# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1436108'
_audit_update_record             
;
2016-09-28 deposited with the CCDC.
2016-11-01 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C36 H43 Eu N7 O16'
_chemical_formula_weight         981.73

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'

_cell_length_a                   8.1737(5)
_cell_length_b                   15.0092(10)
_cell_length_c                   37.574(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 101.828(2)
_cell_angle_gamma                90.00
_cell_volume                     4511.7(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9909
_cell_measurement_theta_min      2.93
_cell_measurement_theta_max      28.34

_exptl_crystal_description       rod
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.445
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1996
_exptl_absorpt_coefficient_mu    1.463
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7489
_exptl_absorpt_correction_T_max  0.8676
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            72739
_diffrn_reflns_av_R_equivalents  0.1715
_diffrn_reflns_av_sigmaI/netI    0.1044
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_limit_l_max       44
_diffrn_reflns_theta_min         2.84
_diffrn_reflns_theta_max         25.02
_reflns_number_total             7782
_reflns_number_gt                5060
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0691P)²+31.8917P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7782
_refine_ls_number_parameters     543
_refine_ls_number_restraints     1345
_refine_ls_R_factor_all          0.1218
_refine_ls_R_factor_gt           0.0640
_refine_ls_wR_factor_ref         0.1671
_refine_ls_wR_factor_gt          0.1437
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_restrained_S_all      0.984
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.31991(5) 0.09839(3) -0.014455(11) 0.02270(15) Uani 1 1 d U . .
O1 O 0.1498(7) 0.0896(4) 0.03367(14) 0.0283(11) Uani 1 1 d U . .
O2 O 0.3896(7) 0.2403(4) -0.04541(16) 0.0342(12) Uani 1 1 d U . .
O3 O 0.2655(7) 0.2180(4) 0.02674(14) 0.0281(11) Uani 1 1 d U . .
O4 O -0.5035(6) 0.0265(4) 0.46520(14) 0.0267(12) Uani 1 1 d U . .
O5 O 0.5885(7) 0.1701(4) -0.00783(16) 0.0337(12) Uani 1 1 d U . .
N1 N 1.0454(9) 0.4751(5) -0.0473(2) 0.0344(13) Uani 1 1 d U . .
H1 H 1.0530 0.5225 -0.0597 0.041 Uiso 1 1 calc R . .
O6 O 0.1803(7) -0.0446(4) -0.02060(16) 0.0346(15) Uani 1 1 d U . .
H6B H 0.1537 -0.0571 -0.0431 0.041 Uiso 1 1 d R . .
H6C H 0.0901 -0.0393 -0.0129 0.041 Uiso 1 1 d R . .
C1 C 0.1074(11) 0.2068(6) 0.0734(2) 0.0307(14) Uani 1 1 d U . .
C2 C 0.8304(10) 0.2909(6) -0.0175(2) 0.0306(14) Uani 1 1 d U . .
H2 H 0.8619 0.2451 -0.0009 0.037 Uiso 1 1 calc R . .
C3 C 0.5426(11) 0.2336(6) -0.0298(2) 0.0296(15) Uani 1 1 d U . .
N2 N -0.0675(9) 0.1493(5) 0.15413(18) 0.0343(13) Uani 1 1 d U . .
H2A H -0.0772 0.0934 0.1582 0.041 Uiso 1 1 calc R . .
C4 C 0.6682(10) 0.2987(6) -0.0366(2) 0.0289(14) Uani 1 1 d U . .
N3 N 1.1135(8) 0.3622(5) -0.00888(19) 0.0295(13) Uani 1 1 d U . .
N4 N -0.0750(9) 0.2974(5) 0.16173(19) 0.0369(13) Uani 1 1 d U . .
C5 C 0.9442(10) 0.3532(6) -0.0239(2) 0.0289(14) Uani 1 1 d U . .
C6 C 1.3890(10) 0.5460(6) -0.0266(2) 0.0293(17) Uani 1 1 d U . .
H6 H 1.3154 0.5771 -0.0445 0.035 Uiso 1 1 calc R . .
C7 C 0.1771(10) 0.1698(6) 0.0431(2) 0.0271(14) Uani 1 1 d U . .
O7 O -0.6540(8) -0.0560(4) 0.42256(15) 0.0376(13) Uani 1 1 d U . .
C8 C -0.4564(11) 0.1931(7) 0.3537(2) 0.0335(15) Uani 1 1 d U . .
N5 N -0.3853(9) 0.0871(6) 0.31743(19) 0.0397(14) Uani 1 1 d U . .
H5 H -0.3677 0.0364 0.3082 0.048 Uiso 1 1 calc R . .
N6 N -0.4008(9) 0.2350(5) 0.32540(19) 0.0374(14) Uani 1 1 d U . .
C9 C -0.4912(11) 0.0426(7) 0.3729(2) 0.0350(14) Uani 1 1 d U . .
H9 H -0.4913 -0.0185 0.3688 0.042 Uiso 1 1 calc R . .
C10 C -0.0099(11) 0.1873(6) 0.1256(2) 0.0317(14) Uani 1 1 d U . .
C11 C -0.4451(11) 0.1017(7) 0.3485(2) 0.0364(14) Uani 1 1 d U . .
C12 C -0.1710(11) 0.2047(7) 0.2080(2) 0.0364(15) Uani 1 1 d U . .
C13 C -0.5665(11) 0.0128(6) 0.4315(2) 0.0308(15) Uani 1 1 d U . .
C14 C 1.1661(11) 0.4361(6) -0.0240(2) 0.0297(15) Uani 1 1 d U . .
C15 C -0.5366(11) 0.0761(6) 0.4033(2) 0.0324(15) Uani 1 1 d U . .
C16 C 0.9033(10) 0.4241(6) -0.0479(2) 0.0311(15) Uani 1 1 d U . .
C17 C -0.1049(11) 0.2168(7) 0.1742(2) 0.0366(14) Uani 1 1 d U . .
C18 C 0.0487(10) 0.1499(6) 0.0969(2) 0.0308(14) Uani 1 1 d U . .
H18 H 0.0486 0.0885 0.0936 0.037 Uiso 1 1 calc R . .
C19 C -0.2561(12) 0.1090(7) 0.2520(2) 0.0434(16) Uani 1 1 d U . .
H19 H -0.2713 0.0519 0.2604 0.052 Uiso 1 1 calc R . .
C20 C -0.0133(11) 0.2783(6) 0.1309(2) 0.0343(15) Uani 1 1 d U . .
C21 C -0.5471(11) 0.1685(6) 0.4086(2) 0.0329(15) Uani 1 1 d U . .
H21 H -0.5798 0.1893 0.4294 0.039 Uiso 1 1 calc R . .
C22 C 0.1039(11) 0.2993(6) 0.0786(2) 0.0341(15) Uani 1 1 d U . .
H22 H 0.1439 0.3368 0.0627 0.041 Uiso 1 1 calc R . .
C23 C -0.5099(11) 0.2290(7) 0.3837(2) 0.0355(15) Uani 1 1 d U . .
H23 H -0.5200 0.2901 0.3867 0.043 Uiso 1 1 calc R . .
C24 C -0.3603(12) 0.1665(7) 0.3047(2) 0.0390(15) Uani 1 1 d U . .
C25 C 0.6247(11) 0.3696(6) -0.0618(2) 0.0331(15) Uani 1 1 d U . .
H25 H 0.5153 0.3740 -0.0749 0.040 Uiso 1 1 calc R . .
C26 C 0.0422(11) 0.3358(7) 0.1070(2) 0.0370(15) Uani 1 1 d U . .
H26 H 0.0380 0.3972 0.1099 0.044 Uiso 1 1 calc R . .
C27 C -0.2930(12) 0.1817(7) 0.2712(2) 0.0383(15) Uani 1 1 d U . .
C28 C -0.1958(12) 0.1201(7) 0.2200(2) 0.0415(16) Uani 1 1 d U . .
H28 H -0.1728 0.0707 0.2069 0.050 Uiso 1 1 calc R . .
C29 C 0.7414(11) 0.4324(6) -0.0675(2) 0.0346(16) Uani 1 1 d U . .
H29 H 0.7114 0.4788 -0.0839 0.042 Uiso 1 1 calc R . .
C30 C 1.4510(10) 0.4236(6) 0.0147(2) 0.0310(17) Uani 1 1 d U . .
H30 H 1.4177 0.3715 0.0246 0.037 Uiso 1 1 calc R . .
C31 C 1.3370(10) 0.4687(6) -0.0119(2) 0.0284(15) Uani 1 1 d U . .
C32 C -0.2083(12) 0.2756(7) 0.2274(2) 0.0423(16) Uani 1 1 d U . .
H32 H -0.1936 0.3327 0.2189 0.051 Uiso 1 1 calc R . .
C33 C -0.2664(12) 0.2664(7) 0.2588(2) 0.0414(16) Uani 1 1 d U . .
H33 H -0.2879 0.3164 0.2717 0.050 Uiso 1 1 calc R . .
O8 O 0.0604(8) 0.1390(5) -0.04840(18) 0.0469(14) Uani 1 1 d U . .
C34 C 0.0232(15) 0.1932(9) -0.0747(3) 0.068(2) Uani 1 1 d U . .
H34 H 0.0951 0.2401 -0.0768 0.082 Uiso 1 1 calc R . .
N7 N -0.1106(13) 0.1839(8) -0.0981(3) 0.078(3) Uani 1 1 d DU . .
O9 O 0.8937(12) 0.9602(6) 0.1479(3) 0.099(3) Uani 1 1 d . . .
H9C H 0.9089 1.0159 0.1510 0.119 Uiso 1 1 d R . .
H9D H 0.8250 0.9520 0.1279 0.119 Uiso 1 1 d R . .
O10 O 0.5997(18) 0.4217(8) 0.3197(3) 0.150(5) Uani 1 1 d . . .
H10A H 0.5558 0.4225 0.2972 0.181 Uiso 1 1 d R . .
H10B H 0.6132 0.3666 0.3247 0.181 Uiso 1 1 d R . .
C35 C -0.2316(19) 0.1188(10) -0.0959(5) 0.117(4) Uani 1 1 d DU . .
H35A H -0.2239 0.0715 -0.1127 0.176 Uiso 1 1 calc R . .
H35B H -0.3409 0.1450 -0.1018 0.176 Uiso 1 1 calc R . .
H35C H -0.2126 0.0953 -0.0716 0.176 Uiso 1 1 calc R . .
O11 O 0.148(4) 0.4363(17) 0.8797(6) 0.337(9) Uani 1 1 d U . .
H11A H 0.0783 0.4329 0.8936 0.404 Uiso 1 1 d R . .
H11B H 0.2271 0.4699 0.8901 0.404 Uiso 1 1 d R . .
O12 O 0.623(6) 0.9134(12) 0.2958(8) 0.62(3) Uani 1 1 d U . .
H12A H 0.5800 0.8793 0.3094 0.746 Uiso 1 1 d R . .
H12B H 0.7225 0.8967 0.2961 0.746 Uiso 1 1 d R . .
O13 O 0.285(3) 0.2618(16) 0.8762(6) 0.335(10) Uani 1 1 d U . .
H13D H 0.2384 0.3126 0.8742 0.403 Uiso 1 1 d R . .
H13B H 0.2474 0.2297 0.8914 0.403 Uiso 1 1 d R . .
C36 C -0.157(2) 0.2474(12) -0.1276(4) 0.122(4) Uani 1 1 d U . .
H36A H -0.0801 0.2964 -0.1240 0.183 Uiso 1 1 calc R . .
H36B H -0.2681 0.2690 -0.1281 0.183 Uiso 1 1 calc R . .
H36C H -0.1538 0.2187 -0.1503 0.183 Uiso 1 1 calc R . .
O14 O 0.988(4) 0.5273(13) 0.8141(5) 0.374(19) Uani 1 1 d . . .
H14D H 0.9049 0.5511 0.8209 0.449 Uiso 1 1 d R . .
H14A H 0.9814 0.4708 0.8146 0.449 Uiso 1 1 d R . .
O15 O 0.253(7) 0.8457(15) 0.3114(9) 0.64(3) Uani 1 1 d U . .
H15C H 0.2118 0.8834 0.3240 0.773 Uiso 1 1 d R . .
H15B H 0.2681 0.7960 0.3224 0.773 Uiso 1 1 d R . .
O16 O 0.325(4) 0.5486(18) 0.8454(7) 0.359(10) Uani 1 1 d U . .
H16C H 0.2287 0.5431 0.8317 0.431 Uiso 1 1 d R . .
H16B H 0.3249 0.5909 0.8605 0.431 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O8 2.321(6) . ?
Eu1 O4 2.388(5) 2 ?
Eu1 O5 2.412(5) . ?
Eu1 O6 2.419(6) . ?
Eu1 O3 2.470(5) . ?
Eu1 O1 2.500(5) . ?
Eu1 O7 2.501(6) 4_655 ?
Eu1 O2 2.547(6) . ?
Eu1 O4 2.576(5) 4_655 ?
Eu1 C3 2.863(9) . ?
Eu1 C7 2.867(8) . ?
Eu1 C13 2.923(9) 4_655 ?
Eu1 H6B 2.8020 . ?
Eu1 H6C 2.8014 . ?
O1 C7 1.261(10) . ?
O2 C3 1.272(10) . ?
O3 C7 1.268(10) . ?
O4 C13 1.282(9) . ?
O4 Eu1 2.388(5) 2 ?
O4 Eu1 2.576(5) 4_456 ?
O5 C3 1.266(10) . ?
N1 C14 1.316(11) . ?
N1 C16 1.387(10) . ?
N1 H1 0.8600 . ?
O6 H6B 0.8500 . ?
O6 H6C 0.8498 . ?
C1 C18 1.382(12) . ?
C1 C22 1.402(12) . ?
C1 C7 1.483(11) . ?
C2 C5 1.374(11) . ?
C2 C4 1.377(11) . ?
C2 H2 0.9300 . ?
C3 C4 1.477(12) . ?
N2 C17 1.334(11) . ?
N2 C10 1.380(10) . ?
N2 H2A 0.8600 . ?
C4 C25 1.420(12) . ?
N3 C14 1.355(11) . ?
N3 C5 1.390(10) . ?
N4 C17 1.337(12) . ?
N4 C20 1.386(11) . ?
C5 C16 1.390(12) . ?
C6 C30 1.371(11) 3_865 ?
C6 C31 1.389(11) . ?
C6 H6 0.9300 . ?
O7 C13 1.262(11) . ?
O7 Eu1 2.501(6) 4_456 ?
C8 N6 1.390(10) . ?
C8 C11 1.393(13) . ?
C8 C23 1.395(12) . ?
N5 C24 1.315(12) . ?
N5 C11 1.373(11) . ?
N5 H5 0.8600 . ?
N6 C24 1.369(12) . ?
C9 C15 1.364(12) . ?
C9 C11 1.383(12) . ?
C9 H9 0.9300 . ?
C10 C20 1.381(13) . ?
C10 C18 1.383(11) . ?
C12 C32 1.359(13) . ?
C12 C28 1.376(13) . ?
C12 C17 1.492(12) . ?
C13 C15 1.481(12) . ?
C13 Eu1 2.923(9) 4_456 ?
C14 C31 1.462(11) . ?
C15 C21 1.407(13) . ?
C16 C29 1.382(12) . ?
C18 H18 0.9300 . ?
C19 C27 1.374(13) . ?
C19 C28 1.401(12) . ?
C19 H19 0.9300 . ?
C20 C26 1.387(12) . ?
C21 C23 1.383(12) . ?
C21 H21 0.9300 . ?
C22 C26 1.381(12) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 C27 1.494(12) . ?
C25 C29 1.388(12) . ?
C25 H25 0.9300 . ?
C26 H26 0.9300 . ?
C27 C33 1.386(13) . ?
C28 H28 0.9300 . ?
C29 H29 0.9300 . ?
C30 C6 1.371(11) 3_865 ?
C30 C31 1.393(12) . ?
C30 H30 0.9300 . ?
C32 C33 1.366(12) . ?
C32 H32 0.9300 . ?
C33 H33 0.9300 . ?
O8 C34 1.269(13) . ?
C34 N7 1.263(14) . ?
C34 H34 0.9300 . ?
N7 C35 1.405(9) . ?
N7 C36 1.452(18) . ?
O9 H9C 0.8500 . ?
O9 H9D 0.8501 . ?
O10 H10A 0.8499 . ?
O10 H10B 0.8500 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
O11 H11A 0.8500 . ?
O11 H11B 0.8500 . ?
O12 H12A 0.8501 . ?
O12 H12B 0.8500 . ?
O13 H13D 0.8500 . ?
O13 H13B 0.8502 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
O14 H14D 0.8500 . ?
O14 H14A 0.8499 . ?
O15 H15C 0.8498 . ?
O15 H15B 0.8501 . ?
O16 H16C 0.8501 . ?
O16 H16B 0.8498 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Eu1 O4 154.5(2) . 2 ?
O8 Eu1 O5 130.5(2) . . ?
O4 Eu1 O5 73.01(19) 2 . ?
O8 Eu1 O6 79.7(2) . . ?
O4 Eu1 O6 83.24(19) 2 . ?
O5 Eu1 O6 143.9(2) . . ?
O8 Eu1 O3 83.8(2) . . ?
O4 Eu1 O3 90.46(18) 2 . ?
O5 Eu1 O3 83.55(19) . . ?
O6 Eu1 O3 124.25(19) . . ?
O8 Eu1 O1 80.2(2) . . ?
O4 Eu1 O1 76.70(18) 2 . ?
O5 Eu1 O1 125.33(19) . . ?
O6 Eu1 O1 72.60(19) . . ?
O3 Eu1 O1 52.18(18) . . ?
O8 Eu1 O7 78.0(2) . 4_655 ?
O4 Eu1 O7 117.15(19) 2 4_655 ?
O5 Eu1 O7 87.7(2) . 4_655 ?
O6 Eu1 O7 79.3(2) . 4_655 ?
O3 Eu1 O7 147.0(2) . 4_655 ?
O1 Eu1 O7 147.0(2) . 4_655 ?
O8 Eu1 O2 78.1(2) . . ?
O4 Eu1 O2 124.61(18) 2 . ?
O5 Eu1 O2 52.38(19) . . ?
O6 Eu1 O2 147.5(2) . . ?
O3 Eu1 O2 76.34(19) . . ?
O1 Eu1 O2 125.72(19) . . ?
O7 Eu1 O2 73.2(2) 4_655 . ?
O8 Eu1 O4 122.2(2) . 4_655 ?
O4 Eu1 O4 66.4(2) 2 4_655 ?
O5 Eu1 O4 78.57(19) . 4_655 ?
O6 Eu1 O4 66.94(18) . 4_655 ?
O3 Eu1 O4 154.01(18) . 4_655 ?
O1 Eu1 O4 127.23(18) . 4_655 ?
O7 Eu1 O4 51.14(18) 4_655 4_655 ?
O2 Eu1 O4 106.36(18) . 4_655 ?
O8 Eu1 C3 104.5(3) . . ?
O4 Eu1 C3 98.7(2) 2 . ?
O5 Eu1 C3 26.0(2) . . ?
O6 Eu1 C3 156.4(2) . . ?
O3 Eu1 C3 79.3(2) . . ?
O1 Eu1 C3 130.8(2) . . ?
O7 Eu1 C3 79.0(2) 4_655 . ?
O2 Eu1 C3 26.4(2) . . ?
O4 Eu1 C3 92.2(2) 4_655 . ?
O8 Eu1 C7 81.3(2) . . ?
O4 Eu1 C7 82.7(2) 2 . ?
O5 Eu1 C7 104.9(2) . . ?
O6 Eu1 C7 98.4(2) . . ?
O3 Eu1 C7 26.1(2) . . ?
O1 Eu1 C7 26.0(2) . . ?
O7 Eu1 C7 159.3(2) 4_655 . ?
O2 Eu1 C7 101.3(2) . . ?
O4 Eu1 C7 146.6(2) 4_655 . ?
C3 Eu1 C7 105.1(2) . . ?
O8 Eu1 C13 98.8(2) . 4_655 ?
O4 Eu1 C13 92.4(2) 2 4_655 ?
O5 Eu1 C13 85.1(2) . 4_655 ?
O6 Eu1 C13 68.8(2) . 4_655 ?
O3 Eu1 C13 167.0(2) . 4_655 ?
O1 Eu1 C13 140.8(2) . 4_655 ?
O7 Eu1 C13 25.4(2) 4_655 4_655 ?
O2 Eu1 C13 91.6(2) . 4_655 ?
O4 Eu1 C13 26.0(2) 4_655 4_655 ?
C3 Eu1 C13 87.7(2) . 4_655 ?
C7 Eu1 C13 166.8(2) . 4_655 ?
O8 Eu1 H6B 72.0 . . ?
O4 Eu1 H6B 95.7 2 . ?
O5 Eu1 H6B 140.4 . . ?
O6 Eu1 H6B 16.8 . . ?
O3 Eu1 H6B 135.3 . . ?
O1 Eu1 H6B 86.4 . . ?
O7 Eu1 H6B 63.5 4_655 . ?
O2 Eu1 H6B 131.1 . . ?
O4 Eu1 H6B 62.4 4_655 . ?
C3 Eu1 H6B 142.3 . . ?
C7 Eu1 H6B 111.2 . . ?
C13 Eu1 H6B 57.0 4_655 . ?
O8 Eu1 H6C 70.4 . . ?
O4 Eu1 H6C 88.2 2 . ?
O5 Eu1 H6C 158.0 . . ?
O6 Eu1 H6C 16.8 . . ?
O3 Eu1 H6C 108.4 . . ?
O1 Eu1 H6C 58.1 . . ?
O7 Eu1 H6C 91.1 4_655 . ?
O2 Eu1 H6C 147.2 . . ?
O4 Eu1 H6C 83.6 4_655 . ?
C3 Eu1 H6C 169.7 . . ?
C7 Eu1 H6C 83.2 . . ?
C13 Eu1 H6C 84.4 4_655 . ?
H6B Eu1 H6C 28.3 . . ?
C7 O1 Eu1 93.5(5) . . ?
C3 O2 Eu1 90.8(5) . . ?
C7 O3 Eu1 94.7(5) . . ?
C13 O4 Eu1 154.1(6) . 2 ?
C13 O4 Eu1 92.3(5) . 4_456 ?
Eu1 O4 Eu1 113.6(2) 2 4_456 ?
C3 O5 Eu1 97.3(5) . . ?
C14 N1 C16 106.0(7) . . ?
C14 N1 H1 127.0 . . ?
C16 N1 H1 127.0 . . ?
Eu1 O6 H6B 108.1 . . ?
Eu1 O6 H6C 108.0 . . ?
H6B O6 H6C 107.4 . . ?
C18 C1 C22 120.2(8) . . ?
C18 C1 C7 119.8(8) . . ?
C22 C1 C7 120.0(8) . . ?
C5 C2 C4 117.8(8) . . ?
C5 C2 H2 121.1 . . ?
C4 C2 H2 121.1 . . ?
O5 C3 O2 119.5(8) . . ?
O5 C3 C4 119.2(7) . . ?
O2 C3 C4 121.4(8) . . ?
O5 C3 Eu1 56.7(4) . . ?
O2 C3 Eu1 62.8(4) . . ?
C4 C3 Eu1 175.6(6) . . ?
C17 N2 C10 106.3(8) . . ?
C17 N2 H2A 126.9 . . ?
C10 N2 H2A 126.9 . . ?
C2 C4 C25 119.6(8) . . ?
C2 C4 C3 118.9(8) . . ?
C25 C4 C3 121.5(7) . . ?
C14 N3 C5 106.5(7) . . ?
C17 N4 C20 103.3(8) . . ?
C2 C5 N3 130.4(8) . . ?
C2 C5 C16 123.5(8) . . ?
N3 C5 C16 106.0(7) . . ?
C30 C6 C31 119.8(8) 3_865 . ?
C30 C6 H6 120.1 3_865 . ?
C31 C6 H6 120.1 . . ?
O1 C7 O3 119.6(7) . . ?
O1 C7 C1 120.0(7) . . ?
O3 C7 C1 120.4(8) . . ?
O1 C7 Eu1 60.5(4) . . ?
O3 C7 Eu1 59.1(4) . . ?
C1 C7 Eu1 178.6(6) . . ?
C13 O7 Eu1 96.3(5) . 4_456 ?
N6 C8 C11 107.2(8) . . ?
N6 C8 C23 130.4(9) . . ?
C11 C8 C23 122.3(8) . . ?
C24 N5 C11 105.8(8) . . ?
C24 N5 H5 127.1 . . ?
C11 N5 H5 127.1 . . ?
C24 N6 C8 104.5(8) . . ?
C15 C9 C11 118.4(9) . . ?
C15 C9 H9 120.8 . . ?
C11 C9 H9 120.8 . . ?
C20 C10 N2 106.0(8) . . ?
C20 C10 C18 122.3(8) . . ?
N2 C10 C18 131.7(9) . . ?
N5 C11 C9 130.9(10) . . ?
N5 C11 C8 108.8(8) . . ?
C9 C11 C8 120.2(8) . . ?
C32 C12 C28 118.9(8) . . ?
C32 C12 C17 121.5(9) . . ?
C28 C12 C17 119.6(9) . . ?
O7 C13 O4 119.0(8) . . ?
O7 C13 C15 120.1(8) . . ?
O4 C13 C15 120.9(8) . . ?
O7 C13 Eu1 58.3(4) . 4_456 ?
O4 C13 Eu1 61.7(4) . 4_456 ?
C15 C13 Eu1 170.6(6) . 4_456 ?
N1 C14 N3 112.6(7) . . ?
N1 C14 C31 126.6(8) . . ?
N3 C14 C31 120.6(8) . . ?
C9 C15 C21 121.2(8) . . ?
C9 C15 C13 118.4(8) . . ?
C21 C15 C13 120.3(8) . . ?
C29 C16 N1 131.7(8) . . ?
C29 C16 C5 119.4(8) . . ?
N1 C16 C5 108.8(7) . . ?
N2 C17 N4 114.2(7) . . ?
N2 C17 C12 123.7(9) . . ?
N4 C17 C12 122.1(9) . . ?
C10 C18 C1 117.8(9) . . ?
C10 C18 H18 121.1 . . ?
C1 C18 H18 121.1 . . ?
C27 C19 C28 120.5(9) . . ?
C27 C19 H19 119.7 . . ?
C28 C19 H19 119.7 . . ?
C10 C20 C26 120.2(8) . . ?
C10 C20 N4 110.3(8) . . ?
C26 C20 N4 129.5(9) . . ?
C23 C21 C15 121.5(8) . . ?
C23 C21 H21 119.3 . . ?
C15 C21 H21 119.3 . . ?
C26 C22 C1 121.4(8) . . ?
C26 C22 H22 119.3 . . ?
C1 C22 H22 119.3 . . ?
C21 C23 C8 116.2(9) . . ?
C21 C23 H23 121.9 . . ?
C8 C23 H23 121.9 . . ?
N5 C24 N6 113.7(8) . . ?
N5 C24 C27 123.8(9) . . ?
N6 C24 C27 122.5(9) . . ?
C29 C25 C4 121.7(8) . . ?
C29 C25 H25 119.2 . . ?
C4 C25 H25 119.2 . . ?
C22 C26 C20 118.1(9) . . ?
C22 C26 H26 120.9 . . ?
C20 C26 H26 120.9 . . ?
C19 C27 C33 119.1(8) . . ?
C19 C27 C24 118.6(9) . . ?
C33 C27 C24 122.3(9) . . ?
C12 C28 C19 119.5(9) . . ?
C12 C28 H28 120.2 . . ?
C19 C28 H28 120.2 . . ?
C16 C29 C25 118.0(8) . . ?
C16 C29 H29 121.0 . . ?
C25 C29 H29 121.0 . . ?
C6 C30 C31 121.8(8) 3_865 . ?
C6 C30 H30 119.1 3_865 . ?
C31 C30 H30 119.1 . . ?
C6 C31 C30 118.4(8) . . ?
C6 C31 C14 120.4(8) . . ?
C30 C31 C14 121.1(8) . . ?
C12 C32 C33 122.6(10) . . ?
C12 C32 H32 118.7 . . ?
C33 C32 H32 118.7 . . ?
C32 C33 C27 119.3(10) . . ?
C32 C33 H33 120.4 . . ?
C27 C33 H33 120.4 . . ?
C34 O8 Eu1 130.0(7) . . ?
O8 C34 N7 120.4(13) . . ?
O8 C34 H34 119.8 . . ?
N7 C34 H34 119.8 . . ?
C34 N7 C35 123.8(13) . . ?
C34 N7 C36 120.8(13) . . ?
C35 N7 C36 115.2(12) . . ?
H9C O9 H9D 108.3 . . ?
H10A O10 H10B 104.1 . . ?
N7 C35 H35A 109.5 . . ?
N7 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
N7 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
H11A O11 H11B 107.1 . . ?
H12A O12 H12B 109.0 . . ?
H13D O13 H13B 110.5 . . ?
N7 C36 H36A 109.5 . . ?
N7 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
N7 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
H14D O14 H14A 110.9 . . ?
H15C O15 H15B 110.2 . . ?
H16C O16 H16B 110.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O8 Eu1 O1 C7 -90.2(5) . . . . ?
O4 Eu1 O1 C7 100.7(5) 2 . . . ?
O5 Eu1 O1 C7 43.1(5) . . . . ?
O6 Eu1 O1 C7 -172.3(5) . . . . ?
O3 Eu1 O1 C7 -0.5(5) . . . . ?
O7 Eu1 O1 C7 -139.5(5) 4_655 . . . ?
O2 Eu1 O1 C7 -22.6(5) . . . . ?
O4 Eu1 O1 C7 146.6(5) 4_655 . . . ?
C3 Eu1 O1 C7 10.6(6) . . . . ?
C13 Eu1 O1 C7 177.8(5) 4_655 . . . ?
O8 Eu1 O2 C3 179.8(5) . . . . ?
O4 Eu1 O2 C3 12.5(6) 2 . . . ?
O5 Eu1 O2 C3 1.1(5) . . . . ?
O6 Eu1 O2 C3 -132.4(5) . . . . ?
O3 Eu1 O2 C3 93.4(5) . . . . ?
O1 Eu1 O2 C3 111.3(5) . . . . ?
O7 Eu1 O2 C3 -99.2(5) 4_655 . . . ?
O4 Eu1 O2 C3 -59.8(5) 4_655 . . . ?
C7 Eu1 O2 C3 101.3(5) . . . . ?
C13 Eu1 O2 C3 -81.5(5) 4_655 . . . ?
O8 Eu1 O3 C7 82.9(5) . . . . ?
O4 Eu1 O3 C7 -72.2(5) 2 . . . ?
O5 Eu1 O3 C7 -145.0(5) . . . . ?
O6 Eu1 O3 C7 9.9(6) . . . . ?
O1 Eu1 O3 C7 0.5(5) . . . . ?
O7 Eu1 O3 C7 139.4(5) 4_655 . . . ?
O2 Eu1 O3 C7 162.2(5) . . . . ?
O4 Eu1 O3 C7 -98.4(6) 4_655 . . . ?
C3 Eu1 O3 C7 -171.0(5) . . . . ?
C13 Eu1 O3 C7 -174.9(9) 4_655 . . . ?
O8 Eu1 O5 C3 -2.7(6) . . . . ?
O4 Eu1 O5 C3 -171.3(5) 2 . . . ?
O6 Eu1 O5 C3 137.6(5) . . . . ?
O3 Eu1 O5 C3 -78.8(5) . . . . ?
O1 Eu1 O5 C3 -112.0(5) . . . . ?
O7 Eu1 O5 C3 69.4(5) 4_655 . . . ?
O2 Eu1 O5 C3 -1.1(5) . . . . ?
O4 Eu1 O5 C3 120.2(5) 4_655 . . . ?
C7 Eu1 O5 C3 -93.9(5) . . . . ?
C13 Eu1 O5 C3 94.7(5) 4_655 . . . ?
Eu1 O5 C3 O2 2.0(9) . . . . ?
Eu1 O5 C3 C4 -178.3(7) . . . . ?
Eu1 O2 C3 O5 -1.9(8) . . . . ?
Eu1 O2 C3 C4 178.5(7) . . . . ?
O8 Eu1 C3 O5 177.9(5) . . . . ?
O4 Eu1 C3 O5 8.5(5) 2 . . . ?
O6 Eu1 C3 O5 -84.7(7) . . . . ?
O3 Eu1 C3 O5 97.3(5) . . . . ?
O1 Eu1 C3 O5 88.4(5) . . . . ?
O7 Eu1 C3 O5 -107.7(5) 4_655 . . . ?
O2 Eu1 C3 O5 178.1(8) . . . . ?
O4 Eu1 C3 O5 -58.0(5) 4_655 . . . ?
C7 Eu1 C3 O5 93.2(5) . . . . ?
C13 Eu1 C3 O5 -83.6(5) 4_655 . . . ?
O8 Eu1 C3 O2 -0.2(5) . . . . ?
O4 Eu1 C3 O2 -169.6(5) 2 . . . ?
O5 Eu1 C3 O2 -178.1(8) . . . . ?
O6 Eu1 C3 O2 97.2(7) . . . . ?
O3 Eu1 C3 O2 -80.8(5) . . . . ?
O1 Eu1 C3 O2 -89.7(5) . . . . ?
O7 Eu1 C3 O2 74.3(5) 4_655 . . . ?
O4 Eu1 C3 O2 123.9(5) 4_655 . . . ?
C7 Eu1 C3 O2 -84.9(5) . . . . ?
C13 Eu1 C3 O2 98.3(5) 4_655 . . . ?
O8 Eu1 C3 C4 -163(8) . . . . ?
O4 Eu1 C3 C4 28(8) 2 . . . ?
O5 Eu1 C3 C4 19(8) . . . . ?
O6 Eu1 C3 C4 -65(8) . . . . ?
O3 Eu1 C3 C4 116(8) . . . . ?
O1 Eu1 C3 C4 108(8) . . . . ?
O7 Eu1 C3 C4 -88(8) 4_655 . . . ?
O2 Eu1 C3 C4 -163(8) . . . . ?
O4 Eu1 C3 C4 -39(8) 4_655 . . . ?
C7 Eu1 C3 C4 112(8) . . . . ?
C13 Eu1 C3 C4 -64(8) 4_655 . . . ?
C5 C2 C4 C25 0.0(13) . . . . ?
C5 C2 C4 C3 -178.9(8) . . . . ?
O5 C3 C4 C2 -3.1(13) . . . . ?
O2 C3 C4 C2 176.6(8) . . . . ?
Eu1 C3 C4 C2 -21(9) . . . . ?
O5 C3 C4 C25 178.0(8) . . . . ?
O2 C3 C4 C25 -2.3(13) . . . . ?
Eu1 C3 C4 C25 160(8) . . . . ?
C4 C2 C5 N3 179.8(9) . . . . ?
C4 C2 C5 C16 1.4(14) . . . . ?
C14 N3 C5 C2 -178.7(9) . . . . ?
C14 N3 C5 C16 -0.1(10) . . . . ?
Eu1 O1 C7 O3 0.9(8) . . . . ?
Eu1 O1 C7 C1 -178.5(7) . . . . ?
Eu1 O3 C7 O1 -0.9(8) . . . . ?
Eu1 O3 C7 C1 178.5(7) . . . . ?
C18 C1 C7 O1 15.8(13) . . . . ?
C22 C1 C7 O1 -165.3(8) . . . . ?
C18 C1 C7 O3 -163.6(8) . . . . ?
C22 C1 C7 O3 15.3(13) . . . . ?
C18 C1 C7 Eu1 -94(26) . . . . ?
C22 C1 C7 Eu1 85(26) . . . . ?
O8 Eu1 C7 O1 85.5(5) . . . . ?
O4 Eu1 C7 O1 -74.6(5) 2 . . . ?
O5 Eu1 C7 O1 -144.8(5) . . . . ?
O6 Eu1 C7 O1 7.4(5) . . . . ?
O3 Eu1 C7 O1 179.1(8) . . . . ?
O7 Eu1 C7 O1 89.3(8) 4_655 . . . ?
O2 Eu1 C7 O1 161.4(4) . . . . ?
O4 Eu1 C7 O1 -52.9(7) 4_655 . . . ?
C3 Eu1 C7 O1 -171.7(5) . . . . ?
C13 Eu1 C7 O1 -6.0(13) 4_655 . . . ?
O8 Eu1 C7 O3 -93.6(5) . . . . ?
O4 Eu1 C7 O3 106.3(5) 2 . . . ?
O5 Eu1 C7 O3 36.1(5) . . . . ?
O6 Eu1 C7 O3 -171.7(5) . . . . ?
O1 Eu1 C7 O3 -179.1(8) . . . . ?
O7 Eu1 C7 O3 -89.8(8) 4_655 . . . ?
O2 Eu1 C7 O3 -17.7(5) . . . . ?
O4 Eu1 C7 O3 128.0(5) 4_655 . . . ?
C3 Eu1 C7 O3 9.2(5) . . . . ?
C13 Eu1 C7 O3 174.9(9) 4_655 . . . ?
O8 Eu1 C7 C1 -164(26) . . . . ?
O4 Eu1 C7 C1 36(26) 2 . . . ?
O5 Eu1 C7 C1 -34(26) . . . . ?
O6 Eu1 C7 C1 118(26) . . . . ?
O3 Eu1 C7 C1 -70(26) . . . . ?
O1 Eu1 C7 C1 111(26) . . . . ?
O7 Eu1 C7 C1 -160(26) 4_655 . . . ?
O2 Eu1 C7 C1 -88(26) . . . . ?
O4 Eu1 C7 C1 58(26) 4_655 . . . ?
C3 Eu1 C7 C1 -61(26) . . . . ?
C13 Eu1 C7 C1 105(26) 4_655 . . . ?
C11 C8 N6 C24 0.3(10) . . . . ?
C23 C8 N6 C24 178.1(9) . . . . ?
C17 N2 C10 C20 1.3(10) . . . . ?
C17 N2 C10 C18 178.8(10) . . . . ?
C24 N5 C11 C9 -179.5(10) . . . . ?
C24 N5 C11 C8 0.5(10) . . . . ?
C15 C9 C11 N5 175.6(9) . . . . ?
C15 C9 C11 C8 -4.4(13) . . . . ?
N6 C8 C11 N5 -0.5(10) . . . . ?
C23 C8 C11 N5 -178.5(8) . . . . ?
N6 C8 C11 C9 179.5(8) . . . . ?
C23 C8 C11 C9 1.4(14) . . . . ?
Eu1 O7 C13 O4 11.4(8) 4_456 . . . ?
Eu1 O7 C13 C15 -169.2(7) 4_456 . . . ?
Eu1 O4 C13 O7 166.4(8) 2 . . . ?
Eu1 O4 C13 O7 -11.0(8) 4_456 . . . ?
Eu1 O4 C13 C15 -13.0(18) 2 . . . ?
Eu1 O4 C13 C15 169.6(7) 4_456 . . . ?
Eu1 O4 C13 Eu1 177.5(13) 2 . . 4_456 ?
C16 N1 C14 N3 -0.1(10) . . . . ?
C16 N1 C14 C31 -174.8(9) . . . . ?
C5 N3 C14 N1 0.1(10) . . . . ?
C5 N3 C14 C31 175.2(8) . . . . ?
C11 C9 C15 C21 4.1(13) . . . . ?
C11 C9 C15 C13 -172.9(8) . . . . ?
O7 C13 C15 C9 -46.2(12) . . . . ?
O4 C13 C15 C9 133.2(9) . . . . ?
Eu1 C13 C15 C9 -123(4) 4_456 . . . ?
O7 C13 C15 C21 136.8(9) . . . . ?
O4 C13 C15 C21 -43.9(12) . . . . ?
Eu1 C13 C15 C21 59(4) 4_456 . . . ?
C14 N1 C16 C29 -179.1(10) . . . . ?
C14 N1 C16 C5 0.0(10) . . . . ?
C2 C5 C16 C29 -2.0(14) . . . . ?
N3 C5 C16 C29 179.3(8) . . . . ?
C2 C5 C16 N1 178.7(8) . . . . ?
N3 C5 C16 N1 0.0(10) . . . . ?
C10 N2 C17 N4 -0.9(11) . . . . ?
C10 N2 C17 C12 -179.6(8) . . . . ?
C20 N4 C17 N2 0.2(10) . . . . ?
C20 N4 C17 C12 178.9(8) . . . . ?
C32 C12 C17 N2 -179.6(9) . . . . ?
C28 C12 C17 N2 0.1(14) . . . . ?
C32 C12 C17 N4 1.8(14) . . . . ?
C28 C12 C17 N4 -178.5(9) . . . . ?
C20 C10 C18 C1 0.9(14) . . . . ?
N2 C10 C18 C1 -176.3(9) . . . . ?
C22 C1 C18 C10 -1.1(13) . . . . ?
C7 C1 C18 C10 177.8(8) . . . . ?
N2 C10 C20 C26 178.2(8) . . . . ?
C18 C10 C20 C26 0.4(14) . . . . ?
N2 C10 C20 N4 -1.2(10) . . . . ?
C18 C10 C20 N4 -179.0(8) . . . . ?
C17 N4 C20 C10 0.6(10) . . . . ?
C17 N4 C20 C26 -178.7(10) . . . . ?
C9 C15 C21 C23 -0.8(14) . . . . ?
C13 C15 C21 C23 176.1(8) . . . . ?
C18 C1 C22 C26 -0.1(14) . . . . ?
C7 C1 C22 C26 -179.0(8) . . . . ?
C15 C21 C23 C8 -2.1(13) . . . . ?
N6 C8 C23 C21 -175.7(9) . . . . ?
C11 C8 C23 C21 1.8(13) . . . . ?
C11 N5 C24 N6 -0.3(11) . . . . ?
C11 N5 C24 C27 179.2(9) . . . . ?
C8 N6 C24 N5 0.0(10) . . . . ?
C8 N6 C24 C27 -179.5(8) . . . . ?
C2 C4 C25 C29 -0.9(14) . . . . ?
C3 C4 C25 C29 178.0(8) . . . . ?
C1 C22 C26 C20 1.4(14) . . . . ?
C10 C20 C26 C22 -1.5(14) . . . . ?
N4 C20 C26 C22 177.8(9) . . . . ?
C28 C19 C27 C33 -1.4(14) . . . . ?
C28 C19 C27 C24 178.7(9) . . . . ?
N5 C24 C27 C19 0.7(14) . . . . ?
N6 C24 C27 C19 -179.8(9) . . . . ?
N5 C24 C27 C33 -179.2(9) . . . . ?
N6 C24 C27 C33 0.3(15) . . . . ?
C32 C12 C28 C19 -1.0(14) . . . . ?
C17 C12 C28 C19 179.3(9) . . . . ?
C27 C19 C28 C12 1.0(15) . . . . ?
N1 C16 C29 C25 -179.9(9) . . . . ?
C5 C16 C29 C25 1.1(14) . . . . ?
C4 C25 C29 C16 0.3(14) . . . . ?
C30 C6 C31 C30 -0.4(14) 3_865 . . . ?
C30 C6 C31 C14 179.3(8) 3_865 . . . ?
C6 C30 C31 C6 0.5(15) 3_865 . . . ?
C6 C30 C31 C14 -179.3(8) 3_865 . . . ?
N1 C14 C31 C6 -3.5(14) . . . . ?
N3 C14 C31 C6 -177.9(8) . . . . ?
N1 C14 C31 C30 176.2(9) . . . . ?
N3 C14 C31 C30 1.8(13) . . . . ?
C28 C12 C32 C33 1.4(15) . . . . ?
C17 C12 C32 C33 -178.9(9) . . . . ?
C12 C32 C33 C27 -1.7(15) . . . . ?
C19 C27 C33 C32 1.7(14) . . . . ?
C24 C27 C33 C32 -178.4(9) . . . . ?
O4 Eu1 O8 C34 171.4(8) 2 . . . ?
O5 Eu1 O8 C34 17.5(11) . . . . ?
O6 Eu1 O8 C34 -139.9(10) . . . . ?
O3 Eu1 O8 C34 93.5(10) . . . . ?
O1 Eu1 O8 C34 146.1(10) . . . . ?
O7 Eu1 O8 C34 -58.8(9) 4_655 . . . ?
O2 Eu1 O8 C34 16.2(9) . . . . ?
O4 Eu1 O8 C34 -85.8(10) 4_655 . . . ?
C3 Eu1 O8 C34 16.3(10) . . . . ?
C7 Eu1 O8 C34 119.8(10) . . . . ?
C13 Eu1 O8 C34 -73.6(10) 4_655 . . . ?
Eu1 O8 C34 N7 153.6(9) . . . . ?
O8 C34 N7 C35 4(2) . . . . ?
O8 C34 N7 C36 177.8(13) . . . . ?

_diffrn_measured_fraction_theta_max 0.976
_diffrn_reflns_theta_full        25.02
_diffrn_measured_fraction_theta_full 0.976
_refine_diff_density_max         1.619
_refine_diff_density_min         -1.280
_refine_diff_density_rms         0.158
