 54.5(5) . . . . ?
P5 C52 C57 C56 175.2(3) . . . . ?
C55 C56 C57 C52 -56.6(6) . . . . ?
C63 C58 C59 C60 58.1(5) . . . . ?
P5 C58 C59 C60 -169.3(3) . . . . ?
C58 C59 C60 C61 -55.4(5) . . . . ?
C59 C60 C61 C62 53.2(6) . . . . ?
C60 C61 C62 C63 -53.2(6) . . . . ?
C61 C62 C63 C58 54.8(5) . . . . ?
C59 C58 C63 C62 -57.7(5) . . . . ?
P5 C58 C63 C62 171.3(3) . . . . ?
C70 C65 C66 C67 53.7(4) . . . . ?
P6 C65 C66 C67 175.6(3) . . . . ?
C65 C66 C67 C68 -55.2(5) . . . . ?
C66 C67 C68 C69 56.3(5) . . . . ?
C67 C68 C69 C70 -56.9(5) . . . . ?
C68 C69 C70 C65 56.0(5) . . . . ?
C66 C65 C70 C69 -53.8(4) . . . . ?
P6 C65 C70 C69 -174.4(3) . . . . ?
C76 C71 C72 C73 54.9(5) . . . . ?
P6 C71 C72 C73 -175.8(3) . . . . ?
C71 C72 C73 C74 -56.2(6) . . . . ?
C72 C73 C74 C75 57.1(7) . . . . ?
C73 C74 C75 C76 -56.9(6) . . . . ?
C74 C75 C76 C71 54.6(6) . . . . ?
C72 C71 C76 C75 -53.4(5) . . . . ?
P6 C71 C76 C75 176.0(4) . . . . ?
O2 C26 O1 Ag1 -16.9(11) . . . . ?
O2 C26 O1 Ag1 148.3(6) . . . 3_546 ?
O1 C26 O2 Ag2 -19.8(12) . . . . ?
O5 N1 O3 Ag2 178.4(3) . . . . ?
O4 N1 O3 Ag2 -3.1(4) . . . . ?
O5 N1 O4 Ag2 -178.5(3) . . . . ?
O3 N1 O4 Ag2 2.9(4) . . . . ?
O8 N2 O6 Ag3 21.8(6) . . . . ?
O7 N2 O6 Ag3 -154.9(4) . . . . ?
O8 N2 O6 Ag6 174.2(4) . . . . ?
O7 N2 O6 Ag6 -2.5(6) . . . . ?
O10 N3 O9 Ag5 0.2(6) . . . . ?
O11 N3 O9 Ag5 179.0(4) . . . . ?
O10 N3 O9 Ag3 -174.3(5) . . . . ?
O11 N3 O9 Ag3 4.5(5) . . . . ?
O14 N4 O12 Ag6 180.0(4) . . . . ?
O13 N4 O12 Ag6 0.2(6) . . . . ?
O14 N4 O12 Ag4 -4.5(6) . . . . ?
O13 N4 O12 Ag4 175.7(4) . . . . ?
O16 N5 O15 Ag4 -174.8(4) . . . . ?
O17 N5 O15 Ag4 7.0(6) . . . . ?
O16 N5 O15 Ag5 45.2(7) . . . . ?
O17 N5 O15 Ag5 -132.9(5) . . . . ?
C2 C1 P1 C13 -63.9(3) . . . . ?
C6 C1 P1 C13 174.8(3) . . . . ?
C2 C1 P1 C7 -175.0(3) . . . . ?
C6 C1 P1 C7 63.6(3) . . . . ?
C2 C1 P1 Ag1 56.0(3) . . . . ?
C6 C1 P1 Ag1 -65.3(3) . . . . ?
P2 C13 P1 C1 118.5(2) . . . . ?
P2 C13 P1 C7 -128.2(2) . . . . ?
P2 C13 P1 Ag1 -0.8(2) . . . . ?
C12 C7 P1 C1 176.3(3) . . . . ?
C8 C7 P1 C1 51.2(4) . . . . ?
C12 C7 P1 C13 63.9(4) . . . . ?
C8 C7 P1 C13 -61.3(4) . . . . ?
C12 C7 P1 Ag1 -59.3(4) . . . . ?
C8 C7 P1 Ag1 175.6(3) . . . . ?
P1 C13 P2 C20 177.3(2) . . . . ?
P1 C13 P2 C14 66.5(2) . . . . ?
P1 C13 P2 Ag2 -56.2(2) . . . . ?
C21 C20 P2 C13 60.2(4) . . . . ?
C25 C20 P2 C13 -175.9(4) . . . . ?
C21 C20 P2 C14 169.4(3) . . . . ?
C25 C20 P2 C14 -66.8(4) . . . . ?
C21 C20 P2 Ag2 -60.6(3) . . . . ?
C25 C20 P2 Ag2 63.2(4) . . . . ?
C19 C14 P2 C13 75.6(3) . . . . ?
C15 C14 P2 C13 -156.2(3) . . . . ?
C19 C14 P2 C20 -32.6(4) . . . . ?
C15 C14 P2 C20 95.5(3) . . . . ?
C19 C14 P2 Ag2 -164.8(3) . . . . ?
C15 C14 P2 Ag2 -36.6(3) . . . . ?
C34 C33 P3 C39 -163.7(3) . . . . ?
C38 C33 P3 C39 74.3(3) . . . . ?
C34 C33 P3 C27 -55.1(4) . . . . ?
C38 C33 P3 C27 -177.2(3) . . . . ?
C34 C33 P3 Ag3 70.7(3) . . . . ?
C38 C33 P3 Ag3 -51.4(3) . . . . ?
P4 C39 P3 C33 -97.8(2) . . . . ?
P4 C39 P3 C27 150.3(2) . . . . ?
P4 C39 P3 Ag3 24.4(3) . . . . ?
C28 C27 P3 C33 -51.6(4) . . . . ?
C32 C27 P3 C33 -177.3(3) . . . . ?
C28 C27 P3 C39 57.3(4) . . . . ?
C32 C27 P3 C39 -68.5(3) . . . . ?
C28 C27 P3 Ag3 -175.6(3) . . . . ?
C32 C27 P3 Ag3 58.7(3) . . . . ?
C47 C46 P4 C40 -177.5(3) . . . . ?
C51 C46 P4 C40 -55.5(3) . . . . ?
C47 C46 P4 C39 74.1(3) . . . . ?
C51 C46 P4 C39 -163.9(3) . . . . ?
C47 C46 P4 Ag4 -54.3(3) . . . . ?
C51 C46 P4 Ag4 67.7(3) . . . . ?
C41 C40 P4 C46 -179.6(3) . . . . ?
C45 C40 P4 C46 -53.2(3) . . . . ?
C41 C40 P4 C39 -71.2(3) . . . . ?
C45 C40 P4 C39 55.1(3) . . . . ?
C41 C40 P4 Ag4 59.1(3) . . . . ?
C45 C40 P4 Ag4 -174.5(2) . . . . ?
P3 C39 P4 C46 -104.4(2) . . . . ?
P3 C39 P4 C40 145.3(2) . . . . ?
P3 C39 P4 Ag4 18.4(3) . . . . ?
P6 C64 P5 C52 144.1(2) . . . . ?
P6 C64 P5 C58 -101.2(2) . . . . ?
P6 C64 P5 Ag5 21.4(3) . . . . ?
C57 C52 P5 C64 166.9(3) . . . . ?
C53 C52 P5 C64 -72.0(3) . . . . ?
C57 C52 P5 C58 57.0(3) . . . . ?
C53 C52 P5 C58 178.1(3) . . . . ?
C57 C52 P5 Ag5 -69.8(3) . . . . ?
C53 C52 P5 Ag5 51.3(3) . . . . ?
C59 C58 P5 C64 161.2(3) . . . . ?
C63 C58 P5 C64 -68.7(3) . . . . ?
C59 C58 P5 C52 -88.6(3) . . . . ?
C63 C58 P5 C52 41.5(3) . . . . ?
C59 C58 P5 Ag5 38.1(3) . . . . ?
C63 C58 P5 Ag5 168.2(3) . . . . ?
P5 C64 P6 C71 65.5(3) . . . . ?
P5 C64 P6 C65 179.2(2) . . . . ?
P5 C64 P6 Ag6 -56.4(2) . . . . ?
C72 C71 P6 C64 68.6(3) . . . . ?
C76 C71 P6 C64 -162.3(3) . . . . ?
C72 C71 P6 C65 -40.7(3) . . . . ?
C76 C71 P6 C65 88.4(3) . . . . ?
C72 C71 P6 Ag6 -166.9(2) . . . . ?
C76 C71 P6 Ag6 -37.8(3) . . . . ?
C70 C65 P6 C64 -176.1(3) . . . . ?
C66 C65 P6 C64 61.9(3) . . . . ?
C70 C65 P6 C71 -66.7(3) . . . . ?
C66 C65 P6 C71 171.3(2) . . . . ?
C70 C65 P6 Ag6 58.3(3) . . . . ?
C66 C65 P6 Ag6 -63.6(3) . . . . ?

_refine_diff_density_max         1.873
_refine_diff_density_min         -1.681
_refine_diff_density_rms         0.123

