# Electronic Supplementary Material (ESI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2016

 
data_cluster1
 
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'C372 H446 Cd24 Eu8 N24 O142' 
_chemical_formula_weight          11438.81 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cd'  'Cd'  -0.8075   1.2024 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Eu'  'Eu'  -0.1578   3.6682 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            Tetragonal 
_symmetry_space_group_name_H-M    P-4n2 
_symmetry_space_group_name_Hall   P-4-2n
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, -y, z' 
 'y, -x, -z' 
 '-y, x, -z' 
 'x+1/2, -y+1/2, z+1/2' 
 '-x+1/2, y+1/2, z+1/2' 
 'y+1/2, x+1/2, -z+1/2' 
 '-y+1/2, -x+1/2, -z+1/2' 
 
_cell_length_a                    42.723(6) 
_cell_length_b                    42.723(6) 
_cell_length_c                    37.856(8) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  90.00 
_cell_angle_gamma                 90.00 
_cell_volume                      69097(20) 
_cell_formula_units_Z             4 
_cell_measurement_temperature     223(1) 
_cell_measurement_reflns_used     30562 
_cell_measurement_theta_min       1.2365 
_cell_measurement_theta_max       28.2180 
 
_exptl_crystal_description        Block 
_exptl_crystal_colour             Yellow
_exptl_crystal_size_max           0.18 
_exptl_crystal_size_mid           0.17
_exptl_crystal_size_min           0.13 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.100 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              22552 
_exptl_absorpt_coefficient_mu     1.489 
_exptl_absorpt_correction_type    Multi-scan 
_exptl_absorpt_correction_T_min   0.531604 
_exptl_absorpt_correction_T_max   1.000000 
_exptl_absorpt_process_details    
'DENZO and Scalepack (Otwinoski and Minor, 1997)'
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       223(1) 
_diffrn_radiation_wavelength      0.710747 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'Sealed tube' 
_diffrn_radiation_monochromator   'Graphite Monochromator' 
_diffrn_measurement_device_type   'Mercury2 (2x2 bin mode)' 
_diffrn_measurement_method        'dtprofit.ref' 
_diffrn_detector_area_resol_mean  13.6612 
_diffrn_reflns_number             57809 
_diffrn_reflns_av_R_equivalents   0.0000 
_diffrn_reflns_av_sigmaI/netI     0.1040 
_diffrn_reflns_limit_h_min        0 
_diffrn_reflns_limit_h_max        50 
_diffrn_reflns_limit_k_min        0 
_diffrn_reflns_limit_k_max        50 
_diffrn_reflns_limit_l_min        0 
_diffrn_reflns_limit_l_max        43 
_diffrn_reflns_theta_min          3.01 
_diffrn_reflns_theta_max          25.00 
_reflns_number_total              57809 
_reflns_number_gt                 30161 
_reflns_threshold_expression      >2sigma(I) 
 
_publ_section_acknowledgements
;
The data were collected using instrumentation purchased with funds provided
by the National Science Foundation Grant No. 0741973.
;

_publ_section_references
;
Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., 
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R. Sir97.  
(1999) J. Appl. Cryst. 32, 115-119.

Otwinowski, Z. and Minor, W.  (1997).  Methods in Enzymology,
276, Macromolecular Crystallography, part A, 307-326, C. W. Carter,
Jr. and R. M. Sweets, Eds., Academic Press.

Sheldrick, G. M.  (1998).  SHELXTL/PC.  Release 5.10.  Siemens 
Analytical X-ray Instruments, Inc., Madison, WI, USA.


;
_computing_data_collection        'Collect software, Nonius B.V. 1998'
_computing_cell_refinement        'Collect software, Nonius B.V. 1998'
_computing_data_reduction         
;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
_computing_structure_solution     
;

SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., 
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_computing_structure_refinement   'XL SHELXTL/PC, Siemens Analytical'
_computing_molecular_graphics     'XP SHELXTL/PC, Siemens Analytical' 
_computing_publication_material   ? 


  
_refine_special_details 
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 

 Some uncoordinated solvent molecules such as MeOH and H2O molecules 
 were found to be badly disordered. Attempts to model the disorder were 
 unsatisfactory. The contributions to the scattering factors due to these 
 solvent molecules were removed by use of the utility SQUEEZE (Sluis and 
 Spek, 1990) in PLATON98 (Spek, 1998). PLATON98 was used as incorporated 
 in WinGX (Farrugia, 1999).

 Restraints: ISOR was applied to all non-hydrogen atoms to allow their Uij 
 components approximate to isotropic behavior.

;
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc  
_refine_ls_weighting_details 
 'calc w=1/[σ²(Fo²)+(0.1736P)²+0.0000P] where P=(Fo²+2Fc²)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     constr
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_abs_structure_details 
 'Flack H D (1983), Acta Cryst. A39, 876-881' 
_refine_ls_abs_structure_Flack    0.00 
_refine_ls_number_reflns          57809 
_refine_ls_number_parameters      2566 
_refine_ls_number_restraints      1739 
_refine_ls_R_factor_all           0.1553 
_refine_ls_R_factor_gt            0.0916 
_refine_ls_wR_factor_ref          0.2587 
_refine_ls_wR_factor_gt           0.2165 
_refine_ls_goodness_of_fit_ref    0.908 
_refine_ls_restrained_S_all       0.913 
_refine_ls_shift/su_max           0.021 
_refine_ls_shift/su_mean          0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Eu1 Eu 1.111216(17) 0.196495(17) 0.39319(2) 0.0510(2) Uani 1 1 d U . . 
Eu2 Eu 1.248412(17) 0.388048(17) 0.39652(2) 0.0529(2) Uani 1 1 d U . . 
Eu3 Eu 1.436628(18) 0.250500(18) 0.39768(2) 0.0573(2) Uani 1 1 d U . . 
Eu4 Eu 1.300486(17) 0.059086(18) 0.39272(2) 0.0542(2) Uani 1 1 d U . . 
Cd1 Cd 1.13798(3) 0.28202(2) 0.39038(3) 0.0522(3) Uani 1 1 d U . . 
Cd2 Cd 1.12487(3) 0.35265(3) 0.47207(3) 0.0737(4) Uani 1 1 d U . . 
Cd3 Cd 1.16276(3) 0.38813(2) 0.39946(3) 0.0606(3) Uani 1 1 d U . . 
Cd4 Cd 1.33399(2) 0.36031(3) 0.39214(3) 0.0527(3) Uani 1 1 d U . . 
Cd5 Cd 1.40390(4) 0.37510(4) 0.47457(4) 0.0878(5) Uani 1 1 d U . . 
Cd6 Cd 1.43759(3) 0.33565(3) 0.40154(3) 0.0626(3) Uani 1 1 d U . . 
Cd7 Cd 1.40969(3) 0.16478(3) 0.39104(3) 0.0564(3) Uani 1 1 d U . . 
Cd8 Cd 1.42279(3) 0.09113(3) 0.47266(3) 0.0702(4) Uani 1 1 d U . . 
Cd9 Cd 1.38585(2) 0.06031(3) 0.39595(3) 0.0565(3) Uani 1 1 d U . . 
Cd10 Cd 1.21494(3) 0.08566(3) 0.38875(3) 0.0521(3) Uani 1 1 d U . . 
Cd11 Cd 1.14266(3) 0.07169(3) 0.46861(3) 0.0573(3) Uani 1 1 d U . . 
Cd12 Cd 1.11104(2) 0.11104(2) 0.39434(3) 0.0518(3) Uani 1 1 d U . . 
N1 N 1.0954(3) 0.3074(3) 0.3664(3) 0.050(3) Uani 1 1 d U . . 
N2 N 1.1368(3) 0.4104(3) 0.3560(3) 0.064(4) Uani 1 1 d U . . 
N3 N 1.0596(3) 0.2075(3) 0.3594(3) 0.064(4) Uani 1 1 d U . . 
N4 N 1.2589(3) 0.4394(3) 0.3644(3) 0.055(3) Uani 1 1 d U . . 
N5 N 1.3607(3) 0.4040(3) 0.3690(4) 0.065(4) Uani 1 1 d DU . . 
N6 N 1.0883(3) 0.0843(3) 0.3502(3) 0.061(3) Uani 1 1 d U . . 
N7 N 1.4605(3) 0.3612(3) 0.3593(3) 0.055(3) Uani 1 1 d U . . 
N8 N 1.1900(3) 0.0433(3) 0.3626(3) 0.051(3) Uani 1 1 d U . . 
N9 N 1.4884(3) 0.2412(3) 0.3663(3) 0.061(3) Uani 1 1 d U . . 
N10 N 1.2892(3) 0.0084(3) 0.3571(3) 0.063(4) Uani 1 1 d U . . 
N11 N 1.4146(3) 0.0368(3) 0.3531(3) 0.064(4) Uani 1 1 d U . . 
N12 N 1.4525(3) 0.1401(3) 0.3667(3) 0.057(3) Uani 1 1 d U . . 
O1 O 1.0715(2) 0.2098(2) 0.4429(3) 0.062(3) Uani 1 1 d U . . 
O2 O 1.0989(2) 0.2488(2) 0.4016(2) 0.053(2) Uani 1 1 d U . . 
O3 O 1.1169(3) 0.3771(3) 0.4207(3) 0.075(3) Uani 1 1 d U . . 
O4 O 1.0707(3) 0.3535(3) 0.4563(3) 0.093(4) Uani 1 1 d DU . . 
O5 O 1.0616(2) 0.1034(2) 0.4281(3) 0.063(3) Uani 1 1 d U . . 
O6 O 1.0775(2) 0.1532(2) 0.3921(3) 0.058(3) Uani 1 1 d U . . 
O7 O 1.2047(2) 0.4209(2) 0.3980(3) 0.065(3) Uani 1 1 d U . . 
O8 O 1.1563(2) 0.4362(2) 0.4368(3) 0.053(3) Uani 1 1 d U . . 
O9 O 1.2623(3) 0.4259(2) 0.4479(3) 0.066(3) Uani 1 1 d U . . 
O10 O 1.3004(2) 0.3997(2) 0.4051(2) 0.057(3) Uani 1 1 d U . . 
O11 O 1.1218(2) 0.0632(2) 0.4169(3) 0.055(3) Uani 1 1 d U . . 
O12 O 1.1449(2) 0.0161(2) 0.4504(3) 0.057(3) Uani 1 1 d U . . 
O13 O 1.4085(3) 0.4292(3) 0.4580(4) 0.096(4) Uani 1 1 d DU . . 
O14 O 1.4274(3) 0.3822(3) 0.4239(3) 0.075(3) Uani 1 1 d U . . 
O15 O 1.2487(2) 0.0464(2) 0.4005(2) 0.053(2) Uani 1 1 d U . . 
O16 O 1.2885(3) 0.0193(3) 0.4422(3) 0.067(3) Uani 1 1 d U . . 
O17 O 1.4855(3) 0.3399(3) 0.4414(3) 0.083(4) Uani 1 1 d U . . 
O18 O 1.4699(3) 0.2930(2) 0.4026(3) 0.068(3) Uani 1 1 d U . . 
O19 O 1.3449(2) 0.0264(2) 0.3918(3) 0.057(2) Uani 1 1 d U . . 
O20 O 1.3936(2) 0.0101(2) 0.4306(3) 0.065(3) Uani 1 1 d DU . . 
O21 O 1.4781(3) 0.0923(2) 0.4579(3) 0.073(3) Uani 1 1 d U . . 
O22 O 1.4323(3) 0.0703(2) 0.4183(3) 0.063(3) Uani 1 1 d U . . 
O23 O 1.4474(2) 0.1986(2) 0.4048(3) 0.061(3) Uani 1 1 d U . . 
O24 O 1.4741(3) 0.2353(2) 0.4483(3) 0.067(3) Uani 1 1 d U . . 
O25 O 1.4201(2) 0.2334(2) 0.3431(3) 0.057(3) Uani 1 1 d U . . 
O26 O 1.3991(2) 0.1867(2) 0.3374(3) 0.063(3) Uani 1 1 d U . . 
O27 O 1.1504(2) 0.2624(2) 0.3349(3) 0.057(3) Uani 1 1 d U . . 
O28 O 1.1287(2) 0.2147(2) 0.3389(3) 0.055(3) Uani 1 1 d U . . 
O29 O 1.1816(2) 0.2638(3) 0.4154(3) 0.064(3) Uani 1 1 d U . . 
O30 O 1.1587(2) 0.2186(2) 0.4070(3) 0.062(3) Uani 1 1 d U . . 
O31 O 1.1275(2) 0.3019(2) 0.4472(3) 0.064(3) Uani 1 1 d U . . 
O32 O 1.1179(3) 0.3073(3) 0.5049(3) 0.087(4) Uani 1 1 d U . . 
O33 O 1.1658(2) 0.3300(2) 0.3799(2) 0.056(3) Uani 1 1 d U . . 
O34 O 1.2032(2) 0.3613(2) 0.3740(3) 0.053(3) Uani 1 1 d U . . 
O35 O 1.1086(4) 0.3857(3) 0.5135(4) 0.106(4) Uani 1 1 d U . . 
O36 O 1.1527(4) 0.3703(4) 0.5308(4) 0.126(5) Uani 1 1 d U . . 
O37 O 1.1730(3) 0.3638(3) 0.4515(3) 0.070(3) Uani 1 1 d U . . 
O38 O 1.2246(2) 0.3692(2) 0.4506(3) 0.059(3) Uani 1 1 d U . . 
O39 O 1.2696(3) 0.3387(3) 0.4082(3) 0.071(3) Uani 1 1 d U . . 
O40 O 1.3144(2) 0.3158(2) 0.4160(3) 0.067(3) Uani 1 1 d U . . 
O41 O 1.3529(2) 0.3696(2) 0.4493(3) 0.061(3) Uani 1 1 d U . . 
O42 O 1.3593(4) 0.3830(4) 0.5053(4) 0.120(5) Uani 1 1 d U . . 
O43 O 1.3795(2) 0.3346(2) 0.3786(2) 0.056(3) Uani 1 1 d U . . 
O44 O 1.4102(2) 0.2952(2) 0.3733(3) 0.057(3) Uani 1 1 d U . . 
O45 O 1.4125(3) 0.3265(3) 0.4520(3) 0.073(3) Uani 1 1 d U . . 
O46 O 1.4168(3) 0.2760(3) 0.4491(3) 0.089(4) Uani 1 1 d U . . 
O47 O 1.3887(3) 0.2290(3) 0.4085(3) 0.074(3) Uani 1 1 d U . . 
O48 O 1.3659(3) 0.1840(3) 0.4157(3) 0.065(3) Uani 1 1 d U . . 
O49 O 1.4196(3) 0.1423(2) 0.4479(3) 0.065(3) Uani 1 1 d U . . 
O50 O 1.4261(3) 0.1370(3) 0.5040(3) 0.087(4) Uani 1 1 d U . . 
O51 O 1.4000(4) 0.0624(4) 0.5224(4) 0.115(5) Uani 1 1 d U . . 
O52 O 1.4476(4) 0.0592(4) 0.5151(5) 0.135(6) Uani 1 1 d U . . 
O53 O 1.3836(3) 0.1191(2) 0.3778(3) 0.062(3) Uani 1 1 d U . . 
O54 O 1.3444(2) 0.0870(2) 0.3714(3) 0.054(3) Uani 1 1 d U . . 
O55 O 1.3231(3) 0.0764(3) 0.4474(3) 0.073(3) Uani 1 1 d U . . 
O56 O 1.3754(3) 0.0827(2) 0.4496(3) 0.065(3) Uani 1 1 d U . . 
O57 O 1.2778(2) 0.1081(3) 0.4064(3) 0.069(3) Uani 1 1 d U . . 
O58 O 1.2328(3) 0.1285(3) 0.4142(3) 0.069(3) Uani 1 1 d U . . 
O59 O 1.1707(2) 0.1126(2) 0.3744(2) 0.052(2) Uani 1 1 d U . . 
O60 O 1.1396(3) 0.1531(2) 0.3698(3) 0.063(3) Uani 1 1 d U . . 
O61 O 1.1281(3) 0.1708(2) 0.4452(3) 0.065(3) Uani 1 1 d U . . 
O62 O 1.1345(2) 0.1211(3) 0.4458(3) 0.065(3) Uani 1 1 d U . . 
O63 O 1.1862(2) 0.0658(3) 0.5023(3) 0.063(3) Uani 1 1 d U . . 
O64 O 1.1943(2) 0.0754(2) 0.4457(3) 0.062(3) Uani 1 1 d U . . 
O65 O 1.1054(3) 0.0484(3) 0.5024(3) 0.076(3) Uani 1 1 d U . . 
O66 O 1.1173(3) 0.0961(3) 0.5205(3) 0.074(3) Uani 1 1 d U . . 
O67 O 1.3131(2) 0.3508(2) 0.3375(2) 0.051(2) Uani 1 1 d U . . 
O68 O 1.2660(2) 0.3709(2) 0.3424(3) 0.064(3) Uani 1 1 d U . . 
O69 O 1.2830(2) 0.0781(2) 0.3401(3) 0.059(3) Uani 1 1 d U . . 
O70 O 1.2352(2) 0.0971(2) 0.3342(2) 0.053(2) Uani 1 1 d U . . 
O71 O 1.4243(4) 0.3543(5) 0.5310(5) 0.167(7) Uani 1 1 d U . . 
H71D H 1.4375 0.3399 0.5272 0.200 Uiso 1 1 d R . . 
H71A H 1.4330 0.3693 0.5419 0.250 Uiso 1 1 d R . . 
C1 C 1.0599(4) 0.1883(4) 0.4708(4) 0.065(4) Uani 1 1 d U . . 
H1A H 1.0583 0.1995 0.4928 0.098 Uiso 1 1 calc R . . 
H1B H 1.0743 0.1712 0.4735 0.098 Uiso 1 1 calc R . . 
H1C H 1.0397 0.1804 0.4643 0.098 Uiso 1 1 calc R . . 
C2 C 1.0555(4) 0.2357(4) 0.4371(4) 0.059(4) Uani 1 1 d U . . 
C3 C 1.0239(3) 0.2415(4) 0.4478(4) 0.060(4) Uani 1 1 d U . . 
H3A H 1.0131 0.2268 0.4612 0.072 Uiso 1 1 calc R . . 
C4 C 1.0101(4) 0.2682(4) 0.4384(5) 0.079(5) Uani 1 1 d U . . 
H4A H 0.9904 0.2726 0.4477 0.095 Uiso 1 1 calc R . . 
C5 C 1.0237(4) 0.2904(4) 0.4147(4) 0.072(5) Uani 1 1 d U . . 
H5A H 1.0136 0.3089 0.4088 0.087 Uiso 1 1 calc R . . 
C6 C 1.0517(4) 0.2830(3) 0.4014(4) 0.077(4) Uani 1 1 d DU . . 
C7 C 1.0729(4) 0.2559(4) 0.4137(4) 0.057(4) Uani 1 1 d DU . . 
C8 C 1.0682(4) 0.3055(3) 0.3767(4) 0.053(4) Uani 1 1 d DU . . 
H8A H 1.0551 0.3209 0.3675 0.064 Uiso 1 1 calc R . . 
C9 C 1.1020(4) 0.3297(3) 0.3349(4) 0.060(4) Uani 1 1 d U . . 
H9A H 1.1242 0.3347 0.3337 0.072 Uiso 1 1 calc R . . 
H9B H 1.0904 0.3491 0.3377 0.072 Uiso 1 1 calc R . . 
C10 C 1.0914(4) 0.3123(4) 0.3006(4) 0.059(4) Uani 1 1 d U . . 
H10A H 1.1027 0.2927 0.2979 0.070 Uiso 1 1 calc R . . 
H10B H 1.0691 0.3078 0.3015 0.070 Uiso 1 1 calc R . . 
C11 C 1.0988(4) 0.3345(4) 0.2698(3) 0.055(4) Uani 1 1 d U . . 
H11A H 1.0910 0.3553 0.2753 0.066 Uiso 1 1 calc R . . 
H11B H 1.1213 0.3360 0.2669 0.066 Uiso 1 1 calc R . . 
C12 C 1.0844(5) 0.3235(4) 0.2360(4) 0.084(5) Uani 1 1 d U . . 
H12A H 1.0618 0.3254 0.2373 0.126 Uiso 1 1 calc R . . 
H12B H 1.0895 0.3016 0.2322 0.126 Uiso 1 1 calc R . . 
C13 C 1.1556(4) 0.4022(4) 0.2967(4) 0.065(4) Uani 1 1 d U . . 
H13B H 1.1346 0.3976 0.2884 0.097 Uiso 1 1 calc R . . 
H13C H 1.1648 0.3829 0.3053 0.097 Uiso 1 1 calc R . . 
C14 C 1.1539(4) 0.4254(4) 0.3262(4) 0.069(5) Uani 1 1 d U . . 
H14A H 1.1748 0.4313 0.3336 0.083 Uiso 1 1 calc R . . 
H14B H 1.1430 0.4441 0.3185 0.083 Uiso 1 1 calc R . . 
C15 C 1.1072(4) 0.4140(3) 0.3564(4) 0.058(4) Uani 1 1 d U . . 
H15A H 1.1006 0.4289 0.3401 0.069 Uiso 1 1 calc R . . 
C16 C 1.0822(4) 0.4009(4) 0.3753(5) 0.071(5) Uani 1 1 d U . . 
C17 C 1.0527(4) 0.4059(4) 0.3663(5) 0.073(5) Uani 1 1 d U . . 
H17A H 1.0486 0.4187 0.3470 0.087 Uiso 1 1 calc R . . 
C18 C 1.0281(4) 0.3932(4) 0.3842(5) 0.084(5) Uani 1 1 d U . . 
H18A H 1.0081 0.3977 0.3760 0.101 Uiso 1 1 calc R . . 
C19 C 1.0304(5) 0.3739(5) 0.4138(5) 0.097(6) Uani 1 1 d DU . . 
H19A H 1.0135 0.3630 0.4232 0.116 Uiso 1 1 calc R . . 
C20 C 1.0612(4) 0.3724(4) 0.4282(5) 0.075(5) Uani 1 1 d DU . . 
C21 C 1.0895(4) 0.3830(4) 0.4086(4) 0.063(4) Uani 1 1 d U . . 
C22 C 1.0440(4) 0.3463(5) 0.4806(4) 0.095(6) Uani 1 1 d DU . . 
H22A H 1.0261 0.3587 0.4740 0.143 Uiso 1 1 calc R . . 
H22B H 1.0498 0.3512 0.5044 0.143 Uiso 1 1 calc R . . 
H22C H 1.0388 0.3245 0.4788 0.143 Uiso 1 1 calc R . . 
C23 C 1.0507(4) 0.0754(4) 0.4457(5) 0.080(5) Uani 1 1 d U . . 
H23A H 1.0451 0.0804 0.4697 0.120 Uiso 1 1 calc R . . 
H23B H 1.0670 0.0600 0.4457 0.120 Uiso 1 1 calc R . . 
H23C H 1.0327 0.0674 0.4335 0.120 Uiso 1 1 calc R . . 
C24 C 1.0382(3) 0.1254(3) 0.4227(4) 0.053(4) Uani 1 1 d U . . 
C25 C 1.0088(4) 0.1233(4) 0.4331(4) 0.060(4) Uani 1 1 d U . . 
H25A H 1.0030 0.1062 0.4466 0.072 Uiso 1 1 calc R . . 
C26 C 0.9868(5) 0.1449(4) 0.4251(5) 0.080(5) Uani 1 1 d U . . 
H26A H 0.9666 0.1434 0.4341 0.095 Uiso 1 1 calc R . . 
C27 C 0.9953(3) 0.1694(3) 0.4032(4) 0.053(4) Uani 1 1 d U . . 
H27A H 0.9808 0.1842 0.3955 0.064 Uiso 1 1 calc R . . 
C28 C 1.0265(3) 0.1706(3) 0.3932(4) 0.051(4) Uani 1 1 d U . . 
C29 C 1.0486(3) 0.1490(3) 0.4018(4) 0.044(3) Uani 1 1 d U . . 
C30 C 1.0323(4) 0.1981(3) 0.3690(4) 0.062(4) Uani 1 1 d U . . 
H30A H 1.0150 0.2089 0.3604 0.074 Uiso 1 1 calc R . . 
C31 C 1.0589(4) 0.2308(4) 0.3303(5) 0.071(5) Uani 1 1 d U . . 
H31A H 1.0398 0.2430 0.3315 0.085 Uiso 1 1 calc R . . 
H31B H 1.0766 0.2449 0.3323 0.085 Uiso 1 1 calc R . . 
C32 C 1.0603(4) 0.2136(4) 0.2962(4) 0.072(5) Uani 1 1 d U . . 
H32A H 1.0790 0.2008 0.2961 0.086 Uiso 1 1 calc R . . 
H32B H 1.0424 0.1996 0.2950 0.086 Uiso 1 1 calc R . . 
C33 C 1.0604(4) 0.2333(4) 0.2640(4) 0.066(4) Uani 1 1 d U . . 
H33A H 1.0787 0.2467 0.2645 0.080 Uiso 1 1 calc R . . 
H33B H 1.0421 0.2466 0.2642 0.080 Uiso 1 1 calc R . . 
C34 C 1.0607(4) 0.2141(4) 0.2294(4) 0.060(4) Uani 1 1 d DU . . 
H34A H 1.0794 0.2012 0.2285 0.072 Uiso 1 1 calc R . . 
H34B H 1.0426 0.2004 0.2286 0.072 Uiso 1 1 calc R . . 
C35 C 1.0601(3) 0.2354(3) 0.1991(4) 0.053(4) Uani 1 1 d DU . . 
H35B H 1.0781 0.2492 0.2000 0.080 Uiso 1 1 calc R . . 
H35C H 1.0414 0.2482 0.2000 0.080 Uiso 1 1 calc R . . 
C36 C 1.2833(3) 0.4394(4) 0.3359(4) 0.052(4) Uani 1 1 d U . . 
H36B H 1.2961 0.4207 0.3374 0.078 Uiso 1 1 calc R . . 
H36C H 1.2966 0.4576 0.3378 0.078 Uiso 1 1 calc R . . 
C37 C 1.2490(4) 0.4682(4) 0.3738(5) 0.068(5) Uani 1 1 d U . . 
H37A H 1.2583 0.4856 0.3634 0.082 Uiso 1 1 calc R . . 
C38 C 1.2258(4) 0.4727(3) 0.3980(5) 0.056(4) Uani 1 1 d U . . 
C39 C 1.2207(4) 0.5026(4) 0.4098(4) 0.065(4) Uani 1 1 d U . . 
H39A H 1.2350 0.5179 0.4030 0.078 Uiso 1 1 calc R . . 
C40 C 1.1960(4) 0.5120(4) 0.4311(5) 0.084(5) Uani 1 1 d U . . 
H40A H 1.1943 0.5328 0.4383 0.101 Uiso 1 1 calc R . . 
C41 C 1.1735(4) 0.4900(4) 0.4416(5) 0.073(5) Uani 1 1 d U . . 
H41A H 1.1567 0.4955 0.4559 0.088 Uiso 1 1 calc R . . 
C42 C 1.1774(4) 0.4604(4) 0.4301(5) 0.066(5) Uani 1 1 d U . . 
C43 C 1.2028(4) 0.4514(4) 0.4068(4) 0.066(4) Uani 1 1 d U . . 
C44 C 1.1308(4) 0.4471(4) 0.4616(5) 0.079(5) Uani 1 1 d U . . 
H44A H 1.1400 0.4538 0.4835 0.118 Uiso 1 1 calc R . . 
H44B H 1.1166 0.4302 0.4660 0.118 Uiso 1 1 calc R . . 
H44C H 1.1197 0.4642 0.4510 0.118 Uiso 1 1 calc R . . 
C45 C 1.2433(4) 0.4361(4) 0.4757(4) 0.064(4) Uani 1 1 d U . . 
H45A H 1.2549 0.4501 0.4906 0.096 Uiso 1 1 calc R . . 
H45B H 1.2365 0.4184 0.4893 0.096 Uiso 1 1 calc R . . 
H45C H 1.2253 0.4468 0.4663 0.096 Uiso 1 1 calc R . . 
C46 C 1.2907(4) 0.4430(4) 0.4418(4) 0.060(4) Uani 1 1 d U . . 
C47 C 1.2994(4) 0.4722(4) 0.4554(4) 0.064(4) Uani 1 1 d U . . 
H47A H 1.2864 0.4820 0.4717 0.077 Uiso 1 1 calc R . . 
C48 C 1.3242(4) 0.4854(4) 0.4459(5) 0.079(5) Uani 1 1 d U . . 
H48A H 1.3291 0.5049 0.4552 0.095 Uiso 1 1 calc R . . 
C49 C 1.3438(4) 0.4722(4) 0.4227(4) 0.073(5) Uani 1 1 d U . . 
H49A H 1.3637 0.4811 0.4215 0.088 Uiso 1 1 calc R . . 
C50 C 1.3387(3) 0.4483(4) 0.4011(4) 0.061(4) Uani 1 1 d DU . . 
C51 C 1.3129(4) 0.4281(4) 0.4166(4) 0.060(4) Uani 1 1 d DU . . 
C52 C 1.3583(3) 0.4298(4) 0.3813(4) 0.051(4) Uani 1 1 d U . . 
H52A H 1.3760 0.4414 0.3754 0.061 Uiso 1 1 calc R . . 
C53 C 1.3800(4) 0.3978(4) 0.3402(4) 0.070(5) Uani 1 1 d DU . . 
H53A H 1.3834 0.3754 0.3388 0.084 Uiso 1 1 calc R . . 
H53B H 1.4002 0.4076 0.3443 0.084 Uiso 1 1 calc R . . 
C54 C 1.3672(3) 0.4092(3) 0.3050(3) 0.052(4) Uani 1 1 d U . . 
H54A H 1.3460 0.4014 0.3023 0.062 Uiso 1 1 calc R . . 
H54B H 1.3662 0.4319 0.3055 0.062 Uiso 1 1 calc R . . 
C55 C 1.3860(4) 0.3993(4) 0.2738(4) 0.064(4) Uani 1 1 d U . . 
H55B H 1.3840 0.3768 0.2711 0.096 Uiso 1 1 calc R . . 
H55C H 1.4079 0.4038 0.2785 0.096 Uiso 1 1 calc R . . 
C56 C 1.0850(4) 0.1232(4) 0.2613(4) 0.061(4) Uani 1 1 d U . . 
H56B H 1.0890 0.1451 0.2660 0.091 Uiso 1 1 calc R . . 
H56C H 1.0626 0.1204 0.2592 0.091 Uiso 1 1 calc R . . 
C57 C 1.0970(4) 0.1037(4) 0.2921(4) 0.069(5) Uani 1 1 d U . . 
H57A H 1.1017 0.0827 0.2838 0.082 Uiso 1 1 calc R . . 
H57B H 1.1163 0.1128 0.3008 0.082 Uiso 1 1 calc R . . 
C58 C 1.0741(4) 0.1019(4) 0.3214(4) 0.061(4) Uani 1 1 d U . . 
H58A H 1.0687 0.1228 0.3293 0.073 Uiso 1 1 calc R . . 
H58B H 1.0552 0.0915 0.3134 0.073 Uiso 1 1 calc R . . 
C59 C 1.0835(4) 0.0544(4) 0.3499(5) 0.072(5) Uani 1 1 d U . . 
H59A H 1.0702 0.0474 0.3322 0.086 Uiso 1 1 calc R . . 
C60 C 1.0958(4) 0.0297(4) 0.3730(4) 0.067(5) Uani 1 1 d U . . 
C61 C 1.0897(4) -0.0013(4) 0.3638(5) 0.068(5) Uani 1 1 d U . . 
H61A H 1.0771 -0.0051 0.3442 0.081 Uiso 1 1 calc R . . 
C62 C 1.1004(4) -0.0251(3) 0.3807(4) 0.057(4) Uani 1 1 d U . . 
H62A H 1.0960 -0.0454 0.3733 0.068 Uiso 1 1 calc R . . 
C63 C 1.1182(3) -0.0199(3) 0.4093(4) 0.052(4) Uani 1 1 d U . . 
H63A H 1.1258 -0.0369 0.4220 0.063 Uiso 1 1 calc R . . 
C64 C 1.1251(4) 0.0091(4) 0.4200(4) 0.062(4) Uani 1 1 d U . . 
C65 C 1.1158(4) 0.0370(4) 0.4039(4) 0.062(4) Uani 1 1 d U . . 
C66 C 1.1484(4) -0.0074(4) 0.4746(5) 0.080(5) Uani 1 1 d U . . 
H66A H 1.1612 -0.0237 0.4647 0.120 Uiso 1 1 calc R . . 
H66B H 1.1282 -0.0158 0.4806 0.120 Uiso 1 1 calc R . . 
H66C H 1.1582 0.0007 0.4955 0.120 Uiso 1 1 calc R . . 
C67 C 1.4017(5) 0.4574(4) 0.4805(5) 0.104(6) Uani 1 1 d DU . . 
H67A H 1.4074 0.4760 0.4678 0.156 Uiso 1 1 calc R . . 
H67B H 1.4136 0.4562 0.5020 0.156 Uiso 1 1 calc R . . 
H67C H 1.3798 0.4580 0.4860 0.156 Uiso 1 1 calc R . . 
C68 C 1.4296(5) 0.4378(5) 0.4295(5) 0.097(6) Uani 1 1 d DU . . 
C69 C 1.4375(5) 0.4668(5) 0.4171(5) 0.097(6) Uani 1 1 d DU . . 
H69A H 1.4282 0.4847 0.4265 0.117 Uiso 1 1 calc R . . 
C70 C 1.4593(7) 0.4689(6) 0.3905(8) 0.140(9) Uani 1 1 d U . . 
H70A H 1.4706 0.4873 0.3870 0.168 Uiso 1 1 calc R . . 
C71 C 1.4635(7) 0.4459(7) 0.3714(8) 0.141(10) Uani 1 1 d U . . 
H71B H 1.4718 0.4489 0.3490 0.170 Uiso 1 1 calc R . . 
C72 C 1.4560(4) 0.4145(4) 0.3828(5) 0.077(5) Uani 1 1 d DU . . 
C73 C 1.4371(4) 0.4079(5) 0.4119(5) 0.073(5) Uani 1 1 d U . . 
C74 C 1.4685(4) 0.3881(5) 0.3596(5) 0.083(5) Uani 1 1 d DU . . 
H74A H 1.4843 0.3935 0.3438 0.099 Uiso 1 1 calc R . . 
C75 C 1.4750(4) 0.3430(4) 0.3298(5) 0.074(5) Uani 1 1 d U . . 
H75A H 1.4956 0.3514 0.3247 0.089 Uiso 1 1 calc R . . 
H75B H 1.4774 0.3213 0.3368 0.089 Uiso 1 1 calc R . . 
C76 C 1.4558(4) 0.3449(4) 0.2988(4) 0.069(5) Uani 1 1 d U . . 
H76A H 1.4547 0.3667 0.2917 0.083 Uiso 1 1 calc R . . 
H76B H 1.4347 0.3386 0.3053 0.083 Uiso 1 1 calc R . . 
C77 C 1.4653(4) 0.3261(4) 0.2674(4) 0.067(4) Uani 1 1 d U . . 
H77A H 1.4602 0.3044 0.2719 0.080 Uiso 1 1 calc R . . 
H77B H 1.4879 0.3275 0.2651 0.080 Uiso 1 1 calc R . . 
C78 C 1.4510(4) 0.3354(4) 0.2328(4) 0.063(4) Uani 1 1 d U . . 
H78B H 1.4554 0.3573 0.2286 0.095 Uiso 1 1 calc R . . 
H78C H 1.4284 0.3332 0.2347 0.095 Uiso 1 1 calc R . . 
C79 C 1.1840(3) 0.0376(4) 0.3005(4) 0.060(4) Uani 1 1 d U . . 
H79B H 1.1857 0.0150 0.2998 0.089 Uiso 1 1 calc R . . 
H79C H 1.2050 0.0462 0.2991 0.089 Uiso 1 1 calc R . . 
C80 C 1.1700(3) 0.0467(3) 0.3342(4) 0.054(4) Uani 1 1 d U . . 
H80A H 1.1635 0.0684 0.3328 0.065 Uiso 1 1 calc R . . 
H80B H 1.1515 0.0341 0.3383 0.065 Uiso 1 1 calc R . . 
C81 C 1.1910(4) 0.0154(4) 0.3762(4) 0.068(5) Uani 1 1 d U . . 
H81A H 1.1755 0.0016 0.3686 0.082 Uiso 1 1 calc R . . 
C82 C 1.2119(3) 0.0034(3) 0.4007(4) 0.053(4) Uani 1 1 d U . . 
C83 C 1.2071(4) -0.0251(4) 0.4148(4) 0.065(4) Uani 1 1 d U . . 
H83A H 1.1878 -0.0342 0.4095 0.079 Uiso 1 1 calc R . . 
C84 C 1.2269(4) -0.0431(4) 0.4363(4) 0.065(4) Uani 1 1 d U . . 
H84A H 1.2232 -0.0640 0.4417 0.078 Uiso 1 1 calc R . . 
C85 C 1.2526(4) -0.0263(4) 0.4486(5) 0.075(5) Uani 1 1 d U . . 
H85A H 1.2646 -0.0347 0.4668 0.090 Uiso 1 1 calc R . . 
C86 C 1.2608(4) 0.0026(4) 0.4346(4) 0.062(4) Uani 1 1 d U . . 
C87 C 1.2402(4) 0.0179(4) 0.4120(4) 0.061(4) Uani 1 1 d U . . 
C88 C 1.3080(4) 0.0103(4) 0.4702(4) 0.068(4) Uani 1 1 d U . . 
H88A H 1.2973 -0.0047 0.4848 0.102 Uiso 1 1 calc R . . 
H88B H 1.3133 0.0283 0.4841 0.102 Uiso 1 1 calc R . . 
H88C H 1.3267 0.0010 0.4609 0.102 Uiso 1 1 calc R . . 
C89 C 1.4929(5) 0.3668(5) 0.4618(6) 0.098(6) Uani 1 1 d U . . 
H89A H 1.4947 0.3611 0.4862 0.147 Uiso 1 1 calc R . . 
H89B H 1.4766 0.3821 0.4592 0.147 Uiso 1 1 calc R . . 
H89C H 1.5124 0.3755 0.4538 0.147 Uiso 1 1 calc R . . 
C90 C 1.5070(4) 0.3203(4) 0.4333(4) 0.065(4) Uani 1 1 d U . . 
C91 C 1.5381(4) 0.3230(5) 0.4459(5) 0.085(5) Uani 1 1 d U . . 
H91A H 1.5430 0.3395 0.4609 0.102 Uiso 1 1 calc R . . 
C92 C 1.5613(5) 0.3025(5) 0.4369(5) 0.092(6) Uani 1 1 d U . . 
H92A H 1.5817 0.3043 0.4453 0.111 Uiso 1 1 calc R . . 
C93 C 1.5517(6) 0.2785(6) 0.4141(6) 0.110(7) Uani 1 1 d U . . 
H93A H 1.5665 0.2634 0.4082 0.131 Uiso 1 1 calc R . . 
C94 C 1.5229(4) 0.2756(4) 0.4000(5) 0.069(5) Uani 1 1 d U . . 
C95 C 1.4987(4) 0.2960(4) 0.4132(4) 0.061(4) Uani 1 1 d U . . 
C96 C 1.5148(4) 0.2499(4) 0.3784(4) 0.064(4) Uani 1 1 d U . . 
H96A H 1.5316 0.2372 0.3719 0.077 Uiso 1 1 calc R . . 
C97 C 1.4918(4) 0.2182(4) 0.3367(4) 0.063(4) Uani 1 1 d U . . 
H97A H 1.4753 0.2027 0.3382 0.076 Uiso 1 1 calc R . . 
H97B H 1.5117 0.2074 0.3388 0.076 Uiso 1 1 calc R . . 
C98 C 1.4902(4) 0.2346(4) 0.3016(5) 0.085(6) Uani 1 1 d U . . 
H98A H 1.4710 0.2466 0.3009 0.102 Uiso 1 1 calc R . . 
H98B H 1.5074 0.2493 0.3003 0.102 Uiso 1 1 calc R . . 
C99 C 1.4913(4) 0.2148(4) 0.2707(4) 0.075(5) Uani 1 1 d U . . 
H99A H 1.4732 0.2010 0.2705 0.090 Uiso 1 1 calc R . . 
H99B H 1.5100 0.2019 0.2715 0.090 Uiso 1 1 calc R . . 
C100 C 1.4915(5) 0.2354(4) 0.2359(5) 0.085(6) Uani 1 1 d U . . 
H10C H 1.4738 0.2497 0.2360 0.102 Uiso 1 1 calc R . . 
H10D H 1.5105 0.2477 0.2348 0.102 Uiso 1 1 calc R . . 
C101 C 1.4895(4) 0.2139(4) 0.2045(4) 0.075(5) Uani 1 1 d U . . 
H10F H 1.5066 0.1990 0.2053 0.113 Uiso 1 1 calc R . . 
H10G H 1.4700 0.2023 0.2054 0.113 Uiso 1 1 calc R . . 
C102 C 1.2677(3) 0.0089(3) 0.3291(4) 0.054(4) Uani 1 1 d U . . 
H10I H 1.2541 0.0270 0.3311 0.080 Uiso 1 1 calc R . . 
H10J H 1.2548 -0.0098 0.3294 0.080 Uiso 1 1 calc R . . 
C103 C 1.3001(4) -0.0192(4) 0.3672(5) 0.068(5) Uani 1 1 d U . . 
H10K H 1.2912 -0.0368 0.3568 0.081 Uiso 1 1 calc R . . 
C104 C 1.3238(3) -0.0240(4) 0.3922(5) 0.065(4) Uani 1 1 d U . . 
C105 C 1.3284(4) -0.0531(4) 0.4041(4) 0.065(4) Uani 1 1 d U . . 
H10L H 1.3153 -0.0687 0.3952 0.078 Uiso 1 1 calc R . . 
C106 C 1.3505(5) -0.0623(5) 0.4285(5) 0.087(6) Uani 1 1 d U . . 
H10M H 1.3487 -0.0815 0.4397 0.104 Uiso 1 1 calc R . . 
C107 C 1.3746(4) -0.0436(4) 0.4360(5) 0.078(5) Uani 1 1 d DU . . 
H10N H 1.3914 -0.0500 0.4498 0.093 Uiso 1 1 calc R . . 
C108 C 1.3726(4) -0.0148(4) 0.4219(5) 0.073(5) Uani 1 1 d DU . . 
C109 C 1.3454(4) -0.0040(4) 0.4012(5) 0.070(5) Uani 1 1 d U . . 
C110 C 1.4218(3) 0.0017(4) 0.4516(4) 0.067(4) Uani 1 1 d DU . . 
H11C H 1.4249 -0.0206 0.4508 0.081 Uiso 1 1 calc R . . 
H11D H 1.4190 0.0083 0.4756 0.081 Uiso 1 1 calc R . . 
H110 H 1.4398 0.0119 0.4418 0.101 Uiso 1 1 calc R . . 
C111 C 1.5007(4) 0.0993(4) 0.4843(5) 0.087(6) Uani 1 1 d U . . 
H11F H 1.5182 0.1098 0.4737 0.131 Uiso 1 1 calc R . . 
H11G H 1.5076 0.0803 0.4952 0.131 Uiso 1 1 calc R . . 
H11H H 1.4914 0.1127 0.5018 0.131 Uiso 1 1 calc R . . 
C112 C 1.4855(4) 0.0761(4) 0.4300(5) 0.066(4) Uani 1 1 d U . . 
C113 C 1.5159(4) 0.0698(4) 0.4220(5) 0.083(5) Uani 1 1 d U . . 
H11I H 1.5325 0.0771 0.4357 0.100 Uiso 1 1 calc R . . 
C114 C 1.5209(4) 0.0506(4) 0.3903(5) 0.072(5) Uani 1 1 d U . . 
H11J H 1.5415 0.0452 0.3852 0.087 Uiso 1 1 calc R . . 
C115 C 1.4994(4) 0.0403(4) 0.3686(5) 0.076(5) Uani 1 1 d U . . 
H11K H 1.5044 0.0296 0.3480 0.091 Uiso 1 1 calc R . . 
C116 C 1.4666(4) 0.0469(3) 0.3792(4) 0.058(4) Uani 1 1 d U . . 
C117 C 1.4592(3) 0.0639(3) 0.4098(4) 0.045(3) Uani 1 1 d U . . 
C118 C 1.4445(3) 0.0349(3) 0.3543(4) 0.052(4) Uani 1 1 d U . . 
H11M H 1.4533 0.0237 0.3358 0.063 Uiso 1 1 calc R . . 
C119 C 1.3971(4) 0.0241(4) 0.3248(5) 0.076(5) Uani 1 1 d U . . 
H11N H 1.3759 0.0199 0.3327 0.091 Uiso 1 1 calc R . . 
H11O H 1.4063 0.0044 0.3175 0.091 Uiso 1 1 calc R . . 
C120 C 1.3965(5) 0.0460(5) 0.2948(5) 0.098(6) Uani 1 1 d U . . 
H12E H 1.4175 0.0480 0.2854 0.147 Uiso 1 1 calc R . . 
H12F H 1.3901 0.0664 0.3033 0.147 Uiso 1 1 calc R . . 
C121 C 1.4643(5) 0.1264(5) 0.2365(4) 0.089(6) Uani 1 1 d DU . . 
H12H H 1.4870 0.1272 0.2380 0.133 Uiso 1 1 calc R . . 
H12I H 1.4567 0.1474 0.2318 0.133 Uiso 1 1 calc R . . 
C122 C 1.4509(4) 0.1146(4) 0.2710(4) 0.059(4) Uani 1 1 d DU . . 
H12J H 1.4284 0.1130 0.2685 0.071 Uiso 1 1 calc R . . 
H12K H 1.4589 0.0936 0.2751 0.071 Uiso 1 1 calc R . . 
C123 C 1.4577(3) 0.1339(4) 0.3026(4) 0.057(4) Uani 1 1 d DU . . 
H12L H 1.4463 0.1534 0.3009 0.068 Uiso 1 1 calc R . . 
H12M H 1.4799 0.1387 0.3031 0.068 Uiso 1 1 calc R . . 
C124 C 1.4489(4) 0.1177(4) 0.3364(4) 0.074(5) Uani 1 1 d DU . . 
H12N H 1.4622 0.0996 0.3400 0.088 Uiso 1 1 calc R . . 
H12O H 1.4274 0.1105 0.3350 0.088 Uiso 1 1 calc R . . 
C125 C 1.4796(5) 0.1406(4) 0.3803(5) 0.077(5) Uani 1 1 d U . . 
H12P H 1.4941 0.1264 0.3714 0.092 Uiso 1 1 calc R . . 
C126 C 1.4908(3) 0.1626(4) 0.4104(4) 0.053(4) Uani 1 1 d U . . 
C127 C 1.5206(4) 0.1547(4) 0.4222(5) 0.075(5) Uani 1 1 d U . . 
H12Q H 1.5312 0.1372 0.4139 0.089 Uiso 1 1 calc R . . 
C128 C 1.5344(5) 0.1756(5) 0.4483(5) 0.094(6) Uani 1 1 d U . . 
H12R H 1.5536 0.1711 0.4587 0.113 Uiso 1 1 calc R . . 
C129 C 1.5170(4) 0.2040(3) 0.4576(4) 0.064(4) Uani 1 1 d U . . 
H12S H 1.5250 0.2181 0.4739 0.076 Uiso 1 1 calc R . . 
C130 C 1.4893(4) 0.2092(5) 0.4422(5) 0.075(5) Uani 1 1 d U . . 
C131 C 1.4747(3) 0.1891(4) 0.4205(4) 0.054(4) Uani 1 1 d U . . 
C132 C 1.4822(4) 0.2540(4) 0.4790(5) 0.082(5) Uani 1 1 d U . . 
H13D H 1.4787 0.2420 0.5000 0.122 Uiso 1 1 calc R . . 
H13E H 1.4695 0.2725 0.4795 0.122 Uiso 1 1 calc R . . 
H13F H 1.5039 0.2598 0.4777 0.122 Uiso 1 1 calc R . . 
C133 C 1.2878(4) 0.3587(4) 0.3262(4) 0.061(4) Uani 1 1 d U . . 
C134 C 1.2816(4) 0.3525(3) 0.2877(4) 0.053(4) Uani 1 1 d U . . 
C135 C 1.3055(4) 0.3524(3) 0.2631(4) 0.056(4) Uani 1 1 d U . . 
H13G H 1.3259 0.3516 0.2716 0.068 Uiso 1 1 calc R . . 
C136 C 1.3014(4) 0.3535(4) 0.2278(5) 0.075(5) Uani 1 1 d U . . 
H13J H 1.3184 0.3538 0.2124 0.113 Uiso 1 1 calc R . . 
C137 C 1.4025(4) 0.2190(3) 0.2872(4) 0.056(4) Uani 1 1 d DU . . 
C138 C 1.2440(4) 0.3519(3) 0.2388(4) 0.057(4) Uani 1 1 d U . . 
H13A H 1.2235 0.3486 0.2312 0.086 Uiso 1 1 calc R . . 
C139 C 1.2516(4) 0.3547(4) 0.2737(4) 0.064(4) Uani 1 1 d U . . 
H13Q H 1.2353 0.3586 0.2894 0.077 Uiso 1 1 calc R . . 
C140 C 1.4059(3) 0.2135(3) 0.3264(4) 0.045(3) Uani 1 1 d DU . . 
C141 C 1.2612(3) 0.0906(3) 0.3226(3) 0.041(3) Uani 1 1 d U . . 
C142 C 1.2683(3) 0.0951(3) 0.2840(3) 0.039(3) Uani 1 1 d U . . 
C143 C 1.2973(4) 0.0960(4) 0.2730(5) 0.067(4) Uani 1 1 d U . . 
H14C H 1.3132 0.0949 0.2897 0.080 Uiso 1 1 calc R . . 
C144 C 1.3056(4) 0.0986(4) 0.2370(4) 0.062(4) Uani 1 1 d U . . 
H14D H 1.3263 0.1009 0.2298 0.093 Uiso 1 1 calc R . . 
C145 C 1.1457(4) 0.2306(4) 0.2850(4) 0.057(4) Uani 1 1 d U . . 
C146 C 1.2493(4) 0.0944(4) 0.2250(4) 0.062(4) Uani 1 1 d U . . 
H14G H 1.2328 0.0907 0.2095 0.093 Uiso 1 1 calc R . . 
C147 C 1.2447(4) 0.0970(4) 0.2612(5) 0.077(5) Uani 1 1 d U . . 
H14M H 1.2245 0.1003 0.2697 0.092 Uiso 1 1 calc R . . 
C148 C 1.1407(4) 0.2356(4) 0.3235(4) 0.048(4) Uani 1 1 d U . . 
C149 C 1.2081(5) 0.2165(5) 0.4313(6) 0.109(7) Uani 1 1 d U . . 
H14N H 1.2036 0.1946 0.4301 0.163 Uiso 1 1 calc R . . 
H14O H 1.2113 0.2226 0.4554 0.163 Uiso 1 1 calc R . . 
H14P H 1.2266 0.2210 0.4178 0.163 Uiso 1 1 calc R . . 
C150 C 1.1811(4) 0.2346(4) 0.4163(4) 0.059(4) Uani 1 1 d U . . 
C151 C 1.1248(4) 0.2566(4) 0.4862(4) 0.078(5) Uani 1 1 d DU . . 
H15B H 1.1180 0.2450 0.4658 0.118 Uiso 1 1 calc R . . 
H15C H 1.1109 0.2524 0.5056 0.118 Uiso 1 1 calc R . . 
H15D H 1.1456 0.2503 0.4924 0.118 Uiso 1 1 calc R . . 
C152 C 1.1244(4) 0.2903(4) 0.4781(4) 0.063(4) Uani 1 1 d DU . . 
C153 C 1.2122(4) 0.3084(4) 0.3533(4) 0.068(5) Uani 1 1 d U . . 
H15E H 1.2007 0.2891 0.3520 0.101 Uiso 1 1 calc R . . 
H15F H 1.2309 0.3053 0.3669 0.101 Uiso 1 1 calc R . . 
H15G H 1.2176 0.3152 0.3299 0.101 Uiso 1 1 calc R . . 
C154 C 1.1919(4) 0.3334(4) 0.3712(4) 0.054(4) Uani 1 1 d U . . 
C155 C 1.1271(6) 0.4034(6) 0.5694(6) 0.129(8) Uani 1 1 d DU . . 
H15H H 1.1474 0.4088 0.5785 0.194 Uiso 1 1 calc R . . 
H15I H 1.1161 0.3907 0.5862 0.194 Uiso 1 1 calc R . . 
H15J H 1.1154 0.4222 0.5650 0.194 Uiso 1 1 calc R . . 
C156 C 1.1308(6) 0.3854(5) 0.5352(6) 0.097(6) Uani 1 1 d DU . . 
C157 C 1.2039(4) 0.3282(4) 0.4814(5) 0.081(5) Uani 1 1 d DU . . 
H15K H 1.2255 0.3237 0.4858 0.122 Uiso 1 1 calc R . . 
H15L H 1.1944 0.3109 0.4692 0.122 Uiso 1 1 calc R . . 
H15M H 1.1933 0.3315 0.5035 0.122 Uiso 1 1 calc R . . 
C158 C 1.2014(4) 0.3556(4) 0.4604(4) 0.066(5) Uani 1 1 d DU . . 
C159 C 1.2702(4) 0.2859(4) 0.4239(6) 0.095(6) Uani 1 1 d DU . . 
H15N H 1.2478 0.2873 0.4235 0.143 Uiso 1 1 calc R . . 
H15O H 1.2770 0.2790 0.4468 0.143 Uiso 1 1 calc R . . 
H15P H 1.2770 0.2711 0.4063 0.143 Uiso 1 1 calc R . . 
C160 C 1.2840(5) 0.3171(4) 0.4161(4) 0.070(5) Uani 1 1 d DU . . 
C161 C 1.3056(3) 0.3726(3) 0.4810(4) 0.062(4) Uani 1 1 d U . . 
H16A H 1.2966 0.3924 0.4874 0.093 Uiso 1 1 calc R . . 
H16B H 1.2995 0.3570 0.4979 0.093 Uiso 1 1 calc R . . 
H16C H 1.2984 0.3665 0.4580 0.093 Uiso 1 1 calc R . . 
C162 C 1.3389(5) 0.3752(5) 0.4806(5) 0.086(6) Uani 1 1 d U . . 
C163 C 1.3588(4) 0.2882(4) 0.3535(4) 0.066(4) Uani 1 1 d U . . 
H16D H 1.3663 0.2675 0.3483 0.099 Uiso 1 1 calc R . . 
H16E H 1.3520 0.2981 0.3321 0.099 Uiso 1 1 calc R . . 
H16F H 1.3416 0.2869 0.3697 0.099 Uiso 1 1 calc R . . 
C164 C 1.3841(3) 0.3065(3) 0.3694(3) 0.033(3) Uani 1 1 d U . . 
C165 C 1.3768(5) 0.2958(5) 0.4862(6) 0.107(7) Uani 1 1 d U . . 
H16G H 1.3737 0.2738 0.4905 0.160 Uiso 1 1 calc R . . 
H16H H 1.3584 0.3044 0.4754 0.160 Uiso 1 1 calc R . . 
H16I H 1.3807 0.3062 0.5082 0.160 Uiso 1 1 calc R . . 
C166 C 1.4054(4) 0.3004(4) 0.4610(4) 0.063(4) Uani 1 1 d U . . 
C167 C 1.3366(5) 0.2282(5) 0.4317(6) 0.099(6) Uani 1 1 d U . . 
H16J H 1.3209 0.2128 0.4372 0.148 Uiso 1 1 calc R . . 
H16K H 1.3284 0.2429 0.4149 0.148 Uiso 1 1 calc R . . 
H16L H 1.3425 0.2390 0.4529 0.148 Uiso 1 1 calc R . . 
C168 C 1.3649(5) 0.2121(5) 0.4161(5) 0.082(5) Uani 1 1 d U . . 
C169 C 1.4197(4) 0.1895(3) 0.4819(5) 0.078(5) Uani 1 1 d U . . 
H16M H 1.4353 0.1994 0.4675 0.118 Uiso 1 1 calc R . . 
H16N H 1.4232 0.1948 0.5062 0.118 Uiso 1 1 calc R . . 
H16O H 1.3993 0.1966 0.4748 0.118 Uiso 1 1 calc R . . 
C170 C 1.4217(4) 0.1537(4) 0.4774(4) 0.057(4) Uani 1 1 d U . . 
C171 C 1.3367(4) 0.1400(4) 0.3544(4) 0.067(5) Uani 1 1 d U . . 
H17B H 1.3489 0.1589 0.3543 0.100 Uiso 1 1 calc R . . 
H17C H 1.3186 0.1429 0.3690 0.100 Uiso 1 1 calc R . . 
H17D H 1.3303 0.1351 0.3308 0.100 Uiso 1 1 calc R . . 
C172 C 1.3557(4) 0.1141(4) 0.3686(5) 0.065(4) Uani 1 1 d U . . 
C173 C 1.4257(5) 0.0351(5) 0.5635(5) 0.102(6) Uani 1 1 d U . . 
H17E H 1.4059 0.0248 0.5670 0.153 Uiso 1 1 calc R . . 
H17F H 1.4305 0.0476 0.5839 0.153 Uiso 1 1 calc R . . 
H17G H 1.4418 0.0197 0.5602 0.153 Uiso 1 1 calc R . . 
C174 C 1.4239(5) 0.0549(5) 0.5327(6) 0.086(6) Uani 1 1 d U . . 
C175 C 1.2777(5) 0.1595(5) 0.4269(6) 0.097(6) Uani 1 1 d U . . 
H17H H 1.2999 0.1563 0.4274 0.145 Uiso 1 1 calc R . . 
H17I H 1.2707 0.1663 0.4497 0.145 Uiso 1 1 calc R . . 
H17J H 1.2727 0.1752 0.4096 0.145 Uiso 1 1 calc R . . 
C176 C 1.2613(4) 0.1289(4) 0.4172(4) 0.060(4) Uani 1 1 d U . . 
C177 C 1.2392(4) 0.0723(4) 0.4843(4) 0.073(5) Uani 1 1 d U . . 
H17K H 1.2505 0.0576 0.4699 0.109 Uiso 1 1 calc R . . 
H17L H 1.2429 0.0677 0.5088 0.109 Uiso 1 1 calc R . . 
H17M H 1.2463 0.0931 0.4792 0.109 Uiso 1 1 calc R . . 
C178 C 1.2057(4) 0.0699(4) 0.4768(4) 0.060(4) Uani 1 1 d U . . 
C179 C 1.1914(3) 0.1596(3) 0.3535(4) 0.053(4) Uani 1 1 d U . . 
H17N H 1.2100 0.1470 0.3520 0.079 Uiso 1 1 calc R . . 
H17O H 1.1950 0.1768 0.3692 0.079 Uiso 1 1 calc R . . 
H17P H 1.1861 0.1674 0.3304 0.079 Uiso 1 1 calc R . . 
C180 C 1.1657(3) 0.1406(3) 0.3669(3) 0.042(3) Uani 1 1 d U . . 
C181 C 1.0802(5) 0.0682(5) 0.5557(5) 0.094(6) Uani 1 1 d U . . 
H18B H 1.0600 0.0773 0.5514 0.141 Uiso 1 1 calc R . . 
H18C H 1.0900 0.0787 0.5752 0.141 Uiso 1 1 calc R . . 
H18D H 1.0778 0.0464 0.5611 0.141 Uiso 1 1 calc R . . 
C182 C 1.1009(4) 0.0719(4) 0.5223(4) 0.053(4) Uani 1 1 d U . . 
C183 C 1.1658(4) 0.1524(4) 0.4859(4) 0.074(5) Uani 1 1 d U . . 
H18E H 1.1732 0.1324 0.4938 0.111 Uiso 1 1 calc R . . 
H18F H 1.1572 0.1638 0.5055 0.111 Uiso 1 1 calc R . . 
H18G H 1.1828 0.1640 0.4759 0.111 Uiso 1 1 calc R . . 
C184 C 1.1398(3) 0.1475(4) 0.4572(4) 0.051(4) Uani 1 1 d U . . 
C185 C 1.3397(6) 0.1118(5) 0.4857(6) 0.121(8) Uani 1 1 d DU . . 
H18H H 1.3592 0.1202 0.4940 0.181 Uiso 1 1 calc R . . 
H18I H 1.3282 0.1032 0.5052 0.181 Uiso 1 1 calc R . . 
H18J H 1.3277 0.1282 0.4749 0.181 Uiso 1 1 calc R . . 
C186 C 1.3458(5) 0.0877(4) 0.4602(4) 0.072(5) Uani 1 1 d DU . . 
 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Eu1 O30 2.297(10) . ? 
Eu1 O2 2.319(8) . ? 
Eu1 O28 2.321(10) . ? 
Eu1 O6 2.345(10) . ? 
Eu1 O61 2.368(11) . ? 
Eu1 O60 2.386(10) . ? 
Eu1 N3 2.592(14) . ? 
Eu1 O1 2.597(10) . ? 
Eu1 C7 3.120(15) . ? 
Eu1 Cd12 3.6513(14) . ? 
Eu1 Cd1 3.8303(14) . ? 
Eu2 O10 2.301(10) . ? 
Eu2 O68 2.303(11) . ? 
Eu2 O7 2.335(9) . ? 
Eu2 O39 2.338(12) . ? 
Eu2 O34 2.402(9) . ? 
Eu2 O38 2.422(10) . ? 
Eu2 N4 2.550(12) . ? 
Eu2 O9 2.599(10) . ? 
Eu2 Cd3 3.6609(15) . ? 
Eu2 Cd4 3.8470(14) . ? 
Eu3 O47 2.282(13) . ? 
Eu3 O23 2.282(9) . ? 
Eu3 O25 2.303(9) . ? 
Eu3 O18 2.314(10) . ? 
Eu3 O46 2.386(14) . ? 
Eu3 O44 2.402(9) . ? 
Eu3 N9 2.544(13) . ? 
Eu3 O24 2.579(10) . ? 
Eu3 C131 3.204(15) . ? 
Eu3 Cd6 3.6410(15) . ? 
Eu3 Cd7 3.8470(14) . ? 
Eu4 O69 2.278(11) . ? 
Eu4 O15 2.297(9) . ? 
Eu4 O19 2.355(9) . ? 
Eu4 O57 2.363(12) . ? 
Eu4 O54 2.365(10) . ? 
Eu4 O55 2.400(12) . ? 
Eu4 O16 2.580(10) . ? 
Eu4 N10 2.597(13) . ? 
Eu4 C87 3.204(17) . ? 
Eu4 Cd9 3.6493(14) . ? 
Eu4 Cd10 3.8299(14) . ? 
Cd1 O29 2.230(11) . ? 
Cd1 O2 2.233(10) . ? 
Cd1 N1 2.301(12) . ? 
Cd1 O27 2.322(10) . ? 
Cd1 O31 2.357(10) . ? 
Cd1 O33 2.399(10) . ? 
Cd2 O35 2.223(13) . ? 
Cd2 O3 2.236(11) . ? 
Cd2 O37 2.251(11) . ? 
Cd2 O32 2.321(12) . ? 
Cd2 O31 2.365(11) . ? 
Cd2 O4 2.389(13) . ? 
Cd2 O36 2.633(16) . ? 
Cd2 C152 2.673(15) . ? 
Cd3 O3 2.168(11) . ? 
Cd3 N2 2.200(14) . ? 
Cd3 O37 2.270(11) . ? 
Cd3 O7 2.275(10) . ? 
Cd3 O34 2.286(10) . ? 
Cd3 O8 2.509(9) . ? 
Cd3 O33 2.596(10) . ? 
Cd4 O10 2.265(9) . ? 
Cd4 O40 2.267(11) . ? 
Cd4 O67 2.289(10) . ? 
Cd4 O43 2.290(10) . ? 
Cd4 O41 2.345(10) . ? 
Cd4 N5 2.357(13) . ? 
Cd5 O14 2.185(13) . ? 
Cd5 O42 2.258(15) . ? 
Cd5 O45 2.276(12) . ? 
Cd5 O41 2.391(9) . ? 
Cd5 O13 2.403(13) . ? 
Cd5 O71 2.471(18) . ? 
Cd6 N7 2.169(13) . ? 
Cd6 O14 2.206(11) . ? 
Cd6 O45 2.225(11) . ? 
Cd6 O18 2.284(11) . ? 
Cd6 O44 2.344(9) . ? 
Cd6 O17 2.549(12) . ? 
Cd6 O43 2.632(9) . ? 
Cd7 O23 2.225(10) . ? 
Cd7 O48 2.245(11) . ? 
Cd7 O26 2.280(10) . ? 
Cd7 N12 2.303(13) . ? 
Cd7 O53 2.304(11) . ? 
Cd7 O49 2.395(10) . ? 
Cd8 O56 2.233(11) . ? 
Cd8 O22 2.279(10) . ? 
Cd8 O50 2.296(12) . ? 
Cd8 O52 2.359(15) . ? 
Cd8 O49 2.383(10) . ? 
Cd8 O21 2.428(12) . ? 
Cd8 O51 2.448(15) . ? 
Cd8 C170 2.679(15) . ? 
Cd8 C174 2.749(19) . ? 
Cd9 O22 2.200(11) . ? 
Cd9 N11 2.271(13) . ? 
Cd9 O19 2.276(10) . ? 
Cd9 O56 2.290(11) . ? 
Cd9 O54 2.303(10) . ? 
Cd9 O20 2.535(10) . ? 
Cd9 O53 2.604(10) . ? 
Cd10 O58 2.204(11) . ? 
Cd10 O15 2.257(9) . ? 
Cd10 O59 2.281(10) . ? 
Cd10 O70 2.290(9) . ? 
Cd10 N8 2.322(12) . ? 
Cd10 O64 2.373(9) . ? 
Cd11 O11 2.180(10) . ? 
Cd11 O63 2.267(10) . ? 
Cd11 O65 2.270(11) . ? 
Cd11 O62 2.308(11) . ? 
Cd11 O64 2.373(9) . ? 
Cd11 O12 2.474(10) . ? 
Cd11 O66 2.476(11) . ? 
Cd11 C182 2.707(15) . ? 
Cd11 C178 2.710(16) . ? 
Cd12 O62 2.232(11) . ? 
Cd12 N6 2.245(13) . ? 
Cd12 O11 2.263(9) . ? 
Cd12 O6 2.301(9) . ? 
Cd12 O60 2.362(10) . ? 
Cd12 O5 2.489(10) . ? 
N1 C8 1.232(17) . ? 
N1 C9 1.555(17) . ? 
N2 C15 1.274(18) . ? 
N2 C14 1.487(19) . ? 
N3 C30 1.286(19) . ? 
N3 C31 1.49(2) . ? 
N4 C37 1.348(19) . ? 
N4 C36 1.496(18) . ? 
N5 C52 1.203(17) . ? 
N5 C53 1.392(17) . ? 
N6 C59 1.295(19) . ? 
N6 C58 1.457(18) . ? 
N7 C74 1.20(2) . ? 
N7 C75 1.494(19) . ? 
N8 C81 1.302(19) . ? 
N8 C80 1.377(17) . ? 
N9 C96 1.272(18) . ? 
N9 C97 1.497(19) . ? 
N10 C103 1.321(19) . ? 
N10 C102 1.405(18) . ? 
N11 C118 1.278(18) . ? 
N11 C119 1.41(2) . ? 
N12 C125 1.26(2) . ? 
N12 C124 1.505(19) . ? 
O1 C2 1.321(18) . ? 
O1 C1 1.486(17) . ? 
O2 C7 1.239(16) . ? 
O3 C21 1.281(18) . ? 
O4 C20 1.395(17) . ? 
O4 C22 1.500(16) . ? 
O5 C24 1.391(17) . ? 
O5 C23 1.446(17) . ? 
O6 C29 1.301(15) . ? 
O7 C43 1.349(18) . ? 
O8 C42 1.395(19) . ? 
O8 C44 1.512(19) . ? 
O9 C45 1.401(16) . ? 
O9 C46 1.432(19) . ? 
O10 C51 1.393(18) . ? 
O11 C65 1.248(18) . ? 
O12 C66 1.370(18) . ? 
O12 C64 1.457(18) . ? 
O13 C68 1.453(19) . ? 
O13 C67 1.503(16) . ? 
O14 C73 1.26(2) . ? 
O15 C87 1.344(18) . ? 
O16 C88 1.404(16) . ? 
O16 C86 1.412(19) . ? 
O17 C90 1.280(18) . ? 
O17 C89 1.42(2) . ? 
O18 C95 1.300(17) . ? 
O19 C109 1.349(18) . ? 
O20 C108 1.430(17) . ? 
O20 C110 1.490(15) . ? 
O21 C112 1.30(2) . ? 
O21 C111 1.420(18) . ? 
O22 C117 1.224(16) . ? 
O23 C131 1.369(16) . ? 
O24 C130 1.31(2) . ? 
O24 C132 1.453(18) . ? 
O25 C140 1.221(15) . ? 
O26 C140 1.254(16) . ? 
O27 C148 1.292(17) . ? 
O28 C148 1.184(17) . ? 
O29 C150 1.247(18) . ? 
O30 C150 1.229(18) . ? 
O31 C152 1.276(17) . ? 
O32 C152 1.281(19) . ? 
O33 C154 1.174(16) . ? 
O34 C154 1.289(17) . ? 
O35 C156 1.25(2) . ? 
O36 C156 1.15(2) . ? 
O37 C158 1.304(19) . ? 
O38 C158 1.209(18) . ? 
O39 C160 1.148(19) . ? 
O40 C160 1.30(2) . ? 
O41 C162 1.35(2) . ? 
O42 C162 1.32(2) . ? 
O43 C164 1.265(14) . ? 
O44 C164 1.226(14) . ? 
O45 C166 1.205(18) . ? 
O46 C166 1.233(18) . ? 
O47 C168 1.28(2) . ? 
O48 C168 1.20(2) . ? 
O49 C170 1.218(17) . ? 
O50 C170 1.247(17) . ? 
O51 C174 1.14(2) . ? 
O52 C174 1.22(2) . ? 
O53 C172 1.258(18) . ? 
O54 C172 1.259(18) . ? 
O55 C186 1.187(19) . ? 
O56 C186 1.35(2) . ? 
O57 C176 1.208(17) . ? 
O58 C176 1.221(18) . ? 
O59 C180 1.246(16) . ? 
O60 C180 1.240(15) . ? 
O61 C184 1.202(17) . ? 
O62 C184 1.228(17) . ? 
O63 C178 1.287(18) . ? 
O64 C178 1.293(17) . ? 
O65 C182 1.271(17) . ? 
O66 C182 1.253(17) . ? 
O67 C133 1.212(18) . ? 
O68 C133 1.228(18) . ? 
O69 C141 1.264(15) . ? 
O70 C141 1.227(15) . ? 
O71 H71D 0.8482 . ? 
O71 H71A 0.8481 . ? 
C1 H1A 0.9600 . ? 
C1 H1B 0.9600 . ? 
C1 H1C 0.9600 . ? 
C2 C3 1.43(2) . ? 
C2 C7 1.44(2) . ? 
C3 C4 1.33(2) . ? 
C3 H3A 0.9300 . ? 
C4 C5 1.43(2) . ? 
C4 H4A 0.9300 . ? 
C5 C6 1.33(2) . ? 
C5 H5A 0.9300 . ? 
C6 C8 1.513(16) . ? 
C6 C7 1.541(18) . ? 
C8 H8A 0.9300 . ? 
C9 C10 1.56(2) . ? 
C9 H9A 0.9700 . ? 
C9 H9B 0.9700 . ? 
C10 C11 1.536(19) . ? 
C10 H10A 0.9700 . ? 
C10 H10B 0.9700 . ? 
C11 C12 1.49(2) . ? 
C11 H11A 0.9700 . ? 
C11 H11B 0.9700 . ? 
C12 C13 1.63(2) 8_665 ? 
C12 H12A 0.9700 . ? 
C12 H12B 0.9700 . ? 
C13 C14 1.50(2) . ? 
C13 C12 1.63(2) 8_665 ? 
C13 H13B 0.9700 . ? 
C13 H13C 0.9700 . ? 
C14 H14A 0.9700 . ? 
C14 H14B 0.9700 . ? 
C15 C16 1.40(2) . ? 
C15 H15A 0.9300 . ? 
C16 C17 1.32(2) . ? 
C16 C21 1.51(2) . ? 
C17 C18 1.37(2) . ? 
C17 H17A 0.9300 . ? 
C18 C19 1.39(2) . ? 
C18 H18A 0.9300 . ? 
C19 C20 1.43(2) . ? 
C19 H19A 0.9300 . ? 
C20 C21 1.49(2) . ? 
C22 H22A 0.9600 . ? 
C22 H22B 0.9600 . ? 
C22 H22C 0.9600 . ? 
C23 H23A 0.9600 . ? 
C23 H23B 0.9600 . ? 
C23 H23C 0.9600 . ? 
C24 C25 1.32(2) . ? 
C24 C29 1.356(19) . ? 
C25 C26 1.35(2) . ? 
C25 H25A 0.9300 . ? 
C26 C27 1.38(2) . ? 
C26 H26A 0.9300 . ? 
C27 C28 1.389(18) . ? 
C27 H27A 0.9300 . ? 
C28 C29 1.361(18) . ? 
C28 C30 1.51(2) . ? 
C30 H30A 0.9300 . ? 
C31 C32 1.49(2) . ? 
C31 H31A 0.9700 . ? 
C31 H31B 0.9700 . ? 
C32 C33 1.48(2) . ? 
C32 H32A 0.9700 . ? 
C32 H32B 0.9700 . ? 
C33 C34 1.55(2) . ? 
C33 H33A 0.9700 . ? 
C33 H33B 0.9700 . ? 
C34 C35 1.464(17) . ? 
C34 H34A 0.9700 . ? 
C34 H34B 0.9700 . ? 
C35 C36 1.54(2) 8_665 ? 
C35 H35B 0.9700 . ? 
C35 H35C 0.9700 . ? 
C36 C35 1.54(2) 8_665 ? 
C36 H36B 0.9700 . ? 
C36 H36C 0.9700 . ? 
C37 C38 1.36(2) . ? 
C37 H37A 0.9300 . ? 
C38 C39 1.37(2) . ? 
C38 C43 1.38(2) . ? 
C39 C40 1.39(2) . ? 
C39 H39A 0.9300 . ? 
C40 C41 1.40(2) . ? 
C40 H40A 0.9300 . ? 
C41 C42 1.35(2) . ? 
C41 H41A 0.9300 . ? 
C42 C43 1.45(2) . ? 
C44 H44A 0.9600 . ? 
C44 H44B 0.9600 . ? 
C44 H44C 0.9600 . ? 
C45 H45A 0.9600 . ? 
C45 H45B 0.9600 . ? 
C45 H45C 0.9600 . ? 
C46 C47 1.40(2) . ? 
C46 C51 1.49(2) . ? 
C47 C48 1.25(2) . ? 
C47 H47A 0.9300 . ? 
C48 C49 1.34(2) . ? 
C48 H48A 0.9300 . ? 
C49 C50 1.33(2) . ? 
C49 H49A 0.9300 . ? 
C50 C52 1.372(19) . ? 
C50 C51 1.518(18) . ? 
C52 H52A 0.9300 . ? 
C53 C54 1.52(2) . ? 
C53 H53A 0.9700 . ? 
C53 H53B 0.9700 . ? 
C54 C55 1.491(19) . ? 
C54 H54A 0.9700 . ? 
C54 H54B 0.9700 . ? 
C55 C56 1.54(2) 8_665 ? 
C55 H55B 0.9700 . ? 
C55 H55C 0.9700 . ? 
C56 C57 1.52(2) . ? 
C56 C55 1.54(2) 8_665 ? 
C56 H56B 0.9700 . ? 
C56 H56C 0.9700 . ? 
C57 C58 1.48(2) . ? 
C57 H57A 0.9700 . ? 
C57 H57B 0.9700 . ? 
C58 H58A 0.9700 . ? 
C58 H58B 0.9700 . ? 
C59 C60 1.47(2) . ? 
C59 H59A 0.9300 . ? 
C60 C61 1.39(2) . ? 
C60 C65 1.48(2) . ? 
C61 C62 1.28(2) . ? 
C61 H61A 0.9300 . ? 
C62 C63 1.34(2) . ? 
C62 H62A 0.9300 . ? 
C63 C64 1.34(2) . ? 
C63 H63A 0.9300 . ? 
C64 C65 1.40(2) . ? 
C66 H66A 0.9600 . ? 
C66 H66B 0.9600 . ? 
C66 H66C 0.9600 . ? 
C67 H67A 0.9600 . ? 
C67 H67B 0.9600 . ? 
C67 H67C 0.9600 . ? 
C68 C69 1.37(3) . ? 
C68 C73 1.47(3) . ? 
C69 C70 1.38(3) . ? 
C69 H69A 0.9300 . ? 
C70 C71 1.23(3) . ? 
C70 H70A 0.9300 . ? 
C71 C72 1.45(3) . ? 
C71 H71B 0.9300 . ? 
C72 C73 1.39(2) . ? 
C72 C74 1.525(19) . ? 
C74 H74A 0.9300 . ? 
C75 C76 1.44(2) . ? 
C75 H75A 0.9700 . ? 
C75 H75B 0.9700 . ? 
C76 C77 1.49(2) . ? 
C76 H76A 0.9700 . ? 
C76 H76B 0.9700 . ? 
C77 C78 1.50(2) . ? 
C77 H77A 0.9700 . ? 
C77 H77B 0.9700 . ? 
C78 C79 1.58(2) 8_665 ? 
C78 H78B 0.9700 . ? 
C78 H78C 0.9700 . ? 
C79 C80 1.462(19) . ? 
C79 C78 1.58(2) 8_665 ? 
C79 H79B 0.9700 . ? 
C79 H79C 0.9700 . ? 
C80 H80A 0.9700 . ? 
C80 H80B 0.9700 . ? 
C81 C82 1.38(2) . ? 
C81 H81A 0.9300 . ? 
C82 C83 1.35(2) . ? 
C82 C87 1.42(2) . ? 
C83 C84 1.40(2) . ? 
C83 H83A 0.9300 . ? 
C84 C85 1.39(2) . ? 
C84 H84A 0.9300 . ? 
C85 C86 1.39(2) . ? 
C85 H85A 0.9300 . ? 
C86 C87 1.39(2) . ? 
C88 H88A 0.9600 . ? 
C88 H88B 0.9600 . ? 
C88 H88C 0.9600 . ? 
C89 H89A 0.9600 . ? 
C89 H89B 0.9600 . ? 
C89 H89C 0.9600 . ? 
C90 C95 1.33(2) . ? 
C90 C91 1.42(2) . ? 
C91 C92 1.36(3) . ? 
C91 H91A 0.9300 . ? 
C92 C93 1.40(3) . ? 
C92 H92A 0.9300 . ? 
C93 C94 1.35(3) . ? 
C93 H93A 0.9300 . ? 
C94 C96 1.41(2) . ? 
C94 C95 1.44(2) . ? 
C96 H96A 0.9300 . ? 
C97 C98 1.50(2) . ? 
C97 H97A 0.9700 . ? 
C97 H97B 0.9700 . ? 
C98 C99 1.44(2) . ? 
C98 H98A 0.9700 . ? 
C98 H98B 0.9700 . ? 
C99 C100 1.59(2) . ? 
C99 H99A 0.9700 . ? 
C99 H99B 0.9700 . ? 
C100 C101 1.51(2) . ? 
C100 H10C 0.9700 . ? 
C100 H10D 0.9700 . ? 
C101 C102 1.50(2) 8_665 ? 
C101 H10F 0.9700 . ? 
C101 H10G 0.9700 . ? 
C102 C101 1.50(2) 8_665 ? 
C102 H10I 0.9700 . ? 
C102 H10J 0.9700 . ? 
C103 C104 1.40(2) . ? 
C103 H10K 0.9300 . ? 
C104 C109 1.30(2) . ? 
C104 C105 1.34(2) . ? 
C105 C106 1.38(2) . ? 
C105 H10L 0.9300 . ? 
C106 C107 1.33(2) . ? 
C106 H10M 0.9300 . ? 
C107 C108 1.34(2) . ? 
C107 H10N 0.9300 . ? 
C108 C109 1.47(2) . ? 
C110 H11C 0.9600 . ? 
C110 H11D 0.9600 . ? 
C110 H110 0.9600 . ? 
C111 H11F 0.9600 . ? 
C111 H11G 0.9600 . ? 
C111 H11H 0.9600 . ? 
C112 C113 1.36(2) . ? 
C112 C117 1.45(2) . ? 
C113 C114 1.47(2) . ? 
C113 H11I 0.9300 . ? 
C114 C115 1.31(2) . ? 
C114 H11J 0.9300 . ? 
C115 C116 1.49(2) . ? 
C115 H11K 0.9300 . ? 
C116 C117 1.40(2) . ? 
C116 C118 1.43(2) . ? 
C118 H11M 0.9300 . ? 
C119 C120 1.47(2) . ? 
C119 H11N 0.9700 . ? 
C119 H11O 0.9700 . ? 
C120 C121 1.60(2) 8_665 ? 
C120 H12E 0.9700 . ? 
C120 H12F 0.9700 . ? 
C121 C122 1.514(18) . ? 
C121 C120 1.60(2) 8_665 ? 
C121 H12H 0.9700 . ? 
C121 H12I 0.9700 . ? 
C122 C123 1.480(19) . ? 
C122 H12J 0.9700 . ? 
C122 H12K 0.9700 . ? 
C123 C124 1.502(18) . ? 
C123 H12L 0.9700 . ? 
C123 H12M 0.9700 . ? 
C124 H12N 0.9700 . ? 
C124 H12O 0.9700 . ? 
C125 C126 1.55(2) . ? 
C125 H12P 0.9300 . ? 
C126 C131 1.38(2) . ? 
C126 C127 1.39(2) . ? 
C127 C128 1.46(2) . ? 
C127 H12Q 0.9300 . ? 
C128 C129 1.46(2) . ? 
C128 H12R 0.9300 . ? 
C129 C130 1.33(2) . ? 
C129 H12S 0.9300 . ? 
C130 C131 1.34(2) . ? 
C132 H13D 0.9600 . ? 
C132 H13E 0.9600 . ? 
C132 H13F 0.9600 . ? 
C133 C134 1.51(2) . ? 
C134 C135 1.38(2) . ? 
C134 C139 1.39(2) . ? 
C135 C136 1.35(2) . ? 
C135 H13G 0.9300 . ? 
C136 C145 1.45(2) 8_665 ? 
C136 H13J 0.9300 . ? 
C137 C144 1.40(2) 8_665 ? 
C137 C146 1.44(2) 8_665 ? 
C137 C140 1.509(17) . ? 
C138 C139 1.36(2) . ? 
C138 C145 1.42(2) 8_665 ? 
C138 H13A 0.9300 . ? 
C139 H13Q 0.9300 . ? 
C141 C142 1.503(18) . ? 
C142 C143 1.31(2) . ? 
C142 C147 1.33(2) . ? 
C143 C144 1.41(2) . ? 
C143 H14C 0.9300 . ? 
C144 C137 1.40(2) 8_665 ? 
C144 H14D 0.9300 . ? 
C145 C138 1.42(2) 8_665 ? 
C145 C136 1.45(2) 8_665 ? 
C145 C148 1.49(2) . ? 
C146 C147 1.39(2) . ? 
C146 C137 1.44(2) 8_665 ? 
C146 H14G 0.9300 . ? 
C147 H14M 0.9300 . ? 
C149 C150 1.50(2) . ? 
C149 H14N 0.9600 . ? 
C149 H14O 0.9600 . ? 
C149 H14P 0.9600 . ? 
C151 C152 1.474(18) . ? 
C151 H15B 0.9600 . ? 
C151 H15C 0.9600 . ? 
C151 H15D 0.9600 . ? 
C153 C154 1.53(2) . ? 
C153 H15E 0.9600 . ? 
C153 H15F 0.9600 . ? 
C153 H15G 0.9600 . ? 
C155 C156 1.51(2) . ? 
C155 H15H 0.9600 . ? 
C155 H15I 0.9600 . ? 
C155 H15J 0.9600 . ? 
C157 C158 1.421(18) . ? 
C157 H15K 0.9600 . ? 
C157 H15L 0.9600 . ? 
C157 H15M 0.9600 . ? 
C159 C160 1.49(2) . ? 
C159 H15N 0.9600 . ? 
C159 H15O 0.9600 . ? 
C159 H15P 0.9600 . ? 
C161 C162 1.42(2) . ? 
C161 H16A 0.9600 . ? 
C161 H16B 0.9600 . ? 
C161 H16C 0.9600 . ? 
C163 C164 1.461(19) . ? 
C163 H16D 0.9600 . ? 
C163 H16E 0.9600 . ? 
C163 H16F 0.9600 . ? 
C165 C166 1.57(3) . ? 
C165 H16G 0.9600 . ? 
C165 H16H 0.9600 . ? 
C165 H16I 0.9600 . ? 
C167 C168 1.51(3) . ? 
C167 H16J 0.9600 . ? 
C167 H16K 0.9600 . ? 
C167 H16L 0.9600 . ? 
C169 C170 1.54(2) . ? 
C169 H16M 0.9600 . ? 
C169 H16N 0.9600 . ? 
C169 H16O 0.9600 . ? 
C171 C172 1.47(2) . ? 
C171 H17B 0.9600 . ? 
C171 H17C 0.9600 . ? 
C171 H17D 0.9600 . ? 
C173 C174 1.45(3) . ? 
C173 H17E 0.9600 . ? 
C173 H17F 0.9600 . ? 
C173 H17G 0.9600 . ? 
C175 C176 1.53(2) . ? 
C175 H17H 0.9600 . ? 
C175 H17I 0.9600 . ? 
C175 H17J 0.9600 . ? 
C177 C178 1.47(2) . ? 
C177 H17K 0.9600 . ? 
C177 H17L 0.9600 . ? 
C177 H17M 0.9600 . ? 
C179 C180 1.457(19) . ? 
C179 H17N 0.9600 . ? 
C179 H17O 0.9600 . ? 
C179 H17P 0.9600 . ? 
C181 C182 1.55(2) . ? 
C181 H18B 0.9600 . ? 
C181 H18C 0.9600 . ? 
C181 H18D 0.9600 . ? 
C183 C184 1.57(2) . ? 
C183 H18E 0.9600 . ? 
C183 H18F 0.9600 . ? 
C183 H18G 0.9600 . ? 
C185 C186 1.43(2) . ? 
C185 H18H 0.9600 . ? 
C185 H18I 0.9600 . ? 
C185 H18J 0.9600 . ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
O30 Eu1 O2 76.9(4) . . ? 
O30 Eu1 O28 77.3(4) . . ? 
O2 Eu1 O28 82.6(3) . . ? 
O30 Eu1 O6 150.4(4) . . ? 
O2 Eu1 O6 128.6(3) . . ? 
O28 Eu1 O6 116.5(3) . . ? 
O30 Eu1 O61 74.4(4) . . ? 
O2 Eu1 O61 113.8(3) . . ? 
O28 Eu1 O61 142.6(4) . . ? 
O6 Eu1 O61 80.6(4) . . ? 
O30 Eu1 O60 87.4(4) . . ? 
O2 Eu1 O60 156.3(4) . . ? 
O28 Eu1 O60 76.6(3) . . ? 
O6 Eu1 O60 72.0(3) . . ? 
O61 Eu1 O60 78.1(4) . . ? 
O30 Eu1 N3 142.1(4) . . ? 
O2 Eu1 N3 72.5(4) . . ? 
O28 Eu1 N3 77.0(4) . . ? 
O6 Eu1 N3 67.2(4) . . ? 
O61 Eu1 N3 139.0(4) . . ? 
O60 Eu1 N3 113.0(4) . . ? 
O30 Eu1 O1 108.8(4) . . ? 
O2 Eu1 O1 62.7(3) . . ? 
O28 Eu1 O1 141.1(3) . . ? 
O6 Eu1 O1 77.6(3) . . ? 
O61 Eu1 O1 72.5(4) . . ? 
O60 Eu1 O1 140.5(3) . . ? 
N3 Eu1 O1 76.2(4) . . ? 
O30 Eu1 C7 94.2(4) . . ? 
O2 Eu1 C7 20.2(4) . . ? 
O28 Eu1 C7 96.7(4) . . ? 
O6 Eu1 C7 109.0(4) . . ? 
O61 Eu1 C7 109.3(4) . . ? 
O60 Eu1 C7 172.6(4) . . ? 
N3 Eu1 C7 61.9(4) . . ? 
O1 Eu1 C7 45.5(4) . . ? 
O30 Eu1 Cd12 114.2(3) . . ? 
O2 Eu1 Cd12 164.1(2) . . ? 
O28 Eu1 Cd12 110.3(2) . . ? 
O6 Eu1 Cd12 37.8(2) . . ? 
O61 Eu1 Cd12 61.8(2) . . ? 
O60 Eu1 Cd12 39.5(3) . . ? 
N3 Eu1 Cd12 100.7(3) . . ? 
O1 Eu1 Cd12 102.1(2) . . ? 
C7 Eu1 Cd12 144.1(3) . . ? 
O30 Eu1 Cd1 49.5(3) . . ? 
O2 Eu1 Cd1 32.0(2) . . ? 
O28 Eu1 Cd1 63.9(2) . . ? 
O6 Eu1 Cd1 159.4(2) . . ? 
O61 Eu1 Cd1 112.0(3) . . ? 
O60 Eu1 Cd1 125.4(3) . . ? 
N3 Eu1 Cd1 93.9(3) . . ? 
O1 Eu1 Cd1 90.4(2) . . ? 
C7 Eu1 Cd1 52.2(3) . . ? 
Cd12 Eu1 Cd1 162.72(3) . . ? 
O10 Eu2 O68 83.1(3) . . ? 
O10 Eu2 O7 129.7(3) . . ? 
O68 Eu2 O7 118.3(4) . . ? 
O10 Eu2 O39 78.2(4) . . ? 
O68 Eu2 O39 75.9(4) . . ? 
O7 Eu2 O39 147.8(4) . . ? 
O10 Eu2 O34 158.5(3) . . ? 
O68 Eu2 O34 78.2(3) . . ? 
O7 Eu2 O34 69.6(4) . . ? 
O39 Eu2 O34 87.1(4) . . ? 
O10 Eu2 O38 111.0(3) . . ? 
O68 Eu2 O38 141.6(4) . . ? 
O7 Eu2 O38 81.0(4) . . ? 
O39 Eu2 O38 72.7(4) . . ? 
O34 Eu2 O38 78.7(3) . . ? 
O10 Eu2 N4 73.2(4) . . ? 
O68 Eu2 N4 77.9(4) . . ? 
O7 Eu2 N4 68.6(4) . . ? 
O39 Eu2 N4 143.1(4) . . ? 
O34 Eu2 N4 112.5(3) . . ? 
O38 Eu2 N4 139.7(4) . . ? 
O10 Eu2 O9 62.5(3) . . ? 
O68 Eu2 O9 142.1(4) . . ? 
O7 Eu2 O9 77.9(4) . . ? 
O39 Eu2 O9 109.4(4) . . ? 
O34 Eu2 O9 138.2(3) . . ? 
O38 Eu2 O9 70.8(3) . . ? 
N4 Eu2 O9 77.3(4) . . ? 
O10 Eu2 Cd3 163.9(2) . . ? 
O68 Eu2 Cd3 110.7(3) . . ? 
O7 Eu2 Cd3 36.9(2) . . ? 
O39 Eu2 Cd3 112.4(3) . . ? 
O34 Eu2 Cd3 37.5(2) . . ? 
O38 Eu2 Cd3 63.6(2) . . ? 
N4 Eu2 Cd3 101.0(3) . . ? 
O9 Eu2 Cd3 101.8(2) . . ? 
O10 Eu2 Cd4 32.3(2) . . ? 
O68 Eu2 Cd4 63.4(3) . . ? 
O7 Eu2 Cd4 161.0(3) . . ? 
O39 Eu2 Cd4 50.4(3) . . ? 
O34 Eu2 Cd4 127.1(2) . . ? 
O38 Eu2 Cd4 109.5(2) . . ? 
N4 Eu2 Cd4 94.4(3) . . ? 
O9 Eu2 Cd4 90.4(2) . . ? 
Cd3 Eu2 Cd4 162.09(3) . . ? 
O47 Eu3 O23 76.7(4) . . ? 
O47 Eu3 O25 76.0(4) . . ? 
O23 Eu3 O25 82.0(3) . . ? 
O47 Eu3 O18 148.4(4) . . ? 
O23 Eu3 O18 129.1(4) . . ? 
O25 Eu3 O18 120.6(4) . . ? 
O47 Eu3 O46 73.7(4) . . ? 
O23 Eu3 O46 114.8(4) . . ? 
O25 Eu3 O46 140.2(4) . . ? 
O18 Eu3 O46 78.0(4) . . ? 
O47 Eu3 O44 88.1(4) . . ? 
O23 Eu3 O44 155.9(3) . . ? 
O25 Eu3 O44 76.3(3) . . ? 
O18 Eu3 O44 72.2(4) . . ? 
O46 Eu3 O44 77.4(4) . . ? 
O47 Eu3 N9 143.4(4) . . ? 
O23 Eu3 N9 74.2(4) . . ? 
O25 Eu3 N9 78.3(4) . . ? 
O18 Eu3 N9 68.1(4) . . ? 
O46 Eu3 N9 139.6(4) . . ? 
O44 Eu3 N9 110.7(4) . . ? 
O47 Eu3 O24 108.9(4) . . ? 
O23 Eu3 O24 62.8(3) . . ? 
O25 Eu3 O24 141.0(3) . . ? 
O18 Eu3 O24 75.9(4) . . ? 
O46 Eu3 O24 74.3(4) . . ? 
O44 Eu3 O24 141.0(3) . . ? 
N9 Eu3 O24 76.5(4) . . ? 
O47 Eu3 C131 94.5(4) . . ? 
O23 Eu3 C131 21.6(3) . . ? 
O25 Eu3 C131 97.9(4) . . ? 
O18 Eu3 C131 108.1(4) . . ? 
O46 Eu3 C131 109.6(4) . . ? 
O44 Eu3 C131 173.0(4) . . ? 
N9 Eu3 C131 63.7(4) . . ? 
O24 Eu3 C131 43.9(3) . . ? 
O47 Eu3 Cd6 113.8(3) . . ? 
O23 Eu3 Cd6 164.7(2) . . ? 
O25 Eu3 Cd6 110.8(2) . . ? 
O18 Eu3 Cd6 37.3(3) . . ? 
O46 Eu3 Cd6 60.9(3) . . ? 
O44 Eu3 Cd6 39.3(2) . . ? 
N9 Eu3 Cd6 99.5(3) . . ? 
O24 Eu3 Cd6 102.4(2) . . ? 
C131 Eu3 Cd6 143.3(3) . . ? 
O47 Eu3 Cd7 50.3(3) . . ? 
O23 Eu3 Cd7 30.9(2) . . ? 
O25 Eu3 Cd7 63.2(2) . . ? 
O18 Eu3 Cd7 159.5(3) . . ? 
O46 Eu3 Cd7 112.5(3) . . ? 
O44 Eu3 Cd7 126.2(2) . . ? 
N9 Eu3 Cd7 94.7(3) . . ? 
O24 Eu3 Cd7 89.7(2) . . ? 
C131 Eu3 Cd7 52.4(3) . . ? 
Cd6 Eu3 Cd7 163.16(3) . . ? 
O69 Eu4 O15 83.2(3) . . ? 
O69 Eu4 O19 117.5(4) . . ? 
O15 Eu4 O19 129.6(3) . . ? 
O69 Eu4 O57 75.0(4) . . ? 
O15 Eu4 O57 77.7(4) . . ? 
O19 Eu4 O57 149.1(3) . . ? 
O69 Eu4 O54 77.3(3) . . ? 
O15 Eu4 O54 157.9(3) . . ? 
O19 Eu4 O54 69.8(3) . . ? 
O57 Eu4 O54 87.3(4) . . ? 
O69 Eu4 O55 140.9(4) . . ? 
O15 Eu4 O55 110.5(4) . . ? 
O19 Eu4 O55 82.6(4) . . ? 
O57 Eu4 O55 72.7(4) . . ? 
O54 Eu4 O55 79.6(4) . . ? 
O69 Eu4 O16 143.6(4) . . ? 
O15 Eu4 O16 63.9(3) . . ? 
O19 Eu4 O16 77.3(4) . . ? 
O57 Eu4 O16 110.1(4) . . ? 
O54 Eu4 O16 137.5(3) . . ? 
O55 Eu4 O16 70.0(4) . . ? 
O69 Eu4 N10 77.5(4) . . ? 
O15 Eu4 N10 72.0(4) . . ? 
O19 Eu4 N10 69.4(4) . . ? 
O57 Eu4 N10 140.9(4) . . ? 
O54 Eu4 N10 113.0(4) . . ? 
O55 Eu4 N10 141.2(4) . . ? 
O16 Eu4 N10 77.9(4) . . ? 
O69 Eu4 C87 97.6(4) . . ? 
O15 Eu4 C87 21.0(3) . . ? 
O19 Eu4 C87 109.0(4) . . ? 
O57 Eu4 C87 96.2(4) . . ? 
O54 Eu4 C87 173.0(4) . . ? 
O55 Eu4 C87 107.2(4) . . ? 
O16 Eu4 C87 46.6(4) . . ? 
N10 Eu4 C87 60.7(4) . . ? 
O69 Eu4 Cd9 110.6(3) . . ? 
O15 Eu4 Cd9 164.1(2) . . ? 
O19 Eu4 Cd9 37.2(2) . . ? 
O57 Eu4 Cd9 112.9(3) . . ? 
O54 Eu4 Cd9 38.0(2) . . ? 
O55 Eu4 Cd9 64.2(3) . . ? 
O16 Eu4 Cd9 100.6(2) . . ? 
N10 Eu4 Cd9 102.4(3) . . ? 
C87 Eu4 Cd9 143.5(3) . . ? 
O69 Eu4 Cd10 63.1(3) . . ? 
O15 Eu4 Cd10 32.4(2) . . ? 
O19 Eu4 Cd10 160.7(2) . . ? 
O57 Eu4 Cd10 49.8(3) . . ? 
O54 Eu4 Cd10 126.4(2) . . ? 
O55 Eu4 Cd10 109.0(3) . . ? 
O16 Eu4 Cd10 91.9(2) . . ? 
N10 Eu4 Cd10 92.9(3) . . ? 
C87 Eu4 Cd10 53.5(3) . . ? 
Cd9 Eu4 Cd10 161.93(3) . . ? 
O29 Cd1 O2 108.8(4) . . ? 
O29 Cd1 N1 172.4(4) . . ? 
O2 Cd1 N1 77.4(4) . . ? 
O29 Cd1 O27 93.8(4) . . ? 
O2 Cd1 O27 96.5(3) . . ? 
N1 Cd1 O27 89.7(4) . . ? 
O29 Cd1 O31 84.1(4) . . ? 
O2 Cd1 O31 85.1(3) . . ? 
N1 Cd1 O31 92.3(4) . . ? 
O27 Cd1 O31 177.7(4) . . ? 
O29 Cd1 O33 87.4(4) . . ? 
O2 Cd1 O33 160.7(3) . . ? 
N1 Cd1 O33 85.7(4) . . ? 
O27 Cd1 O33 92.6(3) . . ? 
O31 Cd1 O33 86.3(3) . . ? 
O29 Cd1 Eu1 84.5(3) . . ? 
O2 Cd1 Eu1 33.4(2) . . ? 
N1 Cd1 Eu1 102.9(3) . . ? 
O27 Cd1 Eu1 75.5(2) . . ? 
O31 Cd1 Eu1 105.2(2) . . ? 
O33 Cd1 Eu1 165.1(3) . . ? 
O35 Cd2 O3 105.6(5) . . ? 
O35 Cd2 O37 113.3(5) . . ? 
O3 Cd2 O37 74.9(4) . . ? 
O35 Cd2 O32 96.4(5) . . ? 
O3 Cd2 O32 146.9(4) . . ? 
O37 Cd2 O32 118.6(4) . . ? 
O35 Cd2 O31 151.4(4) . . ? 
O3 Cd2 O31 95.2(4) . . ? 
O37 Cd2 O31 90.7(4) . . ? 
O32 Cd2 O31 57.0(4) . . ? 
O35 Cd2 O4 82.2(5) . . ? 
O3 Cd2 O4 68.1(4) . . ? 
O37 Cd2 O4 142.6(4) . . ? 
O32 Cd2 O4 91.3(5) . . ? 
O31 Cd2 O4 87.8(4) . . ? 
O35 Cd2 O36 50.4(5) . . ? 
O3 Cd2 O36 132.1(5) . . ? 
O37 Cd2 O36 79.5(5) . . ? 
O32 Cd2 O36 81.0(5) . . ? 
O31 Cd2 O36 125.2(5) . . ? 
O4 Cd2 O36 130.1(5) . . ? 
O35 Cd2 C152 124.8(5) . . ? 
O3 Cd2 C152 122.6(5) . . ? 
O37 Cd2 C152 104.3(5) . . ? 
O32 Cd2 C152 28.6(4) . . ? 
O31 Cd2 C152 28.5(4) . . ? 
O4 Cd2 C152 91.7(5) . . ? 
O36 Cd2 C152 102.5(5) . . ? 
O3 Cd3 N2 85.2(5) . . ? 
O3 Cd3 O37 75.8(4) . . ? 
N2 Cd3 O37 160.8(4) . . ? 
O3 Cd3 O7 148.7(4) . . ? 
N2 Cd3 O7 96.4(4) . . ? 
O37 Cd3 O7 98.6(4) . . ? 
O3 Cd3 O34 136.9(4) . . ? 
N2 Cd3 O34 106.4(4) . . ? 
O37 Cd3 O34 89.4(4) . . ? 
O7 Cd3 O34 72.7(3) . . ? 
O3 Cd3 O8 82.5(4) . . ? 
N2 Cd3 O8 90.7(4) . . ? 
O37 Cd3 O8 84.7(4) . . ? 
O7 Cd3 O8 66.2(3) . . ? 
O34 Cd3 O8 137.0(3) . . ? 
O3 Cd3 O33 86.7(4) . . ? 
N2 Cd3 O33 103.1(4) . . ? 
O37 Cd3 O33 78.4(3) . . ? 
O7 Cd3 O33 122.9(3) . . ? 
O34 Cd3 O33 50.4(3) . . ? 
O8 Cd3 O33 161.7(3) . . ? 
O3 Cd3 Eu2 156.1(3) . . ? 
N2 Cd3 Eu2 118.7(3) . . ? 
O37 Cd3 Eu2 80.4(3) . . ? 
O7 Cd3 Eu2 38.0(2) . . ? 
O34 Cd3 Eu2 39.8(2) . . ? 
O8 Cd3 Eu2 97.3(2) . . ? 
O33 Cd3 Eu2 86.6(2) . . ? 
O10 Cd4 O40 107.7(4) . . ? 
O10 Cd4 O67 94.7(3) . . ? 
O40 Cd4 O67 93.9(4) . . ? 
O10 Cd4 O43 160.4(4) . . ? 
O40 Cd4 O43 90.0(4) . . ? 
O67 Cd4 O43 92.4(3) . . ? 
O10 Cd4 O41 83.8(3) . . ? 
O40 Cd4 O41 84.3(4) . . ? 
O67 Cd4 O41 177.1(4) . . ? 
O43 Cd4 O41 89.8(3) . . ? 
O10 Cd4 N5 78.4(4) . . ? 
O40 Cd4 N5 172.7(4) . . ? 
O67 Cd4 N5 89.6(4) . . ? 
O43 Cd4 N5 83.4(4) . . ? 
O41 Cd4 N5 92.4(4) . . ? 
O10 Cd4 Eu2 32.9(2) . . ? 
O40 Cd4 Eu2 83.7(3) . . ? 
O67 Cd4 Eu2 73.9(2) . . ? 
O43 Cd4 Eu2 164.5(2) . . ? 
O41 Cd4 Eu2 103.6(2) . . ? 
N5 Cd4 Eu2 103.4(3) . . ? 
O14 Cd5 O42 145.0(5) . . ? 
O14 Cd5 O45 73.9(4) . . ? 
O42 Cd5 O45 117.8(5) . . ? 
O14 Cd5 O41 94.7(4) . . ? 
O42 Cd5 O41 56.7(4) . . ? 
O45 Cd5 O41 84.7(4) . . ? 
O14 Cd5 O13 66.4(5) . . ? 
O42 Cd5 O13 93.4(6) . . ? 
O45 Cd5 O13 140.1(4) . . ? 
O41 Cd5 O13 93.7(4) . . ? 
O14 Cd5 O71 130.2(5) . . ? 
O42 Cd5 O71 84.6(6) . . ? 
O45 Cd5 O71 86.5(6) . . ? 
O41 Cd5 O71 129.1(5) . . ? 
O13 Cd5 O71 122.9(6) . . ? 
N7 Cd6 O14 85.3(5) . . ? 
N7 Cd6 O45 159.8(4) . . ? 
O14 Cd6 O45 74.6(5) . . ? 
N7 Cd6 O18 98.2(4) . . ? 
O14 Cd6 O18 146.2(4) . . ? 
O45 Cd6 O18 97.7(4) . . ? 
N7 Cd6 O44 105.1(4) . . ? 
O14 Cd6 O44 137.9(4) . . ? 
O45 Cd6 O44 91.2(4) . . ? 
O18 Cd6 O44 73.9(3) . . ? 
N7 Cd6 O17 92.2(5) . . ? 
O14 Cd6 O17 82.3(4) . . ? 
O45 Cd6 O17 83.7(4) . . ? 
O18 Cd6 O17 64.0(4) . . ? 
O44 Cd6 O17 136.3(4) . . ? 
N7 Cd6 O43 100.9(4) . . ? 
O14 Cd6 O43 87.5(4) . . ? 
O45 Cd6 O43 80.0(4) . . ? 
O18 Cd6 O43 124.2(3) . . ? 
O44 Cd6 O43 50.7(3) . . ? 
O17 Cd6 O43 162.7(4) . . ? 
N7 Cd6 Eu3 118.6(3) . . ? 
O14 Cd6 Eu3 156.1(3) . . ? 
O45 Cd6 Eu3 81.6(3) . . ? 
O18 Cd6 Eu3 37.9(3) . . ? 
O44 Cd6 Eu3 40.5(2) . . ? 
O17 Cd6 Eu3 96.0(3) . . ? 
O43 Cd6 Eu3 87.7(2) . . ? 
O23 Cd7 O48 105.5(4) . . ? 
O23 Cd7 O26 94.9(4) . . ? 
O48 Cd7 O26 93.2(4) . . ? 
O23 Cd7 N12 79.3(4) . . ? 
O48 Cd7 N12 174.2(4) . . ? 
O26 Cd7 N12 89.4(4) . . ? 
O23 Cd7 O53 162.0(3) . . ? 
O48 Cd7 O53 89.9(4) . . ? 
O26 Cd7 O53 93.3(4) . . ? 
N12 Cd7 O53 84.8(4) . . ? 
O23 Cd7 O49 85.5(4) . . ? 
O48 Cd7 O49 85.3(4) . . ? 
O26 Cd7 O49 178.5(4) . . ? 
N12 Cd7 O49 92.1(4) . . ? 
O53 Cd7 O49 86.7(4) . . ? 
O23 Cd7 Eu3 31.8(2) . . ? 
O48 Cd7 Eu3 82.7(3) . . ? 
O26 Cd7 Eu3 74.1(3) . . ? 
N12 Cd7 Eu3 102.9(3) . . ? 
O53 Cd7 Eu3 165.0(3) . . ? 
O49 Cd7 Eu3 105.6(3) . . ? 
O56 Cd8 O22 75.3(4) . . ? 
O56 Cd8 O50 113.2(4) . . ? 
O22 Cd8 O50 142.1(4) . . ? 
O56 Cd8 O52 125.4(5) . . ? 
O22 Cd8 O52 108.0(5) . . ? 
O50 Cd8 O52 96.6(6) . . ? 
O56 Cd8 O49 86.7(4) . . ? 
O22 Cd8 O49 90.8(4) . . ? 
O50 Cd8 O49 54.7(4) . . ? 
O52 Cd8 O49 145.5(5) . . ? 
O56 Cd8 O21 142.7(4) . . ? 
O22 Cd8 O21 68.1(4) . . ? 
O50 Cd8 O21 92.3(4) . . ? 
O52 Cd8 O21 74.5(5) . . ? 
O49 Cd8 O21 86.9(4) . . ? 
O56 Cd8 O51 81.9(5) . . ? 
O22 Cd8 O51 124.7(5) . . ? 
O50 Cd8 O51 93.2(5) . . ? 
O52 Cd8 O51 50.5(6) . . ? 
O49 Cd8 O51 137.7(5) . . ? 
O21 Cd8 O51 125.0(5) . . ? 
O56 Cd8 C170 99.8(4) . . ? 
O22 Cd8 C170 117.0(4) . . ? 
O50 Cd8 C170 27.7(4) . . ? 
O52 Cd8 C170 122.7(6) . . ? 
O49 Cd8 C170 27.0(4) . . ? 
O21 Cd8 C170 90.6(4) . . ? 
O51 Cd8 C170 116.2(5) . . ? 
O56 Cd8 C174 104.3(5) . . ? 
O22 Cd8 C174 121.5(5) . . ? 
O50 Cd8 C174 93.1(5) . . ? 
O52 Cd8 C174 26.3(5) . . ? 
O49 Cd8 C174 147.4(5) . . ? 
O21 Cd8 C174 100.7(5) . . ? 
O51 Cd8 C174 24.4(5) . . ? 
C170 Cd8 C174 120.5(6) . . ? 
O22 Cd9 N11 82.7(4) . . ? 
O22 Cd9 O19 147.5(4) . . ? 
N11 Cd9 O19 94.9(4) . . ? 
O22 Cd9 O56 75.7(4) . . ? 
N11 Cd9 O56 157.6(5) . . ? 
O19 Cd9 O56 100.2(4) . . ? 
O22 Cd9 O54 138.9(4) . . ? 
N11 Cd9 O54 110.3(4) . . ? 
O19 Cd9 O54 72.3(3) . . ? 
O56 Cd9 O54 90.1(4) . . ? 
O22 Cd9 O20 81.2(4) . . ? 
N11 Cd9 O20 85.7(4) . . ? 
O19 Cd9 O20 66.3(3) . . ? 
O56 Cd9 O20 85.4(3) . . ? 
O54 Cd9 O20 136.7(3) . . ? 
O22 Cd9 O53 87.0(4) . . ? 
N11 Cd9 O53 104.9(4) . . ? 
O19 Cd9 O53 124.5(3) . . ? 
O56 Cd9 O53 79.9(3) . . ? 
O54 Cd9 O53 52.2(3) . . ? 
O20 Cd9 O53 163.1(3) . . ? 
O22 Cd9 Eu4 156.6(3) . . ? 
N11 Cd9 Eu4 120.7(3) . . ? 
O19 Cd9 Eu4 38.8(2) . . ? 
O56 Cd9 Eu4 80.9(3) . . ? 
O54 Cd9 Eu4 39.2(2) . . ? 
O20 Cd9 Eu4 97.8(2) . . ? 
O53 Cd9 Eu4 88.2(2) . . ? 
O58 Cd10 O15 108.0(4) . . ? 
O58 Cd10 O59 88.5(4) . . ? 
O15 Cd10 O59 162.3(3) . . ? 
O58 Cd10 O70 95.0(4) . . ? 
O15 Cd10 O70 95.4(3) . . ? 
O59 Cd10 O70 89.4(3) . . ? 
O58 Cd10 N8 172.9(4) . . ? 
O15 Cd10 N8 78.4(4) . . ? 
O59 Cd10 N8 84.9(4) . . ? 
O70 Cd10 N8 87.4(4) . . ? 
O58 Cd10 O64 83.4(4) . . ? 
O15 Cd10 O64 85.5(4) . . ? 
O59 Cd10 O64 90.1(3) . . ? 
O70 Cd10 O64 178.3(4) . . ? 
N8 Cd10 O64 94.2(4) . . ? 
O58 Cd10 Eu4 84.1(3) . . ? 
O15 Cd10 Eu4 33.1(2) . . ? 
O59 Cd10 Eu4 161.9(2) . . ? 
O70 Cd10 Eu4 74.9(2) . . ? 
N8 Cd10 Eu4 103.0(3) . . ? 
O64 Cd10 Eu4 105.4(3) . . ? 
O11 Cd11 O63 145.1(4) . . ? 
O11 Cd11 O65 98.4(4) . . ? 
O63 Cd11 O65 102.1(4) . . ? 
O11 Cd11 O62 75.8(4) . . ? 
O63 Cd11 O62 115.8(4) . . ? 
O65 Cd11 O62 120.4(4) . . ? 
O11 Cd11 O64 93.6(4) . . ? 
O63 Cd11 O64 56.7(4) . . ? 
O65 Cd11 O64 152.3(4) . . ? 
O62 Cd11 O64 86.7(4) . . ? 
O11 Cd11 O12 66.7(3) . . ? 
O63 Cd11 O12 91.1(4) . . ? 
O65 Cd11 O12 76.3(4) . . ? 
O62 Cd11 O12 141.2(4) . . ? 
O64 Cd11 O12 85.8(3) . . ? 
O11 Cd11 O66 127.2(4) . . ? 
O63 Cd11 O66 87.7(4) . . ? 
O65 Cd11 O66 55.3(4) . . ? 
O62 Cd11 O66 81.1(4) . . ? 
O64 Cd11 O66 132.0(4) . . ? 
O12 Cd11 O66 130.0(3) . . ? 
O11 Cd11 C182 113.9(4) . . ? 
O63 Cd11 C182 96.8(4) . . ? 
O65 Cd11 C182 27.9(4) . . ? 
O62 Cd11 C182 100.4(4) . . ? 
O64 Cd11 C182 152.5(4) . . ? 
O12 Cd11 C182 103.7(4) . . ? 
O66 Cd11 C182 27.5(4) . . ? 
O11 Cd11 C178 120.2(4) . . ? 
O63 Cd11 C178 28.2(4) . . ? 
O65 Cd11 C178 128.3(4) . . ? 
O62 Cd11 C178 102.6(4) . . ? 
O64 Cd11 C178 28.5(4) . . ? 
O12 Cd11 C178 88.1(4) . . ? 
O66 Cd11 C178 110.9(4) . . ? 
C182 Cd11 C178 124.7(5) . . ? 
O62 Cd12 N6 160.3(4) . . ? 
O62 Cd12 O11 75.7(4) . . ? 
N6 Cd12 O11 84.8(4) . . ? 
O62 Cd12 O6 99.3(4) . . ? 
N6 Cd12 O6 95.8(4) . . ? 
O11 Cd12 O6 147.9(3) . . ? 
O62 Cd12 O60 87.9(4) . . ? 
N6 Cd12 O60 108.6(4) . . ? 
O11 Cd12 O60 136.9(4) . . ? 
O6 Cd12 O60 73.3(4) . . ? 
O62 Cd12 O5 87.6(4) . . ? 
N6 Cd12 O5 87.0(4) . . ? 
O11 Cd12 O5 82.0(3) . . ? 
O6 Cd12 O5 66.0(3) . . ? 
O60 Cd12 O5 137.7(4) . . ? 
O62 Cd12 Eu1 79.4(3) . . ? 
N6 Cd12 Eu1 120.1(3) . . ? 
O11 Cd12 Eu1 155.1(3) . . ? 
O6 Cd12 Eu1 38.6(2) . . ? 
O60 Cd12 Eu1 40.0(3) . . ? 
O5 Cd12 Eu1 98.0(2) . . ? 
C8 N1 C9 117.0(13) . . ? 
C8 N1 Cd1 126.3(10) . . ? 
C9 N1 Cd1 116.6(9) . . ? 
C15 N2 C14 116.4(14) . . ? 
C15 N2 Cd3 122.9(11) . . ? 
C14 N2 Cd3 120.4(10) . . ? 
C30 N3 C31 113.5(14) . . ? 
C30 N3 Eu1 125.2(11) . . ? 
C31 N3 Eu1 120.4(11) . . ? 
C37 N4 C36 114.3(13) . . ? 
C37 N4 Eu2 127.0(11) . . ? 
C36 N4 Eu2 117.6(9) . . ? 
C52 N5 C53 121.9(14) . . ? 
C52 N5 Cd4 122.8(11) . . ? 
C53 N5 Cd4 115.3(11) . . ? 
C59 N6 C58 115.9(14) . . ? 
C59 N6 Cd12 125.3(12) . . ? 
C58 N6 Cd12 118.4(9) . . ? 
C74 N7 C75 112.7(15) . . ? 
C74 N7 Cd6 127.2(12) . . ? 
C75 N7 Cd6 118.5(10) . . ? 
C81 N8 C80 115.2(13) . . ? 
C81 N8 Cd10 121.9(10) . . ? 
C80 N8 Cd10 122.3(9) . . ? 
C96 N9 C97 112.0(13) . . ? 
C96 N9 Eu3 123.9(11) . . ? 
C97 N9 Eu3 122.4(9) . . ? 
C103 N10 C102 117.6(13) . . ? 
C103 N10 Eu4 121.9(11) . . ? 
C102 N10 Eu4 120.0(10) . . ? 
C118 N11 C119 122.2(14) . . ? 
C118 N11 Cd9 122.8(11) . . ? 
C119 N11 Cd9 115.1(11) . . ? 
C125 N12 C124 114.4(14) . . ? 
C125 N12 Cd7 123.9(11) . . ? 
C124 N12 Cd7 121.0(10) . . ? 
C2 O1 C1 117.7(12) . . ? 
C2 O1 Eu1 113.7(8) . . ? 
C1 O1 Eu1 126.7(9) . . ? 
C7 O2 Cd1 125.8(9) . . ? 
C7 O2 Eu1 119.4(10) . . ? 
Cd1 O2 Eu1 114.6(4) . . ? 
C21 O3 Cd3 130.7(10) . . ? 
C21 O3 Cd2 122.6(10) . . ? 
Cd3 O3 Cd2 106.6(5) . . ? 
C20 O4 C22 111.3(14) . . ? 
C20 O4 Cd2 118.8(10) . . ? 
C22 O4 Cd2 125.6(11) . . ? 
C24 O5 C23 113.2(12) . . ? 
C24 O5 Cd12 116.5(8) . . ? 
C23 O5 Cd12 128.3(10) . . ? 
C29 O6 Cd12 118.3(8) . . ? 
C29 O6 Eu1 133.3(8) . . ? 
Cd12 O6 Eu1 103.6(4) . . ? 
C43 O7 Cd3 122.8(9) . . ? 
C43 O7 Eu2 129.4(10) . . ? 
Cd3 O7 Eu2 105.2(4) . . ? 
C42 O8 C44 110.5(11) . . ? 
C42 O8 Cd3 115.7(8) . . ? 
C44 O8 Cd3 132.9(8) . . ? 
C45 O9 C46 117.1(11) . . ? 
C45 O9 Eu2 128.6(9) . . ? 
C46 O9 Eu2 112.9(8) . . ? 
C51 O10 Cd4 118.2(8) . . ? 
C51 O10 Eu2 127.0(8) . . ? 
Cd4 O10 Eu2 114.8(4) . . ? 
C65 O11 Cd11 126.0(10) . . ? 
C65 O11 Cd12 128.1(10) . . ? 
Cd11 O11 Cd12 105.8(4) . . ? 
C66 O12 C64 116.1(12) . . ? 
C66 O12 Cd11 121.5(10) . . ? 
C64 O12 Cd11 113.3(8) . . ? 
C68 O13 C67 109.7(15) . . ? 
C68 O13 Cd5 119.1(12) . . ? 
C67 O13 Cd5 127.4(12) . . ? 
C73 O14 Cd5 126.1(11) . . ? 
C73 O14 Cd6 125.6(12) . . ? 
Cd5 O14 Cd6 107.6(6) . . ? 
C87 O15 Cd10 124.4(9) . . ? 
C87 O15 Eu4 121.1(9) . . ? 
Cd10 O15 Eu4 114.5(4) . . ? 
C88 O16 C86 120.7(12) . . ? 
C88 O16 Eu4 127.7(9) . . ? 
C86 O16 Eu4 110.7(8) . . ? 
C90 O17 C89 120.1(14) . . ? 
C90 O17 Cd6 112.9(10) . . ? 
C89 O17 Cd6 123.9(11) . . ? 
C95 O18 Cd6 120.0(9) . . ? 
C95 O18 Eu3 133.0(9) . . ? 
Cd6 O18 Eu3 104.7(4) . . ? 
C109 O19 Cd9 125.6(9) . . ? 
C109 O19 Eu4 125.5(9) . . ? 
Cd9 O19 Eu4 104.0(4) . . ? 
C108 O20 C110 116.8(11) . . ? 
C108 O20 Cd9 115.5(9) . . ? 
C110 O20 Cd9 125.8(8) . . ? 
C112 O21 C111 121.2(14) . . ? 
C112 O21 Cd8 114.3(10) . . ? 
C111 O21 Cd8 120.2(11) . . ? 
C117 O22 Cd9 134.7(10) . . ? 
C117 O22 Cd8 119.4(10) . . ? 
Cd9 O22 Cd8 105.2(5) . . ? 
C131 O23 Cd7 121.8(8) . . ? 
C131 O23 Eu3 120.7(9) . . ? 
Cd7 O23 Eu3 117.2(4) . . ? 
C130 O24 C132 119.2(13) . . ? 
C130 O24 Eu3 113.2(10) . . ? 
C132 O24 Eu3 127.2(9) . . ? 
C140 O25 Eu3 146.8(9) . . ? 
C140 O26 Cd7 128.7(9) . . ? 
C148 O27 Cd1 123.2(9) . . ? 
C148 O28 Eu1 145.8(10) . . ? 
C150 O29 Cd1 110.4(10) . . ? 
C150 O30 Eu1 169.3(11) . . ? 
C152 O31 Cd1 135.7(10) . . ? 
C152 O31 Cd2 89.3(9) . . ? 
Cd1 O31 Cd2 134.7(4) . . ? 
C152 O32 Cd2 91.1(9) . . ? 
C154 O33 Cd1 128.6(10) . . ? 
C154 O33 Cd3 90.4(9) . . ? 
Cd1 O33 Cd3 138.2(5) . . ? 
C154 O34 Cd3 102.5(9) . . ? 
C154 O34 Eu2 140.4(9) . . ? 
Cd3 O34 Eu2 102.7(4) . . ? 
C156 O35 Cd2 102.7(13) . . ? 
C156 O36 Cd2 85.0(15) . . ? 
C158 O37 Cd2 134.6(11) . . ? 
C158 O37 Cd3 121.7(10) . . ? 
Cd2 O37 Cd3 102.7(5) . . ? 
C158 O38 Eu2 139.9(11) . . ? 
C160 O39 Eu2 169.0(13) . . ? 
C160 O40 Cd4 109.4(10) . . ? 
C162 O41 Cd4 133.4(10) . . ? 
C162 O41 Cd5 92.1(9) . . ? 
Cd4 O41 Cd5 134.4(5) . . ? 
C162 O42 Cd5 99.0(12) . . ? 
C164 O43 Cd4 130.4(9) . . ? 
C164 O43 Cd6 87.7(7) . . ? 
Cd4 O43 Cd6 135.9(4) . . ? 
C164 O44 Cd6 102.7(8) . . ? 
C164 O44 Eu3 142.0(9) . . ? 
Cd6 O44 Eu3 100.2(4) . . ? 
C166 O45 Cd6 121.8(11) . . ? 
C166 O45 Cd5 134.3(12) . . ? 
Cd6 O45 Cd5 103.9(5) . . ? 
C166 O46 Eu3 145.5(12) . . ? 
C168 O47 Eu3 168.5(13) . . ? 
C168 O48 Cd7 113.6(12) . . ? 
C170 O49 Cd8 90.1(9) . . ? 
C170 O49 Cd7 132.5(10) . . ? 
Cd8 O49 Cd7 136.9(5) . . ? 
C170 O50 Cd8 93.5(10) . . ? 
C174 O51 Cd8 92.8(14) . . ? 
C174 O52 Cd8 95.0(13) . . ? 
C172 O53 Cd7 131.3(10) . . ? 
C172 O53 Cd9 87.0(10) . . ? 
Cd7 O53 Cd9 137.9(5) . . ? 
C172 O54 Cd9 101.2(10) . . ? 
C172 O54 Eu4 142.9(10) . . ? 
Cd9 O54 Eu4 102.8(4) . . ? 
C186 O55 Eu4 143.8(12) . . ? 
C186 O56 Cd8 135.3(10) . . ? 
C186 O56 Cd9 120.9(10) . . ? 
Cd8 O56 Cd9 103.7(5) . . ? 
C176 O57 Eu4 165.2(12) . . ? 
C176 O58 Cd10 113.6(11) . . ? 
C180 O59 Cd10 132.9(9) . . ? 
C180 O60 Cd12 99.9(9) . . ? 
C180 O60 Eu1 145.6(10) . . ? 
Cd12 O60 Eu1 100.5(4) . . ? 
C184 O61 Eu1 145.5(10) . . ? 
C184 O62 Cd12 124.5(10) . . ? 
C184 O62 Cd11 132.9(10) . . ? 
Cd12 O62 Cd11 102.6(5) . . ? 
C178 O63 Cd11 95.4(8) . . ? 
C178 O64 Cd10 136.0(10) . . ? 
C178 O64 Cd11 90.4(9) . . ? 
Cd10 O64 Cd11 133.6(5) . . ? 
C182 O65 Cd11 95.5(9) . . ? 
C182 O66 Cd11 86.6(9) . . ? 
C133 O67 Cd4 128.1(10) . . ? 
C133 O68 Eu2 145.7(11) . . ? 
C141 O69 Eu4 148.4(9) . . ? 
C141 O70 Cd10 128.1(9) . . ? 
Cd5 O71 H71D 110.6 . . ? 
Cd5 O71 H71A 107.6 . . ? 
H71D O71 H71A 109.8 . . ? 
O1 C1 H1A 109.5 . . ? 
O1 C1 H1B 109.5 . . ? 
H1A C1 H1B 109.5 . . ? 
O1 C1 H1C 109.5 . . ? 
H1A C1 H1C 109.5 . . ? 
H1B C1 H1C 109.5 . . ? 
O1 C2 C3 125.8(15) . . ? 
O1 C2 C7 109.7(13) . . ? 
C3 C2 C7 123.9(15) . . ? 
C4 C3 C2 119.2(16) . . ? 
C4 C3 H3A 120.4 . . ? 
C2 C3 H3A 120.4 . . ? 
C3 C4 C5 123.7(17) . . ? 
C3 C4 H4A 118.1 . . ? 
C5 C4 H4A 118.1 . . ? 
C6 C5 C4 116.4(17) . . ? 
C6 C5 H5A 121.8 . . ? 
C4 C5 H5A 121.8 . . ? 
C5 C6 C8 120.0(14) . . ? 
C5 C6 C7 126.2(13) . . ? 
C8 C6 C7 112.9(13) . . ? 
O2 C7 C2 122.8(13) . . ? 
O2 C7 C6 126.9(13) . . ? 
C2 C7 C6 109.4(13) . . ? 
O2 C7 Eu1 40.3(7) . . ? 
C2 C7 Eu1 86.4(9) . . ? 
C6 C7 Eu1 147.7(10) . . ? 
N1 C8 C6 132.6(15) . . ? 
N1 C8 H8A 113.7 . . ? 
C6 C8 H8A 113.7 . . ? 
N1 C9 C10 107.0(11) . . ? 
N1 C9 H9A 110.3 . . ? 
C10 C9 H9A 110.3 . . ? 
N1 C9 H9B 110.3 . . ? 
C10 C9 H9B 110.3 . . ? 
H9A C9 H9B 108.6 . . ? 
C11 C10 C9 106.1(11) . . ? 
C11 C10 H10A 110.5 . . ? 
C9 C10 H10A 110.5 . . ? 
C11 C10 H10B 110.5 . . ? 
C9 C10 H10B 110.5 . . ? 
H10A C10 H10B 108.7 . . ? 
C12 C11 C10 111.7(13) . . ? 
C12 C11 H11A 109.3 . . ? 
C10 C11 H11A 109.3 . . ? 
C12 C11 H11B 109.3 . . ? 
C10 C11 H11B 109.3 . . ? 
H11A C11 H11B 107.9 . . ? 
C11 C12 C13 109.4(13) . 8_665 ? 
C11 C12 H12A 109.8 . . ? 
C13 C12 H12A 109.8 8_665 . ? 
C11 C12 H12B 109.8 . . ? 
C13 C12 H12B 109.8 8_665 . ? 
H12A C12 H12B 108.2 . . ? 
C14 C13 C12 111.2(13) . 8_665 ? 
C14 C13 H13B 109.4 . . ? 
C12 C13 H13B 109.4 8_665 . ? 
C14 C13 H13C 109.4 . . ? 
C12 C13 H13C 109.4 8_665 . ? 
H13B C13 H13C 108.0 . . ? 
N2 C14 C13 107.8(13) . . ? 
N2 C14 H14A 110.2 . . ? 
C13 C14 H14A 110.2 . . ? 
N2 C14 H14B 110.2 . . ? 
C13 C14 H14B 110.2 . . ? 
H14A C14 H14B 108.5 . . ? 
N2 C15 C16 135.6(16) . . ? 
N2 C15 H15A 112.2 . . ? 
C16 C15 H15A 112.2 . . ? 
C17 C16 C15 121.9(17) . . ? 
C17 C16 C21 119.8(16) . . ? 
C15 C16 C21 118.1(16) . . ? 
C16 C17 C18 122.7(19) . . ? 
C16 C17 H17A 118.7 . . ? 
C18 C17 H17A 118.7 . . ? 
C17 C18 C19 126(2) . . ? 
C17 C18 H18A 117.2 . . ? 
C19 C18 H18A 117.2 . . ? 
C18 C19 C20 113.5(18) . . ? 
C18 C19 H19A 123.3 . . ? 
C20 C19 H19A 123.3 . . ? 
O4 C20 C19 125.8(15) . . ? 
O4 C20 C21 108.6(15) . . ? 
C19 C20 C21 123.1(16) . . ? 
O3 C21 C20 120.4(16) . . ? 
O3 C21 C16 125.8(15) . . ? 
C20 C21 C16 113.7(15) . . ? 
O4 C22 H22A 109.5 . . ? 
O4 C22 H22B 109.5 . . ? 
H22A C22 H22B 109.5 . . ? 
O4 C22 H22C 109.5 . . ? 
H22A C22 H22C 109.5 . . ? 
H22B C22 H22C 109.5 . . ? 
O5 C23 H23A 109.5 . . ? 
O5 C23 H23B 109.5 . . ? 
H23A C23 H23B 109.5 . . ? 
O5 C23 H23C 109.5 . . ? 
H23A C23 H23C 109.5 . . ? 
H23B C23 H23C 109.5 . . ? 
C25 C24 C29 122.6(15) . . ? 
C25 C24 O5 126.6(15) . . ? 
C29 C24 O5 110.6(12) . . ? 
C24 C25 C26 123.3(17) . . ? 
C24 C25 H25A 118.4 . . ? 
C26 C25 H25A 118.4 . . ? 
C25 C26 C27 118.0(17) . . ? 
C25 C26 H26A 121.0 . . ? 
C27 C26 H26A 121.0 . . ? 
C26 C27 C28 116.3(14) . . ? 
C26 C27 H27A 121.8 . . ? 
C28 C27 H27A 121.8 . . ? 
C29 C28 C27 125.1(13) . . ? 
C29 C28 C30 124.1(13) . . ? 
C27 C28 C30 110.6(12) . . ? 
O6 C29 C24 125.3(13) . . ? 
O6 C29 C28 119.9(12) . . ? 
C24 C29 C28 114.6(13) . . ? 
N3 C30 C28 124.2(14) . . ? 
N3 C30 H30A 117.9 . . ? 
C28 C30 H30A 117.9 . . ? 
C32 C31 N3 108.2(13) . . ? 
C32 C31 H31A 110.1 . . ? 
N3 C31 H31A 110.1 . . ? 
C32 C31 H31B 110.1 . . ? 
N3 C31 H31B 110.1 . . ? 
H31A C31 H31B 108.4 . . ? 
C33 C32 C31 115.7(15) . . ? 
C33 C32 H32A 108.3 . . ? 
C31 C32 H32A 108.3 . . ? 
C33 C32 H32B 108.3 . . ? 
C31 C32 H32B 108.3 . . ? 
H32A C32 H32B 107.4 . . ? 
C32 C33 C34 113.4(13) . . ? 
C32 C33 H33A 108.9 . . ? 
C34 C33 H33A 108.9 . . ? 
C32 C33 H33B 108.9 . . ? 
C34 C33 H33B 108.9 . . ? 
H33A C33 H33B 107.7 . . ? 
C35 C34 C33 109.7(12) . . ? 
C35 C34 H34A 109.7 . . ? 
C33 C34 H34A 109.7 . . ? 
C35 C34 H34B 109.7 . . ? 
C33 C34 H34B 109.7 . . ? 
H34A C34 H34B 108.2 . . ? 
C34 C35 C36 110.6(12) . 8_665 ? 
C34 C35 H35B 109.5 . . ? 
C36 C35 H35B 109.5 8_665 . ? 
C34 C35 H35C 109.5 . . ? 
C36 C35 H35C 109.5 8_665 . ? 
H35B C35 H35C 108.1 . . ? 
N4 C36 C35 105.0(10) . 8_665 ? 
N4 C36 H36B 110.7 . . ? 
C35 C36 H36B 110.7 8_665 . ? 
N4 C36 H36C 110.7 . . ? 
C35 C36 H36C 110.7 8_665 . ? 
H36B C36 H36C 108.8 . . ? 
N4 C37 C38 122.5(16) . . ? 
N4 C37 H37A 118.8 . . ? 
C38 C37 H37A 118.8 . . ? 
C37 C38 C39 117.9(14) . . ? 
C37 C38 C43 125.8(15) . . ? 
C39 C38 C43 114.9(15) . . ? 
C38 C39 C40 125.5(16) . . ? 
C38 C39 H39A 117.2 . . ? 
C40 C39 H39A 117.2 . . ? 
C39 C40 C41 119.4(16) . . ? 
C39 C40 H40A 120.3 . . ? 
C41 C40 H40A 120.3 . . ? 
C42 C41 C40 116.9(17) . . ? 
C42 C41 H41A 121.5 . . ? 
C40 C41 H41A 121.5 . . ? 
C41 C42 O8 123.9(15) . . ? 
C41 C42 C43 122.6(16) . . ? 
O8 C42 C43 113.4(14) . . ? 
O7 C43 C38 122.4(14) . . ? 
O7 C43 C42 116.8(15) . . ? 
C38 C43 C42 120.3(15) . . ? 
O8 C44 H44A 109.5 . . ? 
O8 C44 H44B 109.5 . . ? 
H44A C44 H44B 109.5 . . ? 
O8 C44 H44C 109.5 . . ? 
H44A C44 H44C 109.5 . . ? 
H44B C44 H44C 109.5 . . ? 
O9 C45 H45A 109.5 . . ? 
O9 C45 H45B 109.5 . . ? 
H45A C45 H45B 109.5 . . ? 
O9 C45 H45C 109.5 . . ? 
H45A C45 H45C 109.5 . . ? 
H45B C45 H45C 109.5 . . ? 
C47 C46 O9 128.2(14) . . ? 
C47 C46 C51 116.6(15) . . ? 
O9 C46 C51 115.2(13) . . ? 
C48 C47 C46 121.3(16) . . ? 
C48 C47 H47A 119.3 . . ? 
C46 C47 H47A 119.3 . . ? 
C47 C48 C49 122.0(19) . . ? 
C47 C48 H48A 119.0 . . ? 
C49 C48 H48A 119.0 . . ? 
C50 C49 C48 128.6(19) . . ? 
C50 C49 H49A 115.7 . . ? 
C48 C49 H49A 115.7 . . ? 
C49 C50 C52 132.7(15) . . ? 
C49 C50 C51 108.7(14) . . ? 
C52 C50 C51 109.2(13) . . ? 
O10 C51 C46 109.1(13) . . ? 
O10 C51 C50 130.7(13) . . ? 
C46 C51 C50 117.9(14) . . ? 
N5 C52 C50 142.2(15) . . ? 
N5 C52 H52A 108.9 . . ? 
C50 C52 H52A 108.9 . . ? 
N5 C53 C54 114.3(13) . . ? 
N5 C53 H53A 108.7 . . ? 
C54 C53 H53A 108.7 . . ? 
N5 C53 H53B 108.7 . . ? 
C54 C53 H53B 108.7 . . ? 
H53A C53 H53B 107.6 . . ? 
C55 C54 C53 114.3(12) . . ? 
C55 C54 H54A 108.7 . . ? 
C53 C54 H54A 108.7 . . ? 
C55 C54 H54B 108.7 . . ? 
C53 C54 H54B 108.7 . . ? 
H54A C54 H54B 107.6 . . ? 
C54 C55 C56 115.0(12) . 8_665 ? 
C54 C55 H55B 108.5 . . ? 
C56 C55 H55B 108.5 8_665 . ? 
C54 C55 H55C 108.5 . . ? 
C56 C55 H55C 108.5 8_665 . ? 
H55B C55 H55C 107.5 . . ? 
C57 C56 C55 112.0(12) . 8_665 ? 
C57 C56 H56B 109.2 . . ? 
C55 C56 H56B 109.2 8_665 . ? 
C57 C56 H56C 109.2 . . ? 
C55 C56 H56C 109.2 8_665 . ? 
H56B C56 H56C 107.9 . . ? 
C58 C57 C56 112.3(13) . . ? 
C58 C57 H57A 109.2 . . ? 
C56 C57 H57A 109.2 . . ? 
C58 C57 H57B 109.2 . . ? 
C56 C57 H57B 109.2 . . ? 
H57A C57 H57B 107.9 . . ? 
N6 C58 C57 108.3(13) . . ? 
N6 C58 H58A 110.0 . . ? 
C57 C58 H58A 110.0 . . ? 
N6 C58 H58B 110.0 . . ? 
C57 C58 H58B 110.0 . . ? 
H58A C58 H58B 108.4 . . ? 
N6 C59 C60 130.3(17) . . ? 
N6 C59 H59A 114.8 . . ? 
C60 C59 H59A 114.8 . . ? 
C61 C60 C59 117.8(15) . . ? 
C61 C60 C65 120.5(15) . . ? 
C59 C60 C65 121.6(15) . . ? 
C62 C61 C60 124.0(16) . . ? 
C62 C61 H61A 118.0 . . ? 
C60 C61 H61A 118.0 . . ? 
C61 C62 C63 118.3(15) . . ? 
C61 C62 H62A 120.9 . . ? 
C63 C62 H62A 120.9 . . ? 
C64 C63 C62 121.6(14) . . ? 
C64 C63 H63A 119.2 . . ? 
C62 C63 H63A 119.2 . . ? 
C63 C64 C65 126.6(16) . . ? 
C63 C64 O12 123.8(14) . . ? 
C65 C64 O12 109.6(14) . . ? 
O11 C65 C64 122.2(15) . . ? 
O11 C65 C60 128.4(15) . . ? 
C64 C65 C60 109.1(15) . . ? 
O12 C66 H66A 109.5 . . ? 
O12 C66 H66B 109.5 . . ? 
H66A C66 H66B 109.5 . . ? 
O12 C66 H66C 109.5 . . ? 
H66A C66 H66C 109.5 . . ? 
H66B C66 H66C 109.5 . . ? 
O13 C67 H67A 109.5 . . ? 
O13 C67 H67B 109.5 . . ? 
H67A C67 H67B 109.5 . . ? 
O13 C67 H67C 109.5 . . ? 
H67A C67 H67C 109.5 . . ? 
H67B C67 H67C 109.5 . . ? 
C69 C68 O13 129.5(19) . . ? 
C69 C68 C73 125.1(19) . . ? 
O13 C68 C73 104.7(17) . . ? 
C68 C69 C70 119(2) . . ? 
C68 C69 H69A 120.7 . . ? 
C70 C69 H69A 120.7 . . ? 
C71 C70 C69 118(3) . . ? 
C71 C70 H70A 120.8 . . ? 
C69 C70 H70A 120.8 . . ? 
C70 C71 C72 122(3) . . ? 
C70 C71 H71B 118.8 . . ? 
C72 C71 H71B 118.8 . . ? 
C73 C72 C71 123.2(19) . . ? 
C73 C72 C74 120.8(17) . . ? 
C71 C72 C74 116.0(19) . . ? 
O14 C73 C72 130.6(17) . . ? 
O14 C73 C68 121.3(17) . . ? 
C72 C73 C68 108.2(17) . . ? 
N7 C74 C72 127.7(18) . . ? 
N7 C74 H74A 116.1 . . ? 
C72 C74 H74A 116.1 . . ? 
C76 C75 N7 110.1(13) . . ? 
C76 C75 H75A 109.7 . . ? 
N7 C75 H75A 109.7 . . ? 
C76 C75 H75B 109.7 . . ? 
N7 C75 H75B 109.7 . . ? 
H75A C75 H75B 108.2 . . ? 
C75 C76 C77 117.7(14) . . ? 
C75 C76 H76A 107.9 . . ? 
C77 C76 H76A 107.9 . . ? 
C75 C76 H76B 107.9 . . ? 
C77 C76 H76B 107.9 . . ? 
H76A C76 H76B 107.2 . . ? 
C76 C77 C78 116.3(13) . . ? 
C76 C77 H77A 108.2 . . ? 
C78 C77 H77A 108.2 . . ? 
C76 C77 H77B 108.2 . . ? 
C78 C77 H77B 108.2 . . ? 
H77A C77 H77B 107.4 . . ? 
C77 C78 C79 115.6(12) . 8_665 ? 
C77 C78 H78B 108.4 . . ? 
C79 C78 H78B 108.4 8_665 . ? 
C77 C78 H78C 108.4 . . ? 
C79 C78 H78C 108.4 8_665 . ? 
H78B C78 H78C 107.4 . . ? 
C80 C79 C78 113.6(12) . 8_665 ? 
C80 C79 H79B 108.9 . . ? 
C78 C79 H79B 108.9 8_665 . ? 
C80 C79 H79C 108.9 . . ? 
C78 C79 H79C 108.9 8_665 . ? 
H79B C79 H79C 107.7 . . ? 
N8 C80 C79 113.5(12) . . ? 
N8 C80 H80A 108.9 . . ? 
C79 C80 H80A 108.9 . . ? 
N8 C80 H80B 108.9 . . ? 
C79 C80 H80B 108.9 . . ? 
H80A C80 H80B 107.7 . . ? 
N8 C81 C82 128.7(17) . . ? 
N8 C81 H81A 115.7 . . ? 
C82 C81 H81A 115.7 . . ? 
C83 C82 C81 119.9(15) . . ? 
C83 C82 C87 113.8(14) . . ? 
C81 C82 C87 126.2(15) . . ? 
C82 C83 C84 129.3(16) . . ? 
C82 C83 H83A 115.4 . . ? 
C84 C83 H83A 115.3 . . ? 
C85 C84 C83 112.7(15) . . ? 
C85 C84 H84A 123.6 . . ? 
C83 C84 H84A 123.6 . . ? 
C86 C85 C84 122.0(16) . . ? 
C86 C85 H85A 119.0 . . ? 
C84 C85 H85A 119.0 . . ? 
C85 C86 C87 119.7(16) . . ? 
C85 C86 O16 125.8(15) . . ? 
C87 C86 O16 114.5(14) . . ? 
O15 C87 C86 117.2(14) . . ? 
O15 C87 C82 121.7(14) . . ? 
C86 C87 C82 121.1(15) . . ? 
O15 C87 Eu4 37.9(6) . . ? 
C86 C87 Eu4 83.8(10) . . ? 
C82 C87 Eu4 148.4(11) . . ? 
O16 C88 H88A 109.5 . . ? 
O16 C88 H88B 109.5 . . ? 
H88A C88 H88B 109.5 . . ? 
O16 C88 H88C 109.5 . . ? 
H88A C88 H88C 109.5 . . ? 
H88B C88 H88C 109.5 . . ? 
O17 C89 H89A 109.5 . . ? 
O17 C89 H89B 109.5 . . ? 
H89A C89 H89B 109.5 . . ? 
O17 C89 H89C 109.5 . . ? 
H89A C89 H89C 109.5 . . ? 
H89B C89 H89C 109.5 . . ? 
O17 C90 C95 117.0(15) . . ? 
O17 C90 C91 122.6(16) . . ? 
C95 C90 C91 120.3(16) . . ? 
C92 C91 C90 123.1(18) . . ? 
C92 C91 H91A 118.5 . . ? 
C90 C91 H91A 118.5 . . ? 
C91 C92 C93 114(2) . . ? 
C91 C92 H92A 122.9 . . ? 
C93 C92 H92A 122.9 . . ? 
C94 C93 C92 125(2) . . ? 
C94 C93 H93A 117.3 . . ? 
C92 C93 H93A 117.3 . . ? 
C93 C94 C96 121.6(17) . . ? 
C93 C94 C95 117.5(18) . . ? 
C96 C94 C95 119.8(14) . . ? 
O18 C95 C90 120.2(15) . . ? 
O18 C95 C94 120.8(15) . . ? 
C90 C95 C94 118.5(15) . . ? 
N9 C96 C94 130.5(15) . . ? 
N9 C96 H96A 114.7 . . ? 
C94 C96 H96A 114.7 . . ? 
N9 C97 C98 110.4(14) . . ? 
N9 C97 H97A 109.6 . . ? 
C98 C97 H97A 109.6 . . ? 
N9 C97 H97B 109.6 . . ? 
C98 C97 H97B 109.6 . . ? 
H97A C97 H97B 108.1 . . ? 
C99 C98 C97 116.1(16) . . ? 
C99 C98 H98A 108.3 . . ? 
C97 C98 H98A 108.3 . . ? 
C99 C98 H98B 108.3 . . ? 
C97 C98 H98B 108.3 . . ? 
H98A C98 H98B 107.4 . . ? 
C98 C99 C100 110.3(14) . . ? 
C98 C99 H99A 109.6 . . ? 
C100 C99 H99A 109.6 . . ? 
C98 C99 H99B 109.6 . . ? 
C100 C99 H99B 109.6 . . ? 
H99A C99 H99B 108.1 . . ? 
C101 C100 C99 108.4(14) . . ? 
C101 C100 H10C 110.0 . . ? 
C99 C100 H10C 110.0 . . ? 
C101 C100 H10D 110.0 . . ? 
C99 C100 H10D 110.0 . . ? 
H10C C100 H10D 108.4 . . ? 
C102 C101 C100 110.3(15) 8_665 . ? 
C102 C101 H10F 109.6 8_665 . ? 
C100 C101 H10F 109.6 . . ? 
C102 C101 H10G 109.6 8_665 . ? 
C100 C101 H10G 109.6 . . ? 
H10F C101 H10G 108.1 . . ? 
N10 C102 C101 107.3(13) . 8_665 ? 
N10 C102 H10I 110.3 . . ? 
C101 C102 H10I 110.3 8_665 . ? 
N10 C102 H10J 110.3 . . ? 
C101 C102 H10J 110.3 8_665 . ? 
H10I C102 H10J 108.5 . . ? 
N10 C103 C104 125.5(16) . . ? 
N10 C103 H10K 117.2 . . ? 
C104 C103 H10K 117.2 . . ? 
C109 C104 C105 114.8(16) . . ? 
C109 C104 C103 126.2(16) . . ? 
C105 C104 C103 118.1(16) . . ? 
C104 C105 C106 126.1(16) . . ? 
C104 C105 H10L 117.0 . . ? 
C106 C105 H10L 117.0 . . ? 
C107 C106 C105 120.3(18) . . ? 
C107 C106 H10M 119.9 . . ? 
C105 C106 H10M 119.9 . . ? 
C106 C107 C108 114.5(18) . . ? 
C106 C107 H10N 122.7 . . ? 
C108 C107 H10N 122.7 . . ? 
C107 C108 O20 123.5(15) . . ? 
C107 C108 C109 123.2(16) . . ? 
O20 C108 C109 112.4(14) . . ? 
C104 C109 O19 123.5(16) . . ? 
C104 C109 C108 119.4(16) . . ? 
O19 C109 C108 117.1(14) . . ? 
O20 C110 H11C 109.5 . . ? 
O20 C110 H11D 109.5 . . ? 
H11C C110 H11D 109.5 . . ? 
O20 C110 H110 109.5 . . ? 
H11C C110 H110 109.5 . . ? 
H11D C110 H110 109.5 . . ? 
O21 C111 H11F 109.5 . . ? 
O21 C111 H11G 109.5 . . ? 
H11F C111 H11G 109.5 . . ? 
O21 C111 H11H 109.5 . . ? 
H11F C111 H11H 109.5 . . ? 
H11G C111 H11H 109.5 . . ? 
O21 C112 C113 121.2(17) . . ? 
O21 C112 C117 115.5(15) . . ? 
C113 C112 C117 123.2(18) . . ? 
C112 C113 C114 115.5(17) . . ? 
C112 C113 H11I 122.2 . . ? 
C114 C113 H11I 122.2 . . ? 
C115 C114 C113 126.9(17) . . ? 
C115 C114 H11J 116.5 . . ? 
C113 C114 H11J 116.5 . . ? 
C114 C115 C116 115.4(17) . . ? 
C114 C115 H11K 122.3 . . ? 
C116 C115 H11K 122.3 . . ? 
C117 C116 C118 125.6(14) . . ? 
C117 C116 C115 122.0(14) . . ? 
C118 C116 C115 112.3(15) . . ? 
O22 C117 C116 122.8(13) . . ? 
O22 C117 C112 120.4(15) . . ? 
C116 C117 C112 116.6(14) . . ? 
N11 C118 C116 131.4(15) . . ? 
N11 C118 H11M 114.3 . . ? 
C116 C118 H11M 114.3 . . ? 
N11 C119 C120 110.5(15) . . ? 
N11 C119 H11N 109.5 . . ? 
C120 C119 H11N 109.5 . . ? 
N11 C119 H11O 109.6 . . ? 
C120 C119 H11O 109.6 . . ? 
H11N C119 H11O 108.1 . . ? 
C119 C120 C121 114.1(16) . 8_665 ? 
C119 C120 H12E 108.7 . . ? 
C121 C120 H12E 108.7 8_665 . ? 
C119 C120 H12F 108.7 . . ? 
C121 C120 H12F 108.7 8_665 . ? 
H12E C120 H12F 107.6 . . ? 
C122 C121 C120 109.3(14) . 8_665 ? 
C122 C121 H12H 109.8 . . ? 
C120 C121 H12H 109.8 8_665 . ? 
C122 C121 H12I 109.8 . . ? 
C120 C121 H12I 109.8 8_665 . ? 
H12H C121 H12I 108.3 . . ? 
C123 C122 C121 115.8(13) . . ? 
C123 C122 H12J 108.3 . . ? 
C121 C122 H12J 108.3 . . ? 
C123 C122 H12K 108.3 . . ? 
C121 C122 H12K 108.3 . . ? 
H12J C122 H12K 107.4 . . ? 
C122 C123 C124 112.4(12) . . ? 
C122 C123 H12L 109.1 . . ? 
C124 C123 H12L 109.1 . . ? 
C122 C123 H12M 109.1 . . ? 
C124 C123 H12M 109.1 . . ? 
H12L C123 H12M 107.9 . . ? 
C123 C124 N12 109.3(13) . . ? 
C123 C124 H12N 109.8 . . ? 
N12 C124 H12N 109.8 . . ? 
C123 C124 H12O 109.8 . . ? 
N12 C124 H12O 109.8 . . ? 
H12N C124 H12O 108.3 . . ? 
N12 C125 C126 126.1(15) . . ? 
N12 C125 H12P 116.9 . . ? 
C126 C125 H12P 116.9 . . ? 
C131 C126 C127 124.5(13) . . ? 
C131 C126 C125 123.0(13) . . ? 
C127 C126 C125 112.0(15) . . ? 
C126 C127 C128 116.2(16) . . ? 
C126 C127 H12Q 121.9 . . ? 
C128 C127 H12Q 121.9 . . ? 
C127 C128 C129 117.6(17) . . ? 
C127 C128 H12R 121.2 . . ? 
C129 C128 H12R 121.2 . . ? 
C130 C129 C128 118.9(16) . . ? 
C130 C129 H12S 120.5 . . ? 
C128 C129 H12S 120.5 . . ? 
O24 C130 C129 120.3(16) . . ? 
O24 C130 C131 114.7(16) . . ? 
C129 C130 C131 125.0(18) . . ? 
C130 C131 O23 118.3(14) . . ? 
C130 C131 C126 117.4(14) . . ? 
O23 C131 C126 123.3(12) . . ? 
C130 C131 Eu3 83.1(11) . . ? 
O23 C131 Eu3 37.8(6) . . ? 
C126 C131 Eu3 148.3(10) . . ? 
O24 C132 H13D 109.5 . . ? 
O24 C132 H13E 109.5 . . ? 
H13D C132 H13E 109.5 . . ? 
O24 C132 H13F 109.5 . . ? 
H13D C132 H13F 109.5 . . ? 
H13E C132 H13F 109.5 . . ? 
O67 C133 O68 128.2(16) . . ? 
O67 C133 C134 116.6(14) . . ? 
O68 C133 C134 115.2(15) . . ? 
C135 C134 C139 115.2(14) . . ? 
C135 C134 C133 121.4(14) . . ? 
C139 C134 C133 121.3(14) . . ? 
C136 C135 C134 124.8(17) . . ? 
C136 C135 H13G 117.6 . . ? 
C134 C135 H13G 117.6 . . ? 
C135 C136 C145 117.0(16) . 8_665 ? 
C135 C136 H13J 121.5 . . ? 
C145 C136 H13J 121.5 8_665 . ? 
C144 C137 C146 120.2(14) 8_665 8_665 ? 
C144 C137 C140 122.0(13) 8_665 . ? 
C146 C137 C140 117.0(13) 8_665 . ? 
C139 C138 C145 115.2(16) . 8_665 ? 
C139 C138 H13A 122.4 . . ? 
C145 C138 H13A 122.4 8_665 . ? 
C138 C139 C134 125.6(16) . . ? 
C138 C139 H13Q 117.2 . . ? 
C134 C139 H13Q 117.2 . . ? 
O25 C140 O26 125.5(12) . . ? 
O25 C140 C137 116.6(13) . . ? 
O26 C140 C137 116.6(13) . . ? 
O70 C141 O69 125.2(13) . . ? 
O70 C141 C142 120.2(12) . . ? 
O69 C141 C142 114.4(12) . . ? 
C143 C142 C147 120.4(15) . . ? 
C143 C142 C141 120.4(13) . . ? 
C147 C142 C141 119.2(13) . . ? 
C142 C143 C144 123.4(16) . . ? 
C142 C143 H14C 118.3 . . ? 
C144 C143 H14C 118.3 . . ? 
C137 C144 C143 116.0(15) 8_665 . ? 
C137 C144 H14D 122.0 8_665 . ? 
C143 C144 H14D 122.0 . . ? 
C138 C145 C136 120.6(14) 8_665 8_665 ? 
C138 C145 C148 121.5(14) 8_665 . ? 
C136 C145 C148 117.9(14) 8_665 . ? 
C147 C146 C137 116.2(15) . 8_665 ? 
C147 C146 H14G 121.9 . . ? 
C137 C146 H14G 121.9 8_665 . ? 
C142 C147 C146 122.0(16) . . ? 
C142 C147 H14M 119.0 . . ? 
C146 C147 H14M 119.0 . . ? 
O28 C148 O27 130.2(14) . . ? 
O28 C148 C145 115.7(14) . . ? 
O27 C148 C145 114.1(14) . . ? 
C150 C149 H14N 109.5 . . ? 
C150 C149 H14O 109.5 . . ? 
H14N C149 H14O 109.5 . . ? 
C150 C149 H14P 109.5 . . ? 
H14N C149 H14P 109.5 . . ? 
H14O C149 H14P 109.5 . . ? 
O30 C150 O29 124.1(15) . . ? 
O30 C150 C149 115.0(17) . . ? 
O29 C150 C149 120.9(16) . . ? 
C152 C151 H15B 109.5 . . ? 
C152 C151 H15C 109.5 . . ? 
H15B C151 H15C 109.5 . . ? 
C152 C151 H15D 109.5 . . ? 
H15B C151 H15D 109.5 . . ? 
H15C C151 H15D 109.5 . . ? 
O31 C152 O32 121.9(14) . . ? 
O31 C152 C151 124.8(16) . . ? 
O32 C152 C151 113.1(14) . . ? 
O31 C152 Cd2 62.2(8) . . ? 
O32 C152 Cd2 60.2(8) . . ? 
C151 C152 Cd2 172.8(13) . . ? 
C154 C153 H15E 109.5 . . ? 
C154 C153 H15F 109.5 . . ? 
H15E C153 H15F 109.5 . . ? 
C154 C153 H15G 109.5 . . ? 
H15E C153 H15G 109.5 . . ? 
H15F C153 H15G 109.5 . . ? 
O33 C154 O34 116.6(14) . . ? 
O33 C154 C153 125.1(15) . . ? 
O34 C154 C153 118.0(14) . . ? 
C156 C155 H15H 109.5 . . ? 
C156 C155 H15I 109.5 . . ? 
H15H C155 H15I 109.5 . . ? 
C156 C155 H15J 109.5 . . ? 
H15H C155 H15J 109.5 . . ? 
H15I C155 H15J 109.5 . . ? 
O36 C156 O35 122(2) . . ? 
O36 C156 C155 120(2) . . ? 
O35 C156 C155 118(2) . . ? 
C158 C157 H15K 109.5 . . ? 
C158 C157 H15L 109.5 . . ? 
H15K C157 H15L 109.5 . . ? 
C158 C157 H15M 109.5 . . ? 
H15K C157 H15M 109.5 . . ? 
H15L C157 H15M 109.5 . . ? 
O38 C158 O37 123.6(16) . . ? 
O38 C158 C157 120.5(17) . . ? 
O37 C158 C157 115.8(16) . . ? 
C160 C159 H15N 109.5 . . ? 
C160 C159 H15O 109.5 . . ? 
H15N C159 H15O 109.5 . . ? 
C160 C159 H15P 109.5 . . ? 
H15N C159 H15P 109.5 . . ? 
H15O C159 H15P 109.5 . . ? 
O39 C160 O40 124.8(17) . . ? 
O39 C160 C159 124.1(18) . . ? 
O40 C160 C159 110.9(16) . . ? 
C162 C161 H16A 109.5 . . ? 
C162 C161 H16B 109.5 . . ? 
H16A C161 H16B 109.5 . . ? 
C162 C161 H16C 109.5 . . ? 
H16A C161 H16C 109.5 . . ? 
H16B C161 H16C 109.5 . . ? 
O42 C162 O41 111.8(17) . . ? 
O42 C162 C161 132.1(19) . . ? 
O41 C162 C161 116.0(15) . . ? 
C164 C163 H16D 109.5 . . ? 
C164 C163 H16E 109.5 . . ? 
H16D C163 H16E 109.5 . . ? 
C164 C163 H16F 109.5 . . ? 
H16D C163 H16F 109.5 . . ? 
H16E C163 H16F 109.5 . . ? 
O44 C164 O43 118.8(11) . . ? 
O44 C164 C163 120.7(12) . . ? 
O43 C164 C163 120.5(12) . . ? 
C166 C165 H16G 109.5 . . ? 
C166 C165 H16H 109.5 . . ? 
H16G C165 H16H 109.5 . . ? 
C166 C165 H16I 109.5 . . ? 
H16G C165 H16I 109.5 . . ? 
H16H C165 H16I 109.5 . . ? 
O45 C166 O46 125.3(18) . . ? 
O45 C166 C165 119.0(16) . . ? 
O46 C166 C165 115.2(17) . . ? 
C168 C167 H16J 109.5 . . ? 
C168 C167 H16K 109.5 . . ? 
H16J C167 H16K 109.5 . . ? 
C168 C167 H16L 109.5 . . ? 
H16J C167 H16L 109.5 . . ? 
H16K C167 H16L 109.5 . . ? 
O48 C168 O47 122.2(19) . . ? 
O48 C168 C167 119.2(18) . . ? 
O47 C168 C167 117.8(18) . . ? 
C170 C169 H16M 109.5 . . ? 
C170 C169 H16N 109.5 . . ? 
H16M C169 H16N 109.5 . . ? 
C170 C169 H16O 109.5 . . ? 
H16M C169 H16O 109.5 . . ? 
H16N C169 H16O 109.5 . . ? 
O49 C170 O50 121.5(15) . . ? 
O49 C170 C169 119.6(14) . . ? 
O50 C170 C169 119.0(14) . . ? 
O49 C170 Cd8 62.8(8) . . ? 
O50 C170 Cd8 58.8(8) . . ? 
C169 C170 Cd8 176.6(13) . . ? 
C172 C171 H17B 109.5 . . ? 
C172 C171 H17C 109.5 . . ? 
H17B C171 H17C 109.5 . . ? 
C172 C171 H17D 109.5 . . ? 
H17B C171 H17D 109.5 . . ? 
H17C C171 H17D 109.5 . . ? 
O53 C172 O54 119.6(15) . . ? 
O53 C172 C171 119.8(16) . . ? 
O54 C172 C171 120.6(15) . . ? 
C174 C173 H17E 109.5 . . ? 
C174 C173 H17F 109.5 . . ? 
H17E C173 H17F 109.5 . . ? 
C174 C173 H17G 109.5 . . ? 
H17E C173 H17G 109.5 . . ? 
H17F C173 H17G 109.5 . . ? 
O51 C174 O52 121(2) . . ? 
O51 C174 C173 119(2) . . ? 
O52 C174 C173 119(2) . . ? 
O51 C174 Cd8 62.8(12) . . ? 
O52 C174 Cd8 58.7(11) . . ? 
C173 C174 Cd8 177.4(17) . . ? 
C176 C175 H17H 109.5 . . ? 
C176 C175 H17I 109.5 . . ? 
H17H C175 H17I 109.5 . . ? 
C176 C175 H17J 109.5 . . ? 
H17H C175 H17J 109.5 . . ? 
H17I C175 H17J 109.5 . . ? 
O57 C176 O58 122.6(16) . . ? 
O57 C176 C175 116.4(16) . . ? 
O58 C176 C175 119.5(16) . . ? 
C178 C177 H17K 109.5 . . ? 
C178 C177 H17L 109.5 . . ? 
H17K C177 H17L 109.5 . . ? 
C178 C177 H17M 109.5 . . ? 
H17K C177 H17M 109.5 . . ? 
H17L C177 H17M 109.5 . . ? 
O63 C178 O64 117.5(13) . . ? 
O63 C178 C177 119.8(14) . . ? 
O64 C178 C177 122.2(15) . . ? 
O63 C178 Cd11 56.4(7) . . ? 
O64 C178 Cd11 61.1(8) . . ? 
C177 C178 Cd11 172.8(12) . . ? 
C180 C179 H17N 109.5 . . ? 
C180 C179 H17O 109.5 . . ? 
H17N C179 H17O 109.5 . . ? 
C180 C179 H17P 109.5 . . ? 
H17N C179 H17P 109.5 . . ? 
H17O C179 H17P 109.5 . . ? 
O60 C180 O59 123.2(13) . . ? 
O60 C180 C179 117.9(13) . . ? 
O59 C180 C179 118.9(13) . . ? 
C182 C181 H18B 109.5 . . ? 
C182 C181 H18C 109.5 . . ? 
H18B C181 H18C 109.5 . . ? 
C182 C181 H18D 109.5 . . ? 
H18B C181 H18D 109.5 . . ? 
H18C C181 H18D 109.5 . . ? 
O66 C182 O65 122.3(14) . . ? 
O66 C182 C181 116.5(15) . . ? 
O65 C182 C181 119.6(15) . . ? 
O66 C182 Cd11 65.9(8) . . ? 
O65 C182 Cd11 56.6(8) . . ? 
C181 C182 Cd11 171.3(11) . . ? 
C184 C183 H18E 109.5 . . ? 
C184 C183 H18F 109.5 . . ? 
H18E C183 H18F 109.5 . . ? 
C184 C183 H18G 109.5 . . ? 
H18E C183 H18G 109.5 . . ? 
H18F C183 H18G 109.5 . . ? 
O61 C184 O62 123.5(14) . . ? 
O61 C184 C183 116.4(15) . . ? 
O62 C184 C183 119.7(14) . . ? 
C186 C185 H18H 109.5 . . ? 
C186 C185 H18I 109.5 . . ? 
H18H C185 H18I 109.5 . . ? 
C186 C185 H18J 109.5 . . ? 
H18H C185 H18J 109.5 . . ? 
H18I C185 H18J 109.5 . . ? 
O55 C186 O56 125.6(17) . . ? 
O55 C186 C185 115(2) . . ? 
O56 C186 C185 118.9(17) . . ? 
 
_diffrn_measured_fraction_theta_max    0.966 
_diffrn_reflns_theta_full              25.00 
_diffrn_measured_fraction_theta_full   0.966 
_refine_diff_density_max    6.798 
_refine_diff_density_min   -2.008 
_refine_diff_density_rms    0.212 

# SQUEEZE RESULTS (APPEND TO CIF)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
  _platon_squeeze_void_nr
  _platon_squeeze_void_average_x
  _platon_squeeze_void_average_y
  _platon_squeeze_void_average_z
  _platon_squeeze_void_volume
  _platon_squeeze_void_count_electrons
  _platon_squeeze_void_content
   1 -0.006  0.001  0.000     30962      6578 ' '
   2  0.224  0.724  0.750       568       117 ' '
   3  0.275  0.224  0.250       568       117 ' '
   4  0.724  0.776  0.250       568       117 ' '
   5  0.775  0.276  0.750       568       117 ' '
_platon_squeeze_details
;
;
