# Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_X-ray5
_audit_block_doi                 10.5517/ccxdb1n
_database_code_depnum_ccdc_archive 'CCDC 845991'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1039/C2CC31753B 2012
_audit_update_record             
;
2011-09-24 deposited with the CCDC.
2016-08-01 downloaded from the CCDC.
;
#TrackingRef 'web_deposit_cif_file_1_AkioKamimura_1316880209.FN03016CIF.cif'

_audit_creation_date             2010-11-29
_audit_creation_method           'by CrystalStructure 4.0'


#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C33 H48 Cl N O4 S Sn'
_chemical_formula_moiety         'C33 H48 Cl N O4 S Sn'
_chemical_formula_weight         708.95
_chemical_melting_point          ?
_chemical_absolute_configuration ?

#==============================================================================
# CRYSTAL DATA
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_Int_Tables_number      19
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 1/2+X,1/2-Y,-Z
3 -X,1/2+Y,1/2-Z
4 1/2-X,-Y,1/2+Z
#------------------------------------------------------------------------------
_cell_length_a                   9.4030(3)
_cell_length_b                   10.4777(4)
_cell_length_c                   36.3472(12)
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_volume                     3581.0(2)
_cell_formula_units_Z            5
_cell_measurement_reflns_used    27729
_cell_measurement_theta_min      3.12
_cell_measurement_theta_max      27.41
_cell_measurement_temperature    296
#------------------------------------------------------------------------------
_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_exptl_crystal_density_diffrn    1.644
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1840.00
_exptl_absorpt_coefficient_mu    1.100
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_absorpt_correction_T_min  0.446
_exptl_absorpt_correction_T_max  0.803

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      296
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.000
_diffrn_reflns_number            35003
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_theta_max         27.42
_diffrn_reflns_theta_full        27.42
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -46
_diffrn_reflns_limit_l_max       46
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
Refinement was performed using all reflections. The weighted
R-factor (wR) and goodness of fit (S) are based on F².
R-factor (gt) are based on F. The threshold expression of
F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_reflns_number_total             8139
_reflns_number_gt                6512
_reflns_threshold_expression     F²>2.0σ(F²)
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_gt           0.0308
_refine_ls_wR_factor_ref         0.0812
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_reflns         8139
_refine_ls_number_parameters     378
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0441P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.000
_refine_diff_density_max         0.550
_refine_diff_density_min         -0.420
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0007(3)
_refine_ls_abs_structure_details 
'Flack, H. D. (1983), Acta Cryst. A39, 876-881. 3550 Friedel Pairs'
_refine_ls_abs_structure_Flack   -0.023(19)

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.000 0.000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
N N 0.006 0.003
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.011 0.006
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
S S 0.125 0.123
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Sn Sn -0.654 1.425
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cl Cl 0.148 0.159
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn(1) Sn 0.27359(2) 0.04793(2) 0.105418(6) 0.05534(8) Uani 1.0 4 d . . .
Cl(1) Cl 0.39356(13) 0.18381(10) 0.14892(3) 0.0875(3) Uani 1.0 4 d . . .
S(1) S 0.01881(10) -0.45886(11) 0.17158(2) 0.0697(3) Uani 1.0 4 d . . .
O(1) O 0.1351(3) -0.3480(3) 0.07106(6) 0.0697(7) Uani 1.0 4 d . . .
O(2) O -0.0856(3) -0.3608(4) 0.17602(8) 0.0875(8) Uani 1.0 4 d . . .
O(3) O -0.0169(4) -0.5753(3) 0.15327(8) 0.0928(9) Uani 1.0 4 d . . .
O(4) O 0.1645(3) -0.1365(3) 0.06607(7) 0.0746(7) Uani 1.0 4 d . . .
N(2) N 0.1478(4) -0.3965(3) 0.14858(7) 0.0609(7) Uani 1.0 4 d . . .
C(1) C 0.1829(4) -0.2583(3) 0.14927(8) 0.0510(7) Uani 1.0 4 d . . .
C(2) C 0.2862(4) -0.2475(3) 0.11536(8) 0.0538(7) Uani 1.0 4 d . . .
C(3) C 0.2116(4) -0.5591(5) 0.28245(10) 0.0786(11) Uani 1.0 4 d . . .
C(4) C 0.2645(5) -0.4733(3) 0.13307(9) 0.0682(9) Uani 1.0 4 d . . .
C(7) C 0.1494(5) -0.4415(5) 0.27665(10) 0.0800(12) Uani 1.0 4 d . . .
C(8) C 0.2464(3) -0.2123(3) 0.18513(7) 0.0505(7) Uani 1.0 4 d . . .
C(9) C 0.3548(4) -0.2770(4) 0.20322(9) 0.0635(9) Uani 1.0 4 d . . .
C(10) C 0.3513(4) -0.1278(4) 0.25376(9) 0.0626(8) Uani 1.0 4 d . . .
C(11) C 0.4040(4) -0.2368(4) 0.23684(9) 0.0655(9) Uani 1.0 4 d . . .
C(12) C 0.0858(4) -0.4998(4) 0.21520(9) 0.0626(9) Uani 1.0 4 d . . .
C(13) C 0.1482(5) -0.6187(4) 0.22034(10) 0.0697(10) Uani 1.0 4 d . . .
C(14) C 0.3809(4) -0.1295(4) 0.11664(9) 0.0564(8) Uani 1.0 4 d . . .
C(15) C 0.1902(4) -0.2375(4) 0.08108(8) 0.0572(8) Uani 1.0 4 d . . .
C(16) C 0.4965(5) -0.3961(5) 0.10907(12) 0.0921(13) Uani 1.0 4 d . . .
C(17) C 0.3617(4) -0.3767(4) 0.11703(9) 0.0639(9) Uani 1.0 4 d . . .
C(18) C 0.4038(6) -0.0845(5) 0.29101(11) 0.0931(14) Uani 1.0 4 d . . .
C(19) C 0.2102(5) -0.6472(5) 0.25414(10) 0.0793(10) Uani 1.0 4 d . . .
C(20) C 0.0854(5) -0.4117(4) 0.24335(10) 0.0736(10) Uani 1.0 4 d . . .
C(21) C -0.0180(9) -0.4986(5) 0.04625(17) 0.138(3) Uani 1.0 4 d . . .
C(22) C 0.3409(5) 0.1287(4) 0.05416(10) 0.0749(10) Uani 1.0 4 d . . .
C(23) C 0.0118(6) -0.3573(5) 0.04512(11) 0.0810(12) Uani 1.0 4 d . . .
C(24) C 0.3704(7) 0.2673(5) 0.05296(12) 0.0974(15) Uani 1.0 4 d . . .
C(25) C 0.0553(4) 0.0821(4) 0.11992(11) 0.0736(10) Uani 1.0 4 d . . .
C(26) C 0.2820(6) -0.5919(6) 0.31831(12) 0.1109(17) Uani 1.0 4 d . . .
C(27) C 0.4298(8) 0.3160(5) 0.01683(13) 0.1141(19) Uani 1.0 4 d . . .
C(28) C 0.0536(8) -0.3161(6) 0.00734(12) 0.115(2) Uani 1.0 4 d . . .
C(29) C -0.1794(5) 0.1827(6) 0.1027(2) 0.126(2) Uani 1.0 4 d . . .
C(30) C -0.0214(5) 0.1639(6) 0.09400(14) 0.1002(15) Uani 1.0 4 d . . .
C(32) C -0.1106(6) -0.2777(7) 0.06151(17) 0.121(2) Uani 1.0 4 d . . .
C(34) C 0.4673(11) 0.4530(7) 0.01619(18) 0.176(4) Uani 1.0 4 d . . .
C(35) C 0.1928(4) -0.1038(4) 0.20201(9) 0.0595(8) Uani 1.0 4 d . . .
C(36) C -0.2606(8) 0.0832(12) 0.0857(3) 0.216(5) Uani 1.0 4 d . . .
C(38) C 0.2450(4) -0.0629(4) 0.23560(9) 0.0676(9) Uani 1.0 4 d . . .
H(1) H 0.0965 -0.2092 0.1441 0.0612 Uiso 1.0 4 calc R . .
H(4A) H 0.2296 -0.5312 0.1143 0.0819 Uiso 1.0 4 calc R . .
H(4B) H 0.3119 -0.5223 0.1521 0.0819 Uiso 1.0 4 calc R . .
H(7) H 0.1505 -0.3811 0.2954 0.0960 Uiso 1.0 4 calc R . .
H(9) H 0.3948 -0.3489 0.1923 0.0762 Uiso 1.0 4 calc R . .
H(11) H 0.4744 -0.2838 0.2486 0.0786 Uiso 1.0 4 calc R . .
H(13) H 0.1485 -0.6785 0.2014 0.0836 Uiso 1.0 4 calc R . .
H(14A) H 0.4570 -0.1401 0.0989 0.0677 Uiso 1.0 4 calc R . .
H(14B) H 0.4240 -0.1242 0.1408 0.0677 Uiso 1.0 4 calc R . .
H(16A) H 0.5376 -0.4754 0.1135 0.1105 Uiso 1.0 4 calc R . .
H(16B) H 0.5507 -0.3306 0.0990 0.1105 Uiso 1.0 4 calc R . .
H(18A) H 0.5053 -0.0753 0.2904 0.1117 Uiso 1.0 4 calc R . .
H(18B) H 0.3783 -0.1468 0.3092 0.1117 Uiso 1.0 4 calc R . .
H(18C) H 0.3610 -0.0040 0.2971 0.1117 Uiso 1.0 4 calc R . .
H(19) H 0.2514 -0.7269 0.2577 0.0951 Uiso 1.0 4 calc R . .
H(20) H 0.0423 -0.3326 0.2400 0.0883 Uiso 1.0 4 calc R . .
H(21A) H -0.0378 -0.5239 0.0711 0.1654 Uiso 1.0 4 calc R . .
H(21B) H 0.0635 -0.5444 0.0374 0.1654 Uiso 1.0 4 calc R . .
H(21C) H -0.0987 -0.5175 0.0310 0.1654 Uiso 1.0 4 calc R . .
H(22A) H 0.4265 0.0844 0.0465 0.0898 Uiso 1.0 4 calc R . .
H(22B) H 0.2682 0.1105 0.0360 0.0898 Uiso 1.0 4 calc R . .
H(24A) H 0.4375 0.2878 0.0724 0.1169 Uiso 1.0 4 calc R . .
H(24B) H 0.2829 0.3128 0.0582 0.1169 Uiso 1.0 4 calc R . .
H(25A) H 0.0065 0.0008 0.1216 0.0883 Uiso 1.0 4 calc R . .
H(25B) H 0.0523 0.1213 0.1441 0.0883 Uiso 1.0 4 calc R . .
H(26A) H 0.2130 -0.5889 0.3378 0.1331 Uiso 1.0 4 calc R . .
H(26B) H 0.3565 -0.5316 0.3232 0.1331 Uiso 1.0 4 calc R . .
H(26C) H 0.3216 -0.6762 0.3168 0.1331 Uiso 1.0 4 calc R . .
H(27A) H 0.5141 0.2669 0.0109 0.1370 Uiso 1.0 4 calc R . .
H(27B) H 0.3602 0.3002 -0.0023 0.1370 Uiso 1.0 4 calc R . .
H(28A) H 0.1359 -0.3633 -0.0004 0.1383 Uiso 1.0 4 calc R . .
H(28B) H 0.0753 -0.2266 0.0075 0.1383 Uiso 1.0 4 calc R . .
H(28C) H -0.0234 -0.3320 -0.0094 0.1383 Uiso 1.0 4 calc R . .
H(29A) H -0.1938 0.1807 0.1292 0.1509 Uiso 1.0 4 calc R . .
H(29B) H -0.2107 0.2651 0.0937 0.1509 Uiso 1.0 4 calc R . .
H(30A) H -0.0132 0.1273 0.0696 0.1202 Uiso 1.0 4 calc R . .
H(30B) H 0.0243 0.2469 0.0935 0.1202 Uiso 1.0 4 calc R . .
H(32A) H -0.0890 -0.1885 0.0591 0.1448 Uiso 1.0 4 calc R . .
H(32B) H -0.1219 -0.2985 0.0871 0.1448 Uiso 1.0 4 calc R . .
H(32C) H -0.1972 -0.2964 0.0486 0.1448 Uiso 1.0 4 calc R . .
H(34A) H 0.5530 0.4663 0.0301 0.2114 Uiso 1.0 4 calc R . .
H(34B) H 0.3914 0.5018 0.0269 0.2114 Uiso 1.0 4 calc R . .
H(34C) H 0.4819 0.4798 -0.0088 0.2114 Uiso 1.0 4 calc R . .
H(35) H 0.1206 -0.0578 0.1906 0.0714 Uiso 1.0 4 calc R . .
H(36A) H -0.2067 0.0054 0.0858 0.2595 Uiso 1.0 4 calc R . .
H(36B) H -0.2819 0.1067 0.0608 0.2595 Uiso 1.0 4 calc R . .
H(36C) H -0.3476 0.0709 0.0990 0.2595 Uiso 1.0 4 calc R . .
H(38) H 0.2072 0.0104 0.2462 0.0811 Uiso 1.0 4 calc R . .



#==============================================================================
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    'SIR2004 (Burla, et al., 2005)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_molecular_graphics    'CrystalStructure 4.0'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
;
ENTER SPECIAL DETAILS OF THE MOLECULAR GEOMETRY
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
Sn(1) Cl(1) 2.4082(12) yes . .
Sn(1) C(14) 2.154(4) yes . .
Sn(1) C(22) 2.142(4) yes . .
Sn(1) C(25) 2.149(4) yes . .
S(1) O(2) 1.431(4) yes . .
S(1) O(3) 1.429(4) yes . .
S(1) N(2) 1.612(3) yes . .
S(1) C(12) 1.759(4) yes . .
O(1) C(15) 1.320(5) yes . .
O(1) C(23) 1.498(6) yes . .
O(4) C(15) 1.214(5) yes . .
N(2) C(1) 1.485(4) yes . .
N(2) C(4) 1.472(5) yes . .
C(1) C(2) 1.573(5) yes . .
C(1) C(8) 1.513(4) yes . .
C(2) C(14) 1.524(5) yes . .
C(2) C(15) 1.542(5) yes . .
C(2) C(17) 1.529(5) yes . .
C(3) C(7) 1.380(7) yes . .
C(3) C(19) 1.383(6) yes . .
C(3) C(26) 1.502(6) yes . .
C(4) C(17) 1.483(5) yes . .
C(7) C(20) 1.388(6) yes . .
C(8) C(9) 1.390(5) yes . .
C(8) C(35) 1.387(5) yes . .
C(9) C(11) 1.373(5) yes . .
C(10) C(11) 1.389(6) yes . .
C(10) C(18) 1.510(6) yes . .
C(10) C(38) 1.377(5) yes . .
C(12) C(13) 1.390(6) yes . .
C(12) C(20) 1.378(6) yes . .
C(13) C(19) 1.392(6) yes . .
C(16) C(17) 1.317(6) yes . .
C(21) C(23) 1.507(7) yes . .
C(22) C(24) 1.479(7) yes . .
C(23) C(28) 1.492(7) yes . .
C(23) C(32) 1.541(8) yes . .
C(24) C(27) 1.515(7) yes . .
C(25) C(30) 1.464(7) yes . .
C(27) C(34) 1.478(9) yes . .
C(29) C(30) 1.532(7) yes . .
C(29) C(36) 1.433(13) yes . .
C(35) C(38) 1.384(5) yes . .

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
Cl(1) Sn(1) C(14) 99.59(9) yes . . .
Cl(1) Sn(1) C(22) 101.47(12) yes . . .
Cl(1) Sn(1) C(25) 100.82(12) yes . . .
C(14) Sn(1) C(22) 111.55(15) yes . . .
C(14) Sn(1) C(25) 122.99(15) yes . . .
C(22) Sn(1) C(25) 115.45(17) yes . . .
O(2) S(1) O(3) 120.30(19) yes . . .
O(2) S(1) N(2) 106.50(17) yes . . .
O(2) S(1) C(12) 108.62(18) yes . . .
O(3) S(1) N(2) 106.32(17) yes . . .
O(3) S(1) C(12) 107.21(18) yes . . .
N(2) S(1) C(12) 107.25(16) yes . . .
C(15) O(1) C(23) 122.3(3) yes . . .
S(1) N(2) C(1) 123.6(3) yes . . .
S(1) N(2) C(4) 122.5(3) yes . . .
C(1) N(2) C(4) 111.9(3) yes . . .
N(2) C(1) C(2) 101.2(3) yes . . .
N(2) C(1) C(8) 114.4(3) yes . . .
C(2) C(1) C(8) 114.1(3) yes . . .
C(1) C(2) C(14) 113.3(3) yes . . .
C(1) C(2) C(15) 106.1(3) yes . . .
C(1) C(2) C(17) 101.1(3) yes . . .
C(14) C(2) C(15) 108.1(3) yes . . .
C(14) C(2) C(17) 116.4(3) yes . . .
C(15) C(2) C(17) 111.4(3) yes . . .
C(7) C(3) C(19) 118.6(4) yes . . .
C(7) C(3) C(26) 121.6(4) yes . . .
C(19) C(3) C(26) 119.8(5) yes . . .
N(2) C(4) C(17) 103.7(3) yes . . .
C(3) C(7) C(20) 121.2(4) yes . . .
C(1) C(8) C(9) 122.8(3) yes . . .
C(1) C(8) C(35) 120.0(3) yes . . .
C(9) C(8) C(35) 117.2(3) yes . . .
C(8) C(9) C(11) 121.2(4) yes . . .
C(11) C(10) C(18) 121.8(4) yes . . .
C(11) C(10) C(38) 116.9(3) yes . . .
C(18) C(10) C(38) 121.2(4) yes . . .
C(9) C(11) C(10) 121.8(4) yes . . .
S(1) C(12) C(13) 119.4(3) yes . . .
S(1) C(12) C(20) 120.3(3) yes . . .
C(13) C(12) C(20) 120.1(4) yes . . .
C(12) C(13) C(19) 119.2(4) yes . . .
Sn(1) C(14) C(2) 114.9(2) yes . . .
O(1) C(15) O(4) 124.2(3) yes . . .
O(1) C(15) C(2) 113.1(3) yes . . .
O(4) C(15) C(2) 122.6(3) yes . . .
C(2) C(17) C(4) 109.5(3) yes . . .
C(2) C(17) C(16) 125.1(4) yes . . .
C(4) C(17) C(16) 125.0(4) yes . . .
C(3) C(19) C(13) 121.2(4) yes . . .
C(7) C(20) C(12) 119.7(4) yes . . .
Sn(1) C(22) C(24) 118.0(3) yes . . .
O(1) C(23) C(21) 101.0(4) yes . . .
O(1) C(23) C(28) 110.9(5) yes . . .
O(1) C(23) C(32) 107.4(4) yes . . .
C(21) C(23) C(28) 111.0(4) yes . . .
C(21) C(23) C(32) 112.5(5) yes . . .
C(28) C(23) C(32) 113.3(5) yes . . .
C(22) C(24) C(27) 115.2(4) yes . . .
Sn(1) C(25) C(30) 114.2(3) yes . . .
C(24) C(27) C(34) 115.4(5) yes . . .
C(30) C(29) C(36) 109.5(6) yes . . .
C(25) C(30) C(29) 114.8(5) yes . . .
C(8) C(35) C(38) 121.0(3) yes . . .
C(10) C(38) C(35) 121.9(4) yes . . .
