# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1487109'
_audit_update_record             
;
2016-06-22 deposited with the CCDC.
2016-11-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C26 H22 Ag N3 O5'
_chemical_formula_sum            'C26 H22 Ag N3 O5'
_chemical_formula_weight         564.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C2/c '
_symmetry_space_group_name_HALL  '-C 2yc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   27.7874(10)
_cell_length_b                   11.7457(7)
_cell_length_c                   17.5147(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 129.073(2)
_cell_angle_gamma                90.00
_cell_volume                     4438.0(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9928
_cell_measurement_theta_min      2.8153
_cell_measurement_theta_max      28.2837

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.19
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.689
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2288
_exptl_absorpt_coefficient_mu    0.954
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8247
_exptl_absorpt_correction_T_max  0.8395
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  bruker-CCD
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            11329
_diffrn_reflns_av_R_equivalents  0.0422
_diffrn_reflns_av_sigmaI/netI    0.0488
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.97
_diffrn_reflns_theta_max         25.01
_reflns_number_total             2903
_reflns_number_gt                2735
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0097P)²+741.3509P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         2903
_refine_ls_number_parameters     316
_refine_ls_number_restraints     24
_refine_ls_R_factor_all          0.1190
_refine_ls_R_factor_gt           0.1167
_refine_ls_wR_factor_ref         0.2873
_refine_ls_wR_factor_gt          0.2863
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.054
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.22588(4) 0.35294(7) 0.42992(6) 0.0192(2) Uani 1 1 d . . .
O1 O 0.0650(3) 0.2092(6) -0.2360(5) 0.0142(17) Uani 1 1 d . . .
O2 O 0.0681(3) 0.1824(7) -0.0342(5) 0.020(2) Uani 1 1 d . . .
O3 O 0.4016(4) 0.3538(9) 0.4878(7) 0.040(3) Uani 1 1 d . . .
O4 O 0.3019(4) 0.3798(9) 0.3923(6) 0.036(3) Uani 1 1 d . . .
O5 O 0.3441(4) 0.2521(8) 0.5077(5) 0.0275(7) Uani 1 1 d U . .
C1 C 0.2490(5) -0.0430(11) -0.1135(8) 0.025(3) Uani 1 1 d . . .
H1A H 0.2877 -0.0748 -0.0842 0.030 Uiso 1 1 calc R . .
C2 C 0.2210(4) 0.0230(9) -0.1975(6) 0.014(2) Uani 1 1 d . . .
H2A H 0.2419 0.0388 -0.2217 0.016 Uiso 1 1 calc R . .
C3 C 0.1618(5) 0.0652(10) -0.2452(7) 0.025(3) Uani 1 1 d . . .
H3A H 0.1417 0.1054 -0.3037 0.030 Uiso 1 1 calc R . .
C4 C 0.1323(4) 0.0460(9) -0.2029(7) 0.018(3) Uani 1 1 d . . .
C5 C 0.1642(5) -0.0157(10) -0.1193(8) 0.021(3) Uani 1 1 d . . .
H5A H 0.1454 -0.0273 -0.0910 0.025 Uiso 1 1 calc R . .
C6 C 0.0680(5) 0.0929(11) -0.2518(9) 0.027(3) Uani 1 1 d . . .
H6A H 0.0428 0.0802 -0.3221 0.033 Uiso 1 1 calc R . .
H6B H 0.0498 0.0497 -0.2286 0.033 Uiso 1 1 calc R . .
C7 C 0.1080(4) 0.2815(9) -0.2277(7) 0.015(2) Uani 1 1 d . . .
C8 C 0.1009(4) 0.3210(9) -0.3073(7) 0.013(2) Uani 1 1 d U . .
C9 C 0.1476(5) 0.3845(10) -0.2948(8) 0.022(3) Uani 1 1 d . . .
H9A H 0.1430 0.4104 -0.3492 0.027 Uiso 1 1 calc R . .
C10 C 0.2016(5) 0.4094(10) -0.1995(8) 0.025(3) Uani 1 1 d . . .
H10A H 0.2342 0.4479 -0.1902 0.030 Uiso 1 1 calc R . .
C11 C 0.2060(5) 0.3764(10) -0.1202(9) 0.023(3) Uani 1 1 d . . .
H11A H 0.2408 0.3964 -0.0570 0.028 Uiso 1 1 calc R . .
C12 C 0.1588(4) 0.3130(9) -0.1334(7) 0.014(2) Uani 1 1 d . . .
C13 C 0.0411(5) 0.2987(10) -0.4112(7) 0.018(3) Uani 1 1 d . . .
H13A H 0.0340 0.2173 -0.4222 0.022 Uiso 1 1 calc R . .
H13B H 0.0447 0.3291 -0.4590 0.022 Uiso 1 1 calc R . .
C14 C 0.1589(5) 0.2845(10) -0.0468(7) 0.018(3) Uani 1 1 d . . .
H14A H 0.1525 0.2035 -0.0461 0.021 Uiso 1 1 calc R . .
H14B H 0.1988 0.3045 0.0150 0.021 Uiso 1 1 calc R . .
C15 C 0.1086(4) 0.3494(10) -0.0579(7) 0.017(3) Uani 1 1 d . . .
C16 C 0.1022(5) 0.4667(10) -0.0732(7) 0.019(3) Uani 1 1 d . . .
H16A H 0.1316 0.5047 -0.0731 0.023 Uiso 1 1 calc R . .
C17 C 0.0555(5) 0.5295(10) -0.0882(8) 0.025(3) Uani 1 1 d . . .
H17A H 0.0543 0.6079 -0.0965 0.030 Uiso 1 1 calc R . .
C18 C 0.0097(4) 0.4758(9) -0.0912(7) 0.016(2) Uani 1 1 d . . .
H18A H -0.0229 0.5172 -0.1030 0.020 Uiso 1 1 calc R . .
C19 C 0.0139(5) 0.3561(10) -0.0757(8) 0.022(3) Uani 1 1 d . . .
C20 C 0.0638(5) 0.2960(10) -0.0529(7) 0.016(3) Uani 1 1 d . . .
C21 C 0.1184(5) 0.1529(11) 0.0671(7) 0.022(3) Uani 1 1 d . . .
H21A H 0.1565 0.1871 0.0865 0.026 Uiso 1 1 calc R . .
H21B H 0.1239 0.0710 0.0724 0.026 Uiso 1 1 calc R . .
C22 C 0.1518(4) 0.2550(9) 0.2191(6) 0.014(2) Uani 1 1 d . . .
H22A H 0.1874 0.2758 0.2281 0.017 Uiso 1 1 calc R . .
C23 C 0.1069(5) 0.1922(10) 0.1354(7) 0.021(3) Uani 1 1 d . . .
C24 C 0.0523(5) 0.1728(10) 0.1195(7) 0.021(3) Uani 1 1 d . . .
H24A H 0.0202 0.1345 0.0630 0.025 Uiso 1 1 calc R . .
C25 C 0.0442(5) 0.2095(10) 0.1865(7) 0.020(3) Uani 1 1 d . . .
H25A H 0.0071 0.1967 0.1751 0.024 Uiso 1 1 calc R . .
C26 C 0.0925(5) 0.2653(11) 0.2697(8) 0.023(3) Uani 1 1 d . . .
H26A H 0.0877 0.2887 0.3153 0.028 Uiso 1 1 calc R . .
N1 N 0.2206(4) -0.0621(8) -0.0730(5) 0.0134(19) Uani 1 1 d U . .
N2 N 0.1468(4) 0.2875(8) 0.2882(6) 0.020(2) Uani 1 1 d . . .
N3 N 0.3503(4) 0.3277(8) 0.4623(6) 0.019(2) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.169(8) . ?
Ag1 N1 2.189(8) 4 ?
Ag1 O4 2.597(11) . ?
Ag1 Ag1 3.0859(17) 7_556 ?
O1 C7 1.396(14) . ?
O1 C6 1.406(15) . ?
O2 C20 1.360(14) . ?
O2 C21 1.447(11) . ?
O3 N3 1.234(14) . ?
O4 N3 1.268(11) . ?
O5 N3 1.274(14) . ?
C1 N1 1.371(18) . ?
C1 C2 1.387(15) . ?
C1 H1A 0.9300 . ?
C2 C3 1.383(16) . ?
C2 H2A 0.9300 . ?
C3 C4 1.43(2) . ?
C3 H3A 0.9300 . ?
C4 C5 1.348(16) . ?
C4 C6 1.516(16) . ?
C5 N1 1.345(14) . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.361(16) . ?
C7 C12 1.385(13) . ?
C8 C9 1.388(16) . ?
C8 C13 1.526(12) . ?
C9 C10 1.402(14) . ?
C9 H9A 0.9300 . ?
C10 C11 1.37(2) . ?
C10 H10A 0.9300 . ?
C11 C12 1.396(17) . ?
C11 H11A 0.9300 . ?
C12 C14 1.550(17) . ?
C13 C19 1.551(17) 2_554 ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C15 1.494(17) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C16 1.393(16) . ?
C15 C20 1.447(17) . ?
C16 C17 1.365(18) . ?
C16 H16A 0.9300 . ?
C17 C18 1.392(18) . ?
C17 H17A 0.9300 . ?
C18 C19 1.422(16) . ?
C18 H18A 0.9300 . ?
C19 C20 1.371(17) . ?
C19 C13 1.551(17) 2_554 ?
C21 C23 1.494(18) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 N2 1.358(16) . ?
C22 C23 1.394(14) . ?
C22 H22A 0.9300 . ?
C23 C24 1.378(18) . ?
C24 C25 1.395(19) . ?
C24 H24A 0.9300 . ?
C25 C26 1.375(14) . ?
C25 H25A 0.9300 . ?
C26 N2 1.355(17) . ?
C26 H26A 0.9300 . ?
N1 Ag1 2.189(8) 4_545 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N1 159.9(4) . 4 ?
N2 Ag1 O4 98.7(4) . . ?
N1 Ag1 O4 99.3(3) 4 . ?
N2 Ag1 Ag1 104.6(3) . 7_556 ?
N1 Ag1 Ag1 78.8(2) 4 7_556 ?
O4 Ag1 Ag1 106.4(2) . 7_556 ?
C7 O1 C6 117.2(9) . . ?
C20 O2 C21 113.6(8) . . ?
N3 O4 Ag1 103.4(8) . . ?
N1 C1 C2 121.2(11) . . ?
N1 C1 H1A 119.4 . . ?
C2 C1 H1A 119.4 . . ?
C3 C2 C1 120.0(12) . . ?
C3 C2 H2A 120.0 . . ?
C1 C2 H2A 120.0 . . ?
C2 C3 C4 118.9(10) . . ?
C2 C3 H3A 120.6 . . ?
C4 C3 H3A 120.6 . . ?
C5 C4 C3 116.6(10) . . ?
C5 C4 C6 122.9(13) . . ?
C3 C4 C6 120.4(10) . . ?
N1 C5 C4 126.3(13) . . ?
N1 C5 H5A 116.9 . . ?
C4 C5 H5A 116.9 . . ?
O1 C6 C4 115.9(9) . . ?
O1 C6 H6A 108.3 . . ?
C4 C6 H6A 108.3 . . ?
O1 C6 H6B 108.3 . . ?
C4 C6 H6B 108.3 . . ?
H6A C6 H6B 107.4 . . ?
C8 C7 C12 120.8(11) . . ?
C8 C7 O1 122.6(8) . . ?
C12 C7 O1 116.6(10) . . ?
C7 C8 C9 120.2(8) . . ?
C7 C8 C13 120.6(10) . . ?
C9 C8 C13 119.2(10) . . ?
C8 C9 C10 119.5(11) . . ?
C8 C9 H9A 120.2 . . ?
C10 C9 H9A 120.2 . . ?
C11 C10 C9 119.5(12) . . ?
C11 C10 H10A 120.3 . . ?
C9 C10 H10A 120.3 . . ?
C10 C11 C12 120.5(10) . . ?
C10 C11 H11A 119.7 . . ?
C12 C11 H11A 119.7 . . ?
C7 C12 C11 119.0(11) . . ?
C7 C12 C14 118.8(10) . . ?
C11 C12 C14 122.0(9) . . ?
C8 C13 C19 109.4(9) . 2_554 ?
C8 C13 H13A 109.8 . . ?
C19 C13 H13A 109.8 2_554 . ?
C8 C13 H13B 109.8 . . ?
C19 C13 H13B 109.8 2_554 . ?
H13A C13 H13B 108.2 . . ?
C15 C14 C12 109.7(8) . . ?
C15 C14 H14A 109.7 . . ?
C12 C14 H14A 109.7 . . ?
C15 C14 H14B 109.7 . . ?
C12 C14 H14B 109.7 . . ?
H14A C14 H14B 108.2 . . ?
C16 C15 C20 115.4(11) . . ?
C16 C15 C14 121.7(12) . . ?
C20 C15 C14 122.8(10) . . ?
C17 C16 C15 124.2(12) . . ?
C17 C16 H16A 117.9 . . ?
C15 C16 H16A 117.9 . . ?
C16 C17 C18 119.8(11) . . ?
C16 C17 H17A 120.1 . . ?
C18 C17 H17A 120.1 . . ?
C17 C18 C19 118.5(11) . . ?
C17 C18 H18A 120.7 . . ?
C19 C18 H18A 120.7 . . ?
C20 C19 C18 120.7(12) . . ?
C20 C19 C13 122.7(10) . 2_554 ?
C18 C19 C13 116.6(10) . 2_554 ?
O2 C20 C19 119.7(11) . . ?
O2 C20 C15 119.4(10) . . ?
C19 C20 C15 120.6(10) . . ?
O2 C21 C23 112.3(10) . . ?
O2 C21 H21A 109.1 . . ?
C23 C21 H21A 109.1 . . ?
O2 C21 H21B 109.1 . . ?
C23 C21 H21B 109.1 . . ?
H21A C21 H21B 107.9 . . ?
N2 C22 C23 124.0(11) . . ?
N2 C22 H22A 118.0 . . ?
C23 C22 H22A 118.0 . . ?
C24 C23 C22 116.2(12) . . ?
C24 C23 C21 123.5(10) . . ?
C22 C23 C21 120.2(11) . . ?
C23 C24 C25 121.3(10) . . ?
C23 C24 H24A 119.3 . . ?
C25 C24 H24A 119.3 . . ?
C26 C25 C24 118.2(12) . . ?
C26 C25 H25A 120.9 . . ?
C24 C25 H25A 120.9 . . ?
N2 C26 C25 122.8(13) . . ?
N2 C26 H26A 118.6 . . ?
C25 C26 H26A 118.6 . . ?
C5 N1 C1 116.9(9) . . ?
C5 N1 Ag1 124.6(9) . 4_545 ?
C1 N1 Ag1 118.0(6) . 4_545 ?
C26 N2 C22 117.2(9) . . ?
C26 N2 Ag1 120.9(8) . . ?
C22 N2 Ag1 121.4(7) . . ?
O3 N3 O4 120.7(10) . . ?
O3 N3 O5 121.8(9) . . ?
O4 N3 O5 117.5(10) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Ag1 O4 N3 -128.0(7) . . . . ?
N1 Ag1 O4 N3 61.0(7) 4 . . . ?
Ag1 Ag1 O4 N3 -20.0(7) 7_556 . . . ?
N1 C1 C2 C3 -3.9(16) . . . . ?
C1 C2 C3 C4 4.1(15) . . . . ?
C2 C3 C4 C5 -1.7(15) . . . . ?
C2 C3 C4 C6 178.7(10) . . . . ?
C3 C4 C5 N1 -1.1(17) . . . . ?
C6 C4 C5 N1 178.5(11) . . . . ?
C7 O1 C6 C4 33.9(15) . . . . ?
C5 C4 C6 O1 101.5(14) . . . . ?
C3 C4 C6 O1 -79.0(15) . . . . ?
C6 O1 C7 C8 80.1(12) . . . . ?
C6 O1 C7 C12 -100.7(12) . . . . ?
C12 C7 C8 C9 6.4(17) . . . . ?
O1 C7 C8 C9 -174.4(10) . . . . ?
C12 C7 C8 C13 -172.0(10) . . . . ?
O1 C7 C8 C13 7.1(17) . . . . ?
C7 C8 C9 C10 -1.1(18) . . . . ?
C13 C8 C9 C10 177.4(11) . . . . ?
C8 C9 C10 C11 -3.9(18) . . . . ?
C9 C10 C11 C12 3.6(18) . . . . ?
C8 C7 C12 C11 -6.7(16) . . . . ?
O1 C7 C12 C11 174.1(10) . . . . ?
C8 C7 C12 C14 168.8(10) . . . . ?
O1 C7 C12 C14 -10.4(14) . . . . ?
C10 C11 C12 C7 1.6(17) . . . . ?
C10 C11 C12 C14 -173.8(11) . . . . ?
C7 C8 C13 C19 62.3(14) . . . 2_554 ?
C9 C8 C13 C19 -116.2(12) . . . 2_554 ?
C7 C12 C14 C15 -65.1(12) . . . . ?
C11 C12 C14 C15 110.3(11) . . . . ?
C12 C14 C15 C16 -51.5(12) . . . . ?
C12 C14 C15 C20 129.1(10) . . . . ?
C20 C15 C16 C17 -3.6(15) . . . . ?
C14 C15 C16 C17 176.9(10) . . . . ?
C15 C16 C17 C18 -1.4(17) . . . . ?
C16 C17 C18 C19 1.6(16) . . . . ?
C17 C18 C19 C20 3.6(16) . . . . ?
C17 C18 C19 C13 -174.8(10) . . . 2_554 ?
C21 O2 C20 C19 -112.1(12) . . . . ?
C21 O2 C20 C15 74.0(13) . . . . ?
C18 C19 C20 O2 177.2(9) . . . . ?
C13 C19 C20 O2 -4.5(16) 2_554 . . . ?
C18 C19 C20 C15 -9.0(16) . . . . ?
C13 C19 C20 C15 169.3(10) 2_554 . . . ?
C16 C15 C20 O2 -177.4(8) . . . . ?
C14 C15 C20 O2 2.1(14) . . . . ?
C16 C15 C20 C19 8.8(14) . . . . ?
C14 C15 C20 C19 -171.8(10) . . . . ?
C20 O2 C21 C23 69.7(14) . . . . ?
N2 C22 C23 C24 6.3(16) . . . . ?
N2 C22 C23 C21 -175.5(10) . . . . ?
O2 C21 C23 C24 48.9(16) . . . . ?
O2 C21 C23 C22 -129.1(11) . . . . ?
C22 C23 C24 C25 -3.1(17) . . . . ?
C21 C23 C24 C25 178.9(11) . . . . ?
C23 C24 C25 C26 -0.4(17) . . . . ?
C24 C25 C26 N2 1.2(17) . . . . ?
C4 C5 N1 C1 1.4(17) . . . . ?
C4 C5 N1 Ag1 173.7(9) . . . 4_545 ?
C2 C1 N1 C5 1.2(16) . . . . ?
C2 C1 N1 Ag1 -171.7(8) . . . 4_545 ?
C25 C26 N2 C22 1.7(17) . . . . ?
C25 C26 N2 Ag1 -170.9(8) . . . . ?
C23 C22 N2 C26 -5.6(16) . . . . ?
C23 C22 N2 Ag1 166.9(8) . . . . ?
N1 Ag1 N2 C26 -23.4(16) 4 . . . ?
O4 Ag1 N2 C26 -176.6(9) . . . . ?
Ag1 Ag1 N2 C26 73.9(9) 7_556 . . . ?
N1 Ag1 N2 C22 164.4(9) 4 . . . ?
O4 Ag1 N2 C22 11.2(9) . . . . ?
Ag1 Ag1 N2 C22 -98.4(8) 7_556 . . . ?
Ag1 O4 N3 O3 -155.0(10) . . . . ?
Ag1 O4 N3 O5 21.7(11) . . . . ?

_diffrn_measured_fraction_theta_max 1
_diffrn_reflns_theta_full        25.01
_diffrn_measured_fraction_theta_full 1
_refine_diff_density_max         3.573
_refine_diff_density_min         -3.443
_refine_diff_density_rms         0.262
