File Name : figure s1.bmp Caption : fig. s1 system boundaries of the traditional (red) and innovative (green) route to chlorohydrins: i) continuous line represents the gate-to-gate boundaries within the laboratory; ii) the dashed box is the entire production chain from the raw materials extraction up to the synthesis of the valuable product(s) (cradle-to-gate approach). *glycidol production using renewables (glycerol) implies the avoided production from allyl alcohol according to the system boundaries in figure s2. File Name : figure s2.bmp Caption : fig. s2 system boundaries of the traditional fossil-route from allyl alcohol.36 File Name : figure s3.bmp Caption : fig. s3 simapro network tool: negative effect (red arrows) and avoided impacts (green arrows) are depicted to show contribution to the cf index. File Name : figure s4.bmp Caption : fig. s4 simapro network tool: negative effect (red arrows) and avoided impacts (green arrows) are depicted to show contribution to the wf index. File Name : figure s5.bmp Caption : fig. s5 contribution to ced indicator. File Name : figure s6.bmp Caption : fig. s6 effect of the improvements on the recipe receptors. File Name : figure s7.bmp Caption : fig. s7 simapro network tool: ss-resources depletion receptor. File Name : figure s8.bmp Caption : fig. s8 simapro weighting tool: contribution of each category to cumulative ss. File Name : figure s9.bmp Caption : fig. s9 system boundaries of the innovative route to produce 1kg of glycidol.