# Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_20160454
_database_code_depnum_ccdc_archive 'CCDC 1497810'
_audit_update_record             
;
2016-08-05 deposited with the CCDC.
2016-11-25 downloaded from the CCDC.
;
_audit_creation_date             2016-04-19
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C15 H11 Cl F3 N3 O3'
_chemical_formula_sum            'C15 H11 Cl F3 N3 O3'
_chemical_formula_weight         373.72
_chemical_absolute_configuration ad
_chemical_melting_point          ?
_chemical_oxdiff_formula         C1H1O1N1Br1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'

_cell_length_a                   7.74798(19)
_cell_length_b                   9.1129(2)
_cell_length_c                   21.7190(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1533.51(6)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    3235
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      70.9270
_cell_measurement_theta_min      4.0490
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.744
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.91770
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.619
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             760
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.18
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0239
_diffrn_reflns_av_unetI/netI     0.0298
_diffrn_reflns_Laue_measured_fraction_full 1.001
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -4
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            5429
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        67.052
_diffrn_reflns_theta_max         67.052
_diffrn_reflns_theta_min         4.071
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.2312
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 1.001
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -49.00   37.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -33.5000   37.0000  -30.0000 86

#__ type_ start__ end____ width___ exp.time_
  2 omega  -52.00   35.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -33.5000   57.0000   60.0000 87

#__ type_ start__ end____ width___ exp.time_
  3 omega  -43.00   13.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -33.5000   37.0000 -150.0000 56

#__ type_ start__ end____ width___ exp.time_
  4 omega   57.00  102.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.4734  178.0000    0.0000 45

#__ type_ start__ end____ width___ exp.time_
  5 omega   80.00  106.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.4734  178.0000  -60.0000 26

#__ type_ start__ end____ width___ exp.time_
  6 omega  -22.00   44.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.4734  -57.0000  -30.0000 66

#__ type_ start__ end____ width___ exp.time_
  7 omega   -1.00   75.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.4734   19.0000   90.0000 76

#__ type_ start__ end____ width___ exp.time_
  8 omega   56.00   89.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -30.0000 -120.0000 33

#__ type_ start__ end____ width___ exp.time_
  9 omega   42.00   83.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -45.0000   90.0000 41

#__ type_ start__ end____ width___ exp.time_
 10 omega   73.00  101.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -61.0000  -90.0000 28

#__ type_ start__ end____ width___ exp.time_
 11 omega   42.00   85.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -30.0000 -150.0000 43

#__ type_ start__ end____ width___ exp.time_
 12 omega   42.00   75.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -30.0000  120.0000 33

#__ type_ start__ end____ width___ exp.time_
 13 omega   43.00   86.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -30.0000  -30.0000 43

#__ type_ start__ end____ width___ exp.time_
 14 omega   50.00  103.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -94.0000  -60.0000 53

#__ type_ start__ end____ width___ exp.time_
 15 omega   41.00   89.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -30.0000  150.0000 48

#__ type_ start__ end____ width___ exp.time_
 16 omega   41.00   76.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -45.0000 -150.0000 35

#__ type_ start__ end____ width___ exp.time_
 17 omega   39.00   99.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -45.0000   30.0000 60
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0178999000
_diffrn_orient_matrix_UB_12      -0.1005128000
_diffrn_orient_matrix_UB_13      0.0566338000
_diffrn_orient_matrix_UB_21      -0.0715574000
_diffrn_orient_matrix_UB_22      -0.1296463000
_diffrn_orient_matrix_UB_23      -0.0376121000
_diffrn_orient_matrix_UB_31      0.1848052000
_diffrn_orient_matrix_UB_32      -0.0406138000
_diffrn_orient_matrix_UB_33      -0.0201236000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Enhance (Cu) X-ray Source'
_reflns_Friedel_coverage         0.710
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                2590
_reflns_number_total             2741
_reflns_odcompleteness_completeness 99.94
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.178
_refine_diff_density_min         -0.297
_refine_diff_density_rms         0.065
_refine_ls_abs_structure_details 
;
 Flack x determined using 1010 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.003(10)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         2741
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0390
_refine_ls_R_factor_gt           0.0367
_refine_ls_restrained_S_all      1.069
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0554P)²+0.0371P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0913
_refine_ls_wR_factor_ref         0.0940
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C8(H8A,H8B), C14(H14A,H14B)
2.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C4(H4), C5(H5), C11(H11), C12(H12), C13(H13)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5268(4) 0.5953(3) 0.62805(13) 0.0393(6) Uani 1 1 d . . . . .
H1 H 0.6122 0.5961 0.6581 0.047 Uiso 1 1 calc R . . . .
C2 C 0.4703(4) 0.7273(3) 0.60344(15) 0.0432(7) Uani 1 1 d . . . . .
H2 H 0.5165 0.8157 0.6170 0.052 Uiso 1 1 calc R . . . .
C3 C 0.3451(4) 0.7253(3) 0.55878(13) 0.0411(6) Uani 1 1 d . . . . .
C4 C 0.2706(4) 0.5965(4) 0.54010(14) 0.0495(7) Uani 1 1 d . . . . .
H4 H 0.1825 0.5969 0.5110 0.059 Uiso 1 1 calc R . . . .
C5 C 0.3280(4) 0.4663(4) 0.56506(15) 0.0460(7) Uani 1 1 d . . . . .
H5 H 0.2781 0.3786 0.5523 0.055 Uiso 1 1 calc R . . . .
C6 C 0.4592(3) 0.4626(3) 0.60900(12) 0.0329(5) Uani 1 1 d . . . . .
C7 C 0.5315(4) 0.3142(3) 0.63237(12) 0.0352(6) Uani 1 1 d . . . . .
C8 C 0.6395(4) 0.3377(3) 0.69148(13) 0.0383(6) Uani 1 1 d . . . . .
H8A H 0.7406 0.3944 0.6801 0.046 Uiso 1 1 calc R . . . .
H8B H 0.5717 0.3981 0.7192 0.046 Uiso 1 1 calc R . . . .
C9 C 0.7012(4) 0.2057(3) 0.72767(14) 0.0425(6) Uani 1 1 d . . . . .
C10 C 0.8308(4) 0.2377(3) 0.77733(13) 0.0383(6) Uani 1 1 d . . . . .
C11 C 0.9244(4) 0.1222(4) 0.80231(14) 0.0449(7) Uani 1 1 d . . . . .
H11 H 0.9049 0.0277 0.7878 0.054 Uiso 1 1 calc R . . . .
C12 C 1.0601(4) 0.2796(4) 0.86528(16) 0.0539(8) Uani 1 1 d . . . . .
H12 H 1.1384 0.2991 0.8967 0.065 Uiso 1 1 calc R . . . .
C13 C 0.9683(4) 0.3940(4) 0.84029(15) 0.0492(7) Uani 1 1 d . . . . .
H13 H 0.9887 0.4882 0.8550 0.059 Uiso 1 1 calc R . . . .
C14 C 0.3871(4) 0.1978(3) 0.63930(14) 0.0410(6) Uani 1 1 d . . . . .
H14A H 0.3359 0.1791 0.5993 0.049 Uiso 1 1 calc R . . . .
H14B H 0.4372 0.1068 0.6540 0.049 Uiso 1 1 calc R . . . .
C15 C 0.6514(4) 0.2557(4) 0.58154(15) 0.0484(7) Uani 1 1 d . . . . .
Cl1 Cl 0.28061(12) 0.89001(9) 0.52471(4) 0.0591(2) Uani 1 1 d . . . . .
F1 F 0.7199(3) 0.1253(2) 0.59512(11) 0.0709(6) Uani 1 1 d . . . . .
F2 F 0.7821(3) 0.3454(3) 0.57080(12) 0.0732(7) Uani 1 1 d . . . . .
F3 F 0.5695(3) 0.2377(3) 0.52822(9) 0.0787(7) Uani 1 1 d . . . . .
N1 N 0.8519(3) 0.3761(3) 0.79619(12) 0.0440(6) Uani 1 1 d . . . . .
N2 N 1.0409(4) 0.1427(3) 0.84630(13) 0.0538(7) Uani 1 1 d . . . . .
N3 N 0.2498(4) 0.2456(3) 0.68279(15) 0.0521(7) Uani 1 1 d . . . . .
O1 O 0.6547(4) 0.0810(2) 0.71977(13) 0.0655(7) Uani 1 1 d . . . . .
O2 O 0.2887(4) 0.2657(3) 0.73589(13) 0.0750(8) Uani 1 1 d . . . . .
O3 O 0.1042(4) 0.2597(3) 0.66201(17) 0.0777(9) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 H1 0.9300 . ?
C1 C2 1.387(4) . ?
C1 C6 1.381(4) . ?
C2 H2 0.9300 . ?
C2 C3 1.371(4) . ?
C3 C4 1.369(5) . ?
C3 Cl1 1.747(3) . ?
C4 H4 0.9300 . ?
C4 C5 1.379(5) . ?
C5 H5 0.9300 . ?
C5 C6 1.394(4) . ?
C6 C7 1.550(4) . ?
C7 C8 1.547(4) . ?
C7 C14 1.549(4) . ?
C7 C15 1.539(4) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 C9 1.514(4) . ?
C9 C10 1.503(4) . ?
C9 O1 1.204(4) . ?
C10 C11 1.388(4) . ?
C10 N1 1.336(4) . ?
C11 H11 0.9300 . ?
C11 N2 1.327(4) . ?
C12 H12 0.9300 . ?
C12 C13 1.374(5) . ?
C12 N2 1.322(5) . ?
C13 H13 0.9300 . ?
C13 N1 1.325(4) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C14 N3 1.487(4) . ?
C15 F1 1.334(4) . ?
C15 F2 1.322(4) . ?
C15 F3 1.331(4) . ?
N3 O2 1.206(4) . ?
N3 O3 1.222(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 H1 119.2 . . ?
C6 C1 H1 119.2 . . ?
C6 C1 C2 121.6(3) . . ?
C1 C2 H2 120.5 . . ?
C3 C2 C1 118.9(3) . . ?
C3 C2 H2 120.5 . . ?
C2 C3 Cl1 119.4(2) . . ?
C4 C3 C2 121.3(3) . . ?
C4 C3 Cl1 119.4(2) . . ?
C3 C4 H4 120.5 . . ?
C3 C4 C5 119.0(3) . . ?
C5 C4 H4 120.5 . . ?
C4 C5 H5 119.2 . . ?
C4 C5 C6 121.6(3) . . ?
C6 C5 H5 119.2 . . ?
C1 C6 C5 117.4(3) . . ?
C1 C6 C7 121.9(2) . . ?
C5 C6 C7 120.5(3) . . ?
C8 C7 C6 110.3(2) . . ?
C8 C7 C14 113.9(2) . . ?
C14 C7 C6 111.6(2) . . ?
C15 C7 C6 106.6(2) . . ?
C15 C7 C8 108.4(2) . . ?
C15 C7 C14 105.6(2) . . ?
C7 C8 H8A 107.5 . . ?
C7 C8 H8B 107.5 . . ?
H8A C8 H8B 107.0 . . ?
C9 C8 C7 119.4(2) . . ?
C9 C8 H8A 107.5 . . ?
C9 C8 H8B 107.5 . . ?
C10 C9 C8 115.4(2) . . ?
O1 C9 C8 125.5(3) . . ?
O1 C9 C10 119.1(3) . . ?
C11 C10 C9 118.8(3) . . ?
N1 C10 C9 119.0(3) . . ?
N1 C10 C11 122.1(3) . . ?
C10 C11 H11 119.0 . . ?
N2 C11 C10 122.0(3) . . ?
N2 C11 H11 119.0 . . ?
C13 C12 H12 118.8 . . ?
N2 C12 H12 118.8 . . ?
N2 C12 C13 122.3(3) . . ?
C12 C13 H13 118.5 . . ?
N1 C13 C12 123.0(3) . . ?
N1 C13 H13 118.5 . . ?
C7 C14 H14A 109.2 . . ?
C7 C14 H14B 109.2 . . ?
H14A C14 H14B 107.9 . . ?
N3 C14 C7 112.2(2) . . ?
N3 C14 H14A 109.2 . . ?
N3 C14 H14B 109.2 . . ?
F1 C15 C7 113.0(3) . . ?
F2 C15 C7 112.0(3) . . ?
F2 C15 F1 106.5(3) . . ?
F2 C15 F3 106.7(3) . . ?
F3 C15 C7 112.3(3) . . ?
F3 C15 F1 105.8(3) . . ?
C13 N1 C10 114.9(3) . . ?
C12 N2 C11 115.7(3) . . ?
O2 N3 C14 118.2(3) . . ?
O2 N3 O3 124.6(3) . . ?
O3 N3 C14 117.1(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 2.7(5) . . . . ?
C1 C2 C3 Cl1 -176.8(2) . . . . ?
C1 C6 C7 C8 17.8(4) . . . . ?
C1 C6 C7 C14 145.4(3) . . . . ?
C1 C6 C7 C15 -99.8(3) . . . . ?
C2 C1 C6 C5 -1.7(4) . . . . ?
C2 C1 C6 C7 175.0(3) . . . . ?
C2 C3 C4 C5 -2.7(5) . . . . ?
C3 C4 C5 C6 0.4(5) . . . . ?
C4 C5 C6 C1 1.8(5) . . . . ?
C4 C5 C6 C7 -175.0(3) . . . . ?
C5 C6 C7 C8 -165.6(3) . . . . ?
C5 C6 C7 C14 -38.0(4) . . . . ?
C5 C6 C7 C15 76.8(3) . . . . ?
C6 C1 C2 C3 -0.5(5) . . . . ?
C6 C7 C8 C9 171.1(3) . . . . ?
C6 C7 C14 N3 -58.9(3) . . . . ?
C6 C7 C15 F1 -178.5(3) . . . . ?
C6 C7 C15 F2 61.2(3) . . . . ?
C6 C7 C15 F3 -58.9(3) . . . . ?
C7 C8 C9 C10 169.4(3) . . . . ?
C7 C8 C9 O1 -10.8(5) . . . . ?
C7 C14 N3 O2 -63.0(4) . . . . ?
C7 C14 N3 O3 118.0(3) . . . . ?
C8 C7 C14 N3 66.8(3) . . . . ?
C8 C7 C15 F1 62.8(3) . . . . ?
C8 C7 C15 F2 -57.5(3) . . . . ?
C8 C7 C15 F3 -177.6(3) . . . . ?
C8 C9 C10 C11 -164.6(3) . . . . ?
C8 C9 C10 N1 15.7(4) . . . . ?
C9 C10 C11 N2 -180.0(3) . . . . ?
C9 C10 N1 C13 179.7(3) . . . . ?
C10 C11 N2 C12 0.9(5) . . . . ?
C11 C10 N1 C13 0.0(4) . . . . ?
C12 C13 N1 C10 -0.4(5) . . . . ?
C13 C12 N2 C11 -1.4(5) . . . . ?
C14 C7 C8 C9 44.8(4) . . . . ?
C14 C7 C15 F1 -59.6(3) . . . . ?
C14 C7 C15 F2 -179.9(3) . . . . ?
C14 C7 C15 F3 60.0(3) . . . . ?
C15 C7 C8 C9 -72.4(3) . . . . ?
C15 C7 C14 N3 -174.3(3) . . . . ?
Cl1 C3 C4 C5 176.9(3) . . . . ?
N1 C10 C11 N2 -0.2(5) . . . . ?
N2 C12 C13 N1 1.2(5) . . . . ?
O1 C9 C10 C11 15.6(5) . . . . ?
O1 C9 C10 N1 -164.1(3) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
