# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1523080'
_audit_update_record             
;
2016-12-16 deposited with the CCDC.
2017-03-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Mg5 Na7 O28 P8'
_chemical_formula_weight         966.08

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   6.3932(7)
_cell_length_b                   9.4219(10)
_cell_length_c                   10.9116(11)
_cell_angle_alpha                64.711(7)
_cell_angle_beta                 80.374(8)
_cell_angle_gamma                73.543(7)
_cell_volume                     569.13(10)
_cell_formula_units_Z            1
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    1790
_cell_measurement_theta_min      2.46
_cell_measurement_theta_max      22.90

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      2.818
_exptl_crystal_density_diffrn    2.819
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             481
_exptl_absorpt_coefficient_mu    1.024
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.9054
_exptl_absorpt_correction_T_max  0.9439
_exptl_absorpt_process_details   face-indexed

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            9140
_diffrn_reflns_av_R_equivalents  0.0463
_diffrn_reflns_av_sigmaI/netI    0.0575
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         2.07
_diffrn_reflns_theta_max         27.50
_reflns_number_total             2587
_reflns_number_gt                1935
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0392P)²+0.9559P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   ?
_refine_ls_hydrogen_treatment    ?
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.005(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         2587
_refine_ls_number_parameters     224
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0632
_refine_ls_R_factor_gt           0.0426
_refine_ls_wR_factor_ref         0.0976
_refine_ls_wR_factor_gt          0.0888
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_restrained_S_all      1.017
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Mg1 Mg 1.0000 1.0000 0.0000 0.078(3) Uani 0.50 2 d SP . .
Mg2 Mg 0.85707(19) 0.73772(14) 0.26350(12) 0.0120(3) Uani 1 1 d . . .
Mg3 Mg 0.7722(2) 0.39116(14) 0.21543(12) 0.0124(3) Uani 1 1 d . . .
Na1 Na 0.4697(2) 0.21076(18) 0.47507(16) 0.0214(4) Uani 1 1 d . . .
Na2 Na 0.9227(3) 0.9843(2) -0.33796(19) 0.0413(5) Uani 1 1 d . . .
Na3 Na 0.2791(4) 0.5411(3) 0.1124(3) 0.0648(8) Uani 1 1 d . . .
Na4 Na 0.2733(14) 0.9416(5) 0.0411(5) 0.110(3) Uani 0.50 1 d P . .
P1 P 0.37876(15) 0.63970(11) 0.31610(9) 0.0121(2) Uani 1 1 d . . .
P2 P 0.79236(16) 0.72863(11) -0.03722(9) 0.0127(2) Uani 1 1 d . . .
P3 P 0.92291(15) 0.34346(11) 0.45372(9) 0.0115(2) Uani 1 1 d . . .
P4 P 0.57015(16) 0.10503(12) 0.21606(10) 0.0162(3) Uani 1 1 d . . .
O1 O 0.2761(4) 0.5781(3) 0.4685(2) 0.0165(6) Uani 1 1 d . . .
O2 O 0.9427(4) 0.4812(3) 0.3150(2) 0.0128(5) Uani 1 1 d . . .
O3 O 0.7179(4) 0.5740(3) 0.0357(3) 0.0204(6) Uani 1 1 d . . .
O4 O 0.4825(4) 0.4854(3) 0.2958(3) 0.0198(6) Uani 1 1 d . . .
O5 O 0.1881(4) 0.7432(3) 0.2259(3) 0.0185(6) Uani 1 1 d . . .
O6 O 0.9422(4) 0.7286(3) -0.1587(3) 0.0210(6) Uani 1 1 d . . .
O7 O 0.8518(4) 0.2144(3) 0.4318(3) 0.0181(6) Uani 1 1 d . . .
O8 O 0.7788(4) -0.0129(3) 0.2008(3) 0.0174(6) Uani 1 1 d . . .
O9 O 0.5364(4) 0.7355(3) 0.3083(3) 0.0243(7) Uani 1 1 d . . .
O10 O 0.8791(4) 0.7753(3) 0.0570(3) 0.0199(6) Uani 1 1 d . . .
O11 O 0.4195(4) 0.1259(3) 0.0992(3) 0.0181(6) Uani 1 1 d . . .
O12 O 1.1156(4) 0.2768(3) 0.5398(3) 0.0178(6) Uani 1 1 d . . .
O13 O 0.6035(5) 0.2706(3) 0.1759(4) 0.0346(8) Uani 1 1 d . . .
O14 O 0.4456(5) 0.0458(4) 0.3502(3) 0.0405(9) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mg1 Na4 1.750(9) 1_655 ?
Mg1 Na4 1.750(9) 2_675 ?
Mg1 O10 2.260(3) 2_775 ?
Mg1 O10 2.260(3) . ?
Mg1 O8 2.377(3) 2_765 ?
Mg1 O8 2.377(3) 1_565 ?
Mg1 Mg2 3.0885(13) 2_775 ?
Mg1 Mg2 3.0885(13) . ?
Mg1 Na2 3.871(2) 2_775 ?
Mg1 Na2 3.871(2) . ?
Mg1 Na3 3.900(2) 2_675 ?
Mg1 Na3 3.900(2) 1_655 ?
Mg2 O9 2.030(3) . ?
Mg2 O8 2.077(3) 1_565 ?
Mg2 O5 2.099(3) 1_655 ?
Mg2 O10 2.112(3) . ?
Mg2 O12 2.125(3) 2_766 ?
Mg2 O2 2.156(3) . ?
Mg2 Na1 3.3696(19) 2_666 ?
Mg2 Na3 3.424(2) 1_655 ?
Mg2 Na4 3.434(5) 2_675 ?
Mg2 Na4 3.663(7) 1_655 ?
Mg2 Na2 3.714(2) 2_775 ?
Mg3 O13 1.977(3) . ?
Mg3 O3 1.985(3) . ?
Mg3 O6 2.010(3) 2_765 ?
Mg3 O4 2.044(3) . ?
Mg3 O2 2.190(3) . ?
Mg3 O7 2.274(3) . ?
Mg3 P3 2.7358(15) . ?
Mg3 Na3 3.241(2) . ?
Mg3 Na1 3.2512(19) . ?
Mg3 Na2 3.321(2) 2_765 ?
Mg3 Na3 3.411(2) 2_665 ?
Mg3 Na3 3.712(3) 1_655 ?
Na1 O12 2.249(3) 1_455 ?
Na1 O14 2.332(4) 2_656 ?
Na1 O7 2.416(3) . ?
Na1 O4 2.504(3) . ?
Na1 O14 2.512(4) . ?
Na1 O9 2.613(3) 2_666 ?
Na1 P4 3.2906(18) . ?
Na1 Mg2 3.3696(19) 2_666 ?
Na1 P3 3.3744(18) 1_455 ?
Na1 P3 3.4042(18) . ?
Na1 P4 3.4426(19) 2_656 ?
Na2 O6 2.352(3) . ?
Na2 O14 2.482(4) 2_665 ?
Na2 O7 2.500(3) 2_765 ?
Na2 O7 2.527(3) 1_564 ?
Na2 O8 2.747(3) 2_765 ?
Na2 P3 3.170(2) 1_564 ?
Na2 P2 3.277(2) . ?
Na2 Mg3 3.321(2) 2_765 ?
Na2 P4 3.399(2) 2_665 ?
Na2 Na2 3.417(4) 2_774 ?
Na2 Na1 3.443(2) 1_564 ?
Na2 P4 3.454(2) 2_765 ?
Na3 O3 2.294(3) 2_665 ?
Na3 O4 2.358(3) . ?
Na3 O5 2.578(3) . ?
Na3 O13 2.693(3) . ?
Na3 O2 2.805(4) 1_455 ?
Na3 O10 2.820(3) 1_455 ?
Na3 O3 2.855(4) . ?
Na3 P1 2.964(2) . ?
Na3 O13 2.967(5) 2_665 ?
Na3 P2 3.147(2) 2_665 ?
Na3 P2 3.405(2) 1_455 ?
Na4 Mg1 1.750(9) 1_455 ?
Na4 O5 2.202(5) . ?
Na4 O10 2.376(5) 2_675 ?
Na4 O11 2.392(7) 2_665 ?
Na4 O8 2.486(6) 2_665 ?
Na4 O11 2.519(7) 1_565 ?
Na4 P4 2.989(4) 2_665 ?
Na4 P2 2.997(4) 2_675 ?
Na4 Na4 3.242(17) 2_675 ?
Na4 Mg2 3.434(5) 2_675 ?
Na4 Na4 3.501(18) 2_575 ?
P1 O9 1.503(3) . ?
P1 O4 1.510(3) . ?
P1 O5 1.521(3) . ?
P1 O1 1.600(3) . ?
P2 O6 1.500(3) . ?
P2 O3 1.502(3) . ?
P2 O10 1.508(3) . ?
P2 O11 1.622(3) 2_665 ?
P2 Na4 2.997(4) 2_675 ?
P2 Na3 3.147(2) 2_665 ?
P2 Na3 3.405(2) 1_655 ?
P3 O12 1.496(3) . ?
P3 O7 1.529(3) . ?
P3 O2 1.530(3) . ?
P3 O1 1.589(3) 2_666 ?
P3 Na2 3.170(2) 1_546 ?
P3 Na1 3.3744(18) 1_655 ?
P4 O13 1.498(3) . ?
P4 O14 1.501(3) . ?
P4 O8 1.512(3) . ?
P4 O11 1.638(3) . ?
P4 Na4 2.989(4) 2_665 ?
P4 Na2 3.399(2) 2_665 ?
P4 Na1 3.4426(19) 2_656 ?
P4 Na2 3.454(2) 2_765 ?
O1 P3 1.589(3) 2_666 ?
O2 Na3 2.805(4) 1_655 ?
O3 Na3 2.294(3) 2_665 ?
O5 Mg2 2.099(3) 1_455 ?
O6 Mg3 2.010(3) 2_765 ?
O7 Na2 2.500(3) 2_765 ?
O7 Na2 2.527(3) 1_546 ?
O8 Mg2 2.077(3) 1_545 ?
O8 Mg1 2.377(3) 1_545 ?
O8 Na4 2.486(6) 2_665 ?
O8 Na2 2.747(3) 2_765 ?
O9 Na1 2.613(3) 2_666 ?
O10 Na4 2.376(5) 2_675 ?
O10 Na3 2.820(3) 1_655 ?
O11 P2 1.622(3) 2_665 ?
O11 Na4 2.392(7) 2_665 ?
O11 Na4 2.519(7) 1_545 ?
O12 Mg2 2.125(3) 2_766 ?
O12 Na1 2.249(3) 1_655 ?
O13 Na3 2.967(5) 2_665 ?
O14 Na1 2.332(4) 2_656 ?
O14 Na2 2.482(4) 2_665 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Na4 Mg1 Na4 180.00(18) 1_655 2_675 ?
Na4 Mg1 O10 71.39(16) 1_655 2_775 ?
Na4 Mg1 O10 108.61(16) 2_675 2_775 ?
Na4 Mg1 O10 108.61(16) 1_655 . ?
Na4 Mg1 O10 71.39(16) 2_675 . ?
O10 Mg1 O10 180.00(14) 2_775 . ?
Na4 Mg1 O8 72.29(16) 1_655 2_765 ?
Na4 Mg1 O8 107.71(16) 2_675 2_765 ?
O10 Mg1 O8 77.71(9) 2_775 2_765 ?
O10 Mg1 O8 102.29(9) . 2_765 ?
Na4 Mg1 O8 107.71(16) 1_655 1_565 ?
Na4 Mg1 O8 72.29(16) 2_675 1_565 ?
O10 Mg1 O8 102.29(9) 2_775 1_565 ?
O10 Mg1 O8 77.71(9) . 1_565 ?
O8 Mg1 O8 180.00(13) 2_765 1_565 ?
Na4 Mg1 Mg2 85.68(14) 1_655 2_775 ?
Na4 Mg1 Mg2 94.32(14) 2_675 2_775 ?
O10 Mg1 Mg2 43.15(7) 2_775 2_775 ?
O10 Mg1 Mg2 136.85(7) . 2_775 ?
O8 Mg1 Mg2 42.22(6) 2_765 2_775 ?
O8 Mg1 Mg2 137.78(6) 1_565 2_775 ?
Na4 Mg1 Mg2 94.31(14) 1_655 . ?
Na4 Mg1 Mg2 85.68(14) 2_675 . ?
O10 Mg1 Mg2 136.85(7) 2_775 . ?
O10 Mg1 Mg2 43.15(7) . . ?
O8 Mg1 Mg2 137.78(6) 2_765 . ?
O8 Mg1 Mg2 42.22(6) 1_565 . ?
Mg2 Mg1 Mg2 180.0 2_775 . ?
Na4 Mg1 Na2 66.43(15) 1_655 2_775 ?
Na4 Mg1 Na2 113.57(15) 2_675 2_775 ?
O10 Mg1 Na2 73.74(7) 2_775 2_775 ?
O10 Mg1 Na2 106.26(7) . 2_775 ?
O8 Mg1 Na2 135.33(7) 2_765 2_775 ?
O8 Mg1 Na2 44.67(7) 1_565 2_775 ?
Mg2 Mg1 Na2 116.67(4) 2_775 2_775 ?
Mg2 Mg1 Na2 63.33(4) . 2_775 ?
Na4 Mg1 Na2 113.57(15) 1_655 . ?
Na4 Mg1 Na2 66.43(15) 2_675 . ?
O10 Mg1 Na2 106.26(7) 2_775 . ?
O10 Mg1 Na2 73.74(7) . . ?
O8 Mg1 Na2 44.67(7) 2_765 . ?
O8 Mg1 Na2 135.33(7) 1_565 . ?
Mg2 Mg1 Na2 63.33(4) 2_775 . ?
Mg2 Mg1 Na2 116.67(4) . . ?
Na2 Mg1 Na2 180.00(5) 2_775 . ?
Na4 Mg1 Na3 116.10(15) 1_655 2_675 ?
Na4 Mg1 Na3 63.90(15) 2_675 2_675 ?
O10 Mg1 Na3 45.45(8) 2_775 2_675 ?
O10 Mg1 Na3 134.55(8) . 2_675 ?
O8 Mg1 Na3 98.61(7) 2_765 2_675 ?
O8 Mg1 Na3 81.39(7) 1_565 2_675 ?
Mg2 Mg1 Na3 57.26(4) 2_775 2_675 ?
Mg2 Mg1 Na3 122.74(4) . 2_675 ?
Na2 Mg1 Na3 85.07(4) 2_775 2_675 ?
Na2 Mg1 Na3 94.93(4) . 2_675 ?
Na4 Mg1 Na3 63.90(15) 1_655 1_655 ?
Na4 Mg1 Na3 116.10(15) 2_675 1_655 ?
O10 Mg1 Na3 134.55(8) 2_775 1_655 ?
O10 Mg1 Na3 45.45(8) . 1_655 ?
O8 Mg1 Na3 81.39(7) 2_765 1_655 ?
O8 Mg1 Na3 98.61(7) 1_565 1_655 ?
Mg2 Mg1 Na3 122.74(4) 2_775 1_655 ?
Mg2 Mg1 Na3 57.26(4) . 1_655 ?
Na2 Mg1 Na3 94.93(4) 2_775 1_655 ?
Na2 Mg1 Na3 85.07(4) . 1_655 ?
Na3 Mg1 Na3 180.000(1) 2_675 1_655 ?
O9 Mg2 O8 90.39(11) . 1_565 ?
O9 Mg2 O5 176.97(12) . 1_655 ?
O8 Mg2 O5 88.57(11) 1_565 1_655 ?
O9 Mg2 O10 99.75(12) . . ?
O8 Mg2 O10 88.00(11) 1_565 . ?
O5 Mg2 O10 83.06(11) 1_655 . ?
O9 Mg2 O12 89.96(12) . 2_766 ?
O8 Mg2 O12 86.72(11) 1_565 2_766 ?
O5 Mg2 O12 87.14(11) 1_655 2_766 ?
O10 Mg2 O12 168.97(12) . 2_766 ?
O9 Mg2 O2 90.70(11) . . ?
O8 Mg2 O2 176.31(11) 1_565 . ?
O5 Mg2 O2 90.51(11) 1_655 . ?
O10 Mg2 O2 88.34(10) . . ?
O12 Mg2 O2 96.81(10) 2_766 . ?
O9 Mg2 Mg1 120.36(9) . . ?
O8 Mg2 Mg1 50.25(8) 1_565 . ?
O5 Mg2 Mg1 60.84(7) 1_655 . ?
O10 Mg2 Mg1 47.04(7) . . ?
O12 Mg2 Mg1 123.10(9) 2_766 . ?
O2 Mg2 Mg1 126.35(8) . . ?
O9 Mg2 Na1 50.79(9) . 2_666 ?
O8 Mg2 Na1 77.65(8) 1_565 2_666 ?
O5 Mg2 Na1 126.19(9) 1_655 2_666 ?
O10 Mg2 Na1 146.30(9) . 2_666 ?
O12 Mg2 Na1 40.96(8) 2_766 2_666 ?
O2 Mg2 Na1 105.74(8) . 2_666 ?
Mg1 Mg2 Na1 127.90(4) . 2_666 ?
O9 Mg2 Na3 133.96(10) . 1_655 ?
O8 Mg2 Na3 122.31(10) 1_565 1_655 ?
O5 Mg2 Na3 48.72(8) 1_655 1_655 ?
O10 Mg2 Na3 55.32(9) . 1_655 ?
O12 Mg2 Na3 120.49(9) 2_766 1_655 ?
O2 Mg2 Na3 54.83(8) . 1_655 ?
Mg1 Mg2 Na3 73.39(5) . 1_655 ?
Na1 Mg2 Na3 155.64(6) 2_666 1_655 ?
O9 Mg2 Na4 89.98(17) . 2_675 ?
O8 Mg2 Na4 45.93(11) 1_565 2_675 ?
O5 Mg2 Na4 91.34(17) 1_655 2_675 ?
O10 Mg2 Na4 43.03(10) . 2_675 ?
O12 Mg2 Na4 132.64(11) 2_766 2_675 ?
O2 Mg2 Na4 130.55(11) . 2_675 ?
Mg1 Mg2 Na4 30.55(15) . 2_675 ?
Na1 Mg2 Na4 112.46(10) 2_666 2_675 ?
Na3 Mg2 Na4 91.88(11) 1_655 2_675 ?
O9 Mg2 Na4 148.51(15) . 1_655 ?
O8 Mg2 Na4 64.77(11) 1_565 1_655 ?
O5 Mg2 Na4 32.46(14) 1_655 1_655 ?
O10 Mg2 Na4 62.36(13) . 1_655 ?
O12 Mg2 Na4 106.62(14) 2_766 1_655 ?
O2 Mg2 Na4 112.96(11) . 1_655 ?
Mg1 Mg2 Na4 28.46(12) . 1_655 ?
Na1 Mg2 Na4 132.68(8) 2_666 1_655 ?
Na3 Mg2 Na4 59.13(8) 1_655 1_655 ?
Na4 Mg2 Na4 59.0(3) 2_675 1_655 ?
O9 Mg2 Na2 119.36(9) . 2_775 ?
O8 Mg2 Na2 46.81(8) 1_565 2_775 ?
O5 Mg2 Na2 58.06(8) 1_655 2_775 ?
O10 Mg2 Na2 115.44(9) . 2_775 ?
O12 Mg2 Na2 54.44(8) 2_766 2_775 ?
O2 Mg2 Na2 135.01(8) . 2_775 ?
Mg1 Mg2 Na2 68.66(4) . 2_775 ?
Na1 Mg2 Na2 75.95(5) 2_666 2_775 ?
Na3 Mg2 Na2 106.63(6) 1_655 2_775 ?
Na4 Mg2 Na2 85.24(12) 2_675 2_775 ?
Na4 Mg2 Na2 57.59(9) 1_655 2_775 ?
O13 Mg3 O3 92.02(13) . . ?
O13 Mg3 O6 92.54(12) . 2_765 ?
O3 Mg3 O6 96.25(12) . 2_765 ?
O13 Mg3 O4 85.44(12) . . ?
O3 Mg3 O4 91.14(12) . . ?
O6 Mg3 O4 172.40(12) 2_765 . ?
O13 Mg3 O2 164.71(13) . . ?
O3 Mg3 O2 102.38(11) . . ?
O6 Mg3 O2 91.01(11) 2_765 . ?
O4 Mg3 O2 89.10(10) . . ?
O13 Mg3 O7 98.09(12) . . ?
O3 Mg3 O7 169.45(11) . . ?
O6 Mg3 O7 86.32(10) 2_765 . ?
O4 Mg3 O7 86.71(11) . . ?
O2 Mg3 O7 67.29(10) . . ?
O13 Mg3 P3 130.89(11) . . ?
O3 Mg3 P3 135.48(9) . . ?
O6 Mg3 P3 93.37(9) 2_765 . ?
O4 Mg3 P3 82.51(8) . . ?
O2 Mg3 P3 33.95(7) . . ?
O7 Mg3 P3 33.98(7) . . ?
O13 Mg3 Na3 56.04(9) . . ?
O3 Mg3 Na3 60.74(10) . . ?
O6 Mg3 Na3 137.00(10) 2_765 . ?
O4 Mg3 Na3 46.48(8) . . ?
O2 Mg3 Na3 127.39(8) . . ?
O7 Mg3 Na3 123.22(10) . . ?
P3 Mg3 Na3 128.96(6) . . ?
O13 Mg3 Na1 67.08(11) . . ?
O3 Mg3 Na1 135.63(10) . . ?
O6 Mg3 Na1 122.16(9) 2_765 . ?
O4 Mg3 Na1 50.37(9) . . ?
O2 Mg3 Na1 98.54(8) . . ?
O7 Mg3 Na1 47.96(8) . . ?
P3 Mg3 Na1 68.69(4) . . ?
Na3 Mg3 Na1 75.44(6) . . ?
O13 Mg3 Na2 77.57(9) . 2_765 ?
O3 Mg3 Na2 137.56(10) . 2_765 ?
O6 Mg3 Na2 44.41(8) 2_765 2_765 ?
O4 Mg3 Na2 128.02(10) . 2_765 ?
O2 Mg3 Na2 94.78(8) . 2_765 ?
O7 Mg3 Na2 48.79(7) . 2_765 ?
P3 Mg3 Na2 73.32(5) . 2_765 ?
Na3 Mg3 Na2 132.53(7) . 2_765 ?
Na1 Mg3 Na2 77.88(5) . 2_765 ?
O13 Mg3 Na3 60.02(12) . 2_665 ?
O3 Mg3 Na3 40.40(9) . 2_665 ?
O6 Mg3 Na3 74.56(9) 2_765 2_665 ?
O4 Mg3 Na3 110.47(9) . 2_665 ?
O2 Mg3 Na3 135.17(9) . 2_665 ?
O7 Mg3 Na3 149.40(9) . 2_665 ?
P3 Mg3 Na3 164.94(7) . 2_665 ?
Na3 Mg3 Na3 64.61(7) . 2_665 ?
Na1 Mg3 Na3 125.28(6) . 2_665 ?
Na2 Mg3 Na3 102.59(6) 2_765 2_665 ?
O13 Mg3 Na3 142.67(11) . 1_655 ?
O3 Mg3 Na3 74.66(9) . 1_655 ?
O6 Mg3 Na3 55.71(9) 2_765 1_655 ?
O4 Mg3 Na3 128.59(9) . 1_655 ?
O2 Mg3 Na3 48.79(7) . 1_655 ?
O7 Mg3 Na3 98.68(8) . 1_655 ?
P3 Mg3 Na3 75.46(5) . 1_655 ?
Na3 Mg3 Na3 133.59(9) . 1_655 ?
Na1 Mg3 Na3 143.99(6) . 1_655 ?
Na2 Mg3 Na3 89.00(6) 2_765 1_655 ?
Na3 Mg3 Na3 90.13(5) 2_665 1_655 ?
O12 Na1 O14 96.77(11) 1_455 2_656 ?
O12 Na1 O7 159.28(11) 1_455 . ?
O14 Na1 O7 90.78(11) 2_656 . ?
O12 Na1 O4 96.02(10) 1_455 . ?
O14 Na1 O4 164.36(12) 2_656 . ?
O7 Na1 O4 74.20(9) . . ?
O12 Na1 O14 99.62(11) 1_455 . ?
O14 Na1 O14 81.05(12) 2_656 . ?
O7 Na1 O14 100.60(11) . . ?
O4 Na1 O14 105.62(11) . . ?
O12 Na1 O9 73.95(10) 1_455 2_666 ?
O14 Na1 O9 75.37(11) 2_656 2_666 ?
O7 Na1 O9 89.47(10) . 2_666 ?
O4 Na1 O9 99.66(10) . 2_666 ?
O14 Na1 O9 154.47(12) . 2_666 ?
O12 Na1 Mg3 133.27(9) 1_455 . ?
O14 Na1 Mg3 129.84(10) 2_656 . ?
O7 Na1 Mg3 44.33(7) . . ?
O4 Na1 Mg3 38.96(6) . . ?
O14 Na1 Mg3 86.36(9) . . ?
O9 Na1 Mg3 116.33(8) 2_666 . ?
O12 Na1 P4 115.84(9) 1_455 . ?
O14 Na1 P4 98.76(9) 2_656 . ?
O7 Na1 P4 81.77(7) . . ?
O4 Na1 P4 83.66(7) . . ?
O14 Na1 P4 25.79(8) . . ?
O9 Na1 P4 169.46(8) 2_666 . ?
Mg3 Na1 P4 60.59(4) . . ?
O12 Na1 Mg2 38.28(7) 1_455 2_666 ?
O14 Na1 Mg2 77.65(9) 2_656 2_666 ?
O7 Na1 Mg2 126.50(8) . 2_666 ?
O4 Na1 Mg2 107.55(8) . 2_666 ?
O14 Na1 Mg2 127.85(9) . 2_666 ?
O9 Na1 Mg2 37.02(7) 2_666 2_666 ?
Mg3 Na1 Mg2 142.07(6) . 2_666 ?
P4 Na1 Mg2 151.19(6) . 2_666 ?
O12 Na1 P3 20.61(7) 1_455 1_455 ?
O14 Na1 P3 109.68(10) 2_656 1_455 ?
O7 Na1 P3 159.35(8) . 1_455 ?
O4 Na1 P3 85.18(7) . 1_455 ?
O14 Na1 P3 85.75(8) . 1_455 ?
O9 Na1 P3 93.01(7) 2_666 1_455 ?
Mg3 Na1 P3 117.56(5) . 1_455 ?
P4 Na1 P3 97.25(5) . 1_455 ?
Mg2 Na1 P3 58.65(4) 2_666 1_455 ?
O12 Na1 P3 135.84(9) 1_455 . ?
O14 Na1 P3 101.10(10) 2_656 . ?
O7 Na1 P3 23.48(6) . . ?
O4 Na1 P3 63.32(7) . . ?
O14 Na1 P3 122.78(9) . . ?
O9 Na1 P3 72.13(7) 2_666 . ?
Mg3 Na1 P3 48.48(3) . . ?
P4 Na1 P3 100.92(5) . . ?
Mg2 Na1 P3 107.84(5) 2_666 . ?
P3 Na1 P3 141.17(5) 1_455 . ?
O12 Na1 P4 77.60(8) 1_455 2_656 ?
O14 Na1 P4 20.52(8) 2_656 2_656 ?
O7 Na1 P4 106.28(8) . 2_656 ?
O4 Na1 P4 162.61(8) . 2_656 ?
O14 Na1 P4 91.46(9) . 2_656 ?
O9 Na1 P4 63.11(7) 2_666 2_656 ?
Mg3 Na1 P4 148.99(6) . 2_656 ?
P4 Na1 P4 113.70(5) . 2_656 ?
Mg2 Na1 P4 57.67(4) 2_666 2_656 ?
P3 Na1 P4 93.06(4) 1_455 2_656 ?
P3 Na1 P4 110.15(5) . 2_656 ?
O6 Na2 O14 81.58(12) . 2_665 ?
O6 Na2 O7 74.43(10) . 2_765 ?
O14 Na2 O7 99.18(12) 2_665 2_765 ?
O6 Na2 O7 160.73(13) . 1_564 ?
O14 Na2 O7 84.90(11) 2_665 1_564 ?
O7 Na2 O7 94.38(10) 2_765 1_564 ?
O6 Na2 O8 85.01(10) . 2_765 ?
O14 Na2 O8 150.48(12) 2_665 2_765 ?
O7 Na2 O8 102.36(10) 2_765 2_765 ?
O7 Na2 O8 113.08(10) 1_564 2_765 ?
O6 Na2 P3 170.87(11) . 1_564 ?
O14 Na2 P3 104.27(10) 2_665 1_564 ?
O7 Na2 P3 110.97(9) 2_765 1_564 ?
O7 Na2 P3 28.38(6) 1_564 1_564 ?
O8 Na2 P3 86.60(8) 2_765 1_564 ?
O6 Na2 P2 24.57(7) . . ?
O14 Na2 P2 73.22(9) 2_665 . ?
O7 Na2 P2 98.63(8) 2_765 . ?
O7 Na2 P2 156.01(10) 1_564 . ?
O8 Na2 P2 83.73(7) 2_765 . ?
P3 Na2 P2 150.20(7) 1_564 . ?
O6 Na2 Mg3 36.74(7) . 2_765 ?
O14 Na2 Mg3 104.72(10) 2_665 2_765 ?
O7 Na2 Mg3 43.17(7) 2_765 2_765 ?
O7 Na2 Mg3 137.08(10) 1_564 2_765 ?
O8 Na2 Mg3 78.53(7) 2_765 2_765 ?
P3 Na2 Mg3 143.97(7) 1_564 2_765 ?
P2 Na2 Mg3 60.62(4) . 2_765 ?
O6 Na2 P4 65.74(8) . 2_665 ?
O14 Na2 P4 23.60(7) 2_665 2_665 ?
O7 Na2 P4 109.49(9) 2_765 2_665 ?
O7 Na2 P4 104.89(9) 1_564 2_665 ?
O8 Na2 P4 127.59(9) 2_765 2_665 ?
P3 Na2 P4 117.41(6) 1_564 2_665 ?
P2 Na2 P4 51.68(4) . 2_665 ?
Mg3 Na2 P4 97.42(6) 2_765 2_665 ?
O6 Na2 Na2 120.12(11) . 2_774 ?
O14 Na2 Na2 92.92(11) 2_665 2_774 ?
O7 Na2 Na2 47.52(8) 2_765 2_774 ?
O7 Na2 Na2 46.85(7) 1_564 2_774 ?
O8 Na2 Na2 116.52(11) 2_765 2_774 ?
P3 Na2 Na2 67.11(6) 1_564 2_774 ?
P2 Na2 Na2 141.78(9) . 2_774 ?
Mg3 Na2 Na2 90.46(7) 2_765 2_774 ?
P4 Na2 Na2 115.74(9) 2_665 2_774 ?
O6 Na2 Na1 124.15(10) . 1_564 ?
O14 Na2 Na1 42.61(9) 2_665 1_564 ?
O7 Na2 Na1 110.18(9) 2_765 1_564 ?
O7 Na2 Na1 44.54(7) 1_564 1_564 ?
O8 Na2 Na1 140.71(9) 2_765 1_564 ?
P3 Na2 Na1 61.80(5) 1_564 1_564 ?
P2 Na2 Na1 111.65(7) . 1_564 ?
Mg3 Na2 Na1 140.73(7) 2_765 1_564 ?
P4 Na2 Na1 60.41(5) 2_665 1_564 ?
Na2 Na2 Na1 74.05(7) 2_774 1_564 ?
O6 Na2 P4 77.16(9) . 2_765 ?
O14 Na2 P4 158.62(10) 2_665 2_765 ?
O7 Na2 P4 77.33(8) 2_765 2_765 ?
O7 Na2 P4 116.27(9) 1_564 2_765 ?
O8 Na2 P4 25.05(6) 2_765 2_765 ?
P3 Na2 P4 96.57(6) 1_564 2_765 ?
P2 Na2 P4 86.34(5) . 2_765 ?
Mg3 Na2 P4 58.26(4) 2_765 2_765 ?
P4 Na2 P4 137.80(7) 2_665 2_765 ?
Na2 Na2 P4 99.61(8) 2_774 2_765 ?
Na1 Na2 P4 158.34(7) 1_564 2_765 ?
O3 Na3 O4 136.96(13) 2_665 . ?
O3 Na3 O5 161.74(13) 2_665 . ?
O4 Na3 O5 61.10(9) . . ?
O3 Na3 O13 71.97(10) 2_665 . ?
O4 Na3 O13 64.99(10) . . ?
O5 Na3 O13 126.04(11) . . ?
O3 Na3 O2 111.80(13) 2_665 1_455 ?
O4 Na3 O2 82.88(11) . 1_455 ?
O5 Na3 O2 68.17(9) . 1_455 ?
O13 Na3 O2 107.93(13) . 1_455 ?
O3 Na3 O10 100.88(11) 2_665 1_455 ?
O4 Na3 O10 121.40(10) . 1_455 ?
O5 Na3 O10 62.10(8) . 1_455 ?
O13 Na3 O10 166.89(13) . 1_455 ?
O2 Na3 O10 63.85(9) 1_455 1_455 ?
O3 Na3 O3 93.31(11) 2_665 . ?
O4 Na3 O3 66.21(10) . . ?
O5 Na3 O3 93.67(10) . . ?
O13 Na3 O3 61.73(10) . . ?
O2 Na3 O3 149.01(10) 1_455 . ?
O10 Na3 O3 130.69(13) 1_455 . ?
O3 Na3 P1 166.62(11) 2_665 . ?
O4 Na3 P1 30.34(6) . . ?
O5 Na3 P1 30.86(6) . . ?
O13 Na3 P1 95.18(9) . . ?
O2 Na3 P1 75.15(7) 1_455 . ?
O10 Na3 P1 92.45(8) 1_455 . ?
O3 Na3 P1 76.86(8) . . ?
O3 Na3 O13 64.12(10) 2_665 2_665 ?
O4 Na3 O13 124.09(13) . 2_665 ?
O5 Na3 O13 105.18(12) . 2_665 ?
O13 Na3 O13 102.28(11) . 2_665 ?
O2 Na3 O13 146.38(11) 1_455 2_665 ?
O10 Na3 O13 83.64(10) 1_455 2_665 ?
O3 Na3 O13 60.80(9) . 2_665 ?
P1 Na3 O13 116.84(10) . 2_665 ?
O3 Na3 P2 26.61(7) 2_665 2_665 ?
O4 Na3 P2 123.46(11) . 2_665 ?
O5 Na3 P2 156.56(12) . 2_665 ?
O13 Na3 P2 64.86(7) . 2_665 ?
O2 Na3 P2 89.03(9) 1_455 2_665 ?
O10 Na3 P2 103.73(8) 1_455 2_665 ?
O3 Na3 P2 109.26(8) . 2_665 ?
P1 Na3 P2 149.67(10) . 2_665 ?
O13 Na3 P2 90.67(7) 2_665 2_665 ?
O3 Na3 Mg3 102.39(10) 2_665 . ?
O4 Na3 Mg3 38.96(7) . . ?
O5 Na3 Mg3 93.34(8) . . ?
O13 Na3 Mg3 37.50(7) . . ?
O2 Na3 Mg3 116.00(9) 1_455 . ?
O10 Na3 Mg3 154.35(9) 1_455 . ?
O3 Na3 Mg3 37.33(6) . . ?
P1 Na3 Mg3 64.30(5) . . ?
O13 Na3 Mg3 96.94(9) 2_665 . ?
P2 Na3 Mg3 101.90(6) 2_665 . ?
O3 Na3 P2 75.16(9) 2_665 1_455 ?
O4 Na3 P2 145.91(10) . 1_455 ?
O5 Na3 P2 88.02(8) . 1_455 ?
O13 Na3 P2 144.12(9) . 1_455 ?
O2 Na3 P2 71.64(7) 1_455 1_455 ?
O10 Na3 P2 25.92(5) 1_455 1_455 ?
O3 Na3 P2 134.91(11) . 1_455 ?
P1 Na3 P2 118.22(7) . 1_455 ?
O13 Na3 P2 75.27(8) 2_665 1_455 ?
P2 Na3 P2 79.31(5) 2_665 1_455 ?
Mg3 Na3 P2 172.17(10) . 1_455 ?
Mg1 Na4 O5 87.9(3) 1_455 . ?
Mg1 Na4 O10 64.3(2) 1_455 2_675 ?
O5 Na4 O10 133.3(3) . 2_675 ?
Mg1 Na4 O11 125.2(3) 1_455 2_665 ?
O5 Na4 O11 117.5(2) . 2_665 ?
O10 Na4 O11 109.2(2) 2_675 2_665 ?
Mg1 Na4 O8 65.6(2) 1_455 2_665 ?
O5 Na4 O8 129.9(3) . 2_665 ?
O10 Na4 O8 73.49(18) 2_675 2_665 ?
O11 Na4 O8 60.94(14) 2_665 2_665 ?
Mg1 Na4 O11 118.7(2) 1_455 1_565 ?
O5 Na4 O11 111.1(2) . 1_565 ?
O10 Na4 O11 60.74(14) 2_675 1_565 ?
O11 Na4 O11 97.4(3) 2_665 1_565 ?
O8 Na4 O11 118.9(2) 2_665 1_565 ?
Mg1 Na4 P4 92.1(2) 1_455 2_665 ?
O5 Na4 P4 120.99(19) . 2_665 ?
O10 Na4 P4 97.97(17) 2_675 2_665 ?
O11 Na4 P4 33.15(9) 2_665 2_665 ?
O8 Na4 P4 30.31(8) 2_665 2_665 ?
O11 Na4 P4 120.0(2) 1_565 2_665 ?
Mg1 Na4 P2 86.76(19) 1_455 2_675 ?
O5 Na4 P2 120.51(18) . 2_675 ?
O10 Na4 P2 29.83(8) 2_675 2_675 ?
O11 Na4 P2 113.5(2) 2_665 2_675 ?
O8 Na4 P2 100.54(16) 2_665 2_675 ?
O11 Na4 P2 32.77(8) 1_565 2_675 ?
P4 Na4 P2 118.40(14) 2_665 2_675 ?
Mg1 Na4 Na4 142.9(3) 1_455 2_675 ?
O5 Na4 Na4 128.3(4) . 2_675 ?
O10 Na4 Na4 82.11(19) 2_675 2_675 ?
O11 Na4 Na4 50.40(18) 2_665 2_675 ?
O8 Na4 Na4 91.0(2) 2_665 2_675 ?
O11 Na4 Na4 47.04(18) 1_565 2_675 ?
P4 Na4 Na4 76.73(17) 2_665 2_675 ?
P2 Na4 Na4 68.95(16) 2_675 2_675 ?
Mg1 Na4 Mg2 63.76(16) 1_455 2_675 ?
O5 Na4 Mg2 151.5(4) . 2_675 ?
O10 Na4 Mg2 37.34(10) 2_675 2_675 ?
O11 Na4 Mg2 80.13(13) 2_665 2_675 ?
O8 Na4 Mg2 36.89(9) 2_665 2_675 ?
O11 Na4 Mg2 86.72(13) 1_565 2_675 ?
P4 Na4 Mg2 61.09(9) 2_665 2_675 ?
P2 Na4 Mg2 63.72(9) 2_675 2_675 ?
Na4 Na4 Mg2 80.16(16) 2_675 2_675 ?
Mg1 Na4 Na4 0.00(16) 1_455 2_575 ?
O5 Na4 Na4 87.9(3) . 2_575 ?
O10 Na4 Na4 64.3(2) 2_675 2_575 ?
O11 Na4 Na4 125.2(3) 2_665 2_575 ?
O8 Na4 Na4 65.6(2) 2_665 2_575 ?
O11 Na4 Na4 118.7(2) 1_565 2_575 ?
P4 Na4 Na4 92.1(2) 2_665 2_575 ?
P2 Na4 Na4 86.76(19) 2_675 2_575 ?
Na4 Na4 Na4 142.9(3) 2_675 2_575 ?
Mg2 Na4 Na4 63.76(16) 2_675 2_575 ?
Mg1 Na4 Na3 89.4(2) 1_455 . ?
O5 Na4 Na3 47.24(12) . . ?
O10 Na4 Na3 152.5(4) 2_675 . ?
O11 Na4 Na3 78.44(13) 2_665 . ?
O8 Na4 Na3 88.80(17) 2_665 . ?
O11 Na4 Na3 146.1(3) 1_565 . ?
P4 Na4 Na3 73.75(10) 2_665 . ?
P2 Na4 Na3 167.37(18) 2_675 . ?
Na4 Na4 Na3 119.8(3) 2_675 . ?
Mg2 Na4 Na3 124.78(19) 2_675 . ?
Na4 Na4 Na3 89.4(2) 2_575 . ?
O9 P1 O4 114.72(16) . . ?
O9 P1 O5 112.14(16) . . ?
O4 P1 O5 112.20(15) . . ?
O9 P1 O1 107.12(15) . . ?
O4 P1 O1 103.60(14) . . ?
O5 P1 O1 106.17(14) . . ?
O9 P1 Na3 130.76(13) . . ?
O4 P1 Na3 52.05(11) . . ?
O5 P1 Na3 60.41(11) . . ?
O1 P1 Na3 121.89(12) . . ?
O6 P2 O3 112.07(15) . . ?
O6 P2 O10 114.02(16) . . ?
O3 P2 O10 112.67(15) . . ?
O6 P2 O11 104.60(15) . 2_665 ?
O3 P2 O11 108.06(15) . 2_665 ?
O10 P2 O11 104.62(14) . 2_665 ?
O6 P2 Na4 105.18(15) . 2_675 ?
O3 P2 Na4 142.56(16) . 2_675 ?
O10 P2 Na4 51.63(18) . 2_675 ?
O11 P2 Na4 57.2(2) 2_665 2_675 ?
O6 P2 Na3 73.12(12) . 2_665 ?
O3 P2 Na3 43.14(12) . 2_665 ?
O10 P2 Na3 149.65(12) . 2_665 ?
O11 P2 Na3 101.54(10) 2_665 2_665 ?
Na4 P2 Na3 158.06(17) 2_675 2_665 ?
O6 P2 Na2 40.69(11) . . ?
O3 P2 Na2 143.40(11) . . ?
O10 P2 Na2 102.75(12) . . ?
O11 P2 Na2 69.95(11) 2_665 . ?
Na4 P2 Na2 68.83(9) 2_675 . ?
Na3 P2 Na2 100.44(7) 2_665 . ?
O6 P2 Na3 79.75(12) . 1_655 ?
O3 P2 Na3 89.86(12) . 1_655 ?
O10 P2 Na3 54.85(11) . 1_655 ?
O11 P2 Na3 157.65(10) 2_665 1_655 ?
Na4 P2 Na3 100.47(18) 2_675 1_655 ?
Na3 P2 Na3 100.69(5) 2_665 1_655 ?
Na2 P2 Na3 103.67(7) . 1_655 ?
O12 P3 O7 113.40(15) . . ?
O12 P3 O2 116.33(15) . . ?
O7 P3 O2 107.94(14) . . ?
O12 P3 O1 107.27(14) . 2_666 ?
O7 P3 O1 106.96(15) . 2_666 ?
O2 P3 O1 104.16(14) . 2_666 ?
O12 P3 Mg3 145.97(11) . . ?
O7 P3 Mg3 56.21(10) . . ?
O2 P3 Mg3 53.07(10) . . ?
O1 P3 Mg3 106.75(10) 2_666 . ?
O12 P3 Na2 70.56(11) . 1_546 ?
O7 P3 Na2 51.78(11) . 1_546 ?
O2 P3 Na2 156.77(11) . 1_546 ?
O1 P3 Na2 93.90(11) 2_666 1_546 ?
Mg3 P3 Na2 107.98(5) . 1_546 ?
O12 P3 Na1 31.94(10) . 1_655 ?
O7 P3 Na1 104.80(11) . 1_655 ?
O2 P3 Na1 92.61(10) . 1_655 ?
O1 P3 Na1 137.04(10) 2_666 1_655 ?
Mg3 P3 Na1 114.81(5) . 1_655 ?
Na2 P3 Na1 83.65(5) 1_546 1_655 ?
O12 P3 Na1 132.74(12) . . ?
O7 P3 Na1 39.03(10) . . ?
O2 P3 Na1 109.93(10) . . ?
O1 P3 Na1 68.71(10) 2_666 . ?
Mg3 P3 Na1 62.84(4) . . ?
Na2 P3 Na1 63.06(5) 1_546 . ?
Na1 P3 Na1 141.17(5) 1_655 . ?
O13 P4 O14 113.0(2) . . ?
O13 P4 O8 112.32(17) . . ?
O14 P4 O8 114.83(17) . . ?
O13 P4 O11 104.52(15) . . ?
O14 P4 O11 107.53(17) . . ?
O8 P4 O11 103.53(14) . . ?
O13 P4 Na4 100.14(17) . 2_665 ?
O14 P4 Na4 145.69(19) . 2_665 ?
O8 P4 Na4 56.12(18) . 2_665 ?
O11 P4 Na4 53.0(2) . 2_665 ?
O13 P4 Na1 68.59(14) . . ?
O14 P4 Na1 46.74(14) . . ?
O8 P4 Na1 121.78(11) . . ?
O11 P4 Na1 133.67(10) . . ?
Na4 P4 Na1 167.41(14) 2_665 . ?
O13 P4 Na2 121.89(13) . 2_665 ?
O14 P4 Na2 41.46(13) . 2_665 ?
O8 P4 Na2 125.76(11) . 2_665 ?
O11 P4 Na2 66.10(11) . 2_665 ?
Na4 P4 Na2 112.58(18) 2_665 2_665 ?
Na1 P4 Na2 79.05(5) . 2_665 ?
O13 P4 Na1 133.09(14) . 2_656 ?
O14 P4 Na1 33.00(13) . 2_656 ?
O8 P4 Na1 81.93(11) . 2_656 ?
O11 P4 Na1 115.47(11) . 2_656 ?
Na4 P4 Na1 122.96(9) 2_665 2_656 ?
Na1 P4 Na1 66.30(5) . 2_656 ?
Na2 P4 Na1 60.44(4) 2_665 2_656 ?
O13 P4 Na2 78.50(12) . 2_765 ?
O14 P4 Na2 97.93(13) . 2_765 ?
O8 P4 Na2 50.31(11) . 2_765 ?
O11 P4 Na2 150.22(11) . 2_765 ?
Na4 P4 Na2 97.23(18) 2_665 2_765 ?
Na1 P4 Na2 75.50(5) . 2_765 ?
Na2 P4 Na2 137.80(7) 2_665 2_765 ?
Na1 P4 Na2 78.57(5) 2_656 2_765 ?
P3 O1 P1 133.71(17) 2_666 . ?
P3 O2 Mg2 128.55(14) . . ?
P3 O2 Mg3 92.97(12) . . ?
Mg2 O2 Mg3 117.40(12) . . ?
P3 O2 Na3 133.98(14) . 1_655 ?
Mg2 O2 Na3 86.23(10) . 1_655 ?
Mg3 O2 Na3 95.23(10) . 1_655 ?
P2 O3 Mg3 134.18(17) . . ?
P2 O3 Na3 110.25(16) . 2_665 ?
Mg3 O3 Na3 105.50(13) . 2_665 ?
P2 O3 Na3 127.07(15) . . ?
Mg3 O3 Na3 81.94(11) . . ?
Na3 O3 Na3 86.69(11) 2_665 . ?
P1 O4 Mg3 136.69(17) . . ?
P1 O4 Na3 97.61(14) . . ?
Mg3 O4 Na3 94.55(11) . . ?
P1 O4 Na1 123.22(15) . . ?
Mg3 O4 Na1 90.68(10) . . ?
Na3 O4 Na1 109.52(12) . . ?
P1 O5 Mg2 129.19(16) . 1_455 ?
P1 O5 Na4 113.7(3) . . ?
Mg2 O5 Na4 116.8(3) 1_455 . ?
P1 O5 Na3 88.73(13) . . ?
Mg2 O5 Na3 93.56(11) 1_455 . ?
Na4 O5 Na3 93.93(16) . . ?
P2 O6 Mg3 142.68(17) . 2_765 ?
P2 O6 Na2 114.74(15) . . ?
Mg3 O6 Na2 98.85(12) 2_765 . ?
P3 O7 Mg3 89.81(12) . . ?
P3 O7 Na1 117.49(14) . . ?
Mg3 O7 Na1 87.72(10) . . ?
P3 O7 Na2 128.01(16) . 2_765 ?
Mg3 O7 Na2 88.03(10) . 2_765 ?
Na1 O7 Na2 114.32(11) . 2_765 ?
P3 O7 Na2 99.84(13) . 1_546 ?
Mg3 O7 Na2 170.34(13) . 1_546 ?
Na1 O7 Na2 88.27(10) . 1_546 ?
Na2 O7 Na2 85.62(10) 2_765 1_546 ?
P4 O8 Mg2 131.97(17) . 1_545 ?
P4 O8 Mg1 128.17(15) . 1_545 ?
Mg2 O8 Mg1 87.53(9) 1_545 1_545 ?
P4 O8 Na4 93.6(2) . 2_665 ?
Mg2 O8 Na4 97.19(14) 1_545 2_665 ?
Mg1 O8 Na4 42.1(2) 1_545 2_665 ?
P4 O8 Na2 104.64(13) . 2_765 ?
Mg2 O8 Na2 99.74(11) 1_545 2_765 ?
Mg1 O8 Na2 97.86(10) 1_545 2_765 ?
Na4 O8 Na2 135.5(2) 2_665 2_765 ?
P1 O9 Mg2 140.54(17) . . ?
P1 O9 Na1 114.73(16) . 2_666 ?
Mg2 O9 Na1 92.19(11) . 2_666 ?
P2 O10 Mg2 140.64(17) . . ?
P2 O10 Mg1 126.70(15) . . ?
Mg2 O10 Mg1 89.81(10) . . ?
P2 O10 Na4 98.5(2) . 2_675 ?
Mg2 O10 Na4 99.63(16) . 2_675 ?
Mg1 O10 Na4 44.3(2) . 2_675 ?
P2 O10 Na3 99.23(13) . 1_655 ?
Mg2 O10 Na3 86.66(10) . 1_655 ?
Mg1 O10 Na3 99.71(11) . 1_655 ?
Na4 O10 Na3 142.8(2) 2_675 1_655 ?
P2 O11 P4 126.50(15) 2_665 . ?
P2 O11 Na4 122.4(2) 2_665 2_665 ?
P4 O11 Na4 93.9(2) . 2_665 ?
P2 O11 Na4 90.0(2) 2_665 1_545 ?
P4 O11 Na4 136.29(19) . 1_545 ?
Na4 O11 Na4 82.6(3) 2_665 1_545 ?
P3 O12 Mg2 130.80(15) . 2_766 ?
P3 O12 Na1 127.45(15) . 1_655 ?
Mg2 O12 Na1 100.75(11) 2_766 1_655 ?
P4 O13 Mg3 143.14(19) . . ?
P4 O13 Na3 124.11(17) . . ?
Mg3 O13 Na3 86.45(11) . . ?
P4 O13 Na3 118.92(17) . 2_665 ?
Mg3 O13 Na3 84.74(12) . 2_665 ?
Na3 O13 Na3 77.72(11) . 2_665 ?
P4 O14 Na1 126.48(18) . 2_656 ?
P4 O14 Na2 114.94(17) . 2_665 ?
Na1 O14 Na2 91.29(13) 2_656 2_665 ?
P4 O14 Na1 107.48(19) . . ?
Na1 O14 Na1 98.95(12) 2_656 . ?
Na2 O14 Na1 117.00(13) 2_665 . ?

_diffrn_measured_fraction_theta_max 0.989
_diffrn_reflns_theta_full        27.50
_diffrn_measured_fraction_theta_full 0.989
_refine_diff_density_max         0.536
_refine_diff_density_min         -0.582
_refine_diff_density_rms         0.127
