# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_qq_sq
_database_code_depnum_ccdc_archive 'CCDC 1509840'
_audit_update_record             
;
2016-11-02 deposited with the CCDC.
2016-11-15 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C36 H27 F3 N2 O2 P2 Pt'
_chemical_formula_weight         833.62

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.1019(7)
_cell_length_b                   11.4751(8)
_cell_length_c                   14.0486(9)
_cell_angle_alpha                77.9640(10)
_cell_angle_beta                 81.1010(10)
_cell_angle_gamma                89.9710(10)
_cell_volume                     1728.4(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9075
_cell_measurement_theta_min      2.55
_cell_measurement_theta_max      28.27

_exptl_crystal_description       needle
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.602
_exptl_crystal_F_000             816
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.270
_exptl_crystal_size_mid          0.260
_exptl_crystal_size_min          0.220
_exptl_absorpt_coefficient_mu    4.202
_shelx_estimated_absorpt_T_min   0.397
_shelx_estimated_absorpt_T_max   0.458
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            9738
_diffrn_reflns_av_unetI/netI     0.1013
_diffrn_reflns_av_R_equivalents  0.1554
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         1.816
_diffrn_reflns_theta_max         25.008
_diffrn_reflns_theta_full        25.009
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             6067
_reflns_number_gt                5707
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ', SQUEEZE'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1438P)²+0.3540P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6067
_refine_ls_number_parameters     415
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0587
_refine_ls_R_factor_gt           0.0572
_refine_ls_wR_factor_ref         0.1479
_refine_ls_wR_factor_gt          0.1459
_refine_ls_goodness_of_fit_ref   0.840
_refine_ls_restrained_S_all      0.840
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8708(7) -0.1020(7) 0.1596(6) 0.0449(17) Uani 1 1 d . . . . .
C2 C 0.7831(6) -0.0288(6) 0.1043(6) 0.0376(15) Uani 1 1 d . . . . .
C3 C 0.7212(6) 0.0590(6) 0.1450(5) 0.0322(14) Uani 1 1 d . . . . .
H3 H 0.7329 0.0696 0.2069 0.039 Uiso 1 1 calc R U . . .
C4 C 0.6412(6) 0.1317(6) 0.0930(5) 0.0244(12) Uani 1 1 d . . . . .
C5 C 0.6251(5) 0.1102(5) -0.0022(4) 0.0282(12) Uani 1 1 d . . . . .
C6 C 0.6876(6) 0.0204(6) -0.0399(5) 0.0386(15) Uani 1 1 d . . . . .
H6 H 0.6759 0.0068 -0.1009 0.046 Uiso 1 1 calc R U . . .
C7 C 0.7668(7) -0.0485(7) 0.0125(6) 0.0396(17) Uani 1 1 d . . . . .
H7 H 0.8092 -0.1078 -0.0133 0.048 Uiso 1 1 calc R U . . .
C8 C 0.5442(6) 0.1912(6) -0.0527(5) 0.0332(14) Uani 1 1 d . . . . .
C9 C 0.5163(6) 0.1967(7) -0.1477(5) 0.0382(15) Uani 1 1 d . . . . .
H9 H 0.5487 0.1417 -0.1839 0.046 Uiso 1 1 calc R U . . .
C10 C 0.4422(7) 0.2818(7) -0.1871(6) 0.0447(17) Uani 1 1 d . . . . .
H10 H 0.4250 0.2856 -0.2504 0.054 Uiso 1 1 calc R U . . .
C11 C 0.3923(7) 0.3628(7) -0.1324(5) 0.0453(17) Uani 1 1 d . . . . .
H11 H 0.3408 0.4209 -0.1579 0.054 Uiso 1 1 calc R U . . .
C12 C 0.4213(6) 0.3549(6) -0.0390(5) 0.0355(14) Uani 1 1 d . . . . .
H12 H 0.3881 0.4093 -0.0024 0.043 Uiso 1 1 calc R U . . .
C13 C 0.5722(6) 0.1882(6) 0.4637(5) 0.0307(13) Uani 1 1 d . . . . .
C14 C 0.4810(7) 0.1769(8) 0.5430(6) 0.0499(19) Uani 1 1 d . . . . .
H14 H 0.4139 0.2251 0.5386 0.060 Uiso 1 1 calc R U . . .
C15 C 0.4873(10) 0.0938(9) 0.6307(7) 0.064(2) Uani 1 1 d . . . . .
H15 H 0.4244 0.0869 0.6838 0.077 Uiso 1 1 calc R U . . .
C16 C 0.5866(10) 0.0223(7) 0.6380(6) 0.058(2) Uani 1 1 d . . . . .
H16 H 0.5923 -0.0323 0.6961 0.070 Uiso 1 1 calc R U . . .
C17 C 0.6771(10) 0.0333(8) 0.5579(7) 0.062(2) Uani 1 1 d . . . . .
H17 H 0.7440 -0.0152 0.5619 0.075 Uiso 1 1 calc R U . . .
C18 C 0.6711(8) 0.1156(7) 0.4706(6) 0.0506(19) Uani 1 1 d . . . . .
H18 H 0.7334 0.1216 0.4171 0.061 Uiso 1 1 calc R U . . .
C19 C 0.6874(6) 0.4010(6) 0.3396(5) 0.0350(14) Uani 1 1 d . . . . .
C20 C 0.6687(7) 0.5007(7) 0.3807(5) 0.0427(16) Uani 1 1 d . . . . .
H20 H 0.5916 0.5152 0.4119 0.051 Uiso 1 1 calc R U . . .
C21 C 0.7657(10) 0.5779(9) 0.3747(8) 0.063(2) Uani 1 1 d . . . . .
H21 H 0.7532 0.6457 0.4010 0.076 Uiso 1 1 calc R U . . .
C22 C 0.8802(9) 0.5573(10) 0.3308(9) 0.075(3) Uani 1 1 d . . . . .
H22 H 0.9448 0.6101 0.3279 0.091 Uiso 1 1 calc R U . . .
C23 C 0.8990(8) 0.4582(10) 0.2912(9) 0.071(3) Uani 1 1 d . . . . .
H23 H 0.9771 0.4431 0.2625 0.085 Uiso 1 1 calc R U . . .
C24 C 0.8030(7) 0.3803(8) 0.2934(7) 0.056(2) Uani 1 1 d . . . . .
H24 H 0.8158 0.3147 0.2643 0.067 Uiso 1 1 calc R U . . .
C25 C 0.2245(6) 0.2815(6) 0.3066(5) 0.0355(14) Uani 1 1 d . . . . .
C26 C 0.2038(8) 0.2098(7) 0.2434(7) 0.055(2) Uani 1 1 d . . . . .
H26 H 0.2559 0.2167 0.1838 0.067 Uiso 1 1 calc R U . . .
C27 C 0.1060(10) 0.1265(9) 0.2668(9) 0.073(3) Uani 1 1 d . . . . .
H27 H 0.0933 0.0776 0.2239 0.087 Uiso 1 1 calc R U . . .
C28 C 0.0276(9) 0.1187(9) 0.3568(10) 0.076(3) Uani 1 1 d . . . . .
H28 H -0.0393 0.0656 0.3727 0.091 Uiso 1 1 calc R U . . .
C29 C 0.0482(8) 0.1883(9) 0.4214(9) 0.072(3) Uani 1 1 d . . . . .
H29 H -0.0023 0.1803 0.4818 0.086 Uiso 1 1 calc R U . . .
C30 C 0.1453(7) 0.2707(7) 0.3955(7) 0.053(2) Uani 1 1 d . . . . .
H30 H 0.1578 0.3198 0.4383 0.063 Uiso 1 1 calc R U . . .
C31 C 0.2884(6) 0.5298(6) 0.2777(5) 0.0326(14) Uani 1 1 d . . . . .
C32 C 0.2305(6) 0.5870(7) 0.2017(5) 0.0400(15) Uani 1 1 d . . . . .
H32 H 0.2258 0.5509 0.1489 0.048 Uiso 1 1 calc R U . . .
C33 C 0.1793(7) 0.6972(7) 0.2021(7) 0.0517(19) Uani 1 1 d . . . . .
H33 H 0.1443 0.7367 0.1488 0.062 Uiso 1 1 calc R U . . .
C34 C 0.1814(7) 0.7471(7) 0.2835(7) 0.053(2) Uani 1 1 d . . . . .
H34 H 0.1433 0.8189 0.2859 0.064 Uiso 1 1 calc R U . . .
C35 C 0.2384(8) 0.6933(8) 0.3612(7) 0.058(2) Uani 1 1 d . . . . .
H35 H 0.2418 0.7295 0.4141 0.069 Uiso 1 1 calc R U . . .
C36 C 0.2914(7) 0.5822(6) 0.3584(6) 0.0425(16) Uani 1 1 d . . . . .
H36 H 0.3287 0.5437 0.4106 0.051 Uiso 1 1 calc R U . . .
F1 F 0.8754(7) -0.2139(5) 0.1481(6) 0.089(2) Uani 1 1 d . . . . .
F2 F 0.8479(7) -0.1079(8) 0.2554(5) 0.111(3) Uani 1 1 d . . . . .
F3 F 0.9846(5) -0.0595(7) 0.1329(6) 0.104(2) Uani 1 1 d . . . . .
N1 N 0.4949(5) 0.2723(5) 0.0014(4) 0.0320(12) Uani 1 1 d . . . . .
N2 N 0.4373(5) 0.3568(6) 0.3598(4) 0.0386(13) Uani 1 1 d . . . . .
O1 O 0.5940(5) 0.2241(5) 0.2667(4) 0.0415(12) Uani 1 1 d . . . . .
O2 O 0.4140(5) 0.3863(5) 0.1702(3) 0.0323(10) Uani 1 1 d . . . . .
P1 P 0.56394(15) 0.29390(15) 0.34998(12) 0.0291(4) Uani 1 1 d . . . . .
P2 P 0.35388(14) 0.38685(14) 0.27544(12) 0.0290(3) Uani 1 1 d . . . . .
Pt1 Pt 0.53817(2) 0.25477(2) 0.13390(2) 0.02668(14) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 F1 1.327(9) . ?
C1 F3 1.323(10) . ?
C1 F2 1.317(10) . ?
C1 C2 1.489(10) . ?
C2 C7 1.393(11) . ?
C2 C3 1.391(10) . ?
C3 C4 1.402(9) . ?
C3 H3 0.9300 . ?
C4 C5 1.446(8) . ?
C4 Pt1 1.941(6) . ?
C5 C6 1.392(9) . ?
C5 C8 1.447(10) . ?
C6 C7 1.377(11) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C8 N1 1.382(9) . ?
C8 C9 1.405(10) . ?
C9 C10 1.361(11) . ?
C9 H9 0.9300 . ?
C10 C11 1.388(11) . ?
C10 H10 0.9300 . ?
C11 C12 1.383(10) . ?
C11 H11 0.9300 . ?
C12 N1 1.344(9) . ?
C12 H12 0.9300 . ?
C13 C18 1.381(11) . ?
C13 C14 1.368(10) . ?
C13 P1 1.808(7) . ?
C14 C15 1.403(13) . ?
C14 H14 0.9300 . ?
C15 C16 1.378(14) . ?
C15 H15 0.9300 . ?
C16 C17 1.373(14) . ?
C16 H16 0.9300 . ?
C17 C18 1.393(12) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.387(10) . ?
C19 C24 1.390(10) . ?
C19 P1 1.810(7) . ?
C20 C21 1.376(12) . ?
C20 H20 0.9300 . ?
C21 C22 1.368(15) . ?
C21 H21 0.9300 . ?
C22 C23 1.368(16) . ?
C22 H22 0.9300 . ?
C23 C24 1.384(14) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C30 1.394(11) . ?
C25 C26 1.373(11) . ?
C25 P2 1.817(7) . ?
C26 C27 1.400(12) . ?
C26 H26 0.9300 . ?
C27 C28 1.406(16) . ?
C27 H27 0.9300 . ?
C28 C29 1.371(17) . ?
C28 H28 0.9300 . ?
C29 C30 1.388(13) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 C36 1.394(10) . ?
C31 C32 1.379(11) . ?
C31 P2 1.798(7) . ?
C32 C33 1.387(11) . ?
C32 H32 0.9300 . ?
C33 C34 1.385(13) . ?
C33 H33 0.9300 . ?
C34 C35 1.380(14) . ?
C34 H34 0.9300 . ?
C35 C36 1.409(11) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
N1 Pt1 1.964(6) . ?
N2 P1 1.580(6) . ?
N2 P2 1.597(6) . ?
O1 P1 1.546(5) . ?
O1 Pt1 2.019(5) . ?
O2 P2 1.526(5) . ?
O2 Pt1 2.131(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F1 C1 F3 105.0(7) . . ?
F1 C1 F2 106.1(7) . . ?
F3 C1 F2 104.6(8) . . ?
F1 C1 C2 114.0(7) . . ?
F3 C1 C2 112.9(7) . . ?
F2 C1 C2 113.4(6) . . ?
C7 C2 C3 121.6(7) . . ?
C7 C2 C1 119.3(6) . . ?
C3 C2 C1 119.0(7) . . ?
C2 C3 C4 120.1(6) . . ?
C2 C3 H3 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 C5 117.6(6) . . ?
C3 C4 Pt1 128.8(5) . . ?
C5 C4 Pt1 113.4(5) . . ?
C6 C5 C4 120.6(6) . . ?
C6 C5 C8 125.1(6) . . ?
C4 C5 C8 114.3(5) . . ?
C7 C6 C5 120.4(6) . . ?
C7 C6 H6 119.8 . . ?
C5 C6 H6 119.8 . . ?
C2 C7 C6 119.7(6) . . ?
C2 C7 H7 120.2 . . ?
C6 C7 H7 120.2 . . ?
N1 C8 C9 119.6(7) . . ?
N1 C8 C5 113.0(6) . . ?
C9 C8 C5 127.4(6) . . ?
C10 C9 C8 120.6(6) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C9 C10 C11 119.6(7) . . ?
C9 C10 H10 120.2 . . ?
C11 C10 H10 120.2 . . ?
C12 C11 C10 118.4(7) . . ?
C12 C11 H11 120.8 . . ?
C10 C11 H11 120.8 . . ?
N1 C12 C11 123.2(7) . . ?
N1 C12 H12 118.4 . . ?
C11 C12 H12 118.4 . . ?
C18 C13 C14 119.1(7) . . ?
C18 C13 P1 119.6(5) . . ?
C14 C13 P1 121.3(6) . . ?
C13 C14 C15 121.1(8) . . ?
C13 C14 H14 119.5 . . ?
C15 C14 H14 119.5 . . ?
C16 C15 C14 119.9(8) . . ?
C16 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
C17 C16 C15 118.6(8) . . ?
C17 C16 H16 120.7 . . ?
C15 C16 H16 120.7 . . ?
C16 C17 C18 121.6(9) . . ?
C16 C17 H17 119.2 . . ?
C18 C17 H17 119.2 . . ?
C13 C18 C17 119.7(8) . . ?
C13 C18 H18 120.1 . . ?
C17 C18 H18 120.1 . . ?
C20 C19 C24 119.9(7) . . ?
C20 C19 P1 120.6(5) . . ?
C24 C19 P1 119.4(6) . . ?
C21 C20 C19 119.0(8) . . ?
C21 C20 H20 120.5 . . ?
C19 C20 H20 120.5 . . ?
C20 C21 C22 121.5(9) . . ?
C20 C21 H21 119.2 . . ?
C22 C21 H21 119.2 . . ?
C23 C22 C21 119.5(9) . . ?
C23 C22 H22 120.3 . . ?
C21 C22 H22 120.3 . . ?
C22 C23 C24 120.7(9) . . ?
C22 C23 H23 119.7 . . ?
C24 C23 H23 119.7 . . ?
C19 C24 C23 119.3(9) . . ?
C19 C24 H24 120.3 . . ?
C23 C24 H24 120.3 . . ?
C30 C25 C26 118.7(7) . . ?
C30 C25 P2 120.8(6) . . ?
C26 C25 P2 120.5(6) . . ?
C25 C26 C27 121.5(9) . . ?
C25 C26 H26 119.3 . . ?
C27 C26 H26 119.3 . . ?
C28 C27 C26 118.2(9) . . ?
C28 C27 H27 120.9 . . ?
C26 C27 H27 120.9 . . ?
C27 C28 C29 121.0(9) . . ?
C27 C28 H28 119.5 . . ?
C29 C28 H28 119.5 . . ?
C28 C29 C30 119.2(10) . . ?
C28 C29 H29 120.4 . . ?
C30 C29 H29 120.4 . . ?
C25 C30 C29 121.4(9) . . ?
C25 C30 H30 119.3 . . ?
C29 C30 H30 119.3 . . ?
C36 C31 C32 119.1(6) . . ?
C36 C31 P2 120.2(6) . . ?
C32 C31 P2 120.7(5) . . ?
C33 C32 C31 121.6(7) . . ?
C33 C32 H32 119.2 . . ?
C31 C32 H32 119.2 . . ?
C34 C33 C32 118.6(8) . . ?
C34 C33 H33 120.7 . . ?
C32 C33 H33 120.7 . . ?
C35 C34 C33 121.8(7) . . ?
C35 C34 H34 119.1 . . ?
C33 C34 H34 119.1 . . ?
C34 C35 C36 118.5(8) . . ?
C34 C35 H35 120.8 . . ?
C36 C35 H35 120.8 . . ?
C31 C36 C35 120.4(8) . . ?
C31 C36 H36 119.8 . . ?
C35 C36 H36 119.8 . . ?
C12 N1 C8 118.6(6) . . ?
C12 N1 Pt1 125.4(5) . . ?
C8 N1 Pt1 116.1(5) . . ?
P1 N2 P2 125.2(4) . . ?
P1 O1 Pt1 128.3(3) . . ?
P2 O2 Pt1 123.2(3) . . ?
O1 P1 N2 118.0(3) . . ?
O1 P1 C13 106.0(3) . . ?
N2 P1 C13 108.8(3) . . ?
O1 P1 C19 108.5(3) . . ?
N2 P1 C19 110.2(3) . . ?
C13 P1 C19 104.4(3) . . ?
O2 P2 N2 117.3(3) . . ?
O2 P2 C31 108.6(3) . . ?
N2 P2 C31 108.8(3) . . ?
O2 P2 C25 107.9(3) . . ?
N2 P2 C25 108.6(3) . . ?
C31 P2 C25 104.9(3) . . ?
C4 Pt1 N1 82.9(3) . . ?
C4 Pt1 O1 91.5(2) . . ?
N1 Pt1 O1 174.31(18) . . ?
C4 Pt1 O2 174.7(2) . . ?
N1 Pt1 O2 92.6(2) . . ?
O1 Pt1 O2 93.11(19) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F1 C1 C2 C7 -35.2(10) . . . . ?
F3 C1 C2 C7 84.5(10) . . . . ?
F2 C1 C2 C7 -156.7(8) . . . . ?
F1 C1 C2 C3 146.0(7) . . . . ?
F3 C1 C2 C3 -94.3(9) . . . . ?
F2 C1 C2 C3 24.5(11) . . . . ?
C7 C2 C3 C4 -0.9(10) . . . . ?
C1 C2 C3 C4 177.9(6) . . . . ?
C2 C3 C4 C5 0.9(9) . . . . ?
C2 C3 C4 Pt1 176.8(5) . . . . ?
C3 C4 C5 C6 -0.1(9) . . . . ?
Pt1 C4 C5 C6 -176.7(5) . . . . ?
C3 C4 C5 C8 -178.1(6) . . . . ?
Pt1 C4 C5 C8 5.4(7) . . . . ?
C4 C5 C6 C7 -0.7(10) . . . . ?
C8 C5 C6 C7 177.0(7) . . . . ?
C3 C2 C7 C6 0.0(11) . . . . ?
C1 C2 C7 C6 -178.8(7) . . . . ?
C5 C6 C7 C2 0.7(11) . . . . ?
C6 C5 C8 N1 -179.5(6) . . . . ?
C4 C5 C8 N1 -1.7(8) . . . . ?
C6 C5 C8 C9 -1.6(11) . . . . ?
C4 C5 C8 C9 176.3(6) . . . . ?
N1 C8 C9 C10 0.7(10) . . . . ?
C5 C8 C9 C10 -177.1(7) . . . . ?
C8 C9 C10 C11 -0.9(11) . . . . ?
C9 C10 C11 C12 0.7(12) . . . . ?
C10 C11 C12 N1 -0.2(12) . . . . ?
C18 C13 C14 C15 0.5(12) . . . . ?
P1 C13 C14 C15 179.3(7) . . . . ?
C13 C14 C15 C16 0.3(14) . . . . ?
C14 C15 C16 C17 -0.9(14) . . . . ?
C15 C16 C17 C18 0.8(14) . . . . ?
C14 C13 C18 C17 -0.7(12) . . . . ?
P1 C13 C18 C17 -179.4(7) . . . . ?
C16 C17 C18 C13 0.0(14) . . . . ?
C24 C19 C20 C21 0.1(11) . . . . ?
P1 C19 C20 C21 177.6(7) . . . . ?
C19 C20 C21 C22 -1.2(14) . . . . ?
C20 C21 C22 C23 0.5(17) . . . . ?
C21 C22 C23 C24 1.3(18) . . . . ?
C20 C19 C24 C23 1.6(13) . . . . ?
P1 C19 C24 C23 -175.8(8) . . . . ?
C22 C23 C24 C19 -2.4(16) . . . . ?
C30 C25 C26 C27 -0.4(13) . . . . ?
P2 C25 C26 C27 178.8(8) . . . . ?
C25 C26 C27 C28 0.9(15) . . . . ?
C26 C27 C28 C29 -1.9(16) . . . . ?
C27 C28 C29 C30 2.5(16) . . . . ?
C26 C25 C30 C29 1.0(12) . . . . ?
P2 C25 C30 C29 -178.2(7) . . . . ?
C28 C29 C30 C25 -2.1(15) . . . . ?
C36 C31 C32 C33 2.3(11) . . . . ?
P2 C31 C32 C33 179.9(6) . . . . ?
C31 C32 C33 C34 -3.3(12) . . . . ?
C32 C33 C34 C35 3.5(12) . . . . ?
C33 C34 C35 C36 -2.5(13) . . . . ?
C32 C31 C36 C35 -1.3(11) . . . . ?
P2 C31 C36 C35 -178.9(6) . . . . ?
C34 C35 C36 C31 1.4(12) . . . . ?
C11 C12 N1 C8 0.0(11) . . . . ?
C11 C12 N1 Pt1 -179.2(6) . . . . ?
C9 C8 N1 C12 -0.2(10) . . . . ?
C5 C8 N1 C12 177.9(6) . . . . ?
C9 C8 N1 Pt1 179.1(5) . . . . ?
C5 C8 N1 Pt1 -2.8(7) . . . . ?
Pt1 O1 P1 N2 29.9(6) . . . . ?
Pt1 O1 P1 C13 152.0(4) . . . . ?
Pt1 O1 P1 C19 -96.3(5) . . . . ?
P2 N2 P1 O1 -18.5(6) . . . . ?
P2 N2 P1 C13 -139.2(4) . . . . ?
P2 N2 P1 C19 106.9(5) . . . . ?
C18 C13 P1 O1 47.5(7) . . . . ?
C14 C13 P1 O1 -131.3(6) . . . . ?
C18 C13 P1 N2 175.3(6) . . . . ?
C14 C13 P1 N2 -3.4(7) . . . . ?
C18 C13 P1 C19 -67.1(7) . . . . ?
C14 C13 P1 C19 114.2(6) . . . . ?
C20 C19 P1 O1 158.0(6) . . . . ?
C24 C19 P1 O1 -24.6(7) . . . . ?
C20 C19 P1 N2 27.4(7) . . . . ?
C24 C19 P1 N2 -155.1(6) . . . . ?
C20 C19 P1 C13 -89.3(6) . . . . ?
C24 C19 P1 C13 88.2(7) . . . . ?
Pt1 O2 P2 N2 41.7(5) . . . . ?
Pt1 O2 P2 C31 165.6(3) . . . . ?
Pt1 O2 P2 C25 -81.2(4) . . . . ?
P1 N2 P2 O2 -17.3(6) . . . . ?
P1 N2 P2 C31 -141.1(4) . . . . ?
P1 N2 P2 C25 105.2(5) . . . . ?
C36 C31 P2 O2 -143.0(6) . . . . ?
C32 C31 P2 O2 39.4(6) . . . . ?
C36 C31 P2 N2 -14.2(7) . . . . ?
C32 C31 P2 N2 168.2(6) . . . . ?
C36 C31 P2 C25 101.8(6) . . . . ?
C32 C31 P2 C25 -75.8(6) . . . . ?
C30 C25 P2 O2 -174.2(6) . . . . ?
C26 C25 P2 O2 6.6(7) . . . . ?
C30 C25 P2 N2 57.7(6) . . . . ?
C26 C25 P2 N2 -121.5(6) . . . . ?
C30 C25 P2 C31 -58.5(7) . . . . ?
C26 C25 P2 C31 122.3(6) . . . . ?

_refine_diff_density_max         5.252
_refine_diff_density_min         -3.443
_refine_diff_density_rms         0.229



_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: CH2Cl2'
_chemical_properties_physical    
', Air-sensitive,Moisture-sensitive,Heat-sensitive,Oxygen-sensitive,Light-sensitive,Photo-sensitive'
_exptl_crystal_preparation       ', Luminescent'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_bbbb
_database_code_depnum_ccdc_archive 'CCDC 1509843'
_audit_update_record             
;
2016-11-02 deposited with the CCDC.
2016-11-15 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C36 H23 F7 N2 O2 P2 Pt'
_chemical_formula_weight         905.59

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.6958(14)
_cell_length_b                   11.3423(12)
_cell_length_c                   21.827(2)
_cell_angle_alpha                90
_cell_angle_beta                 94.556(2)
_cell_angle_gamma                90
_cell_volume                     3379.9(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    7719
_cell_measurement_theta_min      2.33
_cell_measurement_theta_max      27.37

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.780
_exptl_crystal_F_000             1760
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.220
_exptl_absorpt_coefficient_mu    4.321
_shelx_estimated_absorpt_T_min   0.377
_shelx_estimated_absorpt_T_max   0.450
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4574
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            18294
_diffrn_reflns_av_unetI/netI     0.0503
_diffrn_reflns_av_R_equivalents  0.0470
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.697
_diffrn_reflns_theta_max         25.008
_diffrn_reflns_theta_full        25.008
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5965
_reflns_number_gt                5078
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ', SQUEEZE'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0676P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5965
_refine_ls_number_parameters     451
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0474
_refine_ls_R_factor_gt           0.0382
_refine_ls_wR_factor_ref         0.1031
_refine_ls_wR_factor_gt          0.0972
_refine_ls_goodness_of_fit_ref   1.012
_refine_ls_restrained_S_all      1.012
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F5 F 0.9904(3) 0.6575(4) 0.3082(2) 0.0906(15) Uani 1 1 d . . . . .
Pt1 Pt 0.43534(2) 0.48187(2) 0.21806(2) 0.03232(10) Uani 1 1 d . . . . .
P2 P 0.54011(11) 0.68275(13) 0.13871(6) 0.0389(3) Uani 1 1 d . . . . .
P1 P 0.56157(10) 0.70502(13) 0.26677(6) 0.0343(3) Uani 1 1 d . . . . .
N1 N 0.3521(3) 0.3713(4) 0.1675(2) 0.0405(11) Uani 1 1 d . . . . .
C11 C 0.3767(4) 0.4004(5) 0.2842(3) 0.0383(13) Uani 1 1 d . . . . .
O1 O 0.5203(3) 0.5819(3) 0.27803(16) 0.0453(9) Uani 1 1 d . . . . .
O2 O 0.4979(3) 0.5592(4) 0.13950(18) 0.0510(10) Uani 1 1 d . . . . .
C6 C 0.3080(4) 0.3113(5) 0.2652(3) 0.0418(13) Uani 1 1 d . . . . .
C31 C 0.5133(4) 0.8076(5) 0.3188(2) 0.0388(12) Uani 1 1 d . . . . .
C30 C 0.6926(4) 0.6917(5) 0.2861(2) 0.0351(12) Uani 1 1 d . . . . .
F2 F 0.3408(4) 0.4681(4) 0.4767(2) 0.0863(15) Uani 1 1 d . . . . .
C7 C 0.2585(4) 0.2474(5) 0.3075(3) 0.0521(16) Uani 1 1 d . . . . .
H7 H 0.2116 0.1920 0.2939 0.063 Uiso 1 1 calc R U . . .
C5 C 0.2967(4) 0.2945(5) 0.1984(3) 0.0415(13) Uani 1 1 d . . . . .
C25 C 0.7367(4) 0.5820(5) 0.2840(3) 0.0476(14) Uani 1 1 d . . . . .
H25 H 0.6979 0.5151 0.2775 0.057 Uiso 1 1 calc R U . . .
C26 C 0.8358(5) 0.5705(6) 0.2912(3) 0.0582(17) Uani 1 1 d . . . . .
H26 H 0.8652 0.4967 0.2899 0.070 Uiso 1 1 calc R U . . .
C10 C 0.3965(4) 0.4162(5) 0.3467(3) 0.0408(13) Uani 1 1 d . . . . .
H10 H 0.4419 0.4727 0.3610 0.049 Uiso 1 1 calc R U . . .
C24 C 0.6645(4) 0.6719(5) 0.1175(2) 0.0425(13) Uani 1 1 d . . . . .
F4 F 0.9506(3) 0.6507(5) 0.0759(3) 0.118(2) Uani 1 1 d . . . . .
C12 C 0.3752(5) 0.3668(6) 0.4560(3) 0.0601(17) Uani 1 1 d . . . . .
N2 N 0.5388(3) 0.7591(4) 0.19985(19) 0.0376(10) Uani 1 1 d . . . . .
C1 C 0.3499(4) 0.3645(6) 0.1057(3) 0.0518(15) Uani 1 1 d . . . . .
H1 H 0.3874 0.4170 0.0848 0.062 Uiso 1 1 calc R U . . .
F1 F 0.3409(4) 0.2832(4) 0.49107(19) 0.0900(14) Uani 1 1 d . . . . .
C9 C 0.3488(4) 0.3477(5) 0.3891(3) 0.0468(14) Uani 1 1 d . . . . .
F3 F 0.4714(3) 0.3705(5) 0.47043(19) 0.0835(13) Uani 1 1 d . . . . .
C32 C 0.5237(4) 0.7848(6) 0.3818(3) 0.0495(15) Uani 1 1 d . . . . .
H32 H 0.5617 0.7215 0.3966 0.059 Uiso 1 1 calc R U . . .
C14 C 0.4026(6) 0.9480(8) 0.0395(4) 0.072(2) Uani 1 1 d . . . . .
H14 H 0.3863 1.0268 0.0446 0.086 Uiso 1 1 calc R U . . .
C8 C 0.2788(4) 0.2663(6) 0.3693(3) 0.0535(16) Uani 1 1 d . . . . .
H8 H 0.2455 0.2242 0.3976 0.064 Uiso 1 1 calc R U . . .
C18 C 0.4754(4) 0.7686(6) 0.0794(2) 0.0450(14) Uani 1 1 d . . . . .
C35 C 0.4115(5) 0.9731(6) 0.3390(4) 0.0593(18) Uani 1 1 d . . . . .
H35 H 0.3747 1.0382 0.3252 0.071 Uiso 1 1 calc R U . . .
C21 C 0.8557(6) 0.6584(9) 0.0903(4) 0.078(3) Uani 1 1 d . . . . .
C29 C 0.7509(4) 0.7904(5) 0.2965(3) 0.0493(15) Uani 1 1 d . . . . .
H29 H 0.7220 0.8643 0.2985 0.059 Uiso 1 1 calc R U . . .
C36 C 0.4560(4) 0.9020(6) 0.2980(3) 0.0528(15) Uani 1 1 d . . . . .
H36 H 0.4474 0.9177 0.2561 0.063 Uiso 1 1 calc R U . . .
C16 C 0.4019(7) 0.7785(10) -0.0240(4) 0.095(3) Uani 1 1 d . . . . .
H16 H 0.3838 0.7427 -0.0615 0.114 Uiso 1 1 calc R U . . .
C20 C 0.8204(5) 0.7628(8) 0.1068(4) 0.080(2) Uani 1 1 d . . . . .
H20 H 0.8597 0.8297 0.1090 0.095 Uiso 1 1 calc R U . . .
C19 C 0.7240(5) 0.7679(7) 0.1206(3) 0.067(2) Uani 1 1 d . . . . .
H19 H 0.6988 0.8398 0.1325 0.080 Uiso 1 1 calc R U . . .
C2 C 0.2936(5) 0.2817(7) 0.0725(3) 0.070(2) Uani 1 1 d . . . . .
H2 H 0.2928 0.2786 0.0299 0.084 Uiso 1 1 calc R U . . .
C13 C 0.4510(4) 0.8845(6) 0.0876(3) 0.0545(16) Uani 1 1 d . . . . .
H13 H 0.4667 0.9208 0.1253 0.065 Uiso 1 1 calc R U . . .
C23 C 0.7026(6) 0.5670(7) 0.0987(4) 0.073(2) Uani 1 1 d . . . . .
H23 H 0.6628 0.5006 0.0948 0.088 Uiso 1 1 calc R U . . .
C22 C 0.8013(7) 0.5589(9) 0.0855(5) 0.100(3) Uani 1 1 d . . . . .
H22 H 0.8280 0.4878 0.0738 0.120 Uiso 1 1 calc R U . . .
C17 C 0.4509(6) 0.7170(8) 0.0225(3) 0.075(2) Uani 1 1 d . . . . .
H17 H 0.4682 0.6389 0.0160 0.090 Uiso 1 1 calc R U . . .
F6 F 0.3765(4) 1.0144(4) 0.4395(2) 0.0813(13) Uani 1 1 d . . . . .
F7 F 0.3331(4) 0.9564(6) -0.0602(2) 0.121(2) Uani 1 1 d . . . . .
C33 C 0.4783(5) 0.8552(6) 0.4223(3) 0.0579(17) Uani 1 1 d . . . . .
H33 H 0.4857 0.8407 0.4644 0.069 Uiso 1 1 calc R U . . .
C34 C 0.4224(5) 0.9464(7) 0.3995(3) 0.0574(17) Uani 1 1 d . . . . .
C28 C 0.8526(4) 0.7801(6) 0.3042(3) 0.0577(17) Uani 1 1 d . . . . .
H28 H 0.8925 0.8457 0.3115 0.069 Uiso 1 1 calc R U . . .
C27 C 0.8909(4) 0.6698(6) 0.3004(3) 0.0589(17) Uani 1 1 d . . . . .
C4 C 0.2396(5) 0.2094(6) 0.1664(3) 0.0569(17) Uani 1 1 d . . . . .
H4 H 0.2026 0.1568 0.1876 0.068 Uiso 1 1 calc R U . . .
C3 C 0.2383(5) 0.2036(6) 0.1042(4) 0.069(2) Uani 1 1 d . . . . .
H3 H 0.2001 0.1470 0.0828 0.083 Uiso 1 1 calc R U . . .
C15 C 0.3803(6) 0.8935(10) -0.0141(3) 0.083(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F5 C27 1.367(7) . ?
Pt1 C11 1.942(6) . ?
Pt1 N1 1.973(4) . ?
Pt1 O1 2.028(4) . ?
Pt1 O2 2.163(4) . ?
P2 O2 1.516(4) . ?
P2 N2 1.592(5) . ?
P2 C18 1.796(6) . ?
P2 C24 1.804(6) . ?
P1 O1 1.533(4) . ?
P1 N2 1.592(4) . ?
P1 C31 1.789(6) . ?
P1 C30 1.817(5) . ?
N1 C1 1.349(7) . ?
N1 C5 1.367(7) . ?
C11 C10 1.381(8) . ?
C11 C6 1.420(7) . ?
C6 C7 1.392(8) . ?
C6 C5 1.466(8) . ?
C31 C36 1.382(8) . ?
C31 C32 1.394(8) . ?
C30 C29 1.383(7) . ?
C30 C25 1.386(8) . ?
F2 C12 1.333(8) . ?
C7 C8 1.371(9) . ?
C7 H7 0.9300 . ?
C5 C4 1.395(8) . ?
C25 C26 1.360(8) . ?
C25 H25 0.9300 . ?
C26 C27 1.361(9) . ?
C26 H26 0.9300 . ?
C10 C9 1.407(8) . ?
C10 H10 0.9300 . ?
C24 C19 1.359(9) . ?
C24 C23 1.375(9) . ?
F4 C21 1.364(8) . ?
C12 F1 1.328(7) . ?
C12 F3 1.331(7) . ?
C12 C9 1.492(9) . ?
C1 C2 1.383(9) . ?
C1 H1 0.9300 . ?
C9 C8 1.376(8) . ?
C32 C33 1.376(9) . ?
C32 H32 0.9300 . ?
C14 C15 1.337(12) . ?
C14 C13 1.396(10) . ?
C14 H14 0.9300 . ?
C8 H8 0.9300 . ?
C18 C13 1.372(9) . ?
C18 C17 1.391(9) . ?
C35 C34 1.352(10) . ?
C35 C36 1.382(9) . ?
C35 H35 0.9300 . ?
C21 C20 1.340(12) . ?
C21 C22 1.351(13) . ?
C29 C28 1.394(8) . ?
C29 H29 0.9300 . ?
C36 H36 0.9300 . ?
C16 C15 1.359(13) . ?
C16 C17 1.363(11) . ?
C16 H16 0.9300 . ?
C20 C19 1.379(9) . ?
C20 H20 0.9300 . ?
C19 H19 0.9300 . ?
C2 C3 1.386(10) . ?
C2 H2 0.9300 . ?
C13 H13 0.9300 . ?
C23 C22 1.407(11) . ?
C23 H23 0.9300 . ?
C22 H22 0.9300 . ?
C17 H17 0.9300 . ?
F6 C34 1.357(8) . ?
F7 C15 1.355(8) . ?
C33 C34 1.357(10) . ?
C33 H33 0.9300 . ?
C28 C27 1.362(9) . ?
C28 H28 0.9300 . ?
C4 C3 1.358(10) . ?
C4 H4 0.9300 . ?
C3 H3 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Pt1 N1 81.9(2) . . ?
C11 Pt1 O1 92.07(19) . . ?
N1 Pt1 O1 173.40(17) . . ?
C11 Pt1 O2 175.05(19) . . ?
N1 Pt1 O2 93.56(17) . . ?
O1 Pt1 O2 92.38(15) . . ?
O2 P2 N2 117.6(2) . . ?
O2 P2 C18 110.0(3) . . ?
N2 P2 C18 105.8(3) . . ?
O2 P2 C24 107.9(3) . . ?
N2 P2 C24 109.0(3) . . ?
C18 P2 C24 105.9(3) . . ?
O1 P1 N2 116.7(2) . . ?
O1 P1 C31 109.3(2) . . ?
N2 P1 C31 106.1(3) . . ?
O1 P1 C30 104.9(2) . . ?
N2 P1 C30 111.3(2) . . ?
C31 P1 C30 108.3(2) . . ?
C1 N1 C5 119.2(5) . . ?
C1 N1 Pt1 124.2(4) . . ?
C5 N1 Pt1 116.5(4) . . ?
C10 C11 C6 117.0(5) . . ?
C10 C11 Pt1 127.8(4) . . ?
C6 C11 Pt1 115.1(4) . . ?
P1 O1 Pt1 127.3(2) . . ?
P2 O2 Pt1 124.0(2) . . ?
C7 C6 C11 121.5(6) . . ?
C7 C6 C5 125.0(5) . . ?
C11 C6 C5 113.5(5) . . ?
C36 C31 C32 118.6(5) . . ?
C36 C31 P1 121.5(4) . . ?
C32 C31 P1 119.4(4) . . ?
C29 C30 C25 119.0(5) . . ?
C29 C30 P1 121.2(4) . . ?
C25 C30 P1 119.4(4) . . ?
C8 C7 C6 119.9(6) . . ?
C8 C7 H7 120.1 . . ?
C6 C7 H7 120.1 . . ?
N1 C5 C4 120.3(6) . . ?
N1 C5 C6 112.9(5) . . ?
C4 C5 C6 126.8(6) . . ?
C26 C25 C30 121.0(6) . . ?
C26 C25 H25 119.5 . . ?
C30 C25 H25 119.5 . . ?
C25 C26 C27 118.3(6) . . ?
C25 C26 H26 120.8 . . ?
C27 C26 H26 120.8 . . ?
C11 C10 C9 120.9(5) . . ?
C11 C10 H10 119.6 . . ?
C9 C10 H10 119.6 . . ?
C19 C24 C23 117.9(6) . . ?
C19 C24 P2 120.5(5) . . ?
C23 C24 P2 121.6(5) . . ?
F1 C12 F3 105.9(5) . . ?
F1 C12 F2 105.7(6) . . ?
F3 C12 F2 105.2(6) . . ?
F1 C12 C9 113.0(6) . . ?
F3 C12 C9 113.2(5) . . ?
F2 C12 C9 113.0(5) . . ?
P1 N2 P2 123.0(3) . . ?
N1 C1 C2 122.0(6) . . ?
N1 C1 H1 119.0 . . ?
C2 C1 H1 119.0 . . ?
C8 C9 C10 120.7(6) . . ?
C8 C9 C12 120.9(6) . . ?
C10 C9 C12 118.3(6) . . ?
C33 C32 C31 120.6(6) . . ?
C33 C32 H32 119.7 . . ?
C31 C32 H32 119.7 . . ?
C15 C14 C13 118.8(8) . . ?
C15 C14 H14 120.6 . . ?
C13 C14 H14 120.6 . . ?
C7 C8 C9 119.8(6) . . ?
C7 C8 H8 120.1 . . ?
C9 C8 H8 120.1 . . ?
C13 C18 C17 118.4(6) . . ?
C13 C18 P2 122.5(5) . . ?
C17 C18 P2 119.1(5) . . ?
C34 C35 C36 118.8(6) . . ?
C34 C35 H35 120.6 . . ?
C36 C35 H35 120.6 . . ?
C20 C21 C22 123.4(7) . . ?
C20 C21 F4 119.3(9) . . ?
C22 C21 F4 117.3(8) . . ?
C30 C29 C28 120.7(6) . . ?
C30 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
C35 C36 C31 120.5(6) . . ?
C35 C36 H36 119.8 . . ?
C31 C36 H36 119.8 . . ?
C15 C16 C17 118.3(8) . . ?
C15 C16 H16 120.9 . . ?
C17 C16 H16 120.9 . . ?
C21 C20 C19 117.9(8) . . ?
C21 C20 H20 121.0 . . ?
C19 C20 H20 121.0 . . ?
C24 C19 C20 122.4(7) . . ?
C24 C19 H19 118.8 . . ?
C20 C19 H19 118.8 . . ?
C1 C2 C3 118.5(7) . . ?
C1 C2 H2 120.7 . . ?
C3 C2 H2 120.7 . . ?
C18 C13 C14 120.2(7) . . ?
C18 C13 H13 119.9 . . ?
C14 C13 H13 119.9 . . ?
C24 C23 C22 120.8(8) . . ?
C24 C23 H23 119.6 . . ?
C22 C23 H23 119.6 . . ?
C21 C22 C23 117.5(8) . . ?
C21 C22 H22 121.2 . . ?
C23 C22 H22 121.2 . . ?
C16 C17 C18 121.3(8) . . ?
C16 C17 H17 119.4 . . ?
C18 C17 H17 119.4 . . ?
C34 C33 C32 118.5(6) . . ?
C34 C33 H33 120.8 . . ?
C32 C33 H33 120.8 . . ?
C35 C34 F6 118.7(7) . . ?
C35 C34 C33 123.0(6) . . ?
F6 C34 C33 118.3(6) . . ?
C27 C28 C29 117.1(6) . . ?
C27 C28 H28 121.4 . . ?
C29 C28 H28 121.4 . . ?
C28 C27 C26 123.9(6) . . ?
C28 C27 F5 118.1(6) . . ?
C26 C27 F5 118.0(6) . . ?
C3 C4 C5 119.8(6) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
C4 C3 C2 120.2(6) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C14 C15 F7 117.9(10) . . ?
C14 C15 C16 123.1(8) . . ?
F7 C15 C16 119.0(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 P1 O1 Pt1 -2.5(4) . . . . ?
C31 P1 O1 Pt1 117.9(3) . . . . ?
C30 P1 O1 Pt1 -126.1(3) . . . . ?
N2 P2 O2 Pt1 0.6(4) . . . . ?
C18 P2 O2 Pt1 -120.5(3) . . . . ?
C24 P2 O2 Pt1 124.4(3) . . . . ?
C10 C11 C6 C7 3.7(8) . . . . ?
Pt1 C11 C6 C7 -178.5(4) . . . . ?
C10 C11 C6 C5 -175.7(5) . . . . ?
Pt1 C11 C6 C5 2.0(6) . . . . ?
O1 P1 C31 C36 -118.1(5) . . . . ?
N2 P1 C31 C36 8.6(5) . . . . ?
C30 P1 C31 C36 128.2(5) . . . . ?
O1 P1 C31 C32 54.4(5) . . . . ?
N2 P1 C31 C32 -178.9(4) . . . . ?
C30 P1 C31 C32 -59.4(5) . . . . ?
O1 P1 C30 C29 -163.5(4) . . . . ?
N2 P1 C30 C29 69.4(5) . . . . ?
C31 P1 C30 C29 -46.8(5) . . . . ?
O1 P1 C30 C25 23.5(5) . . . . ?
N2 P1 C30 C25 -103.6(5) . . . . ?
C31 P1 C30 C25 140.2(5) . . . . ?
C11 C6 C7 C8 -3.0(9) . . . . ?
C5 C6 C7 C8 176.4(5) . . . . ?
C1 N1 C5 C4 0.8(8) . . . . ?
Pt1 N1 C5 C4 -176.7(4) . . . . ?
C1 N1 C5 C6 179.0(5) . . . . ?
Pt1 N1 C5 C6 1.5(6) . . . . ?
C7 C6 C5 N1 178.3(5) . . . . ?
C11 C6 C5 N1 -2.2(7) . . . . ?
C7 C6 C5 C4 -3.6(9) . . . . ?
C11 C6 C5 C4 175.8(5) . . . . ?
C29 C30 C25 C26 -0.8(9) . . . . ?
P1 C30 C25 C26 172.4(5) . . . . ?
C30 C25 C26 C27 -0.2(10) . . . . ?
C6 C11 C10 C9 -1.1(8) . . . . ?
Pt1 C11 C10 C9 -178.6(4) . . . . ?
O2 P2 C24 C19 -171.7(5) . . . . ?
N2 P2 C24 C19 -42.9(6) . . . . ?
C18 P2 C24 C19 70.5(6) . . . . ?
O2 P2 C24 C23 7.2(6) . . . . ?
N2 P2 C24 C23 136.0(6) . . . . ?
C18 P2 C24 C23 -110.6(6) . . . . ?
O1 P1 N2 P2 -39.5(4) . . . . ?
C31 P1 N2 P2 -161.6(3) . . . . ?
C30 P1 N2 P2 80.8(4) . . . . ?
O2 P2 N2 P1 39.6(4) . . . . ?
C18 P2 N2 P1 163.0(3) . . . . ?
C24 P2 N2 P1 -83.6(4) . . . . ?
C5 N1 C1 C2 -0.3(9) . . . . ?
Pt1 N1 C1 C2 177.0(5) . . . . ?
C11 C10 C9 C8 -2.3(9) . . . . ?
C11 C10 C9 C12 178.5(5) . . . . ?
F1 C12 C9 C8 13.2(9) . . . . ?
F3 C12 C9 C8 133.6(6) . . . . ?
F2 C12 C9 C8 -106.8(7) . . . . ?
F1 C12 C9 C10 -167.6(5) . . . . ?
F3 C12 C9 C10 -47.1(8) . . . . ?
F2 C12 C9 C10 72.5(8) . . . . ?
C36 C31 C32 C33 -0.3(9) . . . . ?
P1 C31 C32 C33 -172.9(5) . . . . ?
C6 C7 C8 C9 -0.5(9) . . . . ?
C10 C9 C8 C7 3.1(9) . . . . ?
C12 C9 C8 C7 -177.7(6) . . . . ?
O2 P2 C18 C13 139.6(5) . . . . ?
N2 P2 C18 C13 11.6(6) . . . . ?
C24 P2 C18 C13 -104.1(5) . . . . ?
O2 P2 C18 C17 -41.9(6) . . . . ?
N2 P2 C18 C17 -169.9(5) . . . . ?
C24 P2 C18 C17 74.5(6) . . . . ?
C25 C30 C29 C28 0.6(9) . . . . ?
P1 C30 C29 C28 -172.4(5) . . . . ?
C34 C35 C36 C31 -2.1(10) . . . . ?
C32 C31 C36 C35 1.0(9) . . . . ?
P1 C31 C36 C35 173.5(5) . . . . ?
C22 C21 C20 C19 1.1(13) . . . . ?
F4 C21 C20 C19 179.6(7) . . . . ?
C23 C24 C19 C20 -1.2(11) . . . . ?
P2 C24 C19 C20 177.8(6) . . . . ?
C21 C20 C19 C24 -0.5(12) . . . . ?
N1 C1 C2 C3 -0.3(10) . . . . ?
C17 C18 C13 C14 0.0(10) . . . . ?
P2 C18 C13 C14 178.5(5) . . . . ?
C15 C14 C13 C18 0.5(11) . . . . ?
C19 C24 C23 C22 2.3(11) . . . . ?
P2 C24 C23 C22 -176.6(6) . . . . ?
C20 C21 C22 C23 0.0(15) . . . . ?
F4 C21 C22 C23 -178.5(7) . . . . ?
C24 C23 C22 C21 -1.7(14) . . . . ?
C15 C16 C17 C18 2.2(13) . . . . ?
C13 C18 C17 C16 -1.3(11) . . . . ?
P2 C18 C17 C16 -179.9(7) . . . . ?
C31 C32 C33 C34 0.7(10) . . . . ?
C36 C35 C34 F6 -178.3(7) . . . . ?
C36 C35 C34 C33 2.6(12) . . . . ?
C32 C33 C34 C35 -1.9(11) . . . . ?
C32 C33 C34 F6 179.0(6) . . . . ?
C30 C29 C28 C27 0.5(10) . . . . ?
C29 C28 C27 C26 -1.6(11) . . . . ?
C29 C28 C27 F5 -179.5(6) . . . . ?
C25 C26 C27 C28 1.5(11) . . . . ?
C25 C26 C27 F5 179.4(6) . . . . ?
N1 C5 C4 C3 -0.7(9) . . . . ?
C6 C5 C4 C3 -178.7(6) . . . . ?
C5 C4 C3 C2 0.2(11) . . . . ?
C1 C2 C3 C4 0.3(11) . . . . ?
C13 C14 C15 F7 179.8(7) . . . . ?
C13 C14 C15 C16 0.4(13) . . . . ?
C17 C16 C15 C14 -1.7(14) . . . . ?
C17 C16 C15 F7 178.9(7) . . . . ?

_refine_diff_density_max         1.994
_refine_diff_density_min         -3.152
_refine_diff_density_rms         0.141


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: CH2Cl2'
_chemical_properties_physical    
', Air-sensitive,Moisture-sensitive,Heat-sensitive,Oxygen-sensitive,Light-sensitive,Photo-sensitive'
_exptl_crystal_preparation       ', Luminescent'
